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===================== Product Identification ===================== Product ID:PERM REPAIR SETTING LOTION CAGE:DO898 CAGE:DO898 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENT Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:NA ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Lower Limits:ND Upper Limits:ND Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:THIS PRODUCT IS APPROXIMATELY 90% WATER. THE RESIDE WILL CHAR. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN THE SPILL AND RECOVER THE LIQUID. SMALL AMOUNTS CAN BE FLUSHED INTO THE MUNICIPAL SEWAGE SYSTEM. ======================Handling and Storage ====================== Handling and Storage Precautions:STANDARD GOOD HOUSEKEEPING PROCEDURES. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NA Ventilation:NA Other Protective Equipment:NA Work Hygienic Practices:NA Supplemental Safety and Health NA ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:200F,93C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:ND Vapor Density:ND Spec Gravity:1.001 Evaporation Rate & Reference:>1 Solubility in Water:COMPLETE Appearance and Odor:STEEL BLUE LIQUID WITH A MODERATE FLORAL SPICE SMELL. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL OF WASTE AND HAZARDOUS MATERIAL SHALL COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: VS 714 VANDIJK BROWN CML OIL BASE INK 1 LB Cage: 55269 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 55269 ======================================================= Contractor Summary ======================================================= Cage: 09177 Cage: 55269 Cage: EO971 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: EYES/SKIN: IRRITATION. Explanation Of Carcinogenicity: SEE INGREDIENTS Signs And Symptions Of Overexposure: IRRITATION. Medical Cond Aggravated By Exposure: PERSONS W/DERMATITIS. First Aid: EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: WIPE UP. DISPOSE OF WIPES IN APPROVED WASTE CONTAINERS. IF PETROLEUM HYDROCARBON IS USED, PROVIDE SUFFICIENT VENTILATION. Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: AVOID STORAGE IN HOT AREAS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. READ & FOLLOW LABEL PRECAUTIONS. DON'T REUSE CONTAINER. Other Precautions: FOR COMMERCIAL/INDUSTRIAL USE ONLY. KEEP FROM REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: CC Flash Point Text: 250F Extinguishing Media: CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures: USE WATER TO KEEP CONTAINERS COOL. WATER WILL NOT BE EFFECTIVE IN FIGHTING FIRES. Unusual Fire/Explosion Hazard: DENSE SMOKE MAY BE GENERATED WHILE BURNING. ======================================================= Control Measures ======================================================= Respiratory Protection: NOT REQUIRED. Ventilation: GENERAL VENTILATION IS REQUIRED Other Protective Equipment: NONE REQUIRED ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 500-590F Vapor Density: >1 Spec Gravity: >1 Evaporation Rate & Reference: SLOWER THAN BU AC Solubility in Water: INSOLUBLE Appearance and Odor: COLORED PASTE W/OILY ODOR Percent Volatiles by Volume: 10-30 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE Materials To Avoid: NON-REACTIVE MATERIAL Hazardous Decomposition Products: BY FIRE: SMOKE Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: VS 714 VANDIJK BROWN CML OIL BASE INK 1 LB Cage: 55269 Company Name: VAN SON HOLLAND INK CORP Street: 92 UNION STREET Zipcode: 11501-3428 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: EYES/SKIN: IRRITATION. IRRITATION. =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:046 RESIN 6 Preparer's Name:MORTEN DAMGAARD CAGE:GO182 CAGE:5T799 CAGE:GO182 ============= Composition/Information on Ingredients ============= Ingred Name:INERT (NUISANCE) DUST Fraction by Wt: <10% Ingred Name:PHENOL (IARC CARC - GROUP 3) *96-2* CAS:108-95-2 RTECS #:SJ3325000 Fraction by Wt: <1% Other REC Limits:5 MG/CUM OSHA PEL:19 MG/CUM ACGIH TLV:19 MG/CUM (SKIN) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION/EYES: IRRITATION. SKIN: IRRITATION & DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR & AT REST. EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/WATER & SOAP. INGESTION: DON'T INDUCE VOMITING, DILUTE BY DRINKING LARGE AMOUNTS OF FLUIDS. OBTAIN M EDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: TREATMENT IS SYMPTOMATIC & NO ANTIDOTES ARE KNOWN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, DRY CHEMICAL, HALON, ALCOHOL FOAM & CO2. Fire Fighting Procedures:DON'T INHALE GASES, WEAR POSITIVE PRESSURE SCBA APPROVED BY MSHA/NIOSH. Unusual Fire/Explosion Hazard:EXPLOSIVE HAZARD. ORGANIC DUST CAN BE EXPLOSIVE WHEN IDEAL CONDITIONS OF CONCENTRATION & HUMIDITY ARE MET. ================== Accidental Release Measures ================== Spill Release Procedures:TO MINIMIZE DUST, VACUUM CLEANING IS PREFERRED. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAIN MATERIAL & PREVENT ACCUMULATION OF DUST. Other Precautions:EXPOSURE TO HIGH TEMP &/MOISTURE AFFECT PRODUCT PERFORMANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A MSHA/NIOSH APPROVED DUST MASK ISN'T REQUIRED UNLESS TLV'S ARE EXCEEDED. Ventilation:LOCAL EXHAUST Other Protective Equipment:EYE WASH FACILITY. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:SLIGHT Appearance and Odor:GREEN GRANULAR POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HIGH TEMPS, MOISTURE Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DRYDENE SPINDLE OILS ISO GRADES 10,22,32 CAGE:40310 CAGE:40310 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY PARAFFINIC, LUBRICATING OIL BASE STOCK CAS:64741-88-4 RTECS #:PY8040500 Fraction by Wt: >85% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:ADDITIVES Fraction by Wt: <15% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN & EYE IRRITANT. INGESTION: RELATIVELY NON-TOXIC. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: REMOVE CONTAMINATED CLOTHING. PRODUCT IS READILY REMOVED BY WATERLESS HAND CLEANER & WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF AVAILABLE. IF OVER-EXPOSED TO OIL MIST, REMOVE FROM FURTHER EXPOSURE UNTIL EXCESSIVE MIST OIL CONDITION SUBSIDES. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:230-411F Lower Limits:0.9% Upper Limits:7% Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CO2, & VAPORIZING TYPE AGENTS Fire Fighting Procedures:USE WATER/WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL/DISPERSE VAPORS/PROVIDE PROTECTION WHEN ATTEMPTING TO STOP LEAK. USE SUPPLIED AIR BREATHING EQUIPMENT Unusual Fire/Explosion Hazard:EMPTY CONTAINERS RETAIN RESIDUE (LIQUID/VAPOR) & CAN BE DANGEROUS & MAY EXPLODE IF PRESSURIZED, CUT, WELED, BRAZED, SOLDERED, DRILLED OR GRINDED. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER FREE PRODUCT. ADD SAND, EARTH, OR OTHER SUITABLE ABSORBENT MATERIAL TO AREA. OPEN ALL WINDOWS/DOORS. MINIMIZE BREATHING VAPORS/SKIN CONTACT. KEEP PRODUCT OUT OF SEWERS, WATERCOURSES & EXTENSIV E LAND AREAS BY DIKING/IMPOUNDING. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. WASH THOROUGHLY AFTER CONTACT, BEFORE BREAKS & MEALS & AT END OF WORK PERIOD. Other Precautions:DON'T PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION AS THEY MAY EXPLODE & CAUSE INJURY OR DEATH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:AS REQUIRED Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE REUSE; DISCARD IF OIL SOAKED. Supplemental Safety and Health VISCOSITY: 2.61-5.40 @100C. EXPOSURE LIMIT FOR TOTAL PRODUCT: 5 MG/CUM OIL MIST. POUR POINT: -31C/-32C. ================== Physical/Chemical Properties ================== Vapor Pres:NEGLIGIBLE Vapor Density:>1 Spec Gravity: 0.8463-0.8623 Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, LIGHT YELLOW LIQUID W/FAINT PETROLEUM HYDROCARBON ODOR Percent Volatiles by Volume:NEGL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS Stability Condition to Avoid:IGNITION SOURCES Hazardous Decomposition Products:COMPLEX MIXTURE OF AIRBORNE SOLID/LIQUID/PARTICULATES/GASES; FUMES, SMOKE, CO, SULFUR OXIDES, ALDEHYDES & OTHER ORGANICS ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY RETURNED TO A DRUM RECONDITIONER. ALL OTHER CONTAINERS SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER & IN ACCORDANCE W/FE DERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:426-40 NO CHROME CLEANER CAGE:GO138 CAGE:61803 CAGE:GO138 ============= Composition/Information on Ingredients ============= Ingred Name:THIOCYANIC ACID, AMMONIUM SALT, AMMONIUM THIOCYANATE CAS:1762-95-4 RTECS #:XK7875000 Fraction by Wt: 30-35% EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (RAT) LD50: 320 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION & ALLERGIC REACTION. INHALATION: RESPIRATORY IRRITATION. INGESTION: IRRITATION OF MUCOUS MEMBRANES OR DIGESTIVE TRACT. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION & ALLERGIC REACTION. INHALATION: RESPIRATORY IRRITATION. INGESTION: IRRITATION OF MUCOUS MEMBRANES OR DIGESTIVE TRACT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF RUNNING WATER FOR AT LEAST 15 MINS. SKIN: FLUSH AFFECTED AREAS PROMPTLY W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL A TTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:ANY EXTINGUISHING MEDIA APPLICABLE TO SURROUNDING AREA. Fire Fighting Procedures:EVACUATE PERSONNEL TO SAFE AREA. KEEP PERSONNEL REMOVED & UPWIND OF FIRE. WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION EMISSION OF TOXIC FUMES IS POSSIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP. DIKE SPILL. PREVENT LIQUID FROM ENTERING SEWERS/WATERWAYS/LOW AREAS. SOAK UP W/SAND/OIL DRY/OTHER ABSORBENT MATERIAL. SPILL MAY BE NEUTRA LIZED W/POWDERED SODIUM CARBONATE. Neutralizing Agent:POWDERED SODIUM CARBONATE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL VENTILATED AREA. KEEP CONTAINER TIGHTLY CLOSED. DON'T STORE W/INCOMPATIBLE MATERIALS. AVOID CONTACT W/SKIN & EYES. Other Precautions:DON'T STORE OR CONSUME FOOD, DRINK, OR TOBACCO IN AREA WHERE THEY MAY BECOME CONTAMINATED W/THIS MATERIAL. AVOID INHALATION OF MIST. ============= Exposure Controls/Personal Protection ============= Ventilation:SUFFICIENT ROOM VENTILATION Other Protective Equipment:APRONS Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Vapor Pres:AS WATER Vapor Density:AS WATER Spec Gravity:1.143 pH:6.5 Evaporation Rate & Reference:AS WATER Solubility in Water:SOLUBLE Appearance and Odor:BROWN COLOR W/SLIGHT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, OXIDIZERS Hazardous Decomposition Products:OXIDES OF SULFUR, CO, CO2, TOXIC FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID/CONTAMINATED WATER/DISPOSE OF IN APPROVED/PERMITTED TREATMENT SYSTEM. REMOVE NONUSABLE SOLID MATERIAL/CONTAMINATED SOIL FOR DISPOSAL IN APPROVED/PERMITTED LANDFILL. DISCH ARGE TO SEWER REQUIRES APPROVAL/PRETREATMENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ED-410, AIRCRAFT CLEANER Preparer's Name:BOB E. FLYNT CAGE:55208 CAGE:55208 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION:SLIGHT HAZARD, LOW VAPOR PRESSURE. EYE:MODERATE, PAINFUL TO EYES. SKIN:MODERATE, IRRITATES SKIN. SLIGHT SKIN ABSORPTION. Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE CARCINOGENIC. Effects of Overexposure:INHALATION:DIZZINESS, NAUSEA, HEADACHE. SKIN:IRRITATION, DEFATTING, DERMATITIS. NO ABSORPTION EXPECTED AT USE CONCENTRATION. EYE:CORROSIVE, PAIN. Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER FOR 15 MIN. CONSULT PHYSICIAN. SKIN:FLUSH W/WATER FOR 15 MIN. WASH W/SOAP & WATER. INHALATION:REMOVE TO FRESH AIR. INGESTION:CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:ANY SUITABLE MATERIAL Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:RINSE W/WATER. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:MFR GAVE NO INFORMATION OF MSDS. Other Precautions:MFR GAVE NO INFORMATION OF MSDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:100 FT/MIN Other Protective Equipment:RUBBER APRON & BOOTS Work Hygienic Practices:AVOID SKIN CONTACT Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:250F,121C Vapor Pres:10 MM Vapor Density:1 Spec Gravity:1 pH:10 Evaporation Rate & Reference:0.5 (WATER = 1) Solubility in Water:PARTIALLY SOLUBLE Appearance and Odor:AMBER, THIN LIQUID, MILD ODOR Percent Volatiles by Volume:80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:MFR GAVE NO INFORMATION OF MSDS. Conditions to Avoid Polymerization:MFR GAVE NO INFORMATION OF MSDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:AS IS, THE PRODUCT IS NOT CONSIDERED A HAZARDOUS WASTE BY EPA GUIDELINES. CONSULT FEDERAL, STATE & LOCAL REGULATIONS FOR PROPER DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:788410 LACQUER LUSTERLESS HOT SPRAY O.D 340 CAGE:KO010 CAGE:KO010 CAGE:61190 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTYL ACETATE RTECS #:NP9100000 Fraction by Wt: 25% ACGIH TLV:150 PPM Ingred Name:NORMAL BUTYL ALCOHOL RTECS #:EO1575000 Fraction by Wt: 8% ACGIH TLV:50 PPM Ingred Name:ISOBUTYL ALCOHOL (SARA III) CAS:78-83-1 RTECS #:NP9625000 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLBENZENE RTECS #:KS5600000 Fraction by Wt: 8% ACGIH TLV:100 PPM Ingred Name:ALIPHATIC NAPHTHA*SHOWN AS NAPHTHA ALIPHATIC Fraction by Wt: 8% ACGIH TLV:200 PPM ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:ANEST,IRRIT OF RESPIR TRACT OR ACUT NERV SYS DEPRESN,HDACH,DIZZ,CONFUS,UNCONSCIOUS, COMA. ======================= First Aid Measures ======================= First Aid:IN CASE OF CONTCT,FLUSH SKN & EYES W/PLENTY OF WATER WHILE REMOVING CONTAMINATED CLOTHING.IF INHALATED, REMOV TO FRESH AIR. CALL A PHYSICIAN IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Flash Point:13F TCC -11C Lower Limits:.90 Extinguishing Media:USE FIRE EXTING(CO*2,DRY CHEM OR ALCOH FOAM)LO FIRE-POLYMER Fire Fighting Procedures:SELF-CONTAINED BREATH APPARATUS SHLD BE AVAIL F/FIREMEN. Unusual Fire/Explosion Hazard:KEEP CONTNRS THGTLY CLOS.ISOLAT FR HEAT,ELECTR EQPMT,SPARKS & OPEN FLAME.CLOS CONTNRS MAY EXPLO. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION(FLAMES,HOT SURFACES, & ELECTRICAL,STATIC OR FRICTIONAL SPARKS).AVOID BREATHING VAPORS.VENTILATE AREA.REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F .STORE LG QUANITITES IN BLDG DESIGNED TO COMPLY W/OSHA 1910.106. Other Precautions:CONTNRS GROUNDED WHEN POURNG.AVD FRE FALL OF LIQD IN EXCES OF FEW INCHES.DON'T FLAM CUT,BRAZE OR WELD COATED MATRL W/O BUR OF MINES APPRVD RESPIRATOR OR APPROP VENT,ADD LABL WARN "DO NOT TAKE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR/OPEN AREA,USE BUR OF MINES APPRVD MECH FILTR RESPIRATOR. Ventilation:PROVD GEN DILUT OR LOC EXHAUST VENT IN VOL TO KP BELOW TLV. Other Protective Equipment:PRVNT PROLNG SKIN CONTACT TO CONTAMINATED CLOTHING. Supplemental Safety and Health UNUS.FIRE & EXPLOS:WHEN EXPOSED TO EXTREME HEAT.DO NOT APPLY TO VERY HOT SURFACES. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:175-290F Vapor Density:HEAV Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:AVOID FIRES,HEAT & HOT SURFACES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOC,STATE & FEDERAL REGULATIONS.INCINERATE IN APPRVD FACILITY.DO NOT INCINERATE CLOSED CONTAINER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PT-207 30% CAGE:06341 CAGE:06341 ============= Composition/Information on Ingredients ============= Ingred Name:POLYVINYL FLUORIDE RTECS #:KW2680000 Fraction by Wt: 30.0% Ingred Name:KETONES (MEK & MIBK) Fraction by Wt: 56.0% ACGIH TLV:50 PPM (MIBK) Ingred Name:AROMATIC HYDROCARBONS Fraction by Wt: 14.0% ACGIH TLV:200 PPM ===================== Hazards Identification ===================== Effects of Overexposure:HEADACHE, NAUSEA, MODERATELY IRRITATING TO EYES & SKIN. ======================= First Aid Measures ======================= First Aid:REMOVE VICTIM FROM VAPORS-RESTORE BREATHING IF NECESSARY. REMOVE FROM SKIN WITH SOAP & WATER. FLUSH EYES WITH PLENTY OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:82F TCC Lower Limits:1.1. Extinguishing Media:CO*2, FOAM OR DRY CHEMICAL Fire Fighting Procedures:DO NOT USE DRY WATER Unusual Fire/Explosion Hazard:VAPOR MAY FORM EXPLOSIVE MIXTURE BETWEEN UPPER & LOWER EXPLOSIVE LIMITS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. APPLY SWEEPING COMPOUND OR OTHER ABSORBENT MATERIAL-KEEP MATERIAL FROM SPREADING. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID OPEN FLAMES & SPARK SOURCES. AVOID SPLASH FILLING. STORE IN SEALED CONTAINERS. STORE IN COOL AREA. Other Precautions:DO NOT TAKE INTERNALLY-AVOID PROLONGED CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR CONFINED AREA USE BUREAU OF MINES RESPIRATORY DEVICE. Ventilation:LOCAL EXHAUST IS PREFERRED. Other Protective Equipment:BM2304 FACE PIECE,BM2304 CARTRIDGE, BM-13&12 FILTERS,CLPS Supplemental Safety and Health THIS FORMULATION DISCONTINUED JAN 1985. SEE PNI B FOR CURRENT FORMULATION. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:225-300F ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:PUT IN APPROVED STORAGE CONTAINER & SHIP TO AN APPROVED STORAGE AREA OR INCINERATE IN A FURNACE UNDER APPROVED CONTROLLED PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPK 615 RESIN Kit Part:Y CAGE:57294 CAGE:1JB33 CAGE:57294 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA GEL; (AMORPHOUS SILICA) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 1-5% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 30-60% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9495 Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER; (EPOXY RESIN) CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: 30-60% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OXIRANE, ((2-PROPENYLOXY)))-; (ALLYLOXY-2,3-EPOXY PROPANE) CAS:106-92-3 RTECS #:RR0875000 Fraction by Wt: 0.995% OSHA PEL:C 10 PPM ACGIH TLV:5 PPM/10 STEL; 9495 Ingred Name:SUPDAT:DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RTECS #:9999999ZZ Ingred Name:EXPLAN OF CARCIN:ANTICIPATED TO BE CARCINOGEN. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:PROD MAY CAUSE SKIN SENSITIZATION. CONTACT W/PROD AT ELEVATED TEMP CAN RSLT IN THERMAL BURNS. (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:INHAL:BECAUSE OF ITS LOW VOLATILITY, THIS PROD IS NOT LIKELY TO BE AN INHAL HAZ. INGEST:BASED ON SIMILAR (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:PRODUCT TESTING PRODUCT IS PRESUMED TO HAVE A LOW ORDER OF ACUTE ORAL TOX. SIGNS & SYMPTOMS: IRRIT AS (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:NOTED. SKIN SENSITIZATION (ALLERGY) MAY BE EVIDENCED BY RASHES, EXPECIALLY HIVES. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHAL:PRLNG OVEREXP TO FREE SILICA DUST, (UNCOMBINED DIOXIDE) ABOVE TLV SPECIFIED ABOVE MAY CAUSE SCARRING OF LUNGS W/COUGH & SHORTNESS OF BRTH. A DELAYED LUNG INJURY, SILICOSIS, MAY RSLT FROM BRTHG F REE SILICA. SILICOSIS IS FORM OF DISABLING PROGRESSIVE & SOMETIMES FATAL PULM FIBROSIS CHARACTERIZED (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONO, VOL 68, 1997:GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: (ING 6) Effects of Overexposure:HLTH HAZ:BY THE PRESENCE OF TYPICAL MODULATION IN THE LUNGS. EYES:BASED ON SIMILAR PROD TESTING, PROD MAY BE MODERATELY IRRIT TO THE EYES. CNTCT W/PROD AT ELEVEATED TEMP CAN RSLT IN THERMAL BURNS. SKI N CNTCT:BASED ON SIMILAR PROD TESTING, PROD MAY BE MODERATELY IRRIT TO THE SKIN. BASED ON SIMILAR PROD TESTING, (ING 7) Medical Cond Aggravated by Exposure:PREEXISTING SKIN & EYE DISORDERS MAY BE AGGRAVATED BY EXP TO THIS PRODUCT. PREEXISTING SKIN/LUNG ALLERGIES MAY INCREASES THE CHANCE OF DEVELOPMENT INCREASED ALLERGY SYMPS FROM EXPOS TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH EYES W/PLENTY OF H*2O FOR AT LEAST 30 MIN WHILE HOLDING EYELIDS OPEN. GET PROMPT MED ATTN. SKIN:REMOVE CONTAMD CLTHG & WASH CNTCT AREA W/SOAP & H*2O FOR 15 MIN. PARTICULAR ATTN SHOULD BE PA ID TO EAR, NOSE, HAIR, & OTHER AREAS NOT EASILY CLEANED. GET MED ATTN. DESTROY CONTAMD LEATHER GOODS. EFTS CAN BE DELAYED FOR 24-48 HRS. CLEAN CLTHG BEFORE REUSE. INHAL:IN CASE OF EXPOSURE (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:480F,249C Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL, OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CLEANUP AND DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE W/ADEQUATE VENT. KEEP AWAY FROM OPEN FLAMES & HIGH TEMPERATURES. HANDLE I/A/W/HAZARD POTENTIAL OF CURING AGENT(S) USED. Other Precautions:MAY CAUSE IRRITATION. AVOID EYE AND SKIN CONTACT. STORE IN COOL, DRY PLACE W/ADEQUATE VENT. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMP. HANDLE I/A/W/HAZARD POTENTIAL OF CURING AGENT(S) USED. MAY CAUSE I RRITATION. AVOID EYE AND SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT ORDINARILY REQUIRED. IF RESIN IS WARMED OR HEATED, VAPORS OR MISTS MAY BE PRODUCED. IN SUCH CASES, USE NIOSH-APPROVED RESPIRATOR FOR ORGANIC VAPORS. Ventilation:LOCAL EXHAUST RECOMMENDED, MECHANICAL ACCEPTABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health CNDTNS (STAB):CONSIDERABLE HEAT IS RELEASED. FIRST AID PROC:TO HIGH CONC OF VAP/MIST, REMOVE PERS TO FRESH AIR. IF BRTHG HAS STOPPED, ADMIN ARTF RESP & SEEK MED ATTN. KEEP PERS WARM & RESTING. INGEST: IF APPRECIABLE QTIES ARE SWALLOWED, CALL A MD/POISON CONTROL CENTER. DRINK ONE OR TWO GLASSES OF WATER. (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>500F,>260C Vapor Pres:NIL Spec Gravity:1.57 Solubility in Water:INSOLUBLE Appearance and Odor:BLUE, HIGH-VISCOSITY; MILD ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, AMINES, MERCAPTANS, BASES. Stability Condition to Avoid:CAN REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS & STONG LEWIS/MINERAL ACIDS. IN RXNS W/MANY CURING AGENTS (SUPDAT) Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES & ACIDS MAY BE FORMED DURING COMBUST. RXN W/SOME CURING AGENTS MAY PRDCE CONSIDERABLE HEAT. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P29-210 VMK 68N PAINT ON OPAQUE, 250 GRAMS CAGE:67251 CAGE:67251 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN CARCINOGEN BY IARC, NTP & ACGIH) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <5% OSHA PEL:1 MG/CUM ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: <5% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/METAL OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT/IRON CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <5% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:NICKEL (SOLUBLE) INTENDED CHANGE (IC) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <5% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC (A1) Ingred Name:VANADIUM CAS:1314-62-1 RTECS #:YW1355000 Fraction by Wt: <5% OSHA PEL:C,0.5 MG/M3 ACGIH TLV:0.05 MG/M3RDUST;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: <5% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 Fraction by Wt: <5% OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:BARIUM (SOLUBLE COMPOUNDS) CAS:7440-39-3 RTECS #:CQ8370000 Fraction by Wt: <5% OSHA PEL:0.5 MG/CUM ACGIH TLV:0.5 MG/CUM Ingred Name:BORON OXIDE, TRIOXIDE CAS:1303-86-2 RTECS #:ED7900000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:CALCIUM OXIDE; LIME CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: <5% OSHA PEL:5 MG/CUM ACGIH TLV:2 MG/CUM Ingred Name:MAGNESIUM OXIDE, MAGNESIA CAS:1309-48-4 RTECS #:OM3850000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3;TDUST; 9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: <5% Other REC Limits:30 MG/CUM TOTAL DUST OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:TIN (AS SN) CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: <5% OSHA PEL:2.0 MG/CUM ACGIH TLV:2.0 MG/CUM Ingred Name:TITANIUM DIOXIDE, TITANIUM(IV) OXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Explanation of Carcinogenicity:CHROMIUM IS A SUSPECTED A1 HUMAN CARCINOGEN BY ACGIH. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLED MATERIAL. ======================Handling and Storage ====================== Other Precautions:AVOID BREATHING CERAMIC DUST. AVOID LICKING CERAMIC APPLICATION BRUSH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NUISANCE DUST MASK RECOMMENDED WHILE GRINDING FIRED PORCELAIN. Ventilation:MECHANICAL EXHAUST Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>2192F Melt/Freeze Pt:M.P/F.P Text:1760F Evaporation Rate & Reference:0 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE OR LIGHT PASTEL COLORED PORCELAIN POWDER W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS SOLID WASTE IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIGHT GREEN LUSTERLESS ENAMEL, PM-6H66 CAGE:84249 CAGE:84249 ============= Composition/Information on Ingredients ============= Ingred Name:ING 7:OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURRED. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:DEPOSITED IN LANDFILL I/A/W LOCAL, STATE & FEDERAL REGULATIONS. RTECS #:9999999ZZ Ingred Name:RESP PROT:BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-10% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOBUTYL ACETATE (SARA III) CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 5-10% OSHA PEL:150 PPM ACGIH TLV:150 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ALIPHATIC PETROLEUM DISTILLATE CAS:64742-89-8 Fraction by Wt: 20-40% OSHA PEL:500 PPM (MFR) ACGIH TLV:300 PPM (MFR) Ingred Name:SUPP DATA:SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PVNT SPREADING(SEE ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:& PUMP LIQ TO SALVAGE TANK. REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB, OR OTHER (SEE ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:ABSORB MATL & SHOVELED INTO CNTNRS. PVNT RUN-OFF TO SEWERS, STREAMS OR BODIES OF WATER. IF RUN-OFF (SEE ING 8) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, OR BLURRED VISION. SKIN:PRLNGD/RPTD CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING OR DERMATITIS. INHAL:EXCESSIVE INHALATION OF VAPORS CAN CAUSE NA SAL & RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCON, (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:& EVEN ASPHYXIATION. INGEST:CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, OR DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:THORO WASH EXPOSED AREA W/SOAP/WATER. REMOVE CONTAMD CLTHG.WASH CONTAMD CLTHG BEFORE RE-USE. EYE:FLUSH W/LG AMTS OF WATER FOR AT LEAST 15 MIN,LIFTING LIDS OCCSNLY.GET MD. INGEST:GIVE 2 GLASSES OF WATER. INDUCE VOMIT IMMED BY STICKING FINGERS DOWN THROAT.CALL MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. INHAL:REMOVE TO FRESH AIR. IF BRTHG STOPPED, GIVE ARTF RESP. KEEP WARM/QUIET. GET MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:45.0F,7.2C Lower Limits:0 Upper Limits:10.50% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VAPS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG GROUND OR MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELEC (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:SML:ABSORB LIQ ON PAPER, FLOOR ABSORB, OR OTHER ABSORB MATL & TRANSFER TO HOOD. ELIMINATE ALL SOURCES OF IGNIT SUCH AS FLARES, FLAMES (INCLDG PILOT LIGHTS) & ELEC SPARKS. LG:ELIMINATE ALL IGNIT SOURCE S (FLARES,FLAMES, INCLDG PILOT LIGHTS, (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. CONTAINERS MAY BE HAZARDOUS WHEN EMPTY. Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID &/OR SOLIDS), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV OF PROD OR ANY COMPONENT IS EXCEEDED, A NIOSH/MSHA APPRVD AIR-SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT OTHER RESP UNDER SPECIFIED CONDS. ENGINE ERING/ADMIN CONTROLS SHOULD (SEE ING 10) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S. Other Protective Equipment:WEAR IMPERVIOUS CLOTHING & BOOTS. USE BARRIER CREAMS & TAKE DAILY SHOWERS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:MOTORS, STATIC DISCHARGE OR OTHER IGNIT SOURCES AT LOCATIONS DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGN ITE EXPLOSIVELY. SPILL PROC:ELEC SPARKS). PERSONS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF (SEE ING 5) ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:232F,111C Vapor Pres:22 Vapor Density:HVR/AIR Spec Gravity:1.157 Evaporation Rate & Reference:1.63 (BUTYL ACETATE=1) Solubility in Water:NONE Appearance and Odor:POURABLE LIQUID. Percent Volatiles by Volume:64.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:SML:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD. ALLOW SUFFICIENT TIME FOR VAPS TO COMPLETLY CLEAR HOOD DUCT WORK. DISPOSE OF REMAINING MATL I/A/W APPLICABLE REGS. LG:DESTROY BY LIQ INCINERATION W/OFF -GASS SCRUBBER. CONTAMD ABSORB MAY BE (SEE ING 9)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OMNI GROUT SANDED, 1490 CAGE:IO174 CAGE:IO174 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA SAND, CRYSTALLINE) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT) CAS:65997-15-1 RTECS #:VV8770000 OSHA PEL:50 MPPCF ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM (II) SULFATE, DIHYDRATE (1:1:2); (GYPSUM) CAS:10101-41-4 RTECS #:EW4150000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:GYPSUM CAS:13997-24-5 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM HYDROXIDE; (LIME) CAS:1305-62-0 RTECS #:EW2800000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3 Ingred Name:LIME (HYDRATED) CAS:39445-23-3 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CALCIUM CARBONATE; (PULVERIZED LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:IRON (III) OXIDE (PIGMENTS) CAS:1309-37-1 RTECS #:NO7400000 OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG(FE)/M3 FUME, B2 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: PROD BECOMES ALKALINE WHEN EXPOSED TO MOISTURE. EXPOS CAN DRY SKIN, CAUSE ALKALI BURNS & AFFECT MUC MEMB. DUST CAN IRRITATE EYES & UPPER RESP SYS. TOX EFTS NOTED IN ANIMALS INCL ALVEOLAR DMG W/ PULM EDEMA. CHRONIC: DUST CAN CAUSE INFLAMM OF LINING TISS OF INTERIOR OF NOSE & INFLAMM OF CORNEA. (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. HUMAN: LUNG. Effects of Overexposure:HLTH HAZ: HYPERSENSITIVE INDIVIDUALS MAY DEVELOP AN ALLERGIC DERM. RESPIRABLE CRYSTALLINE SILICA (QUARTZ) CAN CAUSE SILICOSIS, A FIBROSIS (SCARRING) OF LUNGS. SIGNS & SYMPS OF EXPOS: SYMPS OF EXCESS E XPOS TO DUST INCL SHORTNESS OF BREATH &REDUCED PULM FUNC. EXCESS EXPOS TO SKIN & EYES, ESP WHEN MIXED W/WATER, CAN CAUSE CAUSTIC BURNS AS SEV AS THIRD DEGREE. Medical Cond Aggravated by Exposure:PERS W/SENSITIVE SKIN & W/PULM &/RESP DISEASE, INCL, BUT NOT LIMITED TO, ASTHMA & BRONCH, OR SUBJECT TO EYE IRRIT, SHOULD BE PRECLUDED FROM EXPOS. EXPOS TO CRYSTALLINE SILICA/SILICOSIS IS (SUP DAT) ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE (FLOOD) IMMEDIATELY & REPEATEDLY W/CLEAN WATER FOR AT LEAST 15 MINUTES. SKIN: WASH EXPOSED AREAS W/SOAP & WATER. IF IRRITATION/INFLAMMATION OCCURS, SEEK PROMPT MEDICAL ATTENTION. INHALT ION: FOR GROSS INHALATION, REMOVE PERSON IMMEDIATELY TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION AS NEEDED. GET PROMPT MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NON-COMBUSTIBLE AND NOT EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, USE DUSTLESS METHODS (VACUUM) AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL OR USE IF NOT CONTAMINATED OR WET. USE ADEQUATE VENTILATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS MUST BE OBSERVED BECAUSE BURNS OCCUR WITH LITTLE WARNING - LITTLE HEAT IS SENSED. Other Precautions:CUSTOMERS-USERS MUST COMPLY WITH ALL APPLICABLE HEALTH AND SAFETY LAWS, REGULATIONS, AND ORDERS COVERING SILICA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN DUSTY ENVIRONMENTS, THE USE OF A NIOSH APPROVED RESPIRATOR IS RECOMMENDED. Ventilation:LOCAL EXHAUST CAN BE USED, IF NECESSARY, TO CONTROL AIRBORNE DUST LEVELS. . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE SHOWER . USE BARRIER CREAMS, BOOTS & CLTHG TO PROTECT SKIN FROM CONT. Work Hygienic Practices:FOLLOWING WORK, WORKERS SHOULD SHOWER WITH SOAP AND WATER. Supplemental Safety and Health APPEAR/ODOR: QUIKRETE VINYL CONCRETE PATCHER AVAIL IN WHITE). MED CNDTNS: ASSOC W/INCRD INCIDENCE OF SCLERODERMA, TUBERCULOSIS & POSS INCRD INCIDENCE OF KIDNEY LESIONS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>2700F,>148 Melt/Freeze Pt:M.P/F.P Text:>2700F,>148 Vapor Pres:NONE Vapor Density:NONE Spec Gravity:2.6-3.15 Evaporation Rate & Reference:NONE Solubility in Water:SLIGHT Appearance and Odor:GRAY TO GRAY-BROWN COLORED POWDER; SOME PRODS CONTAIN COARSE AGGREGATE (SUP DAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONT OF SILICA W/POWERFUL OXIDIZING AGENTS SUCH AS FLUORINE, CHLORINE TRIFLUORIDE, MANGANESE TRIOXIDE, OXYGEN DIFLUORIDE, MAY CAUSE FIRES. Stability Condition to Avoid:KEEP DRY UNTIL USED TO PRESERVE PRODUCT UTILITY. Hazardous Decomposition Products:SILICA WILL DISSOLVE IN HYDROFLUORIC ACID AND PRODUCE A CORROSIVE GAS-SILICON TETRAFLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE TREATED AS A COMMON WASTE FOR DISPOSAL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2G7401 FLEXLITE HARDENER Kit Part:Y CAGE:PERRY CAGE:PERRY ============= Composition/Information on Ingredients ============= Ingred Name:TRIETHYLENETETRAMINE CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: 5-20% Ingred Name:WEIGHT PER GALLON IN POUNDS: 8.5 LBS RTECS #:9999999WG Ingred Name:CYCLOALIPHATIC AMINE Fraction by Wt: >75% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: BURNS. SKIN: ABSORBTION, BURNS, SENSITIZATION, ALLERGIC REACTIONS. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:SKIN OR RESPIRATORY SENSITIVITIES. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. INGESTION: CALL PHYSICIAN IMMEDIATELY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2 Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS, FULL PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL. ABSORB W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED & UPRIGHT. STORE W/ADEQUATE VENTILATION. Other Precautions:AVOID EYE/SKIN CONTACT. DON'T TAKE INTERNALLY. FOR INDUSTRY USE ONLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR OR AIR-LINE RESPIRATOR IN CONFINED SPACES Ventilation:LOCAL EXHAUST: PREFERRED. MECHANICAL: GENERAL DILUTION. Other Protective Equipment:EYE & BATH SHOWER Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & DESTROY/DECONTAMINATE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health LIQUID DENSITY: HEAVIER THAN WATER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:401-531F Vapor Density:>1 Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE Appearance and Odor:CLEAR VISCOUS LIQUID Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, MINERAL ACIDS, STRONG LEWIS ACIDS, UNCONTROLLED REACTIONS W/EPOXY RESINS Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. UN 1760, CORROSIVE MATERIAL.
1
eyes_protection_mandatory
======================================================= Product ID: PAINTER'S ACRYLIC LATEX CAULK, 10011 Cage: 90300 Box: 277 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 90300 Box: 277 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE EYE, NOSE AND THROAT IRRITATION. CHRONIC: PROLONGED CONTACT WITH SKIN MAY CAUSE IRRITATION. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONTACT MD IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. CONTACT MD IMMEDIATELY. INGESTION: DO NOT INDU CE VOMITING. CONTACT MD OR REGIONAL POISON CONTROL CENTER IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL AND PLACE INTO CONTAINERS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL STANDARDS. THIS PRODUCT DOES NOT MEET THE DEFINITION OF A HAZARDOUS WASTE ACCORDING TO U.S. EPA HAZARDOUS WASTE MANAGEMENT REGULATIONS, 40 CFR SECTION 261. Handling And Storage Precautions: STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM EXCESSIVE HEAT & FREEZING. Other Precautions: KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: >200F,>93C Extinguishing Media: FOAM, WATER, DRY CHEMICALS. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). USE WATER SPRAY TO COOL EXPOSED SURFACES. Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NORMAL ROOM VENTILATION. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.62 Solubility in Water: SOLUBLE Appearance and Odor: WHITE PASTE WITH A MILD ODOR. Percent Volatiles by Volume: 32 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT. Materials To Avoid: STRONG OXIDIZERS AND CAUSTICS. Hazardous Decomposition Products: NORMAL COMBUSTION PRODUCTS, I.E. CO*X, NO*X. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: PAINTER'S ACRYLIC LATEX CAULK, 10011 Cage: 90300 Company Name: DAP INC. PO Box: 277 Zipcode: 45401-0277 Label Required IND: Y Date Of Label Review: 05/25/1995 Status Code: C Label Date: 05/25/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: MAY CAUSE EYE, NOSE AND THROAT IRRITATION. CHRONIC: PROLONGED CONTACT WITH SKIN MAY CAUSE IRRITATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:225 LIQUITEX ARTIST ACRYLIC COLORS IN TUBES & JARS Preparer's Name:PHILLIP E MOLL CAGE:EO269 CAGE:85419 CAGE:EO269 ============= Composition/Information on Ingredients ============= Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Ingred Name:2-AMINO-2-METHYL-1-PROPANOL CAS:124-68-5 RTECS #:UA5950000 Ingred Name:VOLATILE ORGANIC COMPOUNDS: COATING LESS WATER 1-1.5 LB/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WIPE OFF EXCESS & FLUSH W/WARM WATER & SOAP. INHALATION: REMOVE TO FRESH AIR & TREAT SYMPTOMATICALLY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>250F Lower Limits:NONE Upper Limits:NONE Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP FOR USE/DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE NEAR EXTREME HEAT. USE W/ADEQUATE VENTILATION. Other Precautions:DON'T INHALE DUST/SPRAY FROM AIRBRUSH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH CERTIFIED RESPIRATOR FOR LARGE QUANTITIES OF PAINT, AIRBRUSHING & SANDING DRIED PRODUCT. Ventilation:ADEQUATE TO CONTROL FUMES, VAPOR & DUST CONCENTRATIONS. Other Protective Equipment:PROTECTIVE CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Melt/Freeze Pt:M.P/F.P Text:<32F Vapor Pres:17-20 Vapor Density:>1 Spec Gravity:1.1-1.6 Evaporation Rate & Reference:(BU AC = 1): <1 Solubility in Water:DISPERSES Appearance and Odor:VISCOUS COLORED LIQUID W/SLIGHT ACRYLATE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLANKET WASH, GT-6007 CAGE:0FSZ3 CAGE:0FSZ3 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (90 SOLVENT) CAS:64742-88-7 Fraction by Wt: 100% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:VOLATILE ORGANIC COMPOUNDS: 100%; 6.43 LBS/GAL. RTECS #:9999999VO ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:IRRITATION. SKIN:REDNESS, DEFATTING, DERMATITIS. INHALATION:HEADACHE, DIZZINESS, NAUSEA. INGESTION:HEADACHE, DIZZINESS, NAUSEA, VOMITING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY AILMENTS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO AIR FREE OF VAPS, SUPPORT/RESTORE BRTHG. EYES:FLUSH W/WATER FOR AT LST 15 MINS. SKIN:REMOVE CONTAM CLOTHES/SHOES. WASH AFFECTED AREA W/SOAP & WATER. DO NOT RE-USE CONTAM ARTICLES. INGE ST:DO NOT INDUCE VOMIT. SEEK MED ATTN. NOTE TO MD:DEPENDING ON AMT INGESTED & RETAINED, GASTRIC LAVAGE SHOULD BE CONSIDERED. KEEP PATIENT'S HEAD BELOW HIPS TO PVNT PULM ASPIR. "DO NOT INDUCE VOMIT!" ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:104F,40C Lower Limits:1% Upper Limits:7% Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . DO NOT USE A DIRECT STREAM OF WATER ON POOL FIRES. PROD WILL FLOAT & CAN BE RE-IGNITED ON SURF OF WATER. Unusual Fire/Explosion Hazard:KEEP CONTAINERS COOL W/WATER. PRESSURE BUILDUP COULD RESULT IN CONTAINER RUPTURE. VAPOR HEAVIER THAN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:FOR ALL SPILLS:REMOVE ALL SOURCES OF IGNIT INCL SMOKING MATLS, VENTILATE WELL FLUSHED SPILLED MATL INTO SUITABLE RETAINING AREAS/CNTNRS W/LG QTYS OF WATER. SMALL SPILLS CAN BE ABSORBED W/APPROPRIATE N ON-COMBUSTIBLE ABSORBANT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP PRODUCT CONTAINERS COOL, DRY & AWAY FROM SOURCES OF IGNITION. USE & STORE W/ADEQUATE VENTILATION IN PROPERLY LABELED, CLOSED CONTAINERS. Other Precautions:PERSONNEL SHOULD AVOID INHALATION OF VAPORS & SKIN CONTACT. DO NOT TAKE INTERNALLY. DISPOSAL CONTAINERS MUST BE SEALED TIGHTLY & PROPERLY LABELED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN LARGE QUANTITIES: NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREA. WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>316F,>158C Vapor Pres:7.5 @ 100F Vapor Density:4.7 Spec Gravity:0.77 (H*2O=1) Evaporation Rate & Reference:0.15 (BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT COLORED LIQUID; CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES UNKNOWN AT THIS TIME. Stability Condition to Avoid:HEAT, HOT SURFACES & ALL SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE & UNIDENTIFIED ORGANICS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT FLUSH INTO SEWERS OR WATER COURSES. DISPOSE OF I/A/W LOCAL, COUNTY, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 9100 FLAT WHITE, LIFEMASTER 2000 INTERIOR (SUP DAT) Cage: IO491 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 01PD6 Cage: IO491 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO COUGHING, SNEEZING, RESPIRATORY PROBLEMS, PNEUMOCONIOSIS. SKIN: IRRITATION. EYES: IRRITATION. PROLONGED OR REPEATED CONTACT CAN CAUSE TEARING. INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS. First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. REMOVE TO FRESH AIR IMMED IF INHAL CAUSES E YE WATERING, HDCH, DIZZ/OTHER DISCOMFORT. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG. IF IRRIT OCCURS, CONSULT MD. EYES: FLUSH IMMED W/LGE AMTS OF WATER, ESP (SUP DAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. VENTILATE AREA. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: STORE <100F. KEEP FROM FREEZING. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN & EYES. Other Precautions: AVOID BRTHG OF VAPS. KEEP CONTRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING (SANDING) PAINTED SURFS. IF SUCH CNDTNS CANNOT BE AVOIDED, USE APPROP NIOSH (SUP DAT) ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Extinguishing Media: DRY CHEMICAL OR FOAM. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY BURST IF EXPOSED TO HEAT OR FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). APRON. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). TRADE NAME/PART #: FLAT LM 9100 SERIES. FIRST AID PROC: UNDER LIDS FOR AT LEAST 15 MIN. IF IRRIT/OTHER EFTS PERSIST, OBT AIN MED TREATMENT. INGEST: OBTAIN MED TREATMENT IMMED. OTHER PREC: APPRVD RESP PROT AS DIRECTED UNDER SPECIAL PROT INFO. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212F,100C Spec Gravity: 1.36 (FP N) Appearance and Odor: WHITE Percent Volatiles by Volume: 66.57 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: CONTACT WITH ALUMINUM OR ZINC, STORAGE NEAR ACIDS, FREEZING. Materials To Avoid: ACIDS, ALUMINUM, ZINC, MAGNESIUM, SODIUM, POTASSIUM. Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 9100 FLAT WHITE, LIFEMASTER 2000 INTERIOR (SUP DAT) Cage: IO491 Assigned IND: Y Company Name: ICI PAINTS Street: 925 EUCLID AVE Zipcode: 44115 Label Required IND: Y Date Of Label Review: 02/02/1998 Status Code: C Label Date: 02/02/1998 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO COUGHING, SNEEZING, RESPIRATORY PROBLEMS, PNEUMOCONIOSIS. SKIN: IRRITATION. EYES: IRRITATION. PROLONGED OR REPEATED CONTACT CAN CAUSE TEARING. INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:838 0578 FLEXICOLOR BLEACH III REPLENISHER NR,PART-B Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 75 - 80% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM FERRIC PROPYLENEDIAMINETETRAACETIC ACID CAS:111687-36-6 Fraction by Wt: 5 - 10% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM NITRATE CAS:6484-52-2 RTECS #:BR9050000 Fraction by Wt: 6% Other REC Limits:NONE RECOMMENDED Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM ACETATE (CERCLA) CAS:631-61-8 RTECS #:AF3675000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES. ACUTE- EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALATION:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. ORA L:EXPECTED TO BE A LOW INGESTION HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TRANSIENT EYE IRRITATION ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:DRIED PRODUCT RESIDUE CAN ACT AS AN OXIDIZER. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT IN A NON-COMBUSTIBLE CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. AVOID DRYNESS. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID EYE CONTACT. USE WITH ADEQUATE VENTILATION. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. DRYING ON CLOTH ING MAY CAUSE FIRE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS (10 ROOM VOLUMES PER HOUR). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health KEY1:C3. THIS PRODUCT IS A KIT CONSISTING OF TWO PARTS. PART A HAS PNI D, PART B HAS PNI E, SAME NSN. WORKING SOLUTION HAS PNI W. PERCENTAGE OF INGREDIENTS FOR PART A AND B CHANGED. FOR PREVIOUS PERCE NTAGES, SEE PNI A AND B, SAME NSN. FORMULA FOR WORKING SOLUTION ALSO CHANGED. FOR PREVIOUS FORMULATION, SEE PNI C. ================== Physical/Chemical Properties ================== HCC:C3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Decomp Temp:Decomp Text:>419F,>215C Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.07 pH:3.6 Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID - VINEGAR ODOR Percent Volatiles by Volume:75- 80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, STRONG OXIDIZING AGENTS, SODIUM HYPOCHLORITE. COMBUSTIBLES, REDUCING AGENTS. BASE LIBERATES FLAMMABLE MATERIAL. Stability Condition to Avoid:TEMPERATURES ABOVE 239F (115C) Hazardous Decomposition Products:AMMONIA, NITROGEN OXIDES (NOX), CHLORAMINE, CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER, IF PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:826 9219 KODAK EKTACOLOR RA BLEACH FIX & RPLENSHR NR, PART C Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 80-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 3310-3530 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAPOR IS EXTREMELY IRRITATING. MAY CAUSE DELAYED LUNG INJURY. EYE CONTACT CAUSES SEVERE BURNS. VAPOR EXTREMELY IRRITATING TO EYES. CAUSES SEVERE SKIN BURNS UPON CONTACT. MAY BE HARMFUL IF SWALLOWED. M AY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:MAY CAUSE DELAYED LUNG INJURY. SEVERE EYE/ SKIN BURNS. IRRITATES EYES. BURNS OF GASTROINTESTINAL TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR.BREATH DIFFI/ CYANOTIC GIVE OXY.NOT BREATH GIVE ART RESP.GET MED ATTN IMMED.EYE:IMMED FLUSH W/PLENTY OF WATER @LEAST 15MINS.CALL DR/POIS CNTRL CNTR IMMD.SKIN: IMMED FLUSH W/PLE NTY OF WATER FOR @LEAST 15MINS WHILE REMOVING CONTAMIN CLOTH/SHOES.GET MED ATTN IMMED.INGEST:DO NOT INDUCE VOMIT.GIVE A GLASS OF WATER.CALL DR/POIS CNTRL CNTR IMMED.NEVER GIVE ANYTHING BY MOUTH IF UNC ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:COMBUSTIBLE. MATERIAL CONTAINS A COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN CONTAINER HEADSPACE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MAY REQUIRE NEUTRALIZATION. ABSORB SPILL WITH VERMICULATIE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. USE ONLY WITH ADEQUTE VENTILATION. WASH THOROUGHLY AFTER HANDLING. Other Precautions:KEEP AWAY FROM HEAT AND FLAME. KEEP FROM CONTACT IWTH OXIDIZING MATERIALS. KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSUR LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS ARE USED, A PROGRAM SHO ULD BE INSTITUTED. Ventilation:USE PROCESS ENCLSURES/LOC EXHA VENTI/OTHER ENGINEER CNTRLS TO MAINTAIN AIRBORNE LEVELS BEL RECOMMENDED EXPO LIMITS. Other Protective Equipment:IMPERVIOUS BOOTS,PROT CLOTH APPROPRIATE FOR EXPO RISK. EYEBATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health KEY1:F6. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:239F,115C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:18MM @20C Vapor Density:NOT GIVEN Spec Gravity:1.05 pH:1.0 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE. Appearance and Odor:COLORLESS LIQUID, WITH SHARP VINEGAR ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MATERIAL CAN REACT VIOLENTLY W/STRONG OXIDIZING AGENTS. MATERIAL CAN REACT W/METALS, STRONG BASES, AMINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL/STATE/LOCAL LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. NO CHEM SUBJECT TO REPORTING REQMTS OF SEC 313 OR TITLE III OF SARA & 40CFR PART 372.
1
eyes_protection_mandatory
======================================================= Product ID: BAKELITE PREFORMS/POWDERS/PELLETS, 811-325 Cage: 94174 ======================================================= Contractor Summary ======================================================= Cage: 94174 ======================================================= Ingredients ======================================================= Cas: 9003-35-4 % Wt: 50-56 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 100-97-0 RTECS #: MN4725000 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ % Wt: 36 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 1332-58-7 RTECS #: GF1670500 % Wt: 8-12 OSHA PEL: 2 MG/M3 TDUST ACGIH TLV: 2 MG/M3 TDUST ------------------------------ Cas: 1332-69-0 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ % Wt: 2-6 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 57-11-4 RTECS #: WI2800000 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 557-05-1 RTECS #: ZH5200000 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:VAPS EVOLVED DURING POLYMERIZATION/DECOMP MAY CAUSE IRRIT TO EYES, LUNGS & SKIN. 1. PHENOL-CAS 108-95-2-OSHA PEL 5 PPM - ACGIH TLV/TWA 5 PPM, TLV/STEL 10 PPM HIGHLY TOX - MAY CAUSE KIDNEY, LIVER /HEART DMG. RPTD TO BE TUMOR PROMOTER. FORMALDEHYDE - CAS 50-00-0-OSHA PEL 3 PPM - ACGIH TLV/TWA 1 PPM,(EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:TLV/STEL 2 PPM IRRITANT - TO EYES, LUNGS & SKIN. HAS BEEN SHOWN TO CAUSE CANCER IN LAB ANIMALS, LISTED AS IARC CARCIN. NATIONAL CANCER INSTITUTE STUDY FINDS LITTLE EVID TO CONNECT FORMALDEHYD E EXPOS W/CANCER IN HUMANS. AMMONIA - CAS 7664-41-7- OSHA PEL 50 PPM - ACGIH TLV/TWA 25 PPM, TLV/STEL 35 PPM IRRITANT - TO EYES,MUC MEMB & RESPIRATORY TRACT. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS. GET MED ATTN. SKIN:WASH THOROUGHLY WITH SOAP & WATER. INHAL:USE W/ADEQ VENT. IF BRTHG IS AFFECTED, REMOVE TO FRESH AIR. IF BRTHG STOPS, APP LY MOUTH TO MOUTH RESUSCITATION. GET MED ATTN. INGEST:DO NOT INDUCE VOMITING. DILUTE BY DRINKING LARGE QUANTITIES OF WATER. IF VOMITING OCCURS, ADMINISTER MORE WATER. GET MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SMALL/LARGE SPILL:VACUUM OR SWEEP WITH SWEEPING COMPOUND, SAWDUST OR SAND. AVOID GENERATING DUST. VACUUM WITH EXPLOSION-PROOF MOTORS ARE RECOMMENDED. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: BURY OR INCINERATE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP CONTAINER CLOSED TO AVOID CONTAMINATION. STORE IN COOL, DRY PLACE. Other Precautions: PREVENT ACCUMULATIONS OF DUST RAISED DURING PROCESSING. USE ADEQUATE VENTILATION. ======================================================= Fire and Explosion Hazard Information ======================================================= Lower Limits: NONE Upper Limits: 0.030 OZ/FT3 Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). AVOID INHAL OF GASES. ORG DUST/AIR MIXS ARE HIGHLY FLAM(EXPLO). AVOID DUST ACCUM/DUST-LADEN ATM & SOURCES OF IGNIT. Unusual Fire/Explosion Hazard: NOT KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATORS RECOMMENDED IF TLV ARE EXCEEDED. Ventilation: USE LOC EXHAUST TO REMOVE DUST & VAPS EVOLVED DURING USE. USE GEN VENT AS DUST COLLECTION SYS. POINT SOURCE EXHAUST RECOMMENDED, AND USE EXPLOSION-PROOF MOTORS Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: OBSERVE GOOD HOUSEKEEPING PRACTICES. PRACTICE GOOD HYGIENE & MAINTAIN A CLEAN WORK ENVIRONMENT. Supplemental Safety and Health: HAZARDOUS DECOMPOSITION PRODUCTS: FORMALDEHYDE AS WELL AS WATER VAPOR, CARBON MONOXIDE & CARBON DIOXIDE ARE EVOLVED. BREATHING OF FUMES CAN BE HARMFUL. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.32-2.20 Evaporation Rate & Reference: NOT KNOWN Solubility in Water: NEGLIGIBLE Appearance and Odor: GRANULAR, NODULAR, PELLENT OR BRIQUET; SLIGHT PHENOL ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: AVOID DUST BUILDUP IN STORAGE AND MANUFACTURING AREAS. Hazardous Decomposition Products: VAPS EVOLVED DURING POLYMERIZATION MAY CONTAIN PHENOL, FORMALDEHYDE & AMMONIA. DURING PROCESSING OF PHENOLICS,MELAMINE-PHENOLICS & HEXAMETHYLENETETRAMINE, SM AMTS OF AMMONIA, PHENOL, & (SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: BAKELITE PREFORMS/POWDERS/PELLETS, 811-325 Cage: 94174 Company Name: LECO CORPORATION Street: 3000 LAKEVIEW AVE. Zipcode: 49085-2396 Label Required IND: Y Date Of Label Review: 12/24/1996 Status Code: C Label Date: 12/24/1996 Origination Code: G Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE:VAPORS MAY IRRITATE EYES, LUNGS AND SKIN. CHRONIC:NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHROMIUM (II) FLUORIDE 99%, AC311260000 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:CHROMIUM (II) FLUORIDE CAS:10049-10-2 Fraction by Wt: 97% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: NO INFORMATION REGARDING EYE IRRITATION AND OTHER POTENTIAL EFFECTS WAS FOUND. SKIN: NO INFORMATION REGARDING SKIN IRRITATION AND OTHER POTENTIAL EFFECTS WAS FOUND. INGESTION: THE TOXICOL OGICAL PROPERTIES OF THIS SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED. INORGANIC FLUORIDES CAN BE HARMFUL. ACUTE EXPOSURE TO FLUORINE COMPOUNDS CAN LEAD TO DIGESTIVE TRACT BURNS, AND ABDOMINAL PAIN. IN HALATION: THE TOXICOLOGICAL PROPERTIES OF THIS SUBSTANCE HAVE NOT BEEN FULLY INVESTIGATED. CHRONIC: CHRONIC INHALATION AND INGESTION MAY CAUSE FLUOROSIS WITH SKELETAL (EFTS OF OVEREXPOSURE) Explanation of Carcinogenicity:CAS# 10049-10-2: ACGIH: A4-NOT CLASSIFIABLE AS HUMAN CARCINOGEN (LISTED AS CHROMIUM). IARC: GROUP 3 CARCINOGEN (LISTED AS CHROMIUM). Effects of Overexposure:HLTH HAZS: ABNORMALITIES. CHRONIC EXPOSURE TO FLUORIDE COMPOUNDS MAY CAUSE SYSTEMIC TOXICITY. TARGET ORGANS: NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LST 15 MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN: GET MEDICAL AID. FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHIL E REMOVING CONTAMINATED CLOTHING AND SHOES. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED AID IMMED. INHAL: REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED AID. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE Extinguishing Media:IN CASE OF FIRE, USE WATER FOG, DRY CHEMICAL, CARBON DIOXIDE, OR REGULAR FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION (SECTION 8). SPILL/LEAKS: SWEEP UP OR ABSORB MATERIAL, THEN PLACE INTO SUITABLE CLE AN, DRY, CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. STORE IN A TIGHTLY CLOSED CONTAINER. CAUTION! HYGROSCOPIC. THIS SUBSTANCE MAY FORM HAZARDOUS DECOMPOSITION PRODUCTS WHICH MAY CAUSE IRRITATION AND POSSIBLE BURNS. Other Precautions:WASH THOROUGHLY AFTER HANDLING. USE ONLY IN A WELL VENTILATED AREA. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. AVOID INGESTION AND INHALATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SARA III: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS TOXIC POLLUTANTS UNDER THE CWA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1300760.00C Melt/Freeze Pt:=1100.C, ######F Decomp Temp:Decomp Text:NOT AVAILABLE Vapor Pres:NOT AVAILABLE Spec Gravity:3.79 Solubility in Water:INSOLUBLE Appearance and Odor:BLUE-GREEN CRYSTALS. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:MOISTURE. Hazardous Decomposition Products:HYDROGEN FLUORIDE. =================== Toxicological Information=================== Toxicological Information:RTECS#: CAS# 10049-10-2 UNLISTED. LD50/LC50: NOT AVAILABLE. CARCINOGENICITY: CAS # 10049-10-2: ACGIH: A4-NOT CLASSIFIABLE AS A HUMAN CARCINOGEN (LISTED AS CHROMIUM). IARC: GROUP 3 CARCINOGEN (LISTED A S CHROMIUM). EPIDEMIOLOGY: NOT DATA AVAILABLE. TERATOGENICITY: NO DATA AVAILABLE. REPRODUCTIVE EFFECTS: NO DATA AVAILABLE. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: NO DATA AVAILABLE. OTHER STUD IES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:EXOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, AND OTHER: NOT AVAILABLE. FED REGS: IT IS FOR RESEARCH AND DEVELOPMENTAL USE ONLY. HLTH & SAFETY RPTG LIST: NONE OF THE CHEMS ARE ON THE HLTH & S AFETY RPTG LIST.CHEM TEST RULES: NONE OF THE CHEMS IN THS PROD ARE UNDER A CHEM TEST RULE. SECTION 12B: NONE OF THE CHEMS ARE LISTED UNDER TSCA SEC 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMS IN THIS MATL HAVE A SNUR UNDER TSCA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LI STED. RCRA F, P, & U SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: DOT REGULATED-SMALL QTY PROVISIONS APPLY (SEE 49CFR173.4). IATA: CORROSIVE SOLID, N.O.S.* HAZ CLASS: 8, UN NUMBER: UN1759, PACKING GROUP: III. RID/ADR: SHIPPING NAME: CORROSIVE SOLID, N.O.S., HAZ CLASS: 8(65C), UN NUMBER: UN1759; IMO: SHIPPING NAME: CORROSIVE SOLID, N.O.S., HAZ CLASS: 8, UN NUMBER: UN1759, PACKING GROUP: III. CANADA TDG: NO INFORMATION AVAILIABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302(RQ), SECTION 302 (TPQ): NONE OF CHEMICAL IN THIS MATERIAL HAVE AN RQ OR TPQ. SECTION 313: THIS MATL CNTNS CHROMIUM (II) FLUORIDE (LISTED AS CHROMIUM), 97%, (CAS# 10049-10-2) WHICH IS SUBJE CT REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. CLEAN AIR ACT: MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. MATL DOES NOT CN TN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. (SUPDAT) Federal Regulatory Information:EUROPEAN/INTERNATIONAL REGS. EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVES. HAZARD SYMBOLS: NOT AVAILABLE. SFTY PHRASES: S 25 AVOID CONT W/EYES. S 36/37/39 WEAR ACCIDENT OF IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LABEL WHERE POSSIBLE). WGK (WATER DANGER/PROTECTION) CAS# 10049-10-2: NO INFO AVAIL. CANADA: NONE OF CHEMICALS IN PROD ARE LISTED ON DSL/NDSL LIST. WHMIS: NOT AVAIL. CAS # 10049-10-2 IS NOT LISTED ON CANADA'S INGR ED DISCLOSURE LIST. TSCA: CAS# 10049-10-2 IS NOT LISTED ON THE TSCA INVENTORY. (ECOL INFO) State Regulatory Information:CAS # 10049-10-2 IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: 1380450 IBM, LASER PRINTER, HIGH YIELD CARTRIDGE Cage: 0SD37 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 0SD37 ======================================================= Contractor Summary ======================================================= Cage: 0SD37 ======================================================= Ingredients ======================================================= Cas: 60806-47-5 ------------------------------ Cas: 1333-86-4 RTECS #: FF5800000 GROUP 3) - *95-2* Other REC Limits: 3.5 MG/CUM (NIOSH) OSHA PEL: 3.5 MG/CUM ACGIH TLV: 3.5 MG/CUM ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: MAY ACT AS A MECHANICAL IRRITANT. RARE INDIVIDUALS MAY GET SKIN RASH W/REPEATED CONTACT. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION, RASH First Aid: INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH COPIOUSLY W/RUNNING WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CONTAIN FOR TREATMENT/DISPOSAL. MINIMIZE GENERATION OF DUST DURING CLEANUP. USE OF A VACUUM CLEANER IS PREFERABLE. COLLECT & PLACE IN A CLOSED CONTAINER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID EXCESSIVE HEAT DURING STORAGE. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, DRY CHEMICAL, CO2, FOAM Fire Fighting Procedures: WEAR NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard: TONER DUST, IN HIGH CONCENTRATIONS, CAN FORM AN EXPLOSIVE MIXTURE IN AIR, WHICH, IF IGNITED, COULD RESULT IN DUST EXPLOSION. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE Ventilation: NONE Other Protective Equipment: NONE ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: 140F Appearance and Odor: BLACK POWDERY MATERIAL W/SLIGHT ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: OXIDIZERS Hazardous Decomposition Products: CO, CO2, UNIDENTIFIED ORGANICS Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 1380450 IBM, LASER PRINTER, HIGH YIELD CARTRIDGE Cage: 0SD37 Company Name: LEXMARK INTL INC FEDERAL SALES DIV Street: 2275 RESEARCH BLVD SUITE 360 Zipcode: 20850-1876 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: EYES: MAY ACT AS A MECHANICAL IRRITANT. RARE INDIVIDUALS MAY GET SKIN RASH W/REPEATED CONTACT. IRRITATION, RASH =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:WELDING CONSUMABLES H1072-2 CAGE:80357 CAGE:80357 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA 313) (CERCLA) CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9596 Ingred Name:COBALT (SARA 313) CAS:7440-48-4 RTECS #:GF8750000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG/M3 ACGIH TLV:0.02 MG/M3; A3; 9596 Ingred Name:CHROMIUM (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM. ACGIH TLV:10 PPM. Ingred Name:TUNGSTEN CAS:7440-33-7 RTECS #:YO7175000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Other REC Limits:NONE RECOMMENDED Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 5 MG/M3 (FUME) ACGIH TLV:0.2 MG/M3; 9596 Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST; 9596 Ingred Name:TITANIUM CAS:7440-32-6 RTECS #:XR1700000 Other REC Limits:NONE RECOMMENDED Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BORON CAS:7440-42-8 RTECS #:ED7350000 Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG B203/M3 ACGIH TLV:10 MG B2O3/M3 Ingred Name:INGREDS ABOVE VARIES W/ALLOY Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:SKIN:MAY CAUSE DERMATITIS,ALLERGIES.INGEST:VIA DIRTY HAND CONTACT W/FOOD/MOUTH.ELECTRIC ARC:FUMES/GAS DANGEROUS TO HEALTH.SHORT-TERM EXPO MAY RESULT IN DISCOMFORT(DIZZ,NAU,DRYNESS,IRRIT NOSE/THROAT/EY ES).ARC RAYS INJURE EYE,BURN SKIN.ELECTRIC SHOCK CAN KILL. Explanation of Carcinogenicity:PER MSDS:WELD W/PROD PRODUCES CHEM KNOWN TO SATE OF CA TO CAUSE CANC.CHROMIUNUM,NICKEL,WELD FUMES,COBALT. Effects of Overexposure:DERMATITIS, ALLERGIES, DISCOMFORT, DIZZINESS, NAUSEA, DRYNESS, IRRIT NOSE/THROAT/EYES. EYE INJURY, BURNS SKIN, ELECTRIC SHOCK CAN KILL. Medical Cond Aggravated by Exposure:AGGRAVATION OF PRE-EXISTING RESPIRATORY ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS.SOME STUDIES HAVE SHOWN HIGHER LEVEL OF LUNG RELATED PROBLEMS AMONG OLDER WORKERS WHO SMOKE THAN THOSE WHO DONT. ======================= First Aid Measures ======================= First Aid:REMOVE FROM WELD AREA.ADMIN 1STAID/GET MED ATTN.UNCONSC GIVE OXY;NOT BREATH BEGIN RESUSC IMMED.AMERC RED CROSS 1STAID TECHNICQUES. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NA Upper Limits:NA Extinguishing Media:NOT APPLICABLE. HMIS:USE APPROPRIATE FIRE EXTINGUISHER FOR SURROUNIDNG FIRE/MATLS. Unusual Fire/Explosion Hazard:NOT APPLICABLE. AS SHIPPED PROD NON-FLAMM/NON-EXPLO.WELD ARC/SPARKS CAN IGN COMBUST/INITIATE FIRES/EXPLO.READ/UNDERSTANDE ANSI Z49.1/NFPA 51B BEF USING PRODUCTS ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MAJ OF PROBLEMS/HAZ RESULT FROM PHYS ACCIDENTS(ELECTRIC SHOCK,RESTRICTED VISIBILI/MOBI/PHYS STRAINS/RADIATION BURNS/HEAT BURNS.READ/UNDERSTAND LABELS. Other Precautions:ONE RECOMMENDED WAY TO DETERMINE FUME/GAS COMPO/QUANT-TAKE AIR SPL FROM INSIDE WELDER HELMET/WORKER BREATH ZONE.SEE ANSI/AWS F1.1.AWALYS USE EXHAUST VENTILATION.MONITOR GAS BUILDUP;REMOVE/REDUCE EXCES S TO SAF LEVELS W/SYPPL SYS/GEN VENTI. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:BE SURE TO USE FUME RESP/AIR SUPPLIED RESP WHEN WELD IN CONFINED SPACES/LOC EXHAUST/VENTI DOESNT KEEP EXPO BELOW PEL/TLV LIMITS. Ventilation:USE ENOUGH VENTI/LOC EXHAU @ARC/BOTH-KEEP FUME/GAS FRM WORKER BREATH ZONE/GEN AREA.TRAIN WORKER KEEP HEAT OUT OF WELD FM Other Protective Equipment:RULE:START W/LENS SHADE THATS TOO DAKT TO SEE WELD ZONE;GO LIGHTER SHADE FOR SUFF VIEWING.SEE Z49.1.PROT CLOTH.APRON. Work Hygienic Practices:USE INDUSTRIAL HYGIENE AIR MONITORING TO ENSURE COMPLIANCE W/RECOMMENDED EXPO LIMITS.INSULATE FROM ELECTRIC SHOCK. Supplemental Safety and Health DECOMPO:USED/WELD PROD USED/METAL COAT WELDED/#OF WLEDERS/VOL OF WORKSPACE/WELDER HEAD POSITION/ATM CONTAMIN.COMPLEX COMBINATIONS,CO,CO2.OZONE/OXIDES OF NITROGEN BY ARC RADIATION. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NA Vapor Density:NA Spec Gravity:7-9 pH:NP Viscosity:NP Evaporation Rate & Reference:NA Solubility in Water:INSOLBULE Appearance and Odor:BARE WIRE,STRAING LENGTH/COIL WIRES,METAL CORE RODS COATED W/FLUX. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMPO PORD CANT BE EASILY CLASSIFIED.COMPO/QUANT FUMES/GAS DEPEND:BASE METAL BEING WELD/WELD PROCESS/PROCEDURE (SUPPL) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF FUME/FLUX/WELD GRIND RESIDUES FROM WORKAREA/FILT IAW LOC/STATE/FED REGS.MAY CONTAIN SARA SEC 313 TITLE III CHEMS. ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLASTIC COATING COMPOUND Preparer's Name:THOMAS B EVANS CAGE:56307 CAGE:56307 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT CONTAINS NO KNOWN HAZARDOUS COMPONENTS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Effects of Overexposure:BURN ======================= First Aid Measures ======================= First Aid:APPLIED AT 350F IF COMES IN CONTACT WITH SKIN - TREAT AS OIL BURN ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:>400F,>204C Extinguishing Media:CARBON DIOXIDE Fire Fighting Procedures:TREAT AS OIL FIRE Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT THIS MATERIAL WILL RELEASE FLAMMABLE VAPORS ================== Accidental Release Measures ================== Spill Release Procedures:SOLID ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:OVER 700F Spec Gravity:1 pH:NEUTRL Solubility in Water:INSOLUBLE Appearance and Odor:100% SOLID THERMO PLASTIC WAX LIKE OIL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:NONE, ONLY CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:SAME AS WAX OR OIL. INCINERATION OR LAND FILL
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SEALED MAINTENANCE FREE LEAD ACID BATTERY Preparer's Name:ENGINEER CAGE:56309 CAGE:56309 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 70% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 20% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:FIBERGLASS SEPERATOR Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:POLYSTYRENE CAS:9003-53-6 RTECS #:WL6475000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:LEAD-THE TOXIC EFFECTS OF LEAD ARE ACCUMULATIVE AND SLOW TO APPEAR. IF EFFECTS THE KIDNEYS, REPRODUCTIVE, AND CENTRAL NERVOUS SYSTEM SULFURIC ACID-SULFURIC ACID IS A STRONG CORROSIVE. CONTACT WITH ACI D CAN CAUSE SEVERE BURNS ON THE SKIN ANDIN EYES. INGESTION OF SULFURIC ACID WILL CAUSE GI TRACT BURNS. Explanation of Carcinogenicity:LEAD IS POSSIBLY CARCINOGENIC TO HUMAN (MSDS). Effects of Overexposure:LEAD-THE SYMPTOMS OF LEAD OVEREXPOSURE ARE ANEMIA, VOMITING, HEADACHE, STOMACH PAIN, DIZZINESS, LOSS OF APPETITE, AND MUSCLE AND JOINT PAIN. FIBERGLASS-FIBOROUS GLASS IS AN IRRITANT OF THE UPPER RESPI RATORY TRACT, SKIN AND EYES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN-FLUSH WITH WATER, SEE PHYSICIAN IF CONTACT AREA IS LARGE OR BLISTERING. EYE-CALL A PHYSICIAN IMMEDIATELY AND FLUSH WITH WATER UNTIL PHYSICIAN RRIVES. INGESTION-CALL PHYSICIAN. IF PATIENT IS CONSC IOUS, FLUSH MOUTH WITH WATER, HAVE THE PATIENT DRINK MILK OR SODIUM BICARBONATE SOLUTION. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. Fire Fighting Procedures:(FIBERGLASS SEP.)-TOXIC VAPORS MAY BE RELEASED. IN CASE OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:(478 POLYSTYRENE)-TEMPERATURES OVER 300C MAY RELEASE COMBUSTIBLE GASES. IN CASE OF FIRE; WEAR POSITIVE PRESSURE SELF- CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:IF SULFURIC ACID IS SPILLED FROM A BATTERY, NEUTRALIZE THE ACID WITH SODIUM BICARBONATE, SODIUM CARBONATE OR CALCIUM OXIDE. FLUSH THE AREA WITH WATER AND DISCARD TO THE SEWER SYSTEM. DO NOT ALLOW UNNE UTRALIZED ACID INTO THE SEWER SYSTEM. Neutralizing Agent:SODIUM BICARBONATE , SODIUM CARBONATE, CALCIUM OXIDE. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A RESPIRATOR MUST BE WORN DURING RECLAIM OPERATIONS IF THE TLV IS EXCEEDED. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:RUBBER APRON. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:237F,114C Spec Gravity:1.3(ACID) Solubility in Water:100%, ACIDY Appearance and Odor:CLEAR COLORLESS LIQUID, ACIDIC ODOR. (ACID). ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTIVE METALS, STRONG BASES, MOST ORGANIC COMPOUNDS. Stability Condition to Avoid:PROHIBIT SMOKING, SPARKS, ETC. FROM BATTERY CHARGING AREA. AVOID MIXING ACIDS WITH OTHER CHEMICALS. Hazardous Decomposition Products:SULFURIC DIOXIDE, TRIOXIDE, HYDROGEN SULFIDE, HYDROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:NEUTRALIZED ACID MAY BE FLUSHED DOWN THE SEWER. SPENT BATTERIES MUST BE TREATED AS HAZARDOUS WASTE AND DISPOSED OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS.. ACOPY OF THIS MATERIAL SAFETY DAT A SHEET MUST BE SUPPLIED TO ANY SCRAP DEALER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ROOF PRO ROOF CLEANER CAGE:82464 CAGE:82464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYPOCHLORITE (SARA III) CAS:7681-52-9 RTECS #:NH3486300 Fraction by Wt: <4% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/INGESTION: IRRITATION. EYE: BURNING & WATERING. INHALATION: IRRITATION TO NASAL PASSAGES, NUASEA, COUGHING, HEADACHE, DIZZINESS, VOMITING, & EDEMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/INGESTION: IRRITATION. EYE: BURNING & WATERING. INHALATION: IRRITATION TO NASAL PASSAGES, NAUSEA, COUGHING, HEADACHE, DIZZINESS, VOMITING, & EDEMA. Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, FOAM, & DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN POSITIVE PRESSURE MODE & FULL PROTECTIVE EQUIPMENT. ================== Accidental Release Measures ================== Spill Release Procedures:SCRAPE INTO CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE NEAR HEAT SOURCES, SPARKS, OR FLAME. STORE BETWEEN 40-120F, & IN COOL, DARK AREAS. DON'T FREEZE, INGEST, OR STORE IN METAL CONTAINERS. Other Precautions:KEEP AWAY FROM CHILDREN. AVOID CONTACT W/CLOTHING, WHICH MAY CAUSE PERMANENT DISCOLORATION. USE IN WELL VENTILATED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:PROVIDE ADEQUATE VENTILATION. Work Hygienic Practices:WASH SKIN & HANDS AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Vapor Density:<1 Spec Gravity:1 Evaporation Rate & Reference:SLOWER THAN BU AC Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID W/SHARP ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDIC MATERIALS, & ALUMINUM. Stability Condition to Avoid:HEAT SOURCES, SPARKS, FLAME, TEMPERATURES <40F OR >120F, & FREEZING. Hazardous Decomposition Products:CO2, CO, TOXIC GASES, & AEROSOLS. ==================== Disposal Considerations ==================== Waste Disposal Methods:SANITARY LANDFILL, DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CH 32650 GREEN CAGE:0LG38 CAGE:7L115 CAGE:0LG38 ============= Composition/Information on Ingredients ============= Ingred Name:POLYMER RESIN Ingred Name:COLORANT Ingred Name:THERMOPLASTIC ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: LOW LEVELS OF TOXIC OR IRRITATING VAPORS OR FUMES. PROLONGED OR REPEATED EXPOSURE TO THESE VAPORS OR FUMES MAY EYE OR RESPIRATORY TRACT IRRITATION. SKIN: CONTACT W/HOT MATERIALS DURING PRO CESSING MAY CAUSE BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: CONTACT W/HOT MATERIALS DURING PROCESSING MAY CAUSE BURNS. INHALATION: LOW LEVELS OF TOXIC OR IRRITATING VAPORS/FUMES. PROLONGED OR REPEATED EXPOSURE TO THESE VAPORS OR FUMES MAY CAUSE EYE OR R ESPIRATORY TRACT IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH W/COLD WATER; COVER AREA W/STERILE DRESING; CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, SPRAY, DRY CEHMCIAL, FOAM, OR CO2 Fire Fighting Procedures:STANDARD PROCEDURES FOR CLASS A FIRES; WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:PRODUCT MAY BURN W/DENSE SMOKE GIVEN OFF IN AN OXYGEN DEFICIENT ATMOSPHERE. ================== Accidental Release Measures ================== Spill Release Procedures:UNCONTAMINATED MATERIAL MAY BE SCOOPED UP FOR USE. IF CONTAMINATED, SCOOP OR VACUUM INTO A RECEPTACLE FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A SPRINKLER PROTECTED AREA AT AMBIENT TEMPERATURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED Ventilation:LOCAL EXHAUST: IF PROCESSING AT >400F. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:>320F Vapor Pres:NEGLIGIBLE Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS PELLETS Percent Volatiles by Volume:NEGL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:TEMPS >500F Hazardous Decomposition Products:CO2, FORMALDEHYDE, OR OTHER TOXIC EMISSIONS ARE POSSIBLE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SHELL SPIRAX(R) HEAVY DUTY 80W/90, PN:59210 Preparer's Name:J.C. WILLETT CAGE:EO135 CAGE:3N254 CAGE:EO135 ============= Composition/Information on Ingredients ============= Ingred Name:RESIDUAL OILS, HYDROTREATED CAS:64742-57-0 Fraction by Wt: 0-65% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:SOLVENT, DEWAXED RESIDUAL OIL (PETROLEUM) CAS:64742-62-7 Fraction by Wt: 0-65% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:MINERAL OIL, PETROLEUM PARAFFIN OILS, CATALYTIC DEWAXED HEAVY CAS:64742-70-7 RTECS #:PY8045500 Fraction by Wt: 0-65% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: 0-35% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:HYDROTREATED MIDDLE PETROLEUM DISTILLATE CAS:64742-46-7 RTECS #:JN9379645 Fraction by Wt: 0-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:PETROLEUM DISTILLATES, HYDROTREATED LIGHT NAPHTHENIC CAS:64742-53-6 RTECS #:PY8036000 Fraction by Wt: 0-20% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:DISTILLATES, ACID-TREATED HEAVY NAPHTHENIC CAS:64742-18-3 RTECS #:PY8032000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SEVERLY HYDROTREATED HEAVY NAPHTHENIC DISTILLATE CAS:64742-52-5 RTECS #:PY8035000 Fraction by Wt: 0-15% Other REC Limits:NONE RECOMMENDED Ingred Name:ADDITIVE PACKAGE Fraction by Wt: <10% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PEL=5MMMG/M3 FOR OIL MIST, MINERALA Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:BASED ON COMPONENT INFO EYE:NO MORE THAN MINIMALLY IRRIT. SKIN:NO MORE THAN MILDLY IRRIT. INHAL:MINOR IRRIT OF MUCOUS MEMBRANES OF UPPER RESP TRACT. INGEST:NO MORE THAN SLIGHTLY TOXIC IF INGESTE D. CHRONIC:PROLONGED/REPEATED CONTACT CAN RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, FOLLICULITIS OR OIL ACNE. Effects of Overexposure:SKIN/EYE:REDNESS. INHAL:SNEEZING, SORE THROAT. INGEST:STOMACH PAIN. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER FOR 15MINS LIFTING EYELIDS. SKIN:REMOVE CONTAMINATED CLOTHING. WIPE EXCESS. WASH W/SOAP & WATER OR A WATERLESS HAND CLEANER FOLLOWED BY SOAP & WATER. INHAL:REMOVE TO FRESH AIR. PROVI DE OXYGEN IF BREATH DIFFICULT. INGEST:DO NOT INDUCE VOMIT. IN GEN NO TREATMENT IS NECESSARY UNLESS LG AMTS ARE INGESTED. IN ALL CASES SEEK MED ATTN. (DR:IN GEN EMESIS INDUCTION IS UNNECESSARY FOR MAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:310F,154C Extinguishing Media:USE WATER FOG,FOAM,DRY CHEMICAL,CARBON DIOXIDE.DON'T USE A DIRECT STREAM OF WATER.MATL FLOATS ON WATER & WILL REIGNITE. Fire Fighting Procedures:MATERIAL WILL NOT BURN UNLESS PREHEATED. WEAR FULL BUNKER GEAR INCLUDING POS-PRESSURE NIOSH-APPROVED SCBA. COOL FIRE EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RESPIR & PROTECT CLOTH.SAFELY SHUT OFF SOURCE OF LEAK.DIKE & CONTAIN.REMOVE W/VACUUM TRUCKS OR PUMP.SOAK UP RESIDUE W/ABSORBENT SUCH AS CLAY/SAND/OTHER SUITABLE MATL.FLUSH RESIDUE W/WATER.SPILLS ENTERING WATERS CAUSING A SHEEN CALL 800-424-8802. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. Other Precautions:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES INCLUDING SHOES THAT CANNOT BE DECONTAMINATED. MINIMIZE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS USE NIOSH-APPROVED RESP TO PREVENT OVEREXPOSURE. IAW 29CFR1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESP OR AN AIR-PURIFYING RESP FOR ORGA NIC VAPORS & PARTICULATES. Ventilation:USE GEN (MECHANICAL) VENTILATION OR LOCAL EXHAUST ACCORDINGLY TO MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV). Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT. EYEWASH. Work Hygienic Practices:WASH HANDS W/SOAP &WATER BEFORE EAT/DRINK/SMOKE/USE OF TOILET FACILITIES. Supplemental Safety and Health PER MSDS PRODUCT REFORMULATED. ================== Physical/Chemical Properties ================== HCC:V6 Melt/Freeze Pt:M.P/F.P Text:-22F,-30C Spec Gravity:0.8990 Solubility in Water:NEGLIGIBLE Appearance and Odor:BROWN LIQUID WITH A SLIGHT HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID HEAT, OPEN FLAMES. Hazardous Decomposition Products:COMPLEX MIXTURE OF AIRBORNE SOLID/LIQ/PARTICULATES/GASES WILL EVOLVE WHEN PYROLYZED/COMBUSTED. CO & OTHER UNID ORG CMPD ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:00-2021 DAB ENHANCER CAGE:044H2 CAGE:044H2 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT(II) CHLORIDE HEXAHYDRATE CAS:7791-13-1 RTECS #:GG0200000 Ingred Name:NICKEL CHLORIDE HEXAHYDRATE CAS:7791-20-0 RTECS #:QR6480000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 157 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED/ABSORBED THROUGH SKIN. CAUSES EYE & SKIN IRRITATION. INHALATION: IRRITATING TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. MAY CAUSE DERMATITIS & ALLERGIC RESPIRATORY REA CTION. MAY AFFECT THE LUNGS & THE BLOOD. Effects of Overexposure:IRRITATION, GASTROINTESTINAL DISTURBANCES ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. INGESTION: WASH OUT MOUTH W /WATER IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES. Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR SELF CONTAINED BREATHING COVERALLS & DISCARD THEM AFTER USE. SWEEP UP. PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP TIGHTLY CLOSED. HYGROSCOPIC. Other Precautions:DON'T BREATHE DUST. DON'T GET IN EYES, ON SKIN/ON CLOTHING. AVOID PROLONGED/REPEATED EXPOSURE. TOXIC. DON'T USE IF SKIN IS CUT/SCRATCHED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health LARGE AMOUNTS OF COBALT II CHLORIDE DEPRESS ERYTHROCYTE PRODUCTION WHICH MAY LEAD TO DEATH IN CHILDREN. MIXTURES OF POTASSIUM & SODIUM W/COBALT II CHLORIDE ARE SHOCK SENSITIVE. ================== Physical/Chemical Properties ================== Spec Gravity:1.920 Appearance and Odor:LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ALKALI METALS, ABSORBS AMMONIA FROM AIR. Stability Condition to Avoid:MOISTURE Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, NICKEL/NICKEL OXIDES =================== Toxicological Information=================== Toxicological Information:MAY CAUSE CANCER. MAY AFFECT THE BEHAVIORAL (SOMNOLENCE), BEHAVIORAL(ATAXIA). GASTROINTESTINAL (CHANGES IN STRUCTURE/FUNCTION OF SALIVARY GLANDS) EFFECTS ON NEWBORN (VIABILITY INDEX). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE IN WATER, ACID SOLUTION/OXIDIZE TO A WATER SOLUBLE STATE. PRECIPITATE AS THE SULFIDE, ADJUST PH TO 7 TO COMPLETE PRECIPITATION. FILTER INSOLUBLES &DISPOSE OF IN A HAZARDOUS WASTE SITE. DESTRO Y ANY EXCESS SULFIDE W/SODIUM HYPOCHLORITE. NEUTRALIZE THE SOLUTION BEFORE FLUSHING DOWN THE DRAIN. DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALPHA STYPE 2337-2-TA CAGE:09079 CAGE:09079 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS, FIBROUS RTECS #:LK3651000 OSHA PEL:15 MG/M3 (DUST) ACGIH TLV:10 MG/M3 (DUST);9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE NORMALLY REQUIRED. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NONE KNOWN. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMED . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:>482F,>250C Extinguishing Media:WATER, CO*2, OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:MATERIAL IS A SOLID. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY PLACE. Other Precautions:USE ADEQUATE MATERIAL HANDLING EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. Ventilation:NONE NEEDED. Other Protective Equipment:NONE NEEDED. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>1000F Spec Gravity:1.6 Solubility in Water:NEGLIGIBLE Appearance and Odor:ALUMINUM ONE SIDE/RED OTHER SIDE - NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:HYDROGEN BROMIDE, CO*2, CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURIAL IN A FEDERAL, STATE, OR LOCAL APPROVED LANDFILL.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:MOPS, SODIUM SALT CAGE:016E9 CAGE:016E9 ============= Composition/Information on Ingredients ============= Ingred Name:AMINO ALKYL SULFONIC ACID ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE IRRITATING UPON CONTACT W/EYES, SKIN/MUCOUS MEMBRANES. Explanation of Carcinogenicity:NONE Effects of Overexposure:MAY BE IRRITATING UPON CONTACT W/EYES, SKIN/MUCOUS MEMBRANES. ======================= First Aid Measures ======================= First Aid:TREAT AS A WEAK ACID IF SPLASHED ON SKIN/EYES. FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO2, FOAM Fire Fighting Procedures:TOXIC GASES CAN BE EVOLVED-USE A RESPIRATOR. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE & FLUSH TO SEWER IF PERMITTED BY LOCAL ORDINANCE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMP IN A DRY LOCATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE 3M DUST MASK. Ventilation:LAB HOOD Other Protective Equipment:LABORATORY APRONS, APPROVED CLOTHING & Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:392F Solubility in Water:COMPLETE Appearance and Odor:WHITE CRYSTALS W/NO ODOR Percent Volatiles by Volume:<1/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS; COMPOUND IS ORGANIC & MAY IGNITE. Hazardous Decomposition Products:CO2, CO, NITROGEN DIOXIDES, SULFUR DIOXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH TO SEWER IF PERMITTED/BURN IN A CHEMICAL INCINERATOR/DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOBIL DTE 24 CAGE:3U728 CAGE:3U728 ============= Composition/Information on Ingredients ============= Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0.10% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHOSPHORODITHOIC ACID, O-O-D1 C1-14-ALKYL ESTERS, ZINC SALTS (2:1) (ZDDP) CAS:68649-42-3 Fraction by Wt: 0.67% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50, ORAL, RATS: >2000MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:HARMFUL MIST &OR VAP CONCEN UNLIKELY TO BE ENCOUNTERED THRU HNDLG/USE/MISUSE.EYE/SKIN:PRACTICALLY NON-IRRIT.BASE OILS IN PRODUCT ARE SEVERELY SOLVT REFINED &OR SEVERELY HYDROTREATED. Effects of Overexposure:NO SIGNIFICANT EFFECTS EXPECTED. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WELL W/WATER.IRRIT OCCURS CALL PHYSICIAN.SKIN:WASH W/SOAP/WATER.HIGH PRESSURE ACCIDENTAL INJECTION THRU SKIN REQUIRES IMMED MED ATTN FOR POSSIBLE INCISION,IRRIGATION &/OR DEBRIDEMENT.INHAL/I NGEST:NOT EXPECTED TO BE PROBLEM.IF >1/2L(PT)INGEST.IMMED GIVE 1-2 GLASSES OF WATER.CALL PHYSICIAN/HOSP EMERG RM/POIS CNTRL CNTNR FOR ASSIST.DONT INDUCE VOMIT/GIVE ANYTHING BY MOUTH IF UNCONSC. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>396F,>202C Autoignition Temp:Autoignition Temp Text:N/EST Lower Limits:NA Upper Limits:NA Extinguishing Media:CARBON DIOXIDE,FOAM,DRY CHEMICAL,WATER FOG. Fire Fighting Procedures:WATER/FOAM MAY CAUSE FROTHING.USE WATER TO KEEP FIRE EXPO CNTNR COOL.WATERSPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPO.PREVENT RUNOFF FRM FIRE CNTNR/(SUPPL) Unusual Fire/Explosion Hazard:PRESSURIZED ;MSITS MAY FORM FLAMM MIXTURE. ================== Accidental Release Measures ================== Spill Release Procedures:REPORT AS REQUIRED.REPORT TO COAST GUARD 800-424-8802 IF REACH WATERWAY INCLUDING INTERMITTENT DRY CREEKS.ADSORB ON FIRE RETARDANT TREAT SAWDUST/DIATOMACEOUS EARTH,ETC.SHOVEL UP/DISPO OF @APPROPRIA WA STE DISPO FACILI IAW CURRENT LAWS/REGS/PROD CHARA ======================Handling and Storage ====================== Handling and Storage Precautions:HI PRESSURE INJECTION UNDER SKIN MAY OCCUR DUE TO RUPTURE OF PRESSURIZED LINES.ALWAYS SEEK MED ATTN.DONT STORE IN OPN/UNLABEL CNTNR. Other Precautions:STORE AWAY FROM STRONG OXIDIZING/COMBUST MATLS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQMTS UNDER ORDINARY CONDITOINS OF USE & W/ADEQUATE VENTILATION. Ventilation:NO SPECIAL REQMTS UNDER ORDINARY CONDITIONS OF USE & W/ADEQUATE VENTILATION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES SHOULD ALWAYS BE FOLLOWED. Supplemental Safety and Health FIRE:DIL FROM ENTERING STREAMS/SEWERS/DRINK WATER SUPPLY.IN ENCLSD AREAS MUST USE SCBA. DISPO:APPLIABLE LAWS/REGS/CONSIDERATION OF PROD CHARACTERISTIC @DISPO TIME.UNUSED PROD NOT EPA HAZ WASTE.USE PRO D MAY BE REGULATED.NO CHEM SUBJ TO SARA311/312/313. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:>601F,>316C Melt/Freeze Pt:M.P/F.P Text:>396F,>202C Decomp Temp:Decomp Text:NP Vapor Pres:<0.1 Vapor Density:>2.0 Spec Gravity:0.874 pH:NA Viscosity:>29.8CST @40C Evaporation Rate & Reference:NA Solubility in Water:NEGLIGIBLE. Appearance and Odor:LIQUID, AMBER COLOR, MILD ODOR. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:CARBON MONOXIDE,METAL OXIDES,ELEMENTAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:SUITABLE FOR BURNING IN ENCLSD CNTRL BURNER FOR FUEL VAL/DISPO BY SUPERVISED INCINERATION.MAY BE LIMITED PURSUANT TO RCRA.SUITABLE FOR PROCESSING BY APPROV RECYCL FACI/DISPO @GOVT APPROV WASTE DISPO F ACIL.METHODS SUBJ TO USER COMPLIANCE W/(SUPPLEMEN)
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:HI PURITY RED, Z805 Resp. Party Other MSDS Num.:HP FT RED CAGE:04457 CAGE:04457 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC HYDROCARBON) CAS:64742-95-6 RTECS #:WF3400000 = Wt:71. Other REC Limits:N/K OSHA PEL:100 PPM OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:ROSIN (RESIN) CAS:8050-09-7 RTECS #:VL0480000 = Wt:15. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:PIGMENT RED 170; (PIGMENT RED) CAS:2786-76-7 = Wt:12. Other REC Limits:N/K OSHA PEL:2 MG/M3 OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: SLIGHT TO SEVERE IRRITATION TO EYES AND MUCOUS MEMBRANES OF NOSE AND THROAT. DERMATITIS. AFFECTS CENTRAL NERVOUS SYSTEM. Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, ANESTHESIA, COUGHING, EYE AND THROAT IRRITATION, ======================= First Aid Measures ======================= First Aid:INHALATION: SEEK FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. SKIN: WASH WITH COPIOUS AMOUNTS OF WATER. INGESTION: CALL A PHYSICIAN. EYES: FLUSH WITH POTABLE WATER FOR AT LEAST 15 MINUTES. SEE MD . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=46.7C, 116.F Lower Limits:1.00% Upper Limits:7.00% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. VENTILATE AREA. USE ABSORBENT MATERIAL TO CLEAN SPILL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, FIRE AND STRONG OXIDANTS. STORE IN COOL PLACE (ROOM TEMPERATURE). USE ADEQUATE VENTILATION. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:>158.9C, 318.F B.P. Text:318F - 351F Vapor Pres:3 MM HG @ 25C Vapor Density:4.3 Spec Gravity:1 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NIL Appearance and Odor:THIN LIQUID WITH AROMATIC ODOR. Percent Volatiles by Volume:71 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX WITH STRONG OXIDANTS. Stability Condition to Avoid:HEAT, OPEN FLAME, AND SPARKS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND UNIDENTIFIED ORGANIC COMBUSTION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL AND FEDERAL REGULATIONS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS . =================== MSDS Transport Information =================== Transport Information:DOT HAZARD CLASS: UN 1993 NOS. DOT SHIPPING NAME: COMBUSTIBLE LIQUID NOS. ===================== Regulatory Information ===================== Federal Regulatory Information:THIS PRODUCT IS IN COMPLIANCE WITH THE EPA TSCA INVENTORY. WHMIS (CANADA ONLY): B3. State Regulatory Information: ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COATING, POLYURETHANE, GREEN 383, 34094 ID 754217 Kit Part:Y Preparer's Name:W A ELLISON CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYLENE GLYCOL METHYL ETHER ACETATE (SOLVENT) (VAPOR PRESSURE 2 MM HG @ 20C) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 20% Other REC Limits:NONE RECOMME Ingred Name:XYLENE (SOLVENT) (SARA III) (VAPOR PRESSURE 5 MM HG @ 20C) (LFL 1.0; UFL 7.0) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <5% Other REC Limits:NONE RECOMME OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:100 PPM;STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ETHYL KETONE (SOLVENT) (SARA III) (VAPOR PRESSURE 70 MM HG @ 20C) (LFL 2.0; UFL 10.0) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 5% Other REC Limits:NONE RECOMME OSHA PEL:200 PPM;STEL 300 PPM ACGIH TLV:200 PPM;STEL 300 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ACETATE (SOLVENT) (SARA III) (VAPOR PRESSURE 10 MM HG @ 20C) (LFL 1.7; UFL 7.6) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMME OSHA PEL:150 PPM;STEL 200 PPM ACGIH TLV:150 PPM;STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE (PIGMENT) CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 10% Other REC Limits:NONE RECOMME OSHA PEL:0.0500 MG/M3 ACGIH TLV:0.0500 MG/M3 Ingred Name:SILICA, AMORPHOUS - DIATOMACEOUS EARTH (PIGMENT) CAS:68855-54-9 Fraction by Wt: 5.0% Other REC Limits:NONE RECOMME OSHA PEL:6 MG/M3; 20 MPPCF ACGIH TLV:10 MG/M3 Ingred Name:SILICA, CRYSTALLINE - QUARTZ (PIGMENT) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <1% Other REC Limits:NONE RECOMME OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:SILICA, CRYSTALLINE - TRIPOLI CAS:1317-95-9 RTECS #:VV7336000 Fraction by Wt: <1% Other REC Limits:NONE RECOMME OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:SILICA, CRYSTALLINE CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 15% Other REC Limits:NONE RECOMME OSHA PEL:0.1000 MG/M3 ACGIH TLV:0.1000 MG/M3 Ingred Name:CHROMIUM III OXIDE (PIGMENT) CAS:1308-38-9 RTECS #:GB6475000 Fraction by Wt: 10% Other REC Limits:NONE RECOMME OSHA PEL:0.5000 MG/M3 ACGIH TLV:0.5000 MG/M3 Ingred Name:TOLUENE (SOLVENT) (SARA III) (VAPOR PRESSURE 22 MM HG @ 20C) (SKIN) (LFL 1.7; UFL 7.1) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5% Other REC Limits:NONE RECOMME OSHA PEL:100 PPM;STEL 150 PPM ACGIH TLV:50 PPM; 147 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOC: 4.65 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS; 558 G/L LESS WATER; CALCULATED RTECS #:9999999VO Other REC Limits:NONE RECOMME ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE; INGEST: GI IRRIT, NAUSEA, VOMITING. ASPIRATION INTO LUNG MAY CAUSE CHEM PNEUMONITIS (CAN BE FATAL). INHAL: NOSE OR THROAT IRRIT. ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION (HEADACHES, DIZZINESS, N AUSEA, CONFUSION). EYE: SEVERE IRRIT, CORNEAL DAMAGE. MISUSE BY DELIBERATELY CONCENTRATING/INHALING MAY BE HARMFUL/FATAL Explanation of Carcinogenicity:CONTAINS 2-A [53-96-3] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:CHRONIC; SILICOSIS (DISABLING LUNG DISEASE). LIVER, KIDNEY, LUNG, SPLEEN, BLOOD INJURY. NEUROTOXICITY (SYNERGISTIC EFFECTS HAS RESULT IN PERIPHERAL NEUROPATHY IN HUMAN). PERMANENT BRAIN & NERVOUS SYST EM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING MAY BE HARMFUL OR FATAL. Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. ======================= First Aid Measures ======================= First Aid:INGEST:DON'T INDUCE VOMITING.CALL POISON CONTROL CENTER,EMERGENCY ROOM OR DR IMMED. INHAL:REMOVE TO FRESH AIR. IF BREATHING STOPPED,GIVE ARTIF RESP.KEEP WARM & QUIET.GET MED AID IMMED. EYE: FLUSH W/WA TER 15 MINUTES,LIFTING EYELIDS.GET MED AID. SKIN:REMOVE CONTAM CLOTHING. WASH SKIN W/SOAP & WATER. OBTAIN MED AID IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point:24.0F,-4.4C Lower Limits:1.0 Upper Limits:10.0 Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO2, DRY CHEMICAL, ALCOHOL FOAM) FOR FLAMMABLE LIQ. POLYMER FOAM PREFERRED FOR LARGE FIRES. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL EXPOSED CONTAINERS (FOG NOZZLES PREFERRED) TO PREVENT PRESSURE BUILDUP, AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO HEAT. Unusual Fire/Explosion Hazard:DURING EMERG CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY BE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL AID. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNITION SOURCES. DIKE & CONTAIN WITH INERT MATERIAL (SAND, EARTH, ETC). TRANSFER LIQUID OR USED ABSORBENT TO COVERED METAL CONTAINER. USE NON-SPARKING TOOLS. PREVE NT SEWER, STREAM, OR GROUNDWATER CONTAMINATION. ======================Handling and Storage ====================== Handling and Storage Precautions:DONT STORE ABOVE 115 F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106. DONT INGEST. CLOSE CONTAINER AFTER USE. Other Precautions:CLOSE CONTAINER AFTER EACH USE. DO NOT WASH & REUSE EMPTY CONTAINERS FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO RECEIVING CONTAINER. DONT WELD, BRAZE, OR CUT ON EMPTY CNTNR. NEVER USE PRESSURE TO EM PTY. DRUM IS NOT A PRESSURE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTED,MAY NOT REQ RESP PROTECT.RESTRICTD VENT, CHEM CARTRIDGE MAY BE REQ'D.SPRAYING,MECHAN PREFILTER MAY BE REQ'D. CONFIND,AIR SUPPLD RSPRTR. ABOVE TLV,SEE OSHA 29 CFR 1910.134 "RESP PROTECT" & "R ESP PROTECT-MANUAL & GUIDELINES" AIHA. Ventilation:GENRL DILUTN & LOCAL EXHAUST VENT TO KEEP BELOW TLV.REMOVE DECOMP PRODUCT.SEE"INDUST VENT-MANUAL RECOMM PRACTICES"ACGIH. Other Protective Equipment:NOT LIKELY TO BE NEEDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175 TO 281F Melt/Freeze Pt:M.P/F.P Text:-50F,-46C Decomp Temp:Decomp Text:1832F,1000C Vapor Pres:70 @ 20C Vapor Density:> AIR Spec Gravity:1.4 pH:4-7 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SLIGHT IN WATER Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:61 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115) AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON DIOXIDE. IN ADDITION OXIDES OF CHROMIUM MAY BE GENERATED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL LAWS/REGULATIONS. CONTAINS CHROMIUM. RESIDUE MAY BE HAZARDOUS WASTE (40 CFR 261.74-). DISCARDED DIRECTLY WOULD BE CLASSIFIED HAZARDOUS WASTE. RCRA CLA SSIFICATION: D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FLAME-SAFE FS/FST 900 SERIES FIRESTOP COMPOUNDS Preparer's Name:M. NAVARRO CAGE:45239 CAGE:45239 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND: 10.86 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: EXCESSIVE EXPOSURE MAY CAUSE DRYING AND CHAPPING. INHALATION: MAY CAUSE GAGGING, NAUSEA AND UPPER RESPIRATORY DISTRESS. INGESTION: POSSIBLE NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. DO NOT RUB. CONSULT MD IF IRRITATION PERSISTS. SKIN: WASH WITH MILD SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THIS PRODUCT WILL NOT BURN BUT MAY SPATTER IF THE TEMPERATURE EXCEEDS THE BOILING POINT. DRIED FILM MAY BURN IN AN INTENSE FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP ALL SPECTATORS AWAY. UNCONTAMINATED MATERIAL MAY BE RECOVERED AND REUSED. IF CONTAMINATED, SCOOP INTO RECEPTACLE FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SEAL CONTAINER WHEN NOT IN USE. STORE IN WELL VENTILATED AREA. Other Precautions:INFO & RECOMS OFFERED ARE FOR USERS CONSIDERATION & EXAMINATION & IS TO BE USED IN ADDN TO ALL OTHER INFO THAT IS AVAIL & PERTINENT. IT IS USER'S RESPONSIBILITY TO DETERMINE SUITABILITY OF ITS SPECIFI C CONDITIONS & PARTICULAR USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IN POORLY VENTILATED AREAS. Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION IS TO BE SATISFACTORY FOR NORMAL USAGE. Other Protective Equipment:AS NEEDED. Work Hygienic Practices:AVOID CONTACT WITH SKIN AND CLOTHING. WASH AFTER HANDLING AND LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:>1 Spec Gravity:1.077 Evaporation Rate & Reference:1 (H*2O=1) Solubility in Water:APPRECIABLE Appearance and Odor:WHITE MASTIC; MILD LATEX ODOR. Percent Volatiles by Volume:26 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND STRONG ALKALIS. Stability Condition to Avoid:STRONG ACIDS AND STRONG ALKALIS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, TRACE AMOUNTS OF NITROGEN AND ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW MATERIAL TO DRY. DISPOSE WASTE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDRATED LIME Preparer's Name:ARTHUR F GOHIKE CAGE:0JE83 CAGE:0JE83 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM HYDROXIDE; (LIME, CA(OH)2) CAS:1305-62-0 RTECS #:EW2800000 OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:SUPDAT:OCCUR IN FIRST 24 HRS PATIENT MAY IMPROVE FOR 2-4 DAYS & THEN HAVE SUDDEN ONSET OF SEV ABDOM PAIN, ABDOM (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:RIGIDITY & RAPID HYPOTENSION INDICATING DELAYED GASTRIC ESOPHAGEAL PERFORATION. CHRONIC:INHAL:BRONCHIAL (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:IRRIT W/CHRONIC COUGH. SKIN:CHRONIC DERM MAY FOLLOW RPTD CONT. EYE:PRLNGD CONT MAY CAUSE CONJUNCT. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:ATTN. EYES:WASH IMMED W/LARGE AMTS OF WATER, OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:OF CHEM REMAINS (AT LST 15 MIN). A NEAR NEUT SOLN OF 0.01-0.05 MOLAR SODIUM EDTA IS HELPFUL AS AN IRRIGANT (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:TO LOOSEN MASSES FORM TISS. GET MED ATTN IMMED. (GRANT, TOXICOLOGY OF EYE, VOL II). ADMIN OF DRUGS TO EYES (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:SHOULD BE PERFORMED BY QUALIFIED MED PERS. INGEST:DILUTE BY GIVING WATER/MILK TO DRINK IMMED & ALLOW VOMIT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:TO OCCUR. AS SOON AS POSS, EXAMINE MOUTH & THROAT & IRRIGATE INJURED AREAS W/1% ACETIC ACID UNTIL ALKALI (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:IS COMPLETELY NEUTRALIZED. AVOID GASTRIC LAVAGE/EMETICS. THESE MAY INCREASE POSSIBILITY OF PERFORATION. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:(DREISBACH, HANDBOOK OF POISONING, 11TH ED.). ADMIN OF DRUGS/ANTIDOTES SHOULD BE PERFORMED BY QUALIFIED (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:PERS. ANTIDOTE:GIVE CALCIUM GLUCONATE, 10 ML OF 10% SOLN DILUTED IN 1 LITER OF 5% GLUCOSE INTRAVANEOUSLY (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:AS NEC TO MAINTAIN NORM SERUM CALCIUM LEVELS. CALCIUM ADMIN MAY CAUSE ANURIA DUE TO PRECIPITATION OF (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CALCIUM OXALATE IN KIDNEY. (DREISBACH, HANDBOOK OF POISONING, 11TH ED). ANTIDOTES SHOULD BE GIVEN BY (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:QUALIFIED MEDICAL PERSONNEL. RTECS #:9999999ZZ Ingred Name:SPILL PROC:OF SPILLS SHOULD USE PROTECTIVE EQUIPMENT. RTECS #:9999999ZZ Ingred Name:EYE PROT:AND FULL LENGTH FACE SHIELD . RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:ANY POSSIBILITY THAT AN EMPLOYEE'S EYES MAY BE EXPOSED TO SUBSTANCE, EMPLOYER SHALL PROVIDE AN (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:EYE-WASH FOUNTAIN WITHIN IMMED WORK AREA FOR EMERGENCY USE. DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:CORR. INHAL:INHAL OF LOW CONC MAY CAUSE SORE THROAT, COUGHING, CHOKING & DYSPNEA. INTENSE EXPOS MAY RSLT IN TIGHTNESS IN CHEST & DELAYED PULM EDEMA. SOL OF SUBSTANCE ALLOWS FURTHER PENETRATION T HAT MAY CONTINUE FOR SEVERAL DAYS.SKIN:PENETRATES SLOWLY, PRDCNG SOFT, NECROTIC, DEEPLY PENETRATING (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:AREAS OF CONT. SOL ALLOWS FURTHER PENETRATION THAT MAY CONTINUE FOR SEVERAL DAYS. EXTENT OF DMG DEPENDS ON DURATION OF CONT. EYE:DIRECT CONT W/SOLID/AQUEOUS SOLNS MAY CAUSE CONJUNCT EDEMA &CORNEAL DESTRUCTION. BLINDNESS MAY OCCUR. INGEST:INGEST IS FOLLOWED BY SEV PAIN, VOMIT, DIARR & COLLAPSE. VOMIT(SUPDAT) Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP AFFECTED PERSON WARM & AT REST GET MED ATTN. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGEN T & LG AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MIN). IN CASE OF CHEM BURNS, COVER AFFECTED AREA W/STERILE, DRY DRESSING. BANDAGE SECURELY, BUT NOT TOO TIGHTLY. GET MED (ING 5) ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM. FOR LARGER FIRES USE WATER SPRAY, FOG OR ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CNTNR FROM AREA IF POSS. DO NOT SCATTER SPILLED MATL W/MORE WATER THAN NEEDED FOR FIRE CTL. (SUPDAT) Unusual Fire/Explosion Hazard:CA(OH)*2 IS INCOMBUSTIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP SPILLED POWDER AVOIDING DUSTING CNDTNS & PLACE IN CLEAN STEEL CNTNR FOR DISP. SFTY PERS SHOULD BE INVOLVED WHEN LG SPILLS OCCUR. TRACES OF RESIDUE CAN BE FLUSHED TO SEWER, BY NEUT BEFORE FLUSH ING MAY BE REQ. THOSE INVOLVED IN CLEAN-UP(ING 16) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE PROT EQUIP AS DESCRIBED IN CTL MEASURES. PROT AGAINST PHYSICAL DMG & STORE IN DRY PLACE AWAY FROM WATER/MOISTURE (NFPA 49, HAZ CHEM DATA,1975). Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:HIGH LEVELS:NIOSH/MSHA APPRVD SUPPLIED-AIR RESP W/FULL FACEPIECE, HELMET/HOOD. SCBA W/FULL FACEPIECE. FIREFIGHTING:NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE OPERATED IN PRESS-DEMAND OR OTHER POSITIVE-PR ESSURE MODE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION OR GENERAL DILUTION VENTILATION TO MEET PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EMPLOYEE MUST WEAR APPROP PROT CLTHG & EQUIP TO PVNT ANY POSSIBILITY OF SKIN CONT W/SUBSTANCE. WHERE THERE IS (ING 18) Work Hygienic Practices:DUST ACCUMULATIONS ON HANDS, FACE AND BODY SHOULD BE REMOVED BY WASHING OR SHOWERING PERIODICALLY AS NECESSARY. Supplemental Safety and Health FIRE FIGHT:DIKE FIRE CONTROL WATER FOR LATER DISP. MATLS TO AVOID:FORMATIONS OF AN EXPLOSIVE SALT. PHOSPHOROUS:WHEN BOILED W/ALKALINE HYDROXIDES YIELDS MIXED PHOSPHINES WHICH MAY IGNITE SPONTANEOUSLY IN AIR. WATER:FORMS CORR SOLN. EFTS OF OVEREXP:MAY CONTAIN BLOOD & DESQUAMATED MUCOSAL LINING. IF DEATH DOES NOT (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:M.P/F.P Text:1076F,580C Spec Gravity:2.2 Solubility in Water:.185% @ 0C Appearance and Odor:WHITE GRANULES OR POWDER; FAINT EARTHY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MALEIC ANHYDRIDE:EXPLOSIVE DECOM OF MALEIC ANHYDRIDE. NITROPARAFFINS, NITROMETHANE, NITROETHANE, NITROPROPANE: (SUP DAT) Stability Condition to Avoid:IT WILL ABSORB CARBON DIOXIDE WHEN EXPOSED TO AIR, FORMING CALCIUM CARBONATE. Hazardous Decomposition Products:WHEN HEATED AT TEMPERATURES ABOVE 580C, THE SUBSTANCE LOSES WATER TO FORM CALCIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRECAST POLYACRYLAMIDE ELECTROPHORESIS MINI-GELS, 61355 CAGE:IENU5 CAGE:IENU5 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLAMIDE. LD50 (ORAL, RAT): 295 MG/KG. CAS:79-06-1 RTECS #:AS3325000 < Wt:.2 OSHA PEL:0.3 MG/M3 ACGIH TLV:0.03 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM AZIDE. LD50 (ORAL, RAT): 27 MG/KG. CAS:26628-22-8 RTECS #:VY8050000 = Wt:.02 ACGIH STEL:C0.29 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM. CHRONIC: MAY CAUSE NEUROPATHY SUCH AS INCREASED SWEATING, TINGLING AND WEAKNESS IN THE HANDS AND FEET. UNSTEADY GAIT AND DECREASED REFLEXES MAY A LSO BE OBSERVED. SUSPECTED CANCER AGENT: EITHER ACUTE OR CHRONIC EXPOSURE MAY LEAD TO WEAK OR ABSENT REFLEXES. AN EARLY SIGN OF OVEREXPOSURE IS PEELING OF THE SKIN OF THE FINGERTIPS. Explanation of Carcinogenicity:ACRYLAMIDE: IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 60, PAGE 389, 1994: GROUP 2A. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: ANTICIPATED TO BE HUMAN CARCINO GEN. Effects of Overexposure:INHALED: AIRBORNE ACRYLAMIDE IS READILY ABSORBED THROUGH THE LUNG AND OVEREXPOSURE WILL PRODUCE SIGNS OF NEUROPATHY. CONTACT WITH EYES: SODIUM AZIDE: MAY CAUSE IRRITATION. ACRYLAMIDE: MAY CAUSE CONJUN CTIVAL EYE IRRITATION. ABSORBED THROUGHSKIN: ACRYLAMIDE: READILY ABSORBED THROUGH THE SKIN. MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM. INGESTION: NEUROTOXICITY FROM A SINGLE INGESTION CAN RESULT BUT IS MORE LIKELY TO OCCUR AFTER REPEATED INGESTION OF SMALL AMOUNTS OVER A PERIOD OF SEVERAL DAYS OR WEEKS. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY REMOVE ANY CONTAMI NATED CLOTHING WITHOUT DELAY. DO NOT RE-USE CONTAMINATED CLOTHING WITHOUT RE-LAUNDERING. WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DE VELOPS OR PERSISTS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. CONSULT MEDICAL PERSONAL. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: GIVE TWO GLASSES OF WATER AND THEN INDUCE VOMI TING. (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT COMBUSTIBLE. USE WHATEVER IS NEEDED TO PUT OUT SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:N/A. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ABSORB LIQUID SPILLS WITH A DRY INERT ABSORBENT MATERIAL. DO NOT PERMIT LIQUID SPILLS TO DRY. CONTAINERIZE ABSORBED MATERIAL FOR DISPOSAL IN APPROVED WASTE FACILITY. ======================Handling and Storage ====================== Handling and Storage Precautions:RECOMMENDED STORAGE CONDITIONS: REFREIGERATED, IN THE DARK. STORAGE TEMPERATURE MAXIMUM: 60 DEG F/-15 DEC C. KEEP CONTAINER TIGHTLY SEALED TO PROTECT QUALITY. STORE AT 4-10 DEG CELSIUS. KEEP AWAY FROM HEAT SOURCES. RESPIRATORY EQUIPMENT MUST BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED WHEN SUFFICIENT VENTILATION IS PROVIDED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GOOD ENCLOSURE AND LOCAL VENTILATION SHOULD BE PROVIDED. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR LAB COAT OR APRON. ON INSIDE. WASH HANDS AFTER USING & BEFORE EATING. DO NOT EAT, SMOKE OR DRINK IN WORK AREA. Supplemental Safety and Health FIRST AID PROC: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. SOL IN H*2O: UNPOLYMERIZED MATERIAL SOLUBLE IN ANY PROPORTIONS. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:SAME AS H*2O Spec Gravity:1.0 Solubility in Water:SUPDAT Appearance and Odor:CLEAR GEL AND PACKAGING BUFFER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AND REDUCING AGENTS, BRASS, ALUMINUM, COPPER, IRON AND PEROXIDES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA AND/OR OXIDES OF NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:ACRYLAMIDE (100%): LD50 (DERMAL) RABBIT = 252 MG/KG. SODIUM AZIDE: LD50 (DERMAL) RABBIT= 20 MGKG. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE DONE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS ON SPILL REPORTING, WASTE HANDLING AND WASTE DISPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING NAME: NONE.DOT HAZARD CLASS: NOT REGULATED.DOT REPORTABLE QUANTITY: NONE. UNITED NATIONS INFORMATION: U.N. NUMBER: N/A. U.N. CLASS: N/A. ECOLOGICAL INFO (CONT): VAPORS OR MIS TS. NOTES ON EYE IRRITATION: SEVERELY IRRITATING. IF NOT REMOVED PROMPTLY, WILL INJURE EYE TISSUE, WHICH MAY RESULT IN PERMANENT DAMAGE. OTHER NOTES ON TOXICITY: SENSITIZER. RAW MATERIAL NAME: CUMEN E HYDROPEROXIDE. ORAL LD50, SPECIES TESTED: 800.0 MG/GK RAT; 382.0 MG/KG RAT. NOTES ON ORAL TOXICITY: CORROSIVE TO MOUTH, ESOPHAGUS AND STOMACH. NOTES ON DERMAL TOXICITY: CORROSIVE, CAUSES PERMANENT S KIN DAMAGE. (SARA III) ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1900 AND OF 40 CFR 372: CHEMICAL NA MES: ACRYLAMIDE. CAS NUMBERS: 00079-06-1 PERCENT: <0.2%. APPROX. WT. EXPOSURE LIMITS IN AIR. 0.03 MG/M3 (SKIN). CHEMICAL NAMES: SODIUM AZIDE. CAS NUMBERS: 26628-22-8 PERCENT: 0.02%. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIQUID SULFUR DIOXIDE Preparer's Name:A.D. SOOS CAGE:3U945 CAGE:22360 CAGE:3U945 ============= Composition/Information on Ingredients ============= Ingred Name:SULFUR DIOXIDE CAS:7446-09-5 RTECS #:WS4550000 Fraction by Wt: >99% OSHA PEL:2 PPM;5 PPM STEL ACGIH TLV:2 PPM;5 PPM STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN CONTACT WITH LIQUID SILICON DIOXIDE MAY CAUSE FROSTBITE. RESPIRATORY AILMENTS (COUGHING, SUFFOCATION, BRONCHITIS, LUNG AND THROAT IRRITATION AND DAMAGE) ARE POSSIBLE ACUTE AND CHRONIC EFFE CTS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:OPEN WOUNDS AND SORES. RESPIRATORY DISEASES LIKE EMPHYSEMA, BRONCHITIS AND PNEUMONIA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES HOLDING LIDS OPEN. SEE PHYSCIIAN. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING. SEE PHYSICIAN. INHAL: REMOVE TO FRESH AIR-ADMINI STER OXYGEN. IF NOT BREATHING ADMINISTER ARTF RESP. SEE PHYSICIAN. INGEST: INDUCE VOMITING WITH WARM SOAPY WATER. SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT A FIRE HAZARD. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . COOL OUTSIDE OF CONTAINER WITH WATER IF EXPOSED TO FIRE TO AVOID OVERHEATING CONTRS CONTENTS. Unusual Fire/Explosion Hazard:THIS MATERIAL IS ALWAYS STORED IN PRESSURIZED CONTAINERS. A FIRE MAY WARM THE CONTENTS USING A RISE IN VAPOR PRESSURE AND POSSIBLE CONTAINER RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:ZONE OFF CONTAMINATED AREA. SILICON DIOXIDE WILL VAPORIZE RAPIDLY AND MAY CAUSE SERIOUS AIR POLLUTION. DILUTE AND ABSORB WITH WATER FROM UPWIND. SEE WASTE DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN SHADED COOL AREAS. REPAIR SMALL LEAKS IMMED. AVOID ROUGH HANDLING OF SILICON DIOXIDE CONTAINERS. Other Precautions:SILICON DIOXIDE EMISSIONS MAY EASILY BE A HAZARD OR NUISANCE TO NEIGHBORS. SILICON DIOXIDE MOISTURE WILLFORM CORROSIVE COMPOUNDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED GAS MASKS (LOW LEVELS), SCBA AT HIGH SILICON LEVELS. Ventilation:LOCAL EXHAUST: DISCHARGE AWAY FROM WORK AREA. Other Protective Equipment:ACID RESISTANT CLTHG, HARD OR SOFT TRIMMED HAT, STEEL TOED SFTY SHOES. FULL RUBB SUIT/SPACE SUIT IF CNDTNS ARE SEV. Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE. CHANGE CLOTHES DAILY. WASH HANDS/FACE BEFORE EATING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:14F,-10C Vapor Pres:2480@20C Vapor Density:2.3 Spec Gravity:1.43(H*2O=1) Solubility in Water:17 Appearance and Odor:CLEAR, COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI MATERIALS, WATER. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ABSORB SILICON DIOXIDE WITH WATER AND NEUTRALIZE (TP PH 7) SOLUTION WITH SODA ASH OR CAUSTIC SODA. COMPLY WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL GOVERNMENTAL REGULATIONS. SILICON DIOXIDE MAY BE CONSIDERED A HAZARDOUS WASTE UNDER RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRO-SEAL 890 B Kit Part:Y CAGE:83527 CAGE:83527 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE DIOXIDE (AS MANGANESE) CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 60% OSHA PEL:C,5 MG/M3/1 FUME TWA ACGIH TLV:5 MG/M3 DUST/1 FUME ===================== Hazards Identification ===================== Effects of Overexposure:MINOR IRRITANT TO EYES AND MUCOUS MEMBRANE ======================= First Aid Measures ======================= First Aid:SKIN-WASH WITH SOAP AND WATER. EYES-FLUSH WITH WATER FOR 15 MIN., CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:230F-110C SETA Extinguishing Media:CO2,FOAM,WATER SPRAY OR FOG Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CONTAINS MANGANESE DIOXIDE-MODERATE FIRE HAZARD. POWERFUL OXIDIZER. KEEP AWAY FROM HEAT ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP WITH INERT FILLER (SAND) AND PLACE IN DISPOSAL CONTAINER. DO NOT COMBINE WITH EASILY OXIDIZABLE MATERIALS. LARGE QUANTITIES SHOULD BE REACTED WITH BASE AND DISPOSED OF AS INERT MATERIAL ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 80F. AVOID PROLONGED HIGHER TEMPERATURES. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST AND MECHANICAL RECOMMENDED Supplemental Safety and Health KEY1:N1. ================== Physical/Chemical Properties ================== HCC:V5 Spec Gravity:200 Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS BLACK SLURRY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:DO NOT HEAT WITH EASILY OXIDIZED MATERIALS ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:21-30235 GREENVIEW CERTIFIED STARTER PLUS ENHANCERS CAGE:GO315 CAGE:GO315 CAGE:AGRIC ============= Composition/Information on Ingredients ============= Ingred Name:COMPOSTED POULTRY MANURE Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MILDLY IRRITATING TO SKIN & EYES. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:INGESTION: DRINK WARM WATER & INDUCE VOMITING BY TOUCHING BACK OF THROAT W/FINGER. INHALATION: REMOVE TO FRESH AIR & SUPPORT RESPIRATION. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:WATER SPRAY Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. REMOVE FROM AREA OF FIRE AT FIRST OPPORTUNITY. Unusual Fire/Explosion Hazard:IF HEATED TO DECOMPOSITION, WILL GIVE OFF FUMES OF AMMONIA. ================== Accidental Release Measures ================== Spill Release Procedures:IF MATERIAL IS NOT CONTAMINATED, TRANSFER INTO CONTAINER FOR REUSE. IF CONTAMINATED, SCOOP INTO CONTAINERS FOR DISPOSAL. INFORM AUTHORITIES IMMEDIATELY IF SEWERS OR WATER COURSES ARE CONTAMINATED. ======================Handling and Storage ====================== Other Precautions:DON'T EAT, DRINK OR SMOKE WHILE HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR SUITABLE NIOSH APPROVED DUST RESPIRATOR WITH TC-21C-XXX. Supplemental Safety and Health DENSITY: 40-50 PER CUBIC FOOT. ALTHOUGH GENERAL GUIDANCE HAS BEEN PROVIDED, THE DEGREE OF PROTECTION REQUIRED IN A PARTICULAR SITUATION DEPENDS ON FACTORS SUCH AS CONCENTRATION AND DURATION. ================== Physical/Chemical Properties ================== Solubility in Water:MODERATE Appearance and Odor:BROWN PELLET OR GRANULAR, ODOR TYPICAL OF POULTRY WASTE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3M BRAND RE-STICKABLE GLUE STICK Preparer's Name:HENRY SIMMONS CAGE:76381 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:38. Maxumum % Wt:42. Ingred Name:ACRYLIC POLYMER Minumum % Wt:37. Maxumum % Wt:41. Ingred Name:SODIUM STEARATE CAS:822-16-2 RTECS #:WI4725000 Minumum % Wt:7. Maxumum % Wt:10.5 ACGIH TLV:10 MG/M3 Ingred Name:POLYETHYLENE GLYCOL CAS:25322-68-3 RTECS #:TQ3500000 Minumum % Wt:2. Maxumum % Wt:5. ACGIH TLV:10 MG/M3 Ingred Name:POLYOXYETHYLENE MONOOCTYLPHENYL ETHER CAS:9036-19-5 RTECS #:MD0907600 Minumum % Wt:1. Maxumum % Wt:3. Ingred Name:N-VINYLPYRROLIDINONE POLYMER CAS:9003-39-8 RTECS #:TR8160000 Minumum % Wt:.5 Maxumum % Wt:2.5 Ingred Name:2-AMINOISOBUTANOL CAS:124-68-5 RTECS #:UA5950000 Minumum % Wt:1. Maxumum % Wt:2.5 Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 Minumum % Wt:0. Maxumum % Wt:.3 OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:EYE CONTACT IS NOT EXPECTED TO OCCUR DURING NORMAL USE OF THE PRODUCT. SINGLE EXPOSURE MAY CAUSE: MILD EYE IRRITATION; SIGNS/SYMPTOMS CAN INCLUDE REDNESS, SWELLING, PAIN, AND TEARING. SKIN CONTACT, I NHALATION, SWALLOWED: NO ADVERSE HEALTH EFFECTS ARE EXPECTED. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER. CALL A PHYSICIAN. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER. INHALATION AND SWALLOWED:NO FIRST AID IS ANTICIPATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET, SELF-CONTAINED, POSITIVE PRESSURE OR PRESSURE DEMAND BREATHING DEMAND APPARATUS, BUNKER COAT AND PANTS, BANDS AROUND ARMS, WAIST AND LEGS, FACE MASK, A ND PROTECTIVE COVERING FOR EXPOSED AREAS OF THE HEAD. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE. STORE AWAY FROM ACIDS. STORE AWAY FROM HEAT. STORE OUT OF DIRECT SUNLIGHT. KEEP CONTAINER DRY. KEEP CONTAINER IN WELL-VENTILATED AREA. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=54.C, 129.2F Vapor Pres:11 MMHG Spec Gravity:0.96 pH:10.7 Solubility in Water:APPREC. Appearance and Odor:SEMI-SOLID STICK IN A PLASTIC CONTAINER, FATTY ACID/ACRYLIC ODOR Percent Volatiles by Volume:40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN AN INDUSTRIAL OR COMMERCIAL FACILITY IN THE PRESENCE OF A COMBUSTIBLE MATERIAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:114 4906 HEXANES CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE CAS:110-54-3 RTECS #:MN9275000 = Wt:100. OSHA PEL:1800 MG/M3;500 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:INHALATION: HARMFUL. MAY CAUSE NERVOUS SYSTEM INJURY. SKIN: IRRITATION. HARMFUL IF ABSORBED. EYES: CAUSES IRRITATION. INGESTION: LOW ORAL TOXICITY. Effects of Overexposure:DIZZINESS, GIDDINESS, HEADACHE, NAUSEA, BLURRED VISION, LOSS OF APPETITE & WEIGHT, NUMBNESS, WEAKNESS OF ARMS & LEGS, IRRITATION ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. SKIN/EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-28.C, -18.4F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2, FOAM Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. USE WATER W/CAUTION. MATERIAL IS LIGHTER THAN WATER & INSOLUBLE IN WATER, THE FIRE COULD EASILY SPREAD BY THE USE OF WATER IN AN AREA WHERE THE WATER COULD NOT BE CONT AINED. WATER MAY BE INEFFECTIVE IN FIGHTING FIRE. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG THE GROUND/BE MOVED BY VENTILATION TO AN IGNITION SOURCE & FLASH BACK. VAPORS MAY IGNITE EXPLOSIVELY. PREVENT BUILDUP OF VAPORS TO EXPLOSIVE CONCENTRATIO NS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB MATERIAL IN VERMICULITE/OTHER SUITABLE ABSORBENT & PLACE IN IMPERVIOUS CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM HEAT, SPARKS, FLAME & CONTACT W/OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. USE W/ADEQUATE VENTILATION. COMPLY W/ALL FEDERAL, STATE & LOCAL CODES PERTAINING TO THE STORAGE, HANDLING, DISPENSING & DISPOSAL OF FLAMMABLE LIQUIDS. Other Precautions:MATERIAL IS EXTREMELY FLAMMABLE. STATIC ELECTRICITY CAN BUILD UP DURING THE HANDLING OF NONPOLAR HYDROCARBON SOLVENTS WHICH CAN CAUSE FLASH FIRE/EXPLOSION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF NEEDED. Ventilation:GENERAL ROOM VENTILATION SHOULD BE USED. LOCAL EXHAUST MAY BE NECESSARY TO CONTROL VAPOR CONCENTRATION TO ACCEPTABLE LEVELS. Other Protective Equipment:PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=68.C, 154.4F Vapor Pres:119 Spec Gravity:0.66 Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS LIQUID Percent Volatiles by Volume:100/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Stability Condition to Avoid:HEAT, SPARKS, FLAME Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE BY INCINERATION/CONTRACT W/LICENSED CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT/DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:FOR INFORMATION REGARDING THE TRANSPORTATION OF NEAREST YOU; ROCHESTER, NY 716-254-1300; OAK BROOK IL 312-654-5300;CHAMBLEE GA 404-455- 0123; DALLAS TX 214-241-1611; WHITTIER CA 213-945-1255; HONOLULU HI 808-833-1661. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S.O.S., 21640 Preparer's Name:P.T.W. CAGE:0CKF9 CAGE:0CKF9 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 2-6% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3;3 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:AMMONIUM HYDROGEN FLUORIDE; (AMMONIUM BIFLUORIDE) (CERCLA) CAS:1341-49-7 RTECS #:BQ9200000 Fraction by Wt: 2-6% OSHA PEL:2.5 MG/M3 (F) ACGIH TLV:2.5 MG/M3 (F) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PHOSPHORIC ACID (SARA 313) (CERCLA) CAS:7664-38-2 RTECS #:TB6300000 OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3;3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:MAY IRRITATE EYES OR EXPOSED MUCOUS MEMBRANES. DERMAL IRRITATION: SLIGHT. EYE IRRITATION: MODERATE. MAY CAUSE IRRITATION TO EXPOSED AREAS. INHALATION OF VAPORS MAY CAUSE DIZZINESS OR HEADACHE ON PROLONGED BREATHING. IF SWALLOWED MAY CAUSE GASTRIC IRRITATION. CHRONIC:NONE KNOWN. Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992:GRP 1. ANIMAL:PULM IRRIT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/FRESH WATER FOR AT LEAST 15 MINUTES. SEE MD IMMEDIATELY, BUT WASH FIRST. SKIN:WASH W/SOAP & WATER & RINSE WELL. INHAL:DO NOT BREATHE VAPORS. IF SYMPTOMS OCCUR, LEAVE AREA. INGEST:DRINK LA RGE QUANTITY OF WATER OR MILK. DO NOT INDUCE VOMITING. IF IRRITATION PERSISTS/SYMPTOMS OF INHALATION OCCUR, GET MEDICAL HELP. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK. NEUTRALIZE TO PH BETWEEN 6 & 10. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. AVOID EYE CONTACT. DO NOT INGEST. KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE ONLY. Other Precautions:CORROSIVE. DANGER! THIS CONTAINER HAZARD WHEN EMPTIED. SINCE EMPTIED CONTAINER RETAINS PRODUCT RESIDUES (VAPOR OR LIQUID), ALL LABELED HAZARD PRECAUTIONS MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL MECHANICAL VENTILATION. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . RUBBER APRON, COVERALLS, RUBBER BOOTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F,>93C Spec Gravity:1.03 (H*2O=1) pH:2-4 Appearance and Odor:CLEAR LIQUID. Percent Volatiles by Volume:<5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:OXIDES OF SULFUR & NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . NEUTRALIZED MATERIAL MAY BE FLUSHED TO SEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5% 5 ML-0315-05 ISOPTO HOMATROPINE CAGE:16703 CAGE:16703 ============= Composition/Information on Ingredients ============= Ingred Name:HOMATROPINE HYDROBROMIDE CAS:51-56-9 RTECS #:YM5602000 Fraction by Wt: 2% Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Fraction by Wt: 0.58% Ingred Name:POLYSORBATE 80 USP, POLYOXYETHYLENESORBITOL OLEATE, TWEEN 80 *96-2* CAS:9005-65-6 RTECS #:WG2932500 Fraction by Wt: 0.01% Ingred Name:METHYLBENZETHONIUM CHLORIDE CAS:1320-44-1 RTECS #:BO7380000 Fraction by Wt: 0.01% Ingred Name:HYDROXYPROPYL CELLULOSE CAS:9004-64-2 RTECS #:NF9050000 Fraction by Wt: 0.5% Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID HYDROCHLORIDE CAS:7647-01-0 RTECS #:MW4025000 Other REC Limits:7 PPM OSHA PEL:5 PPM ACGIH TLV:C 11 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM HYDROXIDE, CAUSTIC SODA, LYE CAS:1310-73-2 RTECS #:WB4900000 Other REC Limits:2MG/M3 CEILING NIOSH OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM CEILING EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER PURIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 1200 & 1400 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POSSIBLE ALLERGIC REACTION TO DUST IF INHALED, INGESTED/SKIN CONTACT. POISONOUS, EYE, SKIN, NOSE, THROAT & RESPIRATORY TRACT IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:DRYNESS OF MOUTH, DIFFICULTY SWALLOWING, THIRST, DILATION OF PUPILS, LOSS OF ACCOMODATION, PHOTOPHOBIA, INCREASED INTRAOCULAR PRESSURE, FLUSHING & DRYNESS OF SKIN, TRANSIENT BRADYCARDIA, TACHYCARDIA, PALPITATIONS, ARRHYTHMIAS, IRRITATION, BLURRED VISION, DRYNESS. Medical Cond Aggravated by Exposure:INDIVIDUALS DEVELOPING HYPERSENSITIVITY REACTIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. INGESTION: FLUSH OUT MOUTH W/WATER. IN THE TREATMENT OF AN OVERDOSE, EMESIS/LAVAGE OF TH E STOMACH W/4% TANNIC ACID SOLUTION & GIVE ACTIVATED CHARCOAL ARE RECOMMENDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROVED RESPIRATOR & CHEMICALLY CONTAINER FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHT CONTAINER. MATERIAL SHOULD BE HANDLED & STORED PER LABEL & OTHER INSTRUCTIONS TO ENSURE PRODUCT INTEGRITY. USE W/ADEQUATE DUST CONTROL. Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING. AVOID BREATHING DUST/MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:GENERAL/LOCAL EXHAUST Other Protective Equipment:APPROPRIATE LABORATORY APPAREL. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DON'T PERMIT EATING, DRINKING/SMOKING NEAR MATERIAL. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES, IODINE Hazardous Decomposition Products:CARBON OXIDES, NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOS 6 CAGE:65732 CAGE:65732 ============= Composition/Information on Ingredients ============= Ingred Name:1-HYDROXYETHYLIDENE-1,1-DIPHOSPHONIC ACID. (CONC= 60% APPROX, CALCULATED); (HEDP) Fraction by Wt: 60.0% Ingred Name:WATER, CAS 7732-18-5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40.0% ===================== Hazards Identification ===================== Effects of Overexposure:EYE:IRRT,BURNS.SKN:MOD IRRIT.INHL:N/R. INGEST:SL.TOXIC; IRRT, BURNS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH 15 MIN W/AMPLE WATER.SKN:WASH SOAP & WATER. INGEST: INDUCE VOMIT. CALL PHYS IMMED ALL CASES. MFR STATES HANDLE LIKE 75% PHOSPHORIC ACID. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILLAGE, PUMP TO DRUMS; OR COLLECT WITH BSORBENT MATERIAL AND PLACE IN PLASTIC OR STAINLESS STL CONTAINERS.MAY BE NEUTRALIZED W/LIME OR SODA ASH, WASHED TO SEWER WITH AMPLE WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE, SKIN CONTACT, 1NHL OR INGESTION. KEEP AWAY FROM HEAT SOURCES. Other Precautions:MFR REC REMOVAL AND THOROUGH CLEANING OF CONTAM CLOTHING, SHOES BEFORE REUSE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:GENERAL LOCAL Other Protective Equipment:RUBBER APRON & BOOTS. Supplemental Safety and Health LMSDS DATED: 8/83 ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:212F/100C Spec Gravity:1.47 Solubility in Water:COMPLETE Appearance and Odor:MILO ODOR; COLOR, CLEAR TO PALE YELLOW. PH<1 Percent Volatiles by Volume:40 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES Stability Condition to Avoid:CORROSIVE TO STEEL, ALUMINUM, BRASS. Hazardous Decomposition Products:NON-FLAMMABLE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW ALL LOCAL,STATE, FEDERAL REGULATIONS AS EPA WASTE #D002.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1047116,LIQUITEX ACRYLIC ARTIST COLOR 4.65( CAGE:BINNE CAGE:BINNE CAGE:85419 ============= Composition/Information on Ingredients ============= Ingred Name:ALIZARIN DYE; (ALIZARINE CRIMSON HUE) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: INERT, NUISANCE PARTICULATE DUST. SKIN: NON-TOXIC. INHAL: INERT, NUISANCE PARTICULATE DUST. INGEST: PRODUCT MAY BE IRRITATING TO GI TRACT IF INGEST. PRODS HAVE BEEN CERTIFIED AS NON-TOXIC BY ART & CRAFT MATLS INSTITUTE & CONFORM TO ASTM D 4236 STANDARD PRACTICE FOR LABELING ART MATLS FOR CHRONIC ADVERSE HLTH HAZ. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:NO SPECIFIC HAZARD IS KNOWN. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE AND RESPIRATORY DISORDERS, IMPAIRED FUNCTIONS FROM PRE-EXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTN IF ANY SYMPTOMS PERSIST. SKIN:WIPE EXCESS FROM SKIN AND FLUSH WITH WATER USING SOAP IF AVAILABLE. SEEK MEDICAL ATTN IF IRRITATIONOCCURS. INHAL:REMOVE VICTIM TO FRESH AIR AND TREAT SYMPTOMATICALLY. INGEST:CALL MD, HOSPITAL OR POISON CONTROL CENTER IF PRODUCT IS INGESTED. ===================== Fire Fighting Measures ===================== Flash Point:>212F,>100C Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CO2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PRODUCT AS SUPPLIED WILL SPLATTER AND BOIL ABOVE 212F. PRODUCT WHEN DRY MAY DECOMPOSE AND IGNITE ABOVE 400F. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP RESIDUE W/AN ABSORB SUCH AS CLAY, SAND/OTHER SUITABLE MATL; PLACE IN NON-LEAK CNTNRS FOR PROPER DISP. FLUSH AREA W/WATER TO REMOVE TRACE RESIDUE;DISPOSE OF FLUSH SOLN AS ABOVE.SM SPILLS-TAKE U P W/AN ABSORB MATL & PLACE IN NON-LEAK (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT INHALE SPRAY FROM AIRBRUSH/DUSTS FROM SANDING OPERATION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE GOOD VENT-FOR DUST/MISTS,USE NIOSH/MSHA CERTIFIED MASK. FOR AIR BRUSH: NIOSH/MSHA CERTIFIED RESP. DO NOT INHALE SPRAY FROM AIR BRUSH. FOR SANDING DRIED PAINT: USE NIOSH/MSHA CERTIFIED RESP. DO NOT INHALE FROM SANDING OPERATION. Ventilation:USE VENT AS REQ TO CONTROL VAP CONC. USE WINDOW EXHST FAN TO REMOVE VAPS & ASSURE ADEQ CROSS VENTILATION. Other Protective Equipment:EYEWASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAILABLE FOR USE IN AN EMERGENCY. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR PART NO: OZ TUBE ALIZARINE CRIMSON HUE. SPEC GRAV: 1.08-1.44 (H2O=1). % VOLAT: 50+/-10%. SPILL PROC:CNTNRS; SEAL TIGHTLY FOR PROPER DISPOSAL. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Density:>1 Spec Gravity:SUPP DATA Evaporation Rate & Reference:<1 (ETHER = 1) Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:CO2, CO AND UNIDENTIFIED (UNKNOWN) ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:50225 MULTI-PURPOSE GREASE & WHEEL BEARING LUBRICANT 35 LBS CAGE:DO899 CAGE:77493 CAGE:DO899 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM HYDROCARBONS, SOLVENT DEWAXED RESIDUAL OIL (PETROLEUM) *94-4* CAS:64742-62-7 Fraction by Wt: <90% Ingred Name:PETROLEUM OIL, HYDROTREATED HEAVY NAPHTHENIC DISTILLATE (PETROLEUM), PETROLEUM DISTILLATES, MINERAL OIL (SEVERE) CAS:64742-52-5 RTECS #:PY8035001 Fraction by Wt: <90% Ingred Name:LITHIUM 12 HYDROXYSTEARATE, LITHIUM SOAP THICKENER *94-4* CAS:7620-77-1 Fraction by Wt: 10% Ingred Name:ORGANIC ZINC COMPOUND Fraction by Wt: 3% Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: <90% Other REC Limits:5 MG/CUM ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE NO MORE THAN MINOR TRANSIENT IRRITATION. IF HIGHLY SENSITIVITYCOULD DEVELOP SKIN RASH & HYPERSENSITIVITY W/PROLONGED SKIN EXPOSURE. EYES: MAY BE A MINOR IRR ITANT. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, RASH, HYPERSENSITIVITY. ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING. SKIN: WASH W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: HIGH PRESSURE INJECTION OF THIS MATE RIAL SHOULD BE TREATED IMMEDIATELY. TREAT AS YOU WOULD ANY OTHER HYDROCARBON GREASE. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:350F Extinguishing Media:CO, FOAM, DRY CHEMICAL Fire Fighting Procedures:TREAT THIS MATERIAL AS ONE WOULD ANY OTHER HIGH FLASH POINT PETROLEUM HYDROCARBON MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT & DISCARD. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORING NEAR HEAT & OPEN FLAME. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:NONE REQUIRED. Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. GOOD HYGIENE PRACTICE IS RECOMMENDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:700F Vapor Pres:0.01 Vapor Density:0 Spec Gravity:0.9 Evaporation Rate & Reference:(BU AC = 1): 0.01 Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER SEMI-SOLID BUTTERY PASTE W/SLIGHT TALLOW LIKE ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAME. Hazardous Decomposition Products:CO, CO2, HYDROGEN, SULFUR, PETROLEUM HYDROCARBON VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HILLYARD LIQUID SWABBY II, 104 CAGE:CANBE CAGE:CANBE CAGE:28745 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313) (CERCLA) CAS:7647-01-0 RTECS #:MW4025000 Fraction by Wt: 9.50% OSHA PEL:C 5 PPM ACGIH TLV:C 5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-ALKYL DIMETHYLBENZYL AMMONIUM CHLORIDE CAS:68391-01-5 Fraction by Wt: 0.05% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DODECYL DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE CAS:27479-28-3 Fraction by Wt: 0.05% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:CAUSES CHEMICAL BURNS. SIGNS & SYMPTOMS:IRRITATION, BURNING OF SKIN, MUCOUS MEMBRANES AND RESPIRATORY SYSTEM. CHRONIC:NONE LISTED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PERSONS WITH RESPIRATORY AILMENTS MAY FIND THOSE CONDITIONS AGGRAVATED DURING PERSONAL USE OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MINS. GET MED ATTN. SKIN:FLUSH IMMED W/COOL WATER. WASH W/SOAP & WATER. REMOVE CONTAMD CLTHG. INHAL:REMOVE TO FRESH AIR. GET MED ATTN. INGEST:DO NOT IN DUCE VOMITING. GIVE MILK, WATER/EGG WHITES & GET MED ATTN IMMED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NOT APPLICABLE. Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:RELEASE OF CORROSIVE HYDROGEN CHLORIDE GAS MAY RESULT AT ELEVATED TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA TO DISSIPATE FUMES. CONTAIN SPILL AND COLLECT IN APPROVED CONTAINER. Neutralizing Agent:RINSE WITH DILUTE BICARBONATE SOLUTION TO NEUTRALIZE RESIDUE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. USE WITH TOILET BOWL MOP OR APPLICATOR. USE ONLY ACCORDING TO LABEL DIRECTIONS. DO NOT MIX W/OTHER CHEMICALS. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN OR EYES. AVOID PROLONGED BREATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST:ADEQUATE. Other Protective Equipment:RUBBER APRON AND BOOTS. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES APPLY. Supplemental Safety and Health EYE PROT:FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.050 (H*2O=1) Evaporation Rate & Reference:NOT KNOWN Solubility in Water:COMPLETE Appearance and Odor:GREEN BLUE COLOR/SASSAFRAS ODOR. Percent Volatiles by Volume:95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AMMONIA; BLEACH - DO NOT MIX WITH OTHER CHEMICALS. Stability Condition to Avoid:CONTACT WITH LIGHT METALS MAY GENERATE HYDROGEN GAS. Hazardous Decomposition Products:CHLORINE GAS; HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE/UNUSED MATL MAY BE RENDERED NON-HAZ BY NEUT W/DILUTE ALKALINE SOLN. CAUTION-NEVER ADD CONCENTRATED ALKALI TO PROD. TRIPLE RINSE CNTNR, WRAP & DISCARD IN TRASH. DISPOSAL MUST BE I/A/W FEDERAL, ST ATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLYAMID, COMP II UO-082 Kit Part:Y CAGE:DO165 CAGE:DO165 CAGE:5V430 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 20-50% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 20-50% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:TOXICITY MAY CAUSE HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF CONSCIOUSNESS. EYE IRRITATION, IRRITATED MUCOUS MEMBRANES, VOMITING DUE TO INGESTION, DEFATTING AND DRYING OF THE SKIN. Effects of Overexposure:OVEREXPOSURE MAY PRODUCE VARIOUS EFFECTS-ACUTE TOXICITY, EYE IRRITATON, IRRITATED MUCOUS MEMBRANES, VOMITING, SKIN IRRITATION & DERMATITIS. ======================= First Aid Measures ======================= First Aid:DO NOT INDUCE VOMITING, EYE CONTACT-FLUSH EYES WITH WATER FOR 15 MINUTES, INHALATION-REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF NECESSARY. KEEP VICTIM QUIET. SKIN CONTACT-FLUSH WITH WATER-REMOVE CONTAMINATED CLOTHING, WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:22F/-5.56C Lower Limits:2. Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL Fire Fighting Procedures:WATER MAY BE USED TO KEEP EXPOSED CONTAINERS COOL AND TO KEEP FLAMMABLE STRUCTURES WET. DO NOT ENTER FIRE AREA W/O PROPER PROTECTION. Unusual Fire/Explosion Hazard:SEALED CONTAINERS MAY EXPLODE IF OVERHEATED. WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:TREAT AS A HAZARDOUS-FLAMMABLE MATERIAL. KNOW APPLICABLE DOT REGULATIONS BEFORE ATTEMPTING TO TRANSPORT THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MUST PROVIDE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS BELOW ESTABLISHED TLV LIMIT. IN MORE CONFINED AREAS A NIOSH-MSHA APPROVED RESPIRATOR EQUIPPED WITH ORGANIC VAPOR CARTRIDGE SHOULD BE WORN Ventilation:MUST PROVIDE ADEQUATE VENTILATION Other Protective Equipment:HAVE EYE BATH AVAILABLE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175-180F Vapor Density:>AIR Evaporation Rate & Reference:2.35 X N-BUTYL ACETATE Appearance and Odor:CLEAR LIQUID Percent Volatiles by Volume:78.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS AND STRONG ALKALIES. Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND INCOMPATIBILITIES ABOVE HIGH TEMPERATURE, STRONG OXIDIZING CONDITIONS. Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH CURRENT LOCAL, STATE AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-83286, 36270, 03GY129 Kit Part:Y Preparer's Name:NORM GAUL CAGE:33458 CAGE:33458 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL 3-ETHOXYPROPIONATE (SARA 313) (VAPOR PRESSURE: .7 MM HG) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 20% Other REC Limits:NONE SPECIFIED Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PMGE ACETATE (VAPOR PRESSURE: 3.8 MM HG) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: <0.1% Other REC Limits:RECOMM TLV: 100 PPM ACGIH TLV:NOT EXTABLISHED Ingred Name:DIBUTYLTIN DILAURATE (VAPOR PRESSURE: .2 MM HG) CAS:77-58-7 RTECS #:WH7000000 Fraction by Wt: <0.1% Other REC Limits:NONE SPECIFIED ACGIH TLV:.1MG/M3;.2MG/MC STEL Ingred Name:VOC: 522 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED Ingred Name:METHYL ETHYL KETONE (SARA III) (VAPOR PRESSURE 70 MM HG @ 68 F) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 11.2% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 PPM STEL ACGIH TLV:200 PPM/300 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (SARA III) (VAPOR PRESSURE 86 MM HG @ 68 F) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM ACGIH TLV:400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ANTI MAR AGENT (VAPOR PRESSURE 0 MM HG) Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED Ingred Name:XYLENE (SARA III) (VAPOR PRESSURE 21 MM @ 100 F) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 0.05% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 PPM STEL ACGIH TLV:100 PPM/150 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) (VAPOR PRESSURE 7.1 MM HG @ 68 F) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.02% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 PPM STEL ACGIH TLV:100 PPM/125 PPM STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:DIBUTYLTIN DILAURATE (VAPOR PRESSURE .2 MM HG @ 320 F) CAS:77-58-7 RTECS #:WH7000000 Fraction by Wt: <0.1% Other REC Limits:NONE SPECIFIED ACGIH TLV:0.1 MG/M3 Ingred Name:BARIUM SULFATE (SARA 313) (THIS PRODUCT CONTAINS A BARIUM COMPOUND, 58.9% BY WEIGHT) CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 1.390% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:VOC: 522 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VAPORS IRRITATING TO EYES/NOSE/THROAT. INHALATION: IRRITATION, ACUTE NERVOUS SYSTEM DEPRESSION. CHRONIC: PROLONGED CONTACT WILL CAUSE DEFATTING ACTION, SKIN SENSITIZATION, ASTHMA OR OTHER ALLER GIC RESPONSES MAY DEVELOP. INGESTION: IRRITATION. ASPIRATION CAN CAUSE CHEMICAL PNEUMONITIS. Effects of Overexposure:INHAL: DIFFICULT BREATHING, HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: IRRIT (SWELLING/REDNESS/RASH). EYES: REDNESS, TEARING, SWELLING W/STINGING. SKIN: PROLONGED/RE PEATED--MODERATE IRRIT, DRYING, SKIN CRACKING. INGEST: VOMIT. IRRIT. CORROSIVE TO MOUTH, STOMACH & DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMED/DELAYED BY SEVERAL HRS). GET MED AID. SKIN: REMOVE CONTAM CLOTHING. WASH AREA W/SOAP & WATER. WASH CONTAM C LOTHING BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER (LOW PRESSURE)--15 MIN, LIFTING UPPER/LOWER LIDS. GET MED AID. INGESTION: DON'T INDUCE VOMIT. NOTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:24.0F,-4.4C Lower Limits:1.05% Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:FULL FIRE FIGHTING EQUIP W/SCBA & FULL PROTECTIVE CLOTHING SHOULD BE WORN. WATER USED TO COOL CLOSED CONTAINERS/PREVENT PRESSURE BUILD-UP/AUTO IGNIT/EXPLOSION. Unusual Fire/Explosion Hazard:KEEP FROM IGNITE SOURCES. CLOSED CNTNR MAY EXPLODE W/HEAT. USE SPECIAL PRECAUTION W/APPLIC TO HOT SRFCS. DURING EMERG COND, OVEREXPOS TO DECOMP PROD/HEALTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDG IN COMPLIANCE W/OSHA 1910.106. AVOID HIGH TEMP, IGNITION SOURCES. STORE IN TIGHTLY CLOSED CONTAINERS. STORE IN WELL VENT AREAS. Other Precautions:KEEP CNTNRS TIGHT/UPRIGHT (PREVENT LEAKAGE). NO PROLONGED BREATHING OF VAPORS/SPRAY MISTS. AVOID CONTACT W/SKIN/EYES. DO NOT TAKE INTERNALLY. DO NOT HANDLE UNTIL THE SAFETY PRECAUTIONS HAVE BEEN READ/ UNDERSTOOD. SMOKE ONLY IN SMOKING AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR RECOMMENDED/APPROVED FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED) IS NECESSARY. OBSERVE OSHA REGULATIONS--RESPIRATOR USE. VENT SHOULD BE PROVIDED TO KEEP EXPOSURE LEVELS BELOW OSHA PERMISSIBLE LIMITS. Ventilation:EXHAUST VENT SUFFICIENT TO KEEP AIRBORNE CONC (MIST/VAPOR) BELOW TLV'S MUST BE USED. REMOVE ALL IGNITION SOURCE. Other Protective Equipment:FACE SHIELDS. THE USE OF LONG SLEEVE AND LONG LEG CLOTHING IS RECOMMENDED. Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:169 TO 338F Vapor Density:> AIR Spec Gravity:1.25 Viscosity:* Evaporation Rate & Reference:2.55 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:GRAY LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:58.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED IN ACCORD W/FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED W/CARE (PRODUCT RESIDUE/FLAMMABLE VAPOR). DON'T INCINERATE CLOSED CNTNRS. EPA HAZARDOUS WASTE #: D001, F003, F005.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SONOPLEX HDR (BASE) Kit Part:Y Preparer's Name:CATHY GRIFFITH CAGE:GO273 CAGE:63472 CAGE:GO273 ============= Composition/Information on Ingredients ============= Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN, EPOXY RESIN, EPON 820, ARALDITE 6004, 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN CAS:25068-38-6 RTECS #:KD4380000 Fraction by Wt: 80-100% Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 1-3% Ingred Name:BUTANOL, N-BUTYL ALCOHOL, PROPYL CARBINOL, BUTYL ALCOHOL CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1-5% Other REC Limits:300 MG/CUM OSHA PEL:100 PPM ACGIH TLV:C 152 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FORMALDEHYDE, FORMALIN (2A CARCINOGEN BY NTP, IARC, OSHA) INTENDED CHANGE CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 0.1% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:WEIGHT PER GALLON IN POUNDS: 0.0 RTECS #:9999999WG ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 11400 MG/KG (SEE SUPP) Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES: MODERATE IRRITATION, REVERSIBLE CORNEAL INJURY. SKIN: MODERATE IRRITATION, DERMATITIS & ALLERGIC RESPONSES. REPEATED OR PROLONGED OVEREXPOSURE MAY CAUSE SENSITIZATION. INHALATION: RESPIRATORY IR RITATION WHEN HEATED TO HIGH TEMPS. REPEATED EXPOSURE: INJURY TO LIVER/KIDNEYS/CNS. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:INGESTION: NAUSEA & VOMITING. Medical Cond Aggravated by Exposure:PULMONARY & DERMATOLOGICAL DISORDERS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS THOROUGHLY. INHALATION: REMOVE TO FRESH AIR. IF NECESSARY, GIVE OXYGEN & CPR. INGESTION: DON 'T INDUCE VOMITING. GIVE WATER/MILK IF CONSCIOUS. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT ASPIRATION. CALL PHYSICIAN IMMEDIATELY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:275F Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. USE WATER TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE MAY CAUST FROTHING W/SUBSEQUENT SPREAD OF FIRE. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CLOSED CONTAINERS MAY RUPTURE OR EXPLODE (DUE TO PRESSURE BUILD-UP) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE EQUIPMENT DURING CLEANUP. SHUT OFF SOURCE OF LEAK SAFELY. DIKE/CONTAIN/ABSORB. SWEEP/SHOVEL INTO CONTAINERS W/LIDS. COVER LOOSELY/REMOVE TO WASTE AREA. WASHAREA. PREVENT FROM ENTERING WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:FOR PROFESSIONAL USE ONLY. AVOID CONTACT W/EYES, SKIN, & CLOTHING. DON'T REUSE EMPTY CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED OF IF POORLY VENTILATED AREAS, USE NIOSH-APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR. USE NIOSH-APPROVED RESPIRATOR FOR DUSTS & MISTS WHEN GRINDING OR MACHINING CURED COMPOUND. Ventilation:LOCAL EXHAUST: AS NEEDED TO CONTROL VAPOR/DUST LEVELS TO BELOW RECOMMENDED LIMITS. Other Protective Equipment:CLEAN PROTECTIVE CLOTHING Supplemental Safety and Health LD50 INFORMATION IS FOR BISPHENOL-A EPOXY RESIN. ================== Physical/Chemical Properties ================== Vapor Pres:<0.01 Vapor Density:>1 Spec Gravity:1.08 Evaporation Rate & Reference:SLOWER THAN BU AC Solubility in Water:NEGLIGIBLE Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES OR OXIDANTS, STRONG LEWIS OR MINERAL ACIDS, LARGE QUANTITIES OF AMINES Stability Condition to Avoid:EXTREME HEAT & OR SOURCES OF IGNITION Hazardous Decomposition Products:ACRID FUMES, OXIDES OF CARBON, ALDEHYDES & ACIDS, PHENOLS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. COMBUSTIBLE LIQUID.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AM4153/601AL CAGE:84772 CAGE:84772 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:IRON (III) OXIDE; (IRON OXIDE) CAS:1309-37-1 RTECS #:NO7400000 OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3 FUME (FE) Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <0.1% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURY (SARA 313) (CERCLA) CAS:7439-97-6 RTECS #:OV4550000 Fraction by Wt: <0.1% OSHA PEL:0.1 MG/M3, C ACGIH TLV:0.025 MG/M3, S EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ACRYLIC ACID, ETHYL ESTER; (ETHYL ACRYLATE) (SARA 313) (CERCLA) CAS:140-88-5 RTECS #:AT0700000 Fraction by Wt: <0.1% OSHA PEL:25 PPM, S ACGIH TLV:5 PPM;15 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ARSENIC (SARA 313) (CERCLA) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CADMIUM (SARA 313) (CERCLA) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: <0.1% OSHA PEL:0.2 MG/M3 DUST ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3 DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ISOCYANIC ACID, METHYL-M-PHENYLENE ESTER; (TOLUENE DIISOCYANATE) (MIXED ISOMERS) (SARA 313) (CERCLA) CAS:26471-62-5 RTECS #:NQ9490000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:0.005 PPM;0.02 STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SELENIUM (SARA 313) (CERCLA) (MFR'S CAS NO:7446-34-6) CAS:7782-49-2 RTECS #:VS7700000 Fraction by Wt: <0.1% OSHA PEL:0.2 MG/M3 ACGIH TLV:0.2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ACETIC ACID, VINYL ESTER; (VINYL ACETATE) (SARA 302/313) (CERCLA) CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: <0.1% OSHA PEL:10 PPM ACGIH TLV:10 PPM;15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CHROMIUM; (CHROMIUM (3+)) (SARA 313) (CERCLA) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <0.1% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:MATL AS SHIPPED POSES NO HLTH PROBS. PROCESSING THAT COULD RELS DUST SUCH AS SAWING, SANDING, EXCESSIVE HANDLING, ETC COULD RSLT IN MILD RESP IRRIT. EYE:DUST MAY TEMPORARILY IRRITATE. SKIN :NO EFT KNOWN. INGEST:UNLIKELY RTE OF EXPOS. INGEST OF SM AMTS HAS NO KNOWN EFT. SIGNS & SYMPS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 149, 1996:GROUP 2B. Effects of Overexposure:HLTH HAZ:OVEREXP (BY DUST):EYE/RESP TRACT ITCHING, SCRATCHING OR DRYNESS. THIS PROD MAY CONTAIN TRACE LEVELS OF COMPONENT(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPRO HAR M. NOTE:TOLUENE, MERCURY & LEAD APPEAR ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES, WHILE HOLDING EYELIDS OPEN. CONSULT MD IF IRRITATION PERSISTS. INHAL:REMOVE EXPOSED PERSON TO FRESH AIR. SKIN:WASH EXPOSE D AREAS W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:CLASS A OR B EXTINGUISHMENT, E.G., DRY CHEMICAL, FOAM, CARBON DIOXIDE OR WATER. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PRODUCT IS COMBUSTIBLE PLASTIC FILM. ================== Accidental Release Measures ================== Spill Release Procedures:FOR PERSONAL PROTECTION SEE "PROTECTION FROM OVEREXPOSURE" SECTION. VACUUM DUST THAT MAY BE GENERATED & DISPOSE OF ACCORDING TO APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TO MAINTAIN QUALITY OF MATL, STORE IN COOL, DRY ATMOSPHERE, 60-80F, 40% RELATIVE HUMIDITY. NO SPECIAL SAFETY PRECAUTIONS ARE NECESSARY FOR STORAGE. Other Precautions:DUST PRODUCED IN SAWING, SANDING, EXCESSIVE HANDLING MAY BE IRRITATING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION/CONTAINMENT MEASURES DO NOT RELIABLY PROTECT AGAINST INHALATION OVEREXPOSURE, WEAR NIOSH APPROVED RESPIRATOR SUITABLE FOR PROTECTION FROM DUST CONCENTRATIONS ENCOUNTERED. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION THAT CAPTURES DUST DURING SAWING OR SANDING OPERATIONS. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER AFTER HANDLING & ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health CNDTNS (STAB):SMOKE & ACRID FUMES. HAZ DECOMP PROD:HYDROGEN CHLORIDE & ACETIC ACID. EFTS OF OVEREXP:HLTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO . ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE Appearance and Odor:METALLIZED COATED POLYESTER FILM, VARIOUS COLORS; CHARACTERISTIC ODOR. Percent Volatiles by Volume:1.5MAX ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DOES NOT REACT W/ANY COMMON SUBSTANCE. Stability Condition to Avoid:STABLE WHEN HEATED EXCEPT PROD MAY BECOME UNUSABLE (BLOCK). PRLNG HEATING AT ELEVATED TEMPS >300F CAN GENERATE (SUPDAT) Hazardous Decomposition Products:PRODS OF COMBUST:CAN INCL CARBON MONOXIDE, CARBON DIOXIDE, SM QTYS OF NITRIC OXIDES (NO*X), TRACE LEVELS OF (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:FOR DISPOSAL, INCINERATE OR LANDFILL THIS MATERIAL ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRICHEM 914 EPOXY HARDENER CAGE:TRIMO CAGE:TRIMO ============= Composition/Information on Ingredients ============= Ingred Name:MODIFIED POLYAMINE REACTION PRODUCT Fraction by Wt: 90% Ingred Name:PHENOL,CARBOLIC ACID SOLUTION CAS:108-95-2 RTECS #:SJ3325000 Fraction by Wt: 10% Other REC Limits:5 MG/CUM OSHA PEL:19 MG/CUM ACGIH TLV:19 MG/CUM (SKIN) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION/CORNEAL INJURY/PERMANENT VISION IMPAIRMENT/BLINDNESS. SKIN: SEVERE INJURY/SENSITIZATION/ALLERGIC RESPONSES/ABSORPTION/WHITENING. INGESTION: GASTROINTESTINAL IRRITATION/ULCERATION/ABSO RPTION THRU MUCOUS MEMBRANE & GASTROINTESTINAL/CORROSIVE/STRICTURE. INHALATION: RESPIRATORY SENSITIZATION/ASTHMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION/CORNEAL INJURY/PERMANENT VISION IMPAIRMENT/BLINDNESS. SKIN: SEVERE INJURY/SENSITIZATION/ALLERGIC RESPONSES/ABSORPTION/WHITENING. INGESTION: GASTROINTESTINAL IRRITATION/ULCERATION/ABSO RPTION THRU MUCOUS MEMBRANE & GASTROINTESTINAL/CORROSIVE/STRICTURE. INHALATION: RESPIRATORY SENSITIZATION/ASTHMA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15-30 MINS. INGESTION: DON'T INDUCE VOMITING. GIVE LARGE AMOUNTS OF WATER OR MILK. SKIN: FLUSH W/WATER & TREAT AS THERMAL BURN. INHALATION: REMOVE TO FRESH A IR. OBTAIN MEDICAL ATTENTION IN ALL CASES. PHYSICIAN NOTE: IF LAVAGE IS PERFORMED, DO ENDOTRACHEAL &/OR ESOPHAGOSCOPIC CONTROL. NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:200F Lower Limits:1.5% Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2 OR DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE UP OR PUMP TO APPROPRIATE CONTAINER. USE NONCOMBUSTIBLE ABSORBANT MATERIAL/SAND & SHOVEL INTO CONTAINER. COLLECT IN WASTE DRUMS & SEAL FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:GROUND ALL TRANSFER EQUIPMENT. HOLD BULK STORAGE UNDER A NITROGEN BLANKET. PRODUCT SHOULDN'T COME IN CONTACT W/COPPER OR COPPER-BEARING ALLOYS. Other Precautions:USE ONLY W/ADEQUATE VENTILATION. FOLLOW GOOD HOUSEKEEPING PROCEDURES. AVOID BREATHING VAPORS/GASES RELEASED ON EXPOSURE AT HIGH TEMPERATURES. AVOID CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AN APPROVED AIR-PURIFYING RESPIRATOR OR FULL-FACE RESPIRATOR FOR EXPOSURE >TLV. Ventilation:GENERAL LOCAL EXHAUST WHEN REQUIRED Other Protective Equipment:IMPERVIOUS CLOTHING, BOOTS, APRON, FULL-BODY SUIT, SAFETY SHOWER, & EYE WASH FOUNTAIN. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING. CONTAMINATED LEATHER ITEMS/SHOES/BELTS/WATCHBANDS SHOULD BE REMOVED/DESTROYED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:356F Vapor Pres:76 Vapor Density:3.24 Spec Gravity:1.08 Solubility in Water:SLIGHT Appearance and Odor:AMBER COLORED LIQUID W/MODERATE AMINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EPOXY RESINS AT ELEVATED TEMPERATURES, UNCONTROLLED CONDITIONS, COPPER OR COPPER-BEARING ALLOYS Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:POISONOUS GASES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN LANDFILL OR INCINERATE IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: DETOXI-GEL, 0020344 Cage: 60088 Box: 117 Resp. Party Other MSDS No.: 99 ======================================================= Contractor Summary ======================================================= Cage: 60088 Box: 117 ======================================================= Ingredients ======================================================= ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE AND CHRONIC: NONE SPECIFICED BY MANUFACTURER. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: THERE IS NO KNOWN EFFECT FROM CHONIC EXPOSURE TO THIS PRODUCT. REPEATED OR PRLONGED EXPOSURE IS NOT KNOWN TO AGGRAVATE MEDICAL CONDITION. First Aid: EYE CONT: NO KNOWN EFFECT ON EYE CONT, RINSE WITH WATER FOR AT LEAST 15 MINUTES. SKIN CONT: NO KNOWN EFFECT ON SKIN CONT, RINSE WITH WATER FOR A FEW MINUTES. INHAL: ALLOW VICTIM TO REST IN WELL VENTIL ATED AREA. SEEK IMMEDIATE MEDICAL ATTENTION. INGEST: DO NOT INDUCE VOMITING. EXAMINE LIPS & MOUTH TO ASCERTAIN WHETHER TISSUES ARE DAMAGED, POSS INDICATION THAT TOXIC MATL WAS INGESTED; ABSENCE OF SUC H SIGNS, HOWEVER IS NOT CONCLUSIVE. LOOSEN TIGHT CLTHG SUCH AS COLLAR, TIE, BELT/WAISTBAND. IF VICTIM IS NOT BRTHG, PERFORM MOUTH-TO-MOUTH RESUSCITATION. SEEK IMMED MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SM SPILL & LEAK:USE APPROP TOOLS TO PUT SPILLED SOLID IN CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY SPREADING WATER ON CONTMAD SURF & DISPOSE OF ACCORDING TO LOC & REGIONAL AUTHORITY REQUIREMEN TS. LG SPILL & LEAK: MFR'S DATABASE CNTNS NO ADDNL INFO IN CASE OF SPILL AND/OR LEAK OF PROD. USE SHOVEL TO PUT MATL INTO CONVENIENT WASTE DISP CNTNR. FINISH CLEANING BY SPREADING WATER ON (SUPDAT) Waste Disposal Methods: CONSULT YOUR LOCAL AUTHORITIES. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS (FP N). Handling And Storage Precautions: KEEP CONTAINER DRY. KEEP IN A COOL PLACE. GROUND ALL EQUIPMENT CONTAINING MATERIAL. KEEP CONTAINER TIGHTLY CLOSED. KEEP IN A COOL, WELL-VENTILATED PLACE. Other Precautions: COMBUSTIBLE MATERIALS SHOULD BE STORED AWAY FROM EXTREME HEAT AND AWAY FROM STRONG OXIDIZING AGENTS. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: SMALL FIRE: USE DRY CHEMICALS, CO*2, WATER SPRAY OR FOAM. LARGE FIRE: USE WATER SPRAY, FOG OR FOAM. DO NOT USE WATER JET. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: COMBUSTIBLE. RISKS OF EXPLOSION OF PRODUCT IN PRESENCE OF MECHANICAL IMPACT: NOT AVAILABLE. RISKS OF EXPLOSION OF THE PRODUCT IS PRESENCE OF STATIC DISCHARGE: NOT AVAILABLE. NO SPECIFIC INFO IS AVAIL IN MFR'S DATABASE REGARDING PROD'S RISKS OF EXPLOSION IN PRESENCE OF VARIOUS MATERIALS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: USE PROCESS ENCLOSURES, LOCAL EXHST VENT/OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW REC EXPOSURE LIMITS. (SUPDAT) Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). FULL SUIT. BOOTS. SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT SPECIALIST BEFORE HANDLING THIS PRODUCT. Supplemental Safety and Health: SPILL RELEASE: CONTAMD SURF & ALLOW TO EVACUATE THROUGH THE SANITARY SYSTEM. VENT: IF USER OPERATIONS GENERATE DUST, FUME/MIST, USE VENT TO KEEP EXPOSURE TO AIRBORNE CONTAMINANTS. ======================================================= Physical/Chemical Properties ======================================================= Appearance and Odor: OFF-WHITE SOLID. (GEL) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: NO SPECIFIC INFORMATION IS AVAILABLE IN MFR'S DATABASE REGARDING REACTIVITY OF THIS MATERIAL IN PRESENCE OF VARIOUS OTHER MATERIALS. Hazardous Decomposition Products: NOT AVAILABLE. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: TOX TO ANIMALS: LD50 & LC50: NOT AVAILABLE. CHRONIC EFTS ON HUMANS: NOT AVAILABLE. OTHER TOXIC EFTS ON HUMANS: NO SPECIFIC INFORMATION IS AVAILABLE IN MFR"S DATABASE REGARDING OTHER TOXIC EFFECTS OF T HIS MATERIAL FOR HUMANS. SPECIAL REMARKS ON TOX TO ANIMALS: NO ADDNL REMARK. SPEC REMARKS ON CHRONIC EFTS ON HUMANS: THERE ARE NO KNOWN HAZARDS ASSOC W/THIS PROD. SPECIAL REMARKS ON OTHER TOXIC EFTS O N HUMANS: THERE ARE NO KNOWN HAZARDS ASSOC W/THIS PRODUCT. ======================================================= Ecological Information ======================================================= Ecological: ECOTOXICITY: NOT AVAILABLE. BOD5 AND COD: NOT AVAILABLE. BIODEGRADABLE/OECD, MOBILITY: POSSIBLY HAZARDOUS SHORT TERM DEGRADATION PRODUCTS ARE NOT LIKELY. HOWEVER, LONG TERM DEGRADATION PRODUCTS MAY AR ISE. TOXICITY OF PRODUCTS OF BIODEGRADATION: NOT AVAILABLE. SPECIAL REMARKS ON PRODUCTS OF BIODEGRADATION: NO ADDITIONAL REMARK. ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: INTERNATIONAL REGULATIONS: W(CANADA): NOT CONTROLLED UNDER W(CANADA). NO PRODUCTS WERE FOUND. DSCL(EEC): NOT CONTROLLED UNDER DSCL(EUROPE). INTERNATIONAL LISTS: NO PRODUCTS WERE FOUND. ======================================================= Other Information ======================================================= Other Information: HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.): HEALTH - 0, FIRE HAZARD - 0, REACTIVITY - 0, PERSONAL PROTECTION - A. NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.): HEALTH: 0, FIRE HAZARD: 0, REACTIVI TY: 0. ======================================================= HAZCOM Label ======================================================= Product ID: DETOXI-GEL, 0020344 Cage: 60088 Company Name: PIERCE CHEMICAL COMPANY PO Box: 117 Zipcode: 61105 Label Required IND: Y Date Of Label Review: 03/31/2000 Status Code: A Origination Code: F Skin Protection IND: NO Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: None Contact Hazard: None Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE! ACUTE AND CHRONIC: NONE SPECIFICED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2-PROPENOIC ACID METHYL ESTER, O-1015 CAGE:84898 CAGE:84898 CAGE:8Y898 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC ACID, METHYL ESTER; (2-PROPENOIC ACID METHYL ESTER) CAS:96-33-3 RTECS #:AT2800000 OSHA PEL:S, 10 PPM ACGIH TLV:S, 10 PPM; 9495 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (RAT) 300 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT LENSES SHOULD NOT BE WORN IN THE LABORATORY. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! CAN BE HARMFUL IF ABSORBED THROUGH THE SKIN. CAN BE HARMFUL IF INHALE D. LACHRYMATOR-CAUSES SEVERE EYE IRRITATION. CAN CAUSE SKIN IRRITATION. CAN CAUSE AN ALLERGIC SKIN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:REACTION. VAPORS CAN CAUSE SEVERE EYE INFLAMMATION AND SWELLING AND ADJOINING TISSUES. REPEATED EXPOSURE TO VAPORS AND/OR DUST CAN CAUSE EYE INJURY. CAN BE HARMFUL IF SWALLOWED. NARCOTIC AT H IGH CONCENTRATIONS. CAN BE IRRITATING TO MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFT OF A POISON. IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE OBTAINED FROM POIS CTL CTR. IN CASE OF CONT:EYES:FLUSH CONTINUOUSLY W /H*2O FOR AT LEAST 15-20 MIN. SKIN:FLUSH W/H*2O FOR 15-20 MIN. IF NO BURNS HAVE OCCURRED-USE SOAP & H*2O TO CLEANSE SKIN. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYGEN IF PATIENT IS HAVING (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:42.8F,6.0C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NO EXPLOSION LIMITS ARE AVAILABLE FOR THIS COMPOUND. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA NIOSH/MSHA-REGULATED EQUIPMENT. ABSORB ON VERMICULITE OR SIMILAR MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SUR FACES TO REMOVE ANY RESIDUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE APPROP OSHA/MSMA APPRVD SAFETY EQUIP. AVOID CNTCT W/SKIN, EYES & CLTHG. KEEP TIGHTLY CLSD & STORE IN COOL DRY PLACE. STORE ONLY W/COMPAT CHEMS. Other Precautions:PERS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD NOT HNDLD THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LABORATORY USE ONLY! OUR PRODS MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PR ODS, FOOD ADDITIVES/AS HOUSEHOLD CHEMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:DIFFICULTY BREATHING. IF PATIENT HAS STOPPED BREATHING ADMINISTER ARTIFICAL RESPIRATIONS. IF PATIENT IS IN CARDIAC ARREST ADMINISTER CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MEDICAL ASSISTANCE HAS ARRIVED. INGEST:CALL MDIMMEDIATELY . EYE PROT:& FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:176F,80C Melt/Freeze Pt:M.P/F.P Text:-103F,-75C Spec Gravity:0.956 Solubility in Water:VERY SLIGHTLY SOL Appearance and Odor:COLORLESS LIQUID. PUNGENT, ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH STRONG BASES, STRONG ACIDS, STRONG REDUCING AGENTS, STRONG OXIDIZING AGENTS. REACTS WITH AMINES. Stability Condition to Avoid:SENSITIVE TO LIGHT - DARK COLORS DOES NOT AFFECT PURITY. SENSITIVE TO HEAT. MAY POLYMERIZE UPON STANDING. Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES. DECOMPOSITION PRODUCTS ARE CORROSIVE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEVRAN, DV201 CNVT Kit Part:Y Preparer's Name:H KLINE CAGE:NO217 CAGE:55849 CAGE:NO217 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) (CONTAINING ING 2 & 3). LD50: (ORAL,RAT) 10 G/KG CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <10% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 Fraction by Wt: 2.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMORPHOUS SILICA Fraction by Wt: 3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COPPER, (PHTHALOCYANINATO(2-))-; (PHTHALOCYANINE BLUE) (CONTAINING ING 5) CAS:147-14-8 RTECS #:GL8510000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENE, PENTACHLORO-; (PCB). % WT: <25 PPM CAS:608-93-5 RTECS #:DA6640000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IRON OXIDE; (SYNTHETIC IRON OXIDE (YELLOW) CAS:51274-00-1 Fraction by Wt: <15% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) Ingred Name:IRON (III) OXIDE; (IRON OXIDE (RED)) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG(FE)/M3 FUME, B2 Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA (CRYSTALLINE)) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <5% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM SILICATE) (CONTAINING INGS 10 & 11) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <5% OSHA PEL:0.2 FIBERS/CC ACGIH TLV:0.2 FIBER/CC, A1 Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:CHLORITE CAS:66588-14-5 Fraction by Wt: <3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA) (CONTAINING ING 13). VP: 6.6 @ 68F. LD50: (ORAL,RAT) 3.9 G/KG CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 24.06% OSHA PEL:100 PPM ACGIH TLV:100 PPM/150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA 313) (CERCLA). % WT: 5PPM CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA 313). VP: 7.1 @ 68F CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 5.56% OSHA PEL:100 PPM ACGIH TLV:100 PPM/125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BUTYL ALCOHOL (SARA 313) (CERCLA). VP: 4.3 @ 68F. LD50: (ORAL,RAT) 4.2 G/KG CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 5.09% OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:QUATERNARY AMMONIUM COMPOUNDS, BIS(HYDROGENATED TALLOW ALKYL)DIMETHYL-, SALT W/BENTONITE; (CLAY) (CONTAINING ING 17) CAS:68953-58-2 RTECS #:UZ2996400 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <0.4% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:POLYAMIDE ADDUCT RESIN. VP: 0.9 @ 68F Fraction by Wt: <35% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:TRIETHYLENE TETRAMINE (CONTAINING ING 20). VP: 0.01 CAS:112-24-3 RTECS #:YE6650000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYLENEAMINES Fraction by Wt: <1.6% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MIXED VOLATILE ORGANIC COMPOUND: 432 G/L (EPA) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FIRST AID PROC: PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: NOTIFY LOCAL AUTHORITIES. RTECS #:9999999ZZ Ingred Name:RESP PROT: HAZARDS." FOR MORE INFORMATION CONTACT NEHC . RTECS #:9999999ZZ Ingred Name:VENT: CONTAMINANT CONCS BELOW TLV LIMITS. FOR MORE INFORMATION CONTACT NEHC . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: VAP/SPRAY MIST/SPATTERED MATL CAN BE HARMFUL. IRRIT TO EYES, SKIN, & IF INHALED, TO NOSE & THROAT. EXCESS/PRLNGD INHAL CAN CAUSE HDCH, NAUS/DIZZ. RPTD & PRLNGD OCCUP OVREXP TO SOLVS IS ASSOC W/ PERM BRAIN & NERV SYS DMG. INTENTIONAL ABUSE, MISUSE/OTHER MASSIVE EXPOS TO SOLVS MAY CAUSE MULTIPLE (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO, VOL 68, 1987: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC TO BE (SUPDAT) Effects of Overexposure:HLTH HAZ: ORGAN DMG &/OR DEATH. OVEREXP (PRLNGD/RPTD USE) CAN AGGRAVATE/ACCENTUATE ANY OF THESE EFTS. SKIN: IRRITANT. SENSIT. CAN BE ABSORBED THRU SKIN. CAN CAUSE DEFAT & DRYING. INHAL: IRRITANT. DELA YED LUNG INJURY CNS DMG. RPTD EXPOS TO SILICA DUST CAN CAUSE SILICOSIS. CRYSTALLINE SILICA MAY CAUSE CANCER. (SUPDAT) Medical Cond Aggravated by Exposure:KIDNEYS, LIVER, SKIN, EYES, RESPIRATORY, ALLERGIES, LUNGS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE NORM BRTHG. TREAT SYMPTOMATICALLY. SEE PHYS. SKIN: WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG. CONSULT PHYS IF IRRIT PERSISTS. EYES: FLUSH IMMED W/PLENTY OF WA TER FOR @ LST 15 MINS & GET MED ATTN. INGEST: DRINK 1-2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. DO NOT INDUCE VOMIT (UNLESS METHANOL LISTED IN INGREDS). CONT(ING 22) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:95.0F,35.0C Lower Limits:1.0% Upper Limits:11.20% Extinguishing Media:FOAM, CARBON DIXOIDE, DRY CHEMICAL. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CNTNRS TO PREVENT PRESS BUILD/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT & PRESS BUILDUP. MAY PRDCE FLOATING FIRE HAZ. ISOLATE ELEC EQUIP, SPKS, HEAT & OPEN FLAME. VAPS MAY (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. AVOID BRTHG VAPS. VENTILATE AREA. USE ABSORB, INERT, CLEANUP MATLS. (DO NOT USE SAWDUST). REMOVE ABSORB MATL W/NON-SPK TOOLS. PLACE IN SEPARATE CNTNR. KEEP OUT OF SEWERS & WATERWAYS. IF ENTRY IS THREATENED/OCCURS,(ING 23) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID PROLONGED STORAGE TEMPERATUES ABOVE 100F. Other Precautions:USE CAUTION WHEN POURING. AVOID BREATHING SANDING DUST. DO NOT WELD/FLAME CUT ON EMPTY CONTAINER. DESTROY CONTAMINATED LEATHER AND ABSORBENT SHOES WHICH CANNOT BE DECONTAMINATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH CERTIFIED RESP DESIGNED TO REMOVE COMBINATION OF PARTICULATES(DUST/SPRAY MIST) & VAP. WHEN BRUSHING, ROLLING/SPREADING SELECT APPROP RESP PROT FOR CNDTNS. FOR SPECIFIC CNDTNS, REFER TO CURRENT " NIOSH POCKET GUIDE TO CHEM (ING 24) Ventilation:IMPLEMENT ADMIN & ENGINEERING CTLS TO REDUCE EXPOS. PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR (ING 25) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . RESIST COVERALLS & SHOE COVERINGS. USE EXPLOSION & SPARK-PROOF EQUIP. Work Hygienic Practices:WASH THORO AFTER HNDLG & BEFORE EATING, SMKNG OR USING TOILET. LAUNDER CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health EVAP RATE: LOW:0.50. HIGH: 0.87 (BUTYL ACETATE=1). EXPLO HAZ: SPREAD LONG DIST, CAUSE FLASH FIRE/IGNITE EXPLOSIVELY. EXPLAN OF CARCIN: CARCIN. EFTS OF OVEREXP: RISK OF CANCER DEPENDS ON DURATION & LEV EL OF EXPOS TO DUST FROM SANDING SURF/SPRAY MIST. SMKNG AGGRAVATES PROBS. CHEM PNEUM. FOR MORE INFO CONT NEHC . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>244F,>118C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.15 Evaporation Rate & Reference:SUPP DATA Appearance and Odor:LIQUID, SOLVENT ODOR. Percent Volatiles by Volume:52.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. AMINES UNDER UNCONTROLLED CONDITION. Hazardous Decomposition Products:BY FIRE, BURNING/WELDING: CO, CO*2, ALDEHYDES, SO*X. TOXIC GASES/FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN SEPARATE, APPROPRIATE, CLOSED CONTAINER I/A/W ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN TESTED BY TOX CHARACT LEACHING PROC (TCLP). EPA WASTE NO: D001.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:744-720 CAGE:09869 CAGE:09869 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:SE7555000 OSHA PEL:100 PPM Ingred Name:ISOBUTYL ALCOHOL (SARA III) CAS:78-83-1 RTECS #:NP9625000 OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:EYE,THROAT,SKIN,LUNG IRRITANT;COMA;UNCONSCIOUSNESS;COMFUSION;NERVOUS SYSTEM DEPRESSANT. ======================= First Aid Measures ======================= First Aid:WASH SKIN WELL. FLUSH EYES W/WATER.REMOVE TO FRESH AIR. REMOVE CONTAMINATED CLOTHING GIVE ARTIF.RESP. IF NEEDED,CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:50F, 9C TCC Lower Limits:0.9 Extinguishing Media:FOAM,DRY CHEM.,CARBON DIOXIDE(POLYMERFIAM Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS Unusual Fire/Explosion Hazard:AVOID FIRE,HEAT,SPARKS, IGNITION SOURCES,STORAGE IN DIRECT SUNLIGHT+ HEAT MAY BURST CANS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, KEEP FROM FLAME, FIRE, SPARKS, IGNITION SOURCES; DO NOT BREATHE VAPORS; CLEAN UP WITH ABSORBENT MATERIAL; USE NON-SPARKING TOOLS ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED,UPRIGHT,AWAY FROM FIRE, FLAME, SPARKS, IGNITION SOURCES, DIRECT SUNLIGHT; DO NOT STORE ABOVE 120F. NFPA CLASS I FLAMMABLE BLDG. Other Precautions:DO NOT TAKE INTERNALLY;GROUND ALL CONTAINERS WHEN POURING; DO NOT FLAME CUT,BRAZE,OR WELD COATED MATERIAL WITHOUT RESPIRATOR OR GOOD VENTILATION. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST Supplemental Safety and Health BOILING RANGE IS 223-290F. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:223F, 106C Appearance and Odor:LIQUID; COLOR-WHITE. Percent Volatiles by Volume:63.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:FIRES,HEAT,HOT SURFACES ==================== Disposal Considerations ==================== Waste Disposal Methods:LOCAL,STATE,AND FED. LAWS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANAEROBIC COMPOUNDS SEALING LOCKING & RETAINING MIL-S-22473E Preparer's Name:JAY TATE CAGE:JO969 CAGE:0ZDS4 CAGE:JO969 ============= Composition/Information on Ingredients ============= Ingred Name:POLYGLYCOL DIMETHACRYLATE CAS:25852-47-5 Fraction by Wt: 78.0% Other REC Limits:NONE RECOMMENDED Ingred Name:CUMENE HYDROPEROXIDE (SARA 313) (CERCLA) CAS:80-15-9 RTECS #:MX2450000 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SACCHARIN (SARA 313) (CERCLA) CAS:81-07-2 RTECS #:DE4200000 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:N,N-DIALKYLTOLUIDINE CAS:613-48-9 Fraction by Wt: 1.0% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC = 132G/L RTECS #:9999999VO Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:BISPHENOL A FUMARATE CAS:39382-25-7 Fraction by Wt: 15.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:NONE ACGIH TLV:NONE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED SKIN CONTACT MAY RESULT IN DERMATITIS IN SENSITIVE PEOPLE. WILL IRRITATE EYES ON CONTACT. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER. INGESTION: DO NOT INDUCE VOMITING. CONTACT DR. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>212F,>100C Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER Fire Fighting Procedures:USE SCBA. Unusual Fire/Explosion Hazard:IRRITATING ORGANIC VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE & OUT OF DIRECT SUNLIGHT. Other Precautions:KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED FOR NORMAL USE. Ventilation:MECHANICAL VENTILATION NOT NORMALLY REQUIRED. ENSURE ADEQUATE ROOM VENTILATION FOR COMFORTABLE WORKING CONDITIONS. Other Protective Equipment:BARRIER CREAMS RECOMMENDED Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>400F,>204C Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NA Vapor Pres:0.01 Vapor Density:1.01 Spec Gravity:1.1 pH:NA Viscosity:100-250 CPS Evaporation Rate & Reference:VERY LOW Solubility in Water:INSOLUBLE Appearance and Odor:RED, MILD ORGANIC ODOR. Percent Volatiles by Volume:12.0 Corrosion Rate:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTAMINATION. Stability Condition to Avoid:TEMPERATURES IN EXCESS OF 150F. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATE IN ACCORDANCE W/EPA & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INDUSTRIAL SUPREME COOLANT/EG, 4006 CAGE:MILSO CAGE:MILS0 CAGE:MILSO ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) VP: 0.1 CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: >9% OSHA PEL:N/K ACGIH TLV:C 50 PPM, VAPOR EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:WATER; (DEIONIZED WATER) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUP DAT: FORM OF NEPHROTOXIC METABOLITES OF ETHYLENE GLYCOL IN LIVER. ETHANOL SHOULD BE GIVEN INTRAVENOUSLY, AS (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: 5% SOLN IN SODIUM BICARBONATE, AT RATE OF ABOUT 10 ML ETHANOL/HR. A DESIRED THERAPEUTIC LEVEL OF ETHANOL (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: IN BLOOD IS 100 MG/DL. HEMODIALYSIS MAY BE REQUIRED. PULM EDEMA W/HYPOXEMIA HAS BEEN DESCRIBED IN A (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: NUMBER OF PATIENTS FOLLOWING POISONING W/ETHYLENE GLYCOL. THE MECHANISM OF PRODUCTION HAS NOT BEEN (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ELUCIDATED, BUT IT APPEARS TO BE NON-CARDIOGENIC IN ORIGIN IN SEVERAL CASES. RESP SUPPORT W/MECH VENT (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: AND POSITIVE END-EXPIRATORY PRESSURE MAY BE REQUIRED. RTECS #:9999999ZZ Ingred Name:VENT: SPECIAL, LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPORS OR MISTS ARE EXPECTED TO ESCAPE TO THE WORKPLACE AIR. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INGEST: DIZZ, ABDOM DISCOMFORT, POSS KIDNEY DMG, MALAISE, LUMBAR PAIN, OLIGURIA, UREMIA, CNS DEPRESS, DEATH. SKIN CONT/ABSORPTION: NO EVIDENCE OF ADVERSE EFTS FROM AVAIL INFO. INHAL: HDCH, DIZZ , VOMIT, NAUS, IRRIT. EYES: MINOR IRRIT, CONJ. CHRONIC: INHAL OF MIST MAY PRDCE SIGNS OF CNS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: INVOLVEMENT, PARTICULARLY DIZZ & NYSTAGMUS. ETHYLENE GLYCOL HAS BEEN SHOWN TO PRDCE DOSE-RELATED TERATOGENIC EFTS IN RATS & MICE WHEN GIVEN BY GAVAGE/IN DRINKING WATER AT HIGH CONCS. THERE I S, HOWEVER, NO CURRENTLY AVAIL INFO TO SUGGEST THAT ETHYLENE GLYCOL HAS CAUSED BIRTH DEFECTS IN HUMANS. (SUP DAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. CALL MD. SKIN: FLUSH W/WATER. REMOVE & WASH CONTAM CLTHG PROMPTLY. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. CALL MD. (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>241F,>116C Lower Limits:>3.2% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL-TYPE FOAM, WATER SPRAY, UNIVERSAL-TYPE FOAM. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . A SOLID STREAM OF WATER DIRECTED INTO HOT, BURNING LIQ WOULD CAUSE FROTHING & SCATTERING OF BURNING (SUP DAT) Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTACT LOCAL AUTHORITIES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WARNING! MAY BE FATAL IF SWALLOWED. CANNOT BE MADE NON-POISONOUS. HARMFUL IF ABSORBED THROUGH SKIN. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. Other Precautions:AVOID CONTACT WITH EYES, SKIN, & CLOTHING. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. AVOID PROLONGED/REPEATED CONTACT WITH SKIN. CONTAINS ETHYLENE GLYCOL WHICH CAUSES BIRTH DEFECT IN LABOR ATORY ANIMALS. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VAPORS ARE PRESENT, USE A NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPRS, FRESH AIR BREATHING APPARATUS, OR SCBA. Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION TO MAINTAIN VAPOR LEVELS BELOW TLV IS EXPECTED TO BE SATISFACTORY. (ING 9) Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRE FIGHT PROC: MATL. DO NOT SPRAY POOL FIRES DIRECTLY. EFTS OF OVEREXP: THEREFORE, ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL TERATOGEN. FIRST AID PROC: NOTES TO MD: THE PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL, WHEN SWALLOWED, ARE KIDNEY DMG & METABOLIC ACIDOSIS. ETHANOL IS ANTIDOTAL, & ITS EARLY ADMIN MAY BLOCK (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE ING 1 Vapor Density:HVR/AIR Spec Gravity:1.06 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER Percent Volatiles by Volume:50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG BASES AT HIGH TEMPERATURES, OXIDIZING AGENTS, MATERIALS REACTIVE WITH HYDROXYL COMPOUNDS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPOTCHECK CLEANER/REMOVER SKC-S (SEE SUPPL) Kit Part:Y Preparer's Name:TAMIE SIMMONS,R&D MANAGER CAGE:37676 Contract Num:SP0450-02-M-M080 CAGE:37676 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DIOXIDE (PROPELLANT) (FOR 12 OZ. AND 16 OZ. AEROSOL) CAS:124-38-9 RTECS #:FF6400000 Minumum % Wt:3. Maxumum % Wt:7. Other REC Limits:NOT PROVIDED OSHA PEL:9000 MG/M3;5000 PPM ACGIH TLV:9000 MG/M3;5000 PPM ACGIH STEL:54000 MG/M3 Ingred Name:ISOBUTANE(PROPELLANT) (FOR 0.3 OZ. AEROSOL) CAS:75-28-5 RTECS #:TI4300000 = Wt:30. Other REC Limits:NOT PROVIDED OSHA PEL:1000 PPM ACGIH TLV:NOT AVAILABLE Ingred Name:LIGHT ALIPHATIC SOLVENT NAPHTHA CAS:64742-89-8 Minumum % Wt:60. Maxumum % Wt:100. Other REC Limits:NOT PROVIDED OSHA PEL:NOT AVAILABLE ACGIH TLV:300 PPM(8 HR TWA) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS & SIGNS AND SYMPTOMS OF EXPOSURE: SKIN CONTACT: CAN IRRITATE BY REMOVING NATURAL SKIN OILS ON LONG OR REPEATED EXPOSURES. EYES: IRRITATING. INHALATION: DIZZINESS AND NAUSEA. I NGESTION: NOT SIGNIFICANT IN SMALL (MOUTHFUL) AMOUNTS. Explanation of Carcinogenicity:CONTAINS NO KNOWN OR SUSPECTED CARCINOGENS LISTED WITH OSHA, IARC, NTP, OR ACGIH. Effects of Overexposure:SKIN CONTACT: CAN IRRITATE BY REMOVING NATURAL SKIN OILS ON LONG OR REPEATED EXPOSURES. EYES: IRRITATING. INHALATION: DIZZINESS AND NAUSEA. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:SKIN CONTACT: WASH OFF WITH SOAP AND WATER. USE SOOTHING LOTION. EYES: RINSE CAREFULLY UNDER UPPER AND LOWER EYELIDS USING PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR IF DIZZY OR NAUSEATED. INGES TION: DO NOT INDUCE VOMITING. ACCIDENTAL INGESTION OF A SMALL MOUTHFUL IS NOT EXPECTED TO CAUSE SIGNIFICANT HARM. NOTE: IN ALL SEVERE CASES, CONTACT PHYSICIAN IMMEDIATELY. LOCAL CENTER. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=10.C, 50.F FLAMMABL AEROSOL Lower Limits:1 % Upper Limits:6 % Extinguishing Media:CARBON DIOXIDE, FOAM Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY. DO NOT SPRAY WATER DIRECTLY ON BURNING SKC-S. IT WILL FLOAT AND SPREAD THE FIRE. Unusual Fire/Explosion Hazard:AEROSOL CANS MAY BURST IF HEATED ABOVE 130F (54C) AND SPRAY CONTENTS INTO A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP OR SWEEP UP WITH ABSORBENT. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE CONTACT. AVOID REPEATED OR PROLONGED SKIN CONTACT. AVOID BREATHING SPRAY MIST. DO NOT SPRAY NEAR ARCS OR FLAMES. Other Precautions:NOT PROVIDED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR WITH SOLVENT VAPOR ABSORBING CARTRIDGE IF USED IN ENCLOSED, UNVENTILATED SPACE. Ventilation:USE WHERE VENTILATION WILL CARRY SPRAY MIST AWAY FROM OCCUPIED AREAS. UNAVOIDABLE. Other Protective Equipment:NOT PROVIDED Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health THIS IS A KIT. THE OTHER MSDS SERIAL NUMBERS: CKTRP,CLRJW,CLRKK ================== Physical/Chemical Properties ================== HCC:V3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=115.6C, 240.F B.P. Text:MINIMUM Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:3117-5443 @75F Vapor Density:> 1 Volatile Org Content %:100 Spec Gravity:0.76 Viscosity:NOT PROVIDED Evaporation Rate & Reference:FAST Solubility in Water:0 Appearance and Odor:CLEAR, COLORLESS LIQUID, NAPHTHA ODOR Percent Volatiles by Volume:99.9 Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:SOOT, OXIDES OF CARBON WHEN BURNING =================== Toxicological Information=================== Toxicological Information:CARCINOGENICITY: CONTAINS NO KNOWN OR SUSPECTED CARCINOGENS LISTED WITH OSHA, IARC, NTP, OR ACGIH. THRESHOLD LIMIT VALUE: 300 PPM WHMIS INFORMATION (CANADA): ACCORDING TO AVAILABLE INFORMATION, THE INGREDIENTS HAVE NOT BEEN FOUND TO SHOW REPRODUCTIVE TOXICITY, TERATOGENICITY, MUTAGENICITY, SKIN SENSITIZATION, OR SYNERGISTIC TOXIC EFFECTS WITH OTHER MATERIALS. ===================== Ecological Information ===================== Ecological:NO DATA IS AVAILABLE ON SKC-S. IT FLOATS ON WATER AND EVAPORATES AWAY. IT IS 100% VOC. ==================== Disposal Considerations ==================== Waste Disposal Methods:AS HAZARDOUS WASTE, SEND TO LICENSED WASTE HANDLER WHO CAN BLEND IT INTO SECONDARY FUELS. RCRA: HAZARDOUS WASTE. U.S. EPA WASTE NUMBER: D001 =================== MSDS Transport Information =================== Transport Information:U.S. DOT: 49 CFR 172.101 HAZARDOUS MATERIALS TABLE: PROPER SHIPPING NAME: CONSUMER COMMODITY. HAZARD CLASS OR DIVISION: ORM-D. IDENTIFICATION NO.: NONE. PACKING GROUP: NONE. IATA: LIST OF DANGEROUS GO ODS: PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE. HAZARD CLASS OR DIVISION: 2.1. IDENTIFICATION NO.: UN1950. -IMDG: GENERAL INDEX AEROSOL. PROPER SHIPPING NAME: AEROSOLS. HAZARD CLASS OF DIVISION: 2.1.IDENTIFICATION NO.: UN1950. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III, SECTION 313: NO REPORTABLE INGREDIENTS. Federal Regulatory Information:TSCA: ALL INGREDIENTS ARE LISTED IN TSCA INVENTORY. CERCLA: NOT REPORTABLE. State Regulatory Information:CALIFORNIA PROPOSITION 65: CONTAINS NOTHING ON THIS LIST ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ROOF COATING CAGE:AMERI CAGE:AMERI ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT; (ASPHALT CUTBACK) CAS:8052-42-4 RTECS #:CI9900000 Fraction by Wt: 10-70% OSHA PEL:N/K ACGIH TLV:5 MG/M3 (FUME) Ingred Name:BENZIN; (VOLATILE PETROLEUM SOLVENT) CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 50-90% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:CELLULOSE; (FIBERS, NATURAL) CAS:9004-34-6 RTECS #:FJ5691460 Fraction by Wt: 0-3% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 0-20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SUPDAT:SHOWN TO PRODUCE KIDNEY DAMAGE IN MALE RATS FOLLOWING PROLONGED INHALATION EXPOSURES. THE SIGNIFICANCE OF (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: THESE FINDINGS IN TERMS OF HUMAN HEALTH IS UNCERTAIN AT THIS TIME SINCE MALE RAT APPEARS UNIQUELY PRONE (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: TO KIDNEY DAMAGE FOLLOWING EXPOSURES TO A VARIETY OF HYDROCARBON MATERIALS. ALTHOUGH MFR DOES NOT BELIEVE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: THESE MATERIALS POSE A SERIOUS HUMAN HEALTH RISK, UNTIL ADDITIONAL INFO IS OBTAINED, RECOMMENDS USERS BE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: CAUTIOUS AND AVOID PROLONGED BREATHING OF VAPORS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NO EXPECTED EFFECT UNDER NORMAL CONDITIONS OF USE. USE WITH ADEQUATE VENTILATION. SKIN: CAN CAUSE IRRITATION ON PROLONGED OR REPEATED CONTACT. WEAR PROTECTIVE INDUCEVOMITING. HARMFUL OR FATAL IF ASPIRATED INTO LUNGS. CHRONIC: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SKIN: PETROLEUM DISTILLATES HAVE BEEN SHOWN TO POSSESS WEAK CARCINOGENIC ACTIVITY IN LAB ANIMALS. THEREFORE, THERE MAY BE A POTENTIAL RISK OF SKIN CANCER FROM PROLONGED OR REPEATED SKIN CONT ACT WITH THIS PRODUCT IN THE ABSENCE OFGOOD PERSONAL HYGIENE. THIS PARTICULAR PRODUCT HAS NOT BEEN TESTED FOR (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . EYES: IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN: SEE MD IMMEDIATELY. WASH OFF OF SKIN AT ONCE. IF SKIN IRRITATED, APPLY LOTION AND SEE MD IF IRRITATION PERSISTS. WASH CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:>105F,>41C Lower Limits:0.9% Upper Limits:6.0% Extinguishing Media:DRY CHEMICAL FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . DO NOT USE HALON OR WATER. Unusual Fire/Explosion Hazard:ALLOW TO BECOME COLD BEFORE DISPOSAL. PETROLEUM BASED COMPOUNDS CAN FLOAT ON WATER. ASPHALT FUMES - OSHA SPECIFICALLY REGULATED CARCINOGEN. ================== Accidental Release Measures ================== Spill Release Procedures:USE NON-SPARKING TOOLS. SHOVEL UP AND PLACE IN COTAINERS. Neutralizing Agent:NONE LISTED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE IN VENTILATED AREA. STORE IN COOL, DRY PLACE. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . AVOID PROLONGED BREATHING OF VAPORS. Ventilation:VENTILATION: RECOMMENDED. LOCAL EXHAUST: USE WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . SKIN COVERED WITH CLOTHING. Work Hygienic Practices:WASH EXPOSED AREAS AFTER USE. Supplemental Safety and Health EFTS OF OVEREXP: CARCINOGENIC ACTIVITY, BUT MANUFACTURER HAS CHOSEN TO BE CAUTIOUS IN LIGHT OF FINDINGS WITH OTHER DISTILLATE STREAMS. OCCASIONAL SKIN CONTACT WITH THIS PRODUCT IS NOT EXPECTED TO HAVE SERIOUS EFFECT, BUT GOOD PERSONAL HYGIENE SHOULD BE PRACTICED. INHALATION: PETROLEUM DISTILLATES HAVE BEEN (ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F,>93C Melt/Freeze Pt:M.P/F.P Text:VISCOUS LIQ Vapor Pres:10 (SOLV) Vapor Density:4.8 Spec Gravity:<1 (H*2O=1) Evaporation Rate & Reference:<0.1 (BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK, VISCOUS LIQUID; KEROSENE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:OPEN FLAME. Hazardous Decomposition Products:WHEN BURNED TOXIC FUMES MAY BE EMITTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ENVIRO CARE CONSEAL CONCRETE/STONE PROTECTIVE COATING Preparer's Name:GARY R. BRANDT CAGE:94525 CAGE:94525 ============= Composition/Information on Ingredients ============= Ingred Name:2-(2-BUTOXYETHYOXY)-ETHANOL, DIETHYLENE GLYCOL MONOBUTYL ETHER (BUTYL CARBITOL) CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 5-10% Ingred Name:ETHYLENE GLYCOL, GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 1-5% Other REC Limits:10 MG/CUM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. INGESTION: HARMFUL. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY, DRY CHEMICAL OR FOAM ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE LIQUID W/WET MOP OR WET/DRY VACUUM. FLUSH RESIDUE TO SEWER W/WATER. USE CARE, AS FLOOR MAY BECOME SLIPERY. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. Other Precautions:AVOID EYE & SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.02 pH:7.3 Solubility in Water:COMPLETE Appearance and Odor:WHITE OPAQUE LIQUID W/MILD ACRYLIC ODOR Percent Volatiles by Volume:75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. BIODEGRADABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROGEN SULFIDE IN NITROGEN 0.1 PPM TO 5% Preparer's Name:NONE LISTED CAGE:0FUP3 Contract Num:SP0450-99-M-JN77 CAGE:1E6A1 CAGE:0FUP3 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN SULFIDE (SARA 302/313) (CERCLA) CAS:7783-06-4 RTECS #:MX1225000 Fraction by Wt: 0.001% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 20 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: 99.995% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: NO EFFECTS KNOWN BELOW 10 PPM FOR HYDROGEN SULFIDE. NITROGEN IS A SIMPLE ASPHYXIANT. HYDROGEN SULFIDE IS AN IRRITANT TO THE EYES AND RESPIRATORY TRACT. CHRONIC: NONE KNOWN. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYES: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION, DIZZINESS, HEADACHE , NAUSEA, ASPHYXIATION. HIGHER CONCENTRATIONS OF HYDROGEN SULFIDE GAS (200-300 PPM) MAY RESULT IN RESPIRATORY ARREST LEA DING TO COMA OR UNCONSCIOUSNESS. EXPOSURE TO MORE THAN 30 MINUTES AT CONCENTRATIOINS GREATER THAN 700 PPM HAVE BEEN FATAL. NOTE: THIS MIXTURE CONTAINS ONLY 10 PPM OF HDROGEN SULFIDE IN NITROGEN. Medical Cond Aggravated by Exposure:BLOD DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. INHALATION: MOVE TO FRESH AIR. RESTORE BREATHING, GIVE ARTIFICIAL RESUSITATION AND OXYEGN. GET MEDICAL ATTENTION PROMPTLY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:4.0% H2S Upper Limits:44.0% H2S Extinguishing Media:NONFLAMMABLE. USE WATER, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:NONFLAMMABLE. STOP FLOW OF GAS, USE WATER SPRAY TO COOL SURROUNDING CONTAINERS. FIRE FIGHTERS MUST WEAR PROPER GEARS BEFORE ENTERING THE AREA. Unusual Fire/Explosion Hazard:GAS UNDER PRESSURE, 500 PSIG AT 70F. DO NOT EXCEED 130F. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AREA. VENTILATE AREA. AVOID BREATHING GAS. WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT. STOP LEAK IF CAN DO SO WITHOUT RISK. IF LEAK IS IN CONTAINER OR VALVE , CONTACT CHEMTR EC OR MANUFACTURER FOR ASSISTANCE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES. AVOID BREATHING GAS. Other Precautions:FOLLOW THE CALIBRATION PROCEDURE DETAILED IN THE INSTRUCTION MANUAL PROVIDED WITH THE INSTRUMENT UNDER CALIBRATION. USE IN A WELL VENTILATED AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. A TYPE C RESPIRATOR WITH FULL FACE PIECE EQUIPED WTH AN ESCAPE BOTTLE OR A SELF CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE OR WHEN CONCENTRATIONS EXCEED EXPOSURE LIMITS. Ventilation:USE LOCAL EXAUST TO REDUCE CONCENTRATIONS TO WITHIN EXPOSURE LEVELS. A LABORATORY TYPE HOOD IS SUITABLE FOR HANDLING SMALL OR LTD QUANTITIES. Other Protective Equipment:SAFETY SHOES, SAFETY SHOWER, EYEWASH FOUNTAIN. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health COMPRESED GAS CYLINDERS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENTS OFA COMPRESSED GAS CYLINDER, WHICH HAS NOT BEEN FILLED BY THE OWNER OR WITH HIS WRITTEN CONS ENT IS A VIOLATION OF FEDERAL LAW. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:NOT GIVEN Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:1 Spec Gravity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS GAS, ROTTEN EGG ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MANY METALS CORRODE RAPIDLY IF EXPOSED TO HYDROGEN SULFIDE IN A WET ATMOSPHERE. AVOID USING HARD OR HIGHLY STRESSED STEELS. AVOID COPPER AND COPPER BASED MATERIALS SUCH AS BRASS. Stability Condition to Avoid:PHYSICAL DAMAGE TO CYLINDER, TEMPERATURES ABOVE 130F. Hazardous Decomposition Products:OXIDES OF SULFUR.. =================== Toxicological Information=================== Toxicological Information:HYDROGEN SULFIDE SHOULD BE REGARDED AS A HIGHLY TOXIC. LOWER LEVELS 15-50 PPM ARE IRRITANT TO MUCUS MEMBRANES. HIGHER CONCENTRATIONS OF HYDROGEN SULFIDE GAS (200-300 PPM) MAY RESULT IN RESPIRATORY ARR EST LEADING TO COMA OR UNCONSCIOUSNESS. EXPOSURE TO MORE THAN 30 MINUTES AT CONCENTRATIOINS GREATER THAN 700 PPM HAVE BEEN FATAL. NOTE: THIS MIXTURE CONTAINS ONLY 10 PPM OF HDROGEN SULFIDE IN NITROGEN . TOXICOLOGICALL, IT REACTS WITH ENZYMES IN BLOOD STREAM AND INHIBITS CELLULAR RESPIRATION ERSULTING IN PULMONARY PARALYSIS, SUDDEN COLLAPSE AND DEATH. THIS EFFECT OVESHADOWS IRRITANT PROPERTIES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE OR UNUSED QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE TO MANUFACTURER FO R PROPER DISPOSAL. DISPOSAL MUST BE IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:REGULATED AS COMPRESSED GAS, NOS, 2.2, UN1956. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III HAZ CLASS:ACUTE & CHRONIC HEALTH HAZARD, FIRE AND PRESSURE HAZARDS. PER MSDS, THIS PRODUCT DOES NOT CONTAIN ANY INGREDIENTS WHICH ARE REGULATED ON THE US EPA LIST OF TOXIC CHEMICALS (49 CFR 372) AND IS THEREFORE NOT SUBJECT TO RELEASE REQUIREMENT UNDER SEC 313 OF EPCRA/SARA TITLE III. NOTE: HYDROGEN SULFIDE IS LISTED ON THE TOXIC CHEMICALS LIST SINCE JAN 1994 (HMIS). Federal Regulatory Information:COMPRESED GAS CYLINDERS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENTS OFA COMPRESSED GAS CYLINDER, WHICH HAS NOT BEEN FILLED BY THE OWNER OR WITH HIS WRITTEN CONS ENT IS A VIOLATION OF FEDERAL LAW.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPER VM & P NAPHTHA-EC (WOR) Preparer's Name:J P CAGE:54527 CAGE:54527 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATES, HYDROTREATED HEAVY PARAFFINIC CAS:64742-54-7 RTECS #:PY8035500 Fraction by Wt: 60 - 80% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:NAPHTHA, MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: 65% Other REC Limits:NONE SPECIFIED Ingred Name:ADDITIVE CONTAINING ZINC DIALKYL DITHIOPHOSPHATE - CONTAINS 0.115 % OF ZINC COMPOUND Fraction by Wt: 10 - 20% Other REC Limits:NONE SPECIFIED Ingred Name:VM & P NAPHTHA CAS:64742-89-8 Fraction by Wt: 22.5-25% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Health Hazards Acute and Chronic:ACUTE-EYES/SKIN:MILD IRRITATION.PROLONGED/REPEATED CONTACT WITH SKIN MAY RESULT IN DERMATITIS.INHALATION:HIGH CONCENTRATION MAY BE SLIGHTLY IRRITATING TO MUCOUS MEMBRANE.INGESTION:VOMITING.ASPIRATION INTO THE LUNGS MUST BE AVOIDED.CHRONIC-NONE GIVEN. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:OVEREXPOSURE CAN LEAD TO CENTRAL NERVOUS SYSTEM DEPRESSION PRODUCING SUCH EFFECTS AS HEADACHE,DIZZINESS,NAUSEA AND LOSS OF CONSCIOUSNESS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION.INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.EYES:FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN.SKIN:REMOVE CONTAMINATED CLOTHING.FLUSH SKIN WITH WATER.F OLLOW BY WASHING WITH SOAP & WATER.INGESTION:DO NOT INDUCE VOMITING.IF VOMITING OCCURS SPONTANEOUSLY,KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=12.8C, 55.F Lower Limits:1 Upper Limits:7 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.DO NOT POINT SOLID WATER STREAM DIRECTLY INTO BURNING OIL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. USE WATER TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AND CONTAIN.REMOVE WITH VACUUM TRUCK OR PUMP TO STORAGE SALVAGE VESSELS.SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY,SAND OR OTHER SUITABLE MATERIALS.FLUSH AREA WITH WATER TO REMOVE TRACE RESID UE.TAKE UP SMALL SPILLS WITH AN ABSORBENT MATERIAL Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA.KEEP AWAY FROM FLAMES,SPARKS,HIGH TEMPERATURES AND OXIDIZERS. Other Precautions:WARNING!FLAMMABLE LIQUID.GROUND EQUIPMENT TO PREVENT ACCUMULATION OF STATIC CHARGE.IF POURING OR TRANSFERRING MATERIALS,CONTAINERS MUST BE BONDED AND GROUNDED.DON'T WELD,HEAT OR DRILL ON OR NEAR CONTA INER;EVEN EMPTIED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY/DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS,USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE.IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR- PURIFYING RESPIRATOR FOR ORGANIC VAPOR. Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. Other Protective Equipment:EYE WASH STATION.LONG SLEEVE CLOTHING TO MINIMIZE SKIN CONTACT. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health NOTE TO PHYSICIAN:IF MORE THAN 2 ML/KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED,EMESIS SHOULD BE INDUCED WITH SUPERVISON.IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX,CONVULSIONS OR UNCONSCIOUSNESS OC CUR BEFORE EMESIS,GASTRIC LAVAGE USING ACUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=122.2C, 252.F Vapor Pres:26 @ 100F Vapor Density:3.8 Spec Gravity:0.75 Evaporation Rate & Reference:0.97 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT COLORED LIQUID. TYPICAL HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAME Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:555966 S/G 30-2-10 50% G/T CAGE:PARKR CAGE:PARKR ============= Composition/Information on Ingredients ============= Ingred Name:UREA; CARBAMIDE CAS:57-13-6 RTECS #:YR6250000 Fraction by Wt: 3-61% Ingred Name:AMMONIATED PHOSPHATES Fraction by Wt: 3-61% Ingred Name:POTASSIUM CARBONATE, POTASH, PEARL ASH CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 3-61% Ingred Name:INERT INGREDIENTS (TYPE NOT SPECIFIED) Fraction by Wt: 3-61% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (LAB ANIMAL): 1500 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED. SKIN & EYE IRRITATION OF MUCOUS MEMBRANES. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: IRRITATION. EYES: IRRITATION & BURNS. ======================= First Aid Measures ======================= First Aid:INGESTION: INDUCE VOMITING BY GIVING VICTIM 1 OR 2 GLASSES OF WATER & TOUCHING BACK OF THROAT W/FINGER. DON'T INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON. EYES: FL USH W/PLENTY OF WATER. SKIN: REMOVE CONTAMINATED CLOTHING & WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>400F Extinguishing Media:WATER, FOAM, CO2 Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:HYDROGEN SULFIDE IS A REACTION PRODUCT & IS TOXIC & EXPLOSIVE. SULFUR DUST WILL EXPLODE AT A MINIMUM CONCENTRATION OF 35 G/CUM AIR. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP PRODUCT & REPLACE IN LABELED CONTAINER OR BAG. ======================Handling and Storage ====================== Handling and Storage Precautions:USE PRODUCT ACCORDING TO DIRECTIONS OF USE. STORE PRODUCT IN ITS ORIGINAL CONTAINER LABELED CONTAINER IN A COOL, DRY, LOCKED PLACE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. SHELF LIFE IS 5 TO 7 YEARS OF GOOD PHYSICAL CONDITION IF STORED PROPERLY. DON'T CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR DISPOSAL. DON'T ALLOW BAGS TO GET WET. AVOI D CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED W/ADEQUATE VENTILATIN OR OUT-OF DOORS. IF INADEQUATE VENTILATION WHERE DUST CONCENTRATIONS EXCEED RECOMMENDED PEL USE A NIOSH APPROVED DUST RESPIRATORS. Supplemental Safety and Health PRODUCT SOLUBILITY: GENERALLY, SLOWLY SOLUBLE IN SOIL. ================== Physical/Chemical Properties ================== Spec Gravity:0.5606-0.8329 pH:5-8 Appearance and Odor:GRANULES, NATURAL MINERAL W/FERTILIZER SALT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN SULFIDE Stability Condition to Avoid:TEMP >100C (212F) Hazardous Decomposition Products:UREA: BIURET/CYANURIC ACID/AMMONIA/CO2/HYDROGEN CYANIDE/NITROGEN OXIDES. SULFUR COATED UREA: SULFUR & NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF PRODUCT CANNOT BE USED ACCORDING TO INSTRUCTIONS, DISPOSE OF EXCESS PRODUCT ON SITE OR AT AN APPROVED WASTE DISPOSAL FACILITY. COMPLETELY EMPTY BAG INTO APPLICATION EQUIP & DISPOSE IN A SANITARY LA NDFILL OR INCINERATE IAW/PROPER REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1232 RUSTMASTER ENAMEL CAGE:EO697 CAGE:EO697 CAGE:01PD6 ============= Composition/Information on Ingredients ============= Ingred Name:2-PROPENOIC ACID, 2-METHYL-, METHYL ESTER, POLYMER W/ETHYL 2-PROPENOATE, LUCITE 30 CAS:9010-88-2 Fraction by Wt: 3-8% Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 1-5% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 40-45% Other REC Limits:590 MG/CUM OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 16-21% Other REC Limits:100 PPM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 17-22% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 2-7% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 4-9% Other REC Limits:800 PPM OSHA PEL:800 PPM ACGIH TLV:800 PPM; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY TRACT, MUCOUS MEMBRANES, FATIGUE, DROWSINESS, DIZZINESS, HEADACHE, UNCOORDINATION, NAUSEA, CNS DEPRESSION, ANESTHETIC EFFECT/NARCOSIS. SKIN: IRRITATION/DERMATITIS /DEFATTING. EYE: IRRITATION/BLURRED VISION/TEARING/REDNESS/CORNEAL INJURY. INGESTION: LUNG INFLAMMATION. Explanation of Carcinogenicity:CANCER HAS DETERMINED THAT THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS. Effects of Overexposure:INGESTION: DAMAGE DUE TO ASPIRATION OF MATERIALS INTO LUNGS. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS CAUSES PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. INHALATION: CRYSTALLINE SILICA IS ALSO A KNOWN CA USE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. SKIN: PROLONGED/REPEATED CONTACT CAUSE DERMATITIS, DEFATTING. Medical Cond Aggravated by Exposure:DERMATITIS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE/SUPPORT CONTINUES BREATHING. GET MED ATT. GIVE OXYGEN IF NECESSARY. SKIN: WASH OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER; REMOVE/WASH CONTAMINATED CLOTH ING BEFORE REUSE. EYE: FLUSH W/LARGE AMOUNTS OF WATER. OBTAIN MED TREATMENT. INGESTION: OBTAIN MEDICAL TREATMENT IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:<20F Lower Limits:1.2% Extinguishing Media:DRY CHEMICAL, FOAM Fire Fighting Procedures:WATER MAY BE USED TO COOL/PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:DON'T SPRAY NEAR OPEN FLAME. KEEP AT ROOM TEMPERATURE AS EXPOSURE TO DIRECT SUNLIGHT OR OTHER HEAT MAY CAUSE BURSTING. ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA. SPILLS MAY BE COLLECTED W/NON-COMBUSTIBLE ABSORBENT MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING/INHALING THE CONTENTS MAY BE HARMFUL/FATAL. Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED/UPRIGHT WHEN NOT IN USE. EMPTY CONTAINERS MAY CONTAIN HAZ. RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE. AVOID CONTACT W/SKIN & EYES/BREATHING OF VAPORS. STORE <100F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH/MSHA APPROVED RESPIRATORS. Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO PREVENT BUILD-UP OF VAPORS. Other Protective Equipment:EYE WASH, SAFETY SHOWER Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health PRODUCTS IN THIS SERIES CONTAIN ETHYLENE GLYCOL WHEN TINTED W/DRAMATONE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:133-231F Percent Volatiles by Volume:85.0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENT, ACIDS, BASES, ALDEHYDES, ALKYLHALIDES, HALOGENS, & AMINES Stability Condition to Avoid:ELEVATED TEMPERATURES, SUNLIGHT, OPEN FLAME, & HEAT, IGNITION SOURCES. STORE <100F. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. ORM-D. CONSUMER COMMODITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BUMPER BLACK, PFB-400-S9 CAGE:FO983 CAGE:72556 CAGE:FO983 ============= Composition/Information on Ingredients ============= Ingred Name:DUST, NUISANCE; (NUISANCE DUST) Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:10 MG/M3 (MFR) Ingred Name:S-TRIAZINE-2,4,6 (1H,3H,5H)-TRIONE,1,3,5-TRIS (2,3-EPOXYPROPYL); (GLYCIDYL ISOCYANURATE). VP:0.01. (ING 3) CAS:2451-62-9 RTECS #:XZ1994900 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:0.025 MG/M3 (MFR) Ingred Name:ING 2:LD50:(ORAL,RAT) 319 MG/KG. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS:NOT APPLICABLE. RTECS #:9999999VO ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE CONTACT:POSSIBLE IRRITATION. INHALATION:MAY CAUSE HEADACHE AND RESPIRATORY IRRITATION. SKIN CONTACT:POSSIBLE IRRITATION OR SENSITIZATION. ING 2:INGESTION:MODERATELY TOXIC. SYMPTOMS ARE NOT FULLY K NOWN, MAY INCLUDE LOSS OF APPETITE AND BLEEDING FROM NOSE. INHALATION:IRRITATING TO UPPER RESPIRATORY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:TRACT. MAY CAUSE NOSEBLEEDS. EYE CONTACT:IRRITATING. SKIN CONTACT:IRRITATING. CAN BE ABSORBED IN HARMFUL AMOUNTS. EFFECTS SIMILAR TO INGESTION. Medical Cond Aggravated by Exposure:RESPIRATORY ILLNESS & DERMATITIS MAY BE AGGRAVATED BY EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:INGEST:DRINK 1-2 GLASSES OF WATER & INDUCE VOMITING BY PLACING FINGER AT BACK OF THROAT. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. INHAL:REMOVE FROM AREA TO FRESH AIR. EYES:IMMEDIATELY BEGIN FL USHING W/COOL WATER, OCCASIONALLY LIFTING LIDS TO ENSURE THOROUGH RINSING. CONTINUE FOR AT LEAST 15 MINUTES. WHILE FLUSHING, SEND FOR MEDICAL ASSISTANCE. SKIN:WASH THOROUGHLY W/SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point:>600F,>316C Lower Limits:40 G/M3(AIR) Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG, DRY SAND. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:COMBUSTIBLE. DUST CLOUD OF 40 G/M3 CAN BE IGNITED BY SPARK OF 20 MILLIJOULES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP CAREFULLY OR USE EXPLOSION-PROOF VACUUM CLEANER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP ALL EQUIPMENT CLEAN & PROPERLY GROUNDED TO AVOID STATIC ELECTRICITY BUILD-UP. KEEP WORK AREAS FREE OF DUST THROUGH ADEQUATE VENTILATION. Other Precautions:AVOID PROLONGED CONTACT W/SKIN. DO NOT INGEST. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A PROPERLY FITTED NIOSH APPROVED MECHANICAL RESPIRATOR OR MASK TO AVOID BREATHING DUST. CAREFULLY FOLLOW RESPIRATOR MFR'S INSTRUCTIONS FOR USE. Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP AIR CONTAM CONC BELOW APPLIC OSHA PEL/ACGIH'S TLV TWA LIMIT. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . PROTECTIVE OVERALLS RECOMMENDED. Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Vapor Pres:SEE ING 2 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:STATIC ELECTRICAL CHARGES. Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CO, CO*2 & NO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6604542 PCNA Preparer's Name:S HEALY CAGE:FO645 CAGE:FO645 CAGE:6Z677 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE, AZIDE *96-4* CAS:26628-22-8 RTECS #:VY8050000 Other REC Limits:0.1 PPM ACGIH TLV:C 0.29 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN: IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS, CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY IRRITATION, RESPIRATORY FAILURE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS, NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH, COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA, CONVULSIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND. Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN. Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS. (SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS Other Protective Equipment:ADEQUATE LABORATORY ATTIRE Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N ITROGEN & MOLTEN SODIUM. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:527F Spec Gravity:1.85 Solubility in Water:40.16 Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: CHEMLOK 805 ELASTOMER ADHESIVE, 98050W Cage: DO802 ======================================================= Contractor Summary ======================================================= Cage: DO802 Box: 10038 Cage: 30676 ======================================================= Ingredients ======================================================= Cas: 50-00-0 RTECS #: LP8925000 % Wt: 1 OSHA PEL: SEE 1910.1048 ACGIH TLV: C 0.3 PPM, A2 EPA Rpt Qty: 100 LBS DOT Rpt Qty: 100 LBS ------------------------------ Cas: 1314-13-2 RTECS #: ZH4810000 % Wt: 10 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 % Wt: 4 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 111-76-2 RTECS #: KJ8575000 % Wt: 3 OSHA PEL: 50 PPM, S ACGIH TLV: 25 PPM, S ------------------------------ Cas: 1333-86-4 RTECS #: FF5800000 % Wt: 1 OSHA PEL: 3.5 MG/M3 ACGIH TLV: 3.5 MG/M3 ------------------------------ Cas: 80-05-7 RTECS #: SL6300000 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: >3 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ % Wt: >3 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- RTECS #: 9999999VO OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- IS HANDLED/STORED. WASH THORO AFTER HANDLING. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: NO Effects of Exposure: ACUTE: MAY BE ABSORBED THRU SKIN. SKIN & EYE IRRIT. MAY CAUSE HDCH & NAUS. EXPOS TO FORMALDEHYDE MAY CAUSE DRY, SORE THROAT, ITCH & BURNING OF NOSE, NASAL CONGESTION, COUGH, CHEST TIGHTNESS & WHEEZING . CHRONIC: MAY CAUSE SKIN SENSIT, DERM,RESP SENSIT, LIVER/KIDNEY DMG. MAY AFFECT GI SYS, BLOOD & (EFTS OF OVEREXP) Explanation Of Carcinogenicity: FORMALDEHYDE: IARC MONOGRAPHS, SUPP, VOL 7, PG 211, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT ON CARCINS, 1994: (SUP DAT) Signs And Symptions Of Overexposure: HLTH HAZ: BLOOD FORMING ORGANS. FORMALDEHYDE (GAS), ENTRAPPED IN PROD MAY BE RELEASED DURING HEATING & MIXING. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH) (SUP DAT) Medical Cond Aggravated By Exposure: CHRONIC DISEASES OF THE SKIN, EYES, GASTROINTESTINAL TRACT, LIVER, KIDNEYS, BLOOD AND BLOOD FORMING ORGANS. First Aid: INHAL: MOVE PERS TO FRESH AIR. RESTORE BRTHG BY ARTF RESP IF NEC. TREAT SYMPTOMATICALLY. CONSULT MD. EYES: FLUSH IMMED W/LGE AMTS OF WATER FOR AT LEAST 15 MIN, HOLDING EYELIDS OPEN WHILE FLUSHING. GET PROMPT MED ATTN. SKIN: FLUSH CONTAM SKIN & CLTHG W/LGE AMTS OF WATER. REMOVE CONTAM CLTHG. WASH AFFECTED SKIN AREAS W/SOAP & WATER. CONSULT MD IF IRRIT PERSISTS. INGEST: DRINK 1-2 GLASSES (SUP DAT) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE NON-ESSENTIAL PERSONNEL. AVOID BREATHING VAPORS. VENTILATE AREA. NOTIFY APPROPRIATE AUTHORITIES, IF NECESSARY. CONTAIN AND REMOVE WITH INERT ABSORBENT MATERIAL. AVOID CONTACT. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP SHOULD BE DONE I/A/W FED (40CFR PART 261), STATE & LOC ENVIRONMENTAL CTL REGS. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZ CAUTION INFO IN OTHER SECTIONS OF MSDS. IF WASTE IS DETERMINED TO BE HAZ, U SE LICENSED HAZ WASTE TRANSPORTER & DISP FACILITY. Handling And Storage Precautions: KEEP CLOSURE TIGHT AND CONTAINER UPRIGHT TO PREVENT LEAKAGE. STORE DRUM OUT OF SUN AND AWAY FROM HEAT. STORE ONLY IN WELL-VENTILATED AREAS. Other Precautions: DO NOT GET IN EYES. AVOID SKIN CONTACT. PREVENT PROLONGED OR REPEATED BREATHING OF VAPOR OR SPRAY MISTS. DO NOT HANDLE UNTIL THE MANUFACTURER'S PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP FROM FRE EZING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: SCC Flash Point Text: >200F,>93C Lower Limits: 1.1% Upper Limits: 10.6% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, WATER FOG, FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard: KEEP CONTRS TIGHTLY CLSD. CLSD CONTRS MAY RUPTURE WHEN EXPOS TO EXTREME HEAT. WATER MAY BE USED TO COOL CLSD CONTRS TO PREVENT PRESS BUILD-UP & POSS (SUP DAT) ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTER RESPIRATOR DESIGNED TO REMOVE A COMBINATION OF PARTICULATES & ORGANIC VAPOR IF OCCUPATIONAL LIMITS ARE EXCEEDED. USE NIOSH/MSHA APPROVED AIRLINE TYPERESPIRATORS OR HOODS IN CONFINED AREAS. Ventilation: SUFFICIENT VENT, IN PATTERN & VOL, SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT CONC BELOW APPLIC EXPOS LIM. ALL (SUP DAT) Other Protective Equipment: USE DISPOSABLE/IMPERVIOUS CLTHG IF WORK CLTHG CONTAM IS LIKELY. REMOVE & WASH CONTAM CLTHG BEFORE REUSE. Work Hygienic Practices: WASH HANDS BEFORE EATING, SMOKING/USING THE WASH ROOM. DO NOT SMOKE IN ANY CHEMICAL HANDLING OR STORAGE AREA. Supplemental Safety and Health: EXPLO HAZ:AUTO IGNIT/EXPLO. CARCIN EXPLAN:ANTICIPATED TO BE CARCIN ANIMAL: NASAL TUMORS. EFTS OF OVEREXP:PUBLICATION # 90-118) (FP N). FIRST AID PROC:OF WATER/MILK TO DILUTE. DO NOT INDUCE VOMIT. CONS ULT MD/POIS CTL CTR IMMED. TREAT SYMPTOMATICALLY. VENT:APPLICATN AREAS SHOULD BE VENT I/A/W OSHA REG 29CFR PART 1910.94. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 340F,171C Vapor Pres: (SEE INGS) Vapor Density: HVR/AIR Evaporation Rate & Reference: SLOWER THAN ETHER Solubility in Water: SOLUBLE Appearance and Odor: GRAY LIQUID WITH MILD ODOR Percent Volatiles by Volume: 76 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HIGH TEMPERATURES. PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS. Materials To Avoid: STRONG ACIDS, BASES AND STRONG OXIDIZERS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, CHLORINE, HYDROGEN CHLORIDE, FORMALDEHYDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: CHEMLOK 805 ELASTOMER ADHESIVE, 98050W Cage: DO802 Assigned IND: Y Company Name: LORD CORP Street: 2000 W GRANDVIEW BLVD PO Box: 10038 Zipcode: 16514 Label Required IND: Y Date Of Label Review: 05/26/1995 Status Code: C Label Date: 05/26/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: MAY BE ABSORBED THRU SKIN. SKIN & EYE IRRIT. MAY CAUSE HEADACHE & NAUS. FORMALDEHYDE GAS ENTRAPPED IN PROD MAY BE RELEASED DURING HEATING & MIXING. EXPOS TO FORMALDEHYDE MAY CAUSE DRY, SORE THROAT, ITCHING & BURNING OF NOSE, NASAL CONGESTION, COUGH, CHEST TIGHTNESS & WHEEZING. CHRONIC: CANCER HAZARD. CONTAINS FORMALDEHYDE WHICH IS LISTED AS CARCINOGEN (FP N). ANIMAL STUDIES CLE ARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON THE CNS, HEMATOPIETIC TISSUES, BLOOD, KIDNEYS & LIVER, ASSOCIATED W/ADMINISTRATION OF ETHYLEBE GLYCOL MONOBUTYL ETHER (EGBE) (FP N). MAY CAUSE SKIN SE NSIT, DERM, RESP SENSITIZATION, LIVER/KIDNEY DMG. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROXYZINE Preparer's Name:CHRISTINA J. BARRINGTON CAGE:39832 CAGE:39832 ============= Composition/Information on Ingredients ============= Ingred Name:BENZYL ALCOHOL CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 0.9% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROXYZINE HYDROCHLORIDE CAS:2192-20-3 Other REC Limits:NONE RECOMMENDED Ingred Name:WATER FOR INJECTION CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE,SKIN & RESPIRATORY IRRITATION. CHRONIC: HYPDERSENSITIVITY REACTIONS RANGING FROM MILD TO SEVERE MAY OCCUR. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYE, SKIN, AND RESPIRATORY IRRITATION. HYPERSENSITIVITY REACTIONS-TISSUE NECROSIS, HEMOLYSIS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:IN ALL CASES SEEK MEDICAL ATTENTION. EYES-IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. FLUSH WITH WATER FOR 15 MINUTES. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN /ARTIFICIAL RESPIRATION/CPR AS NEEDED. INGESTED-IF CONSCIOUS, FLUSH OUT MOUTH. FOR ADVERSE DRUG REACTION CALL 708-317-5937. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR FOAM AS APPROPRIATE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RECOMMENDED PERSONAL PROTECTIVE CLOTHING/EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN UP SPILL. WIPE SURFACES CLEAN AND WASH WITH SOAP & WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID ALL CONTACT AND INHALATION OF DUST, FUMES, MIST AND/OR VAPORS ASSOCIATED WITH PRODUCT. Other Precautions:DO NOT INJECT SUBCUTANEOUSLY, INTRAVENEOUSLY OR INTER-ARTERIALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:DISPOSABLE GARMENTS IF DIRECT SKIN CONTACT IS ANTICIPATED. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 pH:3.5-6 Solubility in Water:APPRECIABLE Appearance and Odor:CLEAR, COLORLESS LIQUID; PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SMOKE AND TOXIC FUMES OF HCL. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANCAMINE K54 CURING AGENT, HK54-U CAGE:OEMW2 CAGE:00742 CAGE:OEMW2 ============= Composition/Information on Ingredients ============= Ingred Name:ING 19:WATER QUALITY STDS. DISPOSE IN APPRVD LANDFILL IF ALLOWED LOCALLY. WASTE FROM PROD MAY PRESENT LONG TERM (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: ENVIRON HAZARDS, THUS LANFILL DISPOSAL MUST BE CONSIDERED LESS ACCEPTABLE THAN INCINERATION. RTECS #:9999999ZZ Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD . RTECS #:9999999ZZ USING. DISCARD IF FIND EVIDENCE OF HOLES/CRACKS. RTECS #:9999999ZZ Ingred Name:ING 5: CAN BE EXPECTED TO PRDCE NUMEROUS TOXIC PRODS INCLUDING: NITRILES, CYANIC ACID, ISOCYANATES, CYANOGENS, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: NITROSAMINES, AMIDES, CARBAMATES. IRRITATING & TOXIC FUMES AT ELEVATED TEMPERATURES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: IF BRTHG HAS STOPPED/IS LABORED GIVE ASSISTED RESP (E.G. MOUTH-TO-MOUTH). SUPPLEMENTAL OXYGEN (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MAY BE INDICATED. PVNT ASPIR OF VOMIT. TURN HEAD TO SIDE. ASSURE MUC DOES NOT OBSTRUCT AIRWAY. CALL MD. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: INGEST: ADMINISTER 3-4 GLASSES OF MILK/WATER. DO NOT INDUCE VOMIT. OBTAIN MED CARE & HOSPITAL TREATMENT (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:IMMED. NOTE TO MD:PROD IS HIGHLY INJURIOUS TO ALL TISS, SIMILAR TO AMMONIA/AMMONIA GAS. CHEM PNEUM, PULM (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: EDEMA, LARYNGEAL EDEMA & DELAYED SCARRING OF AIRWAY OR OTHER AFFECTED TISS MAY OCCUR FOLLOWING EXPOS. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: THERE IS NO SPECIFIC TREATMENT. CLINICAL MANAGEMENT IS BASED ON SUPPORTIVE TREATMENT WHICH IS SIMILAR (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: TO THAT FOR THERMAL BURNS. RTECS #:9999999ZZ Ingred Name:SPILL PROC:& REDUCE VAPS. SPRAY W/WATER. PLACE IN METAL CNTNRS FOR RECOVERY/DISP. CLEANUP PERS MUST BE EQUIPPED (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: W/NIOSH/MSHA APPRVD SCBA & BUTYL RUB PROT CLTHG. AVOID CONTAM OF GROUND & SURF WATERS. NOTIFY LOC HLTH (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:AUTHS & OTHER APPROP AGENCIES IF CONTAM SHOULD OCCUR. ALL PERS REMAIN UPWIND OF SPILL. POTNTL FOR CARBON (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: MONOXIDE &/OR NITROUS OXIDES GENERATION IN FIRE MUST BE RECOGNIZED. RTECS #:9999999ZZ Ingred Name:WASTE DISP: SYS CAN BE USED DEPENDING ON QUALITY & QTY OF TREATED WASTE, TREATMENT PLANT CAPABILITY & DISCHARGE (ING 20) RTECS #:9999999ZZ Ingred Name:PHENOL, 2,4,6-TRIS(DIMETHYLAMINOMETHYL); (2,4,6-(DIMETHYLAMINOMETHYL)PHENOL) CAS:90-72-2 RTECS #:SN3500000 Fraction by Wt: >85% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BISPHENOL A EPOXY RESIN; (BIS(DIMETHYLAMINOMETHYL)- PHENOL) CAS:71074-89-0 Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: MANY OF WHICH ARE KNOWN TO BE POTENT CARCINS, MAY BE FORMED WHEN PROD COMES IN CNTCT W/NITROUS ACID, (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: NITRITES OR ATMOSPHERES W/HIGH NITROUS OXIDE CONCENTRATIONS. RTECS #:9999999ZZ Ingred Name:HAZ DECOMP PRODS: W/WATER VAPS TO FORM CORR NITRIC ACID (TLV=2 PPM). COMBUST OF PROD UNDER OXYGEN-STARVED CNDTNS (ING 6) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 1200 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CNTCT OF UNDILUTED PROD W/EYES/SKIN QUICKLY CAUSES SEV IRRIT & PAIN & MAY CAUSE BURNS, NECROSIS & PERM INJURY. BURNS OF EYE MAY CAUSE BLINDNESS. CORNEAL EDEMA MAY GIVE RISE TO PERCEPTION OF "BL UE HAZE" OR "FOG" AROUND LIGHTS. EFTS IS TRANSIENT & HAS NO KNOWN RESIDUAL EFT. INGEST MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: BLEEDING OF GI TRACT & VOMIT OF BLOOD, NAUS, VOMIT. INHAL OF VPAS MAY CAUSE IRRIT IN RESP TRACT. COUGH & CHEST PAIN MAY RSLT. CHRONIC: RPTD &/OR PRLNG EXPOS MAY RSLT IN ADVERSE SKIN EFTS (SU CH AS DEFAT, RASH, IRRIT OR CORR), ADVERSE EYE EFTS (SUCH AS CONJUNCTIVITIS OR CORNEAL DAMAGE). Medical Cond Aggravated by Exposure:EYE DISEASE. SKIN DISORDERS AND ALLERGIES. ======================= First Aid Measures ======================= First Aid:EYES: HOLD LIDS APART & IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN. CALL MD. SKIN: REMOVE PROD & IMMED FLUSH AFFECTED AREAS W/WATER FOR AT LEAST 15 MIN. CALL MD. EXCEPT IN MOST MINOR, SUPE RFICIAL & LOCALIZED BURNS, COVER AFFECTED AREA W/STERILE DRESSING/CLEAN SHEETING & TRANSPORT FOR MED CARE. DO NOT APPLY GREASES/OINTMENTS. CONTROL SHOCK IF PRESENT. INHAL: MOVE TO FRESH AIR. (ING 8) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:284F,140C Extinguishing Media:IGNITION WILL GIVE RISE TO CLASS B FIRE. IN CASE OF FIRE USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . RETAIN EXPENDED LIQS FROM FIRE FIGHTING FOR LATER DISP. WATER SPRAY IS ALSO USEFUL IN COOLING (SUPDAT) Unusual Fire/Explosion Hazard:MAY GENERATE TOXIC OR IRRITATING COMBUSTION PRODUCTS. SUDDEN REACTION AND FIRE MAY RESULT IF PRODUCT IS MIXED WITH AN OXIDIZING AGENT. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK, IF POSS. VENT SPACE INVOLVED. SHUT OFF/REMOVE ALL IGNIT SOURCES. CONSTRUCT DIKE TO PVNT SPREAD. COLLECT RUN-OFF WATER & TRANSFER TO DRUMS/TANKS FOR LATER DISP. PROTECT WORKERS W/WATER SPRAY . COVER SPILLS W/SODIUM BISULFATE TO NEUT (ING 15) Neutralizing Agent:COVER SPILLS W/SODIUM BISULFATE TO NEUTRALIZE & REDUCE VAPORS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN COOL, DRY, VENT STOR & IN CLSD CNTNRS. STORE IN STEEL CNTNRS PREF LOCATED OUTDOORS, ABOVE GROUND & SURROUNDED BY DIKES TO CNTN SPILLS/LEAKS. Other Precautions:KEEP AWAY FROM OXIDIZERS, HEAT OR FLAMES. AVOID CONTACT WITH SKIN, EYES OR CLOTHING, AVOID BREATHING OF VAPORS. HANDLE IN WELL VENTILATED WORK SPACE. ADHERE TO WORK PRACTICE RULES ESTABLISHED BY GOVER NMENT REGULATIONS (E.G. OSHA). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN POORLY VENT AREAS, NIOSH/MSHA APPRVD CARTRIDGE MASK FOR ORG VAPS IS RECOM UNDER FOLLOWING CNDTNS: EMER SITUATIONS; WHEN PROD VAP CONC IS > 20PPM FOR LONGER THAN 15 MIN; DURING EQUIP REPAIR & CLEANI NG; DURING PROD TRANSFER/DISCHARGE. Ventilation:ADEQUATE GENERAL AND LOCAL EXHAUST. Other Protective Equipment:EMERGENCY SHOWERS & EYE WASH STATIONS. LONG SLEEVED CLOTHING. RUBBER APRON. RUBBER BOOTS. Work Hygienic Practices:WASH AT END OF EACH SHIFT & BEFORE EATING, SMKNG, USING TOILET. LAUNDER/DISCARD CONTAMD CLTHG. DISCARD CONTAMD (ING 23) Supplemental Safety and Health PH: 11 (10% AQ SOLN). FIRE FIGHT PROC: FIRE-EXPOS TANKS & IN DISPERSING VAPS. MATLS TO AVOID: & AQUA REGIA. RXN ACCOMPANIED BY LG HEAT RELS OCCURS WHEN PROD IS MIXED W/ACIDS. HEAT GENERATED MAY BE SUF FICIENT TO CAUSE VIGOROUS BOILING CREATING HAZ DUE TO SPLASH/SPATTER OF HOT MATL. CAUTION! N-NITROSAMINES, (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>266F,>130C Melt/Freeze Pt:M.P/F.P Text:<-0F,<-18C Vapor Pres:<0.01 Spec Gravity:1.09 (H*2O=1) pH:SUPDAT Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:80% W/W @ 25C Appearance and Odor:STRAW YELLOW, MOBILE LIQUID; AMMONIACAL, IRRITATING ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS (I.E. PERCHLORATES, NITRATES,ETC.). CLEANING SOLNS SUCH AS CHROMERGE (SULFURIC ACID/DICHROMATE)(SUPDAT) Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE IN FIRE. AMMONIA WHEN HEATED. NITROGEN OXIDES IN FIRE. NITROGEN OXIDE CAN REACT (ING 5) ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/ALL FED, STATE & LOC REGS. INCIN IS ACCEPTABLE & PREF METH OF DISP. HOWEVER, NITROGEN OXIDE EMISSION CONTROLS MAY BE REQD TO MEET SPECIFICATIONS. CHEM &/OR BIOLOGICAL DEGRADATION IS FEASIBLE. SUITABLE INDUS/MUNICIPAL WASTE TREATMENT (ING 19)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BETZ ENTEC 725 CAGE:57394 CAGE:57394 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE; (CAUSTIC SODA) (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SKIN/EYES:CORROSIVE. INHALATION:MISTS OR AEROSOLS CAUSE IRRITATION TO UPPER RESPIRATORY TRACT. SYMPTOMS OF EXPOSURE:CAUSES SEVERE IRRITATION, BURNS OR TISSUE ULCERATION WITH SUBSEQUENT SCARRING. CHRONIC: PROLONGED OR REPEATED CONTACTMAY CAUSE TISSUE NECROSIS AND/OR DERMATITIS. MAY BE TOXIC IF ORALLY INGESTED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT KNOWN. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CLTHG. WASH AREA W/LG AMTS OF SOAP SOLN/WATER FOR 15 MINS. IMMED CONT MD. EYES:IMMED FLUSH W/WATER FOR AT LST 15 MINS. IMMED CONT MD FOR ADDNL TREATMENT. INHAL:REMOVE VICTIM FROM CONTAM AR EA. APPLY NEC FIRST AID TREATMENT. IMMED CONT MD. INGEST:DO NOT FEED ANYTHING BY MOUTH TO UNCON/CONVULSIVE VICTIM. DO NOT INDUCE VOMIT. IMMED CONT MD. DILUTE CONTENTS OF STOM USING 3-4 GLASSES(SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA, USE SPECIFIED PROT EQUIP. CONTAIN & ABSORB ON ABSORB MATL. PLACE IN WASTE DISP CNTNR. WASTE CHARACTS OF ABSORBED MATL/ANY CONTAM SOIL, SHOULD BE DETERMINED I/A/W RCRA REGS. FLUSH AREA W/WAT ER. WET AREA MAY BE SLIPPERY. SPREAD SAND/(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRUMS & PAILS CLOSED WHEN NOT IN USE. DO NOT FREEZE. IF FROZEN, THAW & MIX COMPLETELY PRIOR TO USE. ALKALINE. CORROSIVE (SKIN/EYES). Other Precautions:DO NOT MIX W/ACIDIC MATERIAL. ALL INGREDIENTS IN THIS PRODUCT ARE AUTHORIZED FOR USE AS BOILER WATER ADDITIVES WHERE STEAM PRODUCED MAY CONTACT FOOD. USE PROTECTIVE EQUIPMENT I/A/W 29 CFR 1910.132-134 . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATORS W/IN USE LIMITATIONS OR ELSE USE NIOSH APPROVED SUPPLIED AIR RESPIRATORS. IF VENTILATION IS INADEQUATE OR SIGNIFICANT PRODUCT EXPOSURE IS LIKELY, USE A NIOSH APPROVED RE SPIRATOR WITH DUST/MIST FILTERS. Ventilation:ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW EXPOSURE LIMITS. Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . CHEM RESIST APRON. WASH OFF AFTER EACH USE. REPLACE AS NECESSARY. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH(5% S0LN):13.1. FIRST AID PROC:MILK/WATER. SPILL PROC:GRIT. RQ:157 GALS. WASTE DISP METH:LANDFILL. IF THIS PROD IS DISCARDED AS WASTE, RCRA HAZ WASTE IDENTIFICATION NUMBER IS:D002 (CORROSIVE). PROT FULL LENGTH FACESHIELD . ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:10F,-12C Vapor Pres:18 Vapor Density:<1 Spec Gravity:1.529 pH:SUPDAT Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:100% Appearance and Odor:COLORLESS LIQUID; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT W/ACIDS. Stability Condition to Avoid:DO NOT CONTAMINATE. BETZ TANK CLEAN-OUT CATEGORY 'C'. Hazardous Decomposition Products:THERMAL DECOMPOSITION (DESTRUCTIVE FIRES) YIELDS ELEMENTAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS. WATER CONTAM W/THIS PROD MAY BE SENT TO SANIT SEWER TREATMENT FACILITY, I/A/W ANY LOC AGREEMENT, PERMITTED WASTE TREATMENT FACILITY/DISCHARGED UNDER NPD ES PERMIT PROD(AS IS)-INCIN/BURY IN APPRVD(SUPDAT)
1
eyes_protection_mandatory
======================================================= NIIN: 00-882-7073 Product ID: 75326, CLEAN UP SOLVENT, PART 2 OF KIT 00112 Kit Part: Y Cage: 05972 ======================================================= Contractor Summary ======================================================= Cage: 47210 Box: 1006 Cage: 05972 Cage: 62377 Cage: 3S933 ======================================================= Item Description Information ======================================================= Item Manager: S9I Item Name: BONDING KIT Specification Number: NONE Type/Grade/Class: NONE Unit of Issue: KT UI Container Qty: 1 Type of Container: UNKNOWN ======================================================= Ingredients ======================================================= Cas: 872-50-4 RTECS #: UY5790000 % Wt: 100.0 Other REC Limits: NONE DETERMINED OSHA PEL: NOT ESTABLISHED ACGIH TLV: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL RAT) = 4,000 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: SEVERE EYE IRRITANT. SKIN IRRITANT. Explanation Of Carcinogenicity: MFR GAVE THE ABOVE LISTINGS ON THE MSDS BUT NO OTHER COMMENTS ABOUT CARCINOGENICITY WERE RECORDED. Signs And Symptions Of Overexposure: IRRITATION OF EYE OR SKIN, HEADACHE, NAUSEA, GIDDINESS, MENTAL CONFUSION UPON INHALATION IN AREAS OF VERY HIGH CONCENTRATION. Medical Cond Aggravated By Exposure: NONE KNOWN. First Aid: INGESTION:DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION. INHALATION:REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IF BREATHING IS DIFFICULT. SKIN CONTACT:WASH W/SOAP & WATER. EYE CONTACT:FLUSH AT LEAST 15 MINUTES W/WATER. OBTAIN MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REMOVE IGNITION SOURCES. SOAK UP IN AN INERT ABSORBENT. STORE IN A COOL CONTAINER UNTIL DISPOSAL. Neutralizing Agent: MFR GAVE NO INFORMATION OF MSDS. Waste Disposal Methods: LANDFILL OR INCINERATE FOLLOWING EPA & LOCAL REGULATIONS. Handling And Storage Precautions: STORE BELOW 120F. (CONTACT LOCTITE CUSTOMER SERVICE 800-243-4874 FOR SHELF LIFE INFORMATION.) Other Precautions: AVOID CONTACT W/EYES. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT & FLAMES. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point: =92.8C, 199.F Lower Limits: 1.3 Upper Limits: 9.5 Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures: MFR GAVE NO INFORMATION OF MSDS. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: MFR GAVE NO INFORMATION OF MSDS. Ventilation: SOME LOCAL VENTILATION MAY BE DESIRABLE. Other Protective Equipment: MFR GAVE NO INFORMATION OF MSDS. Work Hygienic Practices: MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health: KEY1:V4 PART OF A 3 PART KIT CONTAINING ADHESIVE, WATERPROOFING & CLEANUP SOLVENT. ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 NRC/State LIC No: NONE Boiling Point: =201.7C, 395.F Vapor Pres: 1 MM Vapor Density: 3.4 Spec Gravity: 1.03 PH: N/A. Viscosity: UNKNOWN Evaporation Rate & Reference: >300 (ETHER=1) Solubility in Water: MISCIBLE Appearance and Odor: CLEAR LIQUID, AMMONICAL ODOR. Percent Volatiles by Volume: 99.9 Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: MFR GAVE NO INFORMATION OF MSDS. Materials To Avoid: IRRITATING ORGANIC VAPORS, STRONG OXIDIZING OR REDUCING AGENTS. Hazardous Decomposition Products: NONE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 89995 Product ID: 75326, CLEAN UP SOLVENT, PART 2 OF KIT 00112 Review Date: 07/16/1997 Tech Entry NOS Shipping Nm: TOLUENE, MEK Net Unit Weight: 29.2 GRAMS Multiple KIT Number: 0 Kit Part IND: Y Review IND: Y Unit Of Issue: KT Container QTY: 1 Type Of Container: UNKNOWN Additional Data: MFR SUPPLIED THE PROPER SHIPPING NAME. PSN IS FOR KIT. IF SHIPPED SEPATATELY, THIS PART WOULD BE NOT REGULATED. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: GJJ Symbols: G DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. Hazard Class: 3 UN ID Num: UN1993 DOT Packaging Group: II Label: FLAMMABLE LIQUID Special Provision: T8,T31 Non Bulk Pack: 202 Bulk Pack: 242 Max Qty Pass: 5L Max Qty Cargo: 60 L Vessel Stow Req: B ======================================================= Detail IMO Information ======================================================= IMO PSN Code: HIN IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMDG Page Number: 3230 UN Number: 1993 UN Hazard Class: 3.2 IMO Packaging Group: I/II Subsidiary Risk Label: - EMS Number: 3-07 MED First Aid Guide NUM: T ======================================================= Detail IATA Information ======================================================= IATA PSN BV IATA UN ID Num: 1993 IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. * IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: II Packing Note Passenger: 305 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 307 ======================================================= Detail AFI Information ======================================================= AFI PSN BV AFI Symbols: * AFI Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. AFI Hazard Class: 3 AFI UN ID NUM: UN1993 AFI Packing Group: II Special Provisions: P5 Back Pack Reference: A7.3 ======================================================= HAZCOM Label ======================================================= Product ID: 75326, CLEAN UP SOLVENT, PART 2 OF KIT 00112 Cage: 05972 Company Name: LOCTITE CORPORATION Street: 1001 TROUT BROOK CROSSING Zipcode: 06067-3910 Label Required IND: Y Date Of Label Review: 07/16/1997 Status Code: C MFG Label NO: NONE Label Date: 07/16/1997 Origination Code: F Skin Protection IND: YES Signal Word: WARNING Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: SEVEREEYE IRRITANT. SKIN IRRITANT. STORE BELOW 120F. (CONTACT LOCTITE CUSTOMER SERVICE 800-243-4874 FOR SHELF LIFE INFORMATION.) =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-85285 B,13538,TYPE I,03 Y 091,PART A Kit Part:Y Preparer's Name:NILE SMITH CAGE:33461 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:N-BUTYL ACETATE (CERCLA) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL-3-ETHOXYPROPIONATE CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NICKEL,ANTIMONY,TITANIUM YELLOW PIGMENT CAS:8007-18-9 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED Ingred Name:METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9596 Ingred Name:ANTI-MAR AGENT Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYL BENZENE (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PENTANE-2,4-DIONE CAS:123-54-6 RTECS #:SA1925000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE/BUTYL CARBITOL ACETATE CAS:124-17-4 RTECS #:KJ9275000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:DISPERSION AID Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, RESPIRATORY TRACT. ACUTE- VAPORS ARE IRRITATING TO EYES, NOSE, THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING, LOSS OF CONSCIOUSNESS. EYE/SKIN CONTACT CAUSES IRRITATION. CHRONIC- WILL CAUSE DRYING/CRACKING OF SKIN, SKIN SENSITIZATION, ASTHMA OR ALLERGIC RESPONSES MAY DEVELOP. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DROWSINESS, DIZZINESS, NAUSEA, VOMITING, HEADACHE, WEAKNESS, ABDOMINAL DISCOMFORT, DRYNESS OF SKIN, ABDOMINAL PAIN, TEARING, REDNESS, UNCONSCIOUSNESS, SWELLING Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO NOT IN DUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=19.4C, 67.F Lower Limits:0.60% Upper Limits:11.40% Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE (CO2), ALCOHOL FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS SAND, EARTH. PREVENT LIQUID FROM ENTERING SEWERS OR WATERWAYS. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA AWAY FROM SOURCES OF IGNITION & STRONG OXIDIZING AGENTS. KEEP OUT OF REACH OF CHILDREN. AVOID STORAGE ABOVE 100F. Other Precautions:EMPTY CONTAINERS MAY RETAIN RESIDUE. FOLLOW ALL PRECAUTIONS. DO NOT GET IN EYES. DO NOT BREATHE VAPOR OR MIST. AVOID PROLONGED OR REPEATED SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATIN G OR DRINKING. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKING IN CONFINED AREAS, OR IF EXPOSURE MAY OR DOES EXCEED RECOMMENDED PERMISSIBLE EXPOSURE LIMITS (PEL), WEAR NIOSH-APPROVED RESPIRATORY PROTECTION FOR ORGANIC VAPORS (REFER TO 29 CFR 1910.134). Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, INDUSTRIAL-TYPE WORK CLOTHING, APRON Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:F2. KIT CONSISTS OF TWO PARTS. PART A HAS PNI I AND PART B HAS PNI J, SAME NSN. ================== Physical/Chemical Properties ================== HCC:F2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=126.7C, 260.F B.P. Text:260F - 475F Vapor Density:>1 Spec Gravity:1.185 VOC Pounds/Gallon:294 Evaporation Rate & Reference:0.35 (N-BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW LIQUID, SOLVENT ODOR Percent Volatiles by Volume:37.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATION IS RECOMMENDED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:THIAMINE HYDROCHLORIC INJECTION Preparer's Name:GREGORY KOLAR CAGE:EO410 CAGE:EO410 CAGE:39832 CAGE:0K706 ============= Composition/Information on Ingredients ============= Ingred Name:THIAMINE HYDROCHLORIDE, 100 MG/ML CAS:67-03-8 Other REC Limits:NONE RECOMMENDED Ingred Name:CHLOROBUTANOL CAS:57-15-8 Fraction by Wt: 0.5% Other REC Limits:NONE RECOMMENDED Ingred Name:MONOTHIOGLYCEROL CAS:96-27-5 Fraction by Wt: 0.5% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 8224 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE, SKIN AND RESPIRATORY IRRITATION MAY OCCUR. Explanation of Carcinogenicity:NOT A CARCINOGEN. Effects of Overexposure:THIS PRODUCT IS INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY A PHYSICIAN. POTENTIAL ADVERSE REACTIONS FROM PRESCRIBED DOSES AND OVERDOSES ARE DESCRIBED IN THE PACKAGE INSERT. OCCUPATIONAL EXPOS URE HAS NOT BEEN FULLY INVESTIGATED. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-MOVE PERSON TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION & CARDIOPULMONARY RESUSCITATION IF REQUIRED. SEEK MEDICAL ATTENTION. INGESTION-FLUSH MOUTH OUT WITH WATER IMMEDIATELY. SEEK MEDICAL ATT ENTION. SKIN-REMOVE CONTAMINATED CLOTHING IMMEDIATELY. FLUSH AREA WITH WATER FOR AT LEAST 15 MIN. SEEK MEDICAL ATTENTION. EYE-IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MIN. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F,>93C Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM AS APPROPIATE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN-UP SPILL. WIPE SURFACES CLEAN AND WASH WITH SOAP AND WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:AS A GENERAL RULE, WHEN HANDLING PHARMACEUTICAL PRODUCTS AVOID ALL CONTACT AND INHALATION OF DUST, FUME, &/OR VAPORS ASSOCIATED WITH THE PRODUCT. Other Precautions:FOR ADDITIONAL INFORMATION SEE THE PRODUCT INSERT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WITH SATISFACTORY VENTILATION, RESPIRATORY PROTECTION NOT USUALLY REQUIRED. Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL EXHAUST VENTILATION WHEN NECESSARY. Other Protective Equipment:DISPOSABLE GRAMENTS IF DIRECT SKIN CONTACT IS ANTICIPATED. Work Hygienic Practices:AVOID SKIN CONATCT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C3 Melt/Freeze Pt:M.P/F.P Text:478F,248C pH:2-4.5 Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS, NUT LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:EXPOSURE TO LIGHT AND/OR HEAT MAY CAUSE DECOMPOSITION. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC FUMES OF SOX AND NOX. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:4339 DEVELOPER Preparer's Name:KRISTINA SAGE CAGE:54726 CAGE:5X817 CAGE:54726 CAGE:4M009 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:STYRENE ACRYLIC RESIN Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED Ingred Name:DYE (PROPRIETARY) Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED Ingred Name:FERRITE Fraction by Wt: 97% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50: >10G/KG (NON-TOXIC) Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE SLIGHT CONJUNCITVAL IRRITATION. MAY CAUSE SLIGHT IRRITATION ON PROLONGED AND REPEATED CONTACT WITH THE SKIN. MILDLY IRRITATING. INHALATION: GASPING. INGESTION: >10G/KG BODYWEIGHT. CHR ONIC: SLIGHT FIBROSIS WAS OBSERVED IN RATS WHO INHALED(PROLONGED) 4 TO 16 MG/M3 OF A SPECIAL TEST TONER. Explanation of Carcinogenicity:CARBON BLACK IS LISTED ON THE IARC MONOGRAPH, BUT INADEQUATE EVIDENCE EXISTS TO DETERMINE IT A HUMAN CARCINOGENIC RISK. Effects of Overexposure:NONE UNDER NORMAL CONDITIONS OF USE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: TRY TO REMOVE WITH EYE DROPS OR FLUSH WITH WATER. IF UNSUCCESSFUL, GET MEDICAL ATTENTION. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION: DILUTE STOMACH C ONTENTS WITH SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:NO SPECIAL FIRE-FIGHTING PROCEDURE IS NECESARY. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, SWEEP UP USING AN APPROVED TONER VACUUM CLEANER WITH A 0.5 MICRON FILTER SUCH AS THE ATRIX AAA TONER VACUUM. USE OF A VACUUM CLEANER NOT RATED FOR TONER PARTICULATE COULD BE A POTENTIAL FI RE HAZARD AND/OR RESULT IN PERSONAL INJURY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP OUT OF REACH OF CHILDREN. DO NOT INCINERATE. Other Precautions:DO NOT HANDLE IN AREAS WHERE WIND BLOWS. FLYING POWDER MAY ENTER EYES. MINIMIZE INHALATION OF DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:MECHANICAL(GENERAL) EXHAUST TO PROVIDE ADEQUATE VENTILATION. LOCAL EXHAUST IS NOT NEEDED UNDER NORMAL CONDITIONS OF USE. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:MINIMIZE BREATHING DUST. CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS AND MEALS, AND AT THE END OF WORK PERIODS. Supplemental Safety and Health IDENTIFIED ON MSDS AS DEVELOPER FOR 7250/7120/7500 (BLACK). ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.97 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER, NO ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER DECOMPOSITION PRODUCTS IN THE CASE OF INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:USED TONER SHOULD BE DISPOSED OF IN AN ENVIRONMENTALLY SAFE MANNER AND IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS. DISPOSAL REGULATIONS VARY FROM LOCALITY TO LOCALITY, THEREFORE, CONSULT YOUR LOCAL O FFICE OF THE EPA TO DETERMINE PROPER METHODS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:36418 COBALT II NITRATE CAGE:0JVJ1 CAGE:0JVJ1 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT (II) NITRATE HEXAHYDRATE (IARC - GROUP 2) *95-3* CAS:10026-22-9 RTECS #:QU7355500 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:DUST IS IRRITATING TO EYES, NOSE & THROAT. SKIN/EYES: SOLID IS IRRITATING. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, COUGHING, DIFFICULT BREATHING, NAUSEA, VOMITING. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: FLOOD W/LARGE VOLUMES OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO2, DRY CHEMICAL, DRY SAND, DRY GROUND DOLOMITE Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA, FLAME & REMOVE MATERIAL FROM FIRE AREA. (SEE SUPP) Unusual Fire/Explosion Hazard:WILL INCREASE THE INTENSITY OF A FIRE. POISONOUS GASES MAY BE PRODUCED IN FIRE. CONTACT W/WOOD & PAPER MAY CAUSE A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEARING FULL PROTECTIVE CLOTHING & RESPIRATORY PROTECTION. ELIMINATE SOURCES OF IGNITION. COVER W/DRY SAND/DRY VERMICULITE, MIX WELL & CAREFULLY TRANSFER TO A WELL MARKED CONTAINER. CLOSE CONTAINER TI GHTLY. SUBMIT RETAIN FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:COMPOUND IS MOISTURE SENSITIVE. HANDLE DRY, WELL-VENTILATED AREA. Other Precautions:POISONOUS GASES MAY BE PRODUCED IN FIRE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR ORDINARY USE, WEAR NIOSH/MSHA APPROVED DUST MASK. FOR EMERGENCY WEAR NIOSH/MSHA APPROVED SCBA. Ventilation:LOCAL EXHAUST: FUME HOOD. MECHANICAL: ADEQUATE. SPECIAL: Other Protective Equipment:LAB COAT, APRON, FLAME & CHEMICAL RESISTANT COVERALLS, EYEWASH & SAFETY DRENCH SHOWER. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER USE. Supplemental Safety and Health COOL CONTAINER W/WATER FROM MAXIMUM DISTANCE. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:131-132.8F Spec Gravity:1.87 Solubility in Water:COMPLETE Appearance and Odor:RED CRYSTALS, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, WOOD, PAPER Stability Condition to Avoid:MOISTURE Hazardous Decomposition Products:NITROGEN OXIDES IN FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TAPE PRIMER SPRAY ADHESIVE CAGE:59986 CAGE:59986 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 20% Other REC Limits:LEL 7.5 OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 45% Other REC Limits:12 OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANE/ISOBUTANE (VAPOR PRESSURE 208 PSIG @ 100F) CAS:68476-86-8 Other REC Limits:NONE SPECIFIED Ingred Name:VOC: 1.89 LBS/GAL RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: BREATHING: RESPIRATORY TRACT IRRIT; MAY AFFECT BRAIN OR NERVOUS SYSTEM-DIZZINESS, HEADACHE, NAUSEA, WEAKNESS & FATIGUE. UNCONSCIOUSNESS & EVEN RESPIRATORY ARREST. EYE/SKIN: IRRIT. SWALLOWING: C AN CAUSE STOMACH &/OR INTESTINAL IRRIT,NAUSEA, VOMIT, DIARRHEA. ASPIR OF VOMITUS CAN CAUSE CHEM PNEUMONITIS/POSS FATAL. Explanation of Carcinogenicity:METHYLENE CHLORIDE IS LISTED BY NTP AND ACGIH AS A SUSPECTED CARCINOGEN. Effects of Overexposure:CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. PROLONGED & REPEATED BREATHING OF SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF YEARS MAY CAUSE DUST DISEASE OF THE LUNGS. Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHALED: REMOVE TO FRESH AIR. CONTINUED DIFFICULTY-GET MED AID IMMED. BREATHING CEASES-GIVE CPR & GET MED AID IMMEDIATELY. EYES: FLUSH W/LARGE AMOUNTS WATER-15 MIN. GET MEDICAL ASSISTANCE. SKIN: WASHAREA THOROUGHLY W/SOAP & WATER. REMOVE SOILED CLOTHING. GET MEDICAL AID IF IRRITATION PERSISTS. INGEST: DO NOT INDUCE VOMIT. GET MED AID. ASPIR OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS/POSS FATAL. ===================== Fire Fighting Measures ===================== Flash Point:NR Extinguishing Media:IN CASE OF FIRE, USE CO2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:USE FULL PROTECT EQUIP, INCLD SCBA. WATER SPRAY INEFFECTIVE. WATER USED/FOG NOZZLES PREFERRED. COOL CLOSED CNTNR W/WATER/PREVENT PRESS BUILDUP/POSS AUTO-IGNITE. Unusual Fire/Explosion Hazard:KEEP CNTNR CLOSED TIGHT & FROM IGNITE SOURCES. DUE TO PRESS BUILDUP, CLOSED CNTNR MAY EXPLODE W/HEAT. DURING EMERG COND, OVEREXPOS TO DECOMP PROD/HEALTH HZD. * ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITE SOURCES. AVOID BREATHING VAPORS. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD CAUTION INFO IN THIS MSDS. VENT AREA. CONTAIN SPILLED MAT'L & REMOVE W/INERT ABSORBENT & NONSPARKING TOOL S. STORE IN CLOSED CNTNRS UNTIL PROPERLY DISPOSED. ======================Handling and Storage ====================== Handling and Storage Precautions:REMOVE IGNITE SOURCES. VAPORS MAY IGNITE EXPLOS OR CAUSE FLASH FIRE. VAPORS MAY SPREAD LONG DISTANCES & BEYOND CLOSED DOORS. CONTENTS UNDER PRESSURE. Other Precautions:PREVENT VAPOR BUILD-UP BY KEEPING CONTINUOUS FLOW OF FRESH AIR. EXTREMELY FLAMM LIQUID & VAPOR. EXPOS TO HEAT OR PROLONGED EXPOS TO SUN MAY CAUSE BURSTING. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 1 20 F. DO NOT PLACE IN GARBAGE COMPACTOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:OUTDOOR/OPEN AREAS: USE NIOSH/MSHA APPROVED MECHANICAL FILTER RESPIRATOR. RESTRICTED AREAS: WEAR NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTERS. CONFINED AREAS: WEAR NIOSH/MSHA APPROVED AIR SUPPLY RE SPIRATORS OR HOODS. Ventilation:USE W/ADEQUATE VENT. PROVIDE DILUTION/LOCAL EXHST VENT IN VOLUME/PATTERN TO KEEP AIR CONTAM CONC BELOW STANDARDS. Other Protective Equipment:DO NOT GET ON SKIN. SOLVENT IMPERMEABLE CLOTHING & BOOTS TO PREVENT CONTACT ARE RECOMMENDED. Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health DO NOT STORE >120 F OR NEAR FIRE OR OPEN FLAME. STORE LG AMTS IN BUILDINGS DESIGNED TO COMPLY W/OSHA1910.106. KEEP CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELLED CNTNR S. DO NOT REUSE EMPTY CNTNRS. KEEP FROMCHILDREN. CONTAINS CHEM KNOWN TO CALIF STATE TO CAUSE CANCER, BIRTH DEFECTS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:44 TO 98 F Vapor Density:> AIR Evaporation Rate & Reference:FASTER THAN ETHER Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:MAY CAUSE HAZARDOUS FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CO, CO2, OXIDES OF METALS & CHLORINE CMPDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MOLYBDENUM IN H*2O 10,000 UG/ML, I42815 CAGE:0L438 CAGE:0L438 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDIC ACID, DIAMMONIUM SALT (AMMONIUM MOLYBDATE) CAS:13106-76-8 RTECS #:QA4900000 Fraction by Wt: 0.1-1% OSHA PEL:5 MG MO/M3 ACGIH TLV:5 MG MO/M3 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 99% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BURNS, COUGHING, IRRITATION, NAUSEA, VOMITING, LABORED BREATHING. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH WATER FOR 15 MINUTES. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. INGEST: DO NOT INDUCE VOMITING. GIVE COPIOUS AMOUNTS OF WATER OF MILK. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP WITH INERT, ABSORBENT MATERIAL. CONTAINERIZE FOR DISPOSAL. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A CORROSION FREE AREA. KEEP CONTAINER SEALED. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST. Other Protective Equipment:LAB COAT OR APRON. EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:USUAL. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Spec Gravity:1 (H*2O=1) Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS, ODORLESS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES OR STRONG REDUCING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT OR COLD. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CORROSIVE WASTE. DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GRANULAR CATALYST, 511-883 Preparer's Name:MEERA DATTA CAGE:56163 CAGE:56163 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT (2+) OXIDE CAS:1307-96-6 RTECS #:GG2800000 Fraction by Wt: 1% OSHA PEL:0.05 MG/M3 (MFR) ACGIH TLV:0.05 MG/M3 (MFR) Ingred Name:ALUMINUM OXIDE (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 99% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT OF UPPER RESP TRACT. SKIN: PROLONGED CONT MAY CAUSE SENSIT. EYES: IRRIT. INGEST: HDCH, NAUS, VOMIT, DIZZ, GI IRRIT. SKIN ABSORPTION: NONE IDENTIFIED. TO THE BEST OF MFR KNOWLEDGE, THE CHEM, PHYSICAL, & TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THORO INVESTIGATED. TARGET ORGANS: RESP SYS, SKIN, EYES. Explanation of Carcinogenicity:COBALT OXIDE: IARC MONOGRAPHS, VOLUME 52, PAGE 363, 1991: GROUP 2B. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. INHALATION: IF PERSON BREATHES IN LARGE AMOUNTS, REMOVE TO FRESH AIR. ADMI NISTER OXYGEN FOR BREATHING DIFFICULTIES. SEEK MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, IMMEDIATELY INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Extinguishing Media:MATERIAL DOES NOT BURN. USE EXTINGUISHING MEDIA FOR SURROUNDING AREA. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE IDENTIFIED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND PLACE IN A SEALED CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. DO NOT STORE NEAR INCOMPATIBLE MATERIALS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST, MIST RESPIRATOR. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH APPROVED SCBA IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . LAB COAT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:3.5-4.0 Solubility in Water:INSOLUBLE Appearance and Odor:DARK BLUE-GRAY GRANULES WITH NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RNASE A SOLUTION,QIAPREP 96 TURBO BIOROBOT KIT,962141 CAGE:01QTQ CAGE:01QTQ ============= Composition/Information on Ingredients ============= Ingred Name:RIBONUCLEASE A CAS:9001-99-4 RTECS #:RF0760000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRITATING TO EYES, RSPIRATORY SYSTEM, AND SKIN. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYE CONT: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING THE EYELIDS WITH FINGERS. SKIN CONT: IMMEDIATELY WASH WITH SOAP AND CO PIOUS AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS . CALL A PHYSICIAN. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, OR APPROPRIATE FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:PRECAUTIONARY MEASURES: WEAR NIOSH APPRVD CLEAN-UP PROCEDURE: SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID DUST. VENT ILATE AREA AND WASH SPILL SITE AFTER MATEIRAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE TIGHTLY CLOSED AT 20-25 C. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT BREATHE VAPOR. STORE IN A DRY PLACE. Other Precautions:THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED OUT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH THORUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Hazardous Decomposition Products:NONE. =================== Toxicological Information=================== Toxicological Information:TOXICITY DATA: N/A. ACUTE EFFECTS. INHALATION: MAY BE HARMFUL BY INHALATION. EYE CONT: MAY CAUSE EYE IRRITATION. SKIN CONT: MAY CAUSE SKIN IRRITATION. INGEST: MAY BE HARMFUL IF SWALLOWED. PROLONGED EX POSURE: N/A. CHRONIC EFFECTS: N/A. ===================== Ecological Information ===================== Ecological:NO DATA AVAILABLE. HOWEVER, THE SUBSTANCE IS READILY BIODEGRADABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL DISPOSAL METHOD REQUIRED. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS. ===================== Regulatory Information ===================== Federal Regulatory Information:LABELING: XN, HARMFUL, R 36/37/38-42/43. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TB 1743 ADHESIVE Preparer's Name:KAZ KISHITA CAGE:60859 CAGE:60859 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL-2-CYANOACRYLATE CAS:708-85-0 Fraction by Wt: 95-98% Other REC Limits:NONE SPECIFIED ACGIH TLV:4 PPM (EYE IRRITANT) Ingred Name:POLYMETHYLMETHACRYLATE CAS:9011-14-7 RTECS #:TR0400000 Fraction by Wt: 2-5% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYE IRRITATION, BONDS SKIN INSTANTLY. Effects of Overexposure:EYE IRRITATION, BONDS SKIN INSTANTLY. ======================= First Aid Measures ======================= First Aid:IN CASE OF EYE CONTACT, HOLD EYELID OPEN AND FLUSH WITH WATER FOR MORE THAN 15 MIN. SEE DOCTOR AT ONCE. IN CASE OF SKIN CONTACT, DO NOT FORCE OR PULL APART. USE GLUE REMOVER, POLISH REMOVER, OR ACETON E. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:181F,83C Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WATER CAUSES POLYMERIZATION OF THE LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. EVACUATE THE AREA, WEAR PROTECTIVE EQUIPMENT. STOP LEAK IF POSSIBLE. RECOVER AS MUCH MATERIAL PRACTICAL. SOAK UP REMAINDER. Neutralizing Agent:VINEGAR TO PREVENT POLYMERIZATION THEN ABSORB WITH ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHILE NOT IN USE. STORE IN COOL AND DRY AREA OUT OF DIRECT SUN. Other Precautions:DO NOT POUR OR CHANGE TO ANOTHER CONTAINER, MAY RESULT IN SHORT SHELF-LINE. DO NOT SPILL LIQUID: WILL REACT WITH ABSORBENT AND BOND WITH OTHERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIAL. IF TLV EXCEEDS, WEAR APPROPRIATE NIOSH/MSHA APPROVED. Ventilation:MECHANICAL AND LOCAL EXHAUST ARE RECOMMENDED. Other Protective Equipment:IMPERVIOUS CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:>150F,>66C Melt/Freeze Pt:M.P/F.P Text:-40F,-40C Decomp Temp:Decomp Text:500F,260C Vapor Pres:2 Vapor Density:> AIR Spec Gravity:1.04 pH:6 TO 7 Evaporation Rate & Reference:VERY SLOW Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR LIQUID, PUNGENT ODOR Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID, BASE WATER, ALCOHOLS. Stability Condition to Avoid:WATER EXCESS HEAT Hazardous Decomposition Products:ACID, CARBON MONOXIDE, CARBON DIOXIDE, POSSIBLE CYANIDE COMPOUND. Conditions to Avoid Polymerization:WATER, BASE, ALCOHOLS, EXCESS HEAT. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NO 377 ODORTROL DEODORANT Preparer's Name:RICK GLISSON CAGE:66086 CAGE:66086 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION TO LUNGS (STRONG ODOR). Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH W/WATER. IF IRRITATION PERSISTS, CALL MD. EYES: FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES. IF IRRITATION PERSISTS, CALL MD. INGEST: IF CONSCIOUS, DRINK A QUART OF WATER & TAKE ADRENALIN. M AY BE CONTRAINDICATED FOR OVEREXPOSURE TO PARADICHLOROBENZENE. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESPIRATION/OXYGEN IF NECESSARY. CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:148F,64C Extinguishing Media:DRY CHEMICAL, FOAM, CO2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE UNPROT PERS FROM AREA OF SPILL. PROVIDE MAX VENT & REMOVE ALL IGNITION SOURCES. ONLY PERS EQUIPPED W/PROPER RESP & EYE/SKIN PROT SHLD BE PERMITTED IN AREA. CAREFULLY SHOVEL/SWEEP UP SPILLED MAT L & PLACE INTO CLOSED CONTRS. MAINTAIN (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALWAYS STORE UNUSED PORTION IN ORIGINAL CONTR W/CAP SECURE. NEVER STORE IN UNLABELED OR IMPROPERLY LABELED CONTR. AVOID TEMPERATURE EXTREMES. Other Precautions:AS W/ALL CHEMICALS, USE W/DUE CARE ACCORDING TO LABEL INSTRUCTIONS & PRECAUTIONS. AVOID BREATHING VAPORS. KEEP OUT OF REACH OF CHILDREN. FOR COMMERCIAL/INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED. USE NIOSH/MSHA APPROVED FULL FACE MASK FITTED W/ORGANIC VAPOR CANISTER FOR CONCENTRATES OVER 75 PPM. Ventilation:MECHANICAL (GENERAL), SUFFICIENT TO CONTROL VAPORS TO 75 PPM OR LESS. Other Protective Equipment:CLEAN AND PROTECTIVE CLOTHING TO AVOID SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPILL PROC: VENT UNTIL ALL VAPORS HAVE BEEN ELIMINATED. THEN THOROUGHLY FLUSH AREA OF SPILL WITH WATER. WASTE DISP METH: TO PVNT ENVIRON CONTAM. IT IS YOUR DUTY TO DISPOSE OF THE CHEM MATLS &/OR THEIR CONTRS I/A/W THE CLEAN AIR ACT, THE CLEAN WATER ACT, THE RCRA & ALL RELEVANT LOCAL, STATE, & FEDERAL REGS FOR DISPOSAL. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:345F,174C Vapor Pres:76 @ 100C Vapor Density:5.1 Spec Gravity:1.248 Solubility in Water:0.008 GM/100 GM Appearance and Odor:ORANGE AND WHITE SOLID WITH FRUITY ODOR. Percent Volatiles by Volume:20-30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:OPEN FLAMES, HOT GLOWING SURFACES OR ELECTRIC AREAS. Hazardous Decomposition Products:HYDROGEN CHLORIDE & POSSIBLE TRACES OF PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL SHLD BE RECOVERED &/OR REPROCESSED. OTHERWISE, IT MUST BE DISPOSED OF BY BURNING IN APPRVD INCINERATOR OR BURIAL IN A PERMITTED HAZ WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN WHEN USING OR DIS POSING OF CHEM MATLS &/OR THEIR CONTRS (SUPP DATA)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5508 ULTRA BLUE 5500 SERIES FLAT POSTER INK,4502808 CAGE:76708 CAGE:06608 CAGE:76708 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE COMPOUNDS/MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0 - 4% Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 5 MG/M3 (FUME) ACGIH TLV:0.2 MG/M3; 9596 Ingred Name:PETROLEUM DISTILLATE,AROMATIC HYDROCARBON/HEAVY AROMATIC NAPHTHA (SOLVENT NAPHTHA) CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 0 - 3% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <3% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ingred Name:VOLATILE ORGANIC CONTENT AS LISTED ON MSDS:359 G/L (3.0 LBS/GAL) RTECS #:9999999VC Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC CAS:64742-88-7 Fraction by Wt: 15 - 80% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:COPPER COMPOUNDS/COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0 - 20% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PETROLEUM DISTILLATE,AROMATIC HYDROCARBON/NAPHTHA,LIGHT AROMATIC (SOLVENT NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 0 - 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 0 - 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST9596 Ingred Name:PETROLEUM DISTILLATE,ALIPHATIC HYDROCARBON/SEVERELY HYDROTREATED LIGHT DISTILLATE CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 0 - 7% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 0 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9596 Ingred Name:ZINC COMPOUNDS/ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0 - 5% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LUNG. ACUTE- MAY CAUSE SEVERE EYE IRRITATION. REPEATED/PROLONGED SKIN CONTACT MAY CAUSE DRYNESS, BURNS. OVEREXPOSURE BY INHALATION/SKIN ABSORPTION MAY CAUSE CNS EFFECTS. INGESTION MAY CAUSE VOMITING. ASPIRATION HAZARD. CHRONIC- MAY CAUSE DERMATITIS, SILICOSIS, PERMANENT BRAIN & CNS DAMAGE. Explanation of Carcinogenicity:CONTAINS CRYSTALLINE SILICA. Effects of Overexposure:SEVERE IRRITATION, DROWSINESS, DIZZINESS, NAUSEA, VOMITING, HEADACHE, WEAKNESS, ABDOMINAL DISCOMFORT, DRYNESS OF SKIN, DERMATITIS, ABDOMINAL PAIN, TEARING, BLURRED VISION Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:CONTACT P HYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:100F,38C Lower Limits:1.0 Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER MAY BE INEFFECTIVE BUT SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. CONTAIN AND PICK UP SPILL WITH NON-FLAMMABLE ABSORBENT SUCH AS SAND, EARTH, VERMICULITE OR NON-SPARKING TOOLS. PREVENT LIQUIDFROM ENTERING SEWERS OR WATERWAYS. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA AWAY FROM SOURCES OF IGNITION & STRONG OXIDIZING AGENTS. KEEP OUT OF REACH OF CHILDREN. DO NOT STORE ABOVE 120F. Other Precautions:FLAMMABLE. EMPTY CONTAINERS RETAIN RESIDUE. FOLLOW ALL PRECAUTIONS. DO NOT GET IN EYES. DO NOT BREATHE VAPOR OR MIST. AVOID PROLONGED OR REPEATED SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING. DO NOT T AKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKING IN CONFINED AREAS, IF EXCESSIVE MISTING IS EXPECTED OR IF EXPOSURE MAY OR DOES EXCEED RECOMMENDED PERMISSIBLE EXPOSURE LIMITS (PEL), WEAR NIOSH-APPROVED RESPIRATORY PROTECTION FOR ORGANIC V APORS (REFER TO 29 CFR 1910.134). Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, INDUSTRIAL-TYPE WORK CLOTHING, APRON Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>300F,>149C Vapor Density:>1 Spec Gravity:1.1645 Evaporation Rate & Reference:<1 (ETHER=1) Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:44 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT, SPARKS, FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER NOXIOUS GASES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REUSING OR RECYCLING IS RECOMMENDED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:U-2486 RESIN CAGE:DO809 CAGE:DO809 CAGE:29966 ============= Composition/Information on Ingredients ============= Ingred Name:ANILINE,4,4'-METHYLENEDI-; (METHYLENE DIANILINE) CAS:101-77-9 RTECS #:BY5425000 Fraction by Wt: <75% ACGIH TLV:0.1 PPM, S EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:METHYLENE DIANILINE MAY BE ABSORBED THRU SKIN/INHALED AS VAPOR IN HARMFUL AMOUNTS. VAPOR INHALATION BECOMES A PROBLEM ONLY WHEN THE MATERIAL IS HEATED. SKIN CONTACT WITH SOLID OR WITH MOLTEN MATERIALFROM SPLASHING MAY PRODUCE CYANOSIS. Explanation of Carcinogenicity:METHYLENE DIANILINE: ANTICIPATED TO BE A CARCINOGEN(NTP); GROUP 2B(IARC). Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. GET MEDICAL HELP! SKIN: REMOVE SPLASHINGS. MECHANICALLY WASH EXPOS AREA (THORO W/SOAP/WATER). OXYGEN SHOULD BE ADMINISTERED IF HDCH/WEAK OCCURS F ROM SKIN ABSORP. IMMED REMOVE CONTAMD CLTHG! GET MED HELP FOR ANY SERIOUS EXPOS. INGEST: GIVE 3 GLASSES OF WATER; INDUCE VOMIT. GET MED HELP! INHAL: REMOVE TO FRESH AIR. GET MED HELP! ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:>220F,>104C Extinguishing Media:DRY CHEMICAL, WATER FOG, OR FOAM. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. DO NOT BREATHE VAPS/FUMES. PVNT ANY CONT OF PROD W/SKIN. Unusual Fire/Explosion Hazard:HEATING PROD IN CLOSED CONTAINERS MAY GENERATE EXCESSIVE PRESSURE WHEN THERMAL BREAKDOWN OCCURS; EXPLOSIVE RUPTURE IS POSSIBLE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SPILLS WITH SOLID ABSORBENT. AVOID SKIN CONTACT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DESIGN STOR AREA TO CNTN SPILLS. PROT CONTRS AGAINST DAM. AREA WHERE UX-911 IS STORED SHOULD BE ISOLATED & LIMITED TO THOSE SPECIALLY AUTHORIZED. Other Precautions:PREVENT SKIN CONTACT. STORAGE TEMPERATURE: 200F. AVERAGE SHELF LIFE: 6 MONTHS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR ONLY IF PRODUCT IS HEATED TO 200F OR HIGHER. Ventilation:GENERAL MECHANICAL AND LOCAL. Other Protective Equipment:AN EYE WASH STATION & SFTY SHOWER SHOULD BE PROVIDED. APRON. LONG SLEEVED & LONG LEGGED BODY COVERING CLTHG (SUPP DATA) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PROT EQUIP: MUST BE USED. LAUNDER AFTER EACH WORK SHIFT. WORKERS MUST SHOWER BEFORE CHANGING TO STREET CLOTHES. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:>300F,>149C Spec Gravity:1.02 Solubility in Water:SLIGHT Appearance and Odor:AMBER LIQUID-MAY CRYSTALLIZE, SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PRODUCT IS HYGROSCOPIC. STRONG OXIDIZERS. Stability Condition to Avoid:AVOID MOIST AIR. Hazardous Decomposition Products:MISCELLANEOUS NITROGENOUS & AROMATIC FRACTIONS CONSIDERED TO BE TOXIC. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR BURY IN A LICENSED FACILITY PER FEDERAL, STATE & LOCAL REGULATIONS. DO NOT DISCHARGE INTO WATERWAYS OR SEWER SYSTEMS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NAPHTHA, COMPASS Preparer's Name:C.A. EISENHARD CAGE:0AHD1 CAGE:60777 CAGE:0AHD1 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 0.4% Other REC Limits:NONE RECOMMENDED Ingred Name:CUMENE CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: 0.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MESITYLENE CAS:108-67-8 RTECS #:OX6825000 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN-IRRITATION OF THIS SUBSTANCE HAS NOT BEEN DETERMINED. HOWEVER IT MAY BE A MODERATE SKIN IRRITANT. INHALATION-CAN CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION-PRACTICALLY NON-TOXIC TO INTERNAL ORGANS, BUT DUE TO LOW VISCOSITY THIS SUBSTANCE CAN DIRECTLY ENTER THE LUNGS & CAUSE SEVERE INJURY TO LUNGS & DEATH. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:SIGNS & SYMPTOMS MAY INCLUDE PAIN OR A FEELING OF HEAT, DISCOLORATION, SWELLING, BLISTERING. INHALATION-HEADACHE, DIZZINESS, LOSS OF APPETITIE, WEAKNESS & LOSS OF COORDINATION. ======================= First Aid Measures ======================= First Aid:EYE-FLUSH EYES WITH WATER IF NECESSARY. SKIN-REMOVE CONTAMINATED CLOTHING & SHOES. WASH CLOTHES BEFORE REUSE. WASH SKIN WITH SOAP & WATER. IF IRRITATION PERSISTS SEE A DOCTOR. INGESTION-DRINK WATER OR MILK TO DILUTE. DO NOT INDUCE VOMITING. PREVENT ASPIRATION WHICH CAN CAUSE CHEMICAL PNEUMONITIS. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:106F,41C Lower Limits:1.0 Upper Limits:6.0 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, AND WATER FOG. Fire Fighting Procedures:LIQUID EVAPORATES AND FORMS FUMES WHICH CAN CATCH FIRE & BURN WITH EXPLOSIVE VIOLENCE. INVISIBLE VAPOR SPREADS EASILY & CAN BE SET ON FIRE BY MANY SOURCES. Unusual Fire/Explosion Hazard:TEMPERATURE RISES ABOVE 85F. FIRE-FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. STOP SOURCE OF LEAK AND CLEANUP RELEASE AS SOON AS POSSIBLE. CLEAN UP SPILLS WITH ABSORBENT MATERIALS OR PUMPING. PREVENT CONTAMINATION OF SOIL, SURFACE WATER, GROUNDWA TER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE OR STORE NEAR FLAME, SPARKS, OR HOT SURFACES. USE ONLY IN WELL VENTILATED AREA. KEEP CONTAINER CLOSED. Other Precautions:DO NOT WELD, HEAT OR DRILL ON OR NEAR THIS CONTAINER. REPLACE CAP OR BUNG. EMPTY CONTAINERS STILL REATIN PRODUCT RESIDUE, HANDLE AS IF THEY WERE FULL. DO NOT USE PRESSURE TO EMPTY CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:BASED UPON CONTAMINATION LEVELS IN THE WORK PLACE, FOR EXAMPLE A SUPPLIED AIR RESPIRATOR. Ventilation:LOCAL EXHAISU OR MECHANICAL VENTILATION. Other Protective Equipment:IMPERVIOUS CLOTHING, RUBBER BOOTS, RUBBER APRON. Work Hygienic Practices:EYE WASH FOUNTAIN, QUICK DRENCH SHOWER. Supplemental Safety and Health FLAMMABLE LIQUID!! ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:325F,163C Vapor Pres:2.8 MMHG Vapor Density:4.8 Spec Gravity:0.788 Evaporation Rate & Reference:0.22 (BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT WITH STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE & WATERL INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS AND DISPOSE OF WITH APPLICABLE REGULATIONS. CONTACT LOCAL ENVIRONMENTAL OR HEALTH AUTHORITIES FOR APPROVED DISPOSAL OF THIS MATERIAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ETHYLENE OXIDE Preparer's Name:GEORGE VAIL CAGE:BALCH CAGE:BALCH ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2; 9495 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 72 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE IRRITATION,CORNEAL INJURY(POSSIBLY PERMANENT).SKIN:LIQUID MAY CAUSE FROSTBITE AND SEVERE IRRITATION.MAY BE DERMALLY ABSORBED IN HARMFUL AMOUNTS.INGEST:MAY CAUSE SEVERE GI TRACT I RRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND CNS DEPRESSION.CHRONIC:SEE SUPPL DATA. Explanation of Carcinogenicity:CONTAINS E [75-21-8] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:SKIN:(REACTIONS MAY BE DELAYED)BLISTERING,BURNS,EDEMA,VESCICLE FORMATION,SEVERE DERMATITIS.SKIN ABSORPTION:HEADACHE,DIZZINESS,NAUSEA,VOMITING.INHAL:HEADACHE,VOMITI NG,CYANOSIS,DROWSINESS,WEAKNESS,INCOO RDINATION,SALIVATION,LABORED BREATHING.INGEST:(UNLIKELY ROUTE OF ENTRY)ABDOMINAL PAIN,NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN,LIVER,KIDNEY,ADRENAL,NERVE OR RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.GET MEDI CAL ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<0F,<-18C Autoignition Temp:Autoignition Temp Text:804F Lower Limits:3 Upper Limits:100 Extinguishing Media:SMALL FIRES:CARBON DIOXIDE,DRY CHEMICAL.LARGER FIRES:POLYMER OR ALCOHOL FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG.FLUSH AREA WITH WATER AFTER FIRE EXTINGUISHED Unusual Fire/Explosion Hazard:**FLAMMABLE - EXPLOSIVE** FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:**ETHYLENE OXIDE GAS LEAK IS AN EMERGENCY** USE PROPER RESIRATORY AND PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF IGNITION.EVACUATE AREA.CALL 800-424-9300(CHEMTREC). Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:DO NOT WEAR CONTACT LENSES.AVOID BREATHING VAPORS.AVOID SKIN AND EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A SELF-CONTAINED BREATHING APPARATUS. Ventilation:USE EXPLOSION-PROOF LOCAL EXHAUST(LABORATORY FUME HOOD). Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health TO SUPRESS VAPORS USE 100:1(WATER:ETHYLENE OXIDE).CHRONIC HEALTH HAZARDS:SKIN-SENSITIZATION;EYES-CATARACT FORMATION;INHAL-CHROMOSOMAL ABERRATIONS,PERIPHERAL NEUROTOXIC EFFECTS,NUMBING OF THE SENSE OF SMELL;INGEST-ANEMIA,LIVER,ADRENAL AND KIDNEY DAMAGE. ================== Physical/Chemical Properties ================== HCC:G8 Boiling Pt:B.P. Text:51.0F,10.6C Vapor Pres:1094 Vapor Density:1.5 Spec Gravity:0.871 pH:7 Evaporation Rate & Reference:72 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:GAS/LIQUID;COLORLESS;SWEET ETHER-LIKE ODOR(ODOR THRESHOLD=700PPM) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SELF-POLYMERIZING CATALYSTS(EG.K,SNCL(ANH),AL,FE,ALCOHOLS,MERCAPTANS,CU,OXIDES OF ALUMINUM OR IRON). Stability Condition to Avoid:TEMPERTURES ABOVE 85F,SOURCES OF IGNITION.EXPLOSIVELY DECOMPOSES ABOVE 800F. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE Conditions to Avoid Polymerization:SELF-POLYMERIZING CATALYSTS(EG.K,SNCL(ANH),AL,FE,ALCOHOLS,MERCAPTANS,CU,OXIDES OF ALUMINUM OR IRON). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.RCRA CODE IS U115.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SAE 50 SF CC MOTOR OIL CAGE:GO691 CAGE:GO691 CAGE:31568 ============= Composition/Information on Ingredients ============= Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: 90-99% Other REC Limits:5 MG/CUM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RATS): >5000 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO EXPECTED TO CAUSE EYE/SKIN IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:NOT EXPECTED TO CAUSE EYE/SKIN IRRITATION. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:330-360F Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER SPRAY, WATER FOG Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS W/FULL FACE PIECE. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT ENTRY INTO SEWERS & WATERWAYS. PICK UP FREE LIQUID FOR RECYCLE/DISPOSAL. ABSORB SMALL AMOUNTS ON INERT MATERIAL FOR DISPOSAL. ============= Exposure Controls/Personal Protection ============= Ventilation:MECHANICAL Other Protective Equipment:NONE Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.875 Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID W/MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Hazardous Decomposition Products:THERMAL DECOMPOSITION: OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FP-98A PENETRANT (SEE SUPPL DATA) Kit Part:Y CAGE:98733 CAGE:98733 ============= Composition/Information on Ingredients ============= Ingred Name:LINEAR ALCOHOL CAS:68131-40-8 RTECS #:WZ5200000 Ingred Name:ETHOXYLATED NONYLPHENOL Fraction by Wt: <1.0% Ingred Name:ISOBUTANE/PROPANE MIXTURE(AS PROPELLANT) OSHA PEL:1000PPM (PROPANE) ACGIH TLV:ASPHYXIANTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE MILD IRRITATION TO SKIN & RESP TRACT SYSTEM. Effects of Overexposure:INHALATION:MAY CAUSE IRRITATION TO NOSE AND RESPIRATORY SYSTEM.EARLY TO MODERATE CNS DEPRESSION MAY BE EVIDENCED BY DIZZ,GIDDINESS,HEADACHE,NAUSEA;EYES:VAPOR MAY CAUSE IRRITATION;SKIN:LIQUID CONTACT M AY IRRITATE MILDLY;INGESTION:NOT LISTED. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN,EYE,AND RESPIRATORY DISORDERS MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.GIVE CPR IF NEEDED;EYES/SKIN:FLUSH WITH RUNNING WATER FOR AT LEAST 15 MINUTES.GET MEDICAL HELP IF IRRITATION OCCURS OR PERSISTS;INGESTION:IF VICTIM IS CONSCIOUS,INDUCE V OMITING.NOTHING BY MOUTH IF UNCONSCIOUSGET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:N/R (AEROSOLS) Extinguishing Media:WATER FOG,"ALCOHOL" FOAM,DRY CHEMICAL OR CO*2 Fire Fighting Procedures:CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER SPRAY TO PREVENT VAPOR PRESSURE BUILD-UP. DON'T STORE ABOVE 120F. Unusual Fire/Explosion Hazard:AEROSOL CANS MAY RUPTURE/EXPLODE DUE TO VAPOR PRESSURE BUILDUP IF EXPOSED TO INTENSE HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES.WEAR PROTECTIVE CLOTHING & APPROPRIATE RESPIRATOR.SOAKUP RESIDUE WITH ABSORBENT CLAY,SAND,EARTH,OR OTHER MATERIAL.PLACE RAGS & ABSORBED WASTE AND DAMAGED BUT EMPTY CANS IN D OT COVERED NON-LEAKING CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HOT PLACES & IGNITION SOURCES.DO NOT STORE OR HANDLE IN ALUMINUM EQUIPMENT AT TEMP ABOVE 120F. Other Precautions:DURING TRANSFER OF LIQUID IN BULK,GROUND THE HANDLING EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR IF EXPOSURE EXCEEDS TLV LIMITS. Ventilation:PER MFR,MECHANICAL(GEN) OR LOCAL EXHAUST TO MAINTAIN TLV OR REDUCE VAPORS. Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS Work Hygienic Practices:WASH WITH SOAP & WATER BEFORE EATING,DRINKING,SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health NSN OF 3 PARTS KIT UNDER TYPE I,METH C,LEVEL 3 OF MIL-I-25135,REV D;KIT CONSISTS OF PENETRANT,DEVELOPER,& REMOVER:I/A/W QPL-25135-15,THE MET-L-CHEK KIT MAY HAVE (1) FP-95,FP-98,OR FP-99 PENETRANT,(2) R-501 REMOVER & (3) D-701 OR D-703 DEVELOPER;KEY1:J7;THIS ENTRY DESCRIBES:FP-98A PENETRANT. ================== Physical/Chemical Properties ================== HCC:V3 Spec Gravity:<1.0 (BULK) Evaporation Rate & Reference:0.01 OF LIQ(BU-ACETAT=1.0 Solubility in Water:APPRECIATE Appearance and Odor:LIQUID BEFORE FILLING IN AEROSOL CANS IS GREENISH SYRUP LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:HEAT,SPARKS,IGNITION SOURCES Hazardous Decomposition Products:CARBON MONOXIDE & UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE #D001,IGNITABLE WASTE.EMPTY AEROSOL CAN BEFORE DISPOSING OF THEM.PRESSURIZED AEROSOL CANS ARE NOT ACCEPTABLE WASTE.COMPLY WITH ALL FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:837 8796 KODAK EKTACOLOR RA BLEACH FIX & RPLENSHR NR, PART C Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 3310-3530 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAPOR IS EXTREMELY IRRITATING. MAY CAUSE DELAYED LUNG INJURY. EYE CONTACT CAUSES SEVERE BURNS. VAPOR EXTREMELY IRRITATING TO EYES. CAUSES SEVERE SKIN BURNS UPON CONTACT. MAY BE HARMFUL IF SWALLOWED. M AY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:MAY CAUSE DELAYED LUNG INJURY. SEVERE EYE/ SKIN BURNS. IRRITATES EYES. BURNS OF GASTROINTESTINAL TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION ASAP. INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY REMOVE CONTAMINATED CLOTHI NG AND WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. CALL PHYSICIAN OR POISON CONTROL. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:COMBUSTIBLE. MATERIAL CONTAINS A COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN CONTAINER HEADSPACE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. MAY REQUIRE NEUTRALIZATION. ABSORB SPILL WITH VERMICULATIE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. USE ONLY WITH ADEQUTE VENTILATION. WASH THOROUGHLY AFTER HANDLING. Other Precautions:KEEP AWAY FROM HEAT AND FLAME. KEEP FROM CONTACT IWTH OXIDIZING MATERIALS. KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSUR LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS ARE USED, A PROGRAM SHO ULD BE INSTITUTED. Ventilation:USE PROCESS ENCLSURES/LOC EXHA VENTI/OTHER ENGINEER CNTRLS TO MAINTAIN AIRBORNE LEVELS BEL RECOMMENDED EXPO LIMITS. Other Protective Equipment:IMPERVIOUS BOOTS,PROT CLOTH APPROPRIATE FOR EXPO RISK. EYEBATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health KEY1:F6. ================== Physical/Chemical Properties ================== HCC:F6 Boiling Pt:B.P. Text:239F,115C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:18MM @20C Vapor Density:NOT GIVEN Spec Gravity:1.05 pH:1.0 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE. Appearance and Odor:COLORLESS LIQUID, WITH SHARP VINEGAR ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MATERIAL CAN REACT VIOLENTLY W/STRONG OXIDIZING AGENTS. MATERIAL CAN REACT W/METALS, STRONG BASES, AMINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL/STATE/LOCAL LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. NO CHEM SUBJECT TO REPORTING REQMTS OF SEC 313 OR TITLE III OF SARA & 40CFR PART 372.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P/S 870 C-12, ACCELERATOR Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGENATED TERPHENYLS CAS:61788-32-7 RTECS #:WZ6535000 Fraction by Wt: 35% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 PPM ACGIH TLV:0.5 PPM; 9596 Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 40% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:MAGNESIUM DICHROMATE CAS:13423-61-5 Fraction by Wt: 25% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.05 MG/M3 TWA Ingred Name:1,3 DIPHENYL GUANIDINE, CAS:102-06-7 RTECS #:MF0875000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HYDROGENATED PERPHENYL: EYES-IRRITATING. SKIN-PROLONGED SOAKKING IN HYDROGENATED PERPHENYL MAY PRODUCE DERMAL IRRITATION. INGESTION-PRACTICALLY NON-TOXIC. Explanation of Carcinogenicity:THIS CHEMICAL IS ON THE LIST ENTITLED "CHEMICALS KNOWN BY THE STATE OF CALIFORNIA TO CAUSE REPRODUCTIVE TOXICITY". Effects of Overexposure:INHALATION-MAY CAUSE DIZZINESS, DROWSINESS AND FATIDUE. DUE TO VERY LOW VOLATILITY OF THIS INGREDIENTS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES, IF SYMPTOMS PERSISTS, CONSULT PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF SY MPTOMS ARE PRESENT CONSULT A PHYSICIAN.INGESTION: CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:>93.3C, 200.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL HEAT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:EXCESSIVE HEAT MAY CAUSE DECOMPOSITION OF MAGNESIUM DIOXIDE, RESULTING IN OXIDATION AND POSSIBLE IGNITION OF HYDROCARBON VEHICLE. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH A SUITABLE SOLVENT. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INGESTION. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED. Ventilation:GENERAL VENTILATION. Other Protective Equipment:NONE KNOWN. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING OR EATING. Supplemental Safety and Health KEY 1: V5. THIS IS PART A OF A TWO PART KIT. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=340.C, 644.F Spec Gravity:1.801 Appearance and Odor:BLACK PASTE. Percent Volatiles by Volume:0.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS. Stability Condition to Avoid:NOT KNOWN. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN. MAGNESIUM AND CHROMIUM COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA NO. D-007 HAZARDOUS WASTE. DISPOSE OF IN COMPLIANCE WITH FEDERAL AND STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MED TAN EPOXY PT A APM 300 Preparer's Name:L DUSSAULT CAGE:MRTNC CAGE:MRTNC CAGE:31850 ============= Composition/Information on Ingredients ============= Ingred Name:TALC.ACGIH TLV AND OSHA PEL FOR RESPIRABLE DUST CONTAINING NO ASBESTOS FIBERS. CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 14.68% Other REC Limits:N/K OSHA PEL:2 MG/M3 RESP DUST ACGIH TLV:2 MG/M3 RESP DUST Ingred Name:TITANIUM DIOXIDE.TLV FOR TOTAL DUST CONTAINING NO ASBESTOS & <1% CRYSTALLINE SILICA.PEL:5 MG/M3 RESP FRACTION. CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 22.99% Other REC Limits:N/K OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:N-BUTYL ALCOHOL.VP:4.39 MMHG.LEL:1.5%. CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 5.34% Other REC Limits:N/K OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE.VP:54.0 MMHG.LEL:1.0%. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 12.48% Other REC Limits:N/K OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE.VP:6.60 MMHG.LEL:1.0%. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4.77% Other REC Limits:N/K OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1-METHOXY-2-PROPANOL (PROPYLENE GLYCOL MONOMETHYLETHER).VP:10.90 MMHG.LEL:6.0%. CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: 7.60% Other REC Limits:N/K OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:RPTD/PRLNG CONT MAY RESULT IN DERM. TOLUENE/XYLENE MAY AFFECT LIVER, KIDNEY/BLOOD. RPTD/PRLNG OVEREXPOS TO SOLVENTS ASSOCD W/PERM BRAIN & NERVOUS SYSTEM DMG. DELIBERATELY CONCENTRATING & INHALING CONT ENTS MAY BE HARMFUL/FATAL. TOLUENE AND/OR XYLENE MAY HARM FETUS IF A PREGNANT WOMAN IS EXPOSED. NOTE:TOLUENE (SUP DATA) Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:IRRITATION. SKIN:IRRITATION AND DRYNESS. INGESTION:TOXIC IF INGESTED. INHALATION:HEADACHE, DIZZINESS AND NAUSEA. IRRITATION TO NOSE AND THROAT. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS, CHRONIC RESPIRATORY DISEASE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CONSULT PHYS. SKIN:WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONT PHYS IF IRRITATION PERSISTS. INGESTION:DRINK 1 TO 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT PHYS OR POISON CONTROL CENTER. INHALATION:REMOVE TO FRESH AIR. RESTORE BREATHING. CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:40.0F,4.44C Lower Limits:1.0 Upper Limits:N/K Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NISOH/MSHA APPRVD SCBA & FULL PROT EQUIP . ISOLATE FROM HEAT, SPARKS, ELEC EQUIP & OPEN FLAME. H*2O IS NOT USUALLY EFFECTIVE IN FIGHTING LIQUID FIRES. Unusual Fire/Explosion Hazard:WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS TO HELP PREVENT EXPLOSION WHEN EXPOSED TO EXTREME HEAT. HAZ DECOMP PROD:MOSTLY CARBON DIOXIDE/CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SPARK SOURCES, FLAMES AND HOT SURFACES. MAINTAIN ADEQUATE VENTILATION. AVOID BREATHING VAPORS. ADD ABSORBENT TO SPILL AREA. RECOVER FREE LIQUID. KEEP CHEMICAL PRODUCTS OUT OF STREAMS AND WA TERWAYS. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE VENTILATION. Other Precautions:AVOID CONTACT WITH EYES AND PROLONGED/REPEATED CONTACT WITH SKIN. DO NOT INGEST. FOR INDUSTRIAL USE ONLY. THIS PRODUCT CONTAINS PIGMENTS WHICH CAN BECOME A DUST NUISANCE WHEN REMOVED BY ABRASIVE BLAST ING, SANDING/GRINDING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNLESS AIR MONITORING DEMONSTRATES VAP/DUST/MIST LEVELS BELOW THE CURRENT PEL OR TLV VALUES, ALWAYS WEAR AN APPROPRIATE, PROPERLY FITTED (NIOSH/MSHA APPROVED) RESPIRATOR DURING USE. Ventilation:SHOULD BE EXPLOSION PROOF AND KEEP THE AIR CONTAMINANT CONC BELOW CURRENT OSHA PEL OR ACGIH TLV. Other Protective Equipment:N/K Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING TOILET FACILITIES. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health BP:LOW:231F,110.6C, HIGH:281F,138.3C. % VOLATILE BY WT:30.45. ROUTE OF .HEALTH HAZ:CAS# 108-88-3 APPEARS ON THE NAVY OCCUPATIO NAL REPRODUCTIVE HAZ LIST. CONSULT APPROP PERSONS ABOUT LATEST HAZ LIST INFO & SAFE HNDLNG & EXPOS RECOMMENDATION. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:54 MMHG Vapor Density:>1 (AIR=1) Spec Gravity:1.41 (WATER=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:N/K Appearance and Odor:LIQUID Percent Volatiles by Volume:49.46 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES N/K Stability Condition to Avoid:NONE REASONABLY FORSEEABLE. Hazardous Decomposition Products:CARBON DIOXIDE WITH SOME CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. XYLENE, TOLUENE, N-BUTANOL:SARA TITLE III SECTION 313 LISTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ION EXCHANGE RESIN A-464 Preparer's Name:HAZ MATLS CONTROL COM CAGE:80014 CAGE:80014 ============= Composition/Information on Ingredients ============= Ingred Name:ING 3: KNOWLEDGABLE IN HANDLING THESE MATERIALS. RTECS #:9999999ZZ Ingred Name:TRIMETHYALMINE FUNCTIONALIZED, CHLOROMETHYLATED COPOLYMER OF STYRENE AND DIVINYLBENZENE IN CHLORIDE FORM CAS:69011-19-4 Fraction by Wt: 40-50% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50-60% Ingred Name:OTHER PREC: CONTEMPLATED. BEFORE USING STRONG OXIDIZING AGENTS IN CONT W/ION EXCHANGE BEADS, CONSULT SOURCES (ING 4) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SOLID OR DUST MAY CAUSE EYE IRRITATION OR CORNEAL INJURY DUE TO MECHANICAL ACTION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES. CONSULT MD. INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTIFICIAL RESPIRATION) CALL MD (F P N). SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER OR DRY CHEMICAL TO EXTINGUISH FIRES. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP UP SPILL AND TRANSFER TO CONTAINERS FOR RECOVERY OR DISPOSAL. FLOOR MAY BE SLIPPERY; USE CARE TO AVOID FALLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT AMBIENT TEMPS. AVOID REPEATED FREEZE-THAW CYCLES. DO NOT PACK COLUMN W/DRY ION EXHANGE RESINS. DRY BEADS EXPAND WHEN WET; THIS (SUPP DATA) Other Precautions:NITRIC ACID & OTHER STRONG OXIDIZING AGENTS CAN CAUSE EXPLOSIVE TYPE REACTIONS WHEN MIXED W/ION EXHANGE RESINS. PROPER DESIGN OF EQUIP TO PVNT RAPID BUILD-UP OF PRESS IS NEC IF USE OF AN OXIDIZING AGE NT SUCH AS NITRIC ACID IS (ING 3) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE WITH ADEQUATE VENTILATION. Other Protective Equipment:WEAR CLEAN, BODY-COVERING CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MP:0C,32F (WATER). VP:17 @ 20C (WATER). HAZ DECOMP PROD: BY COMBUST:ALKYBENZENES, VINYL BENZENES, NAPHTHALENE BENZEALDEHYDES, PHENOL, CO2, WATER, ORG AMINES, CHLORINE, NITROGEN OXIDES, AMMONIA, METHYL CHLORIDE & OXIDES OF SULFUR ARE POSS COMBUST PRODS. HNDLG/ STOR PREC: EXPANSION CAN CAUSE GLASS COLUMN TO SHATTER. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:SUPP DATA Vapor Pres:SUPP DATA Spec Gravity:1.2 Evaporation Rate & Reference:1 (H2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:WHITE TO AMBER SOLID BEADS; ODORLESS TO SLIGHT AMINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/CONCENTRATED NITRIC ACID/ANY OTHER STRONG OXIDIZING AGENTS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT (GREATER THAN 90C (194F). Hazardous Decomposition Products:STYRENE, DIVINYLBENZENE MONOMERS & SULFUR DIOXIDE. (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF RESIN IN LICENSED INDUSTRIAL WASTE LANDFILL/BURN IN APPROVED INCINERATOR ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. FOR RESIN CONTAMINATED WITH HAZARDOUS MATL, DISPOSE OF MIXTURE AS HAZ MATL ACCORDING TO LOCAL, STATE ANDFED REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:578520 JET GLO URETHANE ADDUCT/CATALYST CAGE:PRATT CAGE:PRATT ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC POLYISOCYANATE, HEXAMETHYLENE DIISOCYANATE POLYMER (HDI POLYMER) *96-4* CAS:28182-81-2 RTECS #:NQ9170000 Other REC Limits:1 MG/CUM Ingred Name:ACETIC ACID, ETHYL ESTER, ETHYL ACETATE *96-4* CAS:141-78-6 RTECS #:AH5425000 Other REC Limits:400 PPM OSHA PEL:1400 MG/CUM ACGIH TLV:1400 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *96-4* CAS:123-86-4 RTECS #:AF7350000 Other REC Limits:150 PPM OSHA PEL:710 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXAMETHYLENE DIISOCYANATE *96-4* CAS:822-06-0 RTECS #:MO1740000 ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: MAY BE FATAL. GI IRRITATION. ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION: HARMFUL, LUNG IRRITATION & ALLERGIC RESPIRATORY REACTION, RESPI RATORY SENSITIZATION, NOSE & THROAT IRRITATION, CNS DEPRESSION. EYES: IRRITATION. SKIN: IRRITATION, SENSITIZATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, HEADACHE, DIZZINESS, CONFUSION, DEFATTING. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: TREATMENT SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS & THE CLINICAL CONDITIONS. ===================== Fire Fighting Measures ===================== Flash Point:24F Lower Limits:1.7 Upper Limits:11 Extinguishing Media:CO2, ALL PURPOSE DRY CHEMICAL/ALCOHOL FOAM. LARGE: POLYMER FOAM. Fire Fighting Procedures:WEAR SCBA. WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. AUTOIGNITION TEMP: 572F. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. ELIMINATE IGNITION SOURCES. DIKE & CONTAIN W/INERT MATERIAL. TRANSFER TO COVERED METAL CONTAINERS FOR RECOVERY/DISPOSAL. REMOVE W/INERT ABSORBENT. USE ONLY NON-SPARKING TOOLS. AVOID CON TAMINATION ENTRY INTO SEWERS, STREAMS/GROUNDWATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >115F. CLOSE CONTAINERS AFTER EACH USE. AVOID HEAT & OTHER IGNITION SOURCES. USE ADEQUATE VENTILATION. Other Precautions:DON'T TAKE INTERNALLY. EMPTY CONTAINERS MUSTN'T BE WASHED & RE-USED FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED & BONDED TO THE RECEIVING CONTAINER. PERSONS W/REACTION TO ISOCYANATES/BREATHING PROB LEMS, SHOULD AVOID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE FITTED POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR. IF UNAVAILABLE, USE A VAPOR PARTICULATE (PAINT SPRAY) RESPIRATOR. Ventilation:GENERAL DILUTION & LOCAL EXHAUST VENTILATION. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health DON'T WELD, BRAZE/CUT ON EMPTY CONTAINERS. AVOID BREATHING VAPOR/SPRAY MIST, CONTACT W/SKIN, EYES & CLOTHING. THE URETHANE ACTIVATOR IS 1 PART OF A 2 COMPONENT MIXTURE, ITS INTENT IS TO BE MIXED W/BAS E & MUST BE BLENDED W/OTHER COMPONENTS BEFORE THE PRODUCT CAN BE USED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:171-260F Melt/Freeze Pt:M.P/F.P Text:-50F Vapor Pres:73 Vapor Density:>1 Spec Gravity:1 pH:4-7 Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:66 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS/ALKALINE MATERIALS. Stability Condition to Avoid:EXCESSIVE HEAT & OTHER IGNITION SOURCES, TEMP >115F. Hazardous Decomposition Products:BURNING: SMOKE, CO, CO2, OXIDES OF NITROGEN. THE REACTION OF ISOCYANATES W/WATER MAY RESULT IN CO2 GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. FLAMMABLE LIQUID, UN1263. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CONTINUOUS FIBER P Preparer's Name:JACK L SHENEBERGER CAGE:5D028 CAGE:5D028 CAGE:71984 ============= Composition/Information on Ingredients ============= Ingred Name:SILICON CARBIDE CAS:409-21-2 RTECS #:VW0450000 Fraction by Wt: 100% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: MECH IRRIT MAY RESULT FROM PARTICLES/DUST IN EYE & SUBSEQUENT RUBBING. SKIN: MAY CAUSE SLIGHT IRRIT FROM SHARP FIBERS. DUST IS NOT LIKELY TO IRRITATE. INHAL: DUST MAY IRRIT NOSE & THROAT. PRLNGD/ FREQ RPTD EXPOS MAY INJURE SLIGHTLY. ORAL: AMTS TRANSFERRED TO MOUTH BY FINGERS, ETC, DURING (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: NORMAL OPER SHOULD NOT CAUSE INJURY. COMMENTS: POTENTIAL CHRONIC (LONG TERM) EFTS OF INHALING FIBERS & DUSTS OF THIS PROD HAVE NOT BEEN DETERMINED THORO. AVOID UNNEC INHAL EXPOS. THIS PROD, AS W/ANY CHEM, MAY ENHANCE ALLERGIC CNDTNS ON CERTAIN PEOPLE. Medical Cond Aggravated by Exposure:NONE KNOWN BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MD IF DISCOMFORT PERSISTS. SKIN: GENTLY BRUSH AWAY ANY DUST, PARTICLES, OR FIBERS AND FLUSH WITH WATER. INHAL: REMOVE TO FRESH AIR. IF D ISCOMFORT PERSISTS, GET MD ATTN. TYPICALLY, SHOULD NOT NEED FIRST AID EXCEPT FOR SEVERE OVEREXP. ORAL: GET MED ATTN IF LRG AMTS SWALLOWED-NOT TYPICALLY AN OVEREXP ROUTE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER FOG, CO*2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN TO DOW CORNING. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP MATERIAL TO COLLECT AND CONTAIN FOR SALVAGE OR DISPOSAL. AVOID GENERATING AIRBORNE DUSTS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE REASONABLE CARE AND CAUTION. Other Precautions:KNOWN HAZARDS RESULT MAINLY FROM DUST DURING HANDLING AND USE. PARTICLES OR FIBERS FROM NORMAL HANDLING ARE TOO LRG TO POSE A SIGNIFICANT INHAL RISK. HOWEVER, IF PROCESSING, SUCH AS GRINDING/MILLING, FORMS LRG AMTS OF DUST (SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DUST TYPE RESP UNLESS LOCAL EXHAUST VENTILATION IS ADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN TLV & PEL GUIDELINES. Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): NONE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. USE GOOD HOUSEKEEPING PRACTICES TO CONTROL POSSIBLE DUST PROBLEM. Supplemental Safety and Health OTHER PREC: OF SMALLER, EASILY BREATHED PARTICLES, SOME LUNG INJURY MAY OCCUR. REMOVE GROSS AMTS FROM SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. AVOID BREATHING DUST. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:ABOVE 1 Solubility in Water:INSOLUBLE Appearance and Odor:NO ODOR, THREAD-LIKE FIBER, DARK COLOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL CAN CAUSE A REACTION. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DOW CORNING SUGGESTS THAT ALL LOCAL, STATE AND FEDERAL REGS CONCERNING HLTH & POLLUTION BE REVIEWED TO DETERMINE APPROVED DISP PROCEDURES. CONTACT DOW CORNING IF THERE ARE ANY DISP QUESTIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:838 5882 RA 2001 DEVELOPER READY-TO-USE CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-90% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 2% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES:CAUSES IRRIT. SKIN:CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGEST:EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICIATION:NONE FOR IARC/ACGIH/NTP/OSHA. Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, ALLERGIC SKIN REACTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR.SYMPTOMS PERSIST GET MED ATTN. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS.GET MED ATTN. SKIN:REMOVE CONTAMIN CLOTH/SHOES.WASH W/SOAP/WATER.GET MED ATTN. INGEST:DRINK 1-2 GLASSES OF WATER.SEEKMED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE,NON-COMBUST Extinguishing Media:USE APPROPRIATE AGENT FOR ADAJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB SPILL W/VERMICULITE OR OTHER INERT MATL.THEN PLACE IN CNTNR FOR CHEM WASTE.CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/EYES/SKIN/CLOTH.USE W/ADEQUATE VENTI.KEEP CNTNR CLOSED.KEEP AWAY FRONM INCOMPATIBLE SUBSTANCES. Other Precautions:MODERATELY ALKALINE AQUEOUS SOLN W/PROPERTIES:LOW BIOCHEM OXY;LITTLE POT TO CAUSE OXY DEPLETION IN AQU SYS;HIGH POT TO AFFECTS SOME AQUATIC ORGANISM;MOD POT TO AFFECT GERMINATION &/OR EARLY GROWTH OF SOME PLANTS;LOW POT TO PERSIST (SUPPLEM) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)SHOULD BE USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYEBATH,WASH FACILITIES,SAFTY SHOWER.WASH CONTAMIN CLOTH BEF REUSE;DESTROY/CLEAN WELL SHOES. Work Hygienic Practices:WASH WELL AFT HNDLG.ROUTINE USE OF HELPS MIN SKIN RX. Supplemental Safety and Health OTHER PRECAUT:IN ENVIRO;LOW POT TO BIOCONCEN.AFT DILU W/LG AMTS OF WATER & 2ND WASTE TREATMENT MATL NOT EXPECTED TO CAUSE ADVERSE ENVRIO EFFECTS. MAKES 5 GALLONS READY-TO-USE. THIS NSN REPLACES NSN67 50-01-337-2205 CANCELLED 92092. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18MM Vapor Density:0.6 Spec Gravity:1.094 pH:10.5 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, LIGHT YELLOW, ODORLESS. Percent Volatiles by Volume:85-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SULFUR DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NAT/STATE/LOC LAWS.FLUSH TO SEWER W/LG AMTS OF WATER. CHEM SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III OF SARA & 40CFRPART372:HYDROQUINONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ADHESIVE CYANOACRYLATE 472 Preparer's Name:STEPHEN REPETTO CAGE:05972 CAGE:05972 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL CYANOACRYLATE CAS:7085-85-0 Fraction by Wt: 90-95% Other REC Limits:2 PPM TWA Ingred Name:POLYMETHYLMETHACRYLATE CAS:9011-14-7 RTECS #:TR0400000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA III) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 0.1-0.5% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) 320MG/KG(HYDROQUINONE) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CYANOACRYLATE ADHESIVES BOND TO SKIN QUICKLY.EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:MAY CAUSE GI TRACT IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION AND ALLERGIC SENSITIZATION. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:MAY PRODUCE ASTHA-LIKE SYMPTOMS. Medical Cond Aggravated by Exposure:MANUFACTURER STATES NONE KNOWN. ======================= First Aid Measures ======================= First Aid:FOR ACCIDENTAL CYANOACRYLATE BONDING--SKIN:IMMERSE IN WARM,SOAP WATER;PEEL OR ROLL THE SURFACES APART;REMOVE WITH SOAP AND WATER.EYES:WASH WITH WARM WATER;APPLY GAUZE PATCH.EYE WILL OPEN IN 1-4 DAYS.D O NOT OPEN EYES BY MANIPULATION!!INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:150F,66C Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:WATER CAUSE MATERIAL TO POLYMERIZE.FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:FLOOD WITH WATER TO POLYMERIZE;SOAK UP WITH NON-COMBUSTIBLE INERT ADSORBANT(EG.CLAY);PLACE COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:NO APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 75F. Other Precautions:AVOID SKIN AND EYE CONTACT.DO NOT INHALE VAPORS/MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED IN NORMAL SERVICE. Ventilation:LOCAL VENTILATION(DOWNDRAFT FOR HEAVY VAPORS) AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:<0.2 Vapor Density: 3 Spec Gravity:1.09 Solubility in Water:POLYMERIZES Appearance and Odor:LIQUID;CLEAR;SHARP,PENETRATING ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER,ALCOHOL,AMINES,ALKALIES. Stability Condition to Avoid:MOISTURE,HIGH HEAT,SOURCES OF IGNITION. Hazardous Decomposition Products:UNIDENTIFIED ORGANIC COMPOUNDS. Conditions to Avoid Polymerization:WATER,ALCOHOL,AMINES,ALKALIES. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMMONIUM HYDROXIDE, 28-30% Resp. Party Other MSDS Num.:AA 265 Preparer's Name:MICHAEL RASZEJA CAGE:6V042 CAGE:6V042 Contract Num:MDA414-99-P-3141 CAGE:0X801 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE CAS:1336-21-6 RTECS #:BQ9625000 Minumum % Wt:28. Maxumum % Wt:30. Other REC Limits:NOT PROVIDED. OSHA PEL:NOT ESTABLISHED. Code:F ACGIH TLV:25 PPM/17 MG/M3 NH3 ACGIH STEL:35 PPM/24 MG/M3 NH3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:70. Maxumum % Wt:72. Other REC Limits:NOT PROVIDED. OSHA PEL:NOT ESTABLISHED. ACGIH TLV:NOT ESTABLISHED. ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) 350 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EFFECTS OF OVEREXPOSURE: CAUSES SEVERE IRRITATION OR BURNS TO EYES, SKIN AND MUCOUS MEMBRANES; HIGHLY TOXIC BY ORAL AND INHALATION ROUTES. INHALATION OF AMMONIA GAS CAUSES EDEMA, SPASM, AND ASPHYXIA.IF CONTAINER IS WARM, OPEN CAP SLOWLY WITH ADEQUATE VENTILATION; A SUDDEN RELEASE OF AMMONIA FUMES MAY CAUSE IRRITATION TO EYES AND MUCOUS MEMBRANES. Explanation of Carcinogenicity:NONE Effects of Overexposure:CAUSES SEVERE IRRITATION OR BURNS TO EYES, SKIN AND MUCOUS MEMBRANES; HIGHLY TOXIC BY ORAL AND INHALATION ROUTES. INHALATION OF AMMONIA GAS CAUSES EDEMA, SPASM, AND ASPHYXIA. IF CONTAINER IS WARM, OPE N CAP SLOWLY WITH ADEQUATE VENTILATION; A SUDDEN RELEASE OF AMMONIA FUMES MAY CAUSE IRRITATION TO EYES AND MUCOUS MEMBRANES. Medical Cond Aggravated by Exposure:NOT PROVIDED. ======================= First Aid Measures ======================= First Aid:SKIN: FLOOD WITH WATER, THEN WASH WITH VINEGAR. EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES, LIFTING LIDS OCCASIONALLY. GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE LARGE QU ANTITIES OF WATER TO DRINK, FOLLOW WITH VEGETABLE OIL. GET PROMPT MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTI FICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Lower Limits:16 Upper Limits:25 Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING WITH RESPIRATOR MASK HAVING AMMONIA VAPOR CANISTER, OR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS. (1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAG E NO. 60). Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD; EMITS IRRITATING FUMES AND LIQUID CAN INFLICT BURNS. AMMONIUM HYDROXIDE IS NON-COMBUSTIBLE AND NON-EXPLOSIVE, BUT AMMONIA VAPORS RELEASED FROM SOLUTION CAN FORM AN EXPLOSIVE MIX TURE WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:WEARING PROTECTIVE EQUIPMENT, CAREFULLY NEUTRALIZE WITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. Neutralizing Agent:SODIUM BISULFATE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT 75F. STORE AWAY FROM SOURCES OF IGNITION, SEPARATE FROM ACIDS. S TORE IN WELL-VENTILATED AREA. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. READ LABEL ON CON TAINER BEFORE USING. Other Precautions:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID CONTACT WITH EYES, SKIN AND MUCOUS MEMBRANES. AVOID BREATHING VAPOR. USE WITH ADEQUATE VENTILATION. REMOVE AND WASH CONTAMINATED CLOTHING. KEEP OUT OF REACH OF CHILDREN. FOR LABORATORY USE ONLY. NOT FOR DRUG, FOOD, HOUSEHOLD USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WORK IN VENTILATION HOOD OR WEAR A NIOSH/MSHA APPROVED RESPIRATOR WITH AMMONIA CANISTER IF NECESSARY. Ventilation:LOCAL/MECHANICAL(GENERAL):RECOMMENDED Work Hygienic Practices:NOT PROVIDED. Supplemental Safety and Health P/N: A351-500 ML. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT. Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=-77.C, -106.6F Vapor Pres:584 Vapor Density:< 1 Spec Gravity:0.896-0.902 pH:NOT PROVIDED. Viscosity:NOT PROVIDED. Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:COMPLETE Appearance and Odor:WATER WHITE LIQUID; STRONG, PUNGENT AMMONIA ODOR. Percent Volatiles by Volume:70-72 Corrosion Rate:NOT PROVIDED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ACROLEIN, DIMETHYL SULFATE, HALOGENS, AGNO2, AGMNO4. Stability Condition to Avoid:WHEN HEATED, EMITS TOXIC FUMES OF AMMONIA. Hazardous Decomposition Products:AMMONIA FUMES. =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED. ===================== Ecological Information ===================== Ecological:NOT PROVIDED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. WEARING PROTECTIVE EQUIPMENT, CAREFULLY NEUT RALIZE SITH SODIUM BISULFATE AND FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER. =================== MSDS Transport Information =================== Transport Information:D.O.T.: AMMONIA SOLUTIONS, 8, UN2672. ===================== Regulatory Information ===================== SARA Title III Information:NOT PROVIDED. Federal Regulatory Information:NOT PROVIDED. State Regulatory Information:NOT PROVIDED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:D-TRANS ALLETHRIN 90% (BIO) 24 CAGE:FO900 CAGE:FO900 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED LIGHT DISTILLATE, PETROLEUM; C12-C15 ISOPARAFFINIC HYDROCARBONS CAS:64742-47-8 Other REC Limits:300 PPM (MFR) OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:ALLETHRIN CAS:584-79-2 RTECS #:GZ1925000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RATS LD50: 680 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, TEARING & BLURRED VISION. SKIN: IRRITATION OF MORE SENSITIVE AREAS. INGESTION: IRRITATION TO MOUTH. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION, TEARING & BLURRED VISION. SKIN: IRRITATION TO MORE SENSITIVE AREAS. INGESTION: IRRITATION TO MOUTH. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN: WASH AFFECTED AREAS W/WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN. IF BREATHING HAS STOPPED, ADMINISTER ARTIFICIAL RESPIRATION. INGESTION: DON'T INDUCE VOMITING. KEEPAFFECTED PERSON WARM & QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:180F Extinguishing Media:FOAM, CO2 OR DRY CHEMICAL Fire Fighting Procedures:TREAT AS AN OIL FIRE. USE A FULL-FACED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:KEEP NEARBY CONTAINERS & EQUIPMENT COOL W/WATER SPRAY. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN THE SPILL. SOAK UP THE SPILL W/ABSORBANT MATERIAL (SAND, CLAY, FLOOR ABSORBENT, ETC.). TRANSFER INTO WASTE CONTAINERS FOR DISPOSAL. KEEP THIS PRODUCT OUT OF WATER SUPPLIES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS UPRIGHT & CLOSED. STORE IN AREAS THAT ARE COOL, DRY & WELL VENTILATED. STORE AWAY FROM IGNITION SOURCES. Other Precautions:DON'T CONTAMINATE WATER, FEED OR FOOD BY STORAGE OR DISPOSAL. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERAL/LOCAL Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.995 Solubility in Water:INSOLUBLE Appearance and Odor:VISCOUS AMBER-COLORED LIQUID; SLIGHT AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE CONDITIONS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DISPOSED OF ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS.
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eyes_protection_mandatory