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===================== Product Identification ===================== Product ID:LACQUER S.G. C/N OLIVE DRAB 24084 ID 789406 Preparer's Name:W.A. ELLISON, OPRTNS MGR CAGE:PRATT CAGE:PRATT CAGE:61196 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTYL ACETATE (SARA III) CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 15% Other REC Limits:LFL 2.0 UFL 11.0 OSHA PEL:150 PPM ACGIH TLV:150 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 5% Other REC Limits:LFL 3.0 UFL 13.0 OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:NITROCELLULOSE CAS:9004-70-0 RTECS #:QW0975100 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED Ingred Name:LEAD CHROMATE (SARA 313) (OSHA-CEIL .1000 MG/CU.M.) CAS:7758-97-6 RTECS #:GB2975000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:.0500 MG/CU.M. ACGIH TLV:.0500 MG/CU.M. Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA III) CAS:117-81-7 RTECS #:TI0350000 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3/10 STEL ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: <5% Other REC Limits:LFL 2.0 UFL 11.0 OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10% Other REC Limits:LFL 1.0 UFL 7.0 OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:TALC (CONTAINING NO ASBESTOS) CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 RDUST ACGIH TLV:2 MG/M3 RDUST; 9192 Ingred Name:N-BUTYL ALCOHOL (SARA III) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 5% Other REC Limits:LFL 1.4 UFL 11.2 OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 5% Other REC Limits:LFL 1.0 UFL 6.7 OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PETROLEUM DISTILLATES (VAPOR PRESSURE 40 MMHG @ 20C) CAS:8002-05-9 RTECS #:SE7449000 Fraction by Wt: 10% Other REC Limits:LFL 1.7 UFL 8.6 OSHA PEL:100 PPM/525 MG/CU.M. ACGIH TLV:NONE ESTABLISHED Ingred Name:VOC. 4.91 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS 589 G/L LESS WATER CALCULATED RTECS #:9999999VO Other REC Limits:NONE SPECIFIED Ingred Name:VOC. 18.33 LB/GAL SOLIDS 2200 G/L SOLIDS CALCULATED RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CRYSTALLINE SILICA-PNEUMOCONIOSIS, A DISABLING LUNG DISEASE. XYLENE-INJURY TO LIVER/KIDNEYS/BLOOD. INSOLUBLE CHROMATES-LUNG CANCER. LEAD-SEVERE DAMAGE TO BLOOD FORMING/NERV/URINARY/REPRODUCT SYST. SYM PTOMS;LOSS OF APPETITE,METALLIC TASTE,ANXIETY,CONSTIPATION,NAUSEA,WEAK,INSOMINA,HEADACHE,MUSCLE & JOINT PAIN (SEE FILE) Explanation of Carcinogenicity:CRYSTALLINE SILICA HAS LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS & SUFFICIENT EVIDENCE IN EXPERIMENTAL ANIMALS. Effects of Overexposure:SWALLOW:GASTROINTESTINAL IRRIT,NAUSEA,VOMIT.ASPIRATION INTO LUNGS, POSSIBLE CHEM PNEUMONITIS, CAN BE FATAL. INHALED:NOSE OR THROAT IRRIT, HIGH CONCENTRATE MAY CAUSE ACUTE CENTRAL NERV SYST DEPRESS,HEA DACHES,DIZZ,NAUSEA & CONFUSION. EYES:IRRIT. SKIN:LIQ MATERIAL MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. DEFATT & IRRIT. Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY EXPOSURES TO CRYSTALLINE SILICA. PRE-EXISTING KIDNEY CONDTIONS MAY BE AGGRAVATED BY EXPOSURE TO LEAD. ======================= First Aid Measures ======================= First Aid:SWALLOW:DONOT INDUCE VOMIT. CALL POISON CONTROL/HOSPITAL/DR. INHALED:REMOVE TO FRESH AIR IMMED. IF BREATH STOPPED, GIVE CPR. KEEP WARM/QUIET. GET MED ATTN. EYES:FLUSH W/LG AMTS OF H2O LIFTING LIDS FOR AT LEAST 15 MINS. GET MED ATTN. SKIN:REMOVE CONTAM CLOTHES. WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MED ATTN IF IRRIT PERSIST. NOTE TO DR.:DIRECT TREATMENT AT CONTROL OF SYMPTOMS/CLINICAL CONDITION ===================== Fire Fighting Measures ===================== Flash Point:20 F/-7 C Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS DESIGNED FOR FLAMMABLE LIQUID FIRES. POLYMER FOAM IS PREFERRED FOR LARGE FIRES. Fire Fighting Procedures:USE WATER TO COOL EXPOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP/AUTO-IGNITE/EXPLOSION FROM EXTREME HEAT. IF WATER USED, FOG NOZZLES ARE PREFERABLE. Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. WARNING! FLAMMABLE! ================== Accidental Release Measures ================== Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM IGNITE SOURCES. DIKE & CONTAIN W/MATERIAL(E.G. SAND,ETC)TRANSFER LIQ TO COVERED METAL CONTAINER FOR RECOVERY/DISPOSAL. REMOVE W/INERT ABSORB. USE ONLY NON-SPARK TOOLS. PREVE NT CONTAM OF SEWERS,GROUNDWATERS W/MATERIAL/ABSORB ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 95 F. STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106. CLOSE CONTAINER AFTER EACH USE. Other Precautions:DON'T TAKE INTERNALLY. KEEP AWAY FROM CHILDREN. DON'T BREATHE SANDING DUST. EMPTY CONTAINERS MUST NOT BE WASHED & RE-USED AT ALL. GROUND & BOND CONTAINERS TO RECEIVING CONTAINERS. NEVER USE PRESSURE T O EMPTY. DRUM IS NOT A PRESSURE VESSEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WELL VENTED AREA ORGANIC CHEM MAY NOT REQUIRE USE OF RSPRTR. RESTRICTED VENT:CHEM CARTRIDGE RSPRTR MAYBE REQUIRED. SPRAY:USE MECH PREFILTER. CONFINED AREA:USE AIR SUPPLIED RSPRTR. IF TLV EXCEED USE PR OPERLY FITTED RSPRTR W/PROTECTION FACTOR Ventilation:GEN DILUTION/LOCAL EXHAUST VENT IN SUFFICIENT VOL/PATTERN TO KEEP CONCENTRATE OF HAZARD INGRED BELOW LOWEST LIMITS. ** Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT. SEE OSHA STANDARDS FOR LEAD. Work Hygienic Practices:WASH HANDS AND FACE THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health REMOVE DECOMP PRODUCTS THAT ARE GENERATED WHEN WELDING, CUTTING OR BRAZING OBJECTS COATED W/PRODUCT. WASTE RESIDUE OF PRODUCT MAY QUALIFY AS HAZARDOUS WASTE. IF PRODUCT IS DISCARDED DIRECTLY, WOULD BECLASSIFIED A HAZARDOUS WASTE BASED ON IGNITABILITY CHARACTERISTIC. RCRA CLASS WOULD BE D001. (SEE FILE FOR MORE INFO) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:139 TO 302F Vapor Density:> THAN AIR Spec Gravity:1.0 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS OR ALKALINE MATERIALS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF IGNITION. Hazardous Decomposition Products:BURNING WILL PRODUCE SMOKE, CARBON MONOXIDE/DIOXIDE, OXIDES OF NITROGEN/CHROMIUM/LEAD MAY BE GENERATED. MAY PRODUCE * Conditions to Avoid Polymerization:KEEP FROM HEAT & FLAME. *METAL OXIDES, OVEREXP MAY RESULT IN "METAL FUME FEVER" FLU-LIKE ILLNESS(SEE FILE FOR MORE INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL LAWS. INCINERATE ONLY EPA PERMITTED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. OBSERVE PRECAUTIONS FOR DISPOSAL OF FLAMMABLE MATERIALS. CONTAMINAT ED ABSORB MAY BE DISPOSED IN HAZARD WASTE LANDFILL
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:9754 PED CAGE:0X6L2 CAGE:0X6L2 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:PUT ON SAFETY GLASSES, NOSE & MOUTH SUITABLE ABSORBENT. CLEAN AREA W/DETERGENT, THEN DISINFECTANT & FINALLY A WATER RINSE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT TEMPERATURE INDICATED IN PRODUCT LABELING. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERALLYY NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. Other Protective Equipment:IF RISK OF SPLASH/DROPLET GENERATION, USE MOUTH & NOSE PROTECTION. Supplemental Safety and Health DISINFECT PORTION OF EQUIPMENT THAT HAS COME IN CONTACT W/THIS MATERIAL BEFORE PERFORMING REPAIR & MAINTENANCE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON DISULFIDE, 99.9+% HPLC GRADE 27066-0 CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON DISULFIDE (SARA III) CAS:75-15-0 RTECS #:FF6650000 Fraction by Wt: 99.9%+ OSHA PEL:20 PPM ACGIH TLV:S, 10 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE SUPP DATA Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED/INHALED OR ABSORBED THRU SKIN. VAP/MIST IS IRRIT TO EYES, MUC MEMB/UPPER RESP TRACT. CAUSES SKIN IRRIT. EXPOS CAN CAUSE: DMG TO KIDNEYS/LIVER/HEART. MAY CAUSE NERV SYS DIST URBANCES. MAY CAUSE CONVULSIONS. CHRONIC: OVEREXP MAY CAUSE REPROD DISORDER(S) BASED ON TEST W/LAB (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: ANIMALS. LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES & SKIN: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING PROMPTLY. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHIN G GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-29F,-34C Lower Limits:1.3% Upper Limits:50% Extinguishing Media:WATER SPRAY. CO*2, DRY CHEMICAL POWDER, ALCOHOL OR POLYMER FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:DANGER: EXTREMELY FLAM. VAP MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS AND HEAVY CONTAINERS FOR DISPOSAL. VENT AR EA AND WASH SPILL SITE AFTER MATL PICKUP. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPOR. KEEP TIGHTLY CLOSED. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. MAY EXPLODE WHEN HEATED. MAY DEVELOP PRESSURE. Other Precautions:DO NOT GET IN EYES, ON SKIN OR CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY ABSORBED THRU SKIN. TOXIC. IRRITANT. POSSIBLE MUTAGEN/TERATOGEN. REPRODUCTIVE HAZ. NEUROLOGICAL HAZ. STENCH. REFR IGERATE. CAUTION: CONT (SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES . Supplemental Safety and Health LD50-LC50 MIX: LD50:(ORAL,RAT) 3188 MG/KG, (ORAL,MUS) 2780 MG/KG, (ORAL,RBT) 2550 MG/KG, (ORAL,GPG) 2125 MG/KG. OTHER PREC: WITH AZIDES OR ACTIVE METALS SUCH AS SODIUM, POTASSIUM, ZINC, ETC., MAY CAUS E FIRES AND EXPLOSIONS. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:115F,46C Melt/Freeze Pt:M.P/F.P Text:-170F,-112C Vapor Pres:400.0 @28C Vapor Density:2.67 Spec Gravity:1.266 Evaporation Rate & Reference:22.6 (BUTYL ACETATE = 1) Solubility in Water:2 G/L @ 20C Appearance and Odor:COLORLESS LIQUID, W/MILD SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS & AMINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO, CO*2 & SO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL L AWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CHLOROFORM 04770, C606RS28 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:CHLOROFORM (SARA 302/313) (CERCLA). LD50: (ORAL, RAT) 908 MG/KG. CAS:67-66-3 RTECS #:FS9100000 Fraction by Wt: >99% OSHA PEL:50 PPM, C ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:EFTS OF OVEREXP: TESTS W/LAB ANIMALS. CHRONIC INGEST MAY CAUSE LIVER DMG. PRLNGD/RPTD SKIN CONTACT MAY CAUSE (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: DERMATITIS. PRLNGD/RPTD EXPOS MAY CAUSE ADVERSE REPRO EFTS. MAY CAUSE FETAL EFTS. CHRONIC EXPOS HAS BEEN (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: ASSOC W/INCREASED INCIDENCE OF KIDNEY, LIVER, RECTAL, BLADDER, COLON, BRAIN & LYMPH NODE CANCER. TOXICITY (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: MAY BE INCREASED BY EXPOS TO ALCOHOL, STEROIDS & KETONES. TARGET ORGANS: KIDNEYS, HEART, CNS, LIVER, GI (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: SYSTEM, EXCRETORY SYSTEM. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: CAUSES CARD SENSIT TO ENDOGENOUS CATELCHOLAMINES WHICH MAY LEAD (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: TO CARD ARRHYTHMIAS. DO NOT USE ADRENERGIC AGENTS SUCH AS EPINEPHRINE OR PSEUDOEPINEPHRINE. ANTIDOTE: NO (ING 8) RTECS #:9999999ZZ Ingred Name:ING 9: SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: CONTACT W/LIQ OR VAP CAUSES SEV BURNS & POSS IRREVERSIBLE EYE DMG. VAPS MAY CAUSE EYE IRRIT. SKIN: MAY CAUSE IRRIT W/BURNING PAIN, ITCHING & REDNESS. INGEST: MAY CAUSE CNS DEPRESS, KIDNEY DMG & L IVER DMG. MAY CAUSE GI IRRIT W/NAUS, VOMIT & DIARR. MAY CAUSE CARD DISTURBS. ASPIR OF MATL INTO LUNGS (EFTS OF OVEREXP) Explanation of Carcinogenicity:CHLOROFORM: IARC MONO, SUPP, VOL 7, PG 152, 1987:GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:ANTIC TO BE CARCIN. Effects of Overexposure:HLTH HAZ: MAY CAUSE CHEM PNEUMIT WHICH MAY BE FATAL. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON & COMA. CAUSES RESP TRACT IRRIT. MAY CAUSE LIVER & KIDNEY DMG. MAY CAUSE CARD SENSIT & POSS FAILURE. CHRONIC: OVEREXP MAY CAUSE DELAYED KIDNEY INJURY. POSS CANCER HAZ BASED ON (ING 2) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LST 15 MIN, OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB OR KEEP EYES CLOSED. SKIN: GET MED AID. RINSE AREA W/LARGE AMTS OF WATER FOR AT LEAST 15 MIN. REMOVE CONTAM CLTHG & SHOES. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. POSS ASPIR HAZ. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL OR FOAM. USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . SUBSTANCE IS NONFLAMMABLE. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED. ABSORB SPILL WITH INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. DO NOT GET ON SKIN OR IN EYES. AVOID INGEST & INHAL. Other Precautions:DO NOT STORE IN DIRECT SUNLIGHT. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM ACIDS. DO NOT STORE NEAR ALKALINE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENT TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MATL TO AVOID: ACID, PHOSPHORUS PENTOXIDE, POTASSIUM, POTASSIUM HYDROXIDE, METHYL ALCOHOL, POTASSIUM TERT-BUTOXIDE, SODIUM, SODIUM HYDROXIDE, SODIUM METHYLATE, SODIUM-POTASSIUM ALLOY, TRIISOPROPYLPHOS PHINE, CALCIUM HYDROXIDE, FLUORINE, & ANY STRONG OXIDIZERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:143F,62C Melt/Freeze Pt:M.P/F.P Text:-82F,-63C Vapor Pres:160 Vapor Density:4.12 Spec Gravity:1.5 (H*2O=1) Evaporation Rate & Reference:11.6 (BUTYL ACETATE=1) Solubility in Water:INSOL (0.5% @ 77F) Appearance and Odor:CLEAR, COLORLESS LIQUID; SWEET, FRUITY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETONE, ALKALIS, ALUMINUM, DISILANE, LITHIUM, MAGNESIUM, DINITROGEN DIOXIDE, NITROGEN TETROXIDE, PERCHLORIC (SUPDAT) Stability Condition to Avoid:STABLE AT ROOM TEMP IN CLOSED CNTNRS UNDER NORMAL STORAGE & HNDLG CNDTNS. AVOID HIGH TEMPS, INCOMPATIBLE MATLS, LIGHT. Hazardous Decomposition Products:HYDROGEN CHLORIDE, CARBON DIOXIDE, CHLORINE, PHOSGENE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. CAS #67-66-3 IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA; RCRA D-SERIES WASTE NUMBER D022; RCRA U-SERIES WASTE NUMBER U0 44.
1
eyes_protection_mandatory
======================================================= NIIN: 01-456-2971 Product ID: VCI-110 EMITTER Cage: 44695 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: INHIBITOR,CORROSION,VAPOR BARRIER Specification Number: NONE Type/Grade/Class: NONE Unit of Issue: EA UI Container Qty: 0 Type of Container: PACKAGE ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NOT PROVIDED Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EFFECTS OF OVEREXPOSURE: EYE CONTACT WITH THIS PRODUCT MAY PRODUCE IRRITATION. REPEATED OR PROLONGED CONTACT MAY CAUSE MILD SKIN IRRITATION. INHALATION OF PRODUCT VAPORS IS NOT EXPECTED TO POSE A SIGN IFICANT HEALTH HAZARD DUE TO THE LOW VAPOR PRESSURE OF THE PRODUCT. INGESTION OF THIS PRODUCT MAY BE HARMFUL. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: EYE CONTACT WITH THIS PRODUCT MAY PRODUCE IRRITATION. REPEATED OR PROLONGED CONTACT MAY CAUSE MILD SKIN IRRITATION. Medical Cond Aggravated By Exposure: NONE KNOWN First Aid: EYE CONTACT: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. INHALATION: REMOVE T O AN UNCONTAMINATED AREA; ADMINISTER OXYGEN IF NECESSARY. IF VICTIM HAS STOPPED BREATHING BEGIN CPR. GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, GIVE WATER OR MILK AND INDUCE VOMITING. GET IMMEDIA TE MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COLLECT AS NORMAL SOLID WASTE. Neutralizing Agent: NOT RELEVANT Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH EXISTING FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. Handling And Storage Precautions: KEEP STORAGE CONTAINERS TIGHTLY CLOSED. STORE IN A COOL DRY PLACE. STORE AWAY FROM FOODSTUFFS. Other Precautions: AVOID EYE CONTACT AND PROLONGED OR REPEATED SKIN CONTACT. WORKERS SHOULD THOROUGHLY WASH HANDS WITH SOAP AND WATER PRIOR TO EATING, DRINKING, SMOKING AND USING LAVATORY. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: N.E Lower Limits: N.E Upper Limits: N.E Extinguishing Media: WATER, CARBON DIOXIDE OR OTHER DRY CHEMICAL FIRE FIGHTING AGENTS. Fire Fighting Procedures: FIREFIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard: POLYURETHANE FOAM BURNS VERY RAPIDLY FORMING THICK SMOKE AND POSSIBLE TOXIC DECOMPOSITION PRODUCTS. ======================================================= Control Measures ======================================================= Ventilation: NOT PROVIDED Work Hygienic Practices: NOT PROVIDED Supplemental Safety and Health: PRODUCT DESCRIPTION: AN ADHESIVE-BACKED POLYURETHANE FOAM WITH A PROPRIETARY CORROSION INHIBITOR. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 B.P. Text: NOT ESTABLISHED Decomp Text: NOT PROVIDED Vapor Pres: NOT ESTABLISHED Vapor Density: N.E. Evaporation Rate & Reference: NOT ESTABLISHED Solubility in Water: NOT PROVIDED Appearance and Odor: YELLOW, OPEN CELL FOAM, SLIGHT ODOR. Corrosion Rate: NOT PROVIDED ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: CONTACT WITH INCOMPATIBLE MATERIALS. Materials To Avoid: STRONG ACIDS, ALKALIS AND OXIDIZING AGENTS. Hazardous Decomposition Products: FOAMS PRODUCE TOXIC PRODUCTS WHICH ARE NOT SIGNIFICANTLY DIFFERENT FROM THOSE OF OTHER NITROGEN-CONTAINING POLYMER SUCH AS WOOL, LEATHER, NYLON. TOXICANTS ARE CARBON MONOXIDE, NOX, HYDROGEN CYANIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NONE ======================================================= Toxicological Information ======================================================= Toxicological Information: INGREDIENT #2 ORAL LD50=560 MG/KG (RAT). ======================================================= Ecological Information ======================================================= Ecological: NOT PROVIDED ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= Sara Title III Information: NOT PROVIDED Federal Regulatory Information: TSCA STATUS: LISTED. State Regulatory Information: NOT PROVIDED ======================================================= Other Information ======================================================= Other Information: NONE ======================================================= Transportation Information ======================================================= Trans ID NO: 153297 Product ID: VCI-110 EMITTER Review Date: 09/22/2000 Net Unit Weight: 0.004 LB Multiple KIT Number: 0 Unit Of Issue: EA Container QTY: 0 Type Of Container: PACKAGE Additional Data: NOT REGULATED FOR TRANSPORTATION, PER MSDS. ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: VCI-110 EMITTER Cage: 44695 Company Name: THE CORTEC CORPORATION Street: 4119 WHITE BEAR PKY Zipcode: 55110-7634 Label Required IND: Y Date Of Label Review: 09/22/2000 Status Code: C MFG Label NO: NOT PROVIDED Year Procured: 2000 Origination Code: F Skin Protection IND: NO Signal Word: CAUTION Respiratory Protection IND: NO Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: TARGET ORGANS: NOT PROVIDED. FIRST AID: EYE CONTACT: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN. SKIN CONTACT: WASH AFFECTED AREA WITH SOAP AND WATER. IF IRRITATION PERSISTS, C ONSULT A PHYSICIAN. INHALATION: REMOVE TO AN UNCONTAMINATED AREA; ADMINISTER OXYGEN IF NECESSARY. IF VICTIM HAS STOPPED BREATHING BEGIN CPR. GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, GIVE WATER OR MILK AND INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. SPILL: COLLECT ASNORMAL SOLID WASTE. FIRE: WATER, CARBON DIOXIDE OR OTHER DRY CHEMICAL FIRE FIGHTING AGENTS. FIREFIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. =======================================================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:156 5415 BLEACH REPLENISHER MX 1341 TO MAKE 5 LITRES Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50-55% Ingred Name:AMMONIUM BROMIDE *97-2* CAS:12124-97-9 Fraction by Wt: 30-35% Ingred Name:POTASSIUM NITRATE CAS:7757-79-1 RTECS #:TT3700000 Fraction by Wt: 5-10% Ingred Name:ACETIC ACID (GLACIAL), ETHANOIC ACID *98-2* CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1-5% OSHA PEL:25 MG/CUM ACGIH TLV:25 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION/SKIN: LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION/SKIN: LOW HAZARD FOR INDUSTRIAL HANDLING. EYES: IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE AGENT APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE W/BAKING SODA (SODIUM BICARBONATE). FLUSH MATERIAL TO SEWER W/PLENTY OF WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED & AWAY FROM ALKALI. DRIED PRODUCT RESIDUE CAN INCREASE THE BURNING RATE OF COMBUSTIBLE MATERIALS. Other Precautions:AVOID CONTACT W/CLOTHING, OTHER COMBUSTIBLE MATERIALS, SKIN & EYES. ============= Exposure Controls/Personal Protection ============= Ventilation:GOOD GENERAL SHOULD BE SUFFICIENT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Vapor Pres:18 Vapor Density:0.6 Spec Gravity:1.31 pH:2.5 Solubility in Water:COMPLETE Appearance and Odor:CLEAR WATER-WHITE SOLUTION W/VINEGAR ODOR. Percent Volatiles by Volume:55/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALI, COMBUSTIBLE MATERIALS Stability Condition to Avoid:FIRE OR EXCESSIVE HEAT Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, AMMONIA, BROMINE, & HYDROGEN BROMIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE, OR LOCAL LAWS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:POLANE ORDNANCE CATALYST, V66VC207 CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP:10.00 CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 15% OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE) (CERCLA) VP:0.05 CAS:822-06-0 RTECS #:MO1740000 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:HEXAMETHYLENE DIISOCYANATE POLYMER VP:0.00 CAS:3779-63-3 Fraction by Wt: 85% OSHA PEL:15 MG/M3 TDUST (MFR) ACGIH TLV:10 MG/M3 TDUST (MFR) Ingred Name:WASTE DISP METH:WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:VENT:OSHA STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT, & PERS PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRES S. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. SIGNS & SYMPS:REDNESS & ITCHING/BURNING SENSATION (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZS:MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. HDCH, DIZZ, NAUS, & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. CHRONIC:PRLNGD OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO BLOOD FORMING SYS. PERSONS SENSITIVE TO ISOCYANATES WILL EXPER INCREASED ALLERGIC RXN ON RPTD EXPOS. RPTS HAVE (SUPDAT) Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE AREA AND GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER, IMMEDIATELY GET MEDICAL ATTENTION. SKIN:WASH AFFECTED AREA THOROUGHLY WITH S OAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:98.0F,36.7C Lower Limits:1.4% Upper Limits:7.6% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD (SUPDAT) Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMED APPARENT. OBTAIN MEDICAL ATTENTION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNIT SOURCES. VENT AREA. ALL PERS IN AREA SHOULD BE PROTD AS IN CTL MEASURES. COVER SPILL W/ABSORB MATL. DEACTIVATE SPILLED MATL W/10% AMMONIUM HYDROXIDE SOLN (HOUSEHOLD AMMONIA). AFTER 10 MINS, COLLECT IN OPEN CNTNRS & ADD MORE (SUP DAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO PERSON SHOULD USE THIS PROD, OR BE IN AREA WHERE IT IS BEING USED, IF THEY HAVE CHRONIC LUNG/BRTHG PROBLEMS/IF THEY EVER HAD RXN TO ISOCYANATES. Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN INGS) WHICH MAY BE PRESENT AT HAZ LEV ELS ONLY DURING SANDING/ABRADING(SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO (ING 6) Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. MATLS TO AVOID:BURSTING OF, CLSD CNTNRS. EFTS OF OVEREXP:ASSOC RPTD & PROLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. SPILL PROC:AMMONIA. COVER LOOSELY. WASH AREA W/SOAP & WATER. OTHER PRECS:OF DRIED FILM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>255F,>124C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.10 VOC Pounds/Gallon:164 VOC Grams/Liter:1.37 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:19 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTAM W/WATER, ALCOHOLS, AMINES & OTHER CMPDS WHICH REACT W/ISOCYANATES, MAY RSLT IN DANGEROUS PRESS IN, & POSS(SUPDAT) Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, POSSIBILITY OF HYDROGEN CYANIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RESOURCE CONSERVATION & RECOVERY ACT (RCRA) 40CFR261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE #'S. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISP OF IN ACCORD (ING 5) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:699 LIQUITEX ARTIST ACRYLIC COLORS IN TUBES & JARS Preparer's Name:PHILLIP E MOLL CAGE:EO269 CAGE:85419 CAGE:EO269 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN BY IARC-GROUP 3) *94-4* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:SILICON DIOXIDE, CELITE 322 CAS:7631-86-9 RTECS #:VV3100000 OSHA PEL:80 MG/CUM ACGIH TLV:0.2 MG/CUM Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Ingred Name:2-AMINO-2-METHYL-1-PROPANOL CAS:124-68-5 RTECS #:UA5950000 Ingred Name:VOLATILE ORGANIC COMPOUNDS: COATING LESS WATER 1-1.5 LB/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WIPE OFF EXCESS & FLUSH W/WARM WATER & SOAP. INHALATION: REMOVE TO FRESH AIR & TREAT SYMPTOMATICALLY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>250F Lower Limits:NONE Upper Limits:NONE Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP FOR USE/DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE NEAR EXTREME HEAT. USE W/ADEQUATE VENTILATION. Other Precautions:DON'T INHALE DUST/SPRAY FROM AIRBRUSH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH CERTIFIED RESPIRATOR FOR LARGE QUANTITIES OF PAINT, AIRBRUSHING & SANDING DRIED PRODUCT. Ventilation:ADEQUATE TO CONTROL FUMES, VAPOR & DUST CONCENTRATIONS. Other Protective Equipment:PROTECTIVE CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F Melt/Freeze Pt:M.P/F.P Text:<32F Vapor Pres:17-20 Vapor Density:>1 Spec Gravity:1.1-1.6 Evaporation Rate & Reference:(BU AC = 1): <1 Solubility in Water:DISPERSES Appearance and Odor:VISCOUS COLORED LIQUID W/SLIGHT ACRYLATE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:EXTREME HEAT. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FORMULA 444 KLING 'N KILL CAGE:53798 CAGE:53798 ============= Composition/Information on Ingredients ============= Ingred Name:AROMATIC SOLVENT CAS:64742-95-6 Fraction by Wt: <47.29% Other REC Limits:100 PPM OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALIPHATIC PETROLEUM DISTILLATE (KEROSENE) CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 24.21% Other REC Limits:500 PPM OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2,4-BIS(ISOPROPYLAMINO)-6-METHOXY-S-TRIAZINE (PROMETONE) CAS:1610-18-0 RTECS #:XY4200000 Fraction by Wt: 3.12% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED.LONG TERM EXPOSURE TO LOW LEVELS OF THE MATERIAL IS NOT KNOWN TO CAUSE ANY ILL EFFECTS IN HUMANS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:IRRITATION.SKIN:POSSIBLE IRRITATION AND MAY BE ABSORBED.INGESTION:HARMFUL OR FATAL IF SWALLOWED.INHALATION:INHAL OF VAPORS MAY CAUSE HEADACHE,DIZZINESS,DROWSINESS AND NAUSEA. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH IMMED W/ LOTS OF COOL WATER FOR AT LEAST 15 MIN.GET MEDICAL ATTN.SKIN:FLUSH W/ WATER & WASH W/ SOAP & WATER.REMOVE & WASH CONTAM CLTHG.WASH HAIR & UNDER FINGERNAILS IF AFFECTED.CONTACT MD I F CONT INVOLVES LRG AMT OR IF EXPOS IS PRLNGD.INGEST:DO NOT INDUCE VOMIT.CALL MD IMMED.INHALATION:MOVE TO FRESH AIR.PROVIDE ARTIFICIAL RESPIRATION IF REQUIRED.GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:MINIMUM 125F,52C Lower Limits:N/K Upper Limits:N/K Extinguishing Media:FOAM,CARBON DIOXIDE,DRY CHEMICAL.WATER MAY BE INEFFECTIVE. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .WATER MAY BE INEFFECTIVE IN FIRE FIGHTING,CONTAINS PETROLEUM DISTILLATES. Unusual Fire/Explosion Hazard:NONE KNOWN.HAZARDOUS DECOMPOSITION PRODUCTS:CARBON MONOXIDE,PROPANE AND OTHER HYDROCARBONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF HEAT AND OPEN FLAME.VENTILATE AREA.DO NOT CONTAMINATE WATER,FOOD OR FEED.ABSORB ALL EXCESS MATERIAL. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE >32F,0C OR NEAR HEAT,SPARKS,OPEN FLAME OR NEAR FERTILIZERS,SEEDS,INSECTICIDES OR FUNGICIDES.DO NOT CONTAM WATER,FOOD OR FEED BY (SEE SUP) Other Precautions:WARNING:AVOID ALL CONTACT.TOX TO FISH.DO NOT APPLY DIRECTLY TO ANY BODY OF WATER,WHERE RUNOFF IS LIKELY OR WHEN WEATHER FAVORS DRIFTING.DO NOT CONTAM WATER BY CLEANING OF EQUIP OR WASTE DISP.KEEP CHIL DREN/ANIM AWAY UNTIL DRY.(SEE SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOC & GENERAL VENT NECESSARY TO KEEP AIR CONC BELOW LEVEL OF CONCERN .DO NOT USE INDOORS OR IN CONFINED AREA. Other Protective Equipment:EYEWASH STATION OR SOURCE OF CLEAN WATER NEARBY IN CASE OF ACCIDENTAL EYE CONTACT.RUBBER BOOTS ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING OR BEFORE EATING,DRINKING OR SMOKING. Supplemental Safety and Health % VOLATILES BY WEIGHT:>80.HNDLG/STOR PREC:STOR OR DISP.DO NOT USE ON LAND TO BE CROPPED OR NEAR DESIRABLE PLANTS,INJURY IS POSS.AVOID APPLIC TO AREA UNDERLAID BY ROOTS OF &/OR DRIFTING TO DESIRABLE TR EES.OTHER PREC:READ & FOLLOW ALL LABEL DIRECTIONS & PREC BEFORE USE.FOR INDUS USE ONLY.KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:N/K Spec Gravity:0.899 (WATER=1) Evaporation Rate & Reference:N/K Solubility in Water:EMULSIFIES Appearance and Odor:A CLEAR AMBER LIQUID WITH AROMATIC SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,STRONG BASES. Stability Condition to Avoid:HEAT,SPARKS AND OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE,PROPANE AND OTHER HYDROCARBONS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .THIS PRODUCT HAS A FLASHPOINT OF 125-130F.OPEN DUMPING IS PROHIBITED.FOLLOW ALL LABEL DIRECTIONS FOR DISPOSAL.DO NOT REUS E EMPTY CONTAINERS.
1
eyes_protection_mandatory
======================================================= Product ID: SILICONE OIL Cage: 4T252 Box: 907 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 4T252 Box: 907 ======================================================= Contractor Summary ======================================================= Cage: 4T252 Box: 907 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: IRRITATION. Explanation Of Carcinogenicity: NONE First Aid: EYES: FLUSH IMMEDIATELY W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ABSORB W/PAPER. Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY PLACE AWAY FROM OXIDIZERS. AVOID EYES, SKIN CONTACT. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: OC Flash Point Text: >400F Extinguishing Media: ALCOHOL FOAM, CO2 ======================================================= Control Measures ======================================================= Ventilation: ADEQUATE Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: > 300.2 F Vapor Pres: <5 Spec Gravity: 0.98 Solubility in Water: NEGLIGIBLE Appearance and Odor: COLORLESS LIQUID, W/SLIGHT ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXTREME HEAT Materials To Avoid: OXIDIZERS Hazardous Decomposition Products: TOXIC FUMES, SILICON DIOXIDE, CO, CO2 Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SILICONE OIL Cage: 4T252 Company Name: HACH COMPANY Street: 100 DAYTON RD. PO Box: 907 Zipcode: 50010 Label Required IND: Y Date Of Label Review: 12/28/1993 Status Code: C Label Date: 12/28/1993 Origination Code: F Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: Slight Hazard And Precautions: EYES: IRRITATION. TARGET ORGANS: EYES. INHALATION: IRRITATION OF THE NOSE & THROAT. SKIN: MILD IRRITATION, DERMATITIS. EYES: IRRITATION, CONJUNCTIVITIS, INCREASED CORNEAL PERMEABILI TY. INGE =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:45319 COSTAR CAGE:GO535 CAGE:12120 CAGE:GO535 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB * 96-1 * CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: <5% Other REC Limits:25 PPM (SKIN) OSHA PEL:50 PPM (SKIN) ACGIH TLV:25 PPM (SKIN) Ingred Name:ACETIC ACID (ETHYLENEDIAMINETETRAACETIC ACID), EDTA CAS:60-00-4 RTECS #:AH4025000 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:VOLATILE ORGANIC CONTENT: 43 GMS/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE BURNING. INHALATION: IRRITATION OF NASAL PASSAGES. INGESTION: GASTROINTESTINAL DISTURBANCES. SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:REDNESS, TEARING, BURNING, NAUSEA, HEADACHE, IRRITATION, GI DISTURBANCES, DRYNESS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINS. INHALATION: MOVE TO FRESH AIR. INGESTION: DILUTE BY GIVING 2 GLASSES OF WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. SKIN: WASH THOROUGHLY W/SOAP & WAT ER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:NONE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:MOP UP MATERIAL/PICK UP W/ABSORBENT MATERIAL. RINSE W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE RESPIRATOR. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DON'T INHALE MIST/SPRAY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:LOCAL EXHAUST Other Protective Equipment:EYEWASH, PROTECTIVE CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.07 pH:12 Solubility in Water:COMPLETE Appearance and Odor:CLEAR YELLOW-GREEN LIQUID W/LEMON ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:10-EDAM CAGE:PHARR CAGE:PHARR ============= Composition/Information on Ingredients ============= Ingred Name:10-ETHYL-10-DEAZA-AMINOPTERIN Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 1127 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:10-EDAM IS HIGHLY TOXIC. MAY CAUSE BLOOD DAMAGE & MAY PRESENT A REPRODUCTIVE HAZARD. IS AN ANALOGUE OF METHOTREXATE. MAY CAUSE MUCOSITIS, MYELOSUPPRESSION, GI TOXICITY & ELEVATED LIVER ENZYMES. SLIGHT LY MUTAGENIC. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN RASH, FATIGUE Medical Cond Aggravated by Exposure:PERSONS W/PULMONARY, CARDIOVASCULAR, HEPATIC/RENAL DISORDERS/ACTIVE SEVERE INFECTION MAY BE AT INCREASED RISK. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH SKIN W/PLENTY OF SOAP & WATER. INHALATION: REMOVE TO CLEAN AIR. IF NOT BREATHING, GIVE CPR/OXYGEN IF NECESSARY. OBTAIN MEDICA L ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MATERIALS APPROPRIATE TO THE SURROUNDING FIRE. Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. USE SELF CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR SCBA, RUBBER BOOTS, HEAVY COMPOUND USING HEPA VACUUM, PLACE IN SUITABLE CONTAINER, HOLD FOR WASTE DISPOSAL. AVOID RA ISING DUST. VENTILATE AREA & WASH SITE AFTER USE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS AT ROOM TEMP. MATERIAL SHOULD BE HANDLED ONLY BY THOSE TRAINED IN HANDLING HAZARDOUS MATERIAL. Other Precautions:AVOID CONTACT & INHALATION. AVOID PROLONGED/REPEATED EXPOSURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-MSHA APPROVED RESPIRATOR. Ventilation:LAB OPERATIONS SHOULD BE CONDUCTED IN A CHEMICAL FUME HOOD, Other Protective Equipment:PROTECTIVE LABORATORY COAT/APRON, SAFETY SHOWER, EYE BATH Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:PALE YELLOW CRYSTALLINE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PASA-JELL 107-M CAGE:DO563 CAGE:83574 CAGE:DO563 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA III) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 17.0% OSHA PEL:2 PPM/4 STEL ACGIH TLV:2 PPM/4 STEL; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CHROMIUM (VI) OXIDE CAS:1333-82-0 RTECS #:GB6650000 Fraction by Wt: 2.0% OSHA PEL:C, 0.1 MG/M3 (CRO3) ACGIH TLV:0.05 MG/M3(CR); 8990 Ingred Name:HYDROFLUOSILICIC ACID CAS:16961-83-4 RTECS #:VV8225000 OSHA PEL:2.5 MG/CUM ACGIH TLV:2.5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Explanation of Carcinogenicity:CHROMIUM (+6) IS LISTED AS CARCINOGENIC. Effects of Overexposure:CAN PRODUCE SEVERE BURNS TO EYES & SKIN.CAUSES IRRITATION OF NOSE & THROAT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH LUKE WARM WATER FOR 15 MINUTES; SKIN:FLUSH WITH WATER; INH:REMOVE TO FRESH AIR,GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING,GIVE OXYGEN IF BREATHING IS DIFFICULT; ING:IRRIGATE MOUTH WIT H WATER,GIVE MILK OR WATER TO DRINK.DO NOT INDUCE VOMITING.CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:USE RESPIRATORY PROTECTION Unusual Fire/Explosion Hazard:HYDROGEN FLUORIDE MAY BE EVOLVED. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE WITH WATER.NEUTRALIZE WITH SODIUM CARBONATE OR SODA ASH. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN COOL,DRY AREA. Other Precautions:KEEP AWAY FROM OXIDIZABLE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE CHEMICAL CARTRIDGE RESPIRATOR IF EXCEEDS PEL. Ventilation:LOCAL EXHAUST ADEQUATE TO MINIMIZE VAPORS Other Protective Equipment:PROTECTIVE CLOTHING Supplemental Safety and Health 107-M PASA-JELL,UNLKIE 107 PASA-JELL,DOES NOT CONTAIN INORGANIC THICKENER PERMITTING IMMERSION OF LARGE SURFACES. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:200F Vapor Pres:19 Vapor Density:0.90 Spec Gravity:1.1 Evaporation Rate & Reference:<1.0,BUTYL ACETATE Solubility in Water:COMPLETE Appearance and Odor:RED LIQUID;PUNGENT ODOR. Percent Volatiles by Volume:UNK. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID EXPOSURE TO READILY OXIDIZABLE MATERIALS. Stability Condition to Avoid:AVOID EXPOSURE TO ORGANIC MATERIALS Hazardous Decomposition Products:OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NUMBER D-002,D-007. DISPOSE OF SPILLAGE IN COMPLIANCE WITH FEDERAL & STATE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMOCO CYLINDER OIL NO. 1000 Resp. Party Other MSDS Num.:02000777 Preparer's Name:R. G. FARMER, DIRECTOR CAGE:15958 CAGE:15958 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT REFINED PARAFFINIC PETROLEUM OIL CAS:64741-88-4 RTECS #:PY8040500 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:EYE: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED. SKIN: NONE EXPECTED FOR SINGLE SHORT-TERM EXPOSURES. PROLONGED OR REPEATED CONTACT MAY PRODUCE SOME IRRITATION. INHALATION: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED. INGESTION: EXPECTED TO BE RELATIVELY NON-TOXIC. Explanation of Carcinogenicity:NO COMPONENT OF THIS PRODUCT IS IDENTIFIED AS A CARCINOGEN BY NTP, IARC OR OSHA. Effects of Overexposure:EYE: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED. SKIN: NONE EXPECTED FOR SINGLE SHORT-TERM EXPOSURES. PROLONGED OR REPEATED CONTACT MAY PRODUCE SOME IRRITATION. INHALATION: NO SIGNIFICANT HEALTH HAZARDSIDENTIFIED. INGESTION: EXPECTED TO BE RELATIVELY NON-TOXIC. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH EYES WITH PLENTY OF WATER. SKIN: WASH EXPOSED SKIN WITH SOAP AND WATER. INHALATION: IF ADVERSE EFFECTS OCCUR, REMOVE TO UNCONTAMINATED AREA. INGESTION: IF A LARGE AMOUNT IS SWALLOWED, DO NO T INDUCE VOMITING, DRINK PLENTY OF WATER AND GET IMMEDIATE MEDICAL ATTENTION. NONE REQUIRED. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:=282.2C, 540.F Extinguishing Media:AGENTS APPROVED FOR CLASS B HAZARDS (E.G., DRY CHEMICAL, CARBON DIOXIDE, HALOGENATED AGENTS, FOAM, STEAM) OR WATER FOG. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. REMOVE MECHANICALLY OR CONTAIN ON ABSORBENT MATERIAL. TREAT AS AN OIL SPILL. REMOVE MECHANICALLY. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES ABOUT 130F (54C). Other Precautions:AVOID STRONG OXIDIZERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED; HOWEVER, USE OF ADEQUATE VENTILATION IS GOOD INDUSTRIAL PRACTICE. Ventilation:USE OF ADEQUATE VENTILATION IS GOOD INDUSTRIAL PRACTICE. INDUSTRIAL PRACTICE. Other Protective Equipment:WEAR PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. AVOID PROLONGED OR REPEATED SKIN CONTACT. Supplemental Safety and Health HMIS/NFPA CODES: (HEALTH;0) (FLAMMABILITY;1) (REACTIVITY;0). ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.91 Viscosity:205 SUS @ 210F Solubility in Water:NEGLIGIBLE, BELOW 0.1% Appearance and Odor:DARK-COLORED, VISCOUS LIQUID ================= Stability and Reactivity Data ================= AVOID STRONG OXIDIZERS. Stability Condition to Avoid:DANGEROUS REACTION: NONE IDENTIFIED. Hazardous Decomposition Products:INCOMPLETE BURNING CAN PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE AND OTHER HARMFUL PRODUCTS. =================== Toxicological Information=================== Toxicological Information:NO EXPOSURE LIMIT(S) ESTABLISHED. EYE: PRIMARY IRRITATION SCORE 2.0/110.0 (RABBITS). SKIN: PIMARY DERMAL IRRITATION SCORE 2.1/8.0 (RABBITS). ACUTE DERMAL LD50 GREATER THAN 2.0 G/KG (RABBITS). INGESTIO N: ACUTE ORAL LD50 GREATER THAN 10G/KG (RATS). NO COMPONENTS OF THIS PRODUCT IS IDENTIFIED AS A CARCINOGEN BY NTP, IARC OR OSHA. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, OR LOCAL REGULATIONS. ENCLOSED-CONTROLLED INCINERATION UNLESS DIRECTED OTHERWISE BY APPLICABLE AUTHORITY. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: NOT REGULATED. TRUCK/RAIL SHIPPING CLASS: PETROLEUM LUBRICATING OIL. ===================== Regulatory Information ===================== SARA Title III Information:CERCLA REPORTABLE QUANTITY: THIS PRODUCT IS NOT REPORTABLE UNDER 40 CFR PART 302.4. SARA STATUS: THIS PRODUCT IS NOT REGULATED UNDER SARA TITLE III, 42 USC 9601. Federal Regulatory Information:OSHA HAZARD COMMUNICATION STANDARD: NOT HAZARDUS PER CFR 1910.1200(D). RCRA STATUS: THIS PRODUCT IS NOT SUBJECT TO THE 40 CFR PART 268.30 LAND BAN ON THE DISPOSAL OF CERTAIN HAZARDOUS WASTES. TSCA STA TUS: ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. State Regulatory Information: ======================= Other Information =======================
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:90-S SUPER DEMON AIR WET SET CAGE:KO333 CAGE:KO333 CAGE:77317 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <45% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: <22% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: <65% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:SILICA GEL CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: <20% Other REC Limits:NONE RECOMMENDED OSHA PEL:6 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:ZIRCONIUM SILICATE CAS:14940-68-2 Fraction by Wt: <70% Other REC Limits:NONE RECOMMENDED ACGIH TLV:5 MG/M3 Ingred Name:GRAPHITE, NATURAL CAS:7782-42-5 RTECS #:MD9659600 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MPPCF RDUST ACGIH TLV:2 MG/M3 RDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE RESPIRATORY IRRITATION AND MAY AGGRAVATE BRONCHIAL DISORDERS. SKIN AND EYES MAY BE IRRITATED ON CONTACT. NO INGESTION HAZARDS LISTED BY MANUFACTURER. CHRONIC: PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION; INHALATION MAY CAUSE SILICOSIS (LUNG INJURY). Explanation of Carcinogenicity:CRYSTALLINE SILICA IS LISTED AS BY IARC AND NTP AS SHOWING LIMITED EVIDENCE OF CARCINOGENICITY. Effects of Overexposure:INHALATION: COUGHING, SNEZZING, SHORTNESS OF BREATH. EYES: REDNESS, DISCOMFORT. SKIN: REDNESS, DISCOMFORT. INGESTD: NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALED: MOVE TO FRESH AIR. EYES: FLUSH WITH LOTS OF WATER. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. IF ANY SYMPTOM PERSISTS, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:IMPROPER MIXING AND BAKE-OUT OF MATERIALS MAY RESULT IN STEAM SPALLING. DURING INITIAL HEATING, REFER TO MIXING INSTRUCTIONS/BAKE OUT SCHEDULES. ================== Accidental Release Measures ================== Spill Release Procedures:USE ROUTINE HOUSEKEEPING PROCEDURES, AVOID DUSTING, COLLECT MATERIAL IN CLOSED CONTAINERS OR BAGS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY AREA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF DUST CREATED AND ENGINEERING CONTROLS FAIL OR ARE NOT FEASIBLE; USE NIOSH/MSHA APPROVED RESPIRATOR WITH DUST CARTRIDGE. USE IN ACCORDANCE WITH 29 CFR 1910.134. Ventilation:USE ADEQUATE LOCAL AND/OR MECHANICAL VENTILATION. Other Protective Equipment:AS REQUIRED TO MEET OSHA STANDARDS. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V7 Spec Gravity:2.24-3.36 Solubility in Water:SLIGHT Appearance and Odor:GRANULAR AGGRAGATE & FINE POWDER MIX, GRAY, BROWN, OFF WHITE OR WHITE IN COLOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AIR BONDED MATERILAS MAY GENERATE SULFUR DIOXIDE AND/OR SULFUR OXIDE DURING BAKE-OUT. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO EPA (40CFR261.3) WASTES ARE NOT HAZARDOUS WASTES. WASTES MAY BE DISPOSED OF IN A LANDFILL, HOWEVER, IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POTASSIUM BROMATE CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BROMATE CAS:7758-01-2 RTECS #:EF8725000 Fraction by Wt: Other REC Limits: OSHA PEL: ACGIH TLV: ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:IRRIT TO UP RESP TRACT,COUGH & SHORT OF BREATH.INGEST:NAUSEA,VOMIT,DIARRHEA.ABD PAIN.REDU URINE OUTPUT.LOW BP.METHEMOGLOBINEMIA,CONVULSION.LIVER&KIDNEDAMAGE,COMA,CYANOSIS MAY OCCUR AS LATER SYMP TOM.DEATH MAY OCCUR FROM RENAL FAILURE W/IN 1 TO 2 WKS.EST.LETHAL DOSE 1GM.EYE:IRRIT/CORNEAL DAMAGE.CHRONIC:LIVER/KIDNEY Effects of Overexposure:SEE HEALTH HAZARDS(ACUTE & CHRONIC) Medical Cond Aggravated by Exposure:PERSONS W/ PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPARED LIVER,KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.GET MED ATT FOR ANY BREATH DIFFICULTY.INGEST:INDUCE VOMITING IMMED.GIVE TWO GLASSES OF H*2O & STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSO N.CALL PHYS.SKIN:WASH EXPOSED AREA W/SOAP & H*2O.GET MED ADVICE IF IRRIT DEVELOPS.EYE:WASH EYE W/ PLENTY OF H*2O FOR AT LEAST 15 MIN.LIFT LOWER & UPPER EYELIDS OCCASIONALLY.GET MED ATT IMMED. ===================== Fire Fighting Measures ===================== Flash Point: Lower Limits: Upper Limits: Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED SCBA W/FULL FACEPIECE OPERATED IN PRESS DEMAND OR OTHER POS.PRESS MODE.H*2O SPRAY KEEP FIRE EXPOS CONTR COOL. Unusual Fire/Explosion Hazard:NOT COMBUSTIBLE IS A STRONG OXIDIZER.HEAT OF REACTION W/ REDUC AGENT/COMBUST MAY CAUSE IGNITION.CONTACT W/ OXIDIZABLE SUBS.CAUSE EXTREME VIOLENT COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA.CLEAN UP PERSONNEL MAY REQUIRE RESP PROTECTION FROM DUST. SPILLS: SWEEP UP & CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPOSAL. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTR STORE IN A COOL,DRY VENT AREA.PROT AGAINST PHYSICAL DAMAGE.SEPARATE FROM COMBUSTIBLE,ORGANIC OR OTHER OXIDIZABLE MAT. Other Precautions:N/K ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED.COND OF USE WHERE EXPOS TO DUST IS APPARENT DUST/MIST RESP MAY BE WORN FOR EMERGENCIES A SCBA MAY BE USED. Ventilation:LOCAL EXHAUST WHICH CAPTURE THE CONTAM AT ITS SOURCE IS RECOMMENDED.PREVENT DISPERSION INTO THE WORK PLACE. Other Protective Equipment:CLEAN BODY-COVERING CLOTHING Work Hygienic Practices:OBSERVE GOOD WORK HYGIENIC PRACTICES. Supplemental Safety and Health SOL IN H*2O:20C.MAT TO AVOID:PHOSPHONIUM IODINE,PHOSPHORUS,LEAD ACETATE,SELENIUM & SULFUR.HLTH HAZ(ACUTE/CHRONIC)DAMAGE. ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:698F, 370C Melt/Freeze Pt:M.P/F.P Text:662F 350C Decomp Temp:Decomp Text: Vapor Pres:NO INFO Vapor Density:NO INFO Spec Gravity:3.27 pH: Evaporation Rate & Reference:NO INFO FOUND Solubility in Water:8G1100G H*2O AT68F Appearance and Odor:WHITE POWDER OR GRANULES ODORLESS Percent Volatiles by Volume: Corrosion Rate: ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS,REDUCING AGENTS,ORGANIC MAT,AL,ARSENIC,CALCIUM HYDRIDE,CARBON,COPPER,POWDER METALS,METAL SULFIDES (SEE SUP DATA) Stability Condition to Avoid: Hazardous Decomposition Products:EMITS OXYGEN & TOXIC FUMES OF BROMINE WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY.ENSURE COMPLIANCE W/ LOCAL,STATE & FED REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1-OCTEN-3-OL CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:1-OCTEN-3-OL CAS:3391-86-4 RTECS #:RH3300000 Fraction by Wt: 98% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 340 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: IRRITATION OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SKIN: IRRITATION. ABSORPTION HAZARD. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: WASH OUT MOUTH IF CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:142F Extinguishing Media:CO2, DRY CHEMICAL POWDER, APPROPRIATE FOAM Fire Fighting Procedures:WATER MAY BE INEFFECTIVE FOR EXTIGUISHING FIRE, BUT CAN BE USED TO COOL CONTAINERS. WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID ================== Accidental Release Measures ================== COVER W/DRY LIME OR SODA ASH. PICK-UP & KEEP IN CLOSED CONTAINER. VENTILATE AREA. WASH AREA AFTER CLEAN-UP. EVACUATE AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA. KEEP AWAY FROM HEAT & FLAME. KEEP TIGHTLY CLOSED. Other Precautions:AVOID BRATHING VAPORS & CONTACT W/EYES, SKIN, CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR Ventilation:CHEMICAL FUME HOOD Other Protective Equipment:SAFETY SHOWER & EYE BATH IN AREA Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WASH CONTAMINATED CLOTHING BEFORE RE-USE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:183.2-185F Spec Gravity:0.830 Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS & STRONG ACIDS Stability Condition to Avoid:HEAT, OPEN FLAME, & OTHER IGNITION SOURCES. Hazardous Decomposition Products:CO, CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:0870B1 PRO-SEAL 870 B-1/2 ACCELERATOR Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGENATED TERPHENYLS CAS:61788-32-7 RTECS #:WZ6535000 Fraction by Wt: 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 PPM ACGIH TLV:0.5 PPM; 9596 Ingred Name:DIPHENYL GUANIDINE OR GUANIDINE, N, N', DIPHENYL OR 1,3 DIPHENYL GUANIDINE, CAS:102-06-7 RTECS #:MF0875000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Fraction by Wt: 50% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:MAGNESIUM DICHROMATE CAS:13423-61-5 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.05 MG/M3 TWA Ingred Name:VOLATILE ORGANIC CONTENT (COMBINED TOTAL FOR PARTS A & B): 68 GR/L PER EPA METHOD 24. RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE RESPIRATORY IRRITATION; MANGESES OVEREXPOSURE MAY CAUSE "MANGANESE POISONING." CONTACT MAY CAUSE SKIN & EYE IRRITATION, ULCERS. INGESTION MAY BE HARMFUL; MAY CAUSE "MANGANE SE POISONING." CHRONIC: PROLONGED OR REPEATED EXPOSURE TO HEXAVALENT CHROMIUM COMPOUNDS(MANGANESE CHROMATE) MAY CAUSE C Explanation of Carcinogenicity:HEXAVALENT CHROMIUM COMPOUNDS ARE LISTED AS KNOWN CARCINOGENS BY IARC AND NTP. Effects of Overexposure:"MANGANESE POISONING": APATHY, INSMONIA, WEAKNESS IN LEGS, MUSCULAR TWITCHING, EMOTIONAL DISTRESS. SKIN-IRRITATION,ULCERS. EYES-IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES-FLUSH WITH WARM WATER FOR 15 MINUTES. SEE PHYSICIAN IF SYMPTOMS PERSIST. SKIN-WASH WITH MILD SOAP & WATER. CONSULT A PHYSICIAN IF SYMPTOMS PERSIST. INHALED-REMOVE TO FRESH AIR. CONSULT A PHYSICIA N IF SYMPTOMS PERSIST. INGESTED-CONSULTA PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:EXCESSIVE HEAT MAY CAUSE DECOMPOSITION OF MANGANESE DIOXIDE, RESULTING IN OXIDATION AND POSSIBLE IGNITION OF HYDROCARBON VEHICLE (HYDROGENATED TERPHENYL). ================== Accidental Release Measures ================== Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN-UP RESIDUE WITH A SUIATBLE SOLVENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM EASILY OXIDIZABLE MATERIALS. AVOID INGESTION. WASH THOROUGHLY AFTER HANDLING AND BEFORE SMOKING OR EATING. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCB A, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation:GENERAL VENTILATION. Other Protective Equipment:NONE KNOWN. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health KEY1=N1. PART B OF 2 PART SEALANT. THIS PART IS CATALYST FOR PRDUCT FOUND IN CARTRIDGE AND IS FOUND IN SEPARATE CONTAINER (UNKNOWN TYPE). ================== Physical/Chemical Properties ================== HCC:F3 Vapor Density:NONE Spec Gravity:1.93 Evaporation Rate & Reference:NON-VOLATILE Appearance and Odor:BLACK PASTE. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EASILY OXIDIZABLE MATERIALS. Stability Condition to Avoid:NOT KNOWN. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN, MANGANESE AND CHROMIUM COMPOUNDS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA/RCRA HAZWASTE NUMBER D007 MAY APPLY TO UNUSED/UNCONTAMINATED PRODUCT. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMDRY 960 CAGE:LO715 CAGE:LO715 CAGE:53654 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL-CHROME ALLOY,POWDER FORM Fraction by Wt: 95% ACGIH TLV:1.0 MG/CUM Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 5% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 ===================== Hazards Identification ===================== Effects of Overexposure:NOT KNOWN:AVOID INFLATION.ALLOY IS NON HAZARDOUS,PER MFG. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W LG AMTS H*2O UNTIL POWDER REMOVED;INHALE:REMOVE TO FRESH AIR,CONTACT DR. ===================== Fire Fighting Measures ===================== Extinguishing Media:N/A:NON FLAMMABLE Fire Fighting Procedures:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP,AVOID DUST GENERATION,NON HAZARDOUS TRASH. ======================Handling and Storage ====================== Handling and Storage Precautions:USE REASONABLE CARE.MFG NOTES THAT MATERIAL MAY BE STORED OUTSIDE & WILL NOT FREEZE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSED TLV,DUST:WEAR NIOSH APPR DUST MASK/DUST RESPIR. Ventilation:MECHANICAL(GEN/LOCAL EXHAUST)ADEQUATE TO KEEP DUST BELOW TLV Other Protective Equipment:NORMAL FULL WORK CLOTHING. NO CONTACT LENS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:8 Solubility in Water:NEGLIGIBLE Appearance and Odor:GREY POURABLE POWDER Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXCESSIVE DUSTING(FINE METAL POWDER) ==================== Disposal Considerations ==================== Waste Disposal Methods:NON HAZARDOUS TRASH.DISPOSE IN FULL ACCORD WITH APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:690, COPPER BASE ALLOYS IN RODS, BARS, (SUP CAGE:86924 CAGE:86924 ============= Composition/Information on Ingredients ============= Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 45-100% Other REC Limits:1 MG/M3 DUST/MIST OSHA PEL:0.1MG/M3 FUME ACGIH TLV:0.2MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC (SARA III) (LIMITS GIVEN AS ZN OXIDE) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: 0-43% Other REC Limits:5 MG/M3;10 STEL FUME OSHA PEL:10 MG/M3 TDUST;5RESP ACGIH TLV:10 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 0-15% OSHA PEL:15MG/M3 DUST;5 RESP ACGIH TLV:10MG/M3 DUST;5 FUME Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0-6% OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 0-5.5% OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 DUST/FUME EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 0-5% Other REC Limits:1 MG/M3;3 STEL FUME OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 0-33% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:PHOSPHOROUS (WHITE) (SARA III) CAS:7723-14-0 RTECS #:TH3500000 Fraction by Wt: 0-0.5% OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 0-4.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 Fraction by Wt: 0-11% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 Ingred Name:TELLURIUM; (TELLURIUM COMPOUNDS) (SARA III) CAS:13494-80-9 RTECS #:WY2625000 Fraction by Wt: 0-0.5% OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1 MG/M3 Ingred Name:SUPDAT:IRRIT SKIN/EYES IN BULK FORM. PARTICULATES MAY CAUSE DERM DUE TO MECHANICAL IRRIT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:NOTE:LEAD (CAS #7439-92-1) APPEARS ON THE NAVY LISTING OF OCCUP REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS REC . UNDER NORM AL HNDLG CONDTNS SOLID ALLOY PRESENTS NO SIGNIFICANT HLTH HAZ. PROCESSING OF ALLOY BY DUST/FUME (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NICKEL:GROUP 2B (IARC), ANTICIPATED TO BE A CARCINOGEN (NTP). LEAD:GROUP 2B (IARC). Effects of Overexposure:HLTH HAZ:PRODUCING OPERATION (GRINDING, BUFFING, FORGINGS, ETC) MAY RESULT IN POTENTIAL FOR EXPOS TO AIRBORNE METAL PARTICLATES/FUME. CHRONIC EXPOS TO CU, ZN, PB & MN MAY CAUSE METAL FUME FEVER. SYMPT INCLUDE FEVER, FATIGUE, DRYNESS OF THROAT, HEAD & BODY ACHE & CHILLS. OVEREXPOS TO CU & PB MAY RESULT IN SKIN (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:INGEST OF SIGNIFICANT AMOUNTS OF COPPER ALLOYS ARE UNLIKELY. SEEK MD HELP IF LARGE QUANTITIES OF PRODUCT ARE INGESTED. INHAL:REMOVE FROM EXPOSURE OF DUST OR FUME IF PRESENT. SEEK MD HELP IF REQ UIRED. SKIN:WASH THOROUGHLY WITH SOAP AND WATER. EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK MD HELP IF REQUIRED. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NEVER USE WATER AS AN EXTINGUISHING AGENT AROUND MOLTEN METAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERE ARE NO FIRE OR EXPLOSION HAZARDS WITH THESE ALLOYS. WATER WILL REACT VIOLENTLY WITH ANY MOLTEN METALS. ================== Accidental Release Measures ================== Spill Release Procedures:PRODUCT IS A NON HAZARDOUS SOLID. NO SPECIAL PRECAUTIONS ARE REQUIRED FOR SPILLS OF BULK MATERIAL. SCRAP METAL CAN BE RECLAIMED FOR REUSE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WET MATL SHOULD NEVER BE CHARGED INTO A MOLTEN BATH. TYPICALLY NO SPECIAL PROT REQD BEYOND THAT REQD FOR PROCESS OPERATION BEING USED. BUFFING, ETC, OR ANY OTHER PROCESS THAT GENERATES DUST, FUMES, CHIPS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE DUST OR FUME LEVELS ARE GREATER THAN THOSE SPECIFIED IN INGREDIENT SECTION, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION SHOULD BE USED. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE, ESPECIALLY BEFORE EATING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:STRIPS, COILS, WIRE, TUBE, INGOTS, CAKE, CATHODE & SCRAP. EFTS OF OVEREXPOS:& HAIR DISCOLORATION. CHRONIC EXPOS MAY AFFECT CNS LEADING TO EMOTIONAL DISTURBANCES, GAIT & BALANC E DIFFICULTIES & PARALYSIS. NICKEL & LEAD HAVE BEEN IDENTIFIED AS POTENTIAL CANCER CAUSING AGENTS. PROD WILL NOT(ING 12) ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>1500F,>816 Spec Gravity:7.5-9 Solubility in Water:INSOLUBLE Appearance and Odor:SILVER/YELLOW TO RED SOLID AT ROOM TEMPERATURE AND EXHIBITS NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MATERIAL MAY REACT WITH ACIDS, BASES OR OXIDIZERS. Stability Condition to Avoid:ALLOY IS NON HAZARDOUS AT ROOM TEMPERATURE. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS REGARDING DISPOSAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYLENE CHLORIDE CAGE:86511 CAGE:86511 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 99.9% OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:EYE:IRRT.SKN:IRRT,BURN, DRYNESS,FLAKING.INHL:DIZZ,NARCOSIS,ARRYTH.INGEST:CNS,KIDN,LIVER EFFECTS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH 15 MIN W/COPIOUS WATER.SKN:WASH W/SOAP & WATER.WASH CLOTH BEFORE REUSE.INHL:REMOVE TO FRESH AIR,ART RESP, OXYGEN. INGEST:DO NOT INDUCE VOMIT. CALL PHYSICIAN ALL CASES. ===================== Fire Fighting Measures ===================== Lower Limits:13 Upper Limits:25 Extinguishing Media:WATER FOG Fire Fighting Procedures:SELF CONTAINED RESPIRATORY EQUIPMENT Unusual Fire/Explosion Hazard:FORMS FLAMMABLE VAPOR.AIR MIX AT TEMP ABOVE AMBIENT. LOWER TEMPS DECREASE IGNITION POTENTIAL. ================== Accidental Release Measures ================== Spill Release Procedures:MOP,WIPE,SOAK UP IMMED.REMOVE SPILLAGE TO OUTSIDE. LARGE SPILLS:EVACUATE AREA, CONTAIN SPILL, PLACE IN CLOSED METAL CONTAINER (NOT ALUMINUM). PREVENT CONTAM OF POTABLE WATER SUPPLY. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHL VAPORS. VAPORS CAN COLLECT IN LOW AREAS.ENTER LOW AREAS W/OBSERVER & SCBA. STORE MATL IN COOL AREA. Other Precautions:DO NOT PRESSURE UNLOAD CONTAINERS OR TRANSPORT CONTAINERS W/AIR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SUPPLIED AIR:CF OR SCBA AS REQ'D BY VAPOR CONC. Ventilation:USE LOCAL EXH AS REQ'D Other Protective Equipment:AS REQ'D FOR ANTICPATED CONDITIONS OF USE Supplemental Safety and Health UPDATE PER MSDS(NOT OSHA) DTD 27JAN82.OSHA PEAK EXP LIM=2000 PPM 5 MIN/2HR/8HR DAY. ================== Physical/Chemical Properties ================== HCC:T4 Boiling Pt:B.P. Text:104F/39.8C Vapor Pres:340 Vapor Density:2.93 Spec Gravity:1.320 Solubility in Water:2 GM/100 GM Appearance and Odor:COLORLESS LIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM, SODIUM,POTASSIUM, MAGNESIUM. Stability Condition to Avoid:HYDROLYSIS W/WATER MAY YIELD SMALL AMT HCL. Hazardous Decomposition Products:FLAMES,WELDARCS MAY YIELD HC1,PHOSGENE, CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:SMALL QUANT EVAPORATE IAW LOC,STATE,FED REGS. RECLAIM OR INCINERATE IN PERMITTED FACILITIES IAW ALL LSF REGS.
1
eyes_protection_mandatory
======================================================= Product ID: 84-9801-8644-3 00-51111-42664-7, DISKETTE (SUPDAT) Cage: EO130 ======================================================= Contractor Summary ======================================================= Cage: 06XS2 Box: UNKNOW Cage: EO130 ======================================================= Ingredients ======================================================= Cas: 67-63-0 RTECS #: NT8050000 % Wt: 100 OSHA PEL: 400 PPM ACGIH TLV: 400 PPM; 500 STEL ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: MOD EYE IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELLING, PAIN, TEARING & HAZY VISION. SKIN: MILD SKIN IRRIT: SIGNS/SYMPS CAN INCL REDNESS, SWELLING & ITCHING. INHAL: CNS DEPRESS: SIGNS/SYMPS CAN I NCL HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS & (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ: UNCON. IRRIT (UPPER RESPIRATORY): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGHING & SNEEZING. INGEST: IRRIT OF GI TISSUES: SIGNS/SYMPS CAN INCL PAIN, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS & BLOOD IN FECES. CNS DEPRESS: SIGNS/SYMPS CAN INCL HEADACHE, DIZZINESS, DROWSINESS, MUSC WEAKNESS, INCOORD, SLOWED RXN TIME, FATIGUE, BLURRED VISION, SLURRED SPEECH, GIDDINE SS, TREMORS & CONVULSIONS. ASPIR PNEUM: SIGNS/SYMPS CAN INCLUDE COUGH, DFCLTY BRTHG, WHEEZING, COUGHING UP BLOOD & PNEUM WHICH CAN BE FATAL. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMED FLUSH EYES W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMED MED ATTN. SKIN: FLUSH SKIN W/LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MED ATTN. INHAL: IF SIGNS/SYMPS OCCU R, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPS CONTINUE, CALL MD. INGEST: IF SWALLOWED, CALL MD IMMED. ONLY INDUCE VOMITING AT INSTRUCTION OF MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REFER TO OTHER SECTIONS OF MSDS FOR INFO REGARDING PHYSICAL & HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION & PERSONAL PROTECTIVE EQUIPMENT. IN USA CALL 612-733-1110 OR 612-733-6100 FOR 24-HR SP ILL ASSISTANCE. EXTINGUISH ALL IGNITION SOURCES. COVER W/ABSORBENT MATL. COLLECT SPILLED MATL. CLEAN UP RESIDUE. PLACE IN APPRVD METAL CONTAINER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGS (FP N). INCINERATE IN AN INDUSTRIAL OR COMMERCIAL FACILITY. DISPOSE OF WASTE PRODUCT IN A FACILITY PERMITTED TO ACCEPT CHEMICAL WASTE. MATL TO BE DIS POSED HAS A US EPA HAZ NUMBER D001 (IGNITABLE). Handling And Storage Precautions: FLAMMABLE LIQUID AND VAPOR. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF IGNITION. Other Precautions: AVOID EYE CONTACT. AVOID SKIN CONTACT. DO NOT INGEST. KEEP OUT OF THE REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 53.0F,11.7C Lower Limits: 2.00% Upper Limits: 12.00% Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID BREATHING OF VAPORS.USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: USE IN A WELL-VENTILATED AREA. Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: HEAD CLEANING KIT (FLUIDS AND PACKETS). ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 130F,54C Vapor Pres: 33 Vapor Density: 5.0 Spec Gravity: 0.600 (H*2O=1) VOC Grams/Liter: 785 Evaporation Rate & Reference: 0.80 (H*2O=1) Solubility in Water: 100 G/100 CC Appearance and Odor: CLEAR LIQUID; ALCOHOL ODOR. Percent Volatiles by Volume: 100 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 84-9801-8644-3 00-51111-42664-7, DISKETTE (SUPDAT) Cage: EO130 Assigned IND: Y Company Name: IMATION ENTERPRISES CORPORATION Street: 1 IMATION PLACE Zipcode: 55128-1110 Label Required IND: Y Date Of Label Review: 01/13/1997 Status Code: C Label Date: 01/13/1997 Origination Code: G Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: EXTREMELY FLAMMABLE. ACUTE: EYES: MODERATE EYE IRRITATION WITH REDNESS, SWELLING, PAIN, TEARING AND HAZY VISION. SKIN: MILD SKIN IRRITATION WITH REDNESS, SWELLING AND ITCHING. INHALATION: CNS DEPRESSI ON WITH HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS AND UNCONSCIOUSNESS. IRRITATION. INGESTION: IRRITATION OF GI TISSUE, CNS DEPRESSION, ASPIRATION PNEUMONITIS. CHRONIC: NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR 1422 B-1/2 BASE COMPOUNS,1422 B 10 Kit Part:Y CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/300STEL;9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BISPHENOL A EPOXY RESIN CAS:25036-25-3 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:PHENOL POLYMER WITH FORMALDEHYDE/PHENOLIC RESIN CAS:28470-78-2 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 15% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9495 Ingred Name:SILICON DIOXIDE (AMORPHOUS)/SILICA DERIVATIVES CAS:67762-90-7 Other REC Limits:NONE RECOMMENDED OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:THIOL TERMINATED POLYMER, POLYDITHIOETER/POLYSULFIDE POLYMER CAS:68611-50-7 Other REC Limits:NONE RECOMMENDED Ingred Name:VOLITILE ORGANIC CONTENT AS LISTED ON MSDS: 104 G/L (COMBINED PART A, B) RTECS #:9999999VC Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LIVER, RESPIRATORY & GI TRACTS. ACUTE- MAY BURN EYES CAUSING TRANSIENT CLOUDING. PROLONGED SKIN CONTACT MAY CAUSE BURNING. INHALATION MAY CAUSE CNS EFFECTS. REVERSIBLE LI VER DAMAGE MAY OCCUR. CNS EFFECTS IF INGESTED. CHRONIC- MAY CAUSE SKIN DRYNESS & CRAKING. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, BURNS, NAUSEA, VOMITING, DIARRHEA, HEADACHE, DIZZINESS, REVERSIBLE LIVER DAMAGE, TEARING, PAIN, REDNESS, DROWSINESS, SKIN SENSITIZATION, ALLERGIC SKIN RASH Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. CONSULT PHYSICIAN. INHALED:REMOVE TO FRESH AIR. ORAL:GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER FOG Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:AVOID PERSONAL CONTACT. SCOOP INTO CONTAINER FOR DISPOSAL. CLEAN AREA WITH SUITABLE SOLVENT. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. DO NOT INGEST. Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES ON SKIN OR ON CLOTHING. VAPORS MAY COLLECT IN LOW OR CONFINED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR AIR-SUPPLIED RESPIRATOR MUST BE WORN. Ventilation:USE GENERAL VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:T6. THIS PRODUCT IS A KIT CONSISTING OF TWO PARTS: ACCELERATOR HAS PNI G, BASE COMPOUND HAS PNI F OR H, SAME NSN. PNI H HAS DIFFERENT PRODUCT CODE THAN PNI F. ================== Physical/Chemical Properties ================== HCC:T6 NRC/State Lic Num:NOT RELEVANT Vapor Density:>1 Spec Gravity:1.381 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Appearance and Odor:BROWN THIXOTROPIC PASTE Percent Volatiles by Volume:3.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF SULFUR, TRACES OF HYDROGEN SULFIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D035.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRITON X-120 AG EMULSIFIER (61573) CAGE:77902 CAGE:77902 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESITE CAS:546-93-0 RTECS #:OM2470000 Fraction by Wt: 60% Other REC Limits:N/K OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9192 Ingred Name:OCTYLPHENOXYPOLYETHOXYETHANOL CAS:9036-19-5 Fraction by Wt: 40% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 RAT ORAL >5 G/KG, (SEE SUPP DATA) Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POSSIBLE PERMANENT EYE INJURY.CAN BE ABSORBED THROUGH INTACT SKIN IN HARMFUL AMOUNTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:SEVERELY IRRITATING,POSSIBLE PERMANENT INJURY.LONG LASTING CORNEAL OPACITY.DRAIZE SCORE OF 64 AFTER 1 HOUR DECREASED TO 41.4 AFTER 7 DAYS.CORNEAL BLISTERS & VASCULARIZATION NOTED.SKIN:SLIGHTLY IR RIT.SCORE OF 0.8 IN ACUTE DERMAL TEST.CAN BE ABSORBED THROUGH INTACT SKIN IN HARMFUL AMTS.INGEST/INHAL:N/K . Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH LARGE AMOUNT OF WATER FOR AT LEAST 15 MIN.GET PROMPT MEDICAL ATTENTION.SKIN:WASH THOROUGHLY WITH SOAP AND WATER.REMOVE & WASH CLOTHING BEFORE REUSE.INGESTION:DILUTE BY GIVING 2 GLASSES OF WATER TO DRINK.SEE MD.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.INHALATION:MOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM,CO*2,DRY CHEMICAL,WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED,PRESSURE DEMAND SCBA & FULL PROTECTIVE EQUIPMENT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR EYE PROT & MSHA/NIOSH APPRVD RESP FOR DUST EXPOS.SCOOP/SHOVEL INTO SUITABLE CONTR FOR RECOVERY/DISP.KEEP DUST TO MIN.REMOVE CONTAM CLTHG IMMED,WASH SKIN W/ SOAP & H*2O.KEEP SPILLS & CLEANING RUNO FF OUT OF MUNICIPAL SEWERS & OPEN BODIES OF H*2O. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY AREA (INDOORS OR OUTDOORS,NOT HEATED,NOT REFRIGERATED). Other Precautions:N/K ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:SAFETY SHOWER,EYEWASH FACILITY,PROTECTIVE CLOTHING. Work Hygienic Practices:REMOVE & WASH CLOTHING BEFORE REUSE. Supplemental Safety and Health % VOLATILE BY WT:0.ROUTES OF ENTRY:SKIN .LD50-LC50 MIX:RABBIT DERMAL >3 G/KG. ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:N/K Spec Gravity:2.16 (WATER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE POWDER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AND REDUCING AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE IAW FEDERAL,STATE & LOCAL REGS .INCIN LIQ AT PERMITTED FACILITY.LANDFILL CONTAM DIKING MATL.LANDFILL MUST BE LRG ENOUGH TO ABSORB THE SURFACTANT (SIGNIFICANT QTIES REACHING STREAM O R TREATMENT PLANT VIA LEACHATE CAN CAUSE FOAMING).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:-8705 STEEL RED DX-986,DX-296,RED DL Preparer's Name:LAKS RAMACHANDRAN CAGE:98148 CAGE:98148 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 31-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ingred Name:N-BUTYL ACETATE (CERCLA) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 31-50% Other REC Limits:NONE RECOMMENDED OSHA PEL:150 PPM ACGIH TLV:150 PPM/200STEL;9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9596 Ingred Name:NITROCELLULOSE CAS:9004-70-0 RTECS #:QW0970000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE) CAS:123-42-2 RTECS #:SA9100000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM ACGIH TLV:50 PPM; 9596 Ingred Name:N-PROPYL ACETATE CAS:109-60-4 RTECS #:AJ3675000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM ACGIH TLV:200 PPM/250STEL;9596 Ingred Name:SOLVENT RED 125 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:VOLITILE ORGANIC CONTENT AS LISTED ON MSDS, 6.46 LB/GL. RTECS #:9999999VC Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HIGH CONCEN OF VAP MAY PRODUCE IRRIT OFRESP TRACT,HEADACHE,DIZZ,NAU.SKIN/EYE:MODERATE IRRIT.INGEST:NAU,VOMIT.DO NOT INDUCE VOMIT.INGEST:SIMILAR TO INHAL.CHORNIC:PROLONGED REPEATED OVEREXPO TO THIS P RODUCT MAY LEAD TO SKIN SENSITIZATION ORDERMATITIS. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NTP/IARC/OSHA/ACGIH:NO. Effects of Overexposure:IRRIT RESP TRACT, HEADACHE, DIZZ, NAUSEA. EYE/SKIN MODERATE IRRIT. SKIN SENSITIZATION, DERMATITIS. Medical Cond Aggravated by Exposure:SKIN DISORDERS, RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WELL W/WTER.CONTACT PHYSICIAN IF IRRIT PERSISTS.SKIN:WASH W/SOAP/WATER.INHAL:REMOVE TO FRESH AIR.BREATH DIFFI ADMINISTER OXYGEN.INGEST:DO NOT INDUCE VOMITING.CONTACT PHYSICIAN.IF VOMITING OC CURS KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:53.0F,11.7C Autoignition Temp:Autoignition Temp Text:NP Lower Limits:1.38 Upper Limits:12 Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS IN CONFINED AREAS. Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THATN AIR & MAYT TRAVEL ALONG GROUND OR BE MOVED BY VENTILATION & BE IGNITED BY IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT SKIN/EYE CONTACT.USE NON-COMBUSTIBLE MATL TO CONFINE &/OR ABSORB.ELIMINATE IGNITION SOURCES.VENTILATE AREA. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:EMPTY CNTNRS RETAIN RESIDUE(LIQ &/OR VAP)& CAN BE DANGEROUS.DON'T PRESSURIZE/CUT/WELD/BRAZE/SOLDER,DRILL/GRIND/EXPO SUCH CNTNR TO HEAT/SPARK/FLAMES/ET Other Precautions:USE W/ADEQUTE VENTILATE.MANY HOT ORG CHEM VAP/MIST SUSCEPTIBLE TO SUDDEN SPONT COMBUST WHEN MIX W/AIR.IGN MAY OCCUR @TEMPS BELOW AUTOIGN/IGN LITERATURE TEMPS.IGN TEMP DECR W/INCR VAP VOL & VAP/AIR CON TACT TIME & INFLUENCED BY PRESS CHANGES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED FOR NORMAL USE W/ADEQUATE VENTI.IN POORLY VENTILATED AREA USE NIOSH APPROV ORG VAPOR RESP. Ventilation:LOC EXHAUST RECOMMENDED FOR CONFINED AREAS.GENERAL MECHANICAL VENTI IS ADEQUATE FOR NORMAL USE. Other Protective Equipment:CHEM RESIST PROTECTIVE GEAR AS REQUIRED TO MINIMIZE SKIN CONTACT.EYEBATH,SAFETY SHOWER. Work Hygienic Practices:FOLLOW CURRENT H.M.I.S REGULATIONS. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=73.C, 163.4F Vapor Pres:NP Vapor Density:>1 Spec Gravity:0.84 pH:NP Viscosity:NP Evaporation Rate & Reference:>1, BUAC=1. Solubility in Water:APPRECIABLE. Appearance and Odor:RED TRANSPARENT LOW VISCOSITY LIQ W/SWEET SOLVENT ODOR. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAINS CHEM(S) SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III/40CFR372.REMOVE TO WASTE DISOO FACILITY OPERATING IN COMPLIANCE IWTH LOCAL, STATE AND FEDERAL REGULATIONS.CERCLA/RCRA CODES:D001,U031(BUT YL ALCOHOL).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:D19-700, MIL-L-6082, GRADE 1100 (BASE OIL) CAGE:JOINT CAGE:JOINT ============= Composition/Information on Ingredients ============= Ingred Name:TIN (AS SN) CAS:7440-31-5 RTECS #:XP7320000 OSHA PEL:2 MG/CUM ACGIH TLV:2.0 MG/CUM Ingred Name:TITANIUM (DRY POWDER) (TI) *94-4* CAS:7440-32-6 RTECS #:XR1700000 Ingred Name:CADMIUM (SUSPECTED HUMAN CARCINOGEN BY IARC, SUPSECTED CARCINOGEN BY NTP, IARC - GROUP 1)*94-4* CAS:7440-43-9 RTECS #:EU9800000 Other REC Limits:A2 CARCINOGEN OSHA PEL:0.05 MG/CUM (CD) ACGIH TLV:0.01 MG/CUM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:VANADIUM CAS:1314-62-1 RTECS #:YW1355000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.05 MG/CUM (DUST) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ZINC CAS:7440-66-6 RTECS #:ZG8600000 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE CAS:7439-98-7 RTECS #:QA4680000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM Ingred Name:BARIUM (SOLUBLE COMPOUNDS) CAS:7440-39-3 RTECS #:CQ8370000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.5 MG/CUM Ingred Name:GRADE 1100 OIL (MIL-L-6082) Fraction by Wt: 99% Ingred Name:SILVER CAS:7440-22-4 RTECS #:VW3500000 OSHA PEL:0.01 MG/CUM ACGIH TLV:0.1 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ALUMINUM (POWDER) *94-4* CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:BORON CAS:7440-42-8 RTECS #:ED7350000 Ingred Name:COPPER (DUST & MIST), BRONZE POWDER CAS:7440-50-8 RTECS #:GL5325000 Other REC Limits:1 MG(CU)/M3 (DUST) OSHA PEL:0.1 MG(CU)/M3 (FUME) ACGIH TLV:0.2 MG/M3 (FUME) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (KNOWN CARCINOGEN BY NTP; IARC - GROUP 3) *94-4* CAS:7440-47-3 RTECS #:GB4200000 ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:IRON *94-4* CAS:7439-89-6 RTECS #:NO4565500 Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Ingred Name:MANGANESE, MN COMPOUNDS CAS:7439-96-5 RTECS #:OO9275000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM (DUST) Ingred Name:NICKEL (SUSPECTED ANIMAL CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *94-4* CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:SODIUM CAS:15307-79-6 RTECS #:AG6310000 Ingred Name:LEAD, INORGANIC LEAD (IARC GROUP 2B) *94-4* CAS:7439-92-1 RTECS #:OF7525000 ACGIH TLV:0.15 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 ACGIH TLV:10 MG/CUM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 29,000 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: SLIGHT IRRITATION. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: WASH W/CLEAR WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:420F Extinguishing Media:CO2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:TREAT AS AN OIL SPILL. CLEAN W/TOWEL/RAG. DISPOSE OF RAG IN TRASH. FLOOR MAY BE SLIPPERY. DETERGENT WASH MAY BE REQUIRED. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE W/OXIDIZERS. Other Precautions:AVOID BREATHING MIST/AEROSOLS OF THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR DUST/MIST CARTRIDGE IF OIL MIST OCCURS. Ventilation:LOCAL EXHAUST. Work Hygienic Practices:NORMAL GOOD HOUSEKEEPING PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:750-1200F Vapor Pres:0 Spec Gravity:0.9119 Solubility in Water:0 Appearance and Odor:PEARLESCENT BLACK COLOR W/CHARACTERISTIC ODOR OF LUBRICATING OIL. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Hazardous Decomposition Products:PARTIALLY BURNED HYDROCARBONS, METAL OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF AS WASTE OIL IAW/FEDERAL, STATE & LOCAL REGULATIONS. SMALL RESIDUES OF THESE PRODUCTS AREN'T CONSIDERED HAZARDOUS & MAY BE DISCARDED AS TRASH.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIBERTY CAGE:89044 CAGE:89044 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM METASILICATE CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: 8% Other REC Limits:NONE SPECIFIED Ingred Name:ETHANOLAMINE (MEA) CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 5% Other REC Limits:7.5 MG/M3 ACGIH TLV:8 MG/M3 Ingred Name:BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 14% Other REC Limits:121 MG/M3 ACGIH TLV:121 MG/M3 Ingred Name:GLYCOL ETHERS (THIS PRODUCT DOES CONTAIN 14% GLYCOL ETHER[S] FOR SARA 313 REPORTING PURPOSES) CAS:122-99-6 RTECS #:KM0350000 Fraction by Wt: 14% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:SKIN AND EYE: SEVERE CHEMICAL BURNS. BLINDNESS. HARMFUL CONTACT MAY NOT CAUSE IMMEDIATE PAIN. IMMEDIATE EYE FLUSHING W/WATER VITAL. INGEST: HARMFUL/FATAL. MOUTH,THROAT & STOMACH CHEMICAL BURNS. INHALE D: DAMAGES AIRWAYS & LUNGS. EFFECTS CANVARY FROM SLIGHT IRRIT TO BRONCHITIS OR PNEUMONIA. Effects of Overexposure:NOTE: BUTOXYETHANOL PENETRATES SKIN. IN RODENTS, HEAVY DOSES DAMAGE RED BLOOD CELLS, WITH INJURY TO LIVER, KIDNEY, AND SPLEEN. HUMANS AND OTHER SPECIES ARE MORE RESISTANT. CAN INJURE EYES. NOTE: USE S OLUTIONS MAY ALSO BE CORROSIVE. Medical Cond Aggravated by Exposure:PEOPLE WITH ASTHMA OR OTHER LUNG PROBLEMS MAY BE MORE AFFECTED. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/COOL RUNNING WATER.REMOVE CONTACT LENSES,CONTINUE FLUSHING AT LEAST 15 MIN,HOLDING EYELIDS APART.CALL DR IMMED. SKIN:IMMED FLUSH W/COOL RUNNING WATER AT LEAST 15 MIN,REMOVING CONTAM NTD CLOTHES & SHOES. INGEST:RINSE MOUTH,THEN DRINK 1-2 GLASSES MILK/WATER.DON'T INDUCE VOMIT.NOTHING BY MOUTH TO UNCONSCIOUS PERSON. INHAL: IMMED MOVE TO FRESH AIR. CALL POISON CONTROL CTR/DR IMMED. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:PRODUCTS DOES NOT SUPPORT COMBUSTION. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEANUP: USE PROPER PROTECTIVE EQUIPMENT. DIKE OR DAM LARGE SPILLS. PUMP TO CONTAINERS OR SOAK UP ON INERT ABSORBENT. FLUSH RESIDUE TO SANITARY SEWER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH USE SOLUTIONS. THESE MAY ALSO BE HAZARDOUS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATHING MISTS OR VAPORS OF THIS PRODUCT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.0 pH:13.4 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID; CHARACTERISTIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:DO NOT MIX WITH ANYTHING BUT WATER. KEEP FROM FREEZING. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT STATE AND LOCAL AUTHORITIES FOR RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE. UNUSED PRODUCT AS A WASTE IS CORROSIVE (D002) BY RCRA CRITERIA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEAD / ACID BATTERY Preparer's Name:ALAN L. CSONTAS CAGE:63432 CAGE:63432 CAGE:NO672 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15MG/M3 DUST; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA 313) (CERCLA) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG (SB)/M3; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA 313) (CERCLA) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-38% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <0.15% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE-REPEATED CONTACT W/H2SO4 MAY CAUSE DRYING OF SKIN, IRRITATION, DERMATITIS, SKIN & EYE BURNS. INHALATION MAY CAUSE RESPIRATORY IRRITATION, BRONCHITIS. MIST MAY ERODE TEETH. CHRONIC-ACID CAN CAUSE IRRITATION OR BURNS OF EYES, NOSE, THROAT. BREATHING MIST PRODUCES RESPIRATORY DIFFICULTY. Explanation of Carcinogenicity:MFR ALSO LISTED EPA CAG AS YES. SEE INDIVIDUAL REPORTS FOR DETAILS. Effects of Overexposure:CONTACT W/H2SO4 MAY CAUSE DRYING OF SKIN, IRRITATION, DERMATITIS, SKIN & EYE BURNS. INHALATION OF MIST:RESPIRATORY IRRITATION, BRONCHITIS. MIST MAY ERODE TEETH. Medical Cond Aggravated by Exposure:SULFURIC ACID MIST CAUSES GOUGHING & WILL BURN EYES & SKIN. ======================= First Aid Measures ======================= First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. A ID OR RESTORE BREATHING AS NEEDED. INGESTED:DO NOT INDUCE VOMITING. WASH OUT MOUTH W/RUNNING WATER. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:675F Lower Limits:4.1 HYDROGEN Upper Limits:74.2 HYDROGN Extinguishing Media:HALON,DRY CHEMICAL. Fire Fighting Procedures:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. COOL EXTERIOR OF BATTERY TO PREVENT RUPTURE. ACID MIST & VAPOR ARE CORROSIVE. WEAR SCBA & CLOTHING. Unusual Fire/Explosion Hazard:HYDROGEN GAS & SULFURIC ACID VAPORS ARE GENERATED BY OVERCHARGING. HYDROGEN IS FLAMMABLE/EXPLOSIVE WHEN MIXED W/AIR. VENTILATE CHARGING AREA TO PREVENT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING. VENTILATE AREA. DIKE TO CONTAIN. EVACUATE UNPROTECTED PERSONNEL. NEUTRALIZE W/SODIUM BICARBONATE, SODA ASH, LIME OR OTHER NEUTRALIZING AGENT Neutralizing Agent:SODIUM BICARBONATE, SODA ASH, LIME OR OTHER NEUTRALIZING AGENT. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM FLAMES DURING & AFTER CHANGING. COMBUSTION OR OVERCCHARGING MAY LIBERATE HAZARDOUS/TOXIC GAS. DO NOT SHORT CIRCUIT BATTERY TERMINALS. Other Precautions:AVOID PROLONGED OVERCHARGE. SODIUM BICARBONATE, SODA ASH, SAND OR LIME SHOULD BE KEPT ON-SITE FOR SPILL REMEDIATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SULFURIC ACID MIST - FULL FACE OR HALF MASK RESPIRATOR W/ACID GAS FILTER OR SCBA. Ventilation:CHANGE AIR EVERY 15 MINUTES. Other Protective Equipment:ACID RESISTANT RUBBER OR PLASTIC APRON, BOOTS & PROTECTIVE CLOTHING. Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health PROPER SHIPPING NAME & HAZARD CHARACTERISTIC CODE ASSIGNED BBY TECHNICAL SUPPORT PERSONNEL. LISTED HERE AS ORDERED BY SUPERVISOR. ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:275F,135C Melt/Freeze Pt:M.P/F.P Text:>320F,>160C Decomp Temp:Decomp Text:NP Vapor Pres:1 MM Vapor Density:3.4 Spec Gravity:1.080-1.400 pH:<2 Solubility in Water:ELECTROLYTE; 100% Appearance and Odor:SEE SUPP DATA Percent Volatiles by Volume:N/A. Corrosion Rate:UNKNOWNN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SPARKS, OPEN FLAMES. KEEP BATTERY CASE AWAY FROM STRONG OXIDIZERS. Stability Condition to Avoid:AVOID OVERCHARGING & SMOKIING OR SPARKS NEAR BATTERY SURFACE. Hazardous Decomposition Products:EXPLOSIVE HYDROGEN/OXYGEN MIXTURE WITHIN THE BATTERY MAY OCCUR DURING CHARGING. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:RETURN SCRAP BATTERY TO DISTRIBUTOR, MAUNFACTURER, LEAD SMELTER FOR RECYCLE. FOR NEUTRALIZED SPILLS, PLACE RESIDUE INTO CONTAINERS W/SORBENT MATERIAL, SAND OR EARTH FOR DISPOSAL. CONTACT LOCAL &/OR ST ATE ENVIRONMENTAL OFFICIALS FOR DISPOSAL PROCEDURE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KVT23C200 CAGE:14655 CAGE:14655 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR.GIVE ART.REPSIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS PE RSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUS Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE,THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TG25 CAGE:LO371 CAGE:LO371 CAGE:74276 ============= Composition/Information on Ingredients ============= Ingred Name:CESIUM 137 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health SOURCE OF DATA-EXAM OF STOCK IN WHSE. SAFETY & HEALTH DATA DEVELOPED BY DGSC-STF. ================== Physical/Chemical Properties ================== HCC:A3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SC941 COPPER PLASMA STANDARDS; 10,000 PPM CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID, HYDROGEN NITRATE CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 2-5% OSHA PEL:5 MG/CUM ACGIH TLV:5.2 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CUPRIC NITRATE TRIHYDRATE, COPPER(II) NITRATE TRIHYDRATE CAS:10031-43-3 RTECS #:GL7875000 Fraction by Wt: 1% ACGIH TLV:1 MG/CU M (COPPER) Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 94-97% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: RESPIRATORY IRRITATION/COUGH/CHOKING/DIZZINESS/HEADACHE/NAUSEA/WEAKNESS/PULMONA RY EDEMA/TIGHTNESS IN CHEST/DYSPNEA/FROTHY SPUTUM/CYANOSIS/RAPID PULSE. SKIN: PAIN/BURN/IRRITATION. EYES: IRR ITATION/PAIN/BURNS. INGESTION: CORROSION OF MUCOUS MEMBRANES OF MOUTH/THROAT/ESOPHAGUS/NAUSEA/VOMITING/DIARRHEA/COMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: METALLIC TASTE/BURNING SENSATION IN MOUTH/THROAT/ABDOMINAL PAIN/DIARRHEA OF BLACK/BLOODY STOOLS/CONSTIPATION/FATIGUE/DEATH MAY RESULT FROM CARDIORESPIRATORY ARREST/SHOCK. SKIN: YELLOWISH S TAINS/DERMATITIS. EYES: PHOTOPHOBIA/BLINDNESS. INGESTION: CONVULSIONS/KIDNEY/HEART/BLOOD/REPRODUCTIVE/IMMUNE SYSTEMS. Medical Cond Aggravated by Exposure:KIDNEY, LIVER OR RESPIRATORY DISORDERS ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. KEEP WARM & AT REST. MAINTAIN AIRWAY/BLOOD PRESSURE. TREAT SYMPTOMATICALLY/SUPPORTIVELY. SKIN: WASH W/SOAP/MILD DETERGENT & WATER FOR 15-20 MINS. CHEMICAL BURNS: COVER AREA W/STERILE/DRY DRESSING, BANDAGE SECURELY, BUT NOT TOO TIGHT. EYES: FLUSH W/WATER FOR AT LEAST 15-20 MINS. CONTINUE IRRIGATING W/NORMAL SALINE UNTIL PH HAS RETURNES 30-60 MINS. SEE SUPP. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY OR STANDARD FOAM Fire Fighting Procedures:MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. COOL FIRE EXPOSED CONTAINERS W/WATER FROM SIDE UNTIL WELL AFTER FIRE IS OUT. DON'T USE WATER DIRECTLY ON MATERIAL. Unusual Fire/Explosion Hazard:USE WATER SPRAY TO ABSORB CORROSIVE VAPORS. COOL CONTAINERS W/FLOODING AMOUNTS OF WATER FROM AS FAR A DISTANCE AS POSSIBLE. KEEP UPWIND. AVOID BREATHING VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF YOU CAN DO IT WITHOUT RISK. TAKE UP W/SAND OR OTHER ABSORBENT MATERIAL & PLACE IN CONTAINERS. SHOVEL DRY SPILLS W/CLEAN SHOVEL INTO CONTAINERS. DIKE FAR AHEAD OF SPILL. KEEP UNNECESSARY P EOPLE AWAY. ISOLATE/DENY ENTRY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE MATERIALS. MAY IGNITE COMBUSTIBLE (WOOD, PAPER, OIL, ETC.) Other Precautions:AVOID BREATHING CORROSIVE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SCBA W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND/POSTIVE PRESSURE MODE IN COMBINATION W/AUXILIARY. CHEMICAL CARTRIDGE RESPIRATOR W/ACID GAS CARTRIDGE W/FULL FACEPIECE. TYPE "C" SUPPLIED-AIR RESPI RATOR W/FULL FACEPIECE WHEN >TLV. Ventilation:LOCAL EXHAUST &/OR GENERAL DILUTION TO KEEP <TLV. CLOTHING & EQUIPMENT, EYE WASH FOUNTAIN, QUICK DRENCH SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED/SHOES BEFORE REUSE. Supplemental Safety and Health INGESTION: TREAT SYMPTOMATICALLY & SUPPORTIVELY. IF CONSCIOUS GIVE WATER OR MILK TO DILUTE SUBSTANCE. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO HELP PREVENT ASPIRATION. OBTAIN MEDICAL ATTENTION IN A LL CASES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 212F Melt/Freeze Pt:M.P/F.P Text: 32F Spec Gravity: 1 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID W/ACRID ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, METALS, & ORGANIC MATERIALS Hazardous Decomposition Products:ACRID SMOKE & IRRITATING FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE,FLAKE/PELLET CAGE:GO753 CAGE:GO753 CAGE:1L164 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 97.0% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:SKIN:MAY CAUSE SEV BURNS;EYES:RAPIDLY CAUSES SEV DAMAGE;INH:DUST/MIST MAY DAMAGE ENTIRE RESP TRACT. ======================= First Aid Measures ======================= First Aid:IMMED REMOVEAL OF CAUSTIC IS OF PRIMARY IMPORTANCE;SKIN:FLUSH W/LG AMTS OF WATER FOR 1-2 HRS OR UNTIL MED HELP ARRIVES;EYES:FLUSH IMMED W/WATER FOR 15 MIN.GET MED HELP AT ONCE FOR EYES/ SKIN BURNS;INH :REMOVE TO FRESH AIR.GET MEDICAL. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:FLOOD W/WATER,USING CARE NOT TO SPLATTER OR SPLASH. Fire Fighting Procedures:USE NIOSH APPRVD SELF-CNTND BRTHG APP & FULL PROTEC CLOTHING Unusual Fire/Explosion Hazard:GIVES H2 GAS WHEN IN CONTACT W/AL,LEAD,TIN, ZINC & THEIR ALLOYS;CONTACT W/WATER OR SEE SUPPL DATA ================== Accidental Release Measures ================== Spill Release Procedures:IMMED SWEEP UP,REMOVE & PLACE IN CLOSED CONTNR,PROVIDING STAFF PROTECTION & AVOID CONTACT W/METALS.DISSOLVE/ NEUTRALIZE & FLUSH AWAY REMAINDER,KEEPING OUT OF SEWER.USE W/CARE DIL ACETIC ACID TO NEUTRA LIZE CAUSTIC TRACES.IF GIVES H2 EVAC/VENT AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT MIX HOT WATER W/CAUSTIC SODA.ADD CAUSTIC TO COLD WATER W/STIRRING AS HEAT IS EVOLVED.HEAT IS EVOLVED IN NEUTRALIZING.AVOID SPATTERING THE SOLN. Other Precautions:FOR FURTHER DETAILS SEE MCA CHEM SAFETY DATA SHEET SD-9 AVAILABLE FM MFGR CHEMISTS ASSOC,1825 CONNECTICUT AVE,NW WASH DC. PRECAUTIONS LISTED IN THIS DATA SHEET APPLY ALSO TO AQUEOUS SOLUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SPECIAL(MECH)FILTER RESP FOR MIST/DUST/IF H2 GASSEE SUPP DATA. Ventilation:LOCAL EXH:AS NEEDED TO ELIM DUST/MIST;MECH(GEN);IF NOT DUSTY Other Protective Equipment:FACE SHLD,HARD HATS,RUBBER APRON,RUBBER BOOTS/ CLOTH AS REQD. Supplemental Safety and Health UNUSUAL FIRE:OR MOISTURE MAY GIVE SUFF HEAT TO IGNITE COMBUSTIBLE MATLS.RESP PROTEC:IS BEING PRODUCED,USE HOSE MASK/SELF CNTND BRTHG APP.PRODUCT IN PELLET FORM. ================== Physical/Chemical Properties ================== HCC:B1 Spec Gravity:2.13 Solubility in Water:APPRECIABLE Appearance and Odor:WHITE PELLETS WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS,ACIDS & FLAMMABLE MATL,REACTIVE METALS & SA Stability Condition to Avoid:HUMID AREA Hazardous Decomposition Products:H2 GAS IN CONTACT W/ALUMINUM,ZINC,TIN,LEAT & THEIR ALLOYS Conditions to Avoid Polymerization:UNK ==================== Disposal Considerations ==================== Waste Disposal Methods:IF DISPOSAL REGS PERMIT DISCHARGE OF NEUTRAL SOLNS,DISSOLVE IN WATER,COOL & NEUTRALIZE CAREFULLY W/DILUTE ACID,SUCH AS ACETIC ACID. THEN FLUSH TO SEWER W/LOTS OF WATER.DISPOSAL BY A LICENSED CONTRACTO R MAY OTHERWISE BE NEEDED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:497 LIGHTWEIGHT BODY FILLER CAGE:16522 CAGE:16522 ============= Composition/Information on Ingredients ============= Ingred Name:DIETHYLENE GLYCOL, MALEIC ANHYDRIDE, PHTHALIC ANHYDRIDE POLYMER*97-2* CAS:26123-45-5 Fraction by Wt: <35% Ingred Name:STYRENE, STYRENE MONOMER (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B) *97-2* CAS:100-42-5 RTECS #:WL3675000 Fraction by Wt: <18% EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM SILICATE (IARC - GROUP 3) *97-2* CAS:14807-96-6 RTECS #:WW2710000 Fraction by Wt: <50% OSHA PEL:2 MG/CUM (RESP DUST) ACGIH TLV:2 MG/CUM (RESP DUST) Ingred Name:GLASS OXIDE, FIBER GLASS WOOL, LEAD BOROSILICATE GLASS ENAMEL FLUX CAS:65997-17-3 Fraction by Wt: <50% Ingred Name:VOLATILE ORGANIC CONTENT: 216 G/L RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: VAPORS MAY CAUSE MUCOUS MEMBRANE & UPPER RESPIRATORY TRACT IRRITATION. REPEATED EXPOSURE TO HIGH CONCENTRATIONS OF VAPOR MAY CAUSE LIVER & KIDNEY DAMAGE. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, DISCOMFORT. Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESPIRATORY CONDITIONS (ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA). ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN AL L CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:90F (SEE SUPP) Lower Limits:1.1 Upper Limits:6.1 Extinguishing Media:SMALL FIRES: CO2, DRY CHEMICAL. LARGE FIRES: FOAM, WATER FOG. Fire Fighting Procedures:DENSE SMOKE SERIOUSLY LIMITS VISIBILITY. VENT SMOKE & USE GAS MASK/REMOTE AIR SUPPLY. WEAR MSHA/NIOSH APPROVED SCBA W/PROTECTIVE EQUIPMENT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. INCREASE VENITLATION TO MAXIMIZE VAPOR DISPERSAL. DIKE TO PREVENT RUNOOF INTO SEWERS/WATERWAYS. MATERIAL MAY BE REMOVED BY SHOVELING, WIPING. SWEEP/CLEAN W/INERT MATERIALS & PLACE IN CLOSED CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. DON'T STORE IN DIRECT SUNLIGHT. USE W/ADEQUATE GENERAL & LOCAL EXHAUST VENTILATION TO MINIMIZE EXPOSURE TO VAPORS. Other Precautions:BOND & GROUND CONTAINERS FOR TRANSFER OF PRODUCT TO PREVENT STATIC SPARKS. AVOID PROLONGED/REPEATED CONTACT W/SKIN & EYE CONTACT. STYRENE VAPORS ARE UNIHIBITED & MAY CAUSE BLOCKAGE OF VENTILATION VENT S DUETO POLYMERIZATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR/DUST RESPIRATOR TO AVOID INHALATION OF EXCESSIVE AIR CONTAMINANTS. Ventilation:LOCAL EXHAUST SHOULD BE USED TO CONTROL THE EMISSION OF AIR CONTAMINANTS. GENERAL DILUTION MAY REDUCE AIR CONCENTRATIONS Other Protective Equipment:SAFETY SHOWERS & EYE WASH STATIONS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN HANDS W/SOAP & WATER AFTER EVERY USAGE. Supplemental Safety and Health THE PHYSICAL DATA INFORMATION IS FOR STYRENE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:293F(SUPP) Vapor Pres:5.2(SUPP) Vapor Density:3.6(SUPP) Spec Gravity:1.05-1.35 Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE PASTE W/STYRENE ODOR Percent Volatiles by Volume:18 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, PEROXIDES, OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME. Hazardous Decomposition Products:CO, CO2, HYDROCARBONS, ORGANIC ACIDS. Conditions to Avoid Polymerization:UNREGULATED CONTACT W/ORGANIC PEROXIDES, EXPOSURE TO HEAT, OPEN FLAME & PROLONGED STORAGE >100F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. IF DISCARDED, MATERIAL & CONTAINERS ARE CONSIDERED RCRA HAZARDOUS WASTES BASED ON THE CHARACTERISTIC OF IGNITABILITY. UN1866.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIQUI-JET 2 DETERGENT Resp. Party Other MSDS Num.:MSDS NO.: 1037 Preparer's Name:M. EBERS CAGE:UO563 CAGE:UO563 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 < Wt:5. OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM SILICATE CAS:1344-09-8 < Wt:5. Ingred Name:TETRASODIUM ETHYLENEDIAMINE TETRAACETATE CAS:64-02-8 RTECS #:AH5075000 < Wt:30. ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE: SEVERE EYE IRRITANT. SKIN: IRRITATION WILL OCCUR UPON REPEATED CONTACT. INGESTION: HARMFUL IF SWALLOWED. INHALATION: IRRITATION MAY OCCUR. CHRONIC: NONE KNOWN. Explanation of Carcinogenicity:NOT LISTED AS A CARCINOGEN BY NTP, IARC OR OSHA. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN IF IRRITATION OC CURS. INGESTION: IF SWALLOWED, GIVE MILK OR WATER TO DILUTE MATERIAL. DO NOT INDUCE VOMITING. CALL A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREAT HING IS DIFFICULT, GIVE OXYGEN AND CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER, CARBON DIOXIDE OR FOAM. Fire Fighting Procedures:WEAR POSITIVE-PRESSURE SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WILL NOT BURN BUT MAY SPLATTER IF TEMPERATURE EXCEEDS BOILING POINT. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL AND SOAK UP WITH INERT ABSORBENT. PLACE INTO A CONTAINER FOR PROPER DISPOSAL. RINSE CONTAMINATED AREA WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM FREEZING. STORE AT TEMPERATURES BELOW 115 DEG F. STORE AWAY FROM ACIDS, STRONG OXIDIZING AGENTS, REDUCING AGENTS AND CHLORINE. Other Precautions:NFPA 704 HAZARD RATING: HEALTH-1, FIRE-0, REACTIVITY-0. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. Ventilation:GENERAL LOCAL EXHAUST VENTILATION AS NECESSARY TO CONTROL ANY RELEASE TO THE ENVIRONMENT IN EXCESS OF THE SPECIFIED THRESHOLD LIMIT. Other Protective Equipment:PROTECTIVE BODY EQUIPMENT TO PREVENT SKIN CONTACT. Supplemental Safety and Health PRODUCT NAME: LIQUI-JET 2 DETERGENT. PRODUCT DESCRIPTION: ALKALINE DETERGENT. MSDS NO.: 1037. ================== Physical/Chemical Properties ================== HCC:B3 Melt/Freeze Pt:M.P/F.P Text:N/AV Spec Gravity:1.13 (H20=1 @ 25C) pH:10.6-11.4(1%SOL Solubility in Water:100% Appearance and Odor:CLEAR LIGHT YELLOW LIQUID, BLAND ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZING AGENTS, REDUCING AGENTS AND CHLORINE. Stability Condition to Avoid:NONE KNOWN Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND NITROUS OXIDES IN A FIRE SITUATION. IN CONTACT WITH SOME METALS, HYDROGEN GAS MAY BE RELEASED. Conditions to Avoid Polymerization:WILL NOT OCCUR ==================== Disposal Considerations ==================== Waste Disposal Methods:FEDERAL, STATE, AND LOCAL DISPOSAL LAWS AND REGULATIONS WILL DETERMINE THE PROPER WASTE DISPOSAL PROCEDURE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:60,401-1;VVL-751D #1&2;WIRE ROPE&CHAIN LUBE Preparer's Name:THOMAS G. MUSILLI CAGE:JO986 CAGE:5A565 CAGE:1V074 CAGE:JO986 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL OIL CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: 50% OSHA PEL:5 MG/M3 OIL MIST ACGIH TLV:5 MG/M3 OIL MIST Ingred Name:MINERAL OIL CAS:4742-16-1 Fraction by Wt: 48% OSHA PEL:5 MG/M3 OIL MIST ACGIH TLV:5 MG/M3 OIL MIST Ingred Name:PETROLEUM SULFONATE CAS:25619-56-1 Fraction by Wt: 2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:UNKNOWN Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN AND RESPIRATORY TRACT POSSIBLE.NO ILL EFFECTS ARE KNOWN TO MFR. Explanation of Carcinogenicity:NTP & IARC LIST"SOME MINERAL OIL". MFR CLAIMS PRODUCTS IS NOT CARCINOGENIC. Effects of Overexposure:MILD IRRITATION TO SKIN OR EYE. NOT AN INHALATION HAZARD UNLESS MISTED (A VERY UNUSUAL OCCURRANCE). Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:430F,221C Autoignition Temp:Autoignition Temp Text:470F Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER FOG,EARTH OR SAND. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE NOTED.FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA.KEEP AWAY FROM SPARKS & OPEN FLAMES. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE EXPECTED TO BE NECESSARY. USE NIOSH/MSHA RESPIRATOR APPROVED FOR OIL MIST IN THE UNLIKELY EVENT. THE PRODUCT IS MISTED. Ventilation:NORMAL ROOM VENTILATION. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:700F/371C Spec Gravity:0.91 Solubility in Water:NIL Appearance and Odor:DARK VISCOUS OIL,BLAND ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION;CARBON DIOXIDE,CARBON MONOXIDE,SULFUR OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL,REGULATIONS. MFR SUGGESTS INCINERATE OR RECYCLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MULTITHERM PG-1 CAGE:MULTI CAGE:MULTI ============= Composition/Information on Ingredients ============= Ingred Name:SUPP DATA:ASPIR. SHORTNESS OF BRTH & COUGH ARE MOST COMMON SYMP. ASPIR MAY LEAD TO CHEM PNEUM WHICH IS CHARACT BY(ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: PULM EDEMA & HEMORR, & MAY BE FATAL. SIGNS OF LUNG INVOLVEMENT INCL INCR RESP RATE, INCR HEART RATE, & (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:BLUISH DISCOLORATION OF SKIN. COUGHING, CHOKING, & GAGGING ARE OFTEN NOTED AT TIME OF ASPIR. GI DISCOMFORT (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: MAY DEVELOP, FOLLOWED BY VOMITING, WITH FURTHER RISK OF ASPIRATION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:IS GENERATED WHEN MATL IS HEATED/HANDLED, REMOVE VICTIM FROM EXPOS.IF BRTHG HAS STOPPED/IS IRREG, (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ADMIN ARTF RESP/SUPPLY O*2 IF AVAIL. IF VICTIM IS UNCON, REMOVE TO FRESH AIR/SEEK MED ATTN. INGEST: MAY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: ACT AS A LAXATIVE. DO NOT INDUCE VOMITING. RTECS #:9999999ZZ Ingred Name:SPILL PROC: REMOVE ALL SOURCES OF IGNIT. ABSORB W/APPROP INERT MATL SUCH AS SAND, CLAY, ETC. LRG SPILLS MAY BE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: PICKED UP USING VACUUM PUMPS, SHOVELS, BUCKETS/OTHER MEANS & PLACED IN DRUMS/OTHER SUITABLE CONTAINERS. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: MATL WHEN SPILLED. WASTE MATL MAY BE LANDFILLED/INCIN AT AN APPRVD FACILITY. MATLS SHOULD BE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: RECYCLED IF POSSIBLE. RTECS #:9999999ZZ Ingred Name:RESP PROT: HYDROCARBON ATMOSPHERES. RTECS #:9999999ZZ Ingred Name:VENT: CONCENTRATIONS BELOW SPECIFIED EXPOSURE OR FLAMMABLE LIMITS. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: MATL, USE INSULATED PROTECTIVE CLOTHING RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT: FACE WITH SOAP AND WATER BEFORE EATING, DRINKING, OR SMOKING. RTECS #:9999999ZZ Ingred Name:MINERAL OIL, SLAB OIL; (WHITE MINERAL OIL) (PEL/TLV AS OIL MIST) CAS:8042-47-5 RTECS #:PY8047000 Fraction by Wt: 100% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3;10 STEL ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: PROD IS NON-IRRIT TO EYES UPON DIRECT CONT. SKIN: PROD IS NOT EXPECTED TO CAUSE ANY SKIN IRRIT UPON DIRECT SINGLE/RPTD & PRLNGD CONT; HOWEVER, SIMILAR CHEM COMPOSITION PRODS APPLIED TO SKIN OF LA B ANIMALS RSLTD IN MIN TO SLIGHT DERMALIRRIT. INHAL: PROD HAS LOW VAP PRESS & IS NOT EXPECTED TO (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: PRESENT AN INHAL HAZ AT AMBIENT CNDTNS. CAUTN SHOULD BE TAKEN TO PVNT AEROSOLIZATION/MISTING OF PROD. PEL AND TLV OR PROD AS OIL MIST IS 5 MG/M3. EXPOS BELOW 5 MG/M3 APPEAR TO BE W/ OUT SIGN IFICANT HLTH RISK. INGEST: INGST IS RELATIVELY NON-TOX UNLESS ASPIR OCCURS. PROD HAS LAXATIVE PROPERTIES & MAY (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH EYES W/LRG AMTS OF H2O & CONTINUE FLUSHING FOR AT LEAST 15 MIN. IF MATL IS HOT, TREAT FOR THERM BURNS & TAKE VICTIM TO HOSPITAL IMMED. SKIN: REMOVE CONTAM CLTHG. IF MATL IS HOT, SUBME RGE INJURED AREA IN COLD H2O. IF VICTIMIS SEVERELY BURNED, REMOVE TO HOSPITAL IMMED. INHAL: MATL HAS LOW VAP PRESS & IS NOT EXPECTED TO PRESENT AN INHAL EXPOS AT AMBIENT CNDTNS. IF VAP/MIST (ING 6) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:340F,171C Extinguishing Media:USE DRY CHEMICAL, FOAM, CARBON DIOXIDE, OR WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.H2O MAY BE INEFT BUT CAN BE USED TO COOL CNTNRS EXPOS TO HEAT/ FLAME. CAUTN SHOULD BE EXERCISED WHEN(SUPDAT Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE BURNING, CARBON MONOXIDE, CARBON DIOXIDE, AND OTHER OXIDES MAY BE GENERATED AS PRODUCTS OF COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:CONSULT HLTH EFT INFORM IN HLTH HAZ SEC, PERSONAL HLTH PROT INFORM IN CNTRL MEASURES, FIRE PROT INFORM IN FIRE PROT INFORM, & REACTIVITY DATA. NOTIFY APPROP AUTH OF SPILL. CONTAIN SPILL IMMED. DO NOT ALLOW SPILL TO ENTER SEWERS/WATERCOURSES. (ING 9) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TRANSFER TO UNMARKED CNTNRS. STORE IN CLOSED CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAME, OR OXIDIZING MATERIALS. Other Precautions:THIS PRODUCT IN NOT CLASSIFIED AS HAZARDOUS UNDER DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READILY AVAILABLE. SEE NFPA 30 AND OSHA 1910.106-FLAMMABLE AND COMBUSTIBLE LIQUIDS. NFPA CLASS IIIB STORAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESP PROT IS NOT REQD UNDER CNDTNS OF NORMAL USE. IF VAP/MIST IS GENERATED WHEN MATL IS HEATED/HANDLED, USE A NIOSH/MSHA APPRVD ORG VAP RESP W/DUST AND MIST FILTER. ALL RESP MUST BE NIOSH/MSHA CERTIFI ED. DO NOT USE COMPRESS O2 IN (ING 13) Ventilation:IF VAP/MIST IS GEN WHEN MATL IS HEATED/HNDLD,ADEQ VENT I/A/W GOOD ENGINEERING PRACT MUST BE PROVIDED TO MAINTAIN(ING 14) Other Protective Equipment:USE IMPERVIOUS SYNTH RUB CLTHG (BOOTS, HOT (ING 15) Work Hygienic Practices:CONSUMPTION OF FOOD & BEVERAGE SHOULD BE AVOIDED IN WORK AREAS WHERE HYDROCARB ARE PRESENT. ALWAYS WASH HANDS & (ING 16) Supplemental Safety and Health FIRE FIGHT PROC: USING H2O/FOAM AS FROTHING MAY OCCUR, ESPEC IF SPRAYED INTO CNTNRS OF HOT, BURNING LIQ. HLTH HAZ: RSLT IN ABDOMINAL CRAMPS & DIARR. HLTH DATA: ON RARE OCCAS, PRLNGD/RPTD EXPOS TO OIL MIST POSES RISK OF PULM DISEASE SUCH ASCHRONIC LUNG INFLAM. CNDTN IS USUALLY ASYMPTOMATIC AS RSLT OF RPTD SML (ING 2) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>513F,>267C Vapor Pres:<1 @ 70F Spec Gravity:0.875 @ 60F Solubility in Water:NIL Appearance and Odor:CLEAR FLUID, ODORLESS. Percent Volatiles by Volume:NIL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CO AND ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL DISP MUST COMPLY W/FED,ST,& LOC REGS. MATL,IF SPILLED/DISCARDED, MAY BE REG WASTE.REFER TO STATE & LOC REGS.CAUTN! IF REGULATED SOLV ARE USED TO CLEAN UP SPILLED MATL,RSLTG WASTE MIX MAY BE REGULA TED. DOT REGS MAY APPLY FOR TRANSPORTING (ING 11)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:350 VOC CLEAR OIL STAIN BASE, 3850404 Preparer's Name:ZEKE CAGE:1GK99 CAGE:1GK99 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (SOLVENT NAPHTHA MED ALIPHATIC) VP: 1.2 @ 68F CAS:64742-88-7 RTECS #:WF3450000 Fraction by Wt: 30% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:NAPHTHA, HEAVY ALKYLATE; (SOLVENT NAPHTHA HEAVY ALIPHATIC) VP: 1 @ 100F CAS:64741-65-7 Fraction by Wt: 4% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (SOLVENT NAPHTHA LIGHT AROMATIC) VP: 28.3 @ 68F CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 3% OSHA PEL:400 PPM (MFR) ACGIH TLV:50 PPM (MFR) Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313) VP: 28 @ 68F CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 1% OSHA PEL:25 PPM ACGIH TLV:25 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: DIZZ, FATG, BRTHG DFCLTY, NASAL RESP IRRIT, HDCH & LOSS OF COORD. SKIN CONT: IRRIT, DEFAT, DERM. SKIN ABSORPTION: NOT EXPECTED TO BE A PRIMARY SKIN IRRITANT. HOWEVER, IRRIT MAY BE NOTED FOLLOWING PRLNG/FREQUENTLY RPTD CONT WHICH MAY CAUSE SKIN TO BECOME DRY/CRACKED FROM DEFAT ACTION. (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-TRIPOLI: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: ANTIC TO BE CARCIN. Effects of Overexposure:HLTH HAZ: INGEST: MAY BE HARMFUL/FATAL IF SWALLOWED. MAY CAUSE NAUS, VOMIT, DIARR, & GI IRRIT. EYES: REDNESS, TEARING & BLURRED VISION. CHRONIC: INHAL: RPTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SO LVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL/FATAL. Medical Cond Aggravated by Exposure:ANESTHESIA, RESPIRATORY TRACT IRRITATION, DERMATITIS, NAUSEA, VOMITING, POSSIBLE UNCONSCIOUSNESS AND EVEN ASPHYXIATION. ======================= First Aid Measures ======================= First Aid:SKIN: CLEAN WITH SOAP AND WATER. INGESTION: HARMFUL OR FATAL. DO NOT INDUCE VOMITING. CONSULT MD. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES . CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:0.9% Upper Limits:6% Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIP . DO NOT USE WATER EXCEPT IN THE FORM OF FOG. EXCLUDE AIR. CONSULT LOCAL FIRE MARSHALL. COMBUST CLASS II. Unusual Fire/Explosion Hazard:VAP FORMS EXPLO MIXT W/AIR BETWEEN UPPER & LOWER EXPLO LIMS. DO NOT OPEN/USE NEAR ANY FLAME/SPARK SOURCE. IMPORTANT: TO AVOID SPONT COMBUST DURING (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP IMMEDIATELY AND SAFELY DISCARD ABSORBENTS. IN THE EVENT OF LARGE SPILLS, DIKE THE AREA AND PUMP THE MATERIAL TO AN EPA PERMITTED WASTE TANK. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:TOOLS TO OPEN ANY CONTR MUST BE NON-SPARKING. PRIOR TO OPENING CONTR, ELECTROSTATIC BONDING BETWEEN DISPENSING & RECEIVING CONTR MUST BE ACCOMPLISHED. Other Precautions:IN ADDITION, ELECTROSTATIC GROUNDING OF THE CONTAINERS MUST BE PROVIDED. AVOID PROLONGED BREATHING OF VAPORS. AVOID PROLONGED OR REPEATED SKIN CONTACT. AVOID ALL SOURCES OF HEAT, OPEN FLAMES, SPARKS A ND STATIC ELECTRICITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IF AIRBORNE CONCS ARE MAINTAINED BELOW OCCUP EXPOS LIMS LISTED IN INGS SECTION. FOR AIRBORNE CONCS HIGHER THAN SUCH LIMS, WEAR NIOSH APPRVD MASK FOR ORG VAP, DUST, MIST & FUMES. WHEN USI NG IN POORLY VENTILATED & (SUP DAT) Ventilation:EXHAUST WITH EXPLOSION-PROOF EQUIPMENT IS RECOMMENDED TO MAINTAIN CONCENTRATIONS BELOW TLV AND LEL LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR PROTECTIVE CLOTHING AND BOOTS. Work Hygienic Practices:USE GOOD PERS HYGIENE PRACTICES. DRY CONTAM CLOTHING BEFORE REUSE. BARRIER CREAMS, DAILY SHOWERS & CHANGE OF CLOTHES. Supplemental Safety and Health EXPLO HAZ: STOR, SOAK SOILED RAGS IN WATER-FILLED CLSD METAL CONTR IMMED AFTER USE. RESP PROT: CONFINED SPACES, USE NIOSH APPRVD FRESH-AIR SUPPLYING/SCBA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>315F,>157C Vapor Pres:SEE INGS Vapor Density:HVR/AIR VOC Pounds/Gallon:350 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORED LIGHT LIQUID WITH MINERAL SPIRITS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NEVER USE NEAR TO AN OPEN FLAME. EXCESS HEAT MAY CAUSE CONTAINERS TO RUPTURE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, VARIOUS HYDROCARBONS, ETC, BY COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS CURRENTLY IN FORCE FOR THIS PRODUCT HAZARD CLASS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CLAY PIPE WITH POLYURETHANE JOINTS Preparer's Name:NORMITA G. CALLISON CAGE:TO106 CAGE:TO106 ============= Composition/Information on Ingredients ============= Ingred Name:CLAY/SHALE (ALUMINUM SILICATES) (VARIOUS CAS NUMBERS) > Wt:70. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:GROG > Wt:29. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:BARIUM CARBONATE CAS:513-77-9 RTECS #:CQ8600000 < Wt:1. OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 Ingred Name:QUARTZ; (CRYSTALLINE SILICA (QUARTZ)) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:see Table Z-3 ACGIH TLV:0.1 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE CNTCT: DIRECT CNTCT W/DUST MAY CAUSE IRRIT BY MECH ABRASION. SKIN CNTCT: DIRECT CNTCT MAY CAUSE IRRIT BY MECH ABRASION. SKIN ABSORPTION: NOT EXPECTED TO BE SIGNIFICANT EXPOS ROUTE. INGEST: EXPECTED TO BE PRACTICALLY NON-TOX. INGEST OF LG AMTS MAY CAUSE GI IRRIT & BLOCKAGE. INHAL: DUSTS MAY IRRIT NOSE, THROAT & RESP TRACT BY MECH ABRASION. COUGH, SNEEZING, & SHORTNESS OF BREATH MAY OCCUR FOLLOWING EXPOS IN EXCESS OF APPROP EXPOS LIMS. USE OF NATRL SAND & GRAVEL FOR CONSTRUCTION PURPOSES IF NOT BELIEVED TO CAUSE ADDNL ACUTE TOX EFTS. HOWEVER, RPTD OVEREXP TO VERY HIGH LEVELS OF RESPIR ABLE CRYSTALLINE (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE QUARTZ: IARC MONOGRAPHS, VOL 68, 1997:GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998:REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN. Effects of Overexposure:HLTH HAZS: SILICA (QUARTZ, CRISTOBALITE, TRIDYMITE) FOR PERIODS AS SHORT AS SIX MONTHS HAVE CAUSED ACUTE SILICOSIS. ACUTE SILICOSIS IS RAPIDLY PROGRESSIVE, INCURABLE LUNG DISEASE THAT IS TYPICALLY FAT AL. SYMPS INCL (BUT ARE NOT LIMITED TO):SHORTNESS OF BREATH, COUGH, FEVER, WT LOSS & CHEST PAIN. SUBCHRONIC & CHRONIC EFTS: PULM DISEASES: EXCESSIVE EXPOS TO PARTICULATES (DUST) OVER EXTENDED PERIOD O F TIME MAY RSLT IN DEVELOPMENT OF SILICOSIS & OTHER PULM DISEASE. SEE ALSO: AMERICAN SOCIETY FOR TESTING & MATLS (ASTM ) "STD PRACTICE E-1132-86, "STD PRACTICE FOR HLTH REQS RELATING TO OCCUP EXPOS TO QUARTZ DUST." Medical Cond Aggravated by Exposure:EXCESS DUST EXPOS MAY AGGRAVATE ANY EXISTING RESP DISORDERS OR DISEASES. POSS COMPLICATIONS OF ALLERGIES RSLTG IN IRRIT TO SKIN, EYES & RESP PASSAGE MAY OCCUR FROM EXCESS EXPOS TO DUSTS. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH EYE(S) W/PLENTY OF CLEAN WATER FOR AT LEAST 15 MIN WHILE HOLDING EYELID(S) OPEN. OCCASNLY LIFT EYELID(S) TO ENSURE THOROUGH RINSING. BEYOND FLUSHING, DO NOT ATTEMPT TO REMOVE MATL FR OM EYE(S). CNTCT PHYSICIAN IF IRRIT PERSISTS OR LATER DEVELOPS. SKIN: WASH W/SOAP & WATER. CONTACT PHYSICIAN IF IRRIT PERSISTS OR LATER DEVELOPS. INGEST: IF PERSON IS CONSCIOUS, GIVE LARGE QTY OF WATE R & INDUCE VOMIT; HOWEVER, NEVER ATTEMPT TO MAKE UNCON PERSON DRINK OR VOMIT. GET IMMED MED ATTN. INHAL: REMOVE TO FRESH AIR. DUST IN THROAT & NASAL PASSAGES SHOULD CLEAR SPONT. CNTCT PHYSICIAN IF IRR IT PERSISTS OR LATER DEVELOPS. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NONE. USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:USE ADEQ VENT, DUSTLESS VACUUM OR CLEANUP SYSTEMS FOR HNDLG, STORAGE & CLEAN-UP SO AIRBORNE DUST DOES NOT EXCEED PEL. PRACTICE GOOD HOUSEKEEPING. DO NOT PERMIT DUST TO COLLECT ON WALLS, FLOORS, SILLS, LEDGES, MACHINERY OR EQUIP. MAINTAIN, CLEAN & FIT TEST RESPS I/A/W OSHA STDS. MAINTIAN & TEST VENT & DUST COLLECTION EQUIP. WASH/VACUUM CLTHG WHICH BECOMES DUSTY. SEE ALSO CTL MEASURES. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE FOR NORMAL HNDLG & STORAGE OF INTACT SEWER PIPE. FOR SFTY REASONS, STORE LG DIAMETER PIPE ON RUNNERS & NAIL WOOD BLOCK AT EACH END OF RUNNERS. PROD IS NOT INTENDED OR DESIGNED FOR USE AS ABRASIVE BLASTING MEDIUM OR FOR FOUNDRY APPLICATIONS & SHOULD NOT BE USED FOR THOSE PURPOSES. (SUPDAT) Other Precautions:RESPIRABLE DUST & QUARTZ LEVELS SHOULD BE MONITORED REGULARLY. DUST & QUARTZ LEVELS IN EXCESS OF APPROP EXPOS LIMS SHOULD BE REDUCED BY FEASIBLE ENGINEERING CONTROLS, INCLUDING (BUT NOT LIMITED TO) W ET SANDING, WET SUPPRESSION, VENT & PROCESS ENCLOSURES. NIOSH APPRVD RESPS MUST BE WORN WHEN SUCH CO NTROLS ARE (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:TO MIN EXPOS TO DUST &/OR CRYSTALLINE SILICA, CUTTING/GRINDING VITRIFIED CLAY SEWER PIPE & OTHER CLAY PRODS SHOULD BE CONDUCTED W/WET SAW/GRINDER & W/SUFFICIENT VENT. WHEN SUCH CTLS NOT FEASIBLE, NIOS H APPRVD RESPS MUST BE WORN I/A/W NIOSH APPRVD RESP PROT PROGRAM WHICH MEETS OSHA REQS AS SET FORTH AT 29CFR 1910.134 & ANSI Z88.2-1080 "PRACTS FOR RESP PROT." Ventilation:WHEN DRY SAWING OR GRINDING CLAY ROOF TILE, USE SUFFICIENT LOC EXHST TO REDUCE LEVEL OF RESPIRABLE DUST TO APPLIC STDS SET FORTH. SEE ACGIH (SUPDAT) Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR HARD HATS &/OR STEEL-TOED SAFETY SHOES IF TILES MAY FALL FROM ELEVATION OR BE DROPPED DURING HANDLING. Work Hygienic Practices:AVOID CREATING AND BREATHING DUST. Supplemental Safety and Health HNDLG/STOR PRECS: DO NOT STORE NEAR FOOD & BEVERAGES OR SMKNG MATLS. OTHER PRECS: ARE NOT FEASIBLE OR DO NOT COMPLETELY CONTROL DUST GENERATION. VENT: "INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICE," LATEST EDITION. ================== Physical/Chemical Properties ================== Spec Gravity:2.6 (H*2O=1) Solubility in Water:0 Appearance and Odor:VITRIFIED SOLID, ESSENTIALLY ODORLESS, WIDE RANGE OF COLORS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE KNOWN. =================== Toxicological Information=================== Toxicological Information:OTHER INFO: (OTHER FORMS OF CRYSTALLINE SILICA) ARE EQUAL TO ONE-HALF OF LIMS FOR QUARTZ. PARTICULATES OR DUST: TLV = 10MG/M3 (TOTAL PARTICULATE) OR 3MG/M3 (RESPIRABLE PARTICULATE), NOT OTHERWISE CLAS SIFIED; OSHA PEL = 15MG/M3 (TOTAL PARTICULATE, NOT OTHERWISE REGULATED). OSHA PEL = 5MG/M3 (RESPIRABLE PARTICULATE, NOT OTHERWISE REGULATED). RESPIRABLE CRYSTALLINE SILICA (QUARTZ): TLV = 0.1 MG/M3; O SHA PEL = 10 MG/M3 DIVIDED BY (%SIO*2 + 2); OSHA PROPOSED PEL 0.1 MG/M3. RESPIRABLE DUST CONTAINING SILICA: OSHA PEL = 10MG/M3 DIVIDED BY (%SIO*2 +2). TOTAL DUST CONTAINING SILICA: OSHA PEL = 30MG/M3 DIVIDED BY (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:TOXICOLOGICAL INFO: (%SIO*2 +2). ACGIH & OSHA HAVE DETERMINED THAT ADVERSE EFTS ARE NOT LIKELY TO OCCUR IN WORKPLACE PROVIDED EXPOSURE LEVELS DO NOT EXCEED APPROP TLVS/PELS. HOWEVER, BECAUSE OF THE WI DE VARIATION IN INDIVIDUAL SUSCEPTIBILITY, LOWER EXPOS LIMITS MAY BE APPROP FOR SOME INDIVIDUALS, INCLUDING PERSONS W/PRE-EXISTING MED CONDITIONS SUCH AS THOSE DESCRIBED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . THIS MATERIAL IS CLASSED AS A NON-HAZARDOUS SOLID WASTE FOR DISPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT HAZARD CLASSIFICATION: NOT REGULATED. UN/NA CODE: NONE. PLACARD REQUIRED: NONE. LABELING REQUIREMENT: NONE. ===================== Regulatory Information ===================== Federal Regulatory Information:COMMUNITY RIGHT-TO-KNOW = THIS PRODUCT IS NOT SUBJECT TO THE REPORTING REQUIREMENTS OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (EPCRA) (40 CFR 370 AND 372). State Regulatory Information:CALIRONIA PROPOSITION 65 WARNING: DRY CUTTING, SANDING OR GRINDING OF VITRIFIED CLAY SEWER PIPE AND CLAY PRODUCTS WILL EXPOSE YOU TO RESPIRABLE CRYSTALLINE SILICA WHICH IS "KNOWN IN THE STATE OF CALIF ORNIA TO CAUSE CANCER AND TO OTHER SUBSTANCES WHICH ARE KNOWN OT THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM." ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEKSOL Preparer's Name:RICH HENRY CAGE:ADVCI CAGE:05HH6 CAGE:ADVCI ============= Composition/Information on Ingredients ============= Ingred Name:HALOGENATED HYDROCARBON-TRADE SECRET PENDING Fraction by Wt: 100% Other REC Limits:8-HR TWA - 100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:RECOMMEDED TWA 8-HR: 100 PPM. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS ARE IRRITATING TO THE RESPIRATORY TRACT; MAY CAUSE CNS EFFECTS. CONTACT MAY CAUSE SKIN & EYE IRRITATION. INGESTION MAY CAUSE IRRITATION OF MOUTH & GI TRACT; CNS EFFEC TS. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED-RESPIRATORY IRRITATION, HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS. SKIN-IRRITATION, DERMATITIS. EYES-IRRITATION, PAIN. INGESTED-IRRITATION OF MOUTH/GI TRACT, ABDOMINAL PAIN, VOMITING, HE ADACHE, DIZZINESS, NARCOSIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:IN ALL CASES GET MEDICAL ATTENTION. EYES-FLUSH WITH WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRAT ION AS NEEDED. INGESTED-IF CONSCIOUS, DRINK LARGE AMOUNTS OF WATER. DO NOT INDUCE VOMITING! NOTHING BY MOUTH IF UNCONSCIOUS! ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:MATERIAL IS NON-FLAMMABLE. DLA-HMIS: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:PRODUCT WILL DECOMPOSE AT TEMPERATURES ABOVE 400F RELEASING TOXIC FUMES OF CARBON DIOXIDE, CARBON MONOXIDE AND HYDROGEN BROMIDE. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. STOP LEAK IF CAN BE DONE WITHOUT RISK. CONTAIN SPILL AND COVER WITH VERMICULITE. PLACE IN A CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. PROTECT FROM EXTREME TEMPERATURES. ISOLATE INCOMPATIBLE MATERIALS. Other Precautions:KEEP THIS MATERIAL OUT OF REACH OF CHILDREN. MINIMIZE BODY CONTACT WITH THIS PRODUCT. AVOID INHALAING FUMES OR VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IAW 29 CFR 1910.134. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO KEEP VAPOR AND MISTS LEVELS AS LOW AS POSSIBLE. Other Protective Equipment:DO NOT WEAR CONTACT LENSES. CLEAN, BODY-COVERING CLOTHING, APRON, BOOTS NOT MADE OF NATURAL RUBBER. EYE WASH/SHOWER. Work Hygienic Practices:ELIMINATE BODY CONTACT WITH THIS CHEMICAL. DO NOT EAT, DRINK OR SMOKE UNTIL AFTER WORK OR WASHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:156F,69C Melt/Freeze Pt:M.P/F.P Text:-166F,-110C Vapor Pres:143 Vapor Density:4.3 Spec Gravity:1.32 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. MAY ATTACK SOME PLASTICS, RUBBER AND COATINGS. Stability Condition to Avoid:AVOID TEMPERATURES AABOVE 400F (204.4C). Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE AND CARBON DIOXIDE, HYDROGEN BROMIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS. DO NOT FLUSH TO SANITARY SEWER OR WATERWAY. REFER TO RCRA REGULATIONS 40 CFR 260-281 FOR WASTE DISPOSAL INTRUCTIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HERITAGE GLOSS LATEX HOUSE PAINT, 5-8300 CAGE:WATTL CAGE:WATTL ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHALATION:W/POOR VENTILATION, VAPOR OR MIST MAY IRRITATE RESPIRATORY MUCOUS MEMBRANES, CAUSING HEADACHE & NAUSEA. EYE CONTACT:PRIMARY IRRITANT. CHRONIC:NONE RECOGNIZED. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. EYE:FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. TAKE TO MD FOR MEDICAL TREATMENT. SKIN:REMOVE W/SOAP & WATER. IF DRENCHED, REMOVE CONTAMINATED. INGES T:IF VICTIM IS CONSCIOUS, GIVE 2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD OR POISON CONTROL CENTER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Extinguishing Media:WATER FOG (APPLICABLE ONLY FOR COOLING CLOSED CONTAINERS). Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AS DESCRIBED IN SPECIAL PROTECTION INFO SECTION. AVOID UNNECESSARY SKIN CONTACT. COLLECT BY ABSORPTION, SHOVEL &/OR WET MOPPING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE >120F. CLOSE CONTAINER AFTER EACH USE. DO NOT TAKE INTERNALLY. Other Precautions:PIGMENTED PAINT & COATINGS (THOSE WHICH ARE OPAQUE, COLORED/WHICH HAVE REDUCED GLOSS WHEN DRY) MAY CONTAIN MATLS SUCH AS SILICA, TALC, CALCIUM CARBONATE, TITANIUM DIOXIDE, ETC, WHICH ARE HAZ TO INHALE IN DRY POWDER FORM. THESE HAZS (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DURING SPRAY APPLICATION USE NIOSH/MSHA APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY. Ventilation:PROVIDE SUFFICIENT VENT, IN VOL & PATTERN, TO INSURE VAP CONCS WELL BELOW ANY TLV & LEL LISTED. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:OBSERVE GOOD SANITARY PRACTICES. Supplemental Safety and Health OTHER PREC:ARE NOT BELIEVED TO BE PRESENT WHEN POWDERS ARE DISPERSED IN LIQ COATINGS. HOWEVER, PRECS SHOULD BE CAREFULLY OBSERVED & NIOSH/MSHA APPRVD RESPS SHOULD ALSO BE USED IF DRIED COATING IS SAND ED/ABRADED IN SUCH A WAY AS TO PRDCE DUST. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:LTR/AIR Spec Gravity:1.1-1.26 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:63-69 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, AS IN A FIRE OR IN WELDING, MAY PRODUCE TOXIC FUMES SUCH AS CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:897 4875 CLEANING FLUID CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA 313) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: >99% Other REC Limits:NONE RECOMMENDED OSHA PEL:400 PPM ACGIH TLV:400 PPM/500STEL;9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL (RAT): 5.8 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION OF HIGH VAPOR CONCENTRATIONS MAY CAUSE NARCOSIS, IRRITATION. EYE CONTACT CAUSES IRRITATION. LOW SKIN CONTACT FOR RECOMMENDED HANDLING. EXPECTED TO BE A LOW INGESTION HAZARD. INGESTION OF LA RGE AMOUNTS MAY CAUSE HEADACHE, DIZZINESS, INCOORDINATION, VOMITING, CONFUSION, STUPOR, KIDNEY INJURY, COMA, DEATH. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE/NOSE/THROAT IRRITATION, NARCOSIS, EYE IRRITATION, HEADACHE, DIZZINESS, INCOORDINATION, VOMITING, CONFUSION, STUPOR, KIDNEY INJURY, COMA, DEATH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:53.1F,11.7C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. WATER MAY BE INEFFECTIVE IN FIGHTING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER. Unusual Fire/Explosion Hazard:VAPOR IS FLAMMABLE AND HEAVIER THAN AIR AND MAY TRAVEL TO SOURCE OF IGNITION AND FLASHBACK. PREVENT BUILDUP OF VAPORS OR GASES TO EXPLOSIVE CONCENTRATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. KEEP AWAY FROM HEAT, SPARKS AND FLAMES. Other Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS. USE WITH ADEQUATE VENTILATION. COMPLY WITH ALL NATIONAL, STATE AND LOCAL CODES PERTAINING TO STORAGE, HANDLING, DISPENSING AND DISPOAL OF FLAMMABLE LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ORGANIC VAPOR. Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS. Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health IF PEROXIDE FORMATION IS SUSPECTED, DO NOT OPEN OR MOVE CONTAINER. PERIODICALLY TEST FOR PEROXIDE FORMATION ON LONG-TERM STORAGE. ADDITION OF WATER OR APPROPRIATE REDUCING MATERIALS WILL LESSEN PEROXI DE FORMATION. DO NOT DISTILL OR ALLOW TO EVAPORATE TO NEAR DRYNESS. MINIMIZE EXPOSURE TO AIR. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:180F,82C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:33 Vapor Density:2.1 Spec Gravity:0.79 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID, SOLVENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:FORMS EXPLOSIVE PEROXIDES WHICH MAY BE SHOCK SENSITIVE. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL REGULATIONS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY. DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GERBER COLOR CARTRIDGE; PROCESS YELLOW CAGE:GERBB CAGE:GERBB ============= Composition/Information on Ingredients ============= Ingred Name:VINYL ACETATE CAS:108-05-4 RTECS #:AK0875000 Fraction by Wt: 0.0001% Other REC Limits:10 PPM ACGIH TLV:35 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS (IARC CARC GROUP 3) - *96-2* CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:3.5 MG/CUM (NIOSH) OSHA PEL:3.5 MG/CUM ACGIH TLV:3.5 MG/CUM Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (KNOWN CARCINOGEN BY NTP; IARC CARC - GROUP 3) *96-2* CAS:7440-47-3 RTECS #:GB4200000 ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT CAS:1309-37-1 RTECS #:NO7400000 OSHA PEL:10 MG/CUM ACGIH TLV:5 MG/CUM (FE) Ingred Name:SILICA, AMORPHOUS, PRECIPITATED AND GEL, SYNTHETIC CRYSTALLINE-FREE SILICA GEL *96-2* CAS:112926-00-8 RTECS #:VV7315000 ACGIH TLV:10 MG/CUM Ingred Name:DI-SEC-OCTYL PHTHALATE, BIS (2-ETHYLHEXYL) PHTHALATE (DOP), (SUSP ANIMAL CARC BY IARC-GROUP 2B; SUSP CARC BY NTP) *96-2* CAS:117-81-7 RTECS #:TI0350000 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-2* CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-2* CAS:108-88-3 RTECS #:XS5250000 Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURY, QUICKSILVER (IARC CARCINOGEN GROUP 3) *96-2* CAS:7439-97-6 RTECS #:OV4550000 Other REC Limits:INORGANIC 0.1 MG/CUM ACGIH TLV:0.01 MG/CUM (SKIN) EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AMINOBENZENE, ANILINE (SUSPECTED ANIMAL CARCINOGEN - IARC GROUP 3) *96-2* CAS:62-53-3 RTECS #:BW6650000 Other REC Limits:2 PPM (SKIN) OSHA PEL:OP MG/CUM ACGIH TLV:7.6 MG/CUM (SKIN) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC, ARSENICALS (HUMAN & ANIMAL CARCINOGEN BY IARC, IARC GROUP 1; CONFIRMED CARCINOGEN BY NTP & OSHA) *96-2* CAS:7440-38-2 RTECS #:CG0525000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.2 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CADMIUM (SUSPECTED HUMAN CARCINOGEN BY IARC, SUPSECTED CARCINOGEN BY NTP, IARC - GROUP 1)*96-2* CAS:7440-43-9 RTECS #:EU9800000 Other REC Limits:A2 CARCINOGEN OSHA PEL:0.05 MG/CUM (CD) ACGIH TLV:0.01 MG/CUM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:3,3'-DICHLOROBENZIDINE (SUSPECTED ANIMAL CARCINOGEN BY ACGIH, IARC GROUP 2B & NTP) *96-2* CAS:91-94-1 RTECS #:DD0525000 ACGIH TLV:N/K (A2) EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYL ACRYLATE (CARCINOGEN BY NTP & IARC - GROUP 2B)*96-2* CAS:140-88-5 RTECS #:AT0700000 Other REC Limits:5 PPM OSHA PEL:100 MG/CUM ACGIH TLV:20 MG/CUM (SKIN) A2 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LEAD, INORGANIC LEAD (IARC CARC GROUP 2B) *96-2* CAS:7439-92-1 RTECS #:OF7525000 ACGIH TLV:0.15 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B, SUSPECTED CARCINOGEN BY NTP) *96-2* CAS:7440-02-0 RTECS #:QR5950000 Other REC Limits:1 MG/CUM OSHA PEL:1 MG/CUM ACGIH TLV:0.05 MG/CUM IC Ingred Name:SELENIUM SULFIDE CAS:7446-34-6 RTECS #:VT0525000 OSHA PEL:0.2 MG/CUM ACGIH TLV:0.2 MG/CUM Ingred Name:ANTIMONY CAS:7440-36-0 RTECS #:CC4025000 OSHA PEL:0.5 MG/CUM ACGIH TLV:0.5 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM SULFATE, BARYTES *96-2* CAS:7727-43-7 RTECS #:CR0600000 OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING *96-2* CAS:1317-65-3 RTECS #:EV9580000 ACGIH TLV:10 MG/CUM (DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION: COULD RESULT IN MILD RESPIRATORY IRRITATION WHEN SAWING, SANDING/EXCESSIVE HANDLING. EYES: MAY TEMPORARILY IRRITATE. EXTREME OVEREXPOSURE TO DUST CAN CAUSE DAMAGE TO LIVER. Explanation of Carcinogenicity:SEE INGREDIENTS. Effects of Overexposure:IRRITATION, ITCHING, SCRATCHING, DRYNESS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER WHILE HOLDING EYELIDS OPEN. INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, FOAM, CO2/WATER Fire Fighting Procedures:WEAR RESPIRATOR (PRESSURE DEMAND, SELF CONTAINED BREATHING APPARATUS, MSHA/NIOSH APPROVED) & FULL PROTECTIVE GEAR FOR WORKING FIRES. Unusual Fire/Explosion Hazard:PRODUCT IS COMBUSTIBLE PLASTIC FILM. WHEN HEATED, PRODUCT MAY BECOME UNUSABLE (BLOCK). OVERHEATING AT TEMPS >300F CAN GENERATE SMOKE & ACRID FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:FOR CLEANUP, VACUUM DUST THAT MAY BE GENERATED & DISPOSED OF ACCORDINGLY. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY ATMOSPHERE, 60-80F, 40% RELATIVE HUMIDITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION/CONTAINMENT OF MEASURES DOESN'T RELIABLY PROTECT AGAINST INHALATION OVEREXPOSURE, WEAR MSHA/NIOSH APPROVED RESPIRATOR SUITABLE FOR PROTECTION FROM THE DUST CONCENTRATIONS ENCOUNTERED. Ventilation:LOCAL EXHAUST VENTILATION THAT CAPTURES DUST DURING SAWING/SANDING OPERATIONS. Other Protective Equipment:HAVE SOURCE OF RUNNING WATER FOR CLEANING SKIN & EYES. Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER AFTER HANDLING & ESPECIALLY BEFORE EATING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:<0.1 Appearance and Odor:COATED POLYESTER FILM, YELLOW IN COLOR W/CHARACTERISTIC ODOR Percent Volatiles by Volume:<1.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DOESN'T REACT W/ANY COMMON SUBSTANCE. Stability Condition to Avoid:OVERHEATING/PROLONGED HEATING AT ELEVATED TEMPS > 300F. Hazardous Decomposition Products:CO, CO2, SMALL QUANTITIES OF NITRIC OXIDES, TRACE LEVELS OF HYDROGEN CHLORIDE & ACETIC ACID, SMOKE & ACRID FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF/INCINERATE/LANDFILL IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PAINT BLACK 412-0021 L021 4AHK33407 Preparer's Name:HENRY SIMMONS CAGE:AKZCA CAGE:AKZCA ============= Composition/Information on Ingredients ============= Ingred Name:ALPHATIC HYDROCARBON SOLVENT CAS:64741-41-9 < Wt:5. OSHA PEL:500 PPM Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 < Wt:1. OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Minumum % Wt:30. Maxumum % Wt:45. OSHA PEL:2900 MG/M3;500 PPM ACGIH TLV:525 MG/M3;100 PPM Ingred Name:ORGANIC LEAD DRIER < Wt:5. OSHA PEL:0.05 MG/M3 ACGIH TLV:AS PB, 0.15 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:ACUTE: 1. EXCESSIVE VAPOR CONCENTRATION IN AIR, ESPECIALLY IN CONFINED SPACES, MAY CAUSE ASPHYXIATION. 2. EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL, THROAT, AND RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONCIOUSNESS. 3. SANDING DUST OR DRY SPRAY MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTEM. 4. EYE CONTACT WITH LIQUID, VAPOR OR SPRAY MIST CAUSES IR RITATION, REDNESS, TEARING, BLURRED VISION, AND A SENSATION OF SEEING HALOS AROUND LIGHTS. 5. DRY DUST MAY CAUSE MECHANICAL EYE IRRITATION. 6. PROLONGED SKIN CONTACT MAY LEAD TO EXTRATION OF NATURAL O ILS WITH RESULTANT DRY SKIN, CRACKING. Medical Cond Aggravated by Exposure:NONE EXPECTED. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF NECESSARY.SKIN CONTACT: WASH WITH SOAP AND WATER. DO NOT ORGANIC SOLVENTS. EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CONSU LT A PHYSICIAN. INGESTION: DRINK ONE OR TWO GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point:=40.6C, 105.F Lower Limits:0.6 Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS ARE DESIRABLE. WATER SPRAY IS LESS EFFECTIVE. Fire Fighting Procedures:WATER SHOULD BE USED TO COOL CONTAINERS EXPOSED TO FIRE. FIRE FIGHTING PERSONNEL SHOULD WEAR SELF-CONTAINING BREATHING APPARATUS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED, ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES RE QUIRES SPECIAL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS, VENTILATE AREA, REMOVE WITH INERT ABSORBENT USING NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS OUT OF SUN AND AWAY FROM HEAT, SPARKS AND OPEN FLAMES. STORE PLASTIC CONTAINERS OF FLAMMABLE LIQUIDS INSIDE CLOSED, APPROVED CONTAINERS OR SAFETY CABINETS. CLOSE ALL CONTAINERS AFTER EACH USE. CONSULT NFPA AND LOCAL CODES FOR ADDITIONAL STORAGE REQUIREMENTS. Other Precautions:DO NOT TAKE INTERNALLY. USE APPROVED BONDING AND GROUNDING PROCEDURE WHEN TRANSFERRING LIQUIDS. OBSERVE LABEL PRECAUTIONS. KEEP CLOSURES TIGHT AND CONTAINER UPRIGHT TO PREVENT LEAKAGE. NEVER USE PRESS URE TO EMPTY CONTAINER ? DRUM IS NOT A PRESSURE VESSEL. AVOID BREATHING SANDING DUST. DO NOT WELD OR FLAME CUT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ADEQUATE VENTILATION IS REQUIRED. USE NIOSH/MSHS APPROVES RESPIRATOR DEVICE. SEE YOUR SAFETY EQUIPMENT SUPPLIER FOR EVALUATION AND RECOMMENDATION. IN CONFINED AREAS USE NIOSH/MSHA APPROVED AIRLINE RES PIRATOR OR HOOD. Ventilation:PROVIDE SUFFICIENT VENTILATION TO KEEP VAPOR CONCENTRATION BELOW THE GIVEN TLV AND PEL. SPLASH OF LIQUIDS. Other Protective Equipment:EYE AND BATH SHOWER SHOULD BE AVAILABLE. USE CHEMICAL RESISTANT APRON, BOOTS OR OTHER CLOTHING IF NEEDED TO AVOID REPEATED OR FREQUENT SKIN CONTACT. LIQUID MAY PENETRATE CLOTHING, SHOES AND LEATHER. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING THE WASHROOM, LAUNDER CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=148.9C, 300.F B.P. Text:300-490F Spec Gravity:0.92 Percent Volatiles by Volume:56 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN AND SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL POLLUTION REQUIREMENTS RAGS, FILTERS, PAINT SUITS, EMPTY CANS, ETC., CONTAMINATED WITH PRODUCT MAY BE HAZARDOUS WASTE. DETERMINE WHETHER CONTAMI NATED PRODUCTS ARE HAZARDOUS BEFORE DISPOSAL AND DISPOSE OF AS APPROPRIATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1B3GT/1G3GT CAGE:OD426 CAGE:OD426 CAGE:33173 ============= Composition/Information on Ingredients ============= Ingred Name:RHENIUM 187 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health SOURCE OF DATA-MIL HANDBOOK 600-1 SEP 76.SAFETY & HEALTH DATA DEVELOPED BY DGSC-STF. ================== Physical/Chemical Properties ================== HCC:A3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SAFETY YELLOW, 10502 CAGE:0J879 CAGE:0J879 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHYLENE AMINE AND POLYETHYLENE AMINE EPOXY ADDUCT Fraction by Wt: 27 +/-2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHANOL, 2-PROPOXY-; (2-PROPOXYETHANOL). VP: 1.3 @ 225C. CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: 6% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACETIC ACID (SARA III). VP: 11.4 @ 225C. CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: <5% OSHA PEL:10 PPM ACGIH TLV:10 PPM;15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-, ACETATE; (2-(2-BUTOXYETHOXY) ETHYL ACETATE). VP: 0.04 @ 225C. CAS:124-17-4 RTECS #:KJ9275000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUNDS: 162-164 RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE HEADACHES, NAUSEA, DIZZINESS, AND RESPIRATORY IRRITATION. SKIN: MAY CAUSE REDDENING AND SWELLING. MAY BE A SENSITIZER. CAN CAUSE ALLERGIC SKIN REACTION. EYE: MAY CAUSE EYE INJURY . Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, ADMINISTER ARTIFICIAL RESPIRATION AND SEEK MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH WITH SOAP AND WATER. EYES: FLUSH WI TH LOW-PRESSURE WATER FOR AT LEAST 15 MINUTES (REMOVE CONTACT LENSES). CALL PHYSICIAN. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL, ABSORB WITH INERT MATERIAL AND COLLECT FOR DISPOSAL. FLUSH AREA WITH WATER. PREVENT WASHINGS FROM ENTERING WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTAMINATION OF SKIN. STORE ABOVE 40F. DO NOT FREEZE. Other Precautions:NONE KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR WHENEVER EXPOSURE TO VAPOR/MIST IS LIKELY. Ventilation:LOCAL EXHAUST IS RECOMMENDED. DO NOT USE IN AN ENCLOSED AREA. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FACILITY SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health PERCENT VOLATILES: 60 +/- 8. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F,>93C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.27 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS IN PRESENCE OF HEAT. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, AND POSSIBLY OTHER UNKNOWN MATERIALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT, MIL-C-85285B, CLEAR GLOSS PC 03X085CAT Kit Part:Y Preparer's Name:NORM GAUL CAGE:KO194 CAGE:KO194 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) (VAPOR PRESSURE 22 MM HG @ 68F) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 13.03% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC ISOCYANATE (HEXAMETHYLENE DIISOCYANATE [HDI] CAS: 822-06-0; FREE MONOMER <.5% @MFR. CAS:28182-81-2 RTECS #:HQ9170000 Fraction by Wt: 50% Other REC Limits:MOBAY:CEILING.02 PPM ACGIH TLV:TWA: 0.005 PPM Ingred Name:METHYL ISOBUTYL KETONE (SARA III) (VAPOR PRESSURE 15 MM HG @ 68F) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 37.12% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VOC: 474 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE; EYES, NOSE, THROAT IRRIT &ACUTE NERV SYS DEPRESSN. INHAL: HEADACHES, DIZZINESS, STAGGERING, DIFFICULT BREATHING, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: IRRIT (SWELLING, REDNESS, RASH). EYES: I RRIT (TEARING, REDNESS, SWELLING W/STINGING). INGEST: IRRIT, CORROSIVE TO GI TRACT. ASPIRATION (VOMIT)-CHEM PNEUMONITIS. Effects of Overexposure:CHRONIC; AS A RESULT OF PREVIOUS REPEATED OVEREXPOSURE OR A SINGLE LARGE DOSE, CERTAIN INDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE OF ISOCYANAT E LEVELS WELL BELOW THE TLV VALUE OF ISOCYANATES. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS. ISOCYANATE SENSITIZATION. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMED/DELAYED). GET MED AID. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH SOAP & WATER. WASH CONTAMINA TED CLOTHES BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER (LOW PRESSURE) 15 MIN, LIFTING EYELIDS. GET MED AID. INGEST: DONT INDUCE VOMITING. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:1.00 Upper Limits:8.00 Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:USE FULL PROTECT CLOTH/FIREFIGHT EQUIP W/SCBA. WATER MAY BE USED TO COOL CLSD CNTNRS (PREVENT PRESS BLDUP/AUTOIGNIT/EXPLOS). HDI/IRRIT VAPOR GENERATED BY FIRE. Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BUILDINGS IN COMPLIANCE WITH OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS/IGNITION SOURCE. STORE IN CLOSED CONTAINER IN WELL VENTILATED AREA. Other Precautions:KEEP CNTNR TIGHT/UPRIGHT (PREVENT LEAK). PREVENT PROLONGD VAPOR BREATHING. PROLONGD OVEREXPOSURE MAY CAUSE ALLERGIC REACTION. AVOID SKIN/EYE CONTACT. DONT INGEST.DONT HANDLE TILL MFR PRECAUTIONS READ/ UNDERSTOOD. SMOKE IN SMOKING AREAS ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRATOR RECOMMENDED FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED). OBSERVE OSHA RESPIRATOR REGULATIONS. VAPOR PARTIC RESPIRATOR (TC23C) MAY BE USED WHEN AIR MONITORING SHOWS VAPOR LEVELS BELOW 10X TLV/PEL. Ventilation:EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATION (HDI, POLYISOCYANATES, SOLVENT) BELOW TLVS. REMOVE IGNITION SOURCES. Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:230 TO 241F Vapor Density:> AIR Spec Gravity:0.94358 Evaporation Rate & Reference:1.39 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:57.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE ACTIVE MATERIALS. Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND HDI. Conditions to Avoid Polymerization:CONTACT WITH MOISTURE, MATERIALS WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED WITH CARE, DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR. DONT INCINERATE CLOSED CONTAI NER. EPA HZD WASTE #: D001, F003, F005,IGNITABLE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NASON PAINT PRODUCTS 419-64 Resp. Party Other MSDS Num.:28 CAGE:18873 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL ACETATE; VP: 8.0 MM HG @ 20C CAS:123-86-4 RTECS #:AF7350000 Other REC Limits:N/K OSHA PEL:710 MG/M3;150 PPM OSHA STEL:N/K ACGIH TLV:713 MG/M3;150 PPM ACGIH STEL:950 MG/M3;200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE; VP: 36.7 MM HG @ 20C CAS:108-88-3 RTECS #:XS5250000 = Wt:2. Other REC Limits:N/K OSHA PEL:SEE TABLE Z-2 OSHA STEL:N/K ACGIH TLV:188 MG/M3;50 PPM ACGIH STEL:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM&P NAPHTHA; VP: 15 MM HG @ 37.8CCAS# 64742-89-8 Other REC Limits:N/K OSHA PEL:300 PPM OSHA STEL:400 PPM ACGIH TLV:300 PPM ACGIH STEL:400 PPM Ingred Name:XYLENE; VP: 7.0 MM HG @ 25C CAS:1330-20-7 RTECS #:ZE2100000 = Wt:2. Other REC Limits:N/K OSHA PEL:100 PPM OSHA STEL:150 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM): (MEDIUM MINERAL SPIRITS); VP:10.0 MM HG @ 20C CAS:64742-88-7 Ingred Name:ALKYD RESIN-F; VP: NONE @ 20C CAS:66070-93-7 Ingred Name:ALKYD RESIN-G; VP: NONE @ 20C CAS:67783-08-8 Ingred Name:TITANIUM DIOXIDE; VP: NONE @ 20C CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:GEN EFTS: INGEST: GI DISTRESS. INHAL: MAY CAUSE NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLVS MAY LEAD TO PERM BRAIN & NERV SYS DMG. EYE WATERING, HDCH, NAUS, DIZZ & LOSS OF COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. ADDNL EFTS WHEN THIS MATL CONTAINS/IS MIXED W/ISOCYANATE ACTIVATOR/HARDENER: EXPOS TO ISOCYANATES MAY CAUSE RESP SENSIT. THIS EFT MAY BE PERM. THIS EFT MAY BE DELAYED FOR SEV ERAL HRS AFTER EXPOS. RPTD OVEREXP TO ISOCYANATES MAY CAUSE DECR IN LUNG FUNC WHICH MAY BE PERM. EYES: MAY CAUSE IRRIT/BURNING. SKIN: RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT W/DISCOMFORT & DERM. (EFTS OF OVEREXP) Effects of Overexposure:HEALTH HAZ: TOLUENE APPEARS ON THE NAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST. CONSULT APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE I NFORMATION . SPECIFIC EFFECTS: VM & P NAPHTHA/ MEDIUM MINERAL SPIRITS: LABORATORY STUDIES WITH RATS HAVE SHOWN THAT PETROLEUM DISTILLATES CAN CAUSE KIDNEY DAMAGE & KIDNEY OR LIVER TUMORS. THESE EFFECTS WERE NOT SEEN IN SIMILAR STUDIES WITH GUINEA PIGS, (TOXICOLOGICAL INFO) Medical Cond Aggravated by Exposure:INDIVIDUALS W/BRTHG PROBLEMS/PRIOR RXN TO ISOCYANATES MUST NOT BE EXPOSED TO VAPS/SPRAY MISTS OF THIS PROD. INDIVIDUALS W/PREEXISTING DISEASES OF CNS, LUNGS, LIVER/KIDNEYS MAY HAVE INCRD (SARA REGS) ======================= First Aid Measures ======================= First Aid:INGESTION: IN THE UNLIKELY EVENT OF INGESTION, CALL A PHYSICIAN IMMEDIATELY AND HAVE THE NAMES OF THE INGREDIENTS AVAILABLE. DO NOT INDUCE VOMITING. INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR S PRAY MIST, REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT A PHYSICIAN. EYES: IN CASE EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES; CALL A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION OCCURS, CONTACT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>-6.7C, 20.F 20F - 73F Lower Limits:0.7% Upper Limits:23.0% Extinguishing Media:UNIVERSAL AQUEOUS FILM-FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASH POINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED WITH AIR, CAN BURN OR BE EXPLOSIVE. FINE MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPERATURES BELOW THE FLASH POINT. ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. REMOVE IGNIT SOURCES. PVNT SKIN & PROT CLTHG. CONFINE & REMOVE W/INERT ABSORB. IF MATL CONTAINS/IS MIXED W/ISOCYANATE ACT IVATOR/HARDENER: WEAR POS-PRESS, SUPP-AIR RESP (NIOSH APPRVD TC-19C). POUR LIQ DECONTAM SOLN OVER SPILL & ALLOW TO SIT AT LEAST 10 MINS. TYPICAL DECONTAM SOLNS FOR ISOCYANATES-CONTAINING (FED REGS) ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPARKS AND FLAME. CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING. DO NOT STORE ABOVE 120F. OSHA STORAGE: IB. Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING WITHOUT A NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT BREATHE VAPS/MISTS. WHEN PRODS ARE USED W/PAINTS REQUIRING ISOCYANATE ACTIVATORS/HARDENERS, WEAR POS-PRESS, SUPP-AIR RESP (NIOSH APPRVD TC-19C) WHILE MIXING ACTIVATOR/HARDENER W/PAINT, DURING A PPLICATION & UNTIL ALL VAPS & SPRAY MISTS ARE EXHAUSTED. IF PROD IS USED W/OUT ISOCYANATE ACTIVATORS/HARDENERS, A PROPERLY FITTED AIR-PURIFYING (STATE REGS) Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . COVERALLS ARE RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR SMOKING. Supplemental Safety and Health PHYSICAL/CHEM PROPERTIES: GAL WT (#/GAL): 6.66-13.03; WT % VOLAT: 9.68%-100%; GAL WT:8.31; WT PCT SOLIDS:46.09; VOL PCT SOLIDS: 31.38; SOLV DENSITY:6.53; VOC LE: 4.5; VOC AP: 4.5. ================== Physical/Chemical Properties ================== Boiling Pt:>26.C, 78.8F B.P. Text:26C - 900C Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Evaporation Rate & Reference:LESS THAN ETHER Solubility in Water:MISCIBLE Percent Volatiles by Volume:12.5% - 100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES OF HEAVY METALS IN INGREDIENTS SECTION. =================== Toxicological Information=================== Toxicological Information:OVEREXPOSURE: DOGS OR MONKEYS. SEVERAL STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A SIGNIFICANT INCREASE OF KIDNEY DMG OR AN INCREASE IN KIDNEY OR LIVER TUMORS. TOLUENE: RECURRENT OVEREXP MA Y RESULT IN LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRODUCED IRREG HEARTBEATS IN ANIMALS & OCCASIONAL PALPITATIONS IN HUMANS. RATS EXPOSED TO VERY HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH FRE Q HEARING DEFICITS. SIGNIFICANCE OF THIS TO MAN IS UNKNOWN. CHROMOSOMAL CHANGES IN CIRCULATING BLOOD OF EXPOSED WORKERS HAVE BEEN REPORTED. SIGNIFICANCE OF THESE RPTS IS UNCLEAR BECAUSE OF EXPOS TO OT HER SUBSTANCES. (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:TOX INFO: XYLENE: RECURRENT OVEREXPOSURE MAY RESULT IN LIVER & KIDNEY INUURY. CAN BE ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. INDIVIDUALS W/PRE-EXISTING DISEASE OF THE CENTRAL NERVOUS SYSTEM, KIDNEY S, LIVER, CARDIOVASCULAR SYSTEM, LUNGS OR BONE MARROW MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. CANADA CLASSIFIES XYLENE AS A DEVELOPMENTAL TOXIN AS HIGH EXPOSURES TO X YLENES IN SOME ANIMAL STUDIES HAVE BEEN REPORTED TO CAUSE HEALTH EFFECTS ON THE DEVELOPING FETUS/EMBRYO. THESE EFFECTS WERE OFTEN AT LEVELS TOXIC TO THE ADULT ANIMAL. THE SIGNIFICANCE OF THESE EFFECTS TO HUMANS IS NOT KNOWN. (OTHER INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS. ===================== Regulatory Information ===================== SARA Title III Information:THE FOLLOWING CHEMICALS ARE SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF EMERGENCY PLANNING & RIGHT-TO-KNOW ACT OF 1986 & OF 40 CFR 372: TOLUENE & XYLENE. MEDICAL CONDITIONS: SUSCEPTIBILITY T O TOXICITY OF EXCESS EXPOSURE. INDIVIDUALS WITH PREEXISTING DISEASES OF KIDNEYS, LIVER, CARDIOVASCULAR SYSTEM BONE MARROW MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESS EXPOSURE. Federal Regulatory Information:SPILL PROC: MATERIALS ARE: 20% SURFACTANT (TERGITOL TMN 10) & 80% WATER OR 0-10% AMMONIA, 2-5% DETERGENT & WATER (BALANCE). PRESS CAN BE GENERATED. DO NOT SEAL CONTAINER. AFTER 48 HOURS, MATERIAL MAY BE SEALED & DISPOSED OF PROPERLY. IF MATERIAL DOES NOT CONTAIN/IS NOT MIXED WITH ISOCYANATE ACTIVATOR/HARDENER: WEAR PROPERLY FITTED AIR-PURIFYING RESP WITH ORGANIC VAPOR CARTRIDGES (NIOSH APPRVD TC- 23C). State Regulatory Information:WARNING: TOLUENE IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. RESP PROT: RESPIRATOR W/ORGANIC VAPOR CARTRIDGES (NIOSH TC-23C) & PARTICULATE FILTER (NIOSH TC-8 4A) MAY BE USED. FOLLOW RESP MFR'S DIRECTIONS FOR RESP USE. DO NOT PERMIT ANYONE W/OUT PROTECTION IN PAINTING AREA. REFER TO HARDENER/ACTIVATOR LABEL INSTRUCTIONS & MSDS FOR FURTHER INFORMATION. PERSO NS WITH HISTORY OF LUNG/BREATHING PROBLEMS/PRIOR REACTION TO ISOCYANATES SHOULD NOT USE/BE EXPOSED T O PRODUCT IF MIXED WITH ISOCYANATE ACTIVATORS/HARDENERS. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:S2002 CAGE:21076 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM AZIDE (SARA III) CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: >99% OSHA PEL:S, C 0.1 PPM(HN3) ACGIH TLV:C 0.11 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORL-RAT LD50 27 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE FATAL IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN. CHRONIC EFFECTS: MAY ALTER GENETIC MATERIAL. TARGET ORGANS: NERVES, HEART, AND BRAIN. Explanation of Carcinogenicity:THIS COMPOUND IS NOT LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:ACUTE EFFECTS:MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. EXPOSURE CAN CAUSE NAUSEA, HEADACHE AND VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. CALL A PHYSICIAN. SKIN: WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CALL A PHYSICIAN. EYE: IMMEDIATELY FLUSH EYES WITH PLEN TY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER TO DRINK. GIVE NOTHING BY MOUTH IF UNCONSCIOUS, CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:DO NOT USE WATER. DRY CHEMICAL POWDER. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. Unusual Fire/Explosion Hazard:CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA, WEAR SCBA, RUBBER BOOTS & HEAVY DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLE TE. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:WEAR APPROPRIATE NIOSH/MSHA-APPROVED PROTECTIVE CLOTHING. Other Precautions:USE ONLY IN A CHEMICAL FUME HOOD. SAFETY SHOWER AND EYE BATH. DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER HANDLING. HIGHL Y TOXIC. MUTAGEN. KEEP TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIODH/MSHA-APPROVED RESPIRATOR. Ventilation:LOCAL AND MECHANICAL (GENERAL) VENTILATION AS REQUIRED TO MAINTAIN VAPOR AND MIST CONCENTRATIONS BELOW PELS EST. BY OSHA Other Protective Equipment:EYE WASH STATION, RUBBER BOOTS, SUITABLE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:T3 Melt/Freeze Pt:M.P/F.P Text:527F,275C Spec Gravity:1.85 Evaporation Rate & Reference:N/R (BUTYL ACETATE=1) Solubility in Water:APPRECIABLE Appearance and Odor:COLORLESS HEXAGONAL CRYSTALS Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO METALS, ACIDS, AND ACID CHLORIDES. Stability Condition to Avoid:EXPLODES WHEN HEATED. Hazardous Decomposition Products:NITROGEN OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:PLEASE CONTACT THE TECHNICAL SERVICES DEPARTMENT. BE SURE TO MENTION THE NAME, CATALOG NUMBER AND THE QUANTITY OF THE MATERIAL. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SULFURIC ACID, A468-500 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 Minumum % Wt:95. Maxumum % Wt:98. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 2140 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CAUSES SEVERE EYE BURNS. MAY CAUSE IRREVERSIBLE EYE INJURY. SKIN: CAUSES SKIN BURNS. INGESTION: MAY CAUSE SEVERE AND PERMANENT DAMAGE TO THE DIGESTIVE TRACT. CAUSES GASTROINTESTINAL TRACT BURNS . INHALATION: HARMFUL IF INHALED, MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY TRACT WITH SORE THROAT, COUGHING, SHORTNESS OF BREATH AND DELAYED LUNG EDEMA. CAUSES CHEMICAL BURNS TO THE RESPIRATORY TRACT. CHRONIC: PROLONGED OR REPEATED INHALATION MAY CAUSE NOSEBLEED, NASAL CONGESTION, EROSION OF THE TEETH, PERFORATION OF THE NASAL SEPTUM, CHEST PAIN AND BRONCHITIS. PROLONGED OR REPEATED EYE CONT ACT MAY CAUSE CONJ. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF H*2O FOR AT LEAST 15 MIN, OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: GET MED AID IMMED. FLUSH SKIN W/PLENTY OF SOAP & H*2O FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. SPEEDY ACTION IS CRITICAL! INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/H*2O. NEVER GIVE ANY THING BY MOUTH TO UNCON PERS. GET MED AID IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BREATHING IS DIFFICULT, GIVE OXYGEN. DO NOT USE MOUTH- TO-MOUTH RESPIRATION. (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL. DO NOT GET WATER INSIDE CONTAINERS. COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIP . STRONG OXIDIZER. CONTACT W/COMBUSTIBLE MATLS MAY CAUSE A FIRE. CONTACT W/H*2O CAN CAUSE VIOLENT LIBERATION OF HEAT & SPLATTERING OF THE MATERIAL. CONT ACT W/ METALS MAY EVOLVE FLAMMABLE HYDROGEN GAS. CONTAINERS MAY EXPLODE WHEN HEATED OR IF CONTAMINATED W/H*2O. Unusual Fire/Explosion Hazard:HEALTH: 3; FLAMMABILITY: 0; REACTIVITY: 2. ================== Accidental Release Measures ================== Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN SECTION 8. SPILLS/LEAKS: CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. COVER WI TH SAND, DRY LIME OR SODA ASH AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. USE WATER SPRAY TO REDUCE VAPORS, DO NOT PUT WATER DIRECTLY ON LEAK, SPILL AREA OR INSIDE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLING: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO NOT INGEST OR INHALE. DO NOT ALLOW CONTACT WITH WATER. USE ONLY IN A CHEMICAL FUME HOOD. STORAGE: DO NOT STORE NEAR COMBUSTIBLE MATERIALS. Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. DO NOT STORE NEAR ALKALINE SUBSTANCES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 166 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health FIRST AID PROC: NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. PHYSICAL DATA: MOLECULAR FORUMLA: H2SO4. MOLECULAR WEIGHT: 98.0716. MATLS TO AVOID: AMMONIUM IRON (III) SULFATE DODECAHYDRATE, AMMONI UM TRIPERCHROMATE, ANILINE + GLYCEROL + NITROBENZENE, BENZYL ALCOHOL, BROMATES + METALS, TERT-BUTYL-M- (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:=290.C, 554.F Melt/Freeze Pt:=10.3C, 50.5F Vapor Pres:<0.00120 MM HG Vapor Density:1.2 KG/M3 Spec Gravity:1.841 pH:0.3 (IN SOLN) Viscosity:NEGLIBLE Evaporation Rate & Reference:SLOWER THAN ETHER. Solubility in Water:SOL IN WATER & ETHANOL Appearance and Odor:COLOURLESS LIQUID; ODORLESS. Percent Volatiles by Volume:NEGLIBLE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETIC ANHYDRIDE, ACETONE CYANHYDRIN, ACETONE + NITRIC ACID, ACETONE + POTASSIUM DICHROMATE, ACETONITRILE + SULFUR TRIOXIDE, ACROLEIN, ACRYLONITRILE, ALCOHOLS + HYDROGEN PEROXIDE, ALLYL ALCOHOL, ALLYL CHLORIDE, 2-AMINOETHAN Stability Condition to Avoid:INCOMPATIBLE MATERIALS, CONTACT WITH WATER, METALS, EXCESS HEAT, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, OXIDIZERS, AMINES, BASED. Hazardous Decomposition Products:OXIDES OF SULFUR. Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED. =================== Toxicological Information=================== Toxicological Information:RTECS#: CAS# 7664-93-9 WS5600000. LD50/LC50: CAS# 7664-93-9: INHALATION, MOUSE: LC50=320 MG/M3/2H; INHAL, RAT: LC5=510 MG/M3/2H. CARCINOGENICITY: SULFURIC ACID: ACGIH: ( CONTAINED IN STRONG INORGANIC ACID MISTS): A2 - SUSPECTED. OSHA: SELECT CARCINOGEN. IARC: GROUP 1 CARCINOGEN. WORKERS EXPOSED TO INDUSTRIAL SULFURIC ACID MIST SHOWED A STATISTICAL INCREASE IN LARYNGEAL CANCER. THIS DATA SUGGESTS A POSSIBLE RELATIONSHIP BETWEEN CARCINOGENISIS & INHALATION OF SULFURIC ACID MIST. TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY & OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: SULFURIC ACID IS HARMFUL TO AQUATIC LIFE IN VERY LOW CONCENTRATIONS. IT MAY BE DANGEROUS IF IT ENTERS H*2O INTAKES. THE AQUATIC TOX FOR BLUEGILL IN FRESH H*2O WAS 24.5 PPM/24 HR, WHICH WA S LETHAL. ENVIRONMENTAL FATE, PHYSICAL/CHEM & OTHER: NOT AVAIL CLEAN AIR ACT: THIS MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS , OZONE DEPLETORS. THIS MATL DOES NOT CONTAIN & CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: CAS# 7664-93-9 IS LISTED AS HAZ SUBSTANCE UNDER CWA. NONE OF CHEMS IN THIS PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN TH IS PRODUCT ARE LISTED AS TOX POLLUTANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS, RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS, RCRA F-SERIES, RCRA P-SERIES, RCRA U-SERIES. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA. =================== MSDS Transport Information =================== Transport Information:US DOT: SHIPPING NAME: SULFURIC ACID. HAZARD CLASS: 8, UN NUMBER: UN1830 PACKING GROUP: II. IMO, IATA & RID/ADR: NO INFORMATION AVAILABLE. CANADIAN TDG: SHIPPING NAME: SUFLURIC ACID. HAZARD CLASS: 8(9 .2). UN NUMBER: UN1830. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): CAS # 7664-93-9: FINAL RQ = 1000 POUNDS (454 KG). SECTION 302 (TPQ):CAS # 7664-93-9: TPQ 1000 POUNDS; RQ + 1000 POUNDS. SARA CODES: CAS # 7664-93-9: ACUTE, CHRONIC, REACTIVE. SECTIO N 313: THIS MATERIAL CONTAINS SULFURIC ACID (CAS# 7664-93-9, 95 98 0%), WHICH IS SUBJECT TO THE REPORTING REQUIREMTNTS OF SECTION 313 OF SARA TITILE III AND 40 CFR PART 373. Federal Regulatory Information:TSCA: CAS# 7664-93-9 IS LISTED ON THE TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES: NONE OF THE CHEMICLS ALS INTHIS PRODUCT ARE UNDER A CHEMICAL TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A SNUR CHE MICAL UNDER TSCA. State Regulatory Information:SULFURIC ACID CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMIC ALS IN THIS PRODUCT ARE LISTED. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:43803, WORKABLE FIXITIF SPRAY CAGE:12625 Contract Num:MDA414-99-A-0003-0328 CAGE:27028 Contract Num:MDA414-99-A-0003-0332 CAGE:27028 Contract Num:MDA414-00-T-1285 CAGE:4A560 CAGE:12625 Contract Num:MDA414-00-P-1783 CAGE:0RKV4 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 = Wt:65.5 OSHA PEL:2400 MG/M3;1000 PPM ACGIH TLV:1780 MG/M3;750 PPM ACGIH STEL:2380 MG/M3;1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TI4300000 = Wt:12.5 ACGIH TLV:800 PPM Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE CAS:108-65-6 RTECS #:AI8925000 = Wt:4.8 Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 = Wt:12.5 OSHA PEL:1800 MG/M3;1000 PPM ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE AND CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF CONSCIOUSNESS. Medical Cond Aggravated by Exposure:MAY CAUSE DEFATTING AND DRYING OF SKIN. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. SKIN: WASH WITH SOAP AND WATER. EYES: WASH WITH WATER. INGESTION: DO NOT INDUCE VOMITING, CALL A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:=-104.4C, -156.F Lower Limits:2.2 Upper Limits:8.9 Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:HANDLE AS FLAMMABLE LIQUID. Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCE OF HEAT OR IGNITION. VENTILATE AREA. APPLY ABSORBENT MATERIAL TO SPILL. ======================Handling and Storage ====================== Handling and Storage Precautions:EXTREMELY FLAMMABLE. STORE AND USE AWAY FROM ALL HEAT AND IGNITION SOURCES. Other Precautions:CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:USE LOCAL EXHAUST. USE MECHANICAL(GENERAL) IF REQUIRED. Other Protective Equipment:NONE. Work Hygienic Practices:AVOID BREATHING VAPOR AND EYE AND SKIN EXPOSURE. Supplemental Safety and Health PN FOR CONTRACT MDA414-00-P-1783, SAX ARTS AND CRAFTS: 317-2517, TRUE FLOW WORKABLE FIXATUVE. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:=-41.9C, -43.7F Melt/Freeze Pt:=-93.7C, -137.F Vapor Density:2.2(AIR=1) Evaporation Rate & Reference:4.86 (BUTYL ACETATE=1) Solubility in Water:SOLVENT MIX: APPRECIABLE Appearance and Odor:CLEAR COLOR, SOVVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, OR OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE MAY BE FORMED DURING COMBUSTION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SD AL POLY 17875 17925 WHITE 821X330 Kit Part:Y CAGE:85570 CAGE:85570 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TRIMETHYLOLPROPANE (VP: 1 MM HG) CAS:77-99-6 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED Ingred Name:DICARBOXYLIC ACID (VP: 1 MM HG) CAS:123-99-9 RTECS #:CM1980000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED Ingred Name:PHTHALIC ANHYDRIDE(SARA III) CAS:85-44-9 RTECS #:TI3150000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:2 PPM ACGIH TLV:1 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ISOBUTYL KETONE (SARA III) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/75 STEL ACGIH TLV:50 PPM/75 STEL; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CYCLOHEXANONE (SARA III) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 45% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOC: 482 GRAMS/LITER RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:INHALE:NASAL/RESPIRATORY IRRITATION,ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION-HEADACHE,DIZZINESS,STAGGERING GAIT, CONFUSION OR UNCONSCIOUSNESS.ASPHYXIATION. SKIN: PROLONG/REPEAT CONTACT CAUSES IRRITATIO N, DEFATTING OR DERMATITIS. EYE: IRRITATION. INGEST: MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA. Effects of Overexposure:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. POSSIBLE LIVER DAMAGE. ASPIRATION OF MATERIAL TO LUNGS CAN CAUSE CH EMICAL PNEUMONITIS WHICH CAN BE FATAL. Medical Cond Aggravated by Exposure:BIRTH DEFECTS HAVE BEEN OBSERVED IN TESTS ON LAB ANIMALS EXPOSED TO ETHYLENE GLYCOL BY MOUTH. O/EXPOSURE TO XYLENE HAS CAUSED LIVER, KIDNEY AND SPLEEN DAMAGE IN LAB AMIMALS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE PERSON TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF REQUIRED. IF BREATHING IS DIFFICULT, GIVE OXYGEN. KEEP WARM & QUIET. GET MEDICAL ATTN. SKIN: WASH AREAS WITH SOAP & WATER. DO NOT USE SOLVENTS. REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. GET MEDICAL ATTN. EYES: FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTN. PREFER AN OPTHALMOLOGIST. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:31.0F,-0.6C Lower Limits:1.1% Extinguishing Media:EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR FOAM). Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE, USE TO COOL EXPOSED CNTNRS (FOG NOZZLE PREFERRED). USE NIOSH/MSHA APPR'D SELF- CONTAINED BREATHING APPARATUS & PROTECT CLOTHES. Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN CONFINED AREAS, FORM EXPLOSIVE MIX W/AIR, TRAVEL LONG DISTANCES. FLASHBACK/FLAME TO HANDLING SITE MAY OCCUR. CLOSED CNTNRS MAY EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITE SOURCES. WEAR PERSONAL PROTECTIVE EQUIP. AVOID BREATHING VAPORS & SKIN OR EYE CONTACT. USE NON- SPARK TOOLS. USE EMERGENCY RESPONSE PRO IF MANAGING RELEASE IS BEYOND CAPABILITY OF IN-HOU SE PERSONS. SM:DIKE & ABSORB W/INERT MATERIAL. Neutralizing Agent:DEPEND ON QUANT & CIRCUM UNAURTHORIZED SPILLS REPORTED TO NAT'L RESPONSE CNTR. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED. ISOLATE FROM HEAT, ELEC EQUIPMENT, SPARKS. DO NOT STORE ABOVE 120F. STORE FLAMM LIQ IN ACCORD W/NFPA CODES/GOVERNMENT REGS. Other Precautions:USE GROUND/BOND PROCEDURES WHEN TRANSFERRING. AVOID FREE FALL OF LIQ. DO NOT SMOKE WHERE MATERIAL IS USED OR STORED.DO NOT APPLY TO HOT SURFACES.EMPTIES MAY CONTAIN EXPLOSIVE VAPORS.DO NOT CUT, PUNCTU RE, WELD ON DRUM.DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:TLV'S EXCEEDED/SPRAY MIST PRESENT: USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION APPROPRIATE FOR INDICATED COMPONENTS. CONFINED AREAS: NIOSH APPR'D AIR SUPPLIED RESPIRATORS. FOLLOW OSHA REGULATIONS ( 29CFR1910.134) FOR RESPIRATOR USE. Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN VOLUME/PATTERN TO KEEP LEVEL OF HAZARD INGREDIENT BELOW TLV/PEL LIMITS. Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER PROTECTIVE CLOTHING. A SAFETY SHOWER, EYE BATH & WASHING FACILITIES. Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID SKIN CONTACT & BREATHING VAPORS OR MIST. Supplemental Safety and Health DO NOT CONCENTRATE & INHALE VAPORS. PREVENT PROLONG CONTACT W/CONTAMINATED CLOTHES. VAPORS OF THIS PRODUCT ARE HEAVIER THAN AIR & MAY COLLECT IN LOW OR CONFINED AREAS. DO NOT ENTER SUCH AREAS W/ OUT F OLLOWING APPROPRIATE PROCEDURES INCLUDING AIR MONITORING, USE OF SUPPLIED AIR IF NECESSARY & AN OBSERVER FOR ASSISTANCE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:175 TO 552F Vapor Density:> AIR Evaporation Rate & Reference:SLOWER THAN N-BU AC Appearance and Odor:LIQUID, SOLVENT ODOR Percent Volatiles by Volume:41.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS INCLUDING CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:ENSURE MATERIAL IS PACKAGED, STORED, TRANSPORTED & OTHERWISE MANAGED IN ACCORD W/LOCAL,STATE & FED REGS. NO DISPOSAL METHOD IS TO BE USED THAT WOULD POSE ENVIR OR HUMAN HEALTH THREAT INCLUDING ANY WHI CH WOULD CONTAMINATE GROUND/SURFACE WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TW-25B HIGH TECH LUBRICANT CAGE:0BAN7 CAGE:0BAN7 ============= Composition/Information on Ingredients ============= Ingred Name:SYNTHETIC OILS (ORGANIC ESTERS) Other REC Limits:NONE RECOMMENDED Ingred Name:HIGHLY REFINED MINERAL OILS Other REC Limits:NONE RECOMMENDED ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:CALCIUM SULFONATE/CARBOXYLATE COMPLEX Other REC Limits:NONE RECOMMENDED ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:TRICRESYL PHOSPHATE CAS:1330-78-5 RTECS #:TD0175000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 (MSDS) ACGIH TLV:5 MG/M3 (MSDS) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED EXPOSURE TO SKIN & INHALATION. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:EYE OR SKIN IRRITATION. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:WASH SKIN WITH SOAP & WATER. WASH EYES WITH WATER FOR 15 MINUTES. SO NOT INDUCE VOMITING, DRINK WATER & SEE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:460F,238C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS. WATER MAY CAUSE FOAMING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & USE ABSORBENT TO CONTAIN SPILL. PLACE IN A CONTAINER. RECOVER OR INCINERATE. DO NOT ALLOW TO FLOW INTO SEWERS OR WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE CAUTION TO LIMIT EXPOSURE TO EYES & SKIN. DO NOT BREATH MIST. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:MIST. Ventilation:LOCAL EXHAUST & GENERAL (MECHANICAL) VENTILATION RECOMMENDED. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:WASH SKIN AFTER USE. WASH CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:640F,338C Melt/Freeze Pt:M.P/F.P Text:-85F,-65C Spec Gravity:1.1 Solubility in Water:SLIGHT Appearance and Odor:PALE YELLOW LIQUID; SWEET ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES. Stability Condition to Avoid:STRONG ACIDS, BASES, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5-510 (070992E), SPEEDCRAFT INT SG LATEX (SUPDAT) CAGE:47695 CAGE:47695 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 20-25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CLAY (KAOLIN); (CLAY) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 1-2% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 1-2% OSHA PEL:N/K ACGIH TLV:50 PPM, VAPOR, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:WATER; (TAP WATER) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 35-40% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER; (DEIONIZED WATER) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 20-25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FILM FORMERS, RESINS & ADDITIVES Fraction by Wt: 15-20% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: ARE NOT EXPECTED, THERE IS NO SIGNIFICANT HAZ FOR MAN. PROD CNTNS ETHYLENE GLYCOL WHICH MAY CAUSE KIDNEY (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: & LIVER DMG & WHICH HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN LAB ANIMALS. NO EVID OF THESE EFTS FOUND IN HUMANS. RTECS #:9999999ZZ Ingred Name:VENT: THE LEL BELOW THE STATED LIMIT AND TO REMOVE DECOMPOSITION PRODUCTS DURING WELDING OR FLAME CUTTING. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGEST: HARMFUL/FATAL IF SWALLOWED. EYES: CAUSES IRRIT. REDNESS, ITCH, BURNING SENSATION & VISUAL DISTURBS MAY INDICATE EXCESSIVE EYE CNTCT. SKIN: MAY CAUSE SLIGHT IRRIT. DRYNESS, ITCH, CRACKING, BURN ING, REDNESS & SWELL ARE CNDTNS ASSOC W/EXCESSIVE SKIN CNTCT. INHAL: VAP & SPRAY MIST MAY BE HARMFUL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IF INHALED. VAP GENERATED AT ELEVATED TEMPS IRRIT EYES, NOSE & THROAT. CHRONIC:AVOID LONG TERM & RPTD CNTCT. PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE QTYS OF TITANIUM DIOIXDE DUS T IN LONG TERM STUDY DEVELOPED LUNG TUMORS. STUDIES W/HUMANS INVOLVED IN MFR OF THIS PIGMENT INDICATE NO INCR (SUPDAT) Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMIT. EYES: FLUSH IMMED W/PLENTY OF WATER FOR AT LEAST 15 MIN. SKIN: FLUSH IMMED W/PLENTY OF WATER FOLLOWED BY WASHING W/SOAP & WATER. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RES P & OTHER SUPPORTIVE MEASURES AS REQD. OTHER: IF INGEST, ANY TYPE OF OVEREXP OR SYMPS OF OVEREXP OCCUR DURING/FOLLOWING USE OF PROD, CNTCT POIS CTL CTR, EMER ROOM OR MD IMMED; HAVE MSDS INFO AVAIL. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Extinguishing Media:USE NFPA CLASS B EXTINGS (CARBON DIOXIDE, DRY CHEM OR UNIVERSAL AQ FILM FORMING FOAM) TO EXTING CLASS IIIB (SUPDAT) Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & (SUPDAT) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST (DUE TO THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE MAX VENT. ONLY PERSONNEL EQUIPPED W/PROPER NIOSH/MSHA APPRVD RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAWDUST, VERMICULITE/OTHER ABSORB MATL & PLACE INTO CNTNR FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LG QTYS IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS IIIB COMBUSTIBLE LIQUIDS. PROTECT FROM FREEZING. Other Precautions:IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT SYSTEM, READ THE MSDS FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE VENTILATION IS INADEQUATE, USE A SUITABLE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP CONC OF INGREDS BELOW LOWEST SUGGESTED EXPOS LIMS, (ING 9) Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER WEAR PROT CLTHG INCL IMPERMEABLE APRON.CLEAN/DISCARD CONTAMD CLTHG & SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: WHITE/PASTEL. EXTING MEDIA: COMBUST LIQ FIRES. FIRE FIGHT PROC: POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. IF WATER IS USED, FOG NOZZS ARE PREF. EFTS OF OVEREXP: RISK O F CANCER FROM EXOS. POTNTL FOR INHAL OFTITANIUM DIOXIDE DUSTS FROM COATINGS IS VERY LIMITED. SINCE OVEREXPS (ING 7) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:17.2 Vapor Density:HVR/AIR Spec Gravity:1.24 Evaporation Rate & Reference:34 (BUOAC=100) Solubility in Water:59.9 Appearance and Odor:VISCOUS LIQUID W/ODOR CHARACT OF CHEMICAL FAMILY & ANY SOLVS LISTED IN INGREDS. Percent Volatiles by Volume:73.30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS OR STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY PRDCE HAZ DECOMP PROD WHEN HEATED. WELDING/BRAZING/FLAME-CUTTING MAY PRDCE FUMES INCL:CARBON MONOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, PROVINCIAL & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KOROTHERM 910X407 Preparer's Name:JRW CAGE:83574 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:POLYMETHYLENEPOLYPHENYL ISOCYANATE; (POLYMETHYLENEPOLYPHENYLENE POLYISOCYANATE) (CONTAINING ING 2) CAS:9016-87-9 RTECS #:TR0350000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'-DIPHENYL METHANE DIISOCYANATE (MDI) MONOMER) CAS:101-68-8 RTECS #:NQ9350000 OSHA PEL:C 0.02 PPM ACGIH TLV:0.005 PPM; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES:IRRITATION, WATERING AND POSSIBLE REVERSIBLE CORNEAL DAMAGE. SKIN:LOCAL IRRITATION AND DISCOLORATION. MAY CAUSE ALLERGIC SKIN RASH IN SENSITIZED INDIVIDUALS. INHAL:DUE TO LOW VOLATILITY, S IGNIFICANT EXPOSURE TO VAPORS IS NOT EXPECTED UNLESS OVERHEATED. EXCESSIVE INHALATION CAN PRODUCE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:IRRITATION OF THE NOSE, THROAT AND RESPIRATORY TRACT. EXCESSIVE AND EXTENSIVE EXPOSURE CAN PRODUCE REVERSIBLE SYMPTOMS OF BRONCHITIS. SENSITIZED INDIVIDUALS MAY DEVELOP ASTHMA-LIKE SYMPTOMS A T LOW EXPOSURE. INGEST:IRRITATION AND POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LUKE-WARM WATER FOR AT LEAST 15 MINUTES, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN. INHALATION: MOVE TO FRESH AIR. IF RESPIRATOR Y SYMPTOMS ARE PRESENT, CONSULT A PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. GIVE MILK OR WATER TO DRINK. CONSULT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:DRY CHEMICAL, CO*2, FOAM, WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO COOL HEAT-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE BUILD-UP IN CLOSED CONTAINERS. ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH ABSORBENT MATERIAL, ADD DECONTAMINATION SOLUTION AND ALLOW TO REACT FOR 10 MINUTES. COLLECT IN CONTAINERS, ADD ADDITIONAL DECONTAMINATION SOLUTION AND KEEP LOOSELY COVERED FOR 48 HOURS. Neutralizing Agent:DECONTAMINATION SOLUTION: 5% CONCENTRATED AMMONIA, 2% DETERGENT AND 93% H*2O. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MOISTURE CONTAMINATION WHICH MAY PRODUCE CO*2 PRESSURE. DO NOT RESEAL CONTAINER IF MOISTURE CONTAMINATION IS SUSPECTED. Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Vapor Pres:<10(-5) Spec Gravity:1.24 Solubility in Water:NEGLIGIBLE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, STRONG BASES AND ALCOHOLS, AMINES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN; POSSIBLE TRACES OF HCN. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A HAZARDOUS WASTE ACCORDING TO EPA REGULATIONS. CONSULT FEDERAL, STATE & LOCAL REGULATIONS PRIOR TO DISPOSAL OF SPILLAGE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7746 830 SUNFLOWER YELLOW CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 = Wt:20. OSHA PEL:200 PPM OSHA STEL:300 PPM ACGIH TLV:188 MG/M3;50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 = Wt:20. OSHA PEL:1800 MG/M3;1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 = Wt:15. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:AROMATIC SOLVENT CAS:64742-95-6 RTECS #:WF3400000 = Wt:10. Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 = Wt:10. OSHA PEL:100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:651 MG/M3;150 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 = Wt:5. ACGIH TLV:1900 MG/M3;800 PPM Ingred Name:ISOBUTANE CAS:75-28-5 RTECS #:TI4300000 = Wt:5. Ingred Name:1,2,4-TRIMETHYLBENZENE CAS:95-63-6 RTECS #:DC3325000 = Wt:5. ACGIH TLV:25 PPM Ingred Name:1,3,5-TRIMETHYLBENZENE CAS:108-67-8 RTECS #:OX6825000 = Wt:5. ACGIH TLV:25 PPM Ingred Name:DIPROPYLENE GLYCOL CAS:110-98-5 RTECS #:UB8785000 = Wt:5. Ingred Name:ETHYLBENZENE CAS:100-41-4 RTECS #:DA0700000 = Wt:5. OSHA PEL:435 MG/M3;100 PPM ACGIH TLV:434 MG/M3;100 PPM ACGIH STEL:543 MG/M3;125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ORGANIC YELLOW PIGMENT CAS:492-80-8 RTECS #:BY3500000 = Wt:1. EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:COBALT DRIER CAS:136-52-7 = Wt:.1 Ingred Name:ALKYD RESIN SOLUTION CAS:66070-60-8 > Wt:3. Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 > Wt:3. OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 5000 MG/KG TOLUENE Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INHALED/SWALLOWED. EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: MAY BE IRRITATING TO THE EYES, NOSE, THROAT & LUNGS. INGESTION: ASPIRATION HAZARD. CAN ENTER LUNGS & CAUSE DAMAGE. CNS DISORD ER/DAMAGE. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. MAY EFFECT THE LIVER & CAUSE CARDIAC ABNORMALITIES. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, LOSS OF COORDINATION, WEAKNESS, FATIGUE, MENTAL CONFUSION, BLURRED VISION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING/GIVE ANYTHING BY MOUTH. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:<-6.7C, 20.F Lower Limits:0.9 Upper Limits:12.6 Extinguishing Media:DRY CHEMCIAL, FOAM, WATER FOG Fire Fighting Procedures:EVACUATE AREA & FIGHT FIRE FROM A SAFE DISTANCE. WATER SPRAY MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES W/AIR. CAN TRAVEL TO AN IGNITION SOURCE & FLASHBACK. ISOLATE FROM HEAT/ELECTRICAL EQUIPMENT/SPARKS/OPEN FLAME. PERFORATION OF PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA, REMOVE ALL SOURCES OF IGNITION & VENTILATE. CONTAIN LIQUID W/SAND/EARTH. DON'T USE COMBUSTIBLE MATERIALS SUCH AS SAWDUST. REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM IGNITION SOURCES. DON'T STORE >120F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS I FLAMMABLE LIQUIDS. Other Precautions:USE ONLY IN WELL VENTILATED AREA. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED. IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING VAPOR/MIST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/AN ORGANIC VAPOR CARTRIDGE/CANISTER WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS. USE A POSITIVE AIR SUPPLIED RESPIRATOR IF THERE IS POTENTIAL FOR AN UNCONTROLLED RELEASE/IF EXPOSURE LEVELS ARE UNKNOWN/WHERE AIR PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST/OTHER ENGINEERING TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.USE EXPLOSION PROOF EQUIPMENT. Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. WASH THOROUGHLY W/SOAP & WATER BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-47.2F TO -724F Vapor Density:>1 Spec Gravity:1.0860 Evaporation Rate & Reference:FASTER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID W/SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG ALKALIES Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME, TEMPERATURES >120F & ALL OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:BY OPEN FLAME: CO, CO2 ===================== Ecological Information ===================== Ecological:PRODUCT IS A MIXTURE OF LISTED COMPONENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS. DO NOT ALLOW TO ENTER STORM DRAINS/SEWER SYSTEMS. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA HAZARD CATAGORIES' PROMULGATED UNDER SECTIONS 311 & 312 OF THE SUPERFUND AMENDMENT & REAUTHORIZATION ACT OF 1986 SARA TITLE III IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD, PRESSURIZED GAS HAZARD. Federal Regulatory Information:SARA SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR PA RT 372. TOLUENE, XYLENE, 1,2,4-TRIMETHYLBENZENE, ETHYLBENZENE, ORGANIC YELLOW PIGMENT. State Regulatory Information:NEW JERSEY RIGHT-TO-KNOW : THE FOLLOWING MATERIALS ARE NON-HAZARDOUS, BUT ARE AMONG THE TOP FIVE COMPONENTS IN THIS PRODUCT: ALKYD RESIN SOLUTION. PENNSYLVANIA RIGHT-TO-KNOW: THE FOLLOWING NON-HAZARDO US INGREDIENTS ARE PRESENT IN THE PRODUCT AT GREATER THAN 3%: ALKYD RESIN SOLUTION, BARIUM SULFATE. CALIFORNIA PROPOSITION 65: WARNING: THE CHEMICALS NOTED BELOW & CONTAINED IN THIS PRODUCT ARE KNOW T O THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/OTHER REPRODUCTIVE HARM: TOLUENE. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEFOAMER CAGE:RITEK CAGE:RITEK ============= Composition/Information on Ingredients ============= Ingred Name:NONE PER 29 CFR 1910.1200 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: MILD TO MODERATE IRRITANT. INGESTION: NONE KNOWN. INHALATION: NONE KNOWN. Effects of Overexposure:SKIN & EYES IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MIN. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN: WASH WITH WATER. INHALATION: NONE. INGESTION: IF SWALLOWED, DRINK A LARGE AMOUNTS OF WATER, CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:MEDIA APPROPRIATE TO BASE CAUSE OF FIRE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB RESIDUE WITH SOLID ABSORBENT. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM FREEZING. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO NEED Ventilation:NOT NEEDED Other Protective Equipment:NOT NEEDED Work Hygienic Practices:NOT NEEDED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Pres:18 MM HG Vapor Density:SAME WATER Spec Gravity:0.990 (WATER=1) Evaporation Rate & Reference:1 (BU AC=1) Solubility in Water:EMULSIFIABLE Appearance and Odor:GREEN, OPAQUE, THIN LIQUID: NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:TX-750 CAGE:62530 CAGE:62530 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROQUINONE; 1,4-DIHYDROXYBENZENE; 1,4-BENZENEDIOL CAS:123-31-9 RTECS #:MX3500000 Fraction by Wt: 0-1% OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYL-2-CYANOACRYLATE *95-4* CAS:7085-85-0 Fraction by Wt: 60-100% Ingred Name:POLYMETHYLMETHACRYLATE, PLEXIGLAS (IARC CANCER REVIEW-GROUP 2B) *95-4* CAS:9011-14-7 RTECS #:TR0400000 Fraction by Wt: 10-30% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(MOUSE): 12.22 CC/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE DERMATITIS IN SENSITIVE INDIVIDUALS. INHALATION: IRRITATION OF MUCOUS MEMBRANES. PROLONGED/REPEATED EXPOSURE MAY PRODUCE ALLERGIC REACTIONS W/ASTHMA-LIKE SYMPTOMS IN SENSITIVE INDIVIDUALS. Explanation of Carcinogenicity:NONE Effects of Overexposure:TEARING, IRRITATION, COUGHING, WEEPING OF EYES, DOUBLE VISION, LIPS MAY BECOME STUCK TOGETHER. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE & RESPIRATORY DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: MOVE TO FRESH AIR. FLUSH W/WATER. ADHESIVE WILL DISASSOCIATE OVER TIME, USUALLY W/IN SEVERAL HOURS. SKIN: IMMERSE IN WARM WATER, SOAPY WATER. PEEL/ROLL APART. INHALATION: REMOVE TO FRESH AIR. IN GESTION: APPLY COPIOUS AMOUNTS OF WARM WATER & ENCOURAGE WETTING/PRESSURE FROM SALIVA INSIDE MOUTH. PEEL/ROLL (DON'T PULL) LIPS APART. (SEE SUPPLEMENTAL DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:176F Extinguishing Media:WATER/DRY CHEMICAL EXTINGUISHER Fire Fighting Procedures:FUMES MAY BE IRRITATING IF NOT BURNING & WATER/DRY CHEMICAL EXTINGUISHER. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:POLYMERIZE W/WATER. SOLID MATERIAL MAY BE SCRAPED FROM SURFACE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MOISTURE, DIRECT UV-SUNLIGHT & DON'T STORE >25C. KEEP CONTAINERS CLOSED TIGHTLY WHEN NOT IN USE. STORE IN COOL, DRY PLACE. IDEAL STORAGE: 5-10C. Other Precautions:AVOID BREATHING VAPOR, CONTACT W/SKIN/EYES. DON'T STORE AT -5C WHICH FREEZES PRODUCT TO USELESS STATE. PRODUCT NOT DAMAGED BY FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH-APPROVED ORGANIC VAPOR CANISTER MAY BE USED TO MAINTAIN PROPER VAPOR CONCENTRATION BELOW TLV. Ventilation:LOCAL EXHAUST: TO MAINTAIN VAPOR CONCENTRATION BELOW TLV. MECHANICAL (GENERAL): LARGE AMOUNTS USED TO 2PPM. Other Protective Equipment:RUBBER APRON Supplemental Safety and Health FIRST AID CONT'D: IT'S ALMOST IMPOSSIBLE TO SWALLOW CYANOACRYLATE AS ADHESIVE SOLIDIFIES UPON CONTACT W/SALIVA & MAY ADHERE TO INSIDE OF MOUTH. SALIVA WILL LIFT ADHESIVE IN 1-2 DAYS, AVOID SWALLOWING ADHESIVE AFTER DETACHMENT. OBTAIN MEDICAL ATTENTION IN ALL CASES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:149F Vapor Pres:1 Spec Gravity:1.05 Solubility in Water:INSOLUBLE Appearance and Odor:TRANSPARENT WATER-WHITE TO STRAW COLORED LIQUID W/STIMULATIVE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ALCOHOL, AMINES, ALKALINE MATERIALS. Stability Condition to Avoid:TEMP >122F, MOISTURE & DIRECT UV-SUNLIGHT. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE SOLID COMBUSTIBLE WASTE/DUMP AS CHEMICAL WASTE IAW/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ANTIFOGGING COMPOUND D-A-549 CAGE:60182 CAGE:60182 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== Effects of Overexposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:IN CASE OF SKIN CONTCT FLUSH AFFECTED AREA WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:112F TCC 44C Extinguishing Media:WATR,ALCOHOL, FOAM,DRY CHEMICAL, CARBON DIOXIDE Fire Fighting Procedures:NORMAL PROCEDURES Unusual Fire/Explosion Hazard:NORMAL PROCEDURES ================== Accidental Release Measures ================== Spill Release Procedures:WASH W/PLAIN WATER.USUAL WASTE DRAIN - MATERIAL IS BIODEGRADABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE ABOVE 20F, & BELOW 200F. Other Precautions:KEEP AWAY FROM OPEN FLAMES. ============= Exposure Controls/Personal Protection ============= Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:183F 85C Spec Gravity:1.0359 Solubility in Water:COMPLETE Appearance and Odor:WATER CLEAR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Conditions to Avoid Polymerization:TEMPERATURES ABOVE 200F.
0
eyes_protection_not_mandatory
======================================================= Product ID: R74-2003-850, EP-P TONER CARTRIDGE BLACK (SUP DAT) Cage: 1BA63 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 08YZ7 Cage: 1BA63 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:INHAL/SKIN:EXPECTED TO BE LOW HAZ FOR REC HNDLG. EYES:MAY CAUSE TRANSIENT IRRIT. INGEST:EXPECTED TO BE LOW INGEST HAZ. CHRONIC:BASED UPON AVAIL DATA, HUMAN EXPOS TO TONER HAS BEEN SHOWN TO CAUSE MIN RESP TRACT IRRIT AS MAY OCCUR W/LGE AMTS OF ANY NON-TOX DUSTS. RSLTS OF ONE ANIMAL STUDY WHERE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ:RATS INHALED TONER THAT WAS 10 TIMES MORE RESPIRABLE THAN COMMERCIALLY AVAIL TONER WERE OBSERVED TO HAVE NO LUNG CHANGES AT LOW EXPOS (MOST RELEVANT LEVEL TO POTENTIAL HUMAN EXPOS). AT HIGHER LEVELS A SLIGHT DEGREE OF LUNG FIBROSIS WAS OBSERVED DUE TO EXCESS AMTS OF DUST RETAINED IN LUNGS FOR PRLNG INTERVAL. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACT THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. G ET MEDICAL ATTENTION IF SYMPTOMS OCCUR.SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK 1-2 GLASSES OF WATER. GET MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: NO TONER SPILLAGE OCCURS IN NORMAL OPERATION OR HANDLING. IF IT SHOULD OCCUR, AVOID INHALATION OF THE DUST. SWEEP MATERIAL ONTO PAPER AND DISPOSE COLLECTED TONER AS PLASTIC WASTE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: INCINERATE/LANDFILL. CAN BE INCINERATED WHEN IN COMPLIANCE W/LOCAL REGULATIONS. DISCHARGE, TREATMENT/DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE/LOCAL LAWS. EXHAUSTED CARTRIDGE MAY BE CONSIDERED PLASTIC WASTE. RECYCLING OF CARTRIDGE IS RECOMMENDED. Handling And Storage Precautions: USE WITH ADEQUATE VENTILATION. AVOID BREATHING DUST. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. MINIMIZE DUST GENERATION AND ACCUMULATION. Other Precautions: REFER TO PAMPHLET #654, "PREVENTION OF FIRE AND DUST EXPLOSIONS IN THE CHEMICAL, DYE, PHARMACEUTICAL AND PLASTICS INDUSTRIES". KEEP CONTAINER CLOSED. STORE IN COOL, VENTILATED AREA. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). NON-FLAMMABLE SOLID. Unusual Fire/Explosion Hazard: TONER MATERIAL, LIKE MOST ORGANIC MATERIAL IN POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE SHOULD BE NEEDED. USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES PERS HOUR) SHOULD BE USED. VENT RATES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: WASH THORO AFTER HNDLG. GOOD INDUS HYGIENIC PRACTICES SHOULD BE FOLLOWED WHICH INCL PREVENTING EYE CONT, (SUP DAT) Supplemental Safety and Health: TRADE NAME/PART #: FOR LBP-430/430W. HYGIENE PRACT: MINIMIZING SKIN CONT & INHALATION. ======================================================= Physical/Chemical Properties ======================================================= M.P/F.P Text: >212F,>100C Spec Gravity: 1.5-1.8(H*2O=1) Evaporation Rate & Reference: NEGLIGIBLE Solubility in Water: NEGLIGIBLE Appearance and Odor: BLACK FINE SOLID POWDER; SLIGHT PLASTIC ODOR ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: COMBUSTION WILL PRODUCE CARBON DIOXIDE AND CARBON MONOXIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: R74-2003-850, EP-P TONER CARTRIDGE BLACK (SUP DAT) Cage: 1BA63 Company Name: CANON USA INC Street: ONE CANON PLAZA Zipcode: 11042 Label Required IND: Y Date Of Label Review: 11/19/1997 Status Code: C Label Date: 11/19/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: DUST EXPLOSION HAZARD. ACUTE: INHALATION/SKIN/INGESTION: LOW HAZARD. EYES: MAY CAUSE TRANSIENT IRRITATION. CHRONIC: POSSIBLE LUNG FIBROSIS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Preparer's Name:DOD HMIS/DGSC-SSH CAGE:JO772 CAGE:14153 CAGE:JO772 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9192 Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL COMPOSITION RTECS #:9999999ZZ Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR" RTECS #:9999999ZZ ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN; CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING, FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA. SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG CANCER RISK! Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA. Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION FROM AIRBORNE DUST; INGEST: N/K. Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO REPEATED INHALATION OF AIRBORNE FIBERS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN: WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING DUST PARTICLES INTO OTHER AREAS ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/ AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO THE ATMOSPHERE. ======================Handling and Storage ====================== Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!! Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS & DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME AIRBORNE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK AT HAND. Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS. Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS. USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST CREATION Supplemental Safety and Health GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE REMOVED. ================== Physical/Chemical Properties ================== HCC:T6 Evaporation Rate & Reference:NONE Solubility in Water:NOT SOLUBLE Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS: "ITEM-NAME" Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACETONITRILE, 9255 Resp. Party Other MSDS Num.:A0518-08 CAGE:70829 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONITRILE CAS:75-05-8 RTECS #:AL7700000 Minumum % Wt:90. Maxumum % Wt:100. Other REC Limits:N/K OSHA PEL:70 MG/M3;40 PPM OSHA STEL:N/K ACGIH TLV:67 MG/M3;40 PPM ACGIH STEL:101 MG/M3;60 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 3800 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEVERAL HOURS MAY PASS BETWEEN EXPOSURE AND THE FIRST SIGNS OF SYMPTOMS DUE TO SLOW RELEASE OF CYANIDE. REPRODUTIVE EFFECTS: IN TESTS WITH LABORATORY ANIMALS, EXPOSURE TO THIS CHEMICAL HAS CAUSED EMB RYONIC DEATH, FETAL DEATH, FETAL MALFORMATIONS, AND DAMAGE TO MALE REPRODUCTIVE ORGANS. EFFECTS OF OVEREXPOSURE: INHALATION: HEADACHE, NAUSEA, VOMITING, DIZZINESS, RAPID INEFFECTIVE BREATHING, LOW BL OOD PRESSURE, WEAKNESS, CONVULSIONS, CYANOSIS, UNCONSCIOUSNESS, PULMONARY EDEMA, AND MAY BE FATAL. SKIN/EYE CONTACT: IRRITATION. SKIN ABSORPTION: MAY BE HARMFUL. (EFFECTS OF OVEREXPOSURE) Effects of Overexposure:HEALTH HAZARDS: INGESTION: CYANOSIS, UNCONSCIOUSNESS, HEADACHE, NAUSEA, VOMITING, DIZZINESS, WEAKNESS, RAPID INEFFECTIVE BREATHING, LOW BLOOD PRESSURE, GASTROINTESTINAL IRRITATION, CONVULSIONS, AND MA Y BE FATAL. CHRONIC: CENTRAL NERVOUS SYSTEM DAMAGE, BLURRED VISION, LIVER DAMAGE, KIDNEY DAMAGE, ANEMIA, IRRITATION OF RESPIRATORY SYSTEM. TARGET ORGANS: EYES, SKIN, LIVER, KIDNEYS, BLOOD, CARDIOVAS CULAR SYSTEM, CENTRAL NERVOUS SYSTEM, LUNGS. Medical Cond Aggravated by Exposure:CENTRAL NERVOUS SYSTEM DISORDERS, KIDNEY, LIVER, OR BLOOD DISORDERS, RESPIRATORY SYSTEM DISEASE, SKIN DISORDERS, THYROID DISORDERS. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD. KEEP CYANIDE ANTIDOTE KIT ON HAND AT ALL TIMES! IF SWALLOWED, IF UNCON, BREAK AMYL NITRITE PEARL IN CLOTH & HOLD LIGHTLY UNDER NOSE FOR 15 SECS. GIVE OXYGEN.WHEN CONSCIOUSNESS RE TURNS, INDUCE VOMIT. INHAL: BREAK AMYL NITRITE PEARL IN CLOTH & HOLD LIGHTLY UNDER NOSE FOR 15 SECS. REPEAT 5 TIMES AT ABOUT 15 SEC INTERVALS. IF NOT BRTHG, GIVE ARTF RESP. GIVE OXYGEN. SKIN: IMM ED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS.(SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=5.6C, 42.F Autoignition Temp:=523.9C, 975.F Lower Limits:4.4% Upper Limits:16.0% Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.) Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFACES TO DISTANT IGNIT SOURCES & FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT W/STRONG OXIDIZERS MAY CAUSE FIRE. TOXIC GASES PRODUCED: HYDROGEN CYANIDE, OXIDES OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE. NOT SENSITIVE TO MECH IMPACT. SENSITIVE TO STATIC DISCHARGE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING/FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE U P WITH SAND/OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER. DO NOT ALLOW SPILL TO ENTER DRAINS, SEWER SYSTEM, OR NATURAL WATER SUPPLIES. Neutralizing Agent:J. T. BAKER SOLUSORB(R) SOLVENT ABSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT. ======================Handling and Storage ====================== Handling and Storage Precautions:SAF-T-DATA STORAGE COLOR CODE: RED (FLAMMABLE). KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. DO NOT STORE IN DIRECT SUNLIGHT. ISOLATE FROM I NCOMPATIBLE MATERIALS. Other Precautions:BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 1000 PPM, A NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE ISRECOMMENDED. ABOVE THIS LEVEL, A NIOSH APPROVED SCBA IS RECOMMENDED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . UNIFORM AND PROTECTIVE SUIT ARE RECOMMENDED. Supplemental Safety and Health FIRST AID PROC: NOTES TO MD: IF PATIENT IS CONSCIOUS & ALERT, OXYGEN MAY BE ALL THAT IS NEEDED.IF PATIENT HAS NOT RESPONDED TO AMYL NITRITE, INJECT INTRAVENOUSLY 10ML OF 3% SOLN OF SODIUM NITRATE AT RATE NOT GREATER THAN 2.5-5ML PER MIN. FOLLOW DIRECTLY W/50ML OF 25% SOLN OF SODIUM THIOSULFATE AT SAME (OTHER INFO) ================== Physical/Chemical Properties ================== Boiling Pt:=81.7C, 179.F B.P. Text:@ 760 MM HG Melt/Freeze Pt:=-45.6C, -50.F M.P/F.P Text:@ 760 MM HG Vapor Pres:72.8 MM HG @ 20C Vapor Density:1.41 AIR=1 Spec Gravity:0.79 (H*2O=1) Evaporation Rate & Reference:5.79 (BUTYL ACETATE=1) Solubility in Water:COMPLETE (100%) Appearance and Odor:COLORLESS LIQUID WITH ETHER-LIKE ODOR. Percent Volatiles by Volume:100 @ 21C ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZING AGENTS, STRONG BASES. Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION, SUNLIGHT. Hazardous Decomposition Products:HYDROGEN CYANIDE, OXIDES OF NITROGEN, CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:HEAT, FLAME, OTHER SOURCES OF IGNITION, SUNLIGHT. =================== Toxicological Information=================== Toxicological Information:FOR ACETONITRILE: INTRAPERITONEAL RAT LD50: 3800 MG/KG; SKIN RABBIT LD50: 1250 MG/KG;INHALATION-1HR MOUSE LC50: 2693 PPM. ===================== Ecological Information ===================== Ecological:AQUATIC TOXICITY: FATHEAD MINNOW 96HR-LC50 = 1000 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U003 (TOXIC WASTE). =================== MSDS Transport Information =================== Transport Information:DOMESTIC (D.O.T.): PROPER SHIPPING NAME: ACETONITRILE; HAZ CLASS: 3; UN/NA: UN1648; RQ: 5000 LBS; PACKAGING GROUP: II; LABELS: 3 FLAM LIQ; REG REFERENCES: 49CFR 172.101. INTERNATIONAL (I.M.O.): PROPE R SHIPPING NAME: ACETONITRILE; HAZ CLASS: 3.2; I.M.O. PAGE: 3173; UN: UN1648; MARINE POLLUTANTS: NO; PACKAGING GROUP: II; LABELS: 3 FLAM LIQ; REG REFERENCES: 49CFR PART 176; IMDG CODE. AIR (I.C.A.O.) : PROPER SHIPPING NAME: ACETONITRILE; HAZ CLASS: 3; UN: UN1648; PACKAGING GROUP: II; LABELS: 3 FLAM LIQ; REG REFERENCES: 49CFR PART 175. SPECIAL SHIPPING INFO: SEGREGATE FROM STRONG ACIDS. U.S. CUST OMS HARMONIZATION #: 29269000008. ===================== Regulatory Information ===================== SARA Title III Information:ACUTE/CHRONIC/FLAMMABILITY: YES. PRESSURE/REACTIVITY: NO. EXTREMELY HAZARDOUS SUBSTANCE: NO. CERCLA HAZARDOUS SUBSTANCE: YES, CONTAINS ACETONITRILE (RQ=5000 LBS). SARA 313 TOXIC CHEMICALS: YES, CO NTAINS ACETONITRILE. GENERIC CLASS REMOVED FROM CFR: 7/1/91. Federal Regulatory Information:TSCA INVENTORY: YES. State Regulatory Information:OTHER INFO: MODERATE DEGREES OF CYANOSIS NEED BE TREATED ONLY BY SUPPORTIVE MEASURES SUCH AS BED REST AND OXYGEN. CYANOCOBALAMIN (B12), 1 MG INTRAMUSCULARLY, MAY SPEED RECOVERY. INTRAVENOUS FLUIDS A ND BLOOD TRANSFUSIONS MAY BE INDICATED IN VERY SEVERE CIRCUMSTANCES. MEDICAL SURVEILLANCE: PROVIDE PREPLACEMENT AND PERIODIC MEDICAL EXAMINATIONS WITH EMPHASIS ON KIDNEYS, LIVER, RESPIRATORY SYSTEM, CARDIOVASCULAR SYSTEM, AND CENTRAL NERVOUS SYSTEM. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RACON 12 CAGE:EO152 CAGE:2A580 CAGE:EO152 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 100% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 IS >500,000 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS NEITHER CORROSIVE NOR AN IRRITANT. AS A LIQUID IT WILL EVAPORATE FAST ENOUGH TO CAUSE FREEZING (FROSTBITE). VAPOR IS HEAVIER THAN AIR AND CAN CAUSE SUFFOCATION BY REDUCING AVAILABLE OXYGEN, OR MAY CAUSE FATAL CARDIAC ARRHYTHMIAS. SNIFFING FLUOROCARBONS FOR THEIR INTOXICATING EFFECT HAS CAUSED HUMAN DEATHS. Explanation of Carcinogenicity:CFC 502 IS NOT LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. LIQUID CAN CAUSE FREEZING OF TISSUES CONTACTED. Medical Cond Aggravated by Exposure:PEOPLE WITH HEART OR RESPIRATORY DISORDERS MAY BE ESPECIALLY SUSCEPTABLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/ WATER 15 MIN HOLD LIDS OPEN SEE A DOCTOR. SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING, AS NEEDED. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS. INGESTED:(HIGH LY UNLIKELY) DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL CARE. IF ANY IRRITATION PERSISTS,OR IS SEVERE,SEE A DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE AT FIRE TEMPERATURE. ALSO PRODUCES TOXIC VAPORS AT FIRE TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. EVACUATE PERSONNEL UNTIL VAPORS ARE DISPERSED. DO NOT SMOKE OR OPERATE INTERNAL COMBUSTION ENGINES IN THE VICINITY OF A SPILL. Neutralizing Agent:NONE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A CLEAN, COOL (<120F), DRY AND WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:APPLY ALL SAFETY PRECAUTIONS TO EMPTY CONTAINERS AS THEY MAY CONTAIN PRODUCT RESIDUES/VAPORS/PRESSURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK STATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, USE A SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR, APPROVED BY NIOSH/MSHA. Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER. Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS DANGER OF CONTACT WITH LIQUID. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID CONTACT. REMOVE AND WASH CLOTHING PROMPTLY UPON CONTAMINATION. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-22F,-30C Vapor Pres:79.8 PSIG Vapor Density:4.25 Spec Gravity:1.31 Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS LIQUID OR VAPOR, SLIGHT ETHEREAL TO ODORLESS Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI AND ALKALINE EARTH METALS AND FINELY DIVIDED REACTIVE METALS. Stability Condition to Avoid:HEAT SUCH AS FLAMES OR HOT METAL SURFACES. Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES (OPEN FLAMES, GLOWING METAL SURFACES, ETC.) FORMING HYDROCHLORIC AND HYDROFLUORIC ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OSTER BESTOL CAGE:LO984 CAGE:34864 CAGE:LO984 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIZED PARAFFIN OIL CAS:68201-54-7 Fraction by Wt: 85% OSHA PEL:500 PPM (MFR) ACGIH TLV:N/K Ingred Name:SULFURIZED POLYBUTENE CAS:6829-54-7 Fraction by Wt: 7.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SULFURIZED FATTY MATERIAL; (SULFURIZED FAT) CAS:61790-49-6 Fraction by Wt: 2.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED; (CHLORINATED PARAFFIN) (CONTAINING ING 5) CAS:63449-39-8 RTECS #:RV0450000 Fraction by Wt: 5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HALOGENATED SOLVENTS; (HALOGENS). %:25-35 PPM. Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE SEVERE IRRITATION, REDNESS OR TEARING. SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING OR DERMATITIS. INHALATION/INGESTION:MAY CAUSE NAUSEA, VOMITING AND DIA RRHEA. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, GET MED ATTN. SKIN:THORO WASH W/WATERLESS HAND CLEANER, THEN SOAP & WATER. DISCARD SOAKED CLOTHING. INHALATION:REMOVE TO FRESH AIR. IF BREA THING IS DIFFICULT, USE OXYGEN. INGESTION:DO NOT INDUCE VOMITING - SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:370F,188C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS/OTHER FLAMES & IGNIT SOURCES AT LOCATIONS DIST FROM MATL (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. CONFINE SPILL. PUMP LIQUID TO STORAGE. ABSORB SPILLED LIQUID W/SAND, CLAY OR EARTH FLOOR ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE PER NFPA CLASS IIB (COMBUSTIBLE LIQUID HAVING A FLASH POINT ABOVE 200F/93.4C). Other Precautions:HANDLE AS PER OTHER SECTIONS IN THIS MSDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE IS NEEDED UNDER ANTICIPATED USE CONDITIONS W/ADEQUATE VENTILATION. IF EXPOSURE EXCEEDS PEL USE NIOSH APPROVED RESPIRATOR EQUIPMENT. Ventilation:LOCAL EXHAUST:AS REQUIRED TO MAINTAIN EXPOSURE BELOW PEL. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . WEAR IMPERVIOUS CLOTHING & BOOTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:HANDLING POINT. MATLS TO AVOID:SUCH AS COPPER TUBING OR COPPER STORAGE CONTAINERS. ================== Physical/Chemical Properties ================== Spec Gravity:0.91 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:DARK CLEAR LIQUID; MINERAL OIL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONT W/STRONG OXIDIZING AGENTS (PEROXIDES, CITRIC ACID, CHLORINE, PURE OXYG). AVOID EXPOS TO COPPER MATLS (SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE, SULFUR DIOXIDE, HYDROGEN CHLORIDE & ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN UNDER CONTROLLED CONDITIONS OR DEPOSIT IN DISPOSAL SITE IN COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 201-64W175, SANTOPRENE THERMOPLASTIC RUBBER GENERAL (SUPDAT) Cage: 00S00 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 00S00 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: YES OSHA: NO Effects of Exposure: INHALATION: INHALATION OF FUMES OR VAPORS DURING PROCESSING MAY CAUSE RESPIRATORY TRACT IRRITATION. EYE CONTACT: PELLETS DO NOT CAUSE SIGNIFICANT EYE IRRITATION. SKIN CONTACT: PELLETS DO NOT CAUSE SIG NIFICANT SKIN IRRITATION. Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 149, 1996:GROUP 2B. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. (FP N). INHAL: IF FUMES ARE INHALED, REMOVE TO FRESH AIR. IFBREATHING IS DIFFICULT, GET MEDICAL ATTENTION. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SPILLED PRODUCT MAY CAUSE A SLIPPING HAZARD. IN CASE OF SPILL OR LEAK, VACUUM OR SWEEP UP AND PLACE IN CLEAN, COVERED CONTAINERS FOR RECYCLE OR DISPOSAL. Waste Disposal Methods: WHEN DISCARDED, SANTOPRENE GEN PURPOSE THERMOPLASTIC RUB IS NOT "HAZ WASTE" AS DEFINED IN 40 CFR 261, "IDENTIFICATION & LISTING OF HAZ WASTE." RECYCLE OR BURN IN APPRVD INCINERATOR OR DISPOSE OF IN AP PRVD CHEM LANDFILL I/A/W ALL APPLIC LOCAL, STATE & FED LAWS & REGS. CONSULT YOUR ATTORNEY OR APPROP REGULATORY OFFICIALS FOR INFO ON SUCH (SUPDAT) Handling And Storage Precautions: AVOID LEAVING CONTAINER OPEN FOR PRLNGD PERIODS TO PREVENT EXPOSURE TO HUMITIDY. SANTOPRENE GENERAL PURPOSE THERMOPLASTIC RUBBER WILL PICK UP SMALL AMTS OF MOISTURE. STORE IN A COOL, DRY PLACE. USUAL PRECS IN PELLET HANDLING SHOULD BE OBSERVED TO PREVENT CONTAMINATION BY DIRT OR OTHER MATERIALS. Other Precautions: HANDLE PELLETS I/A/W GOOD INDUS HYGIENE & SAFETY PRACTICES. THESE PRACTICES INCLUDE AVOIDING UNNEC EXPOSURE & REMOVAL OF MATL FROM EYES, SKIN & CLTHG. CAUTION! PROCESSING RELEASES VAPORS OR FUMES WHIC H MAY CAUSE RESPIRATORY TRACT IRRITATION. AVOID BRTHNG PROCESSING FUMES OR VAPORS. PROCESS USING ADE Q VENTILATION. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: SUPDAT Extinguishing Media: WATER SPRAY OR ANY CLASS A EXTINGUISHING AGENT. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). CARBON MONOXIDE IS LIBERATED AS A TOXIC DECOMPOSITION PRODUCT WHEN SANTOPRENE GENERAL PURPOSE THERMOPLASTIC RUBBER IS IGNITED. Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: AVOID BREATHING PROCESS VAPORS OR DUST. USE NIOSH APPRVD RESPIRATORY PROT EQUIPMENT (FULL FACEPIECE RECOM) WHEN AIRBORNE EXPOSURE IS EXCESSIVE. CONSULT RESPIRATOR MFR TO DETERMINE APPROPRIATE TYPE EQU IPMENT FOR GIVEN APPLICATION. OBSERVE RESPIRATOR USE LIMITATIONS SPECIFIED BY NIOSH OR THE MAFR. RESPIRATORY PROT PROGRAMS MUST COMPLY WITH 29 CFR 1910.134. Ventilation: PROVIDE NATURAL OR MECHANICAL VENT TO MINIMIZE EXPOSURE. IF PRACTICAL, USE LOCAL MECH EXHAUST VENT AT SOURCES OF AIR CONTAMINATION SUCH AS OPEN PROCESS EQUIP. Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: ALTHOUGH SANTOPRENE GEN PURPOSE THERMOPLASTIC RUBBER DOES NOT PRESENT SIGNIFICANT SKIN CONCERN, MINIMIZE SKIN CONTAM BY FOLLOWING Supplemental Safety and Health: MFR'S TRADE NAME/PART NO: PURPOSE GRADES. WASTE DISP METH: DISP. REPROCESS ONLY UNCONTAM MATL. SPILL/LEAK PROCS:VACUUM OR SWEEP UP & PLACE IN CNTNR FOR RECYCLE OR DISP AS RECOM ABOVE. CNTNRS: RECYCLE OR BURN IN APPRVD INCINERATOR OR DISP OF IN APPRVD CHEM LANDFILL I/A/W ALL APPLIC LOCAL, STATE & FED LAWS & REGS. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 0.95-0.98 Appearance and Odor: BLACK OR NATURAL (COLORABLE) PELLETS; SLIGHTLY RUBBERLIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES & (STATE REG INFO) Stability Condition To Avoid: THERMALLY STABLE TO 500F (260C). Materials To Avoid: SANTOPRENE THERMOPLASTIC RUBBER MAY REACT W/STRONG OXIDIZING CHEMS. IT ALSO REACT W/ACETAL RESINS AT TEMPS OF 425F(218C) & ABOVE, PRODUCING DECOMP OF ACETAL RESIN & FORMALDEHYDE AS DECOMP PROD. DECOMP OF HALOGENATED POLYMER Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE AND POSSIBLY HYDROCARBONS MAY EVOLVE WHEN PROCESSING TEMPERATURES EXCEED 500F (260C) OR WHEN SANTOPRENE GENERAL PURPOSE THERMOPLSATIC RUBBER IS IGNITED. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: FOLLOWING INFO SUMMARIZES HUMAN EXPERIENCE & RSLTS OF SCIENTIFIC INVESTIGATIONS REVIEWED BY HEALTH PROFESSIONALS FOR HAZ EVALUATION OF SANTOPRENE GEN PURPOSE THERMOPLASTIC RUB. OCCUP EXPOS TO THIS MAT L IN NORM HNDLG & STORAGE HAS NOT BEEN REPORTED TO CAUSE SIGNIFICANT ADVERSE HUMAN HLTH EFTS. DUE TO ITS CHEM & PHYSICAL PROPERTIES. SANTOPRENE GEN PURPOSE THERMOPLASTIC RUB DOES NOT APPEAR TO POSSESS ANY TOXICOLOGICAL PROPERTIES WHICH WOULD REQ SPEC HNDLG OTHER THAN GOOD INDUS HYGIENE & SFTY PRACTS EMPLOYED W/ANY INDUS MATL OF THIS TYPE. HOWEVER, UNDER NORM PROCESSING CNDTNS, PROD WILL (STATE RE G INFO) ======================================================= Ecological Information ======================================================= Ecological: NO DATA AVAILABLE. STATE REG INFO: CANNOT BE PREDICTED BASED ON CURRENT INFO. THESE PROCESS RELEASES MAY PRDCE RESP TRACT IRRIT WHERE SUCH RELEASES ARE ALLOWED TO BUILD UP DUE TO INADEQUATE VENT IN GE NERAL WORK AREA. THESE FUMES & VAPS, W/RPTD & PRLNGD EXPOSURE AT HIGH CONCS, COULD CAUSE NAUS, DROW & HDCH, ESP IF SUCH EXPOSURES EXCEED CURRENT EXPOSURE LIMITS (WHERE ESTABLISHED). GOOD INDUSTRIAL HY GIENE & SAFETY PRACTICES SHOULD BE USED TO AVOID UNNEC EXPOSURES. TOXICOLOGICAL DATA - RSLTS OF SINGLE EXPOSURE (ACUTE) ANIMAL STUDIES CONDUCTED ON REPRESENTATIVE GRADE OF GENERAL (TRANSPORT INFO) ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= Sara Title III Information: SARA HAZARD NOTIFICATION - HAZARD CATEGORIES UNDER CRITERIA OF SARA TITLE III RULES (40 CFR PART 370): N/A. SECTION 313 HAZARDOUS CHEMICAL(S): N/A. SECTION 313 INFO MUST BE INCLUDED IN ALL MSDSS THATARE COPIED & DISTRIBUTED FOR THIS MATL. Federal Regulatory Information: REPORTABLE QUANTITY (RQ) UNDER DOT (49 CFR) & CERCLA REGS: N/A. HAZ CHEM(S) UNDER OSHA HAZ COMMUNICATION STANDARD: BLACK GRADE CONTAIN CARBON BLACK: 2-3% WT RANGE. RATING: REACTIVITY-1; HEALTH: 1 ; FLAMMABILITY: 1.ALLL COMPONENTS OF THESE PRODUCTS APPEAR ON THE INVENTORY OF CHEMICAL SUBSTANCES PUBLISHED BY U.S. EPA/QUALIFY FOR TSCA: POLYMER. State Regulatory Information: NJ TRADE SECRET REGISTRY NO: 01122800003-5001P.MATLS TO AVOID: PHENOLIC RESINS MAY ALSO BE ACCELERATED WHEN THEY ARE IN CONT W/SANTOPRENE THERMOPLASTIC RUBBER AT PROCESSING TEMPS. THOROUGHLY PURGE PRO CESSING EQUIP W/POLYOLEFIN POLYMERS, INCL POLYPROPYLENE, WHEN USING SAME EQUIP TO PROCESS SANTOPRENE THERMOPLASTIC RUBBER & ACETAL RESINS, HALOGENATED POLYMERS & PHENOLIC RESINS. DO NOT MIX SANTOPRENE THERMOPLASTIC RUBBER, ACETAL RESINS, HALOGENATED POLYMERS OR PHENOLIC RESINS AT ELEV TEMPS. TOXIC I NFO: RELS FUMES & VAPS. COMPONENTS OF THESE RELS MAY VARY W/PROCESSING TIMES & TEMPS & THEREFORE SPECIFIC COMPOSITION (ECOLOGICAL INFO) ======================================================= Other Information ======================================================= Other Information: DATE MSDS INITIALLY PREPARED: 5/5/95. REVISION(S): 9/30/96-UPDATED CARBON BLACK INFO. 10/11/96-UPDATED POLYMER EXEMPTION INFO. 12/1/98-REVIEWED FOR ACCURACY; NO CHANGES MADE. FOR ADDNL NON-EMER INFO, CNTCT PROD SFTY-(330)849-5163. HYGIENE PRACTS: WASH HANDS & CONTAM SKIN THOROUGHLY AFTER HNDLG. PHYSICAL DATA - HARDNESS: 45 SHORE A TO 50 SHORE D. NOTE: THESE PHYSICAL DATA ARE TYPICAL VALUES BASED O N MATL TESTED BUT MAY VARY FROM SAMPLE TO SAMPLE. TYPICAL VALUES SHOULD NOT BE CONSTRUED AS GUARANTEED ANALYSIS OF ANY SPECIFIC LOT OR AS SPECIFICATIONS FOR PROD. ======================================================= HAZCOM Label ======================================================= Product ID: 201-64W175, SANTOPRENE THERMOPLASTIC RUBBER GENERAL (SUPDAT) Cage: 00S00 Company Name: ADVANCED ELASTOMER SYSTEMS LP Street: 388 SOUTH MAIN ST Zipcode: 44311 Label Required IND: Y Date Of Label Review: 10/14/1999 Status Code: A Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: INHALATION: INHALATION OF FUMES OR VAPORS DURING PROCESSING MAY CAUSE RESPIRATORY TRACT IRRITATION. EYE CONTACT: PELLETS DO NOT CAUSE SIGNIFICANT EYE IRRITATION. SKIN CONTACT: PELLETS DO NOT CA USE SIGNIFICANT SKIN IRRITATION. CHRONIC: CANCER HAZ. CONTAINS CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AC-236 ACCELERATOR Preparer's Name:HENRY SIMMONS CAGE:1DWR5 CAGE:1DWR5 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE OXIDE CAS:1313-13-9 RTECS #:OP0350000 = Wt:66.4 OSHA PEL:C5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:HYDROGENATED TERPHENYL CAS:61788-32-7 RTECS #:WZ6535000 = Wt:22.7 ACGIH TLV:4.9 MG/M3;0.5 PPM Ingred Name:1,3-DIPHENYLGUANIDINE CAS:102-06-7 RTECS #:MF0875000 = Wt:.7 Ingred Name:TERPHENYL CAS:26140-60-3 RTECS #:WZ6450000 = Wt:4.8 OSHA PEL:C9 MG/M3;C1 PPM ACGIH STEL:C5 MG/M3;C0.53 PPM Ingred Name:ETHOXYLATED NONYLPHENOL PHOSPHATE CAS:51811-79-1 = Wt:4.8 Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 = Wt:1.4 OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:CHRONIC EFFECTS: LIVER, KIDNEYS, NERVOUS SYSTEM. BLOOD AND/OR BLOOD-FORMING ORGANS. LUNGS AND RESPIRATORY SYSTEM. REPRODUCTIVE SYSTEM (AND REPRODUCTIVE EFFECTS). EYES. SKIN. IMMUNE SYSTEM, (E.G., ALLE RGIC REACTIONS). Effects of Overexposure:EYE CONTACT: MAY CAUSE MODERATE IRRITATION SKIN CONTACT: MAY CAUSE SLIGHT TO MILD IRRITATION. MAY CAUSE ALLERGIC SKIN REACTIONS AND SENSITIZATIONS. INHALATION (BREATHING): IRRITATING TO THE EYES, NO SE, AND RESPIRATORY TRACT. CAN CAUSE DIZZINESS, HEADACHE, AND INCOORDINATION.INGESTION (SWALLOWING): IRRITATING TO THE MOUTH. MAY CAUSE NAUSEA, VOMITING, PAIN, AND STOMACH UPSET (E.G., DIARRHEA) Medical Cond Aggravated by Exposure:LIVER, KIDNEYS, LUNGS AND RESPIRATORY SYSTEM. SKIN. IMMUNE SYSTEM AND/OR SPECIFIC CHEMICAL ALLERGIES. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN CONTACT: IMMEDIATELY FLUSH WITH WATER. REMOVE CONTAMINATED CLOTHIN G AND SHOES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. PROFESSIONALLY WASH CLOTHING AND SHOES BEFORE RE-USE. INHALATION (BREATHING): REMOVE TO FRESH AIR. IF SYMPTOMS DEVELOP, SEEK IMMEDIATE MEDIC AL ATTENTION. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. INGESTION (SWALLOWING): SEEK MEDICAL ATTENTION: IMMEDIATELY INDUCE VOMITING, AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUT H TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:>93.3C, 200.F Extinguishing Media:SMALL FIRES: DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY, OR FOAM. LARGE FIRES: WATER SPRAY, FOG, OR ALCOHOL FOAM. Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSED TO THE PRODUCTS OF COMBUSTION SHOULD BE EQUIPPED WITH NIOSH-APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL PROTECTIVE CLOTHIN G. Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND HIGHLY TOXIC GASES MAY BE GENERATED DURING COMBUSTION OR DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:ISOLATE HAZARD AREA. KEEP UNNECESSARY AND UNPROTECTED PERSONNEL FROM ENTERING. SAFETY STOP DISCHARGE. CONTAIN MATERIAL, AS NECESSARY, WITH A DIKE OR BARRIER. STOP MATERIAL FROM CONTAMINATING SOIL, OR FROM ENTERING SEWERS OF BODIES OF WATER. APPROPRIATE SAFETY MEASURES AND PROTECTIVE EQUIPMENT SHOULD BE USED. USE SUPPLIED AIR RESPIRATOR OF SELF-CONTAINED BREATHING APPARATUS IN ENCLOSED SPACES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT, IGNITION SOURCES, AND DIRECT SUNLIGHT. KEEP CONTAINERS TIGHTLY CLOSES. TRANSFER- NO SPECIAL PRECAUTIONS ARE NEEDED. FOLLOW GOOD MANUFACTURING A ND HANDLING PRACTICES. Other Precautions:THIS CONTAINER CAN BE HAZARDOUS WHEN EMPTY. FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED SINCE EMPTY CONTAINERS MAY RETAIN PRODUCT RESIDUES. DO NOT REUSE EMPTY CONTAINER WITHOUT PROFESSIONAL CLEANING FOR FOOD, CLOTHING, OR PRODUCTS FOR HUMAN OR ANIMAL CONSUMPTION OR WHERE SKIN CONTACT CAN O CCUR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATHING VAPOR OR MIST. WEAR NIOSH/MSHA-APPROVED EQUIPMENT. DETERMINE THE APPROPRIATE TYPE BY CONSULTING THE RESPIRATOR MANUFACTURER. HIGH AIRBORNE CONCENTRATION MAY NECESSITATE THE USE OF SELF CONTAINED BREATHING APPARATUS (SCBA) OR A SUPPLIED AIR RESPIRATOR. RESPIRATORY PROTECTION PROGRAMS MUST BE IN COMPLIANCE WITH 29 CFR 1910.134 Ventilation:LOCAL EXHAUST VENTILATION WHEN VAPORS, MISTS, OR DUSTS CAN BE RELEASED IN EXCESS OF ESTABLISHED AIRBORNE EXPOSURE LIMITS (TLV?S OR PEL?S) SHIELDS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING, DRINKING, SMOKING, AND USING RESTROOM FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:0.1 MM HG Vapor Density:>1 Spec Gravity:2.1 Evaporation Rate & Reference:<1 (BUTYL ACETATE) Solubility in Water:INSOLUBLE Appearance and Odor:BLACK PASTE AND DISTANT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS Stability Condition to Avoid:HIGH TEMPERATURES Hazardous Decomposition Products:SMOKE, SOOT, AND TOXIC/IRRITATING FUMES (I.E., CARBON DIOXIDE, CARBON MONOXIDE, ETC). FORMALDEHYDE AND/OR OTHER ALDEHYDES. OXIDES OF NITROGEN, METALLIC OXIDES. =================== Toxicological Information=================== Toxicological Information:MANGANESE OXIDE: EYE, SKIN, AND RESPIRATORY TRACT. CAN CAUSE LIVER AND KIDNEY INJURY. TERPHENYL, HYDROGENATED: ORAL LD50 RAT 17,500 MG/KG MOUSE 12,500 MG/KG DERMAL LD50 RABBIT >2,000 MG/KG 1,3-DIPHENYLQUANIDINE: ORAL RAT 507 MG/KG MOUSE 290 MG/KG TERPHENYL ORAL LD50 RAT 13,200 MG/KG ETHOXYLATED NONYLPHENOL PHOSPHATE ORAL LD50 RAT 3,630 MG/KG SODIUM HYDROXIDE: CORROSIVE! CAUSE EYE AND S KIN BURNS. DERMAL LD50 RABBIT 1000 MG/KG. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS OF THE METHODS OF DISPOSAL CURRENTLY AVAILABLE, IT IS RECOMMENDED THAT AN ALTERNATIVE BE ACCORDING OR THE FOLLOWING ORDER OF PRE FERENCE. BASED UPON ENVIRONMENTAL ACCEPTABILITY. (1) RECYCLE OR REWORK, IF FEASIBLE; (2) INCINERATE AT AN AUTHORIZED FACILITY. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 311 AND 312: IMMEDIATE (ACUTE) HEALTH HAZARD, DELAYED (CHRONIC) HEALTH HAZARD. SARA SECTION 302 EXTREMELY HAZARDOUS MAT-NO REGULATED INGREDIENTS SARA SECTION 313 TOXIC CHEMICALS MANGANESE OX IDE Federal Regulatory Information:UNITED STATES CHEMICAL COMPONENTS THIS PRODUCT ARE ON THE SECTION 8(B) CHEMICAL SUBSTANCE INVENTORY LIST (40 CFR 710) State Regulatory Information:STATE RIGHT TO KNOW PENNSYLVANIA-NEW JERSEY R-T-K MANGANESE OXIDE 1313-13-9 66.4% TERPHENYL, HYDROGENATED 61788-32-7 22.7% 1,3 ? DIPHENYLQUANIDINE 102-06 7% TERPHENYL 26140-60-3 4.8% ETHOXYLATED NONYLPHENOL PHOSPHATE 51811-79-1 2.9% SODIUM HYDROXIDE 1310-73-2 1.4% CALIFORNIA ? CALIFORNIA PROPOSITION 65-NO REGULATED INGREDIENTS ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRESENCE/ABSENCE BROTH WITH MUG, DISPOSAL Resp. Party Other MSDS Num.:M00896 CAGE:91224 CAGE:91224 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 < Wt:5. Other REC Limits:LD50 ORAL RAT=3G/KG Ingred Name:PEPTONES CAS:73049-73-7 < Wt:5. Ingred Name:BEEF EXTRACT < Wt:5. Ingred Name:LACTOSE CAS:63-42-3 RTECS #:OD9625000 Minumum % Wt:1. Maxumum % Wt:10. Ingred Name:WATER (DEMINERALIZED) CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:60. Maxumum % Wt:70. Ingred Name:OTHER COMPONENTS, EACH < Wt:1. Ingred Name:TRYPTOSE (9015-54-7) Minumum % Wt:1. Maxumum % Wt:10. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: NO EFFECTS ARE ANTICIPATED. SKIN: NO EFFECTS ARE ANTICIPATED. INGESTION: PRACTICALLY NON-TOXIC. INHALATION: NO EFFECTS ANTICIPATED. CHRONIC EFFECTS: NO EFFECTS ANTICIPATED. Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY OSHA LISTED CARCINOGENS. THIS PRODUCT DOES NOT CONTAIN ANY IARC AND NTP LISTED CHEMICALS. Effects of Overexposure:NONE ANTICIPATED. Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH EYES WITH WATER. CALL PHYSICIAN IF IRRITATION DEVELOPS. SKIN: WASH SKIN WITH PLENTY OF WATER. INGESTION: GIVE LARGE QUANTITIES OF WATER. CALL PHYSICIAN IMMEDIATELY. INHALATION: NONE REQUIRE D. ===================== Fire Fighting Measures ===================== Flash Point:WILL NOT BURN Extinguishing Media:USE MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:THIS PRODUCT WILL NOT BURN OR EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILLED MATERIAL FROM BEING RELEASED TO THE ENVIRONMENT. ABSORB SPILLED LIQUID WITH NON-REACTIVE SORBENT MATERIAL. CLEANUP OF USED PRODUCT: STERILIZE WITH BLEACH OR BY AUTOCLAVING. PLACE MATERIAL IN A PLASTIC BAG. MARK BAG 'NON-HAZARDOUS TRASH', AND DISPOSE OF AS NORMAL REFUSE. DECONTAMINATE AREA WTH BLEACH SOLUTION. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. STORE IN THE DARK BETWEEN 2C - 25C. Other Precautions:ONLY PERSONS PROPERLY QUALIFIED TO RESPOND TO AN EMERGENCY INVOLVING HAZARDOUS SUBSTANCES MAY RESPOND TO A SPILL ACCORDING TO FEDERAL REGULATION (OSHA 29 CFR 1910.120(A)(V) AND PER YOUR COMPANY'S EMER GENCY RESPONSE PLAN AND GUIDELINES/PROCEDURES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ADEQUATE VENTILATION. Ventilation:MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN USING THIS PRODUCT. Work Hygienic Practices:AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. PROTECT FROM LIGHT. Supplemental Safety and Health CATALOG NUMBER: 2401650. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:=100.C, 212.F Vapor Pres:NOT DETERMINED Spec Gravity:NOT DETERMINED pH:6.9 Evaporation Rate & Reference:NOT DETERMINED Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, RED-PURPLE LIQUID; ODOR NOT DETERMINED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REPORTED. Stability Condition to Avoid:BACTERIAL CONTAMINATION. EXPOSURE TO DIRECT SUNLIGHT. HEAT. Hazardous Decomposition Products:NO HAZARDOUS DECOMPOSITION PRODUCTS KNOWN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:PRODUCT TOXICOLOGICAL DATA: LD50, LC50 = NONE REPORTED. SKIN, EYE IRRITATION DATA= NONE REPORTED. DERMAL TOXICITY DATA= NONE REPORTED. MUTATION DATA = NONE REPORTED. REPRODUCTIVE TOXICITY: IN A LOBORA TORY TEST, MICE GIVEN 2% NACL SOLUTION IN PLACE OF DRINKING WATER DURING PREGNANCY PRODUCED HYPERTENSIVE ADULT OFFSPRING. A SINGLE SUCUTANEOUS INJECTION OF NACL SOLUTION INTO PREGNANT MICE @2500 MG/KG CAUSED FETAL DEATHS AND MALFORMATION. INGREDIENT TOXI DATA: LACTOSE ORAL RAT TLDL0= 375 MG.KG; NACL ORAL RAT LD50= 3000 MG/KG. ===================== Ecological Information ===================== Ecological:NO ECOLOGICAL DATA AVAILABLE FOR THIS PRODUCT AND ITS INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:USED PRODUCT-STERILIZE WITH BLEACH OR BY AUTOCLAVING. UNUSED PRODUCT-MAKE SURE TUBES ARE TIGHTLY CAPPED. PLACE MATERIAL IN A PLASTIC BAG. MARK BAG 'NON-HAZARDOUS TRASH,' AND DISPOSE OF AS NORMAL REFU SE. EMPTY CONTAINERS: RINSE THREE TIMES WITH AN APPROPRIATE SOLVENT. DISPOSE OF EMPTY CONTAINER AS N ORMAL TRASH. FOLLOW ALL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED FOR TRANSPORTATION. ===================== Regulatory Information ===================== SARA Title III Information:SEC 311/312: NOT COVERED. SEC 313 (40 CFR 372): DOES NOT CONTAIN ANY CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SEC 313. SEC 302 (EHS) TPQ, RQ (40 CFR 355): NOT APPLICABLE. SEC 304 CERCLA RQ ( 40 CFR 302.4 : NOT APPLICABLE. CLEAN WATER ACT (40 CFR 116.4): NOT APPLICABLE. Federal Regulatory Information:OSHA: THIS PRODUCT DOES NOT MEET THE CRITERIA FOR A HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZCOM STANDARD ( 29 CFR 1910.1200). TSCA: ALL INGREDIENTS ARE LISTED ON THE TSCA 8(B) INVENTORY (40CFR 710). State Regulatory Information:CALIFORNIA PROPOSITION 65: NO LISTED CHEMICALS ARE PRESENT. ======================= Other Information ======================= ======================================================================
1
eyes_protection_mandatory
======================================================= Product ID: STAMARK HIGH PERFORMANCE 370 Cage: 1BY21 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 1BY21 ======================================================= Ingredients ======================================================= Cas: 65997-17-3 % Wt: 30-42 OSHA PEL: 5 MG/M3 RESP DUST ACGIH TLV: 10 MG/M3 (<7MICRONS) ------------------------------ % Wt: 12-20 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 12-20 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 10-15 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 10-15 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 2-10 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- % Wt: 1-5 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE CONT:DUST CREATED BY CUTTING, GRINDING OR SANDING OF CURED PRODUCT MAY CAUSE MECH IRRIT. SKIN CONT:DUSTS MAY CAUSE IRRIT ON PRLNG/RPTD CONTACT. INHAL:DUST CREATED BY CUTTING, GRINDING OR SANDING O F CURED PRODUCT MAY CAUSE RESP IRRIT. INGEST:MAY CAUSE MINOR IRRIT TO MOUTH, THROAT & STOMACH. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYE:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONTINUE FOR 10 MINUTES HOLDING EYELIDS OPEN. CALL MD. SKIN:WASH AFFECTED AREA W/SOAP & WATER. INHAL:REMOVE PERSON TO FRESH AIR. CALL M D. INGEST:DO NOT INDUCE VOMITING. IF PERSON IS CONSCIOUS GIVE ONE TO TWO GLASSES OF WATER. IMMEDIATELY CALL MD. ======================================================= Handling and Disposal ======================================================= Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE AS DRY SCRAP. SINCE REGULATIONS VARY, CONSULT APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS OR AUTHORITIES BEFORE DISPOSAL. Handling And Storage Precautions: FOR INDUSTRIAL OR PROFESSIONAL USE ONLY. AVOID EYE CONTACT W/INHALATION OF DUSTS CREATED BY CUTTING, GRINDING OR SANDING OF CURED MATERIAL. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: CARBON DIOXIDE, FOAM OR DRY CHEMICALS. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE KNOWN. ======================================================= Control Measures ======================================================= Respiratory Protection: WEAR NIOSH/MSHA APPROVED DUST MASK TO PREVENT DUST EXPOSURE DURING CUTTING OR GRINDING OF PRODUCT. Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: HAZ DECOMP PROD:HYDROGEN CYANIDE. ======================================================= Physical/Chemical Properties ======================================================= HCC: N1 Appearance and Odor: SOLID, WHITE; MINIMAL ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: NONE KNOWN. Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE & CARBON DIOXIDE, HYDROGEN CHLORIDE, ALDEHYDES, HYDROCARBONS &(SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: STAMARK HIGH PERFORMANCE 370 Cage: 1BY21 Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV Street: 3M CTR Zipcode: 55144-1000 Label Required IND: Y Date Of Label Review: 11/17/1994 Status Code: C Label Date: 11/17/1994 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE:EYE CONT:DUST CREATED BY CUTTING, GRINDING OR SANDING OF CURED PRODUCT MAY CAUSE MECH IRRIT. SKIN CONT:DUSTS MAY CAUSE IRRIT ON PRLNG/RPTD CONTACT. INHAL:DUST CREATED BY CUTTING, GRINDING OR SAN DING OF CURED PRODUCT MAY CAUSE RESP IRRIT. INGEST:MAY CAUSE MINOR IRRIT TO MOUTH, THROAT & STOMACH. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPACKLE LITE PASTE, M0683 CAGE:91953 CAGE:91953 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC COPOLYMER OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BOROSILICATE; (BOROSILICATE GLASS) OSHA PEL:5 MG/M3 RESP DUST ACGIH TLV:10 MG/M3 (<7MICRONS) Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ACRYLIC POLYMER OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIUM HYDROXIDE (CERCLA) CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC COMPOUND:0.1 LBS/GAL, 10 GMS/LTR RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION:CAN CAUSE HEADACHE, NAUSEA, IRRITATION OF NOSE, THROAT AND LUNGS. EYE:CAN CAUSE SLIGHT IRRITATION. SKIN:CAN CAUSE SLIGHT IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION:MOVE SUBJECT TO FRESH AIR. EYES:FLUSH WITH A LARGE AMOUNT OF WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. SKIN:WASH AFFECTED AREAS WITH SOAP AND WATER. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. INGESTION:GIVE 2 GLASSES OF WATER TO DRINK. CONSULT A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . IN CASE OF FIRE COOL EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES, ABSORB WITH ABSORBENT, SWEEP OR SCOOP UP, VENTILATE EXPOSED AREAS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM HEAT AND OPEN FLAMES. USE ADEQUATE VENTILATIONS. Other Precautions:AVOID REPEATED BREATHING OF VAPORS OR SKIN CONTACT. USE NIOSH/MSHA APPROVED AIR SUPPLIED RESCUE EQUIPMENT IN ENCLOSED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATHING VAPORS. USE WITH ADEQUATE VENTILATION. Ventilation:USE WITH ADEQUATE VENTILATION. Other Protective Equipment:USE FULL LENGTH CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:0.59 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:AVOID HIGH TEMPERATURES OR FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD ACRYLIC MONOMERS, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3A0-1220 PLASTI-GRIT TYPE III X-HARD (50 LB BAG) CAGE:98231 CAGE:98231 ============= Composition/Information on Ingredients ============= Ingred Name:AMMELIDE, MELAMINE CAS:108-78-1 RTECS #:OS0700000 Fraction by Wt: 99.5% Ingred Name:STEARAMIDOPROPYLDIMETHYL-BETA-HYDROXYETHYL AMMONIUM NITRATE (QUATERNARY AMMONIUM COMPOUND) CAS:2764-13-8 Fraction by Wt: <0.5% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY TRACT IRRITATION. INGESTION: HARMFUL. ======================= First Aid Measures ======================= First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING BY GIVING TWO GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:32F Extinguishing Media:FOAM, DRY CHEMICAL, CO2, WATER, STEAM Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. WEAR A FULL FACE PIECE. Unusual Fire/Explosion Hazard:POWDER FORMS EXPLOSIVE MIXTURE W/AIR. SEALED (CLOSED) CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT (FIRE). ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & PLACE IN APPROPRIATE DISPOSAL CONTAINER. USE PROPER SAFETY EQUIPMENT. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED, PROPERLY LABELED CONTAINERS IN COOL VENTILATED AREA. KEEP AWAY FROM HEAT, OPEN FLAMES, & OXIDIZING AGENTS. Other Precautions:DON'T TRANSFER TO UNMARKED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROVED NIOSH/MSHA PROPERLY FITTED DUST RESPIRATOR. Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV. Other Protective Equipment:FACESHIELD, PROTECTIVE RUBBER APRON, SHOES OR BOOTS Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING, OR APPLYING COSMETICS. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.5 pH:4-8 Solubility in Water:INSOLUBLE Appearance and Odor:GRANULAR, NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS Stability Condition to Avoid:EXCESSIVE HEAT, FIRE, OPEN FLAMES Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A SANITARY LANDFILL IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ISOPROPYL ALCOHOL, ACS, PX 1835 CAGE:HO130 CAGE:1U692 CAGE:HO130 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 100% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 ===================== Hazards Identification ===================== Effects of Overexposure:VAPORS:IRRIT TO EYES, NOSE & THROAT-MAY HAVE NARCOTIC EFFECT. CONTACT:EYE DAMAGE, SKIN IRRIT. ======================= First Aid Measures ======================= First Aid:INH:MOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF NECESSARY. EYES:FLUSH W/PLENTY OF WATER FOR 15 MINS, CALL MD. ING:INDUCE VOMITING FOR LARGE AMOUNTS. ===================== Fire Fighting Measures ===================== Flash Point:53F,11.7C TCC Lower Limits:2.0 Upper Limits:12.0 Extinguishing Media:DRY CHEMICAL,CO*2 OR ALCOHOL-TYPE FOAM Fire Fighting Procedures:WEAR SCBA. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. FLUSH SMALL SPILLS W/WATER. CONTAIN LARGE SPILLS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD Ventilation:EXHAUST VENT ADEQUATE TO KEEP LEVELS BELOW TLV. Supplemental Safety and Health MELTING PT:-127F,-88.5C. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:180F,82.3C Vapor Pres:33. Vapor Density:2.07 Spec Gravity:0.7854 Evaporation Rate & Reference:2.4, BUAC Solubility in Water:COMPLETE Appearance and Odor:CLEAR, COLORLESS LIQUID W/CHARACTERISTIC ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS,HALOGENS & HALOGEN COMPOUNDS Hazardous Decomposition Products:CO ==================== Disposal Considerations ==================== Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE W/ALL CURRENT LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: SPRAY 'N GO DECORATIVE ENAMEL - ALL COLORS, 51122 Cage: 90300 Box: 277 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 90300 Box: 277 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: YES IARC: YES OSHA: YES Effects of Exposure: EYES: MAY CAUSE IRRIT. SKIN: MAY IRRITATE SKIN. PRLNGD/RPTD CONTACT CAN RSLT IN DEFAT & DRYING OF SKIN WHICH MAY RSLT IN IRRIT & DERM (RASH). INHAL: VAP HARMFUL IF INHALED. VAP MAY CAUSE NOSE & THROATIRRIT. VAP INHAL MAY AFFECT BRAIN OR NERVOUS SYS CAUSING DIZZ, HDCH OR NAUS. INHAL OF HIGH CONCS OF (EFTS OF OVEREXP) Explanation Of Carcinogenicity: SEE "LR" VERSION, INGREDIENT 13, FOR ADDITIONAL INFORMATION (FP N). Signs And Symptions Of Overexposure: HLTH HAZ: VAP IS HARMFUL & MAY LEAD TO HEART IRREGULARITIES. INGEST: THIS MATL MAY BE HARMFUL OR FATAL IF SWALLOWED. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUMIT WHICH CAN BE FATAL. IF INGESTED, THIS PROD MAY CAUSE VOMIT, DIARR & DEPRESSED RESPIRATION. CHRONIC: CNTNRS MATL WHICH APPEARS ON THE (SUPDAT) Medical Cond Aggravated By Exposure: IF DRY SANDED, ASTHMA AND ASTHMA-LIKE CONDITIONS MAY WORSEN FROM PROLONGED OR REPEATED EXPOSURE TO DUST. First Aid: EYES: FLUSH WITH LARGE QUANTITIES OF WATER UNTIL IRRITATION SUBSIDES. CONTACT MD. SKIN: WASH WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHIN G IS DIFFICULT, GIVE OXYGEN. CONTACT MDIMMEDIATELY. INGEST: DO NOT INDUCE VOMITING. CONTACT MD OR REGIONAL POISON CONTROL CENTER IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT MATERIAL OR SCRAPE UP DRIED MATERIAL AND PLACE INTO CONTAINERS. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL STDS. USE ALL MATL BEFORE DISPOSAL. IF UNABLE TO USE ENTIRE CONTENTS OF CAN, RELIEVE PRESS IN CONTAINER UNTIL IT EQUALS EXTERNAL PRESSURE. INCINERATION O F THIS CAN W/OUT FIRST RELIEVING ALL Handling And Storage Precautions: STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP AWAY FROM HEAT, SPARK & FLAME. KEEP CNTNRS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CNTNRS FROM Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID SKIN & EYE CONTACT. AVOID BRTHG VAPORS. USE ONLY IN A WELL VENTD AREA. MAKE SURE NOZZLE ARROW IS DIRECTED AWAY FROM YOURSELF PRIOR TO DISCHARGE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: AEROSOL Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N) TO PROTECT FROM COMBUSTION PRODUCTS. COOL EXPOSED CONTAINERS WITH WATER. Unusual Fire/Explosion Hazard: CNTNRS MAY EXPLODE IF EXPOS TO EXTREME HEAT. ELIM IGNIT SOURCES:HEAT, ELEC EQUIP, SPKS & FLAMES. DO NOT PUT IN CNTCT W/OXIDIZING/CAUSTIC MATLS. AEROSOL (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: IF 8 HOUR EXPOS LIMIT OR VALUE IS EXCEEDED FOR ANY COMPONENT, USE NIOSH APPRVD RESP. CONSULT SFTY EQUIP SUPPLIER & OSHA REG, 29 CFR 1910.134 FOR RESP REQS. A RESP PROT PROGRAM THAT MEETS OSHA 1910.134 & ANSI Z88.2 REQS MUST BE Ventilation: PROVIDE SUFFICIENT MECH VENT (LOC OR GEN EXHST) TO MAINTAIN EXPOS BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health: USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). EXPLO HAZ: EXTREMELY FLAM. EFTS OF OVEREXP: LIST OF OCCUP CHEM REPRO HAZS. CONSULT APPROP HLTH PROFESSIONALS CONCERNING LATEST H AZ LIST INFO & SAFE HNDLG & EXPOS INFO (FP N). RPTS ASSOC PERM BRAIN & NERVOUS SYS DMG W/PRLNGD & RPTD OCCUP ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: HVR/AIR Spec Gravity: 0.70-0.80 Evaporation Rate & Reference: FASTER THAN BUTYL ACETATE Solubility in Water: NEGLIGIBLE Appearance and Odor: OPAQUE LIQUID; GASOLINE-LIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: EXCESSIVE HEAT AND FREEZING. Materials To Avoid: STRONG OXIDIZERS AND CAUSTICS. Hazardous Decomposition Products: NORMAL DECOMPOSITION PRODUCTS, IE CO*X, NO*X. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SPRAY 'N GO DECORATIVE ENAMEL - ALL COLORS, 51122 Cage: 90300 Company Name: DAP INC. PO Box: 277 Zipcode: 45401-0277 Label Required IND: Y Date Of Label Review: 03/19/1998 Status Code: C Label Date: 03/19/1998 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: AEROSOL. EXTREMELY FLAMMABLE. ACUTE: EYES: IRRIT. SKIN: IRRIT, DERMATITIS. INHAL: MAY CAUSE NOSE & THROAT IRRIT. MAY AFFECT BRAIN OR NERVOUS SYSTEM W/DIZZINESS, HEADACHE OR NAUSEA. MAY LEAD TO HEART I RREGULARITIES. INGEST: HARMFUL/FATAL IFSWALLOWED. MAY CAUSE VOMITING, DIARRHEA & DEPRESSED RESPIRATION. ASPIR INTO LUNGS CAN CAUSE POSSIBLY FATAL CHEM PNEUMIT. CHRONIC: CANCER HAZARD. CONTAINS MATL WH ICH IS LISTED AS A HUMAN BLOOD CARCIN (FP N). CONTAINS MATL WHICH APPEARS ON THE NAVY OCCUP CHEM REPRO HAZS LIST (FP N). OVEREXP TO SOLVENTS IS ASSOC W/PERM BRAIN & NERVOUS SYS DAMAGE. LIVER, KIDNEY & BRAIN DAMAGE & CARDIAC ABNORMALITIES. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SATINHIDE ALKYD LO-LUSTRE ENAMEL,20-LINE (041390 M) CAGE:DO894 CAGE:DO894 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM SILICATE CAS:1335-30-4 Fraction by Wt: 15 - 20% Other REC Limits:NONE RECOMMENDED Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 25 - 30% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TOTAL DUST ACGIH TLV:10 MG/M3 Ingred Name:HYDROTREATED HEAVY NAPHTHA CAS:64742-48-9 Fraction by Wt: 35 - 40% Other REC Limits:NONE RECOMMENDED Ingred Name:FILM FORMERS, RESINS AND ADDITIVES Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACTS. ACUTE- IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. HARMFUL OR FATAL IF SWALLOWED. VAPOR AND SPRAY MIST MAY BE HARMFUL IF INHALED . CHRONIC- NO SIGNIFICANT HAZARD FOR MAN. Explanation of Carcinogenicity:NONE Effects of Overexposure:REDNESS OF EYES, ITCHING, BURNING SENSATION AND VISUAL DISTURBANCES, SKIN DRYNESS, ITCHING, CRACKING, BURNING, REDNESS AND SWELLING, IRRITATION OF EYES, SKIN AND RESPIRATORY TRACT Medical Cond Aggravated by Exposure:NOT RELEVANT ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. INHALED: REMOVE TO FRESH AIR. PROVIDE OXYGEN IF NEEDED. EYES: FLUSH WITH WATER FOR 15 MINUTES. KEEP EYELIDS OPEN. SKIN: WASH WITH SOAP & WATER. INGESTION: DO NOT INDUCE VOMITING IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. CALL PHYSICIAN IMMEDIATELY. HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:120F,49C Lower Limits:0.7 Extinguishing Media:USE NATIONAL FIRE PROTECTION (NFP) CLASS B EXTINGUISHERS (CARBON DIOXIDE, UNIVERSL AQ. FILM FORMING FOAM/DRY CHEMICAL). Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. TOXIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY FLAME OR HOT SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE RESPIRATORY PROTECTION & PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL. TRANSFER TO SECURE CONTAINERS. WHERE NECESSARY, COLLECT USING NON-FLAMMABLE ABSORBENT SUCH AS SAND/VERMICULITE. ELIMINATE ANY SOURCES OF IGNITION. VENTILATE AREA Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND APPROVED FOR STORAGE OF NFPA CLASS II COMBUSTIBLE LIQUIDS. Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF A FEW INCHES. IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT(S). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH APPROVED RESPIRATORS. RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION OF CONTAMINANT IN AIR & IN ACCO RDANCE WITH OSHA (29 CFR 1910.134). Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, INDUSTRIAL-TYPE WORK CLOTHING, APRON AND BARRIER CREAM FOR EXPOSED SKIN Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:212F - 468F Vapor Pres:<1 Vapor Density:>1 Spec Gravity:1.1 - 1.3 Evaporation Rate & Reference:<13 (BUTYL ACETATE=100) Solubility in Water:0.0 % Appearance and Odor:VISCOUS LIQUID WITH SOLVENT ODOR Percent Volatiles by Volume:<55 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, STRONG BASES Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF ALUMINUM, SILICA AND CALCIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED, LABELED, TRANSPORTED, & DISPOSED OR RECLAIMED IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. EMPTY CONTAINERS SHOULD BE REC YCLED OR DISPOSED OF THROUGH AN APPROVED FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7 STAR ACRYLIC FLAT LATEX HOUSE PAINT, 103A133 CAGE:ACEHA CAGE:ACEHA ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 24.9% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:NEPHELINE SYENITE CAS:37244-96-5 Fraction by Wt: 28.8% OSHA PEL:N/K ACGIH TLV:5 MG/CUM (MFR) Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH; (DIATOMACEOUS SILICA) CAS:61790-53-2 RTECS #:VV7311000 Fraction by Wt: 2.3% OSHA PEL:20 MPPCF; Z-3 ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA GEL; (AMORPHOUS SILICA) CAS:112945-52-5 RTECS #:VV7310000 Fraction by Wt: 1.2% OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 2.3% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:IRON (III) OXIDE; (IRON OXIDE) CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 6.0% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG(FE)/M3 FUME, B2 Ingred Name:HYDRATED IRON OXIDE CAS:20344-49-4 Fraction by Wt: 3.9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIA (SARA 302/313) (CERCLA) CAS:7664-41-7 RTECS #:BO0875000 Fraction by Wt: <0.1% OSHA PEL:50 PPM ACGIH TLV:25 PPM/35 STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ALUMINUM HYDROXIDE CAS:21645-51-2 RTECS #:BD0940000 Fraction by Wt: 0.9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PALYGORSKITE; (MAGNESIUM ALUMINUM SILICATE) CAS:12174-11-7 RTECS #:RT6400000 Fraction by Wt: 0.3% OSHA PEL:15 MG/M3 (MFR) ACGIH TLV:10 MD/M3 (MFR) Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT REFINED (SEVERE) HEAVY PARAFFINIC; (ALIPHATIC PETROLEUM DISTILLATE) CAS:64741-88-4 RTECS #:PY8040501 Fraction by Wt: 0.5% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC. IRRITANT TO UPPER RESPIRATORY SYSTEM. LIGHTHEADEDNESS AND STAGGERED GAIT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:CHRONIC PROBLEMS WITH RESPIRATORY SYSTEM MAY BE AGGRAVATED BY EXPOSURE TO VAPORS. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH FROM SKIN WITH SOAP & WATER. EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL AID. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:199F,93C Extinguishing Media:NON-COMBUSTIBLE. FOR DRY SOLIDS USE WATER, FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO EXTREME HEAT MAY RUPTURE DUE TO PRESSURE BUILD-UP. CONTENTS MAY SPATTER IF TEMPERATURE EXCEEDS 212F. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DOL STORAGE CATEGORY 3B. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DEVICE APPROVED BY NIOSH/MSHA. Ventilation:MECHANICAL (GENERAL) ACCEPTABLE. LOCAL EXHAUST PREFERABLE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:AVOID BREATHING VAPOR OR SPRAY MIST. AVOID CONTACT WITH SKIN OR EYES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Vapor Density:HVR/AIR Spec Gravity:1.26 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INSOLUBLE Appearance and Odor:COLORED PIGMENTED LIQUID WITH SLIGHT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO HAZARDOUS REACTIONS ARE EXPECTED UNDER NORMAL USE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FOSTER 32-90 ASBESTOS REMOVAL SURFACTANT CAGE:9R359 CAGE:0DH19 CAGE:9R359 ============= Composition/Information on Ingredients ============= Ingred Name:WEIGHT PER GALLON IN POUNDS: 8.27 RTECS #:9999999WG Ingred Name:NON-HAZARDOUS FOR INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER FOR 15 MINS. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>210F Extinguishing Media:NON-FLAMMABLE IN LIQUID STATE. USE WATER SPRAY, FOAM, DRY CHEMICAL, OR CO2 ON DRIED PRODUCT. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE EQUIPMENT. WATER SPRAY MAY BE USED TO COOL THE CONTAINERS. Unusual Fire/Explosion Hazard:POSSIBILITY OF PRESSURE BUILD-UP IN CLOSED CONTAINERS WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN & REMOVE W/INERT ABSORBENT. DIKE IF NECESSARY. AFTER CONTAINING, TRANSFER TO CONTAINERS FOR DISPOSAL. KEEP OUT OF SEWERS, WATERSHEDS OR WATER SYSTEMS. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM FREEZING - PRODUCT STABILITY MAY BE AFFECTED. AVOID TEMPERATURE EXTREMES IN STORAGE. Other Precautions:AVOID CONTACT W/EYES & PROLONGED OR REPEATED CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. Ventilation:STANDARD INDUSTRIAL VENTILATION. Other Protective Equipment:EYE WASHES, APPROPRIATE PROTECTIVE CLOTHING Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F pH:8 Appearance and Odor:LIQUID. Percent Volatiles by Volume:3.3/WT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPERATURE EXTREMES Hazardous Decomposition Products:LOW MOLECULAR WEIGHT HYDROCARBONS, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:THIS PRODUCT DOESN'T MEET DEFINITION OF HAZARDOUS WASTE UNDER US EPA HAZARDOUS WASTE REGS. SOLIDIFY & DISPOSE OF IN AN APPROVED INDUSTRIAL LANDFILL IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7224 BLUE 141 G, 8054762 CAGE:DO804 CAGE:DO804 CAGE:38360 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHORIC ACID, TRIBUTYL ESTER; (TRIBUTYL PHOSPHATE) CAS:126-73-8 RTECS #:TC7700000 Fraction by Wt: 20-50% OSHA PEL:5 MG/M3 ACGIH TLV:0.2 PPM; 9293 Ingred Name:HEXAHYDROPHTHALIC ANHYDRIDE CAS:85-42-7 Fraction by Wt: 0-5% Ingred Name:SILANE, 3-(2,3-EPOXYPROPOXY) PROPYLTRIMETHOXY-; (SILANE A-187) CAS:2530-83-8 RTECS #:VV4025000 Fraction by Wt: 0-3% Ingred Name:SPILL PROC: STANDARD: 29 CFR PART 1910.120 HAZARDOUS WASTE OPERATIONS AND EMERGENCY RESPONSE. RTECS #:9999999ZZ Ingred Name:WASTE DISP: RENDER THE RESULTING MATL HAZARDOUS. CONTACT FEDERAL, STATE AND LOCAL AUTHORITIES FOR DISPOSAL INFO. (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: CONSULT 40 CFR PART 261 IDENTIFICATION AND LISTING OF HAZARDOUS WASTE. RTECS #:9999999ZZ Ingred Name:OTHER PREC: AND FOR CONTROLLING THE FIRE/EXPLOSION HAZARD. A QUALIFIED INDEPENDENT TESTING COMPANY CAN DETERMINE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: IF THE EXISTING CONCENTRATIONS ARE WITHIN THE ESTABLISHED RECOMMENDED/PERMISSIBLE EXPOSURE LEVELS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION, INFLAMMATION. SKIN: IRRITATION, DERMATITIS. INHAL: DIZZINESS, LOSS OF CONSCIOUSNESS, IRRITATION, SENSITIZER WITH ASTHMATOID EFFECTS, WHEEZING, COUGHING, SORE THROAT. INGEST: NAUSEA, VOMITING, ABDOMINAL PAIN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR @ LST 15 MIN. CALL A PHYSICIAN IMMED. SKIN: WASH W/SOAP & WATER. LAUNDER CONTAM CLOTHING BEFORE REUSE. GET MED ATTN. INHAL:REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING I S DIFFICULT. BEGIN RESUSCITATION IF BRTHG HAS STOPPED. KEEP PERSON WARM & QUIET. GET MEDICAL ATTN. INGEST: DO NOT INDUCE VOMITING. GET MEDICAL ATTN IMMED. NOTE TO MD: TRIBUTYL PHOSPHATE (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Extinguishing Media:DRY CHEMICAL, CO*2. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND AND MAY BE IGNITED AT DISTANT LOCATIONS. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ABSORB SPILLED MATL WITH VERMICULITE OR FLOOR ABSORBENT. DISPOSE OF CONTAM 4) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CNTNRS OF THESE MATLS MAY BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES WHICH CAN GENERATE VAPORS WITHIN THE FLAMMABLE LIMITS. Other Precautions:FOR FLAMM OR COMBUSTIBLE PRODS FOLLOW STORAGE & HANDLING GUIDELINES PRESENTED IN NFPA 30 FLAMMABLE & COMBUSTIBLE LIQUIDS CODE. THE USE OF A HAZARDOUS CHEMICAL MAY REQUIRE SUPPLEMENTAL VENTILATION FOR THE PROTECTION OF PERSONNEL (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW APPLICABLE OCCUPATIONAL EXPOSURE STANDARDS. ENGINEERING OR ADMINISTRATIVE CONTROLS OR NIOSH/MSHA APPRVD RESPS CAN BE USED TO REDUCE EXPOSURE. ENGINEERING CONTROLS ARE PREFERRED BY OSHA. Ventilation:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW APPLICABLE OCCUPATIONAL EXPOSURE STANDARDS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: POSSESSES ONLY WEAK ANTICHOLINESTERASE ACTIVITY WHICH SHOULD NOT REQUIRE SPECIFIC TREATMENT. LARGE DOSES HAVE BEEN REPORTED TO CAUSE DYSPNEA, WEAKNESS, PULMONARY EDEMA, AND TWITCHING I N RATS. CHRONIC INHALATION OF LARGE DOSES CAN LEAD TO GENERAL POISONING WITH PARALYSIS. ================== Physical/Chemical Properties ================== Vapor Pres:VERY LOW Evaporation Rate & Reference:VERY SLOW Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID OR SEMI-SOLID INK AS COLOR ABOVE, MILD ODOR. Percent Volatiles by Volume:APPROX ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS AND BASES. WATER. Stability Condition to Avoid:HEAT AND FLAME. Hazardous Decomposition Products:CO, CO*2, SILICON OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF THE GENERATOR OF THE WASTE TO DETERMINE, AT THE TIME OF DISPOSAL, WHETHER THE WASTE GENERATED MEETS THE FEDERAL OR STATE HAZAROUS WASTE CRITERIA. USES, TRANSFOR MATIONS, MIXTURES, PROCESSES, ETC. MAY (ING 5)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2000P172 Kit Part:Y Preparer's Name:BARBARA BOROUGHF CAGE:78500 CAGE:78500 ============= Composition/Information on Ingredients ============= Ingred Name:ASBESTOS, CHRYSOTILE CAS:12001-29-5 RTECS #:CI6478500 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.2 FIBERS/CC ACGIH TLV:2 FIBERS/CC; A1;9293 Ingred Name:SILICA, CRYSTALLINE - TRIPOLI CAS:1317-95-9 RTECS #:VV7336000 Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:PHENOLIC RESIN Other REC Limits:NONE RECOMMENDED Ingred Name:WOOD FLOUR Other REC Limits:NONE RECOMMENDED ACGIH TLV:1.0 MG/M3 Ingred Name:IRON, ZINC, ALUMINUM & THEIR OXIDES Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 RDUST ACGIH TLV:10 MG/M3 RDUST Ingred Name:COPPER OXIDE CAS:1317-38-0 RTECS #:GL7900000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1.0 MG/M3 ACGIH TLV:1.0 MG/M3 Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:FLUORIDES AS CRYOLITE CAS:13775-53-6 Other REC Limits:NONE RECOMMENDED OSHA PEL:2.5 MG/M3 (AS F) ACGIH TLV:2.5 MG/M3 (AS F) Ingred Name:RUBBER Other REC Limits:NONE RECOMMENDED Ingred Name:BARIUM COMPOUNDS Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EXPOSURE TO DUSTS OF ASBESTOS, SILICA, TALC, GRAPHITE, CARBON & COAL CAN LEAD TO CHRONIC LUNG DISEASES SUCH AS ASBESTOSIS OR OTHER FORMS OF PNEUMOCONIOSIS. IN SEVERE CASES THESE DISEASES CAN BE FATAL.EXPOSURE TO THESE DUSTS MAY ALSO LEAD TO NONDISABLING CONDITIONS KNOWN AS PLEURAL THICKENING, PLAQUES & CALCIFICATION. Explanation of Carcinogenicity:NTP, IARC AND OSHA HAVE FOUND THAT ASBESTOS CAN CAUSE CANCER IN HUMANS. SMOKING GREATLY INCREASES THE RISK OF CANCER. Effects of Overexposure:SYMPTOMS OF ASBESTOSIS, PNEUMOCONIOSIS, AND LUNG CANCER INCLUDE SHORTNESS OF BREATH, DRY COUGH, FATIGUE ON EXERCISE, CHEST PAINS, CHEST TIGHTNESS, CLUBBING OF FINGERS, AND VAGUE FEELINGS OF SICKNESS. SUCH SYMPTOMS DO NOT USUALLY MANIFEST THEMSELVES UNTIL 15 TO 20 YEARS AFTER FIRST EXPOSURE. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING RESPIRATORY DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE TO AIRBORNE ASBESTOS FIBERS. SMOKERS MAY BE AT INCREASED RISK FROM EXPOSURE TO AIRBORNE ASBESTOS FIBERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. SKIN: WASH EXPOSED AREA WITH SOAP AND WATER. GET MEDICAL ADVICE IF IRRITATION DEVELOPS. EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL ATT ENTION. INGESTION: GET MEDICAL ATTENTION. OTHER: CLOTHING CONTAMINATED WITH ASBESTOS CONTAINING DUST SHOULD BE ISOLATED IN THE WORK AREA UNTIL LAUNDERED. AVOID CONTAMINATION OF OTHER AREAS. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER OR CLASS A, B, OR C EXTINGUISHER. Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE TOXIC. USE A SELF CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES INVOLVING CHEMICAL PRODUCTS. Unusual Fire/Explosion Hazard:NONE KNOWN ================== Accidental Release Measures ================== Spill Release Procedures:ISOLATE BRAKE SERVICING AREAS IF POSSIBLE. USE LOCAL EXHAUST VENTILATION AT ALL TIMES. CLEAN BRAKE PARTS WITH A VACUUM WITH HEPA FILTER. WIPE WITH DAMP RAGS TO REMOVE ASBESTOS CONTAINING RESIDUE. DISP OSE OF USED RAGS WHILE STILL WET IN SEALED BAGS. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTAINS ASBESTOS. DO NOT CLEAN PARTS WITH COMPRESSED AIR. AVOID SCRAPING OR SCRATCHING BRAKE LININGS OR OTHERWISE CREATING DUST DURING ASSEMBLY. Other Precautions:MOLDED ASBESTOS COMPOSITION FRICTION LININGS DO NOT PRESENT A HAZARD. ONLY WHEN THE PARTS ARE PLACED IN SERVICE ARE THE ASBESTOS FIBERS RELEASED. DO NOT BREATH AIRBORN ASBESTOS DUST. ISOLATE AND LAUND ER CONTAMINATED CLOTHING BEFORE REUSE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EXPOSURE TO AIRBORNE ASBESTOS SHALL NOT EXCEED 0.2 F/CC TWA. IF EXPOSURE IS LESS THAN 50 TIMES THE PEL, USE A FULL FACE-PIECE NIOSH/MSHA APPROVED RESPIRATORS WITH A HEPA FILTER FOR ASBESTOS. MAKE SELE CTIONS I/A/W 29CFR1910.1001 & 1910.1101. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. LOCAL EXHAUST MAY BE REQUIRED FOR ENCLOSED OPERATIONS. Other Protective Equipment:HATS, FOOT COVERINGS, COVERALLS OR OTHER WHOLE BODY CLOTHING. CHANGE ROOMS WITH SEPARATE LOCKERS FOR WORK CLOTHES. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. DO NOT WASH DUST LADEN CLOTHING WITH OTHER ITEMS. Supplemental Safety and Health WORKERS EXPOSED TO ASBESTOS SHALL BE TRAINED ANNUALLY AS TO ITS POTENTIAL HAZARDS AND THE MEANS OF REDUCING THOSE HAZARDS. WORKER'S ASBESTOS EXPOSURE SHALL BE MONITORED EVERY SIX MONTHS IF IT MAY REAS ONABLY BE EXPECTED TO BE AT OR ABOVE 0.1 F/CC. DO NOT TAKE HOME ANY PROTECTIVE CLOTHING OR EQUIPMENT. ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:1.6-3.0 Solubility in Water:NEGLIGIBLE Appearance and Odor:SOLID, LIGHT TAN TO DARK GRAY IN COLOR. NO CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:AIRBORNE ASBESTOS DUST. INCOMPLETE COMBUSTION MAY CREATE TOXIC FUMES ==================== Disposal Considerations ==================== Waste Disposal Methods:HANDLE USED PARTS TO AVOID CREATING AIRBORNE DUST. PLACE USED PARTS IN AN AIRTIGHT CONTAINER, LABEL AND DISPOSE IN A LICENSED LANDFILL IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAL-EXII; CS511; ACC41002. CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:FORMIC ACID (SARA III) CAS:64-18-6 RTECS #:LQ4900000 Fraction by Wt: 12.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 PPM ACGIH TLV:5 PPM/10 STEL; 9394 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:FORMALDEHYDE (SARA III) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 3.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM; A2; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 1.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:S,200PPM ACGIH TLV:S,200PPM/250STEL; 94 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 84.0% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:FORMIC ACID:30PPM IMMED DANGEROUS TO LIFE/HEALTH.CORR-INHAL/SKIN/EYE/INGEST.TOXIC BY INHAL.MODERATELY TOXIC BY INGEST.FORMALDEHYDE:SENSITIZER,CORR-INHAL/SKIN/EYE/INGEST.HIGHLY TOXIC BY INHAL.TOXIC BY DERMAL ABSORPTION & INGEST.METHANOL:SLIGHTLY TOXIC BY DERMAL ABSORPTION & INGEST.RELATIVELY NON-TOXIC BY INHAL. Explanation of Carcinogenicity:CONTAINS FORMALDEHYDE:ANTICIPATED HYMAN CARCINOGEN PER NTP;IARC GROUP-2A. Effects of Overexposure:NARCOTIC,THROAT IRRIT/DISCOM,LI-HEAD,NAUS,COUGH,RHINITIS,PULM EDEMA,SHOCK.BREATH DIFF,BURNING SENS IN NOSE/THROAT,SKIN REDNESS/PAIN.TISSUE DAMAGE,RESP TRACT INJ(PNEUITIS)SNEEZING,WHEEZ,TRACHEITIS,CHES T CONSTRICTIN,BRON,HEAD,WEAK,THRIST.OPPRESSION IN CHEST,TINNITUS,UNSTEADY GAIT,TWITCHING,COLIC,CNS EFFECTS,EYE LAC,CONJ Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXITING SKIN OR EYE DISORDERS, OR IMPAIRED PULM, RENAL, LIVER FUNCTION. PERSONS W/ASTHMA, CHRONIC SKIN DISEASE OR PRE-EXISITING LUNG DISEASE. PERSONS W/KIDNEY, EYE, SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR.STOP BREATH GIVE ART RESP/OXY.TREAT SYMPTOMATICALLY/SUPPORTIVELY. SKIN:REMOVE CONTAMIN CLOTH/SLOES IMMED.WASH W/SOAP OR MILD DETERGENT & LG AMTS OF WATER @LEAST 15-20MINS.CHE M BURNS:COVER W/STERILE DRY DRESS.BANDAGE SECURELY. EYE:WASH IMMED W/LG AMTS OF WATER LIFTING EYELIDS @LEAST 1-20MINS.CONT W/NORMAL SALINE TIL PH=NORMAL(30-60MINS).COVER W/STERILE BANDAGES. (SUPPLEME) ===================== Fire Fighting Measures ===================== Extinguishing Media:DERY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM.LG FIRES:USE WATER SPRAY,FOG OR REGULAR FOAM. Fire Fighting Procedures:MOVE CNTNR FROM FIRE W/O RIKS.COOL SIDES OF CNTNRS EXPO TO FIRE W/WATER TIL FIRE WELL OUT.STAY AWAY FROM ENDS OF TNKS.DO NOT USE WATER DIRECTLY ON MATL IF LG FI Unusual Fire/Explosion Hazard:AVOID BREATHING CORROSIVE VAPOPRS.KEEP UPWIND.NEGLIGIBLE FIRE HAZ WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILL.STOP LEAK W/O RISK.SM SPILLS:TAKE UP W/SAND/OTHER ABSORBENT MATL.PLACE INTO CNTNR.DRY SPILLS:SHOVEL INTO MATL & COVER.LG:DIKE.KEEP UNNECASSARY PEOPLE AWAY.ISOLATE/DENY ENTRY. Neutralizing Agent:NONE SPECIFIED BY MFG. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSEVER ALL FED/STATE/LOC REGS WHEN STORING SUBSTANCE.FOR ASSISTANCE CALL DISTRICT DIR OF EPA. Other Precautions:SARA SEC 302 REQUIRES EA FACILITY WHERE EXT HAZ SUB IS PRESENT IN QUANT EQUAL TO OR GREATER THAN TPQ ESTABLISHED FOR SUB NOTIFY STATE EMERG RESP COMM.SARA SEC 303 REQUIRES THESE FACILITIES TO PARTICIP ATE IN LOC EMERG RESP PLAN(40CFR355.30). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN WORKPLACE,SPECIFIC OPERATION,MUST NOT EXCEED WORKING LIMITS OF RESP & MUST BE JOINTLY APPROVED BY NIOSH/MSHA. Ventilation:PROVIDE LOCAL EXHAUST/PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHED EXPO LIMITS. Other Protective Equipment:APPROOPRITE PROT IMPERVIOUS CLOTH/EQPMT.EYEWASH FOUNTAIN & QUICK DRENCH SHOWER IMMED WORK AREA FOR EMERGENCY USE. Work Hygienic Practices:WASH HANDS AFTER HANDLING. LAUNDER CONTAMIN CLOTH PRIOR TO REUSE. Supplemental Safety and Health FIREFIGHTING:USE WATERSPRAY TO ABSORB CORR VAP. 1STADI:INGEST:DO NOT USE GASTRIC LAVAGE OR EMESIS.DILUTE (100 FOLD TO RENDER HARMLESS TO TISSUES)IMMED W/LG QUANT OF WATER OR MILK.IF VOMIT PERSISTS ADM INISTER FLUIDS REPEATEDLY.IN ALL CASES GET MED ATTN IMMED. ================== Physical/Chemical Properties ================== HCC:C2 pH:2.0 Solubility in Water:COMPLETE Appearance and Odor:SOLUTION ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BISULFIEDS,IODINE,IRON PREP,POTASSIUM PERMANGANATE,AG SALTS,AL,METALS,STRONG AICDS,STRONG OXIDIZERS. Stability Condition to Avoid:MAY BURN BUT DOESN'T IGN READILY.FLAMM,POISONOUS GASES MAY ACCUMULATE IN TNKS/HOPPER CARS.MAY IGN COMB(WOOD,PAPER,ETC). Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/STANDARDS APPLICABLE TO GENERATORS OF HAZ WASTE 40CFR262.EPA HAZ WASTE NO:D002. 100LBS=RQ.OBSERVE ALLLOCAL, STATE AND FEDERAL REGS WHEN DISPOSING SUBSTANCE.FOR ASSISTA NCE CALL DISTRICT DIR OF EPA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLAZA CAGE:NO353 CAGE:NO353 CAGE:32204 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLIC POLYMER (NON HAZARDOUS) Fraction by Wt: 10-20% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL ETHYL ETHER (SARA III)(LD50 = 6500 MG/KG ORAL RAT; 4000 MG/KG DERMAL RABBIT) CAS:111-90-0 RTECS #:KK8750000 Fraction by Wt: 2-4% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYLENE GLYCOL 2-ETHYLHEXYL ETHER (SARA 313)(LD50 4674MG/KG ORAL MALE RAT) CAS:1559-35-9 RTECS #:KK9625000 Fraction by Wt: 1-3% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER (NON HAZARDOUS) CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-85% Other REC Limits:NONE RECOMMENDED Ingred Name:WAXES (NON HAZARDOUS) Fraction by Wt: 2-4% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC = GLYCOL ETHER RTECS #:9999999VO Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:ACUTE ORAL LD50 >5000MG/KG RATS ESTIMATE Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO ======================= First Aid Measures ======================= First Aid:EYES: RINSE W/PLENTY OF WATER. SKIN: WASH CONTAMINATED AREA W/WATER & SOAP. INHALATION: MOVE TO FRESH AIR. INGESTION: DRINK 1-2 GLASSES OF WATER OR MILK. ===================== Fire Fighting Measures ===================== Flash Point:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. Unusual Fire/Explosion Hazard:NO SPECIAL HAZARDS KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH OIL-DRI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP AND CONTAINERIZE. CONTAINS AMMONIA. DON'T LET SPILLED MAT'L INTO WATER COURSE. MAY BE TOXIC TO AQUATIC LIFE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY PLACE W/ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM CHILDREN. Other Precautions:USE AS DIRECTED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NO SPECIAL REQUIREMENTS UNDER RECOMMENDED LABEL USE DIRECTIONS. Ventilation:GENERAL ROOM VENTILATION ADEQUATE. Other Protective Equipment:NO SPECIAL REQUIREMENTS. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Decomp Temp:Decomp Text:NOT AVAIL Vapor Pres:NOT AVAIL Spec Gravity:1.03 (WATER=1) pH:* Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:COMPLETE Appearance and Odor:OPAQUE, OFF-WHITE SOLUTION WITH MILD ODOR Percent Volatiles by Volume:NA ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:NO SPECIAL REQUIREMENTS Hazardous Decomposition Products:WHEN EXPOSED TO FIRE, PRODUCES NORMAL PRODUCTS OF COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL METHOD. OBSERVE ALL APPLICABLE FEDERAL, PROVINCIAL, STATE, AND LOCAL/MUNICIPAL ORDINANCES REGARDING DISPOSAL OF NON-HAZARDOUS MATERIAL.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:DRY POWDER TONER CAGE:FGRAP CAGE:0K1B9 CAGE:FGRAP ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLATE COPOLYMER CAS:25153-46-2 Fraction by Wt: 40-50% Other REC Limits:NONE SPECIFIED Ingred Name:IRON OXIDE CAS:1317-61-9 Fraction by Wt: 25-45% Other REC Limits:NONE SPECIFIED Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: <10% Other REC Limits:2.5 MG/M3 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9192 Ingred Name:DRY POWDERED TONER PRODUCT.(THIS PRODUCT IS CONSIDERED A NUISANCE DUST WITH THE FOLLOWING.) RTECS #:9999999ZZ Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:10MG/M3 T-D/5MG/M3 R ACGIH TLV:10MG/M3 T-D/5MG/M3 R ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE AND RESPIRATORY IRRITATION IN PROLONGED EXPOSURE TO EXCESSIVE DUST. Effects of Overexposure:RESPIRATORY IRRITATION. Medical Cond Aggravated by Exposure:RESPIRATORY AILMENTS CAN BE AGGRAVATED BY EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. SKIN: WASH WITH MILD SOAP AND WATER. INHALATION: MOVE TO FRESH AIR. INGESTION: DRINK SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:AVOID BREATHING SMOKE. Unusual Fire/Explosion Hazard:EXCESS DUST IN AIR CAN FORM EXPLOSIVE MIXTURE. COMBUSTABLE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT SPILL WITH VACUUM OR BROOM. AVOID CREATING EXCESS DUST. USE APPROVED DUST MASK. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED AREA. AVOID BREATHING EXCESS DUST. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE OSHA APPROVED NUISANCE DUST MASK WHEN NEEDED. Ventilation:VENTILATE WORK AREA. Other Protective Equipment:NONE NORMALLY REQUIRED. Work Hygienic Practices:AVOID PROLONGED BREATHING OF DUST. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:>248F,>120C Spec Gravity:1.5-1.7 Solubility in Water:NOT SOLUBLE Appearance and Odor:FINE BLACK POWDER. RESIN ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, CARBON. PRODUCTS OF OMBUSTION ARE TOXIC. AVOID SMOKE INHALATION. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT INCINERATE. DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS CONCERNING FINE NUISANCE DUST CONTAINMENT.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:2-METHYLPYRAZINE, 151673 Preparer's Name:R.L. CAGE:IO030 CAGE:30060 CAGE:IO030 ============= Composition/Information on Ingredients ============= Ingred Name:PYRAZINE, 2-METHYL-; (2-METHYLPYRAZINE) CAS:109-08-0 RTECS #:UQ3675000 OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 1800 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATELY TOXIC BY INGESTION & INTRAPERITONEAL ROUTES. MUTAGENIC DATA. PROLONGED OR EXCESSIVE EXPOSURE MAY CAUSE IRRITATION IN SOME INDIVIDUALS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAM CLTHG, RINSE LIBERALLY W/SOAP & WATER FOR CONSIDERABLE PERIOD. CALL MD. INGEST:RINSE MOUTH SEVERAL TIMES W/WATER, DO NOT SWALLOW. CALL MD OR TAKE PATIENT TO A HOSPITAL. EYES:RINSE L IBERALLY W/WATER FOR AT LEAST 15 MINUTES. CALL MD OR TAKE PATIENT TO A HOSPITAL. INHAL:TAKE PATIENT INTO FRESH AIR & ALLOW TO REST. CALL MD OR TAKE PATIENT TO A HOSPITAL. ===================== Fire Fighting Measures ===================== Flash Point:122F,50C Extinguishing Media:CO*2, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EXPLOSIVE MIXTURE IN AIR. EXPLOSION! VAPORS EXPOSED TO HEAT OR FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB LIQUID IN DRY SAND, DIATONITE, VERMICULITE, ETC, SHOVEL MIXTURE INTO PLASTIC BAGS & REMOVE TO CENTRAL DEPOT FOR CHEMICAL WASTE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE: ROOM TEMPERATURE. FLAMMABLE, IRRITANT. Other Precautions:SWEEP INTO SUITABLE CONTAINER FOR DISPOSAL. ALWAYS ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST REQUIRED. ALWAYS USE A HOOD. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>275F,>135C Melt/Freeze Pt:M.P/F.P Text:-20F,-29C Spec Gravity:1.022 Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:HEAT, FLAME. Hazardous Decomposition Products:TOXIC FUMES OF NO*X, CO, CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR LANDFILL AS COMPLIES W/FEDERAL, STATE & LOCAL LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:6252A ALKALINITY ADDITIVE Kit Part:Y Preparer's Name:J.P.J. QC DEPARTMENT CAGE:D9808 CAGE:0BYN5 CAGE:D9808 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 10% OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRIETHYLENE GLYCOL CAS:112-27-6 RTECS #:YE4550000 Fraction by Wt: 40% Ingred Name:ALKYL GLUCOSIDE SURFACTANT CAS:68515-73-1 Fraction by Wt: 5% Ingred Name:N-BUTYL-P-TOLUENE SULFONAMIDE (MFR STATES THIS INGREDIENT IS NON-HAZARDOUS) CAS:1907-65-9 Ingred Name:N-ETHYL-P-TOLUENE SULFONAMIDE (MFR STATES THIS INGREDIENT IS NOT HAZARDOUS) CAS:80-39-7 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE Effects of Overexposure:EYES:MODERATE TO SEVERE IRRITATION;SKIN:MODERATE TO SEVERE IRRITATION,DRYING,DEFATTING;INHALATION:MODERATE IRRITATION,DIZZINESS,HEADACHE.MIST:SEVERE RESPIRATORY IRRITATION,NAUSEA;INGESTION:SEVERE IRRI TATION TO GASTROINTESTINAL TRACT,NAUSEA. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER.IF IRRITATION PERSISTS,SEE DOCTOR;SKIN:REMOVE CLOTHING & SHOES.FLUSH WITH PLENTY OF WATER.WASH WITH SOAP & WATER.RINSE.IF IRRITATION PERSISTS,SEE DOCTOR;INHALATION:REMO VE TO FRESH AIR.GIVE OXYGEN/CPR IF NEEDED,SEE DOCTOR;INGESTION:DO NOT INDUCE VOMIT.GIVE LARGE VOLUMES OF MILK OR WATER.SEE DOCTOR.NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>300F(>149C) Extinguishing Media:FOAM,CO*2,DRY CHEMICAL Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL.STOP LEAK.VENTILATE.EVACUATE PERSONNEL.PUMP LIQUID INTO APPROVED DRUMS FOR DISPOSAL.ABSORB REMAINING LIQUID WITH INERT ABSORBENT & PLACE IN APPROVED DRUMS FOR DISPOSAL.WASH AREA WITH WAT ER.PLACE WASHING IN APPROVED DRUMS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PROTECTED AREA AWAY FROM STRONG OXIDIZING AGENTS. Other Precautions:AVOID SPLASHING.RELIEVE PRESSURE.COVER OPENINGS TO AVOID SPURTING.CLEAN INTERIOR & EXTERIOR BY FLUSHING WITH SOLVENT.COLLECT FLUSHINGS FOR DISPOSAL.USE PROTECTIVE EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED USE NIOSH-APPROVED SCBA OR AIR LINE MASK WITH FULL FACE PIECE.FOR LIMITED EXPOSURE WITH GOOD VENTILATION USE FULL FACE MASK WITH ORGANIC VAPOR CARTRIDGE.DO NOT USE RESPIRATOR WHERE DANGER OF OXYGEN DEFICIENCY EXISTS. Ventilation:MECHANICAL (GENERAL) VENTILATION. Other Protective Equipment:APRON,BOOTS Work Hygienic Practices:WASH HANDS & FACE WITH SOAP & WATER BEFORE SMOKING,EATING.REMOVE & LAUNDER CONTAMINATED CLOTHING.DO NOT LAUNDER @ HOME. Supplemental Safety and Health THIS IS PART A OF A 2-PART KIT.FOR PART B,SEE PNI B,SAME NSN. KEY1:B1. ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:=315.6C, 600.F Vapor Pres:0.01 Vapor Density:>1 Spec Gravity:1.24 pH:13 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:DARK AMBER VISCOUS LIQUID.SLIGHT MUSTY ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS Stability Condition to Avoid:HEAT,IGNITION SOURCES Hazardous Decomposition Products:CO,CO*2,OTHER TOXIC VOLATILE ORGANIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:TRANSFER PURE LIQUID TO RECLAIMING CENTER FOR RECYCLING OR REUSE.TRANSFER CONTAMINATED LIQUID TO LICENSED WASTE TREATMENT OR DISPOSAL SITE FOR DISPOSIOG UNDER APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:559013 H-W HIGH ALUMINA CASTABLE Preparer's Name:S.W. THROWER CAGE:JO290 CAGE:73064 CAGE:JO290 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 2-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST9596 Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (SARA 313) (NON-FIBROUS) CAS:1344-28-1 RTECS #:BD1200000 Fraction by Wt: 60-62% Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9596 Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 Fraction by Wt: 3-4% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:LIME:IRRITANT TO SKIN/EYES/MUC MEMBRANES.ALUMINA:IRRITANT TO SKIN/EYE/MUCOUS MEMBRANES.CRYSTALINE SILICA:DELAYED LUNG FIBROSIS-SILICOSIS,IRRITANT TO SKIN/EYE/MUCOUS MEMBRANES. Explanation of Carcinogenicity:PER MSDS:CRYSTALLINE SILICA-IARC GP 1.SUFFI EVIDENCE IN HUMANS FOR CARC;NTP REASONABLY ANTICIPATED CARC. Effects of Overexposure:IRRIT SKIN/EYE/MUCOUS MEMBRANES, DELAYED LUNG FIBROSIS=SILICOSIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:IRRITANTS:WASH FROM SKIN OR FLUSH FROM EYES USING LARGE AMTS OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:WILL NOT BURN Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NP Upper Limits:NP Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. Unusual Fire/Explosion Hazard:UNLESS OTHERWISE NOTED NO FIRE HAZARD. PRODUCT IS A REFRACTORY AND WILL NOT BURN. ================== Accidental Release Measures ================== Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. SEE WASTE DISPOSAL METHOD SECTION OF MSDS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE CRITERIA USE APPROVED RESPIRATORY PROTECTION EQPMT APPROPRIATE TO FORM AND CONCENTRATION OF AIR CONTAMINANTS. Ventilation:LOC EXHAU VENTI SHOULD BE PROVIDED IF ROUTINE OPERATION GENERATES DUST IN EXCESS OF ALLOWABLE LIMITS. Other Protective Equipment:METATARSEL SAFETY SHOES. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NP Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:NP Spec Gravity:2.20 pH:N/DETR Viscosity:NP Evaporation Rate & Reference:NP Solubility in Water:SLIGHT Appearance and Odor:LIGHT TAN TO GRAY COLOR, EARTHY ODOR, GRANULAR FORM Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:STORE IN DRY LOCATION PRIOR TO USE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MOST REFRACTORY PROD MAY BE LANDFILLED.HOWEVER SINCE YOUR APPLICATION OF THIS PROD MAY CHANGE ITS CHEM CHARACTERISTICS & SINCE DISPO PROCEDURES MAY VARY W/LOCALE & ARE SUBJ TO CHANGE YOU SHOULD CONSUL T GOVT AUTHORITY HAVING JURISDICTION FOR DISPO INF ======================================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CONOCO FLEET MOTOR OIL, GRADE 40 CAGE:KO523 CAGE:58326 CAGE:KO523 ============= Composition/Information on Ingredients ============= Ingred Name:LUBRICATING OIL ===================== Hazards Identification ===================== Effects of Overexposure:EXCESS INH OF MISTS/VAPORS: PULMONARY DISORDERS. MAY CAUSE EYE IRRIT. SKIN IRRIT POSS. ======================= First Aid Measures ======================= First Aid:EYE: IMMED FLUSH W/WATER AT LEAST 15 MIN, CALL MD. SKIN: WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLOTHING & WASH BEFORE REUSE. GROSSLY CONTAM LEATHER SHOES SHOULD BE DISCARDED. INGEST: LG AMTS, INDUCE VOMIT, CALL MD. INH: CALL MD! ===================== Fire Fighting Measures ===================== Flash Point:390-440 COC Extinguishing Media:WATER SPRAY, FOAM, CO*2, DRY CHEM Fire Fighting Procedures:USE PROPER PROT EQUIP INCL SELF-CNTND BRTHNG APPARATUS Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP PROMPTLY BY ABSORPTION IN CLAY OR EARTH ======================Handling and Storage ====================== Handling and Storage Precautions:MAY BE STORED OUTDOORS OR INDOORS AWAY FROM FURNACE OR OTHER HEATING EQUIP Other Precautions:FOLLOW NEC PRECAUTIONS IAW NFPA CODE 30-1969 FOR COMBUSTIBLE LIQ, CLASS IIIB ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQ Ventilation:MECH, NORM SHOP VENT Supplemental Safety and Health VAP PRESS: NIL. SPEC GRAV: 0.86-0.89. MFR STATES PROD NOT CONSIDERED TO BE TOXIC ORALLY OR DERMALLY. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:600F INIT Evaporation Rate & Reference:NIL Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR BROWN VISCOUS LIQ, SLIGHT ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATLS, HEAT, FLAME Hazardous Decomposition Products:NORM COMBUST: CO*2, WATER VAPOR. INCOMP COMBUST: CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:MFR SUGGESTS CONTROLLED INCINERATION, STORE FOR PROFESSIONAL REMOVAL & DISPOSAL. AVOID DRAINAGE INTO SEWER.DISPOSE IAW LOCAL, STATE, FED REG.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:OM00173744 JOHNSON WHITE ACRYLIC CAGE:59581 CAGE:59581 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *96-2* CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 15% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM, SKIN EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-2* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL CARCINOGEN, IARC GROUP 3)*96-2* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 10% OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:ETHYL BENZENE *96-2* CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 5% Other REC Limits:100 PPM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLENE GLYCOL PROPYL ETHER, EKTASOLVE EP, 2-PROPOXYETHANOL CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: 5% OSHA PEL:35 PPM Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *96-2* CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 0.1% Other REC Limits:200 PPM OSHA PEL:200 PPM ACGIH TLV:200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 30% OSHA PEL:750 PPM ACGIH TLV:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE (DIMETHYLMETHANE)*96-2* CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 20% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:BUTANE, N-BUTANE CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 15% Other REC Limits:800 PPM OSHA PEL:800 PPM ACGIH TLV:800 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION, ALLERGIC REACTIONS ARE POSSIBLE. SENSITIZATION & DERMATITIS. INHALATION: MAY BE HARMFUL. INGESTION: HARMFUL/FATAL. IRRITATING TO MOUTH, THROAT & STOMACH. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, PAIN, TEARING, REDDENING, SWELLING, STINGING SENSATION, DEFATTING, DRYNESS, RASH, HEADACHES, DIZZINESS, NAUSEA, DECREASED BLOOD PRESSURE, CHANGES IN HEART RATE, CYANOSIS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. RESCUERS SHOULD WEAR APPROPRIATE PROTECTIVE GEAR. KEEP WARM & QUIET. I NGESTION: DON'T INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER/MILK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:-4F Lower Limits:1 Upper Limits:12.8 Extinguishing Media:WATER FOG, DRY CHEMICAL, CO2, ALCOHOL FOAM, FOAM. Fire Fighting Procedures:AS IN ANY FIRE, WEAR SCBA PRESSURE DEMAND (MSHA/NIOSH APPROVED/EQUIVALENT) & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE W/AIR. CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT/FIRE. MAY CAUSE FLASH FIRE/EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL THEN PLACE IN A CHEMICAL WASTE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. DON'T STORE >120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR W/AN ORGANIC VAPOR CARTRIDGE/CANISTER MAY BE PERMISSIBLE WHERE AIRBORNE EXCEEDS EXPOSURE LIMITS. AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRE SSURE AIR SUPPLIED RESPIRATOR. Ventilation:LOCAL EXHAUST TO CONTROL AIR CONTAMINANTS W/IN THEIR TLVS DURING THE USE OF PRODUCT. Other Protective Equipment:FACE SHIELD, CHEMICAL SUIT, RUBBER BOOTS, PROTECTIVE CLOTHING, ACID SUIT & BOOTS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-44F-308F Vapor Pres:40 Vapor Density:>1 Spec Gravity:0.766 Evaporation Rate & Reference:FASTER THAN ETHER Solubility in Water:SLIGHT Appearance and Odor:LIQUID W/AROMATIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:TEMPS >120F, SPARKS, OPEN FLAMES Hazardous Decomposition Products:HEATED: CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T PUNCTURE, INCINERATE/COMPACT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WESTCORT CREAM 0.2% 15 GRAMS CAGE:GO533 CAGE:4T649 CAGE:GO533 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCORTISONE VALERATE CAS:57524-89-7 Fraction by Wt: 0.2% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >1% Ingred Name:PETROLATUM, GREASE *96-4* CAS:8009-03-8 Fraction by Wt: >1% OSHA PEL:5 MG/CUM ACGIH TLV:10 MG/CUM Ingred Name:1-OCTADECANOL, STEARYL ALCOHOL CAS:112-92-5 RTECS #:RG2010000 Fraction by Wt: >1% Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL) CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: >1% Ingred Name:AMPHOTERIC-9 Fraction by Wt: <1% Ingred Name:ACRYLIC ACID POLYMERS, CARBOPOL 940, CARBOPOL 934P, CARBOPOL 934, CARBOPOL 960 & 961, CARBOPOL 941 (IARC GROUP 3) *96-4* CAS:9003-01-4 RTECS #:AT4680000 Fraction by Wt: <1% Ingred Name:SODIUM PHOSPHATE CAS:7682-85-6 RTECS #:WC4600000 Fraction by Wt: <1% Ingred Name:SORBIC ACID CAS:110-44-1 RTECS #:WG2100000 Fraction by Wt: <1% Ingred Name:SODIUM LAURYL SULFATE, SODIUM LAURETH SULFATE *96-4* CAS:151-21-3 RTECS #:WT1050000 Fraction by Wt: <1% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: NERVOUS SYSTEM EFFECTS & ABSORPTION. SKIN: TOXIC, IRRITATION, SENSITIZATION & DERMATITIS. HYDROCORTISONE VALERATE IS A POTENT ANTI-INFLAMMATORY DRUG CLASSIFIED AS A GLUCOCORTICOID, HIGHLY P OTENT & RANGES FROM 0.0001 MG/CUM-0.005MG/CUM. MONITOR FOR GLUCOSE TOLERANCE, TUBERCULOSIS/PEPTIC ULCER DISEASE. Explanation of Carcinogenicity:NONE Effects of Overexposure:HEADACHE/DIZZINESS/FATIGUE/FAINTNESS/BURNING/IRRITATIO N/DRYNESS/CRACKING/TIGHTNESS/THINNING OF SKIN/ACNEIFORM ERRUPTION/ERYTHEMA/FOLLICULITIS/HYPERTRICHOSIS/REDNESS/TEARING/SWEL LING/PAIN/MUSCLE WEAKNE SS/VERTIGO/HYPERGLYCEMIA/PEPTIC ULCER/CATARACT DEVELOPMENT/MENSTRUAL DIFFICULTIES/FLUID & ELECTROLYTE DISTURBANCES. Medical Cond Aggravated by Exposure:SYSTEMIC FUNGAL INFECTIONS, TUBERCULOSIS, PEPTIC ULCERS, DIABETES MELLITUS, CERTAIN PSYCHIATRIC CONDITIONS, DIABETES, PEPTIC ULCER DISEASE, ACTIVE TUBERCULOSIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. SKIN/EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO2, FOAM/DRY CHEMICAL. Fire Fighting Procedures:WEAR SCBA, FLAME & CHEMICAL RESISTANT REMOVE UNNEEDED MATERIAL & COOL CONTAINERS W/WATER. ================== Accidental Release Measures ================== Spill Release Procedures:WEARING SUITABLE PROTECTIVE CLOTHING, ABSORB CREAM ONTO ABSORBENT MATERIAL & PLACE INTO A CONTAINER FOR CLOTHING/EQUIPMENT MAY BE NEEDED. VENT ILATE & DECONTAMINATE AFTER MATERIAL ISPICKED UP. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE PRODUCT AT ROOM TEMP & PROTECT FROM LIGHT. Other Precautions:AVOID SKIN & EYE CONTACT. AVOID TEMP EXTREMES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN CONTROLS AREN'T SUFFICIENT TO CONTROL EXPOSURE, WEAR NIOSH APPROVED RESPIRATORY PROTECTION TO CONTROL EXPOSURE & SCBA. Ventilation:LOCAL EXHAUST: TO KEEP AIRBORNE CONCENTRATION LOW BY ENCLOSURE. Other Protective Equipment:PROTECTIVE COVERALLS FOR SPLASHING/SPRAYING OF CREAMS. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER HANDLING & BEFORE EATING/SMOKING/USING LAVATORY. Supplemental Safety and Health PH: 4.3-5.3. ================== Physical/Chemical Properties ================== Vapor Density:>1 pH:(SUPP) Solubility in Water:INSOLUBLE Appearance and Odor:SMOOTH WHITE CREAM ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME TEMPS, LIGHT. Hazardous Decomposition Products:CO & CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PR4151 CAGE:GO354 CAGE:2W300 CAGE:GO354 ============= Composition/Information on Ingredients ============= Ingred Name:NON HAZARDOUS INGREDIENTS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: MAY LEAD TO IRRITATION. SKIN: MINOR IRRITATION MAY RESULT. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: MAY LEAD TO IRRITATION. SKIN: MINOR IRRITATION MAY RESULT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/LARGE AMOUNTS OF SOAP & WATER. INHALATION: MOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING UNLESS IMMEDIAT E MEDICAL ASSISTANCE ISN'T AVAILBLE. IFNOT AVAILABLE GIVE 2 GLASSES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>310F Extinguishing Media:WATER, DRY CHEMICAL, CO2, FOAM Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:COMBUSTIBLE MATERIAL ================== Accidental Release Measures ================== Spill Release Procedures:AVOID CONTACT W/MATERIAL. EVACUATE AREA UNTIL CLEAN UP IS COMPLETE. DIKE TO PREVENT SPREADING & SCOOP UP EXCESS TO RECOVERY CONTAINERS. ABSORB REMNANT ON NONCOMBUSSTIBLE MATERIAL & SHOVEL INTO CONTAIN ERS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE UNDER COOL, DRY CONDITIONS AWAY FROM OPEN FLAMES & HIGH TEMPS. RESEAL PARTLY USED CONTAINERS. Other Precautions:AVOID SKIN/EYE CONTACT, BREATHING VAPOR/MIST/FUMES. ENSURE ALL CONTAINERS ARE PROPERLY LABELLED TO PREVENT ACCIDENTAL INGESTION/IMPROPER DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORS WHEN MATERIAL BEING USED PRODUCES MIST, VAPOR, FUMES/SMOKE. Ventilation:SUFFICIENT TO CONTROL ANY MIST/VAPOR/FUMES PRODUCED BY PROCESSING/HANDLING METHOD. Other Protective Equipment:SAFETY GLASSES W/SIDE SHIELDS, CLEAN BODY COVERING CLOTHING & FOOTWEAR. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH W/SOAP & WATER BEFORE EATING/DRINKING/USING TOILET FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.35 Appearance and Odor:TAN LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:ELEVATED TEMPS, OPEN FLAMES Hazardous Decomposition Products:CO2, CO, OTHER UNKNOWN ORGANIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:139 6456 SPEED CHECK RA DEVELOPER STARTER CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 75-80% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM BICARBONATE CAS:298-14-6 Fraction by Wt: 15-20% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CHLORIDE CAS:7447-40-7 RTECS #:TS8050000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR RECOMMENDED HANDLING. EYE:NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRIT. SKIN:LOW HAZARD FOR RECOMMENDED HANDLING. INGEST:EXPECTED TO BE LOW INGESTION HAZARD. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE. Effects of Overexposure:TRANSIENT EYE IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. TARGET ORGANS EFFECTS:KIDNEY. ======================= First Aid Measures ======================= First Aid:INHAL:SYMPTOMATIC MOVE TO FRESH AIR.SYMPTOMS PERSIST GET MED ATTN. EYES:ANY MATL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.SYMPTOMS OCCUR GET MED ATTN. SKIN:WASH W/SOAP/WATER.SYMPTOMS OCCUR GET MED ATTN. INGEST:DRINK 1-2 GLASSESOF WATER.SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE,NON-COMBUST Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. FIRE/EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB SPILL W/VERMICULITE OR OTHER INERT MATL, THEN PLACE IN CNTNR FOR CHEM WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENTILATION.KEEP CNTNR CLOSED. Other Precautions:PROPERTIES:NO BIOCHEM OXY DEMAND & NO POT TO CAUSE OXY DEPLETION IN AQU SYS;LOW POT TO AFFECT AQUATIC ORGANISMS;LOW POT TO AFFECT 2NDS WASTE TREAT MICROBIAL METABOLISM & GERMINATION &/OR EARLY GROWTH OF SOME PLANTS & BIOCONCEN.WHEN (SUPPLE) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULE BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10AIR CHANGES/HR) SHOULD BE USED. VNETILATION RETES SHOULD BE MATCHED TO CONDITIONS. Other Protective Equipment:EYEBATH,WASHING FACILITIES,SAFETY SHOWER. Work Hygienic Practices:WASH WELL AFT HNDLG.GOOD INDUSTRIAL HYG PRAC SHOULD BE FOLLOWED WHICH INCLUDES PREVENT EYE/MIN SKIN CONTACTS & INHAL. Supplemental Safety and Health OTHER PRECAUTION:DILUTE W/LG AMT OF WATER,MATL RELEASED DIR/INDIR INTO ENVIRO NOT EXPECTED TO HAVE SIGNIFICANT IMAPCT. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 @20C Vapor Density:0.6 Spec Gravity:1.17 pH:8.1 Solubility in Water:COMPLETE. Appearance and Odor:LIQUID, COLORLESS, ODORLESS. Percent Volatiles by Volume:75-80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE W/COMMON MATERIALS & CONTAMINANTS W/WHICH THE MATL MAY REASONABLY COME INTO CONTACT. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN CHLORIDE. HAZ COMBUST PROD:NONE (NON-COMBUSTIBLE). ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREAT/DISPOSAL MAY BE SUBJECT TO NAT/STATE/LOC LAWS. FLUSH TO SEWER W/LG AMTS OF WATER. CHEMS SUBJ TO REPORTING REQMTS OF SEC 313 TITLE III OF SARA/40CFR PART 372:NONE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:873 5599 KODAK FLEXICOLOR STABILIZER III & REPLENISHER/C-41 Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 80-85% Other REC Limits:NONE RECOMMENDED Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2; 9596 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 3% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 96 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:OCTYLPHENOXYPOLYETHOXYETHANOL CAS:9036-19-5 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM ALKYL PHENOXY ETHER SULFATE CAS:9014-90-8 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION-FORMALDEHYDE PRODUCES MILD SENSORY IRRITATION OF THE EYES, NOSE & THROAT AT 2-5 PPM. EYES-CAUSES BURNS. SKIN-CAUSES IRRITATION. INGESTION-HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE G ASTROINTESTINAL TRACT. Explanation of Carcinogenicity:CONTAINS F [50-00-0] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:EYES-VAPOR CAUSES EYE IRRITATION AND TEARING. SKIN-MAY CAUSE ALLERGIC SKIN REACTION. INGESTION-MAY CAUSE BURNS OF THE MOUTH, ESOPHAGUS, AND STOMACH.IMMEDIATE SEVERE ABDOMINAL PAIN OCCURS, OFTEN WITHVOMITING, NAUSEA, DIARRHEA, DIZZINESS,UNCONSCIOUSNESS OR COMA, ANURIA, CONVULSION, & POSSIBLE DEATH. Medical Cond Aggravated by Exposure:EXPOSURE TO FORMALDEHYDE MAY CAUSE RESPIRATORY SENSITIZATION IN SOME INDIVIDUALS OR AGGRAVATE PRE-EXISTING ASTHMATIC CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION-MOVE TO FRESH AIR. IF BREATHING IS HARD, GIVE OXYGEN OR CPR. GET MEDICAL ATTENTION. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MIN. GET MEDICAL ATTENTION. SKIN- IMMEDIATELY FLUSH WI TH PLENTY OF WATER FOR 15 MIN. WHILE REMOVING CONTAMINATED CLOTHES/SHOES. GET MEDICAL ATTENTION. INGESTION-DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. Other Precautions:AVOID BREATHING VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF FORMALDEHYDE IS EMITTED AT LEVELS REQUIRING RESPIRATORY PROTECTION, THE FOLLOWING RESPIRATOR TYPE SHOULD BE WORN: FULL FACEPIECE WITH CARTRIDGES OR CANISTERS SPECIFICALLY APPROVED BY NIOSH FOR PROT ECTION AGANIST FORMALDEHYDE. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:CHEMICAL PROTECTIVE CLOTHING MADE OF MATERIAL IMPERVIOUS TO FORMALDEHYDE AND THE USE OF OTHER PERSONAL PROTECTIVE EQUIP. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health WARNING! CONTAINS FORMALDEHYDE. POSSIBLE CANCER HAZARD. ================== Physical/Chemical Properties ================== HCC:C3 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MMHG Vapor Density:0.6 Spec Gravity:1.02 pH:6.0 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, SLIGHT FORMALDEHYDE ODOR. Percent Volatiles by Volume:85-90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXODIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FORMALDEHYDE. CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EV EN AFTER CONTAINER IS EMPTIED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DILANTIN INJECTION, 50 MG/ML Preparer's Name:ROY MUELLER CAGE:93874 CAGE:93874 CAGE:91378 CAGE:82559 ============= Composition/Information on Ingredients ============= Ingred Name:PHENYTOIN (DILANTIN) SODIUM 10 MG/ML CAS:630-93-3 Other REC Limits:0.4 MG/M3 Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9293 Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT):3200 MG/KG PHENYTOIN Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION-MILDLY IRRITATING. INGESTION-MAY CAUSE CNS EFFECTS. SKIN-MAY CAUSE IRRITATION. EYE-IRRITATION. CHRONIC: CARDIOVASCULAR AND BIRTH DEFECTS. Explanation of Carcinogenicity:PHENYTOIN IS LISTED AS A SUSPECT/POSSIBLE CARCINOGEN BY NTP AND IARC. Effects of Overexposure:INHALATION-BREATHING DIFFICULTIES. INGESTION-NYSTAGMUS, ATAXIA, DROWSINESS, STUPOR, SLEEP. EYE/SKIN- IRRITATION. Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASES, AND PREGNANT WOMEN. ======================= First Aid Measures ======================= First Aid:EYE-FLUSH PROMPTLY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN-WASH WITH SOAP & WATER; THEN FLUSH WITH WATER UNTIL CHEMICAL IS REMOVED. INGESTION-IF CONSCIOUS, IMMEDIATELY GIVE 2 TO 4 GLASSES O F WATER AND IMMEDIATELY GET MEDICAL HELP. INHALATION-REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR MOP UP AND PLACE IN A CONTAINER FOR DISPOSAL. FLUSH RESIDUE AWAY WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED, DRY AREA OF LOW FIRE RISK. KEEP CONTAINER TIGHTLY CLOSED. PROTECT FROM PHYSICAL DAMAGE. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. Ventilation:NATURAL VENTILATION IS ADEQUATE. Other Protective Equipment:WEAR REGULAR WORK CLOTHES, INCLUDING LONG- SLEEVED SHIRT & TROUSERS. Work Hygienic Practices:USE NORMAL PERSONAL HYGIENE AND FOLLOW GOOD HOUSEKEEPING PRACTICES. Supplemental Safety and Health THIS MEDICINE IS USED AS ANTICONVULSANT/ ANTILEPTIC, MINIMAL OCCUPATIONAL HAZARD IS INVOLVED. PREGNANT WOMEN SHOULD AVOID CONTACT WITH IT, SINCE IT IS KNOWN TO CAUSE FETAL MALFORMATIONS. EACH ML CONTA INS 50 MG OF PHENYTOIN. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.032 pH:12.2 Appearance and Odor:A CLEAR, COLORLESS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG STRONG ACIDS. Stability Condition to Avoid:HIGH HEAT. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:M8090-3 ALPHA-METHYLSTYRENE 99% CAGE:21076 CAGE:60928 CAGE:63181 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA METHYLSTYRENE (MONOMER) CAS:98-83-9 RTECS #:WL5250000 Fraction by Wt: 99% Other REC Limits:50 PPM ACGIH TLV:242 MG/CUM ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 4900 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED THROUGH SKIN. IRRITATING TO THE EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA, VOMITING, IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. INGESTION: WASH OUT MOUTH W/WATER IF CONSC IOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM, WATER SPRAY. Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION/FLASH BACK. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. AUTOIGNITION TEMP: 1065F. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR SCBA, RUBBER BOOTS & HEAVY CONTAINER & HOLD FOR WASTE DISPOSAL. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE. ======================Handling and Storage ====================== Handling and Storage Precautions:REFRIGERATE. KEEP AWAY FROM HEAT & OPEN FLAME. KEEP TIGHTLY CLOSED. Other Precautions:AVOID PROLONGED/REPEATED EXPOSURE. AVOID CONTACT W/EYES, SKIN/CLOTHING. AVOID BREATHING VAPOR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST REQUIRED. Other Protective Equipment:SAFETY SHOWER & EYE BATH. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:329-336.2F Melt/Freeze Pt:M.P/F.P Text:-11.2F Vapor Pres:2.1 Vapor Density:4.1 Spec Gravity:0.909 Appearance and Odor:COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, OPEN FLAME. Hazardous Decomposition Products:COMBUSTION: CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER, IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRINT HEAD MAINTENANCE LIQUID;#8R1207 CAGE:26921 CAGE:26921 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >99.9% Other REC Limits:NONE SPECIFIED Ingred Name:ADDITIVES Fraction by Wt: <0.1% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: NON-IRRITATING, NON-SENSITIZING. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:NOT APPLICABLE. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL PROCEDURES. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Ventilation:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Other Protective Equipment:NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Work Hygienic Practices:NONE. Supplemental Safety and Health NONE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Density:WATER Spec Gravity:1 Evaporation Rate & Reference:WATER Solubility in Water:INFINITE Appearance and Odor:CLEAR LIQUID/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIFIC WASTE DISPOSAL METHOD REQUIRED. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:ZYTEL, 132F NC010 Kit Part:Y Preparer's Name:D.L. LICZWEK CAGE:B0589 CAGE:82348 CAGE:B0589 ============= Composition/Information on Ingredients ============= Ingred Name:NYLON (NYLON 66) CAS:32131-17-2 Fraction by Wt: >98% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:LUBRICANT Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:STABILIZER Fraction by Wt: <2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:MAY NOT PROVIDE ADEQ PROTECTION. RTECS #:9999999ZZ Ingred Name:EYE PROT:SHIELD WHEN POSSIBILITY EXISTS FOR EYE & FACE CONT DUE TO SPLASHING/SPRAYING OF MOLTEN MATL. NIOSH/MSHA (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:FULL FACE MASK RESP PROVIDES PROTECTION FROM EYE IRRITATION. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT)>10,000 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SINGLE LG ORAL EXPOS (10,000 MG/KG) PRODUCED ONLY SLIGHT INITIAL WEIGHT LOSS. TWO-YEAR TESTS IN RATS & ONE YEAR TESTS IN DOGS @ LEV OF 10% IN DIET PRODUCED NO ADVERSE EFTS. RPTD INHAL EXPOS PROD UCED NO GROSS CHANGES & ONLY MICROSCOPIC LUNG & KIDNEY CHANGES. THE CMPD IS NOT SKIN IRRITANT. TESTS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:IN ANIMALS DEMONSTRATE NO CARCIN ACTIVITY. NO ADVERSE HLTH EFTS ARE EXPECTED FROM HUMAN EXPOS TO POLYHEXAMETHYLENE ADIPAMIDE, EXCEPT FOR MECH IRRIT OF SKIN & EYES CAUSE BY PARTICLES. SIGNIFIC ANT SKIN PERMEATION, AND SYSTEMIC TOX, AFTER CONTACT APPEARS UNLIKELY. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:CONSULT PHYS IF NEC. IF EXPOS TO FUMES FROM OVERHEATING/COMBUST, MOVE TO FRESH AIR. CONSULT PHYS IF SYMP PERSIST. SKIN:CLEANSING SKIN AFTER USE IS ADVISABLE. IF MOLTEN POLYMER GETS ON SKIN, COOLRAPIDLY W/COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MED TREATMENT FOR THERMAL BURN. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MINS. CALL PHYS. INGEST:CONSULT PHYS IF NEC. ===================== Fire Fighting Measures ===================== Flash Point:752F,400C Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . KEEP PERSONNEL REMOVED AND UPWIND OF FIRE. Unusual Fire/Explosion Hazard:LG MOLTEN MASSES MAY IGNITE SPONT IN AIR. WATER QUENCHING OF SUCH MASSES IS GOOD PRACTICE. HAZ GASES/VAP PRODUCED IN FIRE ARE:AMMONIA, CO; SM AMTS OF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:NOTE:REVIEW FIRE FIGHT MEASURES & HNDLG (PERS) SECTIONS BEFORE PROCEEDING W/CLEAN-UP. USE APPROP PERSONAL PROT EQUIP DURING CLEAN-UP. SWEEP UP TO PVNT A SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:COOL, DRY PLACE. KEEP CNTNRS TIGHTLY CLSD TO PVNT MOISTURE ABSORPTION & CONTAMINATION. Other Precautions:MEDICAL USE: CAUTION:DO NOT USE IN MED APPLIC INVOLVING PERM IMPLANTATION IN HUMAN BODY. FOR OTHER MED APPLIC SEE DU PONT CAUTION BULLETIN NO. H-50102. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGE & NIOSH/MSHA DUST/MIST FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONC ARE EXPECTED TO EXCEED EXPOS LIM. PROT PROVIDE D BY NIOSH/MSHA AIR PURIFYING (SUPDAT) Ventilation:LOCAL VENTL TO CONTROL FUMES FROM HOT PROCESSING. Other Protective Equipment:IF THERE IS POTENTIAL CONT W/HOT MOLTEN MATL, WEAR HEAT RESIST CLOTHING AND FOOTWEAR. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health % VOLAT:1% (WATER). EXPLO HAZ:HYDROGEN CYANIDE & ALDEHYDES. WASTE DISP METH:PROVINCIAL, & LOCAL REGS. RESP PROT:RESP IS LIM. USE NIOSH/MSHA POSITIVE PRESS AIR SUPPLIED RESP IF THERE IS ANY POTNTL FOR UNCONTROLLED RELEASE, EXPOS LEV ARE NOTKNOWN, OR ANY OTHER CIRCUMSTANCE WHERE NIOSH/MSHA AIR PURIFYING RESP (ING 4) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>482F,>250C Spec Gravity:1.22-1.38 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:INSOLUBLE Appearance and Odor:GRANULES, NO ODOR Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZING AGENTS. Stability Condition to Avoid:HEATING ABOVE 340 DEGREES C. Hazardous Decomposition Products:CYCLOPENTANONE, CARBON MONOXIDE, ALDEHYDES, AND AMMONIA. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREF OPTIONS FOR DISP ARE (1)RECYCLING, (2)INCIN W/ENERGY RECOVERY, & (3) LANDFILL. HIGH FUEL VALUE OF PROD MAKES OPTION 2 VERY DESIRABLE FOR MAT THAT CANNOT BE RECYCLED. TREATMENT STOR, TRANSPORTATIO N & DISP MUST BE I/A/W APPLIC FED, STATE/ (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:NORSIL SILICONE PRIMER Kit Part:Y CAGE:33530 CAGE:33530 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Fraction by Wt: 90% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9394 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYL SILICATE CAS:78-10-4 RTECS #:VV9450000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:10 PPM; 9394 Ingred Name:NON-HAZARDOUS SOLIDS Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE IRRITATION.AVOID CONTACT WITH SKIN,EYES,& CLOTHING.DIRECT CONTACT WITH UNCURED PRODUCT MAY CAUSE IRRITATION.PROLONGED SKIN CONTACT MAY CAUSE DERMATITIS.INHALATION MAY CAUSE RESPIRATORY IRRIT ATION,DIZZINESS,HEADACHE,NAUSEA,& MENTAL CONFUSION.INGESTION IS HARMFUL & MAY PRODUCE ABDOMINAL PAIN & DIARRHEA. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED: SHORTNESS OF BREATH, DIZZINESS, HEADACHE, NAUSEA, MENTAL CONFUSION. EYES: REDNESS, TEARING, DISCOMFORT. SKIN: REDNESS, DISCOMFORT. INGESTED: ABDOMINAL PAIN, DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGESTED-DO NOT INDUCE VOMITING!IF CONSCIOUS & VOMITING,GIVE MORE FLUID.GET MEDICAL ATTENTION.SKIN-FLUSH AFFECTED AREAS WITH WATER FOR 15 MINUTES.REMOVE CONTAMINATED CLOTHES.GET MEDICAL ATTENTION IF I RRITATION DEVELOPS.EYES-FLUSH WITH LOTSOF WATER FOR 15 MINUTES,HOLD LIDS OPEN.GET IMMEDIATE MEDICAL ATTENTION.INHALED-REMOVE FROM AREA.SEEK MEDICAL ATTENTION IF BREATHING DIFFICULT.RESTORE BREATHING. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-4F,-20C Lower Limits:1.1 Upper Limits:7.5 Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. USE STANDARD FIREFIGHTING TECHNIQUES. Fire Fighting Procedures:WEAR FULL-FACE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND ADJACENT SURFACES ONLY. Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE DUE TO SOLVENT; VAPORS WILL FORM EXPLOSIVE MIXTURES WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROPER EQUIPMENT/CLOTHES. ELIMINATE ALL SOURCES OF IGNITION. CONTAIN SPILL/LEAK. ABSORB WITH SUITABLE ABSORBENT. SWEEP UP & PLACE IN A CONTAINER FOR LATER DISPOSAL. WASH AREA WITH WATER & DETERGE NT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN A WELL-VENTILATED AREA. KEEP AWAY FROM SOURCES OF IGNITION & INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:NEVER LAY CONTAINERS ON THEIR SIDES.KEEP AWAY FROM HEAT, SPARKS, & FLAME. AVOID PROLONGED VAPOR BRETAHING & CONTACT WITH SKIN & EYES. CONTACT LENS WEARS SHOULD TAKE APPROPRIATE PRECAUTIONS. USE NON- SPARKING TOOLS, STATIC MAY DEVELOP. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE MATERIAL SHOULD BE HANDLED IN AN OPEN OR WELL-VENTILATED AREA. WHERE VENTILATION IS NOT AVAILABLE, USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. IN HIGHER CONCENTRATIONS, USE SC BA. USE IAW 29 CFR 1910.134. Ventilation:LOCAL EXHAUST IS REQUIRED & GENERAL MECHANICAL VENTILATION IS SUGGESTED IN A CLOSED AREA. [EXPLOSION-PROOF EQUIPMENT] Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:DLA-HMIS: WASH HANDS AFTER USE AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health MSDS ENTERED BY DLA-HMIS UNDER PROJECT WITH GSA. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:156F,69C Vapor Pres:<155 MM HG Vapor Density:3.0 Spec Gravity:0.82 Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1) Solubility in Water:NOT SOLUBLE Appearance and Odor:COLORLESS, TRANSPARENT LIQUID WITH SOLVENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO WATER, ACIDS, ALKALIS. Stability Condition to Avoid:ACTIVE INGREDIENTS REACT WITH WATER, ACIDS, & ALKALIS BUT DO NOT PRESENT A HAZARD. Hazardous Decomposition Products:METHANOL AND 2-PROPANOL ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. MATERIAL THAT CAN BE USED SHOULD BE DISPOSED OF IN AN EPA AITHORIZED FACILITY. DLA-HMIS: EPA/RCRA WASTE NUMBER D001 MAY APPLY TO UNU SED/UNCONTAMINATED PRODUCT.
1
eyes_protection_mandatory
======================================================= NIIN: 01-306-9167 Product ID: 7292, TERMALENE GREASE 2 Cage: 12474 Box: 526 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 12474 Box: 526 ======================================================= Item Description Information ======================================================= Item Manager: S9G Item Name: GREASE,WATER-WASH RESISTANT Specification Number: A-A-50433 Type/Grade/Class: NONE Unit of Issue: CN Quantitative Expression: 00000000035LB UI Container Qty: 1 Type of Container: PPP-P-704 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: PROBABLY BE NO EVIDENCE OF ACUTE EXPOSURE. EXCEPTION COULD BE EYE IRRITATION. HOWEVER, MODIFYING NATURE OF COMPOSITION MAY RESULT IN LITTLE/NO EYE IRRITATION. CHRONIC EXOSURE MAY CAUSE MILD TO SEVERE SKIN OR EYE IRRITATION. Explanation Of Carcinogenicity: MANUFACTURER GAVE NO INFORMATION ABOUT CARCINOGENICITY. FOUND NO LISTING & DOES NOT EXPECT IT TO BE CARCINOGENIC. Signs And Symptions Of Overexposure: EYE OR SKIN IRRITATION, ESPECIALLY W/PROLONGED &/OR REPEATED CONTACT. Medical Cond Aggravated By Exposure: UNDER NORMAL USE, MEDICAL CONDITIONS ARE NOT GENERALLY AGGRIVATED BU EXPOSURE. First Aid: INHALATION:IMPOSSIBLE IN NORMAL USE. INGESTION:MAY BE MILDLY TOXIC. SEEK MEDICAL AID TO REMOVE RATHER THAN BY VOMITING WHERE LUNG ENTRY COULD BE HARMFUL. SKIN:WIP AWAY EXCESS THEN WASH W/SOAP & WATER. EYES:FLUSH WITH WATER UNTIL REMOVED. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: PICK UP W/SHOVEL OR TROWEL. USE APPLICABLE SOLVENTS & ABSORBENTS TO EFFECT COMPLETE CLEAN-UP. Neutralizing Agent: MFR GAVE NO INFORMATION ON MSDS. Waste Disposal Methods: DISPOSE OF PRODUCT IN A MANNER TO COMPLY W/THE MANDATES OF ALL GOVERNMENTAL AGENCIES. Handling And Storage Precautions: STORE IN CLOSED CONTAINERS AWAY FROM HEAT & OPEN FLAMES. DO NOT STORE W/OXIDIZING AGENTS. Other Precautions: "EMPTY" CONTAINERS RETAIN RESIDUE. DO NOT HEAT, WELD OR EXPOSE TO SPARKS &/OR OPEN FLAMES AS THEY MAY EXPLODE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 460F,238C Lower Limits: NOT ESTABLID Upper Limits: NOT ESTABLID Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY Fire Fighting Procedures: USE AIR SUPPLIED BREATHING APPARATUS FOR ENCLOSED AREAS. Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: MFR GAVE NO INFORMATION ON MSDS. Ventilation: IF MIST CREATED, DO NOT EXCEED TLV FOR OIL. Other Protective Equipment: VERY GOOD INDUSTRIAL HYGIENE PRACTICES. Work Hygienic Practices: MFR GAVE NO INFORMATION OF MSDS. Supplemental Safety and Health: NONE ======================================================= Physical/Chemical Properties ======================================================= HCC: V6 NRC/State LIC No: NONE B.P. Text: >600F,>316C M.P/F.P Text: UNKNOWN Decomp Text: UNKNOWN Vapor Pres: <0.01 MM Vapor Density: >10 Spec Gravity: 0.91 Viscosity: UNKNOWN Evaporation Rate & Reference: NOT ESTABLISHED Solubility in Water: NEGLIGIBLE Appearance and Odor: BLUE-GREEN GREASE, SLIGHT ISOPROPANAL ODOR Percent Volatiles by Volume: TRACE Corrosion Rate: UNKNOWN ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: MFR GAVE NO INFORMATION ON MSDS. Materials To Avoid: STRONG OXIDIZERS, CONCENTRATED OXYGEN & CHLORINE. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, COMPOUNDS OF NITROGEN, ZINC, CALCIUM Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: WILL NOT OCCUR. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 124020 Product ID: 7292, TERMALENE GREASE 2 Review Date: 04/06/1997 Tech Entry NOS Shipping Nm: NONE Net Unit Weight: 35 POUNDS Multiple KIT Number: 0 Review IND: Y Unit Of Issue: CN Container QTY: 1 Type Of Container: PPP-P-704 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: 7292, TERMALENE GREASE 2 Cage: 12474 Company Name: BEL-RAY COMPANY INC. Street: 1201 BOWMAN AVE PO Box: 526 Zipcode: 07727 Label Required IND: Y Date Of Label Review: 04/06/1997 Status Code: C MFG Label NO: NONE Label Date: 04/06/1997 Year Procured: 1997 Origination Code: F Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: PROBABLY BE NO EVIDENCE OF ACUTE EXPOSURE. EXCEPTION COULD BE EYE IRRITATION. HOWEVER, MODIFYING NATURE OF COMPOSITION MAY RESULT IN LITTLE/NO EYE IRRITATION. CHRONIC EXOSURE MAY CAUSE MILD TO SEVERE SKIN OR EYE IRRITATION. STORE IN CLOSEDCONTAINERS AWAY FROM HEAT & OPEN FLAMES. DO NOT STORE W/OXIDIZING AGENTS. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STYLE 77MC STICK/BUCK CAGE:71724 CAGE:71724 ============= Composition/Information on Ingredients ============= Ingred Name:ASPHALT (PETROLEUM) CAS:8052-42-4 RTECS #:CI9900000 Other REC Limits:NONE SPECIFIED ACGIH TLV:5 MG/M3; (FUME);9192 Ingred Name:AROMATIC PETROLEUM OIL Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:ADDITIVES Other REC Limits:NONE SPECIFIED Ingred Name:MICROCRYSTALLINE WAX Other REC Limits:NONE SPECIFIED Ingred Name:ANIMAL FATTY OIL CAS:8016-28-2 Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 (OIL MIST) ACGIH TLV:5 MG/M3 (OIL MIST) Ingred Name:PARAFFIN WAX CAS:8002-74-2 RTECS #:RV0350000 Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 (FUME) ACGIH TLV:2 MG/M3 (FUME); 9192 Ingred Name:TEFLON (TETRAFLUORO ETHYLENE POLYMER) CAS:116-14-3 RTECS #:KX4025000 Other REC Limits:NONE SPECIFIED Ingred Name:DIMETHYL SILOXANE (DOW CORNING 200) CAS:63148-62-9 RTECS #:JT6484500 Other REC Limits:NONE SPECIFIED Ingred Name:MAGNESIUM SILICATE CAS:1480-96-6 OSHA PEL:15 MG/M3(TOTAL DUST) ACGIH TLV:10 MG/M3(TOTAL DUST) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: NONE WHEN USED AS FINISHED PRODUCT. INHALATION OF VAPORS IF PRODUCT IS OVERHEATED MAY CAUSE EYE AND THROAT IRRITATION, LUNG TISSUE DAMAGE, CENTRAL NERVOUS SYSTEM DEPRESSION, CARDIAC DYSRYTHMIA. CHRONIC: PROLONGED CONTACT MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:ASPHALT AND AROMATIC PETROLEUM OIL HAVE BEEN KNOWN TO CAUSE SKIN CANCER IN LABORATORY ANIMALS. Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, DERMATITIS, THERMAL BURNS. INHALATION: INHALATION OF VAPORS WHEN PRODUCT IS OVERHEATED MAY CAUSE TEARING, COUGH, FEVER, FLU-LIKE SYMPTOMS. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER. INHALATION: IF EXPOSED TO TOXIC VAPORS GENERATED WHEN PRODUCT IS OVERHEATED, REMOVE VICTIM TO FRES H AIR. GIVE OXYGEN/CPR IF NEEDED. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:400F,204C Autoignition Temp:Autoignition Temp Text:425F Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. CONTACT WITH STRONG OXIDIZING AGENTS MAY CAUSE AN EXPLOSION. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENT. Other Precautions:STORE AWAY FROM HEAT, SPARKS, OPEN FLAMES AND OXIDIZING MATERIALS. KEEP FIRE EXTINGUISHERS READILY AVAILABLE. NO SMOKING IS ALLOWED IN AREAS USING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. USE SELF-CONTAINED BREATHING APPARATUS IF PRODUCT IS ACCIDENTALLY HEATED TO THERMAL DECOMPOSITION AND TOXIC VAPORS ARE GENERATED. Ventilation:NO SPECIAL REQUIREMENT IN NORMAL CONDITIONS. USE LOCAL EXHAUST IF TOXIC VAPORS ARE GENERATED. Other Protective Equipment:LONG SLEEVED SHIRTS AND LONG PANTS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MSDS IS FOR THE PRODUCT WHEN USED IN NORMAL CONDITIONS. THIS PRODUCT CONTAINS TEFLON. AT 720F, TEFLON STARTS TO DEGRADE THERMALLY, RELEASING FREONS THAT CAN CAUSE ACUTE CENTRAL NERVOUS SYSTEM DEPRESSI ON AND CARDIAC DYSRYTHMIA AT HIGH CONCENTRATIONS. THIS PRODUCT CONTAINS ASPHALT. H2S IS EMITTED FROM HEATED ASPHALT. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>600F,>316C Melt/Freeze Pt:M.P/F.P Text:245F,118C Solubility in Water:INSOLUBLE Appearance and Odor:SOLID CARMEL LIKE GREASE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. THIS PRODUCT CONTAINS TEFLON WHICH MAY REACT WITH POWDERED AL, MG, FL, AND INTERHALOGENATED COM Stability Condition to Avoid:HIGH HEAT SOURCES AND TEMPERATURES ABOVE 350F Hazardous Decomposition Products:FREONS, HYDROGEN CHLORIDE, PERFLUOROCARBON OLEFINS, CO, CO2, SULFUR OXIDES, NOX, POLYCYCLIC AROMATIC HYDROCARBONS, H2S. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ARCAIR SLICE CUTTING ROD,UNCOATED (SUPPLEMENTAL) Preparer's Name:DENNIS WILSON CAGE:89381 CAGE:89381 ============= Composition/Information on Ingredients ============= Ingred Name:MILD STEEL Fraction by Wt: 99%+ Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:WHEN CUTTING CERTAIN MATLS(LEAD,CADMIUM,BERYLLIUM,ETC)AIRBORNE CONC MAY EXCEED TLV'S CAUSING DRYNESS OF THROAT,BREATHING DIFFICULTY OR UNCONSC.VISUAL:EXPO TO ULTRA-VIOLET RADIATION FROM POWDERED ARC CAN RESULT IN KERATONCONJUNCTIVITIS(WELDERS FLASH)CAUSING INFLAMM,BLURRED VISION,HEADACHE. Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:NOT LISTED. Effects of Overexposure:DRYNESS OF THROAT, BREATING DIFFICULTY OR UNCOSNC. KERATONCONJUNCTIVITIS (WELDER'S FLASH) CAUSING INFLAMMATION, BLURRED VISION, HEADACHE. Medical Cond Aggravated by Exposure:POSSIBLY EXISTING RESPIRATORY. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR & SEEK MED ATTN. VISUAL:CONSULT PHYSICIAN-PREFERABLY AN EYE SPECIALIST. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:DOES NOT BURN READILY. Fire Fighting Procedures:DOES NOT BURN READILY. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP SPENT ENDS WHEN COOL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN LOW HUMIDITY ENVIRONMENT.AVOID BREATHING VAPORS!INTENSE HEAT GENERATED WHEN IN OPERATION! Other Precautions:WHEN PLACED INTO SERVICE W/WELDING POWER SOURCE,AN INTENSE ELCTRIC ARC IS CREATED GENERATING FUMES/GASES/ULTRA-VIOLET RAYS WHICH CAN DMG EYE/PENETRATE LIGHT CLOTH/BURN SKIN.WHEN NOT IN SERVICE RODS PO SE NO PARTICULAR HAZARD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH-MESA DETERIMINED FOR FUME/DUST PROTECTION. AS REQUIRED TO MAINTAIN BELOW TLV'S. Ventilation:LOC EXHAUST:PREFERRED FOR FUME/DUST REDUCTION. MECHANICAL:TO MAINTAIN BELOW TLV'S/PEL'S. Other Protective Equipment:AS USED IN CONVENTIONAL ARC WELDING.SUITABLE FOOTWEAR FOR METAL WORKING. Work Hygienic Practices:OPERATOR TRAINED TO AVOID ELECTRICAL SHOCK & UV RAY EXPOSURE. Supplemental Safety and Health CAT #:43-079-002,-003,-007,-009,-005. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:NA Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NP Vapor Pres:NA Vapor Density:NA Spec Gravity:NA pH:NA Viscosity:NP Evaporation Rate & Reference:NA Solubility in Water:INSOLUBLE. Appearance and Odor:SOLID, ROLLED STEEL TUBE, NO NOTABLE ODOR. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Hazardous Decomposition Products:IRON OXIDE FUMES IN ADDITION TO THOSE GENERATED BY MATERIALS BEING CUT. ==================== Disposal Considerations ==================== Waste Disposal Methods:SOLID LANDFILL IF LOCAL REGULATIONS ALLOW.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:21877 BD 7-77 PLUS CAGE:05575 CAGE:05573 CAGE:05575 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 15% Other REC Limits:100 MG/CUM NIOSH Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 42% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:2-BUTOXYETHANOL CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 16% Other REC Limits:25 PPM (SKIN) OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 19% Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 19% Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 RTECS #:9999999VO Fraction by Wt: 63% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: DIZZINESS OR NARCOSIS. SKIN: DEFATTING. INGESTION: HARMFUL OR FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: DIZZINESS OR NARCOSIS. SKIN: DEFATTING. INGESTION: HARMFUL OR FATAL. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE PATIENT TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE QUANTITIES OF WATER. INGESTION: MAY BE HARMFUL OR FATAL. DON'T INDUCE VOMITING. GET M EDICAL ATTENTION ALL IN CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F Lower Limits:1.8% Upper Limits:12.0% Extinguishing Media:CO2, WATER, FOG ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBANT MATERIAL. SWEEP UP & DISPOSE IN HAZARDOUS WASTE TRASH. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T TEMPERATURES >120F. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:NONE Other Protective Equipment:NONE Supplemental Safety and Health WT/GAL: 7.2 LBS ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-40F Vapor Pres:37 PSI Vapor Density:4.0 Spec Gravity:0.8 pH:NONE Solubility in Water:NONE Appearance and Odor:LIQUID GAS; WHITE TO CLEAR-SOLVENT ODOR. Percent Volatiles by Volume:99% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:DON'T STORE AT TEMPERATURES >120F. Hazardous Decomposition Products:CO2, & WATER ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN HAZARDOUS WASTE CONTAINER. RCRA HAZARDOUS WASTE: D-001. CONSUMER COMMODITY, ORM-D, UN-1954.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EX FLEX PRODUCTS CAGE:81851 CAGE:81851 ============= Composition/Information on Ingredients ============= Ingred Name:FIBERGLASS (FIBROUS GLASS); (CONTINUOUS FILAMENT FIBERGLASS) CAS:65997-17-3 Fraction by Wt: 90% OSHA PEL:5 MG/M3 RDUST ACGIH TLV:10 MG/M3 (<7MICRONS) Ingred Name:OXALIC ACID; (NON-HAZARDOUS) CAS:144-62-7 RTECS #:RO2450000 Fraction by Wt: <1% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3;2 STEL Ingred Name:ACRYLIC LATEX; (NON-HAZARDOUS) Fraction by Wt: 9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:COLORANT AND VARIOUS DYES; (COLORANT (NON-HAZARDOUS)) Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIUM HYDROXIDE (CERCLA) CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <1% OSHA PEL:50 PPM (MFR) ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA:OF CONTINUOUS FILAMENT FIBERGLASS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NO HEALTH HAZARDS ARE EXPECTED IN FORM PROVIDED. HOWEVER, FIBERGLASS FIBERS ARE KNOWN TO CAUSE IRRITATION & ITCHING OF SKIN & EYES. INHALED FIBERS MAY CAUSE LUNG IRRITATION. ACUTE:MAY CAUSE IRRITATIONTO MOUTH, NOSE & EYES IN FORM OF RASHES & ITCHING. SIGNS & SYMPTOMS OF EXPOSURE:RASH, ITCHING, CONJ. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CHRONIC:IN JUNE, 1987, IARC CATEGORIZED FIBERGLASS CONTINUOUS FILAMENT YARN AS NOT CLASSIFIABLE AS HUMAN CARCIN. NUMBER OF EPIDEMIOLOGY STUDIES, DONE OVER MANY YRS, OF WORKERS W/UP TO 40 YRS OF SERVICE IN MFG OF CONTINUOUS FILAMENT FIBERGLASS HAVE SHOWN NO EVID OF INCRS IN MALIGNANT/NON-MALIGNANT RESP (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SEEK MEDICAL ASSISTANCE FOR FURTHER TREATMENT, OBSERVATION & SUPPORT IF NECESSARY. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLU SH THOROUGHLY W/CLEAR WATER FOR AT LEAST 15 MINUTES. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. SKIN:RINSE AREA W/COOL WATER & USE MILD SOAP. AVOID SCRATCHING & RUBBING IRRITATED AREAS. ===================== Fire Fighting Measures ===================== Flash Point:NON-BURNING Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NON-BURNING. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:NONE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED - IF CUTTING, USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING OR SMOKING. Supplemental Safety and Health EFTS OF OVEREXP:DISEASE ATTRIBUTED TO FIBERGLASS EXPOS. HOWEVER, RECENT STUDIES HAS SHOWN SLIGHT INCRS IN LUNG CANCER AMONG WORKERS EMPLOYED IN MANUFACTURE OF GLASS WOOL & MINERAL WOOL INSULATION PROD S. THOSE SAME STUDIES SHOW NO EVID OF SIMILAR EFT AMONG CONTINUOUS FILAMENT FIBERGLASS WORKERS. THIS PROD IS MADE(ING 6) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:1472F,800C Spec Gravity:2.45 (H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:TUBULAR PRODUCT - VARIOUS COLORS; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NO THERMAL DECOMPOSITION SHOULD OCCUR UNDER NORMAL USE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE UNDER FEDERAL, STATE & LOCAL GUIDELINE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:#39999-00G COMPLETE SET OF MICROCHEM,CALCIUM CHLORIDE 1.0M Kit Part:Y Preparer's Name:R.M. CARLSON CAGE:11273 CAGE:11273 CAGE:CENC1 CAGE:CENC3 CAGE:CENC2 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CHLORIDE, DIHYDRATE CAS:10035-04-8 RTECS #:EV9810000 Fraction by Wt: 10% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MODERATELY CAUSTIC SOLUTION.ACUTE:IRRIT POSSIBLE TO SKIN AND EYES.CHRONIC:NONE KNOWN. Effects of Overexposure:(WHEN IN DOUBT CALL PHYSICIAN OR LOCAL POISON CONTROL CENTER).IRRIT SKIN/EYES. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:SKIN:WASH THOROUGHLY W/RUNNING H2O.IRRIT DVLPS GET MED ADVICE.EYE:WASH W/LOTS OF H2O FOR @LEAST 15MINS,LIFT EYELIDS OCCASION.GET MED ATTN IMMED.INHAL:NOT EXPECTED TO REQUIRE 1STAID MEASURES.INGEST:IND UCE VOMIT IMMED BY GIVING 2GLASSES OF H2O,STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH TO UNCONSC PERSON.CALL PHYSICIAN IMMED. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NP Lower Limits:NP Upper Limits:NP Extinguishing Media:USE ANY MEDIUM SUITABLE FOR EXTINGUISHING SUPPORTING FIRE. Fire Fighting Procedures:IN EVENT OF FIRE WEAR FULL PROTECTIVE CLOTH & NIOSH-APPROV SELF-CONTAIN BREATH APPARATUS W/FULL FCPIECE OPERATED IN PRESSURE DEMAND OR OTHER +PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE/EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:DILUTE AND NEUTRALIZE WITH DILUTE ACID.CLEANUP/DISPOSAL METHODS ARE RECOMMENDATIONS ONLY.CHECK YOUR LOC/STATE/FED REGS. Neutralizing Agent:DILUTE ACID ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY LOCATION. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED NORMALLY. Ventilation:LOCAL EXHAUST AND MECHANICAL(GENERAL). Other Protective Equipment:LAB COAT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PC:39883-00. KEY1:HCC=N1. PER MFG KIT NOT MANUFACTURED ANY MORE,SIZE OF CHEMS UNK.OTHER PARTS @CAGES 11273,CENC1,CENC2,CENC3,CENC4 ALL PNIND SAME NSN. ================== Physical/Chemical Properties ================== HCC:V1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Decomp Temp:Decomp Text:NP Vapor Pres:NA Vapor Density:NA Spec Gravity:1 pH:NP Viscosity:NP Evaporation Rate & Reference:NA Solubility in Water:100% Appearance and Odor:CLEAR SLIGHTLY TURBID SOLUTION, NO ODOR Percent Volatiles by Volume:NA Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE KNOWN ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH DOWN DRAIN W/EXCESS OF WATER.CLEANUP/DISPOSAL METHODS ARE RECOMMENDATIONS ONLY.CHECK YOUR LOC/STATE/FED REGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACFOAM-I INSULATION (FLAT OR TAPERED) CAGE:HO818 CAGE:HO818 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:FIBROUS GLASS:ACUTE:MECHANICAL IRRIT OF MOUTH, NOSE & THROAT. SKIN:TRANSIENT MECHANICAL IRRIT. EYE:MECHANICAL IRRIT. CHRONIC:MANY STUDIES HAVE BEEN CONDUCTED TO DETERM POTNTL LONG TERM EFTS OF FIBROUS GLASS INHAL. ALTHOUGH INCONCLUSIVE, SOME RESEARCH SUPPORTED BY INUDUSTRY INDICATED THAT MFG PLANT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:EMPLOYEES WHO WERE FIRST EMPLOYED MORE/30 YRS AGO IN FACTORIES THAT MANUFACTURED GLASS WOOL & MINERAL WOOL HAVE AN INCREASED RATE OF LUNG CANCER AS COMPARED TO CERTAIN OTHER REFERENCE POPULAT IONS. FURTHER STUDY IS PLANNED TO IDENTIFY THOSE FACTORS ASSOC W/RPTD INCREASED RATE. SIMILAR FINDINGS WERE (SUPDAT) Medical Cond Aggravated by Exposure:ANY CONDITION GENERALLY AGGRAVATED BY MECHANICAL IRRITANTS IN AIR/ON SKIN. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:WASH W/SOAP & RUNNING WATER. EYES:FLUSH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THIS PROD WILL BURN & SHOULD NOT BE LEFT EXPOSED. UNDER CERTAIN FIRE CNDTNS; COMBUST GASES CAN BE GENERATED CREATING RAPIDLY SPREADING, HIGH INTENSITY (SUPDAT) ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF IRRIT OCCURS/TLV IS EXCEEDED NIOSH/MSHA APPROVED RESPIRATOR SUCH AS 3M MODEL 9900, MODEL 8710, OR EQUIVALENT FOR PROTECTION AGAINST NUISANCE DUSTS. Ventilation:AMBIENT. Other Protective Equipment:LONG SLEEVED, LOOSE FITTING CLOTHING, LONG PANTS. EYE PROT: W/SIDESHIELDS . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:FLAMES & DENSE, BLACK SMOKE. MATLS TO AVOID:DIMETHYL SULFOXIDE, & DIMETHYL FORMAMIDE. EFTS OF OVEREXP:NOT RPTD REGARDING EMPLOYEES IN TEXTILE FIBER MFG PLANTS. ANIMAL STUDIES HAVE NOT DEMONS TRATED AN INCREASED RATE OF LUNG CANCERWHEN ANIMALS BREATHED LG QTYS OF GLASS FIBERS. ARTF IMPLANTATION OR (ING 3) ================== Physical/Chemical Properties ================== Solubility in Water:INSOLUBLE Appearance and Odor:WHITE OR CREAM COLORED SOLID WITH A WHITE FIBERGLASS FACING, AND WITH NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETONE, METHYL ETHYL KETONE, TETRAHYDROFURAN, CHLORINE, CHLOROFORM, HYDROGEN PEROXIDE, ETHYLENE DICHLORIDE, (SUPDAT) Stability Condition to Avoid:SOURCES OF IGNITION. Hazardous Decomposition Products:PRIMARILY CO, CO*2. SOME HCN POSSIBLE UNDER CERTAIN CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. THE PRIMARY METHOD OF DISPOSAL IS IN A MUNICIPAL OR INDUSTRIAL LANDFILL.
1
eyes_protection_mandatory