{"segments": [{"id": 1, "seek": 4665, "start": 20.67, "end": 46.65, "text": "بسم الله الرحمن الرحيم في موضوع الـ heterocyclic synthesis سبق إن اتكلمنا عن أكثر من طريقة عامة لتحضير الـ heterocyclic rings اتكلمنا عن الـ cyclization reactions بأنواعها المرة الماضية أعطينا مقدمة مختصرة لبأس بالمر عليها الآن في الـ cycloaddition reactions", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8978, 3714, 2407, 11242, 45367, 2423, 39184, 20789, 31078, 66, 1050, 30252, 8608, 3555, 4587, 36145, 1975, 2655, 4117, 19528, 8315, 18871, 5551, 4117, 49115, 9154, 23032, 16572, 28671, 6225, 10943, 3660, 5296, 2655, 5016, 11242, 13546, 2423, 39184, 20789, 31078, 66, 1050, 11136, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 39184, 19474, 2144, 12215, 4724, 33456, 14407, 3615, 11296, 9673, 25720, 9673, 46958, 10632, 5551, 3615, 9566, 1829, 8315, 3714, 28543, 46007, 3714, 46456, 9381, 25720, 5296, 3555, 10721, 3794, 20666, 29973, 25894, 11296, 6024, 48506, 8978, 2423, 39184, 38154, 2907, 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هيك", "probability": 0.97265625}, {"start": 72.21, "end": 72.47, "word": " لإن", "probability": 0.7687174479166666}, {"start": 72.47, "end": 72.63, "word": " في", "probability": 0.5478515625}, {"start": 72.63, "end": 72.91, "word": " عندي", "probability": 0.7445068359375}, {"start": 72.91, "end": 73.67, "word": " أناcyclic", "probability": 0.639892578125}, {"start": 73.67, "end": 74.39, "word": " intermediate", "probability": 0.9599609375}, {"start": 74.39, "end": 74.87, "word": " بتصير", "probability": 0.8992513020833334}, {"start": 74.87, "end": 75.33, "word": " بنحكي", "probability": 0.9052734375}, {"start": 75.33, "end": 75.61, "word": " عن", "probability": 0.97119140625}, {"start": 75.61, "end": 76.29, "word": " شيء", "probability": 0.778076171875}, {"start": 76.29, "end": 77.23, "word": " بنسميه", "probability": 0.8873291015625}, {"start": 77.23, "end": 78.21, "word": " pericyclic", "probability": 0.8011474609375}, {"start": 78.21, "end": 79.03, "word": " reactions", 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هو موازي للقلل بس ب triple bond القلل system double bond و بعدين single bond البروباريجيل", "tokens": [10721, 11622, 995, 25708, 30767, 1829, 19446, 8978, 43242, 24793, 20328, 2407, 16254, 20498, 5551, 11622, 995, 25708, 5296, 39319, 19913, 14407, 23758, 3714, 29245, 23328, 4724, 8592, 28820, 14739, 3224, 34105, 15508, 6086, 37037, 8315, 30767, 29245, 16247, 23275, 2655, 2288, 11536, 9307, 6225, 6024, 116, 23557, 11296, 3215, 37495, 22653, 3714, 29245, 23328, 4724, 8592, 28820, 2423, 26890, 37746, 9640, 1829, 7435, 26895, 6055, 3615, 28480, 14407, 2423, 26890, 37746, 9640, 1829, 7435, 26895, 13672, 1829, 31439, 3714, 2407, 31377, 1829, 24976, 4587, 1211, 1211, 4724, 3794, 4724, 15508, 6086, 25062, 1211, 1211, 1185, 3834, 6086, 4032, 39182, 9957, 2167, 6086, 2423, 26890, 37746, 9640, 1829, 7435, 26895], "avg_logprob": -0.29420045045045046, "compression_ratio": 1.9345794392523366, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 971.63, "end": 972.19, "word": "أزايد", 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1491.06, "word": " وانا", "probability": 0.8709309895833334}, {"start": 1491.06, "end": 1491.38, "word": " مافيش", "probability": 0.9181315104166666}, {"start": 1491.38, "end": 1491.64, "word": " عندى", "probability": 0.73095703125}, {"start": 1491.64, "end": 1492.18, "word": " ميكانيزم", "probability": 0.8846028645833334}, {"start": 1492.18, "end": 1492.5, "word": " بدون", "probability": 0.996826171875}, {"start": 1492.5, "end": 1493.02, "word": " ناتج", "probability": 0.98681640625}], "temperature": 1.0}, {"id": 65, "seek": 151423, "start": 1494.23, "end": 1514.23, "text": "يعني إنه حد يقعد يتخيل إنه هذا إجا وعمل هيك وعمل هيك واتفعل هيك وفي نهاية مافيش عنده ناتج فألف بقى أي ميكانيزم إن الإنسان يكون إيش فصل ناتج وفصل هذا الناتج بشكل سليم وصحيح واستطاع إنه يشخص", "tokens": [40228, 22653, 36145, 3224, 11331, 3215, 7251, 4587, 22488, 7251, 2655, 9778, 26895, 36145, 3224, 23758, 11933, 7435, 995, 4032, 25957, 1211, 39896, 4117, 4032, 25957, 1211, 39896, 4117, 4032, 9307, 5172, 30241, 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..", "probability": 0.269775390625}, {"start": 1540.38, "end": 1540.66, "word": " اذا", "probability": 0.761474609375}, {"start": 1540.66, "end": 1541.86, "word": " صياغة", "probability": 0.92109375}, {"start": 1541.86, "end": 1542.56, "word": " الكلام", "probability": 0.9674479166666666}, {"start": 1542.56, "end": 1543.04, "word": " بدأ", "probability": 0.4788818359375}, {"start": 1543.04, "end": 1543.24, "word": " تكون", "probability": 0.7259521484375}, {"start": 1543.24, "end": 1543.7, "word": " بالشكل", "probability": 0.9357096354166666}, {"start": 1543.7, "end": 1544.3, "word": " القادم", "probability": 0.6769205729166666}], "temperature": 1.0}, {"id": 67, "seek": 156024, "start": 1545.2, "end": 1560.24, "text": "لأنه انا في الناتج مثلا في التفاعلات اللي يقول عنها SN1 لأنه انا في الناتج لاحظت انه ال nucleophile ايجا مش محل ال X بس تنتج انه في rearrangement", "tokens": [1211, 33456, 3224, 1975, 8315, 8978, 28239, 9307, 7435, 50113, 15040, 8978, 16712, 5172, 995, 30241, 9307, 13672, 1829, 7251, 39648, 18871, 11296, 13955, 16, 5296, 33456, 3224, 1975, 8315, 8978, 28239, 9307, 7435, 20193, 5016, 19913, 2655, 16472, 3224, 2423, 14962, 49242, 1975, 1829, 7435, 995, 37893, 3714, 5016, 1211, 2423, 1783, 4724, 3794, 6055, 29399, 7435, 16472, 3224, 8978, 39568, 518], "avg_logprob": -0.2536621098406613, "compression_ratio": 1.5496688741721854, "no_speech_prob": 0.0, "words": [{"start": 1545.2, "end": 1546.0, "word": "لأنه", "probability": 0.5616455078125}, {"start": 1546.0, "end": 1546.38, "word": " انا", "probability": 0.6239013671875}, {"start": 1546.38, "end": 1546.6, "word": " في", "probability": 0.939453125}, {"start": 1546.6, "end": 1547.36, "word": " الناتج", "probability": 0.8152669270833334}, {"start": 1547.36, "end": 1547.92, "word": " مثلا", "probability": 0.91259765625}, {"start": 1547.92, "end": 1548.24, "word": " في", "probability": 0.95361328125}, {"start": 1548.24, "end": 1549.42, "word": " التفاعلات", "probability": 0.9177734375}, {"start": 1549.42, "end": 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نموجة وماقطعتش اطلاقا من خلال ايش هذه ال orbitals الان ال orbital التاني بهذا الشكل بده يكون و لو تخيلنا ان في عندنا نموجة كام ند بدها تعمل", "tokens": [14407, 24401, 3660, 2423, 7649, 39182, 39896, 4117, 4032, 39894, 28543, 2288, 14407, 6055, 2655, 9778, 26895, 14407, 23032, 3555, 3615, 995, 1975, 15730, 16472, 2655, 14407, 44650, 15730, 37983, 9957, 9122, 33456, 3224, 1975, 8315, 43242, 11296, 8717, 2304, 29245, 3660, 4032, 15042, 47432, 34268, 8592, 1975, 9566, 15040, 4587, 995, 9154, 16490, 1211, 6027, 1975, 1829, 8592, 29538, 2423, 50015, 2423, 7649, 2423, 27677, 16712, 7649, 1829, 39627, 15730, 25124, 28820, 47525, 3224, 7251, 30544, 4032, 45164, 6055, 9778, 26895, 8315, 16472, 8978, 43242, 8315, 8717, 2304, 29245, 3660, 9122, 10943, 8717, 3215, 47525, 11296, 6055, 25957, 1211], "avg_logprob": -0.22230816654639668, "compression_ratio": 1.8155339805825244, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2058.02, "end": 2058.82, "word": "واحدة", "probability": 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ال", "probability": 0.978515625}, {"start": 2072.96, "end": 2073.42, "word": " orbital", "probability": 0.876953125}, {"start": 2073.42, "end": 2074.04, "word": " التاني", "probability": 0.92822265625}, {"start": 2074.04, "end": 2074.54, "word": " بهذا", "probability": 0.9384765625}, {"start": 2074.54, "end": 2074.98, "word": " الشكل", "probability": 0.98486328125}, {"start": 2074.98, "end": 2075.3, "word": " بده", "probability": 0.65869140625}, {"start": 2075.3, "end": 2075.74, "word": " يكون", "probability": 0.98828125}, {"start": 2075.74, "end": 2077.88, "word": " و", "probability": 0.677734375}, {"start": 2077.88, "end": 2078.04, "word": " لو", "probability": 0.92138671875}, {"start": 2078.04, "end": 2078.64, "word": " تخيلنا", "probability": 0.98681640625}, {"start": 2078.64, "end": 2078.86, "word": " ان", "probability": 0.86572265625}, {"start": 2078.86, "end": 2079.08, "word": " في", "probability": 0.568359375}, {"start": 2079.08, "end": 2079.44, "word": " عندنا", "probability": 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phases متعاكسة اذا هذا ال homo بنفع يتفعل مع هذا ال homo بالتأكيد طب لو اجيت لل homo لل dibolarophile ال phases جهة واحدة و ال homo هنا طلعت الأطراف التفاعل على الأطراف الطرفين خضر و الطرفين", "tokens": [995, 30544, 14407, 30767, 1829, 45030, 11242, 34105, 2423, 18764, 44650, 3615, 995, 4117, 3794, 3660, 4032, 34105, 2423, 18764, 44650, 3615, 995, 4117, 3794, 3660, 1975, 15730, 23758, 2423, 3655, 78, 44945, 5172, 3615, 7251, 2655, 5172, 30241, 20449, 23758, 2423, 3655, 78, 20666, 2655, 10721, 4117, 25708, 23032, 3555, 45164, 1975, 7435, 36081, 24976, 3655, 78, 24976, 23064, 15276, 49242, 2423, 18764, 10874, 3224, 3660, 36764, 24401, 3660, 4032, 2423, 3655, 78, 34105, 23032, 1211, 34268, 16247, 9566, 23557, 5172, 16712, 5172, 995, 30241, 15844, 16247, 9566, 23557, 5172, 41950, 28480, 9957, 16490, 11242, 2288, 4032, 41950, 28480, 9957], "avg_logprob": -0.16038603233356102, "compression_ratio": 1.943298969072165, "no_speech_prob": 0.0, "words": [{"start": 2176.62, "end": 2177.08, "word": 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"probability": 0.9921875}, {"start": 2188.34, "end": 2188.84, "word": " اجيت", "probability": 0.78662109375}, {"start": 2188.84, "end": 2189.3, "word": " لل", "probability": 0.90966796875}, {"start": 2189.3, "end": 2190.04, "word": " homo", "probability": 0.9775390625}, {"start": 2190.04, "end": 2190.46, "word": " لل", "probability": 0.9326171875}, {"start": 2190.46, "end": 2191.88, "word": " dibolarophile", "probability": 0.6125081380208334}, {"start": 2191.88, "end": 2192.64, "word": " ال", "probability": 0.82666015625}, {"start": 2192.64, "end": 2193.2, "word": " phases", "probability": 0.9736328125}, {"start": 2193.2, "end": 2194.1, "word": " جهة", "probability": 0.9475911458333334}, {"start": 2194.1, "end": 2194.76, "word": " واحدة", "probability": 0.9817708333333334}, {"start": 2194.76, "end": 2195.22, "word": " و", "probability": 0.83984375}, {"start": 2195.22, "end": 2195.76, "word": " ال", "probability": 0.962890625}, {"start": 2195.76, "end": 2196.18, "word": " homo", 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Lomo و هذا الـ Homo و هذا الـ Lomo ممكن يتفاعلوا فالاحتمالين من ناحية ال phases سالمين مافيش فيهم ولا مشكلة التفاعل ممكن يتم بين الـ Homo للـ Dipole مع الـ Lomo للـ Dipolarophile أو الـ Lomo للـ Dipole مع الـ Homo للـ Dipolarophile", "tokens": [10721, 1829, 11242, 14111, 995, 23758, 2423, 39184, 441, 13395, 4032, 23758, 2423, 39184, 389, 13395, 4032, 23758, 2423, 39184, 441, 13395, 3714, 43020, 7251, 2655, 5172, 995, 30241, 14407, 6156, 6027, 995, 33753, 2304, 6027, 9957, 9154, 8717, 39319, 10632, 2423, 18764, 8608, 45340, 9957, 19446, 41185, 8592, 8978, 16095, 49429, 37893, 28820, 3660, 16712, 5172, 995, 30241, 3714, 43020, 7251, 39237, 49374, 2423, 39184, 389, 13395, 24976, 39184, 33486, 4812, 20449, 2423, 39184, 441, 13395, 24976, 39184, 33486, 15276, 49242, 34051, 2423, 39184, 441, 13395, 24976, 39184, 33486, 4812, 20449, 2423, 39184, 389, 13395, 24976, 39184, 33486, 15276, 49242], "avg_logprob": -0.23422181124196334, "compression_ratio": 2.066666666666667, "no_speech_prob": 0.0, 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2505.29, "end": 2525.49, "text": "ممنوع و بناء على ذلك لو انتوا انا كنتوا متخيلين مثلا زي ما كتبنا R1 و R3 هذا بدون تفاعل ال R1 و ال R3 تبعونه بتغيروا اه الآن بدنا نرجع لسؤال من ال organic القديمة من ال organic القديمة هو الدوران وين كان ممنوع", "tokens": [2304, 27842, 45367, 4032, 44945, 16606, 15844, 29910, 23275, 45164, 16472, 2655, 14407, 1975, 8315, 9122, 29399, 14407, 44650, 9778, 26895, 9957, 50113, 15040, 30767, 1829, 19446, 9122, 2655, 3555, 8315, 497, 16, 4032, 497, 18, 23758, 47525, 11536, 6055, 5172, 995, 30241, 2423, 497, 16, 4032, 2423, 497, 18, 6055, 3555, 3615, 11536, 3224, 39894, 17082, 13546, 14407, 1975, 3224, 6024, 48506, 47525, 8315, 8717, 47341, 3615, 5296, 3794, 33604, 6027, 9154, 2423, 10220, 25062, 16254, 46007, 9154, 2423, 10220, 25062, 16254, 46007, 31439, 32748, 13063, 7649, 4032, 9957, 25961, 3714, 27842, 45367], "avg_logprob": -0.14276315193427236, "compression_ratio": 1.7868020304568528, "no_speech_prob": 1.8477439880371094e-06, "words": [{"start": 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نقدر بسهولة نقول أن الفتوة مش صحيحة لأنه ليس من أهل الفتوة وليس من أهل العلم لكن يوم ما ييجي عالم كبير", "tokens": [10721, 39648, 6156, 2655, 2407, 3660, 50113, 15040, 8717, 28543, 2288, 4724, 3794, 3224, 12610, 3660, 8717, 39648, 14739, 27188, 2655, 2407, 3660, 37893, 20328, 5016, 1829, 5016, 3660, 5296, 33456, 3224, 32239, 3794, 9154, 5551, 3224, 1211, 27188, 2655, 2407, 3660, 4032, 20292, 3794, 9154, 5551, 3224, 1211, 18863, 19528, 44381, 7251, 20498, 19446, 7251, 1829, 7435, 1829, 6225, 45340, 9122, 3555, 13546], "avg_logprob": -0.22115384615384615, "compression_ratio": 1.7073170731707317, "no_speech_prob": 1.0132789611816406e-06, "words": [{"start": 2923.02, "end": 2923.98, "word": "أقول", "probability": 0.6182861328125}, {"start": 2923.98, "end": 2924.94, "word": " فتوة", "probability": 0.76171875}, {"start": 2924.94, "end": 2925.58, "word": " مثلا", "probability": 0.88818359375}, {"start": 2925.58, "end": 2927.06, "word": " نقدر", "probability": 0.6056315104166666}, {"start": 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صحيه ولا لأ تماما زي لما بيجي المفتى بيحكي فتوة كان إنسان بيجيبله طرف حديث", "tokens": [4587, 995, 22488, 4032, 11778, 9640, 3794, 2423, 15902, 4032, 6156, 16095, 7649, 4032, 3714, 47283, 3215, 11778, 4117, 2655, 13063, 40294, 4032, 4724, 1829, 34740, 7435, 23032, 15040, 3555, 11778, 4117, 2655, 13063, 40294, 4032, 7251, 38149, 2288, 5016, 15902, 39627, 15730, 25124, 28820, 23032, 3555, 31439, 37495, 22653, 8032, 1211, 7435, 36081, 29538, 25124, 17082, 37977, 11778, 9640, 2655, 11933, 23275, 4032, 19446, 3215, 9640, 2655, 8592, 11933, 43761, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 20328, 5016, 1829, 3224, 49429, 5296, 10721, 46811, 10943, 995, 30767, 1829, 5296, 15042, 4724, 1829, 7435, 1829, 9673, 5172, 49975, 4724, 1829, 5016, 4117, 1829, 6156, 2655, 2407, 3660, 25961, 36145, 3794, 7649, 4724, 1829, 7435, 1829, 36150, 3224, 23032, 28480, 11331, 16254, 12984], "avg_logprob": -0.13356855403511755, "compression_ratio": 1.7435897435897436, "no_speech_prob": 0.0, "words": [{"start": 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الرابطة و by radical هذا ال by radical ممكن يعمل cyclization بهذا الشكل و ممكن يعمل rotation followed by cyclization الان بالحسابات اللى كان بيعملها firestone بيقول ان الزمن اللى لازم", "tokens": [7649, 995, 1975, 12610, 19446, 20328, 9640, 43242, 7578, 29538, 34892, 16758, 9566, 3660, 4032, 538, 12001, 23758, 2423, 538, 12001, 3714, 43020, 7251, 25957, 1211, 19474, 2144, 39627, 15730, 25124, 28820, 4032, 3714, 43020, 7251, 25957, 1211, 12447, 6263, 538, 19474, 2144, 2423, 7649, 20666, 5016, 3794, 16758, 9307, 13672, 7578, 25961, 4724, 1829, 25957, 1211, 11296, 2610, 11243, 4724, 1829, 39648, 16472, 6024, 110, 27842, 13672, 7578, 5296, 31377, 2304], "avg_logprob": -0.21104452381395314, "compression_ratio": 1.6994535519125684, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 3260.97, "end": 3261.67, "word": "انا", "probability": 0.52447509765625}, {"start": 3261.67, "end": 3262.07, "word": " اول", "probability": 0.921630859375}, {"start": 3262.07, "end": 3262.33, "word": " 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"text": "لا الـ cyclization أقل كتير من الزمن اللي لازم لل rotation ولذلك هو بيقول انه بالحسابات تبعته هذا بيسكر قبل ما يلوف إذا كان بيسكر قبل ما يلوف لغ هذا الاحتمال إذا طلع الناتج حط تفسير واضح الفكرة فطالما ان هو بيقول قبل ما يلحق يلوف بيكون قمل cyclization", "tokens": [15040, 2423, 39184, 19474, 2144, 5551, 4587, 1211, 9122, 2655, 13546, 9154, 6024, 110, 27842, 13672, 1829, 5296, 31377, 2304, 24976, 12447, 35525, 8848, 23275, 31439, 4724, 1829, 39648, 16472, 3224, 20666, 5016, 3794, 16758, 9307, 6055, 3555, 34268, 3224, 23758, 4724, 1829, 3794, 37983, 12174, 36150, 19446, 7251, 1211, 38688, 11933, 15730, 25961, 4724, 1829, 3794, 37983, 12174, 36150, 19446, 7251, 1211, 38688, 5296, 17082, 23758, 42963, 33753, 2304, 6027, 11933, 15730, 23032, 1211, 3615, 28239, 9307, 7435, 11331, 9566, 6055, 36178, 13546, 4032, 46958, 5016, 27188, 4117, 25720, 6156, 9566, 6027, 15042, 16472, 31439, 4724, 1829, 39648, 12174, 36150, 19446, 7251, 1211, 5016, 4587, 7251, 1211, 38688, 4724, 1829, 30544, 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"temperature": 1.0}, {"id": 143, "seek": 339497, "start": 3368.21, "end": 3394.97, "text": "يعني فكرة أنه نتخيل أنه نقول هذه ال mechanism عامة تصلح لكل ال one three bipolar cycle addition reactions يعني فكرة غير سليمة من ناحية بحتها ولذلك كل التفاعل يجب أن يدرس ويفهم هل يا ترى أنا شوفت فيه free radicals ولا ماشوفتش فيه free radicals اليوم بنقدر نقول القاتل من مجمل", "tokens": [40228, 22653, 6156, 4117, 25720, 14739, 3224, 8717, 2655, 9778, 26895, 14739, 3224, 8717, 39648, 29538, 2423, 7513, 6225, 10943, 3660, 6055, 36520, 5016, 5296, 28820, 2423, 472, 1045, 42469, 6586, 4500, 12215, 37495, 22653, 6156, 4117, 25720, 32771, 13546, 8608, 20292, 46007, 9154, 8717, 39319, 10632, 4724, 33753, 11296, 35525, 8848, 23275, 28242, 16712, 5172, 995, 30241, 7251, 7435, 3555, 14739, 7251, 3215, 2288, 3794, 4032, 33911, 16095, 8032, 1211, 35186, 6055, 2288, 7578, 41850, 13412, 38688, 2655, 8978, 3224, 1737, 12001, 82, 49429, 19446, 8592, 38688, 2655, 8592, 8978, 3224, 1737, 12001, 82, 45595, 20498, 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"word": " فكرة", "probability": 0.8683268229166666}, {"start": 3437.69, "end": 3438.25, "word": " أكمل", "probability": 0.88623046875}, {"start": 3438.25, "end": 3438.91, "word": " المعادلة", "probability": 0.974853515625}, {"start": 3438.91, "end": 3439.13, "word": " ان", "probability": 0.487060546875}, {"start": 3439.13, "end": 3439.25, "word": " ال", "probability": 0.5791015625}, {"start": 3439.25, "end": 3439.65, "word": " mechanism", "probability": 0.9150390625}, {"start": 3439.65, "end": 3439.89, "word": " of", "probability": 0.97216796875}, {"start": 3439.89, "end": 3440.03, "word": " the", "probability": 0.70703125}, {"start": 3440.03, "end": 3440.51, "word": " reaction", "probability": 0.91845703125}], "temperature": 1.0}, {"id": 146, "seek": 346943, "start": 3441.87, "end": 3469.43, "text": "انه سهم اتنين تلاتة هذا الكلام غير مقبول اطلاقا من طالب سنة رابعة انه يقول انه this is a mechanism of deal الكلام نفسه بالظبط وعشانك مش هنشرحه مرة ثانية في deals elder reaction بمعنى في deals elder reaction هنرسم orbitals ونشوف ان هدولة ممكن يعملوا", "tokens": [7649, 3224, 8608, 16095, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 23758, 2423, 28820, 10943, 32771, 13546, 3714, 4587, 3555, 12610, 1975, 9566, 15040, 4587, 995, 9154, 23032, 6027, 3555, 8608, 1863, 3660, 12602, 16758, 27884, 16472, 3224, 7251, 39648, 16472, 3224, 341, 307, 257, 7513, 295, 2028, 2423, 28820, 10943, 8717, 36178, 3224, 20666, 19913, 3555, 9566, 4032, 3615, 8592, 7649, 4117, 37893, 8032, 1863, 46309, 5016, 3224, 3714, 25720, 38637, 7649, 10632, 8978, 11215, 12995, 5480, 4724, 2304, 3615, 1863, 7578, 8978, 11215, 12995, 5480, 8032, 1863, 2288, 38251, 50015, 4032, 1863, 8592, 38688, 16472, 8032, 3215, 12610, 3660, 3714, 43020, 7251, 25957, 1211, 14407], "avg_logprob": -0.133314213621507, "compression_ratio": 1.6812227074235808, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 3441.87, "end": 3442.21, "word": "انه", "probability": 0.646728515625}, {"start": 3442.21, "end": 3442.51, 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357958, "start": 3552.3, "end": 3579.58, "text": "في الـ 1,3-dipolar cycloadditions ولذلك لو كانوا ناس بيحكوا بمنطق العمومية فبتلاقوه بمنطق العمومية بيقولوا most of the 1,3-dipolar cycloadditions reactions proceed by a concerted mechanism معظمها بتمشي ب concerted mechanism في ال deals altered أقل في نسبة لبأس بها فعلا مثبتة وموجودة وبتمشي بإيش؟", "tokens": [41185, 2423, 39184, 502, 11, 18, 12, 67, 647, 15276, 38154, 2907, 67, 2451, 35525, 8848, 23275, 45164, 25961, 14407, 8717, 32277, 4724, 1829, 5016, 4117, 14407, 4724, 27842, 9566, 4587, 18863, 2304, 20498, 10632, 6156, 3555, 2655, 15040, 4587, 2407, 3224, 4724, 27842, 9566, 4587, 18863, 2304, 20498, 10632, 4724, 1829, 39648, 14407, 881, 295, 264, 502, 11, 18, 12, 67, 647, 15276, 38154, 2907, 67, 2451, 12215, 8991, 538, 257, 8543, 292, 7513, 20449, 19913, 2304, 11296, 39894, 2304, 8592, 1829, 4724, 8543, 292, 7513, 8978, 2423, 11215, 28783, 5551, 4587, 1211, 8978, 8717, 35457, 3660, 5296, 3555, 10721, 3794, 4724, 11296, 6156, 3615, 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"probability": 0.916015625}, {"start": 3569.1, "end": 3569.64, "word": " concerted", "probability": 0.869384765625}, {"start": 3569.64, "end": 3570.12, "word": " mechanism", "probability": 0.95751953125}, {"start": 3570.12, "end": 3570.5, "word": " في", "probability": 0.79443359375}, {"start": 3570.5, "end": 3570.6, "word": " ال", "probability": 0.72412109375}, {"start": 3570.6, "end": 3570.84, "word": " deals", "probability": 0.85546875}, {"start": 3570.84, "end": 3571.36, "word": " altered", "probability": 0.350341796875}, {"start": 3571.36, "end": 3572.5, "word": " أقل", "probability": 0.86181640625}, {"start": 3572.5, "end": 3572.86, "word": " في", "probability": 0.63916015625}, {"start": 3572.86, "end": 3573.5, "word": " نسبة", "probability": 0.90185546875}, {"start": 3573.5, "end": 3574.18, "word": " لبأس", "probability": 0.88916015625}, {"start": 3574.18, "end": 3574.68, "word": " بها", "probability": 0.964111328125}, {"start": 3574.68, "end": 3575.78, "word": " فعلا", "probability": 0.88671875}, {"start": 3575.78, "end": 3576.58, "word": " مثبتة", "probability": 0.87265625}, {"start": 3576.58, "end": 3578.02, "word": " وموجودة", "probability": 0.96611328125}, {"start": 3578.02, "end": 3579.02, "word": " وبتمشي", "probability": 0.85322265625}, {"start": 3579.02, "end": 3579.58, "word": " بإيش؟", "probability": 0.90546875}], "temperature": 1.0}, {"id": 152, "seek": 359537, "start": 3580.33, "end": 3595.37, "text": "بي راديكال ميكانيزم الان ال homework اللى انا بدي اكو تتعبوا فيه حقيقة انه من الأشياء اللى اتدرست اجيبولي مثال على ال one three dipolar cycloaddition", "tokens": [21292, 12602, 18513, 1829, 4117, 6027, 3714, 1829, 41361, 1829, 11622, 2304, 2423, 7649, 2423, 14578, 13672, 7578, 1975, 8315, 4724, 16254, 1975, 4117, 2407, 6055, 2655, 3615, 3555, 14407, 8978, 3224, 11331, 38436, 28671, 16472, 3224, 9154, 16247, 8592, 1829, 16606, 13672, 7578, 1975, 2655, 3215, 2288, 3794, 2655, 1975, 7435, 1829, 3555, 12610, 1829, 50113, 6027, 15844, 2423, 472, 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0.6513671875}, {"start": 3584.91, "end": 3585.45, "word": " تتعبوا", "probability": 0.880078125}, {"start": 3585.45, "end": 3585.67, "word": " فيه", "probability": 0.93505859375}, {"start": 3585.67, "end": 3586.27, "word": " حقيقة", "probability": 0.7754720052083334}, {"start": 3586.27, "end": 3587.25, "word": " انه", "probability": 0.91259765625}, {"start": 3587.25, "end": 3587.59, "word": " من", "probability": 0.978515625}, {"start": 3587.59, "end": 3588.15, "word": " الأشياء", "probability": 0.9146728515625}, {"start": 3588.15, "end": 3588.39, "word": " اللى", "probability": 0.820556640625}, {"start": 3588.39, "end": 3589.17, "word": " اتدرست", "probability": 0.7318115234375}, {"start": 3589.17, "end": 3590.23, "word": " اجيبولي", "probability": 0.849365234375}, {"start": 3590.23, "end": 3591.51, "word": " مثال", "probability": 0.98681640625}, {"start": 3591.51, "end": 3593.05, "word": " على", "probability": 0.36279296875}, {"start": 3593.05, "end": 3593.15, "word": " ال", "probability": 0.8916015625}, {"start": 3593.15, "end": 3593.25, "word": " one", "probability": 0.38525390625}, {"start": 3593.25, "end": 3593.57, "word": " three", "probability": 0.7998046875}, {"start": 3593.57, "end": 3594.17, "word": " dipolar", "probability": 0.6494140625}, {"start": 3594.17, "end": 3595.37, "word": " cycloaddition", "probability": 0.686279296875}], "temperature": 1.0}, {"id": 153, "seek": 361678, "start": 3596.58, "end": 3616.78, "text": "أو على ال deals elder reaction مشي ب by radical mechanism يعني شخص بيعمل mechanistic study ودرس وبيقول هي ال ESR و هي شفت ال free radicals و ما إلى ذلك و تجيبولنا و تشوفوا كيف ال mechanistic study هي في نهاية علم", "tokens": [10721, 2407, 15844, 2423, 11215, 12995, 5480, 37893, 1829, 4724, 538, 12001, 7513, 37495, 22653, 13412, 9778, 9381, 4724, 1829, 25957, 1211, 4236, 3142, 2979, 4032, 3215, 2288, 3794, 4032, 21292, 39648, 39896, 2423, 12564, 49, 4032, 39896, 13412, 5172, 2655, 2423, 1737, 12001, 82, 4032, 19446, 30731, 29910, 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0.1724853515625}, {"start": 3600.3, "end": 3600.8, "word": " radical", "probability": 0.869140625}, {"start": 3600.8, "end": 3601.66, "word": " mechanism", "probability": 0.880859375}, {"start": 3601.66, "end": 3602.52, "word": " يعني", "probability": 0.8720703125}, {"start": 3602.52, "end": 3603.0, "word": " شخص", "probability": 0.9833984375}, {"start": 3603.0, "end": 3603.8, "word": " بيعمل", "probability": 0.9639892578125}, {"start": 3603.8, "end": 3604.82, "word": " mechanistic", "probability": 0.5999755859375}, {"start": 3604.82, "end": 3605.38, "word": " study", "probability": 0.970703125}, {"start": 3605.38, "end": 3606.06, "word": " ودرس", "probability": 0.863525390625}, {"start": 3606.06, "end": 3606.38, "word": " وبيقول", "probability": 0.66943359375}, {"start": 3606.38, "end": 3606.56, "word": " هي", "probability": 0.370361328125}, {"start": 3606.56, "end": 3606.72, "word": " ال", "probability": 0.87451171875}, {"start": 3606.72, "end": 3607.62, "word": " ESR", "probability": 0.85498046875}, {"start": 3607.62, "end": 3607.76, "word": " و", "probability": 0.873046875}, {"start": 3607.76, "end": 3607.9, "word": " هي", "probability": 0.225341796875}, {"start": 3607.9, "end": 3608.36, "word": " شفت", "probability": 0.7703450520833334}, {"start": 3608.36, "end": 3608.48, "word": " ال", "probability": 0.880859375}, {"start": 3608.48, "end": 3608.76, "word": " free", "probability": 0.94775390625}, {"start": 3608.76, "end": 3609.74, "word": " radicals", "probability": 0.863037109375}, {"start": 3609.74, "end": 3609.86, "word": " و", "probability": 0.95849609375}, {"start": 3609.86, "end": 3610.0, "word": " ما", "probability": 0.68115234375}, {"start": 3610.0, "end": 3610.28, "word": " إلى", "probability": 0.9072265625}, {"start": 3610.28, "end": 3610.94, "word": " ذلك", "probability": 0.994873046875}, {"start": 3610.94, "end": 3612.16, "word": " و", "probability": 0.493896484375}, {"start": 3612.16, "end": 3612.86, "word": " تجيبولنا", "probability": 0.8736979166666666}, {"start": 3612.86, "end": 3613.42, "word": " و", "probability": 0.654296875}, {"start": 3613.42, "end": 3613.86, "word": " تشوفوا", "probability": 0.9952392578125}, {"start": 3613.86, "end": 3614.16, "word": " كيف", "probability": 0.973876953125}, {"start": 3614.16, "end": 3614.4, "word": " ال", "probability": 0.98193359375}, {"start": 3614.4, "end": 3615.06, "word": " mechanistic", "probability": 0.946533203125}, {"start": 3615.06, "end": 3615.54, "word": " study", "probability": 0.974609375}, {"start": 3615.54, "end": 3616.0, "word": " هي", "probability": 0.87646484375}, {"start": 3616.0, "end": 3616.12, "word": " في", "probability": 0.8701171875}, {"start": 3616.12, "end": 3616.38, "word": " نهاية", "probability": 0.8072916666666666}, {"start": 3616.38, "end": 3616.78, "word": " علم", "probability": 0.940185546875}], "temperature": 1.0}, {"id": 154, "seek": 364325, "start": 3617.59, "end": 3643.25, "text": "كامل متكامل بدنا مثال على one three dipolar cycloaddition reaction او Diels alder reaction مش باش بال by radical mechanism او stepwise mechanism كل الكلام هذا اللي احنا جوابناه بتعلق بأي نقطة نقطة ال stereo selectivity لسه ماحكيناش عن", "tokens": [4117, 10943, 1211, 44650, 4117, 10943, 1211, 47525, 8315, 50113, 6027, 15844, 472, 1045, 10460, 15276, 38154, 2907, 67, 849, 5480, 1975, 2407, 413, 44189, 16798, 260, 5480, 37893, 4724, 33599, 20666, 538, 12001, 7513, 1975, 2407, 1823, 3711, 7513, 28242, 2423, 28820, 10943, 23758, 13672, 1829, 1975, 5016, 8315, 10874, 14407, 3555, 8315, 3224, 39894, 30241, 4587, 4724, 10721, 1829, 8717, 47432, 3660, 8717, 47432, 3660, 2423, 29029, 3048, 4253, 5296, 3794, 3224, 19446, 5016, 4117, 1829, 8315, 8592, 18871], "avg_logprob": -0.291349082821753, "compression_ratio": 1.5069767441860464, "no_speech_prob": 0.0, "words": [{"start": 3617.59, "end": 3618.11, "word": "كامل", "probability": 0.7356770833333334}, {"start": 3618.11, "end": 3618.93, "word": " متكامل", "probability": 0.908935546875}, 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N", "probability": 0.9365234375}, {"start": 5058.35, "end": 5058.77, "word": " N", "probability": 0.99072265625}, {"start": 5058.77, "end": 5059.41, "word": " N", "probability": 0.337646484375}, {"start": 5059.41, "end": 5059.63, "word": " N", "probability": 0.84814453125}, {"start": 5059.63, "end": 5059.71, "word": " N", "probability": 0.7958984375}, {"start": 5059.71, "end": 5060.57, "word": " و", "probability": 0.254638671875}, {"start": 5060.57, "end": 5061.03, "word": " هذي", "probability": 0.7078450520833334}], "temperature": 1.0}, {"id": 213, "seek": 508151, "start": 5063.07, "end": 5081.51, "text": "الكربون مجرد رفع على فوقه عملت double bond يعني هاي الجزء قبل ما يعملوا هذول الرابطين تطلع عليه Oxygen CH2 C triple bond C Oxygen CH2 C triple bond C نيتروجين تنتين تلاتة", "tokens": [6027, 4117, 25513, 11536, 3714, 7435, 2288, 3215, 12602, 5172, 3615, 15844, 6156, 30543, 3224, 6225, 42213, 2655, 3834, 6086, 37495, 22653, 8032, 47302, 25724, 11622, 38207, 12174, 36150, 19446, 7251, 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{"start": 5065.85, "end": 5066.29, "word": " bond", "probability": 0.927734375}, {"start": 5066.29, "end": 5066.91, "word": " يعني", "probability": 0.7373046875}, {"start": 5066.91, "end": 5067.23, "word": " هاي", "probability": 0.4947509765625}, {"start": 5067.23, "end": 5067.89, "word": " الجزء", "probability": 0.8235677083333334}, {"start": 5067.89, "end": 5068.25, "word": " قبل", "probability": 0.98486328125}, {"start": 5068.25, "end": 5068.37, "word": " ما", "probability": 0.861328125}, {"start": 5068.37, "end": 5068.81, "word": " يعملوا", "probability": 0.75921630859375}, {"start": 5068.81, "end": 5069.13, "word": " هذول", "probability": 0.7296549479166666}, {"start": 5069.13, "end": 5070.01, "word": " الرابطين", "probability": 0.71246337890625}, {"start": 5070.01, "end": 5070.67, "word": " تطلع", "probability": 0.830078125}, {"start": 5070.67, "end": 5070.97, "word": " عليه", "probability": 0.96435546875}, {"start": 5070.97, "end": 5072.07, "word": " Oxygen", "probability": 0.629150390625}, {"start": 5072.07, "end": 5073.33, "word": " CH2", "probability": 0.91357421875}, {"start": 5073.33, "end": 5073.63, "word": " C", "probability": 0.390380859375}, {"start": 5073.63, "end": 5073.97, "word": " triple", "probability": 0.408203125}, {"start": 5073.97, "end": 5074.27, "word": " bond", "probability": 0.94384765625}, {"start": 5074.27, "end": 5074.59, "word": " C", "probability": 0.8974609375}, {"start": 5074.59, "end": 5075.29, "word": " Oxygen", "probability": 0.6640625}, {"start": 5075.29, "end": 5076.39, "word": " CH2", "probability": 0.97119140625}, {"start": 5076.39, "end": 5077.09, "word": " C", "probability": 0.8681640625}, {"start": 5077.09, "end": 5077.47, "word": " triple", "probability": 0.89306640625}, {"start": 5077.47, "end": 5077.93, "word": " bond", "probability": 0.953125}, {"start": 5077.93, "end": 5079.07, "word": " C", "probability": 0.96044921875}, {"start": 5079.07, "end": 5080.33, "word": " نيتروجين", "probability": 0.83310546875}, {"start": 5080.33, "end": 5080.75, "word": " تنتين", "probability": 0.7720540364583334}, {"start": 5080.75, "end": 5081.51, "word": " تلاتة", "probability": 0.97119140625}], "temperature": 1.0}, {"id": 214, "seek": 510047, "start": 5082.14, "end": 5100.48, "text": "إذا هذا التفاعل إنتر ولا إنتر موليكلار؟ إنتر موليكلار Cycloaddition reaction للأزيد و لاحظوا كيف كون تلت حلقات كيف كون تلت حلقات أنا بتهيألي كل الأمثلة الحقيقة اللي موجودة", "tokens": [28814, 15730, 23758, 16712, 5172, 995, 30241, 11933, 29399, 2288, 49429, 11933, 29399, 2288, 3714, 12610, 1829, 4117, 1211, 9640, 22807, 11933, 29399, 2288, 3714, 12610, 1829, 4117, 1211, 9640, 10295, 66, 2907, 67, 849, 5480, 24976, 10721, 11622, 25708, 4032, 20193, 5016, 19913, 14407, 9122, 33911, 9122, 11536, 6055, 1211, 2655, 11331, 1211, 4587, 9307, 9122, 33911, 9122, 11536, 6055, 1211, 2655, 11331, 1211, 4587, 9307, 41850, 39894, 3224, 1829, 10721, 20292, 28242, 16247, 2304, 12984, 37977, 21542, 38436, 28671, 13672, 1829, 3714, 29245, 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