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+{"segments": [{"id": 1, "seek": 4964, "start": 21.24, "end": 49.64, "text": "بسم الله الرحمن الرحيم موضوعنا اليوم عن ال stereochemistry ربما يعني انتوا اتشوقتوا اليها لان احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال isomers قسمناهم وقلنا هم نوعين اساسيين structural isomers او constitutional isomers سمناهم و stereo isomers", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 3714, 2407, 11242, 45367, 8315, 45595, 20498, 18871, 2423, 29029, 48353, 12602, 3555, 15042, 37495, 22653, 16472, 2655, 14407, 1975, 2655, 8592, 30543, 2655, 14407, 45595, 11296, 5296, 7649, 1975, 5016, 8315, 9154, 1975, 12610, 3714, 5016, 46958, 25720, 5296, 15042, 1975, 2655, 4117, 19528, 8315, 18871, 9673, 2655, 8592, 28820, 9307, 1975, 2407, 2423, 307, 298, 433, 12174, 38251, 8315, 16095, 4032, 4587, 1211, 8315, 8032, 2304, 8717, 45367, 9957, 24525, 32277, 1829, 9957, 15067, 307, 298, 433, 1975, 2407, 20176, 307, 298, 433, 8608, 2304, 8315, 16095, 4032, 29029, 307, 298, 433], 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"probability": 0.9534912109375}, {"start": 116.91, "end": 117.19, "word": " two", "probability": 0.79248046875}, {"start": 117.19, "end": 118.29, "word": " chloroborbine", "probability": 0.94384765625}, {"start": 118.29, "end": 119.05, "word": " هدولة", "probability": 0.8555908203125}, {"start": 119.05, "end": 119.65, "word": " اسمين", "probability": 0.9239908854166666}, {"start": 119.65, "end": 120.41, "word": " مختلفين", "probability": 0.993408203125}], "temperature": 1.0}, {"id": 5, "seek": 14297, "start": 121.3, "end": 142.98, "text": "الان الشيء التاني في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال stereo isomers المركبات اللى بتكون لها نفس الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا قولنا ال stereo isomers ال atoms they have the same constitution", "tokens": [6027, 7649, 25124, 1829, 38207, 16712, 7649, 1829, 8978, 2423, 307, 298, 433, 13672, 7578, 11331, 49975, 1975, 1829, 11242, 995, 47525, 8315, 8978, 3224, 13672, 7578, 31439, 2423, 29029, 307, 298, 433, 9673, 31747, 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138.36, "end": 138.74, "word": " stereo", "probability": 0.75244140625}, {"start": 138.74, "end": 139.52, "word": " isomers", "probability": 0.9814453125}, {"start": 139.52, "end": 140.2, "word": " ال", "probability": 0.90625}, {"start": 140.2, "end": 140.64, "word": " atoms", "probability": 0.78125}, {"start": 140.64, "end": 140.94, "word": " they", "probability": 0.78759765625}, {"start": 140.94, "end": 141.2, "word": " have", "probability": 0.970703125}, {"start": 141.2, "end": 141.4, "word": " the", "probability": 0.92138671875}, {"start": 141.4, "end": 141.88, "word": " same", "probability": 0.90087890625}, {"start": 141.88, "end": 142.98, "word": " constitution", "probability": 0.91748046875}], "temperature": 1.0}, {"id": 6, "seek": 16797, "start": 144.79, "end": 167.97, "text": "different arrangement in space بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis والترانس يعني مثلا عندنا اثين على موقع واحد كلور هاي اثين جزئي ب double bond على موقع واحد كلور وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه one two dichloro ethane", "tokens": [67, 15790, 17620, 294, 1901, 47525, 10721, 8315, 8978, 16095, 21542, 38436, 28671, 5296, 15042, 1975, 5016, 8315, 5551, 9778, 3215, 8315, 3714, 23557, 4117, 3555, 9307, 2423, 26288, 16070, 2655, 2288, 7649, 3794, 37495, 22653, 50113, 15040, 43242, 8315, 1975, 12984, 9957, 15844, 3714, 30543, 3615, 36764, 24401, 9122, 1211, 13063, 8032, 47302, 1975, 12984, 9957, 10874, 11622, 19986, 1829, 4724, 3834, 6086, 15844, 3714, 30543, 3615, 36764, 24401, 9122, 1211, 13063, 4032, 3615, 23942, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 9122, 1211, 13063, 46599, 1863, 16606, 15844, 29910, 23275, 13412, 2407, 39896, 9381, 13546, 24525, 2304, 3224, 472, 732, 10390, 6746, 78, 6468, 1929], "avg_logprob": -0.22149884852546234, "compression_ratio": 1.649789029535865, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 144.79, "end": 145.41, "word": "different", "probability": 0.537353515625}, {"start": 145.41, "end": 146.05, "word": " 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1225.82, "word": " ذرد", "probability": 0.5900065104166666}, {"start": 1225.82, "end": 1226.18, "word": " كاربون", "probability": 0.9237060546875}, {"start": 1226.18, "end": 1226.56, "word": " واحدة", "probability": 0.9679361979166666}, {"start": 1226.56, "end": 1227.02, "word": " بسرعة", "probability": 0.9873046875}], "temperature": 1.0}, {"id": 52, "seek": 123027, "start": 1227.81, "end": 1230.27, "text": "ميتين؟ شو بتحمل؟", "tokens": [2304, 36081, 9957, 22807, 13412, 2407, 39894, 35571, 1211, 22807], "avg_logprob": -0.22514205087314954, "compression_ratio": 0.7317073170731707, "no_speech_prob": 0.0, "words": [{"start": 1227.81, "end": 1228.97, "word": "ميتين؟", "probability": 0.7315673828125}, {"start": 1228.97, "end": 1229.47, "word": " شو", "probability": 0.69970703125}, {"start": 1229.47, "end": 1230.27, "word": " بتحمل؟", "probability": 0.959716796875}], "temperature": 1.0}, {"id": 53, "seek": 126117, "start": 1232.11, "end": 1261.17, "text": "مافيش غير الواحد ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم alphabetical مش هذي الف باقي التسمية يعني هذا الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو هيدروجيل", "tokens": [15042, 41185, 8592, 32771, 13546, 2423, 14407, 24401, 19446, 6055, 39648, 2407, 3224, 2407, 8592, 11933, 26890, 20498, 2407, 9122, 1211, 13063, 2407, 36632, 2407, 3215, 2407, 3714, 1829, 12984, 26895, 4032, 44945, 8848, 37983, 16095, 23339, 804, 37893, 8032, 8848, 1829, 27188, 4724, 995, 38436, 16712, 38251, 10632, 37495, 22653, 23758, 25724, 11622, 1829, 38207, 5296, 15042, 6055, 7435, 1829, 3555, 33251, 1829, 33599, 2407, 24525, 2304, 3224, 11933, 26890, 20498, 2407, 9122, 1211, 13063, 2407, 36632, 2407, 3215, 2407, 3714, 1829, 12984, 26895, 8978, 37893, 28820, 3660, 5296, 24401, 6024, 48506, 22807, 6024, 48506, 45164, 6225, 42213, 2655, 20328, 13063, 47395, 8978, 9673, 2288, 4587, 995, 3660, 37495, 22653, 3714, 3794, 4117, 47395, 30767, 1829, 39896, 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1270.14, "word": " ولا", "probability": 0.69775390625}, {"start": 1270.14, "end": 1270.64, "word": " لأ", "probability": 0.77783203125}, {"start": 1270.64, "end": 1273.52, "word": " واضح", "probability": 0.7862141927083334}, {"start": 1273.52, "end": 1274.46, "word": " صورة", "probability": 0.84716796875}, {"start": 1274.46, "end": 1274.74, "word": " بعض", "probability": 0.959716796875}, {"start": 1274.74, "end": 1274.9, "word": " في", "probability": 0.9345703125}, {"start": 1274.9, "end": 1275.26, "word": " المرأة", "probability": 0.9683837890625}, {"start": 1275.26, "end": 1275.54, "word": " مية", "probability": 0.71875}, {"start": 1275.54, "end": 1275.7, "word": " في", "probability": 0.73876953125}, {"start": 1275.7, "end": 1276.02, "word": " المية", "probability": 0.965576171875}, {"start": 1276.02, "end": 1276.48, "word": " طب", "probability": 0.78759765625}, {"start": 1276.48, "end": 1276.66, "word": " لو", "probability": 0.98974609375}, {"start": 1276.66, "end": 1276.98, "word": 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{"start": 1291.98, "end": 1292.52, "word": " الجملة", "probability": 0.9541015625}, {"start": 1292.52, "end": 1293.06, "word": " العامة", "probability": 0.9920247395833334}, {"start": 1293.06, "end": 1293.18, "word": " في", "probability": 0.8740234375}, {"start": 1293.18, "end": 1293.56, "word": " تعريف", "probability": 0.9767252604166666}, {"start": 1293.56, "end": 1293.66, "word": " ال", "probability": 0.85009765625}, {"start": 1293.66, "end": 1294.02, "word": " stereo", "probability": 0.1546630859375}, {"start": 1294.02, "end": 1294.7, "word": " isomers", "probability": 0.9578450520833334}, {"start": 1294.7, "end": 1294.88, "word": " they", "probability": 0.382080078125}, {"start": 1294.88, "end": 1295.1, "word": " have", "probability": 0.958984375}, {"start": 1295.1, "end": 1295.28, "word": " the", "probability": 0.9140625}, {"start": 1295.28, "end": 1295.54, "word": " same", "probability": 0.9150390625}, {"start": 1295.54, "end": 1296.06, "word": " bonding", "probability": 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1365.54, "end": 1384.42, "text": "هيدروجين و هيدروجين هدولة انطبقوا على بعض هدولة انطبقوا على بعض هدولة انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقوا", "tokens": [3224, 25708, 2288, 29245, 9957, 4032, 8032, 25708, 2288, 29245, 9957, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 8032, 3215, 12610, 3660, 16472, 9566, 3555, 4587, 14407, 15844, 45030, 11242, 20328, 5016, 22807, 2423, 7649, 8032, 3215, 12610, 3660, 6055, 29399, 26895, 9122, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 9122, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 4724, 9957, 9566, 3555, 4587, 14407, 22807, 20193, 4724, 9957, 9566, 3555, 4587, 14407], "avg_logprob": -0.193444290238878, "compression_ratio": 2.7452830188679247, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1365.54, "end": 1365.96, "word": "هيدروجين", "probability": 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{"start": 1393.56, "end": 1394.22, "word": " سنين،", "probability": 0.912841796875}, {"start": 1394.22, "end": 1394.54, "word": " خليهم", "probability": 0.9479166666666666}, {"start": 1394.54, "end": 1395.24, "word": " ينطبقوا", "probability": 0.9449055989583334}, {"start": 1395.24, "end": 1395.78, "word": " على", "probability": 0.8984375}, {"start": 1395.78, "end": 1397.16, "word": " بعض،", "probability": 0.9567057291666666}, {"start": 1397.16, "end": 1397.34, "word": " لا", "probability": 0.669921875}, {"start": 1397.34, "end": 1398.1, "word": " ينطبقوا", "probability": 0.9657389322916666}], "temperature": 1.0}, {"id": 61, "seek": 142567, "start": 1399.03, "end": 1425.67, "text": "واضح؟ إذا بدأت أكسر رابطتين و أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في الكيميا على ال enantiomers و ال enantiomers بتوجد لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة", "tokens": [2407, 46958, 5016, 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1411.71, "word": " بعض", "probability": 0.963134765625}, {"start": 1411.71, "end": 1411.87, "word": " في", "probability": 0.98681640625}, {"start": 1411.87, "end": 1413.01, "word": " المرآة،", "probability": 0.9110514322916666}, {"start": 1413.01, "end": 1413.37, "word": " فغير", "probability": 0.9645182291666666}, {"start": 1413.37, "end": 1414.49, "word": " متطابقين،", "probability": 0.96337890625}, {"start": 1414.49, "end": 1414.73, "word": " إذا", "probability": 0.80517578125}, {"start": 1414.73, "end": 1415.15, "word": " هذول", "probability": 0.7443033854166666}, {"start": 1415.15, "end": 1415.59, "word": " أول", "probability": 0.904541015625}, {"start": 1415.59, "end": 1416.15, "word": " مثال", "probability": 0.97119140625}, {"start": 1416.15, "end": 1416.33, "word": " في", "probability": 0.978515625}, {"start": 1416.33, "end": 1416.77, "word": " الكيميا", "probability": 0.8839518229166666}, {"start": 1416.77, "end": 1416.97, "word": " على", "probability": 0.427978515625}, {"start": 1416.97, "end": 1417.13, "word": " ال", "probability": 0.89306640625}, {"start": 1417.13, "end": 1417.85, "word": " enantiomers", "probability": 0.7738037109375}, {"start": 1417.85, "end": 1418.31, "word": " و", "probability": 0.48486328125}, {"start": 1418.31, "end": 1418.45, "word": " ال", "probability": 0.9267578125}, {"start": 1418.45, "end": 1419.25, "word": " enantiomers", "probability": 0.91455078125}, {"start": 1419.25, "end": 1420.11, "word": " بتوجد", "probability": 0.88818359375}, {"start": 1420.11, "end": 1420.61, "word": " لما", "probability": 0.887451171875}, {"start": 1420.61, "end": 1420.99, "word": " يكون", "probability": 0.989501953125}, {"start": 1420.99, "end": 1421.43, "word": " عند", "probability": 0.791015625}, {"start": 1421.43, "end": 1422.31, "word": " ذرة", "probability": 0.749267578125}, {"start": 1422.31, "end": 1422.95, "word": " carbon", "probability": 0.4033203125}, {"start": 1422.95, "end": 1423.59, "word": " تحمل", "probability": 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{"start": 1430.1, "end": 1430.22, "word": " في", "probability": 0.955078125}, {"start": 1430.22, "end": 1431.9, "word": " الكيمياء؟", "probability": 0.7681640625}, {"start": 1431.9, "end": 1432.1, "word": " إذا", "probability": 0.91552734375}, {"start": 1432.1, "end": 1432.44, "word": " وجد", "probability": 0.9453125}, {"start": 1432.44, "end": 1432.76, "word": " عندي", "probability": 0.6279296875}, {"start": 1432.76, "end": 1433.14, "word": " ذرّة", "probability": 0.6905517578125}, {"start": 1433.14, "end": 1433.5, "word": " كاربون", "probability": 0.753173828125}, {"start": 1433.5, "end": 1433.88, "word": " تحمل", "probability": 0.9736328125}, {"start": 1433.88, "end": 1434.2, "word": " أربع", "probability": 0.8987630208333334}, {"start": 1434.2, "end": 1434.76, "word": " مجموعات", "probability": 0.98115234375}, {"start": 1434.76, "end": 1435.46, "word": " مختلفة", "probability": 0.9947509765625}, {"start": 1435.46, "end": 1436.06, "word": " الآن", "probability": 0.6082763671875}, {"start": 1436.06, "end": 1436.5, "word": " هذه", "probability": 0.63525390625}, {"start": 1436.5, "end": 1437.12, "word": " الكاربون", "probability": 0.86572265625}, {"start": 1437.12, "end": 1437.76, "word": " بنسميها", "probability": 0.8717041015625}, {"start": 1437.76, "end": 1439.64, "word": " كايرالكاربون", "probability": 0.803955078125}, {"start": 1439.64, "end": 1441.16, "word": " إيش", "probability": 0.6906331380208334}, {"start": 1441.16, "end": 1442.3, "word": " بنسميها؟", "probability": 0.93623046875}, {"start": 1442.3, "end": 1443.76, "word": " كايرالكاربون", "probability": 0.96221923828125}, {"start": 1443.76, "end": 1444.4, "word": " أو", "probability": 0.8330078125}, {"start": 1444.4, "end": 1446.96, "word": " stereogenic", "probability": 0.678955078125}, {"start": 1446.96, "end": 1447.58, "word": " center", "probability": 0.76025390625}, {"start": 1447.58, "end": 1452.08, "word": " أو", "probability": 0.712890625}, {"start": 1452.08, "end": 1454.6, "word": " أحيانا", "probability": 0.92841796875}, {"start": 1454.6, "end": 1455.9, "word": " كايرالسنتر", "probability": 0.7957240513392857}], "temperature": 1.0}, {"id": 63, "seek": 147615, "start": 1456.87, "end": 1476.15, "text": "يعني هو يا مركز المشكلة أو مركز الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء شفتوها chiral carbon أو chiral center أو stereogenic center الفكرة فيها أن الكربون تحمل أربع مجموعات مختلفة", "tokens": [40228, 22653, 31439, 35186, 3714, 31747, 11622, 9673, 8592, 28820, 3660, 34051, 3714, 31747, 11622, 2423, 39184, 745, 323, 8997, 443, 5980, 4724, 10721, 1829, 9154, 29538, 16247, 38251, 16606, 13412, 5172, 2655, 2407, 11296, 8608, 2407, 16606, 13412, 5172, 2655, 2407, 11296, 23782, 304, 5954, 34051, 23782, 304, 3056, 34051, 12730, 25473, 3056, 27188, 4117, 25720, 8978, 11296, 14739, 33251, 25513, 11536, 6055, 35571, 1211, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660], "avg_logprob": -0.1307357530805129, "compression_ratio": 1.5502645502645502, 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"word": " هذه", "probability": 0.92822265625}, {"start": 1461.85, "end": 1462.39, "word": " الأسماء", "probability": 0.9825846354166666}, {"start": 1462.39, "end": 1462.93, "word": " شفتوها", "probability": 0.8708984375}, {"start": 1462.93, "end": 1463.41, "word": " سواء", "probability": 0.822265625}, {"start": 1463.41, "end": 1463.83, "word": " شفتوها", "probability": 0.959765625}, {"start": 1463.83, "end": 1464.33, "word": " chiral", "probability": 0.6884765625}, {"start": 1464.33, "end": 1464.87, "word": " carbon", "probability": 0.939453125}, {"start": 1464.87, "end": 1465.33, "word": " أو", "probability": 0.85888671875}, {"start": 1465.33, "end": 1465.95, "word": " chiral", "probability": 0.951416015625}, {"start": 1465.95, "end": 1466.43, "word": " center", "probability": 0.79443359375}, {"start": 1466.43, "end": 1466.91, "word": " أو", "probability": 0.87548828125}, {"start": 1466.91, "end": 1467.79, "word": " stereogenic", "probability": 0.682373046875}, {"start": 1467.79, "end": 1468.43, "word": " center", "probability": 0.91748046875}, {"start": 1468.43, "end": 1469.39, "word": " الفكرة", "probability": 0.9783528645833334}, {"start": 1469.39, "end": 1469.93, "word": " فيها", "probability": 0.98291015625}, {"start": 1469.93, "end": 1472.05, "word": " أن", "probability": 0.76611328125}, {"start": 1472.05, "end": 1472.67, "word": " الكربون", "probability": 0.9130859375}, {"start": 1472.67, "end": 1473.29, "word": " تحمل", "probability": 0.9918619791666666}, {"start": 1473.29, "end": 1473.99, "word": " أربع", "probability": 0.7916666666666666}, {"start": 1473.99, "end": 1475.53, "word": " مجموعات", "probability": 0.9552734375}, {"start": 1475.53, "end": 1476.15, "word": " مختلفة", "probability": 0.9940185546875}], "temperature": 1.0}, {"id": 64, "seek": 150338, "start": 1477.08, "end": 1503.38, "text": "لحظة أنا بحبش أني أتعبكم في صياغات لغوية the carbon carries four different groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير الشكل و صورته في المرأة غير متطابقين في هذه الحالة صاروا إيش", "tokens": [1211, 5016, 19913, 3660, 41850, 4724, 5016, 3555, 8592, 14739, 1829, 5551, 2655, 3615, 3555, 24793, 8978, 20328, 1829, 5718, 118, 9307, 5296, 17082, 2407, 10632, 264, 5954, 16402, 1451, 819, 3935, 29739, 5172, 32887, 11242, 4724, 3794, 6055, 5172, 16095, 14407, 9122, 19528, 3660, 11933, 1829, 8592, 5551, 25513, 27884, 4032, 39182, 9957, 30767, 1829, 19446, 4724, 1829, 39648, 25124, 45761, 2288, 4032, 4724, 28820, 5296, 17082, 9307, 16247, 43042, 6225, 26890, 14407, 18871, 11296, 9673, 16095, 11933, 1829, 8592, 29910, 25720, 33251, 25513, 11536, 6055, 35571, 1211, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 3555, 9381, 13546, 25124, 28820, 4032, 20328, 13063, 47395, 8978, 9673, 2288, 10721, 3660, 32771, 13546, 44650, 9566, 16758, 4587, 9957, 8978, 29538, 21542, 6027, 3660, 20328, 9640, 14407, 11933, 1829, 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