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===================== Product Identification ===================== Product ID:SQUEEZE N'FILL Preparer's Name:STEVE TAYLOR CAGE:CUSTO CAGE:CUSTO ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA). VP:0.1 @ 68F. LD50:(ORAL,RAT) 6,000-13,000 MG/KG. CAS:107-21-1 RTECS #:KW2975000 OSHA PEL:N/K ACGIH TLV:50 PPM, VAPOR, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VM & P NAPHTHA; (ALIPHATIC HYDROCARBONS). VP:15 @ 68F. CAS:64742-89-8 OSHA PEL:500 PPM (MFR) ACGIH TLV:N/K Ingred Name:ACRYLIC COPOLYMERS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION:VAPOR OR MIST CAN CAUSE HEADACHE, NAUSEA AND IRRITATION OF THE NOSE, THROAT AND LUNGS. SKIN CONTACT:IRRITATING UPON REPEATED OR PROLONGED CONTACT. EYE CONTACT:SLIGHT (TEMPORARY) IRRIT ATION. CORNEAL INJURY IS UNLIKELY. SKINABSORPTION:REPEATED EXPOSURE TO LARGE QUANTITIES MAY RESULT IN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ABSORPTION OF HARMFUL AMOUNTS. INGESTION:AMOUNTS INGESTED INCIDENTAL TO INDUSTRIAL HANDLING NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJURY, EVEN D EATH. CHRONIC:EXCESSIVE EXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM, KIDNEY, BLOOD & POSSIBLE LIVER EFFECTS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE & RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO ETHYLENE GLYCOL. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH W/WATER FOR AT LEAST 15 MINUTES. SEE MD IF IRRITATION RESULTS. SKIN:WASH W/WATER. SEEK MEDICAL ATTENTION IF IRRITATION RESULTS. INHAL:REMOVE TO FRESH AIR. INGEST:IMMEDIATELY IND UCE VOMITING BY GIVING TWO GLASSES OF WATER & STICKING FINGER DOWN THROAT. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . CLOSED CONTAINERS MAY RUPTURE IF EXPOSED TO EXTREME TEMPERATURES. Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE 100C/212F. ACRYLIC POLYMER FILM CAN BURN & CONTAINERS MAY RUPTURE IF EXPOSED TO EXTREME TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID ENTRY INTO SEWERS OR NATURAL WATER WAYS. SMALL SPILLS:SOAK UP W/ABSORBANT MATERIAL. LARGE SPILLS:DIKE & PUMP INTO SUITABLE CONTAINERS FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA OUT OF SUNLIGHT. STORE AWAY FROM HEAT OR ANY HEAT SOURCES. PROTECT FROM FREEZING. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY EXCEED TLV VALUE, USE A NIOSH APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO KEEP VAPOR CONCENTRATIONS W/IN SPECIFIED TLV RANGES. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . ADEQ CLTHG SHOULD BE WORN TO PVNT SKIN CONT. Work Hygienic Practices:HYGIENE & GOOD HOUSEKEEPING PRACTICES SHOULD BE OBSERVED. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.6 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SOLUBLE UNTIL DRIED Appearance and Odor:WHITE, CREAMY PASTE; MILD ACRYLIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING MATERIALS. ETHYLENE GLYCOL WILL REACT VIOLENTLY W/CHLOROSULFONIC ACID, OLEUM, H2SO4. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:THERMAL DECOMPOSITION IN THE PRESENCE OF AIR MAY YIELD CARBON MONOXIDE &/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT I/A/W APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INDUSTRIAL FINISHES HIGH-GLOSS ENAMEL, 819 CAGE:FO133 CAGE:97903 CAGE:FO133 ============= Composition/Information on Ingredients ============= Ingred Name:AZO YELLOW CAS:52320-66-8 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS: 417.6 G/L RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:RESP PROT: WEAR NIOSH/MSHA APPRVD AIR SUPPLY RESP/HOODS. USE NIOSH/MSHA APPRVD RESP WHEN FLAME CUTTING, WELDING, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:BRAZING & SANDING MATL COATED W/THIS PROD. FOLLOW RESP MFR'S DIRECTIONS FOR RESP USE. RTECS #:9999999ZZ Ingred Name:VENT: CURRENT APPLIC SFTY & HLTH STDS IN MIXING, APPLICATN & CURING AREAS & TO REMOVE SANDING DUSTS OF DRIED (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: COATING & DECOMP PROD DURING WELDING & FLAME CUTTING ON SURF COATED W/THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:ALKYD RESIN Fraction by Wt: 40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MINERAL SPIRITS VP: 2 @ 68F LEL: 1% CAS:64742-88-7 Fraction by Wt: 35% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 15% OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:LINSEED OIL; (RAW LINSEED OIL) CAS:8001-26-1 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: IRRITATION OF THE RESPIRATORY TRACT; MAY AFFECT THE BRAIN/NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE, NAUSEA. EYES: IRRITATION. SKIN: IRRITATION. INGEST: CAN CAUSE STOMACH &/OR INTESTINA L IRRITATION, NAUSEA, VOMITING & DIARRHEA. ASPIRATION OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS, WHICH (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CAN BE FATAL. CHRONIC: PROLONGED & REPEATED BREATHING OF SPRAY MIST &/OR SANDING DUST OVER A PERIOD OF YEARS MAY CAUSE DUST DISEASE OF THE LUNGS. Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. SKIN: REMOVE WITH SOAP AND WATER. REMOVE SOILED CLOTHING. INGESTION: DRINK 1 O R 2 GLASSES OF WATER. DO NOT INDUCE VOMITING. CONSULT PHYSICIAN IMMEDIATELY. TREAT SYMPTOMATICALLY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Lower Limits:SEE INGS Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ PREF. IF EXPOS TO FIRE/EXTREME HEAT, WATER (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT & FLAME. DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS TO EXTREME HEAT MAY EXPLODE. NEVER USE WELDING/CUTTING (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:WASH WITH WATER. BEFORE ATTEMPTING CLEANUP, REFER TO HAZARD INFORMATION IN MSDS. CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. STORE IN CLOSED CONTAINERS UNTIL PROPERLY DISPOSED OF. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 110F. KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DO NOT BREATHE VAPORS, SPRAY MIST OR SANDING DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREA W/UNRESTRICTED VENT & DURING SANDING/GRINDING OPERATIONS, USE NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST. WHEN USED IN RESTRICTED AREAS, (ING 7) Ventilation:USE ONLY W/ADEQ VENT. PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP AIR CONTAMINANT CONC BELOW (ING 9) Other Protective Equipment:NOT REQUIRED. Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health FIRE FIGHT PROC: SHOULD BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP/AUTOIGNIT. EXPLO HAZ: TORCH ON/NEAR CNTNR (EVEN EMPTY) AS PROD/ITS RESIDUE MAY IGNITE. DURING EMER CNDTNS, OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE PRESENT/IMMED APPARENT. OBTAIN MED ATTN. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:600F,316C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.047 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:52.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH MATERIALS THAT ARE UNSTABLE WITH WATER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE HAZARDOUS FUMES WHEN HEATED TO DECOMP. FUMES MAY CONTAIN CO, CO*2 AND OXIDES OF METALS LISTED IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NI-202 (PRODUCT CODE 036102-05) Preparer's Name:DELMAR BEIGHT CAGE:0FGH2 CAGE:0FGH2 Contract Num:SP0490-95-D-4037 CAGE:0VYG8 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL CAS:7440-02-0 RTECS #:QR5950000 Minumum % Wt:50. Maxumum % Wt:75. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:CHROMIUM CAS:7440-47-3 RTECS #:GB4200000 Minumum % Wt:5. Maxumum % Wt:20. OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Minumum % Wt:5. Maxumum % Wt:20. Ingred Name:COLUMBIUM/NIOBIUM CAS:7440-03-1 RTECS #:QT9900000 Minumum % Wt:5. Maxumum % Wt:20. Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Minumum % Wt:1. Maxumum % Wt:5. ACGIH TLV:10 MG/M3 Ingred Name:TITANIUM CAS:7440-32-6 RTECS #:XR1700000 Minumum % Wt:1. Maxumum % Wt:5. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE- SKIN: MAY CAUSE ALLERGIC DERMATITIS WITH PAPULAR FORMATION IN SUSCEPTABLE INDIVIDUALS, WHICH USUALLY OCCURS IN THE FOLD OF SKIN. MAY CAUSE ULCERS. EYES: MAY CAUSE IRRITATION. INGESTION: MAY CAU SE CENTRAL NERVOUS SYSTEM DEPRESSION. INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION AND CENTRAL NERVOUS SYSTEM DEPRESSION.CHRONIC- MAY CAUSE SENSITIZATION IN SUSCEPTABLE INDIVIDUALS EYES: CAN C AUSE CORNEAL DAMAGE, POLYCYTHEMIA, HYPERPLASIA OF THE THYROID GLAND, AND DAMAGE TO THE ALPHA CELLS OF THE PANCREAS. INHALATION: MAY CAUSE EMPYHSEMA OR PULMONARY FIBROTIC DISEASE. SKIN: MAY SPREAD TO T HE WHOLE BODY. Explanation of Carcinogenicity:NICKEL & CHROMIUM HAVE BEEN DETERMINED TO CAUSE CANCER IN EXPERIMENTAL ANIMALS (IARC, NTP). NICKEL IS LISTED AS A PROBABLE HUMAN CARCINGEN. CHROMIUM IS LISTED AS A HUMAN CARCINOGEN. Effects of Overexposure:SKIN-MAY CAUSE ALLERGIC DERMATITIS, WITH REDNESS & PAPULAR FORMATION IN SUSCEPTIBLE INDIVIDUALS, WHICH USUALLY OCCURS IN THE FOLDS OF THE SKIN. MAY CAUSE ULCERS PROGRESSING TO DRY & SCALY SKIN, FEVER . EYE-MAY CAUSE IRRITATION, EXPERIENCED AS REDNESS & EXCESS REDNESS OF THE CONJUNCTIVA. SWALLOWING-MAY CAUSE NAUSEA, ABDOMIAL PAIN, VOMITING, DIARRHEA, CNS DEPRESSION, & BURNING SENSATION. INHALATION- MAY CAUSE RESPIRATORY TRACT IRRITATION, WITH CHEST PAIN, VOMITING, DIARRHEA, BURNING SENSATION, & CNS DEPRESSION. Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY ALSO AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:SWALLOWING-GIVE AT LEAST 2 GLASSES OF MILK OR WATER. INDUCE VOMITING, UNLESS PATIENT IS UNCONSCIOUS. CALL A PHYSICIAN. SKIN-WASH THOROUGHLY WITH SOAP AND WATER. INHALATION-REMOVE TO FRESH AIR. GIVE AR TIFICIAL RESPIRATION IF NOT BREATHING. OXYGEN MAY BE GIVEN IF NECESSARY. CALL A PHYSICIAN. EYES-FLUSH THOROUGHLY WITH PLENTY OF WATER. IF DISCOMFORT PERSISTS, SEEK MEDICAL ATTENTION, PREFERABLY AN OPT HALMOLOGIST. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL TO EXTINGUISH METAL FIRES. USE APPROPRIATE EXTINGUISHER TO EXTINGUISH COMBUSTABLE MATERIALS THAT MAY BE IGNITED BY THERMAL FLAME. Fire Fighting Procedures:CONSULT AND COMPLY WITH ANSI Z49.1 SAFETY IN WELDING AND CUTTING, NFPA51B STANDARD FOR FIRE PREVENTION IN USE OF CUTTING AND WELDING PROCESSES. NFPA51B OXYGEN-FUEL GAS SYSTEMS FOR WELDING AND CUTTING, AND NFPA58 STANDARD FOR THE STORAGE AND HANDLING OF LIQUIFIED PETROLEUM GASES. Unusual Fire/Explosion Hazard:AIRBORNE DUST PARTICLES, ESPECIALLY METAL DUST, AND ACCUMULATION OF SUCH SHOULD BE TREATED AS EXPLOSIVES. TO MINIMIZE DANGER FROM DUST EXPLOSIONS, ADEQUATE VENTILATION SHOULD BE PROVIDED TO SPRAY BOOT H IN ACCORDANCE WITH AMERICAN WELDING SOCIETY PUBLICATION AWSC2.1-73, AND ACGIH PUBLICATION "INDUSTRIAL VENTILATION". ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST HAZARDS AND DISPOSE OF PER WASTE DISPOSAL METHOD. ======================Handling and Storage ====================== Other Precautions:CAUTION: WHEN THERMAL SPRAYING - ELECTRICITY CAN CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN BURN EYES AND SKIN! WEAR RECOMMENDED EYE AND BODY PROTECTION. FUMES, GAS, & DUST CA N HARM YOUR HEALTH. PROVIDE ENOUGH VENTILATION AND WEAR RESPIRATORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DEPENDS UPON SPECIFIC USE, CONDITION, AND LOCATION. IF THERE IS DUSTINESS, WEAR RESPIRATOR SELECTED PER OSHA 1910.134, AND OSHA 29 CFR 1910.252 AND ANSI Z49.1 Ventilation:LOCAL DUST PICK UP AND VENTILATION RECOMMENDED. Other Protective Equipment:SEE ANSI Z49.1, ANSI Z87.1, ANSI Z88.2 FOR Supplemental Safety and Health CAUTION: WHEN THERMAL SPRAYING-ELECTRICITY CAN CAUSE FATAL SHOCK! DO NOT TOUCH LIVE ELECTRICAL PARTS! ARC RAYS CAN BURN EYES AND SKIN! WEAR RECOMMENDED EYE ANDBODY PROTECTION. FUMES, GAS, AND DUST CAN HARM YOUR HEALTH. PROVIDE ENOUGH VENTILATION AND WEAR RESPIRATORS.(OTHER INFO) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NONE Vapor Density:N/VOLATILE Appearance and Odor:DUSTY YELLOW GRAY POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:WHEN THERMAL SPRAYING, DECOMPOSITION PRODUCTS WILL VARY WITH OPERATING CONDITIONS. DECOMPOSITION PRODUCTS OF NORMAL OPERATION FROM THIS THERMAL SPRAY POWDER- OXIDES, SUB-OXIDES, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE PER LOCAL, STATE, AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PROPER SHIPPING NAME: METAL ALLOY POWDER NOI ITEM 136500 SUB 1. ===================== Regulatory Information ===================== SARA Title III Information:7440-02-0, NICKEL, <75 PERCENT BY WEIGHT . 7440-47-3, CHROMIUM, <20 PERCENT BY WEIGHT. State Regulatory Information:PROP 65 (CARCINOGEN): WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. CAS #7440-02-0, NICKEL & CAS #7440-47-3, CHROMIUM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SSS TENDER SCRUB CAGE:TRIPL CAGE:TRIPL ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: MODERATE IRRITATION. EYES: MODERATE TO SEVERE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: NAUSEA, VOMITING, DIARRHEA. SKIN: DEFATTING ACTION, DERMATITIS. EYES: TISSUE DAMAGE. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. INGESTION: GIVE LARGE QUANTITIES OF WATER THEN SEVERAL GLASSES OF MILK. INDUCE VOMITING. SKIN: WASH W/PLENTY OF WATER & SOAP. EYES: FLUSH IMMEDIATELY W/LARGE QUANTITIESOF WATER FOR 15 MINUTES. OBTAIN MEDICALATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:AS REQUIRED BY SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED FULL-FACE BREATHING APPARATUS ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN LARGE SPILLS & PUMP TO RECOVER. SMALL SPILLS CAN BE MOPPED UP. FLUSH CONTAMINATED AREA W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ONLY W/O ADEQUATE VENTILATION Ventilation:EQUIVALENT TO OUTDOORS Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Solubility in Water:APPRECIABLE Appearance and Odor:BLUE CREAM W/SASSAFRAS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS/OXIDIZERS Stability Condition to Avoid:EXTREME TEMPERATURES Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/ALL FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SET-UP (A/16), 5941-012 Preparer's Name:MARCIA CAGE:3Y342 CAGE:3Y648 CAGE:3Y342 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL, WHITE; (PETROLATUM) CAS:8042-47-5 RTECS #:PY8047000 OSHA PEL:5 MM/M3 (MFR) ACGIH TLV:5 MM/M3 (MFR) Ingred Name:HEXANE;(N-HEXANE) (CERCLA) CAS:110-54-3 RTECS #:MN9275000 OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 ACGIH TLV:800 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES:SEVERE IRRITATION. SKIN:SEVERE IRRITATION. INGESTION:IRRITATION TO INTESTINES. INHALATION:DIZZINESS, HEADACHE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN SENSITIVITY, CHEMICAL ALLERGIES. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH LARGE AMTS OF WATER FOR @ LEAST 15 MINUTES. SKIN:WASH WITH SOAP & WATER. INGEST:DO NOT INDUCE VOMITING. GET DOCTOR. INHAL:FRESH AIR. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, STANDARD FOAM, DRY CHEMICAL, HALON. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EXPOS TO TEMP OVER 120F MAY CAUSE BURSTING/VENTING. HEAT MAY CAUSE HAZARDOUS FUMES:CARBON MONOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILLS:MOP UP, SOAK UP IMMEDIATELY. REMOVE TO OUT OF DOORS. LARGE SPILL:CONTAIN LIQUID, TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF WATER SUPPLY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST:USUALLY SUFFICIENT. MECHANICAL:NOT USUALLY NECESSARY. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:STANDARD INDUSTRIAL PRACTICES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Vapor Pres:40 PSIG Vapor Density:>1 Spec Gravity:0.743 Evaporation Rate & Reference:<1 Solubility in Water:INSOLUBLE Appearance and Odor:VERY LIGHT AMBER COLOR - SWEET ETHERAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS, POSSIBLE SODIUM, POTASSIUM, AND MAGNESIUM. Stability Condition to Avoid:SOURCES OF HEAT. Hazardous Decomposition Products:OPEN FLAMES CAN CAUSE THERMAL DEGRADATION. Conditions to Avoid Polymerization:SOURCES OF HEAT. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FM11C P1-60 Preparer's Name:UNREADABLE CAGE:55787 CAGE:45152 CAGE:55787 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL CAS:8012-95-1 RTECS #:PY8030000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 (MIST); 9596 Ingred Name:NITROGEN (COMPRESSED) CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 Ingred Name:NON-HAZARDOUS INGREDIENTS Fraction by Wt: 99% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MINOR IRRITATION TO SKIN & EYES. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:MINOR IRRITATION TO SKIN & EYES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WATER FOR 10 MINUTES. SKIN-REMOVE OIL-SOAKED CLOTHES. WASH WITH SOAP & WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:302F,150C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:DO NOT USE WATER. Unusual Fire/Explosion Hazard:PRESSURIZED CYLINDER. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID MATERIAL SPREADING BY BLOCKING THE OIL. USE OIL BINDING MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXTREME HEAT. DO NOT INCINERATE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:LOCAL EXHAUST. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NOTE FOR DLA-HMIS STAFF: THIS MSDS APPARENTLY WRITTEN PRIMARILY FOR THE OIL CONTAINED IN THE CYLINDER (<1%) (SEE FLASH POINT). MSDS FOR THE NITROGEN (<1%) IN THE CYLINDER IS WRITTEN AS PNI B THIS NSN/ CAGE; AS MFR PROVIDED A SECOND MSDS FORNITROGEN. HCC BASED ON FACT THAT SYSTEM(!) IS A COMPRESSED GAS AT 60 PSI. ================== Physical/Chemical Properties ================== HCC:G3 Spec Gravity:870 KG/M3 Solubility in Water:INSOLUBLE Appearance and Odor:TYPICAL OF MINERAL OIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:FA4004/2 CAGE:81831 CAGE:81831 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:RESP TK IRRIT; SKIN/EYE;IRRIT,INFLAM,CHLORACNE; MAY CAUSE LIVER DAMAGE. ======================= First Aid Measures ======================= First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG,GIVE CPR IF BRTHNG DIFF,GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN:WASH W/SOAP&WATER. RMV CONTAM CLTHNG&SHOES. INGEST:INDUCE VOMIT. RPT UNTIL VOMIT IS C LEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:MATL IS NON-FLAMMABLE BUT MAY GENERATE TOXIC GASES IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC NON-ESSENTL PERSONNEL. VENT SPIL AREA. WEAR PROTECT EQUIPT. STOP LEAK. SOAK UP LIQUID W/NON-REACTIVE MATL (SAND, DIRT, ETC) OR RMV BY DIKE & PUMPING OR OTHER SUITABLE MEANS. CLEAN AREA W/SUITABLE SAFETY SOLVENT. LAUNDER CONTAMINATED CLTHNG. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP CONTAINERS TIGHTLY CLOSED Other Precautions:CHLORODIPHENYLS MAY ATTACK SOME TYPES OF RUBBER AND PLASTIC. DO NOT USE CONTAMINATED WORK CLOTHING. WASH/SHOWER AFTER EXPOSURE TO PCB'S. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MESA APPR SCBA/AIR SUPP RESPIR. Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:WEAR FULL PROTECTIVE CLOTHING. Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATON OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE,THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Solubility in Water:NEGLIGIBLE Appearance and Odor:PALE YELLOW VISCOUS LIQUID W/HYDROCARBON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:SEE OTHER PRECAUTIONS Hazardous Decomposition Products:HYDROGEN CHLORIDE, CO, & OTHER TOXIC/IRRITATING GASES/FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQD. GEN. V.HIGH TEMP INCINERATION. IAW ALL LOCAL, STATE, & FEDERAL REGULATIONS. PERMITTED DISPOSAL OPERATOR REQUIRED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAMP PAD INKS, BLACK (PINT) CAGE:EO365 CAGE:86874 CAGE:EO365 ============= Composition/Information on Ingredients ============= Ingred Name:DYE Ingred Name:WATER, H2O CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:GLYCERIN CAS:56-81-5 RTECS #:MA8050000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 (MIST) 9293 Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Ingred Name:GLYCERIN CAS:56-81-5 RTECS #:MA8050000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 (MIST) 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS NOT CONSIDERED TOXIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:PRODUCT IS CONSIDERED SAFE WHEN USED UNDER NORMAL USE CONDITIONS. ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>390F ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP W/ABSORBENT MATERIAL & DISCARD AS SOLID WASTE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CAP ON BOTTLE WHEN NOT IN USE. THE PRODUCT IS CONSIDERED SAFE WHEN USED UNDER NORMAL USE CONDITIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE UNDER NORMAL USE CONDITIONS. Ventilation:NONE UNDER NORMAL USE CONDITIONS. Other Protective Equipment:NONE UNDER NORMAL USE CONDITIONS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>550F Vapor Pres:<0.1 Spec Gravity:1.2 - 1.3 Solubility in Water:COMPLETE Appearance and Odor:WATER WHITE, CLEAR LIQUID W/BLAND ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCARD AS SOLID WASTE IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
======================================================= Product ID: FRESH KOTE INTERIOR LATEX SEMI-GLOSS, 410194 Cage: 85519 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 85519 Box: 600 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS, AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN CONTACT: IRRITATION OF SKIN. PROLO NGED OR REPEATED CONTACT CAN CAUSE DERMATITIS. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:CONTACT CAN CREATE BLURRED VISION, CORNEAL INJURY. INGESTION: AMOUNTS INGESTED INCIDENTAL TO CONSUMER AND INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGE AMOUN TS COULD CAUSE SERIOUS INJURY. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET EMER MED ATTN. SKIN: WASH OFF QUICKLY W/PLENTY OF H*2O, THEN SOAP & H*2O; REMOVE CONTAMD CLTH G. WASH CONTAMD CLTHG BEFORE REUSE. EYE: FLUSH IMMED W/LRG AMTS OF H*2O, ESP UNDER LIDS, FOR AT LEAST 15 MIN. OPTAIN EMERGENCY MEDICAL TREATMENT. INGEST: OBTAIN MEDICAL TREATMENT IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COLLECT IN CONTAINER FOR DISPOSAL, ACCORDING TO HEALTH AND ENVIRONMENTAL REGULATIONS. CLEAN UP WITH WATER BEFORE ALLOWING TO DRY. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: STORE BELOW 100 DEGREE F. KEEP FROM FREEZING. Other Precautions: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NON FLAMMABLE Lower Limits: SEE INGRED Extinguishing Media: DRY CHEMICAL OR FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). NON-FLAMMABLE. WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL EVIRONMMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: MAINTAIN ADEQUATE VENTILATION TO ENSURE AIR ENTRY DURING APPLICATIONS AND DRYING TO PREVENT BUILD-UP OF VAPORS. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). SKIN CREAM (IF NEEDED). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >212F,>100C Vapor Pres: SEE INGRED Vapor Density: SEE INGRED Spec Gravity: 1.08-1.21(FP N) Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 53-67 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT WITH OXIDIZING AGENTS. Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES. Hazardous Decomposition Products: IF INVOLVED IN FIRE (FROM OTHER SOURCES) COULD CONCEIVABLY RESULT IN RELEASE OF CARBON DIOXIDE AND CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: FRESH KOTE INTERIOR LATEX SEMI-GLOSS, 410194 Cage: 85519 Company Name: M A BRUDER & SONS INC Street: 600 REED RD PO Box: 600 Zipcode: 19008 Label Required IND: Y Date Of Label Review: 01/22/1997 Status Code: C Label Date: 01/22/1997 Origination Code: G Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION: IRRITATION OF RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS, AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN CONTACT: IRRITATION OF SKIN . PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT CAN CREATE BLURRED VISION, CORNEAL INJURY. INGESTION: AMOUNTS INGESTED INCIDENTAL T O CONSUMER AND INDUSTRIAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGE AMOUNTS COULD CAUSE SERIOUS INJURY. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VAP CO DEGREASER SOLVENT CAGE:HO297 CAGE:63405 CAGE:HO297 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 25% OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:NAPHTA (PETROLEUM SPIRITS OR BENZIN) CAS:8030-30-6 RTECS #:DE3030000 OSHA PEL:100 PPM ===================== Hazards Identification ===================== Effects of Overexposure:DRY SKIN,EYE IRRIT.CARBOXYHEMOGLOBIN LEVEL POSS ELEVATED.IF TO MUCH BREATHED,POSS DEATH. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/PLENTY OF H*2O FOR @ LEAST 15 MIN.SKIN:WASH OF W/FLOWING H*2O.WASH CLTHG BEFORE REUSE.INHAL:RMV TO FRESH AIR, IF BRTHG STOPS GIVE ARTF RESP.CALL PHYSICIAN.INGEST:DO NOT INDUCE VOMIT ING,CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:104F, TCC Lower Limits:1 Upper Limits:22 Extinguishing Media:FOAM, CO*2,DRY CHEMICAL, H*2O FOG. Fire Fighting Procedures:PRESS DEMAND SCBA.FORMS FLAM VAP-AIR MIX @ TEMP > AMBIENT. Unusual Fire/Explosion Hazard:H*2O MAY BE UNSUITABLE EXCEPT AS A COOLING MEDIUM. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS:MOP UP,WIPE UP/SOAK UP IMMED.RMV TO OUT OF DOORS. LGE SPILL:EVACUATE AREA,CONTAIN LIQ,TRANSFER TO CLSD METAL CNTNRS.KEEP AWAY FROM HEAT,SPARKS & FLAME. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP COOL & AWAY FROM SOURCES OF IGNITION.USE W/ADEQUATE VENT.AVOID PRLNG/RPTD CONT.DO NOT PRESSURE PROD OUT OF VESSEL/TRANSPORT CNTNR W/AIR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP PROT REQ,SCBA IN EMERGENCIES. Ventilation:SUFFICIENT VENT TO KEEP WORKROOM CONC BELOW TLV. Other Protective Equipment:APRON & BARRIER CREAM.EYE BATH. Supplemental Safety and Health VAP PRESS: 86.5 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:104F Vapor Density:4.26 Spec Gravity:0.90 Evaporation Rate & Reference:0.2 (BUTYL AC) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR,COLORLESS & CHARACTERISTIC LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRG OXIDIZING AGENTS,SLUMINUM,SODIUM,POTASSIUM,MAGNESIUM. Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAME,FIRE,WELDING ARCS. Hazardous Decomposition Products:CO,CO*2,HCL,POSS SMALL AMTS OF PHOSGENE & CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP OUT OF H*2O SUPPLY.SEND SOLVENT TO RECLAIMER.DISPOSE IAW FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== CAGE:GEMST CAGE:GEMST ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID, TRISODIUM SALT, DODECAHYDRATE CAS:10101-89-0 RTECS #:TC9575000 Fraction by Wt: 2% OSHA PEL:1 MG/CUM ACGIH TLV:1 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM SULFATE ANHYDROUS, SODIUM SULFATE CAS:7757-82-6 RTECS #:WE1650000 Fraction by Wt: 2% Ingred Name:GLYCERINE, 1,2,3,-TRIHYDROXYPROPANE, GLYCEROL, ANHYDROUS GLYCERINE, GLYCERIN CAS:56-81-5 RTECS #:MA8050000 Fraction by Wt: 0.3% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 (MIST) 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS INCLUDING UNDER EYELIDS. INGESTION: GIVE WATER & INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:250F Extinguishing Media:DRY CHEMICAL, WATER, OR CO2 ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP & COLLECT IN ORDINARY CONTAINER & DISPOSE. RINSE AREA W/WATER. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:240F Vapor Pres:14 Vapor Density:2 Spec Gravity:1.054 Solubility in Water:COMPLETE Appearance and Odor:YELLOW, PLEASANTLY PERFUMED GEL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE FLUSHED INTO SEWER W/PLENTY OF WATER IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3037 NAMALAC-ROYAL BLUE Preparer's Name:JULIE HOAGLAND CAGE:88633 CAGE:88633 ============= Composition/Information on Ingredients ============= Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 45% Other REC Limits:525 MG/CUM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 5% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 10% ACGIH TLV:10 MG/CUM (DUST) Ingred Name:VOL ORGANIC CMPD: 3.82 LB/GL (458 G/L) RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ANESTHETIC, RESPIRATORY IRRITATION/NERVOUS SYSTEM DEPRESSION. SKIN: MODERATE IRRITATION/DERMATITIS/SENSITIZER/ABSORPTION. EYES: SEVERE IRRITATION/SENSITIZER. INGESTION: GI IRRITATION. ASPI RATION INTO THE LUNGS DURING INGESTION/VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY/DEATH. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA, ASPHYXIATION, DEFATTING, REDNESS, TEARING, BLURRED VISION, NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATITIS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF DIFFICULT BREATHING. RESTORE BREATHING IF NECESSARY. TREAT SYMPTOMATICALLY. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/PLENTY O F WATER FOR 15 MINS. INGESTION: DRINK 1-2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:100F-109F Lower Limits:0.9 Upper Limits:7 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERRABLE. WATER MAY BE USED TO COOL CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA. CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. KEEP CLOSURES TIGHT & UPRIGHT. DON'T STORE/USE NEAR HEAT, SPARKS, FLAME. NEVER USE PRESSURE TO EMPTY.DRUMS SHOULD BE GROUNDED. Other Precautions:DON'T WASH/USE DRUMS FOR OTHER PURPOSES. AVOID SKIN/EYE CONTACT. PREVENT BREATHING OF VAPORS/SPRAY MISTS/SANDING DUST. CLOSE CONTAINER AFTER EACH USE. DON'T TRANSFER TO UNLABELED CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR/OPEN AREAS: NIOSH/MSHA APPROVED MECHANICAL FILTER RESPIRATOR. IN RESTRICTED AREAS, USE NIOSH/MSHA APPROVED CHEMICAL-MECHANICAL FILTERS. IN CONFINED AREAS, USE NIOSH/MSHA APPROVED AIR LINE T YPE RESPIRATORS/HOODS. Ventilation:REQUIRED. IF BAKING, VENT FUMES Other Protective Equipment:SAFETY EYEWEAR W/SIDE SHIELDS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH SKIN THOROUGHLY W/SOAP & WATER AFTER HANDLING. Supplemental Safety and Health UNUSUAL FIRE HAZ: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. HEALTH HAZARDS CONT'D: PROLONGED OVEREXPOSURE TO SOLVENTS MAY RESULT IN BRAIN & NERVOUS SYSTEM DAMAGE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F Vapor Density:>1 Spec Gravity:1.0 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:TYPICAL PAINT W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS Stability Condition to Avoid:HIGH TEMPERATURES, TEMPS >120F, HEAT, SPARKS, OPEN FLAME Hazardous Decomposition Products:FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REGULAR WALLBOARD Preparer's Name:NORBERT W KALETA CAGE:85074 CAGE:9N701 CAGE:85074 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM (II) SULFATE, DIHYDRATE (1:1:2); (GYPSUM) CAS:10101-41-4 RTECS #:EW4150000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:CELLULOSE (PAPER FIBER) CAS:9004-34-6 RTECS #:FJ5691460 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: GOLD BOND BOARD PRODS DO NOT PRESENT INHAL, INGEST/CONT HLTH HAZ UNLESS SUBJECTED TO OPERATIONS SUCH AS SAWING, SANDING/MACHINING WHICH RSLT IN GENERATION OF AIRBORNE PARTICULATE. SKIN: CONTINU ED & PRLNG CONT MAY RSLT IN DRY SKIN. EYE: DIRECT CONT MAY CAUSE MECH IRRIT. INHAL: TARGET ORGAN: RESP SYS. Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 341, 1987: GROUP 2A. NTP 7TH ANNUAL REPORT (SUP DAT) Effects of Overexposure:CONTINUED AND PROLONGED EXPOSURE TO AIRBORNE DUST CONCENTRATIONS IN EXCESS OF THE PEL/TLV MAY RESULT IN COUGH, DYSPNEA, WHEEZING, AND IMPAIRED PULMONARY FUNCTION. Medical Cond Aggravated by Exposure:OVEREXPOSURE WOULD GENERALLY AGGRAVATE RESPIRATORY SYSTEM DYSFUNCTIONS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. SKIN: FLUSH AND WASH SKIN WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE. IFNOT BREATHING INITIATE PULMONARY RESUSCITATION. GET MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:DRY CHEMICAL, FOAM, WATER FOG OR SPRAY. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:PICKUP TO AVOID TRIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY TO PRESERVE USEFULNESS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED RESPIRATOR FOR TOXIC DUSTS IS RECOMMENDED IF THE PEL/TLV IS EXCEEDED. Ventilation:PROVIDE VENTILATION TO MAINTAIN A DUST LEVEL BELOW THE PEL/TLV. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:THE SCORE AND SNAP METHOD OF CUTTING IS RECOMMENDED. SAWING, DRILLING OR MACHINING WILL PRODUCE DUST. Supplemental Safety and Health EXPLAN OF CARCIN: ON CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. ANIMAL: LUNG. ================== Physical/Chemical Properties ================== Appearance and Odor:GYPSUM CORE WRAPPED W/PAPER. SURFACE FINISH WILL VARY W/PROD. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, OXIDES OF SULFUR AND CARBON WILL BE RELEASED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:514-10-72-115 MOLECULAR SIEVE CAGE:LO389 CAGE:LO389 CAGE:16210 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM ALUMINOSILICATE CAS:1344-00-9 Other REC Limits:NONE RECOMMENDED Ingred Name:CALCIUM SODIUM ALUMINOSILICATE CAS:1344-01-0 Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM SODIUM ALUMINOSILICATE CAS:12736-96-8 Other REC Limits:NONE RECOMMENDED Ingred Name:KAOLIN (CLAY) CAS:1332-58-7 RTECS #:GF1670500 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 31600 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY IRRITATE MUCOUS MEMBRANES OF UPPER RESPIRATORY SYSTEM. CONTACT MAY IRRITATE SKIN AND EYES. CHRONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE CANCER, SILICOSIS OR OTHER FIBROTIC L UNG DISEASES. Explanation of Carcinogenicity:QUARTZ IS LISTED AS A CARCINOGEN (2A) BY IARC. Effects of Overexposure:INHALED: COUGHING, SNEEZING, SORE THROAT. EYES: REDNESS, DISCOMFORT. SKIN: REDNESS, DISCOMFORT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALED: MOVE TO FRESH AIR. SEE DOCTOR IF SYMPTOMS PERSIST. EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES, HOLD LIDS OPEN. SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER. INGESTED: NONE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP UP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY SEALED. Other Precautions:AVOID GENERATION OF DUSTY CONDITIONS AT WORK PLACE. USE PROPER BONDING AND GROUNDING WHEN TRANSFERRING (STATIC ELECTRICITY), ESPECIALLY WITH FLAMMABLE/COMBUSTIBLE LIQUIDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE A NIOSH-APPROVED RESPIRATOR IF DUSTY CONDITIONS DEVELOP. USE IAW 29 CFR 1910.134. Ventilation:USE WITH ADEQUATE VENTILATION. Other Protective Equipment:LONG SLEEVE SHIRT Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health PH IN 5% SLURRY IS 10.5. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:2.1 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE OR GRAY OR TAN BEADS; ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH HYDROGEN FLUORIDE & STRONG ACIDS OR ALKALI Stability Condition to Avoid:CONTACT WITH HYDROFLUORIDE, STRONG MINERAL ACIDS OR ALKALI ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL IN ACCORDANCE WITH LOCAL,STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMERCOAT, 33AL PSTE CAGE:0Y2E4 CAGE:55849 CAGE:0Y2E4 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <75% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:VM & P NAPHTHA. VP: 5.2 @ 68F. LD50: 5 G/KG. CAS:64742-48-9 Fraction by Wt: 26% Other REC Limits:500 PPM (MFR) OSHA PEL:300 PPM; 400 STEL ACGIH TLV:300 PPM Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: SEE ING OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAPOR/SPRAY MIST &/OR DUST CAN BE HARMFUL. IRRIT TO SKIN/MUC MEMB/EYES & RESP SYSTEM. EXCESSIVE INHAL CAN CAUSE HDACH/NAUS/DIZZ OR ASPHYXIATION. RPTD/PRLNG OCCUP OVEREXP TO SOLVENTS IS ASSOC W/PERM BR AIN/NERVOUS SYSYTEM DAMAGE. CAN BE HARMFUL/FATAL IF SWALLOWED. OVEREXP CAN DAMAGE KIDNEYS & LIVER, LUNGS, CNS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY. SKIN. ======================= First Aid Measures ======================= First Aid:INHAL: PROVIDE FRESH AIR; IF BREATHING LABORED, GIVE OXYGEN OR ARTIFICIAL RESPIRATION. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/PLENTY OF WATER FOR A MINIMUM OF 15 MINUTES & GET MED ATTN. INGEST: DRINK 1 OR 2 GLASSESOF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:114F,46C Lower Limits:0.9% Upper Limits:6% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CLOSED CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. AVOID WATER. GENERATE HYDROGEN. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID BRTHG OF VAPORS/DUST. USE ABSORBENT CLEANUP MATERIALS OR SWEEP UP. PLACE IN SEPARATE CONTAINER. KEEP OUT OF PUBLIC SEWERS & WATERWAYS. IF ENTRY IS THREATENED OR OCCURS, NOTIFY LOCAL AUTHORITIES. ELIMINATE ALL SOURCES OF IGNITION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID STORAGE TEMPERATURES ABOVE 100F. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PRLNG BRTHG OF DUST/VAPS OR SPRAY MIST OR CONT W/SKIN & EYES. DO NOT WELD/FLAME CUT AN EMPTY CONTR. GROUND CONTRS WHEN POURING. AVOID WATER CONTAM. MOISTURE GENERATES HYD ROGEN. CONTAINS TOXIC CHEMICALS (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR. USE NIOSH/MSHA APPROVED AIR-LINE RESPIRATORS IN CONFINED OR RESTRICTED VENTILATION AREAS, OR W/POLYURETHANE OR ISOCYANATES. REFER TO 29CFR, OSHA PARTS 1910, 1915, & 191 6 FOR COATING OPERATIONS. Ventilation:SUFFICIENT VENTILATION, IN VOLUME & PATTERN, SHLD BE PROVIDED TO KEEP AIR CONTAMINANT CONCS BELOW TLV LIMIT. (SUPDAT) Other Protective Equipment:FULL PROTECTIVE CLOTHING. SPARK-PROOF EQUIPMENT. Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING WASHROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health OTHER PREC: SUBJECT TO REPORTING REQUIREMENTS OF SARA AND CERCLA (40CFR 302, 355, 372). VENT: REMOVE WELDING OR FLAME CUTTING DECOMPOSITION PRODUCTS. REFER TO 29 CFR, OSHA PARTS 1910, 1915, AND 1916 F OR COATING OPERATIONS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:250F,121C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Evaporation Rate & Reference:1 (BUTYL ACETATE = 1) Appearance and Odor:LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:53 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. WATER OR MOISTURE. Hazardous Decomposition Products:BY FIRE, BURNING OR WELDING: CO AND CO*2. ALUMINUM OXIDE FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN SEPARATE, CLOSED METAL CONTAINER IN ACCORDANCE W/ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS. EPA WASTE NO. D001 D003.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:910X624 MIL-P-23377F ACTIVATOR Kit Part:Y Resp. Party Other MSDS Num.:MS8449A01 CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:15. OSHA PEL:SEE TABLE Z-2 ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOPROPYL ALCOHOL CAS:67-63-0 RTECS #:NT8050000 = Wt:55. OSHA PEL:980 MG/M3;400 PPM ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 = Wt:15. ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:POLYAMIDE RESIN POLYMERS WITH TALL-OIL FATTY ACIDS AND TRIETHYLENETETRAMINEFATTY ACIDS, C18-UNSATD., DIMERS, POLYMERS WITH TALL-OIL FATTY ACIDS AND TRIETHYLENETETRAMINE CAS:68082-29-1 = Wt:15. Ingred Name:TRIETHYLENETETRAMINE CAS:112-24-3 RTECS #:YE6650000 < Wt:5. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:EYES: MAY CAUSE BURNING, TEARING AND REDDENING. SKIN: PROLONGED EXPOSURE MAY CAUSE DRYING AND CRACKING OF SKIN AND POSSIBLE DERMATITIS. INHALATION MAY CAUSE DIZZINESS, DROWSINESS, NOSE & THROAT IRRITA TION AND FATIGUE. MAY CAUSE NARCOSIS, ANESTHESIA, COMA. MAY CAUSE LIVER AND KIDNEY DAMAGE. INGESTION: MAY CAUSE DROWSINESS, DIZZINESS AND FATIGUE. MAY CAUSE NARCOSIS, ANESTHESIA, COMA. MAY CAUSE CNS D EPRESSION. Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:EYES: BURNING, TEARING, REDDENING, IRRITANT; DISCOMFORT WHICH IS TRANSIENT. SKIN: IRRITANT, DRYING CRACKING OF SKIN POSSIBLE DERMATITIS, SKIN SENSITIZATION. INHALATION: NOSE AND THROAT IRRITATION, FLU SHING, HEADACHE, DIZZINESS, MENTAL DEPRESSION, NAUSEA, VOMITING, NARCOSIS ANESTHESIA AND COMA, FATIGUE, LIVER AND KIDNEY DAMAGE. INGESTION: HEADACHE, DIZZINESS, MENTAL DEPRESSION, NAUSEA, VOMITING, NA RCOSIS, ANERTHESIA AND COMA, IRRITATION OF DIGESTIVE TRACT, LOSS OF COORDINATION, LIVER AND KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:LIVER AND KIDNEY DAMAGE ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR 15 MINUTES. IF SYMPTOMS PERSIST, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. DO NOT USE SOLVENTS. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. IF SYMPTOMS PER SIST, GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR FROM EXPOSURE. GIVE ARTIFICIAL RESPIRATION OR CARDIOPULMONARY RESUSCITATION (CPR) IF BREATHING IS DIFFICULT, GET MEDICAL ATTENTION. INGESTI ON: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=7.2C, 45.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL FIRE EXPOSED CONTAINERS WITH WATER. FOG NOZZLES ARE PREFERRABLE. WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CON TACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN INADEQUATELY VENTILATED OR CONFINED AREAS. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS MAY TRAVEL LONG DISTANCES. FLASHBACK OR FLAME TO THE HANDLING SITE MAY OCCUR. CL OSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:PROTECT FROM IGNITION. WEAR AIR-SUPPLIED RESPIRATOR FOR UNVENTILATED SPILL. COVER WITH ABSORBENT MATERIAL AND SCOOP INTO CONTAINER. CLEAN RESIDUE WITH A SUITABLE SOLVENT. Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FRM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. DO NOT STORE ABOVE 120 F. Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD ON OR NEAR DRUM. VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR AND MAY COLLECT IN LOW CONFINED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN SPRAYING OR APPLYING IN ANY CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVEL OF HAZARDOUS INGREDIENTS IN EXCESS OF TLV, USE AN ORGANIC VAPOR CARTRIDGE OR SUPPLIED-AIR RESPIRATOR. Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW TLV AND PEL. Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER PROTECTIVE CLOTHING. SAFETY SHOWER, EYE BATH AND WASHING FACILITIES SHOULD BE AVAILABLE. Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY. Supplemental Safety and Health NO DATA PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:180-531 F Vapor Density:>AIR Spec Gravity:0.843 Evaporation Rate & Reference:UNAVAILABLE Appearance and Odor:AMBER LIQUID, SOLVENT ODOR Percent Volatiles by Volume:85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE RECOGNIZED UNLESS NOTED BELOW. Stability Condition to Avoid:NONE RECOGNIZED UNLESS NOTED BELOW. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN DISPOSING OF THIS MATERIAL, ENSURE THAT IT IS PACKAGED, STORED, TRANSPORTED AND OTHERWISE MANAGED IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT HAZARD CLASS: FLAMMABLE LIQUID. PROPER SHIPPING NAME: PAINT. HAZARD CLASS: 3. PACKING GROUP II. UN NUMBER: UN1263. ===================== Regulatory Information ===================== SARA Title III Information:TOLUENE AND XYLENE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. Federal Regulatory Information:ALL INGREDIENTS IN THIS PRODUCT ARE LISTED IN THE TSCA INVENTORY. State Regulatory Information:CALIFORNIA: TOLUENE IS ON THE LIST ENTITLE "CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE REPRDUCTIVE TOXICITY". ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPRAY ADHESIVE 22 (791119) CAGE:DO663 CAGE:55772 CAGE:DO663 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 50% OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 3% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROCARBON PROPELLANT (LPG, LIQUIFIED PETROLEUM GAS). CAS:68476-85-7 Fraction by Wt: 35% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CHLOROCARBON/CHLOROFLUOROCARBON (CFC) MATLS HAVE PRDCE SENSIT OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (I.E., EPINEPHRINE) MAY BE CONTR A-INDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS OR CFCS . Explanation of Carcinogenicity:METHYLENE CHLORIDE: CLASS 2B (IARC), CLASS 2, (NTP). Effects of Overexposure:EYE: CONTACT IRRITATION, NO DAMAGE IF FLUSHED. SKIN: CONTACT MAY CAUSE REDNESS OR IRRITATION. MFR IDENTIFIES SKIN AS A PRIMARY ROUTE OF ENTRY . EXCESSIVE INHALATION MAY CAUSE DIZZINESS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH IMMED W/LG AMTS OF WATER FOR AT LEAST 15 MIN. SEE MD. SKIN: WASH THOROUGHLY, REMOVE CONTAMINATED CLTHG, SEE MD. INGEST: GET MD IMMED. INHAL: REMOVE TO FRESH AIR, SUPPORT BREATHING (O*2/ARTI FICIAL RESP) . ===================== Fire Fighting Measures ===================== Lower Limits:1.9-2.1 Upper Limits:8.5-9.5 Extinguishing Media:DRY CHEMICAL, CO2 Fire Fighting Procedures:KEEP CONTAINERS COOL. PROTECT PERSONNEL AGAINST BURSTING, RUPTURING, OR VENTING CONTAINERS. USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES (OVER 54C=130F) CONTAINERS MAY VENT, RUPTURE, OR BURST. THERMAL DECOMP PRODUCTS MAY INCLUDE HCL, PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. AVOID BREATHING VAPORS OR SKIN CONTACT. SOAK UP WITH ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE WHERE TEMPERATURES COULD EXCEED 54C (130F). Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE FORMATION OF HCL, PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL: IF SPRAYING LARGE AMOUNTS. Other Protective Equipment:NONE Work Hygienic Practices:AVOID SKIN CONTACT. WASH THOROUGHLY AND FREQUENTLY DURING USE, AND AT END OF WORK SHIFT . Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:V3 Vapor Pres:120 @ 130F Vapor Density:AIR=1:> Spec Gravity:0.88 Evaporation Rate & Reference:N-BUTYL ACETATE=1:SLOWER Solubility in Water:NEGLIGIBLE Appearance and Odor:FINE MISTY SPRAY: CHLORINATED SOLVENT ODOR. DRIES TO A TACKY FILM. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE, PHOSGENE, HCL. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE CONTAINERS. GIVE EMPTY, LEADING OR FULL CONTAINERS TO A DISPOSAL SERVICE EQUIPPED TO SAFELY HANDLE AND DISPOSE OF PRESSURIZED CONTAINERS. DISPOSE I/A/W FEDERAL, STATE, AN D LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:D22C0028 CLEAR OIL FINISH CAGE:CHCAT CAGE:CHCAT ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM SOLVENT). VP:10 @ 77F. CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 65% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:VOLATILE ORGANIC COMPOUNDS:COATING:4.61 LB/GL (552 G/L). MATERIAL:4.61 LB/GL (552 G/L) RTECS #:9999999VO Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE & CHRONIC:HIGH VAP CONC ARE IRRITATING TO EYES & RESP TRACT. MAY CAUSE HEADACHES & DIZZINESS, ARE ANESTHETIC, & MAY HAVE OTHER CENTRAL NERVOUS SYSTEM EFFECTS. INHAL:DIZZ, BRTHG DFCLTY, HDCH & NA US. SKIN:DRY SKIN, CRACKS, IRRIT & DERM. EYES:IRRIT, TEARING REDNESS & BLURRED VISION. INGEST:MAY (EFFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CAUSE GI IRRIT, VOMIT, NAUSE, & DIARR. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE PERSON TO FRESH AIR. IF BRTHG SLOWS START ARTF RESP & GET MED INFO. EYE:FLUSH FOR 15 MINUTES W/WATER. SKIN:WASH THOROUGHLY W/SOAP & WARM WATER. INGEST:DO NOT INDUCE VOMITING & CONT PHYS IMM EDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:100F,38C Lower Limits:0.9% Upper Limits:7.0% Extinguishing Media:FOAM, CO*2, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER SHOULD BE USED ONLY AS FOG TO KEEP NEARBY CNTNR COOL. Unusual Fire/Explosion Hazard:VAP FROM EMPTY CNTNRS & MFG OPERATIONS MAY FORM EXPLO MIX IN AIR WHICH CAN BE IGNITED BY MANY SOURCES SUCH AS PILOT LIGHTS, ELECTRIC MOTORS, SWITCHES & OTHERS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNIT SOURCES, PVNT RUNOFF INTO BODIES OF WATER (SEWERS, LAKES). REMOVE W/INERT ABSORBENT & NOTIFY PROPER AUTHORITIES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE NON-SPARKING TOOLS WHEN HNDLG THIS MATL. AVOID CONT W/HOT SURF/EXTREME HEAT. USE & KEEP IN COOL, WELL VENTILATED AREA. Other Precautions:KEEP CNTNRS CLSD WHEN NOT USING. SMOKING IN AREAS WHERE MATL IS USED SHOULD BE STRICTLY PROHIBITED. PLASTIC UTENSILS SHOULD NOT BE USED W/MATL TO PVNT STATIC ELEC. RAGS/OTHER MATLS CONTAINING PROD MAY OXIDIZE & IGNITE. ALL CONTAMD (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED FRESH AIR RESPIRATOR IN AREAS WHERE VAPOR CONCENTRATIONS RISE ABOVE GIVEN TLV'S. Ventilation:EXPLOSION PROOF MECHANICAL EXHAUST SYSTEM. Other Protective Equipment:IMPERMEABLE APRONS & PROT CLTHG TO PVNT SKIN CONT. EMER EYE WASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PRECAUT:MATLS SHOULD BE IMMERSED IN WATER IMMEDIATELY TO AVOID SPONT COMBUSTION. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:306F,152C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:0.8 (H*20=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NONE Appearance and Odor:CLOUDY, THIN LIQUID WITH OILY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE MATERIALS & STRONG OXIDANTS. Stability Condition to Avoid:EXCESSIVE HEAT, POOR VENTILATION, CORROSIVE CNDTNS, EXCESSIVE AGING. Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES & OTHER DECOMPOSITION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:COLLECT SPILLED MATL & ABSORBENT IN METAL CNTNRS & ADD ENOUGH WATER TO COVER. CONSULT LOCAL, STATE, & FEDERAL REGULATIONS BEFORE DISPOSING OF AT AN APPRVD INCIN FACILITY ONLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1,8-OCTANEDIOL, 151C-12 CAGE:IO526 CAGE:IO526 CAGE:58378 ============= Composition/Information on Ingredients ============= Ingred Name:1,8-OCTANEDIOL CAS:629-41-4 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INHALED OR SWALLOWED. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. GASTROINTESTINAL DISTURBANCES, NAUSEA, HEADACHE AND VOMITING. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:FLUSH WITH WATER. EYES:TREAT BY IMMEDIATE AND PROLONGED IRRIGATION WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR. INGEST:WASH OUT MOUTH WITH WATER PROVIDED PERS ON IS CONSCIOUS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEM POWDER, APPROPRIATE FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA RESPIRATOR, CHEMICAL SAFETY BAG AND HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKU P IS COMPLETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED MASK. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:USE PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:342F,172C Melt/Freeze Pt:M.P/F.P Text:138F,59C Solubility in Water:NOT KNOWN Appearance and Odor:WHITE CRYSTALLINE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS, CHLOROFORMATES, REDUCING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:F65G40 KEM LUSTRAL ENAMEL NON-LEAD, MEDIUM GREEN CAGE:54626 CAGE:54626 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROTREATED LIGHT DISTILLATE, PETROLEUM; C12-C15 ISOPARAFFINIC HYDROCARBONS CAS:64742-47-8 Fraction by Wt: 35-60% Other REC Limits:300 PPM (MFR) OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 0-5% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 0-5% Other REC Limits:100 PPM OSHA PEL:S,100PPM/150STEL ACGIH TLV:S,100PPM/150STEL9192 Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 0-5% Other REC Limits:25 PPM (SKIN) OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-30% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION, NERVOUS SYSTEM DEPRESSION, HEADACHE, NAUSEA, CONFUSION, STAGGERING GAIT, UNCONSCIOUSNESS & DEATH. EFFECTS TO LIVER, URINARY, BLOOD FORM ING SYSTEMS. PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION, NERVOUS SYSTEM DEPRESSION, HEADACHE, NAUSEA, CONFUSION, STAGGERING GAIT, UNCONSCIOUSNESS & DEATH. EFFECTS TO LIVER, URINARY, BLOOD FORM ING SYSTEMS. PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. KEEP WARM & QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:202F Extinguishing Media:CO, DRY CHEMICAL & FOAM Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WEAR FULL PROTECTIVE CLOTHING & SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP, AUTOIGNITION & EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:ELMINATE IGNITION SOURCES. VENTILATE AREA. REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. COMBUSTIBLE. Other Precautions:USE APPROVED BONDING & GROUNDING PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPRIATORY DEVICE. Ventilation:LOCAL EXHAUST & GENERAL TO KEEP BELOW TLV. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.WASH HANDS AFTER USE. Supplemental Safety and Health INTENTIONAL CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. SANDING OR ABRADING THE DRIED FILM MAY PRESENT A NUISANCE PARTICULATE HAZARD. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:240-416F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:MEDIUM GREEN Percent Volatiles by Volume:58-66% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT & OPEN FLAME Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS UNDER RCRA. TEST FOR IGNITABILITY TO DETERMINE HAZARDOUS WASTE NUMBER. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINER. DISPOSE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. COMBUSTIBLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INSTANT ACRYLON, 1612-16S Preparer's Name:G UNRUH CAGE:DO989 CAGE:DO989 CAGE:54700 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLMETHACRYLATE COPOLYMER Fraction by Wt: 10.5% Ingred Name:TRICHLOROFLUOROMETHANE (CFC-11) (SARA III) CAS:75-69-4 RTECS #:PB6125000 Fraction by Wt: 48% OSHA PEL:1000 PPM ACGIH TLV:C, 1000 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 39.7% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 1.8% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: VAPS MAY CAUSE NAUSEA, DIZZINESS, VOMITING, HEADACHE & POSSIBLE UNCONSCIOUSNESS. EYE: CNTCT W/EYES WILL CAUSE SEVERE IRRIT W/POSSIBLE CORNEAL DAMAGE. SKIN: MILD TO MODERATE IRRIT W/ DRYING/DEFA TTING. INGEST: RESPIRATORY DISTRESS, NAUSEA, VOMITING, MODERATE TO SEVERE MUCOSAL IRRIT & POSSIBLE UNCONSCIOUSNESS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS.CHLOROCARBON/ CHLOROFLUOROCARBON(CFC( MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS.ADRENOMIMETICS (E.G.,EPINEPHRINE)MAY BE CONTRA-INDICATE EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY (SEE SUPPL DAT Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR, GIVE ARTF RESP IF NEC, FOLLOW UP W/MED ATTN. EYES: FLUSH W/CLEAR H2O FOR AT LEAST 15 MIN, SEEK IMMED MED ATTN. SKIN: WASH W/EMOLLIENT SOAP & CLEAR H2O FOLLOWED BY APPLICATIO N OF HYPO-ALLERGENIC HAND CREAM. INGEST: IF CONS, GIVE SOAPY H2O EMETIC, FOLLOWED BY A SALINE CATHARTIC. SEEK IMMED ATTN. NEVER GIVE AN UNCONS PERSON ANYTHING BY MOUTH! OBSERVE ALL SAFETY PREC. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:40.0F,4.4C Lower Limits:1.7 % Upper Limits:7.0 % Extinguishing Media:CO2, HALON OR DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPNMENT FOR ALL FIRE SITUATIONS. DO NOT USE WATER TO FIGHT FIRES. Unusual Fire/Explosion Hazard:DO NOT STORE AEROSOL CANS IN DIRECT SUNLIGHT OR ABOVE 120 F. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE ALL POSSIBLE IGNITION SOURCES. PICK UP ON SUITABLE INERT ABSORBENT AND PLACE IN APPROPRIATE RECEPTACLE. AVOID INHALATION OF VAPORS AND CONTACT WITH SKIN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL AREA. DO NOT STORE AEROSOL CONTAINERS IN DIRECT SUNLIGHT OR ABOVE 120 F. Other Precautions:KEEP OUT OF REACH OF CHILDREN! FOR INDUSTRIAL USE ONLY. NO SMKNG IN AREA OF USE. DO NOT USE IN THE GEN VICIN OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATI ON OF HCL/FLUORIDES & OR PHOSGENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF APPLICABLE - NIOSH/MSHA APPROVED ORGANIC VAPOR MASK ABOVE TLV. Ventilation:MECHANICAL (GENERAL) LAB TYPE FUME HOOD, 340 CFM EXHAUST RATE, 100 FOOT/MIN. FACE VELOCITY. Other Protective Equipment:AVAILABLE EYEWASH AND FIRE EXTINGUISHER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. SIGN & SYMPTOMS:EXPOSED TO CHLOROCATVONS OR CFCS. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:230F,110C Vapor Pres:38 @ 25 C Spec Gravity:0.880 Evaporation Rate & Reference:14.5 (N-BUTYL ACETATE=1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR WATER-WHITE LIQUID WITH FRUITY ODOR. Percent Volatiles by Volume:94.2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:HEAT OR FIRE. Hazardous Decomposition Products:CO2, CO, COCL2, HCL AND HF. ==================== Disposal Considerations ==================== Waste Disposal Methods:FORCED INCINERATION WHERE PERMITTED BY FEDERAL, STATE AND LOCAL LAWS. INCINERATION APPLIES TO EXPENDED AEROSOL MATERIAL ONLY DO NOT PUT CANS IN FIRE.-: CONSIGNMENT TO RECLAIMER/WASTE HAULER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DUAL SHIELD 111-10 CAGE:GO230 CAGE:GO230 CAGE:84021 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 OSHA PEL:5 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:SILICA DIOXIDE, CRYSTALLINE QUARTZ, SAND (SUSPECTED HUMAN CARCINOGEN BY IARC & ACGIH) CAS:14808-60-7 RTECS #:VV7330000 Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:TITANIUM DIOXIDE, TIO2 CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SODIUM TITANATE *93-1* CAS:12034-34-3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:IRRITATION OF NOSE, THROAT, EYES. MAY LEAD TO SIDEROSIS WHICH MAY AFFECT PULMONARY FUNCTION. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SEE SUPP. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:INHALATION: DIZZINESS, NAUSEA, IRRITATION OF NOSE OR THROAT. EYES: IRRITATION. SKIN: DRYNESS & BURNS. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP HEAD OUT OF FUMES, DON'T TOUCH LIVE ELECTRICAL PARTS, INSULATE FROM WORK AND GROUND. Other Precautions:TO DETERMINE COMPOSITION & QUANTITY OF FUMES & GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE THE WELDERS HELMET OR IN THE WORKER'S BREATHING ZONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:LOCAL EXHAUST AT THE ARC TO KEEP THE FUMES & GASES BELOW THE TLV. Other Protective Equipment:HELEMT, ARM PROTECTORS, APRONS, HATS, Supplemental Safety and Health THE PRODUCT AS SUPPLIED IS NON-HAZARDOUS. HEALTH HAZARDS OCCUR DURING OPERATIONS. THE COMPOSITION & QUANTITY OF WELDING FUMES ARE DEPENDENT ON THE PROCESS, PROCEDURES, MEDIA, CONTAMINENTS IN THE ATMOS PHERE, & ELECTRODES USED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SEE SUPP Stability Condition to Avoid:SEE SUPP Hazardous Decomposition Products:CO, CO2, OZONE & NITROGEN OXIDES FORMED BY THE RADIATION FROM ARC. WELDING FUMES - COMPLEX OXIDES FROM THE INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FEDERAL, STATE, & L OCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MAGNABOND 6004, A & B Preparer's Name:ERNEST CARTER CAGE:22121 CAGE:22121 ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN Minumum % Wt:20. Maxumum % Wt:30. Ingred Name:DIBUTYL PHTHALATE(DBP) Minumum % Wt:4. Maxumum % Wt:8. ACGIH TLV:5 MG/M3 Ingred Name:AROMATIC AMINE Minumum % Wt:40. Maxumum % Wt:50. Ingred Name:AMINE Minumum % Wt:20. Maxumum % Wt:30. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATELY IRRITATING TO SKIN AND EYES. POSSIBLE SKIN SENSITIZER. VAPORS ARE IRRITATING TO SKIN AND EYES. PRE-EXISTING SKIN AND EYE DISORDERS MAY BE AGGRAVATED. Effects of Overexposure:NOT LIKELY TO PRODUCE ADVERSE EFFECTS DUE TO LOW VOLATILITY VAPORS ARE IRRITATING TO THE SKIN AND EYES. LOW ORDER OF TOXICITY. MODERATE TOXICITY; MAY CAUSE BURNS OF MOUTH AND THROAT. NOT LIKELY TO BE ABSORBED THROUGH THE SKIN IN TOXIC AMOUNTS.REPEATED OR PROLONGED EXPOSURE MAY BE HARMFUL.MODERATELY IRRITATING;MAY CAUSE SKIN SENSITIZATION. MAY CAUSE CHEMICAL BURNS AND/OR DEVELOP ALLERGIC REACTION MODERATELY IRRITATING. MODERATELY IRRITATING; PERMANENT DAMAGE POSSIBLE ON PROLONGED EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING. WASH FROM SKIN WITH SOAP AND WATER.LAUNDER CLOTHING PRIOR TO RE-USE.EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING THE EYELIDS OPEN.GET MEDICAL ATTENTION.INHALA TION: REMOVE VICTIM TO FRESH AIR.ADMINISTER OXYGEN IF NECESSARY. INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE DOSES OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=93.3C, 200.F Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:AVOID BREATHING SMOKE AND VAPORS. IN A CONFINED AREA, USE FULL FIRE FIGHTING EQUIPMENT INCLUDING AN APPROVED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT WITH LIQUID AND VAPORS . WIPE WITH A CLOTH OR COLLECT ON ABSORBENT MATERIAL. FOR LARGE SPILLS, DIKE AND CONTAIN.PUMP OR SHOVEL INTO SALVAGE CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA IN TIGHTLY CLOSED CONTAINERS.AVOID CONTACT WITH SKIN AND EYES. USE WITH ADEQUATE VENTILATION. USE GOOD HYGIENE PRACTICES. Other Precautions:NOT CONSIDERED TO BE A HAZARDOUS WASTE NOT LISTED.NOT REGULATED.CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S., UN 3267 ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR. RUBBER. Other Protective Equipment:FOR PROLONGED EXPOSURE, IMPERVIOUS CLOTHING AND BOOTS. MAY CAUSE SKIN IRRITATION. CORROSIVE . MAY CAUSE SEVERE EYE BURNS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:>107.2C, 225.F Vapor Pres:NIL Vapor Density:>1 Spec Gravity:2.19 Evaporation Rate & Reference:>1 Solubility in Water:NEGLIGIBLE Appearance and Odor:A BLACK VISCOUS LIQUID; CHARACTERISTIC ODOR B BROWN LIQUID; AMMONIACAL ODOR Percent Volatiles by Volume:0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS AND BASES. Stability Condition to Avoid:LARGE MIXTURES IN BULK. CURING PROCESS IS EXOTHERMIC. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE SALVAGE CONTAINERS TO A WASTE DISPOSAL SITE OPERATING IN COMPLIANCE TO FEDERAL, STATE AND LOCAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S64N536 BURNT SIENNA CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL, GLYCOL *96-2* CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 4% Other REC Limits:10 MG/CUM OSHA PEL:50 PPM ACGIH TLV:C 127 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:PROPANOIC ACID, 2-METHYL, MONOESTER W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL, TEXANOL(ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 3% Ingred Name:AMORPHOUS SILICA GEL *96-2* CAS:7631-86-9 Fraction by Wt: 1% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 61.5% Ingred Name:VOLATILE ORGANIC CONTENT: 0.69 LBS/GAL; 2.27 LBS/GAL LESS WATER RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & UPPER RESPIRATORY SYSTEM. PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY & REPRODUCTIVE SYSTEMS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, DIZZINESS, REDNESS, ITCHING, BURNING. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING W/SCBA. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE & REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE INTERNALLY. Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING VAPOR/SPRAY MIST & CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING THE DRIED FILM, WEAR A DUST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA. Ventilation:USE ONLY ADEQUATE VENTILATION. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH: 8.5-9.5. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212-388F Vapor Density:>1 Spec Gravity:1.1-1.4 pH:(SUPP) Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:92-95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:BY FIRE: CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T INCINERATE CLOSED CONTAINERS. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GASOLINE AND DIESEL FUEL ENGINE GASKET MATE CAGE:73165 CAGE:73165 CAGE:89346 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS (FRIABLE)(SARA III) CAS:1332-21-4 RTECS #:CI6425000 Fraction by Wt: 70-90% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1001 ACGIH TLV:0.2 - 2 FIBERS/CC EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:PROLONGED OR REPEATED EXPOSURE TO AIRBORNE ASBESTOS FIBERS FROM SANDING, CUTTING, SCRAPPING, FILING, ETC. MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. SMOKING COMBINED WITH FIBER INHALATION GREATLY INCREA SES LUNG CANCER RISK. Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS / MESOTHELIOMA; DUST MAY CAUSE EYE IRRITATION. Medical Cond Aggravated by Exposure:PERSONS WITH RESPIRATORY DISEASE OR PERSONS WHO SMOKE MAY BE AT INCREASED RISK FROM EXPOSURE TO DUST CONTAINING ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. EYE: PROMPTLY FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE LIFTING EYELID. GET MEDICAL ATTENTION. SKIN: PROMPTLY FLUSH WITH SOAP AND WATER. REM OVE CONTAMINATED CLOTHING. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: GET MEDICAL ATTENTION AS REQUIRED. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER FOG, DRY CHEMICALS, FOAM, CARBON DIOXIDE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:TOXIC VAPORS MAY BE RELEASED DURING COMBUSTION OF THE BINDER MATERIAL. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED WITH AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. Other Precautions:AS MANUFACTURED, ENCAPSULATED ASBESTOS DOES NOT PRESENT A HAZARD. HOWEVER, IF DUST IS GENERATED BY SANDING, GRINDING, SCRAPPING OR OTHER ABRADING ACTIONS, ASBESTOS FIBERS MAY BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EXPOSURE TO AIRBORNE ASBESTOS SHALL NOT EXCEED 0.2 FIBERS PER CUBIC CENTIMETER OF AIR AS AN 8-HOUR TWA. USE NIOSH APPROVED FULL FACEPIECE AIR PURIFYING RESPIRATOR EQUIPPED WITH HEPA FILTER OR AIR SUPP LIED RESPIRATOR IN PRESSURE DEMAND MODE. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN OPERATIONS WHERE DUST IS GENERATED SUCH AS CUTTING, GRINDING, SCRAPPING, ETC. Other Protective Equipment:WORK CLOTHES OR COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health CONTAINS ASBESTOS FIBERS. AVOID CREATING DUST. CANCER AND LUNG DISEASE HAZARD. AVOID BREATHING AIRBORNE ASBESTOS FIBERS. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:NEGLIGIBLE Appearance and Odor:GASKET MATERIAL, VERY MILD CHARACTERISTIC ODOR. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Hazardous Decomposition Products:PYROLYSIS YIELDS CARBON MONOXIDE, CARBON DIOXIDE AND OTHER TOXIC VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. INDICATE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COMPOSITION A-5, TYPE I CAGE:1D893 CAGE:1D893 ============= Composition/Information on Ingredients ============= Ingred Name:SUPDAT:CREVICES OF STRUCTS, EQUIP & CNTNRS WHICH HAVE BEEN EXPOSED TO EXPLOS. PROPERTY WHICH MAY BE CONTAM BY (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:EXPLOS MUST NOT BE SUBJ TO HEAT, SPKS/FLAME. DETONATION CAN OCCUR. THERMAL DECONTAM UNDER CONTROLLED CNDTNS(ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:IS RECOM METH FOR COMPLETE DECONTAM. THERMAL DECONTAM MUST BE PRECEDED BY WASHING/STEAMING & CHEM NEUT/ (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:DISSOLN. CONTAM PROPERTY MUST NOT BE BURIED. MILITARY HIGH EXPLO ASSIGNED UNITED NATIONS ORG CLASSIFICATION(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:OF 1, DIVISION 1 (MASS DETONATING) BASED ON DOD EXPLOS HAZ CLASSIFICTATION PROCS, ARMY TECH BULLETIN 700-2. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:OF THROAT/BY GIVING SYRUP OF IPECAC. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. GET MED ATTN. RTECS #:9999999ZZ Ingred Name:SPILL PROC:METAL TO METAL CONT, IMPACT W/SHARP OBJECTS, FRICTION/OTHER SITUATIONS WHICH MAY INITIATE EXPLO. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:AVOID SAND, GLASS, GRIT & METAL FRAGMENTS WHICH MAY SENSIT MATL TO IMPACT &/OR FRICTION. WET W/WATER TO DESENSIT. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:CLTHG. DISP SHLD COMPLY W/ALL APPLIC FED, STATE & LOCAL REGULATIONS. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CONTINUING BASIS. EXTREME CARE SHLD BE EXERCISED DURING MAINT OF EXPLO CONTAM EQUIP. DECONTAM PROCS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:INCL WASHING/STEAMING, CHEM DECONTAM & THERMAL DECONTAM. DECONTAM SHLD BE PERFORMED PRIOR TO WELDING, (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:CUTTING/GRINDING METAL PARTS. PENET OIL SHLD BE USED LIBERALLY ON NUTS, BOLTS & ALL THREADED CONNECTIONS (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:TO AID IN DESENSITIZING HIDDEN EXPLOS PRIOR TO DISASSEMBLY. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:SAFETY SHOWER, EYE BATH & WASHING FACILITIES SHOULD BE AVAILABLE. RTECS #:9999999ZZ Ingred Name:S-TRIAZINE, HEXAHYDRO-1,3,5-TRINITRO-; (CYCLOTRIMETHYLENE TRINITRAMINE). LD50:(ORAL,RAT) 100 MG/KG. CAS:121-82-4 RTECS #:XY9450000 Fraction by Wt: 98.5-99% OSHA PEL:1.5 MG/M3, S ACGIH TLV:1.5 MG/M3, S Ingred Name:STEARIC ACID; (OCTADECANOIC ACID) CAS:57-11-4 RTECS #:WI2800000 Fraction by Wt: 1-1.5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:CAN CAUSE ALLERGIC REACTION. EYES:CAN CAUSE IRRITATION. INHAL & INGEST:CHRONIC EXPOSURE TO RDX DUST HAS BEEN REPORTED TO CAUSE CONVULSIONS OR UNCONSCIOUSNESS. INHALATION & INGESTION CAN RESULT IN SYSTEMIC POISONING, USUALLY AFFECTING BONE MARROW (BLOOD-CELL-PRODUCING SYSTEM) & LIVER. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH THORO W/LG AMTS OF WATER FOR @ LST 15 MINS. REMOVE CONT LENSES. GET MED ATTN. SKIN:WASH W/SOAP & WARM RUNNING WATER. CLEAN CLTHG THORO & DISP OF CONTAM SHOES. GET MED ATTN FOR RASH/IRRIT. I NHAL:REMOVE TO FRESH AIR, TREAT ANY IRRIT SYMPTOMATICALLY. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN. INGEST:IF CONSCIOUS, INDUCE VOMIT IMMED BY GIVING 1-2 GLASSES OF WATER & TOUCHING BACK (ING 8) ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRINKLER/DELUGE SYSTEM RECOMMENDED. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . BURNING EXPLOS MAY ACCELERATE TO DETONATION @ ANY TIME WHEN SUBJ TO CONFINEMENT, SHOCK/OTHER (SUPDAT) Unusual Fire/Explosion Hazard:MUST NOT BE CONFINED IF BURNING. CONFINEMENT CAN CAUSE DEFLAGRATION/TRANSITION TO DETONATION W/EXTREMELY VIOLENT RSLTS. EXPLOS MAY BE RETAINED IN (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS IMMED USING SOFT BRISTLE BRUSH & CONDUCTIVE RUB PAN/SHOVEL. USE CONDUCTIVE CNTNRS & GROUND ALL CNTNRS BEFORE TRANSFERRING EXPLOS BTWN CNTNRS. TREAT LIKE FLAMM SOLV W/REGARD TO ELECTROS TATIC DISCHARGE. AVOID PINCHING MATL, (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN APPRVD EXPLOS MAGAZINES I/A/W AMCR 385-100. EXPLOS MUST BE TESTED FOR COMPAT W/ANY MATLS WHICH THEY CONT. KEEP CNTNR CLSD. Other Precautions:STOR & HNDLG MUST BE CARRIED OUT I/A/W APPROP SAFETY AGENCY REGS CONCERNING QTY, DIST, BARRICADING, PERS EXPOS & MATL HNDLG EQUIP. RECYCLE/DISP OF USED CNTNRS I/A/W APPROP SAFETY AGENCY REGS. DUST GEN BY HNDLG MUST BE CLEANED UP ON (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUSTS & PARTICULATES IF EXPOSED TO DUSTING. Ventilation:LOC EXHST:HOODS FOR DUSTY OPERATIONS ARE REQD. MECH:GEN. SPECIAL:DUST COLLECTION EQUIP REQD. Other Protective Equipment:CAPS & COVERALLS FOR FULL BODY PROT. COTTON UNDERWEAR, SOCKS & CONDUCTIVE SHOES TO AVOID HUMAN STATIC DISCHARGE.(ING 16) Work Hygienic Practices:AS PREC, HNDLE ONLY IN WELL-VENTED AREAS, CHANGE CLTHG DAILY, BATHE @ END OF WORK PERIOD & WASH HANDS THORO AFTER HNDLG. Supplemental Safety and Health FIRE FIGHT:SUFFICIENT INITIATION SOURCE. NO ATTEMPT TO FIGHT FIRES INVOLVING EXPLOS SHLD BE MADE EXCEPT FOR MANUAL ACTIVATION OF INSTALLED FIRE EXTING EQUIP. PERS SHLD LEAVE BLDG IMMED USING AS MUCH P ROT COVER AS POSS & ACTIVATING DELUGE SYS & FIRE ALARM EQUIP WHILE ESCAPING. EXPLO HAZ:FISSURES, CRACKS & (ING 3) ================== Physical/Chemical Properties ================== HCC:E1 Melt/Freeze Pt:M.P/F.P Text:>32F,>0C Spec Gravity:1.7 (H*2O=1) Solubility in Water:INSOLUBLE @ 20C Appearance and Odor:WHITE TO OFF WHITE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID ALKALIS, STRONG ACIDS & PHYSICAL SENSITS SUCH AS GLASS, SAND & METAL FRAGMENTS. Stability Condition to Avoid:MILITARY HIGH EXPLOSIVE. AVOID SHOCK, HEAT, ELECTROSTATIC DISCHARGE, IMPACT, IMPINGEMENT & FRICTION. Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:EXPLOS SHLD BE DESTROYED BY OPEN BURNING, BY BURNING IN APPRVD INCIN/BY CHEM TREATMENT W/CAUSTICS. DISP SITE SHLD PROVIDE ADEQ QTY-DIST PROT. EXPLOS SHLD NOT BE BURNED IN CNTNRS. EXPLOS SHLD BE IGNITE D REMOTELY. PERS SHLD WEAR FLAME RESISTANT(ING 11)
1
eyes_protection_mandatory
======================================================= NIIN: 01-237-8414 Product ID: F.P. TRAY POLYMER #64 BLUE, SHADE #26151 (SEE SUPPL) Kit Part: Y Cage: 2R260 Resp. Party Other MSDS No.: PRODUCT CODE: M 044 5066 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: FACSIMILE KIT,DEPOT Specification Number: NONE Type/Grade/Class: NONE Unit of Issue: KT UI Container Qty: 1 Type of Container: UNKNOWN ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES, SKIN AND RESPIRATORY TRACT MAY BE IRRITATED BY OVEREXPOSURE TO PARTICULATE, NOT OTHERWISE CLASSIFIED, CALCIUM CARBONATE AND MINERAL PIGMENT DUST. INHALATION OF VAPOR OR MIST IS MARMFUL AND CAN C AUSE SEVERE IRRITATION OF NOSE, THROAT, AND LUNGS. MAY CAUSE PERMANENT, IRREVERSIBLE EYE DAMAGE. CAN BE ABSORBED THROUGH THE SKIN AND CAUSE SKIN SENSITIZATION. CORROSIVE TO THE SKIN. PROLONGED OR REPE ATED EXPOSURE CAN CAUSE THE ALLERGIC SKIN REACTION, KIDNEY DAMAGE AND LIVER DAMAGE. INGESTION MAY CAUSE NAUSEA, ABDOMINAL PAIN AND DIARRHEA. MAY CAUSE BURNING, TEARING, REDNESS OF EYES. PROLONGED/REPE ATED SKIN CONTACT MAY CAUSE BURNING. Explanation Of Carcinogenicity: ETHYL ACRYLATE, A PRODUCT OF COMBUSTION, IS LISTED AS A SUSPECT CARCINOGEN BY IARC, NTP AND ACGIH. TITANIUM DIOXIDE IS LISTED AS A POSSIBLE CARCINOGEN BY IARC. NONE OF THE OTHER COMPONENTS OF THIS MAT ERIAL ARE LISTED BY IARC, NTP, OSHA, OR ACIGH AS CARCINOGENS. Signs And Symptions Of Overexposure: EYES, SKIN AND RESPIRATORY TRACT MAY BE IRRITATED BY OVEREXPOSURE TO PARTICULATE, NOT OTHERWISE CLASSIFIED, CALCIUM CARBONATE AND MINERAL PIGMENT DUST. INHALATION OF VAPOR OR MIST IS MARMFUL AND CAN C AUSE SEVERE IRRITATION OF NOSE, THROAT, AND LUNGS. CAN CAUSE SKIN SENSITIZATION. INGESTION MAY CAUSE NAUSEA, ABDOMINAL PAIN AND DIARRHEA. MAY CAUSE BURNING, TEARING, REDNESS OF EYES. PROLONGED/REPEATE D SKIN CONTACT MAY CAUSE BURNING. Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: INHALATION: REMOVE TO FRESH AIR. GET MEDICAL HELP IF DISCOMFORT PERSISTS. EYES: FLUSH WITH WATER FOR 15 MINUTES, INCLUDING UNDER EYELIDS. GET MEDICAL HELP IF DISCOMFORT PERSISTS. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL HELP IF DISCOMFORT PERSISTS. INGESTION: RINSE MOUTH OUT WITH WATER. CALL DOCTOR IF AMOUNT WAS LARGE. CLOTHING: WASH THOROUGHLY BEFORE REUSE. TREATMENT: TREAT SYMPTOMS AFTER THOR OUGH DECONTAMINATION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SWEEP UP TO AVOID SLIPPING HAZARD. KEEP AIRBORNE PARTICULATES AT A MINIMUM WHEN CLEARING UP SPILLS. Neutralizing Agent: NOT PROVIDED Waste Disposal Methods: CONTAINS A DIALKYL PHTHALATE, CONTAMINATED PRODUCT MAY BE A RCRA/OSHA HAZARDOUS WASTE (40 CFR PART 261 AND 29 CFR PART 1910). INCINERATE MATERIAL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIO NS. Handling And Storage Precautions: STORE IN COOL DRY PLACE. KEEP CONTAINER CLOSED TO PREVENT WATER ABSORPTION AND CONTAMINATION. Other Precautions: WASH FACE AND HANDS THOROUGHLY WITH SOAP AND WATER AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR APPLYING COSMETICS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point: =304.4C, 580.F Autoignition Temp Text: N/E Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures: AVOID EXTINGUISHING METHODS WHICH MAY GENERATE DUST CLOUDS. WATER STREAM CAN DISPERSE DUST INTO AIR, PRODUCING A FIRE HAZARD AND POSSIBLE EXPLOSION HAZARD IF EXPOSED TO IGNITION SOURCE. Unusual Fire/Explosion Hazard: POLYMER DUST IS COMBUSTIBLE. THE EXPLOSIVE LIMITS OF THE POLYMER PARTICLES SUSPENDED IN AIR ARE APPROXIMATELY THOSE OF COAL DUST. FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. ======================================================= Control Measures ======================================================= Respiratory Protection: USE TYPE FOR PARTICULATES NOT OTHERWISE CLASSIFIED, IF NEEDED. Ventilation: USE GOOD LOCAL EXHAUST AT PROCESSING EQUIPMENT, INCLUDING BUFFERS, SANDERS, GRINDERS AND POLISHERS. Other Protective Equipment: HIGH TEMPERATURE PROCESSING EQUIPMENT SHOULD BE WELL VENTILATED. Work Hygienic Practices: NOT PROVIDED Supplemental Safety and Health: PRODUCT CODE: M 044 5066. CONTD FROM PRODUCT ID: HOOSIER P/N: 16000. OTHER MSDS NUMBERS: CLDYG, CLDYJ, CLDYK. ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 NRC/State LIC No: NOT RELEVANT M.P/F.P Text: NOT PROVIDED Decomp Text: NOT PROVIDED Spec Gravity: 1.185 Solubility in Water: INSOLUBLE Appearance and Odor: FINE BLUE POWDER. FAINT ODOR IN BULK. Percent Volatiles by Volume: <5 BY WEIGHT Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEATING ABOVE 240C, 464F. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: ACRYLATE AND METHACRYLATE MONOMERS, AND OXIDES OF CARBON. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: METHYL METHACRYLATE: LD50 ACUTE ORAL RAT: 7990 MG/KG. LD50 ACUTE DERMAL RABBIT: 35,500 MG/KG. LC50 ACUTE INHALATION RAT: > 12,500 TO 16,500 PPM FOR 0.5 HOUR. ETHYL ACRYLATE ORAL LD50 RAT: 800 MG/KG. D ERMAL LD50 RAT: 1800 MG/KG. FOR CALCIUM CARBONATE: LD50 ORAL RAT: 6450 MG/KG. BENZOYL PEROXIDE: LD50 ORAL RAT: 7710 MG/KG. FOR MINERAL PIGMENT: LD50 ORAL RAT: > 10,000 MG/KG. FOR DIALKYL PHTHALATE: LD 50 ACUTE ORAL RAT: 8 G/KG. LD50 DERMAL RABBIT: >20 ML/KG. ======================================================= Ecological Information ======================================================= Ecological: AQUATIC TOXICITY: FOR METHYL METHACRYLATE MONOMER, ESTIMATE OF 96 HOURS MEDIAN THRESHOLD LIMIT: 100-1000 PPM. FLATHEAD MINNOWS AND GOLDFISH: 420 PPM.BLUGILLS TLM24: 388 PPM. ECOLOGICAL TOXICITY: NONE KNOWN. ======================================================= ======================================================= Transport Information: NOT PROVIDED ======================================================= Regulatory Information ======================================================= Sara Title III Information: NOT PROVIDED Federal Regulatory Information: TSCA: LISTED State Regulatory Information: THE DECOMPOSITION PRODUCT ETHYL ACRYLATE IS KNOWN TO THE STATE OF CALIFORNIA AS A SUBSTANCE WHICH CAUSES CANCER. ======================================================= Other Information ======================================================= Other Information: ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS. ======================================================= Transportation Information ======================================================= Trans ID NO: 157413 Product ID: F.P. TRAY POLYMER #64 BLUE, SHADE #26151 (SEE SUPPL) Review Date: 06/11/2001 Multiple KIT Number: 0 Kit Part IND: Y Unit Of Issue: KT Container QTY: 1 Type Of Container: UNKNOWN ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: F.P. TRAY POLYMER #64 BLUE, SHADE #26151 (SEE SUPPL) Cage: 2R260 Company Name: FLEXBAR MACHINE CORP Street: 250 GIBBS RD Zipcode: 11749-2697 Label Required IND: Y Date Of Label Review: 06/11/2001 Status Code: A MFG Label NO: NOT PROVIDED Year Procured: 1999 Origination Code: F Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: NOSE, LIVER, KIDNEY, CNS, EYE, MALE REPRODUCTIVE SYSTEM. CAUSES IRRITATION. AVOID BREATHING DUST AND CONTACT. IF INGESTED, RINSE MOUTH OUT WITH WATER. IF INHALED, REMOVE TO FRESH AIR. IF IN EYES, FLUSH WITH WATER. SEE MSDS FOR DETAILS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FRYS 60-40 SOLDER CAGE:9S263 CAGE:9S263 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 40.0% OSHA PEL:0.05 MG/M3;1910.1025 ACGIH TLV:0.15 MG/M3;DUST 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 60.0% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:PROLONGED ABSORPTION OF LEAD GIVES LEAD COLIC, METALLIC TASTE IN MOUTH, WT LOSS, PAIN IN MUSCLES. ======================= First Aid Measures ======================= First Aid:REMOVE PATIENT FROM AREA TO FRESH AIR. REFER TO MD. IF MOLTEN, TREAT AS BURN. FLUSH W/CLEAR WATER. EXCESSIVE ABSORPTION OF LEAD BE VERIFIED BY MED EXAM & ANALYSIS OF BIOLIGICAL SPECIMENS. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WHEN MOLTEN, ALLOW TO COOL/SOLIDIFY, THEN PUT IN APPRVD STG CNTNR & SHIP TO APPRVD STG AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH HANDS AFTER CONSIDERABLE HANDLING. NO SPECIAL STG REQ. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORM REQ Ventilation:FUME HOOD OVER SOLDERING AREA Supplemental Safety and Health TYPE SN60WRNAP3 OF FED SPEC. EFFECTS OF OVEREXP: MUSCULAR WEAKNESS, ABDOMINAL PAIN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:2894F Vapor Pres:00 Spec Gravity:8.65 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE, SOFT METAL, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:RETURN FOR SALVAGE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRAFFIC YELLOW AQUA-STRIPE LATEX PAINT, 324 Preparer's Name:J.B.R. CAGE:0GB20 CAGE:0GB20 ============= Composition/Information on Ingredients ============= Ingred Name:AQUEOUS ACRYLIC EMULSION. VP: 17 @ 20C. Fraction by Wt: <30% Ingred Name:IRON OXIDE HYDRATE (GEOTHITE) CAS:51274-00-1 Fraction by Wt: <5% Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SILICON DIOXIDE, SILICA CAS:7631-86-9 Fraction by Wt: <15% OSHA PEL:6 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:ETHYL ALCOHOL (ETHANOL). VP: 53 @ 20C. CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <5% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL ETHER) CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: <5% Ingred Name:HYDROTREATED LIGHT PETROLEUM DISTILLATE CAS:64742-47-8 Fraction by Wt: <5% OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: VAPOR OR MIST CAN CAUSE HEADACHE, NAUSEA, AND IRRITATION OF NOSE, THROAT AND LUNGS. CAUSES EYE IRRITATION. CAUSES SKIN IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR AT LST 15 MINS WHILE HOLDING EYELIDS OPEN.GET MED ATTN.SKIN: WASH W/SOAP & WATER. REMOVE CONTAMD CLTHG & SHOES;DO NOT REUSE UNTIL CLEANED.IF PERSISTENT IRRIT OCCURS, GET MED ATT N. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE OXYGEN IF BRTHG IS DFCLT.GIVE ARTF RESP IF NOT BRTHG.GET MED ATTN. INGEST:DO NOT INDUCE VOMIT.DILUTE BY GIVING WATER/MILK TO DRINK IF VICTIM IS CONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:212F,100C Lower Limits:0.9% Upper Limits:19% Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE, OR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL. COOL FIRE-EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN BUT MAY SPATTER IF TEMPERATURE EXCEEDS BOILING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:LARGE SPILLS: EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL. WEAR APPROPRIATE RESPIRATOR AND PROTECTIVE CLOTHING. DIKE AND CONTAIN. TRANSFER TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUAL WITH AN ABSORB ENT SUCH AS CLAY OR SAND. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. KEEP CNTNRS TIGHTLY CLSD. STORE AWAY FROM STRONG OXIDIZING AGENTS IN COOL,DRY PLACE W/ADEQ EXPLO-PROOF VENT. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS USE A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:MECHANICAL LOCAL EXHAUST VENTILATION AT POINT OF CONTAMINANT RELEASE. Other Protective Equipment:WEAR PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH WITH SOAP & WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health % VOLAT: 23.4 (WEIGHT); 38.7 (VOLUME). ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>165F,>74C Vapor Pres:SEE ING Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, COUNTY, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LACQUER SPRAYING OLIVE DRAB 14087 CAGE:61196 CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:*ISOBUTYL ACETATE RTECS #:NP9100000 Fraction by Wt: 25% ACGIH TLV:150PPM Ingred Name:ISOBUTYL ALCOHOL (SARA III) CAS:78-83-1 RTECS #:NP9625000 Fraction by Wt: 8% OSHA PEL:100 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:*METHYL ETHYL KETONE RTECS #:PM7780000 Fraction by Wt: 15% ACGIH TLV:200PPM Ingred Name:*TOLUOL/TOLUENE (NIOSH SHOWN FOR TOLUOL) RTECS #:XV1400000 Fraction by Wt: 8% ACGIH TLV:100PPM Ingred Name:*ALIPHATIC NAPHTHA Fraction by Wt: 15% ACGIH TLV:200PPM ===================== Hazards Identification ===================== Effects of Overexposure:INHAL:ANEST.IRRIT OF NOSE, THROAT, EYES & POSS.DIZZ & NAUSEA. ======================= First Aid Measures ======================= First Aid:INHAL:REMOV FRM EXPOSR & PROVIDE FRESH AIR.SPLASH EYES:FLUSH IMMED. W/LG AMTS OF WATER F/15 MIN.SPLASH SKIN:REMOV CONTAM CLOTHING & WASH AFFECTED AREA W/WATER. INGESTION:DO NOT INDUCE VOMITING.CONSULT A PHYSICIAN IMMEDIATELY IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:13F TCC -11C T Extinguishing Media:NFPA CL B EXTINGRS (CO*2, DRY CHEM OR ALCOHOL FOAM) Fire Fighting Procedures:SELF-CONTND BREATHING APPAR F/FIREMEN Unusual Fire/Explosion Hazard:KEEP CONTNRS TIGHTLY CLOS & ISOLAT FRM HEAT,ELECT EQPMT SPARKS,& OPN FLAME.CLOS CONTNRS MAY EXPLO(SU ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT(FLAMES,HOT SURFACE & ELECTR, STATIC OR FRICTIONAL SPARKS).VENTILAT AREA & AVOID BREATHING VAPORS.REMOV W/INERT ABSORBENT & USE NON-SPARKING TOOLS.STEPS MUST BE TAKEN TO AVO ID CONTAM OF GROUND WATER OR STREAMS. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOV 120F.STORE LG QTYS IN COMPLIANCE W/OSHA 1910.106.CONTNRS SHOULD BE BONDED TO EACH OTHER & GROUNDED PROPERLY WHN TRANSFR/POURING INT Other Precautions:DO NOT CUT OR WELD ON EMPTY CONTNRS "DO NOT USE UNTIL ALL SAFETY PRECAUTIONS & MIXING DIRECTIONS HAVE BEEN READ & FULLY UNDERSTOOD BY THE USER." ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPRVD MECH RESPIRATOR TO REMOV OVERSPRAY WHN SPRAY OUTDR/OPEN Ventilation:PROVID GEN. DILUT OR LOC EXHAUST VENT TO KP CONCENTR OF HAZ Other Protective Equipment:USE PROTECTIVE EQPMT TO PREVNT SKIN CONTACT. Supplemental Safety and Health *INDICATES SOLVENT. UNUS. FIRE & EXPLOS HAZ: WHEN EXPOSED TO EXTREME HEAT. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:174-700F Vapor Density:HEAV Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:82 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG ACIDS OR ALKALIS. Stability Condition to Avoid:FIRES,HEAT,SPARKS, & HOT SURFACES Hazardous Decomposition Products:SMOKE & OXIDES OF NITROGN & CARBON WHEN BURNED. Conditions to Avoid Polymerization:DO NOT AD DRIERS OR REACTV CHEM W/O TECH SUPVISON.SEE LABEL ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORD W/LOCAL, STATE & FEDERAL REGULATIONS. INCINERATE IN EPA APPRVD FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:4032 TRIM ADHESIVE CAGE:MART2 CAGE:MART2 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 6% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:HEXANE, N-HEXANE CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: <17% Other REC Limits:50 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:176 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXANE ISOMERS RTECS #:MO3860000 Fraction by Wt: <17% OSHA PEL:50 PPM ACGIH TLV:500 PPM Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSPECTED HUMAN CARCINOGEN BY ACGIH, NTP) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 32% OSHA PEL:100 PPM ACGIH TLV:174 MG/CUM (A2) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILICON DIOXIDE, CELITE 322 CAS:7631-86-9 RTECS #:VV3100000 Fraction by Wt: 1% OSHA PEL:80 MG/CUM ACGIH TLV:0.2 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:IRRITATION OF EYES/SKIN/RESPIRATORY SYSTEM. CNS DEPRESSION. PROLONGED SOLVENT MAY CAUSE ADVERSE EFFECTS TO LIVER/URINARY/BLOOD FORMING/REPRODUCTIVE/CARDIOVASCULAR SYSTEMS/PERMANENT BRAIN/CNS DAMAGE. H EXANE MAY CAUSE PERIPHERAL NERVE DAMAGE. EXTREME OVEREXPOSURE MAY CAUSE UNCONSCIOUSNESS & POSSIBLY DEATH. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:INHALATION: HEADACHE/DIZZINESS/NAUSEA/COORDINATION LOSS/UNCONSCIOUSNESS/DEATH. SKIN/EYES: REDNESS/ITCH/BURNING SENSATION. HEXANE: (PERIPHERAL NEUROPATHY) MUSCULAR WEAKNESS, LOSS OF SENSATION. OVEREXPO SURE TO METHYLENE CHLORIDE CAN RAISE THE LEVEL OF CARBON MONOXIDE IN THE BLOOD. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINUTES. INGESTION: OBTA IN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:<0F Lower Limits:0.5% Upper Limits:7% Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:USE SCBA. WATER SPRAY: INEFFECTIVE. FOG NOZZLES PREFERRED. USE WATER TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP/AUTOIGNITION/EXPLOSION. Unusual Fire/Explosion Hazard:HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CONTAINER TO BURST. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA/REMOVE W/INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME. DURING USE & UNTIL ALL VAPORS ARE GONE; KEEP ARE VENTILATED. DON'T SMOKE. Other Precautions:EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS. TURN OFF STOVES/ELECTRIC TOOLS/APPLIANCES & OTHER IGNITION SOURCES. CONSULT NFPA CODE. USE APPROVED BONDING/GROUNDING PROCEDURES. CONTENTS UNDER PRESSURE . KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW TLV BY VENTILATION, USE A FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED FILM, USE A NIOSH/MSHA DUST/MI ST RESPIRATOR. Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF EXPOSURE TO MATERIALS IS MAINTAINED BELOW APPLICABLE LIMITS. Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. DON'T PUNCTURE, INCINERATE OR EXPOSE TO TEMPS >12 0F. DON'T TAKE INTERNALLY. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING/INHALING CONTENTS CAN BE HARMFUL/FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0-395F Vapor Density:>1 Spec Gravity:0.75-0.91 Solubility in Water:INSOLUBLE Percent Volatiles by Volume:>50 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT/SPARKS/OPEN FLAMES/PILOT LIGHTS & OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT WASTE MAY BE HAZARDOUS AS DEFINED UNDER THE RCRA. TEST WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DON'T INCINERATE. DEPRESSURIZE CONTAINER. DISPOSE OF IN A CCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GASOLINE CAGE:0A0Y5 CAGE:0A0Y5 ============= Composition/Information on Ingredients ============= Ingred Name:MIXTURE OF PETROLEUM HYDROCARBONS (AROMATIC AND PARAFFINIC HYDROCARBONS) Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM TWA GASOLINE ACGIH TLV:300 PPM TWA GASOLINE Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE-INHALATION:CENTRAL NERVOUS SYSTEM DEPRESSION, NARCOSIS, UNCONSCIOUSNESS, ASPHYXIATION. EYE:IRRITATION. SKIN:DEFATING, IRRITATION. INGESTION: GI DISTURBANCES, ASPIRATION PNEUMONITIS. CHRONIC: DER MATITIS, ANEMIA, PULMONARY EDEMA, LIVERAND KIDNEY DAMAGE. Explanation of Carcinogenicity:CONTAINS B[71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:RESPIRATORY IRRITATION, COUGHING, DIFFICULTY IN BREATHING, NAUSEA, VOMITING, FATIGUE, BLURRED VISION, DIZZINESS, HEADACHES, UNCONSCIOUSNESS, EYE IRRITATION, REDNESS, DRY SKIN. Medical Cond Aggravated by Exposure:SKIN AND RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-50F,-46C Lower Limits:<1% Upper Limits:8% Extinguishing Media:USE CARBON DIOXIDE, FOAM, HALON OR DRY CHEMICAL. USE WATER FOG TO COOL SRROUNDING CONTAINERS. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:MINOR: ABSORB MATERIAL WITH CLAY, VERMICULITE, OR SIMILAR ABSORBENT MATERIAL. PLACE IN DISPOSAL CONTAINERS. MAJOR: DIKE & CONTAIN SPILL. ELIMINATE SOURCES OF IGNITION. SHUT OFF LEAKS. REMOVE LIQUID BY VACUUM OR ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, VENTILATED WORK AREA. KEEP CONTAINERS CLOSED WHEN NOT IN USE. FLAMMABLE LIQUID; EMPTY CONTAINERS CAN BE HAZARDOUS. Other Precautions:EXTREMELY FLAMMABLE LIQUID AND VAPOR. HIGHLY VOLATILE. VAPOR MAY CAUSE FLASH FIRE. VAPORS MAY SPREAD LONG DISTANCES AND IGNITE. KEEP AWAY FROM HEAT, SPARKS, AND FLAME. KEEP CONTAINER CLOSED. USE WITHADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR. AIR-SUPPLIED OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED. Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED. AVOID OPEN ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT. WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:B.P. Text:85.0F,29.4C Melt/Freeze Pt:M.P/F.P Text:<-76F,<-60C Vapor Pres:275-475MMH Vapor Density:>1 Spec Gravity:O.70-0.77 Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:INCOLUBLE Appearance and Odor:WATER WHITE TO STRAW YELLOW LIQUID, GASOLINE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRRONG ACIDS & ALKALIS, AND HALOGENS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FORMICA BRAND LAMINATE CAGE:FORMI CAGE:FORMI CAGE:80251 ============= Composition/Information on Ingredients ============= Ingred Name:NUISANCE DUST OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:FORMALDEHYDE CAS:50-00-0 RTECS #:LP8925000 OSHA PEL:0.75 PPM, 2 STEL ACGIH TLV:0.3 PPM, C EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:PROD IS NOT HAZ IN NORM USE; DURING FABRICATION OPERATIONS SUCH AS SAW, DRILL, ROUTING & SAND, DUST CONSISTING OF CURED RESIN & CELLULOSE IS GENERATED @ CUTTING FACE ALONG W/MIN AMTS OF FORMALDEHYDE. ACUTE: INHAL: ING 1: OVEREXP TO DUST MAY CAUSE IRRIT OF RESP TRACT. ING 2: NO VAP BUILD-UP IN EXCESS OF(EFTS OF OVEREXP) Explanation of Carcinogenicity:FORMALDEHYDE: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 211, 1987: GRP 2A. NTP 6TH ANNUAL REPORT ON CARCINS, 1991: (SUPDAT) Effects of Overexposure:HLTH HAZ: ACTION LEVEL IS EXPECTED. EXCESS INHAL OF VAP MAY CAUSE NASAL & RESP IRRIT. INGEST: ING 1: MAY CAUSE DIRECT TISSUE IRRIT BUT IS NOT EXPECTED TO CAUSE A SIGNIFICANT TOX RESPONSE. SKIN/EYE: IN G 1: DUST MAY CAUSE IRRIT. ING 2: VAP CONC IS EXPECTED TO BE TOO LOW TO CAUSE ACUTE/CHRONIC IRRIT. EXCESS (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST CONSULT A PHYSICIAN. INGEST: CALL PHYSICIAN. DO NOT INDUCE VOMITING. SKIN: WASH WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF IRRITA TION PERSISTS. EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:TO EXTINGUISH FLAMES, USE WATER SPRAY, CARBON DIOXIDE/DRY CHEM FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. USE WATER TO KEEP COOL & PREVENT REKINDLING. Unusual Fire/Explosion Hazard:MACHINING, SAWING, ROUTING, &/OR SANDING OF PROD PRDCES A CLASS I DUST. SFTY PREC (& PROPER VENT) AS RECOM BY NFPA-68 CLASS I DUSTS SHOULD BE FOLLOWED (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP/PICK UP SCRAP MATERIAL AND PLACE IN DISPOSAL CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:LAMINATES MAY POSSES SHARP EDGES. Other Precautions:AS A CLASS I DUST, SAFETY PRECAUTIONS RECOMMENDED BY NFPA-68 SHOULD BE FOLLOWED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:PROVIDE SUFFICIENT VENT & DUST PICK-UP @ SAW, SANDER, DRILL/ROUTER TO KEEP DUST LEVEL BELOW 10 MG/CUBIC METER TWA/PROVIDE & MAKE MANDATORY THE WEARING OF NIOSH/MSHA APPRVD DUST RESPIRATORS. Ventilation:PROPERLY DESIGNED PARTICULATE CONTROL VENTILATION WILL ALSO PROVIDE FORMALDEHYDE VAP EXPOS CTL. Other Protective Equipment:SAFETY SHOES SHOULD BE WORN WHEN HANDLING OR MACHINING LAMINATES TO PREVENTS CUTS AND ABRASIONS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR/ODOR: CORES; NO ODOR. EXPLO HAZ: TO PVNT THIS/ANY CLASS I DUST FROM PRESENTING AN EXPLO HAZ. HAZ DECOMP: THAN WOOD(COMBUST TOX-NBS PROTOCOL). EXPLAN OF CARCIN: ANTIC TO BE CARCIN. EFTS OF OVERE XP: EXPOS MAY CAUSE IRRIT OF SKIN/EYE, OR TEARING OF EYES. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.35 Solubility in Water:NONE IN NORMAL USE Appearance and Odor:THIN, RIGID SHEET W/COLORED/DECORATIVE/METALLIC SURF(S) & DARK/COLORED (SUPDAT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS/ALKALINE SOULTIONS WILL DESTROY LUSTER OR SURFACE APPEARANCE. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:MAY PRDCE CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA, FORMALDEHYDE &/OR OXIDES OF NITROGEN. NO MORE TOX (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN FOR ENERGY RECOVERY/DISPOSE OF SCRAP LAMINATES AND DUST IN AN APPROVED SANITARY LANDFILL. THIS PRODUCT IS NON-HAZARDOUS UNDER RCRA. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CIMPERIAL 1010, 875 GREEN CAGE:86167 CAGE:86167 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: FOR RECYCLING/SCRAP. CAUTION: MISUSE OF EMPTY CNTNRS CAN BE HAZ. EMPTY CNTNRS CAN BE DANGEROUS IF USED (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: TO STORE TOX, FLAMM OR REACTIVE MATLS. CUTTING/WELDING OF EMPTY CNTNRS MIGHT CAUSE FIRE, EXPLOS/TOXIC (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: FUMES FROM RESIDUES. DO NOT PRESSURIZE OR EXPOSE TO OPEN FLAME/HEAT. KEEP CNTNR CLOSED & DRUM BUNGS IN (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: PLACE. DO NOT REUSE BEFORE COMMERCIAL CLEANING. RTECS #:9999999ZZ Ingred Name:VENT: ARE CLOSE TOGETHER OR VENT IS INADEQ, OPERATORS MAY EXPERIENCE RESP IRRIT. FOR SUCH APPLICATIONS, USE OF (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: SPLASH GUARDS OR MIST COLLECTORS IS RECOMMENDED. IF THERE IS DOUBT ABOUT ACTUAL MIST LEVELS PRESENT, (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: MONITORING SHOULD BE CONDUCTED. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: CREAMS MAY BE TEMPORARY CONTROL MEASURE. CONTACT MFR FOR SPECIFIC RECOMMENDATIONS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXTENDED EXPOS TO MISTS MAY CAUSE UPPER RESP IRRIT. EYES:AT USE DILUTION, CNTCT WILL CAUSE STINGING SENSATION. EYE INJURY MAY RSLT FROM CNTCT W/CONC PROD. SKIN: NOT IRRIT WHEN USED AS DIRECTED & GOOD PERSONAL HYGIENE IS PRACTICED. MILD IRRIT (REDNESS & DRYNESS OF HANDS) MAY BE EXPERIENCED WHEN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: DILUTED PROD HAS BEEN CONTAMD BY CERTAIN OILS, BY DISSOLVED METALS/WHEN MIX RATIO IS TOO STRONG. INGEST: SWALLOWING SMALL QTYS OF PROD AT USE DILUTION MAY CAUSE NAUS OR DIARR. Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN IRRITATION WHERE FURTHER DEFATTING OR SKIN PENETRATION COULD OCCUR. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP). EYES: FLUSH IMMED W/RUNNING WATER FOR AT LEAST 15 MIN, THEN PROMPTLY GET MED ATTN TO CHECK FOR POSS IRRIT. SKIN: WASH W/WATER A S SOON AS POSS. REMOVE SEV CONTAMD CLTHG, INCL SHOES. LAUNDER BEFORE REUSE. IF IRRIT PERSISTS, GET MED ATTN. INGEST: IF CONC/MIX IS SWALLOWED, DO NOT INDUCE VOMIT. DILUTE BY DRINKING WATER OR (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:375F,191C Extinguishing Media:FOAM, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL, COLLECT ON ABSORBENT MATERIAL & DISCARD AS DICTATED BY FEDERAL, STATE AND LOCAL REGULATIONS THAT MAY APPLY. FLUSH AREA THOROUGHLY WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY AS MFR RECOM. AVOID ALL CNTCT OF CONC W/EYES/SKIN. DO NOT SWALLOW. COMBUST LIQ. AVOID OPEN FLAMES, SPK & TEMPS >375F. UNAFFECTED BY FREEZING. Other Precautions:CONTAINS AMINES. DO NOT ADD SODIUM NITRITE OR OTHER NITROSATING AGENTS TO THIS PRODUCT. SUSPECTED CANCER-CAUSING NITROSAMINES COULD BE FORMED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:PRODUCT IS NOT VOLATILE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:FOR MOST APPLICATIONS, NORM SHOP VENT IS ADEQ. HOWEVER, WHEN HIGH MIST LEVELS ARE GENERATED OR WHERE MACHINES (ING 6) Other Protective Equipment:EFTIVE METALWORKING PLANT PROT CLTHG AS APPROP. WHEN PROBS W/SKIN IRRIT OCCUR, USE OF WATER-RESISTANT BARRIER (ING 9) Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD ALWAYS BE FOLLOWED. Supplemental Safety and Health PH: (CONCENTRATE): NA; 5% MIX: 8.8-9.2. FIRST AID PROC: MILK. IMMED CNTCT MD & OBTAIN TREATMENT. WASTE DISP METH: LIST OF WASTE HAULERS FOR YOUR AREA. "EMPTY" CNTNRS WILL CONTAIN RESIDUE WHICH IS NOT CONSIDERED HAZ WASTE UNDER RCRA REGS. DRUMS CAN BE DRAINED TO "DRIP DRY" CNDTN BY INVERSION & CAN BE OFFERED (ING 2) ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:1.0028-1.0128 pH:SUPDAT Evaporation Rate & Reference:LIKE WATER WHEN DILUTED Solubility in Water:MISCIBLE Appearance and Odor:CLEAR LIQUID; SASSAFRAS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZERS. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:SMOKE, FUMES, OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOR USED MIX:DISP PROC MUST COMPLY W/LOC, COUNTY, STATE & FED REGS. IF PRE-TREATMENT IS NEEDED, CHEM EMULSION BREAKING/ULTRAFILTRATION MAY BE USED. CNTCT MFR FOR ASSISTANCE. FOR UNUSED CONC:NOT HAZ AS DEFINED UNDER 40CFR 261. MFR CAN PROVIDE (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EL12-2 SILVER ZINC CELL BATTERY W/MERCURY CAGE:62339 CAGE:62399 CAGE:62339 ============= Composition/Information on Ingredients ============= Ingred Name:SILVER CAS:7440-22-4 RTECS #:VW3500000 OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC OXIDE *95-1* CAS:1314-13-2 RTECS #:ZH4810000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM FUME Ingred Name:MERCURIC OXIDE CAS:21908-53-2 RTECS #:OW8750000 OSHA PEL:0.05 MG/CUM ACGIH TLV:0.1 MG/CUM Ingred Name:POLYSULFONE CAS:25154-01-2 Ingred Name:POTASSIUM HYDROXIDE CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:2 MG/CUM (CEILING) ACGIH TLV:2 MG/CUM (CEILING) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TEFLON ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CONTACT W/POTASSIUM HYDROXIDE MAY BURN TISSUE. INHALATION OF POTASSIUM HYDROXIDE MIST MAY DAMAGE RESPIRATORY TRACT. INGESTION OF POTASSIUM HYDROXIDE CAUSES THROAT & GASTRO-RESPIRATORY BURNS. SKIN CONT ACT W/POTASSIUM HYDROXIDE CAUSES BURNS. Explanation of Carcinogenicity:NONE Effects of Overexposure:POTASSIUM HYDROXIDE - BURNS. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. SKIN: WASH W/WATER. EYES: FLUSH W/WATER. INGESTION: DRINK WATER. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:WEAR SCBA TO PREVENT EXPOSURE TO MERCURY VAPORS WHICH MAY BE LIBERATED DURING A FIRE. Unusual Fire/Explosion Hazard:ACTIVATED BATTERY MAY PROVE A FIRE HAZARD IF EXTERNALLY SHORTED. ================== Accidental Release Measures ================== Spill Release Procedures:FOR POTASSIUM HYDROXIDE SPILL WEAR PROTECTIVE & NEUTRALIZE. FLUSH W/WATER. Neutralizing Agent:WEAK ACID SUCH AS VINEGAR/BORIC ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE DRY BATTERIES AT TEMPS BETWEEN 0-40F. AVOID DIRECT SKIN CONTACT W/POTASSIUM HYDROXIDE. Other Precautions:WET BATTERIES NOT REQUIRED FOR 30 DAYS/LONGER SHOULD BE DISCHARGED AS PER MANUFACTURER'S OPERATING PROCEDURES & STORED AT TEMPS BETWEEN 0-40F. TO REDUCE ELECTROCUTION RISK, ALL ASSOCIATED TOOLS SHOULD BE INSULATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Ventilation:LOCAL EXHAUST Other Protective Equipment:LIQUID RESISTANT APRONS, SAFETY EYE WASH, SHOWER Work Hygienic Practices:REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health DECOMPOSITION PRODUCTS CONT'D: INCOMPLETE BURNING OF POLYSULFONE LIBERATES CO2, HYDROGEN GAS MAY BE RELEASED WHEN TEFLON BURNS. ================== Physical/Chemical Properties ================== Appearance and Odor:CELL: RECTANGULAR CUBE OF CLEAR AMBER COLOR W/MULTIPLE ELECTRODES VISIBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN PEROXIDE, AMINES, REDUCING AGENTS, MOLTEN ALKALI METALS, ALUMINUM, TIN, METALS Stability Condition to Avoid:FIRE & TEMP >1763.6F Hazardous Decomposition Products:TEMP >1763.6F-SILVER OXIDE, POTASSIUM HYDROXIDE + METALS-HYDROGEN GAS, FIRE-MERCURY VAPORS, (SEE SUPPLEMENTAL DATA) Conditions to Avoid Polymerization:STORAGE TEMP >90F ==================== Disposal Considerations ==================== Waste Disposal Methods:SPENT BATTERIES SHOULD BE COLLECTED FOR PRECIOUS METALS RECLAMATIONS IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COPPER-BASED,FILM-INSULATED MAGNET WIRE Preparer's Name:FRANCOIS A LAVALLEE CAGE:5B326 CAGE:5B326 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (DUST & MIST), BRONZE POWDER CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 88-99.5% Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT IRRITATION, METALLIC TASTE IN MOUTH, NAUSEA. SKIN: DISCOLORATION, SENSITIZATION, MUCOUS MEMBRANES IRRITATION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: METAL FUME FEVER. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:COMPATIBLE W/ALL TYPES (A,B,C). AVOID WATER ON MOLTEN METAL. Fire Fighting Procedures:MATCH THE TECHNIQUE TO THE TYPE OF FIRE. Unusual Fire/Explosion Hazard:CONTACT OF WATER W/MOLTEN COPPER CAN CAUSE EXPLOSION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:GENERAL MECHANICAL IF GROUND, HOT-STAKED OR SOLDERED. LOCAL EXHAUST FOR GRINDING, BURINING & MOLTEN CONDITIONS. Supplemental Safety and Health UNDER SOME SOLDERING, HOT-STAKING OR OTHER VERY HIGH TEMPERATURE CONDITIONS, TOLUENEDI-ISOCYANATE (TDI) OR OTHER ISOCYANATE FRACTIONS MAY BE GIVEN OFF. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:4703F/2595C Vapor Pres:<1 Evaporation Rate & Reference:NOT MEASURABLE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER OR COLORED SOLID, W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED ACIDS & BASES. BARE CONDUCTOR SHOULD NOT CONTACT ACETYLENE GAS OR MAGNESIUM. Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:H2O, CO, CO2, OXIDES OF NITROGEN & COMPONENT INGREDIENTS. TOLUENEDI-ISOCYANATE OR OTHER ISOCYANATE FRACTIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. RECYCLE CONDUCTOR, OR SUITABLE LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:V48-039 OMEGA OPACIOUS DENTIN 39 B-4 50 GM BOTTLES CAGE:67251 CAGE:67251 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-4* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:ZIRCONIUM OXIDE, ZIRCONIUM DIOXIDE *96-4* CAS:1314-23-4 RTECS #:ZH8800000 ACGIH TLV:5 MG/CUM Ingred Name:CHROMIUM, CHROMIUM METAL, CHROME (CARCINOGEN BY NTP; IARC GROUP 3) *96-4* CAS:7440-47-3 RTECS #:GB4200000 ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COBALT (ANIMAL CARCINOGEN BY IARC - GROUP 2B) *96-4* CAS:7440-48-4 RTECS #:GF8750000 Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/CUM ACGIH TLV:0.05 MG/CUM Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT CAS:1309-37-1 RTECS #:NO7400000 OSHA PEL:10 MG/CUM ACGIH TLV:5 MG/CUM (FE) Ingred Name:MANGANESE *96-4* CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *96-4* CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:AMORPHOUS SILICA GEL, SILICON DIOXIDE *96-4* CAS:7631-86-9 Ingred Name:TIN *96-4* CAS:7440-31-5 RTECS #:XP7320000 OSHA PEL:2 MG/CUM ACGIH TLV:2.0 MG/CUM Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-4* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:VANADIUM PENTOXIDE*96-4* CAS:1314-62-1 RTECS #:YW2450000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.05 MG/CUM (DUST) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE *96-4* CAS:1344-28-1 RTECS #:BD1200000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:BARIUM *96-4* CAS:7440-39-3 RTECS #:CQ8370000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.5 MG/CUM Ingred Name:BORON OXIDE, TRIOXIDE CAS:1303-86-2 RTECS #:ED7900000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:CALCIUM OXIDE; LIME CAS:1305-78-8 RTECS #:EW3100000 OSHA PEL:5 MG/CUM ACGIH TLV:2 MG/CUM Ingred Name:LITHIUM OXIDE *96-4* CAS:12057-24-8 Ingred Name:MAGNESIUM OXIDE, MAGNESIA CAS:1309-48-4 RTECS #:OM3850000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:POTASSIUM DIOXIDE CAS:12030-88-5 RTECS #:TT6053000 Ingred Name:AMORPHOUS SILICA GEL, SILICON DIOXIDE *96-4* CAS:7631-86-9 Ingred Name:SODIUM OXIDE CAS:1313-59-3 Ingred Name:TIN *96-4* CAS:7440-31-5 RTECS #:XP7320000 OSHA PEL:2 MG/CUM ACGIH TLV:2.0 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Explanation of Carcinogenicity:SEE INGREDIENTS. ======================= First Aid Measures ======================= First Aid:INHALATION: AVOID BREATHING CERAMIC DUST. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AS SOLID WASTE. AVOID BREATHING DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID BREATHING CERAMIC DUST. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NUISANCE DUST MASK RECOMMENDED WHILE GRINDING FIRED CERAMIC. Ventilation:MECHANICAL EXHAUST: RECOMMENDED WHILE GRINDING FIRED CERAMIC. Other Protective Equipment:NOT REQUIRED Work Hygienic Practices:AVOID LICKING CERAMIC APPLICATION BRUSH. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:1760F Evaporation Rate & Reference:NONE Solubility in Water:INSOLUBLE Appearance and Odor:PASTEL COLOR PORCELAINS W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED HYDROFLUORIC ACID Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF SOLID WASTE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PECAN STAIN CAGE:GEMIN CAGE:GEMIN ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 1.76% Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM Ingred Name:2-BUTOXYETHANOL (ETHYLENEGLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 42.80% Other REC Limits:25 PPM (SKIN) OSHA PEL:50 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 14.90% Other REC Limits:375 MG/CUM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 2.89% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ISOBUTYL ACETATE, ESTER CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 3.61% Other REC Limits:150 PPM OSHA PEL:150 PPM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE*93/4* CAS:64742-89-8 Fraction by Wt: 25.97% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:WET NITROCELLULOSE, NITROCELLULOSE, NITRATE CELLULOSE CAS:9004-70-0 RTECS #:QW0975200 Fraction by Wt: 2.91% RTECS #:9999999WG Fraction by Wt: 7.2% RTECS #:9999999VO Fraction by Wt: 6.712% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITAION, SKIN: IRRITATION, DERMATITIS. INGESTION: GASTRONINTESTINAL IRRITAION. INHALATION: NASAL & RESPIRATORY IRRITATION. OVEREXPOSURE TO SOLVENTS MAY CAUSE LIVER, KIDNEY, LUNG & CNS DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: VOMITING, NAUSEA, DIARRHEA. INHALATION: DIZZINESS, WEAKNESS, FATIGUL, NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUNESS. EYES: REDNESS, TEARING, BLURRED VISIONAL. SKIN: REDNESS, DRYNESS, RASH, CRAC HES. Medical Cond Aggravated by Exposure:RESPIRATORY & SKIN SENSITIVITY. ======================= First Aid Measures ======================= First Aid:INHALTION: REMOVE TO FRESH AIR, AID BREATHING EYES: FLUSH IMMEDIATERLY W/LARGE AMOUNTS OF WATER FOR 15 MINUTES. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:40.0 F Lower Limits:.9% Upper Limits:12.1% Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:USE NIOSH APPROVED FULL FACE/SCBA. WATER MAY BE INEFFECTIVE. IF WATERS IS USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG THE GROUND/MAY7 BE MOVED BY VENTILATION & IGNITED BY IGNITION SOURCES, DISTANT FROM HANDLING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP SPILLS W/INERT MATERIAL, SCRAP UP W/NONSPARKING TOOLS. PUT IN COVERED METAL CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS. KEEP AWAY FROM SPARKS/EXCESSIVE HEAT/OPEN FLAMES. TRANSFER BETWEEN CONTAINER THAT HAVE BEEN ELECTRICALLY GROUNDED. Other Precautions:DO NOT TAKE INTERNALLY, CAN NOT BE MADE NONPOISONOUS. AVOID INHALATION/SKIN CONTACT. RELEASE PRESSURE ON CONTAINER SLOWLY. STORE & USE IN WELL VENTILATED AREAS. DO NOT DRAG OR PUNCTURE OR REUSE CONTA INERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NESA/NIOSH APPROVED RESPIRATOR. COMBINATION DUST/VAPOR RESPIRATOR, OR CHEMICAL RESPIRATOR. Ventilation:LOCAL EXHAUST TO MAINTAIN WORK SPACE BELOW TLV Other Protective Equipment:EYEWASH STATION, EMERGENCY SHOWER, AUTO-WATER SPRAY. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOM. SMOKS IN DESIGNATED AREAS ONLY. WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NEVER USE WELDING & CUTTING TORCH ON/NEAR DRUMS BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY. INTERTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING SOLVENTS MAY BE HARMFUL/FATAL. DON'T SPRAY LACQUER PRODUCTS IN THE SAME SPRAY BOOTH W/OXIDIZING STAINS, GLAZES, OR VARNISHES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:167.0-342.5 Vapor Pres:32.80 Vapor Density:> 1 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:95.78 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ALKALINES, STRONG MINERAL ACIDS. Stability Condition to Avoid:HIGH HEAT, SPARKS, FLAMES Hazardous Decomposition Products:OXIDES OF NITROGEN & CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATION. UM1263
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DC-207 BLACK ELECTRICAL/ELECTRONIC ENCAPSULANT CAGE:0ARV9 CAGE:0ARV9 ============= Composition/Information on Ingredients ============= Ingred Name:BENZOPHENONETETRECARBOXYLIC DIANHYDRIDE (BTDA) CAS:2421-28-5 Minumum % Wt:10. Maxumum % Wt:30. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYES: SLIGHT, TEMPORARY MECHANICAL IRRITATION. INHALATION: MECHANICAL IRRITATION OF THE RESPIRATORY PASSAGES. SKIN: PROLONGED/REPEATED EXPOSURE MAY CAUSE IRRITATION. INGESTION: LOW ORAL TOXICITY. Effects of Overexposure:IRRITATION Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN & RESPIRATORY DISORDERS/INDIVIDUALS WHO ARE HYPERSENSITIVE TO SULFONAMIDES. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER WHILE HOLDING EYELIDS OPEN. SKIN: WIPE EXCESS POWDER FROM SKIN. FLUSH W/WATER. FOLLOW BY WASHING W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR & PROVIDE OXYGEN IF BREAT HING IS DIFFICULT. INGESTION: DON'T INDUCE VOMITING. NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER FOG, CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:NONE REQUIRED Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN LEAK IN NATURAL FORM W/SAND/DIRT/INERT MATERIAL. ELIMINATE ALL IGNITION SOURCES. PREVENT RUNOFF INTO STORM SEWERS, DITCHES & WATERWAYS. SWEEP, VACUUM/SHOVEL MATERIALS INTO DISPOSAL CONTAINER, SEAL LID TIGHTLY W/TAPE/LOCKING RING & LABEL PROPERLY. CLEAN UP IMMEDIATELY, OBSERVING PRECAUTIONS INCLUDING ADEQUATE VENTILATION/PERSONAL PROTECTIVE EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED & SEALED WHEN NOT IN USE. STORE IN A COOL (LESS THAN 80F), DRY AREA OUT OF DIRECT SUNLIGHT. HANDLE GENTLY, PRODUCT IN GEOMETRIC FORM CAN BREAK EASILY. Other Precautions:AVOID BREATHING DUST. DON'T BREATHE FUMES WHEN PRODUCT IS IN MOLTEN STATE. AVOID CONTACT W/SKIN, EYES/CLOTHING. MINIMIZE DUST GENERATION & ACCUMULATION. AVOID PHYSICAL CONTACT WHEN MOLTEN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO RESPIRATOR FOR DUST IS REQUIRED IF INGREDIENT EXPOSURE LIMITS ARE NOT EXCEEDED. USE A DUST MASK FOR GENERAL DUST INHALATION PROTECTION. Ventilation:LOCAL EXHAUST VENTILATION NEAR THE SOURCE WHEN PRODUCT IS IN GRANULAR FORM/DURING THE HEAT CURE CYCLE. BUTYL Other Protective Equipment:SAFETY SHOWER, EYE WASH STATION Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:185-212F Vapor Density:NEGLIGIBLE Spec Gravity:1.1-1.7 Solubility in Water:INSOLUBLE Appearance and Odor:SOLID BLACK GEOMETRIC/GRANULAR FORM W/SLIGHT PHENOLIC ODOR Percent Volatiles by Volume:0.6-0.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS; LIQUID OXYGEN Stability Condition to Avoid:NONE Hazardous Decomposition Products:CO, CO2 Conditions to Avoid Polymerization:UPON INTRODUCTION OF HEAT >185F-212F ENDOTHERMIC AT BEGINNING OF REACTION FOLLOWED BY EXOTHERMIC EMISSION. =================== Toxicological Information=================== Toxicological Information:NONE ===================== Ecological Information ===================== Ecological:UNCONTROLLED RELEASES TO SOIL, GROUNDWATER/SURFACE WATERS COULD ENTAIL ACUTE/CHRONIC ECOLOGICAL EFFECTS, DEPENDING ON THE QUANTITY & CONCENTRATION OF SUCH RELEASES. ALL APPROPRIATE MEASURES SHOULD BE TAKEN TO AVOID UNCONTROLLED RELEASES OF THIS MATERIAL TO THE ENVIRONMENT & ANY SPILLS/OTHER UNCONTROLLED RELEASES WHICH MAY OCCUR SHOULD BE CONTAINED & CLEANED UP IMMEDIATELY IAW/SECTION 6. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS RECOMMENDED THAT UNUSED QUANTITIES RESULTING FROM THE USE OF THIS MATERIAL BE REUSED/REINTRODUCED INTO THE PROCESS/RECLAIMED/REGENERATED/OTHERWISE RECYLCED. IF REUSE IS NOT POSSIBLE; BURNED FOR ENERGY RECOVERY/INCINERATED AS PREFERRED MEANS OF DISPOSAL. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE& FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:PLASTIC GRANULES/PREFORMED GEOMETRIC SHAPES. ===================== Regulatory Information ===================== SARA Title III Information:OSHA STATUS: THESE PRODUCTS, AS SOLD, ARE HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. THERMAL PROCESSING & DECOMPOSITION FUMES FROM THESE PRODUCTS MAY BE HAZARDOUS AS NOTED IN SECTIONS 2 & 3. Federal Regulatory Information:RCRA STATUS: THE PRODUCT USER HAS THE RESPONSIBILITY AT DISPOSAL TIME TO DETERMINE IF THE MATERIAL SHOULD BE CLASSIFIED AS A HAZARDOUS WASTE, THESE PRODUCTS, AS SOLD, ARE CLASSIFIED AS RCRA NON-HAZARD OUS WASTE. State Regulatory Information:CALIFORNIA PROPOSITION 65: THESE PRODUCTS CONTAIN NO CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER/BIRTH DEFECTS/OTHER REPRODUCTIVE HARM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BBU-35 CARTRIDGE IMPULSE CAGE:22761 CAGE:22761 ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOTETRAMETHYLENETETRANITRAMINE (HMX) CAS:2691-41-0 RTECS #:XF7450000 Fraction by Wt: 100% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:FUNCTIONING OF DEVICES CAN CAUSE BURNS & SEVERE PHYSICAL TRAUMA. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: STANDARD FIRST AIDE FOR BURNS. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DON'T FIGHT FIRES Fire Fighting Procedures:DON'T FIGHT FIRES. EVACUATE AREA & GUARD AGAINST INTRUDERS. Unusual Fire/Explosion Hazard:DEVICE RELEASES CONSIDERABLE HEAT, GASES, & PARTICLES UPON FUNCTIONING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF HEAT, FLAME, FRICTION, & IMPACT. PICK-UP DEVICES. ======================Handling and Storage ====================== Handling and Storage Precautions:COMPLY W/ALL LOCAL & FEDERAL REGULATIONS FOR STORING & HANDLING CLASS "C" EXPLOSIVE DEVICES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:AS REQUIRED Other Protective Equipment:CONDUCTIVE SHOES Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ELECTRICAL CURRENTS >10 MILLIAMPS SHOULD NOT BE APPLIED TO DEVICE. ================== Physical/Chemical Properties ================== Spec Gravity:>1 Appearance and Odor:YELLOW METAL DEVICE, NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPERATURES >200F, HEAT, FLAME, FRICTION, IMPACT. Hazardous Decomposition Products:OXIDES OF NITROGEN & CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/RCRA & I/A/W LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:31-60059-207 POS ONE CLEANING SOLUTION CAGE:26030 CAGE:26030 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-90% Ingred Name:N-AMYL ACETATE (SARA III) CAS:628-63-7 RTECS #:AJ1925000 Fraction by Wt: 1-5% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS MILDLY IRRITATING TO BODY TISSUES. Effects of Overexposure:EYE:IRRITATION. SKIN:MAY CAUSE IRRITATION WITH PROLONGED/REPEATED CONTACT. INHALED:UNLIKELY DUE TO LOW VOLITILITY. INGESTED:G/I IRRITATION. Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. GIVE ARTIFICIAL RESPIRATION OR OXYGEN IF NEEDED. INGESTED:DO NOT INDUCE VOMITING. GIVE WATER OR MILK. (NOTHING BY MOUTH IF UNCONSCIOUS) GET IMMEDIATE MEDICAL CARE. IF SYMPTOMS PERSIST OR ARE SEVERE,GET MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH INERT MATERIAL AND PLACE IN APPROPRIATE DISPOSAL CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE EXPECTED TO BE NECESSARY. Ventilation:LOCAL MECHANICAL EXHAUST RECOMMENDED BY MFR. Other Protective Equipment:RUBBER APRON IF SPLASHES ARE LIKELY. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health MSDS AND DLSC ARE COVERING THE PRODUCT AS SHOWN HERE; A SOLUTION FOR CLEANING THE POS ONE MACHINERY. THE CTDF FOR THE SAME NSN AT DGSC DESCRIBES P/N 31-600 -202 POS ONE DEVELOPER WHICH CAN BE ACCESSED VIA THE HMIS P/N CROSS REFERENCE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:15 Vapor Density:<1.0 Spec Gravity:1.04 pH:10.8 Solubility in Water:COMPLETE Appearance and Odor:BLUE COLOR-SLIGHT AMYL ACETATE Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR SUGGESTS FLUSH TO DRAIN.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:G4763 GLUCOSE/UREA NITROGEN STANDARD 800/100 MG/DL CAGE:0DK69 CAGE:0DK69 ============= Composition/Information on Ingredients ============= Ingred Name:GLUCOSE Ingred Name:BLOOD UREA NITROGEN ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: HARMFUL, MUCOUS MEMBRANE & UPPER RESPIRATORY IRRITATION. INGESTION: HARMFUL. SKIN: HARMFUL ABSORPTION. EYES: IRRITATION. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:INGESTION: WASH OUT MOUTH W/WATER. SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. EYES: FLUSH W/PLENTY OF WATER SEPARATINGEYELIDS W/FINGERS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL, POWDER, ALCOHOL OR POLYMER FOAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ABSORB ON SAND OR VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Other Precautions:AVOID SKIN & EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROPRITE NIOSH/MSHA APPROVED RESPIRATOR Ventilation:MECHANICAL EXHAUST Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO, CO2, NITROGEN & SULFUR OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX MATERIAL W/COMBUSTIBLE SOLVENT & BURN IN CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BIO-SOLVE-IT CAGE:GO503 CAGE:GO503 ============= Composition/Information on Ingredients ============= Ingred Name:NO HAZARDOUS INGREDIENTS Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST: IRRITATION, NAUSEA. EYE: IRRITATION, REDNESS. SKIN: IRRITATION, REDNESS. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/COOL WATER. INHAL: REMOVE TO FRESH AIR. INGEST: CALL DR. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:122F,50C Lower Limits:0.7 Upper Limits:6.1 Extinguishing Media:DRY CHEMICAL, FOAM, CARBON TETRACHLORIDE. Fire Fighting Procedures:IF MATERIAL IS CONFINED IN A CONTAINER, COOL THE EXTERIOR W/WATER SPRAY. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP ON ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TEMPERATURE BELOW 140F FOR QUALITY CONTROL. Other Precautions:KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:LOCAL EXHAUST. Other Protective Equipment:AS REQUIRED. Work Hygienic Practices:NORMAL. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:339F,171C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:2.0 Vapor Density:4.7 Spec Gravity:0.85 Evaporation Rate & Reference:<1.0 Solubility in Water:EMULSIFIABLE. Appearance and Odor:ORANGE COLOR, W/CHARACTERISTIC ORANGE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ACIDS, PEROXIDES, HALOGENS, VINYL CHLORIDE, IODINE, PENTAFLUORIDE. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE IN ACCORDANCE W/LOCAL/STATE/FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HT LEAK DETECTOR 283 GMS, 20566 CAGE:54968 CAGE:54968 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 14800 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN/EYES: MAY CAUSE IRRITATION. CHRONIC: CAUSES KIDNEY DAMAGE. REPORTED ANIMAL CARCINOGEN. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONTACT MD. SKIN: PROMPTLY WASH WITH MILD SOAP AND LARGE VOLUMES OF WATER. INHAL: IMMEDIATELY MOVE TO FRESH AIR. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TO MAKE AN UNCONSCIOUS PERSON VOMIT. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMITING. CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point:255F,124C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE AREA. ELIMINATE ALL IGNITION SOURCES. FLUSH AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY LOCATION. KEEP AWAY FROM OXIDIZERS. Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ONLY IN WELL VENTILATED AREA. Other Protective Equipment:NOT APPLICABLE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:473F,245C Vapor Pres:0.1 Vapor Density:2.14 Spec Gravity:1.120 Evaporation Rate & Reference:<1 Appearance and Odor:CLOUDY LIQUID WITH MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FD ELECTRONIC CLEANER 100 % FREON TF 1638 A Preparer's Name:J. WITCHER CAGE:JO768 CAGE:54700 CAGE:JO768 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III)/FREON TF CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 80% Other REC Limits:NONE SPECIFIED OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9192 Ozone Depleting Chemical:1 Ingred Name:CHLORODIFLUOROMETHANE CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: 18% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000PPM; 9192 Ozone Depleting Chemical:2 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: < 2% Other REC Limits:NONE SPECIFIED OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALE:MAY CAUSE SUFFOCATION,SHORTNESS OF BREATH,CONFUSION,NARCOSIS,CARDIAC IRREGULARITIES,UNCONSCIOUSNESS OR EVEN DEATH.EYES:CAN CAUSE SLIGHT IRRITATION & CORNEAL INJURY.SKIN:PROLONGED/REPEATED CONTACT CAN CAUSE DEFATTING.ORAL:LOW TOXICITY BUT HAS ASPIRATION HAZARD,GI & CNS EFFECTS.CHRONIC-MAY CAUSE DERMATITIS. Effects of Overexposure:MAY CAUSE SUFFOCATION, SHORTNESS OF BREATH, CONFUSION, NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR EVEN DEATH. CAN CAUSE SLIGHT EYE IRRITATION & CORNEAL INJURY. PROLONGED/REPEATED SKIN CONTAC T CAN CAUSE DEFATTING. ORALLY HAS LOW TOMODERATE TOXICITY AND HAS ASPIRATION HAZARD, GI & CNS EFFECTS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.SKIN:WASH WITH SOAP & WATER.EYE:FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:DO NOT IN DUCE VOMITING.IF CONSCIOUS,DRINK 2 GLASSES OF WATER & IMMEDIATELY SEEK MEDICAL ATTENTION.DO NOT TAKE ADRENALINE OR OTHER SIMILAR CARDIAC STIMULANTS TO TREAT EFFECTS OF OVEREXPOSURE TO THIS PRODUCT. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:AEROSOL CANS MAY ERUPT WITH FORCE AT TEMPERATURES ABOVE 120F. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA WELL AND AVOID BREATHING VAPORS. VAPOR CONCENTRATION WILL BE HIGHEST ALONG FLOOR AND IN LOW LYING AREAS. PICK UP LIQUID ON SUITABLE ABSORBENT AND STORE IN SEALED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN COOL,WELL VENTILATED AREA AWAY FROM HEAT & FLAMES. Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN. THIS PRODUCT FOR INDUSTRIAL USE ONLY. DO NOT USE IN CLOSED SPACE. AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR ORGANIC VAPOR MASK. Ventilation:AS REQUIRED TO CONTROL TLV IN AIR Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES REQUIRE THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE P/N A OR B, SAME NSN. ================== Physical/Chemical Properties ================== HCC:V2 Boiling Pt:=46.7C, 116.F Vapor Density:6.5 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR WATER-WHITE MOBILE LIQUID WITH SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTIVE ALKALI METALS, STRONG ACIDS AND BASES Stability Condition to Avoid:HEAT AND OPEN FLAME Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE, CARBON DIOXIDE AND CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED RECLAIMER OR INCINERATION FACILITY. CONSULT LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IMPREX 4060 LIQUID DETERGENT CAGE:IO707 CAGE:30935 CAGE:IO707 ============= Composition/Information on Ingredients ============= Ingred Name:NONHAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN IRRITATION POSSIBLE TO EXTREMELY SENSITIVE PEOPLE. IF IRRITATION OCCURS SEE PHYSICIAN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:POSSIBLE SKIN IRRITATION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEE PHYSICIAN. INGEST:DO NOT INDUCE VOMITING. CONTACT PHYSICIAN. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: REMOVE TO FRESH AIR. SU PPORT BRTHG (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE W/WATER-FLUSH TO DRAIN. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST: NO SPECIAL VENTILATION. Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:1.05(H*2O=1) Solubility in Water:INFINITE Appearance and Odor:BLUE-NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DILUTE W/WATER-FLUSH TO DRAIN. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0422833 CEFPROZIL (4331683/4331684) CAGE:05545 CAGE:05545 CAGE:15481 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Ingred Name:CEFPROZIL*95-4* CAS:92665-29-7 RTECS #:XI0339000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:PERSONS W/KNOWN/SUSPECTED ALLERGIES TO ANTIBIOTICS. ======================= First Aid Measures ======================= First Aid:NONE ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA FOR SURROUNDING MATERIAL. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:MAY BE SWEPT UP & DISPOSED OF W/NORMAL LABORATORY TRASH. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL LABORATORY CONDITIONS. Ventilation:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Other Protective Equipment:NOT REQUIRED UNDER NORMAL PRODUCT USAGE. Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD BE PRACTICED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:PAPER DISCS FOR VARYING COLORS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:MAY BE DISPOSED OF W/NORMAL LABORATORY TRASH IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARMOR ALL CAR CLEANER CAGE:ARMOR CAGE:ARMOR CAGE:6J703 ============= Composition/Information on Ingredients ============= Ingred Name:PROPASOL P; GLYCOL ETHER P; 1-PROPOXY-2-PROPANOL CAS:1569-01-3 RTECS #:UB9351000 Fraction by Wt: <10% Ingred Name:TETRAPOTASSIUM DIPHOSPHORATE CAS:7320-34-5 RTECS #:JL6735000 Fraction by Wt: <5% Ingred Name:NONYLPHENOL POLYOXYETHYLENE ETHER; POLYOXYETHYLENE NONYLPHENOL; TERGITOL NPX; TRITON N-100; NONIONIC SURFACTANT *96-2* CAS:9016-45-9 RTECS #:MD0900000 Fraction by Wt: <10% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: NON-TOXIC. SKIN: MILD IRRITANT. EYES: MODERATELY IRRITATING. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH W/WATER. EYES: FLUSH THOROUGHLY W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:200F Extinguishing Media:DRY CHEMICAL, FOAM/CO2. Fire Fighting Procedures:USE WATER TO COOL FIRE EXPOSED CONTAINERS. WEAR SCBA W/FACEPIECE OPERATED IN PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT MATERIAL TO COLLECT & CONTAIN FOR SALVAGE &/DISPOSAL. REMOVE SOURCES OF IGNITION & WEAR PROTECTIVE EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL DRY PLACE. Other Precautions:AVOID PROLONGED/REPEATED BREATHING OF VAPOR. AVOID CONTACT W/SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED RESPIRATORY PROTECTIVE EQUIPMENT REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. Other Protective Equipment:SAFETY SHOES, HARD HATS, SUITABLE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH HANDS W/SOAP & WATER AFTER USE. USE STANDARD PRACTICE IN MANY INDUSTRIAL OPERATIONS Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:205F Vapor Pres:2.1 Vapor Density:1 Spec Gravity:1.03 Evaporation Rate & Reference:(BU AC = 1): 0.3 Solubility in Water:97% Appearance and Odor:CLEAR LIQUID W/FRAGRANCE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:SULFUR DIOXIDE, CO2, TRACES OF INCOMPLETELY OXIDIZED CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MACHINE CLEANER & WAX THINNER CAGE:FO206 CAGE:FO206 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM DISTILLATES (NAPHTHA OR RUBBER SOLVENT) CAS:8002-05-9 RTECS #:SE7449000 Fraction by Wt: 9% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 8990 Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 4% OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:INHALING: ANESTHETIC. IRRITATES RESPIRATORY TRACT. MAY CAUSE CNS DEPRESSION. SKIN/EYE: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. INGESTION: CALL PHYSICIAN IMMEDIATELY. DON'T INDUCE VOMITING. EYE & SKIN: FLUSH W/WATER FOR AT LEAST 15 MINUTES. IF IRRITATED, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:28F Lower Limits:1.0% Extinguishing Media:CO2, DRY CHEMICAL OR FOAM Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. KEEP AWAY FROM HEATS/SPARKS/OPEN FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID BREATHING VAPOR. VENTILATE. REMOVE WITH INERT,BSORBENT, NON-SPARKING PRODUCTS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. AVOID FREE FALL OF LIQUID. DON'T FLAME CUT, SAW, BRAZE EMPTY CONTAINER. HAZDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:VENTILATE. IN HEAVY CONCS OF VAPORS, USE SELF-CONTAINER AIR PACK. Ventilation:LOCAL EXHAUST: USE ONLY W/ADEQUATE VENTILATION. Other Protective Equipment:USE AIR-SUPPLIED BREATHING MASKS Supplemental Safety and Health MSDS UNDATED ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:328-360F Vapor Pres:9.1 Vapor Density:4.7 Spec Gravity:.787 Evaporation Rate & Reference:LONG Solubility in Water:MODERATE Appearance and Odor:CLEAR, WATER WHITE--KETONE. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES KEEP AWAY FROM STRONG OXIDIZERS SUCH AS PERMANGANATE Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME Hazardous Decomposition Products:CO ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION, ACCORDING TO AIR SOLLUTION REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1005/6500 YELLOW DEVELOPER, 5R100 CAGE:26921 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: >95% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:STYRENE, ACRYLATE POLYMER CAS:25213-39-2 Fraction by Wt: <5% Ingred Name:YELLOW PIGMENT; ACETYLACETAMIDE DERIVATIVE CAS:12225-18-2 Fraction by Wt: <5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:ORAL(RAT)>15.3 G/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR AS W/EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST. Explanation of Carcinogenicity:NICKEL:GROUP 1(IARC), GROUP 2(NTP). Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN:FLUSH WITH WATER. INHAL:REMOVE FROM EXPOSURE. INGEST:DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, DRY CHEMICAL. Fire Fighting Procedures:AVOID INHALATION OF SMOKE. WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST. MFR EXPOSURE LIMITS FOR PRODUCT:2.5 MG/M3 (TDUST) O.4 MG/M3 (RDUST). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR USE OTHER THAN NORMAL CUSTOMER-OPERATING PROCEDURES, A NIOSH/MSHA APPROVED RESPIRATOR MAY BE REQUIRED. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:5 Appearance and Odor:YELLOW GRANULAR/FAINT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC. AVOID BREATHING SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIFIC WASTE DISPOSAL METHOD REQUIRED. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:08610KUZ-GD ALIPHATIC POLYISOCYANATE #37030 BLACK ZENTHANE Preparer's Name:JANE FREEMAN CAGE:09225 CAGE:09225 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ISOAMYL KETONE SOLVENT CAS:110-12-3 RTECS #:MP3850000 Fraction by Wt: 24.713% Other REC Limits:NONE SPECIFIED OSHA PEL:50 PPM ACGIH TLV:50 PPM Ingred Name:BLACK IRON OXIDE PIGMENT CAS:1317-61-9 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:SILICA PIGMENT (SARA 313) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: 20-30% Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1 MG/M3 Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI)(EXACT PERCENTAGE IS A TRADE SECRET) CAS:28182-81-2 RTECS #:HQ9170000 Fraction by Wt: 20-30% Ingred Name:AROMATIC HYDROCARBONS (MIXTURE OF C8'S TO C10'S) CAS:64742-95-6 Fraction by Wt: 1.19% Other REC Limits:100 PPM = MFR'S Ingred Name:BUTYL ACETATE SOLVENT CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 1.19% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/STEL 200 PPM ACGIH TLV:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXAMETHYLENE DIISOCYANATE MONOMER (SARA 313) CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 0.036% Other REC Limits:NONE SPECIFIED OSHA PEL:0.005 PPM ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VM&P NAPHTHA SOLVENT CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 5.025% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE (SARA 313) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 2.602% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/STEL 150 PPM ACGIH TLV:100 PPM/STEL 150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 0.752% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:CHRONIC: PERMANENT BRAIN/NS/LIVER/KIDNEY/LUNG DAMAGE. RESP SENSITIZATION. SKIN: RED/RASH/SCALING/BLISTER/SESITIZATION. ACUTE: INHAL: RESP TRACT MUCOUS MEMBRANE IRRIT. BRONCHITIS/BRONCHIAL SPASM/PULMON ARY EDEMA/CHEMICAL OR HYPERSENSITIVE PNEUMONITIS/THROAT DRYNESS/CHEST TIGHTNESS/HEADACHE/NAUSEA/FATIGUE/APPETITE LOSS.* Explanation of Carcinogenicity:IARC HAS LISTED SILICA AS A "PROBABLE HUMAN CARCINOGEN", AND CARBON BLACK AS A POSSIBLE HUMAN CARCINOGEN. Effects of Overexposure:*SKIN: IRRIT, RED, RASH, SWELL, SCALING, BLISTER, SENSITIZATION, DEFATTING, DERMATITIS. EYE: IRRIT, TEAR, RED, SWELL, STINGING SENSTION, CORNEAL DAMAGE, INGEST: IRRIT/CORROSION TO MOUTH, STOMACH, DIGE STIVE TRACT (SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMIT, DIARRHEA, CHEMICAL PNEUMONITIS). Medical Cond Aggravated by Exposure:SKIN ALLERGIES AND EXEMA, ASTHMA & OTHER RESPIRATORY AILMENTS, CHEMICAL SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING. CALL DR. EYES: FLUSH IMMED W/LUKE WARM RUNNING WATER >15 MIN, LIFT LIDS. GET MED AID. SKIN: REMOVE CONTAM CLOTHES/WASH BEFORE REUSE. USE SAFETY SHOWER (W ASH W/SOAP/WATER). GET MED AID. INGEST:CALL DR IMMED. DON'T INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:54.0F,12.2C Autoignition Temp:Autoignition Temp Text:450F Lower Limits:0.9 Upper Limits:8.2 Extinguishing Media:CO2, DRY CHEMICAL, FOAM, ALCOHOL FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT W/SCBA. DURING A FIRE, IRRITATING & HIGHLY TOXIC GASES & SMOKE ARE PRESENT FROM THE DECOMPOSITION/COMBUSTION PRODUCTS. Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE W/HEAT OR BURST WHEN CONTAMINATED W/H20 (CO2 RELEASED). DON'T APPLY TO HOT SURFACES, WELD, CUT, OR TORCH DRUM. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC AREA. REMOVE IGNITS. VENT AREA. USE APPROP PROT EQUIPMENT. AVOID BREATHING VAPORS/SKIN CONTACT. DIKE/COVER W/INERT ABSORBENT. ADD DECONTAMINANT, ALLOW TO REACT >10 MIN. CONTAINERIZE, ADD MORE DEC ONTAMINANT. COVER LOSELY FOR 24-48 HRS. Neutralizing Agent:3-8% CONCENTRATED AMMONIA/2% DETERGENT/90-95% H2O OR TERGITOL 20%/WATER 80%. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F OR <32F. STORE LRG AMTS IN BUILDINGS DESIGNED TO COMPLY W/OSHA 1910.106. KEEP AWAY FROM ALL HEAT/MOISTURE. KEEP TIGHTLY CLOSED. Other Precautions:DON'T INGEST. GROUND WHEN POURING. AVOID POURING LIQUID IN EXCESS OF FEW INCHES. VENT, USE PROPER RESP EQUIP. CNTNRS RETAIN RESIDUE AND EXPLOSIVE VAPORS. PROTECT FROM MOISTURE, IF MOISTURE ENTERS CONT AINER PRESSURE CAN BUILD UP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRLINE RESPIRATORS UNLESS AIR SAMPLING SHOWS EXPOSURE BELOW OSHA LIMITS. IF BELOW LIMITS USE CHEMICAL CARTRIDGE RESPIRATORS OR AIRLINE RESPIRATORS. Ventilation:LOCAL EXHAUST VENTILATION TO KEEP AIR CONTAMINANT CONCENTRATION BELOW LIMITS. Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN CONTACT AT A MINIMUM. Work Hygienic Practices:REMOVE & WASH CONTAM CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR SMOKING. Supplemental Safety and Health MORE INFORMATION ON FILE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244 TO 418F Melt/Freeze Pt:M.P/F.P Text:NOT AVAIL. Vapor Pres:15.0 Vapor Density:> AIR Spec Gravity:1.20 pH:NA VOC Grams/Liter:3.49 Viscosity:65-68 KU Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:REACTS WITH WATER Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES, OTHER ACTIVE MATERIALS OR WATER. Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, HYDROGEN CYANIDE, HEXAMETHYLENE DIISOCYANATE, CHLORINE. HYDROGEN CHLORIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO GOVERNMENT REGS. DECONTAMINATE CONTAINERS BEFORE DISPOSAL. ======================= Other Information ======================= ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BRAYCO 363, LUBRICATING OIL CAGE:KO960 CAGE:KO960 DIV CAGE:2R128 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS "THIS PRODUCT IS NOT CONSIDERED HAZARDOUS, NOR DOES IT CONTAIN ANY HAZ INGREDIENTS" PER MFR Fraction by Wt: 100% % Other REC Limits:5 MG/M3 TWA ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BELIEVED TO BE MODERATELY IRRITATING TO EYES, SLIGHTLY IRRITATING TO SKIN. PROLONGED OR REPEATED SKIN CONTACT MAY RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, INHALATION OF VAPORS GENERATED AT HIGH TEMPERATURES OR MISTS MAY IRRITATE RESPIRATORY TRACT. Explanation of Carcinogenicity:PRODUCT CONTAINS NO MATERIALS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:SKIN IRRITATION, DEFATTING, DERMATITUS, RESPIRATORY IRRITATION. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF CLEAN WATER FOR AT LEAST 15 MINUTES. CONTACT A PHYSICIAN IF IRRITATION PERSISTS. SKIN: REMOVE CONTAMINATED CLOTHING. WIPE MATERIAL FROM SKIN. WASH THOROUGHLY WITH SOA P AND WATER. INHALATION: REMOVE FROM AREA OF EXPOSURE. ADMINISTER OXYGEN IF DEEMED NECESSARY. INGESTION: DO NOT INDUCE VOMITING, ASPIRATION HAZARD. CONSULT A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:280F,138C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM Fire Fighting Procedures:USE WATER AS FOG OR SPRAY TO COOL FIRE EXPOSED CONTAINERS. USE SELF-CONTAINED BREATHING APPARATUS IN CONFINED AREAS. Unusual Fire/Explosion Hazard:EMPTY CONTAINERS MAY RETAIN PRODUCT RESIDUE OR VAPORS WHICH CAN IGNITE EXPLOSIVELY. DO NOT CUT, DRILL OR WELD ON OR NEAR FULL OR EMPTY CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT PERMIT PRODUCT TO ENTER STREAMS, SEWERS OR OTHER WATERWAYS. DIKE SPILL AND ELIMINATE LEAK. ABSORB WITH INERT MATERIAL AND STORE IN CLOSED CONTAINERS UNTIL DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MAINTAIN AMBIENT TEMPERATURES. AVOID PROLONGED/REPEATED BREATHING OF VAPORS, MISTS, FUMES. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT STORE NEAT HEAT, FLAME, STRONG OXIDIZERS. MAINTAIN ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CHEMICAL CARTRIDGE RESPIRATOR OR SUPPLIED AIR RESPIRATORY EQUIPMENT AS REQUIRED FOR CONCENTRATIONS EXCEEDING OCCUPATIONAL EXPOSURE RECOMMENDATION. Ventilation:NOT NORMALLY REQUIRED. LOCAL EXHAUST, IN ADDITION TO GENERAL VENTILATION WHEN OCCUPATIONAL EXPOSURE LIMIT IS EXCEEDED. Other Protective Equipment:IMPERVIOUS GARMENTS AS REQUIRED. Work Hygienic Practices:DO NOT WEAR CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE. Supplemental Safety and Health MAY BE DISPOSED OF BY CONTROLLED INCINERATION PER MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:<400F,<204C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:0.88 Evaporation Rate & Reference:NOT DETERMINED Solubility in Water:NEGLIGIBLE Appearance and Odor:BROWN FLUID, SLIGHT PETROLEUM ODOR. Percent Volatiles by Volume:0 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, OPEN FLAMES Hazardous Decomposition Products:SMOKE, FUMES, CARBON DIOXIDE, CARBON MONOXIDE, MINOR AMOUNTS OF VARIOUS HYDROCARBONS AND OXIDES OF SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED, LABELLED, TRANSPORTED AND DISPOSED OF IN CONFORMANCE WITH GOOD ENGINEERING PRACTICES. DISPOSE OF BY METHOD IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULA TIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:01401 55 Kit Part:Y CAGE:10054 CAGE:10054 ============= Composition/Information on Ingredients ============= Ingred Name:POLYESTER RESIN CAS:28679-80-3 Fraction by Wt: <80% Ingred Name:STYRENE, STYRENE MONOMER (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B) *96-2* CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: <35% OSHA PEL:50 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL METHACRYLATE, (MONOMER) CAS:80-62-6 RTECS #:OZ5075000 Fraction by Wt: <10% Other REC Limits:100 PPM OSHA PEL:410 MG/CUM ACGIH TLV:410 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:MAY CAUSE IRRITATION OF SKIN, EYES & ALL PARTS OF RESPIRATORY TRACT. MAY CAUSE DEPRESSION OF THE NERVOUS SYSTEM. ANESTHETIC. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:MAY CAUSE IRRITATION OF SKIN, EYES & ALL PARTS OF RESPIRATORY TRACT. MAY CAUSE DEPRESSION OF THE NERVOUS SYSTEM. ANESTHETIC. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO A WELL VENTILATED AREA, USE OXYGEN/CPR AS REQUIRED. INGESTION: DON'T INDUCE VOMITING. OB TAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:98F Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:WATER, FOG, DRY CHEMICAL, FOAM, CO2 Fire Fighting Procedures:COOL TANKS & DRUMS W/WATER. WEAR SELF CONTAINED BREATHING APPARATUS TO AVOID INHALATION OF SMOKE/VAPORS. Unusual Fire/Explosion Hazard:IF EXPOSED TO ELEVATED TEMPS FOR EXTENDED LENGTH OF TIME SPONTANEOUS EXOTHERMIC POLYMERIZATION MAY OCCUR RESULTING IN VIOLENT RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:EXTINGUISH ALL SOURCES OF FLAME & IGNITION. ABSORB W/INERT MATERIAL SUCH AS VERMICULITE, SAND. SWEEP UP & COLLECT IN CONTAINERS TO BE DISPOSED OF AS SOLID WASTE. WASH AREA W/TRISODIUM PHOSPHATE & WATE R. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE <90F IN COOL, DRY PLACE. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM SOURCES OF HEAT & IGNITION. ISOLATE FROM FOOD & DRINK. Other Precautions:USE EXPLOSION PROOF EQUIPMENT. OPEN CONTAINERS SLOWLY TO RELIEVE ANY INTERNAL PRSSURE. USE W/ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH-APPROVED RESPIRATORS DESIGNED TO REMOVE PARTICULATE MATTER & ORGANIC SOLVENT VAPORS. Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): DRAFT TYPE, DRAWING FUMES AWAY. Other Protective Equipment:PROTECTIVE CLOTHING & SHOES, SAFETY SHOWER, EYE WASH STATION Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:293F (SUPP) Vapor Pres:5.2 (SUPP) Vapor Density:3.6 (SUPP) Spec Gravity:1.11 Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER, HAZY, VISCOUS LIQUID & SHARP ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, PEROXIDES & OTHER OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAME. STORAGE IN OPEN CONTAINERS, PROLONGED STORAGE >100F Hazardous Decomposition Products:CO, CO2, LOW MOLECULAR WEIGHT HYDROCARBONS & ORGANIC ACIDS Conditions to Avoid Polymerization:HEAT, OPEN FLAME/CONTAMINATION W/OXIDIZING AGENTS. PROLONGED STORAGE >100F. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE APPROVED LANDFILL & INCINERATION. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:G-660 CAGE:12904 CAGE:12904 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:EYE,THROAT,SKIN,LUNG IRRITANT;HEADACHE;DIZZINESS;COMA. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WELL. EYES:FLUSH W/WATER.INHAL:REMOVE TO FRESH AIR.GIVE ARTIF.RESP.IF NEEDED.REMOVE CONTAMINATED CLOTHING.INGEST:DO NOT INDUCE VOMIT;TAKE TO DR. IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:18F,-7C SCC Lower Limits:1.1 Upper Limits:2.6 Extinguishing Media:FOAM,DRY CHEM.,CARBON DIOXIDE,WATER FOG Unusual Fire/Explosion Hazard:AVOID FIRE,HEAT,SPARKS,IGNITION SOURCES,STORAGE IN DIRECT SUNLIGHT ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA MECHANICALLY,KEEP FROM FLAME,FIRE,SPARKS, IGNITION SOURCES;DO NOT BREATHE VAPORS;CLEAN UP WITH ABSORBENT MATERIAL;CALL FIRE AND HEALTH AGENCIES;PUT LEAKING CONTAINERS OUTDOORS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED,UPRIGHT FROM FIRE,FLAME,SPARKS,IGNITION SOURCES, DIRECT SUNLIGHT;NO SMOKING;AROUND CONTAINERS WHEN POURING Other Precautions:DO NOT TRANSFER TO UNMARKED CONTAINERS;EXTINGUISH PILOT LIGHTS;USE NON-SPARKING TOOLS; DO NOT APPLY TO HOT SURFACES USE ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MECHANICAL FILTER RESPIRATOR OR CHEMICAL MECHANICAL FILTERS Ventilation:LOCAL EXHAUST Supplemental Safety and Health ALSO CONTAINS CYCLOHEXANONE(5PCT.)NIOSH NO.GW1050000:BOILING RANGE IS 133-281F. (ACETONE-XYLENE) ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:133F,56 C Percent Volatiles by Volume:83.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN AND STRONG OXIDANTS Hazardous Decomposition Products:CARBON DIOXIDE/MONOXIDE Conditions to Avoid Polymerization:TEMP.OVER 150F,HEAT,SPARKS,FLAME,HOT SURFACES. ==================== Disposal Considerations ==================== Waste Disposal Methods:LOCAL,STATE AND FED.LAWS.USE SANITARY LANDFILL;DO NOT INCINERATE CLOSED CONTAINERS;SEAL EMPTY DRUMS TIGHTLY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-P-664,COMP.G,RED QCK DRY RST INHIB PRIMR CAGE:56921 CAGE:56921 ============= Composition/Information on Ingredients ============= Ingred Name:PIGMENTS (SEE SUPP DATA FOR SPECIFIC INGREDIENTS) Fraction by Wt: 41.0% ACGIH TLV:0.5 MG/CUM-MFG Ingred Name:RESIN MODIFIED,DRYING OIL PHTHALIC ALKYD RESIN (AS VEHICLE) Fraction by Wt: 25.8% Ingred Name:SOLVENTS (TYPE UNSPECIFIED) Fraction by Wt: 33%. ACGIH TLV:350 PPM - MFG Ingred Name:ADDITIVES Fraction by Wt: <0.5% ACGIH TLV:0.15 MG/CUM-MFG ===================== Hazards Identification ===================== Effects of Overexposure:VAPOR-ANESTHESIA:HEADACHE,DIZZINESS,NAUSEA. LIQUID MODERATELY IRRITATING TO SKIN & EYES. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE VICTIM TO FRESH AIR & RESTORE BREATHING IF NECESSARY. CALL MD. SKIN: REMOVE MTRL FROM SKIN W/SOAP & WATER. EYE:IMMEDIATELY FLUSH W/WATER AT LEAST 15 MIN. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:80 F TCC Lower Limits:1.2 Upper Limits:6.0 Extinguishing Media:CO*2, DRY CHEM, FOAM-NFPA CLASS B EXTINGUISHERS Fire Fighting Procedures:USE WATER TO COOL EXPOSED CONTAINERS Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLOSED.CLSD CNTNRS MAY EXPLD WHEN EXPSD TO EXTRM HEAT. DO NOT APPLY TO HOT SURFS ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP IMMEDIATELY AND SAFELY DISCARD SATURATED ABSORBENTS IN CASE OF LARGE SPILLS DIKE AREA & PUMP MATERIAL INTO A WASTE TANK. MAINTAIN SUFFICIENT VENTILATION. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F.STORE LARGE QTYS IN BLDGS DESIGNED FOR STORAGE OF NFPA CLASS II FLAMMABLE LIQS. DO NOT STORE NEAR FOOD OR FEED PRODUCTS. Other Precautions:DOT CLASSIFICATION:COMBUSTIBLE. INSULATE CONTAINERS FROM HEAT, SPARKS & OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP. PROT. FOR PARTICULAR EXPOSURE OF CONCERN Ventilation:USE LOCAL EXHAUST TO MAINTAIN CONC. BELOW TLV. Other Protective Equipment:AVOID PROLONGED SKIN CONTACT W/CONTAMINATED CLOTHING Supplemental Safety and Health PIGMENT CONTAINS:10% ZINC CHROMATE,TLV(AS CR)OF 0.05 MG/CUM;50% IRON OXIDE,TLV(FE*20*3,FUME)OF 5 MG/CUM;40%SILICEOUS EXTENDERS.VAPOR DENSITY:HEAVIER THAN AIR. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:245 TO 381F Vapor Pres:3 Spec Gravity:1.2665 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:RED W/NAPHTHA ODOR Percent Volatiles by Volume:62.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, EXCESS ALIPHATIC SLVENT Stability Condition to Avoid:FLAME, HIGH HEAT, MOISTURE. Hazardous Decomposition Products:LIQ PRODUCT MAY EMIT ACRID FUMES & MAY EXPLD W/EXTRM HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HT 424 THIXOTROPIC PASTE,PART B,ADHESIVE Kit Part:Y Preparer's Name:MARVIN FRIEDMAN CAGE:70361 CAGE:70361 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM.OSHA PEL FOR TOTAL DUST,5 MG(AL)/M3 RESP DUST.ACGIH TLV FOR METAL DUST. CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 68.5% Other REC Limits:N/K OSHA PEL:15 MG(AL)/M3 ACGIH TLV:10 MG(AL)/M3 Ingred Name:SILICA,AMORPHOUS.LD50 RAT ORAL >7.5 G/KG.LC50 RAT INHAL >250 MG/M3.ACGIH TLV FROM INTENDED CHANGE LIST,1990. CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 3.30% Other REC Limits:N/K OSHA PEL:6 MG/M3 ACGIH TLV:0.2 MG/M3 RESP DUST Ingred Name:SPILL PROC:IN A WASTE DISPOSAL CONTAINER.FLUSH AREA W/ WATER.HYG PRACT:OR SMOKING,WASH FACE & HANDS WITH SOAP AND WATER. RTECS #:9999999ZZ Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 RAT ORAL >5000 MG/KG, (SEE SUPP) Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:OVEREXPOSURE TO VAPOR DURING HEAT CURING MAY CAUSE INJURY OF THE RESPIRATORY TRACT.REPEATED AND PROLONGED INHALATION OF ALUMINUM POWDER MAY CAUSE SERIOUS LUNG DISORDERS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:VAPORS DURING HEAT CURING MAY CAUSE IRRITATION.SKIN:ALLERGIC REACTION OR PRIMARY SKIN IRRITATION MAY BE PRODUCED BY PROLONGED OR REPEATED DERMAL CONTACT WITH EPOXY RESINS.INGESTION:N/K (FP A/ORNL ).INHALATION:OVEREXPOSURE DURING HEAT CURING MAY CAUSE IRRITATION OF THE RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH CLEAN WATER FOR A MINIMUM OF 15 MINUTES.SEEK MEDICAL ATTENTION IMMEDIATELY .SKIN:IMMEDIATELY WASH AFFECTED AREAS WITH SOAP AND PLENTY OF WATER.REMOVE CONTAMINATED CLOTHING AND SH OES.OBTAIN MEDICAL ATTENTION.DO NOT REUSE CONTAMINATED CLOTHING WITHOUT LAUNDERING.DESTROY OR THOROUGHLY CLEAN SHOES BEFORE REUSE.INGESTION/INHALATION:N/K . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER,CARBON DIOXIDE OR DRY CHEMICAL TO EXTINGUISH FIRES. Fire Fighting Procedures:WEAR SELF-CONTAINED,POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIREFIGHTING PROTECTIVE CLOTHING.SEE EXPOS CONTROL METHODS FOR SPECIAL PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION OR COMBUSTION MAY PRODUCE CARBON MONOXIDE,CARBON DIOXIDE,AMMONIA AND/OR OXIDES OF NITROGEN. ================== Accidental Release Measures ================== Spill Release Procedures:WHERE EXPOS LEVEL IS NOT KNOWN,WEAR NIOSH APPRVD,POSITIVE PRESS,SELF-CONTAINED RESP.WHERE EXPOS LEVEL IS KNOWN,WEAR NIOSH APPRVD RESP SUITABLE FOR LEVEL OF EXPOS.WEAR SAME PROT CLTHG/EQUIP AS IN EXPOS CONTROL METH.SWEEP UP SPILLS & PLACE (SEE ING #3) Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:AVOID SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS BELOW PEL,NO RESP PROT REQ.IF EXPOS EXCEEDS PEL,USE RESP APPRVD BY NIOSH FOR MATL & LEVEL OF EXPOS.A FULL FACEPIECE RESP WILL PROVIDE EYE & FACE PROT.CUTTING/GRINDING/SANDING OF PARTS FABRICA TED AFTER CURING OF THIS MATL (SEE SUPP) Ventilation:IF MATL IS NOT USED IN CLSD SYS,PROVIDE GOOD ENCLOSURE & LOC EXHAUST VENT TO CONTROL EXPOS IF SPRAYING/CURING (SEE SUPP) Other Protective Equipment:APRON,WORKPANTS,LONG SLEEVE WORK SHIRT OR DISPOS COVERALLS ARE RECOM TO PVNT SKIN CONTACT.EYEWASH EQUIP & SFTY SHOWER. Work Hygienic Practices:DO NOT CARRY,STORE OR CONSUME FOOD,BEVERAGE & TOBACCO PROD WHERE THIS MATL IS IN USE.BEFORE EATING,DRINKING (SEE ING #3) Supplemental Safety and Health LD50-LC50 MIX:LD50 RABBIT DERMAL >2000 MG/KG;LC50 RAT INHAL 5 MG/L/4 HR.VENT:AT ELEVATED TEMP.HYG PRACT:AND HANDS W/ SOAP & H*2O.RESP PROT:MAY CREATE RESPIRABLE DUST PARTICLES.RESP PROT APPROP FOR THI S DUST MAY BE REQ.REFER TO THE INGRED FOR POTENTIAL HAZ COMPONENTS IN THE DUST.SEE "GUIDE TO INDUST RESP PROT (NIOSH)". ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:N/K Spec Gravity:1.9,WATER=1 Solubility in Water:NEGLIGIBLE Appearance and Odor:GRAY PASTE;ODORLESS. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION MAY PRODUCE CARBON MONOXIDE,CARBON DIOXIDE,AMMONIA AND/OR OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE & LOCAL REGULATIONS.COORDINATION W/ SUPPORTING INSTALLATION &/OR MACOM ENVIRONMENTAL COORDINATION PRIOR TO DISPOSAL IS RECOMMENDED TO DETERMINE APPROPRI ATE DISPOSAL METHODS .ALUMINUM:SARA LISTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:102 8869 READYMATIC DENTAL DEVELOPER AND REPLENISHER CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA) CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 3% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SODIUM BICARBONATE CAS:144-55-8 RTECS #:VZ0950000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: < 1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IN CONTACT WITH STRONG ACIDS OR IF HEATED, MAY LIBERATE SULFUR DIOXIDE GAS WHICH IS IRRITATING TO RESPIRATORY TRACT. EXPECTED TO BE A LOW INHALATION HAZARD FOR RECOMMENDED HANDLING. EYE CONTACT CAUSES IRRITATION. SKIN CONTACT CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:RESPIRATORY TRACT IRRITATION, EYE IRRITATION, SKIN IRRITATION, ALLERGIC SKIN REACTION. Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE WHEEZING OR CHEST TIGHTNESS. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE TO REMOVE RESIDUA L CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE THE POSSIBILITY OF A SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:B3 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.08 pH:10.1 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, NO ODOR Percent Volatiles by Volume:90% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH < 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE ANDLOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POTASSIUM PERCHLORATE Preparer's Name:ALBERT PARLIK JR CAGE:DO062 CAGE:DO062 CAGE:20865 ============= Composition/Information on Ingredients ============= Ingred Name:PERCHLORIC ACID, POTASSIUM SALT; (1:1); (POTASSIUM PERCHLORATE) CAS:7778-74-7 RTECS #:SC9700000 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: IRRITATED THROAT, CYANOSIS, CONFUSION. SKIN: IRRITATION-MAY CAUSE DERMATITIS WITH PROLONGED EXPOSURE. EYE: REDNESS AND PAIN. MAY CAUSE CONJUNCTIVITIS. INGEST: NAUSEA-VOMITING, DIARRHEA, AND PAI N. PROLONGED EXPOUSRE-ANOREXIA AND WEIGHT LOSS. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:IRRITATION OF EYES AND MUCOUS MEMBRANES. SKIN REDNESS AND DERMATITIS. INGESTION: ABDOMINAL PAIN. THERE ALSO COULD BE CNS DEPRESSION, CONFUSION, AND KIDNEY AND LIVER DAMAGE. Medical Cond Aggravated by Exposure:NONE LISTED. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. KEEP WARM & @ REST-GET MED AID. SKIN: WASH WITH SOAP AND WATER. EYE: WASH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN. INGEST: REMOVE CHEMICAL WITH IPECAC EMESIS/GIVE A CTIVATED CHARCOAL. GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE WATER SPRAY OR FOG. Fire Fighting Procedures:NIOSH/MSHA APPVD SCBA & FULL PROT EQUIP. MOVE CONTR FROM FIRE IF POSS. DO NOT TRY TO SMOTHER. COOL CONTR EXPOS TO FLAMES W/H2O FROM SIDE (SUPP DATA) Unusual Fire/Explosion Hazard:USE FLOODING AMOUNTS OF WATER, APPLY FROM AS FAR AS DISTANCE AS POSSIBLE. EVACUATE TO A RADIUS OF 2500 FEET. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP COMBUSTIBLES AWAY FROM SPILLED MATERIAL. PICK UP WITH CLEAN SHOVEL INTO CLEAN DRY CONTAINER. MOVE FROM SPILL AREA. COVER. LIQUID SPILLS TAKE UP WITH SAND/ABSORB MATL. DIKE AHEAD FOR LARGER SPILLS . KEEP UNNECESSARY PEOPLE AWAY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE POTASSIUM PERCHLORATE IN COOL, DRY, FIRE-RESISTANT BLDG, SEPARATE FROM FLAMM MATLS. H2O HYDRANT & FIRE HOSES SHOULD BE PROVIDED. Other Precautions:AVOID SPILLS & DUSTING. PROVIDE ADEQUATE VENTILATION TO PREVENT DUST FROM SETTLING. DO NOT SKID OR SLIDE. WHEN NOT IN USE, KEEP CONTAINERS TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR TO PROTECT AGAINST DUST. Ventilation:LOCAL EXHAUST ADEQUATE TO KEEP DUST DOWN. Other Protective Equipment:IMPERVIOUS CLOTHING FULL COVER. RUBBER SHOES/ BOOTS. Work Hygienic Practices:RUBBER SHOES OR BOOTS SHOULD BE USED. CLOTHING SHOULD BE CHANGED DAILY. Supplemental Safety and Health BOIL PT: DECOMPOSES @ 400C. FIRE FIGHT PROC: UNTIL WELL AFTER FIRE IS OUT. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:SUPP DATA Melt/Freeze Pt:M.P/F.P Text:752F,400C Spec Gravity:2.53 Solubility in Water:MODERATE Appearance and Odor:WHITE, ODORLESS CRYSTALLINE SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANICS, ACIDS, SULFUR, PHOSPHOROUS, METAL POWDERS & OHTER OXIDIZABLE MATERIALS. Stability Condition to Avoid:MAY CAUSE IGNITION, VIOLENT COMBUSTION OR EXPLOSIONS WHEN IN CONTACT WITH EASILY OXIDIZABLE SUBSTANCES. Hazardous Decomposition Products:CHLORINE AND CHLORINE OXIDES, FLUORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF SOLID FORM, SWEEP UP AND PUT IN METAL CONTR, PUT IN STEEL DRUM & BURY IN AN APPROPRIATE DUMP. IF IN SOLUTION, FLUSH TO SEWER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BREAK-FREE CAGE:MO850 CAGE:65983 CAGE:MO850 ============= Composition/Information on Ingredients ============= Ingred Name:SYNTHETIC HYDROCARBONS (PERCENT COMPOSITION IS BY VOLUME Fraction by Wt: 77% Ingred Name:CHLORINATED SOLVENTS (PERCENT COMPOSITION BY VOLUME) Fraction by Wt: 20% Ingred Name:PETROLEUM DISTILLATES (NAPHTHA OR RUBBER SOLVENT) CAS:8002-05-9 RTECS #:SE7449000 Fraction by Wt: 0.5% OSHA PEL:400 PPM ACGIH TLV:400 PPM; 8990 Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 3% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== Effects of Overexposure:MAY CAUSE SKIN/EYE IRRITATION ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT.CALL DR. THIS IS BECAUSE OF PETROLEUM DISTILLATES.WHEN IN DOUBT CONTACT LOCAL POISON CONTROL CENTER. ===================== Fire Fighting Measures ===================== Flash Point:ABOVE 200F TCC Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE IN LIQUID ================== Accidental Release Measures ================== Spill Release Procedures:USE MOP OR SPONGE TO COLLECT BULK.USE SOLVENT OR DETERGENT TO CLEAN RESIDUE.COLLECT SOLVENT WASTE.WASH DETERGENT WASTE INTO DRAIN. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM OPEN FLAME.PRODUCT CONTAINER CONTAINS CAUTION STATEMENT:CAUTION CONTAINS PETROLEUM DISTILLATES. DO NOT PUNCTURE,INCINERATE Other Precautions:DO NOT STORE ABOVE 120F.KEEP FROM CHILDREN.USE WITH ============= Exposure Controls/Personal Protection ============= Ventilation:AS REQUIRED TO CONTROL MIST IN AIR Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:140F,IBP Spec Gravity:1.02 Appearance and Odor:LIGHT AMBER COLOR,PLEASANT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:COLLECT MOP OR SPONGE WASTE UNTIL IT CAN BE DISPOSED OF WITH REGULAR CONTAMINATED LUBRICANTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:12210 HEKTOEN ENTERIC AGAR Preparer's Name:DALE M. OREM CAGE:06531 CAGE:05545 CAGE:06531 ============= Composition/Information on Ingredients ============= Ingred Name:SUCROSE CAS:57-50-1 RTECS #:WN6500000 Fraction by Wt: 16.8% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 29,700 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION/EYES/SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION/SKIN/EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY Unusual Fire/Explosion Hazard:ORGANIC POWDER CAN BE EXPLOSIVE IF DISBURSED IN AIR IN CERTAIN CENTRATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/PAPER TOWELS OR SWEEP UP & HOLD FOR WASTE DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:USE PRODUCT ACCORDING TO INSTRUCTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL PRODUCT USAGE. Ventilation:PROVIDE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:NONE REQUIRED UNDER NORMAL PRODUCT USAGE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:LIGHT TAN BROWN. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:FIRE ==================== Disposal Considerations ==================== Waste Disposal Methods:WASH DOWN SEWER W/COPIOUS AMOUNTS OF WATER. GELLED & DRY POWDER SHOULD BE DISPOSED OF ACCORDING TO FEDERAL, STATE, & LOCAL REGULATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:75740 TEXSOLVE S/LO CAGE:19630 CAGE:0A9L8 CAGE:19630 ============= Composition/Information on Ingredients ============= Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 100% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: .01-.09% Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RATS LD50 = >5 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:PRODUCT IS PRACTICALLY NON-TOXIC BY INGESTION, BUT IS AN ASPIRATION HAZARD CAUSING LUNG DAMAGE. MAY CAUSE EYE/SKIN IRRITATION. HARMFUL IF INHALED; MAY CAUSE DIZZINESS & DROWSINESS. Explanation of Carcinogenicity:CONTAINS B[71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:EYE:IRRITATION, DISCOMFORT, REDNESS, SWELLING. SKIN:IRRITATION, LOCAL REDNESS & SWELLING. PROLONGED/REPEATED SKIN CONTACT MAY CAUSE MORE SEVERE SYMPTOMS. INHALED:RESPIRATORY IRRITATION, HEADACHE, NAUS EA, DIZZINESS, DROWSINESS, VOMITING, EUPHORIA. INGESTED:(SEVERAL MOUTHFULLS) G/I DISCOMFORT, NAUSEA DIARRHEA, Medical Cond Aggravated by Exposure:PROLONGED/REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:IF IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR. EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. INHALED:REMOVE TO FRES H AIR. AID/RESTORE BREATHING IF NECESSARY. INGESTED:DO NOT INDUCE VOMITING UNLESS ORDERED BY DOCTOR. GET IMMEDIATE MEDICAL CARE. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point:105F,41C Lower Limits:N.D. Upper Limits:N.D. Extinguishing Media:PER NFPA GUIDE, USE DRY CHEMICAL, FOAM, CO2. WATER MAY BE INEFFECTIVE, BUT USE IT TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WHEN HANDLING USE NON-SPARKING TOOLS. EXPLOSIVE VAPOR/AIR MIXTURES MAY FORM. HMIS:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG GROUND OR FLOOR, THEN 'FLASH BACK' FROM A DISTANT IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. AVOID BREATHING VAPOR(USE SCBA). CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATERIAL & SHOVEL UP. PREVENT ENTRY INTO SEWERS & WATERWAYS. AVOID CONTACT WITH SKIN, EYES, CL OTHING. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT & OPEN FLAME. TRANSPORT, HANDLE, AND STORE I/A/W OSHA 1910.106 AND ALL APPLICABLE DOT REGULATIONS. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:KEEP AIRBORNE CONCENTRATIONS AS LOW AS POSSIBLE. IF MIST, VAPOR, DUST IS GENERATED USE NIOSH/MSHA RESPIRATOR AS APPROPRIATE. USE SUPPLIED AIR MASK FOR LARGE SPILLS OR ENTERING TANKS OR CONFINED SPACES . Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS, COVERALLS OR LAB COATS SHOULD BE WORN. LAUNDER WHEN SOILED Work Hygienic Practices:MFR: ?HMIS:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health KEY2:KT ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>321F,>161C Vapor Pres:2.7 MM Vapor Density:4.83 Spec Gravity:0.7781 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; PETROLEUM ODOR. Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY WITH STRONG OXIDIZERS Stability Condition to Avoid:NO INFORMATION GIVEN ON MSDS BY MFR. Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE AND CARBON DIOXIDE AND IRRITATING ALDEHYDES AND KETONES Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT HAS THE RCRA CHARACTERISTIC OF BENZENE TOXICITY AND IGNITABILITY & IF DISCARDED IN ITS PURCHASED FORM WOULD HAVE THE HAZARDOUS WASTE NUMBERS D018 & D001. USE MAY CHANGE THIS CLASSIFICATION. DI SPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:876 5315 RP FIXER AND REPLENISHER XF1, WORKING SOLUTION CAGE:5K871 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85-90% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:ALUMINUM SULFATE CAS:10043-01-3 RTECS #:BD1700000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM BISULFITE (CERCLA) CAS:10192-30-0 RTECS #:WT3595000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES:NO SPECIFIC HAZARD KNOWN.MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HNDLG. INGEST:EXPECTED TO BE LOW INGESTION HAZ ARD. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:TRANSIENT EYE IRRIT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR. GET MED ATTN IF SYMPTONS PERSIST. EYES:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER. SYMPTOMS OCCUR GET MED ATTN. SKIN:WASH W/SOAP & WATER. GETMED ATTN IF SYMPTOMS OCCUR. INGEST:DRINK 1-2 GLASSES OF WATER. SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE,NON-COMBUST Autoignition Temp:Autoignition Temp Text:NP Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB W/VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTILATION.KEEP FROM CONTACT W/OXIDIZING MATLS.KEEP CNTNR TIGHTLY CLSD.KEEP AWAY FROM INCOMPA SUBSTANCES. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYEBATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HNDLG.GOOD INDUSTRIAL HYG PRAC TO MIN EYE/SKIN CONTACT. Supplemental Safety and Health PH:4.2-4.5. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.069 pH:SUPPLE Viscosity:NP Evaporation Rate & Reference:NP Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, ODORLESS Percent Volatiles by Volume:85-90 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NITROGEN OXIDES (NOX), SULFUR DIOXIDE, AMMONIA, CHLORAMINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL/STATE/LOCAL LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. CHEM SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III SARA/40CFR372:NONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROGEN PEROXIDE SOLUTION 50% H2O2 Resp. Party Other MSDS Num.:M00478 CAGE:91224 Contract Num:SP0450-99-M-C715 CAGE:2X264 CAGE:91224 CAGE:4T252 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN PEROXIDE (SARA III) CAS:7722-84-1 RTECS #:MX0900000 Minumum % Wt:45. Maxumum % Wt:55. Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:1 PPM; 9394 Ingred Name:OTHER COMPONENTS (TYPE NOT SPECIFIED) < Wt:.1 Other REC Limits:NONE RECOMMENDED Ingred Name:DEMINERALIZED WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:45. Maxumum % Wt:55. Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE-CAUSES EYE BURNS. SKIN-CAUSES BURNS. INGESTION-MAY CAUSE BURNS OF THE MOUTH AND ESOPHAGUS, ABDOMINAL PAIN, DEATH. HYDROGEN PEROXIDE DECOMPOSES IN THE BOWEL BEFORE ABSORPTION YIELDING ALRGE VOLUMES OF OXYGEN WHICH MAY CAUSE THE BOWEL TORUPTURE. INHALATION-CAUSES SEVERE IRRITATION OF RESPIRATORY TRACT. Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY OSHA LISTED CARCINOGENS. IARC GROUP 3: NON-CLASSIFIABLE. THIS PRODUCT DOES NOT CONTAIN ANY NTP LISTED CARCINOGENS. Effects of Overexposure:NONE REPORTED. Medical Cond Aggravated by Exposure:PRE-EXISTING: EYE CONDITIONS, SKIN CONDITIONS, RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH EYE WITH WATER FOR 15MINS.CALL A PHYSICIAN. SKIN: WASH SKIN WITH PLENTY OF WATER FOR 15 MIN. REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN IMMEDIATELY. INGEST: DO NOT INDUCE VOMI TING. GIVE 1-2 GLASSES OF WATER. CALL PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALE: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NECESSARY. CALL PHYSICIA N. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROPIRATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MAY REACT VIOLENTLY WITH; COMBUSTIBLE MATERIALS, REDUCERS ALCOHOLS. CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL ORGANIC MATERIALS, METALS AND FUELS FROM THE AREA. COVER WITH AN INERT MATERIAL SUCH AS SAND. SWEEP UP MATERIAL. WORK IN AN APPROVED FUME HOOD, DILUTE WITH A LARGE EXCESS OF WATER. ADD GRAD UALLY, WITH AQUEOUS METABISULFITE. MONITOR THE TEMPERATURE, ACIDIFY THE SOLUTION. WHEN THE REACTION IS COMPLETE, CHECK AND ADJUST THE PH ( 6-9). FILTER TO REMOVE SOLIDS. Neutralizing Agent:AQUEOUS SODIUM METABISULFITE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM: OXIDIZABLE MATERIALS, COMBUSTUBLE MATERIALS. STORE AWAY FROM: ALKALIES, METALS, REDUCERS. AVOID CONTAMINATION BY ORGANIC MATERIALS. PROTECT FROM: EXPOSURE TO DIRECT SUNLIGHT. Other Precautions:HANDLING: AVOID CONTACT WITH EYES, SKIN, CLOTHING. DO NOT BREATHE MISTS OR VAPORS. WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:LABORATORY FUME HOODS. Other Protective Equipment:HAVE AN EYEWASH STATION NEARBY. HAVE A SAFETY SHOWER NEARBY. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. LAB COATS. Work Hygienic Practices:AVOID CONTACT WITH: EYES, SKIN AND CLOTHIG. DO NOT BREATHE MIST/VAPOR. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEEP AWAY FROM: COMBUSTIBLE MATERIALS, ALKALIES, OXIDIZABLE MATERIALS. ================== Physical/Chemical Properties ================== HCC:D3 Boiling Pt:=113.9C, 237.F Melt/Freeze Pt:M.P/F.P Text:N/D Vapor Pres:18.3 MMHG @30 Vapor Density:N/D Spec Gravity:1.196 pH:1-3 Evaporation Rate & Reference:<1, REF NOT GIVEN Solubility in Water:VERY SOLUBLE Appearance and Odor:CLEAR, COLORLESS, SHARP ODOR, LIQUID. Corrosion Rate:N/D ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT VIOLENTLY IN CONTACT WITH: ALKALIES REDUCERS, COMBUSTIBLE MATERIALS, FLAMMABLE LIQUIDS. Stability Condition to Avoid:EVAPORATION, EXPOSURE TO DIRECT SUNLIGHT, HEAT. Hazardous Decomposition Products:DECOMPOSITION FORM OXYGEN THAT WILL SUPPORT COMBUSTION. =================== Toxicological Information=================== Toxicological Information:DERMAL TOXICITY DATA: ALBINO RAT DERMAL LD50=4060 MG/KG (90% H2O2). MUTATION DATA: CYTOGENETIC ANALYSIS - HUMAN - 20 UMOL/L, DNA DAMAGE - RAT LYMPHOCYTES - 50 UMOL/L. INGREDIENT TOXICOLOGICAL DATA: HY DROGEN PEROXIDE 90%: ALBINO RAT LC50-2G/M3 N(4 HOUR EXPOSURE); HYDROGEN PEROXIDE 90%; ORAL MOUSE LD50=2 G/KG. ===================== Ecological Information ===================== Ecological:CHANNEL CATFISH: 96 HOURS LC50=37.4 MG/L, FATHEAD MINNOW: 96 HOURS LC50=16.4 MG/L, DAPHNIA MAGNA: 24 HOURS EC50=7.7 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY CONTAINERS: RINSE THREE TIMES WITH AN APPROPIATE SOLVENT. DISPOSE OF EMPTY CONTAINER AS NORMAL TRASH. THSES GUIDELINES ARE BASED ON FEDERAL REGULATIONS AND MAY BE SUPERCEDED BY MORE STRIGENT STA TE OR LOCAL REQUIREMENTS. PLEASE CONSULTYOUR LOCAL ENVIRONMENTAL REGULATORS FOR MORE INFORMATION. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: HYDROGEN PEROXIDE, AQUEOUS SOLUTION (50% PEROXIDE), HAZARD CLASS, 5.1, SUBSIDIARY RISK, 8, ID NUMBER, UN 2014, PACKING GROUP, II. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT MEETS THE CRITERIA FOR A HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZARD COMMUNICATIONS STANDARD (29 CFR 1910.1200). SARA TITLE III SECTION 311/312 CATEGORIZATION (40CFR370): IMMEDIATE (ACUT E) HEALTH HAZARD, FIRE HAZARD. SARA TITLE III SECTION 313 (40 CFR 372): THIS PRODUCT DOES NOT CONTAIN ANY CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF SARA. Federal Regulatory Information:TSCA LISTED: YES. TSCA CAS NUMBER: 7722-84-1. State Regulatory Information:CALIFORNIA PROP. 65: NO PROP. 65 LISTED CHEMICALS ARE PRESENT IN THIS PRODUCT. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SOLDER FLUX REMOVER; 22-270 Preparer's Name:V. HAGEMAN CAGE:EO177 CAGE:72653 CAGE:EO177 ============= Composition/Information on Ingredients ============= Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 82% OSHA PEL:500 PPM;1000 PPM, C ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 15% OSHA PEL:400 PPM;500 PPM STEL ACGIH TLV:400 PPM;500 PPM STEL Ingred Name:CARBON DIOXIDE; (CARBON DIOXIDE PROPELLANT) CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 3% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LABORATORY ANIMALS AND COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAIND ICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . (EFTS OF OVEREXP) Explanation of Carcinogenicity:DICHLOROMETHANE: GRP 2B,IARC, VOL 7, P.194, 1987; ANTIC TO BE CARCIN, NTP 6TH ANNUAL RPT ON CARCINOGENS, 1991. Effects of Overexposure:HLTH HAZ:SKIN & EYES:DERMATITIS, CONJUNCTIVITIS. INGEST:NAUSEA, CARDIAC IRREGULARITIES. INHAL:HEADACHE, DIZZINESS, NARCOSIS, DEPRESSION, NAUSEA, SHORTNESS OF BREATH, CARDIAC IRREGULARITIES, UNCONSCIOU SNESS, DEATH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. CONSULT MD. SKIN:WASH W/SOAP & WATER. INHAL:FRESH AIR, OXYGEN, ARTIFICIAL RESPIRATION. CONSULT MD (NO EPINEPHRINE). INGEST:DO NOT INDUCE VOMITING. CONSULT M D (NO EPINEPHRINE). ===================== Fire Fighting Measures ===================== Extinguishing Media:CHEMICAL FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR PRESSURE DEMAND SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE EQUIPMENT Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE . TOXIC FUMES GENERATED BY EXPOSURE TO FLAME OR FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA WELL. PICK UP W/AN INERT ABSORBENT MATERIAL. STORE IN METAL CONTAINER. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM FIRE/FLAME. AVOID PROXIMITY W/STRONG OXIDIZERS & LIGHT METALS. STORE IN A COOL, DRY AREA. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED SCBA OR CHEMICAL CARTRIDGE RESPIRATOR. Ventilation:LOCAL EXHAUST & MECHANICAL AS REQUIRED TO MEET TLV'S. Other Protective Equipment:APRON IF NECESSARY Work Hygienic Practices:N/K Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:V3 Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:270 Vapor Density:3.2 Spec Gravity:1.23 Evaporation Rate & Reference:11 Solubility in Water:PARTIAL Appearance and Odor:CLEAR LIQUID - ALCOHOL ODOR Percent Volatiles by Volume:100 Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AL, BA, LI, SN, NAK ALLOYS, TI, STRONG OXIDIZERS. Stability Condition to Avoid:EXTREME HIGH TEMPERATURES. Hazardous Decomposition Products:HCL, PHOSGENE . PHOSGENE, CHLORINE COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . LICENSED INCINERATORS OR RECLAIMER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HALON 1211 BROMOCHLORODIFLUOROMETHANE CAGE:54905 Contract Num:SP0450-99-M-J063 CAGE:54905 ============= Composition/Information on Ingredients ============= Ingred Name:BROMOCHLORODIFLUOROMETHANE CAS:353-59-3 RTECS #:PA5270000 = Wt:100. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS NOT KNOWN TO CAUSE CHRONIC ILLNESS. Effects of Overexposure:IN AN OXYGEN DEFICIENT ENVIRONMENT, THIS PRODUCT MAY CAUSE MILD SKIN IRRITATION, MODERATE EYE IRRITATION, DIZZINESS, UNCONSCIOUSNESS AND DEATH UNDER SOME CIRCUMSTANCES. ======================= First Aid Measures ======================= First Aid:SKIN EXPOSURE-IN CASE OF FROSTBITE, PLACE THE FROST BITTEN PART IN WARM WATER OR WRAP AFFECTED PARTS GENTLY IN BLANKETS. EYE EXPOSURE- SEEK IMMEDIATE MEDICAL ATTENTION. INHALATION-IF GAS IS INHALED, R EMOVE VICTIM TO FRESH AIR. IF NECESSARY, USE TRAINED PERSONNEL TO ADMINISTER SUPPLEMENTAL OXYGEN AND ARTIFICIAL RESPIRATION TO SUPPORT VITAL FUNCTIONS. VICTIM AND RESCUERS MUST SEEK IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:NONE. PRODUCT IS A FIRE EXTINGUISHING AGENT. Fire Fighting Procedures:STRUCTURAL FIRE FIGHTERS MUST WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. KEEP UNUSED CYLINDERS COOL USING A WATER SPRAY. WHEN INVOLVED IN A FIRE CYLINDERS MAY RUPTURE VIO LENTLY, CAUSING HIGH-PRESSURE RELEASE OF GAS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: DECONTAMINATE AREA WITH SOAPY WATER. COLLECT ALL RINSATES AND PLACE IN A DOUBLE PLASTIC BAG AND RESISTANT SUIT AND BOOTS, HARD HAT AND SELF CONTAINED BREATHING APPARATUS. FOLLOW STATE AND LOCAL REGULATIONS FOR DISPOSAL OF LARGE NONRECLAIMABLE SPILLS. ======================Handling and Storage ====================== Handling and Storage Precautions:FOLLOW REASONABLE AND SAFE PRACTICES. AVOID GETTING CHEMICALS ON YOU OR IN YOU. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT EXPECTED TO BE NEEDED. MAINTAIN OXYGEN LEVELS OF MINIMUM OF 19.5% IF BELOW 19.5% OXYGEN, USE SUPPLIED AIR RESPIRATORY PROTECTION. AT CONCENTRATIONS ABOVE 2% EXPOSURE TO HALON 1211 CAN PRODUCE DI ZZINESS, IMPAIRED COORDINATION AND CARDIAC EFFECTS. Ventilation:USE WITH ADEQUATE VENTILATION. USE FAN OR VENT TO OUTSIDE. Other Protective Equipment:NONE EXCEPT FOR LARGE SPILLS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:=-3.3C, 26.F Vapor Pres:778 MM Vapor Density:5.7 Spec Gravity:1.83 Solubility in Water:NOT SOLUBLE. Appearance and Odor:COLORLESS GAS OR LIQUID,VERY FAINT,SWEET ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACTIVE METALS SUCH AS POWDERED ALUMINA & MAGNESIUM. Hazardous Decomposition Products:WHEN DISCHARGED ON A FIRE, BROMIDE IONS, HALOGEN COMPOUNDS, HALOGEN ACIDS. ONLY A FEW PPM CREATES AN UNPLEASANT, ACID ODOR. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW STATE AND LOCAL REGULATIONS FOR DISPOSAL OF LARGE NON-RECLAIMABLE SPILLS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:120975 URETHANE ACCELERATOR CAGE:PRATT CAGE:PRATT CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (IARC CARC- GROUP 3) *97-1* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE, 1-METHOXY-2-PROPANOL ACETATE CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 45% Ingred Name:DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE CAS:88917-22-0 Fraction by Wt: 5% Ingred Name:DIBUTYLTIN DILAURATE, URETHANE CATALYST *97-1* CAS:77-58-7 RTECS #:WH7000000 Fraction by Wt: <5% Other REC Limits:0.1 MG/CUM (SN) OSHA PEL:0.1 MG/CUM (SN) ACGIH TLV:0.1 MG/CUM, SN(SKIN) Ingred Name:ACETIC ACID, ETHYL ESTER, ETHYL ACETATE *97-1* CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 30% Other REC Limits:400 PPM OSHA PEL:1400 MG/CUM ACGIH TLV:1400 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL, SYNASOL *97-1* CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 5% Other REC Limits:1900 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: GI IRRITANT. ASPIRATION INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS, CAN BE FATAL. INHALATION: NOSE/THROAT IRRITANT, CNS DEPRESSION. EYES/SKIN: SEVERE IRRITATION. TOLUENE: REPEATED OVEREXPOSU RE MAY CAUSE LIVER DAMAGE. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, HEADACHES, DIZZINESS, CONFUSION ======================= First Aid Measures ======================= First Aid:INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, GIVE CPR. KEEP WARM & QUIET. EYES: FLUSH W/LARGE AMOUNTS OF WATER, CONTINUE FOR 15 MINS. SKIN: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: TREATMENT REQUIRED SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS & CLINICAL CONDITIONS. ===================== Fire Fighting Measures ===================== Flash Point:24F Lower Limits:1.7 Upper Limits:19 Extinguishing Media:CO2, DRY CHEMICAL/ALCOHOL FOAM. LARGE: POLYMER FOAM. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL EXPOSED CONTAINERS WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:WARNING, FLAMMABLE. OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. AUTOIGNITION TEMP: 572F. ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE IGNITION SOURCES. DIKE/CONTAIN LEAK W/INERT MATERIAL. TRANSFER LIQUID TO COVERED METAL CONTAINERS FOR RECOVERY/DISPOSAL/REMOVE W/INERT ABSORBENT W/NON-SPARKING TOOLS. A VOID CONTAMINATION OF SEWERS/STREAMS/GROUNDWATERS. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >115F. STORE LARGE QUANTITIES IN COMPLIANCE W/OSHA 29CFR1910.106. CLOSED CONTAINER AFTER EACH USE. DON'T WELD/BRAZE/CUT ON EMPTY CONTAINER Other Precautions:CONTAINERS SHOULD BE GROUNDED & BONDED TO THE RECEIVING CONTAINER. DON'T TAKE INTERNALLY. EMPTY CONTAINERS MUST NOT BE WASHED & RE-USED FOR ANY PURPOSE. NEVER USE PRESSURE TO EMPTY. DRUM ISN'T A PRESS URE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESTRICTED AREA: NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR. WHEN SPRAYING, USE A MECHANICAL PREFILTER. CONFINED AREA: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR. IF TLV IS EXCEEDED, A PROPERLY FIT TED NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST: IN SUFFICIENT VOLUME & PATTERN SO AS TO MAINTAIN EXPOSURES BELOW NUSIANCE DUST LIMITS & PEL. Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:167F-408F Melt/Freeze Pt:M.P/F.P Text:-50F Decomp Temp:Decomp Text:1832F Vapor Pres:73 Vapor Density:>1 Spec Gravity:0.9 pH:4-7 VOC Grams/Liter:7.59 Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID W/SOLVENT ODOR Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, ALKALINE MATERIALS, ACETYL CHLORIDE Stability Condition to Avoid:EXCESSIVE HEAT >115F & SOURCES OF IGNITION Hazardous Decomposition Products:BY BURNING/HEATED BY WELDING/CUTTING: SMOKE, CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. RCRA HAZARDOUS WASTE NUMBER D001. FLAMMABLE LIQUID UN1263. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VINYL STRIPPABLE COATING, 8040 Preparer's Name:ROBERT E. BAYTON CAGE:92381 CAGE:92381 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 51-70% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIALKYLPATALATE OF C*9; (DIALKYL PHTHALATE) CAS:39393-37-8 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:5 MG/M3 (MFR) Ingred Name:ACETIC ACID, VINYL ESTER, POLYMER WITH CHLOROETHYLENE; (VINYL CHLORIDE/VINYL ACETATE COPOLYMER) CAS:9003-22-9 RTECS #:AK0950000 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALKYD RESIN (SOLUTION) CAS:68188-68-1 Fraction by Wt: 1-10% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 1-10% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYDROCARBON PROPELLANT (PROPANE/ISOBUTANE); (LIQUIFIED PETROLEUM GAS, SWEETENED) CAS:68476-86-8 Fraction by Wt: 11-30% OSHA PEL:N/K ACGIH TLV:1000 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:PRODUCES NARCOSIS & IRRIT OF NOSE, THROAT & RESP TRACT. INGEST:SLIGHTLY TOXIC, CAN CAUSE NARCOSIS. EYE CONT:LIQ & VAPS ARE IRRIT. LIQ MAY CAUSE INJURY. SKIN CONT:RPTD/PRLNG CONT CAN CAUSE DRYING. DERM MAY OCCUR W/PRLNG CONT. SKIN ABSORPTION:NOT ESTABLISHED. INTENTIONAL MISUSE BY DELIB CONC (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:VAPS & INHALING CONTENTS CAN BE HARMFUL/FATAL. CHRONIC:NOTE:TOLUENE APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL REPRO HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNIN G LATEST HAZ LIST INFO & SAFE HANDLING & EXPOSURE INFO . Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN & RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:CALL MD. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OR UNTIL IRRITATION SUBSIDES. SKIN:REMOVE ALL CONTAMINATED CLOTHING. WASH SKIN W/SOAP & WATER. INHAL:REMOVE FROM EXPOSURE IMMEDIATELY. IF BREATHING IS IRREGULAR OR STOPPED, BEGIN ARTF RESP & ADMINISTER OXYGEN. INGEST:DO NOT INDUCE VOMITING. DRINK PLENTY OF WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<20F,<-7C Lower Limits:1.8% Upper Limits:9.5% Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:TREAT AS CYLINDERS OF COMPRESSED GAS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF IGNITION. CLEAN UP W/INERT MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AEROSOL CNTNR:DO NOT STORE IN DIRECT SUNLIGHT, NEAR OPEN FLAMES/AT TEMPS EXCEEDING 120F. DO NOT SMOKE WHILE SPRAYING. USE ONLY AS DIRECTED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE I/A/W 29 CFR 1910.134. Ventilation:LOCAL EXHAUST IS ADEQUATE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . PROT CLTHG & EQUIP: SEE 29 CFR 1910.132 & 133. Work Hygienic Practices:WASH SKIN W/SOAP & WATER. Supplemental Safety and Health VP:AEROSOL CONTAINER 45-50 PSIG. ================== Physical/Chemical Properties ================== Vapor Pres:SUPP DATA Vapor Density:>1 Spec Gravity:<1 Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:SLIGHTLY Appearance and Odor:BLUE; ACETONE LIKE ODOR. Percent Volatiles by Volume:>95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, CHLORINATED HYDROCARBONS IN THE PRESENCE OF ALKALIES. Stability Condition to Avoid:OPEN FLAMES, SPARKS, ELECTRICAL ARCS. Hazardous Decomposition Products:CARBON DIOXIDE & CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. AEROSOL CNTNR:DO NOT PUNCTURE OR INCINERATE. EMPTY CONTAINERS MAY BE DISPOSED OF THRU NORMAL CHANNELS. FULL/PARTIALLY FILLED CNTNRS ARE CONSIDERED HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DAVIDSON MARKING SYSTEM BLUE CAGE:0MJW3 CAGE:0MJW3 ============= Composition/Information on Ingredients ============= Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY ACGIH, NTP, IARC-GROUP 2A) *93-4* CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 1% ACGIH TLV:0.37 MG/CUM IC (2A) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION: IRRITAITON. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH THOROUGHLY W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, WATER, ALCOHOL FOAM, DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB MATERIAL W/ABSORBENT & DISPOSE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID BREATHING DRIED-DOWN DUST. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): SUFFICIENT TO KEEP BELOW TLVS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. USE GOOD LABORATORY HYGIENE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:BLUE LIQUID SOLUTION W/PUGENT FORMALDEHYDE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANAEROBIC ADHESIVE/SEALANT GRADE CV Preparer's Name:ENVIRON. HEALTH & SAFETY CAGE:4Z400 CAGE:4Z400 ============= Composition/Information on Ingredients ============= Ingred Name:"NOT HAZARDOUS" Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ORGANIC PEROXIDE HAS BEEN REPORTED TO CAUSE TUMORS IN EXPERIMENTAL ANIMALS WHEN INJECTED UNDER THE SKIN. THE LOW CONCENTRATION (<5%) CONTAINED IN THE PRODUCT SHOULD PRESENT NO DANGER WHEN USED PROPERL Y UNDER NORMAL CONDITIONS. Effects of Overexposure:PROLONGED SKIN CONTACT MAY CAUSE DERMATITIS IN SENSITIVE INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:SKIN AND EYE CONTACT: FLUSH WITH WATER. INGESTION: KEEP CALM, REMOVE TO FRESH AIR. DO NOT INDUCE VOMITING. OBTAIN MEDICAL ASSISTANCE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>250F,>121C Autoignition Temp:Autoignition Temp Text:> 350F Extinguishing Media:CO2, FOAM, DRY CHEMICALS Fire Fighting Procedures:AIR MASK AND PROCEDURES FOR FIGHTING CHEMICAL FIRES Unusual Fire/Explosion Hazard:CONTAINS ORGANIC PEROXIDE ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE GOOD VENTILATION. AVOID EYE AND SKIN CONTACT. SOAK UP SPILL WITH EARTH, SAND, OR ABSORBENT PRODUCT (ZORBAL). RECOVER IN CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 80F FOR PROLONGED SHELF LIFE. STORE IN ORIGINAL CONTAINER. Other Precautions:AVOID PROLONGED SKIN CONTACT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECESSARY, BUT PRODUCT SHOULD BE USED IN AREAS OF GOOD VENTILATION. Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>300F,>149C Decomp Temp:Decomp Text:>350F,>177C Vapor Pres:< 5 @ 30 F Spec Gravity:1.1 Viscosity:200 CPS Solubility in Water:PARTIAL Appearance and Odor:BLUE LIQUID, LOW ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AND REDUCING AGENTS Hazardous Decomposition Products:CO, CO2, NITROUS OXIDES Conditions to Avoid Polymerization:TEMPERATURES OVER 120F ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE & FEDERAL ANTI-POLLUTION AND WASTE DISPOSAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RP 3215-2 RESIN CAGE:EO949 CAGE:02684 CAGE:EO949 ============= Composition/Information on Ingredients ============= Ingred Name:IRON ION (FE +2) CAS:15438-31-0 RTECS #:NO6925000 OSHA PEL:1 MG/M3 (FE) ACGIH TLV:1 MG/M3 (FE); 8990 Ingred Name:CALCIUM CARBONATE RTECS #:EU9580000 ACGIH TLV:10MG/CUM Ingred Name:ALUMINUM HYDROXIDE (AS NUISANCE DUST OR PARTICULATES NOT OTHERWISE REGULATED) CAS:10043-01-3 RTECS #:BD0940000 OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 TDUST;8990 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIGLYCIDYL ETHER OF BISPHENOL A CAS:1675-54-3 RTECS #:TX3800000 Ingred Name:ALYKL GLYCIDYL ETHERS ===================== Hazards Identification ===================== Effects of Overexposure:SKIN/EYE IRRITATION/ALLERGIC SKIN/RESPIRATORY REACTIONS. POSSIBLE IN SUSCEPTIBLE INDIVIDUALS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING/LAUNDER BEFORE RE-USE. INGESTION: IF CONSCIOUS, GIVE WATER. INDUCE VOMITING. INHALATION: REMOVE TO FRE SH AIR. GIVE OXYGEN. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:>320F (PMCC) Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SPILLAGE BY ABSORBING IN ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING. AVOID PROLONGED OR REPEATED CONTACT W/SKIN. WASH THOROULY AFTER HANDLING. Other Precautions:NUISANCE DUST MAY BE GENERATED WHEN SANDING OR SAWING CURED MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESP WHEN VAPOR/MIST. Ventilation:MECH/LOCAL EXHAUST IN ACCORDANCE W/ACGIH RECOMMENDATIONS Supplemental Safety and Health 11/13/85. ALSO CONTAINS: PARA-TERITIARY (BUTYLPHENYL GLYCIDYL ETHER) (1002512PB). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:293F Vapor Pres:0.0 Appearance and Odor:BLACK LIQUID, ODORLESS. Percent Volatiles by Volume:0% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND BASES. Stability Condition to Avoid:EXCESSIVE HEAT FOR PROLONGED PERIODS OF TIME. Hazardous Decomposition Products:COMBUSTION MAY FORM TOXIC MATERIALS, SUCH AS CO2, CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT QUALIFIED LOCAL OR CORPORATE PERSONNEL FOR METHOD THAT WILL COMPLY WITH LOCAL, STATE AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: SILVER NITRATE N/71, 6061 Cage: 4T252 ======================================================= Contractor Summary ======================================================= Cage: 4T252 Box: 907 ======================================================= Ingredients ======================================================= Cas: 7761-88-8 RTECS #: VW4725000 % Wt: <1 OSHA PEL: 0.01 MG(AG)/M3 ACGIH TLV: 0.01 MG(AG)/M3 EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: <100 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: THIS PRODUCT MAY BE IRRITATING TO EYES AND SKIN. PRACTICALLY NON-TOXIC. CHRONIC: AN INGREDIENT OF THIS MIXTURE IS AN EXPERIMENTAL TUMORIGEN. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: MAY CAUSE IRRITATION. MAY CAUSE DISCOLORATION OF SKIN AND EYES ON CONTACT. Medical Cond Aggravated By Exposure: NONE REPORTED. First Aid: EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH PLENTY OF WATER. INGESTION: GIVE LARGE QUANTITIES OF WATER. CALL MD IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. SUPPORT BRE ATHING (GIVE OXYGEN OR ARTIFICIAL RESPIRATION) (FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COVER CONTAM SURF W/SODIUM BICARBONATE/SODA ASH-SLAKED LIME MIX (50-50). MIX & ADD WATER IF NEC TO FORM SLURRY. SCOOP UP SLURRY & WASH SITE W/SODA ASH SOLN. NEUTRALIZED SLURRY MAY CONTAIN SUFFICIENT H EAVY METAL CONC TO REQUIRE LANDFILLING/(SUP DAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. Handling And Storage Precautions: AVOID CONTACT WITH EYES AND SKIN. STORE IN A COOL PLACE PROTECTED FROM LIGHT. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: ADEQUATE VENTILATION. Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health: SPILL PROC: TREATMENT AT AN EPA APPROVED SITE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >212F,>100C Spec Gravity: 0.988 PH: 5.1 Evaporation Rate & Reference: 0.67 Solubility in Water: MISCIBLE Appearance and Odor: CLEAR AND COLORLESS LIQUID, NO ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXPOSURE TO LIGHT, EVAPORATION. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SILVER NITRATE N/71, 6061 Cage: 4T252 Company Name: HACH COMPANY Street: 100 DAYTON RD. PO Box: 907 Zipcode: 50010 Label Required IND: Y Date Of Label Review: 09/12/1996 Status Code: C Label Date: 09/12/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: None Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: THIS PRODUCT MAY BE IRRITATING TO EYES AND SKIN. MAY CAUSE DISCOLORATION OF THE SKIN AND EYES ON CONTACT. PRACTICALLY NON-TOXIC. CHRONIC: AN INGREDIENT OF THIS MIXTURE IS AN EXPERIMENTAL TUMORI GEN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OFF! SKINTASATIC Resp. Party Other MSDS Num.:111830003 CAGE:32204 Contract Num:SP0450-99-M-ND78 CAGE:8C885 Contract Num:SP0450-99-MNA39 CAGE:8C885 Contract Num:SP0450-99-MND46 CAGE:0TNN7 Contract Num:SP0450-99-MNG43 CAGE:0TNN7 CAGE:32204 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYL TOLUAMIDE CAS:134-62-3 RTECS #:XS3675000 Minumum % Wt:5. Maxumum % Wt:10. Ingred Name:ALKYL AMMONIUM CHLORIDE CAS:107-64-2 Code:F RTECS #:BQ1923000 Minumum % Wt:3. Maxumum % Wt:7. Ingred Name:ISOPROPYL PALMITATE CAS:142-91-6 RTECS #:RT4900000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:CETYL ALCOHOL CAS:36653-82-4 RTECS #:MM0225000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:GLYCERINE CAS:56-81-5 RTECS #:MA8050000 Minumum % Wt:3. Maxumum % Wt:7. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:PETROLATUM CAS:8009-03-8 RTECS #:SE6780000 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:70. Maxumum % Wt:80. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, GASTROINTESTINAL TRACT (HMIS). ACUTE - EYE: MAY CAUSE MODERATE EYE IRRITATION. SKIN: MAY CAUSE SKIN REACTIONS IN RARE CASES. INHALATION. NONE KNOWN. INGESTION: HARMFUL IF IN GESTED. CHRONIC EFFECTS - NONE KNOWN. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES-RINSE WITH PLENTY OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN CONTACT-IF REACTION OCCURS, WASH SKIN & SEEK MEDICAL ATTENTION. INHALATION-NO SPECIAL REQUIREMENTS. INGESTED-CONTAC T NEAREST POISON CONTROL CENTER. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CARBON DIOXIDE (CO2), DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:NORMAL FIRE FIGHTING PROCEDURE MAY BE USED. Unusual Fire/Explosion Hazard:NO SPECIAL HAZARDS KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE LARGE SPILLS. ABSORB WITH OIL-DRI OR SIMILAR MATERIAL. SWEEP OR SCRAPE UP & CONTAINERIZE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. Other Precautions:CAUTION: EYE IRRITANT. AVOID CONTACT WITH EYES & LIPS. DO NOT ALLOW CHILDREN TO RUB EYES IF HANDS HAVE BEEN TREATED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMENTS UNDER NORMAL USE CONDITIONS. Other Protective Equipment:NO SPECIAL REQUIREMENTS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:=0.C, 32.F Vapor Pres:NA Spec Gravity:0.979 Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:DISPERSIBLE Appearance and Odor:LIQUID, OPAQUE WHITE, PLEASANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH RUBBER, PLASTICS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:NONE KNOWN. ===================== Ecological Information ===================== Ecological:NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL METHOD. OBSERVE ALL APPLICABLE FEDERAL/PROVICIAL/STATE REGULATIONS & LOCAL/MUNICIPAL ORDNANCES REGARDING DISPOSAL OF NON-HAZARDOUS MATERIALS. =================== MSDS Transport Information =================== Transport Information:US DOT INFORMATION: PLEASE REFER TO THE BILL OF LADING/RECEIVING DOCUMENTS FOR UP-TO-DATE SHIPPING INFORMATION. ***************** US DOT INFORMATION: INSECTICIDES OR INSECT REPELLENTS, N.O.I., OTH ER THAN POISON. (NOT REGULATED - DLA-HMIS STAFF) CANADIAN SHIPPING NAME: NOT REGULATED. ===================== Regulatory Information ===================== Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE INCLUDED ON OR EXEMPTED FROM LISTING ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) INVENTORY OF CHEMICAL SUBSTANCES. EPA REGISTRATION #....4822-373. State Regulatory Information:THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS UNDER CALIFORNIA'S PROPOSITION 65. ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:MOLYBDENUM DISULFIDE CAGE:TO494 Contract Num:SP0450-00-M-D347 CAGE:4N760 CAGE:TO494 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDENUM DISULFIDE CAS:1317-33-5 RTECS #:QA4697000 > Wt:99. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): UNKOWN Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SHORT TERM EXPOSURE: MAY CAUSE IRRITATION TO SKIN AND EYES. LONG TERM EFFECTS: NO INFORMATION AVAILABLE ON SIGNIFICANT ADVERSE EFFECTS. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP PERSON WARM & AT REST. GET MEDICAL AID. SKIN:REMOVE CONTAMINATED CLOTHING/ SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT & LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROX. 15-20 MINS). GET MEDICAL AID. EYE:WASH EYES IMMEDIATELY WITH L ARGE AMOUNTS OF WATER OR NORMAL SALINE, LIFTING UPPER & LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROX. 15-20 MINS). INGEST:KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. GET MEDICAL AID IF NEEDED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINGUISH USING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. Fire Fighting Procedures:FULL FIREFIGHTING TURN-OUT GEAR (BUNKER GEAR). ANY SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE & OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE IN COMBINATION WITH A SEPARATE ESCAPE SU PPLY. ANY SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE. Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUST; KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:FOR LARGE SPILLS, SWEEP UP WITH A MINIMUM OF DUSTING AND PLACE INTO SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. RESIDUE SHOULD BE CLEANED UP USING A HIGH-EFFICIENCY PARTICULATE F ILTER VACUUM. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ANY DUST, MIST, FUME RESPIRATOR. ANY CHEMICAL CARTRIDGE RESPIRATOR WITH A DUST, MIST, FUME FILTER. ANY POWERED AIR-PURIFYING RESPIRATOR WITH A DUST, MIST, FUME FILTER. ANY TYPE 'C' SUPPLIED-AIR RESPIR ATOR WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE OR WITH A FULL FACEPIECE, HELMET OR HOOD OPERATED IN CONTINOUS-FLOW MODE. Ventilation:PROVIDE LOCAL EXHAUST VENTILATION AND/OR GENERAL DILUTION VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. Other Protective Equipment:PROVIDE AN EYE WASH FOUNTAIN WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. PROTECTIVE CLOTHING NOT REQUIRED. PROTECTIVE CLOTHING NOT REQUIRED. Work Hygienic Practices:AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. Supplemental Safety and Health RESPIRATORY PROTECTION CONTINUED: ANY SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACE PIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:>315.C, 599.F M.P/F.P Text:OXIDIZES Vapor Pres:APPROX. 0@20C Spec Gravity:4.80 @ 14C Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS, DARK GRAY TO BLACK POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROGEN PEROXIDE: VIGOROUS OR VIOLENT REACTION. OXIDIZERS(STRONG): FIRE AND EXPLOSION HAZARD. POTASSIUM NITRATE: FORMS EXPLOSIVE MIXTURE. Stability Condition to Avoid:PREVENT DISPERSION OF DUST IN AIR. Hazardous Decomposition Products:THERMAL DECOMPOSTION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. =================== Toxicological Information=================== Toxicological Information:INHALATION: ACUTE EXPOSURE: NO SPECIFIC DATA VAILABLE. INSOLUBLE MOLYBDENUM COMPOUNDS ARE CHARACTERIZED BY LOW TOXICITY. CHRONIC EXPOSURE: 25 ONE-HOUR EXPOSURES TO 490 MG/M3 CAUSED NO EFFECTS IN ALL T HE ANIMALS TESTED EXCEPT ONE WHICH DIED AFTER THE THIRD EXPOSURE. SKIN CONTACT: ACUTE EXPOSURE: DERMATITIS HAS NOT BEEN REPORTED IN EXPOSED WORKERS. EYE CONTACT: ACUTE EXPOSURE: NO SPECIFIC DATA AVAIL ABLE. SOME INSOLUBLE MOLYBDENUM COMPOUNDS ARE IRRITATING TO THE EYES. INGESTION: CHRONIC EXPOSURE: RATS FED UP TO 500 MG DAILY FOR 44 DAYS SHOWED NO TOXIC SIGNS & ALL GAINED WEIGHT. ===================== Ecological Information ===================== Ecological:ACUTE AQUATIC TOXICITY: TEST CONDUCTED IN 1990 AT LEVELS UP TO 750 MG/L POWDERED MOS2 RESULTED IN 0 MORTALITY TO RAINBOW TROUT (SALMO GAIRDNERI). ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN DISPOSING OF THIS SUBSTANCE. =================== MSDS Transport Information =================== Transport Information:NO CLASSIFICATION CURRENTLY ASSIGNED. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTIONS 302, 304, 313: NO. Federal Regulatory Information:TSCA INVENTORY STATUS: Y. TSCA 12(B) EXPORT NOTIFICATION: NOT LISTED. CERCLA SECTION 103 [40 CFR 302.4]: N. State Regulatory Information:CALIFORNIA PROPOSITION 65: N. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KEMIKAL HYDRATE & GL & SPECIALTY CAGE:GO213 CAGE:0GRK9 CAGE:GO213 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM HYDROXIDE, LIME, CALCIUM HYDRATE CAS:1305-62-0 RTECS #:EW2800000 Fraction by Wt: 100% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION & CORROSION DAMAGE. SKIN: IRRITATION & BURNS. INHALATION: UPPER RESPIRATORY TRACT IRRITATION, & MUCOUS MEMBRANE DAMAGE. INGESTION: DIGESTIVE TRACT CORROSION. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS, INCLUDING UNDER LIDS. SKIN: WASH W/PLENTY OF WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DILUTE BY GIVING 2 GLASSES OF MILK OR WATER TO DRINK, FOLLOWED BY FRUIT JUICES OR DILUTED VINEGAR TO NEUTRALIZE THE ALKALI. OBTAIN MEDIAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT COMBUSTIBLE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS NIOSH APPROVED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PERSONAL PROTECTION. KEEP SPILLED MATERIAL AWAY FROM ACIDS. CAREFULLY PICK UP SOLID W/A MINIMUM OF DUSTING & COLLECT IN METAL CONTAINERS W/COVERS FOR DISPOSAL. TRACE AMOUNTS OF RESIDUE IN SPILL A REA CAN BE FLUSHED TO DRAIN USING PLENTY WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATERIAL IN SEALED CONTAINERS IN DRY PLACE, AWAY FROM ACIDS. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROVED DUST RESPIRATOR WHEN DUSTY CONDITION EXISTS Ventilation:GENERAL & LOCAL EXHAUST TO MEET TLV REQUIREMENTS FOR LIME DUST. MECHANICAL EXHAUST: SUFFICIENT IN ABSENCE OF DUST/MIST. Other Protective Equipment:DRY RUBBER BODY-COVERING PROTECTIVE CLOTHING, EYE WASH STATION & SAFETY SHOWER Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2850C Spec Gravity:2.2-2.6 pH:11.7 Solubility in Water:0.1 G/100G Appearance and Odor:WHITE POWDER W/LOW ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BORIC OXIDE, ACIDS, FLUORINE, ORGANIC MATERIALS ==================== Disposal Considerations ==================== Waste Disposal Methods:ADD TO WATER, DILUTE & FLUSH TO SEWER (LARGE AMOUNTS MAY REQUIRE NEUTRALIZATION BY ACID) IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS. ALTERNATELY, WASTE LIME CAN BE USED FOR NEUTRALIZING PLANT ACID WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRO-SEAL 890 A-1/4, PART A Preparer's Name:MY CAGE:DO563 CAGE:83574 CAGE:DO563 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP3500000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (MN) Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:3.5 MG/CUM (NIOSH) OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:TALC (POWDER), (ASBESTOS FREE) CAS:14807-96-6 RTECS #:VV7720000 OSHA PEL:15 MG/CUM ACGIH TLV:2 MG/CUM (RESP DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. INHALATION: WEAKNESS & SLEEPINESS. THE MAIN HAZARD OF MANGANESE COMPOUNDS IS BY BREATHING DUST. INGESTION: SHOULD BE AVOIDED AS A PRECAUTION AGAINST MANGANESE POISONING. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: THE MAIN HAZARD OF MANGANESE COMPOUNDS IS BY BREATHING DUST, WEAKNESS & SLEEPINESS. INGESTON: SHOULD BE AVOIDED AS A PRECAUTION MANGANESE POISONING. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR 15 MINS. IF SYMPTOMS PERSIST, CONSULT PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF SYMPTOMS PERSIST, CONSULT PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS ARE PRESENT CONSULT PHYSICIAN. INGESTION: CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NON FLAMMABLE Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL HEAT EXPOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH 1,1,1-TRICHLOROETHANE. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE SMOKING OR EATING. AVOID INGESTION. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERAL VENTILATION Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING OR EATING. AVOID INGESTION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:2.0 Solubility in Water:NEGLIGIBLE Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS Hazardous Decomposition Products:OXIDES OF CARBON, MANGANESE COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A HAZARDOUS WASTE ACCORDING TO EPA REGULATIONS. CONSULT STATE REGULATIONS PRIOR TO DISPOSAL OF SPILLAGE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:19KT WHITE GOLD SOLDERS Preparer's Name:J. MONTEIRO CAGE:FO479 CAGE:65024 CAGE:FO479 ============= Composition/Information on Ingredients ============= Ingred Name:GOLD CAS:7400-57-5 RTECS #:MD5070000 Fraction by Wt: 80% Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 12% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 8% OSHA PEL:10 MG ZNO/M3 ACGIH TLV:10 MG ZNO/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DUSTS/FUMES CAUSE UPPER RESPIRATORY TRACT IRRITATION. SKIN: DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DUSTS/FUMES CAUSE UPPER RESPIRATORY TRACT IRRITATION. SKIN: DERMATITIS Medical Cond Aggravated by Exposure:DERMATITIS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. INHALATION: REMOVE TO FRESH AIR, IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. GET MED ATTN. ================== Accidental Release Measures ================== Spill Release Procedures:AS A SOLID, THIS SOLDER POSES NO SPECIAL CLEAN-UP PROBLEM. ======================Handling and Storage ====================== Handling and Storage Precautions:ALL GRINDING EQUIPMENT MUST HAVE SUCTION SYSTEMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP <TLV. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:1640 Spec Gravity:13 Solubility in Water:INSOLUBLE Appearance and Odor:STRIPS, PLATINUM COLOR, NO ODOR, 1 DWT STRIPS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS & STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE Hazardous Decomposition Products:ELEMENTAL METALS & METAL OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:WHENEVER POSSIBLE RECOVER PARTICLES & DUST DUE TO THE ECONOMICAL VALUE. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EPOXY SOLVENT, 00638 CAGE:9C365 CAGE:32939 CAGE:9C365 ============= Composition/Information on Ingredients ============= Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: >90% OSHA PEL:100 PPM ACGIH TLV:50 PPM/75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBON TETRACHLORIDE (SARA 313) (CERCLA) CAS:56-23-5 RTECS #:FG4900000 Fraction by Wt: <10% OSHA PEL:10 PPM Z-2 ACGIH TLV:5PPM/10 STEL, A3, S EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: MATERIAL CONTAINS A POSSIBLE CARCINOGEN. MAY BE HARMFUL IF INHALED, SWALLOWED OR ABSORBED BY THE SKIN. CHRONIC: CHLOROCARBON MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRI NE IN LABORATORY ANIMALS AND COULD HAVEA SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON TETRACHLORIDE: IARC MONOGRAPHS, SUPPLEMENT, VOL 7, PG 143, 1987: GROUP 2B. NTP 7TH ANNUAL REPORT ON (SUP DAT) Effects of Overexposure:HLTH HAZ: MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN/EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. INHALATION: GIVE ARTIFICIAL RESPIRATION OR OXYGEN AS NEEDED. OBTAIN MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE . ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL HAS BEEN PICKED-UP, SWEEP, PLACE IN BAG, AND HOLD FOR DISPOSAL. AVOID RAISING DUST. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS, AND HEAVY RUBBER GLOV ES. ABSORB MATERIAL ON SAND OR VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, KEEP CONTAINER TIGHTLY CLOSED. AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT BREATHE VAPORS. Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:FUME HOOD. Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health CARCIN EXPLAN: CARCINOGENS, 1994: ANTICIPATED TO BE CARCINOGEN. ANIMAL: LIVER, SKIN. ================== Physical/Chemical Properties ================== Spec Gravity:0.843 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR LIQUID, WITH POSSIBLE CAMPHOR ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, ALKALI METALS, FINELY POWDERED METALS, DIMETHYLFORMAMIDE ABOVE 65C. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE GAS AND PHOSGENE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR WITH AFTERBURNER AND SCRUBBER. DISPOSE OF RESIDUES IN ACCORDANCE WITH STATE, LOCAL, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:845 7517 EKTACOLOR RA BLEACH FIX & REGENERATOR,WORK SOLN CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM BISULFITE (SASA III) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 1 - 5% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM SULFITE CAS:10196-04-0 RTECS #:WT3505000 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 85 - 90% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 5 - 10% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIUM FERRIC ETHLYENEDIAMINETETRAACETIC ACID CAS:21265-50-9 Fraction by Wt: 1 - 5% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES. ACUTE- EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INHALATION:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. ORA L:EXPECTED TO BE A LOW INGESTION HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND PLENTY OF WATER. INHALATION:REMOVE TO FRE SH AIR. INGESTION:DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCT. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER IF PERMITTED OR ABSORB SPILL WITH VERMICULITE, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT RELEVENT ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AWAY FROM INCOMPATIBLE MATERIALS. Other Precautions:WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH EYES. KEEP OUT OF REACH OF CHILDREN. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT. TYPICALLY, 10 ROOM VOLUMES PER HR IS CONSIDERED GOOD GENERAL VENTILATION. Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health WORKING SOLUTION: KAN 471264. CONTAINS PART A AND PART B. ECOLOGICAL INFORMATION: THIS MATERIAL IS EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A HIGH BIOCHEMICAL OXYGEN DEMAND, A LOW POTENTIAL TO AFFEC T AQUATIC ORGANISMS. AFTER DILUTION WITH WATER, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE EFFECTS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 @ 68F Vapor Density:O.6 Spec Gravity:1.07 pH:5.5 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, AMMONIA ODOR Percent Volatiles by Volume:85- 90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS, STRONG ACIDS Hazardous Decomposition Products:AMMONIA, CHORAMINE, NITROGEN OXIDES (NOX), SULFUR DIOXIDE, CARBON MONOXIDE, CARBON DIOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AWS 317 CAGE:0AES5 CAGE:0AES5 ============= Composition/Information on Ingredients ============= Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE CAS:7439-98-7 RTECS #:QA4680000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 OSHA PEL:5 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN CARCINOGEN BY IARC, NTP & ACGIH) CAS:7440-47-3 RTECS #:GB4200000 OSHA PEL:1 MG/CUM (CEILING) ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC, ACGIH) INTENDED CHANGE (IC) CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:YES Health Hazards Acute and Chronic:EYES: IRRITATION, BURNS. SKIN: BURNS. INHALATION: DIZZINESS, NAUSEA, NOSE/THROAT IRRITATION, TIGHTNESS IN CHEST, FEVER. ELECTRICK SHOCK CAN KILL. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:INHALATION: SIDEROSIS (IRON DEPOSIT IN LUNGS). MAY AFFECT PULMONARY FUNCTION. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTIBLES & FLAMMABLES. ======================Handling and Storage ====================== Handling and Storage Precautions:READ & UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS & THE PRECAUTIONARY LABEL ON THE PRODUCT. Other Precautions:ONE RECOMMENDED WAY TO DETERMINE THE COMPOSITION/QUANTITY OF FUMES/GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE FROM INSIDE THE WELDER'S HELMET IF WORN OR IN THE WORKER'S BREATHING ZONE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATORY OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN A CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW THE RECOMMENDED EXPOSURE LIMIT. Ventilation:LOCAL EXHAUST AT THE ARC OR BOTH TO KEEP THE FUMES & GASES FROM THE WORKER'S BREATHING ZONE & GENERAL AREA. APRON, HATS, SHOULDER PROTECTION, AS WELL AS SUBSTANTIAL CLOTHING. Work Hygienic Practices:TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. Supplemental Safety and Health COMPOSITION & QUALITY OF WELDING FUMES & GASES ARE DEPENDENT UPON METAL BEING WELDED, PROCESS, PROCEDURE & ELECTRODES USED. DECOMPOSITION PRODUCT OF NORMAL OPERATION INCLUDE THOSE ORIGINATING FROM VOL ATILIZATION, REACTION, OXIDATION OF MATERIALS IN INGREDIENTS, PLUS THOSE FROM THE BASE METAL & COATING, ETC. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO, CO2. OZONE & NITROGEN OXIDES MAY BE FORMED BY THE RADIATION FROM THE ARC, SHIELDING GASES ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FEDERAL, STATE & LOCA L REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DIESEL STARTING FLUID CAGE:NO214 CAGE:61112 CAGE:NO214 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ETHER (SARA III) CAS:60-29-7 RTECS #:KI5775000 Fraction by Wt: 91% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM/500 STEL ACGIH TLV:400PPM/500STEL; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYLENE (SARA III) CAS:74-85-1 RTECS #:KU5340000 Fraction by Wt: 6.5% Other REC Limits:NONE SPECIFIED ACGIH TLV:ASPHYXIANT; 9192 Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 2% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:2,6-DI-TERT-BUTYL-P-CRESOL CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: 1% PPM Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE CONJUNCTIVITIS, IRRITATION OF RESPIRATORY TRACT. Effects of Overexposure:HEADACHE, DIZZINESS, ANOREXIA, NAUSEA AND VOMITING. NARCOSIS ALUMINURIA LASSITUDE. ======================= First Aid Measures ======================= First Aid:INGESTION: IF CONSCIOUS AND ABLE TO SWALLOW, HAVE VICTIM DRINK WATER OR MILK TO DILUTE. DO NOT GIVE SODIUM BICARBONATE, FRUIT JUICES OR VINEGAR. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. INHALATION: IMMEDIATELY REMOVE TO FRESHAIR. ASSIST WITH BREATHING IF NECESSARY. EYES OR SKIN: IMMEDIATELY FLUSH AFFECTED AREA WITH PLENTY OF COOL WATER FOR ABOUT 15 MIN. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-49F,-45C Lower Limits:1.9 Upper Limits:48 Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE IN FIRE FIGHTING, BUT WATER CAN BE USED TO COOL CONTAINERS. FLUSH AWAY SPILLS NOT IGNITED, AND DISPERSE VAPORS. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO AN IGNITION SOURCE AND FLASH BACK. WEAR SELFP-CONTAINED BREATHING APPARATUS IN A POSITIVE MODE WITH A FULL FACE PIECE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE TO REMOVE FUMES, FLUSH LARGE SPILLS WITH WATER. RUNOFF TO SEWERS MAY CREATE FIRE OR EXPLOSION HAZARD. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE OVER 175F. DO NOT STORE NEAR SPARKS, FLAMES, OR CONBUSTIBLES. PROTECT CONTAINER FROM PHYSICAL DAMAGE. Other Precautions:SMOKING SHOULD BE PROHIBITED IN STORAGE AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN IN CONTACT WITH HIGH CINCENTRATION USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SYSTEM. Ventilation:LOCAL EXHAUST: NATURAL VENTILATION IF POSSIBLE. MECHANICAL: (GENERAL) EXPLOSION PROOF. Other Protective Equipment:WEAR NITRILE COATED CLOTHING IF PROLONGED SKIN CONTACT IS ANTICIPATED. Work Hygienic Practices:USE NORMAL PROCEDURES FOR HANDLING CHEMICALS. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:G2 Boiling Pt:B.P. Text:94.0F,34.4C Vapor Pres:7.3 ATM Vapor Density:2.6 Spec Gravity:0.695 Evaporation Rate & Reference:6.9 Solubility in Water:MODERATE Appearance and Odor:COLORLESS WITH AN ETHER ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS AND EASILY COMBUSTIBLE MATERIALS. Stability Condition to Avoid:STORE AT TTEMPERATURES BELOW 175F. Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW SPILLS TO EVAPORATE. ALLOW CYLINDER CONTENTS TO BE USED COMPLETELY, THEN DISPOSE OF IN NORMAL TRASH. DO NOT PUNCTURE, MUTILATE, OR INCINERATE CONTAINER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:O-E-760 ETHYL ACL(ETHANOL);DENAT,ALC;& PROP CAGE:DO973 CAGE:82925 CAGE:DO973 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 86.3% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 13.7% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATION OF EYES & RESPIRATORY TRACT;HEADACHE,DIZZINESS,DROWSINESS,METAL CONFUSION,FATIGUE,NAUSEA ======================= First Aid Measures ======================= First Aid:IRRIGATE EYS WITH WATER GASTRIC LAVAGE,IF SWALLOWED,FOLLOWED BY SALINE CATHARSIS.REMOVE FROM EXPOSURE.KEEP PATIENT WARM,CALL A PHYSICIAN ===================== Fire Fighting Measures ===================== Flash Point:59F TCC Lower Limits:3.3 Upper Limits:19.0 Extinguishing Media:DRY CHEMICAL,OAM,OR CARBON DIOXIDE Fire Fighting Procedures:WATER ONLY TO KEEP FIRE EXPOSED CONTAINERS COOL ================== Accidental Release Measures ================== Spill Release Procedures:USE WATER SPRAY TO PROTECT MEN ATTEMPING TO STOP LEAK.USE WAER SPRAY TO FLUSH SPILLS & TO DILUTE TO NON FLAMMABLE MIXTURE ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE.STORE INDOORS IN A COOL & WELL VENTILATED ROOM.STORE AWAY FROM ALL POSSIBLE IGNITION SOURCES Other Precautions:ELIMINATE STATIC ELECTRICITY.DO NOT STORE WITH PERCHLORATES,PEROXIDES,CHROMIC ACID & NITRIC ACID.WEAR CHEMICAL ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF CONTAINED BREATHING APPARATUS,OR CHEMICAL CARTRIDGE RESPIRATOR Ventilation:AS NEEDED TO CONTROL TLVS Other Protective Equipment:RUBBER BOOTS,APRONS Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:B.P. Text:175F Vapor Pres:43 Spec Gravity:0.8 Solubility in Water:COMPLETE Appearance and Odor:CLEAR,COLORLESS LIQUID,CHARACTERISTIC ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,SIGNITION SOURVES,PEROXIDES,CHROMIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:SPRAY INTO APPROVED INCINERATOR UNDER CONTRLLED PROCEDURES
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GED CAGE:0RGY9 CAGE:0RGY9 CAGE:0R6Y9 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIUM, DIDECYLDIMETHYL-, CHLORIDE; (N,N-DIDECYL-N, DIMETHYL AMMONIUM CHLORIDE) CAS:7173-51-5 RTECS #:BP6560000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:DODECYLAMINE, N,N-DIMETHYL-,N-OXIDE; (N,N-DIMETHYL-1-DODECANAMINE-N-OXIDE) CAS:1643-20-5 RTECS #:JR6650000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:N,N-DIMETHYL-1-TETRADECANAMINE-N-OXIDE CAS:3332-27-2 RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:N,N-DIMETHYL-1-HEXADECANAMINE-N-OXIDE CAS:7198-91-5 RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYL ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:ETHYLENEDIAMINETETRAACETIC ACID, TRISODIUM SALT CAS:150-38-9 RTECS #:AH5250000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: VOMITING. IF VOMITING OCCURS, GIVE FLUIDS AGAIN. GET IMMED MED ATTN. HAVE MD DETERMINE IF PATIENT'S (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: CONDITION ALLOWS FOR INDUCTION OF VOMITING OR EVACUATION OF STOMACH. DO NOT GIVE ANYTHING BY MOUTH TO (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: CONVULSING OR UNCONSCIOUS PERSON. RTECS #:9999999ZZ Ingred Name:SPILL PROC: THE LIQUID & SOLID SEPARATELY TO CNTNRS FOR RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWERS & OPEN (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: BODIES OF WATER. RTECS #:9999999ZZ Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:BASED ON INFORMATION AVAILABLE FOR SIMILAR PRODUCTS, IT IS ANTICIPATED THAT THIS MATERIAL WILL BE CORROSIVE TO THE SKIN AND EYES UPON DIRECT OR PROLONGED CONTACT. SOLVENT VAPORS OR MISTS OF PRODUCT CA N PRODUCE IRRITATION OF THE MUCOUS MEMBRANES. INGESTION CAN PRODUCE IMMEDIATE BURNING PAIN IN THE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MOUTH, THROAT AND ABDOMEN; SEVERE SWELLING OF THE LARYNX; SKELETAL MUSCLE PARALYSIS AFFECTING THE ABILITY TO BREATHE; CIRCULATORY SHOCK; AND/OR CONVULSIONS. MAY BE FATAL. Medical Cond Aggravated by Exposure:UNKNOWN. ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/LARGE AMTS OF FUNNING WATER & SOAP, IF AVAILABLE, FOR 15 MIN. REMOVE CONTAM CLTHG & SHOES. GET IMMED MED ATTN. WASH CLTHG & DECONTAM SHOES BEFORE REUSE. EYES: FLUSH EYES W/LARGE AMTS OF R UNNING WATER FOR AT LEAST 15 MIN, HOLD EYELIDS APART TO ENSURE RINSING OF ENTIRE SURF OF EYE & LIDS W/WATER. GET IMMED MED ATTN. IF MD NOT AVAILABLE, FLUSH FOR ADDNL 15 MIN & THEN TRANSPORT (SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>230F,>110C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:PRODUCTS OF COMBUSTION ARE TOXIC. ================== Accidental Release Measures ================== Spill Release Procedures:DANGER! CORROSIVE MATL. FLOORS MAY BECOME SLIPPERY. WEAR APPROP PROT GEAR & NIOSH APPRVD RESP PROTECTION WHERE MIST OR VAPS OF UNKNOWN CONCS MAY BE GENERATED (SCBA PREFERRED). DIKE & CONTAIN SPILL W/I NERT MATL (SAND, EARTH, ETC) & TRANSFER(ING 11) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT TEMPERATURES BELOW 140F. KEEP CONTAINERS CLOSED UNTIL USED. DO NOT CONTAMINATE DRINKING WATER, FOOD OR FEED BY STORAGE OR DISPOSAL. Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF THE REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR EXPOSURE ABOVE ESTABLISHED LIMITS, NIOSH APPROVED RESPIRATOR IS ADVISED IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROLS. Ventilation:MECHANICAL REQUIRED. Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . PROT CLTHG (LONG SLEEVES, COVERALLS/OTHER AS APPROP) TO PVNT SKIN CNTCT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: VICTIM TO MED CARE. INHAL: REMOVE FROM AREA TO FRESH AIR. IF NOT BRTHG, CLEAR AIRWAY & START ARTF RESPIRATION. IF VICTIM IS HAVING TROUBLE BRTHG, GIVE SUPPLEMENTAL OXYGEN, IF AVAILABLE . GET IMMED MED ATTN. INGEEST: IMMED GIVE 3-4 GLASSES OF MILK (IF UNAVAILABLE, GIVE WATER). DO NOT INDUCE (ING 8) ================== Physical/Chemical Properties ================== Solubility in Water:SOLUBLE Appearance and Odor:CLEAR LIQUID WITH PLEASANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE TOXIC VAPORS/FUMES OF AMINES & OTHER ORGANIC MATERIALS & OXIDES OF CARBON & NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1367 DRAGNET FT TERMITICIDE CAGE:91976 CAGE:91976 ============= Composition/Information on Ingredients ============= Ingred Name:PERMETHRIN; 3-PHENYOXYBENZYL(1RS)CIS/TRANS-3-2.2-DICHLOROVINYL-2.2-DIMETHYL (IARC - GROUP 3) *97-1* CAS:52645-53-1 RTECS #:GZ1255000 Fraction by Wt: <37% Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS *97-1* CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: <25% Other REC Limits:525 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TRIACETIN *97-1* CAS:102-76-1 RTECS #:AK3675000 Fraction by Wt: <25% Ingred Name:SURFACTANT Fraction by Wt: <8% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: SLIGHT IRRITATION, WORSENING AFTER 72 HRS. INHALATION: HIGH CONCENTRATIONS OF SOLVENT MAY CAUSE CNS EFFECTS. INGESTION: VOMITING MAY CAUSE ASPIRATION OF AROMATIC HYDROCARBONS INTO LUNGS WHICH MA Y RESULT IN FATAL PULMONARY EDEMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, REDNESS, SCALLY FLAKING, SKIN THICKENING, HEADACHES, DIZZINESS, LOSS OF FEELING & SENSATIONS, DROWSINESS, UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:NONE PRESENTLY KNOWN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: THOROUGHLY WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: RINSE MOUTH W/WATER. DILUTE BY GIVING 1-2 GLASSES OF WATER. DON'T INDUCE VOMITING. AS PIRATION HAZARD. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN: CONTROL CNS STIMULATION W/SEDATION BY BARBITURATES. CONSIDER GASTRIC LAVAGE W/AN ENDOTRACHEAL TUBE IN PLACE. (SEE SUPP) ===================== Fire Fighting Measures ===================== Flash Point:108F Extinguishing Media:FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & SCBA. CONTAIN ALL RUNOFF. ISOLATE FIRE AREA. EVACUATE DOWNWIND. DON'T BREATHE/CONTACT SMOKE, GASES/VAPORS GENERATED. (SEE SUPP) Unusual Fire/Explosion Hazard:MODERATELY COMBUSTIBLE. SEALED, OVERHEATED CONTAINERS MAY PRESENT AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:ISOLATE & POST AREA. WEAR PROTECTIVE CLOTHING & EQUIPMENT. KEEP MATERIAL OUT OF STREAMS & SEWERS. DIKE & ABSORB W/CLAY, SAND/SOIL. VACUUM, SHOVEL/PUMP WASTES INTO A DRUM. CLEAN AREA, TOOLS & EQUIPMENT W/SOLUTION OF SOAP & WATER. (SEE SUPP) ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. DON'T STORE <40F. DON'T USE/STORE NEAR HEAT, OPEN FLAME/HOT SURFACES. STORE IN ORIGINAL CONTAINERS. Other Precautions:KEEP OUT OF REACH OF CHILDREN & ANIMALS. DON'T CONTAMINATE OTHER PESTICIDES, FERTILIZERS, WATER, FOOD/FEED BY STORAGE/DISPOSAL. STEEL CONTAINERS WHICH HELD THESE MATERIALS MAY BE CLEANED BY BEING TRIP LE-RINSED & INCINERATED. (SEE SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A PROPERLY FITTED NIOSH/MSHA HALF-FACE/FULL-FACE AIR-PURIFYING RESPIRATOR APPROVED FOR PESTICIDES BASED ON AIRBORNE CONCENTRATION. Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO CONTROL RELEASE OF MIST/VAPOR INTO WORK AREAS. Other Protective Equipment:LONG SLEEVED UNIFORM/COVERALLS, HEAD COVER, RUBBER RAIN SUIT, BARRIER CREAM, SAFETY SHOWER, EMERGENCY EYE WASH Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SPECIAL FIRE: KEEP CONTAINERS COOL W/SOFT STREAM WATER FOG. FIRST AID: TREATMENT IS CONTROLLED REMOVAL OF EXPOSURE FOLLOWED BY SYMPTOMATIC & SUPPORTIVE CARE. SPILL PROCEDURES: ADD SOLUTION TO DRUMS OF WASTES ALREADY COLLECTED. LABEL FOR CONTENTS & DISPOSE OF. OTHER PRECAUTIONS: DON'T CUT/WELD STEEL CONTAINERS. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:32F Spec Gravity:1.042 pH:7.5 Solubility in Water:EMULSIFIES Appearance and Odor:CLEAR BROWN LIQUID W/FAINT, MILD PETROLEUM ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:EXCESSIVE HEAT, FIRE, OPEN FLAME, HOT SURFACES. Hazardous Decomposition Products:BY THERMAL DECOMPOSITION & BURNING: CHLORINE, HYDROGEN CHLORIDE, CO2, CO & ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF DRUMMED WASTES & DECONTAMINATION SOLUTION BY BURNING IN AN INCINERATOR IAW/FEDERAL, STATE & LOCAL REGULATIONS. OPEN DUMPING/BURNING OF THIS PESTICIDE/ITS PACKAGING IS PROHIBITED. FLAMMABLE LIQUID UN1993.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PUROLITE C-100 H ION EXCHANGE RESIN Kit Part:Y CAGE:67168 Contract Num:SP0450-00-M-SB32 CAGE:1KES0 CAGE:67168 ============= Composition/Information on Ingredients ============= Ingred Name:NONE ===================== Hazards Identification ===================== Medical Cond Aggravated by Exposure:EYE CONTACT: LIKE OTHER FOREIGN BODIES, PARTICLES MAY CAUSE MECHANICAL IRRITATION OF THE EYE. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH LARGE AMOUNT OF WATER FOR AT LEAST 15 MINS. CONSULT PHYSICIAN IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Autoignition Temp:=426.7C, 800.F Extinguishing Media:CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR MSHA/NIOSH APPROVED, PRESSURE DEMAND, SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:RESIN BEADS ON FLOOR MAY MECHANICALY CAUSE FLOOR TO BE SLIPPERY. USE CARE TO AVOID FALLS. SWEEP UP AND TRANSFER TO CONTAINERS FOR RECOVERY OR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRUMS AND PLASTIC BAGS SEALED TO PREVENT DRYING OR MOISTURE LOSS. Other Precautions:STORE BELOW 49 DEG C (120 DEG F) AND ABOVE 0 DEG C (32 DEG F). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. Ventilation:LOCAL EXHAUST: NORMAL ROOM VENTILATION. Other Protective Equipment:NONE Work Hygienic Practices:CLEANLINESS IS RECOMMENDED. Supplemental Safety and Health ITEM IS A TWO PART KIT. KIT CONTAINS TWO 5 GALLON PAILS OF CATION AND TWO 5 GALLON PAILS OF ANION; FORM: CERAMIC BEAD. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:APPROX 1.26 (H20=1) Solubility in Water:INSOLUBLE Appearance and Odor:AMBER TO MAHOGANY COLORED SPERICAL BEADS WITHOUT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH CONCENTRATED NITRIC ACID, OR STRONG OXIDIZING AGENTS. Stability Condition to Avoid:AVOID TEMPERATURES OVER 220 DEG C (424 DEG F). Hazardous Decomposition Products:SO2, SO3, CO, CO2, STYRENE MONOMER, DIVINYLBENZENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DOUBLE TEAM CAGE:HO205 CAGE:HO205 CAGE:64796 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 3% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:SODIUM NITRITE (SARA III) CAS:7632-00-0 RTECS #:RA1225000 Fraction by Wt: 1% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== Effects of Overexposure:EYE/SKIN: IRRITATION ======================= First Aid Measures ======================= First Aid:EYE/SKIN: FLUSH WITH WATER 15 MINUTES. INGESTION: INDUCE VOMITING,SEE A PHYSICIAN IMMEDIATELY ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:SUFFICIENT FOR SURROUNDING FIRE ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP AND/OR FLUSH INTO DRAIN ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN MODERATE TEMPERATURES Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL/MECHANICAL Supplemental Safety and Health PH AT 5%: 8.5. MFR ADDRESS: P.O. BOX 22263,DALLAS,TX 75222 ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F/100C Spec Gravity:1.1 Evaporation Rate & Reference:<1 (WATER) Solubility in Water:COMPLETE Appearance and Odor:CLEAR,LT YELLOW LIQUID,OCOTEA CYMBARIUM ODOR Percent Volatiles by Volume:52 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HIGH LEAD ALLOYS ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FC-62 ANTIFOAM COMPOUND Preparer's Name:N. J. HILL CAGE:MO350 CAGE:0DR30 CAGE:MO350 ============= Composition/Information on Ingredients ============= Ingred Name:NO HAZARD INGREDIENTS STATED BY MANUFACTURERS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS PRODUCT IS GENERALLY CONSIDERED TO BE INERT AND NON-HAZARDOUS. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:THIS PRODUCT IS GENERALLY CONSIDERED TO BE INERT AND NON-HAZARDOUS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALE- PASTE. NOT LIKELY, BUT, IF IT SHOULD OCCUR, CALL PHYSICIAN. SKIN- WASH WITH SOAP AND A LARGE VOLUME OF WATER. REMOVE CLOTHING IN AFFECTED AREA. EYE- FLUSH THOROUGHLY FOR AT LEAST 15 MINS. WITHLARGE VOLUMES OF WATER . IRRITATION DOES NOT INVOLVE CORNEA AND SHOULD SUBSIDE WITHIN SEVERAL HOURS. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL FOR SURROUNDING FIRE. Fire Fighting Procedures:USE APPROPRIATE PROCEDURES FOR SURROUNDING FIRE. Unusual Fire/Explosion Hazard:THIS MATERIAL IS WATER BASED. THERE IS NO FIRE AND OR EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH WITH WATER, COVER RESIDUE WITH ABSORBENT MATERIAL LIKE SAWDUST OR SWEEPING COMPOUND, BRUSH BACK AND FORTH AND SWEEP UP. AREA OF SPILL MAY BE SLIPPERY AFTER CLEANUP; PROPER PRECAUTIONS SHOULD BE TAKEN. Neutralizing Agent:NONE APPLICABLE FOR THIS MATERIAL ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING. WASH HANDS THOROUGHLY AFTER HANDLING. DO NOT RUB EYES WITH SOILED HANDS. Other Precautions:CLEAN UP SPILLS THOROUGHLY AS RESIDUE IS SLIPPERY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION IS REQUIRED FOR THIS PRODUCT AS SOLD. Ventilation:PROVIDE ADEQUATE VENTILATION. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1.0 Solubility in Water:COMPLETE Appearance and Odor:WHITE LIQUID Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MATERIALS THAT REACT WITH WATER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PL207 FLAT BLACK LACQUER Preparer's Name:JUDY CAGE:GEMIN CAGE:GEMIN ============= Composition/Information on Ingredients ============= Ingred Name:LAMP BLACK 519 Ingred Name:ADDITIVE 283 Ingred Name:PHTHALATE ESTER *97-1* CAS:68515-48-0 Ingred Name:RLN192 REDUCED WITH XYLENE Ingred Name:NITROCELLULOSE 31 Ingred Name:NITROCELLULOSE 67 Ingred Name:ISOBUTYL ACETATE CAS:110-19-0 RTECS #:AI4025000 Other REC Limits:150 PPM OSHA PEL:150 PPM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *97-1* CAS:108-88-3 RTECS #:XS5250000 Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL CARBINOL(IARC-GROUP 3) *97-1* CAS:67-63-0 RTECS #:NT8050000 Other REC Limits:400 PPM OSHA PEL:400 PPM ACGIH TLV:400 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERELY IRRITATING. MAY CAUSE BURNS, CORNEAL INJURY. SKIN: CONTACT FOR SEVERAL HOURS CAN CAUSE IRRITATION. ABSORPTION IN HARMFUL AMOUNTS. INHALATION: NASAL & RESPIRATORY IRRITATION, ASPHYXIATIO N. OVEREXPOSURE MAY RESULT IN DAMAGE TOLIVER, KIDNEYS, LUNGS & BLOOD FORMING ORGANS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS, ASPHYXIATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LUKEWARM WATER FOR 15 MINS. SKIN: WASH IMMEDIATELY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR & AID BREATHING IF NECESSARY. INGESTION: RINSE MOUTH IMMEDIATELY. DRINK 1-2 GLASSES OF WATER TO DILUTE. DON'T INDUCE VOMITING.OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:40F Lower Limits:1 Upper Limits:12 Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:EVACUATE AREA. DON'T ENTER CONFINED SPACE W/O PRESSURE NIOSH APPROVED SCBA. (SEE SUPP) Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT/IGNITION SOURCES/HOT SURFACES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:STAY UPWIND & AWAY FROM LEAK UNLESS WEARING PROTECTIVE EQUIPMENT. STOP & CONTAIN DISCHARGE IF IT CAN BE DONE SAFELY. KEEP IGNITION SOURCES AWAY. VENTILATE AREA. USE NON-SPARKING TOOLS. COVER W/INERT M ATERIAL. KEEP OUT OF DRAINS, SEWERS/WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY & AWAY FROM IGNITION SOURCES. USE/STORE W/ADEQUATE VENTILATION. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. Other Precautions:BOND/GROUND METAL CONTAINERS WHEN TRANSFERRING. DON'T SMOKE IN STORAGE AREA. AVOID INHALATION OF VAPORS/CONTACT W/PRODUCT. CONTAINERS MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN RES IDUES, PRECAUTIONS MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS TLV, USE NIOSH APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:LOCAL EXHAUST AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. Other Protective Equipment:APRON Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS THOROUGHLY BEFORE EATING/USING RESTROOM. Supplemental Safety and Health FIRE PROC CONT'D: WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. FIRE HAZ CONT'D: NEVER USE WELDING/CUTTING TORCH ON/NEAR EMPTY CONTAINER, RESIDUE MAY IGNITE EXPLOSIVELY. UNCONTROLLED RELEASES MAY CONTAMINATE AIR, GROUND, WATERWAYS & SEWERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:147.2F-385F Vapor Pres:36 Vapor Density:>1 VOC Pounds/Gallon:768 VOC Grams/Liter:6.4 Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Appearance and Odor:LIQUID Percent Volatiles by Volume:88.6 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ALKALINES, STRONG MINERAL ACIDS Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, ELECTRICAL EQUIPMENT, HOT SURFACES & OTHER IGNITION SOURCES Hazardous Decomposition Products:OXIDATION MAY PRODUCE CARBON & NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T FLUSH TO SEWER, WATERSHED/WATERWAY. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. UN1263.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GMAW WIRE,TYPE A5356 CAGE:83923 CAGE:83923 CAGE:54393 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 91% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: 5% Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 0.1% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0.1% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 ===================== Hazards Identification ===================== Effects of Overexposure:DIZZINESS,NAUSEA,OR DRYNESS OR IRRITATION OF NOSE,THROAT,OR EYES. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES:FLUSH W LG AMTS H*2O FOR 15 MIN;SKIN:FLUSH W LG AMTS H*2O;INGEST:RINSE MOUTH. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Unusual Fire/Explosion Hazard:WELDING ARC AND SPARKS CAN IGNITE COMBUSTIBLE PRODUCTS ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUE AND PLACE IN SUITABLE DOT APPVD DISPOSAL CONTAINER. ======================Handling and Storage ====================== Other Precautions:WELD IN WELL VENTILATED AREA.AVOID INHALATION OF WELDING FUMES.AVOID ELECTRICAL SHOCK BY MAINTAINING DRY WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FUME RESP.OR AIR SUPPLIED RESP.IN CONFINED SPACES. Ventilation:MECHANICAL (GENERAL) ACCEPTABLE LOCAL EXHAUST IF NEEDED. Other Protective Equipment:APRON,LEGGINGS,BOOTS,CAPES,SHOULDR COVERS-SEE SUPPL.DATA- Supplemental Safety and Health MSDS DATED 11-15-79/HAZ.DECOMP:IN ARC WELDING SLIGHT NO*2,AND OZONE/OTHER PROTECTIVE EQUIPMENT:HARD HAT,SCREENS,LOW REFLECTIVITY WALLS OR BOOTHS/ ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:ELECTRODE,WELDING ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Hazardous Decomposition Products:FUME OF METALS&METAL OXIDES INCLUD.BASE MTL&COATNG-SEE SUPPL ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW LOCAL,STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TETRA-ETCH COMPOUND TEC-1 CAGE:88952 CAGE:88952 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GYLCOL DIMETHYL ETHER CAS:110-71-4 RTECS #:KI1451000 Fraction by Wt: 75% Ingred Name:SODIUM NAPHTHALENE RADICAL CAS:11349-05-0 Fraction by Wt: 25% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DIZZINESS, DROWSINESS, ANESTHESIA, HEADACHE, & NAUSEA. SKIN/EYE: SEVERE IRRITATION, POSSIBLE CAUSTIC BURNS, INJURY Explanation of Carcinogenicity:NONE Effects of Overexposure:RECENT STUDIES HAVE SHOWN THAT THE GYLCOL DIMETHYL ETHER USED IN THIS PRODUCT CAUSES REPRODUCTIVE TOXICITY IN MICE SUCH AS TESTICULAR ATROPHY, TERATOGENIC EFFECTS/EMBRYO TOXICITY. Medical Cond Aggravated by Exposure:CERTAIN RARE INDIVIDUALS MAY SHOW A HYPERSENSITIVITY TO NAPHTHALENE. BECAUSE OF THE TERATOGENIC EFFECTS IN MICE OF THE GLYCOL ETHER SOLVENT, EXPOSURE OF PREGNANT FEMALES SHOULD BE MINIMIZED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE AFFECTED INDIVIDUAL TO FRESH AIR. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION & SEEK MED ATT. INGESTION: CONTACT PHYSICIAN. SKIN: FLUSH W/WATER; WASH THOROUGHLY W/SOAP & WATER, REMOVE ANY CONTAMINATED CLOTHING. SEE PHYSICIAN. EYES: FLUSH W/WATER FOR AT LEAST 15 MINS, CONTACT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:84F Lower Limits:1.8% Extinguishing Media:DRY CHEMICAL-PREFERABLY W/A NITROGEN PROPELLANT AS IN SOME TYPES OF LOW TEMPERATURE EXTINGUISHERS Fire Fighting Procedures:USE A POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR OR A SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:THIS MATERIAL IGNITES READILY & BURNS VIGOROUSLY. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE/COVER W/A MINERAL BASED FLAMMABLE LIQUID ABSORBENT SUCH AS SAFESTEP. THIS MATERIAL IS ALSO CAUSTIC. USING NON-SPARK TOOLS, TRANSFER MATERIAL INTO A POLYPROPYLENE OR POLYETHYLENE DRUM/DISPOSE OF A CCORDING TO FEDERAL, STATE/LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:THIS MATERIAL MAY BE HAZARDOUS TO THE ENVIRONMENT. DURING HANDLING, USE/DISPOSAL, AVOID CONTAMINATION OF SOIL, DRAINS/WATER. AVOID BREATHING VAPOR. Other Precautions:PRESSURE MAY BUILD UP DURING STORAGE OR WHEN SHAKING UP THE CAN'S CONTENTS. ALLOW THE PRESSURE TO ESCAPE SLOWLY BEFORE COMPLETELY OPENING THE CAN. PIERCE THE INNER SEAL W/A SMALL, POINTED TOOL TO VENT PRESSURE. STORE <32F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY NIOSH APPROVED RESPIRATOR OR SUPPLIED AIR BREATHING APPARATUS. CHEMICAL RESPIRATORS SHOULD BE FITTED W/ORGANIC VAPOR CARTRIDGES. Ventilation:ADEQUATE VENTILATION SUCH AS A FUME HOOD OR LOCAL EXHAUST IS ESSENTIAL. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:185F Vapor Pres:48 Vapor Density:3.11 Spec Gravity:0.97 Evaporation Rate & Reference:(N-BU AC = 1): 5.0 Solubility in Water:APPRECIABLE Appearance and Odor:GREEN-BLACK LIQUID, NAPHTHALENE/ETHER ODOR. Percent Volatiles by Volume:75% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS Stability Condition to Avoid:STORE <32F. HEAT, SPARKS & OPEN FLAMES. Hazardous Decomposition Products:REACTS W/WATER TO FORM CAUSTIC SODA, NAPHTHALENE, SMALL AMOUNTS OF HYDROGEN/OTHER POLYCYCLIC COMPOUNDS. Conditions to Avoid Polymerization:MOISTURE/HALOGENATED COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF LIQUID/SOLIDS IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYDROGEN PEROXIDE (30-50%),11189,H 323 500 CAGE:1B464 CAGE:60777 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN PEROXIDE (SARA 302) CAS:7722-84-1 RTECS #:MX0900000 Fraction by Wt: 30 - 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:1 PPM; 9495 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50 - 70% Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE. EYES:PRODUCES IRRITATION, INFLAMMATION, PAIN. SKIN:MAY CAUSE SEVERE IRRITATION, BURNS, ULCERATION. ORAL:MAY CAUSE PERFORATION OF GI TRACT, POSSIBLE DEATH. INHALE:MAY CAUSEIRRITATION OF RESPIRATORY TRACT WITH PAIN. CHRONIC- MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION, TEARING, BLURRING VISION, ULCERATION, BURNS, COUGH, DIFFICULTY IN BREATHING, SHORTNESS OF BREATH, PAIN, SHOCK, UNCONSCIOUSNESS, DEATH Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:IMMEDIATELY FLUSH SKIN WITH WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. INHALE D:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK 2 GLASSES OF MILK OR WATER. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:10 Upper Limits:100 Extinguishing Media:WATER ONLY. NO DRY CHEMICAL, CARBON DIOXIDE OR HALON. FLUSH AWAY WITH WATER. Fire Fighting Procedures:WEAR NIOSH-APPROVED(+)PRESSURE SELF-CONTAINED BREATHING APPARATUS + FULL FACEPIECE. FOR MASSIVE FIRE, USE UNMANNED HOSE HOLDER. MOVE CONTAINERS AWAY IF POSSIBLE Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH CLOTHING OR COMBUSTIBLE MATERIALS MAY CAUSE FIRE. CONTACT WITH ORGANIC VAPORS OR LIQUIDS MAY CAUSE FIRE OR EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA. ABSORB ON SAND, VERMICULITE OR SIMILAR MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. FLUSH SPILL AREA WITH WATE R. Neutralizing Agent:DILUTE WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, WELL-VENTILATED AREA AWAY FROM SUNLIGHT, FLAME AND INCOMPATIBLE MATERIALS. Other Precautions:DANGER! STRONG OXIDIZER AND CORROSIVE. AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PR OMPTLY. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED RESPIRATOR. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:FULL COVER WORK CLOTHES, EYEWASH STATION, EMERGENCY SHOWER Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health NOTE TO PHYSICIAN:IF SWALLOWED, LARGE AMOUNT OF OXYGEN MAY BE RELEASED QUICKLY. THE DISTENSION OF THE STOMACH OR ESOPHAGUS MAY BE INJURIOUS. INSERTION OF A GASTRIC TUBE MAY BE ADVISABLE. ================== Physical/Chemical Properties ================== HCC:D3 Boiling Pt:B.P. Text:225F,107C Melt/Freeze Pt:M.P/F.P Text:-26F,-32C Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:23 @ 30C Vapor Density:1.0 Spec Gravity:1.1 TO 1.2 pH:2.5- 3 Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, REDUCING AGENTS, ALKALINE MATERIALS, ACETIC ACID/ANHYDRIDE, ACETONE, ALCOHOLS+SULFURIC ACID Stability Condition to Avoid:EXCESS HEAT, LIGHT Hazardous Decomposition Products:OXYGEN GAS, HYDROGEN GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. RINSE EMPTY CONTAINERS THOROUGHLY WITH CLEAN WATER BEFORE DISCARDING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GS-1 BLACK INK, 1301225 Preparer's Name:PETER GIMSE CAGE:IO074 CAGE:90316 CAGE:IO074 ============= Composition/Information on Ingredients ============= Ingred Name:4-HYDROXY-4-METHYL-2-PENTANONE; (1,2-PENTANONE, 4-HYDROXY, 4-METHYL). PERCENT:60-80 (WT). CAS:123-42-2 RTECS #:SA9100000 Fraction by Wt: SEE ING OSHA PEL:50 PPM ACGIH TLV:50 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT):4000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:MAY CAUSE DERMATITIS AND IRRITATION. EYES:MAY CAUSE REDNESS AND BLURRED VISION. INHAL:MAY CAUSE IRRITATION, DIZZINESS AND FATIGUE. INGEST:MAY CAUSE VOMITING, IRRITATION AND NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:MAY EFFECT KIDNEY AND LIVER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. INHAL:PROVIDE FRESH AIR AND REST. CALL A PHYSICIAN. INGEST:DRINK SEVERAL GLASSES OF WATER, INDUCE VOMITI NG. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:120F,49C Lower Limits:0.9% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . A STRAIGHT STREAM OF WATER COULD SPREAD FIRE. Unusual Fire/Explosion Hazard:EXPLOSION SENSITIVE TO IMPACT. SENSITIVE TO STATIC. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB ON INERT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM ALL SOURCES OF IGNITION. Other Precautions:ALL COMPONENTS OF THIS PRODUCT ARE LISTED IN THE EPA'S INVENTORY OF CHEMICAL SUBSTANCES AS REQUIRED UNDER THE TOXIC SUBSTANCES CONTROL ACT (TSCA). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR IS RECOMMENDED. Ventilation:VENTILATION IS NEEDED TO KEEP VAPOR CONCENTRATION BELOW TLV LEVEL. Other Protective Equipment:OIL RESISTANT FOOTWEAR. WEAR PROTECTIVE CLOTHING AS NEEDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:180F,82C Vapor Density:HVR/AIR Spec Gravity:0.9948 @ 78F Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE Appearance and Odor:BLACK LIQUID WITH A SOLVENT ODOR. Percent Volatiles by Volume:85% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:AVOID OPEN FLEMS AND SPARKS. Hazardous Decomposition Products:CO, CO*2, HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CORROSION X MARINE Preparer's Name:DAVID WORRALL CAGE:0JV14 CAGE:0JV14 ============= Composition/Information on Ingredients ============= Ingred Name:HIGHLY REFINED BASE OIL; (BASE STOCK) CAS:72623-85-9 OSHA PEL:5 MG/M3(OIL MIST)MFR ACGIH TLV:N/K Ingred Name:MINERAL OIL; (BASE STOCK) CAS:72623-83-7 OSHA PEL:5 MG/M3(OIL MIST)MFR ACGIH TLV:N/K Ingred Name:KEROSENE; (HYDROCARBON SOLVENT) CAS:8008-20-6 RTECS #:OA5500000 OSHA PEL:100 PPM (VAPOR) MFR ACGIH TLV:N/K Ingred Name:STODDARD SOLVENT; (HYDROCARBON SOLVENT) CAS:8052-41-3 RTECS #:WJ8925000 OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9495 Ingred Name:ZINC DINONYLNAPHTHALONESULFONATE CAS:29016-00-4 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:BASED ON TOXICITY OF PETROLEUM DISTILLATE ONLY. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:CLOTHING AND SHOES/BOOTS WITH DETERGENT. APPLY MILD HAND CREAM IF HANDS BECOME DRY OR CHAPPED. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:MILK TO DRINK. SEE AID FOR PHYSICIAN. NOTE TO MD: CONSULT STANDARD LITERATURE RE:HYDROCARBON POISONING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 1400 PPM Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:ESSENTIALLY NON-IRRITATING, HOWEVER, VAPORS AND/OR MISTS CAN CAUSE MILD TO MODERATE IRRITATION. SEVERITY OF REACTIONS DEPENDS UPON DURATION OF EXPOSURE & FIRST AID PROCEDURES ADMISTERED. OVER EXPO SURE MAY CAUSE EYES TO BECOME RED &/OR WATERY. SKIN:ESSENTIALLY NON-IRRITATING. LD50 ABSORBTION FOR(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:SKIN IS 2000 MG/KG. PRLNG/RPTD CNTCT W/SKIN HAS NOT BEEN CAUSE OF DEFAT/DERM IN NORM DAY TO DAY HANDLG OF MATL. EFTS OF OVEREXP MAY BE DRY, CHAPPED SKIN. INHAL:CAN CAUSE IRRIT TO NOSE & THROA T & UPPER RESP TRACT DURING PRLNG EXPOS, BUT NOT NORMALLY. EXERCISE CAUTION IF VAP ARE HOT. IF OVER-EXPOS (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE EXCESS BY WIPING & FOLLOW BY WASHING W/SOAP & H*2O UNTIL THERE IS NO ODOR. EYE:FLUSH W/COPIOUS QTY OF H*2O FOR AT LEAST 15 MIN. LIFT EYELIDS & FLUSH INSIDE. SEE MD IF EYES BECOME INFLAMED. INHAL:EVACUATE FOR FRESH AIR. APPLY CPR IF REQD. IF RESUSCITATION IS REQD, ASSESSMENT BY MD IS MANDATORY. INGEST:DO NOT INDUCE VOMIT. IF IT OCCURS, TAKE CARE TO PVNT ASPIR. GIVE 1/2 PINT OF (ING 8) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>260F,>127C Lower Limits:1.0% Upper Limits:6.0% Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . COVER W/EXTING AGENT. DO NOT SPRAY W/H*2O USING DIRECT STREAM INTO BURNING LIQ AS THIS MAY SPREAD (SUPDAT) Unusual Fire/Explosion Hazard:TREAT AS A COMBUSTIBLE LIQUID. DO NOT FLAME CUT, DRILL OR WELD THE EMPTY CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM SOURCES OF IGNIT. STOP/REDUCE FLOW BY MEANS OF DYKE/BARRICADE. ABSORB SMALL SPILLS USING DRY CLAY/COMMERCIAL ABSORB. COLLECT RESIDUE INTO SUITABLE CONTAINER FOR PROPER DISPOSAL. MATL MAY BE WASHE D INTO FLOOR DRAINS EQUIPPED WITH OIL INTERCEPTOR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED UNLESS ATOMIZING IN ENCLOSED OR CONFINED SPACES. USE NIOSH/MSHA APPROVED ORGANIC MIST VAPOR RESPIRATOR. Ventilation:PROVIDE SUFFICIENT VENT BY MEANS OF GENERAL/MECHANICAL MEANS TO ENSURE THAT EXPOS LEVELS ARE KEPT BELOW COMBUSTIBLE LIMS Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH FACE & HANDS W/SOAP & H*2O AFTER USE, ESP BEFORE EATING/SMOKING/USING REST ROOM FACILITIES. LAUNDER SOILED (ING 7) Supplemental Safety and Health SOL IN H*2O:SLIGHTLY EMULSIFIABLE. FIRE FIGHT PROC:FIRE. USE H*2O SPRAY/MIST TO COOL FIRE. EFTS OF OVEREXP:OCCURS-MAY CAUSE DIZZ/HDCH/NAUS. BASED ON TOX OF COMPONENTS. INGEST:MAY BE HARMFUL/FATAL IF I NGEST. CAN CAUSE SEV IRRIT OF MOUTH, THROAT & ESOPHAGUS. CAN CAUSE NAUS, VOMIT/GI UPSET. MAY CAUSE DIARR. (ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:8 @ 25C Vapor Density:>1 Spec Gravity:0.868 (H*2O =1) Evaporation Rate & Reference:<1 (BUTYL ACETATE = 1) Solubility in Water:SUPDAT Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:<9(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS SUCH AS LIQUID OR COMPRESSED OXYGEN OR PEROXIDES OR CHLORINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BURNING PRODUCES NORMAL BI-PRODUCTS OF COMBUSTION INCLUDING: CARBON MONOXIDE, PHENOLS, OR PETROLEUM PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN AN APPROVED LANDFILL SITE OR INCINERATE AS A LICENSED WASTE RECLAIMING FACILITY. LIQUID WASTE MAY BE REMOVED BY MEANS OF LICENSED RECLAIMER UNDER USED OIL CLASSIFICATION. BE SURE TO FOLLOW ALL LOCAL, STATE, & FEDERAL REQUIREMENTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OIL STAIN;A48 V 111 CLEAR BASE AND STAIN CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHA, MEDIUM ALIPHATIC;FP=140F CAS:64742-88-7 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM; Z-2 ACGIH TLV:S, 50 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9394 Ingred Name:HYDROTREATED LIGHT PETROLEUM DISTILLATE CAS:64742-47-8 Fraction by Wt: 65-75% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:MAY CAUSE IRRITATION.INHAL:MAY IRRITATE UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE PERMANENT BRAIN OR NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:VAPORS ACTS AS AN ANESTHETIC;MAY CAUSE LIGHTHEADEDNESS. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING. GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:95.0F,35.0C Lower Limits:0.9 Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SHUT OFF LEAK IF SAFE.DIKE.SOAK UP WITH A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER CONTAINER FOR DISPOSA L.WASH SPILL AREA TO REMOVE SLIPPINESS. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS AND FLAMES.USE ONLY IN A VENTILATED AREA.DO NOT SMOKE.KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:USE APPROVED GROUNDING BONDING PROCEDURES WHEN TRANSFERRING LIQUIDS.THIS ITEM CONTAINS NUISSANCE PARTICLES WHICH MAY BE PRESENT DURING SANDING OR ABRAIDING OF THE DRIED FILM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR DUST FROM SANDING OR ABRAIDING DRIED FILM,USE A NIOSH RESPIRATOR FOR DUST.FOR VAPORS USE A NIOSH RESPIRATOR FOR ORGANIC VAPORS. Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:222-416F Vapor Density:>1 AIR=1 Spec Gravity:0.841 Evaporation Rate & Reference:<1 ETHER=1 Solubility in Water:NOT REPORTED Appearance and Odor:LIQUID;COLOR AND ODOR NOT REPORTED Percent Volatiles by Volume:85-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.THIS ITEM MUST BE TESTED FOR IGNITABILITY IN ORDER TO ASSIGN THE PROPER EPA HAZARDOUS WASTE NUMBER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:00714402 BENADRYL INJECTION 50 MG/ML Preparer's Name:ROY MUELLER CAGE:EO180 CAGE:EO180 CAGE:2T119 ============= Composition/Information on Ingredients ============= Ingred Name:DIPHENHYDRAMINE HYDROCHLORIDE CAS:147-24-0 RTECS #:KR7000000 Other REC Limits:0.5 MG/CUM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 500 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HAS BEEN REPORTED TO PRODUCE CONTACT DERMATITIS FOLLOWING TOPICAL APPLICATION. FROM "CONTACT DERMATITIS"; 'ANTIHISTAMINES CAN READILY SENSITAIZE SKIN FOLLOWING TOPICAL USE OR OCCUPATIONAL EXPOSURE.' Explanation of Carcinogenicity:NOT FOUND CARCINOGENIC IN RATS Effects of Overexposure:SKIN: RASH, ITCHING. Medical Cond Aggravated by Exposure:NO INFORMATION GIVEN ON MSDS BY MFR. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER FOR 15 MINUTES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN:WASH WITH SOAP & WATER UNTIL FREE OF RESIDUE. INGESTION:GET IMMEDIATE MEDICAL ATTENTION. INHALATION:REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. ACCIDENTAL INJECTION:GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:"NO DATA FOUND" Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND BUNKER GEAR. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP OR MOP SPILLED MATERIAL. WASH ALL CONTAMINATED SURFACES WITH SOAP AND WATER. PLACE WASTE IN A CONTAINER FOR FUTURE DISPOSAL. USE CARE IN THE CLEANUP OF BROKEN GLASS OR DROPPED SYRINGES. Neutralizing Agent:NO INFORMATION GIVEN ON MSDS BY MFR. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AS STATED ON LABEL. HANDLE IN SUCH A WAY AS TO AVOID SKIN AND EYE CONTACT. SHOULD CONTACT OCCUR, WASH CONTAMINATED SKIN PROMPTLY. Other Precautions:LAUNDER CONTAMINATED CLOTHING AND CONTAMINATED EQUIPMENT BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:NONE NORMALLY REQUIRED. Other Protective Equipment:NO INFORMATION GIVEN ON MSDS BY MFR. Work Hygienic Practices:MFR: ?HMIS:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health THERAPUTIC CLASS: ANTIHISTIMINE. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Spec Gravity:1.005-1.007 pH:N/D Solubility in Water:FREELY SOLUBLE Appearance and Odor:LIQUID CLEAR SOLUTION; ODOR:NO DATA FOUND ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INFORMATION GIVEN ON MSDS BY MFR. Stability Condition to Avoid:UNDER LABELED STORAGE CONDITIONS, THIS PRODUCT IS STABLE AND HAZARDOUS POLYMERIZATION SHOULD NOT OCCUR. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN; HYDROGEN CHLORIDE Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS A MEDICAL WASTE I/A/W FEDERAL, STATE & LOCAL REGULATIONS OR AUTHORITY HAVING JURISDICTION. INCINERATION IN A PERMITTED INCINERATOR IS THE PREFERRED DISPOSAL METHOD.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLYCHLORINATED BIPHENYLS Preparer's Name:PAUL R MICHAEL, SAFETY CAGE:3Y784 CAGE:01002 CAGE:3Y784 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: MODERATELY IRRITATING TO EYE TISSUES. SKIN: CAN BE ABSORBED THROUGH INTACT SKIN. MAY CAUSE DEFATTING. A POTENTIAL FOR CONTACTING CHLORACNE. INHALATION: POSSIBLE LIVER INJURY. INGESTION: SLIGH TLY TOXIC. Explanation of Carcinogenicity:IARC: PROBABLE CARCINOGENIC. NTP: REASONABLY ANTICIPATED TO BE CARCINOGENIC. Effects of Overexposure:CAN CAUSE DERMATOLOGICAL SYMPTOMS; HOWEVER, THESE ARE REVERSIBLE UPON REMOVAL OF EXPOSURE SOURCE. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE IMMEDIATELY WITH COPIOUS QUANTITIES OF RUNNING WATER FOR AT LEAST 15 MIN IF LIQUID OR SOLID PCBS GET INTO THEM. SKIN:CONTAMINATED CLOTHING SHOULD BE REMOVED AND THE SKIN WASHED THOROUG HLY WITH SOAP AND WATER. HOT PCBS MAY CAUSE THERMAL BURNS. INHALATION: REMOVE TO FRESH AIR. IF SKIN RASH OR RESPIRATORY IRRITATION PERSISTS, CONSULT A PHYSICIAN. (IF ELECTRICAL EQUIPMENT ARCS OVER, P CBS MAY DECOMPOSE TO PRODUCE HYDROCHLORIC ACID). INGESTION: CONSULT A PHYSICIAN. DO NOT INDUCE VOMITING OR GIVE ANY OILY LAXATIVES. (IF LARGE AMOUNTS ARE INGESTED, GASTRIC LAVAGE IS SUGGESTED). ===================== Fire Fighting Measures ===================== Flash Point:>141.C, 285.8F Extinguishing Media:PCBS ARE FIRE-RESISTANT COMPOUNDS. Fire Fighting Procedures:STANDARD FIRE FIGHTING WEARING APPAREL AND SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN WHEN FIGHTING FIRES THAT INVOLVE POSSIBLE EXPOSURE TO CHEMICAL COMBUSTION PRODUCTS. FIRE FIGHTING EQUIPMEN T SHOULD BE THOROUGHLY CLEANED AND DECONTAMINATED AFTER USE. Unusual Fire/Explosion Hazard:IF A PCB TRANSFORMER IS INVOLVED IN A FIRE-RELATED INCIDENT, THE OWNER OF THE TRANSFORMER MAY BE REQUIRED TO REPORT THE INCIDENT. CONSULT AND FOLLOW APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:CLEANUP & DISPOSAL OF LIQUID PCBS ARE STRICTLY REGULATED BY THE FEDERAL GOVERNMENT. VENTILATE AREA. CONTAIN SPILL/LEAK. REMOVE SPILL BY MEANS OF ABSORPTIVE MATERIAL. SPILL CLEANUP PERSONNEL SHOULD USE PROPER PROTECTIVE CLOTHING. ALL WASTES AND RESIDUES CONTAINING PCBS SHOULD BE COLLECTED, CONTAINERIZED, MARKED AND DISPOSED OF IN THE MANNER PRESCRIBED BY EPA, & APPLICABLE STATE AND LOCAL LAWS. ======================Handling and Storage ====================== Handling and Storage Precautions:CARE SHOULD BE TAKEN TO PREVENT ENTRY INTO THE ENVIRONMENT THROUGH SPILLS, LEAKAGE, USE, VAPORIZATION, OR DISPOSAL OF LIQUID. AVOID PROLONGED BREATHING OF VAPORS OR MISTS. AVOID CONTACT WITH EYES OR P ROLONGED CONTACT WITH SKIN. COMPLY WITH ALL FEDERAL, STATE, AND LOCAL REGULATIONS. Other Precautions:FEDERAL REGULATIONS UNDER THE TOXIC SUBSTANCES CONTROL ACT REQUIRE PCBS, PCB ITEMS, STORAGE AREAS, TRANSFORMER VAULTS, AND TRANSPORT VEHICLES TO BE MARDED. SEE 40 CFR 761 FOR DETAILS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED EQUIPMENT WHEN AIRBORNE EXPOSURE LIMITS ARE EXCEEDED. FULL FACEPIECE EQUIPMENT IS RECOMMENDED AND, IF USED, REPLACES NEED FOR FACE SHIELD AND/OR BY NIOSH/MSHA OR THE MANUFACTURER MUST BE OBSERVED. Ventilation:PROVIDE NATURAL OR MECHANICAL VENTILATION TO CONTROL EXPOSURE LEVELS BELOW AIRBORNE EXPOSURE LEVELS. SKIN CONTACT. AVAILABLE. Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLOTHING. PROVIDE A SAFETY SHOWER AT ANY LOCATION WHERE SKIN CONTACT CAN OCCUR. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:Z3 Vapor Pres:(MM HG @100F).005-.00006 Viscosity:(CENTISTOKES)3.6-540 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:PCBS ARE VERY STABLE, FIRE-RESISTANT COMPOUNDS. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE, PHENOLICS, ALDEHYDES AND OTHER TOXIC COMBUSTION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT THE APPLICABLE STATE AND LOCAL REGULATIONS PRIOR TO ANY DISPOSAL OF PCBS OR PCB-CONTAMINATED ITEMS. CONSULT WITH 40 CFR PART 761 FOR FEDERAL REQUIREMENTS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TARGO CAGE:98443 CAGE:9D824 CAGE:98443 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III) CAS:71-55-6 RTECS #:KJ2975000 Fraction by Wt: 28.0% OSHA PEL:350 PPM/450 STEL ACGIH TLV:350 PPM/450STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ozone Depleting Chemical:1 Ingred Name:TRICHLOROETHYLENE (SARA III) CAS:79-01-6 RTECS #:KX4550000 Fraction by Wt: 8.0% OSHA PEL:100 PPM/100 STEL ACGIH TLV:50 PPM/100,A5STEL;93 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:2-ETHOXYETHANOL (EGEE) (SARA III) CAS:110-80-5 RTECS #:KK8050000 Fraction by Wt: 4.0% OSHA PEL:S,200 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE HEADACHE,DIZZINESS,NAUSEA,VOMITING;REDNESS OR BURNS OF EYES/SKIN POSSIBLE.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATITIS. Explanation of Carcinogenicity:IARC LISTS TRICHLOROETHYLENE AS HAVING LIMITED EVIDENCE OF ANIMAL CARCINOGENITY. Effects of Overexposure:EYE:IRRITATION. SKIN:IRRITATION,DEFATTING. INHALED:RESPIRATORY IRRITATION,DROWSINESS. INGESTED:NOT REPORTED. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F/93C Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:NONE NOTED;FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOS Unusual Fire/Explosion Hazard:NONE NOTED;FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY NEEDED;USE NIOSH/MSHA APPROVED RESPIRATOR AS REQUIRED IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:149F/66C Spec Gravity:1.1 Solubility in Water:HIGHLY SOLUBLE Appearance and Odor:LIGHT YELLOW TO LIGHT AMBER LIQUID,SLIGHTLY SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN TO MFR. Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION PLUS HYDROGEN CHLORIDE AND POSSIBLE PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PX-1,REMANUFACTURED (BLACK) CAGE:0S0F8 CAGE:0S0F8 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLATE COPOLYMER Fraction by Wt: 55 - 65% Other REC Limits:NONE RECOMMENDED Ingred Name:IRON OXIDE CAS:1317-61-9 Fraction by Wt: 30 - 40% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:SALICYLIC ACID CHROMIUM (III) CHELATE CAS:72869-85-3 Fraction by Wt: 1 - 3% Other REC Limits:0.5 MG/M3 AS CR(MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, RESPIRATORY TRACT. ACUTE- EYES:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN:LOW HAZARD FOR INDUSTRIAL HANDLING. INHALE:GASPING. ORAL:EXPECTED TO BE A LOW INGESTIO N HAZARD. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TRANSIENT EYE IRRITATION, GASPING, COUGHING Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH AIR. EYES:FLUSH WITH PLENTY OF WATER, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED. Unusual Fire/Explosion Hazard:AS WITH ANY FINELY DIVIDED ORGANIC SOLID, DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS AND IN THE PRESENCE OF AN IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:CAREFULLY, SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER CARTON. CLEAN SPILL AREA THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILL OF POWDERED TONERS. THE VE RY FINE PARTICLES CAN CAUSE A FIRE OR EXPLOSION. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE AWAY FROM STRONG OXIDIZING AGENTS. MINIMIZE DUST GENERATION AND ACCUMULATION. Other Precautions:AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 4-6 RM VALUME/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH BEFORE EATING OR DRINKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:212-302F Spec Gravity:1.4 - 1.5 Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER - SLIGHT PLASTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:DUST FORMATION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF IRON ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NICAD AIRCRAFT BATTERY CAGE:09052 CAGE:09052 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL OXIDE CAS:1313-99-1 RTECS #:QR8400000 Fraction by Wt: 18% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 AS NI ACGIH TLV:1 MG/M3 AS NI Ingred Name:POTASSIUM HYDROXIDE (CERCLA) 30% SOLUTION CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 19% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CADMIUM OXIDE (SARA 302/313) (CERCLA) CAS:1306-19-0 RTECS #:EV1925000 Fraction by Wt: 13% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 MG (CD)/M3 DUST ACGIH TLV:0.01 MG(CD)/M3; 9495 Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 9% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1MG/M3 FUME/1 DUST ACGIH TLV:0.2 MG/M3 FUME; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NYLON 11, CAS:25587-80-8 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50 NONE STATED Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:UNDER NORMAL CONDITIONS OF USE, NO EXPOSURE TO HAZARDOUS COMPONENTS EXISTS. OVEREXPOSURE TO ELECTROLYTE SOLUTION: SKIN- MAY CAUSE SERIOUS BURNS. INGESTION:DAMAGE TO MOUTH, THROAT & GI TRACT. INHALATIO N OF FUMES MAY CAUSE RESPIRATORY SYSTEMIRRITATION. CHRONIC: METALS-SKIN SENSITIZATION,PULMONARY EDEMA, KIDNEY DAMAGE. Explanation of Carcinogenicity:CADMIUM AND NICKEL ARE REASONABLY ANTICIPATED TO BE CARCINOGENIC (NTP). NICKEL CARCINOGENIC TO HUMAN (IARC) Effects of Overexposure:CONTACT WITH ELECTROLYTE:IRRITATION, BURNS. IF INCINERATED, CHEST PAIN, COUGHING, SWEATING CHILLS, SHORTNESS OF BREATH AND WEAKNESS. Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISORDERS, PROSTATE DISORDERS, LIVER AND KIDNEY DISORDERS (FROM METAL FUMES) ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED. EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIS T. INGESTION:DO NOT INDUCE VOMITING, DRINK 1-2 GLASSES OF WATER. GET MEDICAL HELP IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE-PIECE OPERATED IN POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:TOXIC METAL OXIDE FUMES MAY BE EVOLVED DURING BURNING. ================== Accidental Release Measures ================== Spill Release Procedures:UNDER NORMAL CONDITIONS OF USE, HAZARDOUS COMPONENTS WILL NOT BE RELEASED. IF POTASSIUM HYDROXIDE ELECTROLYTE IS SPILLED, NEUTRALIZE WITH MILD ACID THEN FLUSH WITH WATER. Neutralizing Agent:DILUTE ACID ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREAK OPEN BATTERY CASE; DO NOT MUTILATE OR SHORT CIRCUIT CASE; DO NOT INCINERATE OR OVERCHARGE. Other Precautions:USE ADEQUATE LOCAL EXHAUST VENTILATION WHEN HANDLING THE LIQUID IN THE BATTERY, I.E., POTASSIUM HYDROXIDE SOLUTION. IF CASE IS BROKEN OPEN, ELECTROLYTE IS CORROSIVE ON CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST FUMES Ventilation:GOOD ROOM VENTILATION IS REQUIRED. Other Protective Equipment:IF INVOLVED IN FIRE, FULL PROTECTIVE CLOTHING. Work Hygienic Practices:FOLLOWING CONTACT WITH INTERNAL BATTERY COMPONENTS, WASH HANDS THOROUGHLY BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health NONE GIVEN BY THE MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:B1 Spec Gravity:1.25-1.3 KOH Solubility in Water:COMPLETE FOR KOH Appearance and Odor:BATTERY WITH NYLON CASE CONTAINS POTASSIUM HYDROXIDE SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT ADD ACIDS, KOH WILL REACT WITH ALUMINUM, ZINC, TIN AND OTHER REACTIVE METALS, CHLORINATED HYDROCARBONS. Stability Condition to Avoid:NONE STATED BY THE MANUFACTURER. Hazardous Decomposition Products:METAL OXIDE FUMES MAY BE EVOLVED AT TEMPERATURES ABOVE MELTING POINT. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER. IF DISCARDED, TREAT AS RCRA HAZARDOUS WASTE. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DICLOXACILLIN SODIUM Preparer's Name:WILLIAM M HELLER CAGE:14128 CAGE:14128 ============= Composition/Information on Ingredients ============= Ingred Name:DICLOXACILLIN SODIUM MONOHYDRATE CAS:13412-64-1 RTECS #:XH8925000 Ingred Name:DICLOXACILLIN CAS:3116-76-5 Ingred Name:DICLOXACILLIN SODIUM *94-3* CAS:343-55-5 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 3579 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ALLERGIC REACTION , IRRITATION OF RESPIRATORY TRACT/MUCOUS MEMBRANES, HARMFUL. EYES: IRRITATION. SKIN: ALLERGIC REACTION/IRRITATION/HARMFUL IF ABSORBED. POSSIBLE HYPERSENSITIZATIION. INGES TION: ALLERGIC REACTION. ANAPHYLACTIC SHOCK FOLLOWING A ONE-MICROGRAM TEST DOSE. (SEE SUPP) Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, RASH, LABORED BREATHING, HIVES, ITCHING, WHEEZING, NAUSEA, CHILLS, FEVER. Medical Cond Aggravated by Exposure:HYPERSENSITIVE TO PENICILLIN/CEPHALOSPORINS/GRISEOFULVIN/PENICILLAMINE, ALLERGIES, ASTHMA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. INGESTION: FLUSH MOUTH OUT W/WATER. ANAPHYLACTIC SHOCK CAN BE MANAGED BY EPINEPHRINE. OBTAIN ME DICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2, FOAM AS APPROPRIATE FOR SURROUNDING FIRE/MATERIALS. Fire Fighting Procedures:EVACUATE AREA. WEAR SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:MATERIAL IS ASSUMED TO BE COMBUSTIBLE. AS W/ALL DRY POWDERS IT'S ADVISABLE TO GROUND MECHANICAL EQUIPMENT IN CONTACT W/DRY MATERIAL TO DISSIPATE STATIC. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROVED RESPIRATOR & CHEMICALLY APPROPRIATE CONTAINER FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHT CONTAINER. SHOULD BE HANDLED/STORED PER LABEL/OTHER INSTRUCTIONS TO ENSURE PRODUCT INTEGRITY. USE W/ADEQUATE VENTILATION. Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING. AVOID BREATHING DUST/MIST. USE W/ADEQUATE DUST CONTROL. DON'T PERMIT EATING/DRINKING/SMOKING NEAR MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): RECOMMENDED. Other Protective Equipment:APPROPRIATE LABORATORY APPAREL Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health INDIVIDUALS WORKING W/CHEMICALS SHOULD CONSIDER ALL CHEMICALS TO BE POTENTIALLY HAZARDOUS EVEN IF THEIR INDIVIDUAL HAZARDS MAY BE UNCHARACTERIZED/UNKNOWN. HEALTH HAZARDS CONT'D: ACCELERATED & LATE URT ICARIAL REACTIONS ARE MORE COMMON. ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:WHITE-OFF WHITE CRYSTALLINE POWDER W/VIRTUALLY NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:TOXIC FUMES, SODIUM OXIDE, NITROGEN OXIDES, SULFUR OXIDES, CHLORINE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:825 5549 KODAK FLEXICOLOR RA BLEACH REPLENISHER NR W/STARTER CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 60-65% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM FERRIC PROPYLENEDIAMINETETRAACETIC ACID CAS:111687-36-6 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM BROMIDE CAS:12124-97-9 RTECS #:BO9170000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:AMMONIUM NITRATE CAS:6484-52-2 RTECS #:BR9050000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING FOR INHALATION, SKIN CONTACT AND INGESTION. CONTACT WITH EYES MAY CAUSE TRANSIENT IRRITATION. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYES-MAY CAUSE TARNSIENT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSISTS. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. SKIN-WASH WITH SOAP AN D WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION- DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY CAUSE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG OXIDIZER. DRIED PRODUCT RESIDUE CAN ACT AS AN OXIDIZER. FIRE OR HIGH TEMPERATURE MAY CAUSE DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. STORE IN ORIGINAL CONTAINER. KEEP TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. DO NOT STORE OR SHIP W/COMBUST. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM COMBUSTIBLE MATERIALS. KEEP AWAY F ROM HEAT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE AND LAUNDER CONTAMINATED CLOTHING PROMPTLY. KEEP AWAY FROM HEAT. Supplemental Safety and Health KEEP CONTAINER TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F,>100C Decomp Temp:Decomp Text:419F,215C Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.20 pH:3.6 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, GREEN-BROWN; SLIGHT ACETIC ACID ODOR. Percent Volatiles by Volume:60-65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE, COMBUSTIBLE MATERIALS, STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS. LIBERATES FLAMMABLES Stability Condition to Avoid:STABLE; HOWEVER, MATERIAL CAN DECOMPOSE ABOVE 215C. AVOID TEMPERATURES ABOVE 115C. Hazardous Decomposition Products:AMMONIA, CHLORAMINE, CARBON DIOXIDE, CRABON MONOXIDE, OXIDES OF NITROGEN, HYDROGEN BROMIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED.
1
eyes_protection_mandatory