passages.id: split_9_validation_531_passage
passages.type: progene_text
passages.text: Oxygenation of the copper(I) complex derived from BIT(OMe,SCPh3 ) ligand 12 produces a novel dinuclear disulfide complex , [(BIT(OMe,S)2Cu2(mu-OH)2](PF6)2 ( 17 ) , which is structurally characterized. Reactivity studies under anaerobic conditions in the presence of t-BuNC indicate that 17 is the result of copper(I) - induced detritylation followed by oxygenation of a highly reactive copper(I)-thiolate complex .