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===================== Product Identification ===================== Product ID:SODIUM GLUCONATE CAGE:0UGZ0 CAGE:0UGZ0 Contract Num:SP0450-01-M-ZG42 CAGE:0V485 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM GLUCONATE CAS:527-07-1 RTECS #:LZ5235000 OSHA PEL:5 MG/M3 (N DUST) ACGIH TLV:5 MG/M3 (N DUST) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DUST MAY CAUSE IRRITATION OF MUCOUS MEMBRANE AND RESPIRATORY TRACT. EYE/SKIN/INGESTION: NO DATA AVAILABLE. CHRONIC: NO DATA AVAILABLE. Explanation of Carcinogenicity:NONE Effects of Overexposure:NHALATION: DUST MAY CAUSE IRRITATION OF MUCOUS MEMBRANE AND RESPIRATORY TRACT. EYE/SKIN/INGESTION: NO DATA AVAILABLE. CHRONIC: NO DATA AVAILABLE. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER ======================= First Aid Measures ======================= First Aid:GENERAL ADVICE: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES. IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE. INHALTION: MOVE TO FRESH AIR. IF SYMPTOMS PERSISTS, CALL PHYSICIAN. SKIN CONTACT: WASH OFF WITH SOAP AND WATER. IF SKIN IRRITATION PERSISTS, CALL PHYSICIAN. EYE CONTACT: FLUSH EYES WITH WATER AS A PRECAUTION. IF EYE IRRITATION PERSISTS, CONSULT SPECIALIST. INGESTION: DRINK WATER AS A PRECA UTION. CONSULT A PHYSICIAN IF NECESSARY. PROTECTION OF FIREFIGHTERS: NO HAZARD WHICH REQUIRE SPECIAL FIRST AID MEASURES. ===================== Fire Fighting Measures ===================== Autoignition Temp:>200.C, 392.F Extinguishing Media:WATER, WATER SPRAY, DRY POWDER, FOAM, CARBON DIOXIDE Fire Fighting Procedures:USE PERSONAL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRE IN ENCLOSED AREA. STANDARD PROCEDURES FOR CHEMICAL FIRES. Unusual Fire/Explosion Hazard:NO DATA PROVIDED BY MANUFACTURER ================== Accidental Release Measures ================== Spill Release Procedures:SUE PERSONAL PROTECTIVE EQUIPMENT. AVOID DUST FORMATION. SWEEP UP AND SHOVEL. AFTER CLEANING, FLUSH AWAY TRACES WITH WATER. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL TECHNICAL PROTECTIVE MEASURES REQUIRED. NO SPECIAL HANDLING ADVICE REQUIRED. KEEP TIGHTLY CLOSED IN A DRY AND COOL PLACE. NO SPECIAL RESTRICTIONS ON STORAGE WITH OTHER PRODUCTS. STORE IN OR IGINAL CONTAINER. Other Precautions:NO DATA PROVIDED BY MANUFACTURER ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST RESPIRATOR Ventilation:PROVIDE GENERAL DILUTE VENTILATION. Other Protective Equipment:LLIGHT WEIGHT PROTECTIVE CLOTHING. Work Hygienic Practices:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. Supplemental Safety and Health SYNONYMS: GLUCONIC ACID, SODIUM SALT, PENTAHYDROXYHEXANOIC ACID, SODIUM SALT, PENTAHYDROXYCAPROIC ACID, SODIUM SALT. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:N/E Melt/Freeze Pt:M.P/F.P Text:170-175C Decomp Temp:Decomp Text:196-198C Vapor Pres:NOT VOLATILE pH:6/5-7.5 Evaporation Rate & Reference:0 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE/OFF-SHITE GRANULAR POWDER; NONE TO SLIGHTLY PLEASANT SWEETISH ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZIERS Stability Condition to Avoid:KEEP CONTAINERS DRY AND TIGHTLY CLOSED TO AVOID MOISTURE ABSORPTION AND CONTAMINATION. Hazardous Decomposition Products:NO DECOMPOSITION IF STORED NORMALLY. THERMAL DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS. =================== Toxicological Information=================== Toxicological Information:ACUTE TOXICITY: LD0/IV/RABBIT = 7600-8700 MG/KG. LOCAL EFFECTS: NO DATA AVAILABLE. CHRONIC TOXICITY: NO DATA AVAILABLE. HUMAN EXPERIENCE: HEALTH INJURIES ARE NOT KNOWN OR EXPECTED UNDER NORMAL USE. ===================== Ecological Information ===================== Ecological:MOBILITY: COMPLETELY SOLUBLE. CHEMICAL OXYGEN DEMAND (COD): = 807 MG O2/G. BIOLOGICAL OXYGEN DEMAND WITHIN 5 DAYS (BOD5): = 507 MGO2/G. DIN EN 29888 (OECD 302B): READILY BIODEGRADEABLE (98% AFTER 2 DA YS). BIOACCUMULATION: NO DATA AVAILABLE. ECOTOXICITY EFFECTS: TOXICITY TO FISH = LD50 > 10,000 MG/L. TOXICITY TO BACTERIA = ECO > 5,000 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO FEDERAL, STATE AND LOCAL AUTHORITIES. =================== MSDS Transport Information =================== Transport Information:NOT A HAZARDOUS MATERIAL FOR DOT SHIPPING. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III: NOT CONSIDERED HAZARDOUS. Federal Regulatory Information:CERCLA: NOT HAZARDOUS. THE INGREDIENTS ARE LISTED ON THE TSCA INVENTORY LIST. SODIUM GLUCONATE IS GENERALLY RECOGNIZED AS SAFE (GRAS) BY THE USA FDA. State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAY-CLEAN PASTE FLUX CAGE:27911 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CHLORIDE CAS:7646-85-7 RTECS #:ZH1400000 < Wt:40. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PETROLATUM CAS:8009-03-8 RTECS #:SE6780000 < Wt:80. Ingred Name:ETHYLENE GLYCOL CAS:107-21-1 RTECS #:KW2975000 < Wt:15. ACGIH STEL:C127 MG/M3;C50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AMMONIUM CHLORIDE CAS:12125-02-9 RTECS #:BP4550000 < Wt:10. ACGIH TLV:10 MG/M3 ACGIH STEL:20 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 < Wt:10. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:AMMONIUM CHLORIDE: PROLONGED BREATHING OF FUMES MAY CAUSE IRRITATION OF RESPIRATORY PASSAGES. PETROLATUM: MAY CAUSE SKIN IRRITATION UPON CONTINUAL USE. ZINC CHLORIDE: FUME OR DUST CAN CAUSE DERMATITIS , AND CONJUNCTIVIS. MAY CAUSE RASHES, BOILS, CORNEAL BURN, EPIGASTRIC PAIN, NAUSEA, VOMITING, SHOCK (INTERNAL). Effects of Overexposure:AMMONIUM CHLORIDE: PROLONGED BREATHING OF FUMES MAY CAUSE IRRITATION OF RESPIRATORY PASSAGES. PETROLATUM: MAY CAUSE SKIN IRRITATION UPON CONTINUAL USE. ZINC CHLORIDE: FUME OR DUST CAN CAUSE DERMATITIS , AND CONJUNCTIVIS. MAY CAUSE RASHES, BOILS, CORNEAL BURN, EPIGASTRIC PAIN, NAUSEA, VOMITING, SHOCK (INTERNAL). ======================= First Aid Measures ======================= First Aid:IF SWALLOWED, GIVE PLENTY OF WATER OR MILK. DO NOT INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY. SKIN-FLUSH WITH WATER. INHALATION-IRRITATES RESPIRATORY SYSTEM-MOVE TO FRESH AIR. EYES-EYE IRRITANT-FLUS H WITH WATER AT LEAST 15 MIN. PROMPTLY GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=254.4C, 490.F Lower Limits:2.0 Upper Limits:12.0 Extinguishing Media:NONFLAMMABLE MATERIAL. Fire Fighting Procedures:IF LARGE QUANTITIES ARE INVOLVED IN A FIRE, FIREFIGHTERS SHOULD USE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:WHEN HEATED THE MATERIALS MAY RELEASE ZINC CHLORIDE AND ZINC OXIDE FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:CANTAIN SPILL, ABSORB, SWEEP-UP, DISPOSE, FLUSH AREA WITH WATER TO CHEMICAL SEWER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENTILATION TO KEEP THE FUMES AND GASES BELOW TLV'S IN THE WORKER'S BREATHING ZONE AND THE GENERAL AREA. FILTER LENS OF APPROPRIATE Other Protective Equipment:WEAR HEAD AND BODY PROTECTION WHICH HELP TO PREVENT INJURY FROM SPLASHING, SPARKS AND FLAME. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:=90.C, 194.F Vapor Pres:<0.10 PSI Vapor Density:1.106 Spec Gravity:1.11 pH:5.0 - 5.5 Appearance and Odor:TAN/GOLD COLOR PASTE, NO APPRECIABLE ODOR. Percent Volatiles by Volume:84 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH CYANIDES; MAY RELEASE HCL GAS WHEN MIXED WITH ZINC CHLORIDE. IF COMBINED WITH SULFIDES, THE LIQUID FLUX MAY RELEASE H2S GAS. Stability Condition to Avoid:FLUX IS STABLE MATERIAL IN CLOSED CONTAINERS AT ROOM TEMPERATURE UNDER NORMAL STORAGE & HANDLING CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. ===================== Regulatory Information ===================== SARA Title III Information:INDIVIDUAL FLUXES COVERED BY THIS MSDS MAY CONTAIN TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OFTHE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 3 72.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7164 ALERT ORANGE CAGE:KRYLO CAGE:KRYLO ============= Composition/Information on Ingredients ============= Ingred Name:ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM), HYDROTREATED HEAVY, NON AROMATIC HEAVY NAPHTHA) ISOPAR G CAS:64742-48-9 Fraction by Wt: 7% Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 21% OSHA PEL:2400 MG/CUM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1), CALCIUM CARBONATE, DURAMITE CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 25% Other REC Limits:10 MG/CUM (DUST) Ingred Name:PROPANE (DIMETHYLMETHANE)*96-2* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 13% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:BUTANE, N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 13% Other REC Limits:800 PPM OSHA PEL:800 PPM ACGIH TLV:1900 MG/CUM Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-2* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY SYSTEM. MAY CAUSE CNS DEPRESSION & POSSIBLY DEATH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, DIZZINESS, LOSS OF COORDINATION, ITCHING, REDNESS & BURNING SENSATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING BEFORE REUSE. EYES: FLUSH W/LARGE AMOUNT OF WATE R FOR 15 MINS. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOV EW/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. AVOID BREATHING SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE CAN'T BE CONTROLLED BELOW APPLICABLE LIMITS, WEAR PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<395F Vapor Density:>1 Evaporation Rate & Reference:FASTER THAN ETHER Percent Volatiles by Volume:>75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:FIRE: CO2, CO & OXIDES OF METAL. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HEPACIDE QUAT Preparer's Name:THOMAS J MITCHELL CAGE:23212 CAGE:23212 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: >1% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RATS): >5 G/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. REMOVE CONTACT LENSES. SKIN: FLUSH W/PLENTY OF WATER FOR 15 MINS. INGESTION: DRINK LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH W/WATER. ======================Handling and Storage ====================== Other Precautions:AVOID CONTAMINATION OF FOOD. DON'T GET IN EYES, SKIN/CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:GOOD/GENERAL: SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST: MAY BE NECESSARY FOR SOME OPERATIONS. Other Protective Equipment:NONE Supplemental Safety and Health PH: 10.5-11.5. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:210F Vapor Pres:18 Spec Gravity:0.997 pH:(SUPP) Evaporation Rate & Reference:(BU AC = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID W/SLIGHT AMINE ODOR Percent Volatiles by Volume:0-2/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A SANITARY SEWER, IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:ADHESIVE RESIN C-7 Preparer's Name:M. MUNSELL CAGE:02684 CAGE:02684 ============= Composition/Information on Ingredients ============= Ingred Name:BENTONITE CAS:1302-78-9 RTECS #:CT9450000 Other REC Limits:*=AIR (TOTAL DUST) OSHA PEL:15MG/M3 ACGIH TLV:10MG/M3* Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 Other REC Limits:*=AIR (TOTAL DUST) OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3* Ingred Name:DIGLYCIDYL ETHER OF BISPHENOL A. EPOXY RESIN CAS:25068-38-6 RTECS #:CE6880000 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:(HEATED PRODUCT MAY PRODUCE INHALABLE VAPORS.) HEALTH HAZARDS: SKIN IRRITATION: IRRITANT. EYE IRRITATION: IRRITANT. SENSITIZATION: POSSIBLE IN SUSCEPTIBLE INDIVIDUALS. Effects of Overexposure:SKIN AND EYE IRRITATION AND ALLERGIC SKIN AND RESPIRATORY REACTIONS. Medical Cond Aggravated by Exposure:SKIN AND EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. INGESTION:IF CONS CIOUS, GIVE PLENTY OF WATER TO DRINK. DO NOT INDUCE VOMITING. CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN AND/OR ARTIFICIAL RESPIRATION, IF NEEDED. CALL A PHYSICIAN. OTHER : REFERRAL TO A PHYSICIAN IS RECOMMENDED IF THERE IS ANY QUESTION ABOUT THE SERIOUSNESS FO ANY INJURY. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=136.7C, 278.F 278F Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING! COMBUSTIBLE.CAUSES SKIN AND EYE IRRITATION. MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION. KEEP AWAY FROM HEAT AND FLAME. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID BREATHINGVAPOR OR MIST.AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. Other Precautions:KEEP CONTAINER CLOSSED. USE WITH ADEQUATE VENTILATIONS. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR WHEN VAPOR/MIST EXPOSURE IS LIKELY. Ventilation:GENERAL MECHANICAL AND LOCAL EXHAUST IN ACCORDANCE WITH ACGIH RECOMMENDATIONS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:<0.00001@ 25'C Spec Gravity:1.43-1.53 (WATER = 1) Solubility in Water:INSOLUBLE Appearance and Odor:BLACK PASTE/ MILD ODOR Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, MINERAL ACIDS, AND BASES. Stability Condition to Avoid:ELEVATED TEMPERATURES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF NITROGEN. ===================== Ecological Information ===================== Ecological:NUISANCE DUST MAY BE GENERATED WHEN SANDING OR SAWING CURED MATERIAL. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT QUALIFIED LOCAL OR CORPORATE PERSONNEL FOR METHOD THAT WILL COMPLY WITH LOCAL, STATE AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS. ===================== Regulatory Information ===================== Federal Regulatory Information:TSCA EXPORT NOTIFICATION: THIS PRODUCT CONTAINS CHEMICALS WHICH ARE REGULATED BY TSCA12(B) REGULATION AND IT IS REQUIRED THAT PROPER EXPORT NOTIFICATION SHALL BE SENT TO EPA PRIOR TO SHIPPINGOUT OF THE UNITED STATES OF AMERICA. 1) BISPHENOL A DIGLYCIDYL ETHER State Regulatory Information:PENNSYLVANNIA RIGHT-TO-KNOW ACT: THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION- 1) BENTONITE 2) CALCIUM CARBONATE (LIMESTONE) 3) PHENOL, 4,4'-(1-METHYLETHYLIDENE)BIS POLYMER WITH (CHLORO METHYL)OXIRANE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T.E.C. TRACE ELEMENT CERTIFIED PERMANENT (S CAGE:86874 CAGE:86874 ============= Composition/Information on Ingredients ============= Ingred Name:DYES Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 OSHA PEL:100 PPM;150 STEL ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS NOT CONSIDERED TOXIC UNDER FEDERAL HAZARDOUS SUBSTANCES ACT REGULATIONS, TITLE 16, PART 1500. NEITHER THE PRODUCT NOR ANY OF THE INGREDIENTS HAS BEEN FOUND TO BE A CARCINOGEN POTENTIAL CARCINOGEN BY NTP, IARC, OR OSHA. THE PRODUCT IS CONSIDERED SAFE WHEN USED UNDER NORMAL CONDITIONS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:TOLUENE (108-88-3) APPEARS ON THE NAVY LISTING OF OCCUPATIONAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE RECOMMENDATIONS . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH POTABLE WATER FOR A MINIMUM OF 15 MIN. SEEK ASSISTANCE FROM MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GI VE O*2/ARTF RESP) INGEST: GET MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:<73F,<23C Lower Limits:1% Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH ABSORBENT MATERIAL AND DISCARD AS SOLID WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT SHAKE MARKER. KEEP CAP ON MARKER WHEN NOT IN USE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE UNDER NORMAL USE CONDITIONS. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE UNDER NORMAL USE CONDITIONS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR TRADE NAME/PART NO: MARKERS FINE TIP/BROAD TIP BLACK. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:232F,111C Vapor Pres:22 @ 68F Vapor Density:HVR/AIR Spec Gravity:< WATER Evaporation Rate & Reference:SLOWER THAN ETHER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD AS SOLID WASTE. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TM-620, MOLD CLEANER AND DEGREASER CAGE:2F853 CAGE:2F853 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 73% Other REC Limits:NONE RECOMMENDED OSHA PEL:350 PPM ACGIH TLV:350 PPM/450STEL;9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:ETHYLENE, TETRACHLORO-; (PERCHLOROETHYLENE) CAS:127-18-4 RTECS #:KX3850000 Fraction by Wt: 24% OSHA PEL:100 PPM ACGIH TLV:25PPM/100,A3 STEL;94 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 3% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:MAY CAUSE DIZZINESS OR NARCOSIS IN HIGH VAPOR CONCENTRATIONS. WILL CAUSE DEFATTING OF SKIN. EFFECTS ARE REVERSIBLE. LONG TERM EXPOSURE (YEARS) TO VAPOR MAY CAUSE LUNG, LIVER OR KIDNEY DAMAGE. SOLVENTS LISTED HAVE BEEN REPORTED TO AFFECT THE CNS. INHAL: DFCLTG IN BRTHG. SKIN: REDNESS. INGEST: VOMIT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:TETRACHLOROETHYLENE: GROUP 2 (NTP), GROUP 2B (IARC). Effects of Overexposure:HLTH HAZ: CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAVE SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICA TED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . Medical Cond Aggravated by Exposure:HEART DISEASE; RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL: CALL MD . GIVE O2. INGEST: DO NOT INDUCE VOMIT. CALL MD . GASTRIC LAVAGE. EYES: WASH WITH WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE WATER FOG, DRY CHEMICAL OR CO2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT . AEROSOL CANS MAY RUPTURE WHEN HEATED. Unusual Fire/Explosion Hazard:HEATED CANS MAY BURST. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL, PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT SWEEPING COMPOUND TO SOAK UP MATERIAL. PUT INTO CONTAINER. DISPOSE AS HAZARDOUS WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAME. STORE @ TEMPERATURES BELOW 120F. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED SCBA IF TLV LIMIT EXCEEDED. WHEN SPRAYING MORE THAN ONE HALF CAN CONTINUOUSLY OR MORE THAN ONE CAN CONSECUTIVELY, USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST. Other Protective Equipment:LONG SLEEVE AND LONG PANTS. Work Hygienic Practices:DO NOT SMOKE WHILE USING. WASH HANDS AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>162F,>72C Vapor Pres:100 Vapor Density:HVR/AIR(4) Spec Gravity:1.5 Evaporation Rate & Reference:>1(BUTYL ACETATE=1) Solubility in Water:NONE Appearance and Odor:CLEAR/SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SOLVENT INGREDIENTS ARE INCOMPATIBLE WITH STRONG OXIDIZERS. NOT COMPATIBLE WITH ACTIVE METALS. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:IN FIRE WILL DECOMPOSE TO HALOGEN ACIDS AND PHOSGENE, CO2 AND WATER. HCL . ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE IN ACCORDANCE WITH EPA RCRA. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHANOIC ACID;GLACIAL ACETIC ACID CAGE:0GDF9 CAGE:0GDF9 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD 50 ORAL RAT IS 3310 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HEALTH HAZARDS: ACUTE: SEVERE IRRITATION AND BURNS. MAY CAUSE PERMANENT EYE DAMAGE. CHRONIC: LUNG DAMAGE. Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN. Effects of Overexposure:EYES/SKIN: SEVERE IRRITATION AND BURNS. INHALATION: SEVERE IRRITATION TO RESPIRATORY SYSTEM. INGESTION: SEVERE BURNING TO MOUTH AND STOMACH, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING EYE, SKIN OR RESPIRATORY DISEASES MAY BE MORE AT RISK BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE OXYGEN/CPR IF NEEDED. SEE DOCTOR. I NGESTION: DO NOT INDUCE VOMITING. GIVE WATER, MILK OR MILK OF MAGNESIA. SEE DOCTOR IMMEDIATELY. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:109F,43C Lower Limits:5.4 Upper Limits:16.0 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. COMBUSTIBLE AND CORROSIVE VAPORS. FIGHT FIRE FROM DISTANCE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL. ELIMINATE IGNITION SOURCES. VENTILATE AREA. WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS. NEUTRALIZE SPILL. ABSORB IN INERT MATERIAL AND PLACE IN APPROPIATE D ISPOSAL CONTAINER AND COVER. FLUSH AREAWITH WATER Neutralizing Agent:SODA ASH OR LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. FLAMMABLE LIQUID STORAGE AREA OR CABINET. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA-APPROVED RESPIRATOR OR SCBA AS APPROPIATE FOR EXPOSURE OF CONCERN. Ventilation:MECHANICAL (GENERAL) VENTILATION OR LOCAL EXHAUST VENTILATION TO KEEP EXPOSURE LEVELS BELOW PEL. Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:62.0F,16.7C Vapor Pres:11.4 Vapor Density:2.07 Spec Gravity:1.049 pH:2.4 Evaporation Rate & Reference:0.97 (BUTYL ACETATE = 1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID, PUNGENT ODOR, CHARACTERISTIC OF VINEGAR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID, METALS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER D001, D002 (IGNITABLE, CORROSIVE WASTE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LS 10 LIQUID SHIELD CAGE:DABCX CAGE:DABCX ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:WASH AFFECTED AREA W/SOAP & WATER. EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. INGEST:INDUCE VOMITING W/FINGERS TO BACK OF THROAT. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONFINE & WIPE UP W/ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTAINERS FROM ABUSE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE. Ventilation:LOCAL EXHAUST:NOT REQUIRED. Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:>1 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:100% Appearance and Odor:BLUE; SLIGHT CHARACTERISTIC ODOR. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AT APPROVED FACILITY I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ATF 210 CAGE:1G112 CAGE:6G112 CAGE:1G112 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST') CAS:8012-95-1 RTECS #:PY8030000 Fraction by Wt: >85% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3/10 STEL;9192 Ingred Name:ADDITIVES Fraction by Wt: <15% ===================== Hazards Identification ===================== Effects of Overexposure:SLIGHT EYE IRRITATION. SLIGHT SKIN IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH W/H*2O FOR AT LEAST 15 MIN. SKIN CONTACT: WASH CONTACT AREAS W/SOAP & H*2O. INHALATION: NOT EXPECTED TO BE A PROBLEM. INGEST: NOT EXPECTED TO BE A PROBLEM. HOWEVER,IF > 1/2 LITER (P INT) INGESTED,IMMED GIVE 1-2 GLASSES (SEE SUPP DAT ===================== Fire Fighting Measures ===================== Flash Point:350F,177C Lower Limits:0.6 Upper Limits:7.0 Extinguishing Media:CO*2,FOAM,DRY CHEMICAL & H*2O FOG Fire Fighting Procedures:FIREFIGHTERS MUST USE SCBA Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ADSORB ON FIRE RETARDANT TREATED SAWDUST,DIATOMACEOUS EARTH,ETC. SHOVEL UP & DISPOSE OF AT AN APPROPRIATE WASTE DISPOSAL FACILITY IN ACCORDANCE W/CURRENT APPLICABLE LAWS & REGULATIONS, & PRODUCT CHARA CTERISTICS AT TIME OF DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL PRECAUTIONS REQUIRED. EQUIPMENT REQUIRED. HOWEVER,GOOD PERSONAL HYGIENE PRACTICES SHOULD PRACTICES ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMNTS W/ORDINARY CONDITNS OF USE,ADEQUATE VENTILATN Ventilation:NO SPECL REQUIREMNT W/ORDINARY CONDITNS OF USE,ADEQUATE VENT Supplemental Safety and Health VAP PRESS: <0.1 MMHG. FLASH POINT:(METHOD) ASTM D-92. EMER & FIRST AID PROC: OF H*2O & CALL PHYSICIAN,HOSPITAL EMER RM,POISON CONTROL CTR. DONT INDUCE VOMIT/GIVE ANYTHING ORALLY TO UNCON PERSN ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>600F,316C Spec Gravity:0.868 Solubility in Water:NEGLIGIBLE Appearance and Odor:RED LIQUID,MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE WASTE IN A SOLVENT & DISPOSE BY SUPERVISED INCINERATION IN COMPLIANCE W/APPLICABLE LAWS & REGULATIONS. WASTE DISPOSAL MUST BE IAW FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHENOL RED SOLUTION 0.02%, SI24500 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 > Wt:99. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:PHENOL, 4,4'-(3H-2,1-BENZOXATHIOL-3-YLIDENE)BIS-, S,S-DIOXIDE, MONOSODIUM SALT CAS:34487-61-1 < Wt:1. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE MILD IRRITATION. LOW HAZARD FOR NORMAL INDUSTRIAL HANDLING. SKIN: MAY CAUSE MILD IRRITATION. LOW HAZARD FOR NORMAL INDUSTRIAL HANDLING. INGESTION: INGESTION OF LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL IRRITATION. LOW HAZARD FOR NORMAL INDUSTRIAL HANDLING. INHALATION: INHALATION OF VAPOR MAY CAUSE RESPIRATORY TRACT IRRITATION. LOW HAZARD FOR NORMAL INDUSTRIAL HANDLING. CHRONI C: NO INFORMATION FOUND. TARGET ORGANS: NONE. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: GENTLY LIFT EYELIDS & FLUSH CONTINUOUSLY W/WATER FOR AT LEAST 15 MINUTES. IF IRRITATION DEVELOPS, GET MEDICAL AID. SKIN: GET MEDICAL AID IF IRRITATION DEVELOPS/PERSISTS. FLUSH SKIN W/PLENTY OF S OAP & WATER. INGESTION: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL AID IF IRRITATION/SYMPTOMS OCCUR. INHALATION:REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID IF COUGH/OTHER SYMPTOMS APPEAR. NOTES TO PHYSICIA N: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NON-FLAMMABLE; USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:SUBSTANCE IN NON-FLAMMABLE. NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. ABSORB SPILL WITH INERT MATERIALS (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID INGESTION AND INHALATION. STORE IN A COOL, DRY PLACE. KEEP CONTAINERS TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN STANDARD EN 149 MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. WE AR NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PHYSICAL/CHEMICAL PROPERTIES: MOLECULAR FORMULA: NOT APPLICABLE, MIXTURE; MOLECULAR WEIGHT: NOT AVAILABLE. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:17.5 MM HG Spec Gravity:1 pH:NEUTRAL Solubility in Water:SOLUBLE Appearance and Odor:RED LIQUID, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. Stability Condition to Avoid:INCOMPATIBLE MATERIALS. Hazardous Decomposition Products:SULFUR DIOXIDE, CARBON MONOXIDE, CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:RTECS: CAS # 7732-18-5: ZC0110000; CAS # 34487-61-1: UNLISTED. LD50/LC50: CAS # 7732-18-5: ORAL, RAT: LD50 = >90 ML/KG. CARCINOGENICITY: NO INGREDIENTS LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPID EMIOLOGY: NO DATA AVAILABLE. TERATOGENICITY: NO DATA AVAILABLE. REPRODUCTIVE EFFECTS: NO DATA AVAILABLE. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: NO DATA AVAILABLE. OTHER STUDIES: NO DATA AVAIL ABLE. ===================== Ecological Information ===================== Ecological:RCRA U-SERIES: NONE LISTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT: NO INFORMATION AVAILABLE. IMO/IATA: SHIPPING NAME: ETHANOL SOLUTION; HAZARD CLASS: 3; UN NUMBER: 1170; PACKING GROUP: II. RID/ADR: SHIPPING NAME: ETHANOL SOLUTION; DANGEROUS GOODS CODE: 3(3B); UN NUMBER: 1170. CANADIAN TDG: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:US FED: TSCA: ALL INGS ARE LISTED ON TSCA INVENTORY. HLTH & SFTY REPORTING LIST: NONE OF THE CHEMS ARE ON THE HLTH & SFTY REPORTING LIST. CHEM TEST RULES: NONE OF THE CHEMS ARE UNDER A CHEM TEST RULE. SECTION 12B: NONE OF THE CHEMS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMS HAVE A SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CONTAIN ANY HAZ AIR POLLUT ANTS, ANY CLASS 1 OZONE DEPLETORS/ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF THE CHEMS AR E LISTED AS HAZ SUBSTANCES UNDER CWA. NONE OF THE CHEMS ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. (OTHER INFO) State Regulatory Information:THE INGREDIENTS IN THIS PRODUCT ARE NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PASTEL BASE, F77W101, QUICK DRY ENAMEL, NON CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ING 12:DAM. NOTE:TOLUENE 108-88-3 APPEARS ON THE NAVY LISTING OF OCCUP REPROD HAZARDS. SEEK CONSULTATION FROM (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:APPROP HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE RECOMMENDATIONS . RTECS #:9999999ZZ Ingred Name:OTHER PREC:BONDING & GROUNDING PROCEDURES. TRANSFER ONLY TO APPRVD CONTRS W/COMPLETE & APPROP LABELING. DO NOT (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIB CONCENTRATING/INHALING THE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:CONTENTS CAN BE HARMFUL/FATAL. THIS COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:IN INGRED SECTION, APPLIC LIMITS FOR NUISANCE DUSTS ARE TLV 10 MG/M3 (TOTAL DUST), PEL 15 MG/M3 (TOTAL (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:DUST), 5 MG/M3 (RESPIRABLE FRACTION). DOL STORAGE CATEGORY 1B. RTECS #:9999999ZZ Ingred Name:RESP PROT:APPROVED DUST/MIST RESP FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:VM & P NAPHTHA. VP:12 CAS:64742-48-9 Fraction by Wt: 10-50% OSHA PEL:300 PPM; 400 STEL ACGIH TLV:300 PPM Ingred Name:MINERAL SPIRITS. VP:2 CAS:64742-47-8 Fraction by Wt: 0-5% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:TOLUENE (SARA III). VP:22 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 0-35% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL; (ETHYL BENZENE) (SARA III). VP:7.1 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <5% OSHA PEL:100 PPM; 125 STEL ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA III). VP:5.9 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5-25% OSHA PEL:100 PPM; 150 STEL ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT AROMATIC NAPHTHA). VP:3.8 CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 5-10% ACGIH TLV:100 PPM (MFR) Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE). VP:70 CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 0-5% OSHA PEL:200 PPM;300 PPM STEL ACGIH TLV:200 PPM;300 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY-2-PROPANOL ACETATE). VP:1.8 CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 0-5% Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 0-20% OSHA PEL:2 MG/M3 RDUST ACGIH TLV:2 MG/M3 RDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MATLS TO AVOID:IN DANGEROUSLY INCREASED PRESSURES IN CLOSED CONTAINERS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD/PRLNGD OVEREXPOS TO SOLV W/PERM BRAIN & NERV SYS (ING 13) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXPOS MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESIVE EXPOS TO VAPS/SPRAY MI STS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC: METHYL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:ETHYL KETONE MAY INCR NERV SYS EFTS OF OTHER SOLV. PRLNGD OVEREXPOS TO SOLV INGREDS IN INGRED SECTION MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD FORMING, CARDIO-VASCULAR & REPROD SYS. RA TS EXPOSED TO TITANIUM DIOXDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT (ING 12) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:FLUSH W/LARG E AMOUNTS OF WATER FOR AT LEAST 15 MINS. GET MEDICAL ATTENTION. INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:35F,1.7C Lower Limits:0.7 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL & FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD (SUPP DATA) Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT/ELEC EQUIP/SPARKS/OPEN FLAME. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATN TO HOT SURF (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE FLAMM. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES. KEEP CONTR CLSD WHEN NOT IN USE. USE ONLY W/ADEQ VENT. AVOID BRTHG VAPOR/SPRAY MIST. Other Precautions:AVOID CONT W/SKIN & EYES. DURING USE/UNTIL ALL VAPS ARE GONE:KEEP AREA VENTD; DO NOT SMOKE; EXTING ALL FLAMES/PILOT LIGHTS/HEATERS; TURN OFF STOVES/ELEC TOOLS & APPLIANCES/ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD (ING 15) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMITS BY VENT, WEAR A PROPERLY FITTED NIOSH/MSHA APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGRED SECTION. WHEN SANDING/ABRADING DR IED FILM, WEAR A NIOSH/MSHA (ING 21) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN INGRED SECTION IS MAINTAINED BELOW APPLIC EXPOS (ING 22) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. TO MINIMIZE EXPOSURE FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION & PERSONAL PROT EQUIP. Supplemental Safety and Health FIRE FIGHT PROC:CONTRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION OR EXPLOS WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:REQS SPEC PRECS. DURING EMER CNDTNS OVEREXPOS TO DECOMP PRODS MAY CAUSE A HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAINMEDICAL ATTENTION. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>174F,>79C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:0.86-1.1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:69-72 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALLICS CONTAIN ALUMINUM. CONTAM W/WATER, ACIDS OR ALKALIS CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY RSLT (ING 11) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE & CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER THE RCRA 40CFR261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE NOS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CONTR. DISP OF I/A/W FED, STATE & LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TOWER MARKSOL 213 CAGE:9W454 CAGE:9W454 ============= Composition/Information on Ingredients ============= Ingred Name:PARAFFIN-NAPHTAENES (ALIPHATIC HYDROCARBONS) CAS:64742-88-7 OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 OSHA PEL:S,100PPM/150STEL ACGIH TLV:S,100PPM/150STEL9192 Ingred Name:LANOLIN CAS:8006-54-0 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE MAY LEAD TO CENTRAL NERVOUS SYSTEM DEPRESSION, LEADING TO HEADACHES, NAUSEA AND UNCONSCIOUSNESS. EYE: MAY LEAD TO IRRITATION. SKIN: MAY LEADMATITIS. Explanation of Carcinogenicity:THE COMPONENTS OF THIS PRODUCT HAVE NOT SHOWN ANY EVIDENCE OF BEING CARCINOGENIC. Effects of Overexposure:OVEREXPOSURE MAY LEAD TO DIZZINESS, HEADACHES, DERMATITIS AND EYE IRRITATION. Medical Cond Aggravated by Exposure:PERSONS WITH HEART, RESPIRATORY, OR ANY OTHER MEDICAL CONDITION SHOULD USE CAUTION WHEN HANDLING OR USING THIS PRODUCT. CONSULTATION WITH PHYSICIAN IS RECOMMENDED. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH WITH WATER, GET MEDICAL ATTENTION IF NECESSARY. INHALATION: REMOVE TO FRESH AIR, GET MEDICAL ATTENTION IF NECESSARY. EYE: FLUSH WITH WATER, GET MEDICAL ATTENTION. INGESTION: GET MEDICAL AT UBJECT IS UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:110.0F,43.3C Lower Limits:1.0 Upper Limits:5.0 Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. UPON COMBUSTION, THIS PRODUCT MAY FORM CARBON NOMOXIDE AND OTHER ORGANIC COMPOUNDS. CONTAINERS OF THIS PRODUCT MAY RUPTURE IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:MINOR: ABSORB MATERIAL WITH CLAY, VERMICULITE, OR SIMILAR ABSORBENT MATERIAL. PLACE IN DISPOSAL CONTAINERS. MAJOR: DIKE & CONTAIN SPILL. ELIMINATE SOURCES OF IGNITION. SHUT OFF LEAKS. REMOVE LIQUID BY VACUUM OR ABSORBENT. FLUSH RESIDUE WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VENTILATED WORK AREA. KEEP CONTAINERS CLOSED WHEN NOT IN USE. COMBUSTIBLE LIQUID; EMPTY CONTAINERS CAN BE HAZARDOUS. Other Precautions:IF VENTILATION IS INSUFFICIENT, USE NIOSH/MSHA APPROVED RESPIRATOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. AIR-SUPPLIED OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED. Ventilation:LOCAL AND MECHANICAL(GENERAL) EXHAUST RECOMMENDED. AVOID OPEN ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS. Other Protective Equipment:SAFETY SHOES, EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT. WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:318.0F Vapor Pres:2.4 Vapor Density:4.8 Spec Gravity:0.78 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, PETROLEUM ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER COMPOUNDS DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ALL WASTE IN ACCORDAMCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PALLADIUM(II) CHLORIDE, 99%, 20588-5 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:PALLADIUM (2+) CHLORIDE; (PALLADIUM (II) CHLORIDE) CAS:7647-10-1 RTECS #:RT3500000 Fraction by Wt: 99% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 2704 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ART IFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL PHYSICIAN. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIA L PICKUP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. Other Precautions:HARMFUL SOLID. IRRITANT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:REDDISH-BROWN POWDER AND CHUNKS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CATALYSTS AND EXPENSIVE METALS SHOULD BE RECOVERED FOR REUSE OR RECYCLING. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EUTECTOR 157 FLUX CAGE:EO060 CAGE:72271 CAGE:EO060 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC CHLORIDE (SARA III) CAS:7646-85-7 RTECS #:ZH1400000 OSHA PEL:1 MG/M3/2 STEL ACGIH TLV:1 MG/M3/2STEL FUME93 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AMMONIUM CHLORIDE (SARA III) CAS:12125-02-9 RTECS #:BP4550000 OSHA PEL:10 MG/M3/20 STEL ACGIH TLV:10 MG/M3 FUME; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM FLUORIDE (SARA III) CAS:7681-49-4 RTECS #:WB0350000 OSHA PEL:2.5 PPM F ACGIH TLV:2.5 MG F/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Other REC Limits:50 PPM OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:WELDING FUMES & GASES. INHALATION: DIZZINESS; NAUSEA; DRYNESS OR IRRITATION OF NOSE, THROAT OR EYES, RESPIRATORY SYSTEM; DAMAGE TO LUNGS & ASTHMA; METALLIC TASTE; TIGHTNESS IN CHEST; FEVER; ALLERGIC R EACTIONS; METAL FUME FEVER; VOMITING; COUGH; MUSCULAR PAIN. INGESTION: CAN CAUSE SEVERE INJURY OR DEATH. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: MAY LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNGS)/MAY AFFECT PULMONARY FUNCTIONS, LUNG FIBROSIS OR PNEUMOCONIOSIS/MAY CAUSE NERVOUS DISORDERS. REPEATED EXPOSURE TO FLUORIDES CAN CAUSE SERIOUS BONE EROSION. ARC RAYS CAN INJURE EYES/BURN SKIN. Medical Cond Aggravated by Exposure:ALLERGIC SKIN REACTIONS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO WELL-VENTILATED AREA. CALL FOR MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARC, SPARKS & BRAZING FLAMES CAN IGNITE COMBUSTIBLES & FLAMMABLES. ======================Handling and Storage ====================== Handling and Storage Precautions:TRAIN THE WORKER TO KEEP HIS HEAD OUT OF THE FUMES. Other Precautions:TO DETERMINE THE COMPOSITION/QTY OF FUMES & GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE THE WELDER'S HELMET IF WORN OR IN THE WORKER'S BREATHING ZONE. ARC RAYS CAN INJURE EYES/B URN SKIN. ELECTRIC SHOCK CAN KILL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN CONFINED SPACE, IF >TLV. Ventilation:USE LOCAL EXHAUST VENTILATION TO KEEP <TLV Other Protective Equipment:ARM PROTECTORS, APRONS, HATS, SHOULDER Work Hygienic Practices:GOOD PRACTICE REQUIRES THE REDUCTION OF EMPLOYEE EXPOSURE TO CHROMIUM (VI) MATERIALS. Supplemental Safety and Health TRAIN THE WORKER NOT TO TOUCH LIVE ELECTRICAL PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. ================== Physical/Chemical Properties ================== HCC:C1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHLORINATED HYDROCARBON VAPORS. Stability Condition to Avoid:SPARKS, FLAMES Hazardous Decomposition Products:CO, CO2, OZONE, NITROGEN OXIDES, FLUORIDES, COMPLEX METAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:44, L-TEC SPOOLARC & OXWELD SOLID STEEL (SUP DAT) CAGE:HO829 CAGE:84021 CAGE:HO829 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: <0.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:IRON; (FE) CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MANGANESE; (MN) (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 2% OSHA PEL:C 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST Ingred Name:SILICON; (SI) CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: <0.1% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:COPPER; (CU) (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: <0.5% OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MOLYBDENUM; (MO) CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 0.5% OSHA PEL:10 PPM ACGIH TLV:10 PPM Ingred Name:NICKEL; (NI) (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <1% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:SUP DAT: IN ATM. REASONABLY EXPECTED DECOMP PRODS FROM NORM USE INCL COMPLEX OXIDES OF MATLS IN INGS SECTION, AS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: WELL AS CARBON MONOXIDE & DIOXIDE, OZONE & NITROGEN OXIDES. THE ONLY WAY TO DETERMINE TRUE IDENTITY OF (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: DECOMP PRODS IS BY SAMPLING & ANALYSIS. COMPOSITION & QTY OF FUMES & GASES CAN BE DETERMINED FROM SAMPLE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: OBTAINED FROM INSIDE WELDER'S HELMET, IF WORN/IN WORKERS BRTHG ZONE. FOR MORE SPECIFIC INFO CONT NEHC . RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: IRRIT OF NASAL MEMB & SKIN. NICKEL CMPDS IN FUME CAN CAUSE METALLIC TASTE, NAUS, TIGHTNESS OF (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: CHEST, FEVER, & ALLERGIC RXN. CHRONIC (LONG TERM) OVEREXP TO AIR CONTAMINANTS MAY LEAD TO THEIR ACCUM IN(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: LUNGS, CNDTN WHICH MAY BE SEEN AS DENSE AREAS ON CHEST X-RAYS. SEV OF CHANGE IS PROPORTIONAL TO LENGTH (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: OF EXPOS. CHANGES ARE NOT NEC ASSOC W/SYMPS/SIGNS OF REDUCED LUNG FUNC/DISEASE. LONG TERM OVEREXP TO (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: NICKEL FUMES MAY ALSO CAUSE PULM FIBROSIS & EDEMA. OVEREXP TO MANGANESE CMPDS MAY AFFECT CNS, SYMPS OF (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: WHICH ARE LANGOUR, SLEEPINESS, MUSC WEAK, EMOTIONAL DISTURB & SPASTIC GAIT. CONT NEHC FOR MORE INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. SEE MD . INGESTION: CALL MD IMMEDIATELY . RTECS #:9999999ZZ Ingred Name:EYE PROT: LENS. AS A RULE OF THUMB, START W/SHADE WHICH IS TOO DARK TO SEE WELD ZONE. THEN GO TO NEXT LIGHTER (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. PROVIDE PROT SCREENS & FLASH GOGG, IF NEC, TO SHIELD OTHERS. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: SPKS & ELEC SHOCK. AT MIN, THIS INCL RTECS #:9999999ZZ Ingred Name:ING 21: APRONS, HATS, SHOULDER PROTECTION, AS WELL AS DARK SUBSTANTIAL CLOTHING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: FUMES & GASES CAN BE DANGEROUS TO HLTH. ELEC SHOCK CAN KILL. ARC RAYS CAN INJURE EYES & BURN SKIN. NOISE CAN DMG HEARING. ABSORPTION BY SKIN CONT IS UNLIKELY. WHEN PRODS ARE USED AS REC BY MFR, & VENT MAINTAINS EXPOS TO DECOMP PRODSBELOW LIMS REC IN THIS SECTION, OVEREXP IS UNLIKELY. EFTS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL: IARC MONO, VOL 49, PG 257, 1990: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. HUMAN: LUNG. Effects of Overexposure:HLTH HAZ: OVEREXP TO GASES, FUMES & DUSTS MAY INCL IRRIT OF EYES, LUNGS, NOSE & THROAT. SOME TOX GASES ASSOC W/WELDING MAY CAUSE PULM EDEMA, ASPHY, & DEATH. ACUTE OVEREXP MAY INCL WATERY EYES, NOSE & THROAT IRRIT, HDCH, DIZZ, DFCLTY IN BRTHG, FREQUENT COUGHING/CHEST PAIN. CHROMIUM/CHROMATE IN FUME CAN CAUSE (ING 12) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH ALLERGIES OR IMPAIRED RESPIRATORY FUNCTION. SUCH REACTION CANNOT BE PREDICTED DUE TO VARIATION IN COMPOSITION & QUANTITY OF DECOMPOSITION PRODUCTS. ======================= First Aid Measures ======================= First Aid:IN CASE OF EMER, CALL FOR MED AID. EMPLOY FIRST AID TECHNIQUES REC BY RED CROSS. INHAL: IF BRTHG IS DFCLT, GIVE OXYGEN & CALL FOR MD. FOR ELEC SHOCK, DISCONNECT & TURN OFF POWER. IF NOT BRTHG, BEGIN A RTF RESP, PREF MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE, BEGIN CPR. IMMED CALL MD. FOR ARC BURN, APPLY COLD, CLEAN COMPRESSES & CALL MD. EYES: FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN. SEE MD (ING 18) ===================== Fire Fighting Measures ===================== Extinguishing Media:PROD WILL NOT BURN. USE EXTING MEDIA REC FOR BURNING MATLS & FIRE SITUATION. CONT NEHC FOR MORE SPECIFIC INFO . Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:ONLY THE PACKAGING FOR THIS PRODUCT WILL BURN. HOWEVER, WELDING ARCS AND SPARKS CAN IGNITE COMBUSTIBLE AND FLAMMABLE MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND. Other Precautions:TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACES OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENT, LOC EXHAUST AT ARC/BOTH, TO KEEP FUMES & GASES BELOW TLV IN WORKER'S BREATHING ZONE & GENERAL AREA. Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . WEAR HEAD, HANDS & BODY PROT W/HELP TO PVNT INJURY FROM RADIA, (ING 21) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health TRADE NAME/PART #: WELDING ELECTRODES & RODS. HAZ DECOMP PROD: WORKED, PROCESS, PROC & CONSUMABLES USED. OTHER CNDTNS INCL: COATINGS ON MATL BEING WORKED, NUMBER OF WELDING OPERATIONS & VOL OF WORK AR EA, QUALITY & AMT OF VENT, POSITION OF WORKERS HEAD W/RESPECT TO FUME PLUME, AS WELL AS PRESENCE OF CONTAMINANTS (ING 8) ================== Physical/Chemical Properties ================== Appearance and Odor:COPPER-COATED OR BARE, SOLID STEEL WIRE OR ROD, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE CURRENTLY KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON MATL BEING (SUP DAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER, IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE A ND LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: B COMPONENT-POLYOL RESINS Kit Part: Y Cage: 59134 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 59134 ======================================================= Contractor Summary ======================================================= Cage: 59134 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: ORAL LD50 (RAT): 1780 MG/KG (SEE SUPP) Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INGESTION: IRRITATION OF MOUTH, PHARYNX, ESOPHAGUS, STOMACH. EYES: IRRITATION. SKIN: MILD IRRITATION. SKIN ABSORPTION MAY OCCUR. REPEATED/PROLONGED EXPOSURE MAY CAUSE KIDNEY DISORDERS. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION, HEADACHE, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS. Medical Cond Aggravated By Exposure: SKIN/RESPIRATORY/NEUROLOGICAL DISORDERS, ASTHMA. First Aid: SKIN: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. DON'T APPLY GREASES/OINTMENTS. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. INGESTION: INDUCE VOMITING/REMOVE CONTENTS BY GASTRIC SUCTION ONLY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHINGBY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: MOVE TO FRESH AIR. KEEP QUIET & GIVE OXYGEN. PREVENT ASPIRATION OF VOMIT. (SEE SUPP) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: STOP LEAK IF POSSIBLE/SHUT OFF/REMOVE ALL IGNITION SOURCES. DIKE/COLLECT RUNOFF/TRANSFEER TO DRUMS/TANKS FOR LATER DISPOSAL. PROTECT WORKERS W/WATER SPRAY. ABSORB RESIDUAL MATERIAL ON VERMICULITE & SC OOP UP. FLUSH AREA W/WATER SPRAY. Waste Disposal Methods: INCINERATE IN SUITABLE COMBUSTION CHAMBER. RECOVER/RECLAIM/RECYCLE WHEN PRACTICABLE. DISPOSE OF IN A PERMITTED WASTE MANAGEMENT FACILITY IF INCINERATION/LANDFILL NOT PRACTICABLE IAW/FEDERAL, STATE & L OCAL REGULATIONS. Handling And Storage Precautions: STORE IN TIGHTLY SEALED CONTAINERS. STORE <75F. Other Precautions: PREVENT SKIN/EYES CONTACT. AVOID BREATHING VAPORS/AEROSOLS. WORKERS SHOULD SHOWER/CHANGE TO FRESH CLOTHING AFTER EACH SHIFT. WARNING: MAY CAUSE EYE IRRITATION. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: >200F Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER SPRAY. Fire Fighting Procedures: USE WATER SPRAY TO REDUCE VAPORS/COOL FIRE EXPOSED CONTAINERS. WEAR NIOSH APPROVED SCBA W/INDEPENDENT AIR SUPPLY. SHUT OFF GAS SUPPLY. (SEE SUPP) Unusual Fire/Explosion Hazard: MAY GENERATE TOXIC/IRRITATING/FLAMMABLE COMBUSTION PRODUCTS. MAY GENERATE CARBON MONOXIDE GAS. ======================================================= Control Measures ======================================================= Respiratory Protection: APPROVED POSITIVE PRESSURE FRESH AIR RESPIRATOR IF MATERIAL IS SPRAYED/OTHERWISE ATOMIZED DURING USE. WEAR SELF-CONTAINED BREATHING APPARATUS W/PRESSURE DEMAND MODE IN EMERGENCY SITUATIONS. Ventilation: LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS AT A MINIMUM LEVEL. Other Protective Equipment: APRON, ARM COVERS, FULL BODY SUIT, EYEWASH STATION, SAFETY SHOWER. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. DISCARD CONTAMINATED LEATHER GOODS. Supplemental Safety and Health: BOILING POINT/VAPOR PRESSURE/VAPOR DENSITY/ORAL LD50: INFORMATION IS FOR TRICHLOROFLUOROMETHANE. SPECIAL FIRE CONT'D: CONTAIN RUNOFF WATER IN DIKES. PREVENT STREAM CONTAMINATION. RETAIN EXPENDED LIQUI DS FROM FIRE FIRGHTING FOR LATER DISPOSAL. FIRST AID CONT'D: IF BREATHING HAS STOPPED/IS IMPAIRED, GIVE CPR. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 75F (SUPP) M.P/F.P Text: <32F Vapor Pres: 690 SUPP Vapor Density: 5.06 SUPP Spec Gravity: 1.1-1.18 PH: >7 Evaporation Rate & Reference: (BU 0 AC = 1): >1 Solubility in Water: MODERATE Appearance and Odor: LIGHT AMBER TO DARK BROWN LIQUID W/MILD ODOR. Percent Volatiles by Volume: <25 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPERATURES Materials To Avoid: OXIDIZING AGENTS, PERCHLORATE, NITRATES. Hazardous Decomposition Products: AROMATIC/ALIPHATIC FRAGMENTS, CO, CO2, TETRAHYDROFURAN, HALOGENS, HALOGEN ACIDS, CARBONYL HALIDES. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: B COMPONENT-POLYOL RESINS Cage: 59134 Company Name: UTAH FOAM PRODUCTS INC Street: 3609 S 700 W Zipcode: 84119-2432 Label Required IND: Y Date Of Label Review: 08/11/1994 Status Code: C Label Date: 08/11/1994 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: INGESTION: IRRITATION OF MOUTH, PHARYNX, ESOPHAGUS, STOMACH. EYES: IRRITATION. SKIN: MILD IRRITATION. SKIN ABSORPTION MAY OCCUR. REPEATED/PROLONGED EXPOSURE MAY CAUSE KIDNEY DISORDERS. TARGET ORGANS: SKIN & KIDNEYS. . =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEICER WASHER FLUID, 2024-138 Preparer's Name:JAMES OTTOWITZ CAGE:EO340 CAGE:EO340 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) LEL: 3.2% LD50 (ORAL, RAT): 9100 MG/KG CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 30-40% OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 95 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) UEL: 36% LD50 (ORAL, RAT): 4700 MG/KG CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:C 50 PPM,VAPOR; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: >1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50-70% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP:PERCEPTION, REDUCTION OF VISUAL FIELDS & COMPLETE BLND. W/MASSIVE OVERDOSE, LIVER, (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:KIDNEY & HEART MUSCLE INJURY HAVE BEEN DESCRIBED. THERE MAY BE A DELAY OF SEVERAL HRS BTWN SWALLOWING (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:METHANOL & THE ONSET OF SYMPS. SEV KIDNEY DMG FOLLOWS THE INGEST OF LRG VOL OF ETHYLENE GLYCOL. CHRONIC: (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:LONG TERM RPTD OVEREXP TO METHANOL VAP CONCS OF 3000 PPM GREATER MAY ALLOW A (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CUMULATIVE EFT TO OCCUR W/RSLT NAUS, VOMIT, HDCH, RINGING IN THE EARS, INSOMNIA, TREMBLING, UNSTEADY (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:GAIT, VERTIGO, & CLOUDED & DOUBLE VISION. PRLNG OVEREXP AT LEVELS OF 800 TO 100 PPM MAY RSLT IN SEVERE (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:EYE DMG IN SOME PERS. COMPONENTS OF THIS PROD ARE NOT SUSPECTED CARCIN. SIGNIFICANT LAB DATA W/POSS (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:RELEVENCE TO HUMAN HLTH HAZS:ANIMAL STUDIES SUGGEST THAT ETHYLENE GLYCOL AT HIGH DOSES CAN PRDCE BIRTH DEFECTS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:IF IRRITAT, PAIN, SWELL/TEARING PERSISTS, SEEK IMMED MED ATTN. INGEST:GIVE ONE/TWO GLASSES OF (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:H*2O & INDUCE VOMIT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. IMMED CALL MD, POIS CTL CTR EMER (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:ROOM FOR ASSISTANCE & INSTRUCTIONS ON INDUCING VOMIT & OTHER EMER FIRST AID TREATMENT. NOTES TO MD: (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:COMBINATION OF VISUAL DISTURBANCE, METABOLIC ACIDOSIS & FORMIC ACID IN THE URINE IS EVIDENCE OF METHANOL(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:POISONING. THE PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL WHEN INGESTED, ARE KIDNEY DMG & METABOLIC ACIDOSIS.(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:ETHANOL IS ANTIDOTAL, & ITS EARLY ADMIN MAY BLOCK THE FORMATION OF TOX METABOLITES OF BOTH METHANOL & (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:ETHYLENE GLYCOL. HEMODIALYSIS IS HIGHLY EFFECTIVE AT REMOVING METHANOL, ETHYLENE GLYCOL & THEIR (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:METABOLITIES, AND MAY BE INDICATED DEPENDING UPON THE CLINICAL SITUATION OF BLOOD LEVELS. RTECS #:9999999ZZ Ingred Name:RESP PROT:FOUND IN THE WORK PLACE, MUST BE BASED ON SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMITS OF (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:(NIOSH). A SUPPLIED AIR RESPIR W/FULL FACEPIECE OPERATED IN CONTINUOUS FLOW MODE. POSITIVE PRESS SCBA. (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:ORGANIC VAP CARTRIDGE RESPS ARE NOT REC FOR METHANOL VAP EXPOS. FORE FIREFIGHTING & OTHER IMMED DANGEROUS(ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:TO LIFE OR HEALTH CONDITIONS INCLUDING ALL SITUATIONS OF UNKNOWN CONTAMINANT FACEPIECE & IS OPERATED IN (ING 25) RTECS #:9999999ZZ Ingred Name:ING 24:PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EMER OVERVIEW: FLAMM LIQ! EYE IRRIT. INHAL MAY CAUSE HDCH, DIZZ, DROWS, NAUS, VISUAL IMPAIRMENT, NARCOS & UNCONSCIOUSNESS. POISONOUS IF SWALLOWED. ACUTE:NO ACUTE TOX ETS EXPECTED WHEN PROD IS USED AS DIRECTED. INHAL:INHAL OF HIGH CONC, PARTICULARLY MISTS, MAY CAUSE IRRIT OF THE NOSE & THROAT W/HDCH, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:DIZZ, DROW, & DISTURB OF VISION. SKIN:PRLNG CNTCT W/SKIN TO METHANOL MAY CAUSE REDDENING & DEFAT OF THE SKIN. METHANOL MAY BE ABSORBED THRU THE SKIN POSSIBLY RSLTG IN HARMFUL EFTS. EYE:MAY BE IRRITG & CAUSE PAIN, TEARING, REDDENING & SWELL ACCOMPANIED BY THE STINGING SENSATION &/FEELING LIKE THAT OF (SUPDAT) Medical Cond Aggravated by Exposure:DUE TO ITS DEFATTING PROPERTIES, METHANOL MAY AGGRAVATE AN EXISTING SKIN CONDITION. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPS OF EXPOS DEVELOP, REMOVE TO FRESH AIR. IF BRTHG BECOMES DFCLT, ADMINISTER OXYGEN IF AVAIL. ADMINISTER ARTF RESP IF BRTHG STOPS. SEEK IMMED MED ATTN. SKIN:REMOVE CONTAMD CLTHG. FLUSH EXP OSED SKIN W/COPIOUS AMTS OF H*2O & WASHW/SOAP. IF IRRIT DEVELOPS & PERSISTS, SEEK MED ATTN. EYE:EXPOSED EYES SHOULD BE REMOVED WHILE FLUSHING. FLUSH FOR A MIN OF 15 MIN/UNTIL IRRIT SUBSIDES. (ING 13) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:90.0F,32.2C Lower Limits:SEE INGS Upper Limits:SEE INGS Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL. COOL FIRE EXPOSED CONTAINERS WITH WATER. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FLAMM LIQ. METHANOL-WATER MIX WILL BURN UNLESS VERY DILUTE. FLAME IS INVISIBLE IN DAYLIGHT. VAPS ARE HVR/AIR & MAY FLOW ALONG SURF TO DISTANT IGNIT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT. COLLECT WITH ABSORBENT MATERIAL AND PLACE IN APPROPRIATE, LABELED CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE PROD BELOW 120F & AWAY FROM DIRECT SUNLIGHT. STORE IN A COOL, WELL VENT AREA. DO NOT SWALLOW. AVOID EYE & SKIN CONTACT. AVOID BRTHG VAPS/MISTS. Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. FLAMMABLE LIQUID! KEEP CONTAINER AWAY FROM HEAT, SPARKS, OPEN FLAMES AND ALL OTHER SOURCES OF IGNITION. DO NOT SMOKE DURING USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING RESPS ARE REC ON INFO FOUND IN THE PHYSICAL & CHEM PROPERTIES, TOXICOLOGICAL INFO & HLTH HAZS SECTION. THEY ARE RANKED IN ORDER FROM MIN TO MAXIMUM RESP PROT. THE SPECIFIC RESP MUST BE B ASED ON CONTAM LEVELS (ING 21) Ventilation:USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO MAINTAIN EXPOSURES BELOW THE OCCUPATIONAL EXPOSURE LIMITS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER AFTER USE. Supplemental Safety and Health EXPLO HAZ:SOURCES & FLASH BACK. EFTS OF OVEREXP:FINE DUST IN THE EYES. INGEST:MAY CAUSE NAUS, ABDOM PAIN, VOMIT, SHORTNESS OF BRTH, FATIGUE & LEG CRAMPS. NERVOUS SYS EFTS INCL:HDCH, CONFUSN, DRUNKEN B EHAVIOR, CNS DEPRESS, COMA & DEATH. VISUAL EFTS OF METHANOL INCL BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:158F,70C Melt/Freeze Pt:M.P/F.P Text:-32F,-36C Vapor Pres:36 @ 68F Vapor Density:>1 Spec Gravity:7.9 LBS/GAL pH:7.9 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:100% Appearance and Odor:CLEAR YELLOW LIQUID WITH SLIGHT ALCOHOL ODOR. Percent Volatiles by Volume:>95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT AS HAZARDOUS WASTE (IGNITABLE) IN ACCORDANCE WITH ALL LOCAL, STATE/PROVINCIAL AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CASCOPHEN RS-240 MD (USED W/CATALYST FM124D Kit Part:Y CAGE:JO903 CAGE:JO903 CAGE:07982 ============= Composition/Information on Ingredients ============= Ingred Name:PHENOL CAS:108-95-2 RTECS #:SJ3325000 Fraction by Wt: 6%. OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 8990 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:RESORCINOL(SARA III) CAS:108-46-3 RTECS #:VG9625000 Fraction by Wt: 5%. OSHA PEL:10 PPM/20 STEL ACGIH TLV:10 PPM/20 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <10%. OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:CORROSIVE AND IRRITATING TO EYES, NOSE, THROAT & SKIN IN LIQ. UNCURED STATE.ALLERGIC RXN IN SENSITIV ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.CALL MD.INGEST:CALL MD.SKIN OR EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES.CALL MD.WASH CLOTHING BEFORE REUSE & DESTROY CONTAMINATED SHOES. ===================== Fire Fighting Measures ===================== Flash Point:137F SCC ================== Accidental Release Measures ================== Spill Release Procedures:LARGE:ENCLOSE W/DIKING MATERIAL TO PREVENT RESIN FROM GETTING INTO NATURAL BODIES OF WATER,THEN CALL BORDEN CHEM. SMALL:MAY BE SOAKED UP WITH ANY ABOSRBENT MATERIAL AND REMOVED TO A CHEM DISPOSAL AREA . ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID HIGH TEMPERATURE STORAGE. KEEP AWAY FROM HEAT OR FLAMES. KEEP CONTAINERS CLOSED Other Precautions:DOT CLASSIFICATION:COMBUSTIBLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS,IF NEEDED-NIOSH/MSHA APP. Ventilation:PROVIDE ADEQUATE VENTILATION Supplemental Safety and Health SPECIFIC GRAVITY:1.135-1.145;SOLUBILITY IN WATER:SOLUBLE;DENSITY;HEAVIER THAN AIR. CONFORMS TO MIL-A-22397,GRADE A,PART A OF B PART KIT. SEE NSN,P/N IND:B.KEY1:F4. ================== Physical/Chemical Properties ================== HCC:F4 Appearance and Odor:LIQUID RESIN Percent Volatiles by Volume:47. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:PHENOL & RESORCINOL VAPOR ==================== Disposal Considerations ==================== Waste Disposal Methods:BIODEGRADABLE UNDER PROPER CONDITIONS(CONCENTRATION,RATE OF DISCHARGE,TYPE OF TREATING PLANT,ETC)AS PERMITTED BY LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHYL ALCOHOL, DENATURED (A407) A407SK 4 Resp. Party Other MSDS Num.:08701 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL; LC50 (INHAL, MOUSE): 39 GM/M3/4H; LC50 (INHAL, RAT): 20000 PPM/10H; LD50 (ORAL, MOUSE): 3450 MG/KG; LD50 (ORAL, RABBIT): 6300 MG/KG; LD50 (ORAL, RAT): 7060 MG/KG CAS:64-17-5 RTECS #:KQ6300000 Minumum % Wt:85.4 Maxumum % Wt:92. Other REC Limits:N/K OSHA PEL:1900 MG/M3;1000 PPM OSHA STEL:N/K ACGIH TLV:1880 MG/M3;1000 PPM ACGIH STEL:N/K Ingred Name:METHYL ALCOHOL; LC50 (INHAL, RAT): 64000 PPM/4H; LD50 (ORAL, MOUSE): 7300 MG/KG; LD50 (ORAL, RABBIT): 14200 MG/KG; LD50 (ORAL, RAT): 5628 MG/KG; LD50 (SKIN, RABBIT): 15800 MG/KG CAS:67-56-1 RTECS #:PC1400000 = Wt:3.6 Other REC Limits:N/K OSHA PEL:260 MG/M3;200 PPM OSHA STEL:N/K ACGIH TLV:262 MG/M3;200 PPM ACGIH STEL:328 MG/M3;250 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPYL ALCOHOL; LD50 (ORAL, MOUSE): 3600 MG/KG; LD50 (ORAL, RABBIT): 6410 MG/KG; LD50 (ORAL, RAT): 5045 MG/KG; LD50 (SKIN, RABBIT): 12800 MG/KG CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 25% PPM Other REC Limits:N/K OSHA PEL:980 MG/M3;400 PPM OSHA STEL:N/K ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM Ingred Name:ACETONE; LC50 (INHAL, RAT): 50100 MG/M3/H8; LD50 (ORAL, MOUSE): 3 GM/KG; LD50 (ORAL, RABBIT): 5340 MG/KG; LD50 (ORAL, RAT): 5800 MG/KG; LD50 (SKIN, RABBIT): 20 GM/KG CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 2% PPM Other REC Limits:N/K OSHA PEL:2400 MG/M3;1000 PPM OSHA STEL:N/K ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BENZENE; LC50 (INHAL, MOUSE): 9980 PPM; LC50 (INHAL, RAT): 10000 PPM/7H; LD50 (ORAL, MOUSE): 4700 MG/KG; LD50 (ORAL, RAT): 930 MG/KG; LD50 (SKIN, RABBIT): >9400 MG/KG CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: TRACE Other REC Limits:N/K OSHA PEL:10 PPM OSHA STEL:N/K ACGIH TLV:32 MG/M3;10 PPM ACGIH STEL:N/K EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ACETALDEHYDE; LC50 (INHAL, RAT): 24 GM/M3/4H; LD50 (ORAL, RAT): 661 MG/KG; LD50 (SKIN, RABBIT): 3540 MG/KG CAS:75-07-0 RTECS #:AB1925000 Fraction by Wt: 10% PPM Other REC Limits:N/K OSHA PEL:360 MG/M3;200 PPM OSHA STEL:N/K ACGIH TLV:25 PPM ACGIH STEL:C45 MG/M3;C25 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ISOBUTYL KETONE; LC50 (INHAL, MOUSE): 23300 MG/M3; LD50 (ORAL, MOUSE): 2671 MG/KG; LD50 (ORAL RAT): 2080 MG/KG; LD50 (SKIN, RABBIT): >20 GM/KG CAS:108-10-1 RTECS #:SA9275000 = Wt:1.9 Other REC Limits:N/K OSHA PEL:410 MG/M3;100 PPM OSHA STEL:N/K ACGIH TLV:205 MG/M3;50 PPM ACGIH STEL:307 MG/M3;75 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE; LC50 (INHAL, MOUSE): 400 PPM/24H; LC50 (INHAL, RAT): 49 GM/M3/4H; LD50 (ORAL, RAT): 636 MG/KG; LD50 (SKIN, RABBIT): 12124 MG/KG CAS:108-88-3 RTECS #:XS5250000 = Wt:.8 Other REC Limits:N/K OSHA PEL:see Table Z-2 OSHA STEL:N/K ACGIH TLV:188 MG/M3;50 PPM ACGIH STEL:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ACETATE; LC50(INHAL, MOUSE): 45 GM/M3/2H; LC50(INHAL, RAT): 200 GM/M3; LD50(ORAL, MOUSE): 4100 MG/KG; LD50(ORAL, RABBIT): 4935 MG/KG; LD50(ORAL, RAT): 5620 MG/KG; LD50(SKIN, RABBIT): >20 GM/KG CAS:141-78-6 RTECS #:AH5425000 = Wt:1.3 Other REC Limits:N/K OSHA PEL:1400 MG/M3;400 PPM OSHA STEL:N/K ACGIH TLV:1440 MG/M3;400 PPM ACGIH STEL:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER; LD50 (ORAL, RAT): >90 ML/KG CAS:7732-18-5 RTECS #:ZC0110000 = Wt:5. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM); (SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC) CAS:64742-89-8 > Wt:.72 Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: PRDCES IRRIT, CHARACTERIZED BY BURNING SENSATION, REDNESS, TEARING, INFLAMM, & POSS CORNEAL INJURY. MAY CAUSE PAINFUL SENSIT TO LIGHT. VAPS MAY CAUSE IRRIT. SKIN: MAY CAUSE IRRIT. PRLNG &/OR RPT D CONT MAY CAUSE DEFAT & DERM. MAY BE ABSORBED THRU SKIN. INGEST: MAY BE FATAL/CAUSE BLINDNESS IF SWALLOWED. MAY CAUSE SYSTEMIC TOXICITY W/ACIDOSIS. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE CNS DEPRESS , CHARACTERIZED BY EXCITEMENT, FOLLOWED BY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHA RACTERIZED BY HDCH, (EFTS OF OVEREXP) Explanation of Carcinogenicity:ISOPROPYL ALCOHOL: IARC: GROUP 3 CARCIN. BENZENE: ACGIH: A1-CONFIRMED HUMAN CARCIN; CALIFORNIA: CARCIN-INITIAL DATE 2/27/87; NIOSH: OCCUP CARCIN; NTP: KNOWN CARCIN; OSHA: SELECT CARCIN; IARC: GRP 1 CA RCIN. ACETALDEHYDE: ACGIH: A3-ANIMAL CARCIN; CALIFORNIA: CARCIN-INITIAL DATE 4/1/88; NIOSH: OCCUP CARCIN; NTP: SUSPECT CARCIN; OSHA: POSS SELECT (SUP DAT) Effects of Overexposure:HLTH HAZ: DIZZ, UNCON & COMA. MAY CAUSE RESP TRACT IRRIT. MAY CAUSE EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. MAY CAUSE DROW, UNCON, & CNS DEPRESS. CHRONIC: CHRONIC INHAL & INGEST MAY CAUSE EFTS SIM ILAR TO THOSE OF ACUTE INHAL & INGEST. PRLNG/RPTD SKIN CONT MAY CAUSE DEFAT & DERM. PRLNG/RPTD EXPOS MAY CAUSE ADVERSE REPRO EFTS. MAY CAUSE FETAL EFTS. TOLUENE & BENZENE APPEAR ON THE NAVY OCCUP CHEM REPRO HAZ LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID. IMMED FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MI NUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MED AID. INDUCE VOMITING BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. NOTES TO M D: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:=13.9C, 57.F Autoignition Temp:=362.8C, 685.F Lower Limits:3.3% (ING 1) Upper Limits:19% (ING 1) Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, CHEMICAL FOAM OR ALCOHOL-RESISTANT FOAM. FOR LARGE FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL-RESISTANT FOAM, OR WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. DO NOT USE STRAIGHT STREAMS OF WATER. COOL CONTAINERS WITH FLO ODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK. CONTAINERS MAY EXPLODE IN THE HEAT OF A FIRE. FLAMMABLE LIQUID. MAY FORM EXPLOSIVE PEROXIDES. VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW OR CONFINED AREAS. NFPA RATING: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE ALL SO URCES OF IGNITION. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQ VENT. GROUND & BOND CONTAINERS WHEN TRANSFERRING MATL. AVOID CONT W/EYES, SKIN, & CLOTHING. EMPTY CONTAINERS RETAIN PROD RESIDUE (LIQUID &/OR VAPOR), & CAN BE DANGEROUS. KEEP CONTAINER TIGH TLY CLOSED. AVOID CONT W/SKIN, EYES & CLOTHING. AVOID INGEST & INHAL. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CONTRS TO HEAT, SPKS/OPEN FLAMES. KEEP AWAY FROM HEAT, SPKS, & FLAME. KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLSD CONT RS. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health CARCIN: CARCIN; IARC: GRP 2B CARCIN. TOLUENE: IARC: GRP 3 CARCIN. WASTE DISP METH: CAS# 67-64-1: WASTE # U002 (IGNIT WASTE). CAS# 71-43-2: WASTE # U019 (IGNIT WASTE; TOX WASTE). CAS# 75-07-0: WASTE. C AS# 67-56-1, 67-64-1 & 71-43-2 ARE BANNED FROM LAND DISP ACCORDING TO RCRA. CAS# 75-07-0 IS BANNED. ================== Physical/Chemical Properties ================== Boiling Pt:=78.5C, 173.3F Melt/Freeze Pt:=-90.C, -130.F Vapor Pres:25 MM HG Vapor Density:1.6(ING 1) Spec Gravity:0.7905 Viscosity:NOT AVAILABLE Evaporation Rate & Reference:2.0 Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID WITH AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOPROPANOL IS SUSCEPTIBLE TO AUTOXIDATION & THEREFORE SHOULD BE CLASSIFIED AS PEROXIDIZABLE, ACIDS (MINERAL, NON-OXIDIZING, E.G. HYDROCHLORIC, HYDROFLUORIC, MURIATIC, PHOSPHORIC, NITRIC & SULFURIC ACIDS), ACIDS (ORG, E.G. Stability Condition to Avoid:THIS MATERIAL MAY BE SENSITIVE TO PEROXIDE FORMATION, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:REPRO EFTS: PRENATAL EXPOS TO ETHANOL IS ASSOC W/DISTINCT PATTERN OF CONGENITAL MALFORMATIONS THAT HAVE BEEN COLLECTIVELY TERMED FETAL ALCOHOL SYNDROME. AMONG CHARACTS OF THIS SYNDROME ARE INTRAUTERIN E & POSTNATAL GROWTH DEFICIENCY, A DISTINCTIVE PATTERN OF PHYSICAL MALFORMATION, & BEHAVIORAL/COGNITIVE IMPAIRMENT SUCH AS FINE MOTOR DYSFUNCTION & MENTAL RETARDATION. NOT ALL AFFECTED CHILDREN HAVE A LL OF FEATURES OF SYNDROME. THIS SYNDROME HAS BEEN ASSOC W/ALCOHOLIC WOMEN WHO DRANK HEAVILY & CHRONICALLY DURING PREGNANCY. EPIDEMIOLOGY/TERATOGENICITY/NEUROTOX/MUTAGENICITY/OTHER STUDIES: NO DATA AV AIL. CONT NEHC FOR MORE INFO . ===================== Ecological Information ===================== Ecological:ECOTOXICITY: 250 PPM/6HR/GOLDFISH/LETHAL/FRESH WATER. ENVIRON FATE: ETHANOL: IN WATER, WILL VOLATILIZE & PROBABLY DEGRADE. PHYSICAL/CHEM: NOT AVAIL. OTHER: NOT EXPECTED TO BIOCONCENTRATE IN FISH. OTHE R INFO: (E.G. ALUMINUM CARBIDE, CHLOROSILANE, HYDROGEN PHOSPHIDE, LITHIUM HYDRIDE), WATER REACTIVE SUBSTANCES (E.G. ACETIC ANHYDRIDE, ALKYL ALUMINUM CHLORIDE, CALCIUM CARBIDE, ETHYL DICHLOROSILANE). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FED, STATE, & LOC REGS. RCRA D-SERIES MAX CONC OF CONTAMINANTS: CAS# 71-43-2: WASTE # D018; REG LEVEL=0.5 MG/L. RCRA D-SERIES CHRONIC TOX REFERENCE LEVELS: CAS# 71- 43-2: CHRONIC TOX REFERENCE LEVEL=0.005 MG/L. RCRA F/P-SERIES: NONE LISTED. RCRA U-SERIES: CAS# 67-5 6-1: WASTE # U154 (IGNIT WASTE). (SUP DAT) =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: ETHANOL SOLNS; HAZ CLASS: 3; UN #: UN1170; PACKING GRP: II. IMO/IATA/RID/ADR: NO INFO AVAIL. FED REGS: CLEAN WATER ACT: CAS# 71-43-2/75-07-0/108-88-3: LISTED AS HAZ SUBSTANCES U NDER CWA; CAS# 71-43-2/108-88-3: LISTED AS PRIORITY POLLUTANT UNDER CWA; CAS# 71-43-2/108-88-3: LISTED AS TOX POLLUTANTS UNDER CWA. OSHA: CAS# 75-07-0 CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZ SYMBOLS: F; RISK PHRASES: R 11 HIGHLY FLAM; SFTY PHRASES: S 16 KEEP AWAY FROM SOURCES OF IGNIT-NO SMKNG; S 2 KEEP OUT OF REACH OF CHILDREN; S 7 KEEP CONTR TIGHTLY CLSD. CONT N EHC FOR MORE INFO . ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302(FINAL RQ):CAS# 67-56-1/67-64-1/108-10-1/141-78-6:5000LBS(2270KG);CAS# 71-43-2:10LBS(4.54KG), RECEIVES ADJUSTABLE R; CAS# 75-07-0/108-88-3:1000LBS(454KG). NONE OF CHEMS HAVE TPQ (SECTION 30 2). SARA CODES:CAS# 64-17-5/67-63-0/71-43-2:ACUTE, CHRONIC, FLAM; CAS# 67-56-1/108-88-3:ACUTE, FLAM; CAS# 67-64-1:ACUTE, CHRONIC, FLAM, SUDDEN RELEASE OF PRESS; CAS# 75-07-0/108-10-1:ACUTE, CHRONIC, F LAM. REACTIVE; CAS# 141-78-6:FLAM. SECTION 313:CAS# 67-56-1/67-63-0/75-07-0/108-10-1:SUBJECT TO REPORTING REQS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. CAS# 67-63-0/108-10-1:CONCS TOO LOW T O BE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:ALL INGS ARE LISTED ON TSCA INVENTORY. HLTH & SFTY REPORTING LIST: CAS# 67-63-0: EFFECTIVE DEC 15, 1986, SUNSET DEC 15, 1996; CAS# 108-10-1/108-88-3: EFFECTIVE OCTOBER 4, 1982, SUNSET OCTOBER 4, 1992. CHEM TEST RULES: CAS# 67-63-0: TESTING REQUIRED BY MFRS, IMPORTERS, PROCESSOR. SECTION 12B: CAS# 67-63-0/67-64-1/108-10-1/141-78-6: EXPORT NOTIFICATION REQUIRED-SECTION 4. TSCA SIGNIFICANT NEW USE RU LE : NONE OF CHEMS HAVE SNUR UNDER TSCA. CLEAN AIR ACT: CAS# 67-56-1/71-43-2/75-07-0/108-10-1/108-88 -3: LISTED AS HAZ AIR POLLUTANTS (HAP). MATL DOES NOT CONTAIN ANY CLASS 1 OR 2 OZONE DEPLETORS. (TRANSPORT INFO) State Regulatory Information:ETHYL ALCOHOL, METHYL ALCOHOL, ISOPROPYL ALCOHOL, ACETONE, BENZENE, ACETALDEHYDE, METHYL ISOBUTYL KETONE, TOLUENE & ETHYL ACETATE CAN BE FOUND ON THE FOLLOWING STATE RIGHT-TO-KNOW LISTS: CA, NJ, FL, P A, MN, MA. WATER & SOLV NAPHTHA (PETRO) LIGHT ALIPHATIC ARE NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL/NJ. WARNING: BENZENE IS KNOWN TO STATE OF CA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO H ARM; ACETALDEHYDE IS KNOWN TO STATE OF CA TO CAUSE CANCER; ETHYL ALCOHOL IS KNOWN TO STATE OF CA TOCAUSE BIRTH DEFECTS/OTHER REPRO HARM. CA NO SIGNIFICANT RISK LEVEL: CAS# 71-43-2=7 UG/DAY; CAS# 75-07-0: INHAL=90 UG/DAY. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:READY TO USE LENS CLEANER CAGE:SHELD CAGE:SHELD ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 5% OSHA PEL:400 PPM;500 STEL ACGIH TLV:400 PPM;500 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:IRRITATION. SKIN:IRRITATION, DERMATITIS. INGEST:STOMACH UPSET. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/COOL RUNNING WATER FOR AT LST 15 MINS WHILE HOLDING EYELIDS APART. REMOVE CONTACT LENSES IF APPLIC. S KIN:WASH W/SOAP & WATER. INGEST:CALL 911 IMMED FOR EMER MED ASSISTANCE. DO NOT INDUCE VOMIT. RINSE MOUTH W/WATER, THEN DRINK 1-2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN LARGE SPILLS. ABSORB W/COMMERCIALLY AVAILABLE ABSORBENT. SMALL SPILLS - FLUSH TO SEWER W/WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE. Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH:7 +/- 0.3. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:0.98 +/- 0.002 pH:SUPDAT Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR BLUE LIQUID; LEMON SCENT. Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT STATE, LOCAL & FEDERAL REGULATIONS GOVERNING THE DISPOSAL OF DETERGENTS.
1
eyes_protection_mandatory
======================================================= Product ID: B-BHC SOLUTION AT 100 UG/ML IN METHANOL, PP-120 Cage: 0MU35 ======================================================= Contractor Summary ======================================================= Cage: 0MU35 ======================================================= Ingredients ======================================================= Cas: 67-56-1 RTECS #: PC1400000 MG/KG. % Wt: 99.99 OSHA PEL: 200 PPM, S ACGIH TLV: 200 PPM;250 STEL, S EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 319-85-7 RTECS #: GV4375000 LD50:(ORAL,RAT) 6000 MG/KG. % Wt: 0.013 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS. Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: CONTAINS CARCINOGEN(S) OR CANCER SUSPECT AGENT(S). TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. Explanation Of Carcinogenicity: BETA-BHC:NTP 7TH ANNUAL RPT ON CARCINOGENS, 1994:ANTICIPATED TO BE CARCINOGEN (PRESENT AT LESS THAN 0.1 PERCENT) (FP N). Signs And Symptions Of Overexposure: EE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INGEST:CALL MD IMMEDIATELY (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. EYES:FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR - GIVE OXYGEN, IF NECESSARY. CONTACT MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DUE TO THE SMALL QUANTITY INVOLVED, SPILLS OR LEAKS SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN A PLASTIC BAG & NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON VERMICULITE OR SAND. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS CONCERNING DISPOSAL. Handling And Storage Precautions: KEEP TIGHTLY CLOSED & STORE IN A COOL, DRY PLACE. Other Precautions: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: COMBUSTIBLE. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). USE APPROP NIOSH/MSHA APPRVD SAFETY (SUPDAT) Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: EYE PROT:& FULL LENGTH FACESHIELD (FP N). OTHER PROT EQUIP:EQUIPMENT. WEAR CHEMICAL RESISTANT CLOTHING SUCH AS LAB COAT &/OR RUBBER APRON TO PREVENT CONTACT W/EYES, SKIN & CLOTHING. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: LIQUID. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: LOW REACTIVITY. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ROY-CAL-L AND ROY-CAL-X BRAND GROUND SHELL FILLER CAGE:TO566 CAGE:MO691 CAGE:27292 CAGE:TO566 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CARBONATE (CACO3), MANUFACTURER'S CAS# 1317-65-3, CHEMICAL FAMILY: MOLLUSC SHELL CAS:471-34-1 RTECS #:FF9335000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE (MFR). INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION . CONTACT MAY CAUSE EYE AND SKIN IRRITATION . INGESTION OF LARGE QUANTITIES MAY CAUSE GASTRO-INTESTINAL DISCOMFORT . Effects of Overexposure:NONE ======================= First Aid Measures ======================= First Aid:NOT NECESSARY (MFR). ===================== Fire Fighting Measures ===================== Flash Point:NONE-DIRECT IGNI Extinguishing Media:NOT APPLICABLE (MFR). MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NOT APPLICABLE (MFR).FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP AND DISPOSE OF IN ANY MANNER OR WASH AWAY WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:ONLY AS REQUIRED BY GOOD HOUSEKEEPING PRACTICES. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DESIRED (MFR). NIOSH-APPROVED RESPIRATOR FOR DUSTS . Ventilation:AS IT APPLIES TO POWDERS (MFR). LOCAL AND GENERAL EXHAUST SUFFICIENT TO MAINTAIN AIRBORNE EXPOSURE LEVELS BELOW APPLICABLE LIMITS . Other Protective Equipment:EYEWASH MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE. Supplemental Safety and Health THRESHOLD LIMIT VALUE: NOT APPLICABLE.NPCA HAZARD RATING: HEALTH-0, FLAMMABILITY-0, REACTIVITY-0, PERSONAL PROTECTION-X. ================== Physical/Chemical Properties ================== Decomp Temp:=982.2C, 1800.F Decomp Text:DECOMPOSES Vapor Pres:NONE Vapor Density:NONE Evaporation Rate & Reference:NONE Solubility in Water:0.04 PTS/100 PTS WATER Appearance and Odor:OFF-WHITE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:EXPOSURE TO DILUTE ACIDS. TEMPS OVER 1800F. Hazardous Decomposition Products:CARBON DIOXIDE AND LIME, OVER 1800F ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY (MFR). DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPOXY HARDNER Kit Part:Y CAGE:19092 CAGE:19092 ============= Composition/Information on Ingredients ============= Ingred Name:PIGMENTS Fraction by Wt: 68% Ingred Name:VEHICLE Fraction by Wt: 32% ===================== Hazards Identification ===================== Effects of Overexposure:NAUSEA,HEADACHE,DERMATITIS ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER.INHAL:MOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:>212/250 Extinguishing Media:WATER,FOAM,CO*2,DRY CHEM. Fire Fighting Procedures:WEAR MASKS KEEP EXPOSED CONTAINERS COOL. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP WITH SUITABLE ABSORBENT VENTILATION AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT KEEP AWAY FROM HEAT USE WITH ADEQUATE VENTILATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED RESPIRATOR Ventilation:YES Other Protective Equipment:OVERALLS Supplemental Safety and Health PART B. KEY1:N1. ================== Physical/Chemical Properties ================== Vapor Pres:1 Spec Gravity:1.76 Solubility in Water:<1% Appearance and Odor:BLACK PASTE SLIGHT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HIGH TEMP. Hazardous Decomposition Products:CO*2,CO,NOX,AMMONIA,HYDROCARBON PHENOLICS ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NICE TOUCH M-D LIME HAND CLEANSER-800 ML, 380138 Preparer's Name:RANDY HAMMOND CAGE:IO781 CAGE:IO781 CAGE:02905 ============= Composition/Information on Ingredients ============= Ingred Name:P-MENTHA-1,8-DIENE; (DIPENTENE) CAS:138-86-3 RTECS #:OS8100000 Fraction by Wt: 3-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:9,12-OCTADECADIENAMIDE, N,N-BIS(2-HYDROXYETHYL)-; (LINOLEAMIDE DEA) CAS:56863-02-6 RTECS #:RF9968000 Fraction by Wt: 3-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COCOAMPHODIACETATE CAS:68650-39-5 Fraction by Wt: 5-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYETHYLENE; (SCRUBBING PARTICLES) CAS:9002-88-4 RTECS #:TQ3325000 Fraction by Wt: 3-7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:GLYCOLS,POLYETHYLENE,MONO(NONYLPHENYL) ETHER; (ETHOXYLATED NONYL PHENOL; SURFACTANT) CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: 3-7% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE CONTACT: MAY CAUSE IRRITATION. INHALATION: PROLONGED EXPOSURE TO MIST MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. INGESTION: MAY CAUSE GASTRIC UPSET. SKIN CONTACT: PROLONGED CONTACT MAYCAUSE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYE CONTACT: DO NOT RUB EYES. FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN. INGESTION: CONTACT PHYSICIAN OR POISON CONTROL IMMEDI ATELY. INHALATION: MOVE VICTIM TO FRESHAIR. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB AND COLLECT FOR DISPOSAL. FLUSH AREA WITH WATER TO REDUCE POSSIBLE SLIPPERY FLOOR HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID EYE CONTACT; STORE AT AMBIENT TEMPERATURE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED IF USED AS DIRECTED. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 7.5-8.5 ================== Physical/Chemical Properties ================== Spec Gravity:.9 pH:SUPDAT Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:APPRECIABLE Appearance and Odor:GREEN OPAQUE LIQUID, PLEASANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANTIMONY ATOMIC ABSORPTION STANDARD, AX1661 CAGE:DO242 CAGE:63612 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:ANTIMONY TRICHLORIDE CAS:10025-91-9 RTECS #:CC4900000 Fraction by Wt: 0.2% OSHA PEL:0.5 (SB) MG/M3 ACGIH TLV:0.5 (SB) MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROGEN CHLORIDE; (HYDROCHLORIC ACID) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 1% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 99% Ingred Name:NEUT AGENT: SX0861 ACID SPILL TREATMENT KIT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE EYE IRRITATION ON CONTACT. MAY BE HARMFUL IF SWALLOWED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXP. EYES: IMMED FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR; GIVE ARTIFICIALRESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:ANY SUITABLE FOR ADJACENT MATERIAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES ACRID FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERS. WEAR SUITABLE PROT EQUIP. ELIMINATE ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLOS/FIRE HAZ. CONTAIN RELEASE & ELIMINATE ITS SOURCE, IF THIS C AN BE DONE W/OUT RISK. TAKE UP & (SUPP DATA) Neutralizing Agent:THE FOLLOWING EM SCIENCE SPILL-X NEUT & ABSORBENT IS RECD FOR THE PROD: (ING 4) ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AT CONTROLLED ROOM TEMPERATURE. DO NOT BREATHE SOLUTION MIST. DO NOT GET IN EYES. Other Precautions:AVOID PROLONGED OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN A NIOSH/MSHA APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health SPILL PROC:CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP.COMPLY W/FED, STATE & LOCAL REGS ON REPORTING QUANTITY & OTHER REGULATORY DATA.EM SCIENCE RECS SPILL-X NEUTS & ABSORBENT AGENTS FOR VARI OUS TYPES OF SPILLS. ADDNL INFO ON SPILL-X PRODS CAN BE PROVIDED THRU EM SCIENCE TECH SERVICE DEPARMENT (609)354-9200. ================== Physical/Chemical Properties ================== HCC:C1 Solubility in Water:MISIBLE Appearance and Odor:COLORLESS, ODORLESS LIQUID Percent Volatiles by Volume:99.5+ ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:CHLORINE COMPOUNDS, ANTIMONY COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:SPECIFIED TECHNOLOGY - NEUTRALIZE TO PH 6-9. CONTACT YOUR LOCAL PERMITTED WASTE DISPOSAL SITE (TSD) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANC E WITH ALL CURRENT LOCAL, STATE & FED REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TF SOLUTION/CLEANING SOLUTION; "FREON" CAGE:PERFE CAGE:PERFE CAGE:60902 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III) CAS:76-13-1 RTECS #:KJ4000000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9293 Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV: 100 PPM Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE CONTACT: LIQUID AND NIST MAY IRRITATE THE EYES. SKIN CONTACT: NO IRRITATION IS LIKELY AFTER BRIEF CONATCT BUT MAY BE IRRITATING AFTER PROLONGED CONTACT. SWALLOWED: SWALLOWING LARGE QUANTITIES MAYCAUSE NAUSEA AND VOMITING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:BREATHING HIGH CONCENTRATIONS MAY CAUSE LIGHT HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH & MAY LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS/DEATH. VAPORS ARE HEAVIER THAN AIR & CAN CAUSE SUFFOCATION BY REDUCING O2 AVAILABLE FOR BREATHING. Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR. GIVE CPR IF NOT BRTHG. SEE DOCTOR. EYE:FLUSH W/LOTS OF RUNNING WATER FOR AT LEAST 15 MIN, LIFTING UPPER & LOWER LIDS OCCASIONALLY. SEE DOCTOR. SKIN:WASH W/LOTS OF SOAP & WA TER. REMOVE CONTAMINATED CLOTHES & SHOES; WASH BEFORE REUSE. SEE DOCTOR. INGEST:DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LOTS OF WATER/MILK. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Extinguishing Media:NON COMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS MAY BE REQUIRED IF DRUMS RUPTURE & CONTENTS ARE SPILLED UNDER FIRE CONDITIONS. COOL CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:EXTINGUISH ALL NEARBY SOURCES OF IGNITION, SINCE VAPORS DECOMPOSE TO HAZARDOUS PRODUCTS UNDER HIGH TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVD PROTECTIVE EQUIPMENT PRESSURE DEMAND MODE. IF SPILL/LEAK IS SMALL, FULL FACE PIECE AIR PURIFYING CARTRIDGE RESPIRA TOR EQUIPPED FOR ORGANIC VAPOR MAY BE USED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENT PLACE. STORE AWAY FROM ALL OTHER CHEMICALS & POTENTIAL SOURCES OF CONTAMINATION. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURF. HEAT AND/OR UV RADIA MAY CAUSE FORMATION OF CHLORIDES, FLUORIDES AND/OR PHOSGENE . DO NOT USE PRES S TO EMPTY CONTR. DO NOT GET IN (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED SCBA IN PRESSURE DEMAND MODE, OR A NIOSH/MSHA APPROVED SUPPLIED AIR RESPIRATOR IF USE CONDITIONS GENERATE VAPORS OR MISTS. Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING EMISSION AT POINT OF USE BELOW PEL. Other Protective Equipment:LONG-SLEEVE SHIRT, TROUSERS, SAFETY SHOES AND RUBBER APRON. Work Hygienic Practices:AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:118F,48C Melt/Freeze Pt:M.P/F.P Text:31.0F,-0.6C Vapor Pres:334 Vapor Density:2.9 Spec Gravity:1.57 Evaporation Rate & Reference:>1 (CCL4 = 1) Solubility in Water:NIL Appearance and Odor:COLORLESS LIQUID WITH SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS, OXIDIZING MATLS, WATER & MOIST AIR. ALSO ALKALINE EARTH METALS & POWDER ALUMINUM/ZINC. Stability Condition to Avoid:OPEN FLAMES, WELDING ARCS/OTHER HIGH TEMP SOURCES WHICH MAY INDUCE THERMAL DECOMPOSITION. Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE, CHLORINE OR HYDROGEN FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF CONTAMINATED PRODUCT AND MATERIAL USED IN CLEANING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MATERIAL. CONSULT APPROPRIATE LOCAL, STATE AND FEDERAL REGULATORY AGENCIES TO BE CERTAIN OF PROPER DISPOSAL PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AS973 (SP503) BRUSH ON SEALER/ADH, PREP COAT & TEXTILE MED Preparer's Name:CURT SATHRE CAGE:21546 CAGE:21546 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONTOXIC. ABRASIVE CAN SCRATCH EYES. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE TECHNIQUES & MEDIA FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:MATERIAL CAN SPATTER ABOVE 212F. POLYMER FILM CAN BURN. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP PROPERLY W/PAPER TOWELS & WET SPONGE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER SEALED. Other Precautions:DON'T INHALE MIST. AVOID CONTACT W/EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF SPRAYING, DON'T INHALE MIST. USE RESPIRATOR THAT IS NIOSH APPROVED FOR SPRAYS & MISTS. Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): RECOMMENDED WHEN SPRAYING. Work Hygienic Practices:GOOD HYGIENE PRACTICES SHOULD BE FOLLOWED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.1 Evaporation Rate & Reference:(BU AC = 1): 1 Solubility in Water:INSOLUBLE Appearance and Odor:OPAQUE-COLORED LATEX PAINT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPS >212F ==================== Disposal Considerations ==================== Waste Disposal Methods:PUT PAPER TOWELS IN TRASH & RINSE OUT SPONGE.
1
eyes_protection_mandatory
======================================================= NIIN: 01-318-6008 Product ID: PREMIUM OUTBOARD AND MULTI-PURPOSE 2-CYCLE OIL Cage: 01326 Box: 2967 Resp. Party Other MSDS No.: 000581 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: LUBRICATING OIL,ENGINE Specification Number: NONE Type/Grade/Class: NONE Unit of Issue: QT UI Container Qty: B Type of Container: ADD DATA ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: TLV FOR OIL MIST IS 5 MG/M3. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE- LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY IRRITATING TO EYES & SKIN. INHALATION: THIS PRODUCT HAS A LOW VAPOR PRESSURE & IS NOT EXPECTED TO PRESENT AN INHALATION HAZARD. CAUTION SHOULD BE TAKEN TO PREVENT AEROSOLIZATION OR MISTING. INGESTION: DO NOT INGEST. RELATIVELY NON-TOXIC BY INGESTION. ON RARE OCCASIONS, PROLONGED AND REPEATED EXPOSURE TO OIL MIST POSES A RISK OF PULMONARY DISEASE SUCH AS CHRONIC LUNG INFLAMMATION. THIS CONDITION IS USUALLY ASYMPTOMATIC AS A RESULT OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF BREATH & COUGH ARE THE MOST COMMON SYMPTOMS. Explanation Of Carcinogenicity: WARNING! USED MOTOR OILS WERE SHOWN TO CAUSE SKIN CANCER WHEN REPEATEDLY APPLIED TO MICE WITHOUT CLEANING SKIN. Signs And Symptions Of Overexposure: IRRITATION, NAUSEA, VOMITING, DIARRHEA, ABDOMINAL CRAMPS, TEARING, HEADACHE Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING SKIN DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. First Aid: EYE: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER & CONTINUE FLUSHING UNTIL IRRITATION SUBSIDES. IF MATERIAL IS HOT, TREAT FOR THERMAL BURNS & TAKE VICTIM TO HOSPITAL IMMEDIATELY. SKIN: REMOVE C ONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. IF REDNESS OR IRRITATION OCCUR, SEEK MEDICAL ATTENTION. IF MATERIAL IS HOT, SUBMERGE INJURED AREA IN COLD WATER. IF VICTIM IS SEVERELY BURNED, REMOVE TO A HOSPITAL IMMEDIATELY. INHALATION: THIS MATERIAL HAS A LOW VAPOR PRESSURE & IS NOT EXPECTED TO PRESENT AN INHALATION EXPOSURE AT AMBIENT CONDITIONS. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR PROTECTIVE EQUIPMENT. CONTAIN SPILL IMMEDIATELY. DO NOT ALLOW SPILL TO ENTER SEWERS OR WATERCOURSES. REMOVE ALL SOURCES OF IGNITION. ABSORB WITH APPROPRIATE INERT MATERIAL SUCH AS SAND, CLAY, ETC . LARGE SPILLS MAY BE PICKED UP USING VACUUM PUMPS, SHOVELS, BUCKETS, OR OTHER MEANS & PLACED IN DRUMS OR OTHER SUITABLE CONTAINERS. Neutralizing Agent: NOT RELEVANT Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL STATE AND FEDERAL REGULATIONS. PRODUCT IS AN OIL. SPILLS TO US SURFACE WATERS OR WATERCOURSE OR SEWER THAT CAUSE A VISIBLE SHEEN MUST BE REPORTED TO THE NATIONAL RE SPONSE Handling And Storage Precautions: STORE IN CLOSED CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAMES OR STRONG OXIDIZING MATERIALS. THIS PRODUCT IS NOT CLASSIFIED AS HAZARDOUS UNDER DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READI LY AVAILABLE. SEE NFPA 30 AND OSHA 1910.106-FLAMMABLE AND COMBUSTIBLE LIQUIDS. Other Precautions: THIS MIXTURE MAY BE FORMULATED IN PART WITH COMPONENTS PURCHASED FROM OTHER COMPANIES. ESPECIALLY WHEN PROPRIETARY OR TRADE SECRET MATERIALS ARE USED, PENNZOIL CO. MUST RELY UPON THE HAZARD EVALUATIO N OF SUCH COMPONENTS SUBMITTED TO PENNZOIL BY THE PRODUCT'S MFR OR IMPORTER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point: =133.9C, 273.F Autoignition Temp Text: N/DATA Lower Limits: NO DATA Upper Limits: NO DATA Extinguishing Media: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures: WATER MAY BE INEFFECTIVE BUT CAN BE USED TO COOL CONTAINERS EXPOSED TO HEAT OR FLAME.. Unusual Fire/Explosion Hazard: DENSE SMOKE MAY GENERATED WHILE BURNING. CARBON MONOXIDE, CARBON DIOXIDE AND OTHER OXIDES MAY BE GENERATED AS PRODUCTS OF COMBUSTION. ======================================================= Control Measures ======================================================= Respiratory Protection: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. IF VAPOR OR MIST IS GENERATED WHEN THE MATERIAL IS HEATED OR HANDLED, USE AN ORGANIC VAPOR RESPIRATOR WITH A DUST AND MIST FILTER. ALL RESPIRATORS MUST BE NIOSH CERTIFIED. DO NOT USE COMPRESSED OXYGEN IN HYDROCARBON ATMOSPHERES. Ventilation: USE ADEQUATE VENTILATION TO KEEP OIL MISTS OF THIS MATERIAL BELOW APPLICABLE STANDARD(S). ANTICIPATED Other Protective Equipment: USE IMPERVIOUS CLOTHING (BOOTS, APRONS, ETC.) OVER PARTS OF THE BODY SUBJECT TO EXPOSURE. IF HANDLING HOT MATERIAL, USE Work Hygienic Practices: CONSUMPTION OF FOOD AND BEVERAGE SHOULD BE AVOIDED IN WORK AREAS WHERE HYDROCARBONS ARE PRESENT. ALWAYS WASH HANDS AND FACE WITH SOAP AND WATER BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health: LAUNDER SOILED CLOTHES. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES INCLUDING SHOES, WHICH CANNOT BE DECONTAMINATED. ======================================================= Physical/Chemical Properties ======================================================= HCC: V6 NRC/State LIC No: NONE Boiling Point: >148.9C, 300.F M.P/F.P Text: NO DATA Decomp Text: UNKNOWN Vapor Pres: NO DATA Vapor Density: 4 - 5 Spec Gravity: 0.85 Viscosity: UNKNOWN Evaporation Rate & Reference: NO DATA Solubility in Water: NO DATA Appearance and Odor: GREEN/BLUE LIQUID - PETROLEUM ODOR Percent Volatiles by Volume: 35.37 Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE Materials To Avoid: MAY REACT WITH STRONG OXIDIZING AGENTS Hazardous Decomposition Products: NONE Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 125007 Product ID: PREMIUM OUTBOARD AND MULTI-PURPOSE 2-CYCLE OIL Review Date: 08/12/1997 Tech Entry NOS Shipping Nm: NONE Net Unit Weight: 0.77 KG Multiple KIT Number: 0 Review IND: Y Unit Of Issue: QT Container QTY: B Type Of Container: ADD DATA Additional Data: MFR SUPPLIED THE PROPER SHIPPING NAME. CONTAINER IS DESCRIBED AS "UNBREAKABLE BOTTLE CONFORMING TO P PP-". ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: PREMIUM OUTBOARD AND MULTI-PURPOSE 2-CYCLE OIL Cage: 01326 Company Name: PENNZOIL CO Street: 700 MILIAM PENNZOIL PL PO Box: 2967 Zipcode: 77252-2967 Label Required IND: Y Date Of Label Review: 08/12/1997 Status Code: C MFG Label NO: NONE Label Date: 08/12/1997 Year Procured: 1997 Origination Code: F Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY IRRITATING TO EYES & SKIN. INHALATION OF VAPOR (GENERATED AT HIGH TEMPERATURE S ONLY)/OIL MIST MAY CAUSE MILD IRRITATION. RELATIVELY NON-TOXIC BY INGESTION. CHRONIC- LUNG INFLAMMATION, DERMATITIS. STORE IN COOL PLACE AWAY FROM OPEN FLAMES AND STRONG OXIDIZING AGENTS. KEEP CONTA INER CLOSED. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:324 CAGE:71431 CAGE:71431 ============= Composition/Information on Ingredients ============= Ingred Name:POLYTETRAFLUOROETHYLENE CAS:116-14-3 RTECS #:KX4025000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS ITEM HAS BEEN CLASSIFIED AS AN ARTICLE IAW 29CFR1910.1200.DECOMPOSITION PRODUCT MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:TEMPORARY FLU-LIKE SYMPTOMS. Medical Cond Aggravated by Exposure:UNLIKELY TO AGGRIVATE EXISTING MEDICAL CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE,FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL REQUIREMENTS Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:FOLLOW LABEL DIRECTIONS.DO NOT SMOKE WHEN HANDLING PTFE PRODUCTS.WASH HANDS AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED IN NORMAL SERVICE. Ventilation:USE LOCAL EXHAUST FOR CONDITION ABOVE 752F(400C). Other Protective Equipment:NONE Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Decomp Temp:Decomp Text:752F,400C Appearance and Odor:YARN COATED WITH PTFE. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FLUORINE,FLUOROCARBONS,MOLTEN ALKALI METALS. Stability Condition to Avoid:HEAT ABOVE 752F Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,HYDROGEN FLUORIDE,PENTAFLUOROCARBON OLEFINS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.MFR STATES THAT THIS IS NOT REGULATED WASTE.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:RAPID SET CONCRETE MIX CAGE:CTSCE CAGE:CTSCE ============= Composition/Information on Ingredients ============= Ingred Name:SULFUR TRIOXIDE; (SO*2) (SARA 302) CAS:7446-11-9 RTECS #:WT4830000 Fraction by Wt: 12.52% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LOSS ON IGNITION RTECS #:9999999ZZ Fraction by Wt: 2.84% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALKALIS; (TOTAL ALKALIS (AS NA*2O)) Fraction by Wt: 0.56% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:INSOLUBLE MATTER; (INSOLUBLE RESIDUE) Fraction by Wt: 2.38% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HEXAVALENT CHROMIUM COMPOUND (AS CR); (CEMENT MAY CONTAIN TRACES OF HEXAVALENT CHROMIUM) Fraction by Wt: TRACE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICON DIOXIDE; (SIO*2) CAS:14808-57-0 Fraction by Wt: 15.4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALUMINUM OXIDE; (AL*2O*2) (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 13.74% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:IRON (III) OXIDE; (FE*2O*3) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 2.38% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM OXIDE; (CAO) CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: 50.87% OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:MAGNESIUM OXIDE; (MGO) CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: 1.26% OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3 FUME ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:DRY CEMENT, WHEN COMBINED W/BODY MOISTURE AND WET CEMENT, ESPECIALLY AS AN INGREDIENT IN PLASTIC (UNHARDENED) CONCRETE, CAN DRY SKIN AND CAUSE ALKALI BURN. CEMENT DUST CAN IRRITATE EYES AND UPPE R RESPIRATORY SYSTEM. CHRONIC:CEMENT DUST CAN CAUSE INFLAMMATION OF THE LINING TISSUE OF THE INTERIOR (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF THE NOSE AN INFLAMMATION OF THE CORNEA. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP AN ALLERGIC DERMATITIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IRRIGATE W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH AFFECTED AREAS OF THE BODY W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:USE DRY CLEAN-UP METHODS THAT DO NOT DISPERSE DUST INTO AIR. AVOID BREATHING DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS MUST BE OBSERVED BECAUSE CEMENT BURNS OCCUR W/LITTLE WARNING. LITTLE HEAT IS SENSED. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN DUSTY ENVIRONMENTS, THE USE OF NIOSH APPROVED RESPIRATOR IS RECOMMENDED. Ventilation:LOCAL EXHAUST CAN BE USED, IF NECESSARY, TO CONTROL AIRBORNE DUST LEVELS. Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . USE BARRIER CREAMS, BOOTS & CLTHG TO PROT SKIN FROM PRLNG (SUPDAT) Work Hygienic Practices:IMMEDIATELY AFTER WORKING W/CEMENT, WORKERS SHOULD SHOWER W/SOAP & WATER. Supplemental Safety and Health OTHER PROT EQUIP:CONTACT W/CEMENT, ESPECIALLY WET CEMENT IN PLASTIC CONCRETE. ================== Physical/Chemical Properties ================== Spec Gravity:3.1 Solubility in Water:SLIGHT (0.1-1%) Appearance and Odor:GRAY (OR WHITE) POWDER; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:ALTHOUGH NO HAZARDOUS REACTION WILL OCCUR, RAPID SET PRODUCTS SHOULD BE KEPT DRY UNTIL USED. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . MATERIAL CAN BE RETURNED TO CONTAINER FOR LATER USE, OR IT CAN BE DISPOSED OF AS COMMON WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:G-525 JEL-E-PAK CAGE:57412 CAGE:57412 CAGE:66200 CAGE:97412 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM HYDROCARBONS (AS AN OIL MIST 80-95%) Fraction by Wt: 87.5% ACGIH TLV:5MG/CUM,OILMIST ===================== Hazards Identification ===================== Effects of Overexposure:NO UNUSUAL EFFECTS TO BE EXPECTED. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:400F (C.O.C.) Lower Limits:UNKN Upper Limits:UNKN Extinguishing Media:DRY CHEMICALS,CO*2,WATER SPRAY. Fire Fighting Procedures:NONE SPECIFIED Unusual Fire/Explosion Hazard:NONE SPECIFIED ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN ABSORBENT SWEEPING COMPOUND. ======================Handling and Storage ====================== Handling and Storage Precautions:IN ACCORDANCE WITH GOOD INDUSTRIAL PRACTICE,HANDLE WITH DUE CARE AND AVOID UNNECESSARY PERSONAL CONTACT. Other Precautions:AVOID EYES AND SKIN CONTACT.PROVIDE ADEQUATE VENTILATION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY CONDITIONS/ADEQUATE VENT. Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE VENTILATION Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:0.1 Vapor Density:1.0 Spec Gravity:0.88 Evaporation Rate & Reference:NONE Solubility in Water:NEGLIGIBLE Appearance and Odor:PETROLEUM HYDROCARBONS LIQUID. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING Stability Condition to Avoid:AVOID EXECESSIVE HEAT FOR LONG PERIODS OF TIME Hazardous Decomposition Products:FROM INCOMPLETE COMBUSTION CO MAY BE FORMED ==================== Disposal Considerations ==================== Waste Disposal Methods:USE APPROVED INCINERATION OR LAND FILL IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROXYZINE HYDROCHLORIDE INJECTION Preparer's Name:CHRISTINA J. BARRINGTON CAGE:24832 CAGE:24832 CAGE:0K706 ============= Composition/Information on Ingredients ============= Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 0.9% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROXYZINE HYDROCHLORIDE CAS:2192-20-3 RTECS #:KK2280000 Other REC Limits:NONE RECOMMENDED Ingred Name:WATER PH ADJUSTED CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN. POTENTIAL ADVERSE REACTIONS FROM PRESCRIBED DOSES AND OVERDOSES ARE DESCRIBED IN THE PACKAGE INSERT. OCCUPATIONAL EXPOS URE HAS NOT BEEN FULLY INVESTIGATED. Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY NTP, IARC, OR OSHA Effects of Overexposure:IMMEDIATE EFFECTS:EYE, SKIN AND RESPIRATORY IRRITATION MAY OCCUR. DELAYED EFFECTS:HYPERSENSITIVITY EFFECTS RANGING FROM MILD TO SEVERE MAY OCCUR. TISSUE NECROSIS HAS BEEN ASSOCIATED WITH SUBCUTANEOU SLY AND INTRA-ARTERIAL ADMINISTRATION AND HEMOLYSIS HAS OCCURED AFTER INTRAVENEOUS ADMINISTRATION. SEE OTHER PRECAUTIONS Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & RESPIRATORY CONDITIONS ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN. SEEK MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING IMMEDIATELY. FLUSH AREA W/WATER FOR 15 MIN. SEEK MEDICAL ATTENTION. INHALED:REMOVE TO FRESH AIR. AID/RESTORE BREA THING IF NECESSARY. SEEK MEDICAL ATTENTION. INGESTED:FLUSH OUT MOUTH WITH WATER IMMEDIATELY. SEEK MEDICAL ATTENTION. FOR ADVERSE DRUG REACTION INFORMATION CALL 708-317-5937. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM AS APROPIATE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:GENERAL HAZARD:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN UP SPILL. WIPE SURFACES CLEAN AND WASH WITH SOAP AND WATER. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR. ======================Handling and Storage ====================== Handling and Storage Precautions:WHEN HANDLING PHARMACEUTICAL PRODUCTS, AVOID ALL CONTACT AND INHALATION OF DUST, FUMES, MIST AND/OR VAPORS ASSOCIATED WITH THE PRODUCT. Other Precautions:**DO NOT INJECT SUBCUTANEOUSLY, INTRAVENEOUSLY, OR INTRA-ARTERIALLY.** ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WITH SATISFACTORY VENTILATION, RESPIRATORY PROTECTION NOT USUALLY REQUIRED. Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL EXHAUST VENTILATION WHEN NECESSARY. Other Protective Equipment:DISPOSABLE GRAMENTS IF DIRECT SKIN CONTACT IS ANTICIPATED. Work Hygienic Practices:MFR: ?HMIS:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID ALL UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING OR DRINKI Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE pH:3.5-6. Solubility in Water:VERY SOLUBLE Appearance and Odor:CLEAR, COLORLESS SOLUTION WITH PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:HAZARDOUS COMBUSTION PRODUCTS:SMOKE, TOXIC FUMES OF HCL Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LUBRIKO M-32 GREASE CAGE:76227 CAGE:76227 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM TALLOWATE CAS:8052-48-0 Fraction by Wt: 24-26% OSHA PEL:N/K ACGIH TLV:10 MG/M3 (MFR) Ingred Name:CALCIUM TALLOWATE (MFR CAS NO: 68309-87-5) CAS:64755-01-7 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:10 MG/M3 (MFR) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE) HEAVY NAPHTHENIC; (MINERAL OIL) CAS:64742-52-5 RTECS #:PY8035001 Fraction by Wt: 24-25% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:SOLVENT REFINED HYDROTREATED RESIDUAL OIL; (MINERAL OIL) CAS:64742-57-0 Fraction by Wt: 24-25% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM); (MINERAL OIL) CAS:64742-62-7 Fraction by Wt: 24-25% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED OR REPEATED SKIN OR EYE CONTACT MAY CAUSE MILD (TRANSIENT) IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:ADMINISTER VOLUMES OF WATER OR MILK & GET MEDICAL ATTENTION. SKIN:WIPE OFF & WASH W/SOAP & WATER. EYES:FLUSH W/ COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS & GET MEDICAL ATTENTION. INHAL:REMO VE FROM EXPOSURE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:400F,204C Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY CAUSE FROTHING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB IN SAND OR INERT MATERIAL, SCOOP OR SWEEP UP & REMOVE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE INDOORS W/LIDS IN PLACE & AWAY FROM OPEN FLAME OR DIRECT SUNLIGHT. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMALLY NOT REQUIRED. USE ONLY NIOSH/MSHA APPROVED EQUIPMENT. Ventilation:NORMALLY NOT REQUIRED. Other Protective Equipment:NONE. Work Hygienic Practices:FOLLOW NORMAL CLEANLINESS PROCEDURES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>600F,>316C Melt/Freeze Pt:M.P/F.P Text:365F,185C Vapor Pres:<0.01 @20C Vapor Density:>10 Spec Gravity:0.9 (H2O=1) Evaporation Rate & Reference:<0.01 (BUTYL ACETATE=1) Solubility in Water:DISPERSIBLE Appearance and Odor:SEMI-SOLID; BLAND ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDENTS & LARGE VOLUME OF WATER OR MOISTURE. Stability Condition to Avoid:OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE IN CASES OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT FEDERAL, STATE OR LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NUCLO, ORTEX OR PRIVATE LABEL (SLOW DISSOLVING) CAGE:OELN1 CAGE:OELN1 ============= Composition/Information on Ingredients ============= Ingred Name:TRICHLORO-S-TRIAZINETRIONE, TRICHLOROISOCYANURIC ACID CAS:87-90-1 RTECS #:XZ1925000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 490 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEVERE IRRITATION OR BURNS TO EYES, SKIN, MUCOUS MEMBRANES, RESPIRATORY & GASTROINTESTINAL TRACT. CHRONIC: SKIN SENSITIZATION. DAMAGE TO LIVER & KIDNEYS. CORROSIVE TO EYES & SKIN. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: DRINK PLENTY OF WATER. INDUCE VOMITING BY STICKING FINGER DOWN THROAT. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:USE WATER SPRAY TO COOL CONTAINERS EXPOSED TO FIRE. WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONTACT W/MOST ORGANIC OR EASILY OXIDIZED MATERIAL MAY RESULT IN FIRE. DECOMPOSITION BY PRODUCT, NITROGEN TRICHLORIDE, IS HIGHLY EXPLOSIVE ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT. MINIMIZE CONTAMINATION W/ORGANIC MATERIAL. DON'T RETURN TO ORGINAL CONTAINER, BUT PLACE IN FRESH CONTAINER & ISOLATE OUTSIDE/WELL-VENTILATE AREA . DON'T SEAL. FLUSH RESIDUE W/PLENTY OFWATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM FLAMMABLE LIQUIDS/COMBUSTIBLES/OXIDIZABLE MATERIALS. DRUMS MAY RUPTURE IF EXPOSED TO HEAT/WATER. Other Precautions:DON'T GET IN EYES, ON SKIN OR ON CLOTHING. DON'T TAKE INTERNALLY. AVOID BREATHING DUST. PROTECT FROM PHYSICAL DAMAGE. AVOID PROLONGED STORAGE IN UNVENTILATED AREAS AT SUMMER TEMPERATURES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS FOR SPILLS. Ventilation:LOCAL EXHAUST WHERE EXPOSURE TO DUST MIGHT OCCUR Other Protective Equipment:COVERALLS & IMPERVIOUS BOOTS Supplemental Safety and Health PH: 1% AQ SOLN 2.5-2.9 ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:225-240C Spec Gravity:2.1 pH:SUPPL. Solubility in Water:MODERATE Appearance and Odor:WHITE CRYSTALLINE TABLETS, STICKS, RODS, DONUTS W/SLIGHT CHLORINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANIC MATERIALS, EASILY CHLORINATED OR OXIDIZED MATERIALS, AMMONIUM SALTS, UREA, ACIDS & BASES. FLAMMABLE MATERIALS. Stability Condition to Avoid:CONTAMINATION W/SMALL AMOUNTS OF WATER, HEAT. Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CHLORINE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF CONTAMINATED PRODUCT & MATERIALS USED IN CLEAN-UP IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P/N 31275-02C BATTERY, STORAGE CAGE:DO446 CAGE:DO446 CAGE:74025 ============= Composition/Information on Ingredients ============= Ingred Name:CADMIUM (SARA 313) (CERCLA) CAS:7440-43-9 RTECS #:EU9800000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 MG/M3 DUST; Z-2 ACGIH TLV:0.01 MG/M3 DUST;9596 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CADMIUM HYDROXIDE CAS:21041-95-2 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 (CD FUME) ACGIH TLV:0.05 MG/M3 (CD FUME) Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9596 Ingred Name:NICKEL HYDROXIDE (SARA 313) (CERCLA) CAS:12054-48-7 RTECS #:QR7040000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG(NI)/M3 ACGIH TLV:0.1 MG(NI)/M3; 9596 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CORROSIVE TO ALL BODY TISSUES. CONTACT MAY CAUSE SEVERE IRRITATION AND BURNS. INHALATION MAY CAUSE MUCOUS MEMBRANE IRRITATION, LUNG TISSUE DAMAGE, CHEMICAL PNEUMONIA AND CENTRAL NERVOUS SYSTEM EFFECTS . IRREVERSIBLE LUNG INJURY, KIDNEY DISEASE, AND OTHER ADVERSE EFFECTS MAY RESULT FROM CHRONIC EXPOSURE. Explanation of Carcinogenicity:NICKEL AND CADIUM ARE LISTED UNDER IARC AND NTP. Effects of Overexposure:EYES/SKIN: IRRITATION, SEVERE BURNS, SKIN ULCERATION. INHALATION: UPPER RESPIRATORY SYSTEM IRRITATION, HEADACHE, NAUSEA, DIZZINESS. INGESTION: DIGESTIVE TRACT IRRITATION AND BURNING SENSATION, NAUSEA, VOMITING, DIARRHEA, ABDOMINAL CRAMPS. Medical Cond Aggravated by Exposure:INDIVIDUAL S WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED. GET MEDICAL AT TENTION. INGESTION: DO NOT INDUCE VOMITING. SEE DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONFLAMMABLE. WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION. CADMIUM FUMES OR VAPORS ARE TOXIC AND CAN CAUSE DEATH. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL. ELIMINATE IGNITION SOURCES. VENTILATE AREA. WEAR PROTECTIVE CLOTHING AND EQUIPMENT. NEUTRALIZE CAUTIOUSLY. ABSORB IN INERT MATERIAL AND PLACE IN APPROPRIATE DISPOSAL CONTAINER AND CO VER. Neutralizing Agent:5% ACETIC ACID SOLUTION ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT INVERT. AVOID CRUSHING OR OTHERWISE DESTROYING THE PHYSICAL INTERGRITY OF THE CELL OR BATTERY. Other Precautions:AVOID EYE AND SKIN CONTACT. DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR FOR CAUSTIC GASES OR SCBA AS APPROPRIATE FOR EXPOSURE OF CONCERN WHEN HANDLING THE LIQUID IN THE BATTERY. Ventilation:NO SPECIAL REQUIREMENT. HOWEVER, USE LOCAL EXHAUST VENTILATION WHEN HANDLING THE LIQUID IN THE BATTERY. Other Protective Equipment:PROTECTIVE CLOTHING WHEN HANDLING THE LIQUID IN THE BATTERY. EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:>765F,>407C Melt/Freeze Pt:M.P/F.P Text:>446F,>230C Decomp Temp:Decomp Text:572F,300C Spec Gravity:2.1-8.9 Solubility in Water:52 % (KOH) Appearance and Odor:CAUSTIC ELECTROLYTE IN BATTERY CASE. RECTANGULAR BATTERY, 5.38" HEIGHT. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, NITRATES, NITRIC ACID Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES. Hazardous Decomposition Products:METAL OXIDE FUMES MAY BE EVOLVED AT TEMPERATURES ABOVE MELTING POINT. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 061680, SEA SHORE/FOUR SEASONS ACRYLIC (SUPDAT) Cage: HO637 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 85519 Box: 600 Cage: HO637 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE:INHALATION:IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS, AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN:IRRITATION. PROLONGED OR REPE ATED CONTACT CAN CAUSE DERMATITIS. EYE:IRRITATION. PROLONGED OR REPEATED CONTACT CAN CREATE BLURRED (EFTS OF OVEREXP) Explanation Of Carcinogenicity: SEE "LR" VERSION ING 10 FOR ADDITIONAL INFORMATION (FP N). Signs And Symptions Of Overexposure: HLTH HAZ:VISION, CORNEAL INJURY. INGESTION:AMOUNTS INGESTED INCIDENTAL TO CONSUMER AND INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJU RY. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. HAVE TRAINED PERSON GIVE OXYG IF NECESSARY. GET EMER MED ATTN. SKIN:WASH OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER; REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE REUSE.EYE:FLUSH IMMED W/LG AMTS OF WATER, ESPECIALLY UNDER LIDS, FOR @ LST 15 MINS. OBTAIN EMER MED TREATMENT. INGEST:OBTAIN MEDICAL TREATMENT IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COLLECT IN CONTAINER FOR DISPOSAL, ACCORDING TO HEALTH AND ENVIRONMENTAL REGULATIONS. CLEAN UP WITH WATER BEFORE ALLOWING TO DRY. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: STORE BELOW 100 DEGREE F. KEEP FROM FREEZING. Other Precautions: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NON FLAMMABLE Lower Limits: SEE INGS Extinguishing Media: DRY CHEMICAL OR FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). NON-FLAMMABLE. WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLIC STANDARDS. WHERE RESP PROT IS REQUIRED, USE ONLY NIOSH APPRVD RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: MAINTAIN ADEQUATE VENTILATION TO ENSURE AIR ENTRY DURING APPLICATION & DRYING TO PREVENT BUILD-UP OF VAPORS. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). SKIN CREAM (IF NEEDED). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: USER OF "L" VERSION OFSHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). MFR TRADE NAME/PART NO:LATEX HOUSE PAINT. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >379F,>193C Vapor Pres: SEE INGS Spec Gravity: 1.25-1.37(FP N) Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER Solubility in Water: NOT KNOWN Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 59-65 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT WITH OXIDIZING AGENTS. Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES. Hazardous Decomposition Products: IF INVOLVED IN FIRE (FROM OTHER SOURCES) COULD CONCEIVABLY RESULT IN RELEASE OF CARBON DIOXIDE & CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 061680, SEA SHORE/FOUR SEASONS ACRYLIC (SUPDAT) Cage: HO637 Assigned IND: Y Company Name: MA BRUDER & SONS INC Street: 600 REED RD Zipcode: 19008 Label Required IND: Y Date Of Label Review: 04/01/1997 Status Code: C Label Date: 04/01/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:INHALATION:IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS, AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN:IRRITATION. PROLONGED OR REPE ATED CONTACT CAN CAUSE DERMATITIS. EYE:IRRITATION. PROLONGED OR REPEATED CONTACT CAN CREATE BLURRED VISION, CORNEAL INJURY. INGESTION:AMOUNTS INGESTED INCIDENTAL TO CONSUMER & INDUSTRIAL HANDLING ARENOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJURY. CHRONIC:CANCER HAZARDS. CONTAINS MATERIALS WHICH ARE LISTED AS ANIMAL LUNG CARCINOGENS (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INT- A1 INTERFERENTS A STANDARD Preparer's Name:VANAJA SIWAKUMAR CAGE:07977 CAGE:07977 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID, HYDROGEN NITRATE CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 5% OSHA PEL:5 MG/CUM ACGIH TLV:5.2 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: SEVERE BURNS, IRRITATION. EYES: SEVERE BURNS, PERMANENT DAMAGE , IRRITATION. INGESTION: PAIN & BURNS TO MOUTH.ESOPHAGUS & GASTROINTESTINAL TRACT. INHALATION: FATAL CAUSING SPASM. INFLAMMATION & EDEMA OF THE LARYNX/BRONCHI/CHEMICAL PNEUMONITIS & PULMONARY EDEMA. SYMPTONS ARE: BURNS/COUGHING/WHEEZING/LARYNGITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: SEVERE BURNS, IRRITATION. EYES: SEVERE BURNS, PERMANENT DAMAGE, IRRITATION. INGESTION: PAIN & BURNS TO MOUTH, ESOPHAGUS, & GASTROINTESTINAL TRACT. INHALATION: FATAL CAUSING SPASM. INFLAMMATION & EDEMA OF THE LARYNX/& BRONCHI/CHEMICALPNEUMONITIS & PULMONARY EDEMA. SYMPTON ARE, BURNS/COUGHING/WHEEZING/LARYNGITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH W/PLENTY OF WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS GIVE LOTS OF WATER OR MILK. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS Unusual Fire/Explosion Hazard:CONCENTRATED HYDROGEN NITRATE REACTS EXPLOSIVELY W/COMBUSTIBLE ORGANIC OR READILY OXIDIZABLE MATERIALS; ALCOHOL WOOD, TURPENTINE/METAL POWERS/HYDROGEN SULFIDE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. DILUTE SPILL W WATER & NEUTRALIZE W/SODA ASH, LIMESTONE ETC. WIPE UP & PUT INTO A SEALED CONTAINER FOR DISPOSAL. WASH SPILL SITE OFF W/WATER AFTER MATERIAL PICK UP IS COMPLETE. WEAR CH EMICAL RESISTANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A MSHA/NIOSH APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD Other Protective Equipment:CHEMICAL RESISTANT CLOTHES, EYE WASH Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:N?K Spec Gravity: 1K Solubility in Water:SOLUBLE Appearance and Odor:TRANSPARENT W/AN ACRIS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN NITRATE, STRONG BASES, OXIDIZING AGENTS Stability Condition to Avoid:STRONG OXIDIZER, HEAT, HYDROGEN GAS Hazardous Decomposition Products:TOXIC NITROGEN, OXIDE FUMES& VAPORS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARALDITE 6005 CAGE:EO102 CAGE:27187 CAGE:EO102 ============= Composition/Information on Ingredients ============= Ingred Name:LIQUID EPICHLOROHYDRIN/BISPHENIOL A-TYPE DIEPOXIDE Fraction by Wt: 100% ===================== Hazards Identification ===================== Effects of Overexposure:STRONG SENSITIZER. POSS IRRIT. ======================= First Aid Measures ======================= First Aid:CALL MD. INH: REMOVE TO FRESH AIR. O*2 & ART RESP IF NEC. INGEST: IF CONSCIOUS, GIVE WATER OR MILK. INDUCE VOMIT. SKIN: REMOVE CONTAM CLOTHING. WASH W/SOAP & WATER. EYES: IMMED FLUSH W/WATER AT LEAST 15 MIN. ===================== Fire Fighting Measures ===================== Flash Point:390F PMCC Extinguishing Media:CO*2, FOAM, DRY CHEM Fire Fighting Procedures:USE SELF-CNTND BRTHNG APPARATUS Unusual Fire/Explosion Hazard:PROD SHOULD BE HANDLED AS COMBUSTIBLE MATL ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB ON COMBUSTIBLE MATL FOR PROPER DISPOSAL. FLUSH CONTAM AREAS W/WATER. AVOID SKIN CNTCT, MFR REC. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING, MAY CAUSE SKIN SENSITIZATION OR OTHER ALLERGIC RESPONSES. AVOID INH OF VAPOR. USE GOOD VENT PARTICULARLY IF HEATED OR SPRAYED. Other Precautions:PREVENT ALL CNTCT W/SKIN. IF CNTCT OCCURS, WASH IMMED W/SOAP & WATER. REMOVE CONTAM CLOTHING & WASH BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD ORGANIC VAPOR RESP Ventilation:GENERAL MECH VENT & LOCAL EXHST Supplemental Safety and Health SPEC.GRAV:1.16@ 77F.ORAL:LD50 (RAT)>10,000 MG/KG.DERMAL:LD50 (RABBIT)>2,250 MG/KG. HARDENER 15 LANCAST A WHICH MAY BE USED W/OTHER ARALDITE PRODUCTS. ================== Physical/Chemical Properties ================== Vapor Pres:0.3 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR COLORLESS TO LIGHT-COLORED LIQUID. Percent Volatiles by Volume:0. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CO &/OR CO*2 ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION UNDER APPRVD CONDITIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2-CAMPHONONE, CX0330 CAGE:0SK29 CAGE:0SK29 CAGE:0AL61 ============= Composition/Information on Ingredients ============= Ingred Name:CAMPHOR(+-)-; (2-CAMPHONONE) CAS:21368-68-3 RTECS #:EX1234000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY IRRITATE EYES, NOSE, SKIN & MUCOUS MEMBRANES. MAY CAUSE NAUSEA, VOMIT, DIARRHEA, HEADACHE, DIZZINESS, IRRATIONAL EXCITEMENT, VERTIGO, RESPIRATORY FAILURE, CONVULSIONS, COMA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP & WATER, GET MD. EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES, GET MD. INGEST:INDUCE VOMITING IF CONSCIOUS, GET MD IMMEDIATELY. INHAL:REMOVE TO FRESH AIR, GET MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:150F,66C Lower Limits:0.6% Upper Limits:3.5% Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FLAMMABLE VAPORS; VAPOR MAY FORM EXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND CONTAINERIZE FOR PROPER DISPOSAL; VENT AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD & PROTECTED AGAINST PHYSICAL DAMAGE. STORE IN COOL, WELL-VENTED AREA, OUT OF SUNLIGHT, AWAY FROM HEAT & SEPARATED FROM INCOMPAT MATLS. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED CANISTER FACE MASK. Ventilation:PROVIDE ADEQUATE GENERAL MECHANICAL & LOCAL EXHAUST VENTILATION. Other Protective Equipment:EYE WASH & SAFETY EQUIPMENT SHOULD BE READILY AVAILABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:747F,397C Melt/Freeze Pt:M.P/F.P Text:345F,174C Vapor Pres:0.18 @ 20C Vapor Density:5.24 Spec Gravity:0.992 Solubility in Water:0.12% Appearance and Odor:CLEAR WHITE CRYSTALS, CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZIERS, NAPHTHALENE, P-DICHLOROBENZENE, POTASSIUM PERMANGANATE. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME. Hazardous Decomposition Products:COX. ==================== Disposal Considerations ==================== Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:660970 CALIBRATOR D LEV 7 KIT CAGE:1W937 CAGE:1W937 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <40% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HUMAN PROTEIN Fraction by Wt: <10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT: 8.54 G/KG ETHYLENE GLYCOL Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ETHYLENE GLYCOL MAY CAUSE IRRITATION OF MUCOUS MEMBRANES & RESPIRATORY PASSAGES. INGESTION: ETHYLENE GLYCOL MAY CAUSE INTOXICATION & COMA. SKIN: ETHYLENE GLYCOL MAY CAUSE IRRITATION. HUMANPROTEIN SOURCES ARE CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREAS THOROUGHLY. INGESTION, EYES OR CONTACT W/OPEN WOUND. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Accidental Release Measures ================== Spill Release Procedures:HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. ABSORB ON INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:HEAT WILL DEGRADE EFFICACY. HANDLE AS IF CAPABLE OF TRANSMITTING INFECTIOUS DISEASE. Other Precautions:STORE AS INDICATED ON DIRECTION INSERT. FOR IN VITRO DIAGNOSTIC USE ONLY. NOT FOR HUMAN OR ANIMAL USE. HANDLE BROKEN OR ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:GENERAL IS ACCEPTABLE Other Protective Equipment:EYE BATH Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:>1 Evaporation Rate & Reference:(WATER = 1): <1 Solubility in Water:COMPLETE Appearance and Odor:AMBER VISCOUS LIQUID, W/SLIGHT ODOR Percent Volatiles by Volume:>75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS NECESSARY FOR BIOHAZARDOUS MATERIALS. DISPOSE OF IN ACCORDANCE W/APPLICABLE FEDERAL, STATE, & LOCAL LAWS & REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AQUALINK, 120062 CAGE:0J879 CAGE:0J879 ============= Composition/Information on Ingredients ============= Ingred Name:POLY-AZIRIDINE; (AZIRIDINE POLYMER) CAS:64265-57-2 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107 AND 1910.108. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:COSMETICS, OR USING TOILET FACILITIES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SKIN:PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION & DERMATITIS. EYES:SEVERE IRRITATION. INHALATION:IRRITATION OF UPPER RESPIRATORY TRACT. IN CONFINED AREA, VAPORS PRESENT IN HIGH CONCENTRA TION MAY CAUSE HEADACHES, NAUSEA OR DIZZINESS. CHRONIC:TESTING OF PRODUCT PRODUCED A MILDLY POSITIVE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:RESPONSE IN THE AMES MUTAGENCITY SCREENING TEST. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE, AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOS IF AFFECTED. PROVIDE OXYG IF BRTHG IS DFCLT & OBTAIN MED ATTN. SKIN:FLUSH AFFECTED AREA W/PLENTY OF WATER. THEN WASH AREA W/SOAP & WATER. REMOVE CONTAMD CLTHG & LAUNDER BEFORE RE-USE. EYES:FLUSH IMMED W/LG AMTS OF WATER FOR AT LEAST 15 MINS. OBTAIN MED ATTN. INGEST:INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:280F,138C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . IF WATER IS USED, FOG NOZZ ARE PREFERED. CLSD CNTNRS MAY BE DOUSED W/WATER SPRAY TO COOL & PVNT CNTNR (SUPDAT) Unusual Fire/Explosion Hazard:DUE TO EXPECTED PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. DECOMP PRODS MAY CNTN CO, OXIDES OF NITROGEN & OTHER ORGANIC COMPOUNDS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENTILATE AREA. DIKE & CNTN SPILLED MATERIAL, REMOVE WITH INERT ABSORBENT THEN FLUSH RESIDUE WITH WATER. PREVENT WASHINGS FROM ENTERING THE WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:STORE IN COOL, DRY PLACE UNDER 60F. KEEP AWAY FROM MOISTURE. AVOID CONT W/SKIN & EYES. STORE OUT OF DIRECT SUNLIGHT. USE ONLY W/ADEQ VENT. AVOID BRTHG OF VAP & SPRAY MIST. AVOID CONT W/EYES & SKIN. WA SH HANDS W/SOAP & WATER AFTER USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CAN NOT BE CONTROLLED BY VENT BELOW OCCUP EXPOS LIMS SET FORTH IN INGRED SECTION, WEAR PROPERLY FITTED ORG VAP RESP APPRVD BY NIOSH TO PVNT OVEREXP. WHEN SANDING/ABRADING DRIED FILM, WEAR PROPERLY FITTED DUST (SUPDAT) Ventilation:MECH VENT REC @ POINT OF SPRAY/MIST RELEASE SO THAT EXPOS TO MATL LIST IN INGRED SECTION IS MAINTAINED BELOW (SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:REMOVE & LAUNDER SOILED CLTHG BEFORE REUSE. WASH HANDS THORO W/SOAP & WATER BEFORE EATING, SMKNG, APPLYING (ING 4) Supplemental Safety and Health FIRE FIGHT PROC:RUPTURE FROM PRESS BUILD-UP. FIRST AID PROC:BY MOUTH TO UNCON PERSON. OBTAIN MED ATTN. WASTE DISP METH:FEDERAL, STATE & LOCAL REGS. RESP PROT:RESP APPRVD BY NIOSH TO PROTECT AGAINST NU ISANCE PARTICULATES WHICH MAY BE GENERATED FROM PROD, FROM UNDERLYING PAINTS/ABRASIVE MEDIUM. VENT:APPLIC EXPOS (ING 3) ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.07 @ 25C Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS AND MOISTURE. Stability Condition to Avoid:WARM STORAGE. Hazardous Decomposition Products:TOX FUMES MAY BE GENERATED WHEN HEATED TO DECOMP. FUMES MAY CNTN CO, OXIDES OF NITROGEN & OTHER ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE PROD SHOULD BE FULLY POLYMERIZED PRIOR TO DISP BY MIXING W/5% ACETIC ACID OR DILUTE MINERAL ACID. THE REC DISP METH IS HIGH TEMP INCIN. DO NOT INCIN CLSD CNTNRS. DISP OF MATL IN ITS MIX, RINSATE S & ANY SPILL RESIDUE MUST BE DONE I/A/W (SUPDAT) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FLOTE KLEEN Preparer's Name:RICHARD A. KUEHNE CAGE:MWSUP CAGE:MWSUP ============= Composition/Information on Ingredients ============= Ingred Name:BENTONITE (AS NUISANCE DUST OR PARTICULATES NOT OTHERWISE REGULATED) CAS:1302-78-9 RTECS #:CT9450000 Fraction by Wt: 5.0% OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST;8990 Ingred Name:ORGANIC GUMS Fraction by Wt: 5.0% Ingred Name:CORROSION INHIBITORS Fraction by Wt: 2.0% Ingred Name:ALKALINE BUFFERS Fraction by Wt: 6.7% Ingred Name:OILS Fraction by Wt: 2.0% Ingred Name:INERT INGREDIENTS (TYPE NOT SPECIFIED) Ingred Name:WATER, H2O CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 36.1% Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 50%.% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:SURFACTANTS Fraction by Wt: 0.2% ===================== Hazards Identification ===================== LD50 LC50 Mixture:30,000 MG/KG ORAL-RAT Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: TRANSIENT IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: TRANSIENT IRRITATION. SKIN: NO EFFECT. NON-SENITIZER ======================= First Aid Measures ======================= First Aid:INGESTION: DRINK LARGE AMOUNTS OF ACIDIC BEVRAGES, INDUCE VOMITING. SKIN: FLUSH WITH WATER. EYE: FLUSH WITH LARGE AMOUNTS OF WATER, GET MEDICL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F pH:12.5 Appearance and Odor:LIQUID Percent Volatiles by Volume:40% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:KEEP FROM FREEZING Hazardous Decomposition Products:NONE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPOXY BONDING SHEETS; PREIMPREGNATED GLASS CAGE:0N092 CAGE:0N092 ============= Composition/Information on Ingredients ============= Ingred Name:FIBROUS GLASS; (FIBERGLASS) CAS:65997-17-3 RTECS #:LK3651000 ACGIH TLV:10 MG/M3 DUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRIMARY EXPOSURE ROUTE IS INHAL OF DUST WHEN MACHINED/ PUNCHED OR FUMES WHEN HEATED. EYE:DUST MAY CAUSE MODERATE IRRITATION. SKIN:DUST MAY CAUSE MODERATE IRRITATION. SKIN ABSORPTION:NOT DETERMINED. IN GEST:DO NOT ALLOW FOOD, DRINK OR TOBACCO IN AN AREA WHERE IT MAY BE CONTAMINATED. INHAL:FIBROUS GLASS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:DUST MAY BE RELEASED FROM FIBER-GLASS CLOTH SUBSTRATE WHEN MACHINED. INHALATION OF DUST MAY CAUSE RESPIRATORY IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE WITH FLOWING WATER FOR AT LEAST 15 MIN. SKIN:WASH IN FLOWING WATER OR SHOWER. REMOVE CONTAMINATGED CLOTHING. INGEST:IF LARGE AMOUNTS ARE INGESTED, CONSULT PHYS. INHAL:IF OVERCOME BY DUS T OR SMOKE, MOVE TO FRESH AIR. IF NOT BREATHING, GIVE MOUTH-TO-MOUTH RESUSCITATION. CALL PHYS. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO*2 AND DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT POSITIVE PRESSURE MODE . Unusual Fire/Explosion Hazard:MAY GIVE OFF TOXIC HYDROGEN BROMIDE OR OTHER TOXIC SUBSTANCES WHEN THERMALLY DECOMPOSED. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE NIOSH/MSHA APPROVED DUST RESPIRATOR. Ventilation:CONTROL AIRBORNE DUST CONCENTRATIONS BELOW EXPOSURE GUIDELINES. WHEN MACHINING PROCEDURES GENERATE DUST, USE ADEQ VENT. Other Protective Equipment:GOWN. Work Hygienic Practices:FOLLOW GOOD HYGIENE PRACTICES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.75+/- 0.25 Solubility in Water:NEGLIGIBLE Appearance and Odor:THIN SHEET MATERIAL, FLEXIBLE. NO NOTICEABLE ODOR UNLESS HEATED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT DETERMINED. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY GIVE OFF VARIOUS PHENOLIC AND/OR BROMINATED COMPOUNDS SUCH AS HBR WHEN THERMALLY DECOMPOSED. CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OF SCRAP. FOLLOW ALL LOCAL, STATE, AND FEDERAL REQUIREMENTS FOR DISPOSAL.
1
eyes_protection_mandatory
======================================================= Product ID: FRAZEE, ENAMEL 5 Cage: 07778 ======================================================= Contractor Summary ======================================================= Cage: 07778 Cage: 07708 ======================================================= Ingredients ======================================================= Cas: 67-64-1 RTECS #: AL3150000 % Wt: 32-40 OSHA PEL: 1000 PPM ACGIH TLV: 750 PPM/1000 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 64-17-5 RTECS #: KQ6300000 % Wt: 5-10 OSHA PEL: 1000 PPM ACGIH TLV: 1000 PPM ------------------------------ Cas: 763-69-9 RTECS #: UF3325000 VP:57 @ 20C % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 67-63-0 RTECS #: NT8050000 % Wt: 0-5 OSHA PEL: 400 PPM ACGIH TLV: 400 PPM/500 STEL ------------------------------ Cas: 78-93-3 RTECS #: EL6475000 % Wt: 0-5 OSHA PEL: 200 PPM ACGIH TLV: 200 PPM/300 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 % Wt: 5-10 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM/150 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 68476-86-8 % Wt: 23 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:INHALATION:EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HEADACHE, POSS UNCON & EVEN ASPHYXIATION. EYE:CAN CAUSE SEVERE IRRIT, REDNESS, TEARING, BLURRED VISION. INGE STION:CAN CAUSE GASTROINTESTINAL IRRIT,NAUSEA, VOMIT, DIARR. SKIN:CAN CAUSE IRRIT FOR SOME PERSONS. (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:CHRONIC:REPORTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN/NERV SYS DMG, SEV OVEREXPOS IN LAB ANIMALS HAS ALSO CAUSED LIVER ABNORM AND DMG TO KIDNEYS, LUNGS, & SPLEEN, HEART & ADRENALS. INTENTIONAL MISUSE BY DELIB CONCENTRATING AND INHALING CONTENTS MAY BE HARMFUL OR FATAL. Medical Cond Aggravated By Exposure: GENERALLY AGGRAVATED BY EXPOSURE - CAN CAUSE RESPIRATORY AND/OR SKIN REACTION. First Aid: INHAL:REMOVE INDIVIDUAL TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYG. IF BRTHG IS STOPPED, GIVE ARTF RESP & SEEK MED HELP. EYES:FLUSH W/WATER FOR @ LST 15 MINS WHILE HOLDING EYELIDS OPEN. INGEST:DO NOT INDUCE VOMIT (ASPIR OF MATL INTO LUNGSCAN CAUSE PNEUM, WHICH CAN BE FATAL). KEEP PERSON WARM, QUIET & GET MED ATTN/POIS CTL CTR. SKIN:WASH W/SOAP & WATER OR VARIOUS HAND CLEANERS, & WASH CLOTHING. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIMINATE ALL IGNITION SOURCES, VENTILATE AREA. ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND TRANSFER TO A CLOSED CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. Handling And Storage Precautions: DO NOT STORE IN AREAS ABOVE 120F, OR IN DIRECT SUNLIGHT, OR NEAR HEAT OR OPEN FLAMES. Other Precautions: STORE LARGE QUANTITIES IN BUILDING PROTECTED FOR STORAGE OF FLAMMABLE LIQUIDS. DO NOT PUNCTURE OR INCINERATE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 0F,-18C Lower Limits: 1.0% Extinguishing Media: ALCOHOL FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD & POSS AUTOIGNIT OR (SUPDAT) Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE AND/OR AUTOIGNITE WHEN EXPOS TO EXTREME HEAT, VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/MAY BE MOVED BY VENTILATION & IGNITED (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPRVD RESP APPROP FOR EXPOS OF CONCERN (FP N). FOR CASUAL/OCCASNL USE-TO AVOID BRTHG VAPS/SPRAY MIST, OPEN WINDOWS & DOORS/USE OTHER MEANS TO ENSURE FRESH AIR ENTRY DURING APPLIC & DRYING. IF E XPERIENCE EYE WATERING, HDCH, (SUPDAT) Ventilation: FOR REGULAR/CONTINUOUS USE-PROVIDE SUFFICIENT MECH (GEN) &/OR LOC EXHAUST VENT TO MAINTAIN EXPOS BELOW TLV'S IN INGREDS. Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER(FP N). WHERE SPEC/UNUSUAL CNDTNS EXIST, SEEK EXPERT ASSISTANCE OF INDUST HYGIENIST. Work Hygienic Practices: WASH HANDS BEFORE EATING/USING WASHROOM, AS WITH ALL CHEMS, MINIMIZE PERSONAL CONTACT. Supplemental Safety and Health: FL PT:(PROPELLENT = 100F). FIRE FIGHT PROC:EXPLO WHEN EXPOS TO EXTREME HEAT. WHEN WATER IS USED, FOG NOZZ ARE PREF. EXPLO HAZ:BY PILOT LIGHTS, OPEN FLAMES, SPARKS, HEATERS, SMKNG, ELEC MOTORS/OTHER LO CATIONS DISTANT FROM MATL HNDLG POINT. RESP PROT:OR DIZZ, INCR FRESH AIR, WEAR RESP PROT (NIOSH TC23C/EQUIV)/LEAVE AREA. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >133F,>56C M.P/F.P Text: 1500F,816C Vapor Pres: SEE INGS Vapor Density: HVR/AIR Spec Gravity: <1 (H*2O=1) Evaporation Rate & Reference: SLOWER THAN ETHER Solubility in Water: SLIGHT TO MODERATE Appearance and Odor: TYPICAL SOLVENT PAINT. Percent Volatiles by Volume: 80-90 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, SPARKS AND OPEN FLAMES. Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND HEAT. Hazardous Decomposition Products: MAY FORM TOXIC MATERIALS, CARBON DIOXIDE/CARBON MONOXIDE, VARIOUS HYDROCARBONS, NITROGEN COMPOUNDS, ETC., WHEN BURNED. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: FRAZEE, ENAMEL 5 Cage: 07778 Company Name: PLASTI-KOTE CO INC Street: 1000 LAKE ROAD Zipcode: 44256 Label Required IND: Y Date Of Label Review: 11/11/1996 Status Code: C Label Date: 11/11/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE:INHALATION:EXCESS INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HEADACHE, POSS UNCON & EVEN ASPHYXIATION. EYE:CAN CAUSE SEVERE IRRIT, REDNESS, TEARING, BLURRED VISION. INGESTION:CAN CAUSE GASTROINTESTINAL IRRIT, NAUSEA, VOMIT, DIARR. SKIN:CAN CAUSE IRRIT FOR SOME PERSONS. CHRONIC:RPTS HAVE ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVENTS W/PERMANENT BR AIN AND NERV SYS DMG, SEV OVEREXP IN LAB ANIMALS HAS ALSO CAUSE LIVER ABNORMALITIES AND DMG TO KIDNEYS, LUNGS, & SPLEEN, HEART & ADRENALS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING OR INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALUBE 500 (50/CS), 1316 Preparer's Name:DEBI CAGE:3Y342 CAGE:3Y648 CAGE:3Y342 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, HYDROTREATED (SEVERE), HEAVY PARAFFINIC; (LUBRICATING OIL BASE STOCK) CAS:64742-54-7 RTECS #:PY8035501 OSHA PEL:N/K ACGIH TLV:5 MG/M3 (MFR) Ingred Name:MOLYBDENUM; (MOLYBDENUM DISULFIDE) CAS:7439-98-7 RTECS #:QA4680000 Other REC Limits:10 MG/M3 (MFR) OSHA PEL:10 PPM ACGIH TLV:10 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:POSSIBLE IRRITATION W/PROLONGED CONTACT. SKIN:IF INJECTED UNDER SKIN, NECROSIS COULD RESULT, GET MEDICAL ATTENTION AS SOON AS POSSIBLE. INGEST:COULD CAUSE DIARRHEA, NAUSEA & IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER & UPPER LIDS, GET MEDICAL ATTENTION. SKIN:WASH W/SOAP & WATER PRIOR TO SMOKING OR EATING, IF INJECTED, GET MEDICAL ATTENTION AS SOON AS POSSIBLE. INHAL:DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:395F,202C Extinguishing Media:FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO COOL HEAT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP & PLACE IN CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE W/STRONG OXIDIZERS. Other Precautions:OBSERVE ALL SAFETY PRECAUTIONS LISTED IN THIS MSDS WHEN HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS W/POSITIVE PRESSURE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:600F,316C Vapor Density:1 Evaporation Rate & Reference:1 Solubility in Water:NONE Appearance and Odor:THICK BLACK GREASE W/PETROLEUM ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX W/STRONG OXIDIZERS. Stability Condition to Avoid:DO NOT EXPOSE TO OPEN FLAME. Hazardous Decomposition Products:INCOMPLETE COMBUSTION CAN YIELD CARBON MONOXIDE & VARIOUS HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISPOSE OF IN A UTILIZED PERMITTED INDUSTRIAL WASTE DISPOSAL SITE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TA-0722 THE PRO CAGE:5P957 CAGE:5P957 ============= Composition/Information on Ingredients ============= Ingred Name:CLAY (KAOLIN), ALUMINUM SILICATE 95-4 CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 30-50% ACGIH TLV:10 MG/CUM TOTAL DUST Ingred Name:SILICON DIOXIDE, CRYSTALLINE QUARTZ, SAND (ANIMAL CARC, SUSPECTED HUMAN CARC IARC-GROUP 2A; SUSPECTED CARC NTP) *95-4* CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 0.1-1% Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:0.1 MG/CUM RESP DUST ACGIH TLV:0.1 MG/CUM RESP DUST Ingred Name:LEAD, INORGANIC LEAD (IARC CARC GROUP 2B) *95-4* CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: <0.0023% ACGIH TLV:0.15 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ALIPHATIC HYDROCARBON Fraction by Wt: 1-5% Ingred Name:HYDROCARBON OILS Fraction by Wt: 1-5% Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 1-5% Other REC Limits:525 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TRIETHANOLAMINE*95-4* CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 1-5% Other REC Limits:A2 CARCINOGEN ACGIH TLV:3.1 MG/CUM IC Ingred Name:VOLATILE ORGANIC CONTENT: 78.8 GM/L; 122.8 GM/L (LESS WATER & EXEMPT SOLVENTS) RTECS #:9999999VO Ingred Name:CADMIUM (SUSPECTED HUMAN CARCINOGEN BY IARC, SUPSECTED CARCINOGEN BY NTP, IARC - GROUP 1)*95-4* CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: <0.0002% Other REC Limits:A2 CARCINOGEN OSHA PEL:0.05 MG/CUM (CD) ACGIH TLV:0.01 MG/CUM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 8 MG/KG TRIETHANOLAMINE Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:POSSIBLE CANCER HAZARD. CONTAINS A MATERIAL WHICH MAY CAUSE CANCER. EYES/SKIN: IRRITATION. INGESTION: HARMFUL. LONG-TERM OVEREXPOSURE TO CRYSTALLINE SILICA MAY CAUSE PERMANENT LUNG DAMAGE & REDUCED PU LMONARY FUNCTION. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, DIZZINESS, HEADACHES, NAUSEA, UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: GIVE 1 GLASS OF WATER/MILK. DON'T INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOU S PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL/CO2 ON DRIED PRODUCT. Fire Fighting Procedures:WEAR SCBA & FULL PROTECTIVE EQUIPMENT. WATER SPRAY MAY BE USED TO COOL THE CONTAINERS. Unusual Fire/Explosion Hazard:NON-FLAMMABLE IN LIQUID STATE. POSSIBLE PRESSURE BUILDUP IN CLOSED CONTAINERS WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE, CONTAIN W/INERT ABSORBENT & TRANSFER TO CONTAINERS FOR DISPOSAL. KEEP PRODUCT OUT OF SEWERS, WATERSHEDS/WATER SYSTEMS. ======================Handling and Storage ====================== Handling and Storage Precautions:WEAR APPROPRIATE PROTECTIVE EQUIPMENT. AVOID EXTREME TEMPERATURE. Other Precautions:IN STORAGE, SOLVENT & MONOMER VAPORS WILL MIGRATE FROM THE EMULSION & ESTABLISH AN EQUILIBRIUM BETWEEN THE HEADSPACE IN THE STORAGE CONTAINER & LIQUID EMULSION. LEVELS IN EXCESS OF ACCEPTABLE EXPOSURE S CAN ACCUMULATE IN HEADSPACE >EMULSION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR IF CONDITIONS WARRANT. Ventilation:GENERAL DILUTION VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING, EYE WASH STATION. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ALL PROCEDURES APPROPRIATE FOR A CONFINED SPACE ENTRY SHOULD BE COMPLETED PRIOR TO PERFORMING ANY WORK IN BULK STORAGE TANK. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F Spec Gravity:1.229 pH:8.9 Appearance and Odor:TAN PASTE W/SLIGHT SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME TEMPERATURE Hazardous Decomposition Products:HYDROCARBONS, CO, NITROGEN COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:SOLIDIFY & DISPOSE OF IN AN APPROVED LANDFILL. DISPOSE OF IAW/STATE, LOCAL/PROVINCIAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:A399-4 1-BUTANOL CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: >99% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL,RAT:LD50=790MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:MAY CAUSE MODERATE IRRIT.MAY RESULT IN CORNEAL INJURY VAP MAY CAUSE IRRIT.SKIN:CAUSES IRRIT.MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS.PROL &/OR RESP CONTACT MAY CAUSE DEFATTING OF SKIN,DERM.INGEST :MAY CAUSE SYST TOXICITY W/ACIDOSIS.MAYCAUSE LIV/KID DMG.MAY CAUSE CNS DEPRESS(HEAD,DIZZ,DROWS,NAU.ADV STAGE-(SIGN/SYM) Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NOT LISTED BY ACGIH,IARC,NIOSH,NTP,OSHA. Effects of Overexposure:HEALTH:COLLAPSE,UNCONSC,COMA,DEATH-RESP FAILURE).MAY BE HARMFUL.INHAL:HI CONC MAY CAUSE CNS EFFECTS(HEAD,DIZZ,UNCONSC,COMA).CAUSE RESP TRACT IRRIT,LIVER/KID DMG.CHRONIC:REP EYE EXPO CAUSE VISUAL ABNOR MALITIES INCLUDE BLUR VISION,PHOTOSENSITIVITY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. TARGET ORGANS:KIDNEYS,CENTRAL NERVOUS SYSTEM,LIVER. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/LOTS OF H2O @LEAST 15MIS,LIFT LIDS.GET MED AID.DONT ALLOW TO RUB OR KEEP EYES CLSD.SKIN:FLUSH W/LOTS OF SOAP/H2O @LEAST 15MINS.REMOVE CONTAM CLOTH/SHOE.IRRIT DVLPS/PERSIST GET EMD AI D.INGEST:CONSC/ALERT GIVE 2-4CUP OF MILK/H2O.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.GETE MED AID IMMED.INHAL:MOVE TO FRESH AIR.NOT BREATH GIVE ART RESP;BREATH DIFFI GIVE OXY.GET MED AID.(SUPPLE) ===================== Fire Fighting Measures ===================== Flash Point:98.6F,37.0C Autoignition Temp:Autoignition Temp Text:689F Lower Limits:1.4 Upper Limits:11.2 Extinguishing Media:SM:DRY CHEM,CO2.H2OSPRAY,ALCO-RESIST FOAM.LG:H2OSPRAY,FOG,ALCO-RESIST FOAM.USE H2OSPRAY TO COOL FIRE-EXPO CNTNR.(SUPPLE) Fire Fighting Procedures:WEAR SCBA IN PRESSURE-DEMAND MSHA/NIOSH(APPROV/EQUIV),FULL PROT GEAR.COOL FIRE-EXPO CNTNR W/H2OSPARY.H2O MAY BE INEFFECTIVE;MATL LIGHTER THAN H2O FIRE MAY(SUPP) Unusual Fire/Explosion Hazard:WARNING!FLAMM LIQ.CAN RELEASE VAP FORM EXPLO MIX @TEMP >FLASHPT.VAP MAY FORM EXPLO MIX W/AIR.VAP TRAVEL TO IGN SOURCE-FLASHBK. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PPE AS INDICATED IN MSDS.AVOID RUNOFF INTO STORM SEWERS/DITCHES WHICH LEAD TO WATERWAYS.REMOVE ALL SOURCES OF IGNITION.ABOSRB SPILL USING ABSORBENT,NON-COMBUSTIBLE MATL SUCH AS EARATH,SAND, VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL VENTI AREA.GROUND/BOND CNTNR WHEN TRANSF MATL.USE SPARK-PROOF TOOLS/EXPLO PROOF EQMPT.EMPTY CNTNR RETAIN RESIDUE-CAN BE DANGEROUS. Other Precautions:AVOID CONTACT W/HEAT/SPARKS/FLAME.AVOID INGEST/INHAL.DONT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND,EXPO EMPTY CNTNR TO HEAT/SPARK/OPN FLAME.STORE IN TIGHTLY CLSD CNTNR,IN COOL DRY WELL-VENTI AREA AWAY FROM INCOMPAT SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPRIATOR REGUALTINS FOUND IN 29CFR1910.134.ALWAYS USE NIOSH-APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW PERMISSIBLE EXPO LIMITS. Other Protective Equipment:WEAR APPROP PROT CLOTH TO PREVENT SKIN EXPO.EYES-29CFR1910.133. Work Hygienic Practices:WASH WELL AFT HNDLG.REMOVE CONTGAM CLOTH;WASH BEF REUSE. Supplemental Safety and Health 1STAID:DR NOTE:TREAT SYMPT/SUPPORT. FIREFIGHT:BE SPEAD BY USE OF H2O.VAP HEAV THAN AIR;CAN SPREAD ALONG GROUND/COLLECT IN LOW/CONF AREAS. EXT MEDIA:COOL CNTNR W/FLOOD QUANT OF H2O TIL WELL AFT FIRE OU T. DISPO:CONSISTENT W/FED/STATE/LOC REGS.RCRA WASTE#U031(IGN WASTE).BAN FRM LAND DISPO PER RCRA.SARA 313,RQ=5000LBS. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=117.2C, 243.F Melt/Freeze Pt:=-90.C, -130.F Decomp Temp:Decomp Text:N/AVAI Vapor Pres:6.5 Vapor Density:2.6 Spec Gravity:0.8 pH:N/AVAI Viscosity:2.94 CP @20C Evaporation Rate & Reference:0.46, BUTYL ACETATE=1 Solubility in Water:9.1ML/10ML H20,APPRE Appearance and Odor:COLOURLESS LIQUID, SWEETISH ODOR,PUTRID ODOR,BANANA-LIKE Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM,CHROMIUM TRIOXIDE,ORGANIC PEROXIDES,STRONG OXIDIZERS. Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATLS,IGNITION SOURCES. Hazardous Decomposition Products:CAROBN MONOXIDE,CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN RELEASE TO SOIL EXPECTED TO BIODEGRADE,LEACH TO GROUND H2O OR VOLATILIZE;IN H2O-BIODEGRADE OR VOLATILIZE.BIOCONC POT PREDICTED TO BE LOW.SUBST MODERATELY-HI MOBILE.SUBST RXS W/AIR W/HYDROXYL RADI CALS(1/2LIFE-2.3DAYS).DISPOSE OF IN MANNER(SUPPE)
1
eyes_protection_mandatory
======================================================= Product ID: GREASES SUS-2, PREMIUM LITHIUM EP-2 GREASE, 55-212 Cage: 7X110 Box: 3758 Resp. Party Other MSDS No.: 4774 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 7X110 Box: 3758 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENT 1 Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: INHAL: AT ELEVATED TEMPS DENSE FUMES DEVELOP WHICH MAY CAUSE PULMONARY IRRIT & RESPIRATORY DIFFICULTIES. SKIN: THE PRODUCTS REPRESENTED BY THIS MSDS MAY CAUSE MILD SKIN IRRIT. EYES: THE PRODUCT S REPRESENTED BY THIS MSDS MAY CAUSE EYE IRRIT. INGEST: MILD IRRITATION OF GI TRACT, CRAMPS & NAUSEA MAY OCCUR UPON INGESTION. GI BLOCKAGE MAY OCCUR IF LARGE QUANTITIES OF PRODUCT ARE SWALLOWED. INJEC TION: INJECTION UNDER THE SKIN, IN MUSCLE OR INTO THE BLOOD STREAM MAY CAUSE IRRITATION, ERYTHEMA, EDEMA OR SEVERE PERMANENT TISSUE DAMAGE. CHRONIC: PRLNGD &/OR FREQUENT CONTACT MAY CAUSE IRRIT, DRYIN G, CRACKING OF (EFTS OF OVEREXP) Signs And Symptions Of Overexposure: HLTH HAZS: SKIN, BUT RARELY DERMATITIS OR FOLLICULITIS. OTHER SPECIAL EFFECTS: NONE EXPECTED. Medical Cond Aggravated By Exposure: REPEATED OR PROLONGED SKIN CONTACT MAY AGGRAVATE PRE-EXISTING DERMATOSES. First Aid: INHAL: MOVE TO FRESH AIR. IF NOT BRTHG, IMMED BEGIN CPR. IF BRTHG DFCLT, 100% HUMIDIFIED OXYG SHOULD BE ADMINISTERED BY QUALIFIED INDIVIDUAL. SEEK MED ATTN IMMED. SKIN: REMOVE CONTAM CLTHG. WASH EXPOS ED SKIN W/SOAP & WATER. LAUNDER CLTHG BEFORE USE. SEEK MED ATTN IF TISS APPEARS DAMAGED OR IF IRRIT PERSISTS. EYES: FLUSH EYES W/COOL WATER WHILE OCCASNLY LIFTING & LOWERING EYELIDS. REMOVE CONTACT LE NSES IF WORN. SEEK MED ATTN IF EXCESSIVE TEARING, IRRIT OR PAIN PERSISTS. INGEST: INDUCE VOMIT ONLY UPON ADVICE OF MD. NEVER GIVE ANYTHING BY MOUTH TO PERSON WHO IS NOT FULLY CONSCIOUS. SEEK MED (SUPD AT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE ALL IGNIT SOURCES. ISOLATE AREA OF SPILL & RESTRICT ACCESS TO PERS WEARING PROT CLTHG. VENT AREA OF RELS, AS NEC, TO DISPERSE VAPS & MISTS. SM SPILLS: ABSORB RELEASED MATL W/NON-COMBUST ABSORB. PLACE INTO CNTNRS FOR LATER DISP. LG SPILLS: EVACUATE AREA IN EVENT OF SIGNIFICANT SPILLS. EVACUATE EXPOS POTNTL. USE PROT CLTHG. CONTAIN SPILL IN TEMPORARY DIKES (ECOLOGICAL INFO) Waste Disposal Methods: IT IS RESPONSIBILITY OF USER TO DETERM IF MATL IS HAZ WASTE AT TIME OF DISP. DETERM COMPLIANCE STATUS W/ALL APPLIC REQS PRIOR TO DISP. CNTCT RCRA/SUPERFUND HOTLINE AT 800-424-9346 OR YOUR REGIONAL US EPA OFFICE FOR GUIDANCE CONCERNING CASE SPECIFIC DISP ISSUES. PROT MEASURES DURING REPAIR & MAINT OFCONTAM EQUIP: REFER TO SECTION (ECOLOGICAL INFO) Handling And Storage Precautions: STORE IN A COOL, DRY AREA. DO NOT APPLY HEAT OR FLAME TO CONTAINER. KEEP SEPARATE FROM STRONG OXIDIZING AGENTS. Other Precautions: EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUES THAT MAY IGNITE WITH EXPLOSIVE FORCE. CONSULT APPROPRIATE FEDERAL, STATE AND LOCAL AUTHORITIES BEFORE REUSING, RECONDITIONING, RECLAIMING, RECYCLING OR DI SPOSING OF EMPTY CONTAINERS AND/OR RESIDUES OF THIS PRODUCT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: OC Flash Point: >128.C, 262.4F Flash Point Text: (OTHER INFO) Autoignition Temp Text: ND Lower Limits: NO DATA Upper Limits: NO DATA Extinguishing Media: CO*2, DRY CHEMICAL, FOAM, WATER FOG. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). WATER STREAM MAY SPREAD FIRE; USE WATER SPRAY ONLY TO COOL CONTAINERS NOT ON FIRE. Unusual Fire/Explosion Hazard: WILL NOT FLASH SPONTANEOUSLY; MAY IGNITE IF EXPOSED TO OPEN FLAME. NFPA RATING (LEAST-0, SLIGHT-1, MODERATE-2, HIGH-3, EXTREME-4): HEALTH: 0; FLAMMABILITY: 1; REACTIVITY: 0. ======================================================= Control Measures ======================================================= Respiratory Protection: AT ELEVATED TEMPERATURES, VAPOR OR MIST CONCENTRATIONS MAY EXCEED APPLICABLE WORKPLACE EXPOSURE LEVELS. USE A NIOSH APPROVED ORGANIC VAPOR/MIST CHEMICAL CARTRIDGE RESPIRATOR WHEN ELEVATED AIRBORNE CON CENTRATIONS ARE ANTICIPATED. Ventilation: USE IN WELL VENTD AREA. IN CONFINED SPACES, MECH VENT MAY BE REQD TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW APPLIC WORKPLACE EXPOS LEVELS (OTHER INFO) Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). WEAR BODY-COVERING WORK CLOTHES TO AVOID PRLNGD/RPTD EXPOSURE. LAUNDER CONTAMINATED WORK CLOTHES BEFORE REUSE. Work Hygienic Practices: PERSONAL PROT EQUIP SHOULD BE SELECTED BASED UPON CNDTNS UNDER WHICH THIS MATL IS USED. HAZ ASSESSMENT OF WORK AREA FOR PPE REQS SHOULD BE CONDUCTED BY QUALIFIED PROFESSIONAL PURSUANT TO OSHA REGS. Supplemental Safety and Health: FIRST AID PROC: ATTN IF IMMED. INJECTION: INJECTION UNDER SKIN, IN MUSC/ INTO BLOOD STREAM IS MED EMER. SEEK MED ATTN IMMED. NOTES TO MD: UPON INJECTION, APPLY PROMPT SURGICAL DEBRIDEMENT. INGESTION OF SM QTYS WILL PASS THRU SYS, LG QTYS SHOULD BE REMOVED BY EMESIS/CAREFUL LAVAGE TO PVNT INTESTINAL BLOCKAGE & IRRIT. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: >271.1C, 520.F B.P. Text: 271-427(520-800) M.P/F.P Text: NO DATA Vapor Pres: 1 X 10*-5 TO 2 X 10*-2 Vapor Density: >1(AIR=1) Spec Gravity: NO DATA Solubility in Water: NEGLIGIBLE Appearance and Odor: GRAY/BLACK, RED TO AMBER PASTE; MILD SOAP ODOR. Percent Volatiles by Volume: NEGLIGIBLE ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: THIS PRODUCT MAY REACT WITH STRONG OXIDANTS, ACIDS AND CAUSTICS. Hazardous Decomposition Products: CO*2, (CO WITH INCOMPLETE COMBUSTION). Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: TOXICITY SUMMARY: GENERALLY OF A LOW ORDER OF TOXICITY. ======================================================= Ecological Information ======================================================= Ecological: SPILL PROC: TO AVOID PROD MIGRATION & TO ASSIST IN RECOVERY. DO NOT ALLOW MATL TO ENTER SEWERS, GROUND WATER, DRAINAGE DITCHES OR SURF WATERS. ADMIN APPROP FIRST AID. REPORT RELS AS REQD TO APPROP FED , STATE & LOCAL AUTHS. WASTE DISP METH: ON SPEC PROT INFO. DRAIN & PURGE MATLS SUCH AS HEAVY NITRILE RUB & PROT WORK CLTHG IF DIRECT, EXTENDED, CNTCT IS ANTIC. ELIM HEAT & IGNIT SOURCES. WASH EXPOS SKIN THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLTHG. LAUNDER BEFORE REUSE. KEEP UNNEC PERSONS FROM HAZ AREA. ======================================================= ======================================================= Transport Information: DOT INFORMATION: PROPER SHIPPING NAME: PETROLEUM GREASE. HAZARD CLASS: NON HAZARDOUS. HAZARD IDENTIFICATION NO: NONE ASSIGNED. PACKAGING GROUP: NONE ASSIGNED. PLACARD: NONE. COMPATIBILITY CATEGORY: NO DATA. CHRIS CODE: NO DATA. ======================================================= Regulatory Information ======================================================= Sara Title III Information: PRODS REPRESENTED BY THIS MSDS MAY CNTN FOLLOWING COMPONENTS IN CONCS ABOVE "DE MINIMIS" LEVELS LISTED AS TOX CHEMS IN 40 CFR 372 PURSUANT TO REQS OF SECTION 313 OF SARA: ZINC CMPDS: 0-5% CONC; ANTIMO NY CMPDS: 0-5% CONC. PROD MAY MEET ONE/MORE OF CRITERIA FOR HAZ CATEGORIES DEFINED IN 40 CFR 370 AS ESTABLISHED BY SECTIONS 311 & 312 OF SARA AS INDICATED: IMMED (AUCTE) HLTH HAZ: NO; DELAYED (CHRONIC ) HLTH HAZ: NO; FIRE HAZ: NO; SUDDEN RELS OF PRESS HAZ: NO; REACTIVE HAZ: NO. PROD IS NOT KNOWN TO CNTN ANY COMPONENTS LISTED AS EXTREMELY HAZ IN CONCS GREATER THAN 1$ IN 40 CFR 355 PURSUANT TO REQS O F SARA 302(A). Federal Regulatory Information: UNDER CLEAN WATER ACT (CWA), DISCHARGES OF CRUDE OIL & PETROLEUM PRODS TO SURF WATER W/OUT PROPER FED & STATE PERMITS MUST BE REPORTED IMMED TO NATIONAL RESPONSE CENTER AT 800-424-8802. AS DEFINED BY COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION & LIABILITY ACT (CERCLA) SECTION 102, THE TERM "HAZ SUBSTANCE" DOES NOT INCLUDE PETROLEUM, INCLUDING CRUDE OIL OR ANY FRACTION THEREOF WHICH IS NOT O THERWISE SPECIFICALLY LISTED OR DESIGNATED AS HAZ SUBSTANCE. TOXIC SUBSTANCES CONTROL ACT (TSCA): RE PORTED IN TSCA INVENTORY AS: CITGO GREASES SUS-2 - COMPONENTS. State Regulatory Information: THIS MATERIAL CONTAINS COMPONENTS THAT ARE KNOWN TO THE STATE OF CALIFORNIA TO BE: CARCINOGENIC: NO. REPRODUCTIVE HAZARD: NO. ======================================================= Other Information ======================================================= Other Information: MATL HAZARD EVALUATION (PER OSHA HAZ COMMUNICATION STANDARD (29 CFR 1910.1200)): HEALTH PRECS: PROTECT EXPOSED SKIN FROM RPTD/PRLNGD EXPOS. SAFETY PRECS: DO NOT STORE MATL IN OPN OR UNMARKED CNTNRS. H MIS RATING 1 (SLIGHT); HEALTH: 0 (LEAST); FLAMMABILITY: 1 (SLIGHT); REACTIVITY: 0 (LEAST). CITGO ASSIGNED THESE VALUES BASED UPON AN EVALUATION CONDUCTED PURSUANT TO NPCA GUIDELINES. FL PT/METH: APPRO X 128-269C/263-515F/OC; NO DATA/CC. VENT: AS EVALUATED BY DESIGNATED & PROPERLY TRAINED PERSONNEL. ======================================================= HAZCOM Label ======================================================= Product ID: GREASES SUS-2, PREMIUM LITHIUM EP-2 GREASE, 55-212 Cage: 7X110 Company Name: CITGO PETROLEUM CORP Street: 6100 S YALE AVE PO Box: 3758 Zipcode: 74102 Label Required IND: Y Date Of Label Review: 04/19/2000 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION: AT ELEVATED TEMPERATURES MAY CAUSE PULMONARY IRRITATION AND RESPIRATORY DIFFICULTIES. SKIN: MILD SKIN IRRITATION. EYE: EYE IRRITATION. INGESTION: MILD IRRITATION OF GI TRACT, CRAMPS AND NAUSEA MAY OCCUR. GI BLOCKAGE MAY OCCUR IF LARGE QUANTITIES OF PRODUCT SWALLOWED. INJECTION: INJECTION UNDER SKIN, IN MUSCLE OR INTO BLOOD STREAM MAY CAUSE IRRITATIION, ERYTHEMA, EDEMA OR SEVERE PERMANENT TISSUE DAMAGE. CHRONIC: IRRITATION, DRYING CRACKING OF SKIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT, MIL-C-83286, 17925, L-8733 CAGE:DO188 CAGE:33461 CAGE:DO188 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% Other REC Limits:N/K OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI) CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 55% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 35% Other REC Limits:N/K OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRIT. SKIN: IRRIT. INHAL: VAPORS ARE IRRIT TO EYES, NOSE, THROAT AND MAY CAUSE HEADACHES, DIFFICULT BREATHING AND LOSS OF CONSCIOUSNESS. CHRONIC: AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURE O R SINGLE LG DOSE, CERTAIN PEOPLE WILL DEVELOP ISOCYANATE SENSIT WHICH WILL CAUSE THEM TO REACT TO A LATER (SUPP DATA) Effects of Overexposure:EYES: LIQUID, AREOSOLS, OR VAPORS ARE IRRIT & MAY CAUSE TEARING, REDNESS & SWELLING & A STINGING SENSATION. SKIN: ISOCYANATES REACT W/SKIN PROTEIN & MOISTURE, CAN CAUSE IRRIT W/SWELLING, REDNESS, & RA SH. INHAL: IRRIT OF THE RESP TRACT & ACUTE NERVOUS SYS DEPRESS W/HEADACHE, DIZZ, STAG GAIT, CONFUSION, UNCON (SUPP DATA) Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMITITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/CLEAN LUKEWARM WATER (LOW PRESS) FOR AT LEAST 15 MIN, OFTEN LIFTING EYE LIDS. GET MEDICAL HELP. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA W/SOAP & WATER. INHALATION: REMOVEFROM EXPOS. RESTORE BRTH. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP & MAY BE IMMED OR DELAYED BY SEVERAL HRS. GET MD. INGESTION: DON'T INDUCE VOMITING OR GIVE ANYTHING TO AN UNCON PERSON. GET MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:1 Upper Limits:N/K Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT WATER CAN BE USED TO COOL CONTAINERS TO PREVENT AUTO-IGNITION/EXPLOSION (MFR). Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, SPARKS, ELEC EQUIP & OPEN FLAME. CONTAINERS MAY EXPLODE(EXTREME HEAT). APPLICATION TO HOT SURFACES(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:USE SPACE THAT COMPLY W/OSHA 1910.106. ISOLATE FROM HIGH TEMP, FIRE, OPEN FLAMES, & SPARK SOURCES. STORE IN TIGHTLY CLOSED CONTRS IN WELL VENTED AREA. Other Precautions:KEEP CONTAINERS TIGHT & UPRIGHT (PREVENT LEAKAGE). AVOID PROLONGED BREATHING OF VAPOR OR SPRAY MISTS. PROLONGED OVEREXPOSURE MAY CAUSE AN ALLERGIC REACTION. AVOID SKIN OR EYE CONTACT. DO NOT HANDLE U NTILL PRECAUTIONS ARE READ & UNDERSTOOD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATIOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:VENTILATION APPROPRIATE FOR CONDITIONS OF USE. CONSULT INDUSTRIAL HYGIENIST/SAFETY SPECIALIST FOR SPECIFIC GUIDANCE FP N Other Protective Equipment:LONG SLEEVE & LONG LEG CLOTHING RECOM. REMOVE & WASH CONTAM CLOTHING BEFORE REUSE. EMERG EYEWASH & DELUGE SHOWER . Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health UNUSUAL FIRE & EXPL. HAZ: REQUIRES SPECIAL PRECAUTIONS. OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZ. SYMPTOM MAY NOT BE IMMED APPARENT. HEALTH HAZ ACUTE/CHRONIC: EXPOSURE OF ISOCYANA TE LEVELS WELL BELOW THE TLV VALUE OF ISOCYANATES. EYE PROT: FULL ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:231F,111C Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:> AIR Spec Gravity:0.96 Evaporation Rate & Reference:1.36 X N-BUTYL ACETATE Solubility in Water:N/K Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:52.7 Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH REACT WITH ISOCYANATES AND HIGHT TEMPERATURES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND HDI. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. HANDLE EMPTY CONTAINERS WITH CARE DUE TO RESIDUE AND FLAMMABLE VAPOR. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:11436 SILVER SHOT CAGE:JOMCC CAGE:JOMCC ============= Composition/Information on Ingredients ============= Ingred Name:SILVER CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: 100% OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION/INHALATION: MAY CAUSE KIDNEY DAMAGE. SKIN: MAY CAUSE LOCALIZED PIGMENTATION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN: FLOOD W/LARGE AMOUNTS OF WATER. EYES: FLUSH, INCLUDING UNDER EYELIDS, W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:IF METAL IS BURNING USE DRY CHEMICAL EXTINGUISHING AGENTS/DRY SAND/GROUND DOLOMITE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA/FLAME/CHEMCIAL RESISTANT CLOTHING. REMOVE FROM FIRE AREA. COOL CONTAINER DOWN W/WATER FROM MAXIMUM DISTANCE. Unusual Fire/Explosion Hazard:ONLY POWDER FORMS ARE LIKELY TO BE A FIRE HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL PROTECTIVE EQUIPMENT. COVER W/DRY SAND/VERMICULITE. MIX WELL & CAREFULLY TRANSFER TO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR FINE POWDER NIOSH/MSHA APPROVED DUST MASK REQUIRED. Ventilation:FOR FINE POWDER HANDLE UNDER INERT ATMOSPHERE. Other Protective Equipment:LAB COAT/APRON/FLAME/CHEMICAL RESISTANT COVERALLS/EYEWASH CAPABLE FLUSHING/SAFETY DRENCH SHOWER/HYGENIC FACILITIES. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:4010F Melt/Freeze Pt:M.P/F.P Text:1761.44F Vapor Pres:0 Vapor Density:10.49 Spec Gravity:10.49 Solubility in Water:INSOLUBLE Appearance and Odor:SOFT, DUCTILE, LUSTROUS WHITE METAL W/NO ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETYLENE/AMMONIA/BROMOAZIDE/CHLORINE TRIFLUORIDE/ETHYLENE IMINE/OXALIC ACID/TARTARIC ACID/MINERAL ACIDS/OXIDIZERS. Stability Condition to Avoid:HEAT, SPARKS & FLAME FOR POWDER. Hazardous Decomposition Products:SILVER OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT STATE, LOCAL & FEDERAL EPA REGULATIONS FOR PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STP OIL TREATMENT, ST1024 Preparer's Name:J.O. FUNDERBURK CAGE:DO273 CAGE:0AC35 CAGE:DO273 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED (SEVERE), HEAVY PARAFFINIC; (SOLVENT DEWAXED HEAVY PARAFFINIC (ING 2) CAS:64742-65-0 RTECS #:PY8038501 Fraction by Wt: 65-80% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:ING 1: PETROLEUM, DISTILLATE, HYDROTREATED) RTECS #:9999999ZZ Ingred Name:MINERAL OIL,HYDROTREATED (SEVERE), HEAVY NAPHTHENIC DISTILLATE; (HYDROTREATED HEAVY NAPHTHENIC PETROLEUM DISTILLATE) CAS:64742-52-5 RTECS #:PY8035001 Fraction by Wt: 20-35% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1) (ZDDP); (ZINC DITHIOPHOSPHATE) CAS:68649-42-3 Fraction by Wt: 1-3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM SULFONATE; (CALCIUM ALKARYL SULFONATE) CAS:71486-79-8 Fraction by Wt: 1-3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMINE GRAFTED ETHYLENE/PROPYLENE COPOLYMER Fraction by Wt: 3-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:AT LEAST 15 MIN. SEEK MED ATTN. NOTES TO MD:THERE IS NO SPECIFIC ANTIDOTE. TREATMENT OF OVEREXP SHOULD (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITIONS. IF THIS PRODUCT IS ASPIRATED FOLLOWING (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:INGESTION, IT MAY LEAD TO A LIPID PNEUMONIA. RTECS #:9999999ZZ Ingred Name:RESP PROT:PRACTICE. FOR FIREFIGHTING, USE SELF-CONTAINED BREATHING APPARATUS. RTECS #:9999999ZZ Ingred Name:VENT:EXHAUST MAY BE NEEDED TO MAINTAIN EXPOSURE LEVELS BELOW APPLICABLE LIMITS. RTECS #:9999999ZZ Ingred Name:EYE PROT:AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:INHAL TOX:EXCESSIVE INHAL OF VAP/MIST MAY CAUSE IRRIT OF THE NOSE & THROAT & CNS EFTS INCL (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:HEADACHE, NAUSEA & DROWSINESS. THE RELEASE OF HYDROGEN SULFIDE GAS IN VARIOUS CONCENTRATIONS MAY CAUSE (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:IRRITATION OF THE EYES AND RESP TRACT, HEADACHE, DIZZINESS, NAUSEA AND DROWSINESS. EXPOSURE TO HIGH (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:CONCENTRATIONS OF HYDROGEN SULFIDE MAY BE FATAL.SENSITIZATION:THIS PRODUCT IS NOT EXPECTED TO BE A HUMAN(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:SKIN SENSITIZER BASED ON RESULTS FORM HUMAN SKIN PATCH TESTING. CHRONIC TOCICITY:PROLONGED OR REPEATED (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:CONTACT WITH THIS PRODUCT MAY POSSIBLY LEAD TO IRRITATION AND DERMATITIS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): >5G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:WARNING! ACCIDENTAL INGEST OF THIS MATL MAY CAUSE GI DISTURB INCLUDING IRRIT, NAUS, VOMIT & DIARR. ASPIR FROM INGEST MAY CAUSE LIPID PNEUMONIA. BRTHG HIGH CONCS OF VAPS MAY CAUSE RESP IRRIT & CNS EFTS INCL HDCH, NAUSEA, & DROW. MAY CAUSE EYE & SKIN IRRIT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:TOXICOLOGICAL INFO:ORAL TOX:SWALLOWING LRG AMTS MAY CAUSE GI DISURB INCL ABDOM DISCOMFORT, BELCHING, NAUSEA & DIARR. ASPIR MAY LEAD TO LIPID PNEUMONIA. EYE IRRIT:MAY CAUSE EYE IRRIT W/TEARING , REDDENING & SWELLING OF CONJUNCTIVA. SKIN IRRIT:MAY CAUSE IRRIT, SEEN AS LOCALIZED REDNESS & SWELLING. (ING 13) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING SKIN DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INGEST:GET MED ATTN BY CALLING MD, POIS CTL CTR/HOSPITAL EMER ROOM. IF MED ADVICE CANNOT BE OBTAINED, THEN TAKE PERS & PROD TO NEAREST MED EMER TREATMENT CENTER/HOSPITAL. NEVER GIVE ANYTHING BY MOUTH TO PERS WHO IS UNCONSCIOUS/DROWSY. SKIN: REMOVE CONTAMD CLTHG. WASH ALL AFFECTED & EXPOSED AREAS W/SOAP & H*2O. IF SKIN IRRIT/REDNESS PERSISTS SEEK MEDICAL ATTN. INHAL:REMOVE TO FRESH AIR. (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:400F,204C Extinguishing Media:USE WATER SPRAY, FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER OR FOAM MAY CAUSE FROTHING. USE WATER TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:THE VAPOR SPACE IN CLOSED CONTAINER MAY CONTAIN HYDROGEN SULFIDE IN EXPLOSIVE CONCENTRATIONS. HYDROGEN SULFIDE MAY BE RELEASED WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. AVOID BREATHING VAPOR. COLLECT MATERIAL WITH SUITABLE ABSORBENT MATERIAL AND SHOVEL INTO APPROPRIATE CONTAINER FOR DISPOSAL. PREVENT PRO DUCT FROM ENTERING SEWER OR WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING VAPORS AND MISTS. USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. Other Precautions:AVOID EXPOSURE TO HIGH TEMPERATURES FOR PROLONGED PERIODS. AVOID WATER CONTAMINATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORM USE CNDTNS. FOR OPERATIONS WHERE THE TLV MAY BE EXCEEDED, NIOSH APPRVD SUPPLIED AIR RESP IS REC. EQUIP SELECTION DEPENDS ON CONTAM TYPE & CONC, SELECT I/A/W/29 CFR 1910.134 & GO OD INDUSTRIAL HYGIENE (ING 10) Ventilation:GENRL VENT SHOULD BE ADEQ FOR NORM USE. FOR OPERATIONS WHERE TLV MAY BE EXCEEDED, MECH VENT SUCH AS LOCAL (ING 11) Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . PROT CLTHG IS NEEDED TO AVOID PRLNG/RPTD SKIN CONTACT. Work Hygienic Practices:WASH EXPOSED SKIN W/SOAP & WATER AFTER USE. CONTAMD CLTHG SHOULD BE REMOVED & LAUNDERED OR DRY-CLEANED BEFORE RE-USE. Supplemental Safety and Health HAZ DECOMP PROD:ALDEHYDES, KETONES, & OXIDES OF NITROGEN, SULFUR, CALCIUM, ZINC/PHOSPHORUS. FIRST AID PROC:IF BRTHG BECOMES DFCLT, ADMINISTER OXYGEN. ADMINISTER ARTF RESP IF BRTHG HAS STOPPED. SEEK ME D ATTN. EYES:EXPOSED EYES SHOULD BE IMMED FLUSHED W/COPIOUS AMTS OF H*2O USING A STEADY STREAM FOR (ING 7) ================== Physical/Chemical Properties ================== HCC:V1 Vapor Pres:<0.1 Spec Gravity:0.894 Solubility in Water:<0.1% Appearance and Odor:LIGHT AMBER LIQUID; PETROLEUM ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT FOR PROLONGED PERIODS AND WATER CONTAMINATION. Hazardous Decomposition Products:HEATING WILL GENERATE TOXIC & FLAMMABLE HYDROGEN SULFIDE. BURNING CAN PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:R-114 Preparer's Name:DGSC-VBA/HMIS CAGE:02LX8 CAGE:02LX8 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLOROTETRAFLUOROETHANE (SARA 313) CAS:76-14-2 RTECS #:KI1101000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9495 Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 1000 PPM Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:CARDIOVASCULAR & REPIRATORY SYSTEMS. ACUTE- IF INHALED IN CONCENTRATIONS ABOVE 1000 PPM MAY CAUSE IRRITATION, NARCOSIS & ASPHYXIATION. MAY CAUSE FROSTBITE IF EYES OR SKIN WAS EXPOSED TO LIQUID OR SPRAY. INGESTION IS UNLIKELY DUE TO EXISTANCE AS A GAS AT ROOM TEMPERATURES. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE AND/OR SKIN FROSTBITE, NARCOSIS, ASPHYXIATION, RESPIRATORY TRACT IRRITATION, DIZZINESS, TREMORS, UNCONSCIOUSNESS, CARDIAC ARREST Medical Cond Aggravated by Exposure:INDIVIDUALS WITH CARDIAC ARRHYTHMIA OR RESPIRATORY DISORDERS MAY BE AT INCREASED RISK IN SEVERE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IN ALL CASES. EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. TREAT FOR FROSTBITE, IF NEEDED. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:NOT APOTENTIAL ROUTE OF EXPOSURE; GET MEDICAL ATTENTION IF NECESSARY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CYLINDERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. SEE 1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE NO 12. Unusual Fire/Explosion Hazard:MAY FORM CORROSIVE AND TOXIC HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND/OR PHOSGENE. CYLINDERS MAY RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP UPWIND. VENTILATE ENCLOSED SPACES UNTIL GAS IS DISPERSSED. DO NOT SMOKE OR OPERATE INTERNAL COMBUSTION ENGINES IN IMMEDIATE VICINITY. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL-VENTILATED, DRY, COOL (BELOW 125F) PLACE AWAY FROM OPEN FLAMES AND INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV EXCEEDED, WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR, OPERATED IN POSITIVE PRESSURE MODE. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-VBA/HMIS WITHOUT ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPERLY TO PROTECT EMPLOYEES AND ENVIRONM ENT. OTHER TRADE NAMES: HALON 242, FREON 114, REFRIGERANT 114. CONVERSION FACTOR: 1 PPM = 7.10 MG/M3. ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:38.0F,3.3C Melt/Freeze Pt:M.P/F.P Text:-137F,-94C Vapor Density:5.90 Spec Gravity:NOT RELEVANT Viscosity:NOT RELEVANT Evaporation Rate & Reference:GAS Solubility in Water:0.01% Appearance and Odor:COLORLESS LIQUEFIED GAS - FAINT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CHEMICALLY ACTIVE METALS SUCH AS SODIUM, POTASSIUM, CALCIUM, POWDERED ALUMINUM, ZINC AND MAGNESIUM; ACIDS AND ACID FUMES Stability Condition to Avoid:OPEN FLAME, EXTREMELY HOT/GLOWING METAL SURFACES, HIGH TEMPERATURES Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND/OR PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOR DISCHARGE OR DISPOSING OF MATERIAL, CONSULT LOCAL, STATE AND FEDERAL AUTHORITIES. DO NOT WENT TO ATMOSPHERE. RECYLCE PRODUCT.
1
eyes_protection_mandatory
======================================================= Product ID: SURROGATE STANDARD MIXTURE, STM-330N Cage: 0MU35 ======================================================= Contractor Summary ======================================================= Cage: 0MU35 ======================================================= Ingredients ======================================================= Cas: 67-56-1 RTECS #: PC1400000 % Wt: 99.2415 OSHA PEL: 260 MG/M3;200 PPM ACGIH TLV: 262 MG/M3;200 PPM ACGIH STEL: 328 MG/M3;250 PPM EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 460-00-4 % Wt: 0.2528 ------------------------------ % Wt: 0.2528 ----------------------------- Cas: 2037-26-5 % Wt: 0.2528 ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. CONTAINS TOLUENE WHICH APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS CONCERNING SAFE HANDLING & EXPOSURE INFO (FP N). First Aid: IN CASE OF EYE OR SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER. IF INHALED, REMOVE TO FRESH AIR; GIVE OXYGEN, IF NECESSARY. CONTACT PHYSICIAN. INGESTION: CONTACT A PHYSICIAN IMMEDIATELY (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DUE TO SMALL QUANTITY INVOLVED, SPILLS OR LEAKS SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING AMPULE OR BOTTLE MAY BE PLACED IN A PLASTIC BAG AND NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON VERMICULITE OR SAND. Waste Disposal Methods: BURN IN CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS CONCERNING DISPOSAL. Handling And Storage Precautions: USE APPROPRIATE NIOSH-APPROVED SAFETY EQUIPMENT. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point: =11.1C, 52.F Autoignition Temp: =385.C, 725.F Lower Limits: 6.7 Upper Limits: 36.0 Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures: USE NIOSH-APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: FIRE HAZARD: COMBUSTIBLE. ======================================================= Control Measures ======================================================= Respiratory Protection: USE A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE OF CONCERN (FP N). N). Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). WEAR CHEMICAL-RESISTANT CLOTHING SUCH AS A LABORATORY COAT AND/OR A RUBBER APRON TO PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. Supplemental Safety and Health: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN SAFE HANDLING OF HAZARDOUS CHEMICALS. ======================================================= Physical/Chemical Properties ======================================================= Boiling Point: =64.8C, 148.6F Melt/Freeze Pt: =-98.C, -144.4F Vapor Pres: 100 MM HG @21.2C Vapor Density: 1.1 Solubility in Water: SOLUBLE Appearance and Odor: COLORLESS LIQUID. ODOR: N/A. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG OXIDIZERS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: METHYL ALCOHOL (METHANOL): LD50 (ORAL, RAT): 12,900 MG/KG. ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= Sara Title III Information: SARA TITLE III COMPOUNDS: METHYL ALCOHOL (METHANOL). ======================================================= Other Information ======================================================= Other Information: SOLVENT: METHANOL (METHYL ALCOHOL). PHYSICAL/CHEMICAL (CON'T): DENSITY: 0.7910. ======================================================= HAZCOM Label ======================================================= Product ID: SURROGATE STANDARD MIXTURE, STM-330N Cage: 0MU35 Company Name: ULTRA SCIENTIFIC Street: 250 SMITH STREET Zipcode: 02852-5000 Label Required IND: Y Date Of Label Review: 11/06/2001 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: ACUTE/CHRONIC: TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS; DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. CONTAINS TOLUENE WHICH APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE H AZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS CONCERNING SAFE HANDLING & EXPOSURE INFO (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JENNY 80 COIL CONDITIONER HYDROCHLORIC ACID Preparer's Name:H. MARK JONES CAGE:29215 CAGE:29215 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID; (MURIATIC (HYDROCHLORIC) ACID) (HYDROGEN CHLORIDE) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 31.5% OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:INHAL:PROVIDE FRESH AIR AND REST. IF BRTHG HAS STOPPED, ADMIN CPR AND ADMIN OXYGEN IF NECESSARY. GET MD ATTN. EYES:IMMED FLUSH EYES WITH LG AMTS OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. SK IN:IMMEDIATELY FLUSH SKIN WITH LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOM. DO NOT GIVE CARBONATES. DRINK LG QTYS OF WATER IMMED. GET MD ATTN. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, H*2O, FOAM, DRY POWDER Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . IN FIRE, PUNGENT ACRID ACID FUMES WILL BE RELEASED. Unusual Fire/Explosion Hazard:REACTS WITH METALS TO FORM HYDROGEN WHICH MAY FORM EXPOSIVE MIXTURE IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP UPWIND UNTIL GAS HAS DISPERSED. NEUTRALIZE WITH SODA ASH OR LIME, AND FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. Neutralizing Agent:NEUTRALIZE WITH SODA ASH OR LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM OXIDIZING AGENTS, NITRIC ACID, CHLORIDES, SULFIDES & CYANIDES. STORE IN COOL, DRY PLACE W/ADEQ VENT. KEEP AWAY FROM HEAT & (SUPP DATA) Other Precautions:KEEP AWAY FROM HEAT AND OPEN FLAME. KEEP CONTAINER TIGHTY SEALED. PROTECT CONTAINER FROM DAMAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED VAPOR RESPIRATOR. Ventilation:LOCAL EXHAUST NORMALLY SUFFICIENT. MECHANICAL (GENERAL) AT POINTS OF FUME EMISSION. Other Protective Equipment:ACIDPROOF APRON AND OTHER PROTECTIVE EQUIPMENT TO MINIMIZE SKIN CONTACT. EMERGENCY EYEWASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPEC GRAV:1.16 @ 20C (H*2O=1). MATLS TO AVOID:CYANIDE; WITH SULFIDES, GIVING HYDROGEN SULFIDE; WITH FORMALDEHYDE, GIVING BISCHLOROMETHYL ETHER. HEAT CAN CAUSE EVOLUTION OF GASEOUS HYDROGEN CHLORIDE. H NDLG/STOR PREC:OPEN FLAMES. KEEP CONTAINER TIGHTLY SEALED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:183F,84C Vapor Pres:35 @ 20 C Spec Gravity:SUPP DATA Evaporation Rate & Reference:0.8 (WATER=1) Solubility in Water:100% Appearance and Odor:COLORLESS TO FAINT YELLOW LIQUID WITH PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS W/MOST METALS, GIVING HYDROGEN; W/OXIDIZING AGENTS, GIVING CHLORINE; W/CYANIDE, GIVING HYDROGEN (SUPP DATA) Stability Condition to Avoid:AVOID CONTACT WITH METALS AND ALKALIS. Hazardous Decomposition Products:HEAT CAN CAUSE EVOLUTION OF GASEOUS HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WILL NOT AFFECT ANY WASTE DISPOSAL SYSTEM AFTER PROPERLY NEUTRALIZED. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GRAY EPOXY 16F20-102-36231, 422T100 CAGE:98795 CAGE:98795 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE). VP: 70.2@20C CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <10% OSHA PEL:200 PPM;300 PPM STEL ACGIH TLV:200 PPM;300 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM; (BARIUM IN NON-VOLATILES) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: 1-2% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 Ingred Name:VOLATILE ORGANIC COMPOUNDS: 2.4 POUNDS PER GALLON LESS WATER RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <10% OSHA PEL:0.1 MG/M3 RDUST ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: <10% OSHA PEL:0.05 MG/M3 RDUST ACGIH TLV:0.05 MG/M3 RDUST Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE). VP: 2.14@20C CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 10-20% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:XYLENE. VP: 21@20C CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <10% OSHA PEL:100 PPM;150 PPM STEL ACGIH TLV:100 PPM;150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE BY INHALATION MAY CAUSE IRRITATION OF RESPIRATORY TRACT, HEADACHE, DIZZINESS, OR DROWSINESS. SKIN/ EYE : IRRITANT TO EYES AND SKIN. CHRONIC: THOSE HAZ MATLS LISTED MAY AFFECT THE F OLLOWING ORGANS: RESPIRATORY TRACT, CNS, KIDNEYS, LIVER, CARDIAC SENSITIZATION. Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987: GRP 2A. NTP 6TH ANNUAL (SUPP DATA) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN AT THIS TIME. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE. EYE: FLUSH IMMED WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER. INGEST: DRINK WATER. IF NECESSARY, CONSULT A PHYSICIAN FOR ANYOF THESE CONDITIONS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:23.0F,-5.0C Lower Limits:1.10% Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID BREATHING VAPORS, VENTILATE AREA, & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. CONTRS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQ IN EXCESS OF A FEW INCHES. Other Precautions:MAKE SURE DRUM IS COMPLETELY EMPTY BEFORE ATTEMPTING TO WELD/BRAZE. DRUM SHOULD BE INDUSTRIALLY CLEANED PRIOR TO REUSE. DO NOT FLAME CUT, BRAZE/WELD W/OUT A NIOSH/MSHA APPROVED RESP/APPROPRIATE VENTIL ATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE GEN DILUT/LOC EXHST FAILS TO ADEQUATELY DILUTE TWA/PEL OF MATL, THEN RESP PROT SHOULD BE USED AS FOLLOWS: I/A/W 29CFR 1910.134, USE NIOSH/MSHA APPROVD AIR LINE TYPE RESP/HOODS FOR ENCLSD & CONFI NED AREAS. NIOSH/MSHA APPRVD (SUPP DATA) Ventilation:PROVIDE GEN DILUT/LOC EXHST VENT TO KEEP TWA AND LEL BELOW ACCEPTABLE LIM AND TO REMOVE DECOMP PRODS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLAN OF CARCIN: REPORT ON CARC, 1991:ANTIC TO BE CARCIN. SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987: GRP 2A. NTP 6TH ANNUAL REPORT ON CARCIN, 1991: ANTIC TO BE CARC IN. RESP PROT: AIR PURIFYING RESP MAY BE USED FOR OTHER AREAS. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:>175F,>79C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:1.66 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES MAY CNTN CARBON MONOXIDE & OXIDES OF NITROGEN. MAY PRDCE HAZ FUMES WHEN HEATED TO DECOMP AS IN WELDING. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE, AND FEDERAL REGULATIONS. BEFORE ATTEMPTING TO CLEAN UP, SEE INGREDIENTS SECTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NON-FLAMMABLE GAS MIXTURE Resp. Party Other MSDS Num.:50018 CAGE:04AA7 CAGE:04AA7 Contract Num:SP0440-99-D-5116-0001 CAGE:51906 ============= Composition/Information on Ingredients ============= Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 = Wt:23.5 Ingred Name:METHANE CAS:74-82-8 RTECS #:PA1490000 = Wt:2.5 Ingred Name:HYDROGEN SULFIDE CAS:7783-06-4 RTECS #:MX1225000 = Wt:.02 OSHA PEL:see Table Z-2 ACGIH TLV:14 MG/M3;10 PPM ACGIH STEL:21 MG/M3;15 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:CARBON MONOXIDE CAS:630-08-0 RTECS #:FG3500000 = Wt:1. OSHA PEL:55 MG/M3;50 PPM ACGIH TLV:29 MG/M3;25 PPM Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: BALANCE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HYDROGEN SULFIDE AND CARBON MONOXIDE ARE TOXIC TO HUMANS IN RELATIVELY LOW CONCENTRATIONS. OVER-EXPOSURE TO THIS GAS MIXTURE CAN CAUSE SKIN OR EYE IRRITATION, NAUSEA, DIZZINESS, HEADACHES, COLLAPSE, U NCONSCIOUSNESS, COMA AND DEATH. ADDITIONALLY, RELEASES OF THIS PRODUCT MAY PRODUCE OXYGEN-DEFICIENT ATMOSPHERES (ESPECIALLY IN SMALL CONFINED SPACES OR OTHER POORLY-VENTILATED ENVIRONEMNTS),INENTS) IN DIVIDUALS MAY BE ASPHYXIATED. SEVERE EYE CONTAMINATION MAY CAUSE BLINDNESS. CHRONIC: MAY CAUSE LONG-TERM SYMPTOMS SUCH AS MEMORY LOSS, PARALYSIS OF FACIAL MUSCLES OR NERVE TISSUE DAMAGE. Explanation of Carcinogenicity:THE COMPONENTS ARE OF THIS MIXTURE ARE NOT FOUND IN THE FOLLOWING LISTS: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, & IARC; THEREFORE, THEY ARE NOT CONSIDERED TO BE, CANCER-CAUSING AGENTS BY THESE AGENCIES. Effects of Overexposure:EYES-SCRATCHINESS, IRRITATION, TEARING AND BURNING, PAIN WHEN LOOKING AT LIGHT, BLURRED VISION. SKIN-IRRITATION. INHALED-NAUSEA, DIZZINESS, HEADACHES, COLLAPSE, UNCONSCIOUSNESS, COMA, DEATH. Medical Cond Aggravated by Exposure:SKIN DISORDERS AND RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY REPEATED OVER-EXPOSURES TO THIS GAS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHALED-REMOVE TO FRESH AIR. ONLY TRAINED PERSONNEL SHOULD ADMINISTER SUPPLEMENTAL OXYGEN AND/OR CARDIO-PULMONARY RESUSCITATION (CPR) IF NEEDED. SKIN-IMMEDIATELY FLUSH WITH WATER FOR A MINIMUM OF 15 M INUTES. REMOVE EXPOSED OR CONTAMINATED CLOTHES. SEEK IMMEDIATE MEDICAL ATTENTION. EYES-OPEN EYES AND GENTLY FLUSH WITH WATER FOR A MINIMUM OF 15 MINUTES. SEEK MEDICAL ASSISTANCE FROM AN OPHTHALMOLOGIS T. VICTIMS WHO EXPERIENCE ANY ADVERSE EFFECT AFTER OVER-EXPOSURE TO THIS PRODUCTMUST BE TAKEN FOR MEDICAL ATTENTION. RESCUERS SHOULD BE TAKEN FOR MEDICAL ATTENTION IF NEEDED. ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE GAS MIXTURE. USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:STRUCTURAL FIREFIGHTERS MUST WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL-PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:THIS GAS MIXTURE CONTAINS TOXIC GASES, HYDROGEN SULFIDE AND CARBON MONOXIDE, AND PRESENTS AN HEALTH HAZARD TO FIREFIGHTERS. THIS GAS MIXTURE IS NOT FLAMMABLE; HOWEVER, CONTAINERS, WHEN INVOLVED IN FI RE, MAY RUPTURE OR BURST IN THE HEAT OFTHE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:IN CASE OF A LEAK, CLEAR THE AFFECTED AREA, PROTECT PEOPLE AND RESPOND WITH TRAINED PERSONNEL. FOR EMERGENCY DISPOSAL, SECURE THE CYLINDER AND SLOWLY DISCGARGE THE GAS TO THE ATMOSPHERE IN A WELL-VENT ILATED AREA OR OUTDOORS. ALLOW THE GAS MIXTURE TO DISSIPATE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER'S MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:SFIRMLY SECURE CYLINDERS TO PREVENT FALLING OR BEING KNOCKED OVER. PROTECT CYLINDERS FROM ENVIRONMENT AND FROM PHYSICAL DAMAGE. SEGRAGATE FULL & EMPTY CYLINDERS. USE A FIRST-IN, FIRST-OUT INVENTORY S YSTEM. DURING CYLINDER USE, USE EQUIPMENT RATED FOR PROPER SERVICE PRESSURE. Other Precautions:DURING MAINTENANCE OF CONTAMINATED EQUIPMENT FOLLOW PROCEDURES OUTLINED IN SPILL RELEASE PROCEDURES. MAKE CERTAIN THAT APPLICCATION EQUIPMENT IS LOCKED AND TAGGED-OUT SAFELY. ALWAYS USE PRODUCT IN ADE QUATELY VENILATED AREAS. DO NOT ATTEMPTTO REPAIR, ADJUST OR MODIFY CYLINDERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION IS REQUIRED UNDER NORMAL CIRCUMSTANCES OF USE. USE SCBA IF CO LEVELS EXCEED THE TLV/PEL OR IF OXYGEN LEVELS FALL BELOW 19.5% OR IF EITHER LEVEL IS UNKNOWN IN AN EMERG ENCY RESPONSE. Ventilation:NO SPECIAL VENTILATION SYSTEMS OR ENGINEERING COTROLS ARE NEEDED UNDER NORMAL CONDITIONS OF USE. USE IN WELL-VENTILATED AREA. CIRCUMSTANCES OF USE. Supplemental Safety and Health VENTILATION CONTINUED: INSTALL MONITORING TO DETECT THE LEVELS OF OXYGEN, HYDROGEN SULFIDE AND CARBON MONOXIDE. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:=-195.8C, -320.3F Melt/Freeze Pt:=-209.9C, -345.7F Spec Gravity:0.906 Solubility in Water:0.023 Appearance and Odor:COLORLESS GAS WHICH HAS AN ROTTEN EGG-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES TITANIUM, LITHIUM, STRONG OXIDIZERS, NICKEL, IRON, MOST METALS. Stability Condition to Avoid:NORMALLY STABLE IN GASEOUS STATE. Hazardous Decomposition Products:CARBON OXIDES, WATER, SULFUR OXIDES. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:THERE IS NO SPECIFIC TOXICOLOGICAL DATA FOR METHANE OR NITROGEN; THEY ARE SIMPLE ASPHYXIANTS. HYDROGEN SULFIDE: LC50 (INHALATION, RAT): 444 PPM. CARBON MONOXIDE: LC50 (INHALATION, RAT): 1811 PPM/4 HR S. ===================== Ecological Information ===================== Ecological:THE FOLLOWING ENVIRONEMENTAL DATA ARE APPLICABLE TO THE COMPONENTS OF THIS PRODUCT: HYDROGEN SULFIDE: WATER SOLUBILITY=1 G/242 ML AT 20C. CARBON MONOXIDE: WATER SOLUBILITY=3.3 ML/100CC, 2.3 ML AT 20C. NITROGEN: WATER SOLUBILITY =2.4 VOLUMESNITROGEN/100 VOLUMES WATER AT OC; 1.6 VOLUMES NITROGEN/100 VOLUMES WATER AT 20C.BIOLOGICAL EXPOSURE INDICIES (BEI): CARBON MONOXIDE: (CABOXYHEMOGLOBIN IN BLOODAT END OF SHIFT)= 3.5% OF HEMOGLOBIN; (CARBON MONOXIDE IN END-EXHALED AIR) = 20PPM. NO EVIDENCE IS CURRENTLY AVAILABLE ON THIS PRODUCT'S EFFECTS ON PLANT & ANIMAL LIFE. THIS GAS MIXTURE MAY BE HARMFUL TO PLANT LIFE DUE TO H2S & CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL MUST BE IN ACCORDANCE WITH APPROPRIATE FEDERAL, STATE AND LOCAL REGULATIONS. CYLINDERS WITH UNDESIRED RESIDUAL PRODUCT MAY BE SAFELY VENTED OUTDOORS WITH THE PROPER REGULATOR. =================== MSDS Transport Information =================== Transport Information:PROPER (US DOT) SHIPPING NAME: COMPRESSED GAS, NOS (NITROGEN, HYDROGEN SULFIDE), 2.2, UN1956. DOT LABEL: NON-FLAMMABLE GAS. MARINE POLLUTANT: THE COMPONENTS ARE NOT CLASSIFIED BY THE US DOT AS MARINEPOLLUTANTS (49 CFR 172.101, APP B). CYLINDERS SHOULD BE TRANSPORTED IN A SECURE POSITION, IN A WELL-VENTILATED VEHICLE. THE TRANSPORTATION OF COMPRESSED GAS CYLINDERS IN AUTOMOBILES CAN PRESENT SERIO US SAFETY HAZARDS. TRANSPORT CANADA: THIS MATERIAL IS CONSIDERED DANGEROPUS GOODS. ===================== Regulatory Information ===================== SARA Title III Information:SARA TPQ: HYDROGEN SULFIDE=500 LBS. SARA REPORTING REQUIREMENTS: HYDROGEN SULFIDE: SARA 302/304/313-YES; ALL OTHER COMPENENTS-NO. Federal Regulatory Information:TSCA INVENTORY STATUS: THE COMPONENTS OF THIS GAS MIXTURE ARE LISTED ON THE TSCA INVENTORY. CERCLA REPORTABLE QUANTITY (RQ): HYDROGEN SULFIDE=100 LBS. OTHER REGULATIONS: HYDROGEN SULFIDE AND CARBON MO NOXIDE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF CFR 29 1910.1000. HYDROGEN SULFIDE & METHANE ARE SUBJECT TO THE REPORTING OF SECTION 112 9R) OF THE CLEAN AIR ACT. THE THRESHOLD QUANTITY FOR EACH O F THESE GASES IS 10,000LBS. State Regulatory Information:ALASKA-DESIGNATED TOXIC & HAZARDOUS SUBSTANCES; CALIFORNIA-PERMISSABLE EXPOSURE LIMITS FOR CHEMICAL CONTAMINANTS; FLORIDA-SUBSTANCE LIST; ILLINOIS-TOXIC SUBSTANCE LIST; MASSACHUSETTS-SUBSTANCE LIST; MINNESOTA-LIST OF HAZARDOUS SUBSTANCES;MISSOURI-EMPLOYER INFORMATION/TOXIC SUBSTANCE LIST; NEW JERSEY-RIGHT-TO-KNOW HAZARDOUS SUBSTANCE LIST; NORTH DAKOTA-LIST OF HAZARDOUS CHEMICALS, REPORTABLE QUANT ITIES; PENNSYLVANIA-HAZARDOUS SUBSTANCE LIST; RHODE ISLAND-HAZARDOUS SUBSTANCELIST; TEXAS-HAZARDOUS SUBSTANCE LIST; WEST VIRGINIA-HAZARDOUS SUBSTANCE LIST; WISCONSIN-TOXIC AND HAZARDOUS SUBSTANCES. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VAULT COLOR-V798-28 CRES-LITE METALLIC PIGMENT Preparer's Name:STEPHEN FUGLSANG CAGE:EO514 CAGE:EO514 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (POWDER) *95-4* CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 98-99% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:STEARIC ACID CAS:57-11-4 RTECS #:WI2800000 Fraction by Wt: 0.5-2% Ingred Name:ISOSTEARIC ACID CAS:30399-84-9 Fraction by Wt: 0.5-2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: ALUMINUM DUSTS CAN CAUSE IRRITATION. INHALATION: PROLONGED EXPOSURE TO AIRBORN PARTICULATE MAY CAUSE IRRITATION OF THE NOSE & TRACHEA RESULTING IN NASAL ULCERATION. INGESTION: ALUMINUM ISN' T CONSIDERED NON-TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, METALLIC TASTE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH AREA W/SOAP & WARM WATER. INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, BEGIN ARTIFICIAL RESPIRATION PROCEDURE AT ONCE. INGESTION: DR INK 1/2 GLASSES OF WATER. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Lower Limits:(SUPP) Fire Fighting Procedures:WEAR SCBA. NEVER EMPLOY WATER/HIGH VELOCITY DRY CHEMICAL ON AN ALUMINUM FIRE. SAND/ANOTHER INERT MATERIAL SHOULD BE USED TO RING/DIKE FIRE TO EXTINGUISH ITSELF. Unusual Fire/Explosion Hazard:ALUMINUM POWDER IN BULK FORM IS STABLE, BUT WHEN SUSPENDED AS AIRBORNE PARTICULATE, IT CAN BE POTENTIALLY EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: SWEEP GENTLY INTO A HAZARDOUS WASTE CONTAINER. AVOID GENERATING DUST CLOUDS. USE NON-SPARKING TOOLS. LARGE: HANDLE AS A SMALL SPILL. AVOID RUN-OFF INTO SEWERS, DRAINS/OTHER OPEN BODIES OF WATER . ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN AN AREA AWAY FROM EXTREME TEMP CONDITIONS. KEEP CONTAINERS CLOSED & DRY AFTER USE. KEEP AWAY FROM CHILDREN. HILDREN. Other Precautions:ALUMINUM REACTS W/WATER WHICH WILL SLOWLY GENERATE HYDROGEN GAS & HEAT. THIS REACTION CAN BE HAZARDOUS WHEN TRYING TO STORE COMBINED PRODUCT IN A SEALED CONTAINER. DON'T STORE FINISHED MIXTURES OF WAT ER THAT CONTAIN ALUMINUM FLARE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE (NIOSH APPROVED) RESPIRATOR DURING APPLICATION IF AIR MONITORING DEMONSTRATES THAT AIRBORN PARTICULATE EXCEEDS RECOMMENDED LIMITS. Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP AIR QUALITY W/IN APPROVED OSHA LEVELS. Other Protective Equipment:EYE WASH & SAFETY SHOWER. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. AVOID WEARING CONTACT LENSES. Supplemental Safety and Health BOILING RANGE (ALUMINUM): 4766F. LEL: 0.035 OZ/CUFT. CHLORINATED HYDROCARBONS/CARBON DISULFIDE/SODIUM PEROXIDE PLUS/C02/SULFUR DICHLORIDE/PALLADIUM/MANGANESE/MAGNESIUM PLUS/POTASSIUM CHLORATE/SODIUM C ARBONATE/SULFATES/DIBORNE. ALUMUNIM REACTS W/WATER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:(SEE SUPP) Spec Gravity:ALUMINUM 2.7 Appearance and Odor:SILVERY/GRAY METALLIC LOOKING POWDER W/LITTLE ODOR Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES/CHLORATES/BROMATES/MINERAL ACIDS/STRONG OXIDIZING AGENTS/SILVER CHLORIDE/IODATES/NITRATES/WATER. (SUPP) Stability Condition to Avoid:GENERATING DUST, HEAT Hazardous Decomposition Products:HYDROGEN & NOXIOUS COPPER COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ALUMINUM POWDER UN1309.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CE YELLOW PREMIX TONER CAGE:EO083 CAGE:EO083 CAGE:50804 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPARAFFINIC PETROLEUM SOLVENT CAS 64742-48-9 Fraction by Wt: >90% ACGIH TLV:300 PPM (MFR) Ingred Name:METHACRYLIC COPOLYMER CAS 9011-15-8 Fraction by Wt: <5% Ingred Name:YELLOW DYE (UNSPECIFIED) Fraction by Wt: >5% ===================== Hazards Identification ===================== Effects of Overexposure:SKIN,EYES:MILD IRRIT;INGEST:RESP.DISTRESS & CENTRAL NERVOUS DEPRESSION;INHAL:RESP.ARREST,HEART ARYTH ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP & WATER. RMV CONTAM CLTHG & SHOES. INGEST:DO NOT INDUCE VOMIT. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point:102F/39C TCC Lower Limits:0.8 Upper Limits:7.0 Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG. Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR. Unusual Fire/Explosion Hazard:DO NOT STORE WITH STRONG OXIDANTS ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES, RECOVER FREE LIQUID WITH VERMICULITE, SAWDUST, ETC. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. AVOID STORING/HANDLING NEAR HEAT,STRONG LIGHT,SPARKS,OPEN FLAMES,STRONG OXIDANTS. Other Precautions:AVOID BREATHING VAPORS AND PROLONGED OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:NONE Supplemental Safety and Health MSDS 30SEP86:MSDS COVERS DIFF SIZE CONTR SOLD UNDER VERSATEC PART NUMBERS:4822-1-1,4822-32-6 ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:338F/170C Vapor Pres:IMM Vapor Density:5.0 Spec Gravity:.78 Evaporation Rate & Reference:25-.45 BUAC Solubility in Water:IMMISCIBLE Appearance and Odor:YELLOW LIQUID, SLIGHT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS Stability Condition to Avoid:IGNITION SOURCES,HIGH TEMPERATURES Hazardous Decomposition Products:CO,CO*2 ==================== Disposal Considerations ==================== Waste Disposal Methods:APPROVED DISPOSAL SITE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-102F, TY III, CLASS 1, #17875 WHITE Preparer's Name:ROBERT COMMISSO CAGE:DO312 CAGE:58963 CAGE:DO312 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC HYDROCARBONS (STODDARD TYPE)(SARA III)(VAPOR PRESSURE = 2.0 MMHG @ 68F) CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 10.0% Other REC Limits:NONE RECOMMENDED ACGIH TLV:2 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DIRECT CONTACT MAY CAUSE IRRITATION. PROLONGED CONTACT MAY CAUSE SKIN IRRITATION. INHAL: HIGH VAPOR CONCENTRATIONS MAY LEAD TO LUNG CHANGES, NAUSEA, VOMITING, COUGH, PULMONARY IRRITATION, CNS DE PRESSION. INGEST: POSSIBLE GASTROINTESTINAL DISTURBANCES. ASPIRATION OF PRODUCT INTO LUNGS MAY CAUSE PNEUMONITIS,* Effects of Overexposure:EYES: POSSIBLE IRRITATION W/ DIRECT CONTACT. SKIN: POSSIBLE IRRITATION &/OR DERMATITIS. MAY BE ABSORBED THROUGH SKIN. *PULMONARY EDEMA & HEMORRAGE. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES IN OR HISTORY OF AILMENTS INVOLVING SKIN, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEY. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/ LARGE AMOUNTS WATER 15 MINUTES. SEEK MED AID. SKIN: WASH THOROUGHLY W/ SOAP & WATER. SEEK MED AID IF IRRATION PERSISTS. INGEST: IMMEDIATELY SEEK MED AID. DO NOT INDUCE VOMIT ING. DO NOT ATTEMPT TO GIVE ANYTHING BYMOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Autoignition Temp:Autoignition Temp Text:474F Lower Limits:1.0 Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:APPROVED GAS MASK REQUIRED FOR FIRE FIGHTING PERSONNEL. WATER MAY BE INEFFECTIVE, MAY BE USED TO COOL CONTAINERS. IF WATER USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. REMOVE ALL SOURCES OF IGNITION. STAY UPWIND. ABSORB WITH INERT MATERIAL. FLUSH AREA W/ WATER. VENTILATE AREA FOR AT LEAST 24 HOURS OR UNTIL AREA HAS BEEN DECLARED SAFE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED & UPRIGHT TO PREVENT LEAKAGE. AVOID FLAMES, WELDING, OPEN LIGHTS, ETC. AVOID BREATHING VAPOR & SPRAY MIST, SKIN & EYE CONTACT. Other Precautions:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN CONFINED AREAS, TANK OR PIT WITHOUT ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW TLV (PEL), USE MSHA/NIOSH APPROVED UNITS. USE UNITS PER CURRENT 29 CFR 1910.134 & FOLLOW MANUFACTURERS' INSTRUCTIONS & WARNINGS. IF WITHIN O SHA PROTECTION FACTOR, AIR PURIFYING** Ventilation:LOCAL AND MECHANICAL EXHAUST. Other Protective Equipment:EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:MAINTAIN GOOD PERSON HYGIENE. DO NOT USE IN CONFINED AREAS WITHOUT ADEQUATE VENTILATION. Supplemental Safety and Health **OV/FILTER UNITS OK FOR USE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:334F,168C Vapor Density:>AIR Spec Gravity:1.5 (WATER=1) VOC Grams/Liter:1.91 Viscosity:80-90 KU Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:ESSENTIALLY NIL Appearance and Odor:VISCOUS LIQUID WITH TYPICAL PAINT ODOR, WHITE Percent Volatiles by Volume:28.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:FLAMES, SPARKS, SMOKING & HEAT Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:USE INERT ABSORBENT MATERIAL ON SPILLS. DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM PERIODATE POWDER PILLOWS, 984 Resp. Party Other MSDS Num.:M00021 CAGE:91224 Contract Num:SP0450-00-M-D405 CAGE:91224 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PERIODATE POWDER CAS:7790-28-5 RTECS #:SD4550000 = Wt:100. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION. INGESTION: MAYCAUSE: ABDOMINAL PAIN VOMITING, DIARRHEA. Explanation of Carcinogenicity:NONE REPORTED. Effects of Overexposure:EYE CONTACT: CAUSES SEVERE IRRITATION. SKIN CONTACT: CAUSES MODERATE IRRITATION. INGESTION: MAY CAUSE ABDOMINAL PAIN, VOMITING, DIARRHEA. INHALATION: MAY CAUSE IRRITATION OF NOSE AND THROAT. Medical Cond Aggravated by Exposure:PRE-EXISTING: EYE CONDITIONS, SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. CALL PHYSICIAN. SKIN CONTACT: WASH SKIN WITH PLENTY OF WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN IMMEDIATELY. IN GESTION: GIVE LARGE QUANTITIES OF WATER. CALL PHYSICIAN IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:N/D Extinguishing Media:WATER, CARBON DIOXIDE AND DRY CHEMICAL. Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MAY REACT VIOLENTLY WITH STRONG REDUCERS. HAZARDOUS COMBUSTION PRODUCTS: TOXIC FUMES OF IODINE, IODINE COMPOUNDS, SODIUM MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILLED MATERIAL FROM BEING RELEASED TO ENVIRONMENT. COVER SPILL WITH SAND OR OTHER INERT MATERIAL. WORKING IN SMALL BATCHES, DILUTE WITH EXCESS WATER. ADJUST TO A PH BETWEEN 6 AND 9 WITH AN ALKA LI SUCH AS SODA ASH OR SODIUM BICARBONATE. FLUSH REACTED MATERIAL TO THE DRAIN WITH A LARGE EXCESS OF WATER. DECONTAMINATE SITE WITH AN ALKALI SOLUTION. PRODUCT IS REGULATED AS RCRA WASTE. Neutralizing Agent:SODA ASH OR SODIUM BICARBONATE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN, CLOTHING. DO NOT BREATHE DUST. WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. STORAGE: PROTECT FROM MOISTURE AND OXIDIZABLE MATERIALS. Other Precautions:EMPTY CONTAINERS: RINSE THREE TIMES WITH AN APPROPRIATE SOLVENT. DISPOSE OF EMPTY CONTAINER AS NORMAL TRASH. DISPOSAL OF PRODUCT: VERIFICATION SHOULD BE MADE THAT ABOVE PRODUCT WASTE DISPOSAL IS NOT I NCONSISTENT WITH ANY PRETREATMENT AGREEMENT YOUR FACILITY MAY HAVE WITH THE WASTWATER TREATMENT FACI LITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ADEQUATE VENTILATION. Ventilation:ADEQUATE VENTILATION. Other Protective Equipment:LAB COAT. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. Work Hygienic Practices:AVOD CONTACT WITH: EYES, SKIN, CLOTHING. DO NOT BREATHE: DUST. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:D1 Melt/Freeze Pt:=300.C, 572.F Vapor Density:NA Spec Gravity:3.865 pH:4 - 4.5 Solubility in Water:SOLUBLE Appearance and Odor:WHITE SOLID POWDER, NO ODOR. Percent Volatiles by Volume:ND ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT VIOLENTLY IN CONTACT WITH: REDUCER, ORGANIC MATERIALS. Stability Condition to Avoid:STABLE WHEN STORED UNDER PROPER CONDITIONS. AVOID EXCESS MOISTURE, HEATING TO DECOMPOSITION. Hazardous Decomposition Products:TOXIC FUMES OF IODINE, IODINE COMPOUNDS AND SODIUM MONOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:LD50: NONE REPORTED. LC50: NONE REPORTED. DERMAL TOXICITY DATA: NONE REPORTED. SKIN AND EYE IRRITATION DATA: NONE REPORTED. MUTATION DATA: NONE REPORTED. REPRODUCTIVE EFFECTS DATA: NONE REPORTED. INGR EDIENT TOXICOLOGICAL DATA: NOT APPLICIABLE. ===================== Ecological Information ===================== Ecological:PRODUCT ECOLOGICAL INFORMATION: NO INFORMATION AVAILABLE ON THIS PRODUCT. INGREDIENT ECOLOGICAL INFORMATION: NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WORK IN APPROVED FUME HOOD. WORKING IN A LARGE CONTAINER, CAUTIOUSLY ADD SMALL POR-TIONS OF THE MATERIAL TO COLD WATER WITH AGITATION. ADJUST TO A PH BETWEEN 6 AND 9 WITH AN ALKALI, SUCH AS SODA ASH O R SODIUM BICARBONATE. OPEN COLD WATER TAP COMPLETELY, SLOWLY POUR THE REACTED MATERIAL TO THE DRAIN. RUN COLD WATER5 MIN. TO COMPLETELY FLUSH SYSTEM. =================== MSDS Transport Information =================== Transport Information:D.O.T. PROPER SHIPPING NAME: OXIDIZING SOLID, N.O.S. (SODIUM PERIODATE), CLASS 5.1, UN1479, PKG II. I.C.A.O. PSN: OXIDIZING SOLID, N.O.S. (SODIUM PERODATE), CLASS 5.1, UN1479, PKG II. I.M.O.: PSN: OXI DIZING SOLID, N.O.S. (SODIUM PERIODATE), CLASS 5.1, UN1479, PKG II, PAGE 5163 AMDT-27-94. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311/312 CATEGORATION (40CFR 370): IMMEDIATE(ACUTE) HEALTH HAZARD, FIRE HAZARD. SECTION 313 (40 CFR 372): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SEC TION 313 OF TITLE III OF SARA. 302 (EHS) TPQ (40 CFR 355): NOT APPLICABLE. 304 CERCLA RQ (40 CFR 302.4): NOT APPLICABLE. 304 EHS RQ (40 CFR 355): NOT APPLICABLE. CLEAN WATER ACT (40 CFR 116.4): NOT AP PLICABLE. RCRA: CONTAINS RCRA REGULATED SUBSTANCES. EPA WASTE ID NUMBER: D001. C.P.S.C.: NOT APPLICABLE. Federal Regulatory Information:O.S.H.A.: THIS PRODUCT MEETS THE CITERIA FOR A HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZARD COMMUNICATION STANDARD. (29 CFR 1910.1200). NATIONAL INVENTORY STATUS: TSCA LISTED: YES. TSCA CAS NUMBER: 77 90-28-5. State Regulatory Information:CALIFORNIA PROP. 65: NO PROP. 65 LISTED CHEMICALS ARE PRESENT IN THIS PRODUCT. TRADE SECRET REGISTRY: NOT APPLICABLE. ======================= Other Information ======================= ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RU-SERIES PRODUCTS CAGE:OO153 CAGE:OO153 ============= Composition/Information on Ingredients ============= Ingred Name:HIGH MOLECULAR WEIGHT BIURET OF 1,6 HEXAMETHYLENE DIISOCYANATE Fraction by Wt: 75% Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 12.5% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA) CAS:111-15-9 RTECS #:KK8225000 Fraction by Wt: 12.5% OSHA PEL:S,100 PPM ACGIH TLV:S, 5 PPM; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:MODERATE EYE IRRITATION,POSS SKIN IRRITATION.POSS IRRITATION/NARCOSIS IF INHALE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/PLENTY OF H*2O FOR @ LEAST 15 MIN.CALL EYE PHYSICIAN. SKIN:THOROUGHLY RINSE W/H*2O & WASH W/MILD SOAP. INHAL:REMOVE TO FRESH AIR & TREAT FOR EFFECTS OF SOLVENT. ===================== Fire Fighting Measures ===================== Flash Point:101F (38C), TCC Extinguishing Media:CO*2,DRY CHEMICALS/FOAM. Unusual Fire/Explosion Hazard:REACTS W/H*2O. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/OIL ABSORBING COMPOUND;FLUSH W/LARGE VOLUMES OF H*2O. ======================Handling and Storage ====================== Handling and Storage Precautions:RU-SERIES IS SENSITIVE TO MOISTURE & SHOULD BE KEPT IN TIGHTLY CLOSED CONTAINERS. Other Precautions:PRESCRIBED SAFE HANDLING PROCEDURES FOR ETHYL GLYCOL ACETATE & XYLENE SHOULD BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESPIRATOR REQUIRED FOR SOLVENT USE. Ventilation:MECHANICAL (GENL) VENTILATION. Other Protective Equipment:CHEMICAL RESISTAN PLASTIC GLVS,CLTHG REQ FOR SOLVENT USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:325F, 163C Spec Gravity:1.06 Solubility in Water:INSOLUBLE Appearance and Odor:CLR,PALE YEL LIQ;XYLENE/2-ETHOXYETHYL ACETATE ODOR Percent Volatiles by Volume:25 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES H*2O,ALCOHOLS,AMINES,OTHR COMPOUNDS THAT REACT W/ISOCYANATES ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW PRACTICES FOR DISPOSEAL OF FLAMMABLE ORGANIC SOLVENTS. DISPOSE IAW FEDERAL,STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N40E101, GLOSS ORANGE 12246 Preparer's Name:ERNEST CARTER CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS CAS:64742-88-7 Code:F Minumum % Wt:5. Maxumum % Wt:20. OSHA PEL:100 PPM ACGIH TLV:100 Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Minumum % Wt:.5 Maxumum % Wt:1. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Minumum % Wt:.5 Maxumum % Wt:1. OSHA PEL:100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LIGHT AROMATIC SOLVENT NAPHTHA (PETROLEUM) CAS:64742-95-6 RTECS #:WF3400000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:1,3,5-TRIMETHYLBENZENE CAS:108-67-8 RTECS #:OX6825000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Minumum % Wt:3. Maxumum % Wt:8. OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:COBALTOUS 2-ETHYLHEXANOATE CAS:136-52-7 Minumum % Wt:.1 Maxumum % Wt:.2 Ingred Name:1-METHOXY-2-PROPANOL ACETATE, 108-67-8 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Minumum % Wt:0. Maxumum % Wt:10. OSHA PEL:15 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:TALC CAS:14807-96-6 RTECS #:WW2710000 Minumum % Wt:0. Maxumum % Wt:5. OSHA PEL:SEE TABLE Z-3 ACGIH TLV:2 MG/M3 Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Minumum % Wt:5. Maxumum % Wt:15. Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:0. Maxumum % Wt:30. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Minumum % Wt:0. Maxumum % Wt:5. OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION,AND PERSONAL PROTECTIVE EQUIPMENT.IRRITATION O F EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION.EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. Effects of Overexposure:HEADACHE,DIZZINESS,NASEA,AND LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.REDNESS AND ITCHING OR BURING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE COMTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. FLUSH EYES WITH LA RGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CALC Flash Point:=37.8C, 100.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD.L ATTENTION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT AND OPEN FLAME. CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING. BROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAI NERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TEKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION.WEAR A PROPERLY FITTED ORGANTIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST MATERIALS. W HEN SANDING OR ABRDING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR UNDERLYING PAINT, OR THE ABRASIVE. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOSURE TO MATERIALS IN SECTION11 IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. FOR PROTECTION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:281-395 Vapor Density:HEAVIER Spec Gravity:1.1-1.4 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:35-45 ================= Stability and Reactivity Data ================= Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE Conditions to Avoid Polymerization:WILL NOT OCCUR =================== Toxicological Information=================== Toxicological Information:BASED ON BEST CURRENT INFORMATION, THERE IS NO KNOWN HUMAN SENSITIZATION ASSOCIATED WITH THIS PRODUCT. THERE IS NO KNOWN TOXICOLOGICALLY SYNERGISTIC PRODUCTS ASSOCIATED WITH THIS PRODUCT. CARCINOGENIC ITY: NO ANIMAL SKIN CARCINOGENICITY TESTS OF THESE MATERIALS HAVE BEEN CONDUCTED. NITHER IARC, NTP, ACGIH, NOR OSHA HAVE CLASSIFIED THESE MATERIALS AS TO THEIR CARCINOGENIC RISK. BASED ON CURRENT INFO RMATION , THERE IS NO KNOWN REPRODUCTIVE TOXICITY ASSOCIATED WITH THIS PRODUCT, AND NO KNOWN TERATOGENICITY ASSOCIATED WITH THIS PRODUCT. EXPERIMENTAL EVIDENCE SUGGESTS THIS PRODUCT DOES NOT CAUSE MUT AGENESIS. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NOT AVAILABLE. USEPA WASTE: NOT REGULATED. THIS PRODUCT , IF DISCARDED, IS NOT EXPECTED TO BE A CHARACTERISTIC WASTE. IF RECYCLED IN THE USA, IT MUST BE MANAGED IN ACCORDING WITH 40 CFR P ART 279. PROCESSING, USE, OR CONTAMINATION MAY MAKE THIS INFORMATION INAPPROPRIATE, INACCURATE, OR INCOMPLETE.CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA): THIS PRODUCT IS NOT FOR SALE OR USE IN CANA DA. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE TREATED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. =================== MSDS Transport Information =================== Transport Information:DOT: NOT REGULATED. TDG: THIS PRODUCT IS NOT FOR SALE OR USE IN CANADA. ===================== Regulatory Information ===================== SARA Title III Information:108-88-3, TOLUENE, 1% MAX; 1330-20-7, XYLENE, 1% MAX; 95-63-6, 1,2,4-TRIMETHYLBENZENE, 8% MAX.; COBALT COMPOUND, .2% BY WEIGHT. State Regulatory Information:SARA 313 (40 CFR 372.65 C) SUPPLIER NOTIFICATION ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FIRST DEVELOPER REPLENISHER, PROCESS R-3, M CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60-70% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM HYDROQUINONE MONOSULPHONATE CAS:21799-87-1 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALE-LOW HAZARD FOR RECOMMENDED HANDLING. INGEST-EXPECTED TO BE A LOW INGESTION HAZARD. SKIN-PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE AN ALLERGIC SKIN REACTION. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO KNOWN CARCINOGENS OR SUSPECT CARCINOGEN. Effects of Overexposure:EYE-LIQUID MAY CAUSE MILD TRANSIENT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE-WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN-FLUSH WITH PLENTY OF WATER & WASH WITH NON-ALKALINE (ACID) TYPE OF SKIN CLEANER. IF SKIN IRRITATION OR ALLERGIC REACT ION DEVELOPS, GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHES/SHOES & DESTROY OR CLEAN. INGEST-DRINK 1-2 GLASSES OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE AGENT APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED AND AWAY FROM ACIDS. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:GOOD VENTILATION SHOULD BE SUFFICIENT. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:ROUTINE USE OF NON-ALKALINE TYPE SKIN CLEANER & REACTIONS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.28 pH:9.8 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, LIGHT YELLOW SOLUTION; ODORLESS Percent Volatiles by Volume:65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MUST BE MADE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:705020;COATING,ALIPH.POLYUR.1-COMP,BROWN 38 CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORAMINE-T-TRIHYDRATE CAS:127-65-1 RTECS #:XT5617000 Fraction by Wt: 90-100% Other REC Limits: OSHA PEL: ACGIH TLV: Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% Other REC Limits:100 PPM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% Other REC Limits:100 PPM OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTOXYETHYL ACETAYE; LEL:0.50; VAPOR PRESSURE:1.00 CAS:112-07-2 RTECS #:KJ8925000 Fraction by Wt: 5-10% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/L Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 10-20% Other REC Limits:50 PPM OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:150 PPM OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AROMATIC 100; LEL:100; VA POR PRESSURE:25.00 Fraction by Wt: <5% Other REC Limits:200 PPM OSHA PEL:N/K ACGIH TLV:N/K (FP N9 Ingred Name:HEXAMETHYLENE DIISOCYANATE; LD50 ORAL:0.710GM/KG; VAPOR PRESSURE:0.03 CAS:822-06-0 Fraction by Wt: <0.5% Other REC Limits:0.005 OSHA PEL:N/K ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE SECTION. . Explanation of Carcinogenicity:ACGHI:NO.NTP:CHROMIVM AND CERTAIN CHROMIVM COMPOUNDS ARE KNOWN TO BE CARCINOGENIC Effects of Overexposure:INHALATION:ANESTHETIC.IRRITATION OF NOSE; THROAT; EYES AND POSSIBLE DIZZINESS AND NAUSEA. THE EFFECTS OF CHRONIC EXPOSURE TO THIS PRODUCT HAVE NOT BEEN FULLY INVESTIGATED.REPEATED HANDLING OR USE MAY PRESENT ADDITIONAL HAZARDS.EXERCISE DUECAR Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MIN.INHAL:REMOVE FROM EXPOSURE.SUPPORT BREATHING(GIVE O*2/ARTIFICIAL RESPIRATION) SKIN:REMOVE CONTAMINATED CLOTHING AND WASH AFFECTED AR EA WITH WATER. INGESTION:DO NOT INDUCE VOMITING.CONSULT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:44F/6.67C Lower Limits:N/K Upper Limits:N/K Extinguishing Media:USE NFPA CLASS B EXT(CO*2,DRY CHEM;/ALCOH FOAM)DSGN TO EXT NFPA CLASS B FIRE.POLYMER FOAM APPLI AT STD APPL RA (SUP DAT) Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIPT.WTR MAY BE INEFFEC BUT MAYBE USED TO COOL EXP CNTNB TO PVNT PRESS BUILD-UP & POSS AUT-IGN/EXPSR (SUP DAT) Unusual Fire/Explosion Hazard:KEEP CNTNR TGHT CL.ISOL FROM HT;ELEC EQPT,SPK & OPEN FLAME.CL CNTNR MAY EXPLD WHEN EXP TO EXT HT. DO NOT APPLY TO VERY HOT SURF.SEE STORE,HAND;& OTHER PRECAUT. ================== Accidental Release Measures ================== Spill Release Procedures:RMV ALL SCE OF IGN(FLAMES,HOT SURF,& ELEC; STATIC/FRICT SPARK).VENT AREA AND AVOID BREATHING VAPORS.PMV WI INERT ABSORBENT AND NON-SPARKING TOOLS.STEPS MUST BE TAKEN TO PREVENT CONTAMINATION OF GROUND WATER OR STREAMS. Neutralizing Agent: ======================Handling and Storage ====================== Handling and Storage Precautions:DO STORE ABOVE 120F.ST LGE QTY IN COMPLI W/OSHA 1910.106.CNTNR SHOULD BE BONDED TO EACH OTHER AND PROPERLY GND WHEN POURING/TRANSFERING CONTENTS Other Precautions:DO NOT CUT OR WELD ON EMPTY CONTAINERS. DO USE UENTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDER STOOD BY THE USER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPR MECH RESP TO RMV OVERSPRAY WHEN SPRAYING OUTDOOR/OPEN AREAS.IN RESTRIC VENT AREAS USE NIOSH APPROV CHEM-MECH FILTERS DESIGN TO RMV SPRAY MIST & ORGAN VAPORS.USE NIOSH APPROVED SUPPLIED- AIR RESP/HOODS IN CONFINED AREAS. Ventilation:PROV GEN DIL/LCL EXH VENT IN VOL & PATT TO KEEP CONC OF HAZ INGRED BELOW BOTH ACCEPT TLV & STATED LEL LIM. RMV (SUP DAT) Other Protective Equipment:USE PROTECTIVE EQUIPTMENT TO PREVENT SKIN CONTACT. Work Hygienic Practices:N/K (FP N Supplemental Safety and Health BP:106.11-204.44C.PH:N.EXT MEDIA:TE IS PREF FOR LGE FIRES.SP FF PROC:WHEN EXP TO EXTM HEAT.IF WTR IS USED;FOG NOZ ARE PREF.RT OF ENTRY:VENT DECOM PROD WHN WELD;BRZ/FLM CUT OBJ COAT W/THS PROD.VAPO R PROD WHL DRY/BAK THS PROD MST BE PROPVENT. ACCORD TO MFG:LT:417. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:223-400F OR Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:) Vapor Pres:N/K Vapor Density:HV THN AIR Spec Gravity:1.32 pH:N/K-FP Evaporation Rate & Reference:SLOWER THAN ETHER N/K (FP Solubility in Water:N/K Appearance and Odor:N/K Percent Volatiles by Volume:4B Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG ACIDS OR ALKALINE MATERIELS. Stability Condition to Avoid:AVOID FIRES AND HIGH TEMPERATURES. Hazardous Decomposition Products:CHROMATES AND OXIDES OF CARBON Conditions to Avoid Polymerization:DO NOT ADD DRIERS OR REACTIVE CHEMICALS WITHOUT TECHNICAL SUPERVISION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE IN EPA APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
======================================================= NIIN: 01-370-4209 Product ID: MEMBRANE CLEANER/SOLVENT Cage: NO528 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 02LX8 Cage: 0N140 Cage: NO528 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: CLEANING COMPOUND,SOLVENT Specification Number: UNKNOWN Unit of Issue: DR Quantitative Expression: 00000000025LB UI Container Qty: 1 Type of Container: CONTAINER ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: TISSUE IRRITATION UPON CONTACT WITH SKIN AND EYES. CHRONIC: PROLONGED OR REPEATED EYE AND SKIN CONTACT CAUSES IRRITATION. INJURY TO THE ESOPHAGUS FROM SCARRING MAY OCCUR. ALKALI EXPOSURES MAY N ECESSITATE IRRIGATION FOR EXTENDED DURATION. Explanation Of Carcinogenicity: TRISODIUM PHOSPHATE IS NOT LISTED AS A CARCINOGEN PER MSDS. Signs And Symptions Of Overexposure: INHALING THIS ALKALINE MATERIAL'S DUST OR MIST IRRITATES THE RESPIRATORY TRACT. AQUEOUS, HIGHLY ALKALINE SOLUTIONS MAY ALSO PRODUCE CAUSTIC BURNS. Medical Cond Aggravated By Exposure: PERMANENT TISSUE DAMAGE TO THE SKIN AND EYES. First Aid: EYE CONTACT: FLUSH IMMEDIATELY, INCLUDING UNDER THE EYE LIDS. GENTLY BUT THOROUGHLY FLOOD LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN: AFTER RINSING AFFECTED AREA WITH WATER, WASH IT WITH SOAP AND WATER. INHALATION: REMOVEEXPOSED PERSON TO FRESH AIR. INGESTION: IF INGESTED, HAVE CONSCIOUS PERSON DRINK 1 TO 2 GLASSES OF WATER OR MILK, THEN GIVE FRUIT JUICE. NEVER INDUCE VOMITING. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WEAR PROTECTIVE CLOTHING TO PREVENT SKIN OR EYE CONTACT AND DUST INHALATION. FOR LIQUID SPILLS, COVER THE MATERIAL WITH AN INERT SOLID ABSORBENT (VERMICULITE OR SAND). SWEEP, VACUUM OR SCOOP THE SPILL ED SOLID, AVOIDING DUST GENERATION. FLUSH RESIDUE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: SCRAP MATERIAL CAN BE USED FOR NEUTRALIZING ACID WASTES OR BURIED IN A APPROVED LANDFILL. IF REGULATIONS PERMIT, YOU MAY FLUSH SMALL AMOUNTS TO DRAIN. FOLLOW APPLICABLE FEDERAL, STATE AND LOCAL REGULA TIONS. Handling And Storage Precautions: STORE IN TIGHTLY SEALED CONTAINERS AWAY FROM ACIDIC MATERIAL IN A CLEAN, DRY, VENTILATED AREA. PREVENT PHYSICAL DAMAGE TO CONTAINERS. Other Precautions: NEVER WEAR CONTACT LENSES IN THE WORK AREA. LAUNDER CONTAMINATED CLOTHING BEFORE WEARING. REMOVE THIS MATERIAL FROM YOUR SHOES AND EQUIPMENT. NEVER EAT, DRINK, OR SMOKE IN WORK AREA. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONCOMBUSTIBLE Lower Limits: NONE Upper Limits: NONE Extinguishing Media: USE WHAT IS APPROPRIATE TO THE SURROUNDING FIRE SINCE THIS MATERIAL IS NONCOMBUSTIBLE. Fire Fighting Procedures: WEAR SCBA WITH FULL FACEPIECE OPERATED IN THE PRESSURE-DEMAND OR POSITIVE-PRESSURE MODE. Unusual Fire/Explosion Hazard: IN A FIRE SITUATION AT HIGH TEMPERATURE, PHOSPHATES CAN EMIT HIGHLY TOXIC PHOSPHOROUS OXIDES (POX) FUMES. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR A NIOSH-APPROVED RESPIRATOR IF NECESSARY. FOLLOW OSHA RESPIRATOR REGULATIONS. FOR EMERGENCY OR NONROUTINE OPERATIONS, WEAR AN SCBA. Ventilation: PROVIDE GENERAL AND LOCAL EXPLOSION-PROOF VENTILATION SYSTEMS TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW OSHA PEL. Other Protective Equipment: BOOTS, APRONS, GAUNTLETS, EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH SHOWERS. Work Hygienic Practices: PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS MATERIAL. Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 Solubility in Water: YES (PER MSDS) Appearance and Odor: WHITE OR COLORLESS CRYSTALLINE SOLID (ALSO AS POWDER FLAKE, GRANULES); NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NEVER HEAT TO DECOMPOSITION. Materials To Avoid: THIS MATERIAL REACTS VIOLENTLY WITH STRONG ACIDS TO GENERATE HEAT. Hazardous Decomposition Products: HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDES AND SODIUM OXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 130040 Product ID: MEMBRANE CLEANER/SOLVENT Review Date: 03/10/1999 Net Unit Weight: 25 LBS Multiple KIT Number: 0 Review IND: Y Unit Of Issue: DR Container QTY: 1 Type Of Container: CONTAINER Additional Data: PACK IN 1H2 MADE OF HIGH DENSITY POLYETHYLENE. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: MEMBRANE CLEANER/SOLVENT Cage: NO528 Assigned IND: Y Company Name: VENUS LABORATORY Street: 15571 COMMERCE LANE Zipcode: 92649-1600 Label Required IND: Y Date Of Label Review: 10/03/1996 Status Code: C Label Date: 10/03/1996 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: TISSUE IRRITATION UPON CONTACT WITH SKIN AND EYES. CHRONIC: PROLONGED OR REPEATED EYE AND SKIN CONTACT CAUSES IRRITATION. INJURY TO THE ESOPHAGUS FROM SCARRING MAY OCCUR. STORE IN TIGHTLY SEALE D CONTAINERS AWAY FROM ACIDIC MATERIAL IN A CLEAN, DRY, VENTILATED AREA. FIRST AID: EYE CONTACT: FLUSH IMMEDIATELY, GENTLY BUT THOROUGHLY FLOOD LARGE AMOUNTS OF RUNNING WATER. SKIN: AFTER RINSING AFFE CTED AREA WITH WATER, WASH IT WITH SOAP AND WATER. INHALATION: REMOVE EXPOSED PERSON TO FRESH AIR. INGESTION: HAVE CONSCIOUS PERSON DRINK 1 TO 2 GLASSES OF WATER OR MILK. NEVER INDUCE VOMITING. TARGET ORGANS: EYES, SKIN, RESPIRATORY TRACT. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ULTRA FLUX SILVER BRAZING FLUX CAGE:86337 CAGE:86337 CAGE:93009 ============= Composition/Information on Ingredients ============= Ingred Name:THE PERCENTAGE BY WEIGHT VALUES REPORTED FOR THE INGREDIENTS IN THIS PRODUCT REPRESENT APPROXIMATE FORMULATION VALUES. Ingred Name:POTASSIUM TETRABORATE CAS:1332-77-0 Fraction by Wt: 30-40% Other REC Limits:NONE RECOMMENDED Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: 20-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG BORATES/M3 ACGIH TLV:5 MG BORATES/M3 Ingred Name:POTASSIUM BIFLUORIDE (POTASSIUM HYDROGEN FLUORIDE) CAS:7789-29-9 RTECS #:TS6650000 Fraction by Wt: 20-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:2.5 MG/M3 AS F ACGIH TLV:2.5 MG/M3 AS F Ingred Name:POTASSIUM PENTABORATE CAS:11128-29-3 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM DODECYL SULFATE (DODECYL SULFATE, SODIUM SALT) CAS:151-21-3 RTECS #:WT1050000 Fraction by Wt: 0-0.5% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION AND BURNS. SKIN: FLUORIDE BURNS. MAY BE ABSORBED BY SKIN RESULTING IN SYSTEMIC POISONING. INHALATION: RESPIRATORY AND MUCOUS MEMBRANE IRRITATION. INGESTION: ABDOMINAL PAIN, DIARRHEA, VOMITING, SALIVATION, THIRST, PAINFUL SPASMS OF THE LIMBS. LARGE AMOUNTS MAY BE FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, BURNS. SKIN: BURNS NOT IMMEDIATELY PAINFUL OR EVIDENT, SYSTEMIC POISONING. INHALATION: RESPIRATORY AND MUCOUS MEMBRANE IRRITAION, NASAL DISCHARGE, NOSEBLEED, SORE THROAT, SYSTEMIC TO XICITY. INGESTION: ABDOMINAL PAIN, DIARRHEA, VOMITING, SALIVATION,THIRST,PERSPIRATION,SPASMS.LARGE AMOUNTS MAY BE FATAL. Medical Cond Aggravated by Exposure:MAY ADVERSELY AFFECT EXISTING MEDICAL CONDITIONS SUCH AS EYE, SKIN, RESPIRATORY, LIVER AND/OR KIDNEY AILMENTS, AND CENTRAL NERVOUS SYSTEM DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. DO NOT USE ZEPHIRAN CHLORIDE SOLUTIONS IN EYES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH SKIN WITH WATER. GET MEDICAL ATTENTION. INHALA TION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, ALCHOL FOAM, OR CARBON DIOXIDE. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING AS SPECIFIED IN 29 CFR 1910.156. Unusual Fire/Explosion Hazard:NOT A FIRE OR EXPLOSION HAZARD. HOWEVER, TOXIC AND CORROSIVE FLUORIDE COMPOUNDS MAY BE RELEASED IN A FIRE SITUATION. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL BY DIKING. VENTILATE AREA. SOAK UP SPILL USING AN ABSORBENT. SCOOP INTO CONTAINER. NOTIFICATION OF NATIONAL RESPONSE CENTER MAY BE REQUIRED. REFER TO EPA, DOT AND APPLICABLE STATE AND LO CAL REGULATIONS FOR CURRENT RESPONSE INFORMATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY AREA AWAY FROM INCOMPATABLE MATERIALS.USE WITH ADEQUATE VENTILATION.AVOID CONTACT WITH DUSTS,MISTS,FUMES RESULTING FROM PRODUCT USE. Other Precautions:DO NOT EAT, DRINK, OR SMOKE IN WORK AREA. KEEP CONTAINER CLOSED. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THERE IS A POTENTIAL TO EXCEED THE TLV, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IS REQUIRED. IF RESPIRATOR PROTECTION IS USED, FOLLOW ALL REQUIREMENTS FOR RESPIRATOR PROGRAMS SET FORTH IN THE OS HA REGULATIONS (29 CFR 1910.134). Ventilation:PROVIDE GENERAL VENTILATION AND/OR LOCAL EXHAUST VENTILATION AS NECESSARY TO CONTROL AIR CONTAMINANTS WITHIN PELS/TLVS. Other Protective Equipment:WEAR BODY PROTECTION AS NECESSARY TO PREVENT SKIN CONTACT. REFER TO ANSI/ASC Z49.1-94 FOR INFO ON PROTECTION EQUIPMENT. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THIS PRODUCT DOES NOT CONTAIN TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. ================== Physical/Chemical Properties ================== HCC:B3 Melt/Freeze Pt:M.P/F.P Text:792F,422C Spec Gravity:1.49 pH:8.8 Solubility in Water:COMPLETE Appearance and Odor:WHITE PASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND ALKALIES. Stability Condition to Avoid:TEMPERATURES AT OR ABOVE 225C. Hazardous Decomposition Products:EMITS TOXIC AND CORROSIVE FLUORIDE COMP0UNDS. MAY ALSO EMIT OXIDES OF BORON AND POTASSIUM WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LACQUER ACRYLIC MIL-L-19537C AM.3 CAGE:LO335 CAGE:80592 CAGE:LO335 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC/NITROCELLULOSE Fraction by Wt: 22.9% Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 34% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 8% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 3% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Effects of Overexposure:SYSTEMIC TOXIC EFFECTS MAY ALSO RESULT FR SKIN ABSORPTION.IRRIT.TO EYES,NOSE & THROAT NR OR ABOVE ======================= First Aid Measures ======================= First Aid:IF INHALED,REMOVE TO FRESH AIR.IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION,PREFER MOUTH TO MOUTH CALL A PHYS.IN CASE OF SKIN CONTACT,WASH THOROUGHLY W/SOAP & WATER;FOR EYES,FLUSH IMMED.W/PLENTY OF WA TER F/15 MIN & CNTCT A PHYS.WASH CONTAMNATD CLOTHI ===================== Fire Fighting Measures ===================== Flash Point:23F TCC -5C Extinguishing Media:FOAM,DRY CHEMICAL,WATER SPRAY FOG OR CO*2. Fire Fighting Procedures:USE AIR SUPPLIED EQPMENT F/ENCL. AREAS.COOL EXPOS CONTAINERS Unusual Fire/Explosion Hazard:KEEP AWAY FROM HEAT,SPARKS & FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT(FLAME,ELECTRICAL,STATIC OR FRICTIONAL SPARKS;HOT SURFACES,ETC).AVOID BREATHING VAPORS.VENTILATE AREA.CONTAIN & SCOOP UP SPILL W/NON-SPARKING TOOLS,RAGS,ETC.USE INERT ABSORB ENT MATRLS ON SM SPILLS OR ON RESIDUALSOF LG SPIL ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED & UPRIGHT TO PREVENT LEAKAGE.AVOID BREATHING OF VAP OR SPRAY MIST.AVOID EYE & SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAP CANISTER WHERE OXYG CONTNT IS ADEQ & VAP CONCENT IS LESS Ventilation:LOC EXHAUST-YES MECH-YES Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Vapor Density:HEAV Spec Gravity:8.5 GL Evaporation Rate & Reference:N.BUTYL ACET-FAST Appearance and Odor:GRAY VISCOUS LIQUID W/TYPICAL SOLVENT ODOR Percent Volatiles by Volume:73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORD W/LOCAL APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GANITE Preparer's Name:CHRISTINA J BARRINGTON CAGE:24832 CAGE:24832 CAGE:39832 ============= Composition/Information on Ingredients ============= Ingred Name:GALLIUM NITRATE CAS:13494-90-1 RTECS #:LW9625000 Fraction by Wt: 2.5% Ingred Name:SODIUM CITRATE CAS:6132-04-3 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (MOUSE): 4360 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IMMEDIATE EFFECTS: EYE, SKIN & RESPIRATORY IRRITATION MAY OCCUR. DELAYED EFFECTS: DECREASED BLOOD PRESSURE, ANEMIA, HYPOCALCEMIA, ADVERSE KIDNEY EFFECTS, VOMITING, NAUSEA, SKIN RASH, FEVER & CONFUSION HAVE BEEN EXPERIENCED W/PATIENT ADMINISTRATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IMMEDIATE EFFECTS: EYE, SKIN & RESPIRATORY IRRITATION MAY OCCUR. DELAYED EFFECTS: DECREASED BLOOD PRESSURE, ANEMIA, HYPOCALCEMIA, ADVERSE KIDNEY EFFECTS, VOMITING, NAUSEA, SKIN RASH, FEVER & CONFUSION HAVE BEEN EXPERIENCED W/PATIENT ADMINISTRATION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. GIVE CPR IF REQUIRED. INGESTION: FLUSH MOUTH OUT W/WATER IMMEDIATELY. SKIN: FLUSH AREA W/WATER FOR 15 MINS. EYES: IMMEDIATELY FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL A TTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point: >200F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2/FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT. USE ABSORBENT TOWELS/BOOMS TO CLEAN UP. WIPE SURFACES CLEAN & WASH W/SOAP & WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:WHEN HANDLING PHARMACEUTICAL PRODUCTS, AVOID CONTACT/INHALATION OF DUST, FUMES, MIST/VAPORS ASSOCIATED W/PRODUCT. PROTECT FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE USUALLY REQUIRED W/SATISFACTORY VENTILATION. Ventilation:GENERAL ROOM USUALLY SATISFACTORY. LOCAL EXHAUST WHEN NECESSARY. Other Protective Equipment:DISPOSABLE GARMENTS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THIS PRODUCT IS INTENDED FOR THERAPEUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN. ================== Physical/Chemical Properties ================== pH:6-7 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, STERILE SOLUTION ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:FREEZING Hazardous Decomposition Products:SMOKE & NITROGEN OXIDES FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0279269 SANI-DEX SOLUTION CAGE:0LXP8 CAGE:0LXP8 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 40% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:P-CHLORO-M-XYLENOL (4-CHLORO-3,5-XYLENOL), CHLORO-XYLENOL CAS:88-04-0 RTECS #:ZE6850000 Fraction by Wt: 1% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: PROLONGED USE MAY CAUSE IRRITATION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DEFATTING. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/COOL WATER FOR 15 MIN. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:80F Extinguishing Media:CO2, ALCOHOL TYPE FOAM, DRY CHEMICAL Fire Fighting Procedures:HANDLE AS FLAMMABLE LIQUID ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. CONTAIN W/ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:GOOD HOUSEKEEPING PRACTICES SHOULD BE FOLLOWED. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:182F Vapor Pres:50 Vapor Density:1.5 Spec Gravity:0.94 Solubility in Water:SLIGHT Appearance and Odor:CLEAR LIQUID W/ALCOHOLIC FLORAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:SOURCES OF IGNITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS FLAMMABLE WASTE IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= NIIN: 01-340-2176 Product ID: ZOK-27 Cage: 19527 ======================================================= Contractor Summary ======================================================= Cage: 19527 ======================================================= Item Description Information ======================================================= Specification Number: UNKNOWN Type of Container: DRUM ======================================================= Ingredients ======================================================= Cas: 111-76-2 RTECS #: KJ8575000 % Wt: <6 Other REC Limits: NONE RECOMMENDED OSHA PEL: S, 50 PPM ACGIH TLV: S, 25 PPM; 9394 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: UNKNOWN Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MIXTURE IS NON-HAZARDOUS BUT FREQUENT OR PROLONGED CONTACT MAY CAUSE DEGREASING OF THE SKIN AND EYE IRRITATION. Explanation Of Carcinogenicity: PER MSDS:CARCINOGENICITY PER NTP/IARC/OSHA ARE NO. Signs And Symptions Of Overexposure: REPEATED IHALATION: FATIGUE, NAUSEA, SKIN DRYING AND CRACKING. Medical Cond Aggravated By Exposure: N/A. First Aid: INGEST:DO NOT INDUCE VOMITING. EYE OR SKIN CONTACT:FLUSH WELL WITH WATER. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: FLUSH AWAY WITH WATER OR ABSORB WITH SAND OR EARTH. Neutralizing Agent: NONE SPECIFIED BY MFG. Waste Disposal Methods: BIODEGRADABLE. Handling And Storage Precautions: STORE AT ROOM TEMPERATURE BETWEEN +4 AND +80C. Other Precautions: IF ADVERTENTLY FROZEN PRODUCT IS SERVICEABLE AFTER THAWING. NOTE:PRODUCT IS DILUTED 1:4 (OR AS SPECIFIED BY ENGINE MFG) WITH WATER BEFORE USE. EQUALS LESS THAN 1.2% IN USE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: >212F,>100C Extinguishing Media: MATERIAL IS NON-FLAMMABLE. ANY. EXTINGUISHING MEDIA. Fire Fighting Procedures: WATER SHOULD BE FINE SPRAY. USE ALCOHOL-PROOF FOAM. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: FILTER MASK IF VENTILATION IS POOR. Ventilation: PROVIDE VENTILATION IF PRODUCT IS USED FOR EXTENDED PERIOS IN CONFINED AREAS. Other Protective Equipment: NONE SPECIFIED BY MFG. Work Hygienic Practices: THE USE OF AN EMOLLIENT CREAM IS RECOMMENDED AFATER SKIN CONTACT. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 B.P. Text: 212F,100C Vapor Pres: 0.6 Vapor Density: 4.1 Spec Gravity: 1.018 Solubility in Water: FULLY SOLUBLE. Appearance and Odor: PALE STRAW COLORED LIQUID. MILD SWEET SMELL. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: STRONG OXIDIZING OR REDUCING AGENTS. Hazardous Decomposition Products: NONE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 127192 Product ID: ZOK-27 Review Date: 09/14/1994 Multiple KIT Number: 0 Review IND: Y Type Of Container: DRUM ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: ZOK-27 Cage: 19527 Company Name: LUCAS AEROSPACE Street: ONE CIRCLE WEST Zipcode: 06902 Label Required IND: Y Date Of Label Review: 09/14/1994 Status Code: C Label Date: 09/14/1994 Year Procured: 1994 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: MIXTURE IS NON-HAZARDOUS BUT FREQUENT OR PROLONGED CONTACT MAY CAUSE DEGREASING OF THE SKIN AND EYE IRRITATION. REPEATED INHALATION MAY CAUSE FATIGUE, NAUSEA, SKIN DRYING AND CRACKING. STORE AT ROOM T EMPERATURE BETWEEN +4 AND +80C. FIRST AID: INGEST:DO NOT INDUCE VOMITING. EYE OR SKIN CONTACT:FLUSH WELL WITH WATER. SPILLS:FLUSH AWAY WITH WATER OR ABSORB WITH SAND OR EARTH. DISPOSAL:BIODEGRADABLE. USE FILTER MASK IF VENTILATION IS POOR. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TCLP-ICP, CUSTOM PLASMA STANDARD MULTI (SUPDAT) CAGE:07977 CAGE:07977 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 5% OSHA PEL:2 PPM ACGIH TLV:2 PPM; 4 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BARIUM (SARA 313) %: 500 PPM CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: <0.1% OSHA PEL:0.5 MG/M3 ACGIH TLV:N/K Ingred Name:CHROMIUM (SARA 313) (CERCLA) %: 25 PPM CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <0.1% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILVER (SARA 313) (CERCLA) %: 25 PPM CAS:7440-22-4 RTECS #:VW3500000 Fraction by Wt: <0.1% OSHA PEL:0.01 MG/M3 ACGIH TLV:0.1 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CADMIUM (SARA 313) (CERCLA) %: 5 PPM CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: <0.1% OSHA PEL:0.2 MG/M3 DUST ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80-98% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: PENETRATING BURNS; CONC SOLNS CAUSE DEEP ULCERS & STAIN SKIN BRIGHT YELLOW OR YELLOWISH BROWN (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: COLOR. VAP & MIST MAY ERODE EXPOS TEETH W/PRLNGD EXPOS. INGEST OF LIQ WILL CAUSE IMMED PAIN & BURNS OF (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MOUTH, ESOPHAGUS & GI TRACT. INHAL MAY BE FATAL CAUSING SPASM, INFLAMM & EDEMA OF LARYNX & BRONCHI, CHEM (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: PNEUM & PULM EDEMA. SYMPS INCL: BURNING SENSATION, COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: HDCH, NAUS & VOMIT. THIS SOLN CONTAINS CHEM(S) KNOWN TO CAUSE CANCER ACCDG TO STATE OF CALIFORNIA. RTECS #:9999999ZZ Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE HNO*3 ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC HNO*3. HOWEVER, SINCE HNO*3 IS IN SOLN AT 1% (OR 10,000PPM) OR GREATER, HLTH HAZS FOR CONC HNO*3 ARE GIVEN. SINCE BA & AG ARE BOTH IN SOLN AT <10,000PPM (OR 1%) & CD & CR ARE IN SOLN AT <1,000PPM (OR 0.1%) THEY ARE NOT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: REQD TO BE REPORTED AS HLTH HAZS ACCDG TO OSHA. CONC HNO*3 MAY BE FATAL IF TOO MUCH IS INHALED/ABSORBED THRU SKIN. CONC HNO*3 VAP/MIST IS IRRITANT OF EYES, MUC MEMBS & SKIN. IN CNTCT W/EYES, IT PRDCES SEV BURNS WHICH MAY RSLT IN PERM DMG & VISUAL IMPAIRMENT. ON SKIN, LIQ/CONC VAP PRDCES IMMED, SEV & (ING 7) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MIN OCCAS LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMD CLTHG THEN FLUSH W/WATER FOR AT LEAST 15 MIN. WASH CLTHG THORO BEFORE REUSE. INHAL: MOVE TO FRESH AIR. IF IRRIT CONTINUES, GET MED ATTN IMMED. INGEST: DO NOT INDUCE VOMITING. IMMED OBTAIN MED HELP. SEND TO HOSPITAL. ONLY IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST BUT IS A STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE IGNIT. CAN REACT W/METALS TO RELS FLAMM (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS COMPLETE. APPRVD RESP. Neutralizing Agent:NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC. ======================Handling and Storage ====================== Handling and Storage Precautions:CONC NITRIC ACID WILL ATTACK SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE. Other Precautions:WARNING: IRRITANT, OXIDIZER. CORROSIVE LIQUID. AVOID INHALATION, INGESTION AND CONTACT WITH EYES AND SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE IN A CHEMICAL FUME HOOD. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR CHEMICAL RESISTANT CLOTHING. LAB COAT. Work Hygienic Practices:WASH CAREFULLY AFTER USE. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: ELEMENT SOLN. EXPLO HAZ: HYDROGEN GAS. CONC HNO*3 REACTS EXPLO W/COMBUST ORG/READILY OXIDIZABLE MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE, METAL PWDRS, HYDROGEN SULFIDE, ETC. M ATL TO AVOID: WOOD, TURPENTINE, METAL PWDRS, HYDROGEN SULFIDE, ETC. CNTCT W/STRONG BASES WILL CAUSE VIOLENT SPLATTERING. ================== Physical/Chemical Properties ================== Spec Gravity:APPROX 1 Solubility in Water:SOLUBLE Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONC HNO*3 IS POWERFUL OXIDIZING AGENT; REACTS EXPLO W/COMBUST ORG OR READILY OXIDIZABLE MATLS SUCH AS:ALCOHOL, (SUPDAT) Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS TO BURST AND LIBERATE TOXIC OXIDES OF NITROGEN. Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE FUMES AND VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:826K157 DES P-1000 15044 GLOSS BLUE Kit Part:Y CAGE:83574 CAGE:85570 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:VOLATILE ORGANIC CONTENT: 566 GM/L W/910X946 & 020X541@2/1/1 RTECS #:9999999VO Ingred Name:MANGANESE CARBONATE Fraction by Wt: <5% Ingred Name:1,3-BENZENEDICARBOXYLIC ACID POLYMER (POLYESTER RESIN) CAS:85959-88-2 Fraction by Wt: 40% Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 25% Other REC Limits:50 PPM OSHA PEL:465 MG/CUM ACGIH TLV:233 MG/CUM Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *96-1* CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 10% Other REC Limits:150 PPM OSHA PEL:710 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BIS (1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL) SEPACATE CAS:41556-26-7 Fraction by Wt: <5% Ingred Name:NITROETHANE CAS:79-24-3 RTECS #:KI5600000 Fraction by Wt: <5% Other REC Limits:100 PPM OSHA PEL:310 MG/CUM ACGIH TLV:307 MG/CUM Ingred Name:1-NITROPROPANE CAS:108-03-2 RTECS #:TZ5075000 Fraction by Wt: <5% Other REC Limits:25 PPM OSHA PEL:90 MG/CUM ACGIH TLV:91 MG/CUM Ingred Name:ETHYL 3-ETHOXYPROPIONATE, PROPANOIC ACID, 3-ETHOXY-, ETHYL ESTER *96-1* CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 5% Ingred Name:METHYL PROPYL KETONE CAS:107-87-9 RTECS #:SA7875000 Fraction by Wt: <5% Other REC Limits:200 PPM OSHA PEL:700 MG/CUM ACGIH TLV:705 MG/CUM Ingred Name:NON-HAZARDOUS ADDITIVES, RESINS & PIGMENTS Fraction by Wt: <5% Ingred Name:PHTHALOCYANINE GREEN PIGMENT CAS:14302-13-7 RTECS #:GL7500000 Fraction by Wt: <5% Ingred Name:C. I. PIGMENT BLUE 15, COPPER PHTHALOCYANINE BLUE CAS:147-14-8 Fraction by Wt: <5% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-1* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <0.1% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-1* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NASAL & RESPIRATORY IRRITATION, CNS DEPRESSION, ASPHYXIATION. SKIN: IRRITATION, DERMATITIS, SENSITIZATION IN SOME INDIVIDUALS. EYES: IRRITATION. INGESTION: GI IRRITATION. PROLONG ED/REPEATED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION/UNCONSCIOUSNESS, DEFATTING, NAUSEA, VOMITING, DIARRHEA. OVEREXPOSURE TO SOLVENTS-CONCENTRATION DIFFICULTIES, DIMINISHED ACTUAL DEXTERITY & M EMORY LOSS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. DON'T USE SOLVENTS. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:68F Lower Limits:1 Extinguishing Media:CO2, DRY CHEMICAL/FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL CONTAINERS W/WATER. FOG NOZZLES ARE PREFERRABLE. WEAR NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:VAPORS ACCUMULATE IN INADEQUATELY VENTILATED/CONFINED AREAS, FORM EXPLOSIVE MIXTURES W/AIR, TRAVEL LONG DISTANCES, FLASHBACK/FLAME TO HANDLING SITE. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. WEAR PROTECTIVE EQUIPMENT. USE NON-SPARKING TOOLS. USE EMERGENCY RESPONSE PROFESSIONAL IF MANAGING A RELEASE IS BEYOND THE CAPABILITY OF IN-HOUSE PERSONNEL. SMALL: DIKE & ABSO RB W/INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM HEAT & OTHER IGNITION SOURCES. GROUND & BOND WHEN TRANSFERRING. AVOID FREE FALL OF LIQUID. Other Precautions:DON'T SMOKE WHERE MATERIAL IS USED/STORED. DON'T APPLY TO HOT SURFACES. EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DON'T CUT, PUNCTURE/WELD ON/NEAR DRUM. DON'T TAKE INTERNALLY. DON'T DELIBERATELY CONCE NTRATE & INHALE THE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE TLVS ARE EXCEEDED/IF SPRAY MIST IS PRESENT, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. IN CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATORS. Ventilation:WHERE EMPLOYEES MAY BE EXPOSED, USE GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN VOLUME & PATTERN TO KEEP <25% OF LEL. Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYEBATH, WASHING FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:213-329F Vapor Density:>1 Spec Gravity:1.04 Evaporation Rate & Reference:SLOWER THAN N-BU AC Appearance and Odor:BLUE LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:57.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE RECOGNIZED Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, FLAME, TEMP >120F, HOT SURFACES. Hazardous Decomposition Products:COMBUSTION: CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISPOSING ENSURE THAT IT'S PACKAGED, STORED, TRANSPORTED/OTHERWISE MANAGED IAW/FEDERAL, STATE & LOCAL REGULATIONS. NO METHOD IS TO BE USED THAT POSES ENVIRONMENTAL/HUMAN HEALTH THREAT. INCLUDING ANY WHICH WOULD CONTAMINATE GROUND/SURFACE WATER.
1
eyes_protection_mandatory
======================================================= Product ID: DURA CLAD ALKYD ENAMEL, BLACKS, STAIN 12-984 Cage: 75734 ======================================================= Contractor Summary ======================================================= Cage: 75734 Cage: 55652 ======================================================= Ingredients ======================================================= Cas: 1317-65-3 RTECS #: EV9580000 % Wt: >6.3 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST; 9495 ------------------------------ Cas: 1333-86-4 RTECS #: FF5800000 % Wt: 2.0-3.0 OSHA PEL: 3.5 MG/M3 ACGIH TLV: 3.5 MG/M3; 9495 ------------------------------ Cas: 68855-54-9 % Wt: 0-3.6 OSHA PEL: 0.1 MG/M3 (MFR) ACGIH TLV: 0.1 MG/M3 (MFR) ------------------------------ Cas: 8052-41-3 RTECS #: WJ8925000 % Wt: >31.0 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM; 9495 ------------------------------ Cas: 1332-58-7 RTECS #: GF1670500 % Wt: 0-11.8 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 2 MG/M3 TDUST; 9495 ------------------------------ Cas: 14807-96-6 RTECS #: WW2710000 % Wt: 0-16.1 OSHA PEL: 20 MPPCF Z-3 ACGIH TLV: 2 MG/M3 RDUST; 9495 ------------------------------ Cas: 96-29-7 RTECS #: EL9275000 % Wt: >0.1 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ % Wt: >16.3 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- ----------------------------- FOR HUMANS AT/BELOW REC VAP LIMS IN ----------------------------- &/DERMS. EYES: CAN CAUSE SEV IRRIT, RED, ----------------------------- & DIARR. ASPIR OF MATL INTO LUNGS CAN ----------------------------- HLTH STUDIES HAVE SHOWN THAT MANY PETRO ----------------------------- RISKS WHICH MAY VARY FROM PERS TO PERS. ----------------------------- LAB ANIMAL STUDIES HAVE SHOWN THAT ----------------------------- BOILING RANGE AS THIS PROD CAN PRODUCE ----------------------------- OBSERVED IN SIMILAR STUDIES W/FEMALE RATS ----------------------------- SPECIES. ADDITIONALLY, IN A NUMBER OF HUMAN ----------------------------- LEVELS. METHYL ETHYL KETOXIME IS LISTED ----------------------------- IN THIS PROD IS AT/SLIGHTLY ABOVE 0.1% ----------------------------- ----------------------------- BELOW HIPS TO PREVENT ASPIRATION OF ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL, RAT): > 5 G/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: INHAL: EXCESSIVE INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATIGUE, NAUS, HDCH. HIGH VAP CONCS MAY RSLT IN CNS DEPRESS. LAB ANIMAL STUDIES HAVE SHOWN THAT PRLNG & RPTD INHAL EXPOS TO LIG HT HYDROCARBON VAPS IN SAME NAPHTHA BOILING RANGE AS THIS PROD CAN PRODUCE ADVERSE KIDNEY EFTS IN (EFTS OF OVEREXP) Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 24-27, 1995: GROUP 2B. Signs And Symptions Of Overexposure: HLTH HAZ: MALE RATS. HOWEVER, THESE EFTS WERE NOT OBSERVED IN SIMILAR STUDIES W/FEMALE RATS & MALE & FEMALE MICE & IN LIMITED STUDIES W/OTHER ANIMAL SPECIES. ADDITIONALLY, IN A NUMBER OF HUMAN STUDIES , THERE WAS NO CLINCIAL EVID OF SUCH EFTS AT NORM OCCUP LEVELS. IT IS THEREFORE HIGHLY UNLIKELY THAT KIDNEY Medical Cond Aggravated By Exposure: HIGH VAPOR CONCENTRATIONS (GREATHER THAN APPROXIMATELY 1000 PPM) ARE IRRITATING TO EYES & RESPIRATORY TRACT, MAY CAUSE HEADACHES & DIZZINESS, ARE ANESTHETIC, & MAY HAVE OTHER CNS EFFECTS INCL DATH. First Aid: INHAL: REMOVE VICTIM TO FRESH AIR & PROVIDE OXYGEN IF BRTHG IS DFCLT. IF BRTHG STOPS, BEGIN ARTF RESP & SEEK IMMED MED ATTN. SKIN: REMOVE CONTAMD CLTHG/SHOES. FLUSH SKIN W/H*2O. FOLLOW BY WASHING W/SO AP & H*2O. IF IRRIT OCCURS, GET MED ATTN. DO NOT REUSE CLTHG UNTIL CLEANED. EYES: FLUSH W/CLEAR H*2O FOR AT LEAST 15 MIN/UNTIL IRRIT SUBSIDES. IF IRRIAT PERSISTS, CALL MD. INGEST: DO NOT ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIM ALL IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPARKS). RECOVER FREE PROD. ADD SAND, EARTH/OTHER SUITABLE ABSORB TO SPILL AREA. MINIMIZE SKIN CNTCT. VENT CONFINED SPACES. FOR MORE SPEC IFIC INFORMATION CONTACT NEHC (FP N). Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: AVOID CONTACT WITH EYES SKIN AND CLOTHING. REMOVE CONTAMINATED CLOTHING AND SHOES. Other Precautions: THIS PRODUCT IS USED TO PREVENT SKINNING OF THE COATING IN THE CONTAINER. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTH ING BEFORE REUSE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 104F,40C Lower Limits: 0.9% Upper Limits: 6.0% Extinguishing Media: USE DRY CHEM, FOAM/CARBON DIOXIDE. H*2O MAY BE INEFFECTIVE, BUT H*2O SHOULD BE USED TO KEEP FIRE-EXPOSED CNTNRS (SUPDAT) Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). H*2O MAY BE UNSUITABLE AS AN EXTING MEDIA, BUT HELPFUL IN KEEPING ADJACENT CNTNRS COOL. AVOID SPREADING (SUPDAT) Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & MAY TRAVEL ALONG THE GROUND/BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER FLAME & IGNIT SOURCES AT LOCATIONS DISTANT FROM (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: THE USE OF RESPIRATORY PROTECTION DEPENDS ON VAPOR CONCENTRATION ABOVE THE TIME WEIGHTED TLV: USE NIOSH APPROVED RESPIRATOR. Ventilation: PROVIDE SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: DO NOT EAT, DRINK OR SMOKE WHILE USING THIS PRODUCT. THOROUGHLY WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health: EXTING MEDIA: COOL. IF A LEAK/SPILL HAS IGNITED, USE WATER SPRAY TO DISPERSE VAPS & TO PROT MEN ATTEMPTING TO STOP A LEAK. MINIMIZE BRTHG GASES, VAPS, FUMES/DECOMP PRODS. FIRE FIGHT PROC: BURNING LIQ W/H*2O USED FOR COOLING. EXPLO HAZ: HNDLG POINT. NEVER USE A WELDING/CUTTING TORCH ON/NEAR CNTNR (EVEN EMPTY) ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >360F,>182C Vapor Pres: 2 @ 20C Vapor Density: 4.9 Spec Gravity: 1.318 VOC Pounds/Gallon: 3.47 Evaporation Rate & Reference: 0.1 (BUTYL ACETATE =1) Solubility in Water: NEGLIGIBLE; Appearance and Odor: VISCOUS LIQUID; HYDROCARBON ODOR. Percent Volatiles by Volume: 53.6 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: THIS PRODUCT IS INCOMPATABLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS OR BASES AND SELECTED AMINES. Hazardous Decomposition Products: THERMAL DECOMPOSITION IN THE PRESENCE OF AIR MAY YIELD CARBON MONOXIDE AND/OR CARBON DIOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: VOLATILE ORGANIC CONTENT: 3.47 LB/GAL (416 G/L) ======================================================= HAZCOM Label ======================================================= Product ID: DURA CLAD ALKYD ENAMEL, BLACKS, STAIN 12-984 Cage: 75734 Company Name: DURON INC Street: 10406 TUCKER ST Zipcode: 20705-2297 Label Required IND: Y Date Of Label Review: 05/28/1998 Status Code: C Label Date: 05/28/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: INHALATION: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE. HIGH VAPOR CONCENTRATIONS MAY RESULT IN CNS D EPRESSION. SKIN: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING AND/OR DERMATITIS. EYES: CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION. INGESTION: CAN CAUSE GAS TROINTESTIONAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK, WHICHIS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). =======================================================
1
eyes_protection_mandatory
======================================================= Product ID: PM-102 Cage: 99696 Box: 85 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 99696 Box: 85 ======================================================= Contractor Summary ======================================================= Cage: 99696 Box: 85 ======================================================= Ingredients ======================================================= Cas: 1310-58-3 RTECS #: TT2100000 % Wt: 10-15 Other REC Limits: 2 MG/CUM (CEILING) OSHA PEL: C, 2 MG/M3 ACGIH TLV: C 2 MG/M3; 9192 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 68-11-1 RTECS #: AI5950000 % Wt: 1-5 Other REC Limits: 1 PPM OSHA PEL: S, 1 PPM ACGIH TLV: S, 1 PPM; 9192 ------------------------------ Cas: 7757-83-7 RTECS #: WE2150000 % Wt: 5-10 Other REC Limits: 5 MG/CUM (DUST) ------------------------------ Cas: 123-31-9 RTECS #: MX3500000 % Wt: 5-10 OSHA PEL: 2 MG/M3 ACGIH TLV: 2 MG/M3; 9192 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: HIGHLY CORROSIVE TO SKIN, EYES, MUCOUS MEMBRANES. INGESTION: CORROSION/PERFORATION OF ESOPHAGUS, STOMACH, DEATH. INHALATION: STRONG IRRITATION TO UPPER RESPIRATORY TRACT. SKIN: DERMATITIS. HYPERPIGMEN TATION, DEPIGMENTATION. EYES: KERATITIS, CORNEAL CHANGES. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: DIZZINESS, SENSE OF SUFFOCATION, MUSCULAR TWITCHING, COLLAPSE, NAUSEA, HEADACHE. First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NECESSARY. KEEP WARM/QUIET. EYES/SKIN: FLUSH W/PLENTY OF WATER. INGESTION: DON'T INDUCE VOMITING, GIVE LARGE QUANTITIES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VENTILATE AREA. WEAR PROTECTIVE CLOTHING. DON'T ALLOW MATERIAL TO DISCHARGE TO STORM/SANITARY SEWERS. NUETRALIZE UNTIL A NEUTRAL PRECIPITATE IS OBTAINED, SHOVEL/SCOOP INTO SUITABLE CONTAINER. Neutralizing Agent: SULFURIC & HYDROCHLORIC ACID Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS APPLICABLE TO THE PACKAGING, MANIFESTING, TRANSPORTING & DISPOSING OF CORROSIVE HAZARDOUS WASTE. NEUTRALIZED MATERIAL TO BE LANDFILLED MU ST NOT CONTAIN ANY FREE LIQUIDS. UN1760 Handling And Storage Precautions: PROTECT FROM AIR AND LIGHT INFILTRATION. STORE IN GLASS/OTHER NON-REACTIVE CONTAINER AWAY FROM STRONG ACIDS. Other Precautions: DON'T WEAR CONTACT LENSES. PRODUCT IS CORROSIVE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, CO2, DRY CHEMICAL Fire Fighting Procedures: FIREFIGHTERS SHOULD USE A SCBA W/FULL FACEPIECE UNDER POSITIVE PRESSURE & CHEMICAL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard: DURING EMERGENCY CONDITIONS/IF HEATED TO DRYNESS, THE RESIDUE MAY EMIT TOXIC FUMES OF SULFUR/NITROGEN OXIDES. CONTACT W/REACTIVE METALS MAY CAUSE EVOLUTION. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR, ATMOSPHERE SUPPLYING RESPIRATOR/AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. Ventilation: REQUIRED Work Hygienic Practices: REMOVE/LAUDNER CONTAMINATED CLOTHING BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.18 PH: 12.3 Solubility in Water: COMPLETE Appearance and Odor: CLEAR TO LIGHT YELLOW LIQUID, W/ROTTEN EGG ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AIR, LIGHT FILTRATION, HEAT, DRYNESS Materials To Avoid: STORNG ACIDS, ALUMINUM, TIN, ZINC Hazardous Decomposition Products: OXIDES OF SULFUR & NITROGEN, HYDROGEN GAS, QUINONE, CORROSIVE VAPORS Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: PM-102 Cage: 99696 Company Name: LORAL CORP LORAL DEFENSE SYSTEMS-ARIZONA DIVISION Street: 100 S LITCHFIELD RD PO Box: 85 Zipcode: 85340-0085 Label Required IND: Y Date Of Label Review: 04/07/1994 Status Code: C Label Date: 04/07/1994 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: Slight Hazard And Precautions: HIGHLY CORROSIVE TO SKIN, EYES, MUCOUS MEMBRANES. INGESTION: CORROSION/PERFORATION OF ESOPHAGUS, STOMACH, DEATH. INHALATION: STRONG IRRITATION TO UPPER RESPIRATORY TRACT. SKIN: DERMATITIS. HYPERPIGMEN TATION, DEPIGMENTATION. EYES: KERATITIS, CORNEAL CHANGES. TARGET ORGANS: EYES, SKIN, RESPIRATORY & DIGESTIVE TRACTS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:T30005 CAGE:09023 CAGE:09023 CAGE:14655 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNC ONSCIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5601 BLACK B5601L Preparer's Name:RANDY MARTIN CAGE:DO624 CAGE:47695 CAGE:53309 CAGE:DO624 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT DOES NOT CONTAIN HAZARDOUS INGREDIENTS AS DEFINED IN 29 CFR 1910.1200. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE KNOWN Effects of Overexposure:AT PRESENT, THERE ARE NO KNOWN SIGNS AND/OR SYMPTOMS CAUSED BY EXPOSURE TO THIS PRODUCT. Medical Cond Aggravated by Exposure:THERE ARE NO KNOWN MEDICAL CONDITIONS WHICH ARE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH WARM WATER FOR 15 MINUTES. IF IRRITATION PERSISTS, CONTACT A PHYSICIAN. SKIN CONTACT: WASH CONTAMINATED AREA WITH SOAP AND WATER FOR 15 MINUTES. INGESTION: DO NOT INDUCE VOMITI NG, CONTACT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, AND WATER Fire Fighting Procedures:NONE KNOWN Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ======================Handling and Storage ====================== Handling and Storage Precautions:ROTATE STOCK. STORE UNDER 80 F. DO NOT STACK CARTONS ON ENDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED WITH NORMAL APPLICATION. IF NEEDED, USE AN APPROVED OSHA/NIOSH CARTRIDGE RESPIRATOR. Work Hygienic Practices:ALWAYS WASH HANDS AFTER WORKING WITH THIS MATERIAL; USE GOOD HYGIENE PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.14 (H2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:PLIABLE RUBBERY SEALANT - ODORLESS Percent Volatiles by Volume:0.00 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY FORM CARBON DIOXIDE, CARBON MONOXIDE AND VARIOUS HYDROCARBON FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION OR BURIAL; CONSULT AND FOLLOW ALL LOCAL, STATE, AND FEDERAL COMPLIANCE REGULATIONS FOR YOUR AREA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:122 5572,EKTAPRINT 2 DEVELOPER,PART B CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROXYLAMINE SULFATE(CAS #10039-54) RANGE 15-20% DISSOCIATES FORMING SULFURIC ACID. CAS:10039-54-0 RTECS #:NC5425000 Fraction by Wt: 17.5% Ingred Name:AQUEOUS SOLUTION,NON-HAZARDOUS,UNIDENTIFIED COMPONENTS. Fraction by Wt: 82.5% ===================== Hazards Identification ===================== Effects of Overexposure:EYES:IRRITATION;SKIN:REPEATED CONTACT MAY CAUSE IRRITATION OR ALLERGIC SKIN REACTION. ======================= First Aid Measures ======================= First Aid:EYES,SKIN,MUCOUS MEMBRANES:FLUSH W LG AMTS H*2O AT LEAST 15 MIN;INHALE:REMOVE TO FRESH AIR,KEEP CALM;INGEST:RINSE MOUTH,GET MEDICAL ATTENTION;FOR EYES OR SKIN REACTION,GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT COMBUSTIBLE:USE MEDIA SUITABLE FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT. Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILLED MATERIAL.WEAR PROTECTIVE EQUIPMENT.STOP LEAK IF POSSIBLE WITHOUT RISK.SM SP:ABSORB W COMMERCIAL ABSORBENT & PUT IN APPR CONTAINERS.LG SP:CONTAIN W DIKE & TRANSFER TO APPR CONTAINE RS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW FIRE RISK AREA.PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT.STORE AWAY FROM STRONG ALKALI. Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W CHEMICAL.REMOVE & WASH CONTAMINATED CLOTHING.MAINTAIN STRICT HYGIENE.USE OF NON-ALKALINE(ACID) TYPE HAND CLEANER REDUCES ALLERGIC SKIN REACTION RISK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMENTS Ventilation:MECHANICAL(GEN./LOCAL EXHAUST) AS NECESSARY TO CONTROL MIST Other Protective Equipment:NORMAL FULL WORK CLOTHING COVERING ARMS,LEGS:NO SKIN CONTACT Supplemental Safety and Health MSDS FROM MFG DATED:78033;PART B OF FOUR PART PRODUCT,SAME STOCK NUMBER;NEW MSDS 80121;PH APPROX 2.2.KEY1:J6. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1.19 Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS AQUEOUS MIXTURE;ODORLESS Percent Volatiles by Volume:74 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALI Stability Condition to Avoid:NONE NOTED Hazardous Decomposition Products:SULFUR DIOXIDE MAY BE FORMED; CO*2 & CO POSSIBLE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN FULL ACCORD WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE,& LOCAL REGULATIONS.MFG SUGGESTS FLUSHING TO SEWER WITH EXCESS WATER.AFTER NEUTRALIZATION WITH SODIUM BICARBONATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CLEAR PENETRATING SEALER, 43-10 CAGE:33200 CAGE:33200 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYD RESIN Fraction by Wt: 31.5% Ingred Name:PETROLEUM DISTILLATE Fraction by Wt: 68.5% Other REC Limits:500 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCES SEVERE EYE IRRITATION, DRYING OF SKIN. EXCESSIVE INHALATION CAUSES HEADACHE, DIZZINESS, NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH MILD SOAP AND WATER AND APPLY SKIN CREAM. INHALATION: REMOVE TO FRESH AIR AND CALL PHYSICIAN. APPLY ARTIFICIAL RESPIRATION IF NECESSARY.INGEST: CALL MD IMMEAIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:102F,39C Lower Limits:0.8% Upper Limits:5.0% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:TREAT AS CLASS B FIRE. USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR A NIOSH/MSHA APPROVED RESPIRATOR. FLUSH WITH WATER INTO RETAINING AREA OR CONTAINER. AVOID EXPOSURE TO SPARKS, FIRE OR HOT METAL SURFACES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME. USE WITH ADEQUATE VENTILATION. AVOID PROLONGED OR REPEATED SKIN CONTACT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST. Other Protective Equipment:EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:315F,157C Vapor Pres:<80 Vapor Density:4.9 Spec Gravity:84.2 Evaporation Rate & Reference:0.1 (BUT ACE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, AMBER LIQUID. PETROLEUM DISTILLATE ODOR. Percent Volatiles by Volume:76.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXCESSIVEHEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL, INCINERATION UNDER SAFE AND SUPERVISED CONDITIONS. DISPOSE I/A/W FED, STATE, LOCAL REGS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STELLITE 21 (MODIFY) CAGE:57965 CAGE:55596 CAGE:57965 ============= Composition/Information on Ingredients ============= Ingred Name:IRON *95-4* CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0-5% Ingred Name:TUNGSTEN (INSOLUBLE), WOLFRAM *95-4* CAS:7440-33-7 RTECS #:YO7175000 Fraction by Wt: 0-15% ACGIH TLV:5 MG/CUM Ingred Name:COBALT (ANIMAL CARCINOGEN BY IARC - GROUP 2B) *95-4* CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 30-60% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0-2% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 0-5% ACGIH TLV:10 MG/CUM Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (KNOWN CARCINOGEN BY NTP; IARC CARC - GROUP 3) *95-4* CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 20-40% ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SUSPECTED ANIMAL CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *95-4* CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-5% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: 0-10% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES MAY CAUSE IRRITATION OF NOSE/THROAT/EYES. LONG TERM EXPOSURE TO WELDING FUMES CAN LEAD TO SIDEROSIS & AFFECT THE PULMONARY FUNCTION. ARC RAYS CAN INJURE EYES & BUR N SKIN. HEAT RAYS CAN INJURE EYES. ELECTRIC SHOCK CAN KILL. NOISE CAN DAMAGE HEARING. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:DIZZINESS, NAUSEA, DRYNESS, IRRITATION. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST TECHNIQUES RECOMMENDED BY THE RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLE & FLAMMABLES. ======================Handling and Storage ====================== Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS ARE < THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK. Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE THEMSELVES FROM WORK & GROUND & TO KEEP HIS HEAD OUT OF FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION DOES'NT KEEP EXPOSURE < TLVS. Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES < TLVS IN WORKERS BREATHING ZONE & GENERAL AREA. PROTECTER, APRON, HAT, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING. Supplemental Safety and Health PRODUCT IN NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES (SEE SUPPLEMENTAL DATA) Stability Condition to Avoid:(SEE SUPPLEMENTAL DATA) Hazardous Decomposition Products:COMPLEX OXIDES OF METALS, CO & CO2. OZONE & NITROGEN OXIDES MAY BE FORMED BY THE RADIATION FROM THE ARC. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DU000126 CAGE:0BA38 CAGE:0BA38 CO. CAGE:9V583 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9192 Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION;MAY CAUSE HEART IRREGULARATIES,UNCONSCIOUSNESS OR DEATH. SKIN/EYES;MILD IRRITATANT, TEARING BLURRING OR RASH.INHALATION; CNS DEPRESSION,DIZZINESS,HEADACHE,CONFUSION, INCOORDINATION AND LOSS OF CONSCIOUNESS. Effects of Overexposure:ALTERATION OF THE HEARTS ELECTRICAL SYSTEM,IRREGULAR PULSE, PALPATIONS OR IN ADEQUATE CIRCULATION. MAY LEAD TO ABNORMAL LIVER FUNCTION OR FATALITY. Medical Cond Aggravated by Exposure:CARDIOSVACULAR SYSTEM IRREGULARITIES, ======================= First Aid Measures ======================= First Aid:AVOID BREATHING VAPORS AND PROLONGED SKIN EXPOSURE, USE WITH SUFFICENT VENTILATION. .INHALATION;REMOVE TOFRESHAIR,KEEP CALM,GIVE CPR IF REQUIRED,IF BREATHING IS DIFFICULT GIVE OXYGEN,CALL APHYSCIAN. S KIN:FLUSH WITH PLENTY OF WATER,IF IRRITATION PERSIST SEEK MEDICAL ATTENTION.EYES;FLUSH WITH PLENTY OF COLD WATER CALL A PHYSCIAN. INGESTION;DO NOT INDUCE VOMITING CONSULT A PHYSCIAN IF NECESSARY ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NA Upper Limits:NA Extinguishing Media:AS APPROPIATE FOR IMMEDIATE AREA. Fire Fighting Procedures:USE WATER SPRAY TO COOL CONTAINERS, SCBA REQUIRED IF DRUMS RUPTURE AND CONTENTS ARE SPILL UNDER FIRE CONDITIONS. Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS,DECOMPOSITION MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA,DO NOT FLUSH INTO SEWERS ,DIKE AREA, COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS FOR RECOVERY OR DISPOSAL. USE SCBA FOR LARGE SPILLS. COMPLY WITH LOCAL, STAE AND FEDERAL R EGULATIONS. Neutralizing Agent:NA ======================Handling and Storage ====================== Handling and Storage Precautions:CLEAN, DRY AREA. DO NOT HEAT ABOVE 125F Other Precautions:NONE GIVEN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NORMAL VENTILATION. Ventilation:LOCAL SHOULD SUFFICE. Other Protective Equipment:NONE Work Hygienic Practices:PRUDENT Supplemental Safety and Health NA ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:118F,48C Vapor Pres:6.4 Vapor Density:2.9 Spec Gravity:1.57 Evaporation Rate & Reference:>1 Solubility in Water:0.02 Appearance and Odor:CLEAR, COLORLESS LIQUID WITH SLIGHT ETHERAL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI,OR ALKALINE EARTH METALS-POWERED AL, ZN, BE, ETC Stability Condition to Avoid:OPEN FLAMES AND HIGH TEMPERATURES. Hazardous Decomposition Products:HYDROCHLORIC AND HYDFLUORIC ACIDS AND POSSIBLY CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE A PERMITTED WASTE DISPOSAL FACILITY COMPLY WITH ALL LOCAL,STATE AND FEDERAL REGULATIONS, WASTE#F001 AND F002 MAY APPLY TO WASTE MATERIAL.
1
eyes_protection_mandatory
======================================================= Product ID: SEVIN 50% MANUFACTURING CONCENTRATE (SUPP DATA) Cage: 85926 ======================================================= Contractor Summary ======================================================= Cage: 85926 ======================================================= Ingredients ======================================================= WATER IF CONTACTED BY PESTICIDES. ANY PERS HEAVILY ----------------------------- WAITING FOR SYMPS TO OCCUR. BE ALERT FOR ----------------------------- VISION, COUGHING, TIGHTNESS OF CHEST, ----------------------------- POISINING MAY BE MISTAKEN FOR HEAT ----------------------------- WHILE FIRE FIGHTING SO AS NOT TO INGEST ----------------------------- ----------------------------- ----------------------------- ----------------------------- Cas: 63-25-2 RTECS #: FC5950000 CARBARYL). VP:0.002. MP:288F,142C. % Wt: 50 OSHA PEL: 5 MG/M3 ACGIH TLV: 5 MG/M3 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ ----------------------------- SCBA (AIR PACKS) IS ESSNTL FOR THOSE EXPOSED ----------------------------- POSS POISONING IF EXPOSED TO FUMES OR SMOKE ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: TLV:10 MG/M3 (MFR). CAUSES HEADACHE, NAUSEA, VOMITING, SWEATING, ABDOMINAL CRAMPS & PIN-POINT PUPILS. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: SKIN:REMOVE FROM EXPOS, SHOWER, PUT ON CLEAN CLOTHES & TAKE TO MD. EYES:IMMED FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINS. SEEK ASSIST FROM MD (FP N). INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP). CALL MD (FP N). INGEST:CALL MD IMMED (FP N). NOTE TO MD:CARBARYL IS A MOD, REVERSIBLE, CHOLINESTERASE AS INHIBITION. ATROPINE IS ANTIDOTAL. DO NOT USE 2-PAM, OPIATES OR ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COVER W/SWEEPING COMPOUND & SWEEP UP W/AS LITTLE DUST AS POSSIBLE. PUT IN WASTE CONTAINER. THEN FLUSH AREA W/LARGE VOLUMES OF WATER. Neutralizing Agent: QUICK LIME/CAUSTIC SODA. Waste Disposal Methods: MIX W/EQUAL AMOUNTS OF QUICKLIME OR WET THOROUGHLY W/STRONG CAUSTIC SODA & BURY IN A LANDFILL. DISPOSAL MUST BE IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS (FP N). Handling And Storage Precautions: STORE INDOORS IN A COOL PLACE. DO NOT REFRIGERATE. FOR INDUSTRY USE ONLY. AVOID BRTHG DUST. AVOID CONT W/SKIN & EYES. HARMFUL IF SWALLOWED/INHALED. Other Precautions: KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. AVOID CONTAMINATION OF FOOD, FEED, WATER SUPPLIES, STREAMS & PONDS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: COC Flash Point Text: SEE INGRED Lower Limits: SEE INGRED Extinguishing Media: USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES. USE FOAM (ALCOHOL, POLYMER OR ORDINARY) FOR LARGE FIRES. Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N). PROVIDE PROT OF EMPLOYEES & LOCAL RESIDENTS. EVAC RESIDENTS WHO ARE DOWNWIND OF FIRE. PVNT (SUPP DATA) Unusual Fire/Explosion Hazard: AVOID DISPERSION OF DUST IN AIR TO REDUCE POTENTIAL EXPLOSION HAZARD. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED DUST RESPIRATOR. Ventilation: LOCAL EXHAUST PREFERRED. MECHANICAL (GENERAL) ACCEPTABLE. Other Protective Equipment: EYE BATH & SAFETY SHOWER (MEETS ANSI DSGN STNDS). WEAR REGULAR LONG-SLEEVED WORK CLOTHING. Work Hygienic Practices: CHANGE TO CLEAN CLTHG DAILY. WASH HANDS & FACE BEFORE EATING. WASH THORO AFTER HNDLG. IN CASE OF PRLNGD EXPOS, Supplemental Safety and Health: MFRS TRADE NAME/PART NO:CARBARYL INSECTICIDE. FIRE FIGHT PROC:UNAUTHORIZED ENTRY TO FIRE AREA. HAVE A MED CHECK MADE OF EMPLOYEES THAT MAY HAVE BEEN EXPOSED TO FUMES OR OTHER CONTAM OF PRESTICIDES. NO TIFY LOCAL FIRE AUTHORITIES THAT FIREMEN SHOULD:WEAR PROT CLTHG OVER ======================================================= Physical/Chemical Properties ======================================================= HCC: T3 B.P. Text: DECOMPOSES M.P/F.P Text: SEE INGRED Vapor Pres: SEE INGRED Spec Gravity: 1.28@20C H2O=1 Solubility in Water: 40 PPM (CARBARYL) Appearance and Odor: WHITE, CREAM, TAN OR LIGHT-GRAY SOLID; ESSENTIALLY ODORLESS. Percent Volatiles by Volume: NIL ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: AVOID CONTAMINATION W/AQUEOUS MINERAL ACIDS OR ALKALIES. Hazardous Decomposition Products: THERMAL DECOMPOSITION OR BURNING MAY PRODUCE NITROGEN OXIDES, CARBON MONOXIDE &/OR CARBON DIOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:V84V60, SHER-WOOD CONVERSION VARNISH KEMVAR (SUPDAT) CAGE:54626 CAGE:54626 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA VP: 12 CAS:64742-48-9 Fraction by Wt: 3% OSHA PEL:300 PPM; 400 STEL ACGIH TLV:300 PPM Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA III) VP: 7.1 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1% OSHA PEL:100 PPM; 125 STEL ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA III)VP: 5.9 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 25% OSHA PEL:100 PPM; 150 STEL ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ALCOHOL; (ETHANOL) VP:44 CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 9% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ISOBUTYL ALCOHOL; (2-METHYL-1-PROPANOL) (SARA III) VP: 8.7 CAS:78-83-1 RTECS #:NP9625000 Fraction by Wt: 13% OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FORMALDEHYDE (SARA III) VP: 760 CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.8% OSHA PEL:0.75 PPM; 2 PPM STEL ACGIH TLV:0.3 PPM, C EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:VOLATILE ORGANIC COMPOUNDS: 4.16 LBS/GAL RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HNDLG/STOR PREC:HEATERS. TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CODE. USE APPRVD BONDING & GROUNDING PROC. KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNR (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PREC:OSHA STD FOR OCCUP EXPOS TO FORMALDEHYDE (29 CFR 1910.1048). USE ONLY W/ADEQ VENT. AVOID BRTHG VAP/ (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:SPRAY MIST. DO NOT GET IN EYE/ON SKIN. RTECS #:9999999ZZ Ingred Name:RESP PROT:LEVELS. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIOSH/MSHA FOR DUST WHICH MAY (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:BE GENERATED FROM THIS PROD, UNDERLYING PAINT, OR THE ABRASIVE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATING TO EYES, SKIN & RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH. HEADACHE, DIZZINESS, NAUSEA & LOSS OF COO RDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS & ITCHING OR BURNING (EFTS OF OVEREXP) Explanation of Carcinogenicity:FORMALDEHYDE:IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 211, 1987:GROUP 2A. NTP 6TH ANNUAL REPORT ON CARCINOGENS, (SUPDAT) Effects of Overexposure:HLTH HAZ:SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC:PRLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD FORMING, CARDIO-VASCULAR & R EPRODUCTIVE SYSTEMS. REPORTS HAVE ASSOCIATED RPTD/PRLNG OVEREXPOS TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTIONS IN SUSCEPTIBLE PERSONS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: F LUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:51.0F,10.6C Lower Limits:0.9% Upper Limits:19% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. DURING USE & UNTIL ALL VAPS GONE:KEEP AREA VENT. DO NOT SMOKE. EXTING ALL FLAMES, PILOT LIGHTS & (ING 8) Other Precautions:THIS PROD MUST BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATA L. BEFORE INITIAL USE, CONSULT (ING 11) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD, PROPERLY FITTED, FULL FACE/ HALF-MASK (W/GAS PROOF GOGG) RESP EFTIVE FOR PARTICULATES, ORG SOLV & FORMALDEHYDE/AIR SUPPLIED RESP MUST BE WORN UNLESS AIR MONITORING DEMONSTRATES VAP/ MIST CONCS ARE BELOW PERMISSIBLE (ING 13 Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, 107, 108. Other Protective Equipment:USE OF BARRIER CREAM ON EXPOSED SKIN IS RECOMMENDED. EYE PROT: & FULL LGTH FCSHLD . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:GLOSS RUBBED EFFECT. FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:REQS SPECIAL PREC. DURING EMER CNDTNS OVEREXPOS TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. EXPLAN OF CARCIN: 1991:ANTIC TO BE CARCIN. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:>172F,>78C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.96-0.97 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED Percent Volatiles by Volume:61-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERM APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE OF IN ACCORDANCE W/ FED, STATE & LOCAL REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CRAMER FLEX-I-COLD Preparer's Name:NOT PROVIDED CAGE:24719 CAGE:24719 Contract Num:MDA414-00-T-4269 CAGE:0FBL1 Contract Num:MDA414-01-T-1407 CAGE:0FBL1 Contract Num:MDA414-01-T-1878 CAGE:0FBL1 Contract Num:MDA414-00-T-1701 CAGE:0ZA42 Contract Num:MDA414-00-T-4061 CAGE:0ZA42 Contract Num:MDA414-00-T-1515 CAGE:60694 Contract Num:MDA414-99-T-3980 CAGE:0B3N4 ============= Composition/Information on Ingredients ============= Ingred Name:NO HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:EYES: MAY CAUSE TEMPORARY EYE IRRITATION. SKIN: IN SENSITIVE INDIVIDUALS MAY CAUSE SKIN IRRITATION. INGESTION: EXCESSIVE INGESTION MAY CAUSE EDEMA AND/OR TEMPORY ELEVATED BLOOD PRESSURE EFFECTS. TREAT FOR INGESTION OF SALT. NO ACUTE SYSTEMIC OR CHRONIC SYSTEMIC EFFECTS SHOULD BE EXPECTED. Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:EYES: MAY CAUSE TEMPORARY EYE IRRITATION. SKIN: IN SENSITIVE INDIVIDUALS MAY CAUSE SKIN IRRITATION. INGESTION: EXCESSIVE INGESTION MAY CAUSE EDEMA AND/OR TEMPORY ELEVATED BLOOD PRESSURE EFFECTS. TREAT FOR INGESTION OF SALT. NO ACUTE SYSTEMIC OR CHRONIC SYSTEMIC EFFECTS SHOULD BE EXPECTED. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:INHALATION: NOT APPLICABLE. SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. IF IRRITATION CONTINUES, CONTACT PHYSICIAN. INGESTION:PRODUCT CONTAINS SALT (SODIUM CHLORIDE). IF SWALLOWED, GIVE LARGE AMOUNTS OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NOT APPLICABLE. Fire Fighting Procedures:NOT APPLICABLE. Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:SPILLS SHOULD BE CONTAINED, COLLECTED INTO ABSORBENT MATERIAL AND DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. IS NOT CONSIDERED HAZARDOUS FOR WASTE DISPOSAL. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENTS. Other Precautions:NO DATA PROVIDED BY RESPONSIBLE PARTY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT APPLICABLE. Ventilation:NO SPECIAL REQUIREMENTS. Other Protective Equipment:NOT REQUIRED. Work Hygienic Practices:FOLLOW LABEL DIRECTIONS. Supplemental Safety and Health FLAGHOUSE P/N=032846. DILLARD AND DAKOTA SPORT P/N: 032746 ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:=4.C, 39.2F Spec Gravity:~1.2 Solubility in Water:MISCIBLE Appearance and Odor:BLUE-COLORED VISCOUS GEL; ESSENTIALLY ODORLESS. Percent Volatiles by Volume:75-80% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. IS NOT CONSIDERED HAZARDOUS FOR WASTE DISPOSAL. =================== MSDS Transport Information =================== Transport Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:LIQUITEX DAMAR/MATTE/RETOUCHING VARNISH CAGE:BINNE CAGE:BINNE ============= Composition/Information on Ingredients ============= Ingred Name:TURPENTINE CAS:8006-64-2 RTECS #:YO8400000 Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATING, DAMAGE, CONJUNCTIVITIS OR CORNEAL BURNS. SKIN: DERMATITIS OR CHEMICAL BURNS. CAN PENETRATE TO PRODUCE SYSTEMIC EFFECTS. INHALATION: HEADACHES, DIZZINESS, VERTIGO, CHEST PAIN, BRONCHIT IS, PULMONARY EDEMA, CYANOSIS MARCOMA, ACCELERATE PULSE. INGESTION: NAUSEA, SERIOUS ILLNESS, OR EVEN DEATH. Explanation of Carcinogenicity:NO Effects of Overexposure:SKIN: ALLERGENIC SENSITIZATION. INHALATION: PREDISPOSITION TO PNEUMONIA & NEPHRITIS, HEADACHES, DIZZINESS, VERTIGO, CHEST PAIN, BRONCHITIS, PULMONARY EDEMA, CYANOSIS MARCOMA, ACCELERATE PULSE. EYE: IR RITATING, DAMAGE, CONJUNCTIVITIS OR CORNEA BURNS. Medical Cond Aggravated by Exposure:RESPIRATORY DISORDERS, IMPAIRED FUNCTION, ALLERGENIC SENSITIZATION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/RUNNING WATER FOR 15 MINS. SKIN: WASH EXPOSED AREA W/WARM WATER & SOAP. INHALATION: MOVE VICTIM TO FRESH AIR. GET MED ATT. INGESTION: STOMACH PUMPING/LAVAGE MAY BE REQUIRED. GIVE EDIBLE O IL OR WHITE MINERAL OIL, 1 OR 2 GLASSESOF WATER OR MILK. DON'T INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:93F Extinguishing Media:CO2, DRY CHEMICAL, OR FOAM. WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:WHEN HEATED, MATERIAL IS A MODERATE FIRE/EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP RESIDUE W/AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTIO NS AS ABOVE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF THE REACH OF CHILDREN. AVOID CONTACT W/SKIN, BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH-CERTIFIED RESPIRATOR FOR HIGH EXPOSURE. Ventilation:USE WINDOW EXHAUST FAN TO REMOVE VAPORS/ASSURE ADEQUATE CROSS-VENTILATION Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:310-400F Vapor Density:>AIR Evaporation Rate & Reference:(ETHER = 1): <1 Percent Volatiles by Volume:99+% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ACIDIC MATERIALS, STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:383 BROWN ZENTHANE PC 08606TUY Preparer's Name:JANE FREEMAN CAGE:09225 CAGE:09225 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOBUTYL KETONE (SOLVENT) (SARA III) CAS:108-10-1 RTECS #:SA9750000 Fraction by Wt: 17.31% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PREPOLYMER OF HEXAMETHYLENE DIISOCYANATE Fraction by Wt: 30-40% Other REC Limits:.5 MG/M3;STEL 1MG/M3 Ingred Name:SILICA (PIGMENT) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 20-30% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:IRON OXIDE (PIGMENT) (NUISANCE DUST) CAS:1332-37-2 RTECS #:NO7380000 Fraction by Wt: 1.0-5.0% Other REC Limits:NONE SPECIFIED Ingred Name:METHYL ISOAMYL KETONE (SOLVENT) CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: 7.21% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 Ingred Name:XYLENE (SOLVENT) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5.75% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/STEL 150 PPM ACGIH TLV:100 PPM/STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRIVALENT CHROME (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 5.27% Other REC Limits:NONE SPECIFIED OSHA PEL:0.240 PPM, 0.5 MG/M3 ACGIH TLV:0.240 PPM, 0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:BUTYL ACETATE (SOLVENT) (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 3.970.2% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/STEL 200 PPM ACGIH TLV:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXAMETHYLENE DIISOCYANATE MONOMER CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.22% Other REC Limits:NONE SPECIFIED OSHA PEL:0.005 PPM ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:SKIN, EYE, RESP TRACT IRRIT. CHRONIC: RESPIRATORY SENSITIZATION & SKIN SENSITIZATION. DERMATITIS. PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE, LIVER AND KIDNEY DAMAGE. LUNG INJURY. Explanation of Carcinogenicity:IARC HAS LISTED SILICA AS A PROBABLE HUMAN CARCINOGEN. Effects of Overexposure:WATERING EYES, THROAT DRYNESS, COUGHING, HEADACHE, CHEST TIGHTNESS/BURNING SENSATION. HEADACHE, DIZZINESS, NAUSEA, RASH, ITCHING HIVES & SWELLING OF EXTREMITIES. Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY AILMENTS; CHEMICAL SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. NOTIFY PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH RUNNING WATER FOR AT LEAST 15 MIN, LIFTING EYELIDS. TAKE TO PHYSICIAN. SKIN: WASH AFFECTED AREAS WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. WASH BEFORE REUSE. CONSULT PHYSICIAN IF IRRITATION DEVELOPS/PERSISTS. INGESTION: CALL A PHYSICAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:60.0F,15.6C Autoignition Temp:Autoignition Temp Text:448C Lower Limits:1.0 Upper Limits:8.2 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT WITH SELF-CONTAINED BREATHING APPARATUS. DURING FIRE, IRRITATING/HIGHLY TOXIC GASES & SMOKE PRESENT FROM DECOMP/COMBUSTION PRODUCTS. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD.KEEP FROM HEAT/IGNIT SOURCE.CLSD CNTNR MAY EXPLODE W/HEAT,BURST WHEN CONTAM W/WATER. DONT APPLY TO HOT SRFCS.NEVER CUT,WELD NEAR DRUM-EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC NON-ESSENTL PEOPLE.REMOVE IGNIT SOURCE.VENT.AVOID BREATHING.COVER SPILL W/INERT ABSORB.POUR LIQ DECONTAM OVER SPILLAGE-ALLOW 10 MIN REACT TIME.COLLECT MAT'L IN OPEN CNTNR ADD DECONTAM SOLUTION.CO VER LOOSELY.WASH DOWN AREA W/DECONTAM,FLUSH W/H20. Neutralizing Agent:3-8%CONC AMMONIA,2%DETERGENT & 90-95%WATER. SOLUTN:TEGRITOL TMN-10-20%,WATER-80% ======================Handling and Storage ====================== Handling and Storage Precautions:DONT STORE ABOVE 120F OR BELOW 32F. STORE LRG QTY IN BLDGS DESIGNED TO COMPLY WITH OSHA 1910.106. KEEP FROM IGNIT SOURCE. KEEP CONTAINER CLOSED. Other Precautions:IF MOISTURE ENTERS, DONT RESEAL. DONT INGEST. GROUND CONTAINERS WHEN POURING. AVOID LIQUID FREE FALL >FEW INCHES. USE W/VENT & RESP EQUIP. EMPTIED CONTAINERS MAY RETAIN HZD RESIDUE. FOLLOW PRECAUTIONS . AVOID EYE, SKIN, OR CLOTHING CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AIRLINE RESPIRATOR UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW PEL. THEN, EITHER CHEMICAL CARTRIDGE RESPIRATORS OR AIRLINE RESPIRATORS REQUIRED. USE SAME PRECAUTIONS DURING MIXING OR ANY OPERAT IONS WHERE PAINT FUMES WOULD BE PRESENT. Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO KEEP BELOW PEL/TLV DURING MIXING, APPLICATION, CURING & REMOVE DECOMP PROD (WELD,CUT). Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN CONTACT AT A MINIMUM. Work Hygienic Practices:WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY BEFORE EATING OR SMOKING. SMOKE IN DESIGNATED AREAS ONLY. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:232 TO 298F Decomp Temp:Decomp Text:400F,204C Vapor Pres:15.00 Vapor Density:> AIR Spec Gravity:1.22 Viscosity:65-68 KU Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:REACTS WITH WATER Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR Percent Volatiles by Volume:50.90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOLS, GLYCOL ETHERS, AMINES Stability Condition to Avoid:CONTAMINATION WITH WATER Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION IS PREFERRED METHOD OF DISPOSAL. HAZARDOUS WASTE NUMBER: D001; CHARACTERISTIC: IGNITABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FIRELAB POWERSCRUB LATEX PAINT CAGE:0UH50 CAGE:0UH50 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE GLYCOL METHYL ETHER ACETATE) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 5-10% ACGIH TLV:100 PPM (MFR) Ingred Name:ETHYLENE GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <1% OSHA PEL:50 PPM, C ACGIH TLV:50 PPM,VAPOR, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIETHYLENE GLYCOL (MFR CAS# 111-46-1) CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: <1% ACGIH TLV:50 PPM (MFR) Ingred Name:VOLATILE ORGANIC COMPOUNDS: <100 G/L RTECS #:9999999VO Ingred Name:SUPP DATA: QTY (<0.5 PINT). CONSULT A PHYS IF STOM UPSET/NAUS OCCUR. IF LG AMTS OF MATL ARE INGESTED, & VICTIM (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:IS CONSCIOUS & NOT CONVULSING, INDUCE VOMIT & GET MED ATTN IMMED. DO NOT ATTEMPT TO GIVE ANYTHING BY MOUTH(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:TO AN UNCON PERSON. RTECS #:9999999ZZ Ingred Name:SOL IN H*2O: COMPLETE (AS COLLOIDAL DISPERSION) RTECS #:9999999ZZ Ingred Name:AMMONIUM POLYPHOSPHATE CAS:68333-79-9 Fraction by Wt: 25-30% Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:VINYL ACETATE/ACRYLIC RESIN Fraction by Wt: 15-25% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THERE IS CURRENTLY NO EVIDENCE OF ADVERSE EFTS RSLTG FROM ROUTINE EXPOSURE. PROLONGED SKIN CONTACT MAY CAUSE TRANSIENT REDDENING OF AFFECTED AREA. DIRECT CONTACT W/EYES CAUSES BURNING AND SWELLING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH WITH WATER. REMOVE CONTACT LENSES & FLUSH EYES W/WATER FOR @ LST 15 MIN INCL UNDER LIDS. CONSULT A PHYS IF IRRIT PERSISTS. SKIN: RINSE AFFECTED AREA W/WATER FOR @ LST 5 MIN. DO NOT WE AR CLTHG WHICH IS STILL WET W/MATL. CONSULT A PHYS IF IRRIT PERSISTS/IF SWELLING &/OR RASH DEVELOPS. INHAL: REMOVE TO FRESH AIR IF IRRIT OCCURS. CONSULT A PHYS IF IRRIT PERSISTS. INGEST: (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:NON-COMBUSTIBLE. USE FIRE EXTINGUISHING MEDIA AS MAY BE NEEDED FOR MATERIALS IN SURROUNDING FIRE. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. CONTRS MAY DEVELOP PRESS & BURST IF EXPOSED TO HEAT/FLAME. MOVE CONTRS FROM FIRE AREA IF POSS. COOL (SUPP DATA) Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:PLACE LEAKING CONTRS IN A WELL VENTD AREA. CONFINE SPILLED MATL & ABSORB ON SAND, SAWDUST, EARTH/OTHER AVAIL SOLIDS. SWEEP UP & PLACE IN A SUITABLE CONTR. RINSE MINOR SPILLS INTO SEWER IF PERMITTED BYFEDERAL, STATE, AND LOCAL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN UNCOATED METAL CONTAINERS. KEEP CONTAINER CLOSED. AVOID CONTACT W/SKIN AND EYES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE OF A NIOSH/MSHA APPROVED RESPIRATOR SUITABLE FOR CONTROL OF MISTS IS RECOMMENDED DURING SPRAY APPLICATION IF ADEQUATE VENTILATION CANNOT BE PROVIDED. Ventilation:LOCAL EXHAUST: USE EXHAUST FANS TO CONTROL MIST AND VAPOR IF NECESSARY. Other Protective Equipment:AS MAY BE NECESSARY TO PREVENT EXCESSIVE SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH(20C):7.9-8.3. FIRE FIGHT PROC:CONTRS WHICH HAVE BEEN EXPOSED TO FLAME BY SPRAYING THEM W/WATER. W/DRAW IMMED FROM AREA IF CONTRS BEGIN TO VENT/BECOME DISCOLORED DUE TO FIRE. MATL TO AVOID:DO NOT ST ORE/TRANSFER THIS MATL IN UNCOATED, STDMETAL CONTRS. FIRST AID PROC: SUBSTANCE IS NOT EXPECTED TO BE TOX IN SM (ING 8) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>230F,>110C Vapor Pres:<25@25C Vapor Density:<1 Spec Gravity:1.25-1.35 pH:SUPDAT Solubility in Water:ING 11 Appearance and Odor:WHITE (OR TINTED) VISCOUS LIQUID, CHARACTERISTIC ODOR Percent Volatiles by Volume:35-40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ALKALIS/ACIDS. AVOID CONT BETWEEN THIS MATL & UNPROTECTED METALS (EXCEPT STAINLESS STEELS).(SUPP DATA) Stability Condition to Avoid:DO NOT STORE CONTAINERS IN AREAS OF EXTREME HEAT/COLD. Hazardous Decomposition Products:COMBUST PROD: AMMONIA, CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE, NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE SOLIDIFIED WASTE/BURY IN A SUITABLE, APPROVED LANDFILL. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PT-4121,COMPONENT I Kit Part:Y Preparer's Name:TINBO LO CAGE:06341 CAGE:06341 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III).VP:22 MMHG AT 20C. CAS:108-88-3 RTECS #:XS5250000 Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PM ACETATE (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE).VP:3.7 MMHG AT 20C. CAS:108-65-6 RTECS #:AI8295000 Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPN Ingred Name:MEK (METHYL ETHYL KETONE) (SARA III).VP:71 MMHG AT 20C. CAS:78-93-3 RTECS #:EL6475000 Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (SARA III).VP:86 MMHG AT 20C. CAS:141-78-6 RTECS #:AH5425000 Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOLATILE ORGANIC COMPOUNDS: 544 G/L RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT KNOWN Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:REPEATED SKIN CONTACT MAY CAUSE SENSITIZATION AND SKIN RASH. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION:VAPORS MAY CAUSE DIZZINESS AND HEADACHE WHEN CONCENTRATIONS ARE HIGH. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:WASH AFFECTED AREAS WITH SOAP AND WATER. INHALATION:REMOVE TO FRRESH AIR.IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION.C ONSULT A PHYSICIAN IF REQUIRED IN ALL OF THE ABOVE CASES. INGESTION:CONTACT PHYSICIAN IMMEDIATELY,HAVE THIS MSDS AVAILABLE TO THEM. ===================== Fire Fighting Measures ===================== Flash Point:21.0F,-6.1C Lower Limits:1.4% Upper Limits:NOT KNOWN Extinguishing Media:USE WATER FOG,CARBON DIOXIDE,DRY CHEMICAL,FOAM,OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND TYPICAL PROTECTIVE CLOTHING.USE WATER FOG ON ALL CLOSED CONTAINERS & DRUMS TO KEEP COOL. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION.COVER WITH ABSORBENT MATERIAL AND PLACE IN WASTE CONTAINERS.SECURE GOOD VENTILATION.USE PROTECTIVE EQUIPMENT AND CLOTHING. Neutralizing Agent:NOT KNOWN ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE NEAR HEAT,SPARKS,OR FLAME.GROUND CONTAINERS WHEN POURING AND LIMIT FREE FALL TO A FEW INCHES TO PREVENT STATIC SPARK. Other Precautions:AVOID SPONTANEOUS COMBUSTION OF CONTAMINATED RAGS BY IMMERSION IN WATER AT END OF USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ORGANIC VAPOR RESPIRATOR UNDER NORMAL CONDITIONS.USE AN AIR SUPPLIED MASK FOR HIGHER CONCENTRATION.RESPIRATORS AND MASKS SHOULD BE NIOSH OR OSHA APPROVED. Ventilation:USE LOCAL EXHAUST OR OTHER ADEQUATE VENTILATION TO KEEP VAPOR OR MIST CONCENTRATIONS BELOW APPLICABLE STANDARDS. Other Protective Equipment:EYE WASH AND SAFETY SHOWERS SHOULD BE AVAILABLE. Work Hygienic Practices:AVOID PROLONGED SKIN CONTACT.DO NOT BREATHE SPRAY MIST. Supplemental Safety and Health NOT KNOWN ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:79 TO 295F Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:NOT KNOWN Vapor Density:>1 Spec Gravity:NOT KNOWN Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:LIQUID Percent Volatiles by Volume:46 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT,FIRES,HOT SURFACES,SPARKS,PROLONGED STORAGE AT ELEVATED TEMPERATURES. Hazardous Decomposition Products:ALDEHYDE,CARBON MONOXIDE,NITROGEN OXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE,AND LOCAL REGULATIONS.COORDINATE WITH SUPPORTING INSTALLATION AND/OR MACOM ENVIRONMENTAL OFFICE PRIOR TO DISPOSAL .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:23F1220 CAGE:01002 CAGE:01002 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIO US PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:MAY CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
======================================================= Product ID: DU HARDENERS, DU 6 Cage: 4D920 Box: 9 ======================================================= Contractor Summary ======================================================= Cage: 4D920 ======================================================= Ingredients ======================================================= Cas: 53880-05-0 % Wt: 20-25 OSHA PEL: 0.005 PPM (0.02 C) ACGIH TLV: 0.005 PPM, S ------------------------------ Cas: 28182-81-2 RTECS #: NQ9170000 % Wt: 30-35 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 110-43-0 RTECS #: MJ5075000 % Wt: 30-35 OSHA PEL: 100 PPM ACGIH TLV: 50 PPM ------------------------------ Cas: 64742-95-6 RTECS #: WF3400000 NAPHTHA) % Wt: 5-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 123-86-4 RTECS #: AF7350000 % Wt: 35-40 OSHA PEL: 150 PPM ACGIH TLV: 150 PPM/200STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 4098-71-9 RTECS #: NQ9370000 (ISOPHORONE DIISOCYANATE) (SARA 302) % Wt: <1 OSHA PEL: N/K (FP N) ACGIH TLV: 0.005 PPM ------------------------------ EXCESS EYE CONT. DRYNESS, ITCH, CRACKING, ----------------------------- CHRONIC: AVOID LONG TERM & RPTD CONT. ----------------------------- SENSATION OF THE NOSE, THROAT & LUNGS. ----------------------------- SYMPS SUCH AS CHEST TIGHTNESS, ----------------------------- FOLLOW RPTD EXPOS/SINGLE MASSIVE EXPOS & MAY BE DELAYED. ----------------------------- ----------------------------- EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. ----------------------------- PRODUCTS DURING WELDING OR FLAME-CUTTING. ----------------------------- NEOPRENE RUBBER. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: INGEST: HARMFUL/FATAL IF SWALLOWED. EYE: SEV IRRIT. SKIN: PRIMARY IRRIT. MAY BE HARMFUL IF ABSORBED THRU SKIN. PRLNG/RPTD CONT MAY CAUSE ALLERGIC SKIN RXN. INHAL: VAP & SPRAY MIST HARMFUL IF IN HALED. MAY CAUSE IRRIT &/ALLERGIC RESP RXN IN LUNGS. VAP IRRITATES EYES, NOSE & THROAT. RPTD EXPOS TO (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: HIGH VAP CONCS MAY CAUSE IRRIT OF RESP SYS & PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. SIGNS & SYMPS OF OVEREXP: E YE WATERING, HDCH, NAUS, DIZZ, & LOSS OF COORD ARE INDICATIONS THAT SOLV LEVELS ARE TOO HIGH. REDNESS, ITCH, Medical Cond Aggravated By Exposure: DO NOT USE IF YOU HAVE CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS, OR IF YOU HAVE EVER HAD A REACTION TO ISOCYANATES. First Aid: INGEST: IF SWALLOWED, GIVE 1-2 GLASSES OF WATER, BUT DO NOT INDUCE VOMIT. EYES: FLUSH IMMED W/PLENTY OF WATER FOR AT LEAST 15 MIN. SKIN: FLUSH IMMED W/PLENTY OF WATER FOLLOWED BY SOAP & WATER. INHAL:REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER SUPPORTIVE MEASURES AS REQUIRED. INGEST: CONT A POISON CONTROL CENTER, EMER ROOM/MD IMMED; HAVE MSDS INFORMATION AVAILABLE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST, VERMICULITE/OTHER ABSORB MATL & PLACE INT O CONTRS FOR DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WA STE MANAGEMENT FACILITY. Handling And Storage Precautions: DO NOT STORE ABOVE 120F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IC FLAMMABLE LIQUIDS. Other Precautions: IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT SYSTEM, READ THE MSDS FOR THE OTHER COMPONENT/COMPONENTS BEFORE BLENDING AS THE RESULTING MIX MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOU LD BE GROUNDED WHEN POURING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: 80.0F,26.7C Lower Limits: 1.1% Extinguishing Media: USE NFPA CLASS B EXTING (CARBON DIOXIDE, DRY CHEM/UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTING NFPA (SUP DAT) Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). WATER SPRAY MAY BE INEFFECTIVE BUT MAY BE USED TO COOL CLSD CONTRS TO PVNT PRESS BUILD-UP & POSS (SUP DAT) Unusual Fire/Explosion Hazard: KEEP CONTRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS, & OPEN FLAMES. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON (SUP DAT) ======================================================= Control Measures ======================================================= Respiratory Protection: WHERE OVERSPRAY IS PRESENT USE A POS PRESS AIR-SUPPLIED RESP (NIOSH TC-19C). WEAR RESP FOR THE WHOLE TIME OF SPRAYING & UNTIL ALL VAPS & MISTS ARE GONE. READ RESP MFR'S INSTRUCTIONS & LITERATURE CAREF ULLY TO DETERMINE THE TYPE OF Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP THE CONC OF INGS BELOW THE LOWEST SUGGESTED EXPOS Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER (FP N). WEAR IMPERMEABLE CLOTHING SUFFICIENT TO COVER EXPOSED Work Hygienic Practices: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES. Supplemental Safety and Health: EXTING MEDIA: CLASS IC FLAMM LIQ FIRES. FIRE FIGHT PROC: AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF. EXPLO HAZ: HOT SURF. TOX GASES MAY FORM WHEN PROD IS CONTACT ED BY FLAME/HOT SURF. DECOMP PROD: OXIDES OF NITROGEN, ISOPHORONE DIISOCYANATE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >255F,>124C Vapor Pres: 6.9 Vapor Density: HVR/AIR Spec Gravity: 1.0-1.1 Evaporation Rate & Reference: 87 (BUTYL ACETATE=100) Solubility in Water: 0% Appearance and Odor: VISCOUS LIQUID, W/AN ODOR CHARACTERISTIC OF THE SOLVENTS LISTED IN ING SECTION Percent Volatiles by Volume: 53.5 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS. AVOID WATER AND ALCOHOLS. Hazardous Decomposition Products: MAY PRDCE HAZ DECOMP PRODS WHEN HEATED. WELDING, BRAZING/FLAME-CUTTING MAY PRDCE FUME INCL: CARBON MONOXIDE, (SUP DAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DU HARDENERS, DU 6 Cage: 4D920 Company Name: PPG INDUSTRIES INC Street: 4325 ROSANNA DR Zipcode: 15101 Label Required IND: Y Date Of Label Review: 10/10/1996 Status Code: C Label Date: 10/10/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. CLASS IC. ACUTE: INGESTION: HARMFUL OR FATAL IF SWALLOWED. EYES: SEVERE IRRITATION. SKIN: PRIMARY IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. PROLONGED OR REPEATED CONTACT MAY CAUS E ALLERGIC SKIN REACTION. INHALATION: VAPOR AND SPRAY MIST HARMFUL IF INHALED. MAY CAUSE IRRITATION AND/OR ALLERGIC RESPIRATORY REACTION IN LUNGS. VAPOR IRRITATES EYES, NOSE AND THROAT. CHRONIC: REPEA TED EXPOSURE TO HIGH CONCENTRATIONS MAY CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. ALLERGIC RESPIRATORY REACTIONS MAY FOLLOW REPEATED EXPOSURE OR A SINGLE MASSIVE EXPOSURE AND MAY BE DELAYED. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPOXY SCRATCH COAT HARDENER Kit Part:Y CAGE:KCHCR CAGE:KCHCR ============= Composition/Information on Ingredients ============= Ingred Name:METHYLAMINE, M-PHENYLENEBIS-; (ALIPHATIC AMINE) CAS:1477-55-0 RTECS #:PF8970000 Fraction by Wt: <50% Ingred Name:MODIFIED ALIPHATIC POLYAMINES CONSISTING OF CAS NUMBERS 90-72-2 AND 112-57-2 Fraction by Wt: <50% ACGIH TLV:5 PPM (MFR) Ingred Name:INERT FILLERS CAS:67762-90-7 Fraction by Wt: <10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL,RAT): 2250 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: STRONG IRRITANT. INHALATION: VAPORS VERY IRRITATING. EYE: STRONG IRRITANT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH AFFECTED AREA WITH LARGE AMOUNTS OF WATER AND SOAP. WASH CONTAMINATED CLOTHES BEFORE REUSE. GET MEDICAL ATTENTION. INGESTION: GIVE TWO GLASSES OF WATER TO CONSCIOUS PERSON. DO NOT INDUCE VO MITING. GET MEDICAL ATTENTION. INHALATION: REMOVE VICTIM TO FRESH AIR & PROVIDE OXYGEN IF BRTHG IS DFCLT. GIVE ARTF RESP IF NOT BRTHG. GET MED ATTN. EYE: FLUSH W/WATER FOR AT LST 15 MINS. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:USE WATER, CARBON DIOXIDE, FOAM OR DRY POWDER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. AVOID BRTHG SMOKE, FUMES & DECOMP PRODS. Unusual Fire/Explosion Hazard:HAZARDOUS GASES PRODUCED IN FIRE ARE CARBON MONOXIDE, AMMONIA AND HYDROGEN CYANIDE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT WITH ABSORBENT MATERIAL AND TRANSFER TO SECURE CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE NEAR OXIDIZING AGENTS. STORE IN COOL, DRY AREA. RECOM MAX STORAGE 100F. TYPICAL SHELF LIFE: INDEFINITE IN TIGHTLY SEALED CONTAINERS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR CANISTER RESPIRATOR IF VAPORS IN HIGHER CONCENTRATIONS ARE PRESENT. Ventilation:LOCAL EXHAUST. Other Protective Equipment:ADEQUATE CLOTHING AND EYEWASH STATION. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VAPOR PRESSURE: 0.4 @ 20C/68F. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:420F,216C Vapor Pres:SUPP DATA Spec Gravity:1.08 25C/77F Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS TO LIGHT YELLOW WITH AMINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZING AGENTS. Stability Condition to Avoid:KEEP AWAY FROM OXIDIZING MATERIALS. Hazardous Decomposition Products:DECOMPOSITION MAY PRODUCE FUMES, SMOKE, OXIDES OF CARBON AND/OR HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PROPERLY IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CASCADE (AUTOMATIC DISHWASHING DETERGENT) CAGE:04547 CAGE:04547 CAGE:74188 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM MONOHYDROGEN PHOSPHATE HEPTAHYDRATE (2:1:1:7); (SODIUM PHOSPHATE) CAS:7682-85-6 RTECS #:WC4600000 Ingred Name:PEROXYDICARBONIC ACID, DISODIUM SALT;(SODIUM CARBONATE) CAS:3313-92-6 RTECS #:SD9920000 Ingred Name:NONIONIC SURFACTANTS Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT;(CHLORINE BLEACH) CAS:7681-52-9 RTECS #:NH3486300 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SILICIC ACID (H2SIO3), DISODIUM SALT;(SODIUM SILICATE) CAS:6834-92-0 RTECS #:VV9275000 Ingred Name:SODIUM SULFATE (2:1) CAS:7757-82-6 RTECS #:WE1650000 Ingred Name:SUDS CONTROL AGENT Ingred Name:COLORANT Ingred Name:PERFUME, TYPE UNSPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST:MAY CAUSE VOMITING AND TRANSIENT, MODERATE GI IRRITATION. EYE:MAY CAUSE MODERATE, TRANSIENT IRRITATION. INHAL:HEAVY OR PROLONGED EXPOSURE TO DUST MAY CAUSE TRANSIENT RESPIRATORY TRACT IRRITATIO N. SKIN:TRANSIENT IRRITATION WITH PROLONGED EXPOSURE TO CONCENTRATED MATERIAL. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:INGEST:MAY RESULT IN NAUSEA, VOMITING, AND/OR DIARRHEA. EYE:MAY CAUSE STINGING, TEARING, ITCHING, SWELLING AND/OR REDNESS. INHAL:MAY CAUSE COUGHING, SORE THROAT, WHEEZING, OR TRANSITORY SHORTNESS OF B REATH. SKIN:CONTACT WITH CONCENTRATED MATERIAL MAY BE DRYING OR TRANSIENTLY IRRITATING TO SKIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DRINK A GLASSFUL OF WATER OR MILK. EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. INHAL:LEAVE DUSTY AREA. SKIN:IF PROLONGED CONTACT OCCURS, RINSE THOROUGHLY WITH WATER. IF SYMPTOMS PERSIST OR RE OCCUR, GET MD. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, WATER, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT & PLACE IN SUITABLE CONTAINER & DISPOSE AS DRY SCRAP, OR FLUSH WITH WATER DOWN ACCEPTABLE SEWER (CONTAINS BIODEGRADABLE SURFACTANTS). PREVENT SPILLS FROM REACHING A WATERWAY. PREVENT HEAVY EXP OSURE TO DUST WITH NIOSH/MSHA APPROVED DUST MASK. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO UNUSUAL PRECAUTIONS NECESSARY. AVOID CONTACT OF CARTONS WITH MOISTURE TO AVOID DISPENSING PROBLEMS. Other Precautions:CAUTION:HARMFUL IF SWALLOWED. EYE IRRITANT. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WITH NORMAL USE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NORMAL/GENERAL DILUTION VENTILATION IS ACCEPTABLE. Other Protective Equipment:NONE REQUIRED WITH NORMAL USE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:1.0 G/CC Solubility in Water:APPRECIABLE Appearance and Odor:LIGHT BLUE GRANULAR AGGLOMERATE W/LOW LEVEL WHITE GRANULAR ADMIX. PERFUMED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL IS TO BE PERFORMED IN COMPLIANCE W/ALL LOC, STATE & FED REGS. SMALL OR HOUSEHOLD QTYS MAY BE DISPOSED OF IN REFUSE OR IN SEWER. LARGER QUANTITIES OF CONTAMINATED OR WASTE MATL MAY BE DISPOSED OF IN MUNICIPAL LANDFILL WHERE ALLOWEDBY LAW.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANAEROBIC ADHESIVE/SEALANT Preparer's Name:ENVIRON. HEALTH & SAFETY CAGE:4Z400 CAGE:4Z400 ============= Composition/Information on Ingredients ============= Ingred Name:"NOT HAZARDOUS" Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ORGANIC PEROXIDE HAS BEEN REPORTED TO CAUSE TUMORS IN EXPERIMENTAL ANIMALS WHEN INJECTED UNDER THE SKIN. THE LOW CONCENTRATION (<5%) CONTAINED IN THE PRODUCT SHOULD PRESENT NO DANGER WHEN USED PROPERL Y UNDER NORMAL CONDITIONS. Effects of Overexposure:PROLONGED SKIN CONTACT MAY CAUSE DERMATITIS IN SENSITIVE INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:SKIN AND EYES: FLUSH WITH WATER. INGESTION: KEEP CALM, REMOVE TO FRESH AIR. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ASSISTANCE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>250F,>121C Autoignition Temp:Autoignition Temp Text:> 350F Extinguishing Media:CO2, FOAM, DRY CHEMICALS Fire Fighting Procedures:AIR MASK AND PROCEDURES FOR FIGHTING CHEMICAL FIRES. Unusual Fire/Explosion Hazard:CONTAINS ORGANIC PEROXIDE ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE GOOD VENTILATION. AVOID EYE AND SKIN CONTACT. SOAK UP SPILL WITH EARTH, SAND, OR ABSORBENT PRODUCT (ZORBAL). RECOVER IN CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 80 F FOR PROLONGED SHELF LIFE. STORE IN ORIGINAL CONTAINER. Other Precautions:AVOID PROLONGED SKIN CONTACT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECESSARY, BUT PRODUCT SHOULD BE USED IN AREAS OF GOOD VENTILATION. Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Decomp Temp:Decomp Text:>350F,>177C Vapor Pres:< 5 @ 30 F Spec Gravity:1.1 Viscosity:20 CPS Solubility in Water:PARTIAL Appearance and Odor:RED LIQUID, LOW ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AND REDUCING AGENTS Hazardous Decomposition Products:CO, CO2, NITROUS OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH STATE, FEDERAL, AND LOCAL ANTI-POLLUTION AND WASTE DISPOSAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:B2, AR GROUT CAGE:CCURC CAGE:CCURC ============= Composition/Information on Ingredients ============= Ingred Name:PORTLAND CEMENT CAS:65997-15-1 RTECS #:VV8770000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SAND (SILICA) CAS:14804-60-7 Ingred Name:PIGMENTS (CONTAINING 1 OR MORE OF THE FOLLOWING CAS NUMBERS:57124-00-1, 1309-37-1, 1317-61-9, 12713-03-0, (ING 4) Ingred Name:ING 3:1308-28-9, 1333-56-4, 13463-67-7, 57455-37-5) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:PORTLAND CEMENT MORTAR CAN DRY ON SKIN AND CAUSE ALKALI BURNS. DUST CAN IRRITATE EYES AND UPPER RESPIRATORY SYSTEM. CHRONIC:DUST CAN CAUSE INFLAMMATION OF INTERIOR OF NOSE & EYES. PROLONGED EXPO SURE TO DUST OVER TLV MAY CAUSE SCARRING OF LUNGS, AND DELAYED LUNG INJURY (SILICOSIS). Explanation of Carcinogenicity:CRYSTALLINE SILICA QUARTZ GROUP 2A IARC, ANTICIPATED TO BE CARCINOGEN(NPT) Effects of Overexposure:SHORTNESS OF BREATH, COUGHING, REDDINING OF EYES. Medical Cond Aggravated by Exposure:HYPERSENSITIVE INDIVIDUALS MAY DEVELOP ALLERGIC DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES:IRRIGATE WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH EXPOSED AREAS WITH WATER. INHAL:REMOVE TO FRESH AIR. INGEST:MORTAR MAY SET AND CAUSE BOWEL OBSTRUCTION. CONSULT PHYSICAIN. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SPILLS USING DUSTLESS METHOD, MATERIAL CAN BE RETURNED TO CONTAINER FOR LATER USE, WEAR NIOSH/MSHA APPROVED RESPIRATOR FOR SILICA DUST WHEN CLEANING AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:ELIMINATE EXPOSURE TO DUST, USE NIOSH/MSHA APPROVED MASK FOR SILICA DUST, IF FRESHLY MIXED MORTAR GETS INTO EYES OR CONTACTS SKIN - FLUSH IMMEDIATELY AND REPEATEDLY WITH WATER AND CONTACT MD IMMEDIATE LY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR SILICA DUST. Ventilation:LOCAL EXHAUST. Other Protective Equipment:BARRIER CREAM, BOOTS AND CLOTHING SHOULD PROTECT SKIN FROM DUST AND WET MORTAR. Work Hygienic Practices:WORKERS SHOULD SHOWER WITH SOAP AND WATER AFTER WORKING WITH MORTAR. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.5 Solubility in Water:<1% Appearance and Odor:GRAY, WHITE OR COLORED POWDER WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO2, SILICON TETRA FLUORIDE (W/ HYDROFLUORIC ACID). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . MORTAR CAN BE DISPOSED OF AS COMMON WASTE, UNRESTRICTED SANITARY LAND FILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NEOPRENE ADHESIVE, 77-198 Preparer's Name:MERLE ELLIS CAGE:IDIAD CAGE:IDIAD ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXANE ISOMERS RTECS #:MO3860000 OSHA PEL:500 PPM;1000 STEL ACGIH TLV:500 PPM;1000 STEL Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 33% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 17% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INGEST:UNLIKELY ROUTE OF EXPOSURE. PERSONS INGESTING PRODUCT MAY EXPERIENCE NUMBNESS, RESPIRATORY TRACT IRRITATION AND MUSCLE WEAKNESS. SKIN:PRODUCT IS DEFATTING AGENT AND CAN CAUSE DERMATITIS O R IRRITATION UPON PROLONGED OR REPEATEDCONTACT. EYE:MAY CAUSE IRRITATION. INHAL:OVEREXPOSURE TO PROD (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:MAY CAUSE LIGHTHEADEDNESS, NAUSEA, GIDDINESS OR BREATHING DIFFICULTIES. SEVERE OVEREXPOSURE MAY CAUSE UNCON & ASPHYXIATION. CHRONIC:DAMAGE TO CENTRAL NERVOUS SYSTEM, LIVER, AND KIDNEYS COULD RESULT FROM CHRONIC CONTINUAL OVEREXPOSURE. Medical Cond Aggravated by Exposure:CENTRAL AND PERIPHERAL NERVOUS SYSTEM, PRE- EXISTING EYE AND SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT. GET MD IMMED. SKIN:PROMPTLY WASH W/SOAP & WATER OR SKIN CLEANSER. IF IRRIT PERSISTS, GET MD. IF PROD SOAKS THRU CLTHG, REMOVE CLTHG IMMED & WASH AFFECTED AREA. WET CLTHG SH OULD BE PLACED IN A SAFETY CNTNR & NOT REWORN UNTIL CLTHG HAS BEEN LAUNDERED. EYE:WASH IMMED W/LARGE AMTS OF WATER FOR AT LEAST 15 MINS, LIFTING UPPER & LOWER LIDS OCCASIONALLY. IF IRRIT (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<0F,<-18C Lower Limits:1.2% Upper Limits:13% Extinguishing Media:CO2, DRY CHEMICAL, FOAM, HALON. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:COOL DRUMS WITH WATER SPRAY TO PREVENT PRESSURE EXPLOSION. VAPORS MAY IGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE AND ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA OF SPILL OR LEAK. FOR SMALL QUANTITIES ABSORB ON PAPER TOWELS. LARGE QUANTITIES SHOULD BE RETAINED BY DIKING AND ABSORBED WITH ABSORBENT MA TERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP PRODUCT CONTAINERS COOL, DRY AND AWAY FROM SOURCES OF IGNITION. USE AND STORE THIS PRODUCT WITH ADEQUATE VENTILATION. Other Precautions:THIS PRODUCT SHOULD NOT BE ALLOWED TO ENTER A CONFINED SPACE, SUCH AS A SEWER, BECAUSE OF THE POSSIBILITY OF VAPOR BUILD-UP, POSSIBLY ALLOWING AN EXPLOSION. PERSONS SHOULD AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS USE A NIOSH/MSHA APPROVED TO PREVENT OVEREXPOSURE. USE EITHER A SCBA OR ORGANIC VAPOR RESPIRATOR IN ACCORDANCE WITH 29 CFR 1910.134. Ventilation:LOC EXHAUST GEN REQ TO REDUCE EXPOS BELOW OSHA PEL. MECH (GEN) IF ROOM AIR NOT RECIRCULATED, BUT EXHAUSTED, MAY BE ADEQ. Other Protective Equipment:IMPERVIOUS CLOTHING. Work Hygienic Practices:WASH HANDS WITH SOAP & WATER OR A SKIN CLEANSER BEFDORE EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. Supplemental Safety and Health FIRST AID PROC:PERSIST AFTER WASHING, GET MD. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS PRODUCT. INHAL:REMOVE TO FRESH AIR IMMEDIATELY. IF BREATHING STOPS, BEGIN ARTIFICIAL RESPIRATION. KEEP WARM & AT REST. GET MD IMMEDIATELY. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:131F,55C Vapor Pres:140 @ 20C Vapor Density:>1.0 Spec Gravity:0.812 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:PARTIALLY Appearance and Odor:YELLOW, BLUE IN COLOR. SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND ACIDS. Stability Condition to Avoid:FLAME, SPARK OR EXTREME HEAT. Hazardous Decomposition Products:CO, CO2 & HCL. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAMINATED ABSORBENT MATERIAL OR WASTE PRODUCT MUST BE DISPOSED OF IN ACCORDANCE WITH REGULATIONS IN THE RESOURCE CONSERVATION AND RECOVERY ACT AND/OR STATE, LOCAL, FEDERAL, OR EPA REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:93-77161 SYNTHETIC ENAMEL, TRACTOR & IMPLEMENT ENAMELS Preparer's Name:T R LOUER CAGE:23027 CAGE:90227 CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA, C8&10 AROMATIC HYDROCARBON *96-4* CAS:64742-95-6 RTECS #:WF3400000 Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM *96-4* CAS:64742-94-5 RTECS #:WF3100000 Ingred Name:FERRIC HEXACYANOFERRATE Ingred Name:LEAD CHROMATE(VI) OXIDE, CR-O4-PB. O-PB; (HUMAN CARCINOGEN BY IARC GROUP-1, ANIMAL CARCINOGEN BY NTP) *96-4* CAS:18454-12-1 RTECS #:OF9800000 Fraction by Wt: 6% OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM Ingred Name:LEAD NAPHTHENATE CAS:61790-14-5 RTECS #:QK9150000 Fraction by Wt: 0.4% Other REC Limits:0.10 MG/CUM ACGIH TLV:0.15 MG/CUM INORG PB Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS *96-4* CAS:64742-88-7 Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-4* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE *96-4* CAS:64742-89-8 OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-4* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC CONTENT: 4.4 LBS/GAL RTECS #:9999999VO Ingred Name:SOYBEAN OIL, POLYMER W/GLYCEROL & PHTHALIC ANHYDRIDE *96-4* CAS:66070-61-9 Ingred Name:LINSEED OIL, POLYMER WITH CONJUGATED SAFFLOWER OIL, GLYCEROL, ISOPHTHALIC ACID, ALKYD RESIN C CAS:68213-52-5 Ingred Name:P-TERY-BUTYLBENZOIC ACID, PENTAERYTHRITOL, PHTHALIC ANHYDRIDE, SOYBEAN OIL POLYMER CAS:68083-25-0 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INGESTION: GASTROINTESTINAL DISTRESS. INHALATION: NOSE & THROAT IRRITANT. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY LEAD TO PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. EYES: IRRITATION/BURNING. SKI N: REPEATED/PROLONGED CONTACT MAY CAUSEIRRITATION, DERMATITIS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:GI DISTRESS, IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZIESS, LOSS OF COORDINATION, BURNING, DISCOMFORT ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:<100F Lower Limits:0.8 Upper Limits:23 Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT W/SCBA. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP. Unusual Fire/Explosion Hazard:WHEN HEATED >FLASHPOINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPS 120F. KEEP AWAY FROM HEAT, SPARKS & FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. Other Precautions:DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O A NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. OBSERVE LABEL PRECAUTIONS. DON'T BREATHE VAPORS/MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR PROPERLY FITTED VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA (TC-23C) FOR USE W/PAINTS DURING APPLICATION/UNTIL ALL VAPORS & SPRAY MISTS ARE EXHAUSTED. CONFINED SPACES: WEAR A POSITIVE-PRE SSURE, SUPPLIED-AIR RESPIRATOR (TC-19C). Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS. Other Protective Equipment:COVERALLS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING/SMOKING. Supplemental Safety and Health % VOLATILE BY VOLUME: 59.7-69.5%. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:129-734F Vapor Density:>1 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Percent Volatiles by Volume:(SUPP) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, SPARKS, FLAME & OTHER IGNITION SOURCES Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IAW/LOCAL, STATE & FEDERAL REGULATIONS. DON'T INCINERATE IN CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:146 4726 DEKTOL DEVELOPER(SINGLE POWDER);WORK SOL,KAN 471363 CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA III) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:P-METHYLAMINOPHENOL SULFATE (METOL) CAS:55-55-1 RTECS #:SL8650000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PEL FOR HYDROQUINONE IS 2MG/M3 TWA Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:LOW HAZARD FOR EXPECTED HANDLING.MAY CAUSE GI TRACT IRRITATION.INHAL:LOW HAZARD EXPECTED FOR NORMAL SERVICE.MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:SKIN:ALLERGIC SKIN REACTIONS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR EYE CONDITIONS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:GET PROMPT QUALIFIED MEDICAL ATT ENTION.IF CONSCIOUS,INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:MANUFACTURER STATES NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIEL IN AN APPROPRIATE CONTAINER FOR DISPOSAL.FOR SMALL SPILLS,FLUSH TO SEWER WITH PLENTY OF WATER. Neutralizing Agent:WEAK ACID(EG.VINEGAR). ======================Handling and Storage ====================== Handling and Storage Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID SKIN AND EYE CONTACT. Other Precautions:USE WITH ADEQUATE VENTILATION.USE OF AN ACIDIC HAND CLEANER WILL MINIMIZE THE POSSIBILITY OF AN ALLERGIC SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED IN NORMAL SERVICE. Ventilation:USE GENERAL DILUTION VENTILATION WITH 10 AIR CHANGES/HOUR. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health KEY1;C2. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:>100.C, 212.F Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.04-1.06 pH:10 Solubility in Water:COMPLETE Appearance and Odor:LIQUID;LIGHT YELLOW;ODORLESS. Percent Volatiles by Volume:90-95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MANUFACTURER STATES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,SULFUR DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TOUGH COAT ALKYD ENAMEL, 727-3311 FLAT BLACK CAGE:MART2 CAGE:MART2 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS). VP: 2.0 CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 39% OSHA PEL:100 STEL (MFR) ACGIH TLV:100 STEL (MFR) Ingred Name:SOLVENT NAPHTHA, PETROLEUM, MEDIUM ALIPHATIC; (MINERAL SPIRITS, 140-FLASH). VP: 2.0 CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 39% OSHA PEL:100 STEL (MFR) ACGIH TLV:100 STEL (MFR) Ingred Name:TALC (POWDER) CONTAINING NO ASBESTOS CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 27% OSHA PEL:20 MPPCF Z-3 ACGIH TLV:2 MG/M3 RDUST; 9495 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 2% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9495 Ingred Name:VOLATILE ORGANIC COMPOUNDS (VOC) - 3.73 LBS/GAL RTECS #:9999999VO Ingred Name:WASTE DISP METH:LOCAL REGULATIONS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), OSHA PEL 15 MG/M3 (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:(TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION). KEEP AWAY FROM HEAT, SPARKS, & OPEN FLAME. VAPS WILL (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENT-DO NOT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:SMOKE-EXTINGUISH ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN OFF STOVES, ELECTRIC TOOLS & APPLICANCES, & (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODES. USE APPRVD BONDING & GROUNDING PROC. KEEP CNTNR CLOSED (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:KEEP OUT OF THE REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CONTENTS CAN BE HARMFUL OR FATAL. RTECS #:9999999ZZ Ingred Name:RESP PROT:RESP (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:VENT:LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. RATS EXPOSED TO TITANIUM DIOXIDE DUST (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCONSCIOUSNESS & POSS DEATH. SIGNS & SYMPS OF OVEREXP: HDCH, DIZZ, NAUS, & LOSS OF COORDINATION ARE I NDICATION OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 24-27, 1995: GROUP 2B. Effects of Overexposure:HLTH HAZ:EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNGD OVEREXP TO SOLV INGS IN ING SECTION MAY CAUSE ADVERSE EFTS TO THE LIVER & URINARY SYS. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS & MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE IS NO (ING 17) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATERFOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>99F,>37C Lower Limits:1.0% Upper Limits:6.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD CNTNRS (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. Other Precautions:THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED 'AS DUST' IN ING SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF THE DRIED FILM. IF NO SPECIFIC DU STS ARE LISTED IN ING SECTION, (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN ING SECTION. WHEN SANDING/ABRADING THE DRIED FIL M, WEAR A NIOSH APPRVD DUST/MIST(ING 15) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF THE EXPOS TO MATLS IN ING SECTION IS MAINTAINED BELOW APPLICABLE EXPOS (ING 16) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:HOT SURF REQ SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE A HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAINMED ATTN. MATLS TO AVOID:DANGEROUSLY INCRD PRESS IN CLSD CNTNRS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>284F,>140C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:1.12 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FOR CHROME ALUMINIUM ONLY-CONTAM W/H*2O, ACIDS/ALKALIS CAN CAUSE EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZS AS DEFINED UNDER THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM THE APPLIC EPA HAZS WASTE NUMBER. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD C NTNR. DISPOSE OF I/A/W/FED, STATE & (ING 6)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIRA-SHINE FLOOR FINISH, 1-2, CLASSIC 220 HI (SUPDAT) CAGE:HO777 CAGE:63793 CAGE:HO777 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLATE COPOLYMERS CAS:63744-68-3 Ingred Name:ETHYLENE COPOLYMER CAS:9010-77-9 Ingred Name:OXIDIZED POLYETHYLENE CAS:68441-17-8 Ingred Name:MODIFIED PENTAERYTHRITOL ESTER OF ROSIN Ingred Name:ETHANOL, 2-(2-METHOXYETHOXY)-; (DIETHYLENE GLYCOL MONOMETHYL ETHER) CAS:111-77-3 RTECS #:KL6125000 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE LISTED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT WITH EYES MAY CAUSE SOME DISCOMFORT, REDNESS AND MODERATE IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE REDNESS AND DRYING. INGESTION: MAY RESULT IN SLIGHT MUCOSAL DAMAGE ALONG WITH STOMACH CRA MPS, NAUSEA AND/OR VOMITING. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE NOTED. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CALL PHYSICIAN. SKIN: WASH THOROUGHLY WITH WATER. IF IRRITATION PERSISTS, CALL PHYSICIAN. INGESTION: IMMEDIATELY DRINK LARGE QUA NTITIES OF WATER. CONTACT PHYSICIAN. INHALATION: REMOVE FROM EXPOSURE. SUPPORT BREATHING (GIVE ARTIFICIAL RESPIRATION/OXYGEN) . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER MIST. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH DAMP MOP, SPONGE OR RAGS AND DISCARD. FLUSH AREA WITH CLEAN WATER IF NECESSARY. AVOID DISCHARGE INTO OPEN WATERWAYS. Neutralizing Agent:NONE LISTED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT MIX WITH STRONG ACIDS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:NONE LISTED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST. Other Protective Equipment:NONE. Work Hygienic Practices:NONE LISTED BY MANUFACTURER. Supplemental Safety and Health TRADE NAME/PART #: SOLIDS FLOOR FINISH. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:210F,99C Melt/Freeze Pt:M.P/F.P Text:32F,0C Spec Gravity:1.005 pH:8.6 Solubility in Water:COMPLETE Appearance and Odor:THIN MILKY WHITE EMULSION WITH SLIGHT AMMONIACAL ODOR. Percent Volatiles by Volume:78(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL SPILLS MAY BE FLUSHED INTO SEWAGE SYSTEMS. LARGE SPILLS SHOULD BE CONTAINED WITH ABSORBENT MATERIAL AND DISCARDED IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RUGLYDE, RG-55 Preparer's Name:CHARLES HIDDEMA CAGE:EO473 CAGE:96980 CAGE:EO473 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM VEGETABLE OIL SOAP Fraction by Wt: 5-15% Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 1-5% OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE IRRITATION, DISCOMFORT & PAIN. SKIN: MAY CAUSE IRRITATION/DERMATITIS. INHAL: MAY CAUSE IRRITATION. INGEST: MAY CAUSE NAUSEA AND/OR DIARRHEA; DEPRESSION FOLLOWED BY RESPIRATORY & CARDIAC FAILURE; RENAL & BRAIN DAMAGE.CHRONIC: VAPORIZING SOLUTION MAY CAUSE INHALATION EFFECTS. (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: SUCH AS CNS DEPRESSION AND HEMATOPOIETIC DYSFUNCTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA. REMOVE CONTAMINATED CLOTHING. IF ADVERSE EFFECTS OCCUR, CONSULT A PHYSICIAN. INGEST: INDUCE VOMITING. G ET MEDICAL ATTENTION. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION AS REQUIRED, CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT APPLICABLE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON INERT MATERIAL. FLUSH RESIDUE WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE KNOWN. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL ROOM VENTILATION IS SUFFICIENT. Other Protective Equipment:EYE WASH IN AREA. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:200F,93C Vapor Density:> 1 Spec Gravity:1.01 @15.5C pH:9.6 Solubility in Water:COMPLETE Appearance and Odor:AMBER LIQUID WITH CHARACTERISTIC ODOR. Percent Volatiles by Volume:90(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT DETERMINED. REMOVAL BY AN APPROVED, LICENSED WASTE HAULER. DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory