text
stringlengths
595
18.7k
label
int64
0
1
label_text
stringclasses
2 values
===================== Product Identification ===================== Product ID:SEWER OUT CAGE:69114 CAGE:69114 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: <50.00% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE DESTRUCTION OF TISSUE. SKIN: SEVERE IRRITATION, BURNS AND ULCERATION. INGEST: SEVERE BURNS TO MUCOUS MEMBRANES, DESTRUCTION OF TISSUE, DANGER-MAY BE FATAL IF SWALLOWED. INHAL: SEVERE IRRI TATION OF RESPIRATORY TRACT, PULMONARY EDEMA, LARYNIGAL SPASMS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES & UNDER EYELIDS W/PLENTY OF COOL H2O FOR AT LEAST 15 MIN/WASH W/5% BORIC ACID SOLN. OBTAIN IMMED MED ASSISTANCE & CONTINUE FLUSHING UNTIL ASSISTANCE ARRIVES. SKIN: REMOVE CONTAM CLTHG & LAUNDER BEFORE RE-USE. FLUSH THORO W/VINEGAR & WATER. INGEST: DO NOT INDUCE VOMIT. GIVE LRG QTYS OF WATER FOLLOWED WITH CITRUS FRUIT JUICE. CALL PHYS/POIS CNTRL CENTER IMMED. NEVER (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:ADDITION OF WATER TO THIS PRODUCT WILL GENERATE HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE GEAR. SWEEP UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR RE-USE. WASH AREA WITH VINEGAR AND FLUSH THOROUGHLY WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY IN COOL, DRY PLACE, AWAY FROM ACIDS. DO NOT MIX W/ANY OTHER CLEANING PRODUCT. KEEP CNTNR TIGHTLY CLSD WHEN NOT IN USE. Other Precautions:DO NOT ALLOW MATERIAL TO GET WET IN STORAGE. NEVER ADD WATER TO THIS PRODUCT-ALWAYS ADD THIS PRODUCT TO WATER SLOWLY! CONTAINER MAY RETAIN HAZARDOUS RESIDUE-RINSE CONTAINER BEFORE DISCARDING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT INHALATION OF VAPORS OR DUSTS. USE ONLY WITH ADEQUATE VENTILATION. Ventilation:LOCAL & MECHANICAL EXHAUST RECOMMENDED. Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN, EMERGENCY SHOWER AND EYE WASH STATION. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHAL: REMOVE PERSON TO FRESH AIR AND CALL PHYSICIAN IMMEDIATELY. ================== Physical/Chemical Properties ================== HCC:C2 Solubility in Water:SOLUBLE Appearance and Odor:YELLOW PELLETS WITH ALUMINUM GRANULES, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDIC MATERIALS, REACTS VIGOROUSLY WHEN WETTED. Stability Condition to Avoid:AVOID MOISTURE: MUST BE KEPT DRY. Hazardous Decomposition Products:THERMAL DECOMPOSITION CAN PRODUCE CO AND CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL ENVIRONMENTAL AUTHORITIES. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SOY-3000, BIONOMIC SERIES INKS, PANTONE SOY WARM RED CAGE:0FTL5 CAGE:0FTL5 CAGE:09177 ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM LITHOL RED (RED PIGMENT). CONTAINS ING #3. CAS:1103-38-4 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENESULFONIC ACID, 5-CHLORO-2-((2-HYDROXY-1- NAPHTHALENYL)AZO)-4-METHYL-BARIUM SALT. CONTAINS ING #3. CAS:5160-02-1 RTECS #:DB5500000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BARIUM (SARA III) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: 65% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: SKIN. EYES:CONTACT MAY CAUSE BURNING & IRRITATION. SKIN:PROLONGED OR REPEATED EXPOSURE MAY CAUSE IRRITATION OR DERMATITIS. INHAL:EXCESSIVE INHALATION OF VAPORS MAY CAUSE HEADACHE, DIZZI NESS, DROWSINESS & NAUSEA. INGEST:MAY CAUSE IRRITATION OR GASTRIC DISTURBANCE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:EYES:RINSE THOROUGHLY W/WATER FOR AT LEAST 15 MINS. IF IRRITATION PERSISTS, CONSULT MD. SKIN:WASH W/MILD SOAP & WATER. INHAL:REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION &/OR OXYGEN IF NEEDED. CO NSULT MD. INGEST:DO NOT INDUCE VOMITING. SEEK MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:215F,102C Extinguishing Media:FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER CAN BE USED TO KEEP MATERIAL COOL. Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE BURNING. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP SPILLS W/RAGS. DISPOSE OF RAGS IN CONTAINER APPROVED FOR OILY WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. KEEP AWAY FROM EXCESSIVE HEAT, SPARKS & OPEN FLAME. Other Precautions:DO NOT REUSE CONTAINER. FOR COMMERCIAL & INDUSTRIAL USE ONLY. KEEP FROM REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL VENTILATION AS PER LOCAL OR STATE REGULATIONS. Other Protective Equipment:APRON, FOOTWEAR & IMPERVIOUS CLTHG AS NEEDED TO PVNT EXCESSIVE SKIN CONTACT. EMERGENCY EYEWASH & DELUGE SHOWER . Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER BEFORE EATING OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:>550F,>288C Vapor Density:GREATER Spec Gravity:<1 (H*2O=1) Evaporation Rate & Reference:SLOWER (BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:COLORED PASTE; OILY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESS HEAT. Hazardous Decomposition Products:DENSE SMOKE, CARBON MONOXIDE & CARBON DIOXIDE WHEN BURNING. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. RCRA WASTE NUMBER:D005
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMERLOCK, 400 AL CURE Kit Part:Y Preparer's Name:H KLINE CAGE:0Y2E4 CAGE:55849 CAGE:0Y2E4 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM SILICATE) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <35% OSHA PEL:20 MPPCF Z-3 ACGIH TLV:2 MG/M3 RDUST Ingred Name:POLYAMIDE RESIN LD50:2.5 G/KG CAS:37219-83-3 Fraction by Wt: <30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TRIETHYLENETETRAMINE; (TETA) CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA) VP:6.6 @ 68F, LD50:4.3 G/KG CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 8.66% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA 313) (CERCLA) %:0.900 PPM CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.01% OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA (QUARTZ)) LD50:5 G/KG CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <10% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:PHENOL,4-NONYL-,BRANCHED/NONYLPHENOL; (NONYL PHENOL) VP:<1 @ 68F LD50:1.6 G/KG CAS:84852-15-3 RTECS #:SM5650000 Fraction by Wt: <10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MICA - SILICATES (CONTAINS < 1% CRYSTALLINE SILICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: <5% OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST Ingred Name:QUATERNARY AMMONIUM COMPOUNDS, BIS(HYDROGENATED TALLOW ALKYL)DIMETHYL-, SALT; (CLAY) CAS:68953-58-2 RTECS #:UZ2996400 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:VAPOR, SPRAY MIST AND/OR DUST CAN BE HARMFUL. IRRITATING TO SKIN, MUCOUS MEMBRANES, EYES AND RESPIRATORY SYSTEM. EXCESSIVE INHALATION CAN CAUSE HEADACHE, NAUSEA, DIZZINESS OR ASPHYXIATION. REPEATED AN D PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS IS ASSOCIATED WITH PERMANENT BRAIN AND NERVOUS SYS (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS. (SUPDAT) Effects of Overexposure:HLTH HAZS:DMG. CAN BE HARMFUL IF SWALLOWED. OVEREXP CAN DMG CNS. OVEREXP/INGEST CAN CAUSE LUNG, KIDNEY &/OR LIVER DMG. OVEREXPOS CAN CAUSE SEV EYE & SKIN BURNS &/OR INJURY. SKIN & RESP SENSIT & ALLERG IC RXN SUCH AS RASH, HIVES/ASTHMA CAN OCCUR. OVEREXP CAN CAUSE DELAYED LUNG INJURY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:PROVIDE FRESH AIR; IF BREATHING IS LABORED, GIVE OXYGEN OR ARTIFICAL RESPIRATION. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. EYES:FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUT ES AND GET MEDICAL ATTENTION. INGESTION:DRINK 1-2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:110F,43C Lower Limits:1.00% Upper Limits:7.00% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID BREATHING OF VAPORS OR DUST. USE ABSORBENT CLEANUP MATERIALS OR SWEEP UP. PLACE IN SEPARATE CONTAINER. ELIMINATE ALL SOURCES OF IGNITION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENT AREA. AVOID STOR TEMPS ABOVE 100F. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED BREATHING OF DUST, VAPORS OR SPRAY MIST OR CONTACT WITH SKIN AND EYES. DO NOT WELD OR FLAME CUT ON EMPTY CONTAINER. GROUND CONTAINERS WHEN POURING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD CERTIFIED RESP. FOR SPECIFIC CNTNRS REFER TO NIOSH POCKET GUIDE TO CHEM HAZS, DHEW NO 78-210. USE NIOSH/MSHA APPRVD AIR-LINE RESP IN CONFINED/RESTRICTED VENT AREAS/W/POLYURETHANE/ISO CYANATES. REFER TO 29 CFR, OSHA (SUPDAT) Ventilation:SUFFICIENT VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO KEEP AIR CONTAM CONCS BELOW TLV LIM. REMOVE WELDING OR (SUPDAT) Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . FULL PROTECTIVE CLOTHING. SPARK-PROOF EQUIPMENT. Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING WASHROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health EXPLAN OF CARCIN:1994:ANTIC TO BE CARCIN. ANIMAL:LIVER. RESP PROT:PARTS 1910, 1915 & 1916 FOR COATING OPERATIONS. VENT:FLAME CUTTING DECOMP PRODS. REFER TO 29 CFR, OSHA PARTS 1910, 1915 & 1916 FOR COA TING OPERATIONS. EYE PROT:AND FULL LENGTH FACE SHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:282F,139C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:0.70 (BUTYL ACETATE=1) Appearance and Odor:LIQUID WITH A SOLVENT ODOR. Percent Volatiles by Volume:14 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. EPOXIES UNDER UNCONTROLLED CONDITIONS. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. Hazardous Decomposition Products:BY FIRE, BURNING OR WELDING:CO AND CO*2, NO*X, AMMONIA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . IN SEPARATE, CLOSED METAL CONTAINER IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. EPA WASTE NO:D001 U239.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-1538 AMBER,BLACK,PART B CAGE:DO563 CAGE:83574 CAGE:DO563 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHER POLYOL POLYMER WITH TOLUENE DIISOCYANATE,CAS #9057-91-4 ACGIH TLV:0.005PPM Ingred Name:TLV SHOWN IS FOR TOLUENE DIISOCYANATE RTECS #:9999999ZZ ===================== Hazards Identification ===================== Effects of Overexposure:EYE:IRR,WATERING,REVERS.CORNEAL DMG;SKIN:IRR,DISCOLOR,ALLERGIC RASH;INH:SEE SUPPLEMENTAL DATA- ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. SKIN:WASH WITH SOAP & WATER. EYES:FLUSH WITH WATER 15 MIN. KEEP WARM AND QUIET.ING:GIVE MILK OR WATER.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG. Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR. Unusual Fire/Explosion Hazard:HIGH TEMPS.MAY CAUSE PRESS.BUILDUP IN CLOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:COVER W.ABS.MATERIAL;ADD DECONTAM.SOLN:5% CONC.AMMONIA,2% DETERGNT,93% WTR,AND ALLOW TO REACT FOR 10 MIN.COLLECT IN CONT,ADD ADDL DECONTAM SOLN AND KEEP LOOSELY COVERED FOR 48 HOURS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY WELL VENTED LOW FIRE RISK AREA. PROTECT FROM HEAT,SHOCK,FRICTION. KEEP CONTAINERS CLOSED. Other Precautions:DO NOT RESEAL CONT. IF MOISTURE CONTAM IS SUSPECTED. AVOID INGESTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPVD RESP IF TLV IS EXCEEDED Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health MSDS DATED 10-16-86/KEY1:Z01/OVEREXPSR;INH:IRR.OF NOSE,THROAT,LUNGS,WTRNG EYES,SORE THROAT,TIGHT CHEST,DIFFICULT BREATHNG,ASTHMA-LIKE SYMP;ING:IRR,CORR.ACTION MOUTH,STOMACH,DIGESTIVE TRACT. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.06 Solubility in Water:NEGL Appearance and Odor:NOT SPECIFIED Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WTR,ALCOHOL,AMINES,STRONG BASES Stability Condition to Avoid:AVOID MOISTURE,WILL CAUSE CO*2 PRESS--AVOID HIGH TEMPS-- Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN,TRACES OF HCN ==================== Disposal Considerations ==================== Waste Disposal Methods:MFR STATES NOT A HAZ WASTE ACCORDING TO EPA REGULATIONS-DISPOSE OF IAW LOCAL,STATE,FEDERAL REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACTIVATOR 707 AMPULE, 8112088, 17446 Preparer's Name:STEPHEN REPETTO CAGE:7K128 CAGE:7K128 CAGE:05972 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1,1-TRICHLORO- (SARA 313) (CERCLA) LEL: 7%. UEL: 15%. CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 80-85% OSHA PEL:350 PPM ACGIH TLV:350 PPM; 450 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:BUTANAL-ANILINE CONDENSATE CAS:9003-37-6 Fraction by Wt: 10-15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TERT-BUTYL ALCOHOL (SARA 313) LEL: 2.4%.UEL: 8% CAS:75-65-0 RTECS #:EO1925000 Fraction by Wt: 1-3% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:METHANE, DIMETHOXY- LEL: 2.2%. UEL: 13.1% CAS:109-87-5 RTECS #:PA8750000 Fraction by Wt: 1-3% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:VOLATILE ORGANIC COMPOUND; 82.6%; 802 G/L (LESS EXEMPT SOLVENTS) (EPA METHOD 24) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FO R LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . HEADACHE, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: NAUSEA, DIZZINESS. NARCOSIS AT HIGH CONCENTRATION. Medical Cond Aggravated by Exposure:1,1,1-TRICHLOROETHANE: CNS, LIVER, HEART DISEASE, ALCOHOLISM, SKIN DISORDERS, EYE PROBLEMS, RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION. INHAL: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN MEDICAL ATTENTION. SKIN: FLUSH WITH WATER. EYES: FLUSH THOROUGHL Y WITH WATER FOR AT LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Lower Limits:SEE INGS Upper Limits:SEE INGS Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:ALLOW TO EVAPORATE WITH GOOD VENTILATION. SOAK UP RESIDUE IN AN INERT ABSORBENT. STORE IN A CLOSED CONTAINER UNTIL DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 110F. AVOID PROLONGED BREATHING OF VAPOR. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:PROVIDE ADEQUATE LOCAL VENTILATION TO MAINTAIN VAPOR CONCENTRATION BELOW TLV. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:175F,79C Vapor Pres:<100 Vapor Density:4.5 Spec Gravity:1.20 @ 80F Solubility in Water:SLIGHT Appearance and Odor:BROWN LIQUID; SHARP ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SOLVENT MAY REACT VIOLENTLY WITH ALUMINUM ON PROLONGED CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:PHOSGENE . TOXIC CHLORIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW EPA FEDERAL, STATE AND LOCAL REGULATIONS FOR DISPOSAL OF CHLORINATED HYDROCARBONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RJ-4 Preparer's Name:DALE F. JANES (IH) CAGE:KO284 CAGE:15835 CAGE:KO284 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAHYDRODIMETHYLCYLOPENTADIENE DIMER CAS:30496-78-7 Fraction by Wt: 95%. Other REC Limits:50 PPM OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED Ingred Name:HYDROCARBON (TYPE NOT SPECIFIED) Fraction by Wt: 5%. OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE REQUIRED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE, SKIN & RESPIRATORY IRRITANT. ASPIRATION HAZARD. Effects of Overexposure:EYES:LIQUID CONTACT MAY CAUSE MODERATE IRRITATION; SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION & DERMATITIS; INHAL:HIGH VAPOR CONCENTRATIONS MAY IRRITATE UPPER RESPIRATORY TRACT; INGEST: CAN CAUSE GI IRRITATION(VOMITING & DIARRHEA) & NAUSEA. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY & SKIN CONDITIONS . ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH LIBERALLY W/ LOW PRESSURE WATER FOR 15 MIN. LIFTING EYELIDS OCCASIONALLY. GET MED ATTN IF EYE IRRITATION PERSISTS; SKIN:REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA W/ SOAP & WATER THOROUGHLY. INHAL:REMOVE TO FRESH AIR. GIVE CPR/O*2 AS SITUATION DICTATES. GET MED ATTN; INGEST:ASPIRATION HAZARD! DONOT INDUCE VOMITING!! GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:140F/60C Extinguishing Media:DRY CHEMICAL,CO*2,FOAM,WATER SPRAY. Fire Fighting Procedures:RECOMMEND WATER SPRAY TO COOL FIRE EXPOSED SURFACES & TO PROTECT PERSONNEL. WEAR SELF-CONTAINED BRTHNG APPAR WHEN FIGHTING FIRE IN CONFINED SPACES. Unusual Fire/Explosion Hazard:HIGH HEAT, SPARKS, OPEN FLAME, OR STRONG OXIDIZERS MAY IGNITE THIS MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. STOP LEAKAGE. VENTILATE AREA. ABSORB W/ A SUITABLE MEDIUM; EARTH, SAND, INERT FLOOR ABSORBENT. SHOVEL INTO CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:CLASS IIIA COMBUSTIBLE LIQUID STORAGE REQUIRED BY U.S. DEPT OF LABOR. Other Precautions:PROTECT AGAINST PHYSICAL DAMAGE. OUTSIDE OR DETACHED STORAGE PREFERABLE. SEPARATE FROM OXIDIZING MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONCENTRATION IN AIR DETERMINES PROTECTION REQUIRED. USE NIOSH APPROVED RESPIRATOR. FOR LOW CONC:USE VAPOR CARTRIDGE RESPIRATORS; FOR HI CONC: USE FULL MASK AIR-SUPPLIED POSITIVE PRESSURE RESPIRATORS. Ventilation:AS NEEDED TO KEEP CONCENTRATION IN AIR BELOW THE TLV. Other Protective Equipment:FOR PROLONGED/REPEATED SKIN CONTACT, FACE PROTECT). Work Hygienic Practices:OBSERVE INSTRUCTIONS SET FORTH BY SAFETY/IH OFFICE FOR CORRECT USE. Supplemental Safety and Health ASPIRATION HAZARD! DO NOT ALLOW LIQUID OR MISTS TO ENTER LUNGS.CHEMICAL PNEUMONIA MAY RESULT. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:400-450F Melt/Freeze Pt:M.P/F.P Text:-65F/-53.9C Vapor Pres:< 5 @ 77F Vapor Density:>1. Spec Gravity:0.925 Evaporation Rate & Reference:(ETHYL ETHER=1);>1 SLOW Solubility in Water:<0.1 Appearance and Odor:CLEAR, COLORLESS LIQUID. KEROSENE LIKE ODOR. Percent Volatiles by Volume:90. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS & STRONG MINERAL ACIDS MAY IGNITE THIS MATERIAL. Stability Condition to Avoid:HIGH HEAT, SPARKS, & OPEN FLAME. Hazardous Decomposition Products:COMBUSTION/HIGH TEMPERATURE MAY FORM CARBON MONOXIDE AND/OR VOLATILE VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE RCRA-REGS AS WELL AS STATE & LOCAL WASTE DISPOSAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SURFA PREP TEXTURED, 2510 Preparer's Name:R MILLER CAGE:85260 CAGE:85260 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 20% OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 4.46% OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:FLUX CALCINED DIATOMACEOUS EARTH CAS:68855-54-9 Fraction by Wt: 2.08% OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:PRLNGD INHAL MAY RSLT IN HDCH/NAUS/EYE & LUNG IRRIT. CHRONIC:PRLNGD EXPOS MAY CAUSE DAM TO CNS/RESP SYS/LUNGS/EYES/SKIN/GI TRACT/LIVER/SPLEEN & KIDNEYS. INHAL:EXCESSIVE INHAL OF VAP CAN CAUSE NA SAL/REP IRRIT/DIZZ/WEAKNESS/FATIGUE/NAUSE & HDCH. HIGH CONC MAY RSLT IN NARCOSIS (CNS DEPRESS). (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:CRYSTALLINE SILICA: IARC GROUP 2A. BENZENE: IARC GROUP 1, NTP GROUP 1, OSHA. Effects of Overexposure:HLTH HAZ:SKIN:PRLNGD/RPTD EXPOS CAN CAUSE MODERATE IRRIT/DEFATTING/DERM. EYE:SEV IRRIT/REDNESS/TEARING/BLURRED VISION. INGEST:CAN CAUSE GI IRRIT/NAUS/VOM & DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CH EM PNEUM, WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:MAY DEVELOP SENSITIVITY TO COMPONENTS. MAY AGGRAVATE RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/CLEAN WATER FOR AT LEAST 15 MINS, OCCASNLY LIFTING EYELIDS. OBTAIN MED ATTN. SKIN:REMOVE CONTAMD CLTHG. WASH EFFECTED SKIN AREA THORO W/SOAP & WATER. WASH CONTAMD CLTHG THORO BEFORE REUSE. INHAL:REMOVE VICTIM TO FRESH AIR. USE ARTF RESP OR GIVE O*2 AS NEC. GET MED ATTN. INGEST:KEEP PERSON WARM, QUIET & GET IMMED MED ATTN. DO NOT INDUCE VOM. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:1.0% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2 & DRY CHEMICAL. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER MAY BE USED TO COOL CLOSED CONTAINERS. WEAR NIOSH/MSHA SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT/SPARKS/OPEN FLAME. OVEREXPOS TO DECOMP PROD MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. CALL MD. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION & PROVIDE VENTILATION. COVER SPILL W/INERT ABSORBANT MATERIAL & TRANSFER INTO CONTAINER USING NONSPARKING TOOLS. REMOVE CONTAINERS TO A SAFE AREA & SEAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HEAT/FLAME/HIGH TEMPERATURE. STORE IN WELL-VENTILATED AREA. KEEP CLOSURE TIGHT & CONTAINER UPRIGHT TO PREVENT LEAKAGE. Other Precautions:GROUND ALL EQUIP TO REDUCE ELEC SPARKING. DO NOT TAKE INTERNALLY & AVOID PRLNGD SKIN CONT OR INHAL. RPTS HAVE ASSOC RPTD/PRLNGD OCCUP OVEREXPOS TO SOLV W/PERM BRAIN & NERV SYS DAM. INTENTIONAL MISUSEBY DELIBERATELY (SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR/OPEN AREAS:NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID PARTICLES OF OVERSPRAY FOR SPRAY APPLICATN. RESTRICTED VENT AREA:NIOSH/MSHA APPRVD FILTER RESP DESIGNED TO REMOVE A COMBINATION OF PARTICLES/VAP. CONFINED (SEE SUPP DATA) Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP AIR CONTAM CONC BELOW CURRENT APPLIC OSHA PEL & ACGIG TLV LIMIT. Other Protective Equipment:ALL EQUIPMENT SHOULD COMPLY W/OSHA STANDARDS. Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. SMOKE IN AUTHORIZED AREAS ONLY. Supplemental Safety and Health PREC:CONCENTRATING & INHALING THE CONTENTS MAY BE FATAL. SANDING OF DRIED PAINT FILM WILL RSLT IN EXPOS TO CRYSTALLINE SILICA PIGMENT DUSTS. USE RESP PROT. RESP PROT:AREAS:NIOSH/MSHA APPRVD AIR SUPPLY TYPE RESPIRATORS/HOODS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:306F,152C Vapor Density:HVR/AIR Spec Gravity:1.4 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID W/PETROLEUM DISTILLATE ODOR Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT/SPARKS/OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, LOW MOLECULAR WEIGHT HYDROCARBONS & ORGANIC ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR USE SANITARY LAND FILL IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. BEFORE ATTEMPTING CLEANUP, REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THE SHEET.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FA10924A CAGE:JO867 CAGE:81831 CAGE:JO867 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UN CONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KINSEAL VACUUM SEALANT, 200664-0000 Preparer's Name:ERNEST CARTER CAGE:LO435 CAGE:LO435 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE CAS:108-65-6 Code:F RTECS #:AI8925000 Ingred Name:BIS(2-ETHYLHEXYL) PHTHALATE CAS:117-81-7 RTECS #:TI0350000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 ACGIH STEL:10 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Health Hazards Acute and Chronic:COMPONENTS MAY BE SLIGHTLY IRRITATING TO THE SKIN AND EYE. THIS PRODUCT MAY BE TOXIC BY INGESTION. CONTAINS BIS-(2-ETHYLHEXYL) PHTHALATE WHICH HAS BEEN SHOWN TO CAUSE CANCER IN CERTAIN ANIMAL EXPERIME NTS. RISK TO YOUR HEALTH DEPENDS ON DURATION AND CONCENTRATION OF EXPOSURE, ALTHOUGH NO SPECIFIC TEST DATA IS AVAILABLE FOR THIS GLYCOL ETHER. Explanation of Carcinogenicity:NONE Effects of Overexposure:OVEREXPOSURE TO THIS PRODUCT MAY INCLUDE FATIGUE, HEADACHE, IMPAIRED JUDGEMENT OR CONFUSION, NAUSEA OR VOMITING, EYE IRRITATION, ACCELERATION OF THE PULSE, DROWSINESS, GASTROITESTINAL DISTRESS, DIZZIN ESS, DECREASE IN BLOOD PRESSURE, LOSS OF COORDINATION AND SKIN IRRITATION. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH EYES FOR FIFTEEN MINUTES WITH LUKE WARM, FRESH WATER. CONSULT WITH YOUR PHYSICIAN.SKIN CONTACT: FLUSH EXPOSED SKIN FOR AT LEAST FIFTEEN MINUTES WITH WARM CLEAN WATER. CONSULT WITH Y OUR PHYSICIAN. INHALATION: REMOVE EMPLOYEE FROM THE EXPOSURE ENSURING YOUR OWN SAEFETY. SEEK MEDICAL ADVISE. INGESTION: ALTHOUGH TOXIC, THIS PRODUCT IS NOT TYPICALLY CONSIDERED HARMFUL THROUGH NORMAL INDUSTRIAL ROUTES OF EXPOSURE. IF ANY STOMACH. INTESTINAL OR OTHER SIMILAR PROBLEMS ARISE AND PERSIST. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:LEVEL B PROTECTIVE EQUIPMENT IS NECESSARY FOR VAPOR PRESSURE. AIR PURIFYING RESPIRATOR MUST BE WORN. ONLY PROPERLY TRAINED PERSONNEL SHOULD RESPOND. Unusual Fire/Explosion Hazard:PRODUCT IS VOLATILE AND FLAMMABLE CONCENTRATIONS CAN OCCUR EVEN AT COOL TEMPERATURES. VAPORS ARE SAME WEIGHT AS AIR AND WILL DISPERSE UNIFORMLY. POCKETS OF VAPOR MAY STILL ACCUMULATE IN LOW AREAS AN D CEILINGS. EXPOSED CONTAINERS MAY BUILD UP PRESSURE AND BURST EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:DURING ANY INCIDENT, EVACUATE ALL NON-ESSENTIAL PERSONNEL FROM THE AREA. REFER TO THE DOT GUIDE BOOK, GUIDE NUMBER 26 FOR ANY ADDITIONAL FIRE OR SPILL INFORMATION. ONLY PROPERLY TRAINED PERSONNEL SHOU LD RESPOND TO SIGNIFICANT INCIDENTS INVOLVING THIS MATERIAL. DISPOSAL MUST BE DONE IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN DIRECT SUN OR AN AREA WHERE THE TEMPERATURE CAN EXCEED 100 F. BOND STORAGE CONTAINERS AND GROUND WHILE DISPENSING. CLOSE CONTAINER WHEN NOT IN USE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AN APPROVED AIR FURIFYING RESPIRATOR (ORGANIC FILTER) SHOULD BE USED TO PROVIDE EMPLOYEE PROTECTION. Ventilation:PROVIDE MECHANICAL VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS BELOW FLAMMABLE AND PERMISIBLE EXPOSURE LEVELS. PROTECTIVE CLOTHING. Other Protective Equipment:NONE Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, DRINKING, SMOKING, APPLYING MAKE-UP OR USING GUM, OR OTHER SMOKELESS TOBACCOS. Supplemental Safety and Health AVOID WEARING CONTAMINATED CLOTHING INTO FOOD EATING OR PROCESSING AREAS. ================== Physical/Chemical Properties ================== Boiling Pt:>37.8C, 100.F Melt/Freeze Pt:M.P/F.P Text:NONE Decomp Temp:Decomp Text:NONE Spec Gravity:.98% VOC Grams/Liter:8.2 Viscosity:1000-1800 CPS Solubility in Water:<10% Appearance and Odor:LIQUID COLORLESS SOLVENT Percent Volatiles by Volume:49.00% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:AVOID STORING NEAR OR COMBINING WITH STRONG OXIDIZERS AND NITRIC ACID. Hazardous Decomposition Products:CARBON DIOXIDE AND MONOXIDE AND WATER =================== Toxicological Information=================== Toxicological Information:SLIGHTLY TOXIC BY INGESTION.POISONING IS NOT EXPECTED IN A NORMAL OCCUPATIONAL SETTING. MINOR IRRITATING EFFECT ON EYES AND SKIN. ==================== Disposal Considerations ==================== Waste Disposal Methods:EVALUATE AND DISPOSE OF ALL PROCESS WASTES SUCH AS WIPING RAGS, SPILL DEBRIS, TOWELS, OVERSPRAY AND FILTERS, IN COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-46168D, PART B 4:1 BLEND Kit Part:Y Preparer's Name:MIKE LICHATOWICH CAGE:02388 CAGE:02388 ============= Composition/Information on Ingredients ============= Ingred Name:HOMOPOLYMER OF HDI (VAPOR PRESSURE 7.5E-5 MM @ 20C) CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 75% Ingred Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE) CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.7% ACGIH TLV:0.005 PPM; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 12.5% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 12.5% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC. ORGANIC CMPD 2.21 LB/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOSURE MAY LEAD TO BRONCHITIS, BRONCHIAL SPASM, & PULMONARY EDEMA. CHEMICAL OR HYPERSENSITIVE PNEUMONITIS W/FLU LIKE SYMPTOMS. VOMITING MAY CAUSE ASPIRATIONOF THE SOLV RESULTING IN CHEM PNEUMONITI S. CONTACT W/BUTYL ACETATE OR XYLENECAN RESULT IN DRY,DEFATTED, & CRACKED SKIN CAUSING SUSCEPT. TO INFECTIONS. Effects of Overexposure:EYE: IRRIT.,TEARING,REDDENING, & SWELLING ALONG W/STINGING & DUST SENSATION SKIN: REDDENING,SWELLING,RASH,SCALING, OR BLISTERING, & DERMATITIS INHALE:IRRIT. THE MUCOUS MEMBRANES IN NO SE,THROAT,LUNGS,COUGHING,CHST DISCOMFORTINGEST: IRRIT. & CORROSIVE ACTION TO MOUTH,STOMACH TISSUE, & DIGESTIVE TRACK. Medical Cond Aggravated by Exposure:ASTHMA, RESPIRATORY DISORDERS SUCH AS BRONCHITIS, EMPHYSEMA, & HYPERRACTIVITY, SKIN ALLERGIES, AND ECZMA. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/CLN LKWRM WTR,LOW PRESS FOR 15 MINS,LIFTING EYELIDS, GET MED ATTN SKIN: WASH AREA W/SOAP & WTR. REMOVE CONTAM. CLOTHING IMMED., GET MEDCL ATTN INGST:DO NOT INDUCE VOMITING. DO NOT GIV E ANYTHING BY MOUTH, CONSULT A PHYSICIANINHALE: REMOVE TO FRESH AIR,GIVE ARTIFICIAL RESP. AS NEEDED, GET MEDICAL ATTN ASTHMATIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMED. OR DELAYED UP TO SEVERAL HRS ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:91F/33C Lower Limits:1.0 Upper Limits:7.6 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. ISOLATE FROM HEAT, ELEC. EQUIP, SPARKS, & OPEN FLAME. CLOSED CONTAINER MAY EXPLODE WHEN EXP0SED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:BURST WHEN CONTAMINATED WITH WATER CREATING CO2. STAGNANT AIR MAY CAUSE VAPORS TO BLD UP & TRVL ALNG GRND TO AN IGN SOURCE W/MAY FLASH BK TO SOURCE OF VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION & VENTL AREA. DIKE OR IMPOUND SPILLED MATL & CONTRL FURTHER SPILLAGE IF POSS.COLLECT MATL IN OPEN CONTNR TO SAFE PLACE.COVER LOOSELY & ALLOW TO STAND FOR 24-48 HRS. WASH DOWN SPILL AREAS W/DECONTAMINATION SOLUTIONS. Neutralizing Agent:TERGITOL TMN-10(20%)WATER(80%),CONC AMMONIA(3-8%)DETERGENT(2%)WATER(90-95%) ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPRKS,& OPEN FLAME. STORE IN TIGHTLY CLSD CONTNR TO PREVNT MOISTURE CONTAMIN. IDEAL STORAGE IS 50-81F/10-27C. Other Precautions:DO NOT RESEAL IF CONTAMINATION IS SUSPECTED. IF CONTNR IS EXPOSED TO HIGH HEAT, IT CAN BE PRESSURIZED & POSS RUPTURE EXPLOSIVELY. THIS GAS CAN CAUSE SEALED CONTAINERS TO EXPAND AND POSSIBLY RUPTUR E EXPLOSIVELY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSTV. PRESS. SUPLD AIR RESP. IS MANDATORY FOR CONFND AREAS. OTHER APPROVED PROTECTION, AIR PURIFYING OR FRESH AIR SUPPLIED RESPIRATORS. Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE CONCENT OF THE SOLVENT,HDI, & POLYISOCYANATE BELOW THEIR TLV'S Other Protective Equipment:SAFETY SHOWERS & EYEWASH STATIONS SHOULD BE AVAILABLE & SHOULD BE USED WHEN NEEDED. Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING & BEFORE USING RESTROOMSSMOKE ONLY IN SMOKING AREAS. Supplemental Safety and Health COVER AS MUCH OF THE EXPOSED SKIN AREA AS POSSIBLE WITH APPROPRIATE CLOTHING. IF SKIN CREAMS ARE USED, KEEP THE AREA PROTECTED ONLY BY THE CREAM TO A MINIMUM.WASH CONTAMINATED CLOTHING THOROUGHLY BE FORE REUSE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NE Vapor Density:> AIR Viscosity:183 MPAS @20C Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INSOLUBLE/REACTS WTR Appearance and Odor:CLEAR TO PALE YELLOW LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:30 CA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE ACTIVE MATERIALS Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES,SHOCK FROM DROPPING Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON IOXIDE/MONOXIDE,OXIDES OF NITRO-GEN, TRACES OF HNC AND HDI Conditions to Avoid Polymerization:IF IN CONTACT WITH MOISTURE OR OTHER MATL WHICH REACTS WITH ISOCYANATES. MAY OCCUR AT TEMP >400F/204C ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATE, AND LOCAL REGULATIONS. INCINERATION IS PREFERRED. EMPTY CON-TAINER MUST BE HANDLED W/CARE DUE TO PROD RESIDUE & FLAM VAPOR. DO NOT HEAT OR CUT ON OR NEAR EMPTY CONTAINERS W/ELEC OR GAS TOURCH.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-1539-L, ALL COLORS Preparer's Name:AD CAGE:DO563 CAGE:83574 CAGE:DO563 ============= Composition/Information on Ingredients ============= Ingred Name:POLYURETHANE PREPOLYMER; (POLYPROPYLENE GLYCOL POLYMER WITH POLYURETHANE 4,4'-DIPHENYL METHANE DIISOCYANATE (ING 2) CAS:66072-18-2 Fraction by Wt: 70% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 1: PREPOLYMER CONTAINING INGREDIENT # 3) RTECS #:9999999ZZ Fraction by Wt: N/K (F) Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (ISOCYANATE MONOMER) CAS:101-68-8 RTECS #:NQ9350000 OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER: (1-METHOXY-2-PROPANOL ACETATE) CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DIESEL FUELS; (HYDROCARBON COMBINATION) CAS:68334-30-5 RTECS #:HZ1800000 Fraction by Wt: 4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC CONTENT: 218 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: IRRIT, WATERING & POSS REVERSIBLE CORNEAL DMG. SKIN: LOC IRRIT & DISCOLORATION. MAY CAUSE ALLERGIC SKIN RASH IN SENSITIZED INDIVIDUALS. INHAL: DUE TO LOW VOLATILITY, SIGNIFICANT EXPOS TO VAPS IS NOT EXPECTED UNLESS OVERHEATED.EXCESS INHAL CAN PRODUCE IRRIT OF NOSE, THROAT & RESP TRACT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: EXCESS & EXTENSIVE EXPOS CAN PRODUCE REVERSIBLE SYMP OF BRONCHITIS. SENSITIZED INDIVIDUALS WILL DEVELOP ASTHMA-LIKE SYMP AT LOW EXPOS. INGEST: MAY RSLT IN IRRIT & SOME CORR ACTION IN MOUTH, STOMACH TISS & DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR AT LEAST 15 MINUTES, CONSULT MD. SKIN: WASH WITH SOAP AND WATER. IF SYMPTOMS PERSIST, CONSULT MD. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS ARE PRESENT CONSULT MD. INGESTION: GIVE MILK OR WATER TO DRINK. CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:136F,58C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO COOL HEAT-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE BUILD-UP IN CLOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH ABSORBANT MATERIAL, ADD DECONTAMINATION SOLUTION (5% CONCENTRATED AMMONIA, 2% DETERGENT, 93% WATER) AND ALLOW TO REACT FOR 10 MINUTES. COLLECT IN CONTAINERS, ADD ADDITIONAL DECONTAMINATIONSOLUTION AND KEEP LOOSELY COVERED FOR 48 HOURS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MOISTURE CONTAMINATION WHICH WILL CAUSE CARBON DIOXIDE PRESSURE. DO NOT RESEAL CONTAINERS IF MOISTURE CONTAMINATION IS SUSPECTED. Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN APPLYING IN CONFINED AREAS, OR IN OTHER CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVELS OF SOLVENT OR ISOCYANATE IN EXCESS OF PEL, USE A NIOSH/MSHA APPROVED AIR-SUPPLIED RESPIRATOR. Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:1.09 Solubility in Water:NEGLIGIBLE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOLS, STRONG BASES, AMINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN; POSSIBLE TRACES OF HCN. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE # D-001. DISPOSE OF SPILLAGE IN COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DRY POWDER DEVELOPER PD4 CAGE:KO468 CAGE:KO468 DIV CAGE:2R128 ============= Composition/Information on Ingredients ============= Ingred Name:INORGANIC MATERIALS (NOT SPECIFIED) Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE, SKIN, & RESPIRATORY TRACT IRRITATION. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY RESULT IN AN ALLERGIC SKIN REACTION. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE, SKIN, & RESPIRATORY TRACT IRRITATION SUCH AS TEARING, RASH, OR DIFFICULTY IN BREATHING. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR LUNGS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELID. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE. INHALATION: REMOV E TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:DAMP DOWN WITH WATER, GATHER UP AND DISPOSE OF IN AN APPROVED MANNER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:TO AVOID THE POSSIBILITY OF SKIN DISORDERS, REPEATED OR PROLONGED CONTACT WITH THE PRODUCT IS TO BE AVOIDED AND IT IS ESSENTIAL THAT ALL WHO COME INTO CONTACT WITH THIS PRODUCT MAINTAIN HIGH STANDARDS OF PERSONAL HYGIENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL/TLV. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS OF CONTAMINATES. Ventilation:LOCAL EXHAUST RECOMMENDED. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES. LAUNDER CONTAMINATED CLOTHING BEFORE WEARING. KEEP WORK AREA CLEAN. Supplemental Safety and Health IT IS STRONGLY RECOMME;NDED THAT THESE PRODUCTS SHOULD ONLY BE USED IN DUST STORM CABINETS. CONTAINERS SHOULD BE OPENED CAREFULLY TO PREVENT DUST ENTERING THE ATMOSPHERE. WHERE THERE IS A RISK OF DUST ENTERING THE ATMOSPHERE, OPERATORS MUST WEAR AN APPROVED DUST MASK. AVOID CONTACT WITH SKIN. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:LIGHT FREE FLOWING INORGANIC WHITE POWDERS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALVANIA EP GREASE 2, SHELL CODE 71125 Resp. Party Other MSDS Num.:EQUILON MSDS: 57052E-06 Preparer's Name:KAREN G HAYNES CAGE:3N254 CAGE:3N254 Contract Num:SP0450-01-M-LC11 CAGE:0PGK2 ============= Composition/Information on Ingredients ============= Ingred Name:ALVANIA EP GREASE 2 (PRODUCT) = Wt:100. Ingred Name:HIGHLY REFINED PETROLEUM OILS (MIXTURE, CONTAINS 64742-52-5, 64742-57-0) Minumum % Wt:80. Maxumum % Wt:90. Ingred Name:LITHIUM 12-HYDROXYSTEARATE CAS:7620-77-1 Minumum % Wt:5. Maxumum % Wt:10. Ingred Name:ADDITIVES CONTAINING: ZINC COMPOUNDS Minumum % Wt:5. Maxumum % Wt:10. Ingred Name:ZINC COMPOUNDS Minumum % Wt:1. Maxumum % Wt:2. Ingred Name:HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM) CAS:64742-52-5 RTECS #:PY8035000 Ingred Name:HYDROTREATED RESIDUAL OIL (PETROLEUM) CAS:64742-57-0 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL, RAT, LD50: >5.0 G/KG. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE CONTACT: LUBRICATING GREASES ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY IRRITATING TO THE EYES. SKIN CONTACT: MILDLY IRRITATING. PROLONGED/REPEATED CONTACT MAY CAUSE DEFATTING, IRRITATION, AN D DERMATITIS. RELEASE DURING HIGH PRESSURE USAGE MAY RESULT IN INJECTION OF GREASE INTO THE SKIN CAUSING LOCAL NECROSIS. INHALATION: NOT EXPECTED TO BE A RELEVANT ROUTE OF EXPOSURE. HOWEVER, UNDER HIG H TEMPERATURE CONDITIONS, VAPORS IRRITATING TO THE NOSE, THROAT AND UPPER RESPIRATORY TRACT MAY BE PRODUCED. INGESTION: LUBRICATING GREASES ARE GENERALLY CONSIDERED NO MORE THAN SLIGHTLY TOXIC IF SWAL LOWED. Explanation of Carcinogenicity:THIS PRODUCT AND ITS COMPONENTS ARE NOT CLASSIFIED AS CARCINOGENS BY INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC), NATIONAL TOXICOLOGY PROGRAM (NTP) OR OCCUPATIONAL SAFETY AND HEALTH ADMINISTRAT ION (OSHA). Effects of Overexposure:EYE CONTACT: IRRITATION SKIN CONTACT: IRRITATION, DEFATTING, DRYING OF SKIN, NECROSIS. LOCAL NECROSIS IS EVIDENCED BY DELAYED ONSET OF PAIN AND TISSUE DAMAGE A FEW HOURS FOLLOWING INJECTION. INHALATIO N: NOSE, THROAT, UPPER RESPIRATORY TRACT IRRITATION. INGESTION: SLIGHTLY TOXIC. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE AND SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING/ SHOES AND WIPE EXCESS FROM SKIN. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH S OAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING UNTIL CLEANED. IF MATERIAL INJECTED UNDER SKIN, GET MEDICAL ATTENTION PROMPTLY TO PREVENT SERIOUS INJURY. INHALATION: MOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING DIFFICULT. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IN GENERAL, NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES ARE INGESTED. HOWEVER, GET MEDICAL ADVICE. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=221.1C, 430.F BASE OIL Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CO2. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER. Fire Fighting Procedures:MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:SULFUR OXIDES AND HYDROGEN SULFIDE, BOTH OF WHICH ARE TOXIC, MAY BE RELEASED UPON COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP EXCESS GREASE AND PLACE IN A CONTAINER. DISPOSE OF PROPERLY. Neutralizing Agent:NOT RELEVANT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. Other Precautions:MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETIC OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMIN ATED LEATHER ARTICLES INCLUDING SHOES THAT CANNOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT ORDINARILY REQUIRED. Ventilation:NOT PROVIDED. Other Protective Equipment:WEAR CLOTHING AS REQUIRED TO MINIMIZE CONTACT. Work Hygienic Practices:NOT PROVIDED. Supplemental Safety and Health NOTE TO PHYSICIAN: IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS, I.E., MOST OILS AND GREASES. ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:V6 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:NOT AVAILABLE Melt/Freeze Pt:=177.C, 350.6F M.P/F.P Text:(DROP POINT) Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NOT AVAILABLE Spec Gravity:< 1 (H2O=1)(7.53 LB/GAL) Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:NEGLIBLE. Appearance and Odor:BROWN SMOOTH GREASE, SLIGHT HYDROCARBON ODOR. Percent Volatiles by Volume:NOT PROVIDED Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:AVOID HEAT, FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, SULFUR OXIDES, COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID, PARTICULATES AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON PYROLYSIS OR COMBUSTION. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:FOR HIGHLY REFINED PETROLEUM OILS IN PRODUCT: ACUTE ORAL LD50 > 5.0 G/KG, RAT; ACUTE DERMAL LD50 >5 G/KG, RABBIT. ===================== Ecological Information ===================== Ecological:PRODUCT IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE, RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERC LA (SUPERFUND). HOWEVER, UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA), PRODUCT IS CONSIDERED AN OIL. AS SUCH, SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NA TIONAL RESPONSE CENTER, 800-424-8802. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF THIS PRODUCT BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA CRITERIA (40 CFR 261). PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT HAZARDOUS BY D.OT. REGULATIONS. DOT PROPER SHIPPING NAME: NOT APPLICABLE. OTHER REQUIREMENTS: NOT APPLICABLE. THIS PRODUCT IS AN OIL UNDER 49 CFR (DOT) PART 130. IF SHIPPED BY RAIL OR HIGHWAY IN A TANK WITH A CAPACITY OF 3,500 GALLONS OR MORE, IT IS SUBJECT TO THE REQUIREMENTS OF PART 130. MIXTURE SOLUTIONS IN WHICH THIS PRODUCT IS PRESENT AT 10% OR MORE MAY ALSO BE SUBJECT TO THIS RULE. ===================== Regulatory Information ===================== SARA Title III Information:IN ACCORDANCE WITH SECTION I I I, THE ENVIRONMENTAL DATA SHEET (EDS) SHOULD ALWAYS BE SENT WITH THE MSDS. NOT REGULATED BY SARA TITLE III. TOXIC CHEMICAL, SECTION 313: ZINC COMPOUNDS. THIS PRODUC T IS COVERED BY EPA'S COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA) PETROLEUM EXCLUSION. THEREFORE, RELEASES TO AIR, LAND, OR WATER ARE NOT REPORTABLE UNDER CERCLA ("SU PERFUND"). HOWEVER, UNDER SECTION 311 OF EPA'S CLEAN WATER ACT (CWA), THIS PRODUCT IS CONSIDERED AN OIL. AS SUCH, SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE N ATIONAL RESPONSE CENTER, 800-424-8802. Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/ TSCA INVENTORY OF CHEMICAL SUBSTANCES. PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAN AIR ACT AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR WAS IT DIRECTLY MANUFACTURED WITH ANY CLASS I OR CLASS I I OZONE DEPLETING SUBSTANCES. State Regulatory Information:THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES. ZINC COMPOUNDS, NO CAS NUMBER, 1-2 PERCENT, STATE CODE: CT, FL, IL, LA, MA, NJ, PA, RI. CA = CALIFORNIA HAZ. SUBST. LIST:CA65C, CA 65R, CA65C/R = CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST; CT = CONNECTICUT TOXIC. SUBST. LIST; FL = FLORIDA SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; L A = LOUISIANA HAZ. SUBST. LIST; MA = MASSACHUSETTS SUBST. LIST; ME = MAINE HAZ. SUBST. LIST; MN = MI NNESOTA HAZ. SUBST. LIST; NJ = NEW JERSEY HAZ. SUBST. LIST; PA = PENNSYLVANIA HAZ. SUBST. LIST; RI = RHODE ISLAND HAZ. SUBST. LIST. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:119 DISSOLVED SOLIDS SOLUTION 0-10,000 PPM CAGE:OAFT1 CAGE:94525 CAGE:OAFT1 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM CHLORIDE CAS:7447-40-7 RTECS #:TS8050000 Fraction by Wt: <10% Ingred Name:NON HAZARDOUS INGREDIENTS Fraction by Wt: >90% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING. DILUTE BY GIVING LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER, ALCOHOL FOAM, CO2 Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/VERMICULITE/SIMILAR ABSORBENT, SWEEP UP & PLACE IN DRY GARBAGE/FLUSH TO SEWER/GROUND W/LARGE AMOUNTS OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY AREA AWAY FROM ANY REACTIVE MATERIALS/CHEMICALS. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPORVED RESPIRATOR Other Protective Equipment:RUBBER APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1 Evaporation Rate & Reference:(WATER = 1): 1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID W/SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ANY TYPE OF REACTIVE MATERIALS/CHEMICALS. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= NIIN: 01-363-1632 Product ID: ECO SURE GRAY 16473 (664-183) AEROSOL Cage: 0FTT5 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 0FTT5 ======================================================= Contractor Summary ======================================================= Cage: 0FTT5 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: ENAMEL Specification Number: A-A-2787 Type/Grade/Class: TYPE 2 Unit of Issue: BX Quantitative Expression: 00000000012EA UI Container Qty: 0 ======================================================= Ingredients ======================================================= Cas: 111-76-2 RTECS #: KJ8575000 % Wt: 4.33 Other REC Limits: NONE RECOMMENDED OSHA PEL: 25 PPM ACGIH TLV: 25 PPM ------------------------------ Cas: 78-92-2 RTECS #: EO1750000 % Wt: 2.89 Other REC Limits: NONE RECOMMENDED OSHA PEL: 150 PPM ACGIH TLV: 100 PPM ------------------------------ Cas: 67-63-0 RTECS #: NT8050000 % Wt: 3.62 Other REC Limits: NONE RECOMMENDED OSHA PEL: 400 PPM ACGIH TLV: 400 PPM ------------------------------ Cas: 115-10-6 RTECS #: PM4780000 % Wt: 34.99 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. REPORTS ASSOCIATE REPEATED & PROLONGED OVEREXPOSURE W/ PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. HIGH CONCENTRATINGS ANESTHETIC. SKIN & RESPIRATO RY TRACT IRRITATION. LIGHT HEADEDNESS, STAGGERING, GIDDINESS, NAUSEA. HARMFUL IF SWALLOWED. SEVER EYE IRRITATION. Signs And Symptions Of Overexposure: IRRITATION TO EYES, THROAT, AND RESPIRATORY TRACT. MAY CAUSE HEADACHE, NAUSEA, AND VOMITING. Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS First Aid: FOR CONTACT WITH SKIN OR CLOTHES WASH WITH SOAP & WATER. WASH CLOTHES BEFORE REUSE. FOR CONTACT WITH EYES, FLUSH WITH WATER FOR 15 MINTUES. CONTACT A PHYSICIAN/OPHTHALMOLOGIST IMMEDIATELY. IF SWALLOWE D, DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL AID. INHALATION: GET FRESH AIR. GIVE ARTIFICAL RESPIRATION IF NECESSARY. GET MEDICAL AID. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL SOURCE OF IGNITION AND VENTILATE AREA. MOP SPILLS WITH INERT ABSORBENT. AVOID BREATHING VAPORS. Waste Disposal Methods: DISPOSE IN ACCORD WITH FEDERAL, STATE, & LOCAL REGULATIONS. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 120F. EXPOSURE TO HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN IN TRASH PICKUP. DON'T PLACE IN HOME TRASHCOMPACTOR. Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. CAUTION - CONTENTS UNDER PRESSURE. DO NOT STORE WHERE TEMPERATURES MAY EXCEED 120F. AVOID BREATHING SPRAY, MIST, VAPOR. Other Precautions: AVOID CONTACT WITH EYES AND SKIN. USE WITH GOOD VENTILATION. READ ENTIRE LABEL BEFORE USING. FOLLOW ALL LABEL DIRECTIONS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING OR SWALLOWING CO NTENTS MAY BE HARMFUL OR FATAL. ======================================================= Fire and Explosion Hazard Information ======================================================= Lower Limits: 3.4 Upper Limits: 18.0 Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY. AVOID SPREADING ANY BURNING LIQUID WITH WATER SPRAY. Fire Fighting Procedures: WATER MAY BE INEFFECTIVE,USE TO KEEP FIRE EXPOSED CONTAINER COOL. WEAR SCBA. USE SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING,RUPTURING,VENTING OF CONTAINERS Unusual Fire/Explosion Hazard: DO NOT SPRAY NEAR OPEN FLAME. AT ELEVATED TEMPERATURE (>120F) CONTAINERS MAY VENT, RUPTURE OR BURST. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE BELOW TLV. USE NIOSH/MSHA APPROVED MASK ABOVE TLV. Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE AT POINT OF MIST OR SPRAY RELEASE. Other Protective Equipment: IMPERVIOUS CLOTHES TO PROTECT SKIN. EYE WASH STATION. Work Hygienic Practices: USE GOOD PERSONAL HYGIENE. DO NOT EAT, DRINK, OR SMOKE WHILE USING PRODUCT. Supplemental Safety and Health: SPECIFIC GRAVITY FOR AEROSOL = 0.863. ======================================================= Physical/Chemical Properties ======================================================= Vapor Pres: 63 PSIG Vapor Density: >1.6 Spec Gravity: 1.088 VOC Grams/Liter: 394 Solubility in Water: MISCIBLE Appearance and Odor: GRAY / PAINT ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXTREME HEAT Hazardous Decomposition Products: CARBON MONOXIDE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: EXTREME HEAT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 129423 Product ID: ECO SURE GRAY 16473 (664-183) AEROSOL Review Date: 03/27/1996 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: BX Container QTY: 0 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: DTJ Symbols: D DOT Proper Shipping Name: CONSUMER COMMODITY Hazard Class: ORM-D Label: NONE Non Bulk Pack: 156,306 Bulk Pack: NONE Max Qty Pass: 30KGGROSS Max Qty Cargo: 30KGGROSS Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: AKH IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ? IMDG Page Number: SEE 9022 UN Number: 1950 UN Hazard Class: 9? IMO Packaging Group: - Subsidiary Risk Label: - EMS Number: 2-13 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ALS IATA UN ID Num: 1950 IATA Proper Shipping Name: AEROSOLS, FLAMMABLE IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY) IATA UN Class: 2.1 IATA Label: FLAMMABLE GAS Packing Note Passenger: 203 Max Quant Pass: 75KG Max Quant Cargo: 150KG Packaging Note Cargo: 203 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ALR AFI Symbols: * AFI Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S. AFI PSN Modifier: (EACH NOT EXCEEDING 1L CAPACITY) AFI Hazard Class: 2.1 AFI UN ID NUM: UN1950 Special Provisions: P4 Back Pack Reference: A6.3 ======================================================= HAZCOM Label ======================================================= Product ID: ECO SURE GRAY 16473 (664-183) AEROSOL Cage: 0FTT5 Company Name: LHB INDUSTRIES Street: 8833 FLEISCHER PLACE Zipcode: 63134 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. REPORTS ASSOCIATE REPEATED & PROLONGED OVEREXPOSURE W/ PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. HIGH CONCENTRATINGS ANESTHETIC. SKIN & RESPIRATO RY TRACT IRRITATION. LIGHT HEADEDNESS, STAGGERING, GIDDINESS, NAUSEA. HARMFUL IF SWALLOWED. SEVER EYE IRRITATION. IRRITATION TO EYES, THROAT, AND RESPIRATORY TRACT. MAY CAUSE HEADACHE, NAUSEA, A ND VOMITING. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CT-2404,MIL-C-19853,TYPE I,CLASS I Preparer's Name:BOB E. FLYNT CAGE:55208 CAGE:55208 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE (SARA 313) (CERCLA)/DICHLOROMETHANE CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM; Z-2 ACGIH TLV:50 PPM, A2; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHENOL (SARA 302/313) (CERCLA) CAS:108-95-2 RTECS #:SJ3327000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CRESOL, ALL ISOMERS (CRESYLIC ACID) (SARA 313) (CERCLA) CAS:1319-77-3 RTECS #:GO5950000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- INHALE:INDUCES NARCOSIS, DIZZINESS. EYE:CORROSIVE. MAY CAUSE EYE INJURY. SKIN:CORROSIVE. WILL CAUSE SCARRING WHICH DISAPPEARS IN 1-2 YEARS. OR AL:MAY CAUSE BURNING OF MOUTH, THROAT &STOMACH. CHRONIC- WILL CAUSE HAZY VISION WHICH RETURNS TO NORMAL. Explanation of Carcinogenicity:CONTAINS DICHLOROMETHANE. Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, HEADACHES, PAIN, DIZZINESS Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, RINSE MOUTHWITH WATER. SEEK IMMEDIATE MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, MONITOR FOR BREATHING DIFFICULTY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONTACT WITH FLAME MAY FORM TOXIC FUMES AND/OR PHOSGENE GAS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE PERSONNEL. WEAR PROPER PROTECTIVE CLOTHING AND EQUIPMENTS. VENTILATE AREA. STOP LEAK IF POSSIBLE. ALLOW TO EVAPORATE. SWEEP UP RESIDUE WITH SAWDUST OR SWEEPING COMPOUND. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, WEAR A NIOSH-APPROVED SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST AND/OR MECHANICAL (GENERAL) VENTILATION AS REQUIRED TO KEEP CONCENTRATIONS BELOW OSHA PEL. Other Protective Equipment:RUBBER CLOTHING AS NEEDED TO PREVENT PROLONGED/REPEATED SKIN CONTACT, EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health PERCENTAGE CHANGED. FOR PREVIOUS CONCENTRATION SEE PNI A, SAME NSN. ================== Physical/Chemical Properties ================== HCC:B2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=46.1C, 115.F Vapor Pres:200 Vapor Density:2 Spec Gravity:1.2 pH:11 Viscosity:<10 CPS Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:INSOLUBLE,DISPERSIBL Appearance and Odor:DIPHASE LIQUID - PUNGENT ODOR Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES Stability Condition to Avoid:OPEN FLAMES AND ELECTRICAL ARCS Hazardous Decomposition Products:EMITS HIGHLY TOXIC GAS OF PHOSGEN WHEN HEATED TO DECOMPOSITION. CONTACT WITH HOT SURFACE/FLAME MAY FORM PHOSGENE AND HCL ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN FULL COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. HAZARDOUS WASTE NUMBERS: U052, U080, U188.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ED-394, CLEANING COMPOUND, AIRCRAFT SURFACE Preparer's Name:PAT E. SMITH CAGE:55208 CAGE:55208 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC PETROLEUM NAPHTHAS CAS:68476-34-6 Fraction by Wt: 12.0% Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 5.0% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:UNIDENTIFIED COMPONENTS CAS:141-43-5 OSHA PEL:3 PPM/6 STEL ACGIH TLV:NOT SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATE INHALATION HAZARD, MODERATE SKIN CONTACT HAZARD, CORROSIVE TO EYES. Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:ACUTE AND/OR CHRONIC INHALATION MAY CAUSE IRRITATION, DIZZINESS, NAUSEA AND FATIGUE. MAY CAUSE SKIN IRRITATION; PROLONGED SKIN CONTACT MAY RESULT IN DERMATITIS. CORROSIVE TO EYES! WILL BURN EYES IMMED IATELY UPON CONTACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES. CONSULT PHYSICIAN IMMEDIATLEY. SKIN: REMOVE CLOTHING. WASH SKIN WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. CONSULT PHYSICIAN IF IRRITATION DEVELOPES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NONFLAMMABLE Upper Limits:NONFLAMMABLE Extinguishing Media:TREAT AS CLASS B (OIL TYPE) FIRE Fire Fighting Procedures:CONTAINS MIXTURE OF PETROLEUM DISTILLATES. LIQUID CONTACT MAY CAUSE EYES AND SKIN IRRITATION. SAME PROCEDURES AS FOR PETROLEUM NAPHTHA. Unusual Fire/Explosion Hazard:CONTAINS MIXTURE OF PETROLEUM DISTILLATES. VAPOR INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION. WEAR SELF-CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:RINSE WITH WATER Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM STRONG OXIDIZERS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA REQUIRED IF LIMITS ARE EXCEEDED Ventilation:100 FT/MIN Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health AVOID PROLONGED SKIN CONTACT. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:220F,104C Melt/Freeze Pt:M.P/F.P Text:<10F,<-12C Vapor Pres:20 MM Vapor Density:1 Spec Gravity:1.0 pH:10 Evaporation Rate & Reference:0.5 (WATER = 1) Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:CLEAR, AMBER LIQUID Percent Volatiles by Volume:0 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0748188 4331628/4331629 AMOXICILLIN W/CLAVULANIC ACID CAGE:06531 CAGE:05545 CAGE:06531 CAGE:15481 ============= Composition/Information on Ingredients ============= Ingred Name:AMOXICILLIN CAS:26787-78-0 RTECS #:XH8300000 Ingred Name:CLAVULANIC ACID CAS:58001-44-8 RTECS #:RN6802500 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE MEDIA FOR SURROUNDING FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:MAY BE SWEPT UP & DISPOSED OF W/NORMAL LAB TRASH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL LABORATORY CONDITIONS. Ventilation:NONE REQUIRED UNDER NORMAL PRODUCT USAGE. Other Protective Equipment:NONE REQUIRED UNDER NORMAL PRODUCT USAGE. Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD BE PRACTICED. Supplemental Safety and Health INDIVIDUALS W/KNOWN/SUSPECTED ALLERGIES TO ANTIBIOTICS SHOULD ADVISE PHYSICIAN OF INCIDENT THAT MAY HAVE RESULTED IN EXPOSURE TO ANTIBIOTICS TREATED PRODUCT. ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:PAPER DISCS OF VARIABLE COLOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:MAY BE DISPOSED OF W/NORMAL LAB TRASH IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:667270 DECISION LEV 1 KIT DOM CAGE:1W937 CAGE:1W937 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <40% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HUMAN PROTEIN Fraction by Wt: <10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT: 8.54 G/KG ETHYLENE GLYCOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ETHYLENE GLYCOL MAY CAUSE IRRITATION OF MUCOUS MEMBRANES & RESPIRATORY PASSAGES. INGESTION: ETHYLENE GLYCOL MAY CAUSE INTOXICATION & COMA. SKIN: ETHYLENE GLYCOL MAY CAUSE IRRITATION. HUMANPROTEIN SOURCES ARE CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREAS THOROUGHLY. INGESTION, EYES OR CONTACT W/OPEN WOUND. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. ABSORB ON INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:HEAT WILL DEGRADE EFFICACY. HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Other Precautions:STORE AS INDICATED ON DIRECTION INSERT. FOR IN VITRO DIAGNOSTIC USE ONLY. NOT FOR HUMAN OR ANIMAL USE. HANDLE BROKEN OR ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:GENERAL IS ACCEPTABLE Other Protective Equipment:EYE BATH Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:>1 Evaporation Rate & Reference:(WATER = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:AMBER VISCOUS LIQUID, W/SLIGHT ODOR Percent Volatiles by Volume:>75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS NECESSARY FOR BIOHAZARDOUS MATERIALS. DISPOSE OF IN ACCORDANCE W/APPLICABLE FEDERAL, STATE, & LOCAL LAWS & REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7640 TONER CAGE:S0407 CAGE:S0407 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 13% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:STYRENE ACRYLIC RESIN Fraction by Wt: 85% Ingred Name:DYE (PROPRIETARY) Fraction by Wt: 2% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE ORAL TOXICITY: > 10 G/KG BODY WEIGHT. SKIN IRRITATION (RABBIT): MILDLY IRRITATING. AMES TEST RESULT: NEGATIVE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE UNDER NORMAL USE CONDITION. Medical Cond Aggravated by Exposure:WILL NOT OCCUR. ======================= First Aid Measures ======================= First Aid:SKIN:WASH THOROUGHLY W/SOAP & WATER. EYE:TRY TO REMOVE OR FLUSH W/EYE DROPS. IF UNSUCCESSFUL, GET MD. INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE ARTF RESP/O*2) . INGEST:CALL MD IMMEDIATE LY . ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL OR CO*2 MAY BE SUITABLE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WILL NOT OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, SWEEP UP OR PICK UP BY VACUUM CLEANER. REMOVE RESIDUE W/SOAP & COLD WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL & DRY PLACE. DO NOT HANDLE IN AREAS WHERE WIND BLOWS. FLYING POWDER MAY ENTER EYES. MINIMIZE INHALATION OF DUST. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL USE CONDITIONS. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL (GENERAL) IS ADEQUATE VENTILATION. Other Protective Equipment:NONE NEEDED. Work Hygienic Practices:CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS & MEALS & AT THE END OF WORK PERIOD. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:0.34 (H*2O=1) Evaporation Rate & Reference:NOT APPLICABLE. Solubility in Water:NEGLIGIBLE: <0.1% Appearance and Odor:BLACK POWDER; PRACTICALLY ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:CO & OTHER DECOMPOSITION PRODUCTS IN CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:USED TONER SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER & I/A/W GOVERNMENTAL REGULATIONS. DO NOT INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ST1018 STP NEWER CAR OIL TREATMENT Preparer's Name:R.L.LEWIS CAGE:0CX27 CAGE:0CX27 CAGE:050Q3 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT EXTRACTED MINERAL OIL Other REC Limits:NONE RECOMMENDED Ingred Name:ZINC SALT OF DIALKYL DITHIOPHOSPHORIC ACID Other REC Limits:NONE RECOMMENDED Ingred Name:PROPRIETARY ADDITIVES Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST:INGEST PETROLEUM OIL(MAJOR INGRED)EXPECTED TO HAVE LITTLE ACUTE TOXICITY.NAU,VOMIT,FREQ LOOSE STOOLS,DIARR,ABD PAIN,BELCHING MAY BE NOTED.SERIOUS POT TOXIC EFFECT FOLLOWING INGEST IS ASPIRATION OF PROD INTO LUNGS WHICH MAY RESULT INSER LUNG INJURY.SKIN ABSORP:NO EVIDENCE OF ADVERSE EFFECTS FRM AVAI INFO.(SUPPL) Explanation of Carcinogenicity:PER MSDS:NONE OF INGREDS LISTED AS CARC OR POTENTIAL CARC BY OSHA/NTP/IARC. Effects of Overexposure:PROLONGED/REPEATED SKIN CONTACT W/THIS PRODUCT TENDS TO REMOVE SKIN OIL POSSIBLY LEADING TO IRRITATION AND DERMATITIS. Medical Cond Aggravated by Exposure:PERSONS PRONE TO ACNE/SEBORRHEA SUSCEPT TO HAIR FOLLICLES BLOCAKGE BY INSOL OILS.FOLLICULITIS MAY DVLP.COMEDONES/PERIFOLLICULAR PAPULES/PUSTULES MAY OCCUR.THESE RAPID CLEAR UPON EXPO CESSATION. ======================= First Aid Measures ======================= First Aid:INGEST:DONT INDUCE VOMIT.GET IMMED MED ATTN.VOMIT OCCURS SPONT KEEP HEAD BELOW HIPS-PREVENT ASPIRATION.SKIN:REMOVE CONTAM CLOTH.IMMED WASH W/SOAP/COPIOUS AMTS OF H2O.IRRIT/RED DVLPS/PERSIST GET MED AT TN.INHAL:REMOVE TO FRESH AIR.BREATH DIFFI GIVE OXY;BREATH STOP GIVE ART RESP.GET MED ATTN IMMED.EYE:IMMED FLUSH W/COPIOUS AMTS OF H2O 15MINS MIN.IRRIT/PAIN/SWELL/TEAR GET MED ATTN.DR:NO SPEC ANTIDOTE. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:201F,94C Autoignition Temp:Autoignition Temp Text:N/DETR Lower Limits:N/DETERMINED Upper Limits:N/DETERMINED Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE, OR DRY CHEMICALS. Fire Fighting Procedures:USE POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS WHEN ENTERING A CONFINED SPACE. Unusual Fire/Explosion Hazard:NONE EXPECTED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PERSONAL PROTECTIVE EQPMT.COLLECT FOR DISPOSAL BY PUMPING OR BY USING SUITABLE ABSORBENT MATL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATH VAP/MIST;CONTACT W/EYES;PROL SKIN CONTACT.WASH EXPO SKIN W/SOAP/H2O AFT USE.KEEP AWAY FRM SOURCES OF HEAT/SPARK/FLAME,AWAY FRM STRON OXID Other Precautions:KEEP CNTNRS CLSD WHEN NOT IN USE.OBSERVE ALL REQMTS OF PLANT/COMPANY/GOVT REGS."EMPTY"CNTNR RETAIN PROD RESIDUE,CAN BE DANGEROUS.DONT PRESSURIZE,CUT,WELD,BRAZE,DRILL,GRIND,ETC ON/NEAR CNTNR/EXPO CNTNR TO HEAT.KEEP OUT REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL USE CONDITIONS.TLV EXCEEDED NIOSH/MSHA APPROV ORG VA/DUST/MIST RESP OR SUPPL AIR RESP RECOMMENDED.EQPMT SELECTION DEPEND ON CONTAM TYP/CONCEN,SELECT IAW 29CFR1910.134 & GOOD INDUST HYG PRACT.FIREFIGHT USE SCBA. Ventilation:GEN VENTI SHOULD BE ADEQUA FOR NORMAL USE.OPERATIONS WHERE TLV EXCEED MECH VENTI(LOC EXHA)NEEDED-MAINTAIN EXPO LEVEL Other Protective Equipment:PROT CLOTH IF NEEDED-AVOID SKIN CONTACT.SUITABLE WASH/EYE FLUSH FACILI AVAI IN WORKAREA.REMOVE CONTAM CLOTH,WASH BEF USE Work Hygienic Practices:GOOD HOUSEKEEPING/PERSONAL HYGIENE SHOULD PREVENT LESIONS MENTIONED IN "MED CONDITIONS AGGRAVATED BY EXPO" SEC. Supplemental Safety and Health HEALTH:UNLIKELY W/NORMAL USAGE.MIST/VAP LUNG INJURY MAY OCCUR IF EXPO PROL IN POORLY VENTI SURROUNDINGS.WARN:PROD OVERHEATED ESPEC IN PRESENCE OF H2O HYDROGEN SULFIDE RELEASE-RESP COLLAPSE,COMA,DEATH W/O WARNING ODOR SENSED.SKIN:SLIGHT IRRIT,RED,SWELL,DRYING.EYE:MILD REVERS IRIT OF CONJ W/EXCESS TEAR PROD,BLINK,RED. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:500F,260C Melt/Freeze Pt:M.P/F.P Text:N/DETERMINE Decomp Temp:Decomp Text:NP Vapor Pres:5 Vapor Density:N/DETERMIN Spec Gravity:7.50 LBS/GAL pH:NONE Viscosity:10.3 Evaporation Rate & Reference:NEGLIGIBLE,BUAC=1 Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK AMBER LIQUID WITH HYDROCARBON ODOR Percent Volatiles by Volume:0 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:FUMES, SMOKE, AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATL SHOLD BE INCINERATED,RECYCLED,TREATED,LAND FILLED IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.CONTAIN CHEM SUBJ TO SEC 313 TITLE III SARA/40CFR372:ZINC CMPD 5%MAX.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:310CB-15 COATED WELDING ELECTRODE Preparer's Name:JAN WALLACE CAGE:FO309 CAGE:FO309 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (DUST & MIST), BRONZE POWDER CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0.75% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: BALANCE Ingred Name:AMORPHOUS FUSED SILICA, SILICON DIOXIDE, QUARTZ, SILICON INTENTED CHANGE (IC) CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: .30-.65% Other REC Limits:30 MG/CUM TOTAL DUST OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:CARBON, GRAPHITE PERCENT: 0.08-0.15% CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: ABOVE OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN CARCINOGEN BY IARC, NTP & ACGIH) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 25-28% OSHA PEL:1 MG/CUM (CEILING) ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC, ACGIH) INTENDED CHANGE (IC) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 20-22.5% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC (A1) Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 0.75% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1-2.5% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: DISCOMFORT, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF THE THROAT. Explanation of Carcinogenicity:CHROMIUM IS A SUSPECTED A1 HUMAN CARCINOGEN BY ACGIH. NICKEL IS A SUSPECTED CARCINOGEN BY NTP/IARC. Effects of Overexposure:INHALATION: PULMONARY IRRITATION OR PNEUMOCONIOSIS & SIDEROSIS. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:NONFLAMMABLE. WELDING ARC, OPEN FLAME & SPARKS CAN IGNITE COMBUSTIBLES. ======================Handling and Storage ====================== Handling and Storage Precautions:TRAIN THE EMPLOYEE TO KEEP HIS HEAD OUT OF THE FUMES & NOT TO TOUCH THE ELECTRICAL PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. Other Precautions:TAKE AN AIR SAMPLE FROM INSIDE THE WELDER'S HELMET IF WORN OR IN THE WORKER'S BREATHING ZONE TO DETERMINE THE COMPOSITION & QUANTITY OF FUMES & GASES WHICH WORKERS ARE EXPOSED. AVOID INJURY FROM RADIA TION/SPARKS/FLAME/ELECTRICAL SHOCK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING, BRAZING OR SOLERING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP <TLV. Ventilation:LOCAL EXHAUST SHOULDER PROTECTIVE & DARK SUBSTANTIAL CLOTHING. Work Hygienic Practices:READ & UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS & PRECAUTIONARY LABEL ON THE PRODUCT. Supplemental Safety and Health WELDING ELECTRODE OR WIRE IS A NONHAZARDOUS SOLID AT AMBIENT TEMPERATURE. HAZARDS MAY RESULT FROM FUME GENERATED DURING WELDING. ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID WIRE/RODS. RODS ARE COATED W/FLUX FOR USE WITH SHIELDED METAL ARC PROCESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:WELDING ARC, OPEN FLAME & SPARKS. Hazardous Decomposition Products:CO, CO2, OZONE, OXIDES OF METAL & NITROGEN.
1
eyes_protection_mandatory
======================================================= Product ID: BLACK POLYURETHANE BLACK, US511N6 Cage: 3AG66 ======================================================= Contractor Summary ======================================================= Cage: 3AG66 Country: CD ======================================================= Ingredients ======================================================= Cas: 16091-18-2 RTECS #: JH4745000 POLYMER). LD50: (ORAL,RAT) 2100 450 MG/KG OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: TRACE OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 1333-86-4 RTECS #: FF5800000 OSHA PEL: 3.5 MG/M3 ACGIH TLV: 3.5 MG/M3 ------------------------------ % Wt: TRACE OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENT 1 Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: ACUTE: POWDER COATINGS MAY IRRITATE SKIN OR RESPIRATORY TRACT IN SENSITIVE INDIVIDUALS. EYE CONT MAY BE ABRASIVE. POSSIBILITY OF SWALLOWING IS MINIMAL. IF IT DOES OCCUR IT MAY CAUSE GASTROINTESTINAL I RRIT. CARBON BLACK: PRIMARY HAZARD IS MECH IRRIT OF EYE, LUNG, & SKIN DUE TO EXCESSIVE DUSTING. INHAL:(EFTS OF OVEREXP) Explanation Of Carcinogenicity: CARBON BLACK: IARC MONO, VOL 65, PG 149, GROUP: 2B. Signs And Symptions Of Overexposure: HLTH HAZ:EXCESSIVE DUST EXPOS MAY CAUSE PHYSICAL RESP TRACT IRRIT. AVOID BRTHG DUST. EYE: IRRITATION UPON DIRECT CONTACT. SKIN: POSSIBLE IRRITATION. SKIN ABSORP: SINGLE PROLONGED EXPOS IS NOT LIKELY T O RSLT IN MATL BEING ABSORBED THRU SKININ HARMFUL AMTS. INGEST: MAY BE HARMFUL. Medical Cond Aggravated By Exposure: NO DATA. First Aid: INHAL: REMOVE TO FRESH AIR & CONTACT PHYSICIAN IF NECESSARY. SKIN: WASH W/MILD SOAP & WATER. EYE: FLUSH W/ABUNDANT AMOUNT OF WATER FOR AT LST 15 MINUTES AND CONTACT PHYSICIAN IF NECESSARY. INGEST: IF LARGE AMOUNT IS SWALLOWED, GIVE SEVERALGLASSES OF WATER AND CONTACT PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. SWEEP OR VACUUM INTO CONTAINER IN MANNER AS TO NOT CREATE DUST. UNCONTAMINATED MATERIAL MAY BE SCOOPED UP FOR REUSE. IF CONTAMD, MATERIAL SHOULD BE PLACED IN RECEPTACLE FOR DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: PLACE COLLECTED MATERIAL INTO CLOSED CONTAINER AND DISPOSE IN SUITABLE LANDFILL IN ACCORDANCE WTIH MUNCIPALITY, PROVINCIAL, FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: MINIMIZE CONC OF DUST IN WORKPLACE ENVIRONMENT. PROTECT CNTNRS FROM PHYSICAL DMG. STORE POWDER BELOW 30C. KEEP CNTNRS CLSD WHEN NOT IN USE. Other Precautions: STORE IN COOL, DRY PLACE AWAY FROM HEAT & HUMIDITY. NUISANCE DUST: NUISANCE DUSTS ARE NOT EXPECTED TO CAUSE SIGNIFICANT ORG DISEASE/TOXIC EFT WHEN EXPOS ARE CONTROLLED TO LIMITS STATED. ACGIH SUGGESTS THAT EXCESS CONCS OF NUISANCE PARTICULATES IN WORKPLACE MAY SERIOUSLY REDUCE VISIBILITY. MAY CAUSE UNPLEASANT (SUPDAT) ======================================================= Fire and Explosion Hazard Information ======================================================= Lower Limits: 30 MG/M3 Upper Limits: 2-3 KG/M3 Extinguishing Media: CO*2, DRY CHEMICAL, SAND OR GROUND LIMESTONE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). DO NOT ALLOW POWDER TO BE DISPERSED INTO THE AIR WHILE FIGHTING FIRES. Unusual Fire/Explosion Hazard: DUST MIXTUES IN AIR MAY BE FLAMMABLE. ======================================================= Control Measures ======================================================= Respiratory Protection: IN CASE OF EXPOSURE, USE APPROPRIATE NIOSH APPROVED LISTED DUSTMAK OR RESPIRATORY DEVICES FOR PARTICULATES AND FUMES. Ventilation: SUFFICIENT LOCAL EXHAUST VENT TO STAY BELOW REGULATED EXPOSURE LIMITS. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). WEAR APPROPRIATE, CLEAN PROTECTIVE CLOTHING SUCH AS, SMOCKS, COVERALLS, SHOES, HATS. ALL TO MINIMIZE CONTACT WITH SKIN. Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED SHOES. Supplemental Safety and Health: OTHER PRECAUTIONS: DEPOSITS IN EYES & NASAL PASSAGES MAY CAUSE INJURY TO SKIN OR MUCOUS MEMBRANES BY CHEMICAL OR MECHANICAL ACTION OR BY RIGOROUS SKIN CLEANSING PROCECURE NECESSARY FOR THE REMOVAL. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.2-1.9(H*2O=1) Solubility in Water: NOT SOLUBLE Appearance and Odor: ODORLESS POWDER. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID CONTAMINATION WITH STRONG OXIDIZING AGENTS. Materials To Avoid: ACIDS, ORGANIC SOLVENTS AND CAUSTIC SUBSTANCES. Hazardous Decomposition Products: INCOMPLETE COMBUSTION CAN YIELD LOW MOLECULAR WEIGHT HYDROCARBONS & CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: COATING & MATERIAL VOLATILE ORGANIC COMPOUND: 0.00 ======================================================= HAZCOM Label ======================================================= Product ID: BLACK POLYURETHANE BLACK, US511N6 Cage: 3AG66 Company Name: PROTECH CHEMICALS LTD Street: 7600 HENRI-BOURASSA WEST H4S 1W3 Zipcode: 00000 Country: CD Label Required IND: Y Date Of Label Review: 04/30/1998 Status Code: C Label Date: 04/30/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: POWDER COATINGS MAY IRRITATE SKIN OR RESPIRATORY TRACT IN SENSITIVE INDIVIDUALS. EYE CONT MAY BE ABRASIVE. POSSIBILITY OF SWALLOWING IS MINIMAL. IF IT DOES OCCUR IT MAY CAUSE GASTROINTESTINAL I RRITATION. CARBON BLACK: PRIMARY HAZARDIS MECHANICAL IRRITATION OF EYE, LUNG, & SKIN DUE TO EXCESSIVE DUSTING. INHAL:EXCESSIVE DUST EXPOSURE MAY CAUSE PHYSICAL RESPIRATORY TRACT IRRITATION. SKIN: IRRI TATION UPON DIRECT CONTACT. SKIN: POSSIBLE IRRITATION. INGESTION: MAY BE HARMFUL. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EXTENDED FLANGE FS25 CAGE:45255 CAGE:45255 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS, OXIDE *92/3* CAS:65997-17-3 Fraction by Wt: 85-96% Other REC Limits:10 MG/CUM 8 TWA Ingred Name:UREA EXTENDED PHENOL FORMALDEHYDE RESIN CURED *92-3* CAS:25104-55-6 Fraction by Wt: 4-15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: UPPER RESPIRATORY TRACT, MOUTH, NOSE, & THROAT IRRITATION. SKIN: ITCHING & TEMPORARY MECHANICAL IRRITATION. EYES: TEMPORARY MECHANICAL IRRITATION. INGESTION: DIGESTIVE TRACT TEMPORARY MECH ANICAL IRRITATION. Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY OR SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/MILD SOAP & RUNNING WATER. USE A WASHCLOTH TO HELP REMOVE FIBERS. TO AVOID FURTHER IRRITATION DO NOT RUB OR SCRATCH IRRITATION AREAS. RUBBING OR SCRATCHIN G MAY FORCE FIBERS INTO SKIN. USE OF BARRIER CREAM CAN BE HELPFUL. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, DRY CHEMICAL Fire Fighting Procedures:IN A SUSTAINED FIRE, SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. Unusual Fire/Explosion Hazard:VINYL FACED IN FIRE CONDITIONS MAY GIVE OFF HYDROGEN CHLORIDE, A HIGHLY IRRITATING & TOXIC GAS. EVACUTE THE BUILDING IMMEDIATELY. ================== Accidental Release Measures ================== Spill Release Procedures:USE VACUUM EQUIPMENT TO CLEAN DUSTS & FIBERS. AVOID SWEEPING OR USING COMPRESSED AIR AS THESE TECHNIQUES RESUSPEND DUSTS & FIBERS INTO THE AIR. ======================Handling and Storage ====================== Handling and Storage Precautions:INSULATION SHOULD BE STORED IN A DRY PLACE. FACED MATERIAL SHOULD BE STORED WELL AWAY FROM SOURCES OF IGNITION. Other Precautions:AVOID DUST & FIBERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A PROPERLY FITTED NIOSH OR MSHA APPROVED AIR PURIFYING RESPIRATOR SUCH AS THE 3M MODEL 8710, MODEL 9900 OR EQUIVALENT. Ventilation:GENERAL DILUTION. LOCAL EXHAUST SHOULD BE PROVIDED. Other Protective Equipment:WEAR LOOSE FITTING, LONG SLEEVED SHIRT, LONG PANTS, SAFETY SHOWERS & EYE WASH FOUNTAINS. Work Hygienic Practices:WASH CLOTHES SEPARATELY & WIPE OUT WASHER, TO PREVENT FIBERS FROM GETTING ON OTHER CLOTHES. WASH HANDS THOROUGHLY. Supplemental Safety and Health APPEAR CON'T: SOME PRODUCTS HAVE A VINYL, KRAFT PAPER, FOIL OR POLYPROPYLENE FACING. ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:PINK, YELLOW, OR TAN W/FAINT RESIN ODOR. SEE SUPP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO, CO2, AMMONIA, WATER, & HYDROGEN CHLORIDE. VINYL FACED PRODUCTS WILL RELEASE HYDROGEN CHLORIDE IN A FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. THE PRIMARY METHOD OF DISPOSAL IS IN A MUNICIPAL OR INDUSTRIAL LANDFILL.
1
eyes_protection_mandatory
======================================================= Product ID: CWT-5575 Cage: TO077 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: TO077 ======================================================= Item Description Information ======================================================= ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: SKIN: WILL CAUSE IRRITATION AND BURNING SENSATION; MAY CAUSE BURNS. EYES: SEVERE IRRITATION, REDDENING OF TISSUE, BURNING SENSATION; WILL CAUSE BURNS. INHALATION: INHALATION OF MIST MAY RESULT IN VARY ING DEGREES OF IRRITATION OR DAMAGE TO RESPIRATORY TRACT TISSUE.INGESTION: CAN CAUSE SEVERE BURNS AND COMPLETE TISSUE PERFORATION OF MUCOUS MEMBRANES OF THE MOUTH, THROAT, ESOPHAGUS AND STOMACH. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: ALWAYS HAVE PLENTY OF WATER AVAILABLE FOR FIRST AID. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES: WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES; E NSURE WATER FLUSHING OF ENTIRE SURFACE OF EYE AND LID. OBTAIN MEDICAL ATTENTION. INHALATION: IF INHALED, REMOVE TO FRESH AIR.INGESTION: IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER OR MILK. OBTAIN MEDICAL ATTENTION AT ONCE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE APPROPRIATE PROTECTIVE EQUIPMENT. DIKE TO CONTAIN SPILL. COVER WITH INERT ABSORBENT MATERIAL, SWEEP UP AND PLACE IN SUITABLE CONTAINER. FLUSH AREA WELL WITH WATER. KEEP SPILLS AND CLEANING RUN-OF F OUT OF MUNICIPAL SEWERS AND OPEN BODIES OF WATER. Waste Disposal Methods: AQUEOUS SOLN: NEUTRALIZATION OF THE ALKALINITY, PRECIPITATION OF PHOSPHATES, & FURTHER TREATMENT MAY BE REQD TO MEET LOCAL, STATE & FED WASTE CONTROL REGS. MATL COLLECTED ON ABSORBENT MUST BE DISPOSED TO PERMITTED HAZ WASTE MANAGEMENT FACILITY I/A/W CLEAN AIR & WATER ACTS, RCRA & ALL RELEVANT LAWS O R REGS REGARDING DISPOSAL. Handling And Storage Precautions: KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY LOCATION. Other Precautions: WASH WITH SOAP AND WATER AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE EXTINGUISHING MEDIA PROPER TO THE PRIMARY CAUSE OF THE FIRE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE EXPECTED. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR FOR DUSTS AND MISTS. Ventilation: LOCAL OR MECHANICAL EXHAUST. (FP N). Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). APRON OR PROTECTIVE CLOTHING. Work Hygienic Practices: NO. Supplemental Safety and Health: VOC (AS PACKAGED, MINUS WATER): NONE. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =104.4C, 220.F Melt/Freeze Pt: =0.C, 32.F Vapor Pres: WATER VAP Vapor Density: WATER VAP Spec Gravity: 1.17 (H*2O=1) PH: APPROX 13 Evaporation Rate & Reference: 1.0 (H*2O=1) Solubility in Water: COMPLETE Appearance and Odor: DARK BROWN LIQUID; BLAND ODOR. Percent Volatiles by Volume: NO INFO ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: STRONG ACIDS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= Transport Information: HAZARD CLASS: CORROSIVE MATERIAL. DOT SHIPPING NAME: COMPOUNDS, CLEANING LIQUID. UN NUMBER: N/A. NA#: NA 1760. OTHER HAZARD DATA: POTASSIUM HYDROXIDE SOLUTION. ======================================================= Regulatory Information ======================================================= Sara Title III Information: SARA TITLE III RQ LBS: POTASSIUM HYDROXIDE: 1000 LBS. ======================================================= Other Information ======================================================= Other Information:: HEALTH: 3; FLAMMABILITY: 0; REACTIVITY: 0; PERSONAL PROTECTION: D. ======================================================= HAZCOM Label ======================================================= Product ID: CWT-5575 Cage: TO077 Assigned IND: Y Company Name: CMI INC Street: 5240 CRAWFORDSVILLE RD Zipcode: 46224 Label Required IND: Y Date Of Label Review: 07/15/1999 Status Code: A Origination Code: F Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: SKIN: WILL CAUSE IRRITATION AND BURNING SENSATION; MAY CAUSE BURNS. EYES: SEVERE IRRITATION, REDDENING OF TISSUE, BURNING SENSATION; WILL CAUSE BURNS. INHALATION: INHALATION OF MIST MAY RESULT IN VARYING DEGREES OF IRRITATION OR DAMAGE TO RESPIRATORY TRACT TISSUE. INGESTION: CAN CAUSE SEVERE BURNS AND COMPLETE TISSUE PERFORATION OF MUCOUS MEMBRANES OF THE MOUTH, THROAT, ESOPHAGUS AND STOMA CH. CHRONIC: NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BC100 BIOCOLOR 1 GAL Preparer's Name:WOODHALL STOPFORD CAGE:GO468 CAGE:GO468 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE Explanation of Carcinogenicity:NONE Effects of Overexposure:NONE ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE REQUIRED Fire Fighting Procedures:NONE REQUIRED Unusual Fire/Explosion Hazard:NON COMBUSTIBLE ================== Accidental Release Measures ================== Spill Release Procedures:NONE REQUIRED ======================Handling and Storage ====================== Handling and Storage Precautions:NONE REQUIRED Other Precautions:NONE REQUIRED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:NONE REQUIRED Other Protective Equipment:NONE REQUIRED Work Hygienic Practices:NONE REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:THICK LIQUID W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:873 2513 KODAK RP X-OMAT LO FIXER AND REPLENISHER, PART A Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 45-50% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 35-40% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM THIOSULFATE CAS:7772-98-7 RTECS #:XN6476000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM BISULFITE (CERCLA) CAS:10192-30-0 RTECS #:WT3595000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE A L OW INGESTION HAZARD. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES-ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF S YMPTOMS OCCUR. SKIN-WASH WITH SOAP & WATER. GET MEDCIAL ATTENTION IF SYMPTOMS OCCUR. INGESTED-DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEY1: N1. THIS IS PART "A" OF A TWO PART KIT. KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MMHG Vapor Density:0.6 Spec Gravity:1.35 pH:4.8 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, LIGHT GREEN-YELLOW, VINEGAR ODOR. Percent Volatiles by Volume:35-40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, BASES, STRONG OXIDIZING AGENTS, SODIUM HYPOCHLORITE. CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL. Stability Condition to Avoid:STABLE. Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CHLORAMINE, NITROGEN OXIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RX 3R96859 BINDER TAPE CAGE:26921 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:DIMER FATTY ACID, ETHYLENEDIAMINE, PIPERAZINE AZELAIC ACID POLYMER CAS:68139-70-8 Ingred Name:C36 FATTY ACID DIMER, AZELAIC ACID, ETHYLENEDIAMINE, C36 DIMER DIAMINE POLYMER CAS:69012-93-7 Ingred Name:ETHYLENE-VINYL ACETATE COPOLYMER (ACETIC ACID ETHENYL ESTER, POLYMER W/ETHENE) *95-1* CAS:24937-78-8 Ingred Name:ROSIN ACID *95-1* CAS:8050-09-7 Ingred Name:PARAFFIN WAX FUME, PARAFFIN CAS:8002-74-2 RTECS #:RV0350000 ACGIH TLV:2 MG/CUM Ingred Name:ACRYLONITRILE (SUSPECTED HUMAN CARCINOGEN BY ACGIH & IARC, CONFIRMED ANIMAL CARCINOGEN BY IARC GROUP 2A) *95-1* CAS:107-13-1 RTECS #:AT5250000 OSHA PEL:2 PPM ACGIH TLV:4.3 MG/CUM (A2) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:CELLULOSE CAS:9004-34-6 RTECS #:FJ5691460 OSHA PEL:5 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:ALUMINUM (POWDER) *95-1* CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 5-10% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: MILD IRRITATION. SKIN: MILD IRRITATION. MOLTEN ADHESIVE MAY CAUSE SEVERE BURNS. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION & BURNS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. IMMEDIATELY COOL W/COLD WATER IF CONTACT W/MOLTEN ADHESIVE. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:FOR LARGE QUANTITIES INVOLVED IN A FIRE, USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONSTITUENTS OF THIS MATERIAL ARE COMBUSTIBLE. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED. Other Protective Equipment:NONE REQUIRED WHEN USED AS INTENDED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE Appearance and Odor:ADHESIVE BINDER W/MINIMAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:OPEN FLAME & HIGH ELECTRIC ARC. Hazardous Decomposition Products:CO, CO2 & OTHER TOXIC PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:TITAN AC/DC, SEE "SUPP DATA" CAGE:20038 CAGE:20038 CAGE:28835 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: >60% OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA III) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: >2% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG SB/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA III) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <0.2% OSHA PEL:0.5 MG/M3 (AS) ACGIH TLV:0.01,A1 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <0.2% Other REC Limits:NONE ESTABLISHED Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-30% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYPROPYLENE CAS:9003-07-4 RTECS #:UD1842000 Fraction by Wt: 5% Other REC Limits:NONE ESTABLISHED OSHA PEL:NONE ESTABLISHED ACGIH TLV:NONE ESTABLISHED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE. Effects of Overexposure:CONTACT MAY CAUSE PERMANENT DAMAGE TO EYES,SEVERE BURNS AND ULCERATION OF SKIN. INHALATION CAUSES UPPER RESPIRATORY IRRITATION AND POSSIBLE PULMONARY EDEMA. INGESTION CAUSES SEVERE INJURIES. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS WILL BE AGGRAVATED BY BREATHING ACID MISTS. ======================= First Aid Measures ======================= First Aid:EYES/SKIN:FLUSH WITH PLENTY OF WATER.SEE DOCTOR IMMEDIATELY.REMOVE CONTAMINATED CLOTHING AND SHOES. INHALATION:REMOVE TO FRESH AIR.GIVE OXYGEN/CPR IF NEEDED.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE CARBON DIOXIDE, FOAM, HALOGEN, DRY CHEMICAL. Fire Fighting Procedures:IF ON CHARGE, SHUT OFF POWER. Unusual Fire/Explosion Hazard:NONE STATED ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT.DILUTE CAUTIOUSLY WITH WATER.COVER WITH SODA ASH OR QUICKLIME.SCOOP UP AND PLACE IN APPROPIATE DISPOSAL CONTAINER. Neutralizing Agent:SODA ASH (SODIUM CARBONATE) OR QUICKLIME (CALCIUM OXIDE). ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES AND COMBUSTIBLE MATERIALS.AVOID CONTACT WITH ORGANIC MATERIALS. Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE.AVOID SHORTING BATTERIES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR SULFURIC ACID MIST, USE HALF MASK NEGATIVE PRESSURE WITH DUST AND MIST FILTER. Ventilation:USE MECHANICAL VENTILATION WITH 3 TO 4 AIR CHANGES PER HOUR. Other Protective Equipment:RUBBER APRON AND BOOTS.EYES WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health THIS MSDS IS FOR ACID IN BATTERY.ADDITIONAL HAZARDS ASSOCIATED WITH THE LEAD CONTAINED IN THE BATTERY PLATES MAY BE PRESENT AT TIME OF DISPOSAL. ================== Physical/Chemical Properties ================== HCC:C1 pH:<7 Appearance and Odor:BATTERY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE STATED Stability Condition to Avoid:PROLONGED OVERCHARGE. Hazardous Decomposition Products:MAY GENERATE ARSINE,STIBINE AND/OR SULFURIC ACID MIST ON OVERCHARGE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RETURN SPENT BATTERY TO SECONDARY LEAD SMELTER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPRAY N GO VOC 119 TURQUOISE (56-5220) CAGE:90300 CAGE:90300 CAGE:1B236 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:800 PPM ACGIH TLV:800 PPM; 9596 Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 3-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:AROMATIC HYDROCARBONS OR NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 1-10% Other REC Limits:NONE RECOMMENDED Ingred Name:MINERAL SPIRITS OR STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 2-7% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9596 Ingred Name:PETROLEUM DISTILLATES OR NAPHTHA, HEAVY ALKYLATE CAS:64741-65-7 Fraction by Wt: 2-6% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL PROPYL KETONE (2-PENTANONE) CAS:107-87-9 RTECS #:SA7875000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/250STEL;9596 Ingred Name:TRIMETHYL BENZENE CAS:25551-13-7 RTECS #:DC3220000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9596 Ingred Name:VOLATILE ORGANIC CONTENT: 490-540 G/L. RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED Ingred Name:BENZENE (SARA 313) (CERCLA) (NOT FOUND IN INGREDIENT LIST, HOWEVER, FOUND IN CAL PROP 65 STATEMENT, % ASSUMED) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9596 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:MAY CAUSE EYE, SKIN & UPPER RESPIRATORY TRACT IRRITATION. HARMFUL IF INHALED. HARMFUL OR FATAL IF SWALLOWED. IF INGESTED, MAY CAUSE GI TRACT IRRITATION, DEPRESSED RESPIRATION. INHALATION MAY AFFECT BR AIN & NERVOUS SYSTEM. CHRONIC: PROLONGED/REPEATED EXPOSURE MAY CAUSE BRAIN, NERVOUS SYSTEM, LIVER, KIDNEY DAMAGE. Explanation of Carcinogenicity:CONTAINS BENZENE [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN, ALSO CAL PROP 65. Effects of Overexposure:EYES-IRRITATION. SKIN-IRRITATION. INHALED-DIZZINESS, HEADACHE OR NAUSEA. INGESTED-VOMITING, DIARRHEA, DEPRESSED RESPIRATION. Medical Cond Aggravated by Exposure:IF DRY SANDED, ASTHMA AND ASTHMA-LIKE CONDITIONS MAY WORSEN FROM PROLONGED & REPEATED EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES. CONTACT A PHYSICIAN IMMEDIATELY. SKIN-WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. CONTACT A PHYSICIAN IMMEDIATELY. INGESTED-DO NOT INDUCE VOMITING! CONTACT A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:EXTREMELY FLAMM. Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ELIMINATE ALL SOURCES OF IGNITION. DO NOT PUT IN CONTACT WITH OXIDIZING OR CAUSTIC MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL AREA. USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL & PLACE INTO CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM STRONG OXIDIZING AGENTS AND CAUSTICS. KEEP OUT OF REACH OF CHILDREN. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:KEEP CONTAINERS FROM EXCESSIVE HEAT AND FREEZING. DO NOT STORE AT TEMPERATURES ABOVE 120F. INTENTIONAL MISUSE BY DELIBERATLY CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL. DO NOT TAKE INTE RNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:BARRIES CREAMS MAY BE USED. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health MSDS PRESNETED BY CAGE 1B236 FOR SOLICITATION/CONTRACT NUMBER: UNKNOWN (RECEIVED FROM DESPO-KA, TANDY 20 AUG 97). THE PURCAHSE INCLUDED A NUMBER OF COLORS USING THE SAME MSDS; DLA-HMIS STAFF ELECTED T O MAKE A SEPARATE RECORD FOR EACH COLORAS A DIFFERENT PNI. PNI A-G FOR THE 7 COLORS PURCHASED. ================== Physical/Chemical Properties ================== HCC:V3 Vapor Density:>1 Spec Gravity:0.77 Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORED LIQUID WITH GASOLINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS AND CAUSTICS. Stability Condition to Avoid:MATERIAL IS STABLE AT ROOM TEMPERATURE. EXCESSIVE HEAT AND FREEZING. Hazardous Decomposition Products:NORMAL COMBUSTION PRODUCTS (IE, COX, NOX, ETC.). Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE ALL MATERIAL BEFORE DISPOSAL. IF UNABLE TO USE ENTIRE CONTENTS OF CAN, RELIEVE PRESSURE IN CONTAINER UNTIL IT EQUALS EXTERNAL PRESSURE. DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DENTAL & ORTHOPEDIC HYDROCAL LP 105 CAGE:61357 CAGE:61357 ============= Composition/Information on Ingredients ============= Ingred Name:PORTLAND CEMENT, CONTAINS: TRICALCIUM SILICATE, DICALCIUM SILICATE, TRICALCIUM ALUMINATE, TETRACALCIUM ALUMINOFERRATE CAS:65997-15-1 RTECS #:VV8770000 Fraction by Wt: 0-8% Other REC Limits:50 MPPCF (MSHA) OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:NAPTHALENESULFONIC ACID, FORMALDEHYDE POLYMER, AMMONIUM SALT CAS:9069-80-1 Fraction by Wt: 0-4% Ingred Name:POLYVINYL ALCOHOL CAS:9002-89-5 RTECS #:TR8100000 Fraction by Wt: 0-4% Ingred Name:STARCH CAS:9005-25-8 RTECS #:GM5090000 Fraction by Wt: 0-2% Other REC Limits:NUISANCE PARTICULATE OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/METAL OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT/IRON CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0-2% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:POTASSIUM SULFATE CAS:7778-80-5 RTECS #:TT5900000 Fraction by Wt: 0-1% Ingred Name:HYDROLYZED PROTEIN Ingred Name:ALUMINUM (POWDER) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 0-1% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:POTASSIUM SODIUM TARTRATE *92-2* CAS:304-59-6 Fraction by Wt: 0-0.8% Ingred Name:NAPTHALENESULFONIC ACID, POLYMER W/FORMALDEHYDE, POTASSIUM SALT CAS:9069-79-8 Fraction by Wt: 0-0.6% Ingred Name:PETROLEUM DISTILLATE - STREIGHT RUN MIDDLE CAS:64741-89-5 RTECS #:PY8041500 Fraction by Wt: 0-0.6% OSHA PEL:5 MG/CUM (MIST) ACGIH TLV:5 MG/CUM (MIST) Ingred Name:MELAMINE, FORMALDEHYDE POLYMER, METHYLATED CAS:68002-20-0 Fraction by Wt: 0-0.5% Ingred Name:CITRIC ACID CAS:77-92-9 RTECS #:GE7350000 Fraction by Wt: 0-0.5% Ingred Name:AMMONIUM CHLORIDE CAS:12125-02-9 RTECS #:BP4550000 Fraction by Wt: 0-0.4% OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DOUBLE HYDRATED DOLOMITIC LIME CAS:39445-23-3 Fraction by Wt: 0-0.4% OSHA PEL:5 MG/CUM (TRACE) ACGIH TLV:5 MG/CUM (TRACE) Ingred Name:ALUMINUM SULFATE CAS:10043-01-3 RTECS #:BD1700000 Fraction by Wt: 0-0.3% OSHA PEL:2 MG/CUM (TRACE) ACGIH TLV:2 MG/CUM (TRACE) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUCCINIC ANHYDRIDE; SUCCINYL OXIDE; BUTANEDIOIC ANHYDRIDE CAS:108-30-5 RTECS #:WN0875000 Fraction by Wt: 0-1% Ingred Name:TRIBUTYL PHOSPHATE CAS:126-73-8 RTECS #:TC7700000 Fraction by Wt: 0-0.1% Other REC Limits:0.2 PPM OSHA PEL:5 MG/M3 ACGIH TLV:0.2 PPM; 9293 Ingred Name:HYDROXYPROPYL METHYCELLULOSE CAS:9004-65-3 RTECS #:NF9125000 Fraction by Wt: 0%-TRACE Ingred Name:PLASTER OF PARIS; GYPSUM HEMIHYDRATE CAS:26499-65-0 RTECS #:TP0700000 Fraction by Wt: 90-100% OSHA PEL:10 MG/CUM ACGIH TLV:15/5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: BURNS & DRYNESS. INHALATION: COUGHING, SNEEZING, & NASAL IRRITATION. Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:UPPER RESPIRATORY & LUNG DISEASE SUCH AS BRONCHITIS, EMPHYSEMA & ASTHMA ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: PLASTER HARDENS WHEN WETTED & IF INGESTED, MAY RESULT IN OBTRUCTION. OBTAIN MEDICAL ATTENTION IN ALL CA SES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NOT COMBUSTIBLE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM MATERIAL FROM SPILLAGE INTO WASTE CONTAINER FOR DISPOSAL. AVOID DUSTING CONDITIONS. IF WASHED DOWN, MAY PLUG DRAINS. IF ALREADY MIXED W/WATER, SCRAPE UP & WASH DOWN RESIDUE. ======================Handling and Storage ====================== Handling and Storage Precautions:BE SURE PROPER VENTILATION & ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN DUSTY CONDITION EXISTS, WEAR APPROVED DUST MASK TO GUARD AGAINST NUISANCE PARTICLES. Ventilation:GENERAL & LOCAL EXHAUST TO KEEP BELOW TLV REQUIREMENTS Supplemental Safety and Health WHEN MIXED W/WATER, THIS MATERIAL HARDENS & THEN SLOWLY BECOMES HOT. DON'T ATTEMPT TO MAKE A CAST ENCLOSING ANY PART OF THE BODY. FAILURE TO FOLLOW THESE INSTRUCTIONS MAY CAUSE SEVERE BURNS THAT MAY R EQUIRE SURGICAL REMOVAL OF AFFECTED TISSUE. ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:1450C Spec Gravity:2.7-3 Solubility in Water:0.2% Appearance and Odor:WHITE POWDER W/LOW ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Hazardous Decomposition Products:ABOVE 1450C GENERATES CALCIUM OXIDE & SULFUR DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS MATERIAL CAN BE DISPOSED OF AS INERT SOLID IN A LANDFILL OR BY OTHER PROCEDURES IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VERSI-FOAM SYSTEM I A-COMPONENT Kit Part:Y CAGE:RHHFO CAGE:RHHFO ============= Composition/Information on Ingredients ============= Ingred Name:POLYMETHYLENEPOLYPHENYL ISOCYANATE. CAS:9016-87-9 RTECS #:TR0350000 Fraction by Wt: <50% Ingred Name:HALOGENATED HYDROCARBON Fraction by Wt: <18% OSHA PEL:1000 PPM (MFR) ACGIH TLV:1000 PPM (MFR) Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'DIPHENYLMETHANE DIISOCYANATE(MDI)) CAS:101-68-8 RTECS #:NQ9350000 Fraction by Wt: <50% OSHA PEL:0.02 PPM, C ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION CAN INDUCE ASTHMA LIKE RESPIRATORY SENSITIZATION REACTIONS. VAPOR CAN CAUSE LIGHT-HEADEDNESS, SHORTNESS OF BREATH OR CARDIAC IRREGULARITIES. INGESTION WILL IRRITATE MUCOUS MEMBRANES. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:TIGHTNESS IN CHEST, THROAT IRRITATION, DIZZINESS, DIFFICULTY IN BREATHING. Medical Cond Aggravated by Exposure:PERSONS WITH HISTORY OF ASTHMA, BRONCHITIS OR CHRONIC RESPIRATORY DISEASE MAY BE AT INCREASED RISK OF ALLERGIC SENSITIZATIONS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR AND CONSULT PHYS. EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN AND CONSULT PHYS. INGEST: DO NOT INDUCE VOMIT. SEEK MED HELP. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:425F,218C Extinguishing Media:CO*2, DRY CHEMICAL, HALON 1211, CHEMICAL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT TO PROTECT AGAINST TOXIC DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:CONTAINERS DEVELOP PRESSURE WHEN HEATED. WATER REACTS WITH ISOCYANATE TO FORM CO*2 GAS WHICH CAN INCREASED PRESSURE AND RUPTURING OF SEALED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE VENTILATION, ISOLATE AREA. ABSORB WITH SAWDUST, FULLER'S EARTH, ETC. IN OPEN CONTAINER, SLOWLY DECONTAMINATE SPILLAGE WITH SOLUTION OF 80% WATER, 20% NON-IONIC SURFACTANT. REMOVE CONTAINERS TO SAFE PLACE, ALLOW TO VENT AT LEAST 24 HOURS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CLOSED UNTIL USE. DO NOT STORE ABOVE 120F OR BELOW 40F. KEEP OUT OF REACH OF CHILDREN. Other Precautions:READ AND FOLLOW ALL INSTRUCTIONS. COMPLY WITH LOCAL BUILDING AND FIRE CODES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:VENTILATION OR NIOSH/MSHA APPROVED SELF-CONTAINED RESPIRATOR TO MAINTAIN 0.2 PPM PEL OR .005 TWA. Ventilation:LOCAL EXHAUST:MAINTAIN ADEQ FRESH AIR. Other Protective Equipment:AS NEEDED TO PREVENT SKIN CONTACT OR BREATHING OF MIST AND VAPORS. Work Hygienic Practices:PROTECT PERSONNEL DOWN WIND FROM SPRAY. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:<2700 Vapor Density:>1 Spec Gravity:1.2 Solubility in Water:SOLUBLE Appearance and Odor:BROWN LIQUID. FOAMS WHEN RELEASED FROM CONTAINER. AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID ALCOHOLS, WATER, STRONG BASES OR AMINES, METAL COMPOUNDS. Stability Condition to Avoid:DO NOT STORE ABOVE 120F. Hazardous Decomposition Products:CO, CO*2, NITROGEN OXIDES, TRACES OF HCN, HC1, HL. Conditions to Avoid Polymerization:HIGH TEMPERATURES, ALKALIS, AMINES, METAL COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CAREFULLY VENT CONTAINERS OF ALL REMAINING CONTENTS AND PRESSURE. DISPOSE IN ACCORDANCE WITH STATE, LOCAL OR FEDERAL REGULATIONS. FOAM IS NON-HAZ WASTE. DECONTAMINATED RAW MATERIAL SHOULD BE TAKEN TO APPROVED DUMP SITE OR INCINERATOR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLY-U-FOAM, 638 CAGE:18731 CAGE:18731 ============= Composition/Information on Ingredients ============= Ingred Name:POLYOL BLEND Fraction by Wt: <40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METHANE, TRICHLOROFLUORO-; (TRICHLOROMONOFLUOROMETHANE) (SARA III) CAS:75-69-4 RTECS #:PB6125000 Fraction by Wt: <20% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:POLYMERIC ISOCYANATE Fraction by Wt: <30% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (DIPHENYL METHANE DIISOCYANATE) CAS:101-68-8 RTECS #:NZ9350000 Fraction by Wt: <25% OSHA PEL:N/K ACGIH TLV:0.02 PPM (MFR) EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOLATILE ORGANIC COMPONENT: 0. RTECS #:9999999VO ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SKIN:IRRITATION. INHAL:MUCOUS MEMBRANE IRRITATION & TIGHTNESS OF CHEST. IRRITATION OF RESPIRATORY TRACT, COUGHING, HEADACHE, SHORTNESS OF BREATH. EXPOSURE CAN LEAD TO ALLERGENIC SENSITIVITY. CHR ONIC:CAN CAUSE ALLERGIC SENSITIVITY. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:WASH W/SOAP & WATER. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INHAL:REMOVE PERSON TO FRESH AIR. ADMINISTER OXYGEN OR GIVE ARTIFICIAL RESPIRATION IF NECESSARY. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:160F,71C Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:HIGH FIRE TEMPERATURE CAN BREAK DOWN TRICHLOROFLUOROMETHANE TO TOXIC GAS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID BREATHING FUMES. ABSORB ON SAND, VERMICULITE OR FLOOR SWEEPING COMPOUNDS. WASH AREA W/SOAP & WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN ORIGINAL TIGHTLY CLOSED CONTAINERS. STORE AWAY FROM HEAT & DIRECT SUNSHINE. STORE AWAY FROM SOURCES OF MOISTURE OR WATER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR CANISTER RESPIRATOR OR AIR SUPPLIED RESPIRATOR. Ventilation:MECHANICAL VENTILATION TO KEEP VAPORS BELOW TLV LIMIT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:77.0F,25.0C Vapor Density:5.67 Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:SLIGHT Appearance and Odor:AMBER LIQUID; SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOL, STRONG BASES OR METAL COMPOUNDS. Stability Condition to Avoid:HIGH TEMPERATURE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:TRACT WASTE W/WATER CONTAINING 1% AMMONIA BEFORE DISPOSING. DISPOSAL SHOULD BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:B36 W 306 BASE B WEATHER PERFECT HOUSE & TRIM FLAT CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL CARC, SUSPECTED HUMAN CARC IARC-GROUP 2A; SUSPECTED CARC NTP) *95-4* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 8-25% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:0.1 MG/CUM RESP DUST ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:SILICA CRYSTALLINE, SILICA (CRISTOBALITE) (SUSPECTED HUMAN CARCINOGEN BY IARC, SUSP CARC BY NTP; IARC GROUP 2A) *95-4* CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 1-1% Other REC Limits:0.05 MG/CUM NIOSH ACGIH TLV:0.05 MG/CUM Ingred Name:CLAY (KAOLIN), ALUMINUM SILICATE CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 0-6% ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3) *95-4* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-19% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:ZINC OXIDE *95-4* CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 0-1% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM FUME Ingred Name:ZINC COMPOUND Fraction by Wt: 1.4% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 48.2-52% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & UPPER RESPIRATORY SYSTEM. CRYSTALLINE SILICA-LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST MAY CAUSE LUNG DAMAGE (SILICOSIS). PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSEADVERSE EFFECTS TO THE LIVER, URINARY SYSTEMS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, DIZZINESS, REDNESS, ITCHING, BURNING SENSATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE INTERNALLY. Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQUATE VENTILATION. AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED BELOW TLV BY VENTILATION, USE A NIOSH/MSHA APPROVED PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR. WHEN SANDING/ABRADING FILM, USE A NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE IF THE EXPOSURE IS KEPT < APPLICABLE EXPOSURE LIMITS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USING. Supplemental Safety and Health PH: 8.5-9.8. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212-448F Vapor Density:>1 Spec Gravity:1.1-1.3 pH:(SUPP) VOC Grams/Liter:1.02 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:40-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT & OTHER IGNITION SOURCES Hazardous Decomposition Products:BY FIRE: CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINER. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WATER BASED CATALYZED EPOXY, B70W201 PURE WHITE CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:2-(2-BUTOXYETHOXY)-ETHANOL. VP: 0.1 CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA). VP: 0.1 CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 3-5% OSHA PEL:C 50 PPM (MFR) ACGIH TLV:C 50 PPM,VAPOR; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOLATILE ORGANIC COMPOUNDS (VOC-LBS/GAL): 0.64 RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS LESS WATER (LB/GAL): 1.39. (% WATER: 45.5) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VENT: REFER TO OSHA STANDARDS 1910.94. 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:OTHER PREC: EYES/ON SKIN. THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: IN SECTION 2) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: SPECIFIC DUSTS ARE LISTED IN SECTION 2, APPLICALBE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: (TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). CALIFORNIA PROPOSITION 65: (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: WARNING: THESE PRODUCTS CONTAIN A CHEMICAL(S) KNOWN TO THE STATE FO CALIFORNIA TO CAUSE CANCER. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN & UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. SIGNS & SYMPS OF OVEREXP: REDNESS & ITCHING OR BURN ING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENTS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: INGREDIENTS IN SECTION 2 MAY CAUSE ADVERSE EFTS TO LIVER, URINARY SYSTEMS. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DETECTS IN RATS AND MICE AT HIG H DOSES WHEN GIVEN IN DRINKING WATER ORBY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE PERSONS. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Lower Limits:0.9% Upper Limits:15.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD CNTNRS TO(SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO THE BUILD-UP OF PRESSURE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT TO USE. TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. Other Precautions:KEEP OUT OF REACH OF CHILDREN. THESE PRODUCTS MUST BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS. USE ONLY W/ADEQ VENT. AVOID BRTHG VA P/SPRAY MIST. DO NOT GET IN (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING/WELDING DRIED FILM, (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOS LIMS. (ING 5) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . BARRIER CREAM. Work Hygienic Practices:WASH HANDS AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOSION WHEN EXPOS TO EXTREME HEAT. WASTE DISP METH: INCIN AN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSED OF I/A/W/FED, STATE, & LOCAL REG S REGARDING POLLUTION. RESP PROT:WEAR PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST NON-VOLATILE MATLS IN SECTION 2. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.18 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:57-65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM B70W100 PRIMER MAY BE HAZARDOUS AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR BARIUM EXTRACTABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM OTHER LISTED PRODS IS NOT HAZ AS DEFINED UNDER RCRA 40 CPR 261. (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:M-LINE 261A-20R SOLDER Resp. Party Other MSDS Num.:MSDS # MGM039E Preparer's Name:R. F. FRIDLEY CAGE:016Y7 CAGE:016Y7 ============= Composition/Information on Ingredients ============= Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 = Wt:63. OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:LEAD CAS:7439-92-1 RTECS #:OF7525000 = Wt:36.65 OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY CAS:7440-36-0 RTECS #:CC4025000 = Wt:.35 OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ROSIN CAS:8050-09-7 RTECS #:VL0480000 < Wt:3. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE PROVIDED BY MFR Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION AS ROUTE OF ENTRY: ACCIDENTAL. ACUTE AND CHRONIC: REPEATED INHALATION OR INGESTION OF LEAD CAN RESULT IN SYSTEMIC POISONING. Explanation of Carcinogenicity:NOT LISTED. Effects of Overexposure:INHALATION: OVEREXPOSURE TO LEAD MAY LEAD TO CENTRAL NERVOUS SYSTEM DISORDERS CHARACTERIZED BY DROWSINESS, SEIZURES, COMA & DEATH. EXPOSURE OF THIS MAGNITUDE IS UNLIKELY. FLUX FUMES DURING SOLDERING M AY CAUSE IRRITATION & DAMAGE OF MUCOUS MEMBRANES & RESPIRATORY SYSTEM. PROLONGED BREATHING OF FUMES DURING SOLDERING MAY CAUSE RESPIRATORY SYSTEM IRRITATION, HEADACHE & IRRITATION OF MUCOUS MEMBRANES. SMOKE DURING SOLDERING WILL CONTAIN ROSIN WHICH IS ALLERGEN & CAN CAUSE RESPIRATORY SYSTEM IRRITATION & DAMAGE. EYE: SMOKE FROM SOLDERING MAY CAUSE IRRITATION. SKIN: FLUX/FUMES MAY CAUSE LOCAL IRRITA TION. INGESTION: SIMILAR TO INHALATION. Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS OR DISEASES OF THE BLOOD AND BLOOD FORMING ORGANS, KIDNEYS, NERVES AND POSSIBLY REPRODUCTIVE SYSTEM. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE VICTIM FROM EXPOSURE TO FUMES. GET MEDICAL ATTENTION IF NEEDED. EYE: FOR BURNS, FLUSH IMMEDIATELY WITH COOL WATER. FOR FUME IRRITATION, USE EYE DROPS AND REMOVE FROM EXPOSURE. SKIN: FOR BURNS, FLUSH IMMEDIATELY WITH COOL WATER. IF RASH DEVELOPS FROM FLUX FUMES, REMOVE PERSON FROM EXPOSURE AND WASH SKIN WITH SOAP AND WATER. INGESTION: IF THOUGHT TO BE OVEREXPOSED, THE PERSON SHOU LD HAVE A BLOOD-LEAD ANALYSIS DONE. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS IN CASE OF TOXIC LEAD FUMES. Unusual Fire/Explosion Hazard:FLUX IN CORED SOLDER MAY IGNITE WHEN THE SOLDER MELTS IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:MELTED SOLDER WILL SOLIDIFY ON COOLING AND CAN BE SCRAPED UP. USE CAUTION TO AVOID BREATHING FUMES IF A GAS TORCH IS USED TO CUT UP LARGE PIECES. Neutralizing Agent:NONE PROVIDED BY MFR ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM SOURCES OF SULFUR. WASH HANDS AFTER HANDLING SOLDER CONTAINING LEAD. AVOID BREATHING FUMES DURING SOLDERING. DO NOT PLACE FLUX CORED SOLDER INTO A HOT SOLDER POT SINCE FLUX MAY IGNITE. USE OF STRONG ACID FLUXES MAY RESULT IN LIBERATION OF TOXIC LEAD CHLORIDE FUMES Other Precautions:NONE KNOWN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USUALLY NOT REQUIRED. WHEN VENTILATION IS NOT SUFFICIENT TO REMOVE FUMES FROM THE BREATHING ZONE. A CARTRIDGE TYPE RESPIRATOR SHOULD BE WORN Ventilation:LOCAL EXHAUST: KEEP BELOW TLV. MECHANICAL: KEEP BELOW TLV Other Protective Equipment:NONE Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING SOLDER CONTAINING LEAD AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Decomp Temp:Decomp Text:NONE PROVIDED BY MFR Spec Gravity:> 1 (H2O=1) pH:NONE PROVIDED Viscosity:NONE PROVIDED BY MFR Solubility in Water:INSOLUBLE Appearance and Odor:SILVER-GRAY METAL IN WIRE FORM Percent Volatiles by Volume:NONE PROVIDE Corrosion Rate:NONE PROVIDED BY MFR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACID, STRONG OXIDIZERS Stability Condition to Avoid:NONE Hazardous Decomposition Products:NO LEAD OR ATIMONY ARE DETECTED IN FUMES FROM SOLDERING BELOW 1000 DEG F (537 DEG C) Conditions to Avoid Polymerization:WILL NOT OCCUR =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED ===================== Ecological Information ===================== Ecological:NOT PROVIDED ==================== Disposal Considerations ==================== Waste Disposal Methods:SOLDER CAN BE RECLAIMED. DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED ===================== Regulatory Information ===================== SARA Title III Information:LEAD (CAS 7439-92-1) AND ANTIMONY (7440-36-0) ARE LISTED AS SARA 313 CHEMICALS. HOWEVER, FOR THIS PRODUCT THE ANTIMONY CONTENT IS <1%. Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE TOXIC SUBSATNCE CONTROL ACT INVENTORY. State Regulatory Information:NOT PROVIDED
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR-1440 CLASS B,PART B - POLYSULFIDE RUBBER Kit Part:Y Preparer's Name:AS CAGE:DO563 CAGE:83574 CAGE:DO563 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL FORMALDEHYDE RESIN CAS:9003-35-4 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT MAY BE IRRITATING AND MAY CAUSE LIVER AND/OR KIDNEY DAMAGE. IT ALSO MAY SENSITIZE ALLERGIC REACTIONS. Explanation of Carcinogenicity:MFR CLAIMS NO COMPOUND IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:IRRITATION,BURNING. SKIN:IRRITATION. MAY CAUSE SKIN RASH IN SENSITIZED INDIVIDUALS.INHALED:RESPIRATORY IRRITATION. INGESTED:NAUSEA,VOMITING,G/I PAIN & DISTRESS, AND POSSIBLE LIVER AND/OR KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:SENSITIZED PEOPLE ARE AT INCREASED RISK WHEN USING THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP & WATER. LAUNDER CLOTHING BEFORE REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING. GET MEDICAL CARE. INGESTED:DO NOT INDUCE VOMITING. GIVE TWO GLASSES OF WATER AND GET IMMEDIATE MEDICAL ATTENTION. (GIVE NOTHING BY MOUTH IF UNCONSCIOUS) - IF ANY IRRITATION IS SEVERE OR PERSISTS, GET MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WIPE/SOAK UP WITH CLOTH OR PAPER TOWEL OR INERT ABSORBENT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH SOLVENT. Neutralizing Agent:USE 1,1,1-TRICHLOROETHANE AS SOLVENT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT EXPECTED TO BE NECESSARY. USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION WHEN EXPOSED ABOVE PEL/TLV. Ventilation:GENERAL ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA IS NOT VENTED. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health THIS IS PART B OF A TWO PART KIT. SEE P/N IND A, THIS NSN OR 8030-00-K00-0478 FOR MSDS OF PART A. MFR'S MSDS I.D. NO MS3475B01 ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.60 Solubility in Water:NEGLIGIBLE Appearance and Odor:NOT DESCRIBED ON MSDS BY MFR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SULFUR DIOXIDE, HYDROGEN SULFIDE, POSSIBLE FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR STATES THAT PRODUCT MAY BE DISPOSED AS ORDINARY REFUSE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAY BRITE #8 CAGE:FO309 CAGE:FO309 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 95% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:SILVER CAS:7440-22-4 RTECS #:VW3500000 OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC CHLORIDE CAS:7646-85-7 RTECS #:ZH1400000 OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ROSIN CORE SOLDER PYROLYSIS PRODUCTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEVERE OVEREXPOSURE CAN CAUSE PULMONARY EDEMA. PROLONGED INHALATION EXPOSURE MAY CAUSE LUNG/KIDNEY DAMAGE. FUMES FROM ACID & ROSIN CORE CAN IRRITATE THE NOSE & THROAT. ZINC CHLORIDE IN ACID CORE SOLDE R MAY IRRITATE THE SKIN. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: HEADACHE, NAUSEA, DIZZINESS, BODY ACHES, ANEMIA, CHEST PAINS, COUGH, FEVER, SHORTNESS OF BREATH. Medical Cond Aggravated by Exposure:IMPAIRED PULMONARY FUNCTION ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED PERFORM CPR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Unusual Fire/Explosion Hazard:NONFLAMMABLE. OPEN FLAMES & SPARKS CAN IGNITE COMBUSTIBLES. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH HANDS THOROUGHLY BEFORE SMOKING OR EATING & AFTER USING LEAD BEARING SOLDERS. TRAIN EMPLOYEE TO KEEP HEAD OUT OF THE FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN SOLDERING IN CONFINED AREAS. Ventilation:LOCAL EXHAUST AT THE FLAME TO KEEP THE FUMES & GASES BELOW TLVS. Other Protective Equipment:WEAR PROTECTIVE CLOTHING, APRONS, HATS, SHOULDER PROTECTION, FACE SHIELD IF FILTER LENS OF APPROPRIATE SHADES, SCREENS. Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE SMOKING OR EATING & AFTER USING LEAD BEARING SOLDERS. Supplemental Safety and Health WEAR DARK SUBSTANTIAL CLOTHING. SOLDER FUMES CAN'T BE CLASSIFIED SIMPLY. THE COMPOSITION & QUALITY ARE DEPENDANT UPON METAL BEING SOLDERED, THE PROCESS, PROCEDURES & FILTER METALS USED, COATINGS, NUMB ER OF OPERATORS, VOLUME OF WORK AREA & CONTAMINANTS IN THE ATMOSPHERE. ================== Physical/Chemical Properties ================== Appearance and Odor:WIRE, SOLID GREY TO SILVER IN COLOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ZINC CHLORIDE: CYANIDES, SULFIDES, Hazardous Decomposition Products:SOLDERING FUMES, ZINC CHLORIDE: HYDROGEN CYANIDE GAS, HYDROGEN SULFIDE GAS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOBILGREASE 28 CAGE:0AHK0 CAGE:0AHK0 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: >80.0% Other REC Limits:NONE SPECIFIED Ingred Name:P,P'-DIOCTYLDIPHENYLAMINE CAS:101-67-7 RTECS #:JJ8850000 Fraction by Wt: <2.0% Other REC Limits:NONE SPECIFIED Ingred Name:BENZENEPROPANOIC ACID,3,5-BIS(1,1-DIMETHYLETHYL)-4-HYDROXY-OCTADECYL ESTER CAS:2082-79-3 Fraction by Wt: <2.0% Other REC Limits:NONE SPECIFIED Ingred Name:PENTAERYTHRITOL CAS:115-77-5 RTECS #:RZ2490000 Fraction by Wt: 1.42% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:MONTMORILLONITE CAS:1318-93-0 Fraction by Wt: <10.0% Other REC Limits:NONE SPECIFIED Ingred Name:PHENYL-ALPHA-NAPHTHYLAMINE CAS:90-30-2 RTECS #:QM4500000 Fraction by Wt: <2.0% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM NITRITE (SARA III) CAS:7632-00-0 RTECS #:RA1225000 Fraction by Wt: 1.02% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM PHOSPHATE, TRIBASIC(SARA III) CAS:7601-54-9 RTECS #:TC9490000 Fraction by Wt: 0.61% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID,CALCIUM SALT CAS:62-54-4 Fraction by Wt: <3.0% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT >5G/KG; DERMAL >2G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE:PER MFR,THIS PRODUCT HAS NO PROBLEM.MAY IRRITATE EYES & SKIN ON PROLONGED CONTACT. CHRONIC:NO DATA AVAILABLE Effects of Overexposure:PER MFR NO ADVERSE EFFECTS;HYPERSENSITIVE INDIVIDUALS MAY DEVELOP SKIN ALLERGIES;AVOID SKIN/EYES CON Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE WORSEN. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:450F,232C Lower Limits:0.6 Upper Limits:7.0 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE NOTED;COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;SCRAPE UP AND REMOVE FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY AREA.KEEP AWAY FROM HEAT,OPEN FLAMES & SPARKS. Other Precautions:AVOID CONTACT WITH EYES & SKIN:DO NOT BREATHE VAPORS/MIST.WASH THOROUGHLY AFTER EACH USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY CONDITIONS/ADEQUATE VENT. Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE VENTILATION Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN:DO NOT BREATHE VAPORS/MIST:WASH THOROUGHLY AFTER EACH USE Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>600F/316C Vapor Pres:<.1 Spec Gravity:0.887 Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK RED GREASE,MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLCTED MATERIAL IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REFRIGERANT 22 (HCFC-22) Preparer's Name:RAY MADARIAGA CAGE:4J994 CAGE:4J994 CAGE:7Y146 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORODIFLUOROMETHANE (SARA 313) (CERCLA) CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ozone Depleting Chemical:2 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 1,000 PPM. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Effects of Overexposure:TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANAESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUSNESS, IRREGULAR PULSE, PALPITATIONS, INADEQUATE CIRCULATION, FROST BILTE, IRRITATION, BLURRED VISION, TEARING Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF NEEDED. EYE:IMMEDIATELY FLUSH WITH PLENTY OF WATER. SKIN:FLUSH WITH LUKEWARM WATER. GET MEDICAL ATTENTION IF FROSTBITE HAS OCCURED. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN /CPR IF NEEDED. ORAL:NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE. NOTE TO PHYSICIAN:CATECHOLAMINE DRUGS SHOULD BE USED WITH SPECIAL CAUTION ONLY IN SITUATIONS OF EMERGENCY LIFE SUPPORT. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:>800F Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CYLINDERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. MOVE CYLINDERS FROM FIRE AREA IF POSSIBLE WITHOUT INCREASED PERSONAL RISK. Unusual Fire/Explosion Hazard:THIS PRODUCT MAY IGNITE WHEN MIXED WITH AIR. CYLINDERS MAY RUPTURE. DECOMPOSITION PRODUCTS ARE TOXIC AND CORROSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF-CONTAINED BREATHING APPARATUS FOR LARGE SPILLS OR RELEASES. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA, AWAY FROM FLAMES & INCOMPATIBLE MATERIALS. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION. NEVER USE IN CONFINED OR CLOSED SPACES WITHOUT PROPER PROTECTIVE E QUIPMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IF A LARGE RELEASE OCCURS. Ventilation:NORMAL VENTILATION IS SUFFICIENT. LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED, MECHANICAL VENTILATION IN LOW PLACES Other Protective Equipment:EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-41F,-41C Melt/Freeze Pt:M.P/F.P Text:-256F,-160C Decomp Temp:Decomp Text:>800F,>427C Vapor Pres:7031 @ 70F Vapor Density:2.98 Spec Gravity:1.17 (LIQUID) Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:SLIGHT Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS - SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, ZINC, MAGNESIUM, STRONG OXIDIZING AGENTS Stability Condition to Avoid:FLAME, GLOWING METAL SURFACES, HIGH TEMPERATURES Hazardous Decomposition Products:MAY FORM HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, CARBON MONOXIDE, CARBON DIOXIDE AND CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM BY DISTILLATION. CONSULT LOCAL, STATE AND FEDERAL AUTHORITIES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT, MIL-C-83286, 17886 P/N 03W096CAT Kit Part:Y Preparer's Name:NORM GAUL CAGE:5M511 CAGE:33461 CAGE:5M511 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC ISOCYANATE (BIURET OF HMDI) (VAPOR PRESSURE 0 MM HG) CAS:4035-89-6 Fraction by Wt: 30% Other REC Limits:NONE RECOMMENDED Ingred Name:HEXAMETHYLENE DIISOCYANATE (HDI) FREE MONOMER <0.5% (MFR TIME). AFTER 3-6 MO STORAGE, MAY RISE TO 1.6% MAX. CAS:822-06-0 RTECS #:MO1740000 Other REC Limits:NONE RECOMMENDED ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 13 MM HG @ 68F) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM;STEL 200 PPM ACGIH TLV:150 PPM;STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENE (SARA III) (VAPOR PRESSURE 21 MM HG @ 100F) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4.35% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) (VAPOR PRESSURE 7.1 MM HG @ 68F) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.89% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 125 PPM ACGIH TLV:100 PPM;STEL 125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL 3-ETHOXYPROPIONATE (VAPOR PRESSURE 0.7 MM HG @ 68F) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 10% Other REC Limits:50 PPM; STEL 100 PPM Ingred Name:METHYL ETHYL KETONE (SARA III) (VAPOR PRESSURE 70 MM HG @ 68F) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 46.56% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM;STEL 300 PPM ACGIH TLV:200 PPM;STEL 300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC: 625 G/L RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:RESP TRACT IRRIT (HEADACHE,DIZZY,STAGGER,CONFUSION,UNCONSCIOUS,COMA). SKIN:ISOCYANATES REACT W/SKIN PROTEIN & MOISTURE.IRRIT (SWELL,RED,RASH).ABSORPTN:IRRIT (DRY,DEFAT,SKIN CRACK). EYES:IRRIT (T EAR,RED,SWELL W/STING). INGEST:IRRIT, CORROSIVE IN GI TRACT.VOMITING MAY CAUSE ASPIRATION,RESULTING IN CHEM PNEUMONITIS. Effects of Overexposure:ACUTE: VAPORS ARE IRRITATING TO EYES, NOSE, & THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING & UNCONSCIOUSNESS. CHRONIC: AS RESULT OF PREVIOUS REPEATED OVEREXPOSURE OR SINGLE LARGE DOSE,CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION (REACT TO LATER EXPOSURE OF ISOCYANATE LEVELS BELOW TLV). Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR.RESTORE BREATHING.ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMEDIATE/DELAYED BY SEVERAL HRS).GET MEDICAL AID. SKIN:REMOVE CONTAMINATED CLOTHING.WASH AFFECTED AREAS W/SOAP & WATER.W ASH CONTAMINATED CLOTHING BEFORE REUSE.EYES:FLUSH W/LUKEWARM WATER (LOW PRESSURE) 15 MIN,LIFT EYELIDS.GET MED AID. INGEST:DON'T INDUCE VOMITING.DON'T GIVE ANYTHING TO UNCONSCIOUS PERSON.GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:23.0F,-5.0C Lower Limits:1.00 Upper Limits:11.00 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG, WATER SPRAY Fire Fighting Procedures:USE FULL PROTECT CLOTH/FIREFIGHT EQUIP W/SCBA. WATER MAY BE USED TO COOL CLSD CNTNRS (PREVENT PRESS BLDUP/AUTOIGNIT/EXPLOS). HDI/IRRIT VAPOR GENERATED BY FIRE. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN & REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDG IN COMPLY W/OSHA 1910.106,IN TIGHT CLOSD CNTNR IN VENTD AREA.AVOID STORING NEAR HIGH TEMP/IGNIT SOURCE.PREVENT PROLONGED VAPOR BREATHING Other Precautions:KEEP CONTAINERS TIGHT & UPRIGHT (PREVENT LEAK). PROLONGED OVEREXPOSURE MAY CAUSE ALLERGIC REACTION. AVOID CONTACT WITH SKIN & EYES. DO NOT INGEST. DO NOT HANDLE TILL MFR'S PRECAUTIONS READ OR UNDERSTO OD. SMOKE IN SMOKING AREAS ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR RECOMMENDED FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/AIR SUPPLIED).OBEY OSHA REGS FOR RESPIRATOR. VENT TO PROVIDE TO KEEP EXPOSURE LEVELS BELOW OSHA LIMITS. VAPOR PARTIC RESPIRAT OR (TC23C) WHERE BELOW 10 TIMES TLV/PEL. Ventilation:EXHAUST VENT TO KEEP AIRBORNE CONCENTRATION OF SOLVENT, HDI & POLYISOCYANATES BELOW TLV. REMOVE IGNITION SOURCES. Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175 TO 338F Vapor Density:> AIR Spec Gravity:0.91717 Viscosity:* Evaporation Rate & Reference:3.36 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:75.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND HDI. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE W/FEDERAL, STATE, & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED W/CARE, DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR. DO NOT INCINERAT E CLOSED CONTAINERS. EPA HZD CODE:D001,F003,F005.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INTERTHANE 990HS, 99072A OSHA RED CAGE:50411 CAGE:50411 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC PETROLEUM DISTILLATES) VP: 10 @ 20C; % WHEN MIXED: 3 CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 3% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL-3-ETHOXYPROPIONATE) VP: 1.5 @ 20C; % WHEN MIXED: 4 CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 4% OSHA PEL:N/K ACGIH TLV:50 PPM (MFR) Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE) VP: 2.14 @ 20C; % WHEN MIXED: 12 CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 13% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:BENZENE (SARA 313) (CERCLA) VP: 75 @ 20C; % WHEN MIXED: < 0.1 CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: 0.1% OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP: 10 @ 20C; % WHEN MIXED: 10 CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 12% OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:OTHER PREC: BRAZE/WELD W/OUT NIOSH APPRVD MECH FILTER RESP/APPROP & ADEQ VENT. ALL ELEC EQUIP & INSTALLATIONS (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: SHOULD BE MADE & GROUNDED I/A/W NATIONAL ELEC CODE. WORKMEN ARE REQUIRED TO USE ONLY NON-FERROUS TOOLS & (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: WEAR NON-SPKG SHOES IN AREAS WHERE EXPLO HAZ EXIST. IF WORKMEN ARE EXPOSED TO SPRAY APPLICATION/ABRASIVE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: BLAST CLEANING, ENGINEERING & ADMIN CTLS MUST BE USED TO MAINTAIN EXPOS LEVEL BELOW OSHA REQUIRED LEVEL/ (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: USE NIOSH APPROVED MECHANICAL FILTER RESPIRATOR FOR PROTECTION. RTECS #:9999999ZZ Ingred Name:RESP PROT: W/UNRECTRICTED VENT, USE NIOSH APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: OVERSPRAY DURING SPRAY APPLICATION. IN RESTRICTED VENT AREAS, USE NIOSH APPRVD MECH FILTER RESPS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: DESIGNED TO REMOVE PARTICULATES, GAS & VAP. IN CONFINED AREAS, USE NIOSH APPRVD AIR-LINE RESPS & HOODS. RTECS #:9999999ZZ Ingred Name:VENT: TO REMOVE DECOMPOSITION PRODUCTS DURING WELDING AND FLAME CUTTING OF SURFACES COATED WITH THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN: OSHA REGULATED: CFR 29 1910.1028. HUMAN: BLOOD. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CAN CAUSE PERM BRAIN & NERV SYS DMG/DEATH. DIRECT EYE/SKIN CONT MAY CAUSE SEV IRRIT. SOME (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: PEOPLE DEVELOP SKIN/RESP SYS ALLERGIES & REACT TO HDI AT EVEN LOW EXPOS LEVELS. RESP ALLERGIC RXNS INCL (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: CHEST TIGHTNESS, WHEEZING, SHORTNESS OF BRTH/ASTHMA ATTACK AT TIME OF EXPOS/SEVERAL HRS LATER. SKIN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: RXNS INCL BLISTERS, RASHES & HIVES, & MAY ALSO BE DELAYED FOR SEVERAL HRS. SENSIT MAY BE TEMPORARY/PERM.(ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: PRLNG/RPTD OVEREXP TO COMPONENTS OF THIS MIX IS ALSO REPORTED TO CAUSE NERV SYS DMG, ANEMIA, LIVER & (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: KIDNEY DMG. WARNING! THESE PRODS CONTAIN A CHEM KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER & (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM (CALIFORNIA PROPOSITION 65). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: INHAL: VAPS ARE IRRIT TO NOSE & THROAT & COULD CAUSE NAUS, DIZZ & VOMIT. SKIN: COULD CAUSE IRRIT. EYES: DEFINITE IRRIT. COULD CAUSE INJURY. CHRONIC: ALLERGIC SKIN/RESP RXN MAY OCCUR IN SOME PEO PLE. RESP SENSITIVITY RESULTS IN ASTHMA-LIKE SYMPS ON SUBSEQUENT EXPOS EVEN BELOW TLV. CONTAINS (EFTS OF OVEREXPOSURE) Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120, 1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE CARCIN.(ING 15) Effects of Overexposure:HLTH HAZ: HEXAMETHYLENE DIISOCYANATE (HDI), A CHEM WHICH IS IRRIT TO EYES, NOSE, THROAT & LUNGS & WHICH IS KNOWN TO CAUSE HEPERSENSITIVITY (ALLERGIC) RXNS IN SOME PEOPLE. INHAL OF VAP/ABSORPTION OF SO LV THRU SKIN CAN CAUSE DIZZ, NAUS, HDCH& SLEEPINESS. DELIBERATELY BRTHG CONCENTRATED SOLV VAP (GLUE SNIFFING) (ING 16) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. KEEP WARM AND QUIET. NOTIFY MD. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. TAKE TO MD FOR MEDICAL TREATMENT. SKIN: WASH AFFECTED ARE AS WITH LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:99.0F, (SUP DAT) Lower Limits:0.7-1.0% Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . IN ABSENCE OF ELECTRICITY, WATER SPRAY (FOG NOZZLE PREFERRED) MAY BE USED TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT, SPKS, ELEC EQUIP & OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. AVOID EXPOS TO (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, & ELECTRICAL, STATIC/FRICTION SPARKS). AVOID BREATHING VAPORS, WEAR NIOSH APPROVED RESPIRATOR, & VENTILATE AREA. REMOVE W/INERT ABSORBENT SUCH AS SAND, KITTY LITTER, ETC, & USE NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SECURE CLOSURES & KEEP CONTRS UPRIGHT TO PVNT LEAKAGE. STORE LGE QTYS ONLY IN BLDGS DESIGNED TO COMPLY W/OSHA 1910.106. DO NOT STORE ABOVE 120F. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT GET IN EYES/ON SKIN. AVOID BRTHG VAPS/SPRAY MIST. DO NOT STORE/USE NEAR HEAT, SPKS/OPEN FLAME. CONTRS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQ IN EXCESS O F FEW INCHES. DO NOT FLAME CUT, (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ISOCYANATE MONOMER CONC > 10 TIMES TLV: USE POS PRESS AIR SUPP RESP (TC19C NIOSH APPRVD). ISOCYANATE MONOMER CONC < 10 TIMES TLV: USE ABOVE RESP/SUPP NIOSH APPRVD VAP/PARTICULATE RESP FOR ISOCYANATE V APS & MISTS. INDOOR/OPEN AREAS (ING 11) Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP TLV < STATED OSHA LIMS & LOWER LEL < STATED LIM & (ING 14) Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . RUBBER APRON, ETC, AS NEEDED TO PROTECT BODY. Work Hygienic Practices:BEFORE SMOKING OR EATING, WASH HANDS THOROUGHLY. Supplemental Safety and Health SPEC GRAV: 1.37 (H*2O=1); WHEN MIXED: 1.17-1.34 (H*2O=1). % VOLAT: 36-42; WHEN MIXED: 33-39. FL PT: 37.2C; FL PT WHEN MIXED: 103F,39C. EXPLO HAZ: DECOMP. HIGH HEAT & FIRE MAY PRDCE CARBON DIOXIDE & MO NOXIDE, OXIDES OF NITROGEN, HCN, HDI. HAZ DECOMP PROD: NITROGEN, HCN, MDI. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>210F,>99C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.19- (SUP DAT) Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS, AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY PRDCE HAZ FUMES WHEN HEATED TO DECOMP AS IN WELDING. FUMES MAY PRDCE CARBON DIOXIDE & MONOXIDE, OXIDES OF (SUP DAT) Conditions to Avoid Polymerization:CONTACT W/MOISTURE OR OTHER MATERIAL WHICH REACT W/ISOCYANATES OR TEMPERATURES OVER 400F MAY CAUSE POLYMERIZATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A SAFE MANNER IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS THAT APPLY TO INCINERATION OR SECURE LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:A357 BARE WIRE ALUMINUM ALLOY CAGE:0ACE2 CAGE:0ACE2 ============= Composition/Information on Ingredients ============= Ingred Name:AMORPHOUS FUSED SILICA, SILICON DIOXIDE, QUARTZ, SILICON (SUSPECTED HUMAN CARCINOGEN BY IARC - GROUP 2A) *95-4* CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: 6.5-7.5% Other REC Limits:30 MG/CUM TOTAL DUST ACGIH TLV:0.1 MG/CUM (RESP) IC Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0.2% OSHA PEL:10 MG/CUM ACGIH TLV:5 MG/CUM (FE) Ingred Name:COPPER (DUST & MIST), BRONZE POWDER *95-4* CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0.2% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0.1% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:MAGNESIUM OXIDE, MAGNESIA CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: 0.4-0.7% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:ZINC OXIDE *95-4* CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 0.1% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM FUME Ingred Name:THALLIUM CAS:7440-28-0 RTECS #:XG3425000 Fraction by Wt: 0-0.2% OSHA PEL:0.1 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALUMINUM (POWDER) *95-4* CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 91-92.5% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUME MAY CAUSE IRRITATION OF THE THROAT. LONG TERM EXPOSURE TO WELDING FUME, GASES/DUST MAY CONTRIBUTE TO PULMONARY IRRITATION/PNEUMOCONIOSIS. LONG TERM EXPOSURE TO IRON FUME MAY PRODUCE SIDEROSIS. BURNS FROMELECTROMAGNETIC RADIATION. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUME: DISCOMFORT, DIZZINESS, NAUSEA, DRYNESS, IRRITATION. Medical Cond Aggravated by Exposure:IMPAIRED PULMONARY FUNCTION/ILLNESS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:METAL POWDER FIRE: USE DRY SAND, DRY GRAPHITE/OTHER CLASS D FIRE EXTINGUISHING POWDER. Fire Fighting Procedures:IF MATERIAL IS REDUCED TO POWDER FORM, CAUTION MUST BE USED TO PREVENT FIRE/EXPLOSION. Unusual Fire/Explosion Hazard:CONTACT W/MINERAL ACIDS & OXIDIZING AGENTS MAY GENERATE HYDROGEN GAS WHICH MAY BE AN EXPLOSION HAZARD. ======================Handling and Storage ====================== Handling and Storage Precautions:WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK. TRAIN THE EMPLOYEE TO KEEP HEAD OUT OFUMES. Other Precautions:USE EXHAUST SYSTEM TO CLEAR WELDING FUMES. MAKE SURE THAT INHALED AIR DOESN'T CONTAIN FUME CONSTITUENTS ABOVE PERMISSABLE LEVELS. TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE HIMSELF FRO M WORK & GROUND. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN WELDING, BRAZING/SOLDERING IN CONFINED SPACES/WHERE LOCAL EXHAUST/VENTILATION DOESN'T KEEP EXPOSURE BELOW PELS, TLVS/STELS. Ventilation:USE LOCAL EXHAUST AT THE ARC/FLAME TO KEEP FUMES & GASES BELOW PELS, TLVS/STELS IN WORKERS BREATHING ZONE/GENERAL AREA. ARM PROTECTORS/APRONS/HATS/SHOULDER PROTECTION/DARK SUBSTANTIAL CLOTHING. Work Hygienic Practices:WELDER'S SHOULDN'T WEAR SHORT SLEEVES SHIRTS/SHORT PANTS/CUTOFFS. Supplemental Safety and Health PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSE. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATING, POSITION OF WELDERS H EAD W/RESPECT TO THE FUME PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID WIRE/ROD, GREY TO SILVER IN COLOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/MINERAL ACIDS & OXIDIZING AGENTS MAY GENERATE HYDROGEN GAS. Stability Condition to Avoid:(SEE SUPP) Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANAEROBIC ADHESIVE/SEALANT GRADE C CAGE:SAFTL CAGE:4Z299 CAGE:SAFTL ============= Composition/Information on Ingredients ============= Ingred Name:SACCHARIN (ANIMAL CARCINOGEN BY IARC - GROUP 2B) *95-3* CAS:81-07-2 RTECS #:DE4200000 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ORGANIC PEROXIDE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:SKIN: MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:SKIN: MAY CAUSE DERMATITIS. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH W/WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: KEEP CALM, REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>250F Extinguishing Media:CO2, FOAM, DRY CHEMICALS Fire Fighting Procedures:USE AIR MASK & PROCEDURES FOR FIGHTING CHEMICAL FIRES. Unusual Fire/Explosion Hazard:AUTOIGNITION TEMPS: >350F. CONTAINS ORGANIC PEROXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE GOOD VENTILATION. AVOID EYE & SKIN CONTACT. SOAK UP W/EARTH, SAND/ABSORBENT PRODUCT (ZORBAL). RECOVER IN CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE < 80F FOR PROLONGED SHELF LIFE. STORE IN ORIGINAL CONTAINER. Other Precautions:AVOID PROLONGED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECESSARY. Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>300F Decomp Temp:Decomp Text:>350F Vapor Pres:<5 Spec Gravity:1.1 Solubility in Water:PARTIAL Appearance and Odor:BLUE LIQUID W/LOW ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING & REDUCING AGENTS Stability Condition to Avoid:TEMPS > 120F. Hazardous Decomposition Products:CO, CO2, NITROUS OXIDES, ORGANIC PEROXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:75685-00203,EMPIRE BLUE, RED DEVIL GLOSS (SUP DAT) CAGE:THOMP CAGE:63272 CAGE:THOMP ============= Composition/Information on Ingredients ============= Ingred Name:C.I. PIGMENT RED 49; (BARIUM LITHOL RED) %: 0.01-6.78 CAS:1103-38-4 Fraction by Wt: <6.78% OSHA PEL:0.5 MG/M3 (MFR) ACGIH TLV:0.5 MG/M3 (MFR) Ingred Name:NAPHTHA, HEAVY STRAIGHT RUN; (NAPHTHA (PETROLEUM), HEAVY STRAIGHT-RUN) CAS:64741-41-9 Fraction by Wt: 1-2% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: 12-35% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 5-15% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) %: 0.0001-25.0 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUND: 450 G/L MAXIMUM RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: AVOID PROLONGED BREATHING OF VAPOR OR SPRAY MIST. SKIN/EYES/INGESTION: NONE EXPECTED. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PREEXISTING LUNG DISORDERS MAY BE AGGRAVATED BY INHALATION DURING USE. ======================= First Aid Measures ======================= First Aid:INHALATION: IF BREATHING IS AFFECTED, IMMEDIATELY MOVE TO FRESH AIR. SKIN: IN KEEPING WITH GOOD HYGIENIC PRACTICES, WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONTACT MD. EYES: AS IN THE CASE WHEN ANY FOREIGN MATTER CONTACT THE EYE, RINSE THOROUGHLY WITH WATER. INGESTION: CONTACT MD OR A POISON CONTROL CENTER. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:104F,40C Extinguishing Media:WATER SPRAY, FOAM, DRY CHEM/CARBON DIOXIDE. DO NOT USE DIRECT STREAM OF WATER. PROD WILL FLOAT & CAN BE (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . COMBUSTIBLE. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:COMBUST. CONTAINS PETRO DISTILS. KEEP AWAY FROM HEAT & FLAME. CONTRS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED W/WATER TO PVNT VAP PRESS (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SMALL SPILLS W/SAND/OTHER SUITABLE ABSORB MATL & PLACE IN CONTR FOR DISP. FOR LARGE SPILLS, AREA MAY BE SLIPPERY, DIKE AROUND SPILL W/ABSORB MATL. TRANSFER LIQS & CONTAM DIKING MATL TO SEPARATE , SUITABLE CONTRS FOR RECOVERY/DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTIBLE. CONTAINS PETROLEUM DISTILLATES. AVOID PROLONGED BREATHING OF VAPOR. KEEP OUT OF REACH OF CHILDREN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID PROLONGED BREATHING OF VAPOR. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health TRADE NAME/PART #:POLYURETHANE OIL ENAMEL-NAT VOC-ALL SHADES. % VOLAT: 53.3-70.1. EXTING MEDIA: REIGNITED ON SURF OF WATER. EXPLO HAZ: BUILD-UP WHICH COULD RSLT IN CONTR RUPTURE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:220F,104C Vapor Pres:<55 @ 20C Vapor Density:4.8 Spec Gravity:0.94-1.32 Solubility in Water:INSOLUBLE Appearance and Odor:COLORED, VISCOUS LIQUID WITH PETROLEUM SOLVENT ODOR Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, ALL SOURCES OF HEAT OR IGNITION. Hazardous Decomposition Products:HYDROCARBON FUMES, SMOKE, CARBON MONOXIDE (WHERE COMBUSTION IS INCOMPLETE) MAY BE FORMED DURING THERMAL DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MGI68206 CAGE:08772 CAGE:08772 ============= Composition/Information on Ingredients ============= Ingred Name:ING 7: COMBUST MATLS MAY RSLT IN IGNIT, VIOLENT COMBUST/EXPLOSION. RTECS #:9999999ZZ Ingred Name:HLTH HAZ:NARCOSIS. PERS EXPOSED TO INCREASED PRESS & SUDDENLY RELEASED FROM PRESS MAY DEVELOP DECOMPRESSION (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:SICKNESS, RPTD EXPOS, W/OUT COMPLETE DECOMP, MAY RSLT IN DECOMP SICKNESS. INHAL: SIMPLE ASPHYXIANT. UNCON (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:MAY BE IMMED.W/SLOW DEVELOPMENT THERE MAY BE RAPID RESP & PULSE, AIR HUNGER, DIZZ, REDUCED AWARENESS, (SUPP DATA) RTECS #:9999999ZZ Ingred Name:ING 11:TIGHTNESS IN HEAD, TINGLING SENSATIONS, INCOORDINATION, FAULTY JUDGMENT, EMOTIONAL INSTABILITY, & RAPID (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: FATG. AS THE ASPHYXIA PROGRESSES, NAUS, VOMIT, COLLAPSE, UNCON, CONVULSIONS, DEEP COMA & DEATH ARE POSS.(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SKIN: ACUTE: LIQ MAY CAUSE FROSTBITE W/REDNESS, TINGLING & PAIN/NUMBNESS, IN SEV CASES, SKIN MAY BECOME (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:HARD & WHITE & DEVELOP BLISTERS. EYE: ACUTE: LIQ MAY CAUSE FROSTBITE W/REDNESS, PAIN, & BLURRED VISION. (ING 16) RTECS #:9999999ZZ Ingred Name:INGEST: ACUTE: IF LIQ IS SWALLOWED, FROSTBITE DAMAGE TO THE LIPS, MOUTH, AND MUCOUS MEMBRANES MAY OCCUR. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: WATER IS NOT AVAIL/IMPRACTICAL TO USE, GENTLY WRAP AFFECTED PART IN BLANKETS. ENCOURAGE VICTIM (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: TO EXERCISE AFFECTED PART WHILE IT IS BEING WARMED. ALLOW CIRCULATION TO RETURN NATURALLY. GET MED ATTN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: IMMED. EYE: WASH W/LG AMTS OF WARM WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). GET MED (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: ATTN IMMED. INGEST: TREAT SYMPTOMATICALLY AND SUPPORTIVELY AND GET MED ATTN. RTECS #:9999999ZZ Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: >0.5% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 Ingred Name:OXYGEN CAS:7782-44-7 Fraction by Wt: 0->99.9% Ingred Name:ARGON CAS:7440-37-1 RTECS #:CF2300000 Fraction by Wt: 0-<99.9% ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:HELIUM CAS:7440-59-7 RTECS #:MH6520000 Fraction by Wt: 0-<99.9% ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: 0-<99.9% ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:NEON CAS:7440-01-9 RTECS #:QP4450000 Fraction by Wt: 0-<99.9% ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:EXPLO HAZ: OTHER GASES WHICH WILL INCREASE BURNING RATE OF COMBUST MATTER. CONT W/EASILY OXIDIZABLE, ORG/OTHER (ING 8) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: ING 1:POISONING MAY AFFECT RESP & NERVS SYS & HEART. ING 2:POISONING MAY AFFECT PULM, CVS & NERVS SYS & EYE. RESP SYS, CVS, NERVS SYS MAY BE AFFECTED. CHRONIC:ADMIN OF O*2 @ ATMOS PRESS @ CONC OF 60% & 80% MAY BE FOLLOWED BY ADVERSEEFTS, INCLUDING SEV COUGH, ACUTE CHEST PAIN ASSOCD (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: W/DECREASE IN VITAL CAPACITY, INTRA-ALVEOLAR EDEMA & ATELECTASIS. AFTER HUMAN WAS EXPOSD TO HIGH CONC OF O*2 FOR 160 DAYS, SEV IRREVERSIBLE RETINAL ATROPHY OCCURRED. ING 5: UNDER INCREASED A TMOS PRESS, (>1.5 ATMOS), MAY DISSOLVE IN FAT-CONTAING BRAIN CELLS, & ACT AS AN ANESTHETIC, CAUSING (ING 9) Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF CARDIOVASCULAR OR PULMONARY IMPAIRMENT. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF RESP. MAINTAIN AIRWAY & BLOOD PRESS & ADMIN O*2 IF AVAIL. KEEP AFFECTED PERS WARM & @ REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY. ADMIN OF O*2 SHLD BE PERFORMED BY QUALIFIED PERS. GET MED ATTN IMMED. SKIN: IF ADVERSE EFTS OCCUR, GET MED ATTN. IN CASE OF FROSTBITE, WARM AFFECTED SKIN IN WARM WATER @ TEMP OF 107F. IF WARM (ING 17) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM FIRE AREA IF W/OUT RISK. APPLY COOLING WATER TO SIDES OF CNTNRS THAT ARE (SUPP DATA) Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOSD TO HEAT/FLAME.CYLINDER MAY EXPLODE IN HEAT OF FIRE. OXIDIZER:OXIDIZERS DECOMPOSE, ESPECIALLY WHEN HEATED, TO YIELD O*2/ (ING 7) ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTS (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED MATL. STOP LEAK IF W/OUT RISK. ISOLATE AREA UNTIL GAS HAS DISPERSED. KEEP UNNEC PEOPLE AWAY; ISOLATE HAZARD AREA & DENY ENTRY. STAY UPWIND, OUT OF LOW AREAS & VENT CLSD SPACES BEFOREENTERING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.101.CONSULT NFPA PUBLICATION 43C, STORAGE OF GASEOUS OXIDIZING MATLS, FOR STORAGE REQMTS. STORE AWAY FROM INCOMPAT SUBSTANCES. Other Precautions:DO NOT PERMIT DAM/OVERHEATING OF CNTNRS, CONTENTS UNDER PRESS; CNTNRS MAY VIOLENTLY RUPTURE & TRAVEL CONSIDERABLE DISTANCE.OBSERVE ALL FED, STATE & LOC REGS WHEN STORING/DISPOSING OF SUBSTANCE. FOR AS SISTANCE, CONT DISTRICT DIRECTOR OF EPA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY NIOSH/MSHA. FOR MORE SPECIFIC INFO CONT ACT NEHC . Ventilation:PROVIDE GENERAL DILUTION VENTILATION. Other Protective Equipment:EYE WASH FOUNTAIN & QUICK DRENCH SHOWER W/IN IMMEDIATE WORK AREA. APPROP PROT CLTHG & EQUIP TO PVNT SKIN FROM FREEZING. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. Supplemental Safety and Health FIRE FIGHT PROC: EXPOSD TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITER NOZ; IF THIS IS IMPOSS, W/DRAW FROM AREA & LET FIRE BURN. COOL CNTNRS W/FLOODINGAMTS OF WATER, APPLY FROM AS FAR A DISTANCE AS POSS. ================== Physical/Chemical Properties ================== HCC:G3 Appearance and Odor:GAS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS. FOR A COMPLETE LISTING OF MATERIALS TO AVOID, CONTACT NEHC . Stability Condition to Avoid:AVOID CONTACT WITH COMBUSTIBLE MATERIALS (WOOD, PAPER, FUEL, OILS, ETC); CONTACT MAY RESULT IN IGNITION OR EXPLOSION. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA HAZAREDOUS WASTE NUMBER D001. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6381-25 ROSIN FLUX TYPE RMA Preparer's Name:ROBERT L GILBERT CAGE:03051 CAGE:03051 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL:(ISOPROPANOL) (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 55-65% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 500 STEL Ingred Name:ROSIN;(ROSIN ACID) CAS:8050-09-7 RTECS #:VL0480000 Fraction by Wt: 25-35% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: LIQUID/VAPOR CONTACT MAY CAUSE IRRITATION OF EYES, SKIN, NOSE, THROAT & RESPIRATORY SYSTEM & MAY RESULT IN CNS DEPRESS. THIS MATERIAL IS TOXIC & MAY BE HARMFUL IF SWALLOWED. CHRONIC: PROLONGED CONTACT WITH SKIN MAY CAUSE REDNESS, DRYING & CRACKING TO SKIN. PROLONGED OVEREXP TO SOLVENTS MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CAUSE PERMANENT BRAIN & NERVOUS DAMAGE. Medical Cond Aggravated by Exposure:ROSIN IS AN ALLERGEN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/COPIOUS QTYS OF WATER FOR AT LEAST 15 MINUTES. GET MED ATTN. SKIN: WASH W/SOAP & WATER. INHAL: REMOVE FROM EXPOSURE. GET MED ATTN IF EXPERIENCING EFT OF OVEREXP. INGEST: GET IMMED MED AT TN. INDUCE VOMITING BY TOUCHING FINGER TO BACK OF THROAT. KEEP VICTIM'S HEAD BELOW HIPS WHILE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:62.0F,16.7C Lower Limits:2% Upper Limits:12% Extinguishing Media:CARBON DIOXIDE, ALCOHOL RESISTANT FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT. EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. EVACUATE THE HAZARD AREA OF UNPROTECTED PERSONNEL. ABSORB SPILLED MATL W/ABSORB MATERIAL & PLACE IN NON-LEAKING CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAMES. KEEP CONTAINERS TIGHTLY CLOSED. GROUND ALL HANDLING EQUIPMENT. STORE IN COOL, DRY PLACE. Other Precautions:MINIMIZE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS LIMITS, USE A NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHST: PREFERABLE. MECH(GENL): ADEQUATE. Other Protective Equipment:WEAR PROTECTIVE CLTHG TO PREVENT SKIN CONTACT. SAFETY SHOWER & EYE WASH STATION MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health SPEC GRAV: 0.86 @ 25C(H*2O=1). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>149F,>65C Vapor Pres:33 Vapor Density:2.07 Spec Gravity:SUPP DATA Evaporation Rate & Reference:1.7 (BUAC=1) Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:AMBER LIQUID WITH ALCOHOLIC ODOR. Percent Volatiles by Volume:87 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. RECOMMENDED METHOD IS INCINERATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CLEARFIL PORCELAIN BOND CAGE:OBK19 CAGE:OBK19 ============= Composition/Information on Ingredients ============= Ingred Name:DIMETHACRYLATE Ingred Name:PHOSPHORYLATED METHACRYLATE Ingred Name:SILICON TETRAHYDRIDE CAS:7803-62-5 RTECS #:VV1400000 Other REC Limits:5 PPM OSHA PEL:5 PPM ACGIH TLV:5 PPM; 9192 Ingred Name:UNFILLED RESIN ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OFF ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP REFRIGERATED WHEN NOT IN USE TO AVOID DETERIORATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NECESSARY Ventilation:NOT NECESSARY Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.9 Solubility in Water:INSOLUBLE Appearance and Odor:LIQUID Percent Volatiles by Volume:30% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT SPECIFIED.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:825X3888(MANUF. CODE ID) CAGE:32758 CAGE:96595 CAGE:32758 ============= Composition/Information on Ingredients ============= Ingred Name:ORGANIC TIN COMPOUND Fraction by Wt: <0.5% OSHA PEL:S, 0.1 MG/M3 (SN) ACGIH TLV:S, 0.1 MG/M3 (SN) Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 10% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 5% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 20% OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9192 Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 10% OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:INHALATION-ANESTHETIC;HEADACHE, DIZZINESS, CONFUSION UNCONSCIOUSNESS OR COMA ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WATER;SKIN-WASH WITH WATER; INHALATION-REMOVE FROM EXPOSURE, RESTORE BREATHING, KEEP WARM AND QUIET, NOTIFY PHYSICIAN; INGESTION-CONSULT A PHYSICIAN. REMOVE CONTAMINATED CLOTHING. ===================== Fire Fighting Measures ===================== Flash Point:22.0F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM Fire Fighting Procedures:USE FOG NOZZLES IF USING WATER, WEAR SELF-CONT BREATH. APPR Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA. REMOVE WITH ERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F, STORE IN BUILDINGS DESIGNED FOR STORAGE OF FLAMMABLE LIQUIDS. Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR RESPIRATOR, AIRLINE TYPE RESPIRATORS IN CONFINED AREAS Ventilation:GENERAL DILUTION, OR LOCAL TO KEEP TLV BELOW LIMIT. Other Protective Equipment:PROTECTIVE CLOTHING(BUTYL, NEOPRENE OR NITRILE RUBBER APRON) Supplemental Safety and Health MEHTYL ETHYL KETONE <5% 2OOPPM, LEAD CHROMATE PIGMENT <5%, SILICA-AMORPHOUS 10%. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:171-313F Evaporation Rate & Reference:SLOWER(ETHER=1) Percent Volatiles by Volume:62.3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FED REGULATIONS. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:75360 ETHYLENEDIAMINIE, EDA Preparer's Name:F.E. BENTLEY CAGE:19630 CAGE:19630 CAGE:3B431 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-ETHANEDIAMINE;(ETHYLENEDIAMINE) (SARA III) CAS:107-15-3 RTECS #:KH8575000 Fraction by Wt: 100% OSHA PEL:10 PPM ACGIH TLV:10 PPM,S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL RAT)1.16 G/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:EXTREMELY IRRITATING WITH POSSIBLE PERMANENT INJURY. MAY CAUSE BLINDNESS. SKIN:CORROSIVE. SEVERE SKIN DAMAGE WITH BURNS AND BLISTERING. MAY CAUSE ALLERGIC SKIN REACTION. INHAL:MAY CAUSE IRRI TATION OF UPPER RESPIRATORY TRACT. MAY CAUSE AN ALLERGIC RESPIRATORY/ASTHMA LIKE REACTION.CHRONIC:(EFTS OF OVEREXPOSURE) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:REPEATED OR PROLONGED OVEREXPOSURE MAY CAUSE DERMATITIS, LIVER, KIDNEY OR LUNG INJURY. ASTHMATIC SYMPTOMS MAY OCCUR. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH THOROUGHLY WITH WATER FOR AT LEAST 30 MINUTES. GET MD IMMEDIATELY. SKIN:IF DRENCHED, REMOVE CONTAMINATED CLOTHING UNDER SAFETY SHOWER AND FLOOD EXPOSED AREAS WITH WATER. GET MD IMMEDIATELY. WASH CLOTHING BEFORE REUSE. INGEST:DO NOT INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER. CALL MD. INHAL:MOVE TO FRESH AIR. IF NOT BREATHING, APPLY ARTIFICIAL RESPIRATION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Lower Limits:5.8% Upper Limits:11.1% Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . USE WATER TO KEEP FIRE EXPOSED CNTNRS COOL. IF LEAK/SPILL HAS NOT IGNITED, USE WATER SPRAY (SUPP DATA) Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID ALL PERSONAL CONTACT. CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATERIAL AND SHOVEL UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT AND OPEN FLAME. KEEP CONTAINER CLOSED. USE ONLY IN WELL VENTILATED LOCATIONS. Other Precautions:TRANSPORT, HANDLE AND STORE IN ACCORDANCE WITH OSHA REGULATION 1910.106 AND APPLICABLE DOT REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION FOR CLEANING LARGE SPILLS OR UPON ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES. Ventilation:LOCAL EXHAUST VENTILATION RECOMMENDED. Other Protective Equipment:RUBBER BOOTS. Work Hygienic Practices:DO NOT WEAR CONTACT LENSES. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:TO DISPERSE VAPORS AND TO PROVIDE PROTECTION FOR PERSONS ATTEMPTING TO STOP LEAK. WASTE DISP METH:REGULATIONS . HAZ WASTE NO:D001. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:242F,117C Vapor Pres:10 Vapor Density:2.1 Spec Gravity:0.904 (H*2O=1) pH:12 Evaporation Rate & Reference:0.91 Solubility in Water:APPRECIABLE Appearance and Odor:CLEAR COLORLESS LIQUID, AMMONIA ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY WITH ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AMMONIA, CARBON MONOXIDE, & CARBON DIOXIDE MAY BE FORMED ON BURNING IN LIMITED AIR SUPPLY. OXIDES OF NITROGEN POSSIBLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RE-EVALUATION OF PROD MAY BE REQ BY USER AT TIME OF DISP, SINCE PROD USES, TRANSFORMATIONS, MIXTURES & PROCESSES MAY CHANGE CLASSIFICATION TO NON-HAZ/HAZ FOR REASONS OTHER THAN, OR IN ADDITION TO IGNI T. DISP MUST BE I/A/W LOC, STATE/FED (SUPP DATA)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENAMEL SEMIGLOSS RUST INHB.23 M.C.GREEN CAGE:60189 CAGE:60189 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 36.2% OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 2.6% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 4.6% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:LEAD TETRAOXIDE, LEAD ORTHOPLUMBATE CAS:1314-41-6 Fraction by Wt: 7.0% OSHA PEL:0.2 MG/M3PB Ingred Name:LEAD CHROMATE CAS:1344-37-2 Fraction by Wt: 13.8% OSHA PEL:.05MG/M3PB,.01MG/M3C Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:TALC (CONTAINING NO ASBESTOS) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 2.3% OSHA PEL:2 MG/M3 RDUST ACGIH TLV:2 MG/M3 RDUST; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:YES Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES AND SKIN MAY OCCUR WIHT OVEREXPOSWURE. CONTINUED BREATHING OF VAPORS MAY IRRITATE RESPIRATORY TRACT. CHRONIC: REPORTS HAVE ASSCIATED PROLONGE D OCCUPATIONAL OVEREXPOSURE TO SOLVENTSWITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:LEAD CHROMATE IS LISTED AS A SUSPECT HUMAN CARCINOGEN BY OSHA AND ACGIH. Effects of Overexposure:HEADACHE NAUSEA AND DIZZINESS ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE VICTIM TO FRESH AIR. RESTORE RESPIRATION IF NECESSARY. TREAT SYMPTOMATICALLY. EYE: FLUSH IMMEDIATELY W/COPIOUS AMOUNTS OF WTR FOR 15 MINS. CONSULT A PHYSICIAN. SKIN: WASH AFFECTED AREAS W/SOAP & WATER.CONSULT PHYSICIAN.INGEST: DO NOT INDUCE VOMITING. CONTACT PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F/40.5C Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:CO2, DRY CHEMICAL Fire Fighting Procedures:FIREFIGHTERS SHOULD USE S.C.B.A. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPORS AND COOLING CONTAINERS EXPOSED TO HEAT AND FLAME. Unusual Fire/Explosion Hazard:NO INFORMATION FOUND ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNTION SOURCES, WEAR APPROPRIATE PERSONAL PROTECTION EQUIP & APPROVED RESPIRATOR. CONTAIN SPILL AND PUT IN VAPOR TIGHT CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN AREAS TO COMPLY W/ANSI/NFPA 30 FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED NIOSH/MSHA ORGANIC VAPOR RESPIRATOR. Ventilation:SUFFICIENT VENTL. IN VOL. & PATTERN, REQUIRED TO KEEP HAZARDMATERIALS BELOW APPLICABLE EXPOSURE LEVELS. Work Hygienic Practices:WASH HANDS PROPERLY BEFORE EATING SMOKING OR USING WASHROOM FACILITIES. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:323F/161.6C Vapor Pres:2 MMHG Vapor Density:> AIR Spec Gravity:1.282 pH:NA Viscosity:75-200 4CUP Evaporation Rate & Reference:0.12 Solubility in Water:NO Appearance and Odor:GREEN LIQUID ALIPHATIC ODOR Percent Volatiles by Volume:61.2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZIERS Stability Condition to Avoid:HEAT, OPEN FLAME Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALKALI ALUMINA BORO SILICATE 25/259 CAGE:FO138 CAGE:94567 CAGE:FO138 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BORON OXIDE CAS:1303-86-2 RTECS #:ED7900000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:CALCIUM CAS:7440-70-2 RTECS #:EV8040000 ACGIH TLV:5 MG/CUM Ingred Name:SILICON CARBIDE CAS:409-21-2 RTECS #:VW0450000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ======================= First Aid Measures ======================= First Aid:PLACE PATIENT A BED REST AND CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:NORMAL CLEANUP PROCEDURE. ======================Handling and Storage ====================== Other Precautions:NO SMOKING OR FOOD HANDLING IF IN CONTACT WITH PRODUCT UNTIL WASHUP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MSA TYPE DUST FOE #66 OR EQUIVALENT Ventilation:LOCAL EXHAUST/RECOMMENDED Supplemental Safety and Health MSDS UNDATED. ALSO CONTAINS: SODIUM (VY0686000), POTASSIUM (TS6460000). ================== Physical/Chemical Properties ================== Solubility in Water:SLIGHT Appearance and Odor:POWDER, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:447A CAGE:28835 CAGE:28835 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 70-90% Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9394 Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9394 Ingred Name:MICA - SILICATES (< 1% CRYSTALLINE SILICA) CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:20 MPPCF; Z-3 ACGIH TLV:3 MG/M3 RDUST; 9394 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9394 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <10% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:MAGNESITE CAS:546-93-0 RTECS #:OM2470000 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:SILICATE BINDERS CAS:10006-28-7 Fraction by Wt: <10% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO Health Hazards Acute and Chronic:WELDING CONSUMABLES ARE NON-REACTIVE, NON-FLAMMABLE, NON-EXPLOSIVE, AND ESSENTIALLY NON-HAZARDOUS UNTIL USED IN A WELDING OPERATION. WELDING HAZARDS INCLUDE INHALATION OF FUMES, THERMAL BURNS, RADIAT ION BURNS AND ELECTRIC SHOCK. CHRONIC:EXCESS LEVELS MAY CAUSE BRONCHIAL ASTHMA, LUNG FIBROSIS, PNEUMOCONIOSIS. Explanation of Carcinogenicity:WELDING FUMES MUST BE CONSIDERED AS POSSIBLE CARCINOGENS UNDER OSHA (29 CFR 1910.1200); PER MANUFACTURER. Effects of Overexposure:WELDING FUMES MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA OR DRYNESS OR IRRITATION NOSE, THROAT OR EYES. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY DISFUNCTION MAY BE AGGRAVATED BY FUME INHALATION. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS.EYES AND SKIN- IF IRRITATION OR FLASH BURNS DEVELOP AFTER EXPOSURE, CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. WELDING ARCS AND SPARKS CAN IGNITE COMBUSTIBLES AND FLAMMABLE PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES AND PLACE IN SUITABLE DOT APPROVED CONTAINERS. AVOID INHALATION AND SKIN EXPOSURE. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL HANDLING IS REQUIRED. STORE AS DIRECTED BY MFR. Other Precautions:SEE ANSI STANDARD Z49.1-1983. READ "SAFETY IN WELDING AND CUTTING" FROM AMERICAN WELDING ASSOCIATION, 550 N.W. JEUNE RD., MIAMI,FL 33135. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA WELD FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE BELOW PEL/TLV. Ventilation:USE LOCAL VENTILATION WHEN CUTTING, GRINDING OR WELDING TO KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE. Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT CUTTING OR WELDING. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE. WASH THOROUGHLY BEFORE EATING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health USE INDUSTRIAL HYGIENE MONITORING TO ENSURE THAT YOUR USE OF THIS MATERIAL DOES NOT CREATE EXPOSURES WHICH EXCEED PEL/TLV. ================== Physical/Chemical Properties ================== HCC:N1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING AND CUTTING OPERATION MAY PRODUCE OXIDES OF THE METALS. WELDING FUMES AND GASES CANNOT BE CLASSIFIED SIMPLY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS. RECLAIM METALS IF APPROPRIATE. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MURIATIC ACID(HYDROCHLORIC ACID 20 BE) Preparer's Name:ATIF DABDOUB,PHD CAGE:4K533 CAGE:4K533 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 33% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 67% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RABBIT) IS 900 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:**CORROSIVE** ACUTE-EYES: SEVERE IRRITATION, PAINFUL BURNS. SKIN: SEVERE BURNS. INHALATION: ULCERATION OF NOSE, THROAT, LARYNX. INGESTION: SEVERE BURNS OF MUCOUS MEMBRANE OF MOUTH, ESOPHAGUS, STOMACH. CHRONIC-EYES: PERMANENT VISUAL IMPAIRMENT, TOTAL LOSS OF SIGHT. SKIN: DERMATITIS. INHAL: EDEMA OF LUNGS, TOOTH DAMAGE. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:EYES:PAINFUL BURNS. SKIN:SEVERE BURNS. INHALATION:COUGHING,BURNING OF THROAT,CHOKING SENSATION. INGESTION:LIPS AND MOUTH USUALLY TURN WHITE,AND LATER BROWN.PAIN IN THE THROAT AND STOMACH,DIFFICULTY IN SWALLOWING,INTENSE THIRST,NAUSEA AND VOMITING,FOLLOWED BY DIARRHEA,IN SEVERE CASES BY COLLAPSE AND UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING DISEASE INVOLVING SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE WATER OR MILK OF MAGNESIA. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. DO NOT GET WATER INSIDE CONTAINERS. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE TOXIC AND CORROSIVE HYDROGEN CHLORIDE. EXPLOSIVE HYDROGEN MAY BE PRODUCED ON CONTACT WITH METALS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SCBA AND PROTECTIVE CLOTHING.NEUTRALIZE WITH LIME,SODA ASH OR LIMESTONE SOLUTIONS.NEUTRALIZATION WILL EVOLVE CARBON DIOXIDE.IN ENCLOSED SPACES,PROVIDE AMPLE VENTILATION.ABSORB IN INERT MATERIAL,A ND PLACE IN APPROPIATE DISPOSAL CONTAINER. Neutralizing Agent:LIME(CALCIUM HYDROXIDE),SODA ASH(SODIUM CARBONATE),LIMESTONE(CALCIUM CARBONATE). ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CORROSION-PROOF, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POWERED AIR-PURIFYING RESPIRATOR WITH AN ACID GAS CARTRIDGE OR SELF-CONTAINED BREATHING APPARATUS AS REQUIRED FOR THE EXPOSURE OF CONCERN. Ventilation:GENERAL (MECHANICAL) VENTILATION.LOCAL EXHAUST IN ENCLOSED AREAS. Other Protective Equipment:IMPERVIOUS CLOTHING,FOOTWEAR AND HEAD GEAR. EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=65.6C, 150.F B.P. Text:150-230F Melt/Freeze Pt:=-43.9C, -47.F Vapor Density:1.3 Spec Gravity:1.16 pH:1(SOL) Viscosity:<10CPS Solubility in Water:COMPLETE Appearance and Odor:LIQUID,CLEAR;COLORLESS;PUNGENT,IRRITATING ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS, WATER, AMINES, ALKALIES, STRONG BASES, SULFURIC ACID. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, MOISTURE. Hazardous Decomposition Products:POISONOUS CHLORINE GAS, TOXIC AND CORROSIVE HYDROGEN CHLORIDE, EXPLOSIVE HYDROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOTIFY YOUR LOCAL ENVIRONMENTAL OFFICER.DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PREMIUM DECOR ENAMEL PDS-LINE,30-35 Resp. Party Other MSDS Num.:SPRAY PAINT, 8-15, 2M-298 CAGE:TO087 CAGE:TO087 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE; VP: 186.0 MMHG @ 20C CAS:67-64-1 RTECS #:AL3150000 Minumum % Wt:25. Maxumum % Wt:35. Other REC Limits:N/K OSHA PEL:2400 MG/M3;1000 PPM OSHA STEL:N/K ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE/ISOBUTANE BLEND; VP: 80 PSI @ 20C Minumum % Wt:25. Maxumum % Wt:31. Other REC Limits:N/K OSHA PEL:1000 PPM OSHA STEL:N/K ACGIH TLV:1000 PPM ACGIH STEL:N/K Ingred Name:TOLUENE; VP: 22.0 MMHG @ 20C CAS:108-88-3 RTECS #:XS5250000 Minumum % Wt:10. Maxumum % Wt:20. Other REC Limits:N/K OSHA PEL:see Table Z-2 OSHA STEL:N/K ACGIH TLV:188 MG/M3;50 PPM ACGIH STEL:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZIN; (VM&P NAPHTHA); VP: 5.2 MMHG @ 20C CAS:8030-30-6 RTECS #:DE3030000 Minumum % Wt:3. Maxumum % Wt:10. Other REC Limits:N/K OSHA PEL:400 MG/M3;100 PPM OSHA STEL:N/K ACGIH TLV:1590 MG/M3;400 PPM ACGIH STEL:N/K CAS:14807-96-6 RTECS #:WW2710000 Minumum % Wt:3. Maxumum % Wt:7. Other REC Limits:N/K OSHA PEL:see Table Z-3 OSHA STEL:N/K ACGIH TLV:2 MG/M3 ACGIH STEL:N/K CAS:1333-86-4 RTECS #:FF5800000 Minumum % Wt:.1 Maxumum % Wt:.6 Other REC Limits:N/K OSHA PEL:3.5 MG/M3 OSHA STEL:N/K ACGIH TLV:3.5 MG/M3 ACGIH STEL:N/K CAS:64742-89-8 Minumum % Wt:1. Maxumum % Wt:3. Other REC Limits:N/K OSHA PEL:200 PPM OSHA STEL:N/K ACGIH TLV:200 PPM ACGIH STEL:N/K CAS:14464-46-1 RTECS #:VV7325000 Minumum % Wt:.5 Maxumum % Wt:.8 Other REC Limits:N/K OSHA PEL:see Table Z-3 OSHA STEL:N/K ACGIH TLV:0.05 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: EXPOSURE TO LARGE AMOUNTS OF VAPORS, MISTS OR SANDING DUSTS MAY CAUSE MODERATE IRRITATION TO THE LUNGS, NOSE, AND THROAT. MAY ALSO CAUSE DIZZINESS, NAUSEA OR FATIGUE. SKIN: EXPOSURE MAY CAUSE MILD IRRITATION. PROLONGED EXPOSURE MAY CAUSE DRYING AND CRACKING. EYES: CAUSES IRRITATION, INCLUDING REDNESS, STINGING AND WATERING. INGESTION: MODERATELY TOXIC IN LARGE AMOUNTS. COULD CAU SE DROWSINESS, NAUSEA OR HEADACHE. (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:CARCON BLACK: IARC MONOGRAPHS, VOLUME 65, PAGE 149, 1998: GROUP 2B. ANIMAL: LUNG. SILICA, CRYSTALLINE-CRISTOBALITE: IARC MONOGRAPHS, VOLUME 68, 1998: GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 199 8: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN. HUMAN: LUNG. Effects of Overexposure:HEALTH HAZARDS: CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENT RATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. TOLUENE APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNIN G LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION . Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. USE ARTIFICIAL RESPIRATION IF NECESSARY. SEEK MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA WITH SOAP AND WATER. WASH CLOTHING BEFORE REUSE . EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. INGESTION: GIVE 1 OR 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. G ET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:<-6.7C, 20.F Lower Limits:2.0% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . TREAT AS VOLATILE LIQUID FIRE. WATER SPRAY MAY BE INEFFECTIVE. IF WATER SPRAY IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO C OOL SEALED CONTAINERS TO PREVENT PRESSURE BUILD-UP & POSSIBLE EXPLOSION OR AUTO-IGNITION WHEN EXPOSED TO HEAT OF A FIRE. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, SPARKS AND OPEN FLAME. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM HANDLING SITE. HAZARDOUS DECOMPO SITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. CONTAIN SPILL, ABSORB LIQUID WITH CLAY, SAND OR FLOOR ABSORBENT. PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE AS AN EXTREMELY FLAMMABLE MATERIAL. KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS, AND OPEN FLAME. CLOSE CONTAINER AFTER EACH USE. STORE IN A COOL DRY AREA. DO NOT EXPOSE CONTAINER TO TEMPERATUR ES ABOVE 120F. CAUTION: KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED AIR PURIFYING RESPIRATOR IF TLV LIMITS ARE EXCEEDED. NIOSH APPROVED MECHANICAL FILTER TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING APPLICATION. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. CONTACT. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. WASH HANDS THOROUGHLY AFTER USE, AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health VOLATILE ORGANIC COMPOUND (VOC) MAXIMUM: NONFLAT 65%; FLAT 60%. DENSITY: 7.5 - 15.0 WT (LBS)/GAL. ================== Physical/Chemical Properties ================== Boiling Pt:<-17.8C, 0.F Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Spec Gravity:0.90-1.80 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:COLORED LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:68% - 83% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS REGARDING PROPER DISPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT FLAMMABILITY CLASSIFICATION: COMPRESSED FLAMMABLE GAS ORM-D. ===================== Regulatory Information ===================== SARA Title III Information:TOLUENE IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 SARA TITLE III. State Regulatory Information:WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:263 HENRY ALL WEATHER OUTDOOR CARPET ADHESIVE, GALLON CAGE:FO818 CAGE:11761 CAGE:FO818 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 18-25% Other REC Limits:50 PPM OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:BENZIN, NAPHTHA, MINERAL SPIRITS, PETROLEUM NAPHTHA CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 10-14% Other REC Limits:STEL 400 PPM OSHA PEL:500 PPM ACGIH TLV:300 PPM Ingred Name:VOL ORGANIC CMPD: 396 - 400 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: WATERING & DISTRESS. SKIN: IRRITATION & DERMATITIS. INHALATION: HARMFUL/FATAL, HEADACHES, DIZZINESS, ASPHYXIA, NOSE, THROAT, & LUNG DISTRESS, PERMANENT BRAIN & NERVOUS SYSTEMDAMAGE. INGESTION: H ARMFUL Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: WATERING & DISTRESS. SKIN: IRRITATION & DERMATITIS. INHALATION: HARMFUL, FATAL, HEADACHES, DIZZINESS, ASPHYXIA, NOSE, THROAT, LUNG DISTRESS, PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INGESTION: H ARMFUL Medical Cond Aggravated by Exposure:CURRENT ANEMIA, RESPIRATORY TRACT OR LIVER AILMENTS & SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MIN. SKIN: WASH THOROUGHLY W/SOAP & WATER OR HAND CLEANER. INHALATION: REMOVE TO FRESH AIR & APPLY ARTIFICIAL RESPIRATION IF NEEDED. INGESTION: OBTAIN MEDICAL ATTE NTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:<20F Lower Limits:1% Extinguishing Media:FOAM, CO2, DRY CHEMICAL, OR WATER FOG. Unusual Fire/Explosion Hazard:VAPORS >AIR MAY TRAVEL DISTANCE, IGNITE EXPLOSIVELY/FLASH FIRE IF ALLOWED TO COLLECT/CONCENTRATE. CLOSED CONTAINERS PRESSURIZE/ERUPT WHEN HEATED. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE OR EXTINGUISH ALL SOURCES OF IGNITION IN THE AREA, INCLUDING EQUIPMENT WHICH MAY SPARK. SCOOP MATERIAL INTO APPROVED DOT CONTAINER & REMOVE TO SAFE PLACE WHERE MATERIAL CAN DRY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/FLAMES/IGNITION SOURCES/CHILDREN/SWITCHES/FANS/TOOLS. USE AS DIRECTED ON LABEL. DON'T SMOKE. USE OUTDOORS ONLY. Other Precautions:CLOSE CONTAINER AFTER EACH USE. DON'T RE-USE CONTAINER OR USE INDOORS DON'T USE OVER ROOFING ASPHALT OR PLANK DECKING. A SOLVENT ODOR IS NOTED UNTIL ADHESIVE DRIES. TURN OFF ELECTRICAL/GAS APPLIANCES/ WATER HEATER. AVOID SPLASHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR FRESH AIR CROSS VENTILATION NORMALLY SUFFICIENT. PROVIDE FRESH AIR SUPPLY IF NECESSARY. WEAR NIOSH APPROVED RESPIRATORY EQUIPMENT, OR LEAVE AREA. Ventilation:PROVIDE ADEQUATE FRESH AIR CROSS VENTILATION. Other Protective Equipment:AS REQUIRED Work Hygienic Practices:WASH HANDS THROUGHLY W/SOAP & WATER AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:150-220F Vapor Pres:100 Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:TAN W/SOLVENT ODOR Percent Volatiles by Volume:50-55% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, PILOT LIGHTS, & ALL OTHER SOURCES OF IGNITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. DON'T FLUSH ADHESIVE DOWN DRAINS. FLAMMABLE, DOT UN1133.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:70203 MORPHOLINE CAGE:5H062 CAGE:0F8M0 CAGE:0LNB7 CAGE:5H062 ============= Composition/Information on Ingredients ============= Ingred Name:MORPHOLINE CAS:110-91-8 RTECS #:QD6475000 Fraction by Wt: 100.00% Other REC Limits:NONE SPECIFIED OSHA PEL:S,20 PPM/30 STEL ACGIH TLV:S, 20 PPM; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1050 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: PRODUCT IS SEVERELY IRRITATING TO CORROSIVE TO ALL BODY TISSUES, PARTICULARLY TO MUCOUS MEMBRANES. PROLONGED OR REPEATED CONTACT MAY CAUSE IT TO BE ABSORBED THROUGH THE SKIN IN HARMFUL QUANTITI ES, AND IT CONTAINS AMINES WHICH MAY CAUSE TRANSITORY BLURRED VISION. CHRONIC: DERMATITIS AND/OR LUNG DAMAGE. Explanation of Carcinogenicity:DO NOT ADD NITRATES TO PRODUCT. IT CONTAINS AMINES WHICH MAY REACT TO FORM CARCINOGENIC NITROSOAMINES. Effects of Overexposure:EYE IRRITATION,REDNESS,SWELLING,BURNS & EYE DAMAGE.SEVERE SKIN IRRITATION,BURNS,BLISTER & TISSUE DESTRUCTION.INHALATION MAY CAUSE IRRITATION,COUGHING,PAIN IN EYES,NOSE,THROAT & CHEST,HEADACHE, NAUSEA, VOMITING,DROWSINESS.MAY CAUSE LUNG DAMAGE.ORAL:BURNING IN MOUTH, THROAT & STOMACH.ABDOMINAL & CHEST PAIN.VOMITING,DIARRH Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING RESPIRATORY CONDITIONS, SUCH AS ASTHMA, BRONCHITIS AND INFLAMMATORY OR FIBROTIC RESPIRATORY DISEASE. MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IN ALL CASES.INHALED: REMOVE TO FRESH AIR.PROVIDE CPR/OXYGEN IF NEEDED.EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES.HOLD EYELIDS OPEN.ORAL:DO NOT INDUCE VOMITING.IF CONSCIOUS, DRINK TWO GLASSES OF WATER.NOTE TO PHYSICIAN:SWALLOWING MAY RESULT IN SEVERE ULCERATION & POSSIBLE PERFORATION.ASPIRATION CAN CAUSE LUNG INJURY. GASTRIC LAVAGE USING ENDOTRACHEAL INTUBATION IS RECOMMENDED. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:95.0F,35.0C Autoignition Temp:Autoignition Temp Text:590F Lower Limits:1.8 Upper Limits:10.8 Extinguishing Media:CARBON DIOXIDE, FOAM OR DRY CHEMICAL. WATER MAY BE INEFFECTIVE ON FLAMES BUT SHOULD BE USED TO COOL FIRE EXPOSED CONTAIN Fire Fighting Procedures:IF LEAK HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE VAPORS AND TO PROTECT PERSONNEL ATTEMPTING TO STOP LEAK. Unusual Fire/Explosion Hazard:DANGER! VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. EXPLOSIVE AIR-VAPOR MIXTURES MAY FORM. CONTAINERS MAY EXPLODE IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. EVACUATE UNNEEDED PERSONNEL. STAY UPWIND AND WARN OF EXPLOSION HAZARD. USE SCBA & AVOID SKIN/CLOTHING CONTACT. CONTAIN SPILL IF POSSIBLE. REMOVE WITH INE RT ABSORBENT. PREVENT ENTRY TO SEWERS &WATERWAYS. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY SUPPLIER ======================Handling and Storage ====================== Handling and Storage Precautions:TRANSPORT, HANDLE AND STORE PER OSHA 1910.106 AND DOT REGS. GROUND CONTAINERS WHEN TRANSFERRING LIQUID. USE SPARK-PROOF TOOLS. Other Precautions:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VAPOR, DUST OR MIST IS GENERATED, USE RESPIRATOR APPROVED BY NIOSH AS APPROPRIATE. USE SCBA WHEN CLEANING LARGE SPILLS OR FOR ENTRY TO TANKS, VESSELS OR OTHER CONFINED SPACE. Ventilation:ADEQUUATE TO MEET OCCUPATIONAL LIMITS. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,PLUS UNIFORMS, COVERALLS, OR LAB COATS MUST BE WORN. IMPERVIOUS SUITE FOR LG QUANTITY Work Hygienic Practices:MFR DID NOT ADDRESS THIS FIELD. USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY AFTER USE Supplemental Safety and Health 'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR. TREAT THEM WITH THE RESPECT DUE FULL ONES. DO NOT CUT,WELD,ETC. ON THEM. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:263F,128C Vapor Pres:7 MM Vapor Density:3.0 Spec Gravity:1.0017 pH:11.2 Viscosity:2.23 CP @ 20C Solubility in Water:APPRECIABLE Appearance and Odor:CLEAR, COLORLESS LIQUID - AMMONIA ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS, NITRATES Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:TOXIC LEVELS OF AMMONIA, COMBUSTION PRODUCTS OF NITROGEN, CARBON MONOXIDE, IRRITATING ALDEHYDES AND KETONES Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT HAS THE RCRA CHARACTERISTICS OF IGNITIBILITY WITH THE RCRA WASTE NUMBER OF D001. USER HAS RESPONSIBILITY TO DETERMINE AT TIME OF DISPOSAL IF THE PRODUCT MEETS THE RCRA DEFINITION OF A HAZ ARDOUS WASTE. CLASSIFICATION MAY CHANGEWITH USE.
1
eyes_protection_mandatory
======================================================= Product ID: EP-H CARTIRDGE MAGENTA (RED), F74-3018-150 Cage: 1BA63 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 08YZ7 Cage: 1BA63 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL RAT): > 5,000 MG/KG. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: INHAL/SKIN: EXPECTED TO BE LOW HAZ FOR REC HNDLG. EYES: NO SPECIFIC HAZS KNOWN. MAY CAUSE TRANSIENT IRRIT. INGEST: EXPECTED TO BE LOW INGEST HAZ. CHRONIC: BASED UPON AVAIL DATA, HUMAN EXPOS TO TONER HAS BEEN SHOWN TO CAUSE MIN RESP TRACT IRRIT AS MAY OCCUR W/LGE AMTS OF ANY NON-TOX DUSTS. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: RSLTS OF 1 ANIMAL STUDY WHERE RATS INHALED TONER THAT WAS 10 TIMES MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER WERE OBSERVED TO HAVE SLIGHT DEGREE OF LUNG FIBROSIS AT HIGH LEVELS, DUE TO E XCESS AMTS OF DUST RETAINED IN LUNGS FOR PRLNG INTERVAL. MUTAGENICITY: SALMONELLA TYPHIMURIUM ASSAY (AMES TEST): NEG. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NO TONER SPILLAGE OCCURS IN NORM OPERATION/HNDLG. IF IT SHOULD OCCUR, AVOID INHAL OF DUST. SWEEP MATL ONTO PAPER & DISPOSE COLLECTED TONER AS PLASTIC WASTE. IN SPILL SITUATION THIS MATL MAY BE VISUALL Y UNPLEASANT, HOWEVER, IT IS NOT EXPECTED(SUP DAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATE OR LANDFILL. CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL REGULATIONS. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE, OR LOCAL LAWS. CARTRIDGE MAY BE DISPOSED OF AS PLASTIC WASTE. Handling And Storage Precautions: AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. MINIMIZE DUST GENERATION AND ACCUMULATION. Other Precautions: REFER TO PAMPHLET # 654, "PREVENTION OF FIRE AND DUST EXPLOSIONS IN THE CHEMICAL, DYE, PHARMACEUTICAL AND PLASTICS INDUSTRIES". USE ADEQUATE VENTILATION. STORE IN A COOL PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CARBON DIOXIDE (CO*2), DRY CHEMICAL. Fire Fighting Procedures: NONE. WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NON-FLAMMABLE SOLID (ACCORDING TO TEST METHOD OF 16 CFR 1500.44). TONER MATL, LIKE MOST ORGANIC MATL IN POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE REQUIRED WHEN USED IN INTENDED FASHION. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES/HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. GOOD INDUSTRIAL HYGIENE PRACTICE SHOULD BE FOLLOWED WHICH INCLUDES PREVENTING (SUP DAT) Supplemental Safety and Health: SPILL PROC: TO CAUSE ANY ADVERSE ENVIRONMENTAL EFFECTS. HYGIENE PRACTICES: EYE CONTACT, MINIMIZING SKIN CONTACT AND INHALATION. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >212F,>100C Spec Gravity: 1.0-1.4(H*2O=1) Solubility in Water: NEGLIGIBLE Appearance and Odor: RED (MAGENTA) FINE POWDER WITH TYPICAL PLASTIC ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: COMBUSTION WILL PRODUCE CARBON DIOXIDE, AND CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: EP-H CARTIRDGE MAGENTA (RED), F74-3018-150 Cage: 1BA63 Company Name: CANON USA INC Street: ONE CANON PLAZA Zipcode: 11042 Label Required IND: Y Date Of Label Review: 06/29/1998 Status Code: C Label Date: 06/29/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION/SKIN: LOW HAZARD. EYES: MAY CAUSE TRANSIENT IRRITATION. INGESTION: LOW HAZARD. CHRONIC: MINIMAL RESPIRATORY TRACT IRRITATION. POSSIBLE LUNG FIBROSIS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:23F50 CAGE:JO842 CAGE:24446 CAGE:JO842 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CRONASOLV F22 FLUX CAGE:67292 CAGE:67292 ============= Composition/Information on Ingredients ============= Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: 51-100% OSHA PEL:10 MG BORATES/M3 ACGIH TLV:5 MG BORATES/M3 Ingred Name:SODIUM CARBONATE (2:1); (SODA ASH) CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 31-60% OSHA PEL:10 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:SUPDAT:TIN, LEAD, SILVER, ZINC/CADMIUM WHEN PRESENT. GASEOUS REACTION (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:PRODS MAY INCL CARBON MONOXIDE & CARBON DIOXIDE. ONE REC WAY TO DETERM THE COMPOSITION & QTY OF FUMES & (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE WELDER'S HELMET, IF WORN/IN WORKER'S (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:BRTHG ZONE. SEE ANSI/AWS F1.1, AVAIL FROM THE AMERICAN WELDING SOCIETY. FOR MORE SPECIFIC INFO CNTCT NEHC . RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:DEPOSITS IN THE LUNGS) & IS BELIEVED BY SOME INVESTIGATORS TO AFFECT PULM FUNCTION. LONG TERM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:INHAL OF LEAD FUMES/INGEST OF LEAD MAY LEAD TO LEAD POISONING W/SYMPS SUCH AS METALLIC TASTE, ABDOMINAL (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:PAIN, NAUSEA, JOINT/MUSCLE PAIN/WEAK, POSS WEIGHT LOSS, MENTAL CONFUSION, ANEMIA & A "LEAD LINE" ON GUMS.(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CHRONIC FLUORIDE ABSORPTION CAN RSLT IN INCR RADIOGRAPHIC DENSITY OF THE BONES & MOTTLING OF TEETH. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC RTECS #:9999999ZZ Ingred Name:VENT:AREA. TRAIN THE WELDER TO KEEP HIS HEAD OUT OF THE FUMES. RTECS #:9999999ZZ Ingred Name:EYE PROT:. HELMET/USE FACE SHIELD W/FILTER LENS. START W/SHADE WHICH IS TOO DARK TO SEE WORK AREA. THEN (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WORK AREA. WHEN WORKING W/FLUXES & ALLOYS, (ING 16) RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:& ELECTRIAL SHOCK. MAY INCLUDE ARMS PROTECTION, APRONS, HATS, SHOULDER PROTECTION, AS WELL AS (ING 18) RTECS #:9999999ZZ APRONS. TRAIN NOT TO TOUCH HOT METALS/LIVE (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:ELECTRICAL PARTS & TO INSULATE HIMSELF FROM WORK AND GROUND. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. ACUTE:OVEREXP TO WELDING/BRAZING FUMES MAY RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS/DRYNESS/IRRIT OF NOSE, THROAT/EYES. INHAL:FUMES FROM FLUX MAY CAUSE IRRIT TO RESP SYS, SALIVATION, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CHOKING & CHILLS. SKIN CNTCT:FLUXES MAY CAUSE IRRIT/MINOR BURNS TO SKIN. EYE CNTCT:FLUXES MAY CAUSE IRRIT TO EYES & POSS BURNS OF EYE SURFS. INGEST:FLUXES CAN CAUSE SEV DMG TO DIGEST SYS & PO ISONING. SWALLOWING LRG AMTS COULD BE FATAL, DO NOT INGEST. CHRONIC:OVEREXP MAY LEAD TO SIDEROSIS (IRON (ING 7) Medical Cond Aggravated by Exposure:MAY AGGRAVATE LUNG, KIDNEY OR LIVER AILMENTS. RESPIRATORY OR ALLERGIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECD BY THE AMERICAN RED CROSS. INHAL:REMOVE FROM AREA OF EXPOS TO LOCATION W/FRESH AIR. SKIN:WASH AFFECTED AREAS W/SOAP & H*2O. EYE:FLUSH W/H*2O FORAT LEAST 15 MIN. SEEK MED AID. INGEST:GIVE LARGE QTIES OF H*2O/MILK TO DILUTE. DO NOT INDUCE VOMIT. SEEK MED AID. CALL POISON CONTROL CENTER AT ONCE. ADVISE OF INGREDIENTS FROM INGREDIENT SECTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, WATER, CO*2. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . FLUXES MAY GIVE OFF AMMONIA, HYDROFLUORIC ACID & BORON TRIFLUORIDE FUMES UPON DECOMP AT THIGH TEMPERATURES. Unusual Fire/Explosion Hazard:NON-FLAMM:FUEL GAS TORCHES & SOLDERING IRONS USED FOR WELDING, BRAZING & SOLDERING CAN IGNITE COMBUST. REFER TO ANS Z49.1 FOR FIRE PREVENTION DURING WELDING. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SPILLED MATERIAL FOR RECLAMATION OR DISPOSAL IN SEALED CONTAINERS. AVOID INHALATION OF DUST. REMOVE SOURCES OF HEAT OR IGNITION. KEEP AIRBORNE DUST AT A MINIMUM WHEN CLEANING UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, AVOIDING CONTACT WITH EXTREME HEAT TO MAINTAIN PRODUCT QUALITY. DO NOT STORE IN GLASS OR PORCELAIN CONTAINERS. Other Precautions:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. USE GOOD HOUSEKEEPING PRACTICES TO PREVENT ACCUMULATIONS OF DUST OR FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUMES RESPIRATOR OR NIOSH APPROVED AIR SUPPLIED RESPIRATOR WHEN WELDING, BRAZING OR SOLDERING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENT, LOC EXHST/BOTH AT WORK AREA TO KEEP FUMES & GASES BELOW TLV'S IN WORKER'S BRTHG ZONE & GENERAL (ING 13) Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . WEAR PROT WHICH HELP PVNT INJURY FROM RADIATION, SPARKS, HEAT (ING 17) Work Hygienic Practices:WASH HANDS AFTER HANDLING. DO NOT SMOKE, EAT OR DRINK IN WORK AREA. Supplemental Safety and Health MATLS TO AVOID:ACETYLENE GAS, AMMONIA & HYDROGEN PEROXIDE. WHILE SOLDERING/BRAZING, MOLTEN ALLOYS MAY REACT VIOLENTLY W/H*2O. HAZ DECOMP PROD:INCL FLUORIDES & COMPLEX OXIDES OF INGREDS. DECOMP PROD CO ULD INCL FUMES OF AMMONIA, HYDROFLUORICACID, BORON TRIFLUORIDE GASES, & TOX FUMES OF ORG/INORGANIC CMPDS OF (ING 3) ================== Physical/Chemical Properties ================== Spec Gravity:3.1 (H*2O = 1) Evaporation Rate & Reference:0.5 (H*2O = 1) Solubility in Water:98% Appearance and Odor:PINK POWDER; VERY LITTLE ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FLUXES & BRAZING & SOLDERING ALLOYS MAY BE INCOMPAT W/STRONG ACIDS, BASES, CYANIDES, SULFIDES, OXIDERS, (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING, BRAZING & SOLDERING FUMES CANNOT BE CLASSIFIED SIMPLY. REASONABLY EXPECTED FUME CONSTITUENTS WOULD (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE A ND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IPS EMPRESS WAX Preparer's Name:LLOYD ZIEMENDORF CAGE:0T2N6 CAGE:0T2N6 ============= Composition/Information on Ingredients ============= Ingred Name:PARAFFIN WAX FUME, PARAFFIN CAS:8002-74-2 RTECS #:RV0350000 Fraction by Wt: 60-100% ACGIH TLV:2 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BURNS FROM HOT WAX. Explanation of Carcinogenicity:NONE Effects of Overexposure:BURNS FROM HOT WAX. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: IMMERSE IN COLD WATER, REMOVE HARDENED WAX CAREFULLY. OBT AIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:788F Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:DON'T USE WATER ON BURNING WAX. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT FOR NORMAL DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY AREA. Other Precautions:AVOID DIRECT CONTACT W/HOT WAXES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REQUIRED IF TLV IS EXCEEDED. Ventilation:ADEQUATE GENERAL/LOCAL Supplemental Safety and Health IVOCLAR NORTH AMERICA INC BOUGHT OUT WILLIAM DENTAL INC ABOUT 9-10 YEARS AGO. PER JACKIE SACCO ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>649.4F Melt/Freeze Pt:M.P/F.P Text:122-134.6 Spec Gravity:-0.8-0.9 Appearance and Odor:COLORED WAXES, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS Hazardous Decomposition Products:ACID SMOKE FROM COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1450,RED LITHIUM GREASE CAGE:27674 CAGE:27674 ============= Composition/Information on Ingredients ============= Ingred Name:GREASE Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT AVAILABLE Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MFR STATES THAT NO ADVERSE HEALTH EFFECTS ARE EXPECTED IN RECOMMENDED USE. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:MFR STATES THAT THERE ARE NO KNOWN EFFECTS FROM OVEREXPOSURE,BUT EXPOSURE SHOULD BE KEPT AT A MINIMUM. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.APPLY SKIN CREAM WITH LANOLIN.GETMEDICAL ATTENTION IF IRRITATION PERSISTS.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET PROMPT MEDICAL ATTENTION.I NHAL:REMOVE TO FRESH AIR.GIVE OXYGEN ORARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE PLENTY OF WATER TO DRINK. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:430F,221C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP EXCESS GREASE. CLEAN AREA WITH DETERGENT SOLUTION AND RINSE WELL WITH WATER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 40-120F WITH ADEQUATE VENTILATION. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP OUT OF EYES.KEEP AWAY FROM CHILDREN. Other Precautions:MINIMIZE SKIN CONTACT. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES (SHOES) THAT CAN NOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS. RESPIRATORY PROTECTION NOT ORDINARILY R EQUIRED. Ventilation:USE GENERAL DILUTION VENTILATION. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health DO NOT GET IN EYES OR ON CLOTHING. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:700F,371C Spec Gravity:0.89 Solubility in Water:NIL Appearance and Odor:RED SEMI-SOLID WITH A BLAND ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:H-D MOTORCYCLE OIL SAE 20W50, H-D 99820 SP Preparer's Name:JOANNE HOUCK CAGE:78628 CAGE:78628 CAGE:8X531 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETRO DISTILS, SOLVENT-REFINED (SEVERE) HEAVY PARAFFINIC; (SEVERELY SOLV REFINED HEAVY PARAFFINC PETRO OIL) CAS:64741-88-4 RTECS #:PY8040501 Fraction by Wt: 60-75% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:STYRENE COPOLYMERS ;(STYRENE/ETHYLENE-PROPYLENE COPOLYMER (HYDROGENATED)) Fraction by Wt: 0-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYISOBUTENYL SUCCINIMIDE/AMIDE CAS:67762-80-5 Fraction by Wt: 2-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MAGNESIUM SULFONATE; (MAGNESIUM PETROLEUM SULFONATE) CAS:61789-87-5 Fraction by Wt: 0-2% OSHA PEL:5 MG/M3, C (MG) ACGIH TLV:10 MG/M3 (MG) Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1); (ZINC DIALKYL DITHIOPHOSPHATE) (ZDDP) CAS:68649-42-3 Fraction by Wt: 1.35% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM PHENATE CAS:72162-32-4 Fraction by Wt: 2-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PROPENOIC ACID, 2-METHYL-, EICOSYL ESTER, POLYMER; (ACRYLIC COPOLYMER) CAS:68171-46-0 Fraction by Wt: 0-1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:SEEN IN RATS. SUPPLIER BELIEVES THERE IS NO RISK OF HUMAN MALE REPRO IMPAIRMENT FROM EXPOS. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DISPOSAL SERVICE. RTECS #:9999999ZZ Ingred Name:RESP PROT:FULL-FACE AIR PURIFYING RESP WITH DUST/MIST FILTERS/HEPA FILTER CARTRIDGES IS ACCEPT TO 50 TIMES EXPOS(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:LIM. PROT BY AIR PURIFYING RESPS IS LTD. USE POS PRESS-DEMAND FULL-FACE SUPPLIED AIR RESP/SCBA FOR EXPOS (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:>50X EXPOS LIM. IF EXPOS IS ABOVE IDLH (IMMED DANGEROUS TO LIFE & HLTH) OR THERE IS POSSIBILITY OF AN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:UNCONTROLLED RELS/EXPOS LEVELS ARE UNKNOWN THEN USE POS PRESS-DEMAND FULL-FACE SUPPLIED AIR RESP W/ESCAPE(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:BOTTLE OR SCBA. RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:RESIST CLTHG. FOLLOWING MATLS ARE ACCEPT AS PROT CLTHG MATLS: POLYVINYL ALCOHOL (PVA); (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:POLYVINYL CHLORIDE (PVC); NEOPRENE; NITRILE; VITON; POLYURETHANE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL) >15 G/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NOT EXPECTED TO CAUSE SEV EMER HAZ. INHAL:NO EFTS EXPECTED. LOW ACUTE TOX. SKIN:PRACTICALLY NON-TOXIC IF ABSORBED. MAY CAUSE MILD TO MOD IRRIT W/PRLNG OR RPTD CONT. EYE:CONT MAY CAUSE MILD IRRIT. INGE ST:PRACTICALLY NON-TOXIC. CAUT! PRLNG/RPTD CONT W/USED MOTOR OIL MAY BE HARMFUL TO SKIN & COULD CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:SKIN CANCER. TOX INFO:MAGNESIUM PETRO SULFONATE:IN ANIMAL STUDIES, OTHER METAL SULFONATES CAUSED SKIN IRRIT & ALLERGIC RXNS; NO EVID IN HUMANS OF SIMILAR EFTS. ZINC DIALKYL DITHIOPHOSPHATE:IN HAL:TOX HYDROGEN SULFIDE IS GENERATED WHEN HEATED >155F. THIS CAN CAUSE RESP COLLAPSE, COMA & DEATH. SKIN:PRLNG/(SUPDAT) Medical Cond Aggravated by Exposure:SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE PERSON TO FRESH AIR. SKIN:WASH W/SOAP & WATER UNTIL NO ODOR REMAINS. WASH CLOTHING BEFORE REUSE. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, OBTAIN MED ASSISTANCE. I NGEST:INDUCTION OF VOMITING NOT REQUIRED. OBTAIN EMERGENCY MEDICAL ATTENTION. SMALL AMOUNTS WHICH ACCIDENTALLY ENTER MOUTH SHOULD BE RINSED OUT UNTIL TASTE OF IT IS GONE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>400F,>204C Extinguishing Media:WATER SPRAY, REGULAR FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CAN BE MADE TO BURN (FLASH POINT GREATER THAN 200F). ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. ADVISE EPA; STATE AGENCY IF REQUIRED. ABSORB ON INERT MATERIAL SHOVEL, SWEEP OR VACUUM SPILL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NFPA CLASS IIIB STORAGE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONC-IN-AIR DETERMINES PROT NEEDED. USE ONLY NIOSH APPRVD RESP PROT. RESP PROT USUALLY NOT NEEDED UNLESS PROD IS HEATED/MISTED. HALF-MASK AIR PURIFYING RESP W/DUST/MIST FILTERS/HEPA FILTER CARTRIDGES IS ACCEPT TO 10 TIMES EXPOS LIM.(ING 10) Ventilation:VENTILATE AS NEEDED TO COMPLY W/EXPOSURE LIMIT. GENERAL DILUTION VENTILATION ACCEPTABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . IF CONT IS UNAVOIDABLE, WEAR CHEM (ING 16) Work Hygienic Practices:WASH THOROUGHTLY AFTER HANDLING. PROMPTLY WASH AFFECTED AREA W/SOAP & WATER. LAUNDER SOILED CLOTHES. Supplemental Safety and Health VP:<0.0001 @ 20C. EVAP RATE:1000X SLOWER (ETHYL ETHER=1). EFTS OF OVEREXP:RPTD CONT MAY CAUSE MOD IRRIT, REDNESS, DRYING, CRACKING, DERM. EYES:IRRIT. INGEST:HARMFUL IF SWALLOWED. CALCIUM PHENATE:SKIN: IRRIT. AFTER DAILY HIGH DOSE APPLICATIONS IN MALE RABBITS, TESTICLES FAILED TO MATURE NORMALLY. THIS EFT WAS NOT (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:WIDE RANGE Vapor Pres:SUPP DATA Spec Gravity:0.88 (H*2O=1) Evaporation Rate & Reference:SUPP DATA Solubility in Water:NIL Appearance and Odor:DARK FLUID; SLIGHT ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON MONOXIDE & ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW FEDERAL, STATE & LOCAL REGULATIONS. NOT A RCRA HAZARDOUS WASTE IF UNCONTAMINATED. IF "USED", RCRA CRITERIA (IGNITABILITY, REACTIVITY, CORROSIVITY, TOX CHARACTS) MUST BE DETERMINED. DO NOT FLUSH TO DRAIN/STORM SEWER. CONTRACT TO AUTH(ING 9)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:00202 OPEN CHAIN&LT OIL LUB CAGE:09800 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 10% Other REC Limits:1000PPM OSHA PEL: ACGIH TLV:800PPM Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10% Other REC Limits:1000PPM OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NA Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE,ALSO KIDNEY AND LIVER DAMAGE. Explanation of Carcinogenicity:NA Effects of Overexposure:IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC. IRRITANT TO SKIN AND UPPER RESPIRATORY SYSTEM.OVEREXPOSURE MAY RESULT IN LIGHT-HEADEDNESS, STAGGERING GAIT,GIDDINESS AND POSSIBLE NAUSEA . HARMFUL OR FATAL IF SWALLOWED. Medical Cond Aggravated by Exposure:NONE ESTABLISHED (MFG) ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR,SUPPORT BREATHING.EYES:FLUSH WITH WATER FOR AT LEAST 15 MIN.SKIN WASH WITH SOAP AND WATER.INGEST:GET MEDICAL ATTENTION,DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:<20F.-6.67C Lower Limits:1.8&2.3 Extinguishing Media:CO*2,DRY CHEMICAL,FOAM. Fire Fighting Procedures:H*2O MAY BE INEFFECTIVE.H*2O MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DO NOT SPRAY NEAR OPEN FLAME. KEEP AT ROOM TEMP. AS EXPOSURE TO DIRECT SUNLIGHT OR OTHER HEAT MAY CAUSE BURSTING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE. AVOID BREATHING VAPORS AND REMOVE WITH INERT ABSORBENT.(MFG)NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Neutralizing Agent:NA ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. KEEP AT ROOM TEMPERATURE AS EXPOSURE TO DIRECT SUNLIGHT OR HEAT MAY CAUSE BURSTING. Other Precautions:KEEP AWAY FROM CHILDREN.DO NOT PUNCTURE OR INCINERATE. DO NOT SPRAY INTO OPEN FLAME OR FIRE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATHING OF VAPORS OR SPRAY MIST.(MFG) NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN.. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP TLV & LEL BELOW STATED LIMITS. Other Protective Equipment:NONE Work Hygienic Practices:OBSERVE GOOD HYGIENIC WORK PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0.0F Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NA Vapor Density:>AIR Evaporation Rate & Reference:FASTER THAN ETHER Solubility in Water:NA Appearance and Odor:AEROSOL Percent Volatiles by Volume:20 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE (MFG) Stability Condition to Avoid:DO NOT STORE ABOVE 120F(48C) Hazardous Decomposition Products:CO, CO*2 Conditions to Avoid Polymerization:WILL NOT OCCUR (MFG) ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE-DISPOSE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SEALER #8551 CAGE:76381 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 44% OSHA PEL:100 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 11% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:MAY IRRITATE EYES,SKIN & UPPER RESPIRATORY STSTEM.BREATHING CONCENTRATED VAPORS MAY CAUSE NARCOSIS ======================= First Aid Measures ======================= First Aid:EYE-FLUSH WITH PLENTY OF WATER;GET MEDICAL AID.SKIN-WASH WITH SOAP & WATER. INHALATION-PROVIDE FRESH AIR.INGESTION-DO NOT INDUCE VOMITING.CALL A PHYSICIAN ===================== Fire Fighting Measures ===================== Flash Point:40F,4.4C TCC Lower Limits:1.0 Upper Limits:7.0 Extinguishing Media:CO*2,FOAM, DRY CHEMICAL Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:EXTINGUISH ALL IGNITION SOURCES,COLLECT SPILLED MATERIAL.CLEAN UP RESIDUE ======================Handling and Storage ====================== Handling and Storage Precautions:EXTREMELY FLAMMABLE. KEEP AWAY FROM ALL SOURCES OF IGNITION.USE ONLY IN WELL VENTILATED AREAS.AVOID EYE CONTACT AND PROLONGED BREATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:230F,110C Vapor Pres:25 Vapor Density:3.2 Spec Gravity:0.85 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR LIQUID-ODOR OF NAPHTHA Percent Volatiles by Volume:55 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERTE PROPERLY-DO NOT LANDFILL
1
eyes_protection_mandatory
======================================================= NIIN: 01-081-6307 Product ID: SCOTCH-WELD AF-126 STRUCTURAL ADHESIVE FILM Cage: 0F0U5 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 04963 Cage: 0F0U5 Country: UK ======================================================= Item Description Information ======================================================= Item Name: PRIMER ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE:MILD IRRIT. SIGNS/SYMPS CAN INCLUDE REDNESS, SWELLING, PAIN & TEARING. VAPS FROM HEATED MATL MAY CAUSE IRRIT. DUST CREATED BY CUTTING, GRINDING, SANDING/MACHINING MAY CAUSE IRRIT. SKIN:ALLERGIC RX N. SIGNS/SYMPS CAN INCLUDE REDNESS, SWELLING, BLISTERING & ITCHING. MILD IRRIT (AFTER PRLNG/RPTD CONT).(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:SIGNS/SYMPS CAN INCLUDE REDNESS, SWELLING & ITCHING. INHAL:VAPS OF HEATED MATL MAY CAUSE RESP SYS IRRIT. DUST FROM CUTTING, GRINDING, SANDING/MACHINING MAY CAUSE IRRIT OF RESP SYS. INGEST:MAY CAUSE IRRIT OF GI TISS. SIGNS/SYMPS CAN INCLUDE PAIN, VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS/FECES. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE:IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN:FLUSH W/LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHAL:REMOV E PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL MD. INGEST:DO NOT INDUCE VOMITING. DRINK TWO GLASSES OF WATER. CALL MD. ======================================================= Handling and Disposal ======================================================= Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATE UNCURED WASTE IN INDUSTRIAL OR COMMERCIAL INCINERATOR. DISPOSE OF COMPLETELY CURED (OR POLYMERIZED) MATL IN SANITARY LANDFILL. SINCE REGS VARY, CONSULT APPLICABLE FEDERAL, STATE & LOCAL REG S OR AUTHORITIES BEFORE DISPOSAL. Handling And Storage Precautions: STORE AT ROOM TEMPS WHICH ARE <32F (0C). ALLOW MATL TO RETURN TO ROOM TEMP BEFORE USE. KEEP OUT OF REACH OF CHILDREN. AVOID SKIN CONTACT. Other Precautions: AVOID INHAL OF VAPS CREATED DURING CURE CYCLE. AVOID INHAL OF DUST CREATED BY CUTTING, SANDING/GRINDING. USE WATER AS LUBRICANT ON MACHINING TOOLS TO ELIM DUST & IMPROVE MACHINABILITY OF CURED PARTS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). ======================================================= Control Measures ======================================================= Respiratory Protection: SELECT FOLLOWING NIOSH/MSHA APPROVED RESPIRATOR BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS & I/A/W OSHA REGS:HALF-MASK DUST RESPIRATOR. Ventilation: USE W/APPROP LOC EXHST VENT. PROVIDE APPROP LOC EXHST FOR GRINDING, CUTTING/SANDING CURED MATL. CURING OVENS (SUPDAT) Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED AREAS THOROUGHLY W/SOAP & WATER. Supplemental Safety and Health: VENT:MUST BE EXHSTED TO OUTDOORS/TO SUITABLE EMISSION CONTROL DEVICE. IF EXHST VENT IS NOT ADEQ, USE APPROP NIOSH/MSHA ======================================================= Physical/Chemical Properties ======================================================= Solubility in Water: NOT SOLUBLE Appearance and Odor: FILM, ESSENTIALLY NO ODOR. Percent Volatiles by Volume: 0 (WT) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: CARBON MONOXIDE & CARBON DIOXIDE, OXIDES OF NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 105854 Product ID: SCOTCH-WELD AF-126 STRUCTURAL ADHESIVE FILM Review Date: 05/04/1993 Multiple KIT Number: 0 Review IND: Y Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: SCOTCH-WELD AF-126 STRUCTURAL ADHESIVE FILM Cage: 0F0U5 Company Name: PACEBROOK LTD Street: 15 GOSDITCH ST Zipcode: 00000 Country: UK Label Required IND: Y Date Of Label Review: 11/10/1992 Status Code: C Label Date: 11/10/1992 Origination Code: G Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:EYE:MILD IRRITATION. REDNESS, SWELLING, PAIN & TEARING. SKIN:ALLERGIC REACTION. MILD IRRITATION (AFTER PROLONGED OR REPEATED CONTACT). REDNESS, SWELLING & ITCHING. INHAL:VAPORS OF HEATED MATERIA L MAY CAUSE RESPIRATORY SYSTEM IRRITATION. DUST FROM CUTTING, GRINDING, SANDING OR MACHINING MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM. INGEST:MAY CAUSE IRRITATION OF GI TISSUE. SIGNS OR SYMPTOMS CAN INCLUDE PAIN, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS OR FECES. AVOID INHALATION OF VAPORS CREATED DURING CURE CYCLE & DUSTS CREATED DURING CUTTING, SANDING & GRINDING. CHRONIC:NONELISTED BY MANFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:UREASE CAGE:GO448 CAGE:GO448 ============= Composition/Information on Ingredients ============= Ingred Name:UREASE CAS:9002-13-5 RTECS #:YU1700000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE INDIVIDUALS MAY DEVELOP. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS. Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL. USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR DUST MASK. Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN. Supplemental Safety and Health SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE. ================== Physical/Chemical Properties ================== Solubility in Water:(SEE SUPP) Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH HAVE TYPICAL ENZYME ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMOSITE CAGE:DO501 CAGE:DO501 CAGE:0G9K0 ============= Composition/Information on Ingredients ============= Ingred Name:AMOSITE (CONFIRMED CARCINOGEN BY ACGIH, IARC, OSHA & NTP) GROUP 1 BY IARC *94-2* CAS:12172-73-5 RTECS #:CI6477000 Fraction by Wt: 100% ACGIH TLV:O.5 MG/CUM (A1) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: MAY CAUSE COUGHING, CHEST PAIN, TUMORS. CHRONIC: IN ADDITION TO SHORT TERM EFFECTS MAY CAUSE FEVER, LACK OF APPETITE, WEIGHT LOSS, DIFFICULTY BREATHING, LUNG DAMAGE, BLUISH SKIN COLOR, WEAKNESS , HEART FAILURE, COMA & CANCER. RISK OFCANCER DEPENDS ON DURATION & LEVEL OF EXPOSURE. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:ACUTE: MAY CAUSE COUGHING, CHEST PAIN, TUMORS. CHRONIC: IN ADDITION TO SHORT TERM EFFECTS MAY CAUSE FEVER, LACK OF APPETITE, WEIGHT LOSS, DIFFICULTY BREATHING, LUNG DAMAGE, BLUISH SKIN COLOR, WEAKNESS , HEART FAILURE, COMA & CANCER. RISK OFCANCER DEPENDS ON DURATION & LEVEL OF EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. KEEP WARM & AT REST. SKIN: WASH W/SOAP/MILD DTERGENT & LARGE AMOUNTS OF WATER FOR 15-20 MINS. EYES: WASH W/LARGE AMOUNTS OF WATER/NORMAL SALINE FO R 15-20 MINS. INGESTION: IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL/CO2/WATER SPRAY/REGULAR FOAM. LARGE: WATER SPRAY/FOG/REGULAR FOAM. AGENTS SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:SCBA W/FULL FACEPIECE IN A PRESSURE-DEMAND/OTHER POSITIVE-PRESSURE MODE. MOVE CONTAINER FROM AREA W/O RISK. KEEP UPWIND. DIKE FOR LATER DISPOSAL. Unusual Fire/Explosion Hazard:DON'T SCATTER SPILLED MATERIAL W/HIGH-PRESSURE WATER STREAMS. NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT/FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:ADEQUATELY WET/MIX W/WATER TO FORM A SLURRY. SEAL MATERIAL IN A LEAK-TIGHT CONTAINER WHILE WET. LABEL CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:ASBESTOS SHALL BE HANDLED, MIXED, APPLIED, REMOVED, CUT, SCORED, OTHERWISE WORKED IN A WET STATE SUFFICIENT TO PREVENT EMISSION OF AIRBORNE FIBERS IN EXCESS OF EXPOSURE LIMITS. DON'T BREATHE DUST, GET IN EYES, ON SKIN/CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:<2 FIBERS/CC: HALF-MASK RESPIRATOR W/HEPAFILTERS. <10 FIBERS/CC: FULL FACEPIECE RESPIRATOR W/HEPA FILTERS. <20 FIBERS/CC: POWERED AIR-PURIFYING RESPIRATOR W/HEPA FILTER/SUPPLIED-AIR RESPIRATOR. Ventilation:LOCAL EXHAUST/PROCESS ENCLOSURE TO MEET PUBLISHED EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH FOUNTAIN, IMPERVIOUS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health RESPIRATION CONT'D: SPECIFIC RESPIRATOR SELECTION MUST BE BASED ON CONTAMINATION LEVELS FOUND IN WORK PLACE & NOT EXCEED WORKING LIMITS OF THE RESPIRATOR. NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE. TREA T SYSMPTOMATICALLY & SUPPORTIVELY. ================== Physical/Chemical Properties ================== Spec Gravity:3.1-3.25 Solubility in Water:INSOLUBLE Appearance and Odor:LONG, ASH GRAY, GREEN/BROWN FIBERS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES Stability Condition to Avoid:DISPERSION OF DUST IN AIR, HEAT & FLAME Hazardous Decomposition Products:TOXIC/HAZARDOUS GASES ==================== Disposal Considerations ==================== Waste Disposal Methods:AIRBORNE CONCENTRATIONS OF ASBESTOS FIBERS IN EXCESS OF THE EXPOSURE LIMITS PRESCRIBED SHALL BE COLLECTED & DISPOSED OF IN A SEALTED IMPERMEABLE BAG/CONTAINER. DISPOSE OF IAW/FEDERAL, STATE & LOCAL RE GULATIONS. UN # 2590
1
eyes_protection_mandatory
======================================================= Product ID: THREADLOCKER 243 1 LTR,21433 Cage: 05972 ======================================================= Contractor Summary ======================================================= Cage: 05972 ======================================================= Ingredients ======================================================= Cas: 18268-70-7 RTECS #: MO7710000 DIOCTANOATE % Wt: 20 - 25 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 116-14-3 RTECS #: KX4025000 % Wt: 5 - 10 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 9003-20-7 RTECS #: AK0920000 % Wt: 5 - 10 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 68611-44-9 DIOXIDE % Wt: 3 - 5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 9002-88-4 RTECS #: KX3270000 % Wt: 3 - 5 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 80-15-9 RTECS #: MX2450000 (CERCLA) % Wt: 1 - 3 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 51796-19-1 % Wt: 1 - 3 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 81-07-2 RTECS #: DE4200000 % Wt: 1 - 3 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 114-83-0 RTECS #: AJ2900000 % Wt: 0.1 - 1 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ------------------------------ Cas: 110-16-7 RTECS #: OM9625000 % Wt: 0.1 - 1 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 25852-47-5 % Wt: 60 - 65 Other REC Limits: NONE RECOMMENDED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL) IS >5,000 MG/KG. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- EYE CONTACT MAY CAUSE MILD IRRITATION. MAY CAUSE DERMATITIS ON PROLONGED SKIN CONTACT. ACUTE ORAL TOXICITY IS LOW. INHALATION IS UNLIKELY TO OC CUR AT AMBIENT TEMPERATURE. CHRONIC- UNKNOWN. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: MILD IRRITATION, HEADACHE, NAUSEA, VOMITING Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. First Aid: GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:DOES NOT APPLY. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT INDUCE VOMITING. CALL PHYSICIAN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ABSORB SPILLS WITH INERT MATERIAL SUCH AS SAND OR VERMICULITE. TRANSFER TO SUITABLE CONTAINER FOR DISPOSAL. Neutralizing Agent: NOT RELEVANT Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION IS RECOMMENDED. Handling And Storage Precautions: STORE IN CLOSED CONTAINER, AWAY FROM STRONG OXIDIZING AGENTS. Other Precautions: WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. DO NOT INHALE. DO NOT GET IN EYES OR ON SKIN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: >200F,>93C Lower Limits: UNKNOWN Upper Limits: UNKNOWN Extinguishing Media: USE CARBON DIOXIDE, FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. IRRITATING ORGANIC VAPORS MAY BE FORMED. Unusual Fire/Explosion Hazard: NONE ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NORMALLY REQUIRED. Ventilation: ADEQUATE Other Protective Equipment: EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 NRC/State LIC No: NOT RELEVANT B.P. Text: >300F,>149C M.P/F.P Text: UNKNOWN Decomp Text: UNKNOWN Vapor Pres: <0.1 @ 88F Vapor Density: UNKNOWN Spec Gravity: 1.08 Viscosity: UNKNOWN Evaporation Rate & Reference: UNKNOWN Solubility in Water: SLIGHT Appearance and Odor: BLUE LIQUID, MILD ODOR Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE Materials To Avoid: NONE Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, ORGANIC VAPORS MAY BE FORMED. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 3135 Product ID: THREADLOCKER 243 1 LTR,21433 Review Date: 04/08/1996 Radioactivity: NOT RELEVANT Net Unit Weight: UNKNOWN Multiple KIT Number: 0 Review IND: Y Container QTY: 2.5 L ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: THREADLOCKER 243 1 LTR,21433 Cage: 05972 Company Name: LOCTITE CORPORATION Street: 1001 TROUT BROOK CROSSING Zipcode: 06067-3910 Label Required IND: Y Date Of Label Review: 04/08/1996 Status Code: C MFG Label NO: UNKNOWN Label Date: 04/08/1996 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- EYE CONTACT MAY CAUSE MILD IRRITATION. MAY CAUSE DERMATITIS ON PROLONGED SKIN CONTACT. ACUTE ORAL TOXICITY IS LOW. INHALATION IS UNLIKELY TO OC CUR AT AMBIENT TEMPERATURE. CHRONIC- UNKNOWN. STORE IN CLOSED CONTAINER, AWAY FROM STRONG OXIDIZING AGENTS. IN CASE OF SPILL: ABSORB SPILLS WITH INERT MATERIAL SUCH AS SAND OR VERMICULITE. TRANSFER TO SUITABLE CONTAINER FOR DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:DOES NOT APPLY. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL :DO NOT INDUCE VOMITING. CALL PHYSICIAN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JET-MELT ADHESIVE 3792-AE CAGE:76381 DIV CAGE:52152 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE-VINYL ACETATE COPOLYMER (ACETIC ACID ETHENYL ESTER, POLYMER W/ETHENE) *96-3* CAS:24937-78-8 Fraction by Wt: 60-70% Ingred Name:HYDROCARBONS, C6-20, POLYMERS, HYDROGENATED (HYDROCARBON RE IN) *96-3* CAS:69430-35-9 Fraction by Wt: 30-40% Ingred Name:TETRAKIS (METHYLENE) 3,5-DI-TERT-BUTYL-4-HYDROXYHYDROCIN *96-3* CAS:6683-19-8 Fraction by Wt: 0.5-5% Ingred Name:VINYL ACETATE CAS:108-05-4 RTECS #:AK0875000 Other REC Limits:10 PPM ACGIH TLV:35 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. SKIN: BURNS FROM CONTACT W/MOLTEN MATERIAL. MILD IRRITATION/BLISTERS. INHALATION: IRRITATION TO UPPER RESPIRATORY. INGESTION: MAY CAUSE IRRITATION OF GASTROINTESTINAL TISSU ES. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, REDNESS, SWELLING, PAIN, TEARING, BURNS, SORENESS, COUGHING, SNEEZING, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, BLOOD IN FECES ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER. SKIN: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER & COVER W/A CLEAN DRESSING. DON'T ATTEMPT TO REMOVE ADHESIVE. INHALATION: REMOVE TO FRESH AIR. INGEST ION: DON'T INDUCE VOMITING. DRINK 2 GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>450F Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING W/HELMET, SCBA W/POSITIVE PRESSURE/PRESSURE DEMAND, BUNKER COAT/PANTS, BANDS AROUND ARMS/WAIST/LEGS, FACE MASK & HEAD COVERING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT MATERIAL. OBSERVE PRECAUTIONS FROM OTHER SECTIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID EYE CONTACT W/VAPOR, SPRAY/MIST. AVOID SKIN CONTACT W/HOT ADHESIVE & APPLICATOR TIP. AVOID PROLONGED BREATHING OF VAPORS. DON'T INGEST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REQUIRED Ventilation:PROVIDE APPROPRIATE LOCAL EXHAUST FOR MOLTN/EXTRUDED MATERIAL. USE IN A WELL VENTILATED AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.97 Solubility in Water:INSOLUBLE Appearance and Odor:WAXY SOLID, WHITE OPAQUE, SOLID ADHESIVE IN RODS, ODORLESS Percent Volatiles by Volume:0/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO, CO2, TOXIC VAPORS, GASES/PARTICULATES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE PRODUCT IN A SANITARY LANDFILL IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MODIFIED MAYER'S FROM CONGO RED KIT CAGE:0LK90 CAGE:0LK90 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID, ALUMINUM SALT (3:2), OCTADECAHYDRATE; (ALUMINUM SULFATE) CAS:7784-31-8 RTECS #:WS5697000 Fraction by Wt: 3.4% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9495 Ingred Name:HEMATOXYLIN CAS:517-28-2 RTECS #:MH7875000 Fraction by Wt: 0.4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IODIC ACID, SODIUM SALT; (SODIUM IODATE) CAS:7681-55-2 RTECS #:NN1400000 Fraction by Wt: 0.04% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 25.0% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID; (ACETIC ACID, GLACIAL) (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 8.0% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: ULCERONECROTIC LESIONS, DIARRHEA, NERVE DAMAGE. CHRONIC: NOT APPLICABLE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:PAIN IN THE MOUTH, THROAT, AND ABDOMEN. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:GIVE LARGE AMOUNTS OF MILK OR WATER. GET MEDICAL ATTENTION. EYE: FLUSH EYE WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES AND CONTACT A PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHAL ATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING AND CONTACT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER, ALCHOLIC FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH AREA WITH WATER. MOP UP. MAY USE SOAP TO PICK UP COLOR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXTREME HEAT OR COLD. DO NOT FREEZE OR BOIL. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:17.5 @ 20C Spec Gravity:1.1 Solubility in Water:COMPLETE Appearance and Odor:DARK PURPLE, SWEET, VINEGAR ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG CHEMICALS. Stability Condition to Avoid:HEAT/BRIGHT LIGHT. Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LP DECAL CAGE:65872 CAGE:65872 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:CORROSIVE. MAY BE FATAL IF SWALLOWED. AVOID CONTACT WITH EYES,SKIN OR CLOTHING ======================= First Aid Measures ======================= First Aid:INTERNAL:CALL A PHYSICIAN, DRINK MILK.RAW EGG WHITE.A TEASPOON OF MAGNESIA,CHALK OR SOAP SOFTENED WITH WATER;OR LARGE AMOUNT OF WATER. EXTERNAL:FLUSH EYES FOR 15 MIN. GET PROMPT MEDICAL CARE. SKIN SHO ULD BE WASHED GENTLY WITH SOAP & WATER."SEE SUPP." ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MFG DID NOT SPEC. Fire Fighting Procedures:MFG DID NOT SPEC. Unusual Fire/Explosion Hazard:MFG DID NOT SPEC ================== Accidental Release Measures ================== Spill Release Procedures:INADVERTENT SPILLAGE ON CLOTHING OR OTHER MATERIALS SHOULD BE THOROUGHLY RINSED WITH WATER IMMEDIATELY. ======================Handling and Storage ====================== Handling and Storage Precautions:DID NOT SPEC. Other Precautions:BEFORE USING LP DECAL IN FEDERALLY INSPECTED MEAT & POULTRY PLANT. FOOD PRODUCTS AND PACKAGING MAT'L MUST BE REMOVED FROM THE ROOM OR CAREFULLY PROTECTED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DID NOT SPEC. BY MFG. Ventilation:DID NOT SPEC. BY MFG. Other Protective Equipment:DID NOT SPEC. BY MFG. Supplemental Safety and Health STABLE FOR 1 YR UNDER NORMAL CONDITIONS. PH=1.4. FIRST AID:COVER WITH MOIST MAGNESIA OR BAKING SODA. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:U/K Vapor Pres:U/K Spec Gravity:1.5 Appearance and Odor:LIGHT GREEN, NON-DESCRIPT. CLEAR ================= Stability and Reactivity Data ================= MFG DID NOT SPEC. Stability Condition to Avoid:DID NOT SPEC. Hazardous Decomposition Products:MFG DID NOT SPEC. Conditions to Avoid Polymerization:MFG DID NOT SPEC. ==================== Disposal Considerations ==================== Waste Disposal Methods:RINSE EMPTY CONTAINER THOROUGHLY WITH WATER BEFORE DISCARDING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:14180-1 HORIZON 600 SUPER CONCENTRATE STRIPPER Preparer's Name:TERRY A MEYERS CAGE:0U826 CAGE:0U826 CAGE:32204 ============= Composition/Information on Ingredients ============= Ingred Name:2-AMINOETHANOL, ETHANOLAMINE, MONOETHANOLAMINE CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 15-25% Other REC Limits:3 PPM OSHA PEL:3 PPM ACGIH TLV:7.5 MG/CUM Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 10-20% Other REC Limits:2MG/M3 CEILING NIOSH OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM GLUCONATE CAS:527-07-1 RTECS #:LZ5235000 Fraction by Wt: 3-6% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50-60% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CAN CAUSE IRRITATION. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION. INGESTION: PRODUCT MAY CAUSE CORROSIVE DAMAGE TO MOUTH, THROAT/STOMACH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO IRRITATING EFFECTS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15-20 MINS. SKIN: REMOVE W/SOAP & WATER. INGESTION: DUE TO THE EXTREME PH OF THE PRODUCT, THE POSSIBILITY OF CORROSIVE DAMAGE TO MOUTH, THROAT & STOMACH SHOULD BE CONSIDERED IN TREATMENT. OBTAIN MEDICAL ATTENTION INALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. COOL & USE CAUTION WHEN APPROACHING/HANDLING FIRE-EXPOSED CONTAINERS. DIKE FIRE CONTROL WATER FOR LATER DISPOSAL. Unusual Fire/Explosion Hazard:CORROSIVE MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/OIL-DRI/SIMILAR INERT MATERIAL. SWEEP/SCRAPE UP & CONTAINERIZE. RINSE AFFECTED AREA THOROUGHLY W/WATER. WEAR/USE APPROPRIATE PROTECTIVE EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. PRODUCT RESIDUE MAY REMAIN ON/IN EMPTY CONTAINERS. ALL PRECAUTIONS FOR HANDLING MUST BE USED IN HANDLING EMPTY CONTAINER/RESIDUE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT OF PRODUCT W/SKIN & CLOTHING. DON'T GET IN EYES. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERAL ROOM: NORMALLY ADEQUATE. Other Protective Equipment:WEAR/USE APPROPRIATE PROTECTIVE EQUIPMENT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH: 12.7 (UNDILUTED) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F Spec Gravity:1.23 pH:(SUPP) Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID W/CITRUS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, MURIATIC ACID, CAUSTIC ALKALI. Stability Condition to Avoid:FREEZING. Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:UNDILUTED PRODUCT: DISPENSE UNDER THE RCRA AS A CORROSIVE WASTE. DISPOSE OF REGULATED QUANTITIES SHOULD BE BY NEUTRALIZATION AT A PERMITTED FACILITY IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN1760.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BFW-504 BOILER CORROSION & SCALE INHIBITOR CAGE:13091 CAGE:13091 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: <5% Other REC Limits:2 MG/CUM (CEILING) OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM (CEILING) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-DIETHYLAMINOETHANOL, DIETHYLAMINOETHANOL CAS:100-37-8 RTECS #:KK5075000 Fraction by Wt: <1% OSHA PEL:10 PPM SKIN ACGIH TLV:10 PPM SKIN Ingred Name:NON HAZARDOUS INGREDIENTS Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Other REC Limits:5 MG/CUM (DUST) Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: CAUSES SEVERE BURNS; POSSIBLE PERMANENT DAMAGE/BLINDNESS. VAPORS MAY BE IRRITATING. SKIN: IRRITATION; PROLONGED CONTACT CAN CAUSE SEVER BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL/VISIBLE. INHALA TION: SPRAY MIST/VAPOR IRRITATION. POSSIBLE DAMAGE TO MUCOUS MEMBRANES OF NOSE & THROAT. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS. Medical Cond Aggravated by Exposure:EXISTING DERMATITIS/RESPIRATORY CONDITIONS. INHALATION OF MISTS/INGESTION, CAN CAUSE SEVERE RESPIRATORY/ALLERGIC REACTION IN SULFITE-SENSITIVE INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. ASSIST BREATHING IF NEEDED. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, GIV E WATER/MILK TO DILUTE. OBTAIN MEDICAL ATTETION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SCBA. Unusual Fire/Explosion Hazard:CAN REACT W/METALS, ESPECIALLY SOFT METALS SUCH AS ALUMINUM/ZINC, TO GENERATE HYDROGEN. GAS IS FLAMMABLE/EXPLOSIVE IN PRESENCE OF AN IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: FLUSH DOWN DRAIN W/WATER. LARGE: DIKE TO PREVENT RUNOFF, RECLAIM ALL POSSIBLE. ABSORB W/INERT MATERIAL. FLUSH RESIDUE W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T GET ON SKIN/IN EYES. DON'T BREATHE STEAM/SPRAY MIST. STORE IN A COOL, DRY AREA. Other Precautions:WARNING: CONCENTRATED, CAUSTIC PRODUCT. AVOID PROLONGED/REPEATED CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IN NORMAL USE. NIOSH APPROVED DUST/MIST RESPIRATOR IF MIST IN AIR. Ventilation:WHEN USING SYSTEMS PROVIDING HUMIDIFICATION AT WORK/CONCENTRATION DIETHYLAMINOETHANOL MAYNOT EXCEED 10 PPM IN STEAM. Work Hygienic Practices:REMOVE/LAUDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health HEALTH HAZARD: INGESTION: SEVERE BURNS TO MUCOUS MEMBRANES OF MOUTH, THROAT & DIGESTIVE TRACT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:AS WATER Vapor Pres:AS WATER Vapor Density:AS WATER Spec Gravity:1.202 pH:13-14 Evaporation Rate & Reference:AS WATER Solubility in Water:COMPLETE Appearance and Odor:CLEAR DARK BROWN LIQUID W/MILD ODOR Percent Volatiles by Volume:75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ALUMINUM, ZINC, SOFT METALS, GALVANIZED METAL. Stability Condition to Avoid:NONE Hazardous Decomposition Products:HYDROGEN GAS, SULFUR DIOXIDE, NITROGEN OXIDES, CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHYLENE EATERS Preparer's Name:NOT PROVIDED CAGE:TO278 Contract Num:SP0450-01-M-D740 CAGE:0FJH7 Contract Num:SP0450-99-M-NH72 CAGE:0FJH7 CAGE:TO278 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM OXIDE/ACTIVATED ALUMINA CAS:1344-28-1 RTECS #:BD1200000 Other REC Limits:NONE OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:POTASSIUM PERMANGANATE CAS:7722-64-7 RTECS #:SD6475000 Other REC Limits:NONE OSHA PEL:C5 MG/M3 ACGIH TLV:5 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE IRRITATING TO BODY TISSUE. CHRONIC: NO KNOWN CHRONIC HEALTH HAZARDS. Explanation of Carcinogenicity:NOT CLASSIFIED BY OSHA, NTP OR IARC. Effects of Overexposure:IRRITATION OF EYES AND MUCOUS MEMBRANES, BROWN DISCOLORATION OF SKIN. Medical Cond Aggravated by Exposure:OPEN WOUNDS AND BURNS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY WASH WITH WATER FOR 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: GIVE LARGE QUANTITIES OF WATER. SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:NONE, USE RESPIRATORY PROTECTION. Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT AND OXIDIZABLE MATERIAL AND EXPLOSION HAZARDS. NONCOMBUSTIBLE, BUT WILL SUPPORT COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR SHOVEL MATERIAL AND DISCARD IN PROTECTED REFUSE CONTAINER. TO CLEAN FLOORS, FLUSH WITH WATER INTO SEWER OR ACCORDING TO LOCAL LAWS. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY PLACE. Other Precautions:NOT PROVIDED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED. Ventilation:LOCAL MECHANICAL EXHAUST RECOMMENDED IF DUSTING IS EXCESSIVE. Other Protective Equipment:REGULAR WORK CLOTHES. SAFETY SHOWER, EYE BATH AND WASHING FACILITIES SHOULD BE AVAILABLE. Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, OR USING TOILET FACILITIES. Supplemental Safety and Health ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:=2050.C, ######F Decomp Temp:Decomp Text:NOT PROVIDED Spec Gravity:3.2 pH:NOT PROVIDED Solubility in Water:PERMANGANATE COMPONENT Appearance and Odor:PURPLE BEADS Percent Volatiles by Volume:NOT PROVIDED Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, OXIDIZABLE OR REDUCING MATTER. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:CONTACT WITH HYDROCHLORIC ACID RELEASES CHLORINE GAS =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED ===================== Ecological Information ===================== Ecological:NOT PROVIDED ==================== Disposal Considerations ==================== Waste Disposal Methods:NEW MATERIAL; MAY BE DISPOSED IN LANDFILL. USED MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS GOVERNING ADSORBED CONTAMINANTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED BY DOT. ===================== Regulatory Information ===================== SARA Title III Information:NOT PROVIDED Federal Regulatory Information:NOT PROVIDED State Regulatory Information:NOT PROVIDED ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P5515 PROSTAGLANDIN E1 CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:PROSTAGLANDIN E1, CYCLOPENTANEHEPTANOIC ACID, 3-HYDROXY-2-(3-HYDROXY-1-OCTENYL)-5-OXO-, 1 *96-2* CAS:745-65-3 RTECS #:GY4569800 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 228 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED THROUGH SKIN. EYES/SKIN: IRRITATION. REPRODUCTIVE HAZARD. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, HEADACHE, VOMITING, DIARRHEA, FLUSHING, SHIVERING, DIZZINESS. ======================= First Aid Measures ======================= First Aid:INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH AREA SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE W/DESICCANT. LIGHT SENSITIVE. Other Precautions:DON'T BREAHTE DUST. PREVENT CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES Stability Condition to Avoid:LIGHT SENSITIVE Hazardous Decomposition Products:COMBUSTION: CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE/MIX W/A COMBUSTIBLE SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3CX3000FL CAGE:06980 CAGE:06980 ============= Composition/Information on Ingredients ============= Ingred Name:THORIUM 232 CAS:7440-29-1 RTECS #:XO6400000 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health SOURCE OF DATA-MIL HANDBOOK 600-1 SEP 76.SAFETY & HEALTH DATA DEVELOPED BY DGSC-STF. ================== Physical/Chemical Properties ================== HCC:A2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON MONOXIDE CAGE:HO796 CAGE:80382 CAGE:HO796 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON MONOXIDE CAS:630-08-0 RTECS #:FG3500000 Fraction by Wt: 100.000% Other REC Limits:NONE SPECIFIED OSHA PEL:50 PPM ACGIH TLV:25 PPM; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ALL THE DISORDERS ARE DUE TO MARKEDLY REDUCED CELLULAR RESPIRATION AND MAY INCLUDE CENTRAL NERVOUS SYSTEM IMPAIRMENT, CARDIOVASCULAR COLLAPSE, RENAL INSUFFICIENCY, COMA, ETC. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:DEPENDING ON LEVELS AND DURATION OF EXPOSURE, SYMPOMS MAY INCLUDE HEADACHE, DIZZINESS, HEART PALPITATIONS WEAKNESS, CONFUSION AND NAUSEA TO CONVULSIONS, EVENTUAL UNCONSCIOUSNESS AND DEATH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:CONSCIOUS PERSONS SHOULDBE ASSISTED TO AN UNCONTAMINATED AREA AND BE TREATED WITH SUPPLEMENTAL OXYGEN. QUICK REMOVAL FROM THE CONTAIMNATED AREA IS MOST IMPORTANT. UNCONSCIOUS PERSONS SHOULD BE MOVED T O AN UNCONTAIMNATED AREA AND BE GIVEN ARTIFICIAL RESPIRATION AND OXYGEN AT THE SAME TIME. THE ADMINISTERING OF OXYGEN AT ELEVATED PRESSURE HAS SHOWN TO BE BENEFICIAL AS A HYPERBARIC CHAMBER. ===================== Fire Fighting Measures ===================== Flash Point:GAS Autoignition Temp:Autoignition Temp Text:1166F Lower Limits:12.5% Upper Limits:74.0% Extinguishing Media:WATER, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:IF POSSIBLE, STOP FLOW OF GAS; USE WATER SPRAY TO COOL SURROUNDING CONTAINERS. Unusual Fire/Explosion Hazard:FLAMMABLE IN AIR OVER A VERY WIDE RANGE. IT REACTS VIOLENTLY WITH OXYGEN DIFLUORIDE AND BARIUM PEROXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM EFFECTED AREA. USE APPROPIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CONTAINER OR VALVE, CONTACT CHEMTREC FOR HELP. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT CYLINDERS FROM PHYSICAL DAMAGE. STORE IN COOL, DRY, WELL-VENTILATED AREAS AWAY FROM HEAVY TRAFFICKED AREAS & EMERGENCY EXITS. Other Precautions:DO NOT ALLOW THE TEMPERATURE WHERE CYLINDERS ARE STORED TO EXCEED 130F. CYLINDERS SHOULD BE STORED UPRIGHT AND FIRMLY SECURED. FULL AND EMPTY CONTAINERS SHOULD BE SEGREGATED. POST "NO SMOKING OR OPEN FLAMES" SIGNS IN STORAGE AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH MASK OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVALIABLE. Ventilation:HOOD WITH FORCED VENTILATION. USE LOCAL EXHAUST TO PREVENT ACCUMULATION. USE GENERAL VENTILATION IN ACCORDANCE WITH CODE Other Protective Equipment:SAFETY SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EARTH-GROUND AND BOND ALL LINES AND EQUIPMENT ASSOCIATED WITH THE CARBON MONOXIDE SYSTEM. ELECTRICAL EQUIPMENT SHOULD BE NON SPARKING OR EXPLOSION PROOF. USE ONLY IN WELL VENTILATED AREA. ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:B.P. Text:-312F,-191C Melt/Freeze Pt:M.P/F.P Text:-337F,-205C Vapor Pres:>220.4 Spec Gravity:0.96 Solubility in Water:SLIGHT Appearance and Odor:COLORLESS GAS, ODORLESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE OR UNUSED QUAANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE TO AIRCO FOR PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:HMIS TECHNICIAN CAGE:JO772 CAGE:16236 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE:MINOR EYS/SKIN IRRITATION. INGESTION- IRRITATION OF GI TRACT. INHALATION-IRRITATION OF RESPIRATORY TRACT. CHRONIC: ASBESTOSIS, LUNG CANCER, & MESOTHELIOMA, ALL OF WHICH ARE DISABLING AND FATAL D ISEASES OF THE LUNG. INHALATION AND INGESTION OF ASBESTOS FIBERS MAY CAUSE CANCER OF THE BOWEL. Explanation of Carcinogenicity:ASBESTOS IS A KNOWN HUMAN CARCINOGEN. Effects of Overexposure:INHALATION: FATIGUE AND SHORTNESS OF BREATH THAT GETS WORSE WITH TIME AND EVENTUALLY BECOMES DISABLING. EYES: IRRITATION. SKIN: IRRITATION. INGESTION: MILD STOMACH DISTRESS. DIARRHEA, VOMITING, AND NA USEA. Medical Cond Aggravated by Exposure:ASTHMA, EMPHYSEMA, AND TUBERCULOSIS ARE ALL GENERALLY AGGRAVATED BY EXPOSURE TO ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SEE DOCTOR. EYES: RINSE THOROUGHLY WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEE DOCTOR. INGESTION: DIL UTE WITH WATER. DO NOT INDUCE VOMITING.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NOT REQUIRED Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM THE MATERIAL WITH A HEPA FILTERED VACUUM. THE EQUIPMENT SHALL BE USED & EMPTIED SO AS TO MINIMIZE THE RE- ENTRY OF ASBESTOS INTO THE WORKPLACE. OTHERWISE, WET THE MATERIAL WITH WATER & SURFACTA NT AND THEN SHOVEL OR MOP UP CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:ITEM IS NONFRIABLE & WILL NOT SHED FIBERS IN NORMAL USE AND STORAGE. USED ITEMS SHALL BE WETTED BEFORE, DURING & AFTER DISASSEMBLY. Other Precautions:IF IT IS NECESSARY TO CUT OR IMPACT THE ITEM WHILE INSTALLING IT, WEAR A RESPIRATOR AND PROTECTIVE CLOTHING. USED ITEMS SHALL BE IDENTIFIED AND DISPOSED OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDE RAL REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED HEPA RESPIRATOR IF REQUIRED. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS OF CONTAMINATES. Ventilation:LOCAL EXHAUST SUFFICIENT TO ENTRAIN ALL PARTICULATE EMISSIONS. HEPA FILTER REQUIRED. NO LEAKS ON PRESSURE SIDE OF FAN. Other Protective Equipment:USE COVERALLS OR DISPOSABLE CLOTHING. Work Hygienic Practices:WET WORK TO THE DEGREE POSSIBLE. WASH HANDS AFTER HANDLING ITEM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health MSDS GENERATED BY HMIS TECHNICIAN. MANUFACTURER IS UNKNOWN OR OUT OF BUSINESS. ================== Physical/Chemical Properties ================== HCC:T6 Appearance and Odor:BRAKE SHOE, OF MOLDED ASBESTOS COMPOSITION WITH INTERNAL REINFORCEMENT Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, AND STRONG ALKALIS Stability Condition to Avoid:ACCUMULATIONS OF DUST Hazardous Decomposition Products:ASBESTOS DUST ==================== Disposal Considerations ==================== Waste Disposal Methods:WET THE MATERIAL WITH WATER AND SURFACTANT. PLACE IN 6 MIL THICK POLYETHYLENE PLASTIC BAG. PLACE THESE BAGS INTO ANOTHER POLY BAG OR A SAFE PLACE UNTIL IT CAN BE SHIPPED TO AN APPROVED DISPOSAL SITE. IDENTIFY WITH ASBESTOS CANCER WARNING LABEL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHLOROFORM CAGE:BAXTE CAGE:BAXTE CAGE:2H215 ============= Composition/Information on Ingredients ============= Ingred Name:CHLOROFORM CAS:67-66-3 RTECS #:FS9100000 Fraction by Wt: 98.99% OSHA PEL:(C) 50 PPM ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:AMYLENE CAS:513-35-9 Fraction by Wt: <0.01% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYL ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 1% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:MED CNDTNS: MAKE SPECIAL REFERENCE TO LIVER AND KIDNEY FUNCTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: MED ASSIST. INGEST: CALL LOC POIS CTL CTR FOR ASSIST. CONT PHYS IMMED. NEVER INDUCE VOMIT/GIVE (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:ANYTHING BY MOUTH TO A VICTIM UNCON/HAVING CONVULSIONS. RTECS #:9999999ZZ Ingred Name:SPILL PROC: REPORTABLE QTY-5,000 LBS. RTECS #:9999999ZZ Ingred Name:VENT: WILL DEPEND ON CNDTNS OF USE, QTY OF MATL, AND OTHER OPERATING PARAMETERS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: EXPOS CAUSES EXCITATION FOLLOWED BY DIZZ, NAUS, HDCH, UNCON, & RESP FAILURE. DEATH MAY OCCUR FROM CARDIAC ARREST/HEPATIC DAM. CHRONIC INHAL MAY RSLT IN LIVER/KIDNEY DAM. HIGH CONC OF VAP CAUSES CONJ & SPASMODIC WINKING. LIQ CONT W/EYE RSLTS IN BURNING PAIN & IRRIT, W/POSS CORNEAL INJURY. INHAL: (EFTS OF OVEREXP) Explanation of Carcinogenicity:CHLOROFORM: IARC MONOGRAPHS, SUPPLEMENT VOL 7, PG 152, 1987: GRP 2B. NTP 6TH ANNUAL REPORT ON CARCIN, 1991: (SUPP DATA) Effects of Overexposure:HLTH HAZ:EXPOS CAN CAUSE NAUS, VOMIT, DROW, HDCH & DIZZ, UNCON, & EVEN DEATH IN EXTREME CASES. SUBSEQUENT LIVER & KIDNEY DAM MAY RSLT FROM BOTH ACUTE & CHRONIC EXPOS. CHLOROFORM CAN CAUSE OLFACTORY FA TG & HAS POOR WARNING PROPERTIES. EYE: LIQ/HIGH VAP CONC CAN CAUSE PAIN & IRRIT W/SLIGHT CORNEAL INJURY POSS.(SUPP DATA) Medical Cond Aggravated by Exposure:PRECLUDE FROM EXPOS INDIVIDUALS W/DISEASE OF LIVER, KIDNEYS & CNS. SIMULTANEOUS EXPOS TO CHLOROFORM & ALCOHOL CAN INCR TOX HAZ OF CHLOROFORM. ANNUAL PHYSICAL EXAMS OF EXPOSED PERSONS SHOULD (ING 4) ======================= First Aid Measures ======================= First Aid:INHAL: IMMED REMOVE TO FRESH AIR. IF NOT BRTHG, ADMIN MOUTH-TO-MOUTH RESUSCITATION. IF THERE IS NO PULSE, ADMIN CARDIOPULMONARY RESUSCITATION (CPR). CONT PHYS IMMED. EYE: RINSE W/COPIOUS AMTS OF WATER FOR @ LST 15 MIN. GET EMER MED ASSIST.SKIN: FLUSH THORO FOR @ LST 15 MIN. WASH AFFECTED SKIN W/SOAP & WATER. REMOVE CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE RE-USE & DISCARD SHOES. GET EMER (ING 5) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:NONE Extinguishing Media:NON-FLAMM MATL.USE DRY CHEM, CARBON DIOXIDE, FOAM/ WATER SPRAY AS APPROPRIATE FOR SURROUNDING FIRE AND MATLS. Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT EQUIP. NON-FLAMM MATL. HEAT WILL BUILD PRESS & MAY RUPTURE CLSD STOR CONTRS. KEEP FIRE-EXPOSED (SUPP DATA) Unusual Fire/Explosion Hazard:CONCENTRATED VAPS CAN BE IGNITED BY HIGH INTENSITY HEAT SOURCE/FLAME. TOX & CORR GASES ARE FORMED ON CONT W/FLAMES/ HOT GLOWING SURF. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROT CLTHG & USE NIOSH/MSHA APPRVD RESP EQUIP. ABSORB SPILLED MATL IN AN ABSORB RECOM FOR SOLV SPILLS & REMOVE TO A SAFE LOCATION FOR DISP BY APPRVD METH. IF REL TO ENVIRON, COMPLY W/ALL REGULATO RY NOTIFICATION REQUIREMENTS. CERCLA (ING 7) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROD SHOULD BE PROTECTED FROM MOISTURE, TEMP EXTREMES, & DIRECT SUNLIGHT. PRLNGD STOR/PRLNGD EXPOS TO AIR/LIGHT WILL INCR ACIDITY. Other Precautions:PROPER STOR OF PROD MUST BE DETERMINED BASED ON OTHER MATLS STORED & THEIR HAZ & POTNTL CHEM INCOMPATIBILITY. IN GEN, PROD SHOULD BE STORED IN A COOL, WELL VENTD & SECURE TOX STOR ROOM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD RESP EQUIP. FOLLOW NIOSH & EQUIP MFR'S RECOMM TO DETERM APPROP EQUIP (AIR-PURIFYING, AIR-SUPPLIED/ SCBA). Ventilation:ADEQ VENT IS REQD TO PROTECT PERS FROM EXPOS TO CHEM VAPS EXCEEDING PEL. CHOICE OF VENT EQUIP, EITHER LOC/GEN, (ING 8) Other Protective Equipment:EMER EYE WASH FOUNTAINS & SFTY SHOWERS SHOULD BE AVAIL IN THE VICIN OF ANY POTNTL EXPOS. PROT CLTHG RECOMM. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV: 1.49@20C(H2O=1). FIRE FIGHT PROC: CONTRS COOL W/WATER SPRAY. EXPLAN OF CARCIN: ANTIC TO BE CARCIN. EFTS OF OVEREXP: SKIN: PRLNGD/RPTD CONT CAN CAUSE IRRIT & DERM THRU DEFAT OF SKIN. INGEST: SWALLOWING IS FOLLOWED BY BURNING OF THROAT & MOUTH. LIVER & KIDNEY DAMAGE CAN RESULT. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:142F,61C Melt/Freeze Pt:M.P/F.P Text:-82F,-64C Vapor Pres:159@20C Vapor Density:4.1 Spec Gravity:SUPP DATA Evaporation Rate & Reference:0.6(ETHER=1) Solubility in Water:0.8%@20C Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A MILDLY SWEET ODOR Percent Volatiles by Volume:CA100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACTIVE METALS AND STRONG ALKALINE SOLUTIONS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, OPEN CONTRS, POOR VENT, & MOISTURE. PRONGD STOR/PRLNGD EXPOS TO AIR/LIGHT WILL INCR ACIDITY. Hazardous Decomposition Products:PHOSGENE, HYDROGEN CHLORIDE, AND CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PROD AS AN EPA HAZ WASTE. CONTACT STATE ENVIRONMENTAL AGENCY FOR LISTING OF LICENSED HAZARDOUS WASTE DISPOSAL FACILITIES AND APPLICABLE REGS. HAZ WASTE # U044(TOX). DISPOSE OF I/A/W FED, ST AND LOC REGS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6603904 2H4-FITC Preparer's Name:S HEALY CAGE:FO645 CAGE:FO645 CAGE:6Z677 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE *96-4* CAS:26628-22-8 RTECS #:VY8050000 Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN: IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS, CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY IRRITATION, RESPIRATORY FAILURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS, NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH, COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA, CONVULSIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND. Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN. Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS. (SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS Other Protective Equipment:ADEQUATE LABORATORY ATTIRE Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N ITROGEN & MOLTEN SODIUM. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:527F Spec Gravity:1.85 Solubility in Water:40.16 Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:56142 57307 ANTI-S RARE SERA CAGE:67018 CAGE:67018 CAGE:67823 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:SODIUM AZIDE, AZIDE *98-1* CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: 0.1% Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 27 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED/ABSORBED THROUGH SKIN. Explanation of Carcinogenicity:NONE Effects of Overexposure:HEADACHE, NAUSEA, BLURRED VISION, DIZZINESS, LOW BLOOD PRESSURE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY W/WATER FOR 15 MINS. SKIN: RINSE W/PLENTY OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. AID IN BREATHING IF NECESSARY. INGESTION: FLUSH MOUTH. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:DRY CHEMICAL/CO2 ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WEAR PROTECTIVE CLOTHING TO GUARD AGAINST EYE & SKIN CONTACT. USE SPILL PILLOWS/OTHER APPROPRIATE ABSORBENT. PLACE MATERIALS IN SEALED CONTAINER FOR PROPER DISPOSAL. LARGE: WEAR SELF CONTAINEDBREATHING APPARATUS & FULL PROTECTIVE CLOTHING. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 35.6-46.4F. DON'T STORE NEAR ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USE. Ventilation:USE W/ADEQUATE VENTILATION. Other Protective Equipment:CHEMICAL RESISTANT APRON, PROTECTIVE CLOTHING Work Hygienic Practices:GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED TO AVOID EYE & SKIN CONTACT W/THIS PRODUCT. Supplemental Safety and Health THESE PRODUCTS CONTAIN MATERIALS THAT HAVE BEEN PREPARED FROM HUMAN BLOOD COMPONENTS & SHOULD BE HANDLED AS IF CAPABLE OF TRANSMITTING INFECTIOUS AGENTS. THESE PRODUCTS CONTAIN 0.1% SODIUM AZIDE AS A PRESERVATIVE. THEREFORE, WE HAVE ENCLOSED A MSDS FOR 0.1 SODIUM AZIDE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Vapor Pres:AS WATER Evaporation Rate & Reference:(WATER=1): 1 Appearance and Odor:COLORLESS LIQUID W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Hazardous Decomposition Products:TOXIC HYDRAZOIC GAS, MAY FORM EXPLOSIVE LEAD/COPPER AZIDE IN LABORATORY PLUMBING ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. MAY FORM EXPLOSIVE LEAD/COPPER AZIDE IN LABORATORY PLUMBING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:146 6416 EASTMAN COLOR DEVELOPING AGENT, CD-2 (50LBS) CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:4-N,N-DIETHYL-2-METHYLPHENYLENEDIAMINE MONOHYDROCHLORIDE CAS:2051-79-8 RTECS #:SS9560000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 RAT:F 107MG/KG;M 132MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE LIVER DAMAGE BASED ON ANIMAL DATA. INHAL:HARMFUL.AIRBORNE DUST IRRIT. EYE:AIRBORNE DUST IRRIT.HOWEVER IMMED FLUSHING OF EYE W/WATER WILL MIN ANY IRRIT EFFECT. SKIN:MAY CAUSE ALLERGIC SKIN RE ACTION. INGEST:HARMFUL. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICATION IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:LIVER DAMAGE, HARMFUL IF INGEST/INHAL. EYE IRRIT, ALLERGIC SKIN REACTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR.NOT BREATH GIVE ART RESP.DIFFI BREATH GIVE OXY.GET MED ATTN IMMED. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS.GET MED ATTN. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @LEA ST 15MINS WHILE REMOVING CONTAMIN CLLTH/SHOES.GET MED ATTN. INGEST:INDUCE VOMIT AS DIRECTED BY MED PERSONNEL.CALL PHYSICIAN/POIS CNTRL CNTR IMMED.NEVER GIVE ANYTHING BY MOUTH TO UNCONSC PERSON. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2). Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING.FIRE/EXCESSIVE HEAT MAY PRODUCE HAZ DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:POWDERED MATL MAY FORM EXPLOSIVE DUST-AIR MMXTURES. FIRE/HIGH TEMPS MAY CAUSE EXPLOSIVE DECOMPOSITION. COMBUSTIBLE SOLID. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR SCOOP UP & REMOVE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/EYE/SKIN/CLOTH.AVOID BREATH DUST.USE W/ADEQUATE VENTI.KEEP FROM CONTACT W/OXIDIZING MATLS.KEEP CNTNR CLSD. Other Precautions:REF:NFPA PAMPHLET654:"PREVENTION OF FIRE/DUST EXPLO IN CHEM/DYE/PHARM/PLAST INDUSTRIES".PROPERTIES:LOW BIOCHEM OXY DEMAND;LITTLE POT TO CAUSE OXY DEPLETION IN AQU SYS;HI POT TO AFFECT SOME AQUA ORGANI SMS & GERMINATION &/OR EARLY GROWTH(SUP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NTO MAINTAIN AIRBORNE CONCEN BELOW RECOMMENDED EXPOSURE LIMITS AN APPROVED RESP MUST BE WORN.RESP TYP:DUST.IF RESP USED PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE W/O SHA STD 29CFR 1910.134. Ventilation:USE GOOD GEN VENTI(TYP 10AIR CHANGES/HR).MATCH VENTI RATES W/CONDITIONS.USE PROCESS ENCLOSURES/LOC EXHAU/OTHER (SUPPLEM) Other Protective Equipment:BOOTS,PROTECTIVE CLOTHING APPROPRIATE FOR RISK EXPO.EYEBATH,SAFETY SHOWER,WASHING FACILITIES. Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.DESTROY/THOROUHGLY CLEAN CONTAMIN SHOES.WASH THOROUGHLY AFT HNDLG. Supplemental Safety and Health PH:6.0(@10G/L WATER). OTHER PRECAUT:OF SOME PLANTS & GROWTH OF SOME PLATN SEEDLINGS;LOW POT TO PERSIST IN ENVIRO & TO BIOCONCEN.AFT DIL W/LG AMTS OF WATER @ 2ND WASTE TREAT MATL NOT EXPECTED TO CAUSE ADVERSE ENVIRO EFFECTS. VENTI:ENGINEERING CNTRLS TO MAINTAIN AIRBORNE LEVELS BEL RECOMMENDED EXPO LIMITS. ================== Physical/Chemical Properties ================== HCC:T4 Melt/Freeze Pt:M.P/F.P Text:500F,260C Decomp Temp:Decomp Text:500F,260C Vapor Pres:NEGLIGIBLE Vapor Density:7.1 Spec Gravity:N/AVAILABLE pH:SUPPLE Solubility in Water:APPRECIABLE Appearance and Odor:SOLID (CRYSTAL), WHITE COLOR, ODORLESS. Percent Volatiles by Volume:N/APPL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:MINIMIZE DUST GENERATION & ACCUMULATION. MATL CAN DECOMPOSES ABOVE 255C(491F).AVOID TEMPS >155C(311F). Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN CHLORIDE, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREAT/DISPOSAL MAY BE DUBJ TO NAT/STATE/LOC LAWS.INCINERATE.SINCE EMPTIED CNTNRS RETAIN PROD RESIDUE FOLLOW LABEL WARN EVEN AFT CNTNR IS EMPTIED.CHEM SUBJ TO REPORT REQMTS OF SEC 313 TITLE I II SARA/40CFR PART 372:NONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PERMA-SLIK "G" CAGE:KO238 CAGE:8F024 CAGE:KO238 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDENUM DISULFIDE CAS:1317-33-5 RTECS #:QA4697000 OSHA PEL:10 MG/M3 TDUST (MO) ACGIH TLV:10 MG/M3 (MO); 8990 Ingred Name:INORGANIC LEAD COMPOUND Fraction by Wt: <10.0% Other REC Limits:NONE SPECIFIED OSHA PEL:0.15 MG/CUM AS LEAD ACGIH TLV:0.05 MG/CUM AS LEAD Ingred Name:ANTIMONY TRIOXIDE (SARA III) CAS:1309-64-4 RTECS #:CC5650000 Fraction by Wt: <10.0% Other REC Limits:NONE SPECIFIED OSHA PEL:0.5 MG/M3 (SB) ACGIH TLV:0.5 MG SB/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 60-70% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <10.0% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MINERAL SPIRITS Other REC Limits:100PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE EFFECTS:EYES, SKIN AND MUCOUS MEMBRANE IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS. CHRONIC EFFECTS:BLOOD, ORGAN AND REPRODUCTIVE EFFECTS, LUNG TUMORS. Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES:IRRITATION, REDNESS, BLURRED VISION. SKIN:IRRITATION, DERMATITIS. INHALATION:IRRITATION, DIZZINESS, NAUSEA, FATIGUE, HEADACHE, UNCONSCIOUSNESS, ASPHYXIATION, INGESTION:GASTROINTESTINAL IRRITATION , NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.IF IRRITATION PERSISTS,SEE DOCTOR. SKIN:WASH WITH MILD SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. INHALATION:REMOVE VICTIM T O FRESH AIR.GIVE OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION:DO NOT INDUCE VOMIT.SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:59.0F,15.0C Extinguishing Media:FOAM,DRY CHEMICAL,CARBON DIOXIDE,HALON Fire Fighting Procedures:WEAR SELF-CONTAINED BRTHNG APPART;DO NOT EXTINGUISH W/WATER Unusual Fire/Explosion Hazard:IRRITATING/TOXIC FUMES,INCLUDING CARBON,SULFUR,ANTIMONY & LEAD MAY BE RELEASED IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL.ELIMINATE IGNITION SOURCES.VENTILATE AREA.WEAR PROTECTIVE CLOTHING AND EQUIPMENT.ABSORB IN INERT MATERIAL AND PLACE IN APPROPIATE DISPOSAL CONTAINER AND COVER.FLUSH RESIDUE WITH PLENT Y OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT, IGNITION SOURCES, ACIDS AND ALKALIES. KEEP CONTAINERS CLOSED. Other Precautions:DO NOT SPRAY NEAR OPEN FLAME. DO NOT PUNCTURE, INCINERATE, THROW INTO FIRE OR STORE ABOVE 120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:MECHANICAL (GENERAL) VENTILATION OR LOCAL EXHAUST VENTILATION TO KEEP EXPOSURE LEVELS BELOW PEL. USE EXPL-PROOF EQUIPM. Other Protective Equipment:WEAR RUBBER APRON. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175F/79.4C Spec Gravity:1.00 Solubility in Water:NIL Appearance and Odor:GRAY/BLACK LIQUID; ORGANIC SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:OPEN FLAMES. Hazardous Decomposition Products:IRRITATING & TOXIC FUMES, SO*X, ANTIMONY & LEAD MAYBE RELEAS Conditions to Avoid Polymerization:WILL NOT POLYMERIZE ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:02029 ECOLO-CLEAN 35 CAGE:VARNP CAGE:VARNP ============= Composition/Information on Ingredients ============= Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 0.3% Ingred Name:VOL ORGANIC CMPD: 420 G/L RTECS #:9999999VO Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; PETROLEUM DISTILLATE, HYDROTREATED ,(MINERAL SPIRITS) CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 40% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION TO NOSE, THROAT, LUNGS, NERVOUS SYSTEM DEPRESSION. EYES/SKIN: MODRATE IRRITATION. INGESTION: GI IRRITATION. REPEATED/ABUSIVE BREATHING MAY AFFECT PULMONARY, CARDIOVASCULAR & CNS . ASPIRATION HAZARD IF SWALLOWED, ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:DIZZINESS, DROWSINESS, HEADACHE, NAUSEA, DRYNESS, CRACKING, IRRITATION. Medical Cond Aggravated by Exposure:PRE-EXISITING DERMATITIS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F Lower Limits:0.9 Upper Limits:7 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. WATER MAY NOT BE EFFECTIVE TO EXTINGUISH FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS & PROTECT PERSONNEL. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SMALL AMOUNTS W/SOAP, WATER & A MOP. LARGE: SOAK UP W/ABSORBENT/TRANSFER LIQUID INTO A CLOSED CONTAINER FOR LATER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS SHOULD BE GROUNDED BEFORE TRANSFERRING THIS PRODUCT. STORE IN ORIGINAL CLOSED CONTAINER AWAY FROM SUNLIGHT/EXCESS HEAT/IGNITION SOURCES. Other Precautions:AVOID SKIN CONTACT. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR W/APPROPRIATE ORGANIC VAPOR CARTRIDGE Ventilation:LOCAL EXHAUST, GENERAL: ADEQUATE Work Hygienic Practices:WASH W/SOAP & WATER AFTER HANDLING THIS PRODUCT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Vapor Density:>1 Spec Gravity:0.9 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:EMULSIBLE Appearance and Odor:WHITE EMULSION W/MILD PETROLEUM ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIAL Stability Condition to Avoid:EXCESS HEAT, FREEZING TEMPERATURES, SUNLIGHT, IGNITION SOURCES Hazardous Decomposition Products:OXIDES OF CARBON, DENSE SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JD LITH #2 CAGE:7P852 CAGE:7P852 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM HYDROCARBON AND COMPLEX LITHIUM SOAP; (PETROLEUM HYDROCARBON WITH METALLIC SOAP THICKENER) Fraction by Wt: 100% ACGIH TLV:5 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: HAZ IS NEGLIGIBLE UNLESS HEATED TO PRODUCE VAPORS OR AS A MIST. VAPORS OR MISTED OILS CAN IRRITATE MUCOUS MEMBRANES AND CAUSE PULMONARY IRRITATION, DIZZINESS AND NAUSEA. EYE: CONTACT CAN CAUSE IRRITATION. SKIN: PROLONGED OR REPEATEDCONTACT WITH SKIN MAY CAUSE IRRITATION OF HAIR FOLLICLES (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: AND BLOCK SEBECEOUS GLANDS CAUSING RASHES, OIL ACNE OR DERMATITIS. INGESTION: MAY IRRITATE DIGESTIVE TRACT BUT IS GENERALLY NOT HARMFUL UNLESS IN LARGE QUANTITIES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER, OR USE WATERLESS HAND CLEANER AFTER SKIN CONTACT. LAUNDER CONTAM CLTHG BEFORE REUSE. EYE: FLUSH W/WATER FOR AT LEAST 15 MINUTES, GETTING UNDER EYELIDS. CONTACT PHYS IF IRRIT PERSISTS. INHAL: (MISTS/VAPORS): REMOVE VICTIM FROM AREA OF EXPOSURE TO FRESH AIR. IF BRTHG DFCLTY/IRRIT PERSISTS CONTACT A PHYS FOR ASSISTANCE. INGEST: DO NOT INDUCE VOMIT! CONT PHYS FOR ADVICE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>350F,>177C Extinguishing Media:H2O SPRAY (FOG), DRY CHEMICAL, FOAM, HALON, CARBON DIOXIDE. WATER STREAM MAY SPLASH BURNING LIQUID, SPREADING FIRE. Fire Fighting Procedures:CLASS IIIB COMBUST LIQ. USE NIOSH/MSHA APPRVD SCBA AND FULL PROTECTIVE EQUIPMENT . COOL FIRE EXPOSED CNTNRS W/H2O. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNIT, CONT SPILL TO SMALLEST AREA POS. STOP LEAK IF POS. PICK UP SMALL SPILLS W/ABSORB MATLS SUCH AS PAPER TOWELS, "OIL DRY", SAND/DIRT. RECOVER LRG SPILLS FOR SALVAGE/ DISP. WASH H ARD SURFS W/SFTY SOLV/DETERGENT TO (SEESUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS BELOW 120 DEGREES F. KEEP AWAY FROM OXIDIZING AGENTS. EXCESSIVE HEAT OR SOURCES OF IGNITION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP ACCEPTABLE FOR MISTS/ PARTICULATES RECOM FOR PROT FROM OIL VAPS/MISTS. NIOSH/MSHA APPROVED AIR SUPP/SELF CONTAINED BREATHING EQUIP RECOM FOR CONC ABOVE 250 MG/M3. Ventilation:PROVIDE EXPLOSION PROOF VENTILATION WHERE OILS ARE HEATED OR MISTED TO MEET TLV LEVEL. Other Protective Equipment:NEOPRENE OR NITRILE CLOTHING RECOMMENDED TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASHING EXPOSED SKIN SEVERAL TIMES DAILY AND LAUNDERING CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health SPILL PROC: REMOVE REMAINING OIL FILM. EYE PROT: MAY ADD FULL LENGTH ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.956 Solubility in Water:0 Appearance and Odor:DARK AMBER, SEMI-SOLID GREASE WITH MINERAL OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:AVOID STRONG OXIDIZERS SUCH AS CHLORINE AND OXYGEN, HEAT AND SOURCES OF IGNITION. Hazardous Decomposition Products:COMBUSTION PRODUCES CARBON MONOXIDE AND CARBON DIOXIDE ALONG WITH THICK BLACK SMOKE. TRACES OF OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE DISP OF BY LICENSED WASTE DISP COMPANY. CONTAM ABSORB MATLS MAY BE DISP OF IN AN APPROVED LANDFILL. FEDERAL, STATE, AND LOCAL DISPOSAL REGULATIONS MUST BE FOLLOWED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SULFURIC ACID,108-002679 & 108-003679 CAGE:1L168 CAGE:1L168 CAGE:1L164 CAGE:19796 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 96.0% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 4.0% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Effects of Overexposure:CAUSES SEVER BURNS TO EYES,SKIN,MUCOUSA.CAN BE FATAL IF INGESTED.RESPIR IRRIT IF INHALED. ======================= First Aid Measures ======================= First Aid:SKIN/EYES:FLUSH W LG AMOUNTS H2O FOR 15 MIN.REMOVE CONTAMINATED CLOTHING.INGEST:DRINK LG AMTS H2O.DO NOT INDUCE VOMIT.INHALATION:REMOVE TO FRESH AIR.GIVE CPR/O2 IF NEED.OBSERVE FOR DELAYED REACTION.IN ALL CASES,GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:SM FIRE:DRY CHEM.LG:H2O SPRAY,AVOID SPRAYNG INTO CONTAINER Fire Fighting Procedures:USE NIOSH APPRVD RESPIR,FULL PROTECTIVE CLOTHING Unusual Fire/Explosion Hazard:CAN GENERATE H2 GAS(FLAMMABLE)UPON REACT W. METALS.CAN IGNITE COMBUSTIBLES ON CONTACT. ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL:DILUTE W WATER.NEUTRALIZE WITH SODA ASH OR LIME.LG SPILL:DIKE W SODA ASH/LIME.ADEQUATE VENTILATION IS NEEDED AS CO2 IS RELEASED.NO SMOKING.LG SPILLS HANDLED BY PREDETERMINED PLAN.KEEP OUT OF SEWERS.CHECK WITH AUTHORITIES FOR REPORTING. Neutralizing Agent:SODA ASH ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W.LIQUID.PROTECT FROM PHYSICAL DAMAGE.STORE IN COOL,WELL-VENTILATED AREA AWAY FROM COMBUSTIBLES & REACTV CHEM.KEEP AWAY FROM SUN/HEAT Other Precautions:HAVE NEUTRALIZATION SUPPLIES AND EQUIPMENT NEARBY.KEEP CONT UPRIGHT.DO NOT ADD WATER TO ACID,ALWAYS ACID TO WATER.NO SMOKING IN AREA.USE PROTECTIVE EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE REQUIRED,NIOSH APPRVD RESPIR,IF MIST-GAS MASK W.ACID GAS CANST Ventilation:HEAVY HANDLING:LOCAL EXHAUST OR MECH.SPECIAL HANDLING-EXH HO Other Protective Equipment:RUBBER APRON, BOOTS, EYE WASH, SAFETY SHOWER, FACE SHIELD. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MORE INCOMPATIBLE MATERIALS: GAS-FORMNG SALTS, OXIDIZERS AND REDUCERS. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:154F,68C Spec Gravity:1.835 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS TO SLIGHT YELLOW, CLEAR TO TURBID OILY LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID, ANHYDRIDES, ALKALI, ALLYL/UNSATURATED ORGANICS, AMINES, GLYCOLS, ORGANIC OXIDES, OXIMES, NITROGEN COMPOUNDS (SUPP) Stability Condition to Avoid:HIGH HEAT, MOISTURE Hazardous Decomposition Products:OXIDES SULFUR, HYDROGEN SULFIDE, HYDROGEN GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL IS SUBJECT TO FEDERAL,STATE AND LOCAL REGS.USERS SHOULD REVIEW THEIR OPERATIONS FOR COMPLIANCE,THEN CONSULT WITH APPROPRIATE REGULATORY AGENCIES BEFORE DISCHARGING,DISPOSING OF MATERIAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KROME KOTE S, 220-1910 CAGE:04465 CAGE:04465 ============= Composition/Information on Ingredients ============= Ingred Name:FIRST AID PROC:SPECIFIC ANTIDOTE FOR EFTS FROM OVEREXP TO THIS MATL. TREATMENT SHOULD BE DIRECTED AT THE CONTROL (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OF SYMPTOMS AND THE CLINICAL CONDITION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:CONTAIN RUNOFF FROM FIRE CONTROL AND DILUTION WATER. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER (1 800-424-8002). THE REPORTABLE QTY (RQ) (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:FOR THIS PRODUCT IS 56,200 POUNDS. RTECS #:9999999ZZ Ingred Name:OTHER PREC:WASH EXPOSED AREAS PROMPTLY AND THOROUGHLY AFTER SKIN CONTACT AND BEFORE EATING, DRINKING, USING (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:TOBACCO PRODUCTS OR REST ROOMS. RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:EYE PROT:AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:ON WORKING CNDTNS, WEAR RESISTANT PROT GARMENTS SUCH AS APRONS, JACKETS, PANTS, COVERALL, BOOTS, ETC. RTECS #:9999999ZZ Ingred Name:BENTONITE CAS:1302-78-9 RTECS #:CT9450000 Fraction by Wt: <5% OSHA PEL:50 MPPCF (MFR) ACGIH TLV:N/K Ingred Name:FORMALDEHYDE; (FORMALDEHYDE SOLUTION) (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <1% OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9495 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM SILICATE) LD50 (ORAL, RAT): 500 MG/KG CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <5% OSHA PEL:20 MPPCF Z-3 ACGIH TLV:2 MG/M3 RDUST; 9495 Ingred Name:NO. 2 FUEL OIL; (PETROLEUM DISITLLATE); LD50 (ORAL, RAT): >5G/KG CAS:68476-30-2 RTECS #:LS8930000 Fraction by Wt: <5% OSHA PEL:5 MG/M3 (MIST) (MFR) ACGIH TLV:N/K Ingred Name:SILICA GEL CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 60-70% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:TALL OIL; (TALL OIL DISTILLATE) CAS:8016-81-7 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL/FATAL IF INGESTED & ASPIRATED INTO LUNGS. EYE:CNTCT MAY CAUSE IRRIT. SKIN:FUEL OIL HAS BEEN SHOWN TO PRDCE LOW LEVEL TUMOR INCIDENCE WHEN APPLIED TO THE SKIN OF MICE THROUGHOUT T HEIR LIFETIME. INHAL:IF DRIED MATL BECOMES AIRBORNE, SHORT-TERM HIGH-LEVEL OVEREXP MAY CAUSE COUGHING (EFTS OF OVEREXP) Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 211, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT ON CARCIN, (SUPDAT) Effects of Overexposure:HLTH HAZ:& UPPER RESP IRRIT. INGEST:NOT EXPECTED. CHRONIC:EXPOS TO AIRBORNE DUST MAY LEAD TO LUNG DMG. LONG-TERM OVEREXPOS TO AIRBORNE DUST MAY CAUSE PROGRESSIVE SCARRING OF THE LUNGS, LEADING TO DFCL TY IN BRTHG. THIS PROD CNTNS SILICA. IARC RPTS THAT THERE IS SUFFICIENT EVID FOR THE CARCIN OF CRYSTALLINE (SUPDAT) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASE IN OR A HISTORY OF AILMENTS INVOLVING THE RESPIRATORY SYSTEM, SKIN ARE AT A GREATER THAN NORMAL RISK OF DEVELOPING ADVERSE EFFECTS WHEN EXPOSED TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:EYE:GENTLY FLUSH ANY PARTICLES FROM THE EYES W/LRG AMTS OF COLD H*2O FOR AT LEAST 15 MIN. SEEK MED AID. SKIN:WASH THORO W/SOAP & H*2O. IF REDNESS, ITCHING, BURNING/OTHER SYMPS DEVELOP/PERSIST, SEEK ME D AID. INHAL:REMOVE FROM EXPOS. IF BRTHG HAS STOPPED OR IS DFCLT, ADMIN ARTF RESP/OXYGEN AS INDICATED. SEEK MED AID. INGEST:DO NOT INDUCE VOMIT, GET IMMED MED ATTN. NOTES TO MD:THERE IS NO (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER SPRAY. WATER OR FOAM MAY CAUSE FROTHING. DOES NOT SUPPORT COMBUSTION. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIP . USE WATER TO COOL FIRE-EXPOSED CONTAINER/STRUCTURE/PROTECT PERSONNEL. TOXIC VAPS MAY BE GIVEN OFF IN A FIRE. Unusual Fire/Explosion Hazard:WHEN HEATED (FIRE CNDTNS), VAPS/DECOMP PRODS MAY BE RELS & MAY ADD TO THE INTENSITY OF THE FIRE. CLSD CNTNRS MAY EXPLODE (DUE TO THE BUILD-UP OF STEAM).(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND. SOLIDIFIED SPILLS:SHOVEL/VACCUM INTO DRY CNTNRS & COVER. FLUSH AREA W/H*2O. SMALL WET SPILLS:TAKE UP W/SAND/OTHER NONCOMBUSTIBLE ABSORB MATL. FLUSH AREA W/H *2O. DIKE LRG SPILLS FOR LATER DISPOSAL. (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. KEEP IN A CLOSED, LABELED CONTAINER WITHIN A COOL (WELL SHADED), DRY-VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:KEEP CNTNRS CLSD WHEN MATL IS NOT IN USE. MAINTAIN GOOD HOUSEKEEPING. IF POST APPLIC/USE PROCESSING OF THIS PROD GENERATES DUST/IF SPRAY APPLICATN IS MADE, EXPOS LIMS APPLY. DO NOT USE UNTIL MFR'S PRE C HAVE BEEN READ/UNDERSTOOD. (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:COMBINATION FILTER/ORGANIC VAPOR CARTRIDGES OR CANISTER MAY BE USED. IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURE BELOW TLV(PEL). USE NIOSH APPROVED UNITS AS PER CURRENT 29 CFR 1910.134 AND MF R'S INSTRUCTIONS AND WARNINGS. Ventilation:NOT NORMALLY REQD. PROVIDE SUFFICIENT GEN/LOC EXHST VENT IN PATTERN/VOL TO CNTRL INHAL EXPOS BELOW CURRENT EXPOS LIMS. Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . WEAR INDUSTRIAL TYPE WROK CLTHG & SAFETY FOOTWEAR. DEPENDING (ING 16) Work Hygienic Practices:DO NOT WEAR CNTCT LENS W/OUT PROPER EYE PROT WHEN USING THIS PROD. Supplemental Safety and Health EXPLO HAZ: UNDER FIRE CNDTNS, MAY EMIT IRRITANT/TOX GAS AND/OR FUMES. EXPLAN OF CARCINOGENS: 1994: ANTICIPATED TO BE CARCIN. OSHA REGULATED: CFR 29 1910.1048. ANIMAL: NASAL TUMORS. EFTS OF OVEREXP: FO RM OF SILICA TO EXPERIMENTAL ANIMALS, W/LTD EVID OF CARCIN EFTS IN HUMANS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:>1 Solubility in Water:DISPERSIBLE Appearance and Odor:GREEN PLASTIC PASTE WITH A MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PROD IS NOT DEFINED AS A USE EPA HAZ WASTE, BUT SHOULD BE DISPOSED OF AS ONE. DISPOSE OF AS A HAZ WASTE I/A/W/LOCAL, STATE & FED REGS. PLACE IN TIGHTLY SEALED LABELED CNTNRS. PROD RELSD INTO THE EVIRONMENT (ING 10)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ZEP TIME SAVER #2017 (WAX STRIPPER) CAGE:27674 CAGE:27674 ============= Composition/Information on Ingredients ============= Ingred Name:MONOETHANOLAMINE (2-AMINOETHANOL, MEA) CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:3 PPM/STEL 6 PPM ACGIH TLV:3 PPM/STEL 6 PPM Ingred Name:PHENYL GLYCOL ETHER (SARA 313) (2-PHENOXYETHANOL, PHENYLMONOGLYCOLETHER, PHENOXYTOL) CAS:122-99-6 RTECS #:KM0350000 Fraction by Wt: 5-15% Other REC Limits:NONE RECOMMENDED Ingred Name:NONYLPHENOXYPOLY (ETHYLENEOXY) ETHANOL CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM METASILICATE (OSHA DUST LIMIT, 2 MG/M3, FOR POWDERS ONLY) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:PROPYLENE GLYCOL N-BUTYL ETHER (ALSO CAS 15821-83-7, 1-PROPANOL-2-BUTOXY) CAS:5131-66-8 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT EST. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CONCENTRATE MAY BE CORROSIVE TO EYES/MUCOUS MEMBRANES, SOLUTIONS ARE SEVERE EYE IRRIT. EYES - MAY RESULT IN CORNEAL DAMAGE/BLINDNESS. SKIN - MAY PRODUCE IRRITATION DEPENDING LENGTH OF CONTACT T IME. INHAL: OVEREXPOSURE MAY CAUSE RESPIRATORYIRRIT. CHRONIC: REPEATED/PROLONGED SKIN EXPOSURE CAN PRODUCE CHRONIC Explanation of Carcinogenicity:NONE OF THE INGREDIENTS ARE LISTED AS CARCINOGENS BY IARC, NTP, OSHA. Effects of Overexposure:NK *DERMATITIS - REDNESS, SCALING, BLISTERING. REPEATED EXPUSURE TO SPRAY MISTS MAY LEAD TO CHRONIC EYE INFLAMMATION, RESPIRATORY IRRITATION OR LUNG DAMAGE. ANIMAL STUDIES INDICATE POTENTIAL FOR LIVE R, KIDNEY, RED BLOOD CELL DAMAGE. RELEVANCE OF THESE STUDIES FOR HUMANS NOT ESTABLISHED. Medical Cond Aggravated by Exposure:INGREDIENTS IN THIS PRODUCT MAY AGRAVATE EXISTING SKIN, EYE, RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:SKIN: IMMEDIATELY FLUSH CONTAMINATED SKIN W/PLENTY WATER AT LEAST 15 MINUTES. GET MED AID IF IRRITATION DEVELOPS. EYES: IMMED FLUSH W/PLENTY WATER AT LEAST 15 MINUTES, OCCASIONALLY LIFTING LIDS. GET M EDICAL AID AT ONCE. INHAL: GET FRESH AIR. IF IRRITATION PERSISTS GET MEDICAL AID PROMPTLY. INGESTION: DON'T INDUCE VOMITING. IF VICTIM CONSCIOUS GIVE PLENTY WATER TO DRINK. GET MEDICAL AID AT ONCE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Lower Limits:NA Upper Limits:NA Extinguishing Media:NONCOMBUSTIBLE Fire Fighting Procedures:POSITIVE PRESSURE SCBA. Unusual Fire/Explosion Hazard:FIRE-EXPOSED DRUMS SHOULD BE COOLED W/STREAM OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON INERT ABSORBENT MAT'L (E.G. ZEP-O-ZORB). OBSERVE HANDLING/STORAGE/PROTECTIVE MEASURES AS LISTED BELOW. PICK UP/PLACE IN CLEAN DOT SPEC CONTAINER FOR DISPOSAL. WASH AREA THOROUGHLY W/DETERGEN T SOLUTION THEN RINSE WELL W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN DRY AREA AT TEMPS BETWEEN 40-120F. KEEP AWAY FROM SKIN, EYES. DON'T BREATHE SPRAY/MISTS/VAPORS. PH (DILUTED 1:4) 12.0 Other Precautions:CLOTHING/SHOES THAT BECOME CONTAMINATED W/SUBSTANCE SHOULD BE REMOVED PROMPTLY, NOT REWORN UNTIL THOROUGHLY CLEANED. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO EXTRA MEASURES NEEDED IF VENTILATION ADEQUATE. Ventilation:PROVIDE LOCAL EXHAUST/VENT AS NEEDED TO KEEP VAPOR CONCENTRATIONS <PEL & TLV Supplemental Safety and Health CONTACT EXPECTED. **TIGHT-FITTING SAFETY GLASSES RECOMMENDED IF SPLASHING MAY OCCUR. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.05 pH:12.75C Evaporation Rate &amp; Reference:<1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, SLIGHTLY AMBER LIQUID, CITRUS ODOR Percent Volatiles by Volume:86 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALIES, OXIDIZERS. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OTHER UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:LIQ NOT PERMITTED IN LANDFILLS UNLESS SOLIDIFIED. MAY NEED DISPOSE UNUSABLE PROD/SPENT USE-DILUTIONS AT HAZ WASTE TREATMENT/STORAGE/DISPOSAL FACILITY. SOME STATES CHEM/WASTE LANDFILL OKAY. SOME AREAS FLUSHING TO SEWER OK. SEE LAWS FOR YOURAREA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARCON 2795 Preparer's Name:ROBERT DAVIS CAGE:17433 CAGE:ADHEN CAGE:17433 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE, 1-BUTOXY-2,3-EPOXY-; (N-BUTYL GLYCIDYL ETHER) (BGE) CAS:2426-08-6 RTECS #:TX4200000 Fraction by Wt: <15% OSHA PEL:50 PPM ACGIH TLV:25 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC: NOT ESTABLISHED AS OF THE CURRENT ISSUE DATE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MIN. CONSULT MD. SKIN: REMOVE UNCURED PROD W/DRY CLOTH/TOWEL, WASH THORO W/SOAP & WATER. CONSULT MD IF IRRIT DEVELOPS. DO NOT USE SOLV TO REMOVE PROD. INHAL: REMOVE TO FRESH AIR IMMED. INGEST: GIVE MILK/WHITE OF EGG BEATEN W/WATER, & REPEAT UNTIL VOMIT FLUID IS CLEAR. IF VOMIT DOES NOT OCCUR, INDUCE VOMIT BY GAGGING VICTIM. DO NOT INDUCE VOMIT/GIVE (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:200F,93C Extinguishing Media:MOST STANDARD FIREFIGHTING AGENTS ARE SUITABLE, I.E. SAND, FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . DO NOT USE FOAM ON FIRES INVOLVING ELECTRICAL EQUIPMENT. Unusual Fire/Explosion Hazard:DURING A FIRE IRRITATING AND/OR TOXIC GASES MAY BE PRESENT FROM THE DECOMPOSITION/COMBUSTION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:COVER SPILLS WITH DRY ABSORBENT MATERIAL SUCH AS SAND OR SAWDUST; SCOOP UP AND PLACE IN AN APPROPRIATE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURE, AT 80F (27C). AVERAGE SHELF LIFE: 12 MONTHS IN ORIGINAL SEALED CONTAINERS. Other Precautions:STORE IN DRY AREA AWAY FROM EXCESSIVE HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNLESS VAPOR CONCENTRATIONS ARE EXCESSIVE. A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR CAN BE USED. OBSERVE THE MANUFACTURER'S DIRECTIONS CONCERNING THE USE OF RESPIRATORY PROTEC TION. Ventilation:NO SPECIAL REQUIREMENTS. LOC EXHAUST/DILUTION VENTILATION WILL HELP DISSIPATE VAPS IN ENCLOSED/POORLY VENTILATED AREAS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: ANYTHING BY MOUTH TO AN UNCON PERS. CALL MD IMMED. ================== Physical/Chemical Properties ================== Vapor Pres:2 Vapor Density:3.78 Spec Gravity:1.13 Solubility in Water:<1% Appearance and Odor:CLEAR TO STRAW COLORED VISCOUS LIQUID; SWEET PLEASANT ODOR Percent Volatiles by Volume:15 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDIC/BASIC OXIDIZING AGENTS, WATER, HEAT. Stability Condition to Avoid:MOISTURE, EXCESSIVE HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION WILL PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATE UNDER CONDITIONS WHICH MEET FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALUMINUM BRONZE, BRONZE CAGE:I1045 CAGE:I1045 ============= Composition/Information on Ingredients ============= Ingred Name:BASE METAL CONSISTING OF INGREDIENT 2 RTECS #:9999999ZZ Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 70-99% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ALLOYING ELEMENTS CONSISTING OF INGREDIENTS 4-11 RTECS #:9999999ZZ Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-14% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 0-14% OSHA PEL:15MG/M3 DUST;5 FUME ACGIH TLV:10MG/M3 DUST Ingred Name:IRON CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: <4% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <4% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: <2% OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: <1% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: <1% OSHA PEL:10 MG/M3 (ZNO) ACGIH TLV:10 MG/M3 (ZNO) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEADED ALLOYS CONSISTING OF INGREDIENT 13 RTECS #:9999999ZZ Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: <1% OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOS TO FUMES/DUST MAY PRDCE IRRIT OF EYES AND RESP SYS. INHAL OF HIGH CONC OF FRESHLY FORMED OXIDE FUMES OF COPPER AND LEAD MAY CAUSE METAL FUME FEVER CHARACT BY METALLIC TASTE IN MOUTH, DRYNESS OF THROAT AND INFLUENZA-LIKE SYMP. INHAL/INGEST OF LEAD PARTICLES MAY RSLT IN LEAD-INDUCED SYS (EFTS OF OVEREXP) Explanation of Carcinogenicity:LEAD AND LEAD COMPOUNDS: GROUP 2B (IARC); NICKEL: GROUP 2B (IARC), ANTICIPATED TO BE A CARCIN (NTP);COBALT GROUP 2B(IARC Effects of Overexposure:HLTH HAZ: TOX. SYMP OF LEAD POISONING INCL ABDOMINAL CRAMPS, ANEMIA, MUSCLE WEAKNESS & HDCH. PRLNGD EXPOS CAN CAUSE BEHAVIORAL CHANGES, KIDNEY DMG, CNS DMG, & REPROD EFTS. EXPOS TO HIGH CONC OF NICKEL DUST & FUMES CAN CAUSE SENSIT DERM, INFLAM &/OR ULCERATION OF UPPER RESP TRACT & POSS CANCER OF NASAL PASSAGES (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: IF EXPOSED TO EXCESSIVE LEVELS OF METAL FUMES, REMOVE TO FRESH AIR, SEEK MEDICAL AID IMMEDIATELY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER . INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . PRODUCTS IN SOLID STATE PRESENT NO FIRE OR EXPLOSION HAZARD. Unusual Fire/Explosion Hazard:DUST HAZARDS EXIST UNDER FAVORING CONDITIONS OF SMALL PRACTICE SIZE. DISPERSION IN AIR AND STRONG IGNITION SOURCE MAY RESULT IN AN EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:IN WELDING, PRECAUTIONS SHOULD BE TAKEN FOR AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMPONENTS OF WELDING ROD. Other Precautions:ARC OR SPARK GENERATED WHEN WELDING OR BURNING COULD BE SOURCE OF IGNITION FOR COMBUSTIBLE AND FLAMMABLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST AND FUME, RESPIRATOR SHOULD BE USED TO AVOID EXCESSIVE INHALATION OF PARTICULATES WHEN EXPOSURE EXCEEDS TLV'S. Ventilation:LOC EXHST VENT SHOULD BE UTILIZED WHEN WELDING,BURNING, SAWING, BRAZING, GRINDING OR MACHINING WHEN EXPOS EXCEEDS TLV'S. Other Protective Equipment:OTHER PROTECTIVE EQUIPMENT SHOULD BE UTILIZED AS REQUIRED BY WELDING STANDARDS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PRODS: ARE INVOLVED. EFTS OF OVEREXP: & LUNGS. NOTE: LEAD 7439-92-1 APPEARS ON NAVY LISTING OF OCCUPATIONAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CON CERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOUSRE RECOMMENDATIONS . ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>1700F,>927 Spec Gravity:>7 Appearance and Odor:RED-GOLD METALLIC SOLID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MERCURY, AMMONIA, ACETYLENE. Stability Condition to Avoid:EXPOSURE DURING STORAGE TO STRONG ACIDS, BASES OR OXIDIZING AGENTS. Hazardous Decomposition Products:TOX GASES,AEROSOLS & VAPS MAY BE RELS IN FIRE INVOLVING COPPER ALLOYS IF FUME OF OTHER CMPDS/OTHER CONT MATLS (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LITHIUM POWER CELL, 3 VOLT-U3VL CAGE:JO511 CAGE:0UU59 CAGE:JO511 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 12-15% OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:LITHIUM (METAL) CAS:7439-93-2 RTECS #:OJ5540000 Fraction by Wt: 2-3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CARBONIC ACID, CYCLIC PROPYLENE ESTER; (PROPYLENE CARBONATE) CAS:108-32-7 RTECS #:FF9650000 Fraction by Wt: 7-8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:1,3-DIOXOLANE CAS:646-06-0 RTECS #:JH6760000 Fraction by Wt: 6-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LITHIUM HEXAFLUOROARSENATE CAS:29935-35-1 Fraction by Wt: 2-3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: BY VENTILATION TO AN IGNITION SOURCE AND FLASH BACK. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN & GET MED ATTN. EYES: IMMED FLUSH W/PLENTY OF (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: WATER FOR AT LEAST 15 MIN & GET IMMED MED ATTN. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN OR (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: ARTIFICIAL RESPIRATION) . INGESTION: CALL MD IMMEDIATELY . RTECS #:9999999ZZ Ingred Name:OTHER PREC: BATTERY CHARGING: BATTERIES ARE NOT DESIGNED TO BE RECHARGED. CHARGING MAY RSLT IN ELECTROLYTE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: LEAKAGE &/CAUSE BATTERY TO FLAME. BATTERY DISASSEMBLY: NEVER DISASSEMBLE. SHOULD BATTERY UNINTENTIONALLY(ING 12) RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED MUST BE USED TO HANDLE ALL BATTERY COMPONENTS. AVOID (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: INHAL OF ANY VAPS THAT MAY BE EMITTED. IN THE EVENT OF SKIN/EYE EXPOS TO ELECTROLYTE, REFER TO FIRST AID(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SECTION. BATTERY SHORT CIRCUIT: MORE THAN A MOMENTARY SHORT CIRCUIT WILL GEN REDUCE BATTERY SERVICE (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: LIFE. EXTENDED SHORT CIRCUITING CREATES HIGH TEMPS IN CELL. HIGH TEMPS CAN CAUSE SKIN BURNS/CAUSE CELL (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: TO FLAME. AVOID REVERSING BATTERY POLARITY W/IN BATTERY ASSEMBLY. TO DO SO MAY CAUSE CELL TO FLAME/LEAK.(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: MIXED BATTERIES & TYPES: THE USE OF OLD & NEW BATTERIES/BATTERIES OF VARYING SIZES & TYPES IN THE SAME (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: BATTERY ASSEMBLY SHOULD BE AVOIDED. BATTERIES' ELEC CHARACTS & CAPABILITIES VARY & DMG MAY RSLT TO (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: BATTERIES OR ELECTRICAL EQUIPMENT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE/CHRONIC: NONE SPECIFIED BY MANUFACTURER. NEVER DISASSEMBLE A BATTERY. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:ELECTROLYTE CONT: SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. IF SYMPS ARE PRESENT AFTER FLUSHING, GET MED ATTN. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN & GET MED ATTN. IN HAL: REMOVE TO FRESH AIR. SUPPORT BRTHG(GIVE OXYGEN/ARTF RESP) . INGEST: CALL MD IMMED . LITHIUM METAL CONT: SKIN: REMOVE PARTICLES OF LITHIUM FROM SKIN AS RAPIDLY AS POSS. (ING 7) ===================== Fire Fighting Measures ===================== Extinguishing Media:COPIOUS AMTS OF COLD WATER IS AN EFFECTIVE EXTING MEDIUM FOR LITHIUM BATTERIES. DO NOT USE WARM WATER/HOT (SUP DAT) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIP . DURING WATER APPLICATIONS, CAUTION IS ADVISED AS BURNING PIECES OF LIGHITUM MAY BE EJECTED FROM FIRE. Unusual Fire/Explosion Hazard:BATTERIES MAY FLAME/LEAK POTENTIALLY HAZ ORG VAPS IF EXPOSED TO EXCESS HEAT/FIRE. FIRE/EXCESS HEAT MAY PRDCE HAZ DECOMP PRODS. DAMAGED/OPENED BATTERIES(SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MAY LEAK &/FLAME IF OPENED, RECHARGED, CONNECTED IMPROPERLY/DISP OF IN FIRE. DO NOT STORE IN A MANNER THAT ALLOWS TERMINALS TO SHORT CIRCUIT. Other Precautions:STORE IN COOL (<70F), DRY AREA THAT IS SUBJECT TO LITTLE TEMP CHANGE. DO NOT PLACE NEAR HEATING EQUIP, NOR EXPOSE TO DIRECT SUNLIGHT FOR LONG PERIODS. ELEVATED TEMPS CAN RSLT IN REDUCED BATTERY SERVIC E LIFE. (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA: WATER. LITH-X (CLASS D EXTING MEDIA) IS EFFECTIVE ON FIRES INVOLVING ONLY A FEW CELLS. DO NOT USE CARBON DIOXIDE/HALON TYPE EXTING. DRY CHEM TYPE EXTING HAVE LIMITED EXTING POTENTIAL. EX PLO HAZ: CAN RSLT IN RAPID HEATING & RELEASE OF FLAM VAPS. VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED (ING 6) ================== Physical/Chemical Properties ================== Appearance and Odor:NONE SPECIFIED BY MANUFACTURER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:BATTERY MUST BE COMPLETELY DISCHARGED PRIOR TO DISP &/TERMINALS MUST BE TAPED/CAPPED TO PVNT SHORT CIRCUIT. DISP BY INCIN/BURIAL AT PERMITTED WASTE TREATMENT &/DISP SITE. DISP OF LGE QTYS OF LITHIUM P OWER CELLS MAY BE SUBJECT TO FED, STATE/LOC REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENVIRO SAFE CLEANER AND DEGREASER, 82122 Preparer's Name:STEPHEN REPETTO CAGE:62377 CAGE:62377 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% Ingred Name:P-MENTHA-1,8-DIENE; (DIPENTENE) CAS:138-86-3 RTECS #:OS8100000 Fraction by Wt: 1-20% Ingred Name:HYDROCARBON PROPELLANT Fraction by Wt: 1-10% ACGIH TLV:1000 PPM (MFR) Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 1-10% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-PROPANOL, 1-BUTOXY; (PROPYLENE BASED GLYCOL ETHER). LEL: 1.1%. UEL: 14.4%. CAS:5131-66-8 RTECS #:UA7700000 Fraction by Wt: 1-10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE EYE, SKIN AND RESPIRATORY IRRITATION AND DEFATTING OF SKIN. VAPORS MAY CAUSE EUPHORIA LEADING TO BLACK-OUT. HARMFUL OR FATAL IF INGESTED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HEADACHE, NAUSEA, DIZZINESS. NARCOSIS AT HIGH CONCENTRATIONS. Medical Cond Aggravated by Exposure:SKIN DISEASES OR ERUPTIONS; RESPIRATORY DISEASES OR CONDITIONS. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. CALL MD. INHAL: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL MD. SKIN: FLUSH WITH WATER. EYES: FLUSH FOR AT LEAST 15 MINUTES WITH WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:140F,60C Lower Limits:SEE INGRED Upper Limits:SEE INGRED Extinguishing Media:CO2, WATER FOG, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CANS MAY RUPTURE IN FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. MAINTAIN ADEQUATE VENTILATION. SOAK UP WITH AN INERT ABSORBENT. STORE IN A CLOSED CONTAINER UNTIL DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 130F TO PRESERVE SHELF LIFE. AVOID PROLONGED BREATHING VAPOR. KEEP AWAY FROM EYES. AVOID SKIN CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:PROVIDE ADEQUATE LOCAL VENTILATION TO MAINTAIN VAPOR CONCENTRATION BELOW TLV. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V3 Vapor Pres:95PSIG@130 Vapor Density:>1 Spec Gravity:0.99 Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:>50% Appearance and Odor:CLOUDY LIQUID WITH MIXED SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:IRRITATING ORGANIC VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE FOLLOWING EPA AND FEDERAL, STATE AND LOCAL REGULATIONS FOR DISPOSAL OF PRESSURIZED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PTY202 PIG REPAIR PUTTY CAGE:FO648 CAGE:1JA49 CAGE:FO648 ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN, EPOXY RESIN, EPON 820, ARALDITE 6004, 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN CAS:25068-38-6 RTECS #:KD4380000 Fraction by Wt: 10-15% Ingred Name:MERCAPTAN TERMINATED POLYETHER Fraction by Wt: 10-15% Ingred Name:2,4,6-TRI(DIMETHYLAMINOMETHYL)PHENOL, DMP-30 CAS:90-72-2 RTECS #:SN3500000 Fraction by Wt: 1-3% Ingred Name:AMORPHOUS FUSED SILICA, SILICON DIOXIDE, QUARTZ, SILICON (SUSPECTED HUMAN CARCINOGEN BY IARC - GROUP 2A) *94-4* CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: 20% Other REC Limits:30 MG/CUM TOTAL DUST ACGIH TLV:0.1 MG/CUM (RESP) IC Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 35-45% ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:ZINC SULFIDE*94-4* CAS:1314-98-3 Fraction by Wt: 1-3% Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL SUFFICIENT/HUMAN LIMITED EVIDENCE BY IARC, NTP). GROUP 2A - *94-4* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 10% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:0.1 MG/CUM RESP DUST ACGIH TLV:0.1 MG/CUM RESP DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: POSSIBLE SENSITIZER. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:EYES/SKIN: POSSIBLE SENSITIZER. ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, FOAM, CO2/DRY CHEMICALS. Fire Fighting Procedures:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP AS A NON-HAZARDOUS SUBSTANCE. ======================Handling and Storage ====================== Other Precautions:AVOID EYE CONTACT & EXCESSIVE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:NONE REQUIRED. Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:WASH W/SOAP & WATER IMMEDIATELY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.9 Solubility in Water:NEGLIGIBLE Appearance and Odor:PUTTY LIKE SUBSTANCE W/A SLIGHT MERCAPTAN ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE Hazardous Decomposition Products:ALDEHYDES, ACIDS, CO/OXIDES OF SULFUR & NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:A-A-50493 TYPE I CAGE:0CF76 CAGE:0CF76 ============= Composition/Information on Ingredients ============= Ingred Name:OXYGENATED HYDROCARBON Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 OIL MIST ACGIH TLV:5 MG/M3 OIL MIST Ingred Name:PETROLEUM HYDROCARBONS (NOT SPECIFIED) Fraction by Wt: 90% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 OIL MIST ACGIH TLV:5 MG/M3 OIL MIST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS VERY MILDLY IRRITATING TO BODY TISSUES. MOST LIKELY HAZARD IS THAT OF BREATHING THE MIST OR VAPORS SHOULD THE PRODUCT BE HEATED OR MISTED. Effects of Overexposure:EYE:MILD IRRITATION. SKIN:POSSIBLE MILD IRRITATION. INHALED:RESPIRATORY IRRITATION,POSSIBLE PULMONARY EDEMA OR CHEMICAL PNEUMONITIS IF MIST IS INHALED. INGESTED:NONE REPORTED. Medical Cond Aggravated by Exposure:NONE REPORTED ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF NECESSARY.INGESTED:D O NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES OF MILK OR WATER AND GET IMMEDIATE MEDICAL CARE. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS SEVERE,SEE A DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:125F,52C Lower Limits:0.7 Upper Limits:5.0 Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. WATER, ESPECIALLY STREAM, MAY CAUSE FROTHING. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER AS LIQUID IF POSSIBLE. ADSORB REMAINDER ON EARTH,SAND,SAWDUST,ETC. KEEP OUT OF DRAINS, SEWERS, AND WATERWAYS. STORE IN CLOSED CONTAINERS PENDING DISPOSAL. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. KEEP AWAY FROM IGNITION SOURCES OR OXIDIZERS. KEEP TIGHTLY CLOSED. Other Precautions:READ ALL LABELS BEFORE USING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR OIL MIST IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE. Ventilation:NORMAL ROOM VENTILATION SHOULD BE SUFFICIENT. SUPPLEMENT WITH LOCAL EXHAUST IF NEEDED (OIL MIST). Other Protective Equipment:AS NEEDED TO PREVENT PROLONGED/REPEATED CONTACT. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE. MINIMIZE PERSONAL CONTACT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:302F,150C Vapor Pres:1 MM Vapor Density:4.5 Spec Gravity:.8121 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR BROWN LIQUID, ODOR NOT GIVEN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NOT GIVEN BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE, LOCAL REGULATIONS. MFR SUGGESTS INCINERATE IF UNABLE TO RECYCLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-S-001992,COLOR CHIP #33564,YELLOW CAGE:EO554 CAGE:EO554 CAGE:61945 ============= Composition/Information on Ingredients ============= Ingred Name:WATER (SOLVENT) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >53% Ingred Name:PIGMENTS Fraction by Wt: >20% Ingred Name:VEHICLE (TYPE NOT SPECIFIED) Fraction by Wt: >12% Ingred Name:ADDITIVES Fraction by Wt: 2% ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN: IRRITATION. INGESTION: GASTRONIMICAL IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER 15 MINUTES. SKIN: WASH WITH SOAP AND WATER,USE EMOLLIENT CREAM. INGESTION: INDUCE VOMITTING AT ONCE,SEE PHYSICIAN. INHALTION: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Fire Fighting Procedures:WATER FOG TO COOL EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:DRIED FILMS ARE CAPABLE OF BURNING. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL WITH INERT MATERIAL,TRANSFER LIQUID TO CONTAINERS FOR RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWERS OR OPEN BODIES OF WATER,FLOORS MAY BE SLIPPERY. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT FREEZE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH EXPOSURE OF CONCERN. Ventilation:LOCAL Other Protective Equipment:EYE WASH STATION,AS NEEDED TO PREVENT SKIN CONTACT. Supplemental Safety and Health CONTAINER SIZE: 1 GAL. CLASS B. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F/100C Vapor Pres:17 Spec Gravity:1.08 Evaporation Rate & Reference:1 (WATER) Solubility in Water:SLIGHT Appearance and Odor:OPAQUE COLORED LIQUID,SLIGHT ODOR. Percent Volatiles by Volume:>65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:TOXIC MONOMER FUMES,OXIDES OF CARBON AND NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION OR LANDFILL IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ICP CALIBRATION STANDARD CAGE:ENVRN CAGE:ENVRN ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (MFR CAS NO:76967-37-2) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 2% OSHA PEL:2 PPM;4 PPM STEL ACGIH TLV:2 PPM;4 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROCHLORIC ACID (SARA III) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 1% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VARIOUS METALS & METAL SALTS Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POISON, CORROSIVE, PRIMARY IRRIT TO ALL TISSUES. BURNS, IRRITS SKIN, EYES, AIRWAYS, MOUTH, STOMACH. MAY CAUSE METHEMOGLOBINEMIA. MAY CAUSE BLINDNESS, COUGH, PULM EDEMA, PERFORATION OF GI TRACT. MAY SE NSITIZE SKIN & CAUSE ALLERGIC DERM. MAYCAUSE ASTHMA & DEATH. SKIN & EYES:BURNING, PAIN & REDNESS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:INHAL:PAIN, BURNING, COUGH, SHORTNESS OF BREATH. INHAL OF DRIED RESIDUE MAY CAUSE ASTHMA. MAY CAUSE CYANOSIS & DEATH. INGEST:BURNING, PAIN, VOMIT. NOTE:FOR INFO ON SPECIFIC METALS/METAL SALTS IN PROD CONT ERA AT 303-431-8454. ALL CONCS ARE BELOW THOSE WHICH MIGHT BE EXPECTED TO CAUSE ANY TOX EFTS UNDER(SUPDAT) Medical Cond Aggravated by Exposure:DERMATITIS, CONJUNCTIVITIS, ASTHMA, BRONCHITIS, COUGH OF NON-SPECIFIC NATURE. CONGENITAL METHEMOGLOBINEMIA. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. GIVE MOIST OXYGEN. GET MEDICAL ATTENTION PROMPTLY. SKIN:FLUSH W/WATER FOR 15 MINUTES. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. INGEST:GIVE WATER OR MILK, IF SWALLOWED. D O NOT GIVE ALKALI. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/WATER OR NEUTRALIZE & WASH TO DRAINS. OR, NEUTRALIZE & ABSORB. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM FREEZING & ROUGH HANDLING TO AVOID BREAKAGE. STORE WHERE SAFETY SHOWER IS AVAILABLE. Other Precautions:AVOID BREATHING OR HANDLING DRIED DUSTY RESIDUE. DO NOT MAKE MIST OR AEROSOLS. TRACE METALS ARE PRESENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF MIST IS PRODUCED A NIOSH/MSHA APPROVED DUST/ MIST ACID GAS RESPIRATOR IS REQUIRED. Ventilation:LOCAL EXHAUST/MECHANICAL: USE IN HOOD. VENTILATE SPILLS. Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . ACID RESISTANT APRON W/SLEEVES. LABORATORY COAT, CLOSED SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP:ORDINARY CNDTNS OF USE & HNDLG. IF MATL IS INGESTED, INHALED OR CONTACTS SKIN/EYES, PRINCIPAL EFTS WILL BE THOSE OF ACID SOLN. IF INGESTED/INHALED CHRONICALLY, BIOLOGICAL TOXICITY DUE TO THE METALS MAY OCCUR. EYE PROT: W/FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:23.76 @25C Vapor Density:HVR/AIR Spec Gravity:1 (H2O=1) pH:2 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:WATER CLEAR; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISPOSE OF AS NON-HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SKYFLEX AIRCRAFT SEALANT Preparer's Name:THOMAS E DYKES CAGE:17217 CAGE:17217 ============= Composition/Information on Ingredients ============= Ingred Name:POLYTETRAFLUOROETHYLENE CAS:9002-84-0 RTECS #:KX4025000 Minumum % Wt:90. Maxumum % Wt:99. Ingred Name:INORGANIC PIGMENTS = Wt:1. ===================== Hazards Identification ===================== LD50 LC50 Mixture:INHALATION LC50 RAT >4900 MG/M3 Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO HEALTH EFFECTS UNDER NORMAL HANDLING & USE. OVERHEATING MAY CAUSE IRRITATION OF THE EYES, SKIN & RESPIRATORY TRACT/POLYMER FUME FEVER. INHALATION: MAY RESULT IN TEMPORARY LUNG IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, FEVER, CHILLS, COUGH, DIFFICULTY BREATHING, SHORTNESS OF BREATH Medical Cond Aggravated by Exposure:PRE-EXISTING DISEASES OF THE LUNGS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR AT ONCE. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. SKIN: IF MOLTEN MATERIAL GETS ON SKIN, COOL RAPIDLY W/COLD WATER. DON'T ATTEMPT TO REMOVE MATERIAL FROM SKIN. EY ES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:DRY CHEMICAL, CO2, WATER/REGULAR FOAM. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:KEEP PERSONNEL REMOVED FROM & UPWIND OF FIRE. USE SELF CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:HYDROGEN FLUORIDE FUMES EMITTED DURING A FIRE CAN REACT W/WATER TO FORM HYDROFLUORIC ACID. ================== Accidental Release Measures ================== Spill Release Procedures:MATERIAL MAY PRESENT A SLIPPING HAZARD. COLLECT BY SWEEPING/VACUUMING ANY LOOSE MATERIAL TO PREVENT ACCUMULATION OF PRODUCT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY AREA. Other Precautions:AVOID BREATHING DUST/DECOMPOSTION PRODUCTS. AVOID CONTAMINATION OF CIGARETTES/TOBACCO W/DUST FROM THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. USE ONLY NIOSH/MSHA APPROVED RESPIRATORS. Ventilation:LOCAL EXHAUST WHEN HEATING/MELTING MATERIAL. VENTILATION SHOULD BE PROVIDED IAW/GUIDELINES IN INDUSTRIAL VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING NOT REQUIRED UNLESS FOR PROTECTION FROM THERMAL BURNS OR DUST. Work Hygienic Practices:WASH HANDS AFTER HANDLING. SMOKERS SHOULD AVOID CONTAMINATED TOBACCO PRODUCTS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.4-1.7 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE/GRAY, RIBBED/NON-RIBBED, MARSHMALLOWY TAPE W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MOLTEN ALKALINE METALS, STRONG OXIDIZERS, STRONG ACIDS, REACTIVE INTERHALOGEN COMPOUNDS Stability Condition to Avoid:HEATING >572F, LONG PROCESSING TIME, HIGH TEMPERATURES Hazardous Decomposition Products:HYDROGEN FLUORIDE, CARBONYL FLUORIDE, CO, CO2 =================== Toxicological Information=================== Toxicological Information:AT VERY HIGH/REPEATED EXPOSURE LEVELS, ANIMALS WERE SUFFOCATED BY ACCUMULATED DUST IN THE LUNGS. ===================== Ecological Information ===================== Ecological:NO INFORMATION AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLING/LANDFILL. INCINERATE ONLY IF INCINERATOR IS CAPABLE OF SCRUBBING OUT HYDROGEN FLUORIDE & OTHER ACIDIC COMBUSTION PRODUCTS. TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL SHOULD BEIN ACCORDA NCE W/LOCAL, STATE & FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:NONE Federal Regulatory Information:INGREDIENTS ON TSCA INVENTORY LIST. RCRA STATUS: THIS PRODUCT WOULD NOT BE A HAZARDOUS WASTE BY LISTING. HOWEVER, UNDER RCRA, IT IS THE RESPONSIBILITY OF THE PRODUCT USER TO DETERMINE AT THE TIME OF D ISPOSAL, WHETHER A MATERIAL CONTAINING THE PRODUCT/DERIVED FROM THE PRODUCT SHOULD BE CLASSIFIED AS A HAZARDOUS WASTE. 40 CFR 261.20-24. State Regulatory Information:POLYTETRAFLUOROETHYLENE: PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLCR2-2Y, CUSTOM PLASMA STANDARD 1,000 (SUPDAT) Preparer's Name:SUSHA RAMANO CAGE:04XT3 CAGE:04XT3 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 2-5% OSHA PEL:2 PPM ACGIH TLV:2 PPM; 4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CHROMIUM (III) NITRATE, NONAHYDRATE (1:3:9); (CR(NO*3)3-9H*2O). % WT: 0.77-7.7. LD50: (ORAL, RAT) 3250 MG/KG. CAS:7789-02-8 RTECS #:GB6300000 Fraction by Wt: <7.7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 88-90% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SYMPS & HEALTH HAZARDS FOR DILUTE NITRIC ACID ARE EXPECTED TO BE LESS SEVERE THAN EXPOSURE TO CONCENTRATED NITRIC ACID. HOWEVER, SINCE NITRIC ACID IS IN SOLUTION AT 1% (OR 10,000 PPM) OR GREATER, HEAL TH HAZARDS FOR CONCENTRATED NITRIC ACIDARE GIVEN. THIS SOLUTION MAY CAUSE IRRIT IF INHALED, INGESTED OR ABSORBED THRU SKIN. IT WILL CAUSE IRRIT IF IT COMES INTO CONTACT W/EYES. TRIVALENT CHROMIUM SALT S ARE CONSIDERED TO BE CARCIN. HOWEVER, THERE IS NOT ENOUGH INFO ABOUT CARCIN OF HEXAVALENT CHROMIUM SALTS SUCH AS CHROMIUM NITRATE. CARCINOMA OF LUNGS IS OF GREATEST CONCERN ASSOCIATED W/INDUSTRIAL ( EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: EXPOS TO CHROMIUM. PRLNGD EXPOS CAN CAUSE DMG TO LIVER & KIDNEYS & PROMOTE STOMACH PAINS, VOMIT, DIARR & GASTRIC CANCER. BLOOD CHANGES SUCH AS LEUKOCYTOSIS, LEUKOPENIA, MONOCYTOSIS & EOSINOP HILLA MAY ALSO OCCUR FOLLOWING EXPOS TO CHROMIUM CMPDS. CONCENTRATED NITRIC ACID MAY BE FATAL IF TOO MUCH IS INHALED/ABSORBED THRU SKIN. CONCENTRATED NITRIC ACID VAP/MIST IS IRRITANT OF EYES, MUC MEMB S & SKIN. IN CNTCT W/EYES, PRDCES SEV BURNS WHICH MAY RSLT IN PERM DMG & VISUAL IMPAIRMENT. ON SKIN, LIQ/CONCENTRATED VAP PRDCES IMMED, SEV & PENETRATING BURNS; CONCENTRATED SOLNS CAUSE DEEP ULCERS & STAIN SKIN BRIGHT YELLOW OR (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MIN OCCASIONALLY LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING THEN FLUSH W/WATER FOR AT LEAST 15 MIN. WASH CLOTHING THOROUGHLY BEFORE REUSE. IN HAL: MOVE TO FRESH AIR. INGEST: DO NOT INDUCE VOMITING. GET IMMED MEDICAL HELP. IF PATIENT IS CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. IF IRRITATION CONTINUES, GET MEDICAL ATTENTION IMMED. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONCENTRATED HNO*3 IS NOT COMBUST BUT IS STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE IGNIT. CAN REACT W/METALS TO RELS FLAM HYDROGEN GAS. CONCENTRATED HNO*3 REACTS EXPLO W/C OMBUST ORGANIC OR READILY OXIDIZABLE MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN SULFIDE, ETC. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUTRALIZE W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS APPRVD RESP. Neutralizing Agent:NEUTRALIZE W/SODA ASH, LIMESTONE, ETC. ======================Handling and Storage ====================== Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP TIGHTLY SEALED WHEN NOT IN USE. Other Precautions:WARNING: IRRITANT, OXIDIZER, CORROSIVE. AVOID INHALATION, INGESTION AND CONTACT WITH EYES AND SKIN. WASH CAREFULLY AFTER USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR. Ventilation:USE IN A CHEMICAL FUME HOOD. FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR CHEMICAL RESISTANT CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART #: PPM CHROMIUM IN 2% NITRIC ACID. EFTS OF OVEREXP: YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOSED TEETH W/PRLNGD EXPOS. INGEST OF LIQ WILL CAUSE IMMED PAIN & BURNS OF MOUTH , ESOPHAGUS & GI TRACT. INHAL MAY BE FATAL CAUSING SPASM, INFLAM & EDEMA OF LARYNX & BRONCHI, CHEM (OTHER INFO) ================== Physical/Chemical Properties ================== Spec Gravity:APPROX 1 Solubility in Water:SOLUBLE Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLO W/COMBUST ORGANIC OR READILY OXIDIZABLE MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYDROGEN SULFIDE, ETC. CONTACT WITH STRONG BASES WILL CAUSE VIO Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE & USE. ELEVATED TEMPS MAY CAUSE CONTAINERS TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN. Hazardous Decomposition Products:WILL RELEASE TOXIC NITORGEN OXIDE FUMES AND VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:05-RED CAGE:0AU16 CAGE:0AU16 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 4% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:NAPHTHA, MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 2% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NAPHTHA, LIGHT AROMATIC CAS:64742-95-6 Fraction by Wt: 5% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:NAPHTHA, LIGHT ALIPHATIC (PETROLEUM) (THIS MATERIAL CONTAINS UP TO 5 VOL.% BENZENE AND 20 VOL.% N-HEXANE) CAS:64742-89-8 Fraction by Wt: 4.5% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 40% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HYDROCARBON PROPELLANT (BLEND PROPANE & ISOBUTANE) CAS:68476-86-8 Fraction by Wt: 35% OSHA PEL:1000 PPM (MFR) Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 7% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 5% OSHA PEL:400 PPM ACGIH TLV:400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:WHEN SANDED MAY BE AN IRRIT TO RESP TRACT. CHRONIC:PRLNGD EXPOS MAY LEAD TO PULM INVOLVEMENT. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD , KIDNEYS & LIVER ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) & ETHYLENE GLYCOL MONOBUTYL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ETHER ACETATE (EGBEA). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118. DIZZINESS, NAUSEA, HEADACHE & POSSIBLE SKIN & EYE IRRITATION. Medical Cond Aggravated by Exposure:INCREASES & SUSTAINS CARBOXY HEMOGLOBIN LEVELS IN THE BLOOD, REDUCING OXYGEN CARRYING CAPACITY IN THE BLOOD. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION. KEEP QUIET & WARM. DO NOT USE ADRENALIN. EYE:FLUSH CONTACTED AREAS W/PLENTY OF WATER FOR AT LEAST 15 MINS. IF PERSISTENT, GET MEDICAL ATTENTION.SKIN:WASH W/SOAP & WATER. IF PERSISTENT, GET MEDICAL ATTENTION. INGEST:GET PROMPT MEDICAL ATTENTION. DO NOT GIVE ADRENALIN. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:-156F,-104C Lower Limits:1.8% Upper Limits:9.5% Extinguishing Media:12 BC EXTINGISHER, CARBON DIOXIDE & FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP (FP N ). STOP RELS OF MATLS IF POSSIBLE. COOL STORAGE CONTAINER. AVOID ACCUM OF UNBURNED MATL. EXCLUDE AIR. Unusual Fire/Explosion Hazard:EXPANSION OF LIQ & CHANGE OF STATE FROM LIQ TO VAP WILL ALLOW COMBUST MIX TO ENCOMPASS LGE AREA. VAPS HVR THAN AIR. MAY TRAVEL TO AN IGNIT SOURCE & FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. ABSORB LIQUID W/INERT MATERIAL SUCH AS SAND OR VERMICULITE. PLACE IN LEAK PROOF CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID WATER CONTACT & HIGH TEMPERATURES IN STORAGE. Other Precautions:DO NOT PUNCTURE CANS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE. USE EITHER AN ATMOSPHERE SUPPLYING RESPIRATOR OR ORGANIC VAPOR. Ventilation:USE EXPLOSION PROOF VENTILATION TO CONTROL VAPOR CONCENTRATION. Other Protective Equipment:IMPERVIOUS CLOTHING. Work Hygienic Practices:WASH W/SOAP & WATER AFTER EACH USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:-44F,-42C Vapor Pres:70 Vapor Density:1.83 Spec Gravity:0.90 Solubility in Water:MINIMAL Appearance and Odor:THIN RED LIQUID; TYPICAL PAINT AROMA. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:TEMPERATURES OVER 120F. AVOID HEAT, SPARKS & OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE & HYDROGEN CHLORIDE GAS. Conditions to Avoid Polymerization:TEMPERATURES OVER 120F. STORAGE NEAR OXIDIZING MATERIAL. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS ORDINARY PAINT IN ACCORDANCE W/FEDERAL, STATE, LOCAL REQUIREMENTS.
1
eyes_protection_mandatory