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===================== Product Identification ===================== Product ID:BTC 2125 80% CAGE:91993 CAGE:91993 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE(SEE SUPP DATA) Ingred Name:ALKYL DIMETHYL ETHYL BENZYL AMMONIUM CHLORIDE (SEE SUPP DATA) ===================== Hazards Identification ===================== Effects of Overexposure:SKIN & EYES:SEVERE IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN & EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:130F; 54C (PMCC) Extinguishing Media:WATER Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP EXCESS WITH SHIOVEL OR ABSORBRNT MATERIAL AND PLACE IN SEPARATE CONTAINER. FLUSH REMAINING WITH WATER OR IF FOAMING OCCURS, ISOPROPANOL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PLACE W/TEMPERATURES BELOW 120F; 49C AND ABOVE 50F; 10C. Other Precautions:AVOID CONTACT W/ ALUMINUM, BRASS, COPPER, BLACK IRON, OR PLAIN STEEL. ============= Exposure Controls/Personal Protection ============= Ventilation:NORMAL VENTILATION Other Protective Equipment:PROTECTIVE APRON Supplemental Safety and Health INGREDIENTS:WHEN ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE IS COMBINED W/ ALKYL DIMETHYL ETHYL AMMONIUM CHLORIDE IT FORMS 80% OF THE PRODUCT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:200F; 93C Spec Gravity:0.94 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID, ALMOND ODOR Percent Volatiles by Volume:20 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ANIONIC MATRLS, STRONG OXIDIZERS, SEE OTHER PRECAUTIONS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FEDERAL, STATE AND LOCAL REGULATIONS.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:FREON 22 W/DYTEL LEAK DETECTIVE CAGE:EO721 CAGE:73925 CAGE:EO721 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORODIFLUOROMETHANE CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: 99.9% OSHA PEL:1000 PPM ACGIH TLV:1000PPM; 9192 Ozone Depleting Chemical:2 ===================== Hazards Identification ===================== Effects of Overexposure:INHALATION: VAPOR IS >AIR. LIGHT-HEADEDNESS/GIDDINESS/SHORTNESS OF BREATH/UNCONSCIOUSNESS OR DEATH ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT BREATHING, GIVE ARTIFICIAL RESP, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYE: FLUSH W/WATER. CALL A PHYS. SKIN: FLU SH W/WATER. TREAT FOR FROSTBITE IF NECESSARY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NONFLAMMABLE Fire Fighting Procedures:SCBA MAY BE REQUIRED IF A SPILL OCCURS OR RELEASE UNDER FIRE Unusual Fire/Explosion Hazard:CYLINDERS ARE EQUIPPED W/PRESSURE AND TEMPERATURE RELIEF DEVICES BUT STILL MAY RUPTURE UNDER FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREAA--ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT. REMOVE OPENLAMES. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING VAPORS AND LIQUID CONTACT WITH THE SKIN OR EYES. USE ONLY IN WELL VENTILATED AA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT Ventilation:LOCAL EXHAUST AND MECHANICAL Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:41.4F Vapor Pres:138 Vapor Density:2.98 Solubility in Water:0.30 Appearance and Odor:RED; CLEAR; SLIGHT ETHEREAL ODOR. Percent Volatiles by Volume:99.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN, BE, ETC. Stability Condition to Avoid:HOWEVER, AVOID OPEN FLAMES AND HIGH TEMPERATURES. Hazardous Decomposition Products:HYDROCHLORIC/HYDROFLUORIC ACIDS-POSSIBLE CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM BY DISTILLATION. COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:T-IV L CAGE:67532 CAGE:0VWY3 CAGE:67532 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER CAS:7440-22-4 RTECS #:VW3500000 OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COPPER (DUST & MIST), BRONZE POWDER CAS:7440-50-8 RTECS #:GL5325000 Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:INDIUM CAS:7440-74-6 RTECS #:NL1050000 Fraction by Wt: <1% OSHA PEL:0.1 MG/CUM ACGIH TLV:0.1 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: DISCOLORATION OR BLUE-GRAY DARKENING, IRRITATION. METAL SOLUTIONS MAY CAUSE SWELLING & ITCHING. EYES: DISCOLORATION OR BLUE-GRAY DARKENING. IRRITATION. INHALATION: METAL FUME FEVER. MODERATELY T OXIC. INGESTION: STOMACH PAIN, NAUSEA, VOMITING, DIARRHEA. EXTREMELY TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: FRAGMENTS IN THE CORNEA MAY CAUSE CATARACTS, DISCOLORATION (KAPER-FLEISCHER RINGS) & LOSS OF THE EYES. Medical Cond Aggravated by Exposure:WILSON'S DISEASE ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Extinguishing Media:DRY CHEMICAL, SAND OR OTHER APPROVED EXTINGUISHING MATERIAL FOR METAL FIRES. Fire Fighting Procedures:PROTECTIVE CLOTHING & POSITIVE PRESSURE, SCBA. Unusual Fire/Explosion Hazard:METAL POWDERS & METAL DUSTS MAY CAUSE CATALYTIC OXIDATION OF FLAMMABLE ORGANIC SOLVENT VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM UP SPILL. PLACE SPILLED MATERIAL IN METAL SAFETY CAN. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED & STORE IN COOL, DRY AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AN APPROPRIATE NIOSH APPROVED RESPIRATOR IN POORLY VENTILATED AREAS. Ventilation:LOCAL EXHAUST Other Protective Equipment:APRON OR PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS & FACE AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN PEROXIDE, METHANOL & FLAMMABLE ORGANIC SOLVENT VAPORS. Hazardous Decomposition Products:METAL OXIDE FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS OR SENT TO A REFINERY FOR RECOVERY OF PRECIOUS METALS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LUCITONE 199 LIQUID Preparer's Name:EARL C. FRANCIS CAGE:11107 CAGE:11107 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL METHACRYLATE (SARA III) CAS:80-62-6 RTECS #:OZ5075000 Fraction by Wt: <95% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLENE GLYCOL DIMETHACRYLATE CAS:97-90-5 RTECS #:OZ4400000 Fraction by Wt: <10% Ingred Name:HYDROQUINONE (SARA III) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: TRACE OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: HEADACHE, NAUSEA, IRRITATION OF RESPIRATORY SYSTEM. EYES: IRRITATION, CORNEAL DAMAGE, SMARTING. SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: HEADACHE, NAUSEA, IRRITATION OF RESPIRATORY SYSTEM. EYES: IRRITATION, SMARTING, CORNEAL DAMAGE. SKIN: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE SUBJECT TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION AS REQUIRED. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER & CONSULT PHYSICIAN. SKIN: WASH W/SOAP & WATER. INGESTION: INDUCE VOMIT ING & CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:55F Lower Limits:2.12% Upper Limits:12.5% Extinguishing Media:FOAM, CO2, DRY CHEMCIAL, WATER FOG Fire Fighting Procedures:WATER MAY BE INEFFECTIVE UNLESS USED AS A FINE SPRAY OR FOG. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS OF METHYL METHACRYLATE. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO SOURCE OF IGNITION & FLASH BACK. CLOSED CONTAINERS MAY RUPTURE EXPLOSIVELY. AVOID IGNITION SOURCES 0R EXCESSIVE TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. AVOID BREATHING VAPORS. DIKE & ABSORB SPILL W/INERT MATERIAL (SAND, SODA, ASH, VERMICULITE) & TRANSFER TO CONTAINERS FOR DISPOSAL. USE NON-SPARKING TOOLS, REMOVE SATURATED CLOTHING & WASH AFECTED SKIN W/SOAP & WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES OUT OF DIRECT SUNLIGHT/ADVISABLE TO USE OLDEST MATERIALS FIRST. USE ADEQUATE VENTILATION. Other Precautions:AV0ID REPEATED BREATHING & CONTACT W/SKIN. KEEP CONTAINERS CLOSED & AWAY FROM HEAT, SPARKS & OPEN FLAME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF CONTAINED BREATHING APARATUS DURING HIGH VAPOR. Other Protective Equipment:IMPERVIOUS APRON & OVERSHOES Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:214F Vapor Pres:29 Vapor Density:3.45 Spec Gravity:0.94 Solubility in Water:SLIGHT Appearance and Odor:WATER CLEAR LIQUID, CHARACTERISTIC ACRYLIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMINES, REDUCING OR OXIDIZING MATERIALS Stability Condition to Avoid:ELEVATED TEMPERATURES, IGNITION SOURCES, SPARKS, OPEN FLAME, HEAT, & SUNLIGHT Hazardous Decomposition Products:ACRID FUMES, CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE UNDER CONTROLLED CONDITIONS IN A SAFE OPEN AREA, OR ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. BIOLOGICAL DEGRADATION IS ALSO POSSIBLE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:250 VOC POLYSHEEN WHITE & WTR, 855-0001N CAGE:42590 CAGE:42590 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS (ALIPHATIC HYDROCARBON) CAS:64742-86-5 RTECS #:LX3296500 Fraction by Wt: 15% OSHA PEL:100 PPM ACGIH TLV:500 PPM (MFR) Ingred Name:ZIRCONIUM-2-ETHYLHEXANATE SOLUTION (ORGANIC SOLUTION OF A ZIRCONIUM SALT OF A SYN. ACID) CAS:22464-99-9 Fraction by Wt: <5.0% OSHA PEL:100 PPM (MFR) ACGIH TLV:5MG/M3 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYES:CAUSE SEVERE IRRIT,REDNESS,TEARING & BLURRED VISION. SKIN:CAN CAUSE MOD IRRIT,DEFAT,& DERM. INHAL:CAN CAUSE NASAL & RESP IRRIT. ASPIR INTO LUNGS CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. CHR ONIC: PRLNGD/RPTD EXPOS ABOVE TVL CAN RESULT IN PERM BRAIN/NERV SYS DAMAGE. CHRONIC: OVEREXP TO DUST(SUPP DATA) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:INHAL: EXCESS VAPORS CAN CAUSE NASAL/RESP IRRIT, WEAK,DIZ,FATG,NAUS,HDCH,POSS UNCON & EVEN ASPHY. SKIN/EYE:PRLNGD/RPTD CONTACT CAN CAUSE MOD IRRIT, DEFAT,DERM. CAN CAUSE SEVERE EYE IRRIT,REDNESS, TEAR ING & BLURRED VISION. SKIN:ORGANIC SOLVARE EASILY ABSORBED, DRYING OF SKIN,REDNESS,OR DERM ARE SIGNS OF RPTD(SUPP DATA) Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMED W/LRG AMTS OF H*2O FOR AT LST 15 MIN. TAKE TO MD FOR TREATMENT. SKIN: WASH AFFECTED AREAS W/SOAP & H*2O. INHAL: REMOVE TO FRESH AIR. RESTORE BRTHG. TREAT SYMPTOMATICALLY. CONSULT MD. INGEST: DRINK 1 OR 2 GLASSES OF H*2O TO DILUTE. DO NOT INDUCE VOMIT. CONSULT MD OR POISON CONTROL MD IMMED. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:1 % Upper Limits:6 % Extinguishing Media:FOAM, CO*2, DRY CHEMICALS Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIP . DURING EMERGENCY CONDITION OVEREXPOSURE TO DECOMP PROD CAN IMMED/DELAYED HEALTH HAZARD. Unusual Fire/Explosion Hazard:VAPORS ARE HVR/AIR & MAY TRAVEL ALONG GROUND & BE IGNITED BY HEAT, OPEN FLAME OR OTHER IGNIT SOURCES. KEEP CNTNRS TIGHTLY CLOSED. ISOLATE FROM HEAT,(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITON SOURCES. DIKE, CONTAIN, OR ABSORB W/INERT MATLS(SAND,VERMICULITE, ETC.) TRANSFER TO CONTAINERS FOR RECOVERY OR DISPOSAL. PREVENT RUNOFF INTO SEWERS, STREAMS OR OTHER BODIES OF WA TER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE OR USE NEAR SOURCES OF HIGH TEMPS, NEAR FIRE OR OPEN FLAME, OR OTHER IGNITION SOURCES. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED OR REPEATED EXPOSURE TO LEVELS ABOVE TLV. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR & MIST, SUPPLIED AIR OR SCBA. Ventilation:USE ADEQUATE MECANICAL (GENERAL AND/OR LOCAL) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING. EYEWASH STATIONS. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOMS. REMOVE & WASH CONTAMINATED CLOTHING BEFORE RE-USE. Supplemental Safety and Health EXPLO HAZ: SPARKS, ELECTRICAL EQUIPMENT, AND OPEN FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. HLTH HAZ: MAY CAUSE SLIGHT LUNG FIBROSIS. EFT OF OVEREXP: OR OVER EXPOSURE TO THEI R DEFATTING ACTION. INGEST: CAN CAUSE GI IRRIT, NAUSEA, VOMIT & DIARRHEA. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:310F,154C Vapor Density:HVR/AIR Spec Gravity:1.4 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NONE Appearance and Odor:TYPICAL FOR SOLVENT BASED COATING. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:DO NOT EXPOSE TO HIGH TEMPS OR OPEN IGNITION SOURCES. Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CO, CO*2, VARIOUS HYDROCARBONS, ETC. NO THERMAL DECOMP. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE, OR FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:99638 POTATO FLAKES AGAR CAGE:05545 CAGE:05545 CAGE:15481 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:SHOULD BE APPROPRIATE MEDIA FOR SURROUNDING AREAS. Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN. ================== Accidental Release Measures ================== Spill Release Procedures:USE PAPER TOWELS TO PICKUP GELLED MATERIAL & TO ABSORB ANY LIQUID MATERIAL. WASH AREA W/SOAP & WATER AFTER CLEANUP IS COMPLETE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Ventilation:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Other Protective Equipment:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Supplemental Safety and Health WASTE CONT'D: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ================== Physical/Chemical Properties ================== Appearance and Odor:GELLED MEDIA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ASEPTIC TECHNIQUES & ESTABLISH PRECAUTIONS AGAINST MICROBIOLOGICAL HAZARDS THROUGHOUT ALL PROCEDURES. PRIOR TO DISPOSAL, ALL INOCULATED PLATES SPECIMEN CONTAINERS & OTHER CONTAMINATED MATERIAL MUST BE AUTOCLAVED. (SEE SUPP)
0
gloves_not_mandatory
======================================================= Product ID: STAINLESS STEEL BARE WIRE, AWS 50S Cage: 34920 Resp. Party Other MSDS No.: A=NIC & CHR, MSDS VERSION NUMBER: 3 ======================================================= Contractor Summary ======================================================= Cage: 34920 ======================================================= Ingredients ======================================================= Cas: 7439-89-6 RTECS #: NO4565500 % Wt: BALANCE ACGIH TLV: 10 MG/M3 (FE203) ------------------------------ Cas: 7440-47-3 RTECS #: GB4200000 % low Wt: 11.5 % high Wt: 37. OSHA PEL: 1 MG/M3 ACGIH TLV: 0.5 MG/M3 ACGIH STEL: NOT ESTABLISHED EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7440-02-0 RTECS #: QR5950000 % low Wt: .06 % high Wt: 37. OSHA PEL: 1 MG/M3 ACGIH TLV: 1 MG/M3 ACGIH STEL: NOT ESTABLISHED ----------------------------- Cas: 7439-96-5 RTECS #: OO9275000 % low Wt: .6 % high Wt: 14. Other REC Limits: ACGIH TLV:1 MG/M3(M) OSHA PEL: C5 MG/M3 ACGIH TLV: 5 MG/M3 ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 7440-21-3 RTECS #: VW0400000 % low Wt: .3 % high Wt: 5. Other REC Limits: TLV:3 MG/M3(SIO2)(M) OSHA PEL: 15 MG/M3 ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 7439-98-7 RTECS #: QA4680000 % low Wt: .05 % high Wt: 6. ACGIH TLV: 10 MG/M3 ACGIH STEL: NOT ESTABLISHED ------------------------------ Cas: 7440-44-0 RTECS #: FF5250000 % low Wt: 0. % high Wt: 1. ACGIH TLV: 2 MG/M3 ----------------------------- Cas: 7723-14-0 RTECS #: TH3495000 % low Wt: 0. % high Wt: .5 OSHA PEL: 0.1 MG/M3 ACGIH TLV: 0.1 MG/M3;0.02 PPM ACGIH STEL: NOT ESTABLISHED EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7704-34-9 RTECS #: WS4250000 % low Wt: 0. % high Wt: .5 ------------------------------ Cas: 7727-37-9 RTECS #: QW9700000 % low Wt: 0. % high Wt: .5 ------------------------------ Cas: 7440-50-8 RTECS #: GL5325000 % low Wt: 0. % high Wt: 5. OSHA PEL: 1 MG/M3 ACGIH TLV: 1 MG/M3 ACGIH STEL: NOT ESTABLISHED EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 7440-03-1 RTECS #: QT9900000 % low Wt: 0. % high Wt: 1. ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ELECTRIC ARC-WELDING MAY CREATE: FUMES AND GASES CAN BE DANGEROUS. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. CHROMIUM COMPOUNDS ARE REQUIRED BY OSHA TO BE CONSIDERED CARCINOGENI C (MFR). Explanation Of Carcinogenicity: NICKEL: IARC MONOGRAPHS ON THE EVALUATION OF CARINOGENIC RISK OF CHEMICALS TO MAN, VOL 49, PG 257, 1990: GROUP 2B. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCIN OGEN. ANIMAL: LUNGS, NASAL CAVITIES. Signs And Symptions Of Overexposure: SHORT TERM TO WELDING FUMES - DIZZINESS, NAUSEA, DRYNESS AND IRRITATION OF NOSE, EYES, THROAT, CHEST TIGHTNESS, FEVER, ALLERGIC REACTION. LONG TERM - SIDEROSIS, BELIEVED TO AFFECT PULMONARY FUNCTION. First Aid: EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY (FP N). SKIN: FLUSH WITH COPIOUS AMOUNTS OF WAT ER. CALL MD (FP N). EYE: IMMEDIATELY FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES, SEEK ASSISTANCE FROM MD (FP N). ======================================================= Handling and Disposal ======================================================= Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSAL CONTAINER OR LINER IN ENVIRONMENTAL ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. Handling And Storage Precautions: TRAIN WORKER TO KEEP HEAD OUT OF FUMES. DO NOT TOUCH LIVE ELEC PARTS & INSULATE FROM WORK & GROUND. FOR MAX SAFETY: BE CERTIFIED FOR, & WEAR NIOSH APPRVD RESP AT ALL TIMES WHEN WELDING OR BRAZING. USE EXHST SYS. MAKE SURE INHALED AIR DOES NOT CONTAIN FUME CONSTITUENTS ABOVE PEL'S. Other Precautions: OTHER PRECAUTIONS FOR ADDITIONAL SAFETY INFORMATION ON WELDING AND CUTTING, SEE ANSI Z49.1-1983, SAFETY IN WELDING AND CUTTING, AND THE WELDING HANDBOOK, VOL 1, CHAPTER 9, SAFE PRACTICES IN WELDING AN D CUTTING. BOTH AVAILABLE FROM AWS INC, 550 N.W. LEJEUNE RD, P.O. BOX 351040, ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONFLAMMABLE Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: WELDING ARC AND SPARKS CAN IGNITE COMBUSTIBLES AND FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING THE USE OF WELDING AND ALLIED PROCEDURES. HAZARD RATING: HEALTH - 3; FLAMMABILITY - 0 ; REACTIVITY - 0. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH APPROVED RESPIRABLE FUME RESPIRATORY OR AIR SUPPLIED RESPIRATOR WHEN IN CONFINED SPACE OR LOCAL EXHAUST DOES NOT KEEP EXPOSURE BELOW RECOMMENDED EXPOSURE LIMIT. Ventilation: USE ENOUGH LOCAL VENTILATION AND LOCAL EXHAUST AT ARC TO KEEP FUMES AND GASES FROM WORKER'S BREATHING ZONE AND GENERAL AREA. LENS, (SUPP DATA) Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). HAND, HEAD, BODY PROTECTION TO PREVENT INJURY FROM RADIATION, SPARKS AND ELECTRICAL SHOCK. Supplemental Safety and Health: EYE PROT:PROT SCREENS. FLASH GOGGS TO SHIELD OTHERS. START W/SHADE TOO DARK THEN GO TO LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE. -- HAZ DECOMP PROD: WHICH WORKERS MAY BE EXPOS INCL: COAT INGS ON METAL BEING WELDED (SUCH AS PAINT, PLATING/GALVANIZING), NUMBER OF WELDERS & VOL OF WORK AREA, (TOX INFO) ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: N/A(AIR=1) Appearance and Odor: BARE FILLER METALS ARE SOLID WIRE, SHINY SILVER APPEARANCE. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE UNLESS OTHERWISE STATED. Materials To Avoid: NONE. Hazardous Decomposition Products: COMPOSITION & QUALITY OF WELDING FUMES & GASES ARE DEPENDENT UPON METAL BEING WELDED, PROCESS, PROC & ELECTRODES USED. OTHER CNDTNS WHICH ALSO INFLUENCE COMPOSITION & QTY OF FUMES & GASES TO (SUPP DATA) Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: N/P --SUPP DATA: QUALITY & AMT OF VENT, POSITION OF WELDER'S HEAD W/RESPECT TO FUME PLUME & PRESENCE OF CONTAMS IN ATM (CHLORINATED HYDROCAROBN VAPS FROM CLEANING & DEGREASING ACTIVITIES). WHEN ELECTR ODE IS CONSUMED, FUME & GAS DECOMP PRODS GENERATED ARE DIFF IN PERCENT & FORM FROM INGS LISTED. FUME & GAS DECOMP PRODS, & NOT INGS IN ELECTRODE, ARE IMPORTANT. CONC OF GIVEN FUME/GAS COMPONENT MAY DE CR/INCR BY MANY TIMES ORIGINAL CONC. NEW CMPDS IN ELECTRODE MAY FORM. DECOMP PRODS OF NORMAL OPERATION INCL THOSE ORIGINATING FROM VOLATILIZATION, RXN/OXIDATION OF MATLS IN INGS SECTION, PLUS THOSE FR OM BASE METAL & COATING, (ECOL INFO) ======================================================= Ecological Information ======================================================= Ecological: N/P --TOX INFO: ETC., AS NOTED. REASONABLY EXPECTED FUME CONSTITUENTS OF PROD COULD INCL PRIMARILY OXIDES OF IRON; SECONDARILY OXIDES OF CHROMIUM, NICKEL, MANGANESE, SILICON & MOLYBDENUM. PRESENT OSHA EXPOS LIMS FOR HEXAVALENT-CHROMIUM IS 0.05 MG/M3 & NICKEL 1 MG/M3 WHICH WILL RSLT IN SIGNIFICANT REDUCTION FROM 5 MG/M3 GEN FUME LEVEL. GASEOUS RXN IN PRODS MAY INCL CARBON MONOXIDE & CARBON DIOXIDE.OZONE & NITROGEN OXIDES MAY BE FORMED BY RADIA FROM ARC, IN ADDN TO SHIELDING GASES LIKE ARGON & HELIUM WHEN EMPLOYED. ONE REC WAY TO DETERM COMPOSITION & QTY OF FUMES & GASES ARE TO TAKE AIR SAMPLE FROM INSIDE WELDER'S (TRANSPORT INFO) ======================================================= ======================================================= Transport Information: N/P --ECOLOGICAL INFO: HELMET IF WORN OR IN BREATHING ZONE. SEE ANSI/AWS FIL-97, AVAILABLE FROM THE AMERICAN WELDING SOCIETY (AWS). SEE AWS PUBLICATION: "FUMES AND GASES IN THE WELDING ENVIRONMENT" AN D AWS "EFFECTS OF WELDING ON HEALTH 1X". ======================================================= Regulatory Information ======================================================= Sara Title III Information: CHROMIUM, NICKEL AND MANGANESE ARE LISTED IN SECTION 313 OF SARA TITLE III. Federal Regulatory Information: NICKEL AND CHROMIUM COMPOUNDS ARE REQUIRED BY OSHA TO BE CONSIDERED CARCINOGENIC. State Regulatory Information: THE STATE OF CALIFORNIA REQUIRES THE FOLLOWING INFORMATION: WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. ======================================================= Other Information ======================================================= Other Information: MFR'S FAX NUMBER: 704-739-2801. ======================================================= HAZCOM Label ======================================================= Product ID: STAINLESS STEEL BARE WIRE, AWS 50S Cage: 34920 Company Name: J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO Street: 1051 YORK RD Zipcode: 28086 Label Required IND: Y Date Of Label Review: 04/18/2000 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: ELECTRIC ARC-WELDING MAY CREATE DANGEROUS FUMES AND GASES. WELDING FUME EXPOSURE CAN CAUSE DIZZINEAA, NAUSEA, DRYNESS AND IRRITATION OF THE NOSE, EYES AND THROAT, CHEST TIGHTNESS, FEVER, ALLERG IC REACTION. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. CHRONIC: CANCER HAZARD. CONTAINS NICKEL WHICH IS LISTED AS A LUNG CARCINOGEN (FP N). CHROMIUM COMPOUNDS ARE REQUIRED BY O SHA TO BE CONSIDERED CARCINOGENIC (MFR). WELDING FUME EXPOSURE MAY CAUSE SIDEROSIS AND AFFECT PULMONARY FUNCTION. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:A-36 PART B, ADHESIVE ACTIVATOR Kit Part:Y Preparer's Name:STEVEN L. KIEFER CAGE:DO043 CAGE:DO043 CAGE:98911 ============= Composition/Information on Ingredients ============= Ingred Name:BORON TRIFLUORIDE (SARA III) CAS:7637-07-2 RTECS #:ED2275000 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED OSHA PEL:C 1 PPM ACGIH TLV:C 1 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Effects of Overexposure:EYE IRRITATION:IRRITATING TO EYES. SKIN IRRITATION:MILD SKIN IRRITANT. ======================= First Aid Measures ======================= First Aid:INHALATION:MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GET PROMPT MEDICAL ATTENTION. EYE CONTACT:FLUSH EYES WITH LARGE VOLUMES OF WATER. GET PROMPT MEDICAL ATTENTION. SKIN CONTACT:WASH WITH SOAP AND WATER. IF IRRITATION OCCURS SEE PHYSICIAN. INGESTION:IF CONSCIOUS, INDUCE VOMITING. GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:200F/93C Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL AND SAND Fire Fighting Procedures:DO NOT BREATHE SMOKE OR FUMES. WEAR NIOSH/MSHA APPROVED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP UP EXCESS AND REMOVE. SOAK UP ON ABSORBENT MATERIAL AND REMOVE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:AVOID INHALATION OF FUMES OR SKIN AND EYE CONTACT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR. Ventilation:PROVIDE VENTILATION PER LEL. Other Protective Equipment:OTHER EQUIPMENT AS NECESSARY TO PREVENT CONTACT WITH SKIN, EYES AND STREET CLOTHES. Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING THE TOILET. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.65+/-.05 Solubility in Water:SLIGHT Appearance and Odor:DARK AMBER PASTE SLIGHT ODOR Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, BORON OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ORDINANCES.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:153 7927 DK-50 DEVELOPER, PART A Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 50% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:P-METHYLAMINOPHENOL SULFATE (METOL)/4-(METHYLAMINO)PHENOL SULFATE CAS:55-55-1 RTECS #:SL8650000 Fraction by Wt: 45 - 50% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR HYDROQUINONE IS 2 MG/M3. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACTS. ACUTE- CAUTION. CONTAINS HYDROQUINONE. INHALE:MAY CAUSE IRRITATION. HARMFUL IF INHALED. EYES/SKIN:CAUSES IRRITATION. MAY CAUSE ALLERG IC SKIN REACTION. ORAL:HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF GI TRACT. CHRONIC- MAY CAUSE EYE INJURY. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:IRRITATION, ALLERGIC SKIN REACTION, EYE INJURY, PAIN Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL:IF CONSCIOUS, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:COMBUSTIBLESOLID Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCT. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST- AIR MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. VACUUM SPILLAGE WITH A VACUUM CLEANER OR CAREFULLY SWEEP UP. AVOID RAISING DUST. WASH SPILL SITE AFTER PICK-UP IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AWAY FROM INCOMPATIBLE MATERIALS. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL MINIMIZE SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCETABLE LEVEL, A NIOSH-APPROVED RESPIRATOR FOR DUST MUST BE WORN. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASS URE COMPLIANCE WITH OSHA 29CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT. TYPICALLY, 10 ROOM VOLUMES PER HR IS CONSIDERED GOOD GENERAL VENTILATION. Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health KEY1:T4. SEE PNI B FOR PART B. THIS PRODUCT HAS: A HIGH BIOCHEMICAL OXYGEN DEMAND, A HIGH POTENTIAL TO AFFECT AQUATIC ORGANISMS. AFTER DILUTION WITH A LARGE AMOUNT OF WATER, FOLLOWED BY WASTE TREATMEN T, IT IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENT EFFECTS. ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NEGLIGIBLE Vapor Density:NOT GIVEN Spec Gravity:1.00 Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:COMPLETE Appearance and Odor:LIGHT TAN SOLID - ODORLESS Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF SULFUR, OXIDES OF NITROGEN MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:WATER MASTER WATERBORNE DARK OAK, LF#KB25C CAGE:0ZXD0 CAGE:0ZXD0 ============= Composition/Information on Ingredients ============= Ingred Name:THERE ARE NO HAZARDOUS MATERIALS IN THIS PRODUCT. Other REC Limits:NONE RECOMMENDED Ingred Name:VOC: 0.000 POUNDS/GALLON RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE: IRRITATION (DIRECT CONTACT). SKIN: SLIGHT IRRITATION (REPEATED/PROLONGED CONTACT). INHALATION: (EXTREMELY HIGH CONCENTRATIONS) IRRITATING TO EYE & RESPIRATORY TRACT. SIGNS & SYMPTOMS OF TOXICITY ARE SIMILAR TO THOSE OF SWALLOWING. SWALLOWING: SWALLOWING OF LARGE AMOUNTS MAY BE HARMFUL. Medical Cond Aggravated by Exposure:MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER AND CONTINUE WASHING FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH SKIN WITH WATER. INHALATION: REMOVE TO FRESH AIR. SWALLOWING: CONSULT PHYSICIAN AT ONCE. IF PATIENT IS CONSCIOUS AND HAS A GAG REFLEX, GIVE TWO GLASSES OF WATER. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:NONCOMBUSTIBLE Extinguishing Media:TYPE A, B, C, OR COMBINATION TYPE ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AND CONTAIN SPILLS. ABSORB WITH SUITABLE MATERIAL. COLLECT MATERIAL INTO SUITABLE CONTAINERS AND DISPOSE OF PROPERLY. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT ALLOW PRODUCT TO FREEZE! ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ADEQUATE VENTILATION IS NOT MAINTAINED, RESPIRATORS (OSHA/NIOSH APPROVED) MAY BE NECESSARY. IF EXPOSURE TO SPRAY MIST EXISTS, WEAR NIOSH APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR. Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:> AIR Spec Gravity:1.01 (H2O=1) Evaporation Rate & Reference:LESS THAN 1 (BU AC=1) Solubility in Water:DILUTABLE Appearance and Odor:COLORED LIQUIDS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.
1
gloves_mandatory
======================================================= Product ID: 8P502, AWLGRIP AWLSTAR ANTI-FOULING GOLD (SUPP DATA) Cage: HO572 ======================================================= Contractor Summary ======================================================= Cage: HO572 Cage: 90608 ======================================================= Ingredients ======================================================= IN SPONT COMBUST (CNDTNS MAY APPLY WHEN SANDING). ----------------------------- PRECS GIVEN IN THIS MSDS MUST BE OBSERVED. ----------------------------- & PRECS ON LBLS OF ALL PRODS BEING ----------------------------- INDUSTRIAL USE ONLY BY PROFESSIONAL, TRAINED ----------------------------- BY, THE GENERAL PUBLIC. ----------------------------- Cas: 1317-39-1 % Wt: 44-47 OSHA PEL: 10 MG/M3 (MFR) ACGIH TLV: 10 MG/M3 (MFR) ------------------------------ Cas: 7440-50-8 RTECS #: GL5325000 % Wt: 10 MIN OSHA PEL: 0.1MG/M3 FUME;1 DUST ACGIH TLV: 0.2 MG/M3 FUME EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ RTECS #: 9999999VO ----------------------------- & UNTIL ALL VAPS ARE GONE. VAPS MAY IGNITE ----------------------------- VAPS BY MAINTAINING CONTINUOUS FLOW OF FRESH ----------------------------- CUPROUS OXIDE PARTICULATES WHEN EXPOS TO ----------------------------- ----------------------------- VITAL ORGS; INJURY TO KIDNEYS, LIVER, ----------------------------- DISORDERS. WARNING:RPTS HAVE ASSOC RPTD/PRLNG ----------------------------- INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY ----------------------------- CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/REPRO HARM. ----------------------------- AREA OF SPILL TO PVNT SPREADING, PUMP ----------------------------- SUCH AS SAND, CLAY, EARTH/FLOOR ABSORB & ----------------------------- STREAMS/OTHER BODIES OF WATER. IF ----------------------------- HAS OCCURRED. ----------------------------- Cas: 1330-20-7 RTECS #: ZE2100000 LD50:(ORAL,RAT) 4.3 G/KG. % Wt: 8 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM;150 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 71-36-3 RTECS #: EO1400000 LD50:(ORAL,RAT) 2.5 G/KG. % Wt: 11 OSHA PEL: 100 PPM ACGIH TLV: 50 PPM, S, C EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 100-41-4 RTECS #: DA0700000 % Wt: 1 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM;125 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 1314-13-2 RTECS #: ZH4810000 % Wt: 13 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 % Wt: 2 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: SEE INGREDIENTS. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING & BLURRED VISION, PAIN & INFLAMM OF TISS. SKIN:CAN CAUSE MOD IRRIT, DEFAT & DERM. SOLVS CAN PENETRATE CAUSING EFTS AS IN ACUTE INHAL. ING 7:IRRIT (OXID E POX). INHAL:CAN CAUSE NASAL & RESP IRRIT, CONGESTION, DIZZ, WEAK, CHILLS, FEVER, FATG, MUSCLE ACHES, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:NAUS, HDCH, POSS UNCON, TIGHTNESS IN CHEST, FLU-LIKE SYMPS CALLED "METAL-FUME FEVER" & EVEN ASPHY. INGEST:HARMFUL & CAN CAUSE BURNING SENSATION, SORE THROAT, ABDOM PAIN, NAUS, VOMIT & DIARR. CHRONIC:PRLNG & RPTD BRTHG OF SPRAY MIST &/OR SANDING DUST OVER PERIOD OF YRS MAY CAUSE DISEASES OF LUNGS. CAN Medical Cond Aggravated By Exposure: PRE-EXISTING LUNG DISEASES MAY BE AGGRAVATED BY EXPOSURE; MAY RESULT IN RESPIRATORY DISEASE IF OVEREXPOSED ON A CHRONIC BASIS. First Aid: INGEST:DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY (FP N). INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP N). FOR MORE SPECIFIC INFORMATION REGARDING FIRST AID TREATMENT CONTACT NEHC (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SM SPILL:ABSORB LIQ ON INERT MATL SUCH AS PAPER, VERMICULITE, FLOOR ABSORB & TRANSFER TO HOOD. LG SPILL:ELIM ALL IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUI P SHOULD BE EXCLUDED FROM AREA OF SPILL Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: ALLOW VOLAT PORTION TO EVAP IN HOOD BEING SURE TO ALLOW SUFFICIENT TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT WORK. DISP OF CONTAM ABSORB, CNTNR & UNUSED CONTENTS I/A/W LOC, STATE & FED REGS. DO NOT INCIN CLSD CNTNRS. LG MASSES OF CUPROUS Handling And Storage Precautions: CARE SHOULD BE TAKEN WHEN SANDING PIGMENTED PAINTS. USE ONLY W/ADEQ VENT. DO NOT BREATHE VAPS, SPRAY MISTS/SANDING DUSTS. DO NOT STORE >120F. Other Precautions: DO NOT GET IN EYES, ON SKIN/ON CLTHG. KEEP CLOSURE TIGHT & UPRIGHT TO PVNT LEAKAGE. KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES/OTHER UNLABELED CNTNRS. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED BECAUSE ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 82.0F,27.8C Lower Limits: 1.1% Upper Limits: 11.2% Extinguishing Media: IN CASE OF FIRE, USE CO*2, DRY CHEMICAL, FOAM OR OTHER APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). SUMMON PROFESSIONAL FIREFIGHTERS. DURING FIRE, TOX GASES & SMOKE ARE IRRITS PRESENT FROM DECOMP/COMBUST.(SUPDAT) Unusual Fire/Explosion Hazard: FLAMM. VAPS MAY CAUSE FLASH FIRE. SENSITIVITY/STATIC DISCHARGE-GROUNDING/BONDING REQD. KEEP AWAY FROM HEAT, SPKS & FLAME. DO NOT SMOKE. EXTING ALL PILOT(SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR APPROP, PROPERLY FITTED NIOSH APPRVD RESP DURING & AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAP, MIST & PARTICULATE LEVELS ARE BELOW APPLIC LIMS. FOLLOW RESP MFR'S DIRECTIONS FOR RESPUSE. ENGINEERING/ADMIN CONTROLS(SUPDAT) Ventilation: MAINTAIN CONTINUOUS FLOW OF FRESH AIR. PROVIDE SUFFICIENT MECH (GEN &/OR LOC EXHST) VENT TO MAINTAIN EXPOS BELOW TLV(S). Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER (FP N). SOLV IMPERMEABLE CLTHG & BOOTS ARE REC TO PREVENT SKIN CONTACT. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR'S TRADE NAME/PART #:LABEL-DEEP BLUE. FIRE FIGHT PROC:CLSD CNTNR MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. HAZ DECOMP PROD:MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN. WHEN HEATED TO DECOMP EMITS T OX FUMES. RESP PROT:SHOULD BE IMPLEMENTED TO REDUCE EXPOS. EXPLO HAZ:LIGHTS & TURN OFF ALL SOURCES OF IGNIT, INCL ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >241F,>116C M.P/F.P Text: SEE ING 6 Vapor Pres: SEE INGS Vapor Density: HVR/AIR Spec Gravity: 1.96 Evaporation Rate & Reference: SLOWER THAN ETHER Appearance and Odor: VISCOUS LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume: 47 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESS HEAT. Materials To Avoid: OXIDIZING MATLS; STRONG REACTANTS SUCH AS ACIDS, BASES & METALS (ALUMINUM, MAGNESIUM). PERMANGANATE, CHROMIUM TRIOXIDE. Hazardous Decomposition Products: COPPER FUMES WILL BE RELS IF CUPROUS OXIDE IS TREATED >2255F (MELTING POINT). DECOMPOSES INTO FUMES CNTNG CARBON(SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 8P502, AWLGRIP AWLSTAR ANTI-FOULING GOLD (SUPP DATA) Cage: HO572 Assigned IND: Y Company Name: US PAINT CORP Street: 831 SOUTH 21ST ST Zipcode: 63103 Label Required IND: Y Date Of Label Review: 06/24/1997 Status Code: C Label Date: 06/24/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMM LIQUID. ACUTE:EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING & BLURRED VISION, PAIN & INFLAMM OF TISS. SKIN:CAN CAUSE MOD IRRIT, DEFAT & DERM. SOLVS CAN PENETRATE CAUSING EFTS AS IN ACUTE INHAL. INH AL:CAN CAUSE NASAL & RESP IRRIT, CONGESTION, DIZZ, WEAK, CHILLS, FEVER, FATG, MUSCLE ACHES, NAUS, HDCH, UNCON & ASPHY. INHAL OF FUMES MAY CAUSE "METAL FUME FEVER". INGEST:HARMFUL. CAN CAUSE BURNING SE NSATION, SORE THROAT, ABDOM PAIN, NAUS, VOMIT & DIARR. CHRONIC:PRLNG BRTHG OF SANDING DUST MAY CAUSE DUST DISEASE OF LUNGS. MAY CAUSE INJURY TO KIDNEYS, LIVER, LUNGS & CVS. MAY CAUSE BLOOD DISORDERS. SOLV OVEREXP CAN CAUSE PERM BRAIN & NERV SYS DMG. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ULANO SCREEN DEGREASER LIQUID #3 CAGE:ULANO CAGE:53176 CAGE:ULANO ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH W/PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS MUST BE RINSED DOWN THE DRAIN. ABSORB LARGE SPILLS ON SOLID MATERIAL. ============= Exposure Controls/Personal Protection ============= Ventilation:NORMAL Other Protective Equipment:PROTECTIVE APRON Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1 pH:9.3 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS TO SLIGHTLY YELLOW LIQUID, ODORLESS Percent Volatiles by Volume:90% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS Hazardous Decomposition Products:IODINE, IODINE OXIDES, & OXYGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:MICRO FREEZE CIRCUIT COOLER, MCC-FRZ CAGE:DO807 CAGE:0ATV9 CAGE:DO807 ============= Composition/Information on Ingredients ============= Ingred Name:ING 4:CONT; WILL IRRIT EYES & MAY CAUSE CONJUNCT. VAP CONT:MILD IRRIT. RTECS #:9999999ZZ Ingred Name:ING 3:CAUSE FROSTBITE. EYES:PERSONS WEARING CONT LENSES SHOULD WEAR CHEM PROT SFTY GLASSES WHEN USING PROD. LIQ (ING 5) RTECS #:9999999ZZ Ingred Name:1,1,1,2-TETRAFLUOROETHANE; (TETRAFLUOROETHANE) CAS:811-97-2 Fraction by Wt: 100% OSHA PEL:1000 PPM (MFR) ACGIH TLV:1000 PPM (MFR) Ingred Name:SUPDAT:INADEQ CIRCULATION. INDIVIDUALS W/PREEXISTING DISEASES OF CNS/CARDIOVASCULAR SYS MAY HAVE INCREASED (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:SUSCEPTIBILITY TO TOX OF EXCESSIVE EXPOS. INGEST:NOT CONSIDERED POTNTL RTE OF EXPOS. SKIN:LIQ CONT CAN (ING 4) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:INHAL OF HIGH CONCS OF VAP IS HARMFUL & MAY CAUSE HEART IRREGS, UNCON/DEATH. INTENTIONAL MISUSE/DELIB INHAL MAY CAUSE DEATH W/OUT WARNING. VAP REDUCES OXYG AVAIL FOR BRTHG & IS HVR/AIR. ANIMAL D ATA:INHAL 4-HR ALC:567,000 PPM IN RATS.CMPD IS UNTESTED FOR SKIN & EYE IRRIT, & IS UNTESTED FOR ANIMAL(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:SENSIT. LETHARGY & RAPID RESP WERE OBSERVED AT VAP CONC OF 205,000 PPM & PULM CONGESTION, EDEMA & CNS EFTS OCCURRED AT VAP CONC OF 750,000 PPM. CARDIAC SENSIT OCCURRED IN DOGS AT 75,000 PPM FROM ACTION OF EXOGENOUS EPINEPHRINE. EMBRYOTOX ACTIVITY HAS BEEN OBSERVED IN SOME ANIMAL TESTS BUT ONLY AT (SUPP DATA) Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMED. INHALATION:REMOVE TO FRESH AIR. DO NOT GIVE EPINEPHRINE. GIVE ARTF RESP IF NEC. IF BRTHG IS DFCLT, GIVE OXYG. CALL MD. EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MIN, LIFTI NG EYELIDS OCCAS UNTIL NO EVIDENCE OF CHEM REMAINS. IF IRRIT PERSISTS CALL MD. SKIN:WASH PROMPTLY W/SOAP & WATER FOR AT LST 15 MIN. REMOVE CONTAM CLTHG & SHOES. ===================== Fire Fighting Measures ===================== Flash Point:WILL NOT BURN Extinguishing Media:CO*2, DRY CHEMICAL OR H*2O. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CONTAINERS GENERATE PRESSURE WHEN HEATED CAUSING VIOLENT BURSTING AND DANGEROUS PROPELLING OF CONTAINER. FORMS TOXIC DECOMPOSITION PRODUCTS ABOVE 250F, 120C. ================== Accidental Release Measures ================== Spill Release Procedures:ALTHOUGH CHANCES OF SIGNIFICANT SPILL OR LEAK IS UNLIKELY IN AEROSOL CONTAINERS, IN THE EVENT OF SUCH AN OCCURRENCE, EVACUATE AREA. REMOVE UNPROT PERS. PROT PERS SHOULD REMOVE IGNITION SOURCES & SHUT OFF FIRE SOURCES. PROVIDE VENTILATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING VAPORS. USE ONLY WITH ADEQUATE VENTILATION. AVOID LIGHTED CIGARETTES, FLAME, WELDING/HOT SPOTS WHICH MAY GENERATE TOX DECOMP PRODS. Other Precautions:VAPORS ARE HEAVY AND MAY CONCENTRATE IN LOW POORLY VENTILATED AREAS. STORE IN CLEAN, DRY AREA. DO NOT HEAT ABOVE 125F/50C. AVOID POSSIBLE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IN VENTILATED WORK AREAS. ALTHOUGH UNLIKELY IN AEROSOL PACKAGING, USE NIOSH/MSHA APPROVED SELF-CONTAINED OR SUPPPLIED AIR RESPIRATORS FOR EMERGENCIES AND IN SITUATIONS WHERE AIR MAY BE D ISPLACES BY VAPORS. Ventilation:ADEQUATE. LOCAL EXAUST:FOR POORLY VENTILATED WORK AREAS.MECHANICAL:ADEQUATE FOR STORAGE. Other Protective Equipment:PROTECTIVE CLOTHING FOR REPEATED CONTACT. PVA OR NEOPRENE PREFERRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VP:96 PSIA @ 77F, 25C. MATLS TO AVOID:MOLTEN ALUMINUM, BARIUM & LITHIUM SHAVINGS. STRONG OXIDIZING AGENTS. EFTS OF OVEREXP:MATERNALLY TOX DOSE LEVELS. HUMAN HLTH EFTS:HUMAN HLTH EFTS OF OVEREXP BY INH AL TO VERY HIGH CONCS MAY CAUSE TEMPORARY ALTERATION OF HEART'S ELEC ACTIVITY W/IRREG PULSE, PALPITATIONS OR (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-16F,-27C Vapor Pres:SUPP DATA Vapor Density:3.18 Spec Gravity:1.21 Solubility in Water:0.15WT%@77F&14.7PSIA Appearance and Odor:CLEAR WITH SLIGHT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS & ALKALIS, REACTIVE METALS E.G. POWDERED ALUMINUM, SODIUM, POTASSIUM, CALCIUM, MAGNESIUM, ZINC, (SUP DAT) Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES. HEAT WILL DECOMPOSE ABOVE 250F, 120C. Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS, AND CARBONYL HALIDES SUCH AS PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. CONSULT APPROPRIATE REGULATORY AGENCY PRIOR TO DISPOSAL OR DISCHARGE OF WASTE MATERIAL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CONOFLEX SRI LUBRICANT, LUBC0100 CAGE:DO148 CAGE:DO148 CAGE:15445 ============= Composition/Information on Ingredients ============= Ingred Name:MIXTURE; (PETROLEUM HYDROCARBON MIXTURE) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WASTE DISP METH:CONSIDERED HAZ IF IT MEETS CRITERIA FOR BEING TOX, CORR, IGNITABLE/REACTIVE ACCORDING TO US EPA (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:DEFINITIONS (40 CFR 261). THIS MATL COULD ALSO BECOME HAZ WASTE IF IT IS MIXED WITH/COMES IN CONT W/LISTED (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:HAZ WASTE. IF IT IS HAZ WASTE, REG 40 CFR 262-266 & 268 MAY APPLY. PETROLEUM HYDROCARBON IS CONSIDERED (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HAZ IF SPILLED IN NAVIGABLE WATERS. RQ:FILM/SHEEN UPON/DISCOLORATION OF WATER SURF/ADJOINING SHORELINE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MOUSE SKIN PAINTING STUDIES HAVE SHOWN THAT HIGHLY SOLVENT-REFINED PETROLEUM LUBRICATING OILS, WHICH ARE SIMILAR TO INGREDIENTS IN THIS PRODUCT, HAVE NOT CAUSED SKIN TUMORS. THE PRODUCT DOES NOT POSE A SIGNIFICANT HEALTH HAZARD, BUT AS W/MANY PETROLEUM PRODUCTS, POOR HYGIENIC PRACTICES OR INADEQUATE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ENGINEERING DESIGN THAT ALLOW PROLONGED OR REPEATED EXPOSURE MAY CAUSE MINOR SKIN IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. SKIN:CLEANSING ATER USE IS ADVISABLE. IF IRRIT DEVELOPS, CONSULT MD. EYE:IMMED FLUSH W/ PLENTY OF WATE R FOR AT LST 15 MINS. CALL MD. INGEST:DO NOT INDUCE VOMIT. IMMED GIVE 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. CALL MD. NOTES TO MD:ACTIVATED CHARCOAL SLURRY MAY BE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:350F,177C Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER/FOAM MAY CAUSE FROTHING. USE WATER TO KEEP FIRE-EXPOS CNTNRS COOL. WATER SPRAY MAY BE USED TO(SUPDAT) Unusual Fire/Explosion Hazard:PRODS OF COMBUST MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OTHER TOX MATLS. DO NOT ENTER ENCLSD/CONFINED SPACE W/OUT PROPER PROT EQUIP INCL NIOSH/ (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:NOTE:REVIEW FIRE & EXPLO HAZS & SAFETY PRECS BEFORE PROCEEDING W/CLEAN UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN UP. DIKE SPILL. PREVENT LIQ FROM ENTERING SEWERS, WATERWAYS/LOW AREAS. RECOVER FR EE LIQ FOR REUSE/RECLAMATION. SOAK UP W/ (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE I/A/W NFPA REGULATIONS. Other Precautions:AVOID CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE NORMALLY REQUIRED EXCEPT UNDER UNUSUAL CIRCUMSTANCES SUCH AS DESCRIBED IN THE FIRE & EXPLOSION SECTION. Ventilation:NORMAL SHOP VENTILATION. Other Protective Equipment:COVERALLS IF SPLASHING IS PROBABLE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health FIRE FIGHT PROC:FLUSH SPILLS AWAY FROM EXPOS. EXPLO HAZ:MSHA APPRVD RESP PROT. FIRST AID PROC:ADMIN. TO PREPARE ACTIVATED CHARCOAL SLURRY, SUSPEND 50 GRAMS ACTIVATED CHARCOAL IN 400 ML WATER & MIX THO RO. ADMIN 5 ML/KG OR 350 ML FOR AVG ADULT. SPILL PROC: SAWDUST, SAND, OIL DRY/OTHER ABSORB MATL. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>750F,>399C Vapor Pres:NIL Vapor Density:>1 Spec Gravity:0.91 (H2O=1) Evaporation Rate & Reference:NIL Solubility in Water:INSOLUBLE Appearance and Odor:CLOUDY LIQUID; MILD PETROLEUM HYDROCARBON ODOR. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE W/STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID HEAT & FLAME. Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE; INCOMPLETE COMBUSTION MAY PRODUCE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STOR, TRANSPORTATION & DISP MUST BE I/ A/W APPLIC FED, STATE/PROVINCIAL & LOC REGS. DO NOT FLUSH TO SURF WATER/ SANIT SEWER SYS. MATL, WHEN DISCARDED/DISP OF, IS NOT SPECIFICALLY LISTED AS HAZ WASTE IN FED REGS; HOWEVER, IT COULD BE (ING 2
1
gloves_mandatory
===================== Product Identification ===================== Product ID:AMORPHOUS SILICA, PRECIPITATED SILICIC ACID, 7736 CAGE:DO242 CAGE:63612 CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL CAS:63231-67-4 RTECS #:VV7340000 Fraction by Wt: 100% OSHA PEL:80 MG/M3 / % SIO2 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE IRRITATING TO SKIN, EYES AND MUCOUS MEMBRANES. PROLONGED OR REPEATED INHAL MAY CAUSE DAMAGE TO RESP SYSTEM. MAY IRRITATE EYES ON CONTACT. PROLONGED OR REPEATED INHALATION OF DUST MAY CAUSE DAMA GE TO RESPIRATORY SYSTEM. PROLONGED OR REPEATED INHALATION OF DUST MAY CAUSE DAMAGE TO RESP SYSTEM. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE IRRITATION. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE IF ANY ADVERSE EFFECTS SHOULD DEVELOP. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. EYES:IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR;GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGEST:GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONCOMBUSTIBLE Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE INDICATED ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER EXPOS/PERSONAL PROT. ELIMINATE ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLOS/FIRE HAZ. CONTAIN RELEASE AND ELIMINATE ITS SOURCE, IF THIS CAN (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. DO NOT BREATHE DUST. DO NOT GET IN EYES. AVOID PRLNGD/RPTD, SKIN CNTCT. WHEN POURING INTO CNTNR OF FLAMM LIQ, (SUPP DATA) Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SPILL PROC:BE DONE W/OUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP. COMPLY W/FED, STATE & LOC REG ON REPORTING RELEASES. REFER TO REGULATORY INFO FOR REPORTABLE QTY & OTHER REGULATORY DATA. HNDLG/STOR PREC:GROUNDBOTH CNTNRS ELEC TO PRVNT ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:3110F,1710C Spec Gravity:2.2 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:WHITE, ODORLESS POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID Stability Condition to Avoid:HEATING ABOVE 600F (WILL DESTROY DESICCANT PROPERTIES) Hazardous Decomposition Products:NONE INDICATED ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL DOES NOT HAVE AN EPA WASTE NUMBER & IS NOT A LISTED WASTE, HOWEVER CONSULTATION W/PERMITTED WASTE DISP SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONTACT PERMITTED WASTE DISPOSER(TSD) TO ASSURE C OMPLIANCE WITH ALL CURRENT LOC, STATE &FED REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PIGMENTED POLYMER TT-P-115F TYPE I YELLOW CAGE:OBRN9 CAGE:33832 CAGE:OBRN9 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 27% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 18% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC NAPTHA Fraction by Wt: 55% ACGIH TLV:300 PPM Ingred Name:VOC. ORGANIC CMPD 3.67 LB/GAL LESS WATER & NPRS* 441 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:PROLONGED/REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE CAN BE HARMFUL OR FATAL. Effects of Overexposure:HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYE AND RESPIRATORY TRACT. MAY CAUSE HEADACHES, DIZZINESS, AND PROLONG SKIN CONTACT IRRITATES. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 15 MINS. OR UNTIL IRRITATION SUBSIDES CALL A PHYSICIAN. SKIN: WASH THOROUGHLY W/SOAP AND WATER, REMOVE CONTAMINATED CLOTHES INHAL: REMOVE TO FRESH AIR CALL A PHYSIC IANINGST: DO NOT INDUCE VOMITING, CALL A PHYSICIAN ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:60F/15.56C Lower Limits:1.0 Upper Limits:7.6 Extinguishing Media:CARBON DIOXIDE, FOAM, WATER FOG, DRY CHEMICAL Fire Fighting Procedures:USE AIR SUPPLIED BREATHING EQUIPMENT FOR ENCLOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPOR OR FUMES. Unusual Fire/Explosion Hazard:IF LEAK OR SPILL HAS IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS FROM FIRE FIGHTERS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. KEEP FROM HEAT, SPARKS, OPEN FLAMES. ADD ABSORBENT TO SPILL. IF LGSPILL KEEP PRODUCT FROM ENTERING SEWERS/WTRCOURSESBY DIKING. ADVISE AUTHORITIES IF PRODUCT HAS ENTER ED. ======================Handling and Storage ====================== Handling and Storage Precautions:HAZARDOUS CLASSIFICATION FLAMMABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE HYDROCARBON VAPOR CANISTER OR SUPPLIED AIR RESPIRATORY IN CONFINED AREA. Ventilation:LOCAL EXHAUST OR MECHANICAL Other Protective Equipment:CHEMICAL RESISTANT APRON OR OTHER CLOTHING Work Hygienic Practices:WASH HAND THOROUGHLY AFTER USE AND KEEP CONTAINER CLOSEDWHEN NOT IN USE. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:230F Vapor Pres:25 Vapor Density:4 Spec Gravity:1.42 Evaporation Rate & Reference:1.2 Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW LIQUID WITH PAINT SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAN REACT WITH OXIDIZING MATERIALS WHEN HEATED TO DECOMPOSITION. Stability Condition to Avoid:HIGH TEMPERATURE Hazardous Decomposition Products:CARBON MONIXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ABSORBED MATERIAL AT AN APPROVED DISPOSAL SITE OR FACILITY.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ECLIPSE GOLD CLEANER EGC2502 CAGE:0NLM0 CAGE:0NLM0 ============= Composition/Information on Ingredients ============= Ingred Name:DIPROPYLENE GLYCOL, MONOMETHYL ETHER; (2-PROPANOL, 1-(2-METHOXY-1-METHYLETHOXY)) CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 5-10% OSHA PEL:100 PPM;150 STEL; S ACGIH TLV:100 PPM;150 STEL; S ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:SLIGHTLY IRRIT TO EYES. SKIN:IRRIT TO SKIN UPON REPEATED OR PROLONGED CONTACT. INHAL:VAPOR OR MIST CAN CAUSE HDCH, NAUS, AND IRRIT OF NOSE, THROAT, AND LUNGS. INGEST:IRRIT TO MOUTH, ESOPHAGUS, AN D STOMACH. PRLNGD/RPTD CONTACT CAN CAUSE DRYING, DEFATTING AND DERM TO SKIN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEE A PHYSICIAN IF IRRITATION PERSISTS. SKIN:WASH AFFECTED AREAS WITH SOAP AND WATER. INHAL:MOVE SUBJECT TO FRESH AIR. INGEST:INDUCE VOM ITING. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRES . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MATERIALS CAN SPLATTER ABOVE 100C/212F. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS:ABSORB SPILL ON INERT MATERIAL (E.G. SAND, EARTH) AND DISPOSE OF AS WASTE MATERIAL IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAW. LG SPILLS:KEEP SPECTATORS AWAY. FLOORS MAY BE SLIPPERY ; USE CARE TO AVOID FALLING. DIKE AND (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE TEMPERATURE (MAX. 60C/140F) (MIN. 1C/34F). Other Precautions:KEEP FROM FREEZING, PRODUCT MAY COAGULATE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN PERMISSIBLE AIRBORNE CONCENTRATIONS ARE NOT EXCEEDED. IN EMERGENCY, USE NIOSH/MSHA APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING DEVICE. Ventilation:MECHANICAL LOCAL EXHAUST VENTILATION AT POINT OF CONTAMINATION RELEASE. Other Protective Equipment:AS REQUIRED BY EMPLOYER CODE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH:9.00+/-0.25. % VOL:92.0+/-0.5% (WT). WASTE DISP METH:DIKING MATL ACCORD TO LOCAL, STATE, & FED REGS. SPILL PROC: CONTAIN SPILL W/INERT MATL (E.G. SAND, EARTH). TRANSFER LIQ TO CNTNRS FOR RECOVERY/D ISP & SOLID DIKING MATL TO SEPARATE CNTNRS FOR DISP. KEEP SPILLS & CLEANING RUNOFF OUT OF SEWERS & OPEN BODIES OF WATER. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:212F,100C Vapor Density:<1 Spec Gravity:1.02 pH:SUPDAT Evaporation Rate & Reference:<1 (WATER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR YELLOW LIQUID. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:COAGULATE EMULSION BY STEPWISE ADDITION OF FERRIC CHLORIDE AND LIME. REMOVE CLEAR SUPERNATANT LIQ & FLUSH TO A CHEM SEWER OR DRUM LIQ WASTE & TURN IT OVER TO A LICENSED HAZ WASTE DISP FACILITY FOR DIS P, LANDFILL, OR INCIN SOLIDS & CONTAM (SUPP DATA)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:X17GS5565 SODIUM SACCHARIN GRANULAR CAGE:PMCSP CAGE:0T805 CAGE:PMCSP ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SACCHARINE, SODIUM SACCHARIN (ANIMAL CARCINOGEN BY IARC; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2B) *98-2* CAS:128-44-9 RTECS #:DE4550000 Fraction by Wt: 85-86% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 14-15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:IRRITATION TO THE EYES, SKIN & RESPIRATORY TRACT. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: WASH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & RECLAIM/PLACE IN A COVERED WASTE DISPOSAL CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT ON STORAGE TO PREVENT CAKING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:3M 9900, AMER. OPTICAL R 5030, WILLSON 1211, NORTON 7506/EQUIVALENT NIOSH TC-21C. Ventilation:LOCAL EXAUST RECOMMENDED FOR DUST CONTROL. Other Protective Equipment:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:>1 Solubility in Water:46%/WT Appearance and Odor:WHITE NON DUSTING GRANULES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:CO, NITROGEN OXIDES, SULFUR OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE/HEAT IN A CLOSED CONTAINER.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DOW CORNING FS 1265 FLUID, 1000CST. Resp. Party Other MSDS Num.:01160460 CAGE:5D028 CAGE:5D028 ============= Composition/Information on Ingredients ============= Ingred Name:THIS IS NOT A HAZARDOUS MATERIAL AS DEFINED IN THE OSHA HAZARD COMMUNICATION STANDARD ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: DIRECT EYE CONTACT MAY CAUSE TEMPORARY DISCOMFORT WITH MILD REDNESS AND DRYNESS SIMILAR TO WINDBURN. SKIN: A SINGLE PROLONGED EXPOSURE (24 TO 48 HOURS) CAUSES NO KNOWN ADVERSE EFFECT. INHALATION: NO IRRITATION TO EYES AND RESPIRATORY PASSAGES. NO INJURY IS LIKELY FROM RELATIVELY SHORT EXPOSURES OF LESS THAN 8 HOURS. ORAL: SMALL AMOUNTS TRANSFERRED TO THE MOUTH BY FINGERS DURING USE, ETC., SHO ULD NOT INJURE. SWALLOWING LARGE AMOUNTS MAY CAUSE DIGESTIVE DISCOMFORT. REPEATED EXPOSURE EFFECTS: SKIN-NONE KNOWN. INHALATION-NONE KNOWN. ORAL: NONE KNOWN. Explanation of Carcinogenicity:NONE KNOWN. Effects of Overexposure:EYE: DIRECT EYE CONTACT MAY CAUSE TEMPORARY DISCOMFORT WITH MILD REDNESS AND DRYNESS SIMILAR TO WINDBURN. SKIN: A SINGLE PROLONGED EXPOSURE (24 TO 48 HOURS) CAUSES NO KNOWN ADVERSE EFFECT. INHALATION: NO IRRITATION TO EYES AND RESPIRATORY PASSAGES. NO INJURY IS LIKELY FROM RELATIVELY SHORT EXPOSURES OF LESS THAN 8 HOURS. ORAL: SMALL AMOUNTS TRANSFERRED TO THE MOUTH BY FINGERS DURING USE, ETC., SHO ULD NOT INJURE. SWALLOWING LARGE AMOUNTS MAY CAUSE DIGESTIVE DISCOMFORT. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH WATER. SKIN: NO FIRST AID SHOULD BE NEEDED. INHALATION: NO FIRST AID SHOULD BE NEEDE. ORAL: NO FIRST AID SHOULD BE NEEDED. COMMENTS: TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>101.C, 213.8F Autoignition Temp:Autoignition Temp Text:N/D Lower Limits:N/D Upper Limits:N/D Extinguishing Media:WATER SPRAY. CARBON DIOXIDE(CO2). DRY CHEMICAL. FOAM. WATER CAN BE USED TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING LARGE FIRES INVOLVING CHEMICALS. EVACUATE AREA IN CASE OF OVERHEATING OR FIRE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP REMAINING MATERIALS FROM SPILL WITH SUITABLE ABSORBENT. CLEAN AREA AS APPROPRIATE SINCE SOME SILICONE MATERIALS, MAY PRESENT A SLIP HAZARD. FINAL CLEANING MAY REQUIRE USE OF STEAM, SOLVENTS O R DETERGENTS. FOR LARGE SPILLS, PROVIDE DIKING OR OTHER APPROIOPRIATE CONTAINMENT TO KEEP MATERIAL FROM SPREADING. IF DIKED MATERIAL CAN BE PUMPED, STORE RECOVERED MATERIAL IN APPRIATE CONTAINER. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. THIS MATERIAL MAY FORM HIGHLY TOXIC VAPOR OF TRIFLUOROPIONALDEHYDE IF HEATED IN AIR ABOVE 300F(149C). PROVIDE VENTILATION TO CONTROL VAPOR EXPOSURE (INHALATION GUIDELINE S HAVE NOT BEEN ESTABLISHED). AVOID EYE CONTACT. Other Precautions:STORAGE: NO SPECIAL PRECAUTION. USE REASONABLE CARE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:LOCAL: NONE SHOULD BE NEEDED. GENERAL: RECOMMENDED. Other Protective Equipment:NO DATA PROVIDED BY RESPONSIBLE PARTY. Work Hygienic Practices:AVOID EYE CONTACT. USE REASONABLE CARE. WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. Supplemental Safety and Health THIS MATERIAL MAY FORM HIGHLY TOXIC VAPORS OF TRIFLUOROPROPIONALDEHYDE IF HEATED IN AIR ABOVE 300F (149C). PROVIDE VENTILATION TO CONTROL VAPOR EXPOSURE. NOTE: ALL THE ABOVE PRECAUTIONS ARE FOR ROOM T EMPERATURE HANDLING. USE AT ELEVATED TEMPERATURES MAY REQUIRE ADDED PRECAUTIONS. ================== Physical/Chemical Properties ================== HCC:V5 Vapor Pres:N/D Vapor Density:N/D Spec Gravity:1.27 Viscosity:1000.00 CST Solubility in Water:N/D Appearance and Odor:COLORLESS LIQUID; SLIGHT ODOR Percent Volatiles by Volume:N/D ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL CAN CAUSE A REACTION. Stability Condition to Avoid:NONE Hazardous Decomposition Products:MAY FORM HIGHLY TOXIC VAPORS OF TRIFLUOROPROPIONALDEHYDE IF HEATED IN AIR ABOVE 300F/149C. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:COMPLETE INFORMATION NOT YET AVAILABLE. ===================== Ecological Information ===================== Ecological:COMPLETE INFORMATION NOT YET AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN A DECISION IS MADE TO DISCARD THIS MATERIAL IT IS NOT CLASSIFIED AS A HAZARDOUS WASTE. FEDERAL HAZARDOUS WASTE CODE: N/A. CHARACTERISTIC WASTE: N/A. STATE OR LOCAL LAWS MAY IMPOSE ADDITIONAL REGU LATORY REQUIREMENTS REGARDING DISPOSAL. =================== MSDS Transport Information =================== Transport Information:US DOT INFORMATION (49 CFR 172.101): PROPER SHIPPING NAME: NOT APPLICABLE. HAZARD TECHNICAL NAME: NOT APPLICABLE. HAZARD CLASS: NOT APPLICABLE. UN/NA NUMBER: 0000. PACKING GROUP: N/A. N/A=NOT APPLICAB LE. CALL DOW CORNING TRANSPORTATION (517-496-8577) IF MORE INFORMATION NEEDED. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: NONE. SECTION 304: NONE. SECTION 312 HAZARD CLASS: ACUTE-NO, CHRONIC-NO, FIRE-NO, PRESSURE-NO, REACTIVE-NO. SECTION 313 TOXIC CHEMICALS: NONE PRESENT OR NON E PRESENT IN REGULATED QUANTITIES. Federal Regulatory Information:CONTENTS OF THIS MSDS COMPLY WITH THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. TSCA STATUS: ALL CHEMICAL SUBSTANCES FOUND IN THIS PRODUCT COMPLY WITH THE TOXIC SUBSTANCES CONTROL ACT INVE NTORY REPORTING REQUREMENTS. State Regulatory Information:WARNING: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) LISTED BY THE STATE OF CALIFORNIA UNDER THE SAFE DRINKING WATER AND TOXIC INFORMATION ACT OF 1986 (PROPOSITION 65) AS BEING KNOWN TO CAUSE CANC ER: NONE. WARNING: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) LISTED BY THE STATE OF CALIFORNIA UNDER THE SAFE DRINKING WATER AND TOXIC INFORMATION ACT OF 1986 (PROPOSITION 65) AS BEING KNOWN TOCAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: NONE. MASSACHUSETTS: NO INGREDIENT REGULATED BY MA R IGHT-TO-KNOW LAW PRESENT. NEW JERSEY & PENNSYLVANIA: 063148561, 100, TRIFLUOROPROPYLMETHYL SILOXANE, TRIMETHYL TERMINATED. ======================= Other Information =======================
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:550028-11 TF SOLUTION/CLEANING SOLUTION CAGE:PERFE CAGE:PERFE CAGE:60902 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9293 Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) 43000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OF VERY HIGH CONCENTRATIONS MAY CAUSE ASPHYXIATION. SWALLOWING MAY CAUSE GI TRACT IRRITATION. CONTACT WITH EYES MAY CAUSE MINOR IRRITATION. SKIN CONTACT MAY CAUSE DEFATTING OR IRRITA TION. CHRONIC: PROLONGED OR REPEATED INHALATION MAY CAUSE LIGHTHEADEDNESS, GIDDINESS, NARCOSIS, UNCONSCIOUSNESS, DEATH. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALED: LIGHTHEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, NARCOSIS, UNCONSCIOUSNESS, DEATH. EYES: REDNESS, DISCOMFORT. SKIN: DRYNESS, REDNESS, DISCOMFORT. INGESTED: NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASES MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALED: MOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING STOPPED. GET IMMEDIATE MEDICAL ATTENTION. EYES: FLUSH WITH WATER FOR 15 MINUTES, HOLD LIDS OPEN. GET IMMEDIATE MEDICAL ATTENTION. S KIN: FLUSH WITH WATER. SEE DOCTOR IF SYMPTOMS PERSIST. INGESTED: DO NOT INDUCE VOMITING! GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. EXTINGUISH SOURCES OF IGNITION; PRODUCT DECOMPOSES UNDER HEAT TO TOXIC/HAZARDOUS VAPORS/FUMES. Unusual Fire/Explosion Hazard:DECOMPOSES UNDER HIGH TEMPERATURS TO TOXIC/HAZARDOUS HYDROCHLORIC AND HYDROFLUORIC ACIDS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROPER PROTECTIVE CLOTHING. REMOVE ALL OPEN FLAMES. MOP OR WIPE UP, PLACE IN A CONTAINER FOR LATER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FOM SOURCES OF OPEN FLAME, DIRECT SUNLIGHT, OR TEMPERATURES ABOVE 120F. Other Precautions:DO NOT CUT, GRIND, WELD, OR DRILL NEAR THIS CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR CONDITIONS WARRANT; USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR SUPPLIED AIR RESPIRATOR, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.134. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CLOTHING TO PREVENT PROLONGED OR REPEATED SKIN CONTACT. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health DO NOT WEAR CONTACT WHEN USING THIS MATERIAL. ================== Physical/Chemical Properties ================== HCC:V2 Boiling Pt:=47.8C, 118.F Melt/Freeze Pt:=-.6C, 31.F Vapor Pres:334 MM HG Vapor Density:2.9(AIR=1) Spec Gravity:1.57 (WATER=1) Evaporation Rate & Reference:>1 (CCL4=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID; SLIGHT ETHERAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS, OXIDIZING AGENTS, WATER AND MOIST AIR, ALKALINE EARTH METALS, POWDERED ALUMINUM AND ZINC. Stability Condition to Avoid:OPEN FLAMES, WELDING ARCS, OR OTHER HIGH TEMPERATURES WHICH CAUSE THERMAL DECOMPOSITION. Hazardous Decomposition Products:OXIDES OF CARBON, HYDROGEN CHLORIDE, CHLORINE, PHOSGENE, HYDROGEN FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE OR PUNCTURE AEROSOL CANS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PARCO CLEANER 2192 CAGE:69505 CAGE:71410 CAGE:69505 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: >60% Other REC Limits:N/K OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT WITH EYES CAN CAUSE BLINDNESS.INGESTION/INHALATION CAN RESULT IN GI AND RESPIRATORY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:SEVERE BURNS AND POSSIBLE BLINDNESS.SKIN:SEVERE BURNS AND POSSIBLE ULCERATION OF SKIN AND MUCOUS MEMBRANES.INGESTION:GI DAMAGE,BURNS OF THE DIGESTIVE TRACT.INHALATION:MIST CAN CAUSE BURNS TO THE RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED PULMONARY FUNCTION AND PRE-EXISTING CHRONIC SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH IN DIRECT STREAM OF H*2O FOR AT LEAST 15 MIN WITH LIDS HELD APART.GET MED ATTN.SKIN:IMMED REMOVE CONTAM CLTHG/SHOES.FLUSH W/ H*2O FOR AT LEAST 15 MIN.RINSE CLTHG.IF IRRIT PERSISTS,GET MED ATTN.INGEST:DRINK LRG AMT H*2O.CORROSIVE.DO NOT INDUCE VOMITING.IF VOMITING OCCURS,DRINK MORE H*2O.GET MED ATTN.NEVER GIVE ANYTHING BY MOUTH IF UNCON.INHAL:REMOVE TO FRESH AIR AND (SEE SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NON-FLAMM Upper Limits:NON-FLAMM Extinguishing Media:AS REQUIRED BY THE SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING.SWEEP UP OR OTHERWISE COLLECT AND STORE IN SUITABLE DRUM.FLUSH THE CONTAMINATED AREA WITH WATER. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE/USE IN LOCATION W/ DIRECT ACCESS TO SANITARY/SURFACE DRAINS.CONSTRUCT AREAS SO CHEMICALS LOST CAN BE SALVAGED OR TREATED W/O POLLUTION. Other Precautions:STORE IN VENT AREA AWAY FROM DIRECT HEAT & AWAY FROM ACIDS.DO NOT GET IN EYES,ON SKIN OR ON CLOTHING.DO NOT BREATHE DUST OR TAKE INTERNALLY.FOR INDUSTRIAL USE ONLY.WHEN ADDING TO COLD SOLN:ADD DRY CHE M SLOWLY TO THE SURFACE OF (SEE SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:AS REQUIRED TO AVOID CONTACT.EYE WASH FACILITY & EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH:1% SOLUTION,STRONGLY BASIC.FIRST AID PROC:REMOVE CONTAM CLTHG.IF BRTHG IS DIFFICULT,GIVE O*2.IF RESP STOPS,GIVE MOUTH-TO-MOUTH RESUSCITATION.GET MED ATTN.OTHER PREC:THE SOLN TO DISSOLVE CHEM & AVOI D SPATTERING.ADDING TO HOT SOLN:ADD TO COLD WATER W/ STIRRING,COOL OR DILUTE & POUR SLOWLY INTO HOT SOLN WHILE STIRRING. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Spec Gravity:N/K pH:SUP DA Evaporation Rate & Reference:N/K Solubility in Water:COMPLETE Appearance and Odor:WHITE POWDER WITH SLIGHT ORGANIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES KEEP SEPARATE FROM ACIDS. Stability Condition to Avoid:N/K Hazardous Decomposition Products:NONE Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .THIS CHEMICAL CONTAINS A CHELATING AGENT.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ENAMEL ALKYD, SEMI GLOSS LO VOC CT GRAY 26134, ID 775611 Preparer's Name:W A ELLISON CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (SOLVENT) (VAPOR PRESSURE 10 MM HG @ 20C) (LFL 1.7; UFL 7.6) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM;STEL 200 PPM ACGIH TLV:150 PPM;STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENE (SOLVENT) (SARA III) (VAPOR PRESSURE 5 MM HG @ 20C) (LFL 1.0; UFL 7.0) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE (PIGMENT) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SILICA, CRYSTALLINE (PIGMENT) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:SILICA, CRYSTALLINE - TRIPOLI CAS:1317-95-9 RTECS #:VV7336000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:TALC (PIGMENT) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 20% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3; 20 MPPCF ACGIH TLV:2 MG/M3; 15 MPPCF Ingred Name:METHYL ISOAMYL KETONE (SOLVENT) CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM; 240 MG/M3 ACGIH TLV:50 PPM; 240 MG/M3 Ingred Name:METHYL ETHYL KETONE (SOLVENT) (SARA III) (VAPOR PRESSURE 70 MM HG @ 20C) (LFL 2.0; UFL 10.0) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM;STEL 300 PPM ACGIH TLV:200 PPM;STEL 300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MINERAL SPIRITS (SOLVENT) (VAPOR PRESSURE 2 MM HG @ 20C) (LFL: 1.0 UFL: 7.0) CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM; 525 MG/M3 ACGIH TLV:100 PPM; 525 MG/M3 Ingred Name:VOC: 2.88 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS; 346 G/L LESS WATER; CALCULATED RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES Health Hazards Acute and Chronic:ACUTE; INGEST: GASTROINTESTINAL IRRIT, NAUSEA, VOMITING. ASPIRATION INTO LUNG MAY CAUSE CHEM PNEUMONITIS (CAN BE FATAL). INHAL: NOSE OR THROAT IRRIT. ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHES , DIZZINESS, NAUSEA, CONFUSION). EYE: SEVERE IRRIT. SKIN: ABSORBED THROUGH SKIN IN HARMFUL AMTS. DEFATTING & SKIN IRRIT. Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS & SUFFICIENT IN ANIMALS. Effects of Overexposure:CHRONIC; SILICOSIS (DISABLING LUNG DISEASE). LIVER, KIDNEY AND BLOOD INJURY. ENHANCES NEUROTOXICITY (SYNERGISTIC EFFECT RESULTED IN PERIPHERAL NEUROPATHY). PROLONGED & REPEATED OVEREXPOSURE: PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. CONCENTRATING & INHALING PRODUCT MAY BE HARMFUL OR FATAL. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. ======================= First Aid Measures ======================= First Aid:INGEST: DONT INDUCE VOMITING. CALL POISON CTR/EMERG ROOM/DR IMMED. INHAL:REMOVE TO FRESH AIR IMMED. IF BREATHING STOPPED, GIVE ARTIF RESPRTN. KEEP WARM & QUIET. GET MED AID IMMED. EYE: FLUSH W/WATER 1 5 MIN, LIFTING EYELIDS. GET MED AID. SKIN: REMOVE CONTAM CLOTHES. WASH AFFECTED AREA W/SOAP & WATER. GET MED AID IF IRRIT PERSISTS. NOTE TO DR:DIRECT TREATMENT AT CLINICAL CONDITION & SYMPTOM CONTROL. ===================== Fire Fighting Measures ===================== Flash Point:24.0F,-4.4C Autoignition Temp:Autoignition Temp Text:572 F Lower Limits:1.0 Upper Limits:10.0 Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO2, DRY CHEMICAL, ALCOHOL FOAM) FOR FLAMMABLE LIQ. POLYMER FOAM PREFERRED FOR LARGE FIRES. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL EXPOSED CONTAINERS (FOG NOZZLES PREFERRED) TO PREVENT PRESSURE BUILDUP, AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO HEAT. Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY BE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. GET MEDICAL AID. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNITION SOURCES. DIKE & CONTAIN WITH INERT MATERIAL (SAND, EARTH, ETC). TRANSFER LIQUID OR USED ABSORBENT TO COVERED METAL CONTAINER. USE NON-SPARKING TOOLS. PREVE NT SEWER, STREAM, OR GROUNDWATER CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 115 F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106. DO NOT TAKE INTERNALLY. DO NOT BREATHE SANDING DUST. Other Precautions:CLOSE CONTAINER AFTER EACH USE. DO NOT WASH & REUSE EMPTY CONTAINER FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO RECEIVING CONTAINER. DO NOT WELD, BRAZE, OR CUT ON EMPTY CONTAINER. NEVER USE PRESSURETO EMPTY. DRUM IS NOT A PRESSURE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTD,MAY NOT REQ RSPRTR.IN RESTRICTD VENT,NIOSH CHEM CARTRIDGE RSPRTR MAY BE REQ'D.SPRAYNG,MECHAN PREFILTER MAY ALSO BE REQ'D.CONFIND AREAS,USE AIR SUPPLD RSPRTR.SEE OSHA 29CFR1910.134"RESP PROTEC T"&"RESP PROTECT-MANUAL & GUIDELINE"AIHA Ventilation:LOCAL EXHAUST VENT TO KEEP BELOW TLV. REMOVE DECOMPOSITION PRODUCT. SEE "INDUST VENT-MANUAL RECOMMENDED PRACTICES" ACGIH Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175 TO 388F Melt/Freeze Pt:M.P/F.P Text:-50F,-46C Decomp Temp:Decomp Text:1832F,1000C Vapor Pres:70 @ 68F Vapor Density:> AIR Spec Gravity:1.3 pH:4-7 Viscosity:67 - 77 KU Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Solubility in Water:SLIGHT IN WATER Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F) AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, & LOCAL LAWS OR REGULATIONS. THIS PRODUCT, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED A HAZARDOUS WASTE BASED ON ITS IGNITABILITY CHARACTERISTIC (FLASH POINT 140F OR LESS). PROPER RCRA CLASSIFICATION: D001.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:INTERGARD HS UNIV EPOXY LTC REAC FCA321 PTB CAGE:26351 CAGE:26351 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 10-15% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9192 Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 1-5% OSHA PEL:300 PPM/400 STEL ACGIH TLV:300 PPM; 9192 Ingred Name:DIETHYLENE TRIAMINE CAS:111-40-0 RTECS #:IE1225000 Fraction by Wt: 1-5% OSHA PEL:1 PPM ACGIH TLV:S, 1 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NK UNLESS OTHERWISE NOTED. CHRONIC OVEREXPOSURE TO AND MISUSE OF, SOLVENTS HAS BEEN LINKED TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Effects of Overexposure:EYES: EXTREMELY IRRI. LIQ CAUSES EYE BURNS. SKIN: MAY CAUSE BURNS, SENSITIZATIONALLERGIC RESPONSES. INHAL: IRRI OF RESPIRATORY TRACT. HEADACHE, DIZZINESS AND UNCONSCIOUSNESS. & INGESTION: GASTRO-INTES TINAL IRRI, NAUSEA, VOMITING AND DIARRHEA Medical Cond Aggravated by Exposure:SKIN AND RESPIRATORY CONDITIONS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMED W/COPIOUS QUANT OF WTR 15 MIN. GET MED ATTN IMMED. SKIN: REMOVE CONT CLOTHING, WASH SKIN W/PLENTY OF SOAP & WATER. LAUNDER CLOTHES BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. GET MED ATTN. & INGESTION:CALL A PHYSICIAN IMMED TO DETERMINE WHETHER OR NOT TO INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:141 F 60.56 C Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:SMOTHER FLAMES W/EXTING MEDIA. WTR MAY BE USED TO COOL UNOPENED CONT. BUT NOT ANEXTING MEDIA. PREVENT SPREAD BURNING LIQ W/WTR. CLOSED CONT MAY EXPLODE HEATED Unusual Fire/Explosion Hazard:NK UNLESS OTHERWISE NOTED. CONTAINS FLAMM SOLVENT. DO NOT USE IN AREAS WHERE SPARKS OR OPEN FLAME ARE PRESENT. CLOSED CONT MAY EXPLODE WHEN EXPOSED TO HEAT ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID INHALATION OF VAPORS. VENTILATE AREA. CLEAN UP WITH ABSORBANT MATERIALS ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLD DESIGNED/PROTECTED FOR STORAGE OF LIQW/NFPA CL GIVEN BY OSHA. AVOID BREATHING DUST/CHIPFROM SANDING/BLASTING SURFACES COATED W/PRODUCT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR/OPEN AREAS, UNRESTRICTED VENT USE A NIOSH APPROVED FILTER RESPIRATOR REMOVE SOLID AIR-BORNE PARTICLES OF OVERSPRAY. RESTRICTED VENT AREAS, USE A NIOSH APPROVED RESPIRATOR TO REMOVE A COMBINATI ON OF PARTICULATES & VAPOR Ventilation:SUFFICIENT VENT IN VOL & PATTERN TO KEEP TLV/LEL OF HAZARD INGRED BELOW LIMITS & TO REMOVE DECOMP PRODUCT (WELDING, ETC) Other Protective Equipment:WEAR APPROPRIATE IMPERVIOUS PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health NONE KNOWN UNLESS OTHERWISE NOTED. CHRONIC OVEREXPOSURE TO & MISUSE OF SOLVENTS HAS BEEN LINKED TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:200-482 F Vapor Density:> AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:16 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:PROTECT FROM FREEZING. STORE AWAY FROM DIRECT HEAT, FLAME ORSPARK Hazardous Decomposition Products:CO, CO2, VARIOUS HYDROCARBON FRAGMENTS NITROGEN COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE UNOPENED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CENTARI 5000 ENAMEL, 516H CAGE:B0589 CAGE:90227 CAGE:B0589 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC RESIN CAS:70942-12-0 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID, BUTYL ESTER; (BUTYL ACETATE) (SARA III) VP: 8 @ 120C CAS:123-86-4 RTECS #:AF7350000 OSHA PEL:150 PPM ACGIH TLV:150 PPM; 200 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA III) VP: 71 @ 120C CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5% OSHA PEL:200 PPM ACGIH TLV:200 PPM; 300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PIGMENT, VIOLET; (QUINACRIDONE PIGMENT) CAS:1047-16-1 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA III) VP: 36.7 @ 120C CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 58% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (1,6 HEXAMETHYLENE DIISOCYANATE) CAS:822-06-0 RTECS #:MO1740000 OSHA PEL:N/K ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SUPDAT: TO SHORTEN TIME OF ONSET OF THE PERIPHERAL NEUROPATHY CAUSED BY ETHER N-HEXANE OR METHYL N-BUTYL KETONE. (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: MEK BY ITSELF HAS NOT BEEN DEMONSTRATED TO CAUSE PERIPHERAL NEUROPATHY. LIQ SPLASHES IN EYE MAY RSLT IN (ING 9) RTECS #:9999999ZZ Other REC Limits:NONE RECOMMENDED Ingred Name:ING 8: CHEM BURNS. TOLUENE APPEARS ON THE NAVY LISTING OF OCCUP CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . RECURRENT OVEREXP TO (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: TOLUENE MAY RSLT IN LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRDCED IRREGULAR HEARTBEATS IN (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: ANIMALS & OCCAS PALPITATIONS IN HUMANS. RATS EXPOS TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: FREQUENCY HEARING DEFICITS. THE SIGNIFICANCE OF THIS TO MAN IS UNKNOWN. RTECS #:9999999ZZ Ingred Name:SPILL PROC: SPILL & ALLOW TO SIT 10 MIN, MINIMUM. TYPICAL DECONTAM SOLNS ARE: 20% SURFACTANT (TERGITOL TMN 10) (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: & 80% WATER OR 0-10% AMMONIA, 2-5% DETERGENT, BALANCE WATER. RTECS #:9999999ZZ Ingred Name:RESP PROT: PROBS/PRIOR RXN TO ISOCYANATE SHOULD NOT USE/BE EXPOSED TO PROD. DO NOT PERMIT ANYONE W/OUT PROT (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: IN PAINTING AREA. FOLLOW THE RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST: GI DISTRESS. INHAL: MAY CAUSE NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLV MAY LEAD TO PERM BRAIN & NERVOUS SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORDINATION ARE SIGNS THAT S OLV LEVELS ARE TOO HIGH. EXPOS TO ISOCYANATES MAY CAUSE RESP SENSIT; MAY BE PERM. EFT MAY BE DELAYED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SEVERAL HRS AFTER EXPOS. RPTD OVEREXP TO ISOCYANATES MAY CAUSE DECR IN LUNG FUNC WHICH MAY BE PERM. PERS WITH BRTHG PROBS/PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOS TO VAPS/SPRAY MIST OF PRO D. SKIN/EYE CNTCT: MAY CAUSE IRRIT/BURNING OF EYES. RPTD/PRLNG LIQ CNTCT MAY CAUSE SKIN IRRIT W/DISCOMFORT & (SUPDAT) Medical Cond Aggravated by Exposure:PRE-EXISTING BREATHING PROBLEMS OR PRIOR ISOCYANATE REACTION. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY & HAVE NAMES OF INGREDIENTS AVAILABLE. INHAL: REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT MD. EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES; CALL MD. SKIN: WASH WITH SOAP & WATER. IF IRRITATION OCCURS, CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:100F,38C Lower Limits:0.9% Upper Limits:23.0% Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FL PT, EMITS FLAMM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN OR BE EXPLOSIVE. FINE MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW THE FL PT. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT BREATHE VAPS. DO NOT GET IN EYES/ON SKIN. WEAR POS PRESS SUPPLIED AIR VAP/PARTICULATE RESP (NIOSH/MSHA IGNIT. ABSORB W/INERT MATL . VENT AREA. POUR LIQ DECONTAM SOLN OVER (ING 14) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPK & FLAME. CLOSE CNTNR AFTER EACH USE. GROUND CNTNRS WHEN POURING. DO NOT STORE ABOVE 120F. Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WEAR POS PRESS SUPPLIED AIR RESP (NIOSH/MSHA APPRVD (TC-19C) WHILE MIXING ACTIVATOR W/ANY PAINT/CLEAR ENAMEL DURING APPLICATN & UNTIL ALL VAPS & SPRAY MISTS ARE EXHAUSTED. P ERS W/HISTORY OF LUNG/BRTHG (ING 16) Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS. Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . COVERALLS ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR SMOKING. Supplemental Safety and Health % VOLAT: 7.3-100. EFTS OF OVEREXP: DERM. BUTYL ACETATE MAY CAUSE ABNORM LIVER FUNC. TESTS FOR EMBRYOTOX ACTIVITY IN ANIMALS HAS BEEN INCONCLUSIVE. HAS BEEN TOX IN FETUS IN LAB ANIMALS AT DOSES THAT AR E TOX TO MOTHER. HIGH CONC OF METHYL ETHYL KETONE HAVE CAUSED EMBRYOTOX EFTS IN LAB ANIMALS. MEK HAS BEEN SHOWN (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>135F,>57C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.79-1.89 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORSEEABLE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:NICKEL ACETATE CAGE:EO906 CAGE:0BDV7 CAGE:EO906 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL ACETATE TETRAHYDRATE CAS:6018-89-9 RTECS #:QR6126000 Fraction by Wt: 100% ACGIH TLV:0.1 MG/CUM Ingred Name:_ Fraction by Wt: _ ACGIH TLV:_ ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN: MAY CAUSE ALLERGIC DERMATITIS (NICKEL ITCH OR RASH). ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IRRIGATE W/WATER FOR 15 MINUTES. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN. INGESTION: INDUCE VOMI TING IF CONSCIOUS. CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY Fire Fighting Procedures:WEAR SCBA WHEN LARGE QUANTITIES ARE INVOLVED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN THE SPILL. PICK UP THE SPILL IN AN APPROVED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. PROTECT AGAINST PHYSICAL DAMAGE. AVOID CONTACT WITH SKIN, EYES, CLOTHIN Other Precautions:AVOID BREATHING AND USE ONLY WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. NO FOOD OR BEVERAGE SHOULD BE CONSUM IN WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH RESP WHERE AIRBORNE LEVELS EXCEEDS <TLV/LEL. Ventilation:PROVIDE LOCAL EXHAUST/MECH VENTILATION TO KEEP BELOW TLV Other Protective Equipment:WEAR PROTECTIVE COVERALL/SAFETY SHOWER/EYEWASH STATIONS. Supplemental Safety and Health MSDS DATE: 01 NOV 85. ================== Physical/Chemical Properties ================== Spec Gravity:1.774 Solubility in Water:COMPLETE Appearance and Odor:LIGHT GREEN CRYSTAL, SLIGHT VINEGAR-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Hazardous Decomposition Products:TOXIC FUMES/METAL OXIDES MAY BE PRESENT DURING DECOMPOSITION ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:43P81, 8R3669, PLATEN GLASS, LENS AND MIRROR CLEANER Resp. Party Other MSDS Num.:D-0403A CAGE:26921 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL CAS:64-17-5 RTECS #:KQ6300000 Minumum % Wt:75. Maxumum % Wt:85. OSHA PEL:1900 MG/M3;1000 PPM ACGIH TLV:1880 MG/M3;1000 PPM ACGIH STEL:500 PPM Ingred Name:ISOPROPANOL CAS:67-63-0 RTECS #:NT8050000 Minumum % Wt:5. Maxumum % Wt:15. OSHA PEL:980 MG/M3;400 PPM ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:5. Maxumum % Wt:10. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (RATS) LD50: >21 G/KG. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE IRRITATNT.EYE: FLUSH THOROUGHLY WITH WATER. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. Explanation of Carcinogenicity:NO CARCINOGENS PRESENT IN PRODUCT. Effects of Overexposure:CENTRAL NEVOUS SYSTEM DEPRESSION, RESPIRATORY DISTRESS, AND GASTROINTESTINAL IRRITATION.EYE: FLUSH THOROUGHLY WITH WATER. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH THOROUGHLY WITH WATER. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=26.7C, 80.F Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, OR DRY CHEMICAL. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ESTIMATE SOURCES OF IGNITION. SMALL SPILLS SHOULD BE FLUSHED WITH LARGE QUANTITIES OF WATER. LARGE SPILLS SHOULD BE ABSORBED ON VERMICULITE OR SIMILAR ABSORBENT MATERIAL, AND COLLECTED FOR DISPOSAL. A BSORB LIQUID ON VERMICULITE OR OTHE R ABSORBENT MATERIAL TO ATOMIZE INTO AN INCINERATOR WHERE PERMITTED. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT HANDLE OR STORE NEAR HEAT, SPARKS, FLAMES, OR OXIDIZING AGENTS. STORE IN A COOL PLACE, AVOID PROLONGED OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX PRODUCTS. NEW OPERATION. Other Protective Equipment:NONE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=76.C, 168.8F B.P. Text:76 C TO 82 C. Vapor Pres:15 MM HG @20C Vapor Density:0.85(AIR=1 Spec Gravity:0.82 VOC Pounds/Gallon:780 pH:10.6 Evaporation Rate & Reference:3.1 (N-BUTYLACETATE= 1) Solubility in Water:COMPLETELY. Appearance and Odor:CLEAR LIQUID/ALCOHOLIC ODOR. Percent Volatiles by Volume:100 %(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETYL CHLORIDE, OXIDIZERS. Hazardous Decomposition Products:NONE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:ORAL LD50: >21 G/KG (RATS). DERMAL LD50: >20 G/KG (RABBITS). INHALATION LC50: N/D. EYE IRRITATION: IRRITANT. SKIN SENSITIZATION:NOT A SENSITIZER. SKIN IRRITATION: NOT AN IRRITANT. HUMAN PATCH: NON-IRR ITATING, NON-SENSITIZING. MUTAGENICITY:N.D. CARCINOGENS: NONE PRESENT. AQUATIC LC50: N.D. ADDITIONAL INFORMATION: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DEFATTING OF THE SKIN. TLV: 1000 PPM (ETH YL ALCOHOL), 400 PPM (ISOPROPYL ALCOHOL). PEL: 1000 PPM (ETHYL ALCOHOL), 400 PPM (ISOPROPYL ALCOHOL). STEL: 500 PPM(ISOPROPYL ALCOHOL). CEILING: N.E. XEROX EXPOSURE LIMIT: N.E. ==================== Disposal Considerations ==================== Waste Disposal Methods:ABSORB LIQUID ON VERMICULITE OR OTHER ABSORBENT MATERIAL OR ATOMIZE INTO AN INCINERATOR WHERE PERMITTED. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:D.O.T. PSN: FLAMMABLE LIQUID, N.O.S., (ETHANOL, ISOPROPANOL), CLASS 3, UN 1993, PACKING GROUP I I I. EXCEPTION MAY APPLY: LIMITED QUANTITY: 49 CFR 173.150(B). CONSUMER COMMODITY, ORM-D: 49 CFR 173.150 (B). I.A.T.A. PSN: FLAMMABLE LIQUID, N.O.S. (ETHANOL, ISOPROPANOL), CLASS 3, UN 1993, PACKING GROUP I I I . I.M.O. PSN: FLAMMABLE LIQUID, N.O.S.(ETHANOL, ISOPROPANOL), CLASS 3.3, UN 1993, PACKING GROU P I I I. ===================== Regulatory Information ===================== SARA Title III Information:ISO PROPANOL (67-63-0): THIS INGREDIENT IS A TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE I I I OF THE SUPERFUND AMENDMENTS AND REAUTHORIAZATION ACT OF 1986 AND 40 CFRPART 372. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CRONATIG 59T Preparer's Name:CARL E WALTER CAGE:67292 CAGE:67292 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON, ACTIVATED CARBON, GRAPHITE CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: <1% OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:IRON *95-4* CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: <1% Ingred Name:TITANIUM, DRY POWD *95-4* CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: 61-100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/EYES. LONG TERM EXPOSURE TO WELDING FUMES: SIDEROSIS (IRON DEPOSITS IN THE LUNGS) & AFFECT PULMONARY FUNCTIO N. EYES: ARC RAYS CAN INJURE. SKIN: BURNS. ELECTRIC SHOCK CAN KILL. Explanation of Carcinogenicity:NONE Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES: DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/EYES. LONG TERM EXPOSURE TO WELDING FUMES: SIDEROSIS (IRON DEPOSITS IN THE LUNGS) & AFFECT PULMONARY FUNCTIO N. EYES: ARC RAYS CAN INJURE. SKIN: BURNS. ELECTRIC SHOCK CAN KILL. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARCS & SPARKS CAN IGNITE COMBUSTIBLE & FLAMMABLE PRODUCTS. ======================Handling and Storage ====================== Handling and Storage Precautions:MONITOR FUMES FOR THESE ELEMENTS WHEN INDICATED. WEAR APPROPRIATE EQUIPMENT TO PREVENT INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK. Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & INSULATE THEMSELVES FROM WORK & GROUND. TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION DOESN'T KEEP EXPOSURE < TLV. Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES < TLV IN WORKERS BREATHING ZONE & GENERAL AREA. PROTECTORS, APRON, HATS, SHOULDER PROTECTION, DARK SUBSTANTIAL CLOTHING. Supplemental Safety and Health PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN THE ATMOSPHERE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES (SEE SUPPLEMENTAL DATA) Stability Condition to Avoid:(SEE SUPPLEMENTAL DATA) Hazardous Decomposition Products:FLUORIDES & COMPLEX OXIDES OF METALS, CO, CO2, OZONE, NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LIQUID ICE GO, 2343 CAGE:86938 CAGE:86938 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 95% OSHA PEL:N/K ACGIH TLV:50 PPM,VAPOR, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:CAN CAUSE IRRITATION UPON PROLONGED CONTACT. EYES:CAN BE IRRITATING UPON CONTACT. INHAL:SLIGHT EFFECT SINCE LOW VOLATILITY. INGEST:CAN CAUSE NAUSEA AND VOMITING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. EYES:FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONSULT PHYSICIAN. INHAL:MOVE TO FRESH AIR. INGEST:DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WA TER AND CALL A PHYSICIAN IMMEDIATELY. SEE LABEL FOR ADDITIONAL INFORMATION. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:240F,116C Extinguishing Media:CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP WITH WATER OR ABSORB SPILL WITH AN ABSORBENT MATERIAL (I.E. SELIG'S AP ABSORBENT); PICK UP AND DEPOSIT IN A SUITABLE WASTE CONTAINER. FLUSH AREA THOROUGHLY WITH A DETERGENT SOLUTION. RINSE AREA THOROUGHLY WITH CLEAN WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. HARMFUL IF SWALLOWED. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL Other Protective Equipment:PROTECTIVE CLOTHING NOT NORMALLY NECESSARY. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HMIS(LEVIEN) NOTES THAT THE ORAL LD50 (RAT) FOR ETHYLENE GLYCOL IS 4700MG/KG. ETHYLENE GLYCOL IS TOXIC TO KIDNEYS AND IS A SUSPECTED REPRODUCTIVE TOXIN. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:387F,197C Vapor Pres:0.12 @ 25C Spec Gravity:1.110 pH:7 Solubility in Water:SOLUBLE Appearance and Odor:GREEN COLOR, CLEAR LIQUID, ODOR OF ETHYLENE GLYCOL. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID, BASE Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:CHECK LOCAL, STATE AND FEDERAL REGULATIONS PRIOR TO DISPOSAL. PRODUCT IS NOT CONSIDERED A HAZARDOUS WASTE UNDER RCRA. LIQUIDS MAY BE ABLE TO BE DISPOSED OF BY FLUSHING INTO SANITARY SEWERS WITH PLENTY OF WATER. NEUTRALIZATION OF PH MAY BE REQUIRED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CALCIUM 10000 UG/ML (1% W/V) CAGE:0EK28 CAGE:0EK28 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:CALCIUM NITRATE CAS:10124-37-5 RTECS #:EW2985000 Ingred Name:NITRIC ACID, HYDROGEN NITRATE CAS:7697-37-2 RTECS #:QU5775000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: SEVERE IRRITATION/BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION, MAY BE FATAL. SKIN/EYES: SEVERE IRRITATION/BURNS. INGESTION: SEVERE BURNS/ULCERATION OF MOUTH, THROAT & S TOMACH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, COUGHING, DIFFICULT BREATHING, CHEST PAINS, UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS GIVE WATER, MILK/MILK OF MAGNESIA. SKIN/EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE APPROPRIATE MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR PROPER PROTECTIVE EQUIPMENT & SELF CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SCBA & FULL PROTECTIVE CLOTHING. STOP LEAK IF POSSIBLE W/OUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP W/SAND/OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPO SAL. FLUSH AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:LOCAL EXHAUST/VENT HOOD. Other Protective Equipment:LAB COAT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS SOLUTION W/SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANIC MATERIALS, STRONG REDUCING AGENTS. Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. CORROSIVE WASTE D002.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:QUICK DRY ENAMEL, F77W102 MIDTONE BASE CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, M-DIVINYL-; (1,3,5-TRIMETHYLBENZENE). VP:10. CAS:108-57-6 RTECS #:CZ9450000 Fraction by Wt: 1% OSHA PEL:25 PPM (MFR) ACGIH TLV:25 PPM (MFR) Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313). VP:2. CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 2% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 14% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUNDS: 4.76 LBS/GAL. RTECS #:9999999VO Ingred Name:SUPP DATA:CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BE DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:OR FATAL. NOTE:TOLUENE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ Ingred Name:OTHER PREC:APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THIS COATING MAY CONTAIN (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:(TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:MINERAL SPIRITS; (V.M. & P. NAPHTHA). VP:12. CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 12% OSHA PEL:300 PPM (MFR) ACGIH TLV:300 PPM (MFR) Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 20% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313). VP:7.1. CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM;125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 17% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN UNCON& POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOL INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLO OD-FORMING, CVS & REPRO SYS. RATS EXPOSTO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, (ING 10) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:35.0F,1.7C Lower Limits:0.7% Upper Limits:6% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:FLAMM. KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DOL STORAGE CATEGORY - 1B. CONTENTS ARE FLAMM. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAME, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. KEEP CNTNR CLSD WH EN NOT IN USE. TRANSFER ONLY TO (ING 14) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING/WELD ING DRIED FILM, WEAR A NIOSH (SUPP DATA) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. WASTE DISP METH:REGARDING POLLUTION. RESP PROT:APPRVD PARTICULATE RESP FOR PROT AGAINST NON-VOLAT INGS. VENT:1910 .94, 1910.107, 1910.108. EXPLO HAZ:HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY (ING 9) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>222F,>106C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.87-1.1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:68-73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTN R. DISP OF I/A/W FED, STATE & LOC REGS (SUPP DATA)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ACETONE, A16S-20 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE; (2-PROPANONE) (SARA 313) (CERCLA) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 99% OSHA PEL:1000 PPM ACGIH TLV:750 PPM/1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 5800 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: PRDCES IRRIT, CHARACTERIZED BY BURNING SENSATION, REDNESS, TEARING, INFLAMM, & POSS CORNEAL INJURY. SKIN: MAY CAUSE IRRIT INCL REDNESS, DRYNESS, & INFLAMM. INGEST: MAY CAUSE IRRIT OF DIGE STIVE TRACT. MAY CAUSE CNS DEPRESS, KIDNEY & LIVER DMG. SYMPS MAY INCL HDCH, EXCITEMENT, FATG, NAUS, (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: VOMIT, STUPOR, & COMA. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON & COMA. CAUSES RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE MOTOR INCOORD & SPEECH ABNORMS. CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL MAY CAUSE EFTS SIMILAR TO ACUTE INHAL. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS.INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GI VE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:-4F,-20C Lower Limits:2.5% Upper Limits:12.8% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. FOR LARGE FIRES, USE WATER SPRAY, FOG, OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT AND/OR FIRE. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERS PROTECTIVE EQUIP AS INDICATED IN SECTION 8. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. WEAR APPROP PROTECTIVE CLOTHING TO M INIMIZE CONT W/SKIN. REMOVE ALL SOURCES OF IGNIT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. AVOID CONTACT W/EYES, SKIN & CLOTHING. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE (LIQUID &/OR VAPOR), & CAN BE DANGEROUS. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS OR OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN A TIGHTLY CLOSED CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE PROCESS ENCLOSURE, LOC EXHST VENT/OTHER ENGINEERING CTLS TO CTL AIRBORNE LEVELS BELOW RECOMMENDED EXPOS LIMITS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health MATLS TO AVOID: THIODIGLYCOL + HYDROGEN PEROXIDE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:133F,56C Melt/Freeze Pt:M.P/F.P Text:-140F,-95C Vapor Pres:180 Vapor Density:2.0 Spec Gravity:0.79 (H*2O=1) pH:7 Evaporation Rate & Reference:7.7 (N-BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID WITH SWEETISH ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FORMS EXPLOSIVE MIXTURES WITH HYDROGEN PEROXIDE, ACETIC ACID, NITRIC ACID, NITRIC ACID + SULFURIC ACID, CHROMIC ANHYDRIDE, CHROMYL CHLORIDE, NITROSYL CHLORIDE, HEXACHLOROMETHANE, NITROSYL PERCHLORATE, NITRYL PERCHLORATE, PE Stability Condition to Avoid:HIGH TEMPERATURES, TEMPERATURES ABOVE 220C. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: CAS # 67-64-1: WASTE NUMBER: U002.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DIFFERENTIATED KLARIFIANT Preparer's Name:M ANTOSIAK CAGE:DUBOI CAGE:72008 CAGE:DUBOI ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: <40% Other REC Limits:N/K OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: <5% Other REC Limits:N/K OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9192 Ingred Name:SILICA,GEL CAS:63231-67-4 Fraction by Wt: <3% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF OVEREXPOSURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN:CORROSIVE,DUSTS ARE CORROSIVE.INGESTION:N/K .INHALATION:DUSTS ARE CORROSIVE TO RESPIRATORY SYSTEM. Medical Cond Aggravated by Exposure:SENSITIVE SKIN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH THOROUGHLY WITH FRESH WATER FOR AT LEAST 15 MINUTES.GET MEDICAL ATTENTION.SKIN:FLUSH WITH FRESH WATER,WASH WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHES & SHOES.INGESTION:GIVE MILK OR WATER ,DO NOT INDUCE VOMITING.GET MEDICAL ATTENTION.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.INHALATION:REMOVE TO FRESH AIR.SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:CO*2,DRY CHEMICALS. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE.HAZARDOUS DECOMPOSITION PRODUCTS:CO WITH INCOMPLETE COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH SMALL AMOUNTS TO DRAIN.COLLECT AND RETURN LARGE AMOUNTS TO CONTAINER. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY PLACE.KEEP COVER ON DRUM. Other Precautions:DOT CORROSIVE:CAUTIONS ON CONTAINER LABEL UN 1759. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:NONE Work Hygienic Practices:N/K Supplemental Safety and Health EVOLUTION:HIGH. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Spec Gravity:1.15 (WATER=1) Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:7% Appearance and Odor:WHITE OR OFF-WHITE POWDER;ODOR MILD. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FLAMMABLE LIQUIDS,ACTIVE METALS,ORGANIC HALOGEN COMPOUNDS,STRONG ACIDS CAUSE VIOLENT REACTIONS. Stability Condition to Avoid:N/K Hazardous Decomposition Products:CO WITH INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE & LOCAL REGS .ADJUST ALKALINITY & SEPARATE INSOLUBLES;CONTAINS NO PHOSPHATES.USE UNTIL <1 INCH REMAINS;EMPTY CONTR,TRIPLE RINSE W/ WATER,ADD TO OP ERATION.REMOVE/DEFACE LABEL BEFORE SELLING/DISP.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ID 08605 GUA-GD,383 GREEN ZENTHANE Preparer's Name:JANE FREEMAN CAGE:09225 CAGE:09225 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOAMYL KETONE CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: 29.69% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 Ingred Name:PREPOLYMER OF HEXAMETHYLENE DIISOCYANATE Fraction by Wt: 30-40% Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 20-30% OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:COBALT-ZINC SPINEL PIGMENT Fraction by Wt: 1.0-5.0% Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 7.31% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 1.24% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1,6-DIISOCYANATOHEXANE (HEXAMETHYLENE DIISOCYANATE) CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: <0.05% ACGIH TLV:0.005 PPM; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AROMATIC HYDROCARBONS (MIXTURE OF C8'S-C10'S) CAS:64742-95-6 Fraction by Wt: 1.66% Other REC Limits:100 PPM MFR'S LIMIT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:OVEREXPOSURE TO ISOCYANATE MAY LEAD TO RESPIRATORY SENSITIZATION, ASTHMA-LIKE SYMPTOMS, SKIN SENSITIZATION, ALLERGIC DERMATITIS, RASH, ITCHING, HIVES, SWELLING. REPEATED/PROLONGED OVEREXPOSURE TO SOLV ENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE, LIVER & KIDNEY DAMAGE. MAY CAUSE LUNG INJURY. Explanation of Carcinogenicity:BASED ON LABORATORY ANIMAL DATA, IARC HAS LISTED SILICA AS A "PROBABLE HUMAN CARCINOGEN" Effects of Overexposure:OVEREXPOSURE TO VAPOR &/OR MIST: CAN CAUSE IRRITATION TO SKIN, EYES & RESPIRATORY TRACT (NOSE, THROAT, LUNGS). SYMPTOMS MAY BE WATERING EYES, DRYNESS OF THROAT, COUGHING, HEADACHE, TIGHTNESS IN CHEST OR BURNING SENSATION. HEADACHE, DIZZINESS OR NAUSEA MAY BE EXPERIENCED BY SOME AS A RESULT OF EXPOSURE TO SOLVENTS. Medical Cond Aggravated by Exposure:ASTHMA & OTHER RESPIRATORY AILMENTS; CHEMICAL SENSITIZATION. TRIVALENT CHROME MAY CAUSE DERMATITIS. ======================= First Aid Measures ======================= First Aid:VAPORS: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. NOTIFY A PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. TAKE TO A PHYSICIAN FOR MED ICAL TREATMENT. SKIN: WASH AFFECTED AREAS WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING. CONSULT A PHYSICIAN. INGESTION: IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:60 F/15 C Autoignition Temp:Autoignition Temp Text:840 F Lower Limits:0.5 Upper Limits:8.2 Extinguishing Media:FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT WITH SCBA SHOULD BE WORN. DURING A FIRE, IRRITATING & HIGHLY TOXIC GASES & SMOKE ARE PRESENT FROM DECOMPOSITION/COMBUSTION PRODUCTS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELEC EQUIP, SPARK & OPEN FLAME. CLOSED CONTAINER MAY EXPLODE FROM EXTREME HEAT/BURST WHEN CONTAM WITH WATER* ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE NON-ESSENTIONAL PERSONS.REMOVE ALL SOURCES OF IGNITE(FLAME,HOT SURFACES,ELECTRIC,STATIC OR FRICTION SPARK).VENT AREA.AVOID BREATHING VAPOR.COVER SPILL W/INERT ABSORB.POUR NEUTRALIZING AGENT O N SPILL-ALLOW TO REACT AT LEAST 10 MINS;COLLECT ** Neutralizing Agent:3-8% CONCENTRATED AMMONIA, 2% DETERGENT & 90-95% WATER;OR A SOLUTION OF UNION*** ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F OR < 32F. STORE LRG AMTS IN BLDG DESIGNED TO COMPLY W/OSHA1910.106.KEEP AWAY FROM SPARKS, OPEN FLAME.KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:IF MOISTURE ENTERS CONTAINERS, PRESSURE CAN BUILD DUE TO REACTION, PRODUCE CO2, CAN CAUSE SEALED CONTAINER TO PRESSURIZE & BURST. DO NOT RESEAL IF CONTAMINATED. DO NOT TAKE INTERNALLY. CONTAINERS SHOU LD BE GROUNDED WHEN POURING. **** ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS TO BE USED UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW OSHA LIMITS. THEN USE EITHER CHEM CARTRIDGE/AIRLINE RSPRTRS REQUIRED. USE SAME PRECAUTIONS DURINGMIXING OR WHERE PAINT FUMES ARE PRESENT Ventilation:GEN DILUTION/LOCAL EXHAUST VENT IN VOL/PATTERN TO KEEP AIR CONTAM CONCENT BELOW LIMITS.REMOVE DECOMP PROD WHEN WELD, ETC Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN CONTACT AT MINIMUM. AVOID CONTACT WITH EYES, SKIN & CLOTHING. WASH THOROUGHLY. Work Hygienic Practices:WASH HANDS & ANY EXPOSED SKIN THOROUGHLY BEFORE EATING OR SMOKING. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health **** AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. USE W/ADEQUATE VENTILATION & RESPIRATORY EQUIP. EMPTIED CONTAINERS MAY RETAIN HAZARDOUS RESIDUE OR EXPLOSIVE VAPORS. FOLLOW ALL PRECAUTIONS IN THIS DATA SHEET UNTIL CONTAINER IS THOROUGHLY CLEANED OR DESTROYED.**FLUSH AREA W/WATER.REMOVE CONTAINER TO SAFE PLACE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:244 TO 418F Decomp Temp:Decomp Text:400F,204C Vapor Pres:8.00 Vapor Density:> THAN AIR Spec Gravity:1.256 Viscosity:65-68 KREBS Evaporation Rate & Reference:EQUAL TO BUTYL ACETATE Solubility in Water:REACTS WITH WATER Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:51.43 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOLS, GLYCOL ETHERS, AMINES. Stability Condition to Avoid:WATER CONTAMINATION. *(CO2 EVOLVED). DON'T APPLY TO HOT SURFACES. NEVER USE WELD/CUT TORCH ON/NEAR DRUM(EVEN EMPTY DRUM) Hazardous Decomposition Products:BY FIRE: CO2, CO, OXIDES OF NITROGEN, TRACES OF HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. INCINERATION IS PREFERRED METHOD OF DISPOSAL.***CARBIDE'S TERGITOL TMN-10 (20%) & WATER (80%).**W/NON-SPARK TOOLS INTO OPEN CONTAINER- ADD MORE NEUTRALIZER & WASH AREA W/NEUTRALIZER **
1
gloves_mandatory
======================================================= NIIN: 01-169-5304 Product ID: EA 9394 PART A (AA9277) Kit Part: Y Cage: 33564 Box: 312 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 33564 Box: 312 ======================================================= Contractor Summary ======================================================= Cage: 33564 Box: 312 Cage: 03355 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: ADHESIVE Unit of Issue: KT UI Container Qty: 0 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: MIXTURE HAS NOT BEEN TESTED AS A WHOLE. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: BRIEF CONTACT MAY IRRIT SKIN OR CAUSE A RASH. REPEATED OR PROLONGED SKIN CONTACT MAY RESULT IN ALLERGIC SENSITIZATION. CARCINOGENICITY NOTE: BISPHENOL A/EPICHLOROHYDRIN EPOXY RESIN HAS EXHIBITED MUTAG ENICITY IN BACTERIA. Explanation Of Carcinogenicity: NEITHER THIS MATERIAL NOR ANY OF ITS COMPONENTS IS CONSIDERED A CARCINOGEN. Signs And Symptions Of Overexposure: SKIN RASH, IRRITATION. Medical Cond Aggravated By Exposure: SKIN SENSITIZATION. First Aid: EYE:FLUSH W/WATER FOR 15MINS. IF IRRIT PERSISTS GET MED ATTN. SKIN:WASH THOROUGHLY W/SOAP & WATER. IF IRRIT PERSISTS GET MED ATTN. INHAL:REMOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST GET MED ATTN. I NGEST:DRINK PLENTY OF WATER. GET MED ATTN IMMED. ======================================================= Handling and Disposal ======================================================= GLASSES. SCRAPE UP OR SHOVEL INTO DOT APPROVED WASTE CONTAINERS. Waste Disposal Methods: NOT RCRA HAZ WASTE.HOWEVER, INCINERATION IN EPA APPROVED WASTE INCINERATOR IS PREFERRED.CHEM ADDITIONS/ PROCESSING/OTHERWISE ALTERING MATL MAY MAKE WASTE MANAGEMENT INFOR HEREIN INCOMPLETE/INACCURATE/ INAPPROPRIATE.CONSULT STATE/LOC REGULATIONS. Handling And Storage Precautions: REFRIGERATED STORAGE IS RECOMMENDED TO MAINTAIN PRODUCT QUALITY. THIS PRODUCT MAY BE STORED @ (40F) FOR UP TO 12 MONTHS. Other Precautions: FOLLOW CURING SCHEDULE AS RECOMMENDED IN PRODUCT LITERATURE.DON'T CUT/GRIND/WELD/DRILL ON/NEAR CONTAINER.AVOID MIXING PARTS A&B IN BATCHES >1LB UNLESS PLAN TO USE IMMED.DON'T HEAT MIXED ADHESIVE >75F UNLESS CURING SURFACES TO BE BONDED. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NOT TESTED Lower Limits: NOT TESTED Upper Limits: NOT TESTED Extinguishing Media: DRY CHEMICAL, OR HALON FIRE EXTINGUISHER, OR WATER SPRAY, FOAM OR FOG. Fire Fighting Procedures: WEAR SCBA & FULL PROTECTIVE CLOTHING, SUCH AS TURN-OUT GEAR. CARTRIDGE RESP DO NOT PROVIDE ADEQUATE PROTECTION FOR FIREFIGHTERS OR EXOTHERM MITIGATION. Unusual Fire/Explosion Hazard: MAY LIBERATE LARGE QUANTITIES OF DENSE FOUL-SMELLING SMOKE WHICH MAY CONTAIN UNIDENTIFIED TOXIC GASES. ======================================================= Control Measures ======================================================= Respiratory Protection: IF LOCAL EXHAUST VENTILATION INADEQUATE, NIOSH/MSHA APPROVED ORGANIC CARTRIDGE RESPIRATOR RECOMMENDED. Ventilation: LOCAL EXHAUST VENTILATION AT THE POINT OF USE. Other Protective Equipment: AN EYEWASH AND SAFETY SHOWER SHOULD BE NEARBY AND READY FOR USE. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING MATERIALS. Supplemental Safety and Health: VISCOSITY:BROOKFIELD, SPDKL 5. FAILURE TO OBSERVE PRECAUTIONS IN MIXING/HEATING MAY RESULT IN EXCESSIVE HEAT BUILD-UP CAUSING AN EXOTHERM. THE EXOTHERM HAS POTENTIAL FOR RELEASE OF TOXIC GASES. SEE SA ME NSN/CAGE PN/IND: F FOR PART B OF 2-PART KIT. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: UNDEFINED Decomp Text: UNTESTED Vapor Pres: NIL Vapor Density: >1 Spec Gravity: 1.0 Viscosity: 4000-8000 BRK Solubility in Water: NEGLIGIBLE. Appearance and Odor: VISCOUS GRAY PASTE, SLIGHT ODOR Corrosion Rate: NA ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID MIXING PARTS A & B IN BATCHES >1.0 LB & HEATING MIXTURE >125F. Materials To Avoid: STRONG OXIDIZING AGENTS, STRONG LEWIS OR MINERAL ACIDS. Hazardous Decomposition Products: CO, NOX, ALDEHYDES, ACIDS & UNDETERMINED ORGANICS. Hazardous Polymerization Indicator: YES Conditions To Avoid Polymerization: NO INFORMATION PROVIDED BY MFG. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 112749 Product ID: EA 9394 PART A (AA9277) Review Date: 02/21/1996 Multiple KIT Number: 0 Kit Part IND: Y Review IND: Y Unit Of Issue: KT Container QTY: 0 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: AJH Symbols: G DOT Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. OR POLYAMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN ID Num: UN2735 DOT Packaging Group: II Label: CORROSIVE Special Provision: B2,T8 Non Bulk Pack: 202 Bulk Pack: 242 Max Qty Pass: 1 L Max Qty Cargo: 30 L Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: AQA IMO Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. o IMDG Page Number: 8109-2 UN Number: 2735 UN Hazard Class: 8 IMO Packaging Group: I/II/III Subsidiary Risk Label: - EMS Number: 8-05 MED First Aid Guide NUM: 320 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: AWR IATA UN ID Num: 2735 IATA Proper Shipping Name: ALKYLAMINES, N.O.S. (POLYALKYLAMINES, N.O.S.) IATA PSN Modifier: * CORROSIVE IATA UN Class: 8 Subsidiary Risk Class: - IATA Label: CORROSIVE UN Packing Group: II Packing Note Passenger: 808 Max Quant Pass: 1L Max Quant Cargo: 30L Packaging Note Cargo: 812 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: AWR AFI Proper Shipping Name: ALKYLAMINES, N.O.S., OR POLYALKYLAMINES, N.O.S. AFI PSN Modifier: ,CORROSIVE AFI Hazard Class: 8 AFI UN ID NUM: UN2735 AFI Packing Group: II AFI Label: CORROSIVE Special Provisions: N34 Back Pack Reference: A12.3 ======================================================= HAZCOM Label ======================================================= Product ID: EA 9394 PART A (AA9277) Cage: 33564 Company Name: DEXTER CORPORATION ADHESIVE & COATING SYSTEMS Street: 2850 WILLOW PASS ROAD PO Box: 312 Zipcode: 94565-3299 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: BRIEF CONTACT MAY IRRIT SKIN OR CAUSE A RASH. REPEATED OR PROLONGED SKIN CONTACT MAY RESULT IN ALLERGIC SENSITIZATION. CARCINOGENICITY NOTE: BISPHENOL A/EPICHLOROHYDRIN EPOXY RESIN HAS EXHIBITED MUTAG ENICITY IN BACTERIA. SKIN RASH, IRRITATION. =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TRYPSINOGEN FROM BOVINE PANCREAS PI MAKER 9.3 T1146 CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:TRYPSINOGEN FROM BOVINE PANCREAS PI MAKER 9.3 CAS:9002-08-8 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. PROLONGED OR REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN SENSITIVE INDIVIDUALS. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. CALL A P HYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, CALL A PHYSICIAN. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER OR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING TH E EYELIDS WITH FINGERS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SPILLED MATERIAL SHOULD BE CAREFULLY WIPED UP OR MOISTENED WITH WATER AND REMOVED. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AWAY FROM HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . OTHER PROTECTIVE CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. Conditions to Avoid Polymerization:WILL NOT OCCU. =================== Toxicological Information=================== Toxicological Information:THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. ===================== Ecological Information ===================== Ecological:DATA NOT YET AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION. ===================== Regulatory Information ===================== Federal Regulatory Information:DATA NOT AVAILABLE. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ID 0320T136, H.S. HARDENER MIL-C-85285 Kit Part:Y Preparer's Name:CAP CAGE:0HKK2 CAGE:98795 CAGE:0HKK2 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10-20% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC. 1.352 POUNDS PER GALLON LESS WATER. RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE BY INHALATION MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT, HEADACHE, DIZZINESS OR DROWSINESS. SKIN OR EYE CONTACT: IRRITANT TO THE EYES AND SKIN AND SKIN SENSITIVITY. MAY AFFECT RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM, ALLERGIC RESPIRATORY AND SKIN REACTION. Explanation of Carcinogenicity:NO Effects of Overexposure:OVEREXPOSURE BY INHALATION MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT, HEADACHE, DIZZINESS OR DROWSINESS. SKIN OR EYE CONTACT: IRRITANT TO THE EYES AND SKIN AND SKIN SENSITIVITY. Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WAT ER. INGESTION: DRINK WATER. IF NECESSARY, CONSULT A PHYSICIAN FOR ANY OF THESE CONDITIONS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:26 F/-3 C Lower Limits:1.80 Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID BREATHING VAPORS, VENTILATE AREA AND REMOVE WITH INERT ABSORBANT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. MAKE SURE DRUM IS COMPLETELY EMPTY BEFORE WELDING,ETC Other Precautions:DO NOT TAKE INTERNALLY. THE DRUM SHOULD BE INDUSTRIALLY CLEANED PRIOR TO REUSE. DO NOT FLAME CUT, BRAZE OR WELD WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:GEN DILUTE/LOCAL EXHAUST FAIL TO KEEP TWA/PEL BELOW LIMIT, DON'T BREATHE VAPORS/SPRAY MIST. WEAR PROPERLY FITTED RSPRTR. AIR LINE RSPRTR RECOMMENDED. VAPOR/PARTICULATE RSPRTR WHEN AIR-BORNE MONITOR SH OWS ISOCYANATES 10 TIME LESS THAN LIMITS Ventilation:GENERAL DILUTION OR LOCAL EXHAUST VENTILATION TO KEEP TWA/LEL BELOW ACCEPTABLE LIMITS & TO REMOVE DECOMPOSITION PRODUCTS Supplemental Safety and Health KEEP CONTAINER CLOSED WHEN NOT IN USE! ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:172 TO 176F ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO WILL REACT WITH WATER OR WATER CONTAINING PRODUCTS TO GIVE OFF HEAT AND FUMES. Stability Condition to Avoid:DO NOT ALLOW WATER TO ENTER SEALED DRUMS AS THE DRUMS MAY EXPLODE. Hazardous Decomposition Products:FUMES MAY CONTAIN CARBON MONOXIDE & OXIDES OF NITROGEN. MAY PRODUCE HAZARDOUS FUMES WHEN HEATED TO DECOMP, AS IN WELDING ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. BEFORE ATTEMPTING TO CLEAN UP, SEE INGREDIENTS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HIGH TEMPERATURE MOLD MAKER(C-1)-HARDENER Kit Part:Y CAGE:16059 CAGE:16059 ============= Composition/Information on Ingredients ============= Fraction by Wt: >60% ===================== Hazards Identification ===================== Effects of Overexposure:EYES:SEVERE IRRIT.SKIN:MILD IRRIT.INHAL:POSS INTOXICATION W/ POOR VENT. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/ WATER FOR AT LEAST 15 MIN,CALL MD.SKIN: WASH OFF W/ SOAP & WATER.INGEST:GIVE 2 GLASSES OF WATER ORMILK,TRANSPORT TO MEDICAL FACILITY.INHAL:REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:>250F,121C TCC Extinguishing Media:WATER,CO*2,FOAM,DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING Unusual Fire/Explosion Hazard:AMMONIA GASES & MIXED NITROGEN OXIDES RELEASED ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT SKIN & EYE CONTACT.REMOVE CONTAMINATED CLOTHING.DISCARD CONTAMINATED LEATHER ARTICLES LIKE SHOES & BELT.ABSORB SPILL ON INERT MATERIAL & DISCARD IN SUITABLE CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE CONTACT.WASH THOROUGHLY AFTER HANDLING OR EXPOS. Other Precautions:THIS HEALTH HAZ DATA PERTAIN ONLY TO HARDENER. WHEN FULLY CURED,THE MIXED PRODUCT IS NON-HAZARDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPR ORGANIC VAP MASK W/ POOR VENT AREAS. Ventilation:LOCAL EXHAUST RECOMMENDED.MECHANICAL ADEQUATE. Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Supplemental Safety and Health SIDE SHIELD. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>500F,>260C Vapor Pres:<1 Vapor Density:>1 Spec Gravity:0.99 Evaporation Rate & Reference:<1(BUTYL ACETATE) Solubility in Water:APPRECIABLE Appearance and Odor:AMBER LIQUID,FAINT AMINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS AND ACIDS Stability Condition to Avoid:OPEN FLAME,EXCESSIVE HEAT Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE TO WASTE DISPOSAL FACILITY OPERATING IN COMPLIANCE W/ FEDERAL,STATE,& LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:POTASSIUM CHLORIDE, 6275 Resp. Party Other MSDS Num.:P5631 CAGE:70829 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM CHLORIDE CAS:7447-40-7 RTECS #:TS8050000 = Wt:100. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:10 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF HIGH CONCENTRATIONS OF DUST MAY CAUSE NASAL OR LUNG IRRITATION. INGESTION: LARGE QUANTITIES CAN PRODUCE GASTROINTESTINAL IRRITATION AND VOMITING. MAY PRODUCE WEAKNESSAND CIRCULATORY PROBLEMS. MAY AFFECT HEART. IN SEVERE CASES, INGESTION MAY BE FATAL. SKIN: CONTACT MAY CAUSE IRRITATION OR RASH, PARTICULARLY WITH MOIST SKIN. EYES: POTASSIUM CHLORIDE IS A MODERATE EY E IRRITANT. REDNESS, TEARING, POSSIBLE ABRASION CAN OCCUR. CHRONIC: NO INFORMATION FOUND. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED KIDNEY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER G IVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DEV ELOPS OR PERSISTS. EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. CALL A PHYSICIAN IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL MEASURES SECTION. PICK UP AND PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES(DUST, SOLIDS); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. Other Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT) Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT CAN CTL EMISSIONS OF (OTHER INFO) Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR CLEAN BODY-COVERING CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT WORKER S IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES: DENSITY: 1.987; PH: CA. 7 SATURATED AQ. SL. @ 15C. ================== Physical/Chemical Properties ================== Boiling Pt:=1500.C, 2732.F B.P. Text:SUBLIMES Melt/Freeze Pt:=772.2C, ######F pH:SEE SUP DAT Solubility in Water:28.1 G/100G OF WATER @ 0C Appearance and Odor:WHITE CRYSTALS OR POWDER; ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BROMINE TRIFLUORIDE; POTASSIUM PERMANGANATE PLUS SULFURIC ACID. Stability Condition to Avoid:NO INFORMATION FOUND. Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN. =================== Toxicological Information=================== Toxicological Information:ORAL RAT LD50: 2600 MG/KG; IRRITATION EYE RABBIT (STANDARD DRAIZE): 500 MG/24 HR MILD; INVESTIGATED AS A MUTAGEN. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE/CONTAMINATION OF PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISP REGULATIONS MAY DIFFER FROM FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & UNUSED C ONTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. OTHER INFORMATION: LAB PROTECTIVE STORAGE). EMERGENCY OVERVIEW: CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITAT ION TO SKIN, EYES, AND RESPIRATORY TRACT. ===================== Regulatory Information ===================== SARA Title III Information:SARA 302 RQ/TPQ: NOT LISTED. SARA LIST/CHEMICAL CATG.: NOT LISTED. SARA 311/312: ACUTE: YES; CHRONIC: NO; FIRE: NO; PRESSURE: NO; REACGIVITY: NO (PURE/SOLID). Federal Regulatory Information:POTASSIUM CHLORIDE LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL; NOT LISTED IN CANADA NDSL, CERCLA, RCRA 261.33, TSCA 8 (D). CHEMICAL WEAPONS CONVENTION: NO. TSCA 12 (B): NO. CDTA: NO. AUST RALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS REGULATIONS (CPR) AND T HE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. State Regulatory Information:POTASSIUM CHLORIDE LISTED IN PHILADELPHIA. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:19464 OPEN GEAR & FIFTH WHEEL LUBE CAGE:05575 CAGE:05573 CAGE:05575 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: <21% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: <21% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSPECTED HUMAN CARCINOGEN BY ACGIH, NTP, IARC - GROUP 2B) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 23% ACGIH TLV:174 MG/CUM (A2) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU), AEROTHANE TT, CHLOROTHENE CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 12% Other REC Limits:450 PPM STEL OSHA PEL:350 PPM ACGIH TLV:1910 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:PETROLEUM HYDROCARBONS Fraction by Wt: 44% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SKIN: DEFATTING. INHALATION: CENTRAL NERVOUS SYSTEM EFFECTS, METHYLENE CHLORIDE WILL HAVE AN AFFECT ON CARDIOVASCULAR SYSTEM, LUNG, LIVER OR KIDNEY DAMAGE MAY OCCUR W/CHRONIC (YEARS) EXPOSURE. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:INHALATION: DIZZINESS, NARCOSIS, DIFFICULTY BREATHING. SKIN: REDNESS. INGESTION: VOMITING. Medical Cond Aggravated by Exposure:HEART DISEASE, RESPIRATORY DISORDERS ======================= First Aid Measures ======================= First Aid:EYES/SKIN: WASH W/WATER. INHALATION: GIVE OXYGEN. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F Lower Limits:1.8% Upper Limits:12% Extinguishing Media:WATER FOG, DRY CHEMICAL, CO2 Fire Fighting Procedures:AEROSOL CANS MAY RUPTURE WHEN HEATED Unusual Fire/Explosion Hazard:HEATED CANS MAY BURST ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBANT SWEEPING COMPOUND TO SOAK UP MATERIAL. PUT INTO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES. STORE AT TEMPERATURES <120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF CONTAINED BREATHING APPARATUS IF TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:LONG SLEEVES & LONG PANTS Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-40F Vapor Pres:65 PSI Vapor Density:4.0 Spec Gravity:0.9 Evaporation Rate & Reference:(BU AC = 1): <2 Solubility in Water:INSOLUBLE Appearance and Odor:BROWN/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METHYLENE CHLORIDE WILL REACT W/ACTIVE METALS. STRONG OXIDIZERS Stability Condition to Avoid:HIGH TEMPERATURES, HEAT, SPARKS, OPEN FLAMES Hazardous Decomposition Products:CO2, WATER, HALOGEN ACIDS, PHOSGENE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE IN ACCORDANCE W/EPA RCRA.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EPOXY #515X408 SK FR PRIMER, GREEN, #5749 Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (CERCLA)(VP = 10.0) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM/STEL 200 ACGIH TLV:150 PPM/STEL 200 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:EPOXY RESIN CAS:37312-33-7 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYL-3-ETHOXYPROPIONATE (VP = 1.1) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: <5.0% Other REC Limits:MFR 50 PPM/STEL 100 Ingred Name:CYCLOHEXANONE (CERCLA)(VP = 2.0) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: <5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM SKIN/STEL 100 ACGIH TLV:25 PPM SKIN/STEL 100 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)(VP = 70.0 CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/STEL 300 ACGIH TLV:200 PPM/STEL 300 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ZINC CHROMATE (SARA 313) CAS:13530-65-9 RTECS #:GB3290000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 CRO3 MG/M3 STEL ACGIH TLV:0.01 MG/M3 AS CR Ingred Name:TALC CAS:14807-96-6 RTECS #:MW2700000 Fraction by Wt: 10.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:PIGMENT YELLOW 16 (NON-HAZ) CAS:5979-28-2 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: BURN/TEAR/RED/TRANSEINT CORNEAL INJURY/SWELLING/CONJUNCTIVITIS. SKIN: DRY/CRACKED/ALLERG RASH/IRRIT/DERMATITIS/DAMAGE. INHAL: DIZZY/DROWSY/FATIGUE/NASAL/RESP IRRIT. CNS: DIZZY/WEAK/FATIGUE/NAUSEA /HEADACHE/UNCONACIOUS. LIVER/KIDNEY DAMAGE/COUGH/CHEST PAIN/THROAT IRRIT. INGEST:DROWSY/DIZZY/NAUSEA. CHRONIC:* Effects of Overexposure:*PENETRATING ULCERS OF SKIN/MUCOUS MEMBRANES OF NOSE/PERFORATION OF CARTILAGINOUS NASAL SEPTUM. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER 15 MINUTES. GET MEDICAL AID. SKIN: WASH W/SOAP & WATER/NO SOLVENTS. REMOVE CONTAM CLOTHES/WASH BEFORE REUSE. GET MEDICAL AID. INHALATION: GET FRESH AIR. GIVE ARTIFICIAL RESP/CPR IF TROUBLE BREATHING. GET MEDICAL AID. INGESTION: GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:40.0F,4.4C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:COOL EXPOSED CNTNRS W/WATER. FOG NOZZELS PREFERRED. USE NIOSH/MSHA APPROVED SCBA/PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN/EYES. Unusual Fire/Explosion Hazard:VAPORS ACCUMULATE/FORM EXPLOSIVE MIXTURES W/AIR/TRAVEL LONG DISTANCE/FLASH BACK/FLAME. CLOSED CONTAINERS MAY EXPLODE W/EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP FROM IGNITS. USE AIR-SUPPLIED RESPIRATOR FOR UNVENTED SPILL. COVER W/ABSORBENT. SWEEP INTO CONTAINER. CLEAN RESIDUE W/SUITABLE SOLVENT. CERCLA RQ N-BUAC = 5000 LBS, CYCLOHEXANONE = 5000 LBS, MEK = 5000 LBS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP FROM HEAT/OTHER IGNITS. DON'T STORE >120F. Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DON'T CUT, PUNCTURE, WELD ON/NEAR DRUM. VAPORS >AIR MAY COLLECT IN LOW/CONFINED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAYING OR APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVEL OF HAZARDOUS INGREDIENTS IN EXCESS OF TLV, USE ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLIED RESPIRATOR. Ventilation:GENERAL TO MAINTAIN VAPORS BELOW TLV & PEL. Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYEBATH, WASHING FACILITIES SHOULD BE AVAILABLE. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175 TO 329F Vapor Density:>AIR Spec Gravity:1.322 VOC Pounds/Gallon:517 Evaporation Rate & Reference:UNAVAILABLE Appearance and Odor:GREEN LIQUID, SOLVENT ODOR Percent Volatiles by Volume:55.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE RECOGNIZED Stability Condition to Avoid:NONE RECOGNIZED Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE W/LOCAL, STATE, FEDERAL REGULATIONS. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:EMIT D.A.U. AMPHETAMINE CONFRMATN (SUP DATA) CAGE:HO623 CAGE:HO623 CAGE:61815 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 2.7% Other REC Limits:N/K OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 97.3% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE EYE DAMAGE.INGESTION WILL CAUSE POSSIBLE DAMAGE TO MOUTH & ESOPHAGUS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:MAY CAUSE DAMAGE.SKIN:PROLONGED CONTACT MAY CAUSE IRRITATION.INGESTION:WILL CAUSE IRRITATION & POSSIBLE DAMAGE TO MOUTH & ESOPHAGUS.INHALATION:WILL CAUSE IRRITATION TO NOSE,LUNGS,RESPIRATORY TRAC T,MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES.CONTACT SUPERVISOR & PHYSICIAN.SKIN:FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES.IF IRRITATION PERSISTS,CONTACT SUPERVISOR & PHYSICIAN.INGESTIO N:DO NOT INDUCE VOMITING.GIVE LARGE QUANTITIES OF MILK OR WATER & CONTACT SUPERVISOR & PHYSICIAN.INHALATION:CONTACT SUPERVISOR & PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Lower Limits:NONE Upper Limits:NONE Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:HAZARDOUS DECOMPOSITION PRODUCTS:WILL LIBERATE HYDROGEN GAS UPON CONTACT WITH SOME METALS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID SKIN CONTACT.NEUTRALIZE W/ CITRIC ACID OR DILUTE HCL SOLUTION.ABSORB W/ DRY ABSORBING MATLS.WEAR PERSONAL PROTECTION.LARGE SPILL:WEAR APPROPRIATE PROTECTIVE CLOTHING (EYE PROTECTION,NEOPRENE GLO VES,LAB COAT/COVERALLS,RESPIRATOR). Neutralizing Agent:CITRIC ACID OR DILUTE HCL SOLUTION ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:CAUTION,IRRITANT.MAY CAUSE EYE DAMAGE.MAY CAUSE IRRITATION TO SKIN & MUCOUS MEMBRANES.AVOID INHALATION & CONTACT W/ EYES,SKIN & CLOTHING.CONTAINS STRONG ALKALI. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:IN CASE OF LARGE SPILL-APPROP PROT EQUP:EYE Work Hygienic Practices:N/K Supplemental Safety and Health PART NO:REAGENT 1,3C159,PART A.BP:N/K (WATER:100C,212F).ROUTES OF ENTRY:INHALATION/SKIN/INGESTION . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPP DATA Melt/Freeze Pt:M.P/F.P Text:SOLUTION Decomp Temp:Decomp Text:N/K Solubility in Water:SOLUTION Appearance and Odor:CLEAR AQUEOUS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS & METALS (AL,SN,ZN).NAOH MAY REACT WITH CO*2 IN AIR TO FORM NA*2CO*3. Stability Condition to Avoid:N/K Hazardous Decomposition Products:WILL LIBERATE HYDROGEN GAS UPON CONTACT WITH SOME METALS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE & LOCAL REGULATIONS .NEUTRALIZED SOLUTIONS CAN BE RELEASED TO SEWER.ASSAY SOLUTIONS MAY NEED TO BE HANDLED AS INFECTIOUS WASTE AS HUMAN FLUIDS A RE BEING ASSAYED.HANDLE/DISPOSE ACCORDING TO REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:LX500 TEFLON WHITE, 8W24 Preparer's Name:J SCARBALIS CAGE:0HKK2 CAGE:98795 CAGE:0HKK2 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 4-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: < 10% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER (1-METHOXY 2-PROPANOL ACETATE) (PMGE ACETATE). VP: 3.8 @ 20C. CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 40-50% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT, HEADACHE, DIZZINESS, OR DROWSINESS. CHRONIC: THOSE HAZARDOUS MATERIALS LISTED MAY AFFECT THE FOLLOWING ORGANS: RESPIRATORY TRACT, LIVER, CE NTRAL NERVOUS SYSTEM. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN AT THIS TIME. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE. EYE: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER. INGEST: DRINK WAT ER. IF NECESSARY, CONSULT MD FOR ANY OFTHESE CONDITIONS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:22.0F,-5.6C Lower Limits:1.50 Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID BEATHING VAPORS, VENTILATE AREA, AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. MAKE SURE (SEE OTHER PREC) Other Precautions:HNDLG/STOR PREC: DRUM IS COMPLETELY EMPTY BEFORE ATTEMPTING TO WELD OR BRAZE. THE DRUM SHOULD BE INDUSTRIALLY CLEANED PRIOR TO REUSE. DO NOT FLAME CUT, BRAZE, OR WELD WITHOUT A NIOSH/MSHA APPROVED RES PIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE GENL DILUTION/LOC EXHST FAIL TO ADEQ DILUTE TWA/PEL, THEN RESP PROT SHOULD BE USED AS FOLLOWS: I/A/W 29CFR 1910.134, USE NIOSH/MSHA APPRVD AIR LINE TYPE RESPS/HOODS FOR ENCLOSED/CONFINED AREAS. USE AIR PURIFYING RESPS FOR OTHER AREAS. Ventilation:PROVIDE GENL DILUTION OR LOCAL EXHAUST VENTILATION TO KEEP TWA/LEL BELOW ACCEPTABLE LIMITS & TO REMOVE DECOMP PRODUCTS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:172F,78C Vapor Pres:SEE INGRED Vapor Density:> AIR Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FUMES MAY CONTAIN CO AND NO*X. MAY PRODUCE HAZARDOUS FUMES WHEN HEATED TO DECOMPOSITION AS IN WELDING. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:METHYL ETHYL KETONE CAGE:TO186 CAGE:TO186 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE CAS:78-93-3 RTECS #:EL6475000 Minumum % Wt:99. Maxumum % Wt:100. Other REC Limits:N/K OSHA PEL:590 MG/M3;200 PPM OSHA STEL:N/K ACGIH TLV:590 MG/M3;200 PPM ACGIH STEL:885 MG/M3;300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INGESTION: MAY CAUSE NAUSEA, DIARRHEA, VOMITING, INEBRIATION (DRUNKENNESS), DIFFICULTY BREATHING, HEADACHE, COMA. SKIN: IRRITATION, DEFATTING, CRACKING, DERMATITIS. INHALATION: VAPORS CAN CAUSE DIZZINESS, DROWSINESS, STUPOR. EYES: SEVERE IRRITANT - MAY CAUSE DAMAGE. SUBCHRONIC (TARGET ORGAN): CENTRAL NERVOUS SYSTEM DEPRESSANT. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE THE FOLLOWING EFFECTS: DERMATITIS AND SKIN DEFATTING; CONJUNCTIVITIS; INFLAMMATION OF THE RESPIRATORY TRACT, WEAKNESS, DROWSINESS; LIVER AND KIDNEY DAMAGE, CLINICAL NEUROPATHY. (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS: OTHER TOXICOLOGICAL DATA: CONSUMPTION OF ALCOHOL MAY INCREASE THE ACUTE EFFECTS OF EXPOSURE. EXPOSURE MAY POTENTIATE THE EFFECTS OF N-HEXANE. Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY OR SKIN DISEASES. PERSONS WITH A HISTORY OF PERIPHERAL NEUROPATHY. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, UNTIL MEDICAL ASSISTANCE IS OBTAINED. SKIN: IMMEDIATELY REMOVE CONTAMINATED CLOTHING. RINSE EXPOSED AREAS THOROUGHLY. IF IR RITATION OCCURS CONSULT MD. CONTAMINATED CLOTHING MUST BE LAUNDERED BEFORE REUSE. INHALATION: IMMEDIATELY REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, A QUALIFIED PERSON SHOULD IMMEDIATELY BEGIN ARTI FICIAL RESPIRATION. OBTAIN IMMEDIATE MEDICAL ASSISTANCE! INGESTION: IF CONSCIOUS, INDUCE VOMITING KEEPING HEAD BELOW HIPS TO AVOID ASPIRATION. GET IMMEDIATE MEDICAL ASSISTANCE. NOTE TO MD: NO SPECIFIC ANTIDOTE, TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=-8.9C, 16.F Autoignition Temp:=403.9C, 759.F Lower Limits:1.4% @ 200F Upper Limits:11.4% @ 200F Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. FOR LARGE FIRES, USE WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . CONSIDER EVACUATION DOWNWIND. IF POSS MOVE CONTRS FROM FIRE AREA. APPLY COOLING WATER TO SIDES OF CONTRS ENSURING YOU STAY AWAY FROM ENDS OF TANKS (BUL K STOR, RAIL CARS, TANK TRUCKS). EVACUATE IMMED IF TANKS ARE DISCOLORED/IF RISING SOUND IS EMITTED FROM TANKS. (SUP DAT) Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPOR-AIR MIXTURES ARE EXPLOSIVE. SENSITIVITY TO MECHANICAL IMPACT: NO. SENSITIVITY TO STATIC DISCHARGE: YES. FLAMMABILITY CLASS (OSHA): IB. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF SOURCE, IF W/OUT RISK. EVACUATE NON-ESSENTIAL PERSONNEL. ELIMINATE ALL SOURCES OF IGNITION. DIKE AREA TO PREVENT SPREADING. PREVENT RUNOFF INTO SEWERS, WATERWAYS, DITCHES/STREAMS. SHOVEL/PUMP TO SALVAGE TANK USING NON-SPARKING EQUIPMENT. ABSORB RESIDUAL MATERIAL W/INERT ABSORBENT. SHOVEL ABSORBED RESIDUE INTO PROPERLY IDENTIFIED DRUMS FOR LATER DISPOSAL. CONTACT LOC OFFICIALS AS REQUIRED. ======================Handling and Storage ====================== Handling and Storage Precautions:PROD MUST BE HANDLED BY PROPERLY TRAINED PERS. USE PROPER HNDLG EQUIP FOR SPECIFIC HNDLG OPERATION. WHEN TRANSFERRING MATL FROM ONE CONTR TO ANOTHER ENSURE BONDING & GROUNDING TO PVNT STATIC DISCHARGE . DO NOT BREATHE VAPS. AVOID ALL SKIN & EYE CONT BY WEARING PROPER PROT EQUIP. Other Precautions:HANDLE & STORE AWAY FROM ALL SOURCES OF IGNITION & INCOMPATIBLE MATERIALS. ENSURE THAT STORAGE AREA IS ADEQUATELY VENTILATED & EQUIPPED W/PROPER EMERGENCY RESPONSE EQUIPMENT IN THE EVENT OF LEAK, SPIL L/FIRE. OBSERVE ALL FEDERAL, STATE, & LOCAL REGULATIONS WHEN STORING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, MUST NOT EXCEED WORK LIMS OF RESP & BE NIOSH APPRVD. THE FOLLOWING ARE MIN REQS: EXPOS TO 1000 PPM: ORG VAP CARTRIDGE RESP; E XPOS 1000-3000 PPM: AIR-PURIFYING FULL-FACEPIECE W/CHIN STYLE FRONT/BACK MOUNTED ORG VAP CANISTER; ESCAPE RESP: ANY SELF-CONTAINED ESCAPE TYPE BRTHG APPARATUS. Ventilation:PROVIDE LOCAL EXHAUST VENT TO MEET PUBLISHED EXPOSURE LIMITS. VENT EQUIPMENT SHOULD BE EXPLOSION-PROOF IF EXPLOSIVE CONCS OF DUST, VAPOR/FUME ARE PRESENT. Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THORO AFTER HANDLING. ENGINEERING CONTROLS: ENSURE THAT VENT SYSTEM USED IS DESIGNED TO MEET PUBLISHED EXPOS LIMITS. PROPER HANDLING SYSTEMS SHOULD BE DESIGNED FOR SPECIFIC HANDLING OPERATION. Supplemental Safety and Health FIRE FIGHTING PROC: MINIMUM EVACUATION RADIUS SHOULD BE 1/2 MILE. FOR MASSIVE FIRE USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES. WATER MAY BE INEFFECTIVE IF FLOW OF FLAMMABLE LIQUID IS NOT STOPPED. ================== Physical/Chemical Properties ================== Boiling Pt:=80.C, 176.F Melt/Freeze Pt:=-86.1C, -123.F Vapor Pres:100.0 MM HG @ 25C Vapor Density:2.5(AIR=1) Spec Gravity:0.8054 (H*2O=1) Evaporation Rate & Reference:2.7 (ETHER=1) Solubility in Water:27.5% @ 20C Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH CHARACTERISTIC KETONE ODOR (SWEETISH MINT-LIKE). Percent Volatiles by Volume:100.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ISOPROPYL ALCOHOL (DURING STORAGE), CHLOROFORM, EXPLOSIVES, PEROXIDES, OLEUM, STRONG OXIDIZERS, PLASTICS, RESINS, RUBBER, POTASSIUM TERT-BUTOXIDE, RADIOACTIVE MATERIALS. Stability Condition to Avoid:EXPOSURE TO HEAT, FLAME OR IGNITION SOURCES. CONTACT WITH INCOMPATIBLE SUBSTANCES. Hazardous Decomposition Products:OXIDES OF CARBON. =================== Toxicological Information=================== Toxicological Information:METHYL ETHYL KETONE, RTECS 95/01 EL6475000: LD50 RAT: 2737 MG/KG; LD50 MOUSE: 4050 MG/KG; LD50 DERMAL RABBIT: 6500 MG/KG; LC50 INHALATION RAT: 23500 MG/M3 8 HOURS; LC50 INHALATION MOUSE: 40 G/M3 2 HOU RS. EXPERIMENTAL TERATOGEN. AMES TEST RESULTS: NO DATA AVAILABLE COVERING AMES TEST RESULTS. SKIN RABBIT - MILD 402 MG/24 HR. SKIN RABBIT - MODERATE 500 MG/24 HR. EYE HUMAN - IRRITATION @ 350 PPM. ===================== Ecological Information ===================== Ecological:ECOTOXICOLOGICAL INFORMATION: NO DATA AT THIS TIME. CHEMICAL FATE INFORMATION: NO DATA AT THIS TIME. OTHER INFORMATION: EMERGENCY OVERVIEW: CLEAR, COLORLESS, VOLATILE LIQUID WITH CHARACTERISTIC KETONE ODOR. RESPIRATORY TRACT - AVOID BREATHING VAPORS - MAY AFFECT CENTRAL NERVOUS SYSTEM. SKIN IRRITATION - AVOID CONTACT WITH SKIN AND CLOTHING. EYE IRRITATION - AVOID EYE CONTACT. FLAMMABLE LIQUID - KE EP AWAY FROM ALL SOURCES OF IGNITION. WASH THOROUGHLY AFTER HANDLING. HANDLE WITH CAUTION AND USE ONLY WITH ADEQUATE VENTILATION. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. REPORTABLE QUANTITY: RCRA U159 5000 LBS. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING NAME: METHYL ETHYL KETONE. DOT HAZARD CLASS: 3 - FLAMMABLE LIQUID; PACKAGING GROUP II. DOT LABELS: ALL PACKAGED MATERIAL MUST BE LABELED IN ACCORDANCE WITH DOT AND OSHA STANDARDS. UN NUMB ER: UN1193. PLACARDS: SHIPMENTS OVER 2000 LBS. IATA: CLASS 3. IMO/IMDG: 3.2. EUROPEAN CLASS: FLAMMABLE LIQUID. TRANSPORT EMERGENCY PROCEDURES: CONTACT CHEMTREC 1-800-424-9300; IN CANADA CONTACT CANUTE C 1-613-996-6666. OTHER: NOT APPLICABLE. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTION 302: NO. SARA SECTION 304: NO. SARA HAZARD CATEGORIES SECTIONS 311/312: ACUTE HAZARDS: YES; CHRONIC HAZARDS: NO; FIRE HAZARDS: YES; REACTIVITY HAZARDS: NO; SUDDEN RELEASE HAZARDS: NO. SAR A (313) CHEMICALS: YES - METHYL ETHYL KETONE. Federal Regulatory Information:EPA TSCA INVENTORY: APPEARS. CERCLA SECTION 103: YES - METHYL ETHYL KETONE - 5000 LBS REPORTABLE QUANTITY. CANADIAN WHMIS CLASSIFICATION: B2, D2B. OSHA PROCESS SAFETY: NO. CANADIAN DOMESTIC SUBSTANCES LIST (DSL): APPEARS. EINECS INVENTORY: APPEARS. State Regulatory Information:CALIFORNIA PROPOSITION 65: NO. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HEMPEL'S H939-118F, DARK GRAY, COMP A Kit Part:Y CAGE:DO341 CAGE:DO341 CAGE:4Y901 ============= Composition/Information on Ingredients ============= Ingred Name:TALC (CONTAINING NO ASBESTOS) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 35-50% OSHA PEL:2 MG/M3 RDUST ACGIH TLV:2 MG/M3 RDUST; 9192 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 25-35% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 5-5% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:TETRAETHYLENE PENTAMINE CAS:112-57-2 RTECS #:KH8585000 Fraction by Wt: < .5% Ingred Name:TRIETHYLENE TETRAMINE CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: 5-5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Explanation of Carcinogenicity:ACGIH LISTS CHROMATES OF LEAD AS "INDUSTRIAL SUBSTANCES SUSPECT OF CARCINOGENIC POTENTIAL FOR MAN". Effects of Overexposure:INHL: IRRITATION RESPIRATORY TRACT,NERVOUS SYSTEM DEPRESSION SUCH AS GIDDINESS,HDACHE,DIZZINESS,NAUSEA, & LOSS OF CONSCIOUSNESS. DEATH MAY OCCUR. EYE IRRITATIONSKIN PROLONGED/REPEATED LIQUID CONTACT R ESULT DEFATTING,DRYING MAY RESULT INIRRITATION AND DERMATITIS. Medical Cond Aggravated by Exposure:PREEXISTING EYE,SKIN,RESPIRATORY DISORDERS MAY BE AGGRAVATED BY ANY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INHL: REMOVE VICTIM TO FRESH AIR/PROVIDE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. SKIN: REMOVE CONTAMINATED CLOTHIN, FLUSH W/WTR, EYE: FLUSH W/PLENTY OF WTR AT LEAST 15MINS. GET MEDICAL AID. INGST N: DONOT INDUCE VOMITING, PREVENT LIQUIDASPIRATION INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:99F/37.22C Lower Limits:1.4 Extinguishing Media:FOAM, C02, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:CONTAINERS EXPOSED TO INTENSE HEAT SHOULD BE COOLED W/WATER. AVOID SPREADING LIQUID W/WTR USED FOR COOLING. DONOT ENTER FIRE AREA W/O PROPER PROTECTION. Unusual Fire/Explosion Hazard:CONTAINERS TIGHTLY CLSD. ISOLATE FROM HEAT,ELEC EQUIP,SPARKS & OPEN FLAME. VAPRSMAY BE HVYR THAN AIR & TRAVEL ALONG GRND BEFORE IGNITION/FLASHING. NO WELD/CUTNG ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF/ELIMINATE ALL IGNITION SOURCES. KEEP PEOPLE AWAY FROM SPILL. RECOVER ANY FREE PRODUCT. ADD SAND,EARTH OR OTHER SUITABLE ABSORBANT TO SPILL AREA. MINIMIZE BREATHING VAPORS/SKIN CONTACT. VENT C ONFINED SPACES.KEEP OUT OF SEWERS/PUBLIC WATERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP PRODUCT CONTAINERS COOL,DRY, & AWAY FROM ANY SOURCE OF IGNITION. USE AND STORE THIS PRODUCT W/ADEQUATE VENT. Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. STORAGE CONDITIONS REFER TO OSHA REGULATION 29 CFR 1910.106. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION DEPENDS ON THE VAPOR CONCENTRATION ABOVE THE TLV-PEL. USENIOSH/MSH APPROVED CARTRIDGE-TYPE PARTICULATE/VAPOR RESPIRATOR OR AIR-SUPPLIED MASK IN CONFINED AREAS. Ventilation:VENTILATE IN ACCORDANCE W/OSHA REG.29 CFR1910. LOCAL EXHST PROVIDED TO KEEP LEL/TLV-PEL OF HAZRDS INGRED BELOW LIMITS Other Protective Equipment:USE AS NECESSARY DEPENDING UPON THE METHOD OF APPLICATION & IMMEDIATE WORKING ENVIRONMENT. Work Hygienic Practices:WASH HANDS AFTER USING MATERIAL & BEFORE EATING,DRINKING, & SMOKING Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:247.0 246.0 Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:TYPICAL OF SOLVENTS USED Percent Volatiles by Volume:53.06 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/OXIDIZING AGENTS Stability Condition to Avoid:HEAT,FLAME,SPARKS & CONTACT W/OXIDIZING AGENTS. PRESENCE OF HEAT/ORGANIC MATTER,LEAD CHROMATE CAUSE OXIDIZATION REACTION Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY GENERATE CARBON MONOXIDE,DIOXIDE,&OTHER HAZRD TOXIC VAPORS FROM ORGANIC COMPOUNDS. Conditions to Avoid Polymerization:HEAT,FLAME,SPARKS, & CONTACT W/OXIDIZING AGENTS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL,STATE,& LOCAL REGULATIONS. OBSERVE PRECAUTIONS FOR THE VOLATILE VAPORS FROM THE ABSORBED MATERIAL. INCINERATE ONLY IN AN APPROVED MANNER AND LOCATION.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DEVFLEX 601 595A22563 BEACH SAND P/N 601S6963 Preparer's Name:LOUIS F HOLZKNECHT CAGE:1HK86 CAGE:1HK86 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC RESIN Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:ANTIMONY TRIOXIDE (SARA III) CAS:1309-64-4 RTECS #:CC5650000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CHLOROHYDROCARBON POLYMER CAS:9002-86-2 RTECS #:KV0350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10MG/M3 TOTAL DUST Ingred Name:DIPROPYLENE GLYCOL MONO METHYL ETHER (VAPOR PRESSURE <0.1 MM HG) CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM (SKIN) ACGIH TLV:100 PPM (SKIN) Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TOTAL DUST Ingred Name:VINYL ACETATE RESIN Fraction by Wt: 25% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER (VAPOR PRESSURE 17.5 MM HG) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40% Other REC Limits:NONE RECOMMENDED Ingred Name:CALCULATED VOC: 236.91 GM/L RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE: BREATHING: IRRITATION OF THE RESPIRATORY TRACT; HEADACHE, NAUSEA, DIZZINESS. SKIN OR EYE CONTACT: PRIMARY IRRITATION. CHRONIC: PROLONGED AND REPEATED BREATHING OF SPRAY MIST AND/OR SANDING DUST OVER A PERIOD OF YEARS MAY CAUSE DUST DISEASE OF THE LUNGS. Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:IF BREATHED: REMOVE TO FRESH AIR. IF IN EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN FOR MEDICAL TREATMENT. IF ON SKIN: REMOVE WITH SOAP AND WATER. REMOVE SOILED CLOTHING. IF SWALLOWED: DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT PHYSICIAN IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:1.1 Extinguishing Media:IN CASE OF FIRE USE CO2, DRY CHEMICAL, FOAM, OR OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:PROFESSIONAL FIREFIGHTER-FULL PROTECT EQUIP (SCBA).WATER SPRAY MAY BE INEFFECTIVE,USE TO COOL FIRE EXPOSD CNTNR (FOG NOZZLES PREFERABLE) PREVENT BLDUP/AUTOIGNIT Unusual Fire/Explosion Hazard:DUE TO PRESSR BLDUP,CLSD CNTNR EXPOSD TO HEAT MAY EXPLODE.DURING EMERG CONDTNS,OVEREXPOSURE TO DECOMP PRODUCT-HEALTH HZD.SYMPTOM NOT IMMED APPARENT.GET MED AID. ================== Accidental Release Measures ================== Spill Release Procedures:WASH WITH WATER. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THIS MATERIAL SAFETY DATA FORM. CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 110F AND KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY CONTAINERS. Other Precautions:DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELLED CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT BREATHE VAPOR,SPRAY,DUST.WHEN SPRAY APPLIED IN OUTDOOR OR OPEN AREAS & DURING SANDING OR GRINDING OPERATIONS,NIOSH/MSHA APPRV'D MECHANICAL FILTER RSPRTR TO REMOVE SOLID AIRBORNE PARTICLES OF OV ERSPRAY & DUST.WHEN USED IN RESTRICTED * Ventilation:USE W/VENT.GENERAL DILUTION OR LOCAL EXHAUST VENT TO KEEP BELOW HEALTH STD IN MIXING,APPLIC,CURING AREA &DECOMP PRODUCTS Other Protective Equipment:NONE REQUIRED Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health * VENTILATN AREAS, WEAR NIOSH/MSHA CHEMICAL/MECHANICAL FILTER DESIGNED TO REMOVE COMBINATION OF PARTICULATE & VAPOR. WHEN USED IN CONFINED AREAS, WEAR NIOSH/MSHA AIR SUPPLY RESPIRATORS/HOODS. USE NIOS H/MSHA RESPIRATORS WHEN FLAME CUTTING, WELDING, BRAZING, SANDING MAT'L COATED W/PRODUCT. FOLLOW RSPRTR MFR'S DIRECTIONS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212 TO 356F Vapor Density:>AIR Spec Gravity:1.2 - 1.3 pH:5-8 Viscosity:70 - 90 KU Solubility in Water:APPRECIABLE Appearance and Odor:BEACH SAND VISCOUS LIQUID, MILD ODOR Percent Volatiles by Volume:59.73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:WHEN HEATED TO DECOMP. FUMES MAY CONTAIN CO, CO2, OXIDES OF NITROGEN, CHLORINE OR HCL, OXIDES & CHLORIDES OF ANTIMONY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TASIL 101 D PATCH CAGE:59290 CAGE:78690 CAGE:59290 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE/INHAL:MODERATE IRRITANT. SKIN:MILD IRRITANT. CHRONIC:SILICA MAY CAUSE SILICOSIS. ON THE BASIS OF INITIAL TESTS IN ANIMALS & LIMITED EPIDEMILOGICAL STUDIES IN HUMAN POPULATIONS, THE IARC HASCONCLUDED THAT THERE IS LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS. Explanation of Carcinogenicity:CRYSTALLINE SILICA:GROUP 2A (IARC); GROUP 2 (NTP) Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/CLEAN WATER FOR AT LEAST 15 MINUTES. CALL MD IMMEDIATELY IF IRRITATION PERSISTS. SKIN:FOR IRRITATION, WASH AREA THOROUGHLY W/SOAP & WATER. INHAL:MOVE TO CLEAN AIR IMMEDIATELY. INGEST:GET M D IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP OR VACUUM. DO NOT WASH INTO SEWERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STEAM SPALLING MAY OCCUR FROM IMPROPER DRYING, CURING & FIRING. Other Precautions:STEAM SPALLING OF THICK REFRACTORY SECTIONS CAN BE EXPLOSIVE IN CHARACTER. POTNTL FOR SERIOUS INJURY EXISTS FROM FAILURE TO FOLLOW RECOMM HEATING SCHEDULES. CHECK W/EMPLOYER FOR RECOMM SCHEDULE AVAIL FROM NARCO. IF FURTHER (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED MASK OR RESPIRATOR FOR CONTAMINANTS PRESENT. Ventilation:USE ADEQUATE VENTILATION TO ASSURE TLV LIMITS ARE NOT EXCEEDED. Other Protective Equipment:LONG SLEEVES. Work Hygienic Practices:ALWAYS WASH HAZARDOUS MATL FROM SKIN W/SOAP & WATER AS SOON AS PRACTICAL. DO NOT EAT, DRINK, SMOKE BEFORE WASHING HANDS. Supplemental Safety and Health PH:ALKALINE. OTHER PREC:INFORMATION IS REQUIRED, CONTACT NORTH AMERICAN REFRACTORIES COMPANY. ================== Physical/Chemical Properties ================== HCC:N1 pH:SUPDAT Appearance and Odor:GRAY, POWDER/PASTE, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW GOVERNMENTAL (FEDERAL, STATE, LOCAL) REGULATIONS. LANDFILL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:23F1116FC CAGE:01002 CAGE:01002 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR.GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS PE RSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE,THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW COLORED LIQUID-AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A947SS200 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA) LD50 (ORAL RAT): 5628 MG/KG CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM/250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: THOSE OF ACUTE INHALATION AND INGESTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: EFTS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, INCL EXCITEMENT, FOLLOWEDBY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT, LIVER & KIDNEY DAMAGE, ADVERSE CNS EFTS INCLUDING HDCH, CONVULSIONS, & PO SS DEATH. MAY CAUSE VISUAL IMPAIRMENT &POSS PERM BLINDNESS, & EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.00% Upper Limits:31.00% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CONTRS CAN BUILD-UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERS PROT EQUIP AS INDICATED. SCOOP UP W/NON-SPARKING TOOL, THEN PLACE INTO SUITABLE CONTR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE SOURCES OF IGNIT. ABSORB SPILL USING ABSORB,NON-COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS RETAIN PROD RESIDUE (LIQUID, &/OR VAPOR), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM IN COMPATIBLE SUBSTANCES. FLAMMABLES-AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ: MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASH POINT. MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSI UM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 MMHG Vapor Density:1.1 Spec Gravity:0.791 Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: WASTE NUMBER U154 (IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:809 0532 FLEXICOLOR STABLIZER REPLENISHER L CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70 - 75% Other REC Limits:NONE RECOMMENDED Ingred Name:HEXAMINE/HEXAMETHYLENETETRAMINE CAS:100-97-0 RTECS #:MN4725000 Fraction by Wt: 25 - 30% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM DODECYLBENZENESULFONATE (SARA III) CAS:25155-30-0 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NONIONIC SURFACTANTS Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED Ingred Name:SUBSTITUTED THIAZOLIN-3-ONE Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE- WARNING! HARMFUL IF SWALLOWED. CAN CAUSE GASTROINTESTINAL IRRITATION. CAUSES SKIN AND EYE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. LOW INHALATION HAZARD FOR RECOMMENDED HANDLING. UNDER ACI DIC CONDITION, MAY RELEASE FORMALDEHYDEWHICH MAY CAUSE RESPIRATORY SENSITIZATION IN SOME INDIVIDUALS. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE, SKIN, GASTROINTESTINAL TRACT IRRITATION Medical Cond Aggravated by Exposure:IF FORMALDEHYDE IS FORMED, IT MAY AGGRAVATE PRE-EXISTING ASTHMATIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. ORAL: DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK A GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH SMALL SPILLS OR RELEASES TO SEWER WITH LARGE AMOUNT OF WATER IF PERMITTED. LARGE SPILLS SHOULD BE COLLECTED FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM ACIDS AND OXIDIZERS. KEEP CONTAINERS CLOSED. Other Precautions:WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP OUT OF REACH OF CHILDREN. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER I S EMPTIED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF FORMALDEHYDE IS PRESENT AT LEVELS REQUIRING RESPIRATROY PROTECTION, A NIOSH APPROVED RESPIRATOR FOR PROTECTION AGAINST FORMALDEHYDE OR A TYPE C AIR-SUPPLIED RESPIRATOR DEMAND TYPE, WITH FULL FACEPI ECE, HOOD OR HELMET SHOULD BE WORN. Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS (10 ROOM VOLUMES PER HOUR). Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health CONCENTRATE: TO MAKE 10 LITRES. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:<32F,<0C Decomp Temp:Decomp Text:>563F,>295C Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.06 pH:7.7 Solubility in Water:COMPLETE Appearance and Odor:AMBER LIQUID WITH SLIGHT AMINE ODOR Percent Volatiles by Volume:70- 75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS Stability Condition to Avoid:EXCESSIVE HEAT (TEMPERATURES ABOVE 195C (383F)) Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR, AMMONIA, FORMALDEHYDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN CONFORMITY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:XYLENE CYANOL FF, 113 1069, 248983 CAGE:GO467 CAGE:ACRSR CAGE:GO467 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENOLS; (XYLENE CYANOL FF) CAS:4463-44-9 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN INVESTIGATED. EXERCISE APPROPRIATE PROCEDURES TO PREVENT OPPORTUNITIES FOR DIRECT CONTACT WITH THE SKIN OR EYES AND TO PREVENT INHALATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. IF SYMPS ARE PRESENT GET MED ATTN. SKIN: IMMED FLUSH SKIN W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CONTAMD CL THG BEFORE REUSE. DESTROY/THORO CLEAN CONTAMD SHOES. GET MED ATTN IF SYMPS ARE PRESENT AFTER WASHING. EYES: IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN & GET MED ATTN. INGEST: IF (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZ DECOMPOSITION PRODUCTS. THIS MATL IN SUFFICIENT QUANTITY & REDUCED PARTICLE SIZE IS CAPABLE OF CREATING DUST EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP MATERIAL AND PACKAGE FOR SAFE FEED TO AN INCINERATOR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQ TO CONTROL DUST CONCS TO AN ACCEPTABLE LEVEL, A NIOSH/MSHA APPRVD DUST RESPIRATOR SHOULD BE WORN IF NEEDED. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED T O ASSURE COMPLIANCE W/29 CFR 1910.134. Ventilation:USE PROCESS ENCLOSURES, LOC EXHST VENT OR OTHER ENGINEERING CONTROLS TO REDUCE DUST CONCS TO AN ACCEPTABLE LEVEL. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: SWALLOWED, CALL MD OR POIS CTL CTR IMMED. ONLY INDUCE VOMIT AT INSTRUCTIONS OF MED PERS OR POIS CTL CTR. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. ================== Physical/Chemical Properties ================== Vapor Pres:NEGLIG Evaporation Rate & Reference:NEGLIG(N-BUTYL ACETATE=1) Appearance and Odor:DARK BLUE-GREEN CRYSTALLINE SOLID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, REDUCING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON DIOXIDE AND PROBABLY CARBON MONOXIDE. OXIDES OF NITROGEN AND SULFUR MAY ALSO BE PRESENT. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE BY INCINERATION OR CONTRACT WITH LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT OF DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE AND LOCAL LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:791-716 CAGE:09869 CAGE:09869 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <12% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:SE7555000 Fraction by Wt: <12% OSHA PEL:100 PPM Ingred Name:CYCLOHEXANONE Fraction by Wt: <12% ACGIH TLV:50 PPM Ingred Name:ISOBUTYL ACETATE Fraction by Wt: <25% ACGIH TLV:150 PPM Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <20% OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:INHALE: ANESTHETIC,IRRITATION OF RESPIRATORY TRACT,ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY ======================= First Aid Measures ======================= First Aid:INCASE OF CONTACT, FLUSH SKIN AND EYES WITH PLENTY OF WATER WHILE REMOVING CONTAMINATED CLOTHING. IF INHALED, REMOVE TO FRESH AIR. CALL A PHYSICIAN IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Flash Point:28F, -2C TCC Lower Limits:1.1 Extinguishing Media:CARBON DIOXIDE/DRY CHEMICAL-SMALL; POLYMER FOAM-LARGE FIRE Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS AVAILABLE FOR FIREMEN Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE DUE TO PRESSURE BUILD-UP ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, AND ELECTRICAL, STATIC, OR FRICTIONAL SPARKS). AVOID BREATHING VAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS ONE FLAMMABLE (OR COMBUSTIBLE) LIQUID. Other Precautions:DO NOT TAKE INTERNALLY,CONTAINERS SHOULD BE GROUNDED WHEN POURING,AVOID FREE FALL IN EXCESS OF A FEW INCHES,DO NOT FLAME CUT,BRAZE, OR WELD COATED MATERIAL WITHOUT VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED BUREAU OF MINES RESPIRATORS W/PROPER FILTER OR HOOD Ventilation:GENERAL DILUTION/LOCAL EXHAUST FOR TLV&LEL SAFETY& WELDING Other Protective Equipment:PREVENT PROLONGED SKIN CONTACT TO CONTAMINATED CLOTHING. Supplemental Safety and Health BOILING RANGE 48-161C. MIBK % <5, TLV-100 PPM; ISOPROPYL ALCOHOL % <3, TLV-400 PPM. EFFECTS OF OVEREXPOSURE - HEADACHE, DIZZINESS ETC. OR COMA. PRIMARY IRRITATION FOR SKIN OR EYE CONTACT. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:118-321F Evaporation Rate & Reference:< ETHER Percent Volatiles by Volume:86.0 ================= Stability and Reactivity Data ================= Stability Condition to Avoid:FIRES, HEAT, AND HOT SURFACES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
gloves_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NICKEL & COPPER ALLOY COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMCIAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
gloves_mandatory
======================================================= Product ID: BAKELITE GREEN PREFORMS, 811-327 Cage: 94174 ======================================================= Contractor Summary ======================================================= Cage: 94174 ======================================================= Ingredients ======================================================= % Wt: 5-15 OSHA PEL: 10 MG/M3;5 RESP ACGIH TLV: 10 MG/M3;5 RESP ----------------------------- Cas: 108-95-2 RTECS #: SJ3325000 % Wt: 4.3 OSHA PEL: 5 PPM, S ACGIH TLV: 5 PPM, S EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 50-00-0 RTECS #: LP8925000 % Wt: 1.1 OSHA PEL: SEE 1910.1048 ACGIH TLV: C 0.3 PPM; A2; 9293 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 7664-41-7 RTECS #: BO0875000 OSHA PEL: 50 PPM ACGIH TLV: 25 PPM/35 STEL; 9293 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: YES Effects of Exposure: ACUTE:VAP MAY BE IRRIT TO SKIN, EYES/RESP TRACT. CHRONIC:EFTS OF RPTD INHAL OF VAPS <TLV'S LISTED, PRESUMED SAFE. VAPS EVOLVED DURING POLYMERIZATION/DECOMP MAY CAUSE IRRIT TO EYES, LUNGS & SKIN. PHENO L:HIGHLY TOX - MAY CAUSE KIDNEY, LIVER/HEART DMG. REPORTED TO BE TUMOR PROMOTER. FORMALDEHYDE:IRRIT - (EFTS OF OVEREXP) Explanation Of Carcinogenicity: FORMALDEHYDE:GROUP 2A(IARC), GROUP 2(NTP), OSHA REGULATED. Signs And Symptions Of Overexposure: HLTH HAZ:TO EYES, LUNGS & SKIN. HAS BEEN SHOWN TO CAUSE CANCER IN LAB ANIMALS, LISTED AS IARC CARCINOGEN. (NATIONAL CANCER INSTITUTE STUDY FINDS LITTLE EVID TO CONNECT FORMALDEHYDE EXPOS W/CANCER IN H UMANS.) AMMONIA:IRRITANT - TO EYES, MUCOUS MEMBRANES & RESP TRACT. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL:IF BRTHG AFFECTED, REMOVE TO FRESH AIR. IF BRTHG STOPS, APPLY MOUTH TO MOUTH RESUSCITATION. GET MD. SKIN:WASH THORO W/SOAP & WATER. EYE:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST 15 MIN. G ET MD. INGEST:DO NOT INDUCE VOMIT. DILUTE BY DRINKING LG QTYS OF WATER. IF VOMIT OCCURS, ADMIN MORE WATER. GET MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: VACUUM OR SWEEP W/SWEEPING COMPOUND, SAWDUST OR SAND. AVOID GENERATING DUST. VACUUMS W/EXPLOSION PROOF MOTORS ARE RECOMMENDED. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: BURY OR INCINERATE I/A/W LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: OBSERVE GOOD HOUSEKEEPING PRACTS. STORE IN COOL, DRY PLACE. KEEP CNTNRS CLSD TO AVOID CONTAM. PVNT ACCUM OF DUST RAISED DURING PROCESSING. Other Precautions: USE ADEQ VENT. ======================================================= Fire and Explosion Hazard Information ======================================================= Upper Limits: 0.030 OZ/FT3 Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). AVOID INHALATION OF GASES. Unusual Fire/Explosion Hazard: ORGANIC DUST/AIR MIXTURES ARE HIGHLY FLAMMABLE. (EXPLOSIVE). AVOID DUST ACCUMULATIONS OR DUST-LADEN ATMOSPHERES & SOURCES OF IGNITION. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATORS RECOMMENDED IF TLV'S ARE EXCEEDED. Ventilation: LOC EXHST:TO REMOVE DUST & VAPS EVOLVED DURING USE. MECH (GEN):DUST COLLECTION SYS. SPECIAL:POINT SOURCE EXHST (SUPDAT) Other Protective Equipment: EYE WASH FACILITY SHOULD BE AVAILABLE. Work Hygienic Practices: PRACTICE GOOD HYGIENE & MAINTAIN CLEAN WORK ENVIRONMENT. Supplemental Safety and Health: VENT:RECOMMENDED. OTHER:USE EXPLOSION PROOF MOTORS. ======================================================= Physical/Chemical Properties ======================================================= HCC: T3 Spec Gravity: 1.32-2.20 Solubility in Water: NEGLIGIBLE Appearance and Odor: GRANULAR, NODULAR, PELLET OR BRIQUET W/SLIGHT PHENOL ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID DUST BUILDUP IN STORAGE & MANUFACTURING AREAS. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: PHENOL, FORMALDEHYDE, AMMONIA, CO, CO*2. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: VAPORS EVOLVED DURING POLYMERIZATION MAY CONTAIN PHENOL, FORMALDEHYDE, AMMONIA. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 31225 Product ID: BAKELITE GREEN PREFORMS, 811-327 Review Date: 03/04/1993 Multiple KIT Number: 0 Review IND: Y Additional Data: NOT REGULATED FOR TRANSPORTATION ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: BAKELITE GREEN PREFORMS, 811-327 Cage: 94174 Company Name: LECO CORPORATION Street: 3000 LAKEVIEW AVE. Zipcode: 49085-2396 Label Required IND: Y Date Of Label Review: 02/19/1992 Status Code: C Label Date: 02/19/1992 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Moderate Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: OBSERVE GOOD HOUSEKEEPING PRACTICES. STORE IN COOL, DRY PLACE. KEEP CONTAINERS CLOSED TO AVOID CONTAMINATION. PREVENT ACCUMULATIONS OF DUST RAISED DURING PROCESSING. USE ADEQUATE VENTILATION. ACUTE:VA POR MAY BE IRRITATING TO SKIN, EYES OR RESPIRATORY TRACT. PRODUCTS EVOLVED DURING POLYMERIZATION OR DECOMPOSITION ARE IRRITATING TO EYES, SKIN AND RESPIRATORY TRACT, AND MAY CAUSE KIDNEY, LIVER OR HEA RT DAMAGE. CHRONIC:CONTAINS CANCEROUS MATERIALS. =======================================================
1
gloves_mandatory
======================================================= Product ID: CERTANE 55 Cage: FO432 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: FO432 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: VERY HAZ TO LUNGS IF ASPIRATED. PENETRATES & ABSORBED THRU SKIN. MOD ORAL TOX. SEV EYE IRRIT, SEV LUNG INJURY IF MIST IS INHALED/LIQ IS ASPIR INTO LUNGS DURING VOMIT/INGEST. RPTD SKIN CONT MAY CAUSE I RRIT; PROD IS ABSORBED THRU SKIN. LG EXPOS MAY CAUSE DEPRESS OF CNS. SIGNS & SYMPS OF EXPOS:EXPOS TO (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:HIGH VAP CONCS MAY CAUSE EYE IRRIT, RESP IRRIT, HDCHS, DIZZ, DROW & OTHER CNS EFTS. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS &LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOLMONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION (SUPP DATA) Medical Cond Aggravated By Exposure: EXISTING DERMATITIS MAY BE AGGRAVATED BY SKIN EXPOSURE. First Aid: INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES:FLUSH FOR AT LEAST 15 MINUTES W/WATER. SKIN:REMOVE CONTAMINATED CLOTHING & WASH SKIN THOROUGHLY W/SOAP & WATER. INGEST:DO NOT INDUCE VOMITING, RESUSCITATE IF NECESSARY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: KEEP OUT OF SEWERS & WATERCOURSES BY DIKING OR IMPOUNDING. RECOVER ANY FREE LIQUID. USE SOLID ADSORBENTS TO RECOVER REMAINING SPILLED MATERIAL. VENTILATE CONFINED SPACES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATE WASTE LIQUID. DISPOSE OF USED MATERIALS I/A/W FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINERS SEALED. AVOID SKIN & EYE CONTACT & BREATHING MIST. AVOID HEAT, FLAME & SPARKS. DO NOT APPLY BY SPRAYING. Other Precautions: COMBUSTIBLE LIQUID. DOT PLACARD REQUIRED ONLY IF SHIPPED BULK OR IN CONTAINERS LARGER THAN 110 GALLONS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 145F,63C Lower Limits: 1% Upper Limits: 10% Extinguishing Media: ALCOHOL FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). USE WATER SPRAY, DRY CHEMICAL, FOAM OR CO*2 TO EXTINGUISH FIRES. Unusual Fire/Explosion Hazard: INCOMPLETE COMBUSTION WILL PRODUCE FUMES, SMOKE, CARBON MONOXIDE, ALDEHYDES & OTHER DECOMPOSITION PRODUCTS. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED FULL FACE OR HALF FACE RESPIRATOR W/ORGANIC VAPOR CARTRIDGES. Ventilation: MAINTAIN VAPOR CONCENTRATION BELOW 25 PPM. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). WEAR SOLVENT RESISTANT APRONS & BOOTS (SUPDAT) Work Hygienic Practices: CLEANSE SKIN THORO W/WATERLESS HAND CLEANER, FOLLOWED BY THOROUGH WASHING W/SOAP & WATER. LAUNDER CONTAM CLTHG. (SUPDAT) Supplemental Safety and Health: SOL IN H*2O:SOLUBLE, READILY EMULSIFIES. EFTS OF OVEREXP:NO.90-118) (FP N). OTHER PROT EQUIP:TO AVOID CONTACTING CLOTHING. HYGIENE PRACT:CLEAN & DRY CONTAMINATED SHOES. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >340F,>171C M.P/F.P Text: <0F,<-18C Vapor Pres: <3 @ 78F Vapor Density: 4.8 Spec Gravity: 0.9 (H*2O=1) Solubility in Water: PARTIALLY (SUPDAT) Appearance and Odor: CLEAR LIQUID; AROMATIC HYDROCARBON ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: AVOID ZINC, MAGNESIUM & GALVANIZED METAL. AVOID OXIDIZING AGENTS. Hazardous Decomposition Products: HAZARDOUS DECOMPOSITION BYPRODUCTS NOT KNOWN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: CERTANE 55 Cage: FO432 Assigned IND: Y Company Name: CERTIFIED TECHNOLOGIES CORPORATION Street: 7404 WASHINGTON AVENUE SOUTH Zipcode: 55344 Label Required IND: Y Date Of Label Review: 11/14/1995 Status Code: C Label Date: 11/14/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE:VERY HAZARDOUS TO LUNGS IF ASPIRATED. PENETRATES & ABSORBED THROUGH SKIN. MODERATE ORAL TOXICITY. SEVERE EYE IRRITATION, SEVERE LUNG INJURY IF MIST IS INHALED OR LIQUID IS ASPIRATED INTO LUNGS DURING VOMITING OR INGESTION. REPEATED SKIN CONTACT MAY CAUSE IRRITATION; PRODUCT IS ABSORBED THROUGH SKIN. LARGE EXPOSURE MAY CAUSE DEPRESSION OF CENTRAL NERVOUS SYSTEM. CHRONIC:ANIMAL ST UDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON THE CENTRAL NERVOUS SYSTEM, BLOOD FORMING TISSUES, BLOOD, KIDNEY & LIVER, ASSOCIATED W/ADMINISTRATION OF 2-BUTOXYETHANOL (FP N). =======================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:UNSATURATED POLYESTER RESIN, W2299 CAGE:GWXLX CAGE:GWXLX ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE (SARA 313)VAP DENS: 3.6.LEL: 1.1% IN AIR. UEL: 6.1%. CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: 30-60% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 100 STEL, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXP MAY PRDCE DROWSINESS, WEAK UNSTEADY GAIT, NARCOSIS. SKIN CONTACT: RPTD/PRLNGD CONTACT MAY CAUSE DERMATITIS. SKIN ABSORPTION DOES NOT OCCUR. EYES: CONTACT W/LIQ OR VAP MAY CAUSE IRRIT W/ CORNEAL INJURY. MAY CAUSE LACRIMATION (TEARS). INHAL: CAN CAUSE IRRIT OF RESP TRACT, NARCOSIS & POSS (EFTS OF OVEREXP) Explanation of Carcinogenicity:STYRENE: IARC MONO, VOL 60, PG 233, 1994:GROUP 2B. Effects of Overexposure:HLTH HAZ: LUNG DAMAGE. INGEST: CAN CAUSE PRONOUNCED IRRIT OF MOUTH, ESOPHAGUS & STOMACH. IRRITANCY: PROD EXPECTED TO BE IRRITATING TO SKIN, EYES & THROAT. SENSIT: NOT PREDICTED TO BE SKIN SENSITIZER. TERATOGENICITY, MUTAGENICITY EFTS: NOT AVAILABLE. REPRO EFTS OF MATL: ON TEST ANIMALS MAY CAUSE ADVERSE REPRO EFTS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. SEEK MED ATTN IF IRRITATION PERSISTS. EYES: FLUSH W/FLOWING WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, OBTAIN MED ATTN. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN O R ARTIFICIAL RESPIRATION AS REQUIRED. OBTAIN MED ATTN. INGEST: DO NOT INDUCE VOMITING. SEEK MED ATTN. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:87.8F,31.0C Lower Limits:SEE ING 1 Upper Limits:SEE ING 1 Extinguishing Media:FOAM, DRY CHEMICAL OR CARBON DIOXIDE, WATER FOG, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DIVISION 2 FLAMMABLE LIQS; MODERATE FLAM WHEN EXPOSED TO FLAMES. SENSITIVE TO STATIC DISCHARGE. CARBON MONOXIDE & CARBON DIOXIDE ARE PRDCED ON COMBUST. (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA. ABSORB W/INERT MATERIAL SUCH AS VERMICULITE, SAND OR EARTH. PLACE IN CLOSED CONTAINER, WASH AREA W/WATER & TRISODIUM PHOSPHATE - TREAT AS FLAMMABLE. THE VAPOR CAN TRAVEL ALONG GROUND & ACCUMULATE INLOW AREAS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID DIRECT SUNLIGHT. AVOID ALL CONTACT W/SKIN OR EYES. STORE AWAY FROM HEAT & OXIDIZING AGENTS IN WELL VENTD AREA. PROTECT CNTNRS FROM (SUPDAT) Other Precautions:DO NOT SMOKE IN AREAS OF STORAGE OR USE. AVOID CONTACT W/SKIN & EYES. WEAR APPROPRIATE PROTECTIVE EQUIPMENT. STYRENE VAPOR IS UNINHIBITIED & MAY POLYMERIZE, POSSIBLY BLOCKING EXHAUST VENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN AIRBORNE CONCENTRATION EXCEEDS TLV OR UPPER RESPIRATORY TRACT IRRITATION OCCURS, USE NIOSH APPROVED ORGANIC VAPOR CHEMICAL CARTRIDGE RESPIRATOR. Ventilation:USE EXPLO-PROOF VENT TO PVNT VAP ACCUM. EMPTY CNTNRS MAY CNTN HAZ PROD RESIDUES. FIXED EQUIP AS WELL AS TRANSFER(SUPDAT) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP: 293F,145C (WILL POLYMERIZE). EXPLO HAZ: ALDEHYDES & EXPLO PEROXIDES ARE FORMED FROM INCOMPLETE COMBUST. EMITS ACRID FUMES. HNDLG/STOR PRECS: PHYSICAL DMG. STORAGE TEMPS BELOW 49C. LOWER STORAGE TE MPS WILL EXTEND PROD SHELF LIFE. VENT: CNTNRS & EQUIP SHOULD BE GROUNDED TO PREVENT ACCUM OF STATIC DISCHARGE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Melt/Freeze Pt:M.P/F.P Text:-24F,-31C Vapor Pres:4.5 Vapor Density:SEE ING 1 Spec Gravity:1.05-1.20 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:VISCOUS RED-PURPLE LIQUID; AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO ACID, BASE, OXIDIZING MATERIALS, ALUMINUM CHLORIDE. Stability Condition to Avoid:UNSTABLE AT HIGH TEMPERATURES. KEEP VAPOR AWAY FROM POSSIBLE IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, ALDEHYDES. EMITS ACRID FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL AUTHORITIES CONCERNING THE DISPOSAL OF THE WASTE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:VAPOR GARD CAGE:29057 CAGE:29057 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (LAB ANIMAL): >16 G/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO HEALTH HAZARD. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/WARM WATER & SOAP. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F Extinguishing Media:DRY CHEMICAL, CO2, FOAM ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP W/ABSORBENT MATERIAL. FLUSH AREA W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. Other Precautions:AVOID VAPOR INHALATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:MECHANICAL (GENERAL) IF NEEDED. Other Protective Equipment:CLEAN BODY COVERING CLOTHING. Work Hygienic Practices:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.94 Appearance and Odor:AMBER LIQUID, TERPENE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:COMP A, ZINC RICH PRIMER, W/R, 44GY016 Kit Part:Y CAGE:33458 CAGE:33458 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:FIRST AID PROC:VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:PRECAUTIONS HAVE BEEN READ & UNDERSTOOD. SMOKE IN SMOKING AREAS ONLY. FLAMMABLE LIQUID. RTECS #:9999999ZZ Ingred Name:VENT:REMOVE ALL IGNITION SOURCES (HEAT, SPARKS, FLAME & HOT SURFACES). RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ Ingred Name:SEC-BUTYL ALCOHOL (SARA 313). VP:12.5 @ 68F. CAS:78-92-2 RTECS #:EO1750000 Fraction by Wt: <5% OSHA PEL:150 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22 @ 68F. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC; (ZINC DUST) (SARA 313) (CERCLA). VP:0. CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 80% OSHA PEL:N/K ACGIH TLV:10 MP/F3 (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPDAT:DEVELOP. POTNTL FOR KIDNEY & LIVER DMG. WARNING:THIS PROD CONTAINS CHEM KNOWN TO STATE OF CALIFORNIA TO (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO HARM. NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. (ING 6) RTECS #:9999999ZZ Ingred Name:IGN 5:SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:VAPS ARE IRRIT TO EYES, NOSE & THROAT. INHAL MAY CAUSE HDCHS, DFCLT BRTHG & LOSS OF CONSCIOUSNESS. INHAL:IRRIT OF RESP TRACT & ACUTE NERV SYS DEPRESS CHARACT BY FOLLOWING PROGRESSIVE STEPS:HDCH, DIZZ, STAG GAIT, CONFUSN, UNCON/COMA. SKIN:CONT CAN CAUSE IRRIT. SYMPS MAY BE SWELL, REDNESS & RASH. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EYES:LIQ, AEROSOLS/VAPS ARE IRRIT & MAY CAUSE TEARING, REDNESS & SWELL ACCOMPANIED BY STINGING SENSATION. SKIN ABSORPTION:PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DRYING & DEFAT WHICH CAN CAUSE S KIN TO CRACK. INGEST:CAN RLST IN IRRIT & POSS CORR ACTION IN MOUTH, STOM TISS & DIGEST TRACT. VOMIT MAY CAUSE (SUPDAT) Medical Cond Aggravated by Exposure:ASTHMA & ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA & DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO AREA FREE FROM RISK OF FURTHER EXPOS. RESTORE BRTHG. ASTHMATIC TYPE SYMPS MAY DEVELOP & MAY BE IMMED/DELAYED BY SEVERAL HRS. OBTAIN MED ATTN. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA S THORO W/SOAP & WATER. WASH CONTAM CLTHG THORO BEFORE REUSE. EYES:FLUSH W/CLEAN LUKEWARM WATER (LOW PRESS) FOR AT LST 15 MINS, OCCAS LIFTING EYELIDS. OBTAIN MED ATTN. INGEST:DO NOT INDUCE (ING 7) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:1% Upper Limits:9.8% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP, AUTO IGNITION OR EXPLOSION. Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, SPKS, ELEC EQUIP & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDGS DESIGNED TO COMPLY W/OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS, FIRE, OPEN FLAMES & SPK SOURCES. STORE IN TIGHTLY CLSD CNTNRS. Other Precautions:STORE IN WELL VENTED AREAS. KEEP CNTNRS TIGHT & UPRIGHT TO PVNT LEAKAGE. PVNT PRLNG BRTHG OF VAPS/SPRAY MISTS. PRLNG OVEREXP MAY CAUSE ALLERGIC RXN. AVOID CONT W/SKIN & EYES. DO NOT TAKE INTERNALLY. D O NOT HANDLE UNTIL MFR'S SFTY (ING 8) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP THAT IS REC/APPRVD FOR USE IN ORG VAP ENVIRON (AIR PURIFYING/FRESH AIR SUPPLIED) IS NEC. OBSERVE OSHA REGS FOR RESP USE. VENT SHOULD BE PROVIDED TO KEEP EXPOS LEVELS BELOW OSHA PELS. Ventilation:EXHST VENT SUFFICIENT TO KEEP AIRBORNE CONCS OF SOLV VAPS/MISTS BELOW THEIR RESPECTIVE TLV'S MUST BE UTILIZED. (ING 9) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE OF LONG SLEEVE & LONG LEG CLTHG IS REC. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ:REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. EFTS OF OVEREXP:ASPIR OF SOLV, RESULTING IN CHEM PNEUM. CHRONIC:PRLNG CONT WILL CAUSE DRYING & CRACKING OF SKIN, DUE TO DEFAT ACTION. SKIN SENSIT, ASTHMA/OTHER ALLERGIC RESPONSES MAY (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>211F,>99C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:3.4922 Evaporation Rate & Reference:1.1 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:THIN LIQUID TO HEAVY VISCOUS MATERIAL, RED LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:28.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS & STRONG ACIDS. EPOXY RESINS UNDER UNCONTROLLED CONDITIONS. Stability Condition to Avoid:HIGH TEMPERATURES. EPOXY RESINS UNDER UNCONTROLLED CONDITIONS. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF I/A/W FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CNTNRS MUST BE HANDLED W/CARE, DUE TO PRODUCT RESIDUE & FLAMM VAP. DO NOT INCIN CLSD CNTNRS. EPA HAZ WAS TE #/CODE: D001, F005 (IGNITABILITY, REACTIVITY).
1
gloves_mandatory
===================== Product Identification ===================== Product ID:INDIUM, WIRE, 0.5MM DIAM., 99.99%, 35708-1 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:INDIUM CAS:7440-74-6 RTECS #:NL1050000 Fraction by Wt: 99.99% OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INHALED OR SWALLOWED. CAUSES IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: TREAT BY IMMEDIATE AND PROLONGED IRRIGATION WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ADVICE. SKIN: FLUSH WITH WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:AVOID CONT & INHAL.WASH THORO AFTER HNDLG.IRRIT. HARMFUL SOLID.HARMFUL BY INHAL, IN CONT W/SKIN & IF SWALLOWED. IRRIT TO EYES, RESP SYS & SKIN.IN CASE OF CONT W/EYES, RINSE IMMED W/PLENTY OF WATER & S EEK MED ADVICE. WEAR SUITABLE (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. WEAR SUITABLE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health OTHER PRECAUTIONS: PROTECTIVE CLOTHING. MATERIALS TO AVOID: SHAKEN. INDIUM-CATALYZED OXIDATION OF ACETONITRILE IS SUSPECTED CAUSE. INDIUM REACTS VIGOROUSLY W/MERCURY (II) BROMIDE AT 350C. A MIXTURE OFINDIUM AND SULFUR IGNITE UPON HEATING RESULTING IN INCANDESCENCE. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:7.3 Appearance and Odor:SILVER WIRE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, SULFUR, STRONG ACIDS.MIX OF ACETONITRILE, DINITROGEN TETRAOXIDE & INDIUM EXPLO WHEN (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL IN ELEMENTAL STATE SHOULD BE RECOVERED FOR REUSE OR RECYCLING. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:PC-31-625C BATTERY ELECTRICAL STORAGE, WET CAGE:OMM77 CAGE:0FGN2 CAGE:0K4U5 CAGE:88219 CAGE:OMM77 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA III) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 27% OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ELECTROLYTE- ACUTE: BURNS, SEVERE IRRITATION OF SKIN & EYES, MOUTH, THROAT, ESOPHAGUS AND STOMACH; INFLAMMATION OF BRONCHIAL MEMBRANES. CHRONIC: EROSION OF TEETH, INFLAMMATION OF NOSE, THROAT AND BRON CHIAL TUBES. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALED: COUGHING, WHEEZING, SHORTNESS OF BREATH. SKIN: BURNING SENSATION, BURNS, REDNESS, BLISTERS, PAIN. EYES: PAIN, REDNESS, BLURRED VISION, TEARING. INGESTED: BURNS OF MOUTH AND THROAT, SEVERE STO MACH PAIN, NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:EXPOSURE TO MISTS MAY CAUSE LUNG DAMAGE AND AGGRAVATE PULMONARY CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE TO FRESH AIR. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHES. FLUSH WITH LOTS OF WATER FOR 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. Unusual Fire/Explosion Hazard:ELECTROLYTE REACTS VIOLENTLY WITH WATER AND ORGANIC MATERIALS WITH EVOLUTION OF HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT. DILUTE CAUTIOUSLY WITH WATER. COVER WITH SODA ASH OR QUICKLIME. SCOOP UP AND PLACE IN APPROPIATE DISPOSAL CONTAINER. Neutralizing Agent:SODA ASH (SODIUM CARBONATE) OR QUICKLIME (CALCIUM OXIDE). ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES AND COMBUSTIBLE MATERIALS.AVOID CONTACT WITH ORGANIC MATERIALS. Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE.AVOID SHORTING BATTERIES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. NIOSH/MSHA-APPROVED CARTRIDGE RESPIRATOR FOR ACIDS OR FULL FACE MASK AS APPROPIATE FOR EXPOSURE OF CONCERN WHEN TLV IS EXCEEDED. Ventilation:GENERAL (MECHANICAL) VENTILATION. LOCAL EXHAUST IN CONFINED AREAS. Other Protective Equipment:RUBBER APRON AND BOOTS.EYES WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health THIS MSDS IS FOR ACID IN BATTERY.ADDITIONAL HAZARDS ASSOCIATED WITH THE LEAD CONTAINED IN THE BATTERY PLATES MAY BE PRESENT AT TIME OF DISPOSAL. ================== Physical/Chemical Properties ================== HCC:C1 Appearance and Odor:BATTERY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLES, ORGANIC MATERIALS, STRONG REDUCING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES. OVERCHARGING. Hazardous Decomposition Products:SULFURIC ACID FUMES, SULFUR DIOXIDE, SULFUR TRIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL ENVIRONMENTAL REGUALTIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:WATER BASED CATALYZED EPOXY, B60V15 HARDENER CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL MONOPROPYL ETHER; (2-PROPOXYETHANOL). VP: 1.3 CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: 8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EPOXY POLYMER Fraction by Wt: 43% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS (VOC-LBS/GAL): 0.67 RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS LESS WATER (LB/GAL): 1.40. (% WATER: 49.0) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VENT: REFER TO OSHA STANDARDS 1910.94. 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:OTHER PREC: EYES/ON SKIN. THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: IN SECTION 2) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: SPECIFIC DUSTS ARE LISTED IN SECTION 2, APPLICALBE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: (TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION). CALIFORNIA PROPOSITION 65: (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: WARNING: THESE PRODUCTS CONTAIN A CHEMICAL(S) KNOWN TO THE STATE FO CALIFORNIA TO CAUSE CANCER. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN & UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. SIGNS & SYMPS OF OVEREXP: REDNESS & ITCHING OR BURN ING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENTS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: INGREDIENTS IN SECTION 2 MAY CAUSE ADVERSE EFTS TO LIVER, URINARY SYSTEMS. ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DETECTS IN RATS AND MICE AT HIG H DOSES WHEN GIVEN IN DRINKING WATER ORBY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE PERSONS. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Lower Limits:0.9% Upper Limits:15.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD CNTNRS TO(SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO THE BUILD-UP OF PRESSURE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT TO USE. TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE LABELING. DO NOT TAKE INTERNALLY. Other Precautions:KEEP OUT OF REACH OF CHILDREN. THESE PRODUCTS MUST BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS. USE ONLY W/ADEQ VENT. AVOID BRTHG VA P/SPRAY MIST. DO NOT GET IN (ING 6) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING/WELDING DRIED FILM, (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN SECTION 2 IS MAINTAINED BELOW APPLICABLE EXPOS LIMS. (ING 5) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . BARRIER CREAM. Work Hygienic Practices:WASH HANDS AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOSION WHEN EXPOS TO EXTREME HEAT. WASTE DISP METH: INCIN AN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSED OF I/A/W/FED, STATE, & LOCAL REG S REGARDING POLLUTION. RESP PROT:WEAR PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST NON-VOLATILE MATLS IN SECTION 2. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.06 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:57-65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM B70W100 PRIMER MAY BE HAZARDOUS AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR BARIUM EXTRACTABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM OTHER LISTED PRODS IS NOT HAZ AS DEFINED UNDER RCRA 40 CPR 261. (SUPDAT)
1
gloves_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & STEEL OVERALL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
gloves_mandatory
===================== Product Identification ===================== Product ID:B67DQ1000, ANTI-SKID, ARMOR SEAL 1000 HEAVY DUTY (SUPDAT) CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WASTE DISP METH: FEDERAL, STATE & LOCAL REGULATIONS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PRECS: DO NOT SMOKE - EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF STOVES, ELEC TOOLS & (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: APPLIANCES & ANY OTHER SOURCES OF IGNITION. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCEDURES. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: KEEP CNTNR CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: USE ONLY W/ADEQ VENTILATION. AVOID BRTHG VAPOR & SPRAY MIST. DO NOT PERMIT CONTACT W/SKIN & EYES. (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: WASH HANDS AFTER USING. THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: DUST" IN INGRED SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING OR ABRADING OF THE DRIED (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: FILM. IF NO SPECIFIC DUSTS ARE LISTED, THE APPLICABLE LIMITS FOR NUISANCE DUST ARE ACGIH TLV 10 MG/M3 (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT: ABRADING, BURNING OR WELDING DRIED FILM, WEAR A PARTICULATE RESP APPRVD BY NIOSH FOR PROTECTION (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: AGAINST NON-VOLATILE MATLS LISTED IN INGRED SECTION. RTECS #:9999999ZZ Ingred Name:VENT: MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS TO VAP/SPRAY MISTS. REDN ESS & ITCH OR BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC: PRLNGD OVEREXP TO SOLVS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: LISTED IN INGRED SECTION MAY CAUSE ADVERSE EFTS TO LIVER, URINARY & REPRO SYS. RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS SYS DMG. Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC SKIN REACTION IN SUSCEPTIBLE PERSONS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Lower Limits:0.7% Upper Limits:7.0% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREFERABLE. WATER MAY BE USED TO COOL CLSD (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & OPEN FLAME. VAPS WILL ACCUMULATE & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL VAPS ARE GONE: KEEP AREA VENTILATED - (ING 3) Other Precautions:THESE PRODS MUST BE MIXED WELL W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING THE PACKAGES, READ & FOLLOW WARNING LABELS ON ALL COMPONENTS. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING C ONTENTS CAN BE HARMFUL/FATAL. (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINST MATLS LISTED IN INGRED SECTION. WHEN SANDING, WIREBRUSHING, (ING 12) Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE EXPOS TO MATLS LISTED IN INGRED SECTION IS (ING 14) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE OF BARRIER CREAM ON EXPOSED SKIN IS RECOMMENDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: MARINE & INDUSTRIAL COATING. FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQS SPECIAL PRECS. DURING E MER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HEALTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>237F,>114C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.90 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF METALS LISTED IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODUCTS MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZ WASTE NUMBER. INCINERATE IN APPRVD FACILITY. DO NOT INC INERATE CLOSED CNTNR. DISPOSE OF I/A/W (ING 2)
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM CARBONATE ANHYDROUS CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE ANHYDROUS (SYNONYMS: CARBONIC ACID, DISODIUM SALT; DISODIUM CARBONATE) CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: DUST MAY CAUSE IRRIT TO RESP TRACT. SYMP MAY INCL COUGHING & LABORED BRTHING. EXCESSIVE CONT IS KNOWN TO CAUSE DAMAGE TO NASAL SEPTUM. INGEST: ONLY SLIGHTLY TOXIC, BUT LGE DOSES MAY BE CORR TO GI TRACT WHERE SYMPTOMS MAY INCL SEV ABDOM PAIN, VOMIT, DIARR, AND COLLAPSE. (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SKIN: EXCESSIVE CONT MAY CAUSE IRRIT W/BLISTERING AND REDNESS. SOLNS MAY CAUSE SEV IRRIT OR BURNS. EYE: CONT MAY BE CORR TO EYES AND CAUSE CONJ EDEMA AND CORNEAL DESTRUCT. CHRONIC: PROLONGEDOR REPEATED SKIN EXPOSURE MAY CAUSE SENSITIZATION. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.IF BRTHING DFCLT, GET MD ATTN.INGEST:DO NOT INDUCE VOMIT.GIVE LGE QTYS OF H2O/MILK IF AVAIL. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON.GET MD ATTN IMMED.SKIN:REMOVE ANY CO NTAM CLTHG.WASH SKIN W/SOAP/MILD DETERGENT&H2O FOR AT LEAST 15 MIN. GET MD ATTN IF IRRIT DEVELOPS/PERSISTS.EYE:WASH W/PLENTY OF H2O AT LEAST 15 MIN,LIFTING UPPER&LOWER EYELIDS OCCASNLY.GET MD IMMED ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE PROTECTIVE CLOTHING AND NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT APPROPRIATE FOR THE SURROUNDING FIRE Unusual Fire/Explosion Hazard:NOT CONSIDERED AN EXPLOSION OR FIRE HAZAR BUT EXPLOSION MAY OCCUR WHEN APPLIED TO RED-HOT ALUMINUM. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROT AGAINST SKIN CONT/INHAL OF DUST/ MIST. SCOOP UP SOLID&PLACE IN SEALABLE CNTNRS FOR RECOVERY/DISP.FLUSH RESIDUES&LIQ SPILLS TO HOLDING AREA FOR NEUT(E.G.,W/DILUTE HCL)BEFORE DISCHARGE. (SEE SU PP DATA) Neutralizing Agent:SEE ABOVE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CNTNR, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. Other Precautions:DO NOT GET IN EYES, SKIN, OR ON CLTHG. AVOID BRTHING DUST. KEEP CNTNR CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONDTNS WHERE EXPOS TO DUST IS APPARENT, WEAR NIOSH/MSHA APPROVED DUST/MIST RESP. FOR EMER, A NIOSH/MSHA APPROVED SCBA MAY BE NEC. Ventilation:A LOCAL EXHST SYS WHICH CAPTURES THE CONTAM AT ITS SOURCE IS RECOM TO PVNT DISPERSION OF CONTAM INTO THE WORKROOM AIR. Other Protective Equipment:MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA. WEAR CLEAN BODY-COVERING CLOTHING. Work Hygienic Practices:CNTCT LENSES SHOULD NOT BE WORN WHEN WORKING W/ THIS MATL. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATL TO AVOID:REACTS VIOLENTLY W/ACIDS TO FORM CARBON DIOXIDE. SPILL PROC:RECLAIM&REUSE AS MUCH AS POSS.SEND REMAINDER TO APPRVD WASTE DISP FACILITY.ALTERNATIVELY,IF LOCAL ORDINANCES ALLOW NEUT WASTES CAN USUALLY BE FLUSHED TO DRAIN W/MUCHEXCESS WATER. ENSURE COMPLIANCE W/LOCAL,STATE&FED REGS. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:851C(1564F) Spec Gravity:2.53 Solubility in Water:45.5G/100MLH20@100C Appearance and Odor:ODORLESS, WHITE POWDER OR GRANULES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PHOSPHOROUS PENTOXIDE, SULFURIC ACID,ZINC,LITHIUM, MOISTUR CALCIUM HYDROXIDE&2,4,6-TRINITROTOLUENE.(SEE SUPP DATA) Stability Condition to Avoid:APPLICATION TO RED-HOT ALUMINUM. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:TT-L-32A, CLEAR GLOSS LACQUER, #700C04 Preparer's Name:ROBERT COMMISSO CAGE:DO312 CAGE:58963 CAGE:DO312 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) (VP = 70 @ 68F) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CELLULOSE NITRATE CAS:9004-00-0 Fraction by Wt: <5.0% Other REC Limits:NONE RECOMMENDED Ingred Name:ISOPROPYL ALCOHOL (SARA 313) (VP = 90 @ 68F) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:500 PPM Ingred Name:ALIPHATIC PETROLEUM DISTILLATES (SARA 313) (VP = 15 @ 100F) CAS:64742-89-8 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYLPHTHALATE) (SARA 313) (CERCLA) (VP = 1.2 @ 200F) CAS:117-81-7 RTECS #:TI0350000 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:XYLENES (SARA 313) (VP = 5.1 @ 68F) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 8.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AROMATIC PETROLEUM DISTILLATES (VP = 10 @ 68F) CAS:64742-95-6 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:300 PPM Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) (VP = 5.9 @ 68F) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 2.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) (VP = 4.3 @ 68F) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ACETATE (CERCLA) (VP = 8.0 @ 68F) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 2.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC = 4.84 LB/GL RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: DROWSINESS, DIZZINESS, FATIGUE, COMA, LUNG CHANGES, NAUSEA, VOMITING, COUGH, PULMONARY IRRITATION, CNS DEPRESSION. EYE: IRRITATION. SKIN: IRRITATION &/OR DERMITITIS, ABSORPTION (IRRITATION, DEF ATTING & DERMITITIS). INGEST: PNEUMONITIS, PULMONARY EDEMA, HEMORRAGE, GI DISTURBANCE. Medical Cond Aggravated by Exposure:DISEASES OF SKIN, CENTRAL NERVOUS SYSTEM, LIVER AND KIDNEYS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS WATER FOR 15 MINUTES. SEEK MED AID. SKIN: WASH THOROUGHLY W/SOAP & WATER. SEEK MED AID. INGEST: IMMEDIATELY SEEK MED AID. DONT INDUCE VOMITING. DONT GIVE ANYTHI NG BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:24.0F,-4.4C Autoignition Temp:Autoignition Temp Text:474F Lower Limits:0.3 Upper Limits:NA Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:APPROVED GAS MASK REQUIRED FOR FIRE FIGHTING PERSONNEL. WATER MAY BE INEFFECTIVE, MAY BE USED TO COOL CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM IGNITION SOUCES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. REMOVE ALL SOURCES OF IGNITION. STAY UPWIND. ABSORB WITH INERT MATERIAL. FLUSH AREA W/WATER. VENTILATE AREA FOR AT LEAST 24 HOURS OR UNTIL AREA HAS BEEN DECLARED SAFE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED & UPRIGHT TO PREVENT LEAKAGE. AVOID IGNITION SOURCES. Other Precautions:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN CONFINED AREAS, TANKS OR PITS WITHOUT ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE MSHA/NIOSH APPROVED UNITS. USE UNITS PER CURRENT 29 CFR 1910.134 REGULATIONS & FOLLOW MANUFACTURERS' INSTRUCTIONS & WARNINGS. AIR PURIFYING OV/FILTER UNITS MAY BE ACCEPTABLE. Ventilation:LOCAL AND MECHANICAL EXHAUST. Other Protective Equipment:EYE BATH AND SAFETY SHOWER. Work Hygienic Practices:MAINTAIN GOOD PERSON HYGIENE. DO NOT USE IN CONFINED AREAS WITHOUT ADEQUATE VENTILATION. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:147 TO 724F Decomp Temp:Decomp Text:NA Vapor Density:>AIR Spec Gravity:0.9 pH:NA Viscosity:20 #4 FC Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:ESSENTIALLY NIL Appearance and Odor:VISCOUS LIQUID WITH STRONG SOLVENT ODOR Percent Volatiles by Volume:68.48 Corrosion Rate:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:IGNITION SOURCES. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE INERT ABSORBENT MATERIAL ON SPILLS. DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:RUBBERIZER BOOMS, PILLOWS, PARTICULATE Preparer's Name:PHILLIP W. STAGG CAGE:0GFG5 CAGE:0GFG5 ============= Composition/Information on Ingredients ============= Ingred Name:THE MANUFACTURER STATES THAT NO HAZARDOUS INGREDIENTS ARE PRESENT IN THIS PRODUCT. Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EXPOSURE MAY CAUSE EYE, SKIN & RESPIRATORY TRACT IRRITATION. CHRONIC: NONE STATED. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED: COUGHING, SNEEZING, WHEEZING, SHORTNESS OF BREATH. EYES: REDNESS, TEARING, DISCOMFORT. SKIN: REDNESS, DISCOMFORT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE TO FRESH AIR. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES, HOLD LIDS OPEN. SEE DOCTOR IF SYMPTOMS PERSIST. SKIN: REMOVE CONTAMINATED CLOTHES. WASH WITH SOAP AND WATER. INGESTED: NONE STATED. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:325F,163C Extinguishing Media:CARBON DIOXIDE, LOW PRESSURE WATER, OR DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. USE LOW PRESSURE WATER; HIGH PRESSURE MAY CAUSE DUST TO BECOME AIRBORN-CAUSING A DUST EXPLOSION. Unusual Fire/Explosion Hazard:DUST AND AIR MIXTURES MAY BE EXPLOSIVE IN THE PRESENCE OF SPRAKS OR ANY IGNITION SOURCE. SIMILAR AHZARD AS FOUND WITH ORGANIC DUST/AIR MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN A CONTAINER FOR LATER DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM SOURCES OF IGNITION AND STRONG OXIDIZING AGENTS. STORE UNDER 125F. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR WITH DUST CARTRIDGE OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.134. Ventilation:SUFFICIENT LOCAL EXHAUST TO AMINTAIN EXPOSURE BELOW REGULATORY LIMITS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.89 (WATER=1) Evaporation Rate & Reference:N/K (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE GRAINY MATERIAL; MILD, SWEET ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:IGNITION SOURCES, EXCESSIVE HEAT, CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ======================================================================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:5318/5320/5322/5622 BLACK DRY INK, 502S63520 CAGE:0E6G9 CAGE:0E6G9 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC ACID BUTYL ESTER POLYMER WITH STYRENE; (STYRENE/ACRYLATE POLYMER) CAS:25767-47-9 Fraction by Wt: 45-50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IRON OXIDE CAS:1309-38-2 RTECS #:OM4800000 Fraction by Wt: 45-50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYPROPYLENE CAS:9003-07-0 RTECS #:TR5000000 Fraction by Wt: 1-4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:QUATERNARY AMMONIUM SALT CAS:102561-46-6 Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POLYETHYLENE CAS:9002-88-4 RTECS #:TQ3325000 Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:STATIC BUILDUP. RESIDUE CAN BE REMOVED WITH SOAP AND COLD WATER. GARMENTS MAY BE WASHED OR DRY CLEANED, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:AFTER REMOVAL OF LOOSE TONOR. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:(SUCH AS IN BULK TONER PROCESSING XEROX. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): >5 G/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST. ADDITIONAL INFO:RESULTS OBTAINED FROM A XEROX SPONSORED, CHRONIC TONER INHAL STUDY, DEMONSTRATED NO LUNG CHANGE IN RATS FOR LOWEST (1MG/M3) EXPOS LEVEL (I.E. LEVEL MOST RELEVANT TO POTENTIAL HUMAN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:EXPOS). A VERY SLIGHT DEGREE OF FIBROSIS WAS NOTED IN 25% OF ANIMALS AT MIDDLE (4MG/M3) EXPOS LEVEL, WHILE A SLIGHT DEGREE OF FIBROSIS WAS NOTED IN ALL ANIMALS AT HIGHEST (16MG/M3) EXPOS LEVE L. THESE FINDINGS ARE ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC RESPONSE TO EXCESSIVE AMTS OF ANY DUST (SUPDAT) Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH SKIN THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. OBSERVE FOR ANY DIFFICULTY IN BREATHING. INGESTION: DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, DRY CHEMICAL, CARBON DIOXIDE OR FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID INHALATION OF SMOKE. Unusual Fire/Explosion Hazard:TONER IS COMBUSTIBLE POWDER. LIKE MOST ORGANIC MATERIALS IN POWDER FORM, WHEN DISPERSED IN AIR, IT CAN FORM EXPLOSIVE MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY TRANSFER INTO A SEALABLE WASTE CNTNR. SWEEP SLOWLY TO MINIMIZE GENERATION OF DUST DURING CLEAN-UP. IF A VACUUM IS USED, MOTOR MUST BE RATED AS DUST TIGHT. A C ONDUCTIVE HOSE BONDED TO MACHINE SHOULD(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . FOR USE OTHER THAN NORMAL CUSTOMER-OPERATING PROCEDURES (ING 8) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP:RETAINED IN THE LUNGS FOR A PRLNGD PERIOD. THIS STUDY WAS CONDUCTED USING A SPECIAL TEST TONER TO COMPLY W/EPA TESTING PROTOCOL. TEST TONER WAS TEN TIMES MORE RESPIRABLE THAN COMMERCIA LLY AVAIL XEROX TONER, & WOULD NOT BE FUNCTIONALLY SUITABLE FOR XEROX EQUIP. SPILL PROC:BE USED TO REDUCE (ING 6) ================== Physical/Chemical Properties ================== Spec Gravity:3 (H*2O =1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER/FAINT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC. AVOID BREATHING SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISPOSED, THIS MATL IS NOT A HAZ WASTE ACCORDING TO FED REG 40 CFR 261. STATE & LOCAL REQUIREMENTS HOWEVER, MAY BE MORE RESTRICTIVE. CONSULT W/APPROPRIATE STATE & LOCAL WASTE DISP AUTHORITIES FOR FUTHER INFO. INCINERATE ONLY IN A CLOSED CNTNR.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SILICON TETRAFLUORIDE Kit Part:=== Responsible Party === 780-471-4036 780-471-4036 CAGE:Company Name:MATHESON TRI-GAS, INC. 780-471-4036 CAGE: ============= Composition/Information on Ingredients ============= Ingred Name:SILICON TETRAFLUORIDE CAS:7783-61-1 Fraction by Wt: 100.0% ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:No IARC:NoOSHA:No Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure SKIN CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure EYE CONTACT: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure INGESTION: SHORT TERM EXPOSURE: burns LONG TERM EXPOSURE: same as effects reported in short term exposure Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid: INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention. SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get immediate medical attention. Thoroughly clean and dry contaminated clothing and shoes before reuse. Destroy contaminated shoes. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. INGESTION: If swallowed, drink plenty of water, do NOT induce vomiting. Get immediate medical attention. NOTE TO PHYSICIAN: For inhalation, consider oxygen. For skin contact, consider ice water bath, iced alcohol, iced magnesium sulfate, magnesium oxide/glycerin gels, calcium gluconate gel or benzalkonium chloride solution. Avoid gastric lavage or emesis. ===================== Fire Fighting Measures ===================== Flash Point:not flammable Extinguishing Media:carbon dioxide, regular dry chemical Large fires: Use regular foam or flood with fine water spray. Fire Fighting Procedures:Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. Use extinguishing agents appropriate for surrounding fire. Flood with fine water spray. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Unusual Fire/Explosion Hazard:Negligible fire hazard. Pressurized containers may rupture or explode if exposed to sufficient heat. ================== Accidental Release Measures ================== Spill Release Procedures:Do not touch spilled material. Stop leak if possible without personal risk. Reduce vapors with water spray. Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Large spills: Dike for later disposal. Keep unnecessary people away, isolate hazard area and deny entry. Neutralizing Agent: ======================Handling and Storage ====================== Handling and Storage Precautions:Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Store below 52 C. Store in a cool, dry place. Store in a well-ventilated area. Keep separated from incompatible substances. Other Precautions: ============= Exposure Controls/Personal Protection ============= Respiratory Protection:The following respirators and maximum use concentrations are drawn from NIOSH and/or OSHA. Measurement Element: F 12.5 mg/m3 Any dust and mist respirator. 25 mg/m3 Any dust and mist respirator. Any supplied-air respirator. 62.5 mg/m3 Any supplied-air respirator. Any powered, air-purifying respirator with a dust and mist filter. May need acid gas sorbent. 125 mg/m3 Any air-purifying respirator with a full facepiece and a high-efficiency particulate filter. May need acid gas sorbent. Any self-contained breathing apparatus with a full facepiece. Any supplied-air respirator with a full facepiece. 250 mg/m3 Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. Escape - Any air-purifying respirator with a full facepiece and a high-efficiency particulate filter. May need acid gas sorbent. Any appropriate escape-type, self-contained breathing apparatus. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full facepiece. Ventilation:Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Other Protective Equipment:Wear appropriate chemical resistant clothing. Supplemental Safety and Health SILICON TETRAFLUORIDE: 2.5 mg(F)/m3 OSHA TWA 2.5 mg(F)/m3 ACGIH TWA 2.5 mg(F)/m3 NIOSH recommended TWA 10 hour(s) ================== Physical/Chemical Properties ================== Boiling Pt:-123 F (-86 C) Melt/Freeze Pt:-130 F (-90 C) Vapor Pres:Not available Vapor Density:3.63 Spec Gravity:1.7 @ -95 C pH:acidic in solution Evaporation Rate & Reference:Not applicable Solubility in Water:decomposes Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:irritating odor, pungent odor Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:Reacts violently with water, releasing toxic gases. Releases corrosive gases. Stability Condition to Avoid:Avoid heat, flames, sparks and other sources of ignition. May ignite or explode on contact with combustible materials. Hazardous Decomposition Products:Thermal decomposition products or contact with water or moisture: acids, hydrogen fluoride Thermal decomposition products or contact with water or moisture: acids, hydrogen fluoride Conditions to Avoid Polymerization:Will not polymerize. =================== Toxicological Information=================== Toxicological Information:SILICON TETRAFLUORIDE: TOXICITY DATA: 2272 ppm inhalation-rat LC50 LOCAL EFFECTS: Corrosive: inhalation, skin, eye, ingestion ACUTE TOXICITY LEVEL: Moderately Toxic: inhalation MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: central nervous system disorders, bone, joint or tooth disorders, eye disorders, kidney disorders, respiratory disorders, skin disorders and allergies ADDITIONAL DATA: May cross the placenta. May be excreted in breast milk. ===================== Ecological Information ===================== Ecological:Not available ==================== Disposal Considerations ==================== Waste Disposal Methods:Dispose in accordance with all applicable regulations. =================== MSDS Transport Information =================== Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME: Silicon tetrafluoride, compressed ID NUMBER: UN1859 HAZARD CLASS OR DIVISION: 2.3 LABELING REQUIREMENTS: Poison gas; Corrosive QUANTITY LIMITATIONS: PASSENGER AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: Forbidden ===================== Regulatory Information ===================== SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated.SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: Yes FIRE: No REACTIVE: Yes SUDDEN RELEASE: YesSARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated. Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY (29CFR1910.119): Not regulated. State Regulatory Information: California Proposition 65: Not regulated. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:REPEL LOTION 20 IPF INSECT BLOCK,15 SPF SUNBLOCK,1200 Preparer's Name:JEAN KILLOREN CAGE:7R059 CAGE:7R059 ============= Composition/Information on Ingredients ============= Ingred Name:N,N-DIETHYL-META-TOLUAMIDE CAS:134-62-3 RTECS #:XS3675000 Fraction by Wt: 20% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, GASTROINTESTINAL TRACT. ACUTE- CAN CAUSE EYE IRRITATION. VERY SLIGHTLY TOXIC BY ABSORPTION THROUGH SKIN. NON-IRRITATING ON SKIN CONTACT. INHALATION UNLIKELY. CAN CAUSE IRRITAT ION OF MUCOUS MEMBRANE BY INGESTION. ORAL TOXICITY IS VERY LOW. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:IF CONSCIOUS, DRINK PLENTY OF WATER. GE T MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT. RECOVER BY ABSORPTION ON DIATOMACEOUS EARTH. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. Work Hygienic Practices:GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL. Supplemental Safety and Health EPA REGISTRATION NUMBER: 305-43 ================== Physical/Chemical Properties ================== HCC:T6 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F,100C Spec Gravity:APPROXIMATELY 1 Solubility in Water:DISPERSIBLE Appearance and Odor:MEDIUM VISCOSITY EMULSION - CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, HALOGENS & ALDEHYDES, STRONG ACIDS & BASES Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. AVOID CONTAMINATING ENVIRONMENT.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:F034ND BLACK TONER CAGE:18520 CAGE:18520 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: > 9.0% % Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:STYRENE ACRYLATE COPOLYMER Fraction by Wt: > 88% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYPROPYLENE Fraction by Wt: > 3.0% Other REC Limits:NONE RECOMMENDED Ingred Name:ORGANIC PIGMENT CAS:31714-55-3 Fraction by Wt: < 2.0% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED FOR PRODUCT Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE EYE IRRITAION OR CORNEAL INJURY DUE TO MECHANICAL ACTION. ESSENTIALLY NONIRRITATING TO SKIN. MINIMAL IRRITATION TO RESPIRATORY TRACT MAY OCCUR. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE IRRITATION, CORNEAL INJURY, RESPIRATORY TRACT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE, DRY CHEMICAL Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. Unusual Fire/Explosion Hazard:NONE UNDER NORMAL CONDITIONS OF STORAGE AND USE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP OR CLEAN UP WITH A VACUUM CLEANER. AVOID CREATING AIRBORNE DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:INHALATION AND CONTACT WITH SKIN OR EYES SHOULD BE AVOIDED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. IN DUSTY AREAS, AN APPROVED RESPIRATOR SHOULD BE USED. Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO MAINTAIN EXPOSURE LEVELS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:1.1 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NEGLIGIBLE Appearance and Odor:FINE BLACK POWDER, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:USA 6012 Resp. Party Other MSDS Num.:CODED ELECTRODES CAGE:JO533 Contract Num:SP0490-01-M-XL97 CAGE:0A4S7 CAGE:JO533 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 OSHA PEL:5 MG/M3 ACGIH TLV:NOT REPORTED Ingred Name:MANGANESE CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:5 MG/M3 ACGIH TLV:1 MG/M3 (FUME) Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SODIUM SILICATES. CAS# 1344-09-9. OSHA PEL:NOTHING FOUND ACGIH TLV:NOTHING FOUND Ingred Name:MAGNESIUM CAS:546-93-0 RTECS #:OM2470000 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:CELLULOSE AND OTHER CARBOHYDRATES CAS:65996-61-4 OSHA PEL:NOTHING FOUND ACGIH TLV:NOTHING FOUND Ingred Name:MINERAL SILICATES. CAS# 1332-68-7. OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ALUMINUM AND ALUMINUM ALLOYS CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:NOTHING FOUND ACGIH TLV:10 MG/M3 Ingred Name:CALCIUM CARBONATES CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:NOTHING FOUND ACGIH TLV:10 MG/M3 Ingred Name:ZINC OXIDES CAS:1314-13-2 RTECS #:ZH4810000 OSHA PEL:NOTHING FOUND ACGIH TLV:3 MG/M3 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:NOTHING FOUND ACGIH TLV:10 MG/M3 Ingred Name:ALUMINUM OXIDE CAS:1344-28-1 RTECS #:BD1200000 OSHA PEL:5 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:QUARTZ CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:0.1 MG/M3 RESPIRABLE ACGIH TLV:0.1 MG/M3 Ingred Name:GRAPHITE CAS:7732-42-5 RTECS #:DB4800000 OSHA PEL:NOTHING FOUND ACGIH TLV:5 MG/M3 Ingred Name:FLOURSPAR CAS:7789-75-5 RTECS #:EW1760000 OSHA PEL:2.5 MG/M3 AS F ACGIH TLV:2.5 MG/M3 AS F Ingred Name:POTASSIUM SILICATE CAS:1312-76-1 OSHA PEL:NOTHING FOUND ACGIH TLV:NOTHING FOUND Ingred Name:ALKALI AND METALLIC CARBONATES. CAS# 581-08-7. OSHA PEL:NOTHING FOUND ACGIH TLV:10 MG/M3 Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:LONGTERM CHRONIC OVEREXPOSURE CAN LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNGS) AND IS BELIEVED TO AFFECT PULMONARY FUNCTION. REPEATED EXPOSURE MAY CAUSE EXCESSIVE CALCIFICATION OF BONES AND LIGAMENTS OF RIBS, PELVIS AND SPINAL COLUMN. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. Explanation of Carcinogenicity:THESE PRODUCTS DO NOT CONTAIN INGREDIENTS THAT ARE DEFINED AS CARCINOGENIC PER 29CFR 1910.1200. Effects of Overexposure:INHALATION OF WELDING FUMES & GASES MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA, DRYNESS OR IRRITATION OF NOSE, THROAT OR EYES. INHALATION OF EXTREMELY HIGH LEVELS OF FLUORIDES MAY CAUSE ABDOMI NAL PAIN, DIARRHEA, MUSCULAR WEAKNESS & CONVULSIONS. CONTINUED INHALATION COULD CAUSE LOSS OF CONSCIOUSNESS & DEATH. LONGTERM CHRONIC OVEREXPOSURE CAN LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNGS) & IS B ELIEVED TO AFFECT PULMONARY FUNCTION. REPEATED EXPOSURE MAY CAUSE EXCESSIVE CALCIFICATION OF BONES & LIGAMENTS OF RIBS, PELVIS & SPINAL COLUMN. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL ASSISTANCE. USE FIRST AID AND PROCEDURES RECOMMENDED BY THE AMERICAN RED CROSS. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, USE CPR (CARDIOPULMONARY RESUSCITATION). ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Fire Fighting Procedures:N/PWELDING ARC AND SPARKS CAN IGNITE COMBUSTIBLES. SEE Z49.1 . ======================Handling and Storage ====================== Other Precautions:READ & UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS & PRECAUTIONARY LABEL ON THIS PRODUCT. SEE AMERICAN STANDARD Z49.1 SAFETY IN WELDING & CUTTING PUBLISHED BY THE AMERICAN WELDING SOCIETY, 550 N.W. LEJ EONE ROAD, MIAMI, FL. 33126 & OSHA PUBLICATION 2206 (29 CFR 1910) US GOVERNMENT PRINTING OFFICE, WAS HINGTON D.C. 20402 . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN A CONFINED SPACE OR GENERAL WORK AREA WHERE LOCAL EXHAUST AND/OR VENTILATION DOES NOT KEEP EXPOSURE BELOWE THRESHOLD VALUE. Ventilation:USE PLENTY OF VENTILATION AND/OR LOCAL EXHAUST AT THE ARC, TO KEEP FUMES AND GASES BELOW THRESHOLD VALUE. Other Protective Equipment:WEAR APPROVED HEAD, HAND AND BODY PROTECTION WHICH HELP PREVENT INJURY FROM RADIATION, SPARKS AND ELECTRICAL SHOCK. ARM PROTECTORS, APRON, HATS, SHOULDER PROTECTION AS WELL AS DARK SUBSTANTIAL CLOTHING. Work Hygienic Practices:THE WELDERS SHOULD INSULATE THEMSELVES FROM THE WORK AND GROUND. Supplemental Safety and Health VENTILATION: USE PLENTY OF VENTILATION AND/OR LOCAL EXHAUST AT THE ARC, TO KEEP FUMES AND GASES BELOW THRESHOLD VALUE WITHIN THE WORKERS BREATHING ZONE & THE GENERAL WORK AREA. WELDERS SHOULD BE ADVIS ED TO KEEP THEIR HEAD OUT OF THE FUMES. EYE: SHIELD OTHER WORKERS BY ================== Physical/Chemical Properties ================== HCC:N1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:REASONABLE EXPECTED FUME CONSTITUENTS OF THIS PRODUCT WOULD INCLUDE OXIDES OF IRON, MANGANESE, SILICON, TITANIUM, MAGNESIUM, CALCIUM, POTASSIUM, ZINC, SODIUM & ALUMINUM. FLUORIDES WILL ALSO BE PRESENT. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER APPROVED BY FEDERAL, STATE AND LOCAL REGULATIONS. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:N THINNER, 8000092 CAGE:DO804 CAGE:DO804 CAGE:38360 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL ETHER). SPEC GRAV:0.954. VP:0.02. EVAP RATE:<0.01 (N-BUAC=1). CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 60-100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:DILUTION. NOTIFY AUTHS IF LIQ ENTERS SEWERS/OTHER PUBLIC WATERS. WATER MAY NOT BE EFTIVE TO EXTING FIRE. (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS & TO PROTECT PERSONNEL. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:CONTACTED IMMED & BE PROVIDED W/THIS MSDS. RECENT INFO SUGGEST THAT RISK ASSOC W/INDUCING VOMIT (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:EXCEEDS POIS RISK OF SUBSTANCE, ESP FOR SM QTYS LIKELY TO BE INGESTED UNDER NORMAL INDUS USE. GET MED ATTN (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:IMMED. DRINK 2 GLASSES OF WATER. CONT POIS INFO SERVICE. STOM EVACUATION MAY BE APPROP, AS REC BY MED (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:PROFESSIONALS, ONLY IF SIGNIFICANT QTY OF MATLS HAS BEEN INGESTED. STOM EVACUATION SHOULD ONLY BE CARRIED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OUT BE TRAINED & PROPERLY EQUIPPED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:FOR DEALING W/SPILL OF ANY SIZE. PPE NEEDS MUST BE EVALUATED BASED ON INFO PROVIDED ON THIS MSDS & (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:SPECIAL CIRCUMSTANCES CREATED BY SPILL INCL; MATL SPILLED, QTY, AREA IN WHICH IT OCCURRED; & EXPERTISE OF (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:EMPLOYEES IN AREA RESPONDING TO SPILL. NEVER EXCEED ANY OCCUP EXPOS LIMS & CONSIDER THAT EVAP OF VOLAT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:SOLVENTS CAN LEAD TO DISPLACEMENT OF AIR CREATING AN ENVIRONMENT THAT CAN CAUSE ASPHYXIATION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 5,660 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE CONTACT:CAN CAUSE SEVERE IRRITATION, TEARING AND REDDENING, BUT NOT LIKELY TO PERMANENTLY INJURE TISSUE. TEMPORARY VISION IMPAIRMENT (CLOUDY OR BLURRED VISION) IS POSSIBLE. SKIN CONTACT:CAN CAUSE MINOR IRRITATION, DEFATTING AND DERMATITIS. SKIN ABSORPTION:TOXIC IF ABSORBED THROUGH SKIN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CAUSING SYSTEMIC DAMAGE. INHAL:CAN CAUSE RESP IRRIT, DIZZ, WEAK, FATIGUE, NAUSEA, HDCH & POSSIBLE UNCON. INGEST:TOXIC. IF SWALLOWED, MAY CAUSE ABDOMINAL DISCOMFORT, NAUSEA, VOMITING, DIARRHEA& SYSTEMIC POISONING. TARGET ORGANS:LUNGS, EYES, SKIN, DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:NO DATA FOUND. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 20 MINS RETRACTING LIDS OFTEN. GET IMMED MED ATTN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. INHAL :REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP/HAVE TRAINED INDIVIDUAL ADMIN OXYGEN. GET MED ATTN IMMED. INGEST:INFO PRESENTED IN THIS SECTION IS ONLY A GUIDE. EMERGENCY PERS SHOULD BE (ING 4) ===================== Fire Fighting Measures ===================== Flash Point:220F,104C Lower Limits:0.9% Upper Limits:24.6% Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE (CO*2), OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . FIGHT FIRE FROM SAFE DIST & PROT LOCATION. HEAT MAY BUILD PRESS & RUPTURE CLSD CNTNRS, SPREADING FIRE & (SUPDAT) Unusual Fire/Explosion Hazard:MATERIAL MAY BE IGNITED IF PREHEATED TO TEMPERATURES ABOVE FLASH POINT IN PRESENCE OF A SOURCE OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:PVNT SPREAD OF ANY SPILL TO MIN HARM TO HUMAN HLTH & ENVIRON. DIKE W/SUITABLE ABSORB MATL LIKE SPEEDIDRI. WEAR COMPLETE & PROPER PPE & VENT SPACE INVOLVED. FOLLOW GUIDELINES OF EXPOS CONTROLS & PERSON AL PROT SECTION (& FOLLOW 29 CFR 1910.120) (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/MATERIAL, AVOID BREATHING VAPORS, USE ONLY IN A WELL-VENTILATED AREA. STORE IN A COOL, DRY PLACE. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MAY NOT BE REQUIRED UNDER NORMAL CONDITIONS OF USE. IF LOCAL EXHAUST VENT IS NOT AVAILABLE, A NIOSH APPROVED RESPIRATORY PROTECTION PROGRAM FOLLOWING GUIDELINES OF OSHA STANDARD 1910.134 SHOULD BE CON SIDERED TO MAINTAIN OPERATOR COMFORT. Ventilation:NO EXPOS LIMS EXIST FOR CONSTITUENTS OF THIS PROD. USE PROCESS ENCLOSURES, LOC EXHST VENT/OTHER ENGINEERING (SUPP DATA) Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . PREVENT SKIN CONTACT BY WEARING APRON & BOOTS. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. ALL EQUIP SHOULD BE CLEANED THORO AFTER EACH USE & SHOULD NOT LEAVE THE WORK PLACE. Supplemental Safety and Health VENT:CONTROLS TO MIN EXPOS & MAINTAIN OPERATOR COMFORT. PROT PROT:FULL LGTH FSHLD . FIRE FIGHT PROC:INCR RISK OF BURNS/INJURIE S. USE WATER SPRAY/FOG FOR COOLING. EVEN IF MATL IS WATER SOL, IT MAY NOT BE PRACTICAL TO EXTING FIRE BY WATER (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:448F,231C Vapor Pres:0.01-0.1 Vapor Density:HVR/AIR Spec Gravity:0.96 Evaporation Rate & Reference:0.01-0.1 (N-BUAC=1) Solubility in Water:100% Appearance and Odor:LIQUID, SEMI-SOLID OR SOLID; MILD SOLVENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, CAUSTICS (BASES), STRONG OXIDIZING AGENTS. Stability Condition to Avoid:ELEVATED TEMPERATURES IN COMBINATION W/SPARKS, OPEN FLAMES OR OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF BY INCINERATION OR WASTE WATER TREATMENT FOLLOWING FEDERAL, STATE, PROVINCIAL OR LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:THIMEROSAL, 37029 CAGE:GO062 CAGE:45896 CAGE:67823 CAGE:GO062 ============= Composition/Information on Ingredients ============= Ingred Name:THIMEROSAL, ETHYLMERCURITHIOSALICYCIC ACID, SODIUM SOLUTION CAS:54-64-8 RTECS #:OV8400000 OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: FATAL, ALLERGIC REACTION, PAPULAR OR VESTICULAR ERUPTIONS, MUCOUS MEMBRANE, & UPPER RESPIRATORY TRACT IRRITATION. INGESTION: FATAL, & ALLERGIC REACTION. SKIN: ABSORPTION, IRRITATION, & ALL ERGIC REACTION. EYES: IRRITATION, & ALLERGIC CONJUNCTIVITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: FATAL, ALLERGIC REACTION, PAPULAR OR VESTICULAR ERUPTIONS, MUCOUS MEMBRANE & UPPER RESPIRATORY IRRITATION. INGESTION: FATAL, & ALLERGIC REACTION. SKIN: ABSORPTION, ALLERGIC REACTION, & IRR ITATION. EYES: IRRITATION, & ALLERGIC CONJUNCTIVITIS. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNT OF WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: OB TAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY PLACE. KEEP TIGHTLY CLOSED. USE ONLY IN CHEMICAL FUME HOOD. MAY DISCOLOR ON EXPOSURE TO LIGHT, LIGHT SENSITIVE. Other Precautions:DON'T BREATH DUST. AVOID CONTACT W/EYES, SKIN, & CLOTHING. AVOID PROLONGED/REPEATED EXPOSURE. HIGHLY TOXIC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:CHEMICAL FUME HOOD Other Protective Equipment:RUBBER BOOTS, PROTECTIVE CLOTHING, SAFETY SHOWER, & EYE BATH Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:450F ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, & STRONG BASES Hazardous Decomposition Products:TOXIC FUMES OF CO, CO2, SULFUR OXIDES, MERCURY, & MERCURY OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL & HAZARDOUS WASTES. OBSERVE ALL FEDERAL, STATE, & LOCAL LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:176 4844 KODAK DI-10 DEVELOPER CAGE:5K871 CAGE:0ZW37 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:KYNAR, 1,1-DIFLUOROETHANE HOMOPOLYMER CAS:24937-79-9 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:STYRENE, ACRYLATE COPOLYMER CAS:25213-39-2 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9596 Ingred Name:QUARTERNARY AMMONIUM COMPOUND Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV: CARBON BLACK: 3.5 MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: AIRBORNE DUST IRRITATING. EYES: MAY BE IRRITATING. SKIN: MAY CAUSE IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:OVEREXPOSURE TO CARBON BLACK MAY RESULT IN IRRITATION OF THE RESPIRATORY TRACT AND BENIGN DEPOSITION OF CARBON BLACK IN THE LUNG. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. GET MEDICAL ATTENTION. SKIN-IMMEDIATELY FLUSH WITH PLEN TY OF WATER FOR 15 MIN WHILE REMOVING CONTAMINATED CLOTHE/SHOES & WASH WITH SOAP & WATER. GET MEDCIAL ATTENTION IF SYMPTOMS OCCUR. INGESTED-DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAT SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST- AIR MIXTURE. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS OF POWDERED TONERS. THE VERY FINE PARTICLES CAN CAUSE A FIRE OR EXPLOSION. AVOID GENERATION OF DUST. SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER CARTO N. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:WASHING FACILITIES. Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:NEGLIGIBLE Vapor Density:NEGLIGIBLE Spec Gravity:5.0 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:SOLID (POWDER). BLACK. SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, BASES, SODIUM HYPOCHLORITE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF IRON, OXIDES OF NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL REGULATIONS. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:THINNER CELLULOSE-NITRATE DOPE Preparer's Name:MAURICE J. PUMA CAGE:OBBA1 CAGE:OBBA1 CAGE:0BBA1 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL ACETATE (RQ:5000#) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 40% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ALCOHOL 5000# CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 25% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NAPHTA, AROMATIC MIXTURE2000# Fraction by Wt: 25% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/STEL 150 PPM Ingred Name:AMYL ACETATE CAS:628-63-7 RTECS #:AJ1925000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/STEL 150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. RESULT IN EYE DAMAGE, NOT REMOVED PROPERLY. SKIN: IRRITATION & CAUSE DERMATITIS. INHALATION: IRRITATION TO EYES & RESPIR. TRACT, HEADACHE, DIZZINESS, ARE ANESTHETIC & OTHER NERVOUS E FFECTS. INGESTION: LOW TOXICITY. SM AMTS OF LIQUID ASPRIATED INTO THE RESPIR. SYS. DURING INGEST CAUSE PULMONARY EDEMA. Effects of Overexposure:INGESTION: DURING INGESTION OR FROM VOMITING, MAY CAUSE BRONCHLOPNEUMONIA. Medical Cond Aggravated by Exposure:REPEATED EXCESSIVE EXPOSURE MAY CAUSE MINOR LUNG, LIVER, KIDNEY EFFECTS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP & WATER. REMOVE & WASH CONTAMINATED CLOTHING; & SHOES. INHALATION: REMOVE TO FRESH AIR. GIV E CPR IF BREATHING HAS STOPPED. CONSULTA PHYSICIAN. INGESTION: IF SWALLOWED DO NOT INDUCE VOMITING. KEEP AT REST. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>20F,>-7C Extinguishing Media:FLAMMABLE LIMIT. NO INFORMATION FOUND. Fire Fighting Procedures:WEAR POSITIVE-PRESSURE, SCBA. WATER SPRAY COOL FIRE EXPOSED SURFACES. IF LEAK/SPILL NOT IGNITED, WATER SPRAY DISPERSE VAPOR.EXTING.W/ALCOHOL TYPE FOAM,DRY CHEM. Unusual Fire/Explosion Hazard:CAN RELEASE VAPORS THAT FORM FLAMMABLE MIXTURES AT TEMPER. AT/ABOVE FLASH POINT. DON'T PRESSURIZE, CUT, WELD BRAZE, DRILL, GRIND, OR EXPOSE TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILL, SOAK UP WITH SUITABLE, NON- REACTIVE ABSORBENT MATERIAL. COLLECT WITH RUBBER SHOVEL INTO CONTAINER FOR PROMPT DISPOSAL. FOR LARGE SPILL KEEP PUBLIC AWAY & NOTIFY AUTHORITIES & EPA AS THIS PRODUCT IS A EPA HAZARDOUS SUBSTANCES. ======================Handling and Storage ====================== Handling and Storage Precautions:ALL EQUIPMENT GROUNDED IN HANDLING THIS PRODUCT. USE EXPLOSION PROOF VENTILATION EQUIPMENT. STORE IN COOL, DRY PLACE & AWAY FROM ALL IGNITION SOURCES. Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. AVOID SKIN & EYE CONTACT. KEEP AWAY FROM HEAT & OPEN FLAME. THE USE OF MECH. DILUTION VENT. IS RECOMM. WHENEVER THIS PRODUCT IS USED IN CONFINED SPACE, IS HEATED ABOVE AMBIENT TEMP. OR AGITAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORS MAY BE NECESSARY TO PREVENT OVEREXPOSURE BY INHALATION. Ventilation:LOCAL EXHAUST & MECHANICAL DILUTION VENTILATION IS RECOMMENDED WHENEVER THIS PRODUCT IS USED. Other Protective Equipment:HANDLING EQUIPMENT SHOULD BE GROUNDED PROPERLY AND USE EXPLOSION PROOF EQUIPMENT. Work Hygienic Practices:ALWAYS WASH THOROUGHLY WITH SOAP & WATER AFTER HANDLING, NO SMOKING IN WORKING & NEARBY AREAS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Spec Gravity:0.843 @77F(25C) Viscosity:> 1.0@68F/20C Solubility in Water:NEGLIGIBLE @ 68F/20C Appearance and Odor:CLEAR WATER WHITE SOLVENT MIXTURE, STRONG ALCOHOL SOVLENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, CAUSTICS, AMINES, ALKANOIAMINES, ALDEHYDES, AMMONIA. Stability Condition to Avoid:KEEP AWAY FROM FLAME, PILOT LIGHT, STATIC ELECTRICITY, SPARKS, & OTHER IGNITION SOURCES. Hazardous Decomposition Products:NO IMFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT MIGHT BE BURNED IN AN APPROVED INCINERATOR IN ACCORDANCE W/ALL LOCAL, STATE & FEDERAL REGULATIONS. CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL & ENSURE CONFORMITY TO ALL LOCAL,STA TE & FEDERAL REGULATIONS. THIS PRODUCT IGNIT.WASTE
1
gloves_mandatory
===================== Product Identification ===================== Product ID:20804-1238 SMDC SHIELDED MILD DETONATING CORD Preparer's Name:S SCHOOLFIELD/J KOHRING CAGE:17610 CAGE:17610 ============= Composition/Information on Ingredients ============= Ingred Name:X-CHORD, 2.5 GRAINS/FT, SILVER SHEATH ACGIH TLV:0.1 MG/CUM Ingred Name:HEXANITROSTILBENE I ACGIH TLV:10.0 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION TO THE NOSE, THROAT & MUCOUS MEMBRANE, ALLERGIC REACTIONS. SKIN: IRRITATION & ABSORPTION, ALLERGIC REACTIONS. EYES: IRRITATION. INGESTION: TOXIC, MAY CAUSE DEATH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, REDNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:DON'T ATTEMPT TO EXTINGUISH. EVACUATE AREA. USE SCBA TO CONTAIN RESULTING FIRE. Unusual Fire/Explosion Hazard:IF EXPOSED TO FIRE, THE UNIT MAY ACTUATE/EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:CALL LOCAL HAZARDOUS MATERIALS TEAM. REMOVE IGNITION SOURCES. COVER ANY EXPOSED MATERIAL W/VEGETABLE OIL & REMOVE FOR APPROVED DISPOSAL. USE FLAME RETARDANT CLOTHING, SAFETY GLASSES & NON-SPARKING TOO LS. ======================Handling and Storage ====================== Handling and Storage Precautions:ANTI-STATIC ARE TO BE USED FOR STORAGE & SHIPPING. Other Precautions:THIS MSDS ISN'T INTENDED TO BE AN ORDNANCE HANDLING DOCUMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED HEPA RESPIRATOR IF PEL/TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST: REQUIRED FOR TEST FIRING. Other Protective Equipment:FLAME RETARDANT COAT & GROUNDING STRAPS TO PREVENT ELECTROSTATIC DISCHARGE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:SMDC: SILVER; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS, ACIDS, BRONZE, CORROSIVES & OXIDIZERS. Stability Condition to Avoid:MECHANICAL SHOCK, STATIC ELECTRICITY, HEAT, FLAME/SPARKS. Hazardous Decomposition Products:CO, NITROGEN, NITROUS OXIDES, HYDROGEN, CARBON, CO2 & WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:UNFIRED UNITS/WASTE SHOULD BE DISPOSED AS REACTIVE (D003) & TOXIC (D011) HAZARDOUS WASTE, IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN-0367.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:CRESYLIC ACID ;CODE:T 3217 CAGE:0AN91 CAGE:60777 CAGE:0AN91 ============= Composition/Information on Ingredients ============= Ingred Name:CRESOL, ALL ISOMERS (CRESYLIC ACID) (SARA III) CAS:1319-77-3 RTECS #:GO5950000 Fraction by Wt: 55.0% OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHENOL CAS:108-95-2 RTECS #:SJ3325000 Fraction by Wt: 30.0% OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 8990 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:OTHER COMPONENTS (AROMATIC ALCOLOLS) Fraction by Wt: BALANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1454 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:CORROSIVE TO EYES,SKIN,RESPIRATORY TRACT OR G.I.TRACTS;MAY DAMAGE ALL BODY TISSUES;BURNS EYES AND SKIN;MAY DAMAGE EYES AND RESPIRATORY AND G.I. SYSTEMS.MAY BE FATAL IF INGESTED. CHRONIC:DAMAGE T O CNS,LUNGS,AND KIDNEYS. MAAL Explanation of Carcinogenicity:DATA PER MSDS Effects of Overexposure:SEE HEALTH HAZARDS DATA. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE SUBJECT TO FRESH AIR. EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIA TE MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:180F,82C Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:AVOID EXTREME HEAT;FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR SOAK UP SMALL SPILLS WITH PAPER TOWEL OR INERT ABSORBANT. DIKE TO RETAIN LARGE SPILLS. VACUUM UP FREE LIQUID. REMOVE RESIDUE WITH INERT ABSORBANT. PLACE IN DISPOSAL CONTAINER. FLUSH AREA WITHWATER. Neutralizing Agent:DILUTE WITH WATER ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE, HEAT AND IGNITION SOURCES. KEEP CONTAINERS CLOSED. Other Precautions:AVOID CONTACT WITH EYES AND SKIN.DO NOT BREATHE VAPORS OR MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) VENTILATION IS REQUIRED. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA IS NOT VENTED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health DO NOT TAKE INTERNALLY;USE PROPER PERSONAL PROTECTION. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:374F,190C Melt/Freeze Pt:M.P/F.P Text:40.0F,4.4C Vapor Pres:1 Vapor Density:3.4 Spec Gravity:1.03-1.05 Evaporation Rate & Reference:NIL(N-BUTYL ACETATE = 1). Solubility in Water:MODERATE Appearance and Odor:LIGHT COLORED LIQUID;TARRY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,ALKALIES.DO NOT STORE IN BRASS,BRONZE,COPPER OR ALUMINUM CONTAINER. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND OTHER TOXIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:X-CALIBER CAGE:0K209 CAGE:0K209 ============= Composition/Information on Ingredients ============= Ingred Name:N-METHYLPYRROLIDONE CAS:872-50-4 RTECS #:UY5790000 Fraction by Wt: <65% Other REC Limits:NONE RECOMMENDED Ingred Name:D-LIMONENE CAS:5989-27-5 RTECS #:GW6360000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-PRODUCT CONTACT THE EYE MAY CAUSE EYE IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION AND DEFATTING. EXCESSIVE INHALATION OF VAPOR CAN CAUSE NASAL AND RESPIRATORY IRRITATION, POSSIBLE UN CONSCIOUSNESS & ASPHYXIATION. SWALLOWING LARGE AMOUNTS CAN CAUSE GASTROINTESTINAL DISTURBANCES. CHRONIC-MILD IRRITATION. Explanation of Carcinogenicity:NONE KNOWN. Effects of Overexposure:EYE-REDNESS AND TEMPORARY CORNEAL CLOUDING. SKIN-REDNESS. INHALATION-DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES-IF EYE CONTACT OCCURS, FLUSH WITH WATER FOR AT LEAST 15 MIN OCCASIONALLY OPEN UPPER & LOWER LIDS. IF IRRITATION PERSISTS, CALL DOCTOR. SKIN-IN CASE OF SKIN CONTACT WASH SKIN THOROUGHLY WITH SOAP & WATER. IF IRRITATION DEVELOPS CONSULTPHYSICIAN. INHALATION-IF OVERCOME BY VAPOR OR MIST, REMOVE TO FRESH AIR & ASSIST BREATHING AS NECESSARY. INGESTION-DO NOT INDUCE VOMITING. SEEK MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:136F,58C Lower Limits:0.8 Extinguishing Media:REGULAR FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS. COOL CONTAINER WITH SPRAY IF POSSIBLE. Unusual Fire/Explosion Hazard:AUTO IGNITION TEMPERATURE APPROXIMATELY 460F. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK AT ONCE. CONTAIN AND COLLECT MATERIAL. ABSORB RESIDUE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE AND STORE AWAY FROM HEAT, SPARKS AND OPEN FLAMES. KEEP CONTAINER SEALED WHEN NOT IN USE. Other Precautions:READ AND UNDERSTAND ALL CAUTIONS, LABELS AND MSDS BEFORE USING ANY CHEMICAL PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED ORGANIC VAPOR RESPIRATOR IF EXCESSIVE MIST OR VAPORS ARE CREATED. Ventilation:USE MECHANICAL VENTILATION WHENEVER PRODUCT IS USED IN CONFINED SPACE, ATOMIZED, HEATED OR AGITATED. Other Protective Equipment:BOOTS, COVERALLS, APRONS AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:DO NOT HAVE FOOD OR DRINK IN THE VICINITY. MINIMIZE BREATHING OF VAPOR OR MIST. AVOID PROLONGED OR REPEATED CONTACT SKIN Supplemental Safety and Health WASH CONTAMINATED CLOTHING BEFORE RESUE. KEEP ALL CHEMICALS OUT OF THE REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:370F,188C Vapor Pres:<2 MMHG Vapor Density:4.5 Spec Gravity:0.92 Evaporation Rate & Reference:<0.1 (N-BUTYL ACETATE=1) Solubility in Water:VERY SLIGHT (WATER) Appearance and Odor:CLEAR WITH MILD CITRUS ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT FEDERAL, STATE, COUNTRY OR LOCAL ENVIRONMENTAL REGULATORY AGENCIES FOR GUIDANCE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:09-D5078-000, RESOLVE PROCARE TANNIN (SUPDAT) CAGE:IO272 CAGE:IO272 CAGE:63180 ============= Composition/Information on Ingredients ============= Ingred Name:GLYCOLS, POLYETHYLENE, MONO(P-NONYL PHENYL); (NONYL PHENOL POLYETHYLENE GLYCOL) CAS:26027-38-3 RTECS #:MD0906000 Fraction by Wt: 2.8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OXALIC ACID CAS:144-62-7 RTECS #:RO2450000 Fraction by Wt: 0.8% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/2 STEL Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM Ingred Name:2-PROPANOL, 1-METHOXY-; (PROPYLENE GLYCOL MONOMETHYL ETHER) CAS:107-98-2 RTECS #:UB7700000 OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: DO NOT GET IN EYES. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER ASSOCIATED WITH ADMINISTERING OF ETHYLENE GLYC OL MONOBUTYL ETHER (EGBE). (EXTRATED FROM DHHS (NIOSH) PUB NO. 90-118) . Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES: IMMEDIATELY REMOVE CONTACT LEN SES AND RINSE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Extinguishing Media:USE WATER SPRAY, FOAM, DRY CHEMICAL OR CARBON DIOXIDE, AS SUITABLE FOR THE SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SPILLS DUE TO RUPTURED CONTAINERS, FLUSH WITH LARGE QUANTITIES OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING: DO NOT GET IN EYES. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DO NOT MIX WITH BLEACH OR USE WITH OTHER CHEMICALS. KEEP FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE REQUIRED. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR TRADE NAME/PART NO:CARPET SPOT CLEANER. PH:3.5-4.5. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.012 pH:SUPDAT Evaporation Rate & Reference:1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR, WATER WHITE LIQUID. SWEET PEACH ODOR. Percent Volatiles by Volume:>95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX WITH BLEACH OR USE WITH OTHER CHEMICALS. Stability Condition to Avoid:KEEP FROM FREEZING. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE, AND FEDERAL REGULATIONS. PLEASE ENCOURAGE STATE & LOCAL AUTH TO ESTABLISH A RECYCLING PROGRAM SO THAT THIS CONTAINER CAN BE RECYCLED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:08570 4707 LT.GRAY CRU TILE-LIKE GLAZE COATING PART B CAGE:59500 CAGE:59500 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 40-50% Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-2* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1-10% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC POLYISOCYANATE, HEXAMETHYLENE DIISOCYANATE POLYMER (HDI POLYMER) *96-2* CAS:28182-81-2 RTECS #:NQ9170000 Fraction by Wt: 45-55% Other REC Limits:1 MG/CUM Ingred Name:HEXAMETHYLENE DIISOCYANATE CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: <1% ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): >10000 MG/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION & ABSORPTION. EYES: MAY CAUSE IRRITATION & CORNEAL INJURY. INGESTION: CAN CAUSE BURNING & TISSUE DAMAGE. ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION: ANESTHETIC, IRRITATION OF THE RESPIRATORY TRACT/CNS DEPRESSION. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNING SENATION, VOMITING, DIARRHEA, DROWSINESS, HEADACHE, DIZZINESS, STAGGERING GAINT, CONFUSION, UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/WATER FOR 15 MINS. INGESTION: ASPIRATION HAZARD. CALL A PHYSICIAN/POISON CONTROL CENTER. DON'T ATTEMPT TO INDUCE VOMITING. INHALATION: R EMOVE TO FRESH AIR. RESTORE BREATHING IF REQUIRED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:108F Lower Limits:1 Upper Limits:7 Extinguishing Media:USE N.F.P.A CLASS B EXTINGUISHERS, CO2, DRY CHEMICAL/FOAM. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL CLOSED CONTAINERS. FOG NOZZLES ARE PREFERRED. WEAR SCBA. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DON'T APPLY TO HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA. REMOVE W/INERT ABSORBENT/SCRUB W/SOAP & WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS II COMBUSTIBLE LIQUIDS. Other Precautions:DON'T TAKE INTERNALLY. AVOID CONTACT W/SKIN & CLOTHING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THIS PRODUCT MAY BE HARMFUL/FAT AL. DON'T SPRAY APPLY THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A CHEMICAL RESPIRATOR APPROVED FOR ORGANIC VAPORS (NIOSH 23C/EQUIVALENT) DURING THE APPLICATION & UNTIL THE WORK AREA HAS BEEN EXHAUSTED OF ALL VAPORS. Ventilation:LOCAL EXHAUST TO KEEP VAPOR CONCENTRATIONS BELOW TLV. Other Protective Equipment:PROTECTIVE CLOTHING, UNIFORMS/COVERALLS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. SENSITIZATION: HEXAMETHYLENE DIISOCYANATE IS A PULMONARY & SKIN SENSITIZER IN HUMANS. THE ORAL LD50 INFOR MATION IS FOR 1,6-HEXAMETHYLENE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:295F Vapor Pres:3.7 Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN N-BU AC Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR LIQUID W/ESTER LIKE ODOR Percent Volatiles by Volume:47/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, HOT SURFACES & SOURCES OF IGNITION. Hazardous Decomposition Products:CO2, CO & NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. COMBUSTIBLE LIQUID NA1993.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:DRY-GLIDE Preparer's Name:ES/KD CAGE:0AXK7 CAGE:0AXK7 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYLENE, TETRAFLUORO-, POLYMER; (FLUOROTELOMER) CAS:116-14-3 RTECS #:KX4025000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9495 Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 OSHA PEL:800 (MFR) ACGIH TLV:800 (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:EXCESSIVE INHALATION OF VAPORS CAN BE HARMFUL AND MAY CAUSE HEADACHE, DIZZINESS, ASPHYXIA, ANESTHETIC EFFECTS AND POSSIBLE UNCONSCIOUSNESS. EYE:POSSIBLE MILD IRRITATION. SKIN:POSSIBLE MILD IRRITATION. INGEST:POSSIBLE CHEMICAL PNEUMONITIS IF ASPIRATED INTO LUNGS. NAUSEA. CHRONIC:EFFECTS DUE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:TO EXCESSIVE EXPOSURE TO THE RAW MATERIALS OF THIS MIXTURE MAY CAUSE CARDIAC ABNORMALITY, LIVER ABNORMALITIES, KIDNEY AND OR LUNG DAMAGE. Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING EYE, SKIN, OR UPPER RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATED, SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. IF IRRITATED, SEEK MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. RESUSCITATE IF NECESSARY. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. DRINK TWO LARGE GLASSES OF WATER. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DO NOT EXPOSE AEROSOLS TO TEMPERATURES ABOVE 130F OR THE CONTAINER MAY RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH SUITABLE MEDIUM. INCINERATE OR LANDFILL ACCORDING TO LOCAL, STATE OR FEDERAL REGULATIONS. DO NOT FLUSH TO SEWER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT PUNCTURE OR INCINERATE CONTAINERS. DO NOT STORE AT TEMPERATURES ABOVE 130F. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID FOOD CONTAMINATION. AVOID BREATHING VAPORS. REMOVE IGNITION SOURCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . IF VAPOR CONCENTRATION EXCEEDS TLV, USE RESPIRATOR APPROVED BY U.S. BUREAU OF MINES FOR ORGANIC VAPOR. Ventilation:ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATION BELOW TLV. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE HANDLING FOOD. REMOVE CONTAMINATED CLOTHING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:0.675 (H*2O =1) Solubility in Water:INSOLUBLE Appearance and Odor:OPAQUE LIQUID, WITH SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE METALS, WATER, STRONG OXIDIZING AGENTS, REACTIVE METALS SUCH AS ALUMINUM AND MAGNESIUM. Stability Condition to Avoid:OPEN FLAME, WELDING ARCS, HEAT. Hazardous Decomposition Products:CO, CO*2, HF, PFIB, TEE, HEP, AND OLIGOMERS. ABOVE 800F TOXIC FLUORONATED GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . AEROSOL CANS WHEN VENTED TO ATMOSPHERIC PRESSURE THROUGH NORMAL USE, POSE NO DISPOSAL HAZARD.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:HYDROCHLORIC ACID,20 DEG BAUME TECH & F.P. CAGE:KO653 CAGE:18873 CAGE:KO653 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 34.5% OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 65.5% ===================== Hazards Identification ===================== Effects of Overexposure:EYES/SKIN:CAUSES BURNS.INGEST:SEVERE BURNS OF MOUTH,GI TRACT.VAPOR IS EXTREMELY IRRITATING. ======================= First Aid Measures ======================= First Aid:SKIN:WASH W.SOAP & H*2O. EYES:FLUSH W. H*2O. INGESTED:DON'T INDUCE VOMITING. INHALED:REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE CONTAMINATED CLOTHING. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.NO CARBONATES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG. Fire Fighting Procedures:USE H*20 TO COOL EXPD CONTRS. USE SCBA & FULL PROT.CLTHG. Unusual Fire/Explosion Hazard:ON CONTACT W METALS,FLAMMABLE,EXPLSIVE HYDROGEN GAS IS EVOLVED.EXPLOS AMTS MAY ACCUMULATE IN TANKS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK W/O RISK. EVACUATE AREA. SM SPILL:ABSORB WITH INERT ABSORBENT,FLUSH AREA WITH WATER. LG SPILL:NEUTRALIZE WITH SODA ASH. FLUSH NEUTRALIZED SOLUTION TO SEWER IN ACC ORDANCE WITH INTERNATIONAL FED,STA, & LOCAL REGS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN COOL PLACE AWAY FROM IGNITION SOURCES.KEEP CONTAINER CLOSED,PROTECT FR DAMAGE.DO NOT MIX/STORE WITH CYANIDES,SULFIDES,FORMALDEHYDE. Other Precautions:AVOID ANY CONTACT.DO NTO BREATHE VAPOR.WASH THOROUGHLY AFTER HANDLING.REFER TO DUPONT HCL HANDLING & STORAGE BULLETIN,HCL DATA SHEET. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IN FIRE,OTHERWISE CHEM CARTR RESPIR. Ventilation:USE ONLY WITH ADEQUATE VENT.KEEP IN WELL-VENTILATED ROOM. Other Protective Equipment:RUBBER BOOTS,CHEMICAL SUIT. Supplemental Safety and Health MSDS EFFECTR:8/1/79. SYNONYM:HYDROGEN CHLORIDE,CHLOROHYDRIC ACID.PB:REAGENT-122F/50C.VAP PRESS.REAGENT-240 AT 25C. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=82.8C, 181.F Vapor Pres:35 Vapor Density:1.27 Spec Gravity:1.175 Evaporation Rate & Reference:>1(BUTYL ACETAT=1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS-LT YELLOW LIQ;PUNGENT ACRID ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS,CYANIDE,SULFID,FORMALDEHYDE MOST METALS. Stability Condition to Avoid:HEAT, IGNITION SOURCES,OPEN FLAME. Hazardous Decomposition Products:HEATING WILL RELEASE GASEONS HCL. ==================== Disposal Considerations ==================== Waste Disposal Methods:WEAR RUBBER CLOVES,SCBA, PROTECT CLTHG. ADD SLOWLY TO LG VOL OF AGITATED SOLN OF NA*2 CO*2 & CA(OH)*2. ADD THIS SOLN TO LG EXCESS OF H*20. ELIM IGN SOURCES OR KEEP IN COVD DRS. HDLE & DISPOSE LW ALL APPL INTERN, FED, STATE & LOCAL REGS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:S261-10 SODIUM CARBONATE ANHYDROUS 21080 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE (SODA ASH, TRONA, CARBONIC ACID, CRYSTOL CARBONATE, DISODIUM CARBONATE) *97-4* CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 4090 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION & BURNS. INGESTION: MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT. INHALATION: MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT W/BURNING PAIN IN THE NOSE, THROAT & PULMONARY EDEMA. P ROLONGED/REPREATED CONCENTRATED SOLUTIONS CAUSED TISSUE DAMAGE. SODA ULCERS ON HANDS & PERFORATION OF THE NASAL SEPTUM. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, PAIN, COUGHING, WHEEZING, SHORTNESS OF BREATH. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY & SUPPORTIVELY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING. WEAR A SCBA. Unusual Fire/Explosion Hazard:MATERIAL WILL NOT BURN, NON-COMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT. VACUUM/SWEEP UP MATERIAL & PLACE INTO A SUITABLE DISPOSAL CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY WELL VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:AVOID INGESTION & INHALATION. KEEP CONTAINER TIGHTLY CLOSED. DON'T GET IN EYES, SKIN/CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GOOD GENERAL SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health 2,4-DINITROTOLUENE, 2,4,6-TRINITROTOLUENE, SODIUM SULFIDE & WATER, LITHIUM, PHOSPHORUS PENTOXIDE, FLUORINE, HYDROGEN PEROXIDE, SODIUM CARBONATE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:752F Melt/Freeze Pt:M.P/F.P Text:1564F Spec Gravity:1.55 pH:11.6 Solubility in Water:COMPLETE Appearance and Odor:SOLID WHITE HYGROSCOPIC POWDER W/AN ALKALINE TASTE; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE MATERIALS/RED-HOT ALUMINUM METAL/INCOMPATIBLE W/AMMONIA & SILVER NITRATE/SULFURIC ACID. (SEE SUPP) Hazardous Decomposition Products:CO2, TOXIC FUMES OF SODIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:809 5549, FUSER OIL CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:POLY (DIMETHYLSILOXANE) CAS:63148-62-9 RTECS #:JJ6484500 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: LOW HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE ALLERGIC SKIN REACTION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES-ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN-WASH WITH SOAP & WATER. GET MEDCIAL ATTENTION IF SYMPTOMS OCCUR. INGESTED-IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. FOR LARGE SPILLS: SOAK UP WITH SAND OR EARTH. FLUSH SPILL AREA WITH WATER SPRAY. PREVENT RUNOFF FRO M ENTERING DRAINS, SEWERS OR STREAMS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. Other Precautions:USE WITH ADEUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:5 MMHG Spec Gravity:0.98 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID, COLORLESS, SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FORMALDEHYDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. INCINERATE OR LANDFILL.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BRUSHABLE QWIK SEAM SEALER, BJ-N CAGE:2L332 CAGE:2L332 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA 313) (CERCLA). BP:230F,110C. VP:38 @ 20C. EVAP RATE:1.5 (N-BUAC=1). FL PT:45F,7C. LEL:1.2%. UEL:7%. CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA:& PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. SYMPS INCL:LOSS OF MEMORY, INTELLECTUAL (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:ABILITY & COORD. NOTE:INTENTIONAL MISUSE BY DELIB CONC & INHAL SOLV VAPS MAY BE HARMFUL/FATAL! SKIN:EXPOS (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:TO SM AMTS OF SOLV OVER LONG PERIODS OF TIME MAY CAUSE SOME/ALL OF SYMPS AS IN ACUTE EXPOS TO SOLVS. EYES: (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:SYMPS AS IN ACUTE EXPOS BUT TO A LESSER DEGREE & DMG NOT LIKELY. INGEST:UNKNOWN. NOTE:TOLUENE APPEARS ON (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:FROM RISK OF FURTHER EXPOS. ADMIN OXYG/ARTF RESP AS NEEDED. OBTAIN MED ATTN. INGEST:INDUCE VOMIT. (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CONSULT MD, HOSPITAL, EMER ROOM/POIS CTL CTR IMMED. HAVE LIST OF INGS AVAIL. NOTES TO MD:EYES:STAIN FOR (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:EVID OF CORNEAL INJURY. IF CORNEA BURNED, INSTILL ANTIBIOTIC/STEROID PREPARATION FREQUENTLY. SKIN:TREAT (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:SYMPTOMATICALLY. INHAL:TREAT AS FOR SOLVENT FUME INHALATION. INGEST:INDUCE VOMITING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:SOLV VAPS AT CONCS ABOVE TLV CAN IRRIT RESP TRACT (NOSE, THROAT, LUNGS) CAUSING BURNING SENSATION, RUNNY NOSE, SORE THROAT, COUGH, CHEST DISCOMFORT (TIGHTNESS). MAY CAUSE CNS DEPRESS W/FOL LOWING PROGRESSIVE SYMPS:HDCH, DIZZ, NAUS, STAG GAIT, CONFUSN, UNCON, CESSATION OF BRTHG & DEATH. SKIN:(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:RPTD/PRLNG CONT W/SOLVS CAN RSLT IN DRY, DEFATTED & CRACKED CAUSING INCR SUSCEPTIBILITY TO INFECTION. IRRIT MAY DEVEL INTO CONT DERM. EYE:SOLV FUMES MAY IRRIT W/RESULTING ITCH, BURNING, REDNE SS. PERM TISS DMG MAY OCCUR IF SEALANTSARE APPLIED DIRECTLY & NOT FLUSHED OUT IMMED. INGEST:IRRIT TO MOUTH, & (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFICALLY KNOWN TO MFR, BUT IT IS POSS THAT EYE, RESP TRACT, SKIN, LIVER, KIDNEY, BLOOD CELL FORM, NERV SYS & BRAIN DISEASES MAY BE AGGRAVATED BY OVEREXP TO PRODS ON THIS MSDS. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/CLEAN, LUKEWARM WATER (LOW PRESS) FOR AT LST 15 MINS WHILE LIFTING LIDS. REFER PERS TO MD FOR IMMED ATTN. SKIN:REMOVE CONTAM CLTHG IMMED. WIPE OFF EXCESS MATL W/RAGS/PAPER TOWELS. CLEAN W /WATERLESS HAND CLEANER/WASH AFFECTED AREAS THORO W/SOAP & WATER. WASH CONTAM CLTHG THORO BEFORE REUSE. APPLY SKIN CREAM IF IRRITATED. SEEK MED ATTN IF IRRIT PERSISTS. INHAL:MOVE TO AREA FREE (ING 8) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:SEE INGS Upper Limits:SEE INGS Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CNTNRS TO PREVENT PRESS BUILD-UP (CNTNRS MAY LEAK OR BURST). Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, ELEC MOTORS, SMOKING/OTHER IGNIT (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROT EQUIP INCL NIOSH APPRVD RESP PROT. PVNT FURTHER SPILLAGE. EVACUATE NONESSNTL PERS. REMOVE ALL SOURCES OF IGNIT & VENT AREA. KEEP SPILL FROM REACHING SEWERS & WATERWAYS. COLLECT MATL W/NONSPA RKING TOOLS & PUT IN TIGHTLY SEALED CNTNR.(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STOR TEMP:MIN-50F(10C); MAX-130F(54C). REC SHELF LIFE:1 YR. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. DO NOT INHALE VAPS. AVOID CONT W/SKIN & EYES. Other Precautions:DO NOT STORE IN TEMPS >130F(54C) OR IN DIRECT SUNLIGHT. EDUCATE & TRAIN EMPLOYEES IN SAFE USE & HNDLG OF THESE MATLS AS REQD UNDER OSHA HAZ COMMUNICATION STD (29 CFR 1910.1200). FOLLOW ALL LBL INSTRUC TIONS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXHAUST VENT SUFFICIENT TO KEEP AIR-BORNE CONC OF SOLVS BELOW THEIR RESPECTIVE TLV'S IS NOT POSSIBLE, A NIOSH APPROVED TC23C RESPIRATOR OR TC-19C AIR SUPPLIED RESP MUST BE USED. OBSERVE OSHA REGS ( 29 CFR 1910.134) FOR RESPIRATOR USE. Ventilation:THERE MUST ALWAYS BE ENOUGH VENTILATION TO KEEP VAPOR CONCENTRATION BELOW LOWER FLAMMABLE LIMIT! Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . COVER AS MUCH OF SKIN AS POSSIBLE W/APPROPRIATE CLOTHING. Work Hygienic Practices:WASH HANDS AFTER USE & BEFORE EATING, DRINKING, SMOKING OR USING TOILET. CONTACT LENSES SHOULD NOT BE WORN. Supplemental Safety and Health EXPLO HAZ:SOURCES AT LOCATIONS FAR FROM MATL BOILING POINT. AT ELEVATED TEMPS (130F(54C) OR OVER) CNTNRS MAY VENT, RUPTURE/BURST (CARTRIDGES MAY EXTRUDE THEIR PLUNGERS). SPILL PROC:REMOVE CNTNR TO SAF E PLACE. EFTS OF OVEREXP:IF SWALLOWED, TO ESOPHAGUS, STOM TISS & DIGEST TRACT. CHRONIC:INHAL:RPTS HAVE ASSOC RPTD(ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE INGS Vapor Pres:SEE INGS Vapor Density:HVR/AIR Evaporation Rate & Reference:SEE INGREDIENTS Solubility in Water:<1% (WT). Appearance and Odor:BEIGE PASTE; MILD SOLVENT ODOR. Percent Volatiles by Volume:42-47 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:STABLE UNDER NORMAL ROOM CONDITIONS. Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON DIOXIDE, CARBON MONOXIDE, HYDROGEN FUMES, SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. INCINERATION OF MATERIAL IS PREFERRED METHOD. CONTAINERS MUST BE HANDLED W/CARE DUE TO FLAMMABLE RESIDUE. RCRA STATUS:SINCE THESE P RODS ARE IGNITABLE, THEY ARE HAZ WHEN DISCARDED.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SHARPIE FINE POINT PERMANENT MARKER, ORANGE CAGE:86874 CAGE:86874 ============= Composition/Information on Ingredients ============= Ingred Name:DYES OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SOLVENTS (CONSISTING OF INGS 3 - 5) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPYL ALCOHOL; (N-PROPANOL) CAS:71-23-8 RTECS #:UH8225000 OSHA PEL:200 PPM ACGIH TLV:200 PPM;250 STEL, S Ingred Name:BUTYL ALCOHOL; (N-BUTANOL)(SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 OSHA PEL:100 PPM ACGIH TLV:50 PPM, S, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-PENTANONE, 4-HYDROXY-4-METHYL-; (4-HYDROXY-4-METHYL-2-PENTANONE); (DIACETONE ALCOHOL). CAS:123-42-2 RTECS #:SA9100000 OSHA PEL:50 PPM ACGIH TLV:50 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS NOT CONSIDERED TOXIC UNDER FEDERAL HAZARDOUS SUBSTANCES ACT REGULATIONS, TITLE 15, PART 1500. PRODUCT IS CONSIDERED SAFE WHEN USED UNDER NORMAL USE CONDITIONS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:84.0F,28.9C Lower Limits:2.2% Upper Limits:14% Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP W/ABSORBENT MATERIAL & DISCARD AS SOLID WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT SHAKE MARKER. KEEP CAP ON MARKER WHEN NOT IN USE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE UNDER NORMAL USE CONDITIONS. Ventilation:NONE UNDER NORMAL USE CONDITIONS. Other Protective Equipment:NONE UNDER NORMAL USE CONDITIONS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NOTE:PHYSICAL DATA & REACTIVITY DATA PERTAINS TO N-PROPANOL (ING 3). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:207F,97C Vapor Pres:13 @ 20C Vapor Density:2.07 Spec Gravity:0.8044 (H*2O=1) Evaporation Rate & Reference:1.3 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS MOBILE LIQUID W/MILD ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT AVAILABLE. Stability Condition to Avoid:NOT AVAILABLE. Hazardous Decomposition Products:NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . DISCARD AS SOLID WASTE.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ZINC CHROMATE PRIMER GREEN TTP1757A002 CAGE:0GB20 CAGE:0GB20 ============= Composition/Information on Ingredients ============= Ingred Name:VM & P NAPHTHA CAS:64742-48-9 Fraction by Wt: 20.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:300 PPM/STEL 400 PPM Ingred Name:N-BUTYL ACETATE (CERCLA) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOBUTINOL ALCOHOL (SARA 313) (CERCLA) CAS:78-83-1 RTECS #:NP9625000 Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HYDROCARBON MIXTURE CAS:64741-41-9 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-HEPTANE CAS:142-82-5 RTECS #:MI7700000 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMMENDED ACGIH TLV:400 PPM/500PPM STEL ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRIT (PAIN, TEAR, RED, SWELL, STINGING SENSATION). SKIN: DEFATTING, DRYING, IRRIT, DERMATITIS. INHAL: HEADACHE, DIZZY, NAUSEA, DECREASED BLOOD PRESSURE, ARRHYTHMIA, CYANOSIS. INGEST: HARMFUL/FAT AL. CHRONIC: MAY CAUSE NS/BRAIN DAMAGE. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/PLENTY WATER >15 MIN, GET MED AID. SKIN: WASH W/SOAP/WATER, GET MED AID, REMOVE CONTAM CLOTHES/SHOES, WASH BEFORE REUSE. INHAL: GET FRESH AIR, IF NO BREATH, GIVE ARTIF RESP, IF BREA THING DIFFICULT, GIVE OXYGEN, GET IMMEDMED AID. INGEST: INDUCE VOMIT IMMED AS DIRECTED BY DOCTOR, NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON, GET MED AID IMMED. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:54.0F,12.2C Autoignition Temp:Autoignition Temp Text:>400F Lower Limits:0.9 Upper Limits:10.9 Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL FOAM, WATER FOG. Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA, FULL PROTECTIVE GEAR. DIKE/COLLECT WATER USED TO FIGHT FIRE. Unusual Fire/Explosion Hazard:CAN RELEASE EXPLOSIVE VAPORS, CONTAINER RETAINS RESIDUE. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA, ABSORB, PLACE IN CHEMICAL WASTE CONTAINER, IF LARGE SPILL DIKE AREA, CALL SPILL RESPONSE TEAM, NOTIFY APPROPRIATE STATE/LOCAL AGENCIES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM IGNITS, KEEP CONTAINER CLOSED WHEN NOT IN USE, STORE IN COOL, DRY PLACE W/APPROPRIATE VENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/ORGANIC VAPOR CARTRIDGE OR CANISTER. IF LEVELS EXCEEDED, USE POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR. Ventilation:LOCAL EXHAUST VENT, USE EXPLOSION PROOF EQUIPMENT. Other Protective Equipment:CHEMICAL SUIT, RUBBER BOOTS. Work Hygienic Practices:WASH BEFORE EAT/DRINK/SMOKE, AVOID CONTACT W/EYES/SKIN/CLOTHING. Supplemental Safety and Health (MORE INFORMATION ON FILE). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:202 TO 395F Melt/Freeze Pt:M.P/F.P Text:NONE Vapor Pres:>9.6 Vapor Density:>AIR Spec Gravity:1.0595 pH:NA VOC Grams/Liter:4.45 Viscosity:20-25 #2 ZAHN Evaporation Rate & Reference:<BUAC Appearance and Odor:GREEN LIQUID W/MILD ODOR Percent Volatiles by Volume:67.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES, AQUEOUS ACIDS, AMINES & ACIDIC ALCOHOLS & STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN FACILITY PERMITTED FOR DISPOSAL OF HAZARDOUS WASTE. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:1231 ES ANTI-SLIP BEACH WHITE Preparer's Name:HASCHAL GOLDEN CAGE:3R217 CAGE:3R217 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 30.8% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANE IRRITATION, NARCOSIS, NAUSEA, DIZZINESS. SKIN: IRRITATION. INGESTION: HARMFUL OR FATAL. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP OR MILD DETERGENT & WATER FOR 15 MINUTES. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. INGESTIO N: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:81F Lower Limits:1.1% Upper Limits:7.0% Extinguishing Media:FOAM, DRY CHEMICAL EXTINGUISHER, CO2 OR WATER OR FOG. Fire Fighting Procedures:USE AIR-SUPPLIED RESCUE FOR ENCLOSED AREAS. COOL EXPOSED CONTAINERS W/WATER. Unusual Fire/Explosion Hazard:DON'T STORE OR MIX W/STRONG OXIDANTS. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP W/ABSORBENT MATERIAL & TRANSFER TO CONTAINER. KEEP FROM OXIDIZERS, HEAT & OPEN FLAME. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY PLACE AWAY FROM HEAT, SPARKS OR OPEN FLAMES. KEEP CONTAINER CLOSED & LABELED. USE W/ADEQUATE VENTILATION. Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING. KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR HEAVY FUMES WEAR SOLVENT TYPE MASK. FOR NORMAL WORK-NONE Ventilation:LOCAL EXHAUST: NORMAL Other Protective Equipment:APRON Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:289F Spec Gravity:1.259 Solubility in Water:INSOLUBLE Appearance and Odor:BEACH WHITE COLOR W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS SUCH AS PERMANGANATE Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME Hazardous Decomposition Products:CO FROM BURNING ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL: EVAPORATE UNTIL ALL VAPORS ARE GONE. LARGE: RECYCLE OR INCINERATE OBSERVING LOCAL, STATE & FEDERAL HEALTH SAFETY POLLUTION LAWS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:ZR-1659 ZINC-X MATTE-GRAY, BZR1650 CAGE:75038 CAGE:75038 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 2.69% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC (AROMATIC PETROLEUM SOLVENT) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 7.54% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM HYDROCARBON). VP:10 @ 20C. LD50:(ORAL,RAT) 25 MG/KG CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 8.73% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 74.01% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:VAPORS MAY IRRITATE EYES, SKIN AND RESPIRATORY TRACT. EXPOSURE/INGESTION MAY CAUSE HEADACHE, DIZZINESS AND NAUSEA. OVEREXPOSURE MAY CAUSE KIDNEY AND/OR LIVER DAMAGE. CHRONIC:NONE LISTED BY MANUF ACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR. EYE:FLUSH W/WATER (LIFT LIDS) FOR @ LEAST 15 MINUTES. SKIN:WASH AFFECTED AREAS WITH SOAP AND WATER. IN CASE OF CONTACT, CONSULT PHYSICIAN IMMEDIATELY. INGEST:DO NOT INDUCE VOM ITING, AND CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:114F,46C Lower Limits:0.9% Upper Limits:7.0% Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE (CO*2), DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER FOG TO COOL CONTAINERS. FIGHT FIRE FROM A SAFE DISTANCE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/SAND & DISPOSE OF IN APPRVD MANNER. DIKE AREA W/SAND TO CONTAIN SPILLED LIQUID. WEAR PROTECTIVE CLOTHING DURING CLEANUP. SHUT OFF AND ELIMINATE ALL IGNITION SOURCES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:OVERHEATING MAY CAUSE CLSD CNTNRS TO RUPTURE. USE EXPLO-PROOF ELEC EQUIP. ISOLATE PROD FROM HEAT, SPKS & OPEN FLAME. KEEP CNTNRS CLSD WHEN NOT IN USE. Other Precautions:EMPTY CNTNRS RETAIN RESIDUE, & CAN BE DANGEROUS. DO NOT CUT, WELD, BRAZE/SOLDER SUCH CNTNRS. AVOID RPTD/PRLNGD BRTHG OR CONT W/SKIN. DO NOT HNDL/STORE NEAR HEAT, SPKS OR FLAME. MINIMIZE BRTHG VAP/MIST . DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IS RECOMMENDED IN AREAS OF POOR VENTILATION. MAINTAIN GOOD VENTILATION. Ventilation:PROVIDE ADEQUATE CROSS AIR CIRCULATION. EXHAUST AT POINT OF USE. Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. Supplemental Safety and Health EVAP RATE:FASTER (RELATIVE TO N-BUTYL ACETATE). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>279F,>137C Vapor Pres:SEE ING 3 Vapor Density:5.00 EST Spec Gravity:2.525 Evaporation Rate & Reference:SUPDAT Solubility in Water:NEGLIGIBLE (<0.1%) Appearance and Odor:GRAY LIQUID - SOLVENT ODOR. Percent Volatiles by Volume:59.21 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:EXTREME HEAT AND/OR HIGH HUMIDITY. OPEN FLAMES OR SPARKS. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN AN APPRVD MANNER IN AN APPRVD FACILITY. LANDFILL I/A/W LOCAL, STATE AND FEDERAL REGS. DISPOSE OF I/A/W LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BIOGUARD BURN OUT Preparer's Name:WENDY L. HOLLINGSWORTH CAGE:54760 CAGE:54760 ============= Composition/Information on Ingredients ============= Ingred Name:HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE) CAS:7778-54-3 RTECS #:NH3485600 Fraction by Wt: 65% EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: NONE SPECIFIED BY MANUFACTURER. CHRONIC: NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:PROMPTLY FLUSH W/LG QTYS OF WATER FOR AT LEAST 15 MIN. SEEK MEDICAL ATTN PROMPTLY. SKIN:BRUSH OFF EXCESS & FLUSH W/WATER FOR 15 MIN. CALL MD. WASH ALL CONTAMD CLTHG BEFORE REUSE. INGEST:IMMED DRIN K LG QTYS OF WATER & ANY COMMON COOKINGOIL. DO NOT INDUCE VOMIT. SEEK MEDICAL ATTN PROMPTLY. INHAL: REMOVE TO FRESH AIR. SUPPORT RESP, IF NEEDED. SEEK MEDICAL ATTN. NOTE:DO NOT GIVE (SUPP DATA) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FIRES CAN ERUPT AND SPREAD RAPIDLY. COOL AFFECTED CONTAINERS WITH LARGE AMOUNTS OF WATER. ================== Accidental Release Measures ================== Spill Release Procedures:USE EXTREME CAUTION. CONTAM WITH ORG/COMBUST MATL MAY CAUSE FIRE/VIOLENT DECOMP. IF FIRE/DECOMP OCCURS IN AREA OF SPILL, IMMED DOUSE WITH PLENTY OF WATER. OTHERWISE, SWEEP ALL VISIBLE MATL USING A CLE AN DRY SHOVEL & BROOM & DISSOLVE MATL IN WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. DO NOT STORE IN DIRECT SUNLIGHT. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. KEEP ORIGINAL CONTAINER. Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT SOURCES. KEEP OUT OF THE REACH OF CHILDREN. AVOID CONTACT WITH ORGANIC MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXCESSIVE DUSTING OCCURS, USE A NIOSH/MSHA APPROVED SCBA. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. Ventilation:PROVIDE ADEQUATE MECHANICAL (GENERAL AND/OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S). Other Protective Equipment:THE USE OF A RUBBER OR VINYL APRON IS RECOMMENDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON OR IF CONVULSIONS ARE OCCURRING. ================== Physical/Chemical Properties ================== HCC:D1 Solubility in Water:COMPLETE Appearance and Odor:FREE FLOWING, WHITE, GRANULAR SOLID WITH CHLORINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MOISTURE, ACIDS, UREA AND ANY FORM OF CONTAMINATION ESPECIALLY COMBUSTIBLE MATERIALS. Stability Condition to Avoid:HIGH TEMPERATURE, POOR VENTILATION, CONTAMINATION, MOISTURE/HIGH HUMIDITY. Hazardous Decomposition Products:CHLORINE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:TRANSPORT TO A PERMITTED HAZARDOUS WASTE FACILITY FOR DISPOSAL ACCORDING TO ALL LOCAL, STATE, AND FEDERAL WASTE DISPOSAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:5800 ULTRA-HIDE LATEX LOW LUSTRE ENAMEL CAGE:01PD6 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 1-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: 1-5% Ingred Name:STYRENE POLYMER, POLYSTYRENE CAS:9003-53-6 RTECS #:WL6475000 Fraction by Wt: 2-7% Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 2-7% Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 16-21% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:VINYL ACRYLIC RESIN CAS:25067-01-0 Fraction by Wt: 16-21% Ingred Name:WATER, H2O CAS:7732-18-5 RTECS #:ZC0110000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY TRACT, DIZZINESS, LIGHTHEADEDNESS, HEADACHE, & NAUSEA. SKIN: IRRITATION, DERMATITIS, & ABSORPTION. EYES: IRRITATION. INGESTION: SERIOUS INJURY. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: IRRITATION OF RESPIRATORY TRACT, DIZZINESS, LIGHTHEADEDNESS, HEADACHE, & NAUSEA. SKIN: DERMATITIS, IRRITATION, & ABSORPTION. EYES: IRRITATION. INGESTION: SERIOUS INJURY. Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS, KIDNEY DISORDERS, LIVER DISORDERS, & NERVOUS SYSTEM DISORDERS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASE S. ===================== Fire Fighting Measures ===================== Flash Point:>200F Extinguishing Media:DRY CHEMICAL OR FOAM Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST WHEN EXPOSED TO EXTREME HEAT OR FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. SPILLS MAY BE COLLECTED W/ABSORBENT MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE <100F. KEEP FROM FREEZING. USE ONLY W/ADEQUATE VENTILATION. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN & EYES. Other Precautions:AVOID BREATHING VAPORS. KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE. IF SANDING IS DONE, WEAR A DUST MASK TO AVOID BREATHING OF SANDING DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS <TLV. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH/MSHA APPROVED RESPIRATORS IN ACCORDANCE W/OSHA STANDARDS. Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST VENTILATION TO PREVENT BUILD-UP OF VAPORS. Other Protective Equipment:SAFETY SHOWER & EYE WASH Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health PRODUCTS IN THIS SERIES CONTAIN ETHYLENE GLYCOL WHEN TINTED W/DRAMATONE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Percent Volatiles by Volume:67.2% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Stability Condition to Avoid:ELEVATED TEMPERATURES, FREEZING Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:POTASSIUM CHROMATE-6870 CAGE:DO880 CAGE:37940 CAGE:DO880 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM CHROMATE(SARA III) CAS:7789-00-6 RTECS #:GB2940000 Fraction by Wt: >99%. OSHA PEL:C,0.1 MG/M3 CRO3 ACGIH TLV:0.5 MG CR/M3; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Effects of Overexposure:CORROSIVE ACTION ON SKIN/MUCOUS MEMBRANES;IRRITATES; INGEST:CAN BE HARMFUL OR FATAL;SYSTEMIC POISON; ======================= First Aid Measures ======================= First Aid:SKIN:WASH W/PLENTY OF WATER W/O DELAY, REMOVE CONTAMINATED CLOTHING; EYES:PROMPTLY FLUSH W/PLENTY OF WATER FOR 15 MIN MINIM. -GET MEDICAL ATTN; INGEST:IF CONSCIOUS-HAVE VICTIM DRINK WATER & INDUCE VOM ITING; GET MED. ATTN. FOR INGEST,INHAL,IRRIT,SORES ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE SELF-CNTD BRTHG APP. IF EXPOSURE TO(CR) DUST/MIST POSIBL Unusual Fire/Explosion Hazard:NONE CITED BY MFGR. ================== Accidental Release Measures ================== Spill Release Procedures:CAREFULLY SWEEP UP & PLACE IN AUTHORIZED CONTAINER; CAUTIOUSLY SPRAY RESIDUE W/PLENTY OF WATER. RECOVER RESULTING SOLUTION FOR PROPER DISPOSAL.// ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE.KEEP CONTAINERS CLOSED. MAINTAIN STRICT HYGIENE FOR CHEM HANDLING. Other Precautions:HEXAVALENT CHROMIUM CANNOT BE DISCHARGED DIRECTLY TO WATERWAYS. DISPOSAL METHOD MAY DEPEND ON REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPRV. HI-EFFICIENCY DUST/MIST RESPIRATOR, AS APPLICABLE. Ventilation:SUFFICIENT TO MAINTAIN CR(VI) CONC. < TLV.; LOCAL/MECHANICAL Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR PROLONGED CONTACT. Supplemental Safety and Health MSDS DATE:FEB. 1980 ================== Physical/Chemical Properties ================== HCC:D2 Boiling Pt:B.P. Text:986C/MELTP. Spec Gravity:2.73 Solubility in Water:>10 % Appearance and Odor:YELLOW CRYSTALS; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID REDUCING AGENTS. Stability Condition to Avoid:SITUATIONS WHERE EXPOSURE TO REDUCING AGENTS MAY OCCUR. Hazardous Decomposition Products:THERMAL DECOMPOSITION: OXIDES OF CHROMIUM ==================== Disposal Considerations ==================== Waste Disposal Methods:ADD MATERIAL SLOWLY TO A LARGE CONTAINER OF WATER. STIR IN SLIGHT EXCESS OF SODA ASH. LET STAND FOR 24 HR. DECANT/SIPHON INTO ANOTHER CONTAINER -NEUTRALIZE W/ 6M-HCL. WASH TO AUTHORIZED DRAIN W/EXCESS WATER.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:GACOFLEX,U-66 PART A CAGE:HO305 CAGE:09463 CAGE:HO305 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 3.6% Other REC Limits:N/K OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 9.5% Other REC Limits:N/K OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DERMATITIS.LONG TERM EXPOSURE TO LOW VAPOR CONCENTRATIONS MAY CAUSE CHRONICALLY PROGRESSIVE PULM DISEASE.RPTD SKIN CONT CAN RESULT IN SENSIT.RPTD EXPOS CAN CAUSE ALLERGIC REACTION W/ DEVELOPMENT OF OC CUPATIONAL ASTHMA.INGEST IS HARMFUL OR FATAL.DATA SHOWS THAT NONE OF THE ING ARE CARCIN,TERATOGENIC OR MUTAGENIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:CONTACT CAUSES SEVERE IRRITATION,REDNESS,TEARING AND BLURRED VISION.SKIN:CONTACT CAN CAUSE SEVERE IRRITATION,POSSIBLE BURNS,DEFATTING AND DERMATITIS.INGESTION:HARMFUL OR FATAL IF SWALLOWED.INHALA TION:INHALATION OF HIGH CONCENTRATIONS CAN PRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH WITH WATER FOR AT LEAST 15 MIN.CALL MD AS SOON AS POSSIBLE.SKIN:WASH WITH SOAP AND WATER & REMOVE CONTAMINATED CLOTHING.INGESTION:SEE MD AS SOON AS POSSIBLE.INHALATION:IF OVERCOME BYVAPORS,REMOVE TO FRESH AIR AND IF BREATHING HAS STOPPED,GIVE ARTIFICIAL RESPIRATION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:60F,15.5C Lower Limits:N/K Upper Limits:1.0% Extinguishing Media:FOAM,CO*2,DRY CHEMICAL OR WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .COOL CONTR W/ H*2O FOG TO PVNT RUPTURE.BOILOVER POSS IF TEMP NEARS SOLV BP.DO NOT EXTING FLAME AT (SEE SUPP) Unusual Fire/Explosion Hazard:GAS/LIQ LEAKS FORM FLAMM MIX AT/OR ABOVE FLASH PT.EXPLO DUE TO MECH IMPACT UNLIKELY BUT FIRE/EXPLO IS POSS FROM STATIC ACCUM & DISCHARGE.HAZ DECOMP PROD:CO,CO*2 ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION.KEEP PEOPLE AWAY.AVOID BREATHING VAPORS.RECOVER FREE LIQUID AND ADD ABSORBENT TO REMAINDER OF SPILL BEFORE COLLECTING WITH NON-SPARKING TOOLS. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR CLSD & STORE IN COOL,DRY PLACE W/ ADEQ EXPLO PROOF VENT.AVOID HEAT,SPARKS AND OPEN FLAME.GROUND EQUIPMENT TO PVNT ACCUM OF STATIC CHARGE. Other Precautions:SOLVENTS MAY BE HARMFUL OR FATAL IF SWALLOWED.VAPOR HARMFUL.MAY CAUSE SKIN OR EYE IRRITATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:EYE BATH & SAFETY SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:N/K Supplemental Safety and Health FIRE FIGHT PROC:LEAK:POSS OF UNCONTROLLED EXPLOSIVE REIGNITION EXISTS.CUT OFF FUEL &/OR ALLOW FIRE TO BURN OUT.EXTING RESIDUAL FIRE W/ CHEM POWDER OR FOAM.SPEC GRAV:1.8 +/- 0.06 (WATER=1).% VOLATILES BY VOL:29 +/- 0.5.PRODUCT TLV:100 PPM (MFR). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:237-288F Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:>1 (AIR=1) Spec Gravity:SEE SUPP DATA Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:N/K Appearance and Odor:N/K Percent Volatiles by Volume:SUP DA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING MATERIALS LIKE LIQUID CHLORINE AND CONCENTRATED OXYGEN. Stability Condition to Avoid:HEAT,SPARKS AND OPEN FLAME. Hazardous Decomposition Products:INCOMPLETE BURNING MAY PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:BLEACH 5 1/4% CAGE:45202 CAGE:45202 ============= Composition/Information on Ingredients ============= Ingred Name:HYPOCHLOROUS ACID, SODIUM SALT; (SODIUM HYPOCHLORITE) (SARA III) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: 5.25% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 1% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL RAT):6200 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO INFORMATION FOUND. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH PLENTY OF SOAP & WATER. EYE:RINSE EYE FIRST, REMOVE CONTACT LENSES (IF APPLICABLE), AND CONTINUE FLUSHING WITH WATER FOR AT LEAST 15 MINUTES. GET MD. INGEST:DRINK LARGE QUANTITIES OF WA TER. DO NOT GIVE VINEGAR OR OTHER ACIDS. DO NOT INDUCE VOMITING. GET MD IMMEDIATELY. INHAL:MOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Extinguishing Media:DOES NOT BURN. Fire Fighting Procedures:DECOMPOSES AT 230F WITH LIBERATION OF HAZARDOUS GASES. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:230F,110C Spec Gravity:1.09 @ 20C Solubility in Water:COMPLETE Appearance and Odor:STRAW YELLOW LIQUID WITH CHARACTERISTIC ODOR OF BLEACH Percent Volatiles by Volume:74.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MIXING WITH OTHER CHEMICALS AND OTHER CONSUMER PRODUCTS MAY CAUSE CHEMICAL RXN WITH LIBERATION OF HAZARDOUS GASES. Stability Condition to Avoid:EXPOSURE TO HEAT AND LIGHT WILL ACCELERATE DECOMPOSITION. Hazardous Decomposition Products:TOXIC GASES GENERATED WHEN HEATED TO DECOMPOSITION OR WHEN REACTED WITH OTHER COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
gloves_mandatory
===================== Product Identification ===================== Product ID:8570GM, SIGHT SAVERS BRAND ANTI-FOG (SUPDAT) CAGE:64804 CAGE:64804 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 12% OSHA PEL:400 PPM ACGIH TLV:400 PPM/500 STEL Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 2% OSHA PEL:S, 100 PPM ACGIH TLV:S,100 PPM/150 STEL Ingred Name:SUPDAT: MD . EYES: IMMED FLUSH W/POTABLE WATER FOR AT LST 15 MINS, SEEK ASSISTANCE FROM MD . RTECS #:9999999ZZ Ingred Name:OTHER PREC: DO NOT USE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE CONT: THIS PROD IS INTENDED TO BE USED PER LBL INSTRUCTIONS. AVOID EYE CONT. IN EVENT OF ACCIDENT EYE CONT FLUSH W/WATER FOR 15 MINS & OBTAIN MED ASSISTANCE. SKIN CONT: THIS PROD IS INTENDE D TO BE USED PER LBL INSTRUCTIONS. DISCONTINUE USE OF SKIN IRRIT DEVELOPS. INGEST: IN EVENT OF INGEST (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: OF PROD/ANY OTHER UNTOWARD EVENTS, CONT POIS CTL CTR/OTHER EMER SERVICE & OBTAIN APPROP MED ATTN. ACCIDENTAL INGEST OF SIGHT SAVERS ANTI-FOG LIQ MAY CAUSE GASTRIC & INTESTINAL IRRIT. INGEST OF LGR QTYS MAY CAUSE NAUS, VOMIT, HDCH, DIZZ, ABDOM PAIN/RELATED GI DISTURB. GIVE FLUIDS & SEEK MED CARE. (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN IRRIT IS NOT EXPECTED. HOWEVER, SHOULD IRRIT DEVELOP DISCONTINUE USE. THIS PROD IS NOT INTENDED TO BE INGEST/TAKEN INTERNALLY. IN EVENT OF INGEST OF CONTENTS/ANY UNTOWARD EVENTS, CONT POIS CTL CT R/OTHER EMER SERVIC & OBTAIN APPROP MEDATTN. REFER TO STATEMENTS IN HLTH HAZARD SECTION. INGEST:CALL MD IMMED . INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:88.0F,31.1C Lower Limits:2.0% Upper Limits:12.7% Extinguishing Media:USE FOAM, CO*2, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AS W/ALL FIRES, EVACUATE PERSONNEL TO SAFE AREA. NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. Unusual Fire/Explosion Hazard:CARBON DIOXIDE AND CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION AND ABSORB WITH VERMICULITE OR OTHER ABSORBENT. USE NIOSH APPRVD RESPIRATORY Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:THIS PRODUCT IS STABLE AND NON-REACTIVE. KEEP AWAY FROM HEAT, SPARKS AND FLAME. Other Precautions:THIS PROD IS INTENDED TO BE USED TO CLEAN LENSES IN PERSONAL ITEMS SUCH AS EYEWARE, FACE SHIELDS. THIS PROD IS NOT INTENDED TO BE INGESTED NOR ADMIN THRU ANY OTHER ROUTES OF EXPOS. IF YOU ARE SENSITIV E TO ANY INGRED IN THIS PROD, (ING 4) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES SHOULD BE USED FOR SPILL CLEANUP. Ventilation:GENERAL ROOM VENTILATION. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NO SPECIAL WORK PRACTICES ARE REQUIRED. Supplemental Safety and Health MFR TRADE NAME/PART NO: LIQUID WITHOUT SILICONE. EFTS OF OVEREXP: INHAL: NORM USE OF THIS PROD WILL NOT PRESENT INHAL HAZ. ACUTE EXPOS TO HIGH CONCS, AS FROM SPILL, MAY RSLT IN UPPER RESP TRACT IRRIT & CNS DEPRESS. MOVE TO FRESH AIR & SEEKMED CARE. FIRST AID PROC: SKIN: FLUSH W/COPIOUS AMTS OF WATER. CALL (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32F,0C Vapor Pres:30 @ 77F Spec Gravity:1.0 pH:7 Evaporation Rate & Reference:<1(I.E. BUTYL ACETATE =1) Solubility in Water:SOLUBLE Appearance and Odor:CLEAR LIQUID. SLIGHT ODOR OF RUBBING ALCOHOL. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PREVENT CONTACT WITH STRONG ACIDS AND BASES, AS WITH WATER. Stability Condition to Avoid:PREVENT CONTACT WITH STRONG ACIDS AND BASES, AS WITH WATER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. THIS PRODUCT DOES NOT MEET THE DEFINITION OF HAZARDOUS WASTE PER 40 CFR, PART 261.11.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:0501 DIESEL PRO-FLO FUEL CONDITIONER CAGE:0TAY6 CAGE:0TAY6 ============= Composition/Information on Ingredients ============= Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA PETROLEUM *98-2* CAS:64742-94-5 RTECS #:WF3100000 Ingred Name:KEROSENE, KEROSINE (SUSP ANIMAL CARC BY IARC) *98-2* CAS:8008-20-6 RTECS #:OA5500000 Other REC Limits:100 MG/CUM NIOSH Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER, DOWANOL DPM, DIPROPYLENE GLYCOL MONOMETHYL ETHER *98-2* CAS:34590-94-8 RTECS #:JM1575000 Other REC Limits:100 PPM OSHA PEL:100 PPM SKIN ACGIH TLV:100 PPM Ingred Name:VOLATILE ORGANIC CONTENT: COMPOUNDS 814.3 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: IRRITATION/DERMATITIS & ABSORPTION. EYES: IRRITATION. INHALATION: ANESTHETIC. IRRITATES RESPIRATORY TRACT. HARMFUL, CAN CAUSE SERIOUS NERVOUS SYSTEM DEPRESSION & DAMAGE TO KIDNEYS, LIVER & LUNGS . INGESTION: HARMFUL/FATAL, CAN CAUSE ABDOMINAL IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DEFATTING, REDNESS, TEARING, BLURRED VISION, NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS W/SEVERE SKIN, LIVER, HEART, LUNG/KIDNEY PROBLEMS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: GIVE 1/2 GLASSES OF WATER. DON'T INDUCE VOMITING UNLESS INSTRUCTED. OBTAINMEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:145F Lower Limits:0.9 Extinguishing Media:FOAM, DRY CHEMICAL, CO2. Fire Fighting Procedures:COOL FIRE EXPOSED CONTAINERS W/WATER SPRAY. WEAR SCBA & AVOID SKIN CONTACT. Unusual Fire/Explosion Hazard:COMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN W/INERT ABSORBENT MATERIAL. DON'T FLUSH LIQUID DOWN DRAIN. PLACE ABSORBED LIQUID IN APPROVED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT & OPEN FLAME. STORE CONTAINERS IN A COOL AREA <120F. DON'T STORE IN DIRECT SUNLIGHT. KEEP LID TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T INCINERATE CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR NOT REQUIRED WHEN USED W/ADEQUATE VENTILATION. Ventilation:LOCAL EXHAUST: NECESSARY. MECHANICAL (GENERAL): ACCEPTABLE. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:380-510F Vapor Pres:0.4 Vapor Density:5.2 Spec Gravity:0.86 Appearance and Odor:LIQUID AMBER COLOR W/AROMATIC ODOR Percent Volatiles by Volume:95.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, PAINTED SURFACES. Stability Condition to Avoid:OPEN FLAMES, HEATED SURFACES. Hazardous Decomposition Products:THERMAL: CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF EMPTY CONTAINERS BY APPROVED LOCAL, STATE & FEDERAL REGULATIONS. UN 1993.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:SODIUM PHOSPHATE,TRIBASIC DODECAHYDRATE,TEC CAGE:DO735 CAGE:60777 CAGE:DO735 CAGE:0AN91 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PHOSPHATE, TRIBASIC(SARA III) CAS:7601-54-9 RTECS #:TC9490000 Fraction by Wt: 100% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE & CHRONIC:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE. CHRONIC:ALTHOUGH NO LONG TERM HUMAN STUDIES HAVE BEEN REPORTED,THERE ARE NO REPORTED CHRONIC EFFECTS THAT WARRANT CONTROL BEYOND THAT REQUIRED TO AVOID IRRITATION FROM AIRBORNE DUST. Effects of Overexposure:EYES:LOCAL IRRITATION & POSSIBLE CONJUNCTIVITIS;SKIN:IRRITATION;INHALATION:IRRITATION OF NOSE & THROAT;INGESTION:MAY INJURE MOUTH,THROAT & GASTROINTESTINAL TRACT.--PRODUCT IS EXTREMELY ALKALINE & MAY REMOVE SEBACEOUS OILS LEAVING SKIN UNPROTECTED & MAY CAUSE CHEMICAL BURNS. Medical Cond Aggravated by Exposure:NONE NOTED. ======================= First Aid Measures ======================= First Aid:EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES.IF IRRITATION PERSISTS,SEE DOCTOR;INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT OR DISCOMFORT PERSISTS,SEE DOCTOR;INGESTION:RINSE MOUTH WITH WATER. GIVE WATER OR MILK.DO NOT INDUCE VOMIT.SEE DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SCBA & CHEMICAL PROTECTIVE SUIT. Unusual Fire/Explosion Hazard:NONE NOTED ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CONTAINER FOR SALVAGE OR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY AREA. Other Precautions:MATERIAL IS STRONGLY BASIC (ALKALINE);TAKE CARE TO AVOID CONTACT WITH LARGE AMOUNTS OF DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR CHEMICAL DUST. Ventilation:MECHANICAL (GENERAL) OR LOCAL EXHAUST Other Protective Equipment:APPROPRIATE CLOTHING TO PREVENT SKIN CONTACT. EYEWASH & SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE & LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>2372F,FZPT Spec Gravity:1.0 (BULK DENS) Solubility in Water:12% Appearance and Odor:WHITE GRANULES OR POWDER. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE NOTED Stability Condition to Avoid:NONE NOTED Hazardous Decomposition Products:NONE NOTED ==================== Disposal Considerations ==================== Waste Disposal Methods:IF MATERIAL CAN NOT BE SALVAGED,A METHOD OF DISPOSAL IS IN A LANDFILL IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,STATE AND LOCAL REGULATIONS.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:IPA 99% CAGE:4W432 CAGE:4W432 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV: 200 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE & SKIN-PRIMARY IRRITATION TO SKIN, DEFATTING, DERMATITIS. PRIMARY IRRITATION TO EYES. LIQUID CAN CAUSE EYE IRRITATION. INHALATION-ANESTHETIC. IRRITATES RESPIRATORY TRACT. ACUTE OVEREXPOSURE CAN CA USE SERIOUS NERVOUS SYSTEM DEPRESSION. VAPOR HARMFUL. SWALLOWING-HRAMFUL OR FATAL IF SWALLOWED. Explanation of Carcinogenicity:THIS PRODUCT HAS NO CARCINOGENS LISTED BY IARC, NTP, NIOSH, OSHA OR ACGIH, AS OF THIS DATE, GREATER OR EQUAL TO 0.1%. Effects of Overexposure:EYES-REDNESS, TERAING, BLURRED VISION. SWALLOWING-CAN CAUSE ABDOMINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS WITH SEVERE SKIN, LIVER OR KIDNEY PROBLEMS SHOULD AVOID USE. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN & GET MEDICAL ATTENTION. SKIN:IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH THOROUGHLY WITH SOAP & WATER. INHALATION:REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYG EN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. SWALLOWING:CALL A PHYSICIAN IMMEDIATELY. INDUCE VOMITING PROMPTLY USING PHYSICIAN'S INSTRUCTIONS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:51.8F,11.0C Autoignition Temp:Autoignition Temp Text:371C Lower Limits:2 Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE OR FOAM) FOR CLASS II LIQUID FIRES. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE ON FIRE BUT CAN PROTECT FIRE-FIGHTERS. USE FOG NOZZLES. USE NIOSH APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTIBLE! KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM OXIDIZERS, HEAT & OPEN FLAMES. CLOSED CONTAINER MAY EXPLODE IF EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILL AT SOURCE. DIKE AREA AND CONTAIN. CLEANUP REMAINDER WITH ABSORBENT MATERIAL. MOP UP AND DISPOSE OF. PERSONS WITHOUT PROPER PROTECTION SHOULD BE KEPT FROM AREA UNTIL CLEANED UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ISOLATE FROM OXIDIZERS, HEAT AND OPEN FLAMES. DO NOT STORE ABOVE 49C/120F. STORE LARGE AMOUNTS IN STRUCTURES MADE FROM OSHA CLASS II LIQUIDS. Other Precautions:KEEP CONTAINER TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE TO PREVENT LEAKAGE. USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING OF VAPOR OR SPRAY MIST. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED POSITIVE PRESSURE SELF- CONTAINED BREATHING APPARATUS. CONSULT SAFETY EQUIPMENT SUPPLIER. USE EXPLOSION PROOF EQUIPMENT. Ventilation:LOCAL EXHAUST-NECESSARY. MECHANICAL (GENERAL)-ACCEPTABLE. Other Protective Equipment:WEAR APRON & FOOT WARE IMPERVIOUS TO THIS MATERIAL. Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. Supplemental Safety and Health EMPTY CONTAINERS VERY HAZARDOUS! ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NONE Boiling Pt:=80.C, 176.F Vapor Pres:33 MMHG Vapor Density:2.1 Spec Gravity:0.787 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, WATER-WHITE, ALCOHOL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES AND PEROXIDES. Stability Condition to Avoid:ISOLATE FROM OXIDIZERS, HEAT, SPARKS, ELECTRICAL EQUIPMENT AND OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE FROM BURNING. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE OR DISPOSE OF OBSERVING LOCAL, STATE AND FEDERAL HEALTH, SAFETY AND POLLUTION LAWS. IF QUESTIONS EXXIST, CONTACT THE APPROPIATE AGENCIES.
1
gloves_mandatory
===================== Product Identification ===================== Product ID:9200000 POLISHERS & FINISHERS CAGE:FO509 CAGE:63735 CAGE:FO509 ============= Composition/Information on Ingredients ============= Ingred Name:QUARTZ, SILICON DIOXIDE CAS:14808-60-7 RTECS #:VV7330000 Other REC Limits:50 UG/CUM OSHA PEL:10 MG/CUM RESP ACGIH TLV:10 MG/CUM DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP TO AVOID SLIPPING. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENTS Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED Ventilation:LOCAL EXHAUST Supplemental Safety and Health ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:0 Solubility in Water:INSOLUBLE Appearance and Odor:GRAY & GREEN COLOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE W/NORMAL WASTE.
0
gloves_not_mandatory
===================== Product Identification ===================== Product ID:ARC 855N BL, PART B Resp. Party Other MSDS Num.:3240B-2 CAGE:71431 CAGE:71431 ============= Composition/Information on Ingredients ============= Ingred Name:BENZYL ALCOHOL; EC# 603-057-00-2, SYMBOL XN, R 20.22 CAS:100-51-6 RTECS #:DN3150000 Minumum % Wt:40. Maxumum % Wt:50. Ingred Name:PHENOL, 4,4'-ISOPROPYLIDENEDI- ; (BISPHENOL A) EC# 604-030-00-0, SYMBOL XL, R 36/37/38-43. CAS:80-05-7 RTECS #:SL6300000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: DIRECT CONTACT WILL CAUSE SEVERE IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES. HIGH VAPOR CONCENTRATIONS CAN CAUSE SEVERE EYE AND RESPIRATORY TRACT IRRITATION, HEADACHE, DIZZINESS, NAUSEA AND POSSIBLY SHORTNESS OF BREATH. CHRONIC: PROLONGED OR REPEATED CONTACT MAY CAUSE ASTHMA, SKIN SENSITIZATION AND OTHER ALLERGIC REACTIONS. Explanation of Carcinogenicity:OTHER INFO: 29 CFR 1910.1200 (HAZARD COMMUNICATION),, THIS PRODUCT CONTAINS NO CARCINOGENS AS LISTED IN NATIONAL TOXICOLOGY PROGRAM (NTP), THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) OR TH E OCCUPATION HEALTH AND SAFETY ADMINISTIONS (OSHA). Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONNEL WITH PRE-EXISTING ALLERGIES, ECZEMA OR SKIN CONDITIONS MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, ADMINISTER ARTIFICIAL RESPIRATION. CONTACT PHYSICIAN. SKIN CONTACT: FLOOD AREA WITH WATER WHILE REMOVING CONTAMINATED CLOTHING. WASH CLOTHING BEFORE REUSE. CONSULT PHYSICIAN. EYE CONTACT: FLUSH FOR AT LEAST 15 MINUTES WITH LARGE AMOUNTS OF WATER. CONSULT PHYSICIAN. INGESTION: IF CONSCIOUS, DO NOT INDUCE VOMITING; DRINK MILK, WATER OR VINEGAR. CONT ACT PHYSICIAN IMMEDIATELY. ADVICE TO PHYSICIAN: TREAT SYMPTOMS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=110.C, 230.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NONE. HAZCHEM EMERGENCY ACTION CODE: 3 ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. PROVIDE ADEQUATE VENTILATION. AVOID SKIN CONTACT. CONTAIN SPILL TO SMALL AREA, PICK UP WITH ABSORBENT MATERIAL (SAND, SAWDUST, CLAY, ETC) AND PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. FLUSH FINAL TRACES OF SPILL WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA. AVOID BREATHING MIST. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH CLOTHING BEFORE REUSE. CONTAMINATED LEATHER INCLUDING SHOES CANNOT BE DECONTAMINATED AND SHOULD BE DISCARD ED. Other Precautions:STRONG IRRITANT TO EYES, SKIN & MUCOUS MEMBRANES. HARMFUL BY INHALATION AND IF SWALLOWED. THE SAFETY AND HEALTH HAZARDS ARE DETAILED SEPARATELY FOR PART A AND PART B. THE FINAL CURED PRODUCT IS CONSID ERED NONHAZARDOUS. UPON MACHINING, IT CAN ONLY BE CATEGORIZED AS NUISANCE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. IF NECESSARY, UTILIZE AN NIOSH APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:NO SPECIAL REQUIREMENTS. IF NECESSARY, PROVIDE ADEQUATE VENTILATION. Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . IMPERVIOUS CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. CONTAMINATED LEATHER INCLUDING SHOES CANNOT BE DECONTMINATED AND SHOULD BE DISCARDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Density:>1 Spec Gravity:0.99 Evaporation Rate & Reference:<1 (ETHER =1) Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER LIQUID WITH AMINE ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND STRONG OXIDIZERS LIKE LIQUID CHLORINE AND CONCENTRATED OXYGEN. Stability Condition to Avoid:OPEN FLAMES AND RED HOT SURFACES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, NO*2, ALDEHYDES AND OTHER TOXIC FUMES. ===================== Ecological Information ===================== Ecological:DETERMINING ENVIRONMENTAL MOBILITY, CONSIDER THE PRODUCT'S PHYSICAL AND CHEMICAL PROPERTIES (SEE PHYSICAL & CHEMICAL PROPERTIES SECTION). ==================== Disposal Considerations ==================== Waste Disposal Methods:COMBINE RESIN AND CURATIVE. THE FINAL CURED MATERIAL IS CONSIDERED NONHAZARDOUS. LANDFILL SEALED CONTAINERS IN AN APPROVED LANDFILL. CHECK LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:TDG: ISOPHORONEDIAMINE SOLUTION, 8, UN2289,III. IMDG: ISOPHORONEDIAMINE SOLUTION CLASS B. UN2288, III. ERG NO. 60 OR 159, EMS NO. 8-06, MFAG NO. 820. A/ICAO: ISOPHORONEDIAMINE SOLUTION, CLASS B, UN228 9, III. DR/RID: 2288 ISOPHORONEDIAMINE, SOLUTION, 8, 53(C), ADR. U.S. DOT: SHIPPING NAME: ISOPHORONEDIAME SOLUTION. HAZARD CLASS: B. UN/NA#: UN2289. PACKAGING GROUP #: III. EMER RESPONSE GUIDE BOOK NO 60 OR 153. NOTE: SHIPPED AS CONSUMER COMMODITY ORM-D IN PACKAGING HAVING A RATED CAPACITY GROSS WEIGHT OF 88 LBS OR LESS (49 CFR 173.154(S). ===================== Regulatory Information ===================== SARA Title III Information:HAZARDS: 313 CHEMICALS: IMMEDIATE. BISPHENOL A 80-05-7, 1-8%. DELAYED. ======================= Other Information =======================
1
gloves_mandatory
===================== Product Identification ===================== Product ID:3,5-DIFLUOROPHENOL, 99% 19757-2 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:3,5-DIFLUOROPHENOL, 99% CAS:2713-34-0 Fraction by Wt: 99% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHAL OR INGEST. CAUSES EYE & SKIN IRRIT. MATL IS IRRIT TO MUC MEMB & UPPER RESP TRACT. DEPENDING ON INTENSITY & DURATION OF EXPOS, EFTS MAY VARY FROM MILD IRRIT TO SEV DESTRU CTION OF TISS. PRLNGD CONT CAN CAUSE: DMG TO EYES, SEV IRRIT/BURNS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR . IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:159F,71C Extinguishing Media:CO*2, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. COMBUSTIBLE. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC AREA. WEAR NIOSH/MSHA APPRVD RESP, CHEM LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER AND HOLD FOR WASTE DISP. VENT AREA & WASH SPILL SITE AFTER MATL PICKUP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING DUST. HARMFUL SOLID OR LIQUID. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT AND OPEN FLAME. STORE IN A COOL DRY PLACE. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. IRRITANT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING AND USING SANITARY FACILITIES . Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F8 Melt/Freeze Pt:M.P/F.P Text:54C TO 57C Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG BASES, ACID CHLORIDES & ACID ANHYDRIDES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CO, CO*2 & HYDROGEN FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE & LOCAL LAWS.
1
gloves_mandatory