{"segments": [{"id": 1, "seek": 4232, "start": 21.26, "end": 42.32, "text": "بسم الله الرحمن الرحيم بعد ما أخدنا الطرق العامة لتحضير ال heterocycles انتقلنا لاخذ أنفلة محددة بدأنا بالحلقات السوداسية وأخدنا تقريبا من أشهر الحلقات السوداسية الberidine في المرة الماضية، الآن الberidine إذا صار", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 39182, 19446, 5551, 9778, 3215, 8315, 41950, 2288, 4587, 18863, 10943, 3660, 5296, 2655, 5016, 11242, 13546, 2423, 20789, 31078, 6520, 16472, 2655, 4587, 1211, 8315, 5296, 47283, 8848, 14739, 5172, 37977, 3714, 24401, 41891, 47525, 10721, 8315, 20666, 5016, 1211, 4587, 9307, 21136, 23328, 32277, 10632, 36725, 9778, 3215, 8315, 6055, 4587, 16572, 3555, 995, 9154, 5551, 8592, 3224, 2288, 21542, 1211, 4587, 9307, 21136, 23328, 32277, 10632, 2423, 607, 327, 533, 8978, 9673, 25720, 9673, 46958, 10632, 12399, 6024, 48506, 2423, 607, 327, 533, 11933, 15730, 20328, 9640], "avg_logprob": -0.10984375342726707, "compression_ratio": 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{"start": 80.15, "end": 80.51, "word": " حسب", "probability": 0.97119140625}, {"start": 80.51, "end": 81.11, "word": " القواعد", "probability": 0.9710286458333334}, {"start": 81.11, "end": 81.87, "word": " المتبعة", "probability": 0.9327392578125}, {"start": 81.87, "end": 82.27, "word": " بدنا", "probability": 0.745361328125}, {"start": 82.27, "end": 82.61, "word": " نبدأ", "probability": 0.9874674479166666}, {"start": 82.61, "end": 82.81, "word": " هان", "probability": 0.718994140625}, {"start": 82.81, "end": 82.99, "word": " من", "probability": 0.98193359375}, {"start": 82.99, "end": 83.15, "word": " ال", "probability": 0.93017578125}, {"start": 83.15, "end": 83.63, "word": " nitrogen", "probability": 0.73486328125}, {"start": 83.63, "end": 84.15, "word": " واحد", "probability": 0.802490234375}, {"start": 84.15, "end": 84.59, "word": " اتنين", "probability": 0.9390869140625}, {"start": 84.59, "end": 85.11, "word": " تلاتة", "probability": 0.9049072265625}, {"start": 85.11, "end": 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هكذا واضح؟ و لذلك في ال isoquinoline لما بيكون ترقيم من هنا واحد اتنين تلاتة بتكون هذه A وهذه B فلو اجى ال isoquinoline مع حلقة تانية من هنا بيكون عامل fusion من وين من B إذا كان هو ال base component ان كون منتبهين لهذه النقطة الآن", "tokens": [2407, 34105, 43242, 7578, 691, 4032, 383, 4032, 413, 4032, 8032, 4117, 15730, 4032, 46958, 5016, 22807, 4032, 5296, 8848, 23275, 8978, 2423, 307, 29826, 259, 401, 533, 5296, 15042, 4724, 1829, 30544, 6055, 2288, 4587, 32640, 9154, 34105, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 39894, 30544, 29538, 316, 37037, 24192, 363, 6156, 1211, 2407, 1975, 7435, 7578, 2423, 307, 29826, 259, 18773, 20449, 11331, 1211, 28671, 6055, 7649, 10632, 9154, 34105, 4724, 1829, 30544, 6225, 10943, 1211, 23100, 9154, 4032, 9957, 9154, 363, 11933, 15730, 25961, 31439, 2423, 3096, 6542, 16472, 9122, 11536, 9154, 2655, 3555, 3224, 9957, 46740, 24192, 28239, 47432, 3660, 6024, 48506], "avg_logprob": -0.24127252869777852, "compression_ratio": 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{"start": 270.03, "end": 270.81, "word": " بيطلع", "probability": 0.83466796875}, {"start": 270.81, "end": 271.09, "word": " هذا", "probability": 0.962890625}, {"start": 271.09, "end": 271.69, "word": " المركب", "probability": 0.8056640625}, {"start": 271.69, "end": 271.85, "word": " اللي", "probability": 0.8994140625}, {"start": 271.85, "end": 272.31, "word": " بيعمل", "probability": 0.987060546875}, {"start": 272.31, "end": 272.87, "word": " رائحة", "probability": 0.962646484375}, {"start": 272.87, "end": 273.43, "word": " نفاذة", "probability": 0.972412109375}, {"start": 273.43, "end": 274.27, "word": " وبتعرفوا", "probability": 0.886474609375}, {"start": 274.27, "end": 274.69, "word": " بغزة", "probability": 0.876708984375}, {"start": 274.69, "end": 275.13, "word": " نتيجة", "probability": 0.962646484375}, {"start": 275.13, "end": 275.81, "word": " الحصار", "probability": 0.9365234375}, {"start": 275.81, "end": 276.63, "word": " السيارات", "probability": 0.987548828125}, {"start": 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282.95, "end": 283.33, "word": " وقشة", "probability": 0.650115966796875}, {"start": 283.33, "end": 283.83, "word": " وكان", "probability": 0.94091796875}, {"start": 283.83, "end": 284.19, "word": " يطلع", "probability": 0.9942626953125}, {"start": 284.19, "end": 284.45, "word": " هذا", "probability": 0.97705078125}, {"start": 284.45, "end": 285.07, "word": " المركب", "probability": 0.9718424479166666}, {"start": 285.07, "end": 285.71, "word": " المزعج", "probability": 0.982666015625}, {"start": 285.71, "end": 285.95, "word": " من", "probability": 0.91015625}, {"start": 285.95, "end": 286.09, "word": " ال", "probability": 0.8955078125}, {"start": 286.09, "end": 286.77, "word": " glycerin", "probability": 0.9773763020833334}, {"start": 286.77, "end": 287.39, "word": " اللي", "probability": 0.9755859375}, {"start": 287.39, "end": 287.63, "word": " بيجي", "probability": 0.969482421875}, {"start": 287.63, "end": 287.75, "word": " من", "probability": 0.97998046875}, {"start": 287.75, "end": 288.37, "word": " تكسر", "probability": 0.9183349609375}, {"start": 288.37, "end": 289.11, "word": " الزيوت", "probability": 0.9566650390625}], "temperature": 1.0}, {"id": 13, "seek": 30226, "start": 289.66, "end": 302.26, "text": "في كل الأحوال إذا وصلت الأمور زي هيك قليلين و Alpha Beta Unsaturated Carbonyl Compounds بيصير بالزمن الجلمين الأحمر والإيش والأزرق ال", "tokens": [41185, 28242, 16247, 5016, 2407, 6027, 11933, 15730, 4032, 36520, 2655, 16247, 2304, 13063, 30767, 1829, 39896, 4117, 12174, 20292, 1211, 9957, 4032, 20588, 33286, 25017, 19493, 770, 2741, 65, 2526, 75, 6620, 4432, 4724, 1829, 9381, 13546, 20666, 11622, 27842, 25724, 19528, 9957, 16247, 5016, 29973, 16070, 28814, 1829, 8592, 16070, 10721, 11622, 2288, 4587, 2423], "avg_logprob": -0.31196121768704776, "compression_ratio": 1.3081761006289307, "no_speech_prob": 0.0, "words": [{"start": 289.66, "end": 289.9, "word": "في", "probability": 0.474853515625}, {"start": 289.9, "end": 290.1, "word": " كل", "probability": 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"end": 313.58, "word": " compound", "probability": 0.9208984375}, {"start": 313.58, "end": 314.04, "word": " في", "probability": 0.69970703125}, {"start": 314.04, "end": 314.62, "word": " النهاية", "probability": 0.92041015625}, {"start": 314.62, "end": 315.16, "word": " بيصير", "probability": 0.75128173828125}, {"start": 315.16, "end": 315.5, "word": " عليها", "probability": 0.979248046875}, {"start": 315.5, "end": 315.68, "word": " اي", "probability": 0.766845703125}, {"start": 315.68, "end": 316.34, "word": " تفاعل", "probability": 0.930419921875}, {"start": 316.34, "end": 317.06, "word": " Michael", "probability": 0.269775390625}, {"start": 317.06, "end": 317.66, "word": " addition", "probability": 0.88671875}, {"start": 317.66, "end": 319.82, "word": " الاضافة", "probability": 0.812255859375}, {"start": 319.82, "end": 320.02, "word": " على", "probability": 0.456298828125}, {"start": 320.02, "end": 320.4, "word": " هذا", "probability": 0.921875}, {"start": 320.4, "end": 321.04, "word": " الطرف", "probability": 0.98095703125}, {"start": 321.04, "end": 321.82, "word": " الطرف", "probability": 0.746337890625}, {"start": 321.82, "end": 322.4, "word": " البعيد", "probability": 0.90087890625}, {"start": 322.4, "end": 323.2, "word": " هيعملنا", "probability": 0.8182373046875}, {"start": 323.2, "end": 323.4, "word": " هنا", "probability": 0.7529296875}, {"start": 323.4, "end": 323.58, "word": " ال", "probability": 0.8291015625}, {"start": 323.58, "end": 323.82, "word": " Michael", "probability": 0.6240234375}, {"start": 323.82, "end": 324.36, "word": " addition", "probability": 0.9501953125}, {"start": 324.36, "end": 324.54, "word": " و", "probability": 0.90087890625}, {"start": 324.54, "end": 324.96, "word": " حولنا", "probability": 0.84228515625}, {"start": 324.96, "end": 325.08, "word": " ال", "probability": 0.83251953125}, {"start": 325.08, "end": 325.3, "word": " double", "probability": 0.91943359375}, {"start": 325.3, "end": 325.58, "word": " bond", "probability": 0.94189453125}, {"start": 325.58, "end": 325.82, "word": " الى", "probability": 0.646240234375}, {"start": 325.82, "end": 326.1, "word": " single", "probability": 0.93603515625}, {"start": 326.1, "end": 326.48, "word": " bond", "probability": 0.9345703125}, {"start": 326.48, "end": 326.98, "word": " هذا", "probability": 0.83984375}, {"start": 326.98, "end": 328.04, "word": " اليوكليوفايل", "probability": 0.9681222098214286}, {"start": 328.04, "end": 328.22, "word": " مع", "probability": 0.9873046875}, {"start": 328.22, "end": 328.38, "word": " ال", "probability": 0.8427734375}, {"start": 328.38, "end": 329.24, "word": " electrophile", "probability": 0.5467529296875}], "temperature": 1.0}, {"id": 15, "seek": 35892, "start": 333.06, "end": 358.92, "text": "بطلع عندى Equinoline واضحة الفكرة؟ الان اصل الـ Scrap Synthesis ماكنش هذا المركب كان Glycerin H2SO4 لكن لما فهموا التفاعل قالوا هدول الاتنين بيطلعوا هذا المركب الان صار الناس اللى فهمت التفاعل جيدا يقولوا طب لو جيبنا اي Alpha Beta Unsaturated Carbonyl Compound بحطينا هنا Methyl, Ethyl, Propyl", "tokens": [3555, 9566, 1211, 3615, 43242, 7578, 15624, 259, 18773, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 22807, 2423, 7649, 1975, 36520, 2423, 39184, 2747, 4007, 318, 45601, 19446, 19452, 8592, 23758, 9673, 31747, 3555, 25961, 460, 356, 1776, 259, 389, 17, 17188, 19, 44381, 5296, 15042, 6156, 16095, 14407, 16712, 5172, 995, 30241, 50239, 14407, 8032, 3215, 12610, 2423, 9307, 1863, 9957, 4724, 1829, 9566, 1211, 3615, 14407, 23758, 9673, 31747, 3555, 2423, 7649, 20328, 9640, 2423, 8315, 3794, 13672, 7578, 6156, 16095, 2655, 16712, 5172, 995, 30241, 10874, 25708, 995, 7251, 39648, 14407, 23032, 3555, 45164, 10874, 1829, 3555, 8315, 1975, 1829, 20588, 33286, 25017, 19493, 770, 31453, 5088, 6620, 554, 4724, 5016, 9566, 1829, 8315, 34105, 48602, 5088, 11, 10540, 5088, 11, 21944, 5088], "avg_logprob": -0.23363680679967083, "compression_ratio": 1.5360824742268042, "no_speech_prob": 5.960464477539063e-08, 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"temperature": 1.0}, {"id": 16, "seek": 38582, "start": 359.1, "end": 385.82, "text": "حضرناها بأي طريقة تانية يعني مش ضرورة من ال glycerin و ال sulfuric acid يعني جيبناها substituted alpha beta unsaturated carbonyl compound وفعلنا نفس التفاعل هيعمل نفس الشيء لكن هيطلع عند البريدين في هذا ال .. الليكونولين في هذا الحالة substituted هذا deutner von miller synthesis فهو واضح أن هو اشتقاق من ال scrub synthesis", "tokens": [5016, 11242, 2288, 8315, 11296, 4724, 10721, 1829, 23032, 16572, 28671, 6055, 7649, 10632, 37495, 22653, 37893, 48812, 2288, 13063, 3660, 9154, 2423, 22633, 1776, 259, 4032, 2423, 33831, 299, 8258, 37495, 22653, 10874, 1829, 3555, 8315, 11296, 26441, 4866, 8961, 9861, 2693, 19493, 770, 12143, 2526, 75, 14154, 4032, 5172, 30241, 8315, 8717, 36178, 16712, 5172, 995, 30241, 39896, 25957, 1211, 8717, 36178, 25124, 1829, 38207, 44381, 39896, 9566, 1211, 3615, 43242, 2423, 26890, 25708, 9957, 8978, 23758, 2423, 4386, 13672, 1829, 30544, 12610, 9957, 8978, 23758, 21542, 6027, 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"text": "و لذلك هاي انا عندى ال die nucleophile اتفعل اول ال nucleophile و اتفعل تاني nucleophile و عمل عندنا ايش ال cyclization و عمل عندنا ال cyclization هذا ايش بيسموه pectid sphingular isoquinoline synthesis Boomerang synthesis لو بنجى بنطلع عليه فى عندنا هنا", "tokens": [2407, 5296, 8848, 23275, 8032, 47302, 1975, 8315, 43242, 7578, 2423, 978, 14962, 49242, 1975, 2655, 5172, 30241, 1975, 12610, 2423, 14962, 49242, 4032, 1975, 2655, 5172, 30241, 6055, 7649, 1829, 14962, 49242, 4032, 6225, 42213, 43242, 8315, 1975, 1829, 8592, 2423, 19474, 2144, 4032, 6225, 42213, 43242, 8315, 2423, 19474, 2144, 23758, 1975, 1829, 8592, 4724, 1829, 38251, 2407, 3224, 520, 349, 327, 637, 571, 1040, 307, 78, 29360, 18773, 30252, 3286, 14301, 656, 30252, 45164, 44945, 7435, 7578, 44945, 9566, 1211, 3615, 47356, 6156, 7578, 43242, 8315, 34105], "avg_logprob": -0.3494162022412478, "compression_ratio": 1.765, "no_speech_prob": 0.0, "words": [{"start": 674.39, "end": 674.57, "word": "و", "probability": 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"word": " المرة", "probability": 0.792724609375}, {"start": 807.28, "end": 807.68, "word": " الماضية", "probability": 0.9803059895833334}, {"start": 807.68, "end": 807.84, "word": " في", "probability": 0.8359375}, {"start": 807.84, "end": 808.48, "word": " البريدين", "probability": 0.78515625}, {"start": 808.48, "end": 808.74, "word": " الـ", "probability": 0.449951171875}, {"start": 808.74, "end": 809.22, "word": " chiba", "probability": 0.15606689453125}, {"start": 809.22, "end": 809.62, "word": " bean", "probability": 0.56689453125}, {"start": 809.62, "end": 810.42, "word": " reaction", "probability": 0.9052734375}, {"start": 810.42, "end": 811.0, "word": " اللى", "probability": 0.80322265625}, {"start": 811.0, "end": 811.68, "word": " بيساعد", "probability": 0.94306640625}, {"start": 811.68, "end": 812.2, "word": " عليه", "probability": 0.5234375}, {"start": 812.2, "end": 812.9, "word": " وجود", "probability": 0.978515625}, {"start": 812.9, "end": 813.04, "word": " ال", "probability": 0.8994140625}, {"start": 813.04, "end": 813.6, "word": " nitrogen", "probability": 0.60302734375}, {"start": 813.6, "end": 813.8, "word": " و", "probability": 0.71875}, {"start": 813.8, "end": 814.18, "word": " بيتم", "probability": 0.71728515625}, {"start": 814.18, "end": 814.92, "word": " عادة", "probability": 0.9830729166666666}], "temperature": 1.0}, {"id": 36, "seek": 83720, "start": 816.12, "end": 837.2, "text": "جنب الـ Nitrogen ففي الكوينولين هي الموقع اللي جنب الـ Nitrogen وفي ال ISO كوينولين هذا الموقع اللي عادة بتتم عليه اللي هو الموقع المجاور لـ Nitrogen عشان لما النيوكليوفاين ييجي ال Nitrogen بصفتها Electronegative أتم تحمل الشحن السالي بقى هي المشكلة أنه بدو ييجي السالي بيهاجم على", "tokens": [7435, 1863, 3555, 2423, 39184, 37942, 7747, 6156, 41185, 33251, 2407, 9957, 12610, 9957, 39896, 9673, 30543, 3615, 13672, 1829, 10874, 1863, 3555, 2423, 39184, 37942, 7747, 4032, 41185, 2423, 25042, 9122, 2407, 9957, 12610, 9957, 23758, 9673, 30543, 3615, 13672, 1829, 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الـ", "probability": 0.916015625}, {"start": 851.65, "end": 852.33, "word": " Nitrogen", "probability": 0.7705078125}, {"start": 852.33, "end": 852.81, "word": " لما", "probability": 0.89599609375}, {"start": 852.81, "end": 853.13, "word": " ييجي", "probability": 0.9404296875}, {"start": 853.13, "end": 853.33, "word": " الـ", "probability": 0.858642578125}, {"start": 853.33, "end": 854.17, "word": " Eucleophile", "probability": 0.9122314453125}, {"start": 854.17, "end": 854.77, "word": " بهذا", "probability": 0.959716796875}, {"start": 854.77, "end": 855.29, "word": " الشكل", "probability": 0.9921875}, {"start": 855.29, "end": 855.85, "word": " الآن", "probability": 0.6728515625}, {"start": 855.85, "end": 856.19, "word": " الـ", "probability": 0.95556640625}, {"start": 856.19, "end": 856.87, "word": " Nitrogen", "probability": 0.877685546875}, {"start": 856.87, "end": 858.69, "word": " بتحمل", "probability": 0.9715169270833334}, {"start": 858.69, "end": 859.79, "word": " الإلكترونات", 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plus بيمشي بعدين بتم الفقد بيكتمل ال nucleophilic substitution الميكانيزم وضحناه في حالة", "tokens": [2407, 46958, 5016, 27188, 4117, 25720, 37495, 22653, 34105, 39894, 1829, 7435, 1829, 2423, 426, 389, 17, 8032, 8848, 995, 1411, 20328, 9640, 2655, 426, 3175, 426, 3175, 10874, 1863, 3555, 2423, 316, 1804, 4724, 32640, 8592, 1829, 39182, 9957, 4724, 39237, 27188, 28543, 4724, 1829, 4117, 39237, 1211, 2423, 14962, 5317, 388, 299, 35827, 9673, 1829, 41361, 1829, 11622, 2304, 4032, 11242, 5016, 8315, 3224, 8978, 11331, 6027, 3660], "avg_logprob": -0.3468309909525052, "compression_ratio": 1.3898305084745763, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 866.53, "end": 866.93, "word": "واضح", "probability": 0.89697265625}, {"start": 866.93, "end": 867.45, "word": " الفكرة", "probability": 0.9459635416666666}, {"start": 867.45, "end": 868.05, "word": " يعني", "probability": 0.652099609375}, {"start": 868.05, "end": 868.23, "word": " هنا", "probability": 0.708984375}, {"start": 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1058.56, "end": 1058.98, "word": " Malonic", "probability": 0.5653076171875}, {"start": 1058.98, "end": 1059.32, "word": " yeast", "probability": 0.6572265625}], "temperature": 1.0}, {"id": 46, "seek": 108469, "start": 1060.81, "end": 1084.69, "text": "اللي هو في وجود base زي Sodium Hydride او غيره هيصير ايون سالب في النهاية حال ما حل اي chlorine على موقع واحد برضه selective substitution اذا لو احنا و مرات كثيرة بنيجي بنسأل الطلاب والله ال eucleophilic substitution occurs at position فراغ في الكونولين two في ال isoquine", "tokens": [6027, 20292, 31439, 8978, 49610, 23328, 3096, 30767, 1829, 42059, 2197, 5701, 16753, 482, 1975, 2407, 32771, 13546, 3224, 39896, 9381, 13546, 1975, 1829, 11536, 8608, 6027, 3555, 8978, 28239, 11296, 10632, 11331, 6027, 19446, 11331, 1211, 1975, 1829, 39888, 15844, 3714, 30543, 3615, 36764, 24401, 4724, 43042, 3224, 33930, 35827, 1975, 15730, 45164, 1975, 5016, 8315, 4032, 3714, 2288, 9307, 9122, 12984, 48923, 44945, 1829, 7435, 1829, 44945, 3794, 10721, 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1063.63, "end": 1063.75, "word": " او", "probability": 0.669189453125}, {"start": 1063.75, "end": 1063.95, "word": " غيره", "probability": 0.93505859375}, {"start": 1063.95, "end": 1064.31, "word": " هيصير", "probability": 0.8087565104166666}, {"start": 1064.31, "end": 1064.69, "word": " ايون", "probability": 0.83251953125}, {"start": 1064.69, "end": 1065.27, "word": " سالب", "probability": 0.974609375}, {"start": 1065.27, "end": 1065.39, "word": " في", "probability": 0.90625}, {"start": 1065.39, "end": 1065.95, "word": " النهاية", "probability": 0.96533203125}, {"start": 1065.95, "end": 1066.75, "word": " حال", "probability": 0.4686279296875}, {"start": 1066.75, "end": 1066.87, "word": " ما", "probability": 0.7470703125}, {"start": 1066.87, "end": 1067.21, "word": " حل", "probability": 0.926513671875}, {"start": 1067.21, "end": 1067.57, "word": " اي", "probability": 0.75634765625}, {"start": 1067.57, "end": 1068.09, "word": " chlorine", "probability": 0.1527099609375}, {"start": 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0.6834309895833334}, {"start": 1074.97, "end": 1075.27, "word": " بنيجي", "probability": 0.87548828125}, {"start": 1075.27, "end": 1075.77, "word": " بنسأل", "probability": 0.9371337890625}, {"start": 1075.77, "end": 1076.53, "word": " الطلاب", "probability": 0.9443359375}, {"start": 1076.53, "end": 1077.17, "word": " والله", "probability": 0.787841796875}, {"start": 1077.17, "end": 1077.59, "word": " ال", "probability": 0.912109375}, {"start": 1077.59, "end": 1078.35, "word": " eucleophilic", "probability": 0.7736409505208334}, {"start": 1078.35, "end": 1079.05, "word": " substitution", "probability": 0.94091796875}, {"start": 1079.05, "end": 1079.53, "word": " occurs", "probability": 0.82470703125}, {"start": 1079.53, "end": 1079.93, "word": " at", "probability": 0.92236328125}, {"start": 1079.93, "end": 1080.49, "word": " position", "probability": 0.958984375}, {"start": 1080.49, "end": 1081.21, "word": " فراغ", "probability": 0.638824462890625}, {"start": 1081.21, "end": 1081.39, "word": " في", "probability": 0.859375}, {"start": 1081.39, "end": 1082.49, "word": " الكونولين", "probability": 0.55010986328125}, {"start": 1082.49, "end": 1083.23, "word": " two", "probability": 0.290283203125}, {"start": 1083.23, "end": 1083.95, "word": " في", "probability": 0.74169921875}, {"start": 1083.95, "end": 1084.07, "word": " ال", "probability": 0.9013671875}, {"start": 1084.07, "end": 1084.69, "word": " isoquine", "probability": 0.5421549479166666}], "temperature": 1.0}, {"id": 47, "seek": 110897, "start": 1085.53, "end": 1108.97, "text": "mainly two لو بتحكي اتش اتش بابيه ال reaction او هنا على اتنين و اربع في ال eyes of quinoline واحد موقع واحد طبعا ال electrophilic substitution و ال nucleophilic substitution على الberidine أخدناهم كانوا على الberidine على موقع اتنين و ال electrophilic substitution على موقع تلاتة", "tokens": [49417, 356, 732, 45164, 39894, 5016, 4117, 1829, 1975, 2655, 8592, 1975, 2655, 8592, 4724, 16758, 1829, 3224, 2423, 5480, 1975, 2407, 34105, 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"probability": 0.8564453125}, {"start": 1091.47, "end": 1091.67, "word": " eyes", "probability": 0.17578125}, {"start": 1091.67, "end": 1091.83, "word": " of", "probability": 0.73681640625}, {"start": 1091.83, "end": 1092.35, "word": " quinoline", "probability": 0.5682373046875}, {"start": 1092.35, "end": 1093.09, "word": " واحد", "probability": 0.84130859375}, {"start": 1093.09, "end": 1093.59, "word": " موقع", "probability": 0.908203125}, {"start": 1093.59, "end": 1094.35, "word": " واحد", "probability": 0.9892578125}, {"start": 1094.35, "end": 1095.43, "word": " طبعا", "probability": 0.987060546875}, {"start": 1095.43, "end": 1095.77, "word": " ال", "probability": 0.9619140625}, {"start": 1095.77, "end": 1096.79, "word": " electrophilic", "probability": 0.67388916015625}, {"start": 1096.79, "end": 1097.77, "word": " substitution", "probability": 0.931640625}, {"start": 1097.77, "end": 1098.25, "word": " و", "probability": 0.61279296875}, {"start": 1098.25, "end": 1098.35, "word": " ال", "probability": 0.69677734375}, {"start": 1098.35, "end": 1099.05, "word": " nucleophilic", "probability": 0.931640625}, {"start": 1099.05, "end": 1099.61, "word": " substitution", "probability": 0.9169921875}, {"start": 1099.61, "end": 1099.83, "word": " على", "probability": 0.61474609375}, {"start": 1099.83, "end": 1100.31, "word": " الberidine", "probability": 0.71722412109375}, {"start": 1100.31, "end": 1101.05, "word": " أخدناهم", "probability": 0.87861328125}, {"start": 1101.05, "end": 1102.13, "word": " كانوا", "probability": 0.936279296875}, {"start": 1102.13, "end": 1102.23, "word": " على", "probability": 0.8916015625}, {"start": 1102.23, "end": 1102.71, "word": " الberidine", "probability": 0.90087890625}, {"start": 1102.71, "end": 1102.93, "word": " على", "probability": 0.8701171875}, {"start": 1102.93, "end": 1103.37, "word": " موقع", "probability": 0.9954427083333334}, {"start": 1103.37, "end": 1103.93, "word": " اتنين", "probability": 0.985107421875}, {"start": 1103.93, "end": 1104.65, "word": " و", "probability": 0.70068359375}, {"start": 1104.65, "end": 1104.77, "word": " ال", "probability": 0.90576171875}, {"start": 1104.77, "end": 1105.63, "word": " electrophilic", "probability": 0.9244384765625}, {"start": 1105.63, "end": 1106.29, "word": " substitution", "probability": 0.94677734375}, {"start": 1106.29, "end": 1106.65, "word": " على", "probability": 0.92236328125}, {"start": 1106.65, "end": 1107.23, "word": " موقع", "probability": 0.9951171875}, {"start": 1107.23, "end": 1108.97, "word": " تلاتة", "probability": 0.9697265625}], "temperature": 1.0}, {"id": 48, "seek": 112228, "start": 1109.68, "end": 1122.28, "text": "و البريدين أن أكسيد بيعمل إبدال على بوقع أربعة لما نتذكر هذه الأشياء الأن طيب ال electrophilic substitution على الكوينولين و ال ISO كوينولين وين بتبدأ؟", "tokens": [2407, 2423, 26890, 25708, 9957, 14739, 5551, 4117, 3794, 25708, 4724, 1829, 25957, 1211, 11933, 44510, 6027, 15844, 4724, 30543, 3615, 5551, 25513, 27884, 5296, 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"word": " بوقع", "probability": 0.7177734375}, {"start": 1112.86, "end": 1113.96, "word": " أربعة", "probability": 0.83837890625}, {"start": 1113.96, "end": 1114.52, "word": " لما", "probability": 0.16070556640625}, {"start": 1114.52, "end": 1115.0, "word": " نتذكر", "probability": 0.88037109375}, {"start": 1115.0, "end": 1115.22, "word": " هذه", "probability": 0.87158203125}, {"start": 1115.22, "end": 1115.8, "word": " الأشياء", "probability": 0.9913330078125}, {"start": 1115.8, "end": 1117.26, "word": " الأن", "probability": 0.6107177734375}, {"start": 1117.26, "end": 1117.5, "word": " طيب", "probability": 0.8229166666666666}, {"start": 1117.5, "end": 1117.64, "word": " ال", "probability": 0.73193359375}, {"start": 1117.64, "end": 1118.42, "word": " electrophilic", "probability": 0.768157958984375}, {"start": 1118.42, "end": 1119.06, "word": " substitution", "probability": 0.78564453125}, {"start": 1119.06, "end": 1119.32, "word": " على", "probability": 0.5341796875}, {"start": 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"probability": 0.91357421875}], "temperature": 1.0}, {"id": 87, "seek": 201873, "start": 2003.79, "end": 2018.73, "text": "واضح؟ صار عندكم O C double bond O و بعد هيك هذه ال CH2 لما يرجع عن double bond ال double bond تهاجم على ال C double bond O هتعمل", "tokens": [2407, 46958, 5016, 22807, 20328, 9640, 43242, 24793, 422, 383, 3834, 6086, 422, 4032, 39182, 39896, 4117, 29538, 2423, 5995, 17, 5296, 15042, 7251, 47341, 3615, 18871, 3834, 6086, 2423, 3834, 6086, 6055, 3224, 26108, 2304, 15844, 2423, 383, 3834, 6086, 422, 8032, 2655, 25957, 1211], "avg_logprob": -0.32878989361702127, "compression_ratio": 1.3984375, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2003.7900000000002, "end": 2004.63, "word": "واضح؟", "probability": 0.5963134765625}, {"start": 2004.63, "end": 2004.91, "word": " صار", "probability": 0.722900390625}, {"start": 2004.91, "end": 2005.25, "word": " عندكم", "probability": 0.93505859375}, {"start": 2005.25, "end": 2005.77, "word": " O", "probability": 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الشكل وهنا OH وبالتالي هاي شوفنا أول تسكير وبعد هيك هذه ال double bond بتسكرها يعني ما استعملناش ايش ما استعملناش strong base في هذه الحالة طلعت ده ال alpha", "tokens": [3224, 1829, 20328, 9640, 16472, 3215, 3224, 25708, 39627, 15730, 25124, 28820, 37037, 8315, 13931, 46599, 6027, 2655, 6027, 1829, 8032, 47302, 13412, 38688, 8315, 5551, 12610, 6055, 3794, 4117, 13546, 46599, 22488, 39896, 4117, 29538, 2423, 3834, 6086, 39894, 3794, 37983, 11296, 37495, 22653, 19446, 44713, 25957, 1211, 1863, 33599, 1975, 1829, 8592, 19446, 44713, 25957, 1211, 1863, 33599, 2068, 3096, 8978, 29538, 21542, 6027, 3660, 23032, 1211, 34268, 11778, 3224, 2423, 8961], "avg_logprob": -0.2229166642824809, "compression_ratio": 1.5675675675675675, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2044.24, "end": 2044.56, "word": "هي", "probability": 0.85400390625}, {"start": 2044.56, "end": 2044.78, "word": " صار", "probability": 0.939453125}, {"start": 2044.78, "end": 2045.26, "word": " اندهيد", 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"probability": 0.90234375}, {"start": 2062.0, "end": 2062.4, "word": " في", "probability": 0.916015625}, {"start": 2062.4, "end": 2062.74, "word": " هذه", "probability": 0.8408203125}, {"start": 2062.74, "end": 2063.38, "word": " الحالة", "probability": 0.9913736979166666}, {"start": 2063.38, "end": 2064.12, "word": " طلعت", "probability": 0.97216796875}, {"start": 2064.12, "end": 2064.66, "word": " ده", "probability": 0.76953125}, {"start": 2064.66, "end": 2065.34, "word": " ال", "probability": 0.92822265625}, {"start": 2065.34, "end": 2065.88, "word": " alpha", "probability": 0.8271484375}], "temperature": 1.0}, {"id": 90, "seek": 207926, "start": 2074.92, "end": 2079.26, "text": "بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون بيرون", "tokens": [3555, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536, 4724, 13546, 11536], "avg_logprob": -0.2260841788077841, "compression_ratio": 7.608695652173913, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 2074.9199999999996, "end": 2075.3199999999997, "word": "بيرون", "probability": 0.5909016927083334}, {"start": 2075.3199999999997, "end": 2075.72, "word": " بيرون", "probability": 0.6979166666666666}, {"start": 2075.72, "end": 2075.92, "word": " بيرون", "probability": 0.75341796875}, {"start": 2075.92, "end": 2076.14, "word": " بيرون", "probability": 0.869140625}, {"start": 2076.14, "end": 2076.14, "word": " بيرون", "probability": 0.94482421875}, {"start": 2076.14, "end": 2076.32, "word": " بيرون", "probability": 0.9674479166666666}, {"start": 2076.32, "end": 2076.38, "word": " بيرون", "probability": 0.97705078125}, {"start": 2076.38, "end": 2076.58, "word": " بيرون", "probability": 0.9816080729166666}, {"start": 2076.58, "end": 2077.94, "word": " بيرون", "probability": 0.9840494791666666}, {"start": 2077.94, "end": 2078.98, "word": " بيرون", "probability": 0.9850260416666666}, {"start": 2078.98, "end": 2079.04, "word": " بيرون", "probability": 0.98486328125}, {"start": 2079.04, "end": 2079.12, "word": " بيرون", "probability": 0.9850260416666666}, {"start": 2079.12, "end": 2079.18, "word": " بيرون", "probability": 0.9853515625}, {"start": 2079.18, "end": 2079.26, "word": " بيرون", "probability": 0.98583984375}, {"start": 2079.26, "end": 2079.26, "word": " بيرون", "probability": 0.9866536458333334}, {"start": 2079.26, "end": 2079.26, "word": " بيرون", "probability": 0.9869791666666666}], "temperature": 1.0}, {"id": 91, "seek": 209719, "start": 2080.57, "end": 2097.19, "text": "مافيش فيه substitution بمعنى هذه عملية decarboxylation عملية decarboxylation بتحذف مجموعة ال acid واضح؟ بتحذف مجموعة ال acid من ناحية المبدأ هذا ال synthesis", "tokens": [15042, 41185, 8592, 8978, 3224, 35827, 4724, 2304, 3615, 1863, 7578, 29538, 6225, 42213, 10632, 979, 289, 4995, 5088, 399, 6225, 42213, 10632, 979, 289, 4995, 5088, 399, 39894, 5016, 8848, 5172, 3714, 7435, 2304, 2407, 27884, 2423, 8258, 4032, 46958, 5016, 22807, 39894, 5016, 8848, 5172, 3714, 7435, 2304, 2407, 27884, 2423, 8258, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 23758, 2423, 30252], "avg_logprob": -0.14939903846153846, "compression_ratio": 1.5675675675675675, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2080.57, "end": 2081.05, "word": "مافيش", "probability": 0.83642578125}, {"start": 2081.05, "end": 2081.21, "word": " فيه", "probability": 0.867919921875}, {"start": 2081.21, "end": 2081.83, "word": " substitution", "probability": 0.8271484375}, {"start": 2081.83, "end": 2082.55, "word": " بمعنى", "probability": 0.90908203125}, {"start": 2082.55, "end": 2083.19, "word": " هذه", "probability": 0.2147216796875}, {"start": 2083.19, "end": 2083.81, "word": " عملية", "probability": 0.9791666666666666}, {"start": 2083.81, "end": 2085.77, "word": " decarboxylation", "probability": 0.87802734375}, {"start": 2085.77, "end": 2086.29, "word": " عملية", "probability": 0.8873697916666666}, {"start": 2086.29, "end": 2087.53, "word": " decarboxylation", "probability": 0.9154296875}, {"start": 2087.53, "end": 2088.35, "word": " بتحذف", "probability": 0.9156494140625}, {"start": 2088.35, "end": 2089.07, "word": " مجموعة", "probability": 0.94716796875}, {"start": 2089.07, "end": 2089.75, "word": " ال", "probability": 0.93994140625}, {"start": 2089.75, "end": 2090.21, "word": " acid", "probability": 0.2408447265625}, {"start": 2090.21, "end": 2091.35, "word": " واضح؟", "probability": 0.78594970703125}, {"start": 2091.35, "end": 2092.25, "word": " بتحذف", "probability": 0.9134521484375}, {"start": 2092.25, "end": 2092.69, "word": " مجموعة", "probability": 0.9533203125}, {"start": 2092.69, "end": 2092.83, "word": " ال", "probability": 0.99169921875}, {"start": 2092.83, "end": 2093.13, "word": " acid", "probability": 0.98681640625}, {"start": 2093.13, "end": 2093.77, "word": " من", "probability": 0.90185546875}, {"start": 2093.77, "end": 2094.11, "word": " ناحية", "probability": 0.9446614583333334}, {"start": 2094.11, "end": 2095.11, "word": " المبدأ", "probability": 0.9884440104166666}, {"start": 2095.11, "end": 2095.73, "word": " هذا", "probability": 0.8095703125}, {"start": 2095.73, "end": 2096.57, "word": " ال", "probability": 0.9560546875}, {"start": 2096.57, "end": 2097.19, "word": " synthesis", "probability": 0.87158203125}], "temperature": 1.0}, {"id": 92, "seek": 212594, "start": 2098.17, "end": 2125.95, "text": "في نسبة شبه هذي ال oxygen هتهاجم هنا الديهيد زي ال alpha beta unsaturated acid هذي ال oxygen بتهاجم هنا بتطرد ال OH هيصار في عندك ال O C double bond O و بعد هيك ال double bond بتسكر هنا فبيطلع عندنا هذا المركب طبعا ال dihydro", "tokens": [41185, 8717, 35457, 3660, 13412, 3555, 3224, 8032, 8848, 1829, 2423, 9169, 8032, 47395, 26108, 2304, 34105, 2423, 16254, 3224, 25708, 30767, 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oxygen", "probability": 0.332763671875}, {"start": 2101.53, "end": 2102.47, "word": " هتهاجم", "probability": 0.9149169921875}, {"start": 2102.47, "end": 2102.81, "word": " هنا", "probability": 0.80322265625}, {"start": 2102.81, "end": 2103.59, "word": " الديهيد", "probability": 0.656494140625}, {"start": 2103.59, "end": 2103.91, "word": " زي", "probability": 0.832763671875}, {"start": 2103.91, "end": 2104.25, "word": " ال", "probability": 0.9150390625}, {"start": 2104.25, "end": 2104.73, "word": " alpha", "probability": 0.548828125}, {"start": 2104.73, "end": 2105.03, "word": " beta", "probability": 0.71728515625}, {"start": 2105.03, "end": 2105.99, "word": " unsaturated", "probability": 0.9278971354166666}, {"start": 2105.99, "end": 2106.43, "word": " acid", "probability": 0.92333984375}, {"start": 2106.43, "end": 2107.05, "word": " هذي", "probability": 0.7694498697916666}, {"start": 2107.05, "end": 2107.15, "word": " ال", "probability": 0.97265625}, {"start": 2107.15, "end": 2107.59, "word": " oxygen", "probability": 0.9189453125}, {"start": 2107.59, "end": 2108.67, "word": " بتهاجم", "probability": 0.918212890625}, {"start": 2108.67, "end": 2109.01, "word": " هنا", "probability": 0.9375}, {"start": 2109.01, "end": 2109.87, "word": " بتطرد", "probability": 0.81353759765625}, {"start": 2109.87, "end": 2110.05, "word": " ال", "probability": 0.93994140625}, {"start": 2110.05, "end": 2110.29, "word": " OH", "probability": 0.09100341796875}, {"start": 2110.29, "end": 2111.27, "word": " هيصار", "probability": 0.7491455078125}, {"start": 2111.27, "end": 2111.39, "word": " في", "probability": 0.84130859375}, {"start": 2111.39, "end": 2111.95, "word": " عندك", "probability": 0.6112060546875}, {"start": 2111.95, "end": 2112.55, "word": " ال", "probability": 0.88623046875}, {"start": 2112.55, "end": 2113.15, "word": " O", "probability": 0.80615234375}, {"start": 2113.15, "end": 2114.69, "word": " C", "probability": 0.3369140625}, {"start": 2114.69, "end": 2115.01, 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" عندنا", "probability": 0.990966796875}, {"start": 2122.37, "end": 2122.73, "word": " هذا", "probability": 0.9130859375}, {"start": 2122.73, "end": 2123.79, "word": " المركب", "probability": 0.8473307291666666}, {"start": 2123.79, "end": 2124.63, "word": " طبعا", "probability": 0.988525390625}, {"start": 2124.63, "end": 2124.95, "word": " ال", "probability": 0.253662109375}, {"start": 2124.95, "end": 2125.95, "word": " dihydro", "probability": 0.6698404947916666}], "temperature": 1.0}, {"id": 93, "seek": 215329, "start": 2128.41, "end": 2153.29, "text": "Dihydroalphabyron، لاحظوا هنا Dihydroalphabyron، هاي C double bond O CH واضح؟ كارمون اتنين تلاتة، هذه لما هاجمت صار عندي single Dihydroalphabyron، الالت Dihydroalphabyron، شو عمله في الالب روموساكسينمايد؟ اتراي ايه في الأميل؟ Oxidation", "tokens": [35, 4247, 6655, 340, 304, 950, 2509, 2044, 12399, 20193, 5016, 19913, 14407, 34105, 413, 4247, 6655, 340, 304, 950, 2509, 2044, 12399, 8032, 47302, 383, 3834, 6086, 422, 5995, 4032, 46958, 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0.8367513020833334}, {"start": 2406.55, "end": 2406.91, "word": " هذا", "probability": 0.927734375}, {"start": 2406.91, "end": 2407.57, "word": " اي", "probability": 0.721435546875}, {"start": 2407.57, "end": 2408.29, "word": " بيرون", "probability": 0.7044270833333334}, {"start": 2408.29, "end": 2408.65, "word": " Alpha", "probability": 0.1981201171875}, {"start": 2408.65, "end": 2408.91, "word": " ولا", "probability": 0.78955078125}, {"start": 2408.91, "end": 2409.37, "word": " Gamma", "probability": 0.87451171875}, {"start": 2409.37, "end": 2409.51, "word": " اللى", "probability": 0.94189453125}, {"start": 2409.51, "end": 2410.13, "word": " بيحضروا", "probability": 0.9146321614583334}, {"start": 2410.13, "end": 2410.57, "word": " الآن", "probability": 0.59771728515625}], "temperature": 1.0}, {"id": 104, "seek": 243171, "start": 2412.41, "end": 2431.71, "text": "مازال الفا بيرون بيحمل على هذا الموقع OH طبعا بتكون C double bond O بتعمل ولا توتو ميريزي بتصير ايش؟ OH فهذا ال oxygen في النهاية", "tokens": [2304, 31377, 6027, 27188, 995, 4724, 13546, 11536, 4724, 1829, 35571, 1211, 15844, 23758, 9673, 30543, 3615, 13931, 23032, 3555, 3615, 995, 39894, 30544, 383, 3834, 6086, 422, 39894, 25957, 1211, 49429, 6055, 35473, 2407, 3714, 13546, 1829, 11622, 1829, 39894, 9381, 13546, 1975, 1829, 8592, 22807, 13931, 6156, 3224, 15730, 2423, 9169, 8978, 28239, 11296, 10632], "avg_logprob": -0.4630926631647965, "compression_ratio": 1.3973509933774835, "no_speech_prob": 0.0, "words": [{"start": 2412.41, "end": 2412.97, "word": "مازال", "probability": 0.7732747395833334}, {"start": 2412.97, "end": 2413.57, "word": " الفا", "probability": 0.404541015625}, {"start": 2413.57, "end": 2415.81, "word": " بيرون", "probability": 0.732666015625}, {"start": 2415.81, "end": 2421.61, "word": " بيحمل", "probability": 0.75384521484375}, {"start": 2421.61, "end": 2421.71, "word": " على", "probability": 0.64306640625}, {"start": 2421.71, "end": 2421.91, "word": " هذا", "probability": 0.55517578125}, {"start": 2421.91, "end": 2423.03, "word": " الموقع", "probability": 0.9869791666666666}, {"start": 2423.03, "end": 2423.37, "word": " OH", "probability": 0.12744140625}, {"start": 2423.37, "end": 2423.89, "word": " طبعا", "probability": 0.81805419921875}, {"start": 2423.89, "end": 2424.21, "word": " بتكون", "probability": 0.67919921875}, {"start": 2424.21, "end": 2424.43, "word": " C", "probability": 0.43408203125}, {"start": 2424.43, "end": 2424.61, "word": " double", "probability": 0.3291015625}, {"start": 2424.61, "end": 2424.97, "word": " bond", "probability": 0.92626953125}, {"start": 2424.97, "end": 2425.21, "word": " O", "probability": 0.63037109375}, {"start": 2425.21, "end": 2425.59, "word": " بتعمل", "probability": 0.7386067708333334}, {"start": 2425.59, "end": 2425.75, "word": " ولا", "probability": 0.50927734375}, {"start": 2425.75, "end": 2426.19, "word": " توتو", "probability": 0.5525309244791666}, {"start": 2426.19, "end": 2426.59, "word": " ميريزي", "probability": 0.613232421875}, {"start": 2426.59, "end": 2427.01, "word": " بتصير", "probability": 0.8255208333333334}, {"start": 2427.01, "end": 2428.55, "word": " ايش؟", "probability": 0.686767578125}, {"start": 2428.55, "end": 2428.99, "word": " OH", "probability": 0.461181640625}, {"start": 2428.99, "end": 2430.17, "word": " فهذا", "probability": 0.7649739583333334}, {"start": 2430.17, "end": 2430.33, "word": " ال", "probability": 0.890625}, {"start": 2430.33, "end": 2430.79, "word": " oxygen", "probability": 0.6943359375}, {"start": 2430.79, "end": 2431.11, "word": " في", "probability": 0.90673828125}, {"start": 2431.11, "end": 2431.71, "word": " النهاية", "probability": 0.9578450520833334}], "temperature": 1.0}, {"id": 105, "seek": 245875, "start": 2432.73, "end": 2458.75, "text": "اللي هنا هتسكر على ال c double bond o يعني اللي بده يلزم ان انتوا تعملوا c double bond o o h و تمشوا بهذا الشكل ch2 c double bond o ch2 c double bond o r هاي المركب بهذا الشكل الان لو عملتوله in on form لو عملتوله in on form شو هيصفة عندكم", "tokens": [6027, 20292, 34105, 8032, 2655, 3794, 37983, 15844, 2423, 269, 3834, 6086, 277, 37495, 22653, 13672, 1829, 47525, 3224, 7251, 1211, 11622, 2304, 16472, 16472, 2655, 14407, 6055, 25957, 1211, 14407, 269, 3834, 6086, 277, 277, 276, 4032, 46811, 8592, 14407, 39627, 15730, 25124, 28820, 417, 17, 269, 3834, 6086, 277, 417, 17, 269, 3834, 6086, 277, 367, 8032, 47302, 9673, 31747, 3555, 39627, 15730, 25124, 28820, 2423, 7649, 45164, 6225, 42213, 2655, 12610, 3224, 294, 322, 1254, 45164, 6225, 42213, 2655, 12610, 3224, 294, 322, 1254, 13412, 2407, 39896, 9381, 5172, 3660, 43242, 24793], "avg_logprob": -0.27050782460719347, "compression_ratio": 1.9285714285714286, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 2432.73, "end": 2433.09, "word": "اللي", "probability": 0.54248046875}, {"start": 2433.09, "end": 2433.43, "word": " هنا", "probability": 0.625}, {"start": 2433.43, "end": 2434.35, "word": " هتسكر", "probability": 0.84619140625}, {"start": 2434.35, "end": 2434.69, "word": " على", "probability": 0.78515625}, {"start": 2434.69, "end": 2435.23, "word": " ال", "probability": 0.68115234375}, {"start": 2435.23, "end": 2435.35, "word": " c", "probability": 0.11065673828125}, {"start": 2435.35, "end": 2435.55, "word": " double", "probability": 0.50634765625}, {"start": 2435.55, "end": 2435.85, "word": " bond", "probability": 0.9130859375}, {"start": 2435.85, "end": 2435.95, "word": " o", "probability": 0.74951171875}, {"start": 2435.95, "end": 2436.13, "word": " يعني", "probability": 0.732666015625}, {"start": 2436.13, "end": 2436.29, "word": " اللي", "probability": 0.876220703125}, {"start": 2436.29, "end": 2436.49, "word": " بده", "probability": 0.706298828125}, {"start": 2436.49, "end": 2437.01, "word": " يلزم", "probability": 0.9923095703125}, {"start": 2437.01, "end": 2437.47, "word": " ان", "probability": 0.7001953125}, {"start": 2437.47, "end": 2437.83, "word": " انتوا", "probability": 0.76416015625}, {"start": 2437.83, "end": 2438.35, "word": " تعملوا", "probability": 0.9532470703125}, {"start": 2438.35, "end": 2438.55, "word": " c", "probability": 0.736328125}, {"start": 2438.55, "end": 2438.75, "word": " double", "probability": 0.791015625}, {"start": 2438.75, "end": 2439.19, "word": " bond", "probability": 0.97314453125}, {"start": 2439.19, "end": 2439.71, "word": " o", "probability": 0.88427734375}, {"start": 2439.71, "end": 2440.09, "word": " o", "probability": 0.2451171875}, {"start": 2440.09, "end": 2440.59, "word": " h", "probability": 0.8505859375}, {"start": 2440.59, "end": 2440.79, "word": " و", "probability": 0.67822265625}, {"start": 2440.79, "end": 2441.19, "word": " تمشوا", "probability": 0.9318033854166666}, {"start": 2441.19, "end": 2441.63, "word": " بهذا", "probability": 0.872314453125}, {"start": 2441.63, "end": 2442.01, "word": " الشكل", "probability": 0.98974609375}, {"start": 2442.01, "end": 2442.91, "word": " ch2", "probability": 0.59521484375}, {"start": 2442.91, "end": 2443.81, "word": " c", "probability": 0.61279296875}, {"start": 2443.81, "end": 2444.11, "word": " double", "probability": 0.87646484375}, {"start": 2444.11, "end": 2444.53, "word": " bond", "probability": 0.9794921875}, {"start": 2444.53, "end": 2444.93, "word": " o", "probability": 0.96044921875}, {"start": 2444.93, "end": 2446.07, "word": " ch2", "probability": 0.841064453125}, {"start": 2446.07, "end": 2446.79, "word": " c", "probability": 0.8818359375}, {"start": 2446.79, "end": 2447.09, "word": " double", "probability": 0.919921875}, {"start": 2447.09, "end": 2447.51, "word": " bond", "probability": 0.9814453125}, {"start": 2447.51, "end": 2448.43, "word": " o", "probability": 0.56591796875}, {"start": 2448.43, "end": 2449.37, "word": " r", "probability": 0.64892578125}, {"start": 2449.37, "end": 2450.45, "word": " هاي", "probability": 0.6563720703125}, {"start": 2450.45, "end": 2451.05, "word": " المركب", "probability": 0.8499348958333334}, {"start": 2451.05, "end": 2451.47, "word": " بهذا", "probability": 0.9443359375}, {"start": 2451.47, "end": 2451.91, "word": " الشكل", "probability": 0.990234375}, {"start": 2451.91, "end": 2452.53, "word": " الان", "probability": 0.6400146484375}, {"start": 2452.53, "end": 2452.69, "word": " لو", "probability": 0.98486328125}, {"start": 2452.69, "end": 2453.39, "word": " عملتوله", "probability": 0.88134765625}, {"start": 2453.39, "end": 2453.75, "word": " in", "probability": 0.1898193359375}, {"start": 2453.75, "end": 2453.89, "word": " on", "probability": 0.552734375}, {"start": 2453.89, "end": 2454.47, "word": " form", "probability": 0.89306640625}, {"start": 2454.47, "end": 2455.15, "word": " لو", "probability": 0.6923828125}, {"start": 2455.15, "end": 2455.83, "word": " عملتوله", "probability": 0.97734375}, {"start": 2455.83, "end": 2457.07, "word": " in", "probability": 0.9560546875}, {"start": 2457.07, "end": 2457.27, "word": " on", "probability": 0.9482421875}, {"start": 2457.27, "end": 2457.61, "word": " form", "probability": 0.95849609375}, {"start": 2457.61, "end": 2457.83, "word": " شو", "probability": 0.930419921875}, {"start": 2457.83, "end": 2458.23, "word": " هيصفة", "probability": 0.6068115234375}, {"start": 2458.23, "end": 2458.75, "word": " عندكم", "probability": 0.96533203125}], "temperature": 1.0}, {"id": 106, "seek": 248314, "start": 2460.78, "end": 2483.14, "text": "عملوا cyclization وهذا هو C-double bond وهذا هو E-null form هنا بيصير double bond OH واضح الفكرة تقريبا يمكن هذا الكلام انا مواضحه هنا هاي المركب الأصلي هذا اللي طلع عندنا كيف عمل cyclization هاي هذا ال ketone عمل", "tokens": [25957, 1211, 14407, 19474, 2144, 37037, 15730, 31439, 383, 12, 67, 33147, 6086, 37037, 15730, 31439, 462, 12, 77, 858, 1254, 34105, 4724, 1829, 9381, 13546, 3834, 6086, 13931, 4032, 46958, 5016, 27188, 4117, 25720, 6055, 4587, 16572, 3555, 995, 7251, 43020, 23758, 2423, 28820, 10943, 1975, 8315, 3714, 2407, 46958, 5016, 3224, 34105, 8032, 47302, 9673, 31747, 3555, 16247, 9381, 20292, 23758, 13672, 1829, 23032, 1211, 3615, 43242, 8315, 9122, 33911, 6225, 42213, 19474, 2144, 8032, 47302, 23758, 2423, 14979, 546, 6225, 42213], "avg_logprob": -0.3750000126221601, "compression_ratio": 1.613861386138614, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2460.78, "end": 2461.26, "word": "عملوا", "probability": 0.6856282552083334}, {"start": 2461.26, "end": 2462.06, "word": " cyclization", "probability": 0.5118408203125}, {"start": 2462.06, "end": 2463.24, "word": " وهذا", "probability": 0.536865234375}, {"start": 2463.24, "end": 2463.46, "word": " هو", "probability": 0.358642578125}, {"start": 2463.46, "end": 2463.6, "word": " C", "probability": 0.326416015625}, {"start": 2463.6, "end": 2463.86, "word": "-double", "probability": 0.5555013020833334}, {"start": 2463.86, "end": 2464.12, "word": " bond", "probability": 0.9521484375}, {"start": 2464.12, "end": 2464.68, "word": " وهذا", "probability": 0.4739990234375}, {"start": 2464.68, "end": 2464.72, "word": " هو", "probability": 0.666015625}, {"start": 2464.72, "end": 2464.9, "word": " E", "probability": 0.35888671875}, {"start": 2464.9, "end": 2465.2, "word": "-null", "probability": 0.4122314453125}, {"start": 2465.2, "end": 2465.6, "word": " form", "probability": 0.7431640625}, {"start": 2465.6, "end": 2465.88, "word": " هنا", "probability": 0.1007080078125}, {"start": 2465.88, "end": 2466.58, "word": " بيصير", "probability": 0.643310546875}, {"start": 2466.58, "end": 2466.82, "word": " double", "probability": 0.76708984375}, {"start": 2466.82, "end": 2467.18, "word": " bond", "probability": 0.95556640625}, {"start": 2467.18, "end": 2468.9, "word": " OH", "probability": 0.48876953125}, {"start": 2468.9, "end": 2469.56, "word": " واضح", "probability": 0.9488932291666666}, {"start": 2469.56, "end": 2470.06, "word": " الفكرة", "probability": 0.9020182291666666}, {"start": 2470.06, "end": 2472.04, "word": " تقريبا", "probability": 0.91162109375}, {"start": 2472.04, "end": 2472.74, "word": " يمكن", "probability": 0.878662109375}, {"start": 2472.74, "end": 2473.0, "word": " هذا", "probability": 0.970703125}, {"start": 2473.0, "end": 2473.6, "word": " الكلام", "probability": 0.96875}, {"start": 2473.6, "end": 2474.92, "word": " انا", "probability": 0.703369140625}, {"start": 2474.92, "end": 2475.48, "word": " مواضحه", "probability": 0.84091796875}, {"start": 2475.48, "end": 2475.78, "word": " هنا", "probability": 0.50537109375}, {"start": 2475.78, "end": 2477.16, "word": " هاي", "probability": 0.4959716796875}, {"start": 2477.16, "end": 2477.82, "word": " المركب", "probability": 0.8855794270833334}, {"start": 2477.82, "end": 2478.48, "word": " الأصلي", "probability": 0.7902018229166666}, {"start": 2478.48, "end": 2478.8, "word": " هذا", "probability": 0.8525390625}, {"start": 2478.8, "end": 2479.02, "word": " اللي", "probability": 0.900146484375}, {"start": 2479.02, "end": 2479.34, "word": " طلع", "probability": 0.9591471354166666}, {"start": 2479.34, "end": 2479.82, "word": " عندنا", "probability": 0.98193359375}, {"start": 2479.82, "end": 2480.02, "word": " كيف", "probability": 0.93798828125}, {"start": 2480.02, "end": 2480.26, "word": " عمل", "probability": 0.828125}, {"start": 2480.26, "end": 2481.24, "word": " cyclization", "probability": 0.6148681640625}, {"start": 2481.24, "end": 2481.84, "word": " هاي", "probability": 0.80224609375}, {"start": 2481.84, "end": 2482.1, "word": " هذا", "probability": 0.85498046875}, {"start": 2482.1, "end": 2482.24, "word": " ال", "probability": 0.8408203125}, {"start": 2482.24, "end": 2482.7, "word": " ketone", "probability": 0.719482421875}, {"start": 2482.7, "end": 2483.14, "word": " عمل", "probability": 0.9873046875}], "temperature": 1.0}, {"id": 107, "seek": 249561, "start": 2484.17, "end": 2495.61, "text": "الـ E0 الـ OH هذه هاجمت سكرت هنا طردت substitution OH و طبعا هنا عاملين already E0 تاني واضح", "tokens": [6027, 39184, 462, 15, 2423, 39184, 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"text": "الان لو اجينا ل ال alpha byrons و قولنا ايش اهم تفاعلاتهم اهم تفاعلات ال alpha byrons بالمجمل ان they are masked Dayens طبعا ايش اللي موجود فيهم و بده ينحذف", "tokens": [6027, 7649, 45164, 1975, 7435, 1829, 8315, 5296, 2423, 8961, 538, 13270, 4032, 12174, 12610, 8315, 1975, 1829, 8592, 1975, 16095, 6055, 5172, 995, 30241, 9307, 16095, 1975, 16095, 6055, 5172, 995, 30241, 9307, 2423, 8961, 538, 13270, 20666, 2304, 7435, 42213, 16472, 436, 366, 45249, 5226, 694, 23032, 3555, 3615, 995, 1975, 1829, 8592, 13672, 1829, 3714, 29245, 23328, 8978, 16095, 4032, 47525, 3224, 7251, 1863, 5016, 8848, 5172], "avg_logprob": -0.2678256933118256, "compression_ratio": 1.544871794871795, "no_speech_prob": 0.0, "words": [{"start": 2499.3, "end": 2499.86, "word": "الان", "probability": 0.796875}, {"start": 2499.86, "end": 2500.24, "word": " لو", "probability": 0.95556640625}, {"start": 2500.24, "end": 2500.78, "word": " اجينا", "probability": 0.7733154296875}, {"start": 2500.78, "end": 2501.0, 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"end": 2515.64, "word": " فيهم", "probability": 0.9755859375}, {"start": 2515.64, "end": 2516.4, "word": " و", "probability": 0.7333984375}, {"start": 2516.4, "end": 2516.62, "word": " بده", "probability": 0.6300048828125}, {"start": 2516.62, "end": 2517.2, "word": " ينحذف", "probability": 0.89482421875}], "temperature": 1.0}, {"id": 109, "seek": 254503, "start": 2517.97, "end": 2545.03, "text": "الـ CO2 و بناء على ذلك لما انتم تشتغلوا deals under reaction عليهم و نحط الناتج النهائي لاحظوا هي هنا تفاعل مع ال triple bond عادة ال deals under reaction بطلع في الحلقة السادسية كم buy bond؟ واحدة لما تكون هذا triple bond صاروا تلتين لما يفقد ال CO2 صاروا تلاتة", "tokens": [6027, 39184, 3002, 17, 4032, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 16472, 39237, 6055, 8592, 2655, 17082, 1211, 14407, 11215, 833, 5480, 25894, 16095, 4032, 8717, 5016, 9566, 2423, 8315, 2655, 7435, 28239, 3224, 16373, 1829, 20193, 5016, 19913, 14407, 39896, 34105, 6055, 5172, 995, 30241, 20449, 2423, 15508, 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ولاحظوا هذه الحلقة السوداسية اللي من هدول الطرف اللي بدي اتعمل ضيق الان لو كنا حاطين بهذا الشكل", "tokens": [5172, 15042, 6055, 14851, 17082, 25513, 2407, 8592, 23758, 28239, 9307, 7435, 45164, 3714, 25720, 6055, 7649, 10632, 4724, 16254, 34051, 11242, 5016, 23275, 14407, 35186, 269, 3834, 6086, 277, 269, 3834, 6086, 277, 293, 2572, 4032, 15040, 5016, 19913, 14407, 29538, 21542, 1211, 28671, 21136, 23328, 32277, 10632, 13672, 1829, 9154, 8032, 3215, 12610, 41950, 28480, 13672, 1829, 4724, 16254, 1975, 2655, 25957, 1211, 48812, 1829, 4587, 2423, 7649, 45164, 9122, 8315, 11331, 41193, 9957, 39627, 15730, 25124, 28820], "avg_logprob": -0.2716049441584834, "compression_ratio": 1.6282722513089005, "no_speech_prob": 0.0, "words": [{"start": 2917.3699999999994, "end": 2918.1299999999997, "word": "فما", "probability": 0.58837890625}, {"start": 2918.1299999999997, "end": 2918.89, "word": " تستغربوش", "probability": 0.91845703125}, {"start": 2918.89, "end": 2919.23, "word": " هذا", 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