| episode | first aired | entrepreneur (s) | company or product name | money requested | investing dragon (s) |
| episode 1 | 15 october 2007 | celia norowzian & ian forshew | beach break live | 50000 | peter jones |
| episode 1 | 15 october 2007 | laban roomes | goldgenie (formerly midas touch) | 60000 | james caan |
| episode 2 | 22 october 2007 | sarah lu | youdoodoll | 35000 | deborah meaden |
| episode 2 | 22 october 2007 | emmie matthews & ed stevens | gaming alerts | 200000 | theo paphitis |
| episode 3 | 29 october 2007 | mark champkins | concentrate design | 100000 | peter jones |
| episode 4 | 5 november 2007 | max mcmurdo | reestore | 50000 | deborah meaden & theo paphitis |
| episode 4 | 5 november 2007 | jamie jenkinson | cush'n 'shade | 100000 | deborah meaden & peter jones |
| episode 5 | 19 november 2007 | shane lake and tony charles | hungryhousecouk | 100000 | james caan & duncan bannatyne |
| episode 6 | 26 november 2007 | ian helmore | steri spray | 145000 | deborah meaden & theo paphitis |
| episode 6 | 26 november 2007 | mark and eleanor davis | caribbean ready meals | 100000 | james caan & duncan bannatyne |
| episode 7 | 3 december 2007 | sammy french | fit fur life | 100000 | james caan |
| episode 7 | 3 december 2007 | jerry mantalvanos & paul merker | jpm eco logistics | 100000 | deborah meaden & theo paphitis |
| episode 8 | 11 december 2007 | peter moule | electroexpo , chocbox | 150000 | duncan bannatyne & james caan |
| episode 9 | 18 december 2007 | amanda jones & james brown | red button design | 50000 | all five dragons |