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===================== Product Identification ===================== Product ID:PIP 194 ABS PIPE CEMENT BLACK CAGE:14703 CAGE:14703 ============= Composition/Information on Ingredients ============= Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 70-80% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE DERMATITIS, IRRITATION AND DRYNESS OF MUCOUS MEMBRANES AND SKIN ON PROLONGED BREATHING OF MIST OR VAPORS OR PROLONGED AND REPEATED CONTACT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:IRRITATION AND/OR DRYNESS OF SKIN, SORE THROAT, LACRIMATION, SYMPTOMS SIMILAR TO ALCOHOL INEBRIATION AND IN HIGHER CONCENTRATIONS NARCOTIC EFFECTS. Medical Cond Aggravated by Exposure:DERMATITIS, BRONCHITIS, COMMON COLDS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE PATIENT TO WELL-VENTILATED AREA, AWAY FROM EXPOSURE TO FUMES. SKIN: WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND WATER. USE MOISTURIZING CREAMS FOR EXTREME DRYNESS OF SKIN. EYES: FL USH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:23F,-5C Lower Limits:2% Extinguishing Media:CHEMICAL FIRE EXTINGUISHER, CARBON DIOXIDE OR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. VAPS ARE HVR/AIR & MAY TRAVEL ALONG GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, FLAMES, SPARKS, HEATERS, ELEC MOTORS, STATIC(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE ABSORBENT SWEEPING COMPOUND OR SAND TO ABSORB LIQUID SPILL. PLACE ABSORBED MATERIAL IN METAL CANS OR CONTAINERS. WASH DOWN SPILL AREA WITH WATER THOROUGHLY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS AWAY FROM HEAT, SPARKS, OR OTHER IGNITION SOURCES. STORE IN A COOL, DRY PLACE. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT TAKE INTERNALLY; HARMFUL OR FATAL IF SWALLOWED. DO NOT SMOKE IN OR NEAR AREAS OF USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:EXHAUST FANS IN CLOSED QUARTERS. Other Protective Equipment:NONE REQUIRED UNDER NORMAL USE. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE EATING OR SMOKING. DO NOT SMOKE WHILE USING OR APPLYING MATERIAL. Supplemental Safety and Health EXPLOSION HAZARDS: ELECTRICITY, SMOKING OR OTHER IGNITION SOURCES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:175F,79C Vapor Pres:70 @ 68F Vapor Density:2.5 Spec Gravity:0.89 (H*2O=1) Evaporation Rate & Reference:5.7 (BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK LIQUID, PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, KETONES, AND OTHER TOXIC GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE CONTAMINATED ABSORBENT IN LANDFILL IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS OF ENVIRONMENTAL CONTROL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:300/QR CAGE:IO291 CAGE:IO291 CAGE:4E271 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-AMINO-; (ETHANOLAMINE,2-AMINOETHANOL, MONOETHANOLAMINE).VP: 0.2 @ 68F.VAP DENS: 2.1. CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 5-9% OSHA PEL:3 PPM ACGIH TLV:3 PPM; 6 STEL Ingred Name:ETHANOL, 2-BUTOXY-; (GLYCOL ETHERS (2-BUTOXYETHANOL)) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 9% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: DIRECT CONTACT MAY CAUSE IRRIT SEEN AS REDNESS & SWELLING. INGEST: MAY CAUSE GASTROINTESTINAL IRRIT & PAIN OR DISCOMFORT IN THE MOUTH, THROAT & STOMACH. SKIN: PRLNGD/RPTD CONTACT MAY CAUSE IRRIT SEEN AS REDNESS. 2-BUTOXYETHANOL MAY BE ABSORBED IN HARMFUL AMOUNTS. INHAL: EXCESS INHAL OF MISTS MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CAUSE RESPIRATORY IRRIT & CAUSE COUGHING & DISCOMFORT IN THE NOSE, THROAT & CHEST. ACUTE OVEREXP TO 2-BUTOXYETHANOL MAY CAUSE LETHARGY & DROWSINESS. CHRONIC: ANIMAL STUDIES HAVE SHOWN DOSE-RE LATED ADVERSE EFFECTS ON THE CNS, HEMATOPOIETIC TISSUES, BLOOD, LIVER & KIDNEYS ASSOCIATED W/THE ADMINISTRATION (SUPDAT) Medical Cond Aggravated by Exposure:ETHANOLAMINE MAY AGGRAVATE ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY ALSO AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES LIFTING UPPER & LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION. INHAL: IF AFFECTED, REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. SKIN: WASH WITH MILD SOAP& WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INGEST: IF CONSCIOUS, DILUTE BY GIVING AT LEAST TWO GLASSES OF WATER. CALL MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON SOLID ABSORBENT AND SHOVEL INTO CONTAINERS FOR DISPOSAL. LARGE SPILLS - VENTILATE THE AREA WELL. SOAK UP ON SOLID ABSORBENT AND SHOVEL INTO CONTAINERS FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BETWEEN 40-120F. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. NIOSH APPROVED RESPIRATOR IF TLVS ARE EXCEEDED. Ventilation:MECHANICAL (GENERAL) NORMALLY SUFFICIENT. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:AVOID BREATHING SPRAY MIST. Supplemental Safety and Health EFTS OF OVEREXP: OF 2-BUTOXYETHANOL (EXTRACTED FROM DHHS (NIOSH) PUB 90-118) . CHRONIC EXPOSURE MAY CAUSE BLOOD EFFECTS & LIVER OR KIDNEY INJURY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:30.0F,-1.1C Vapor Pres:SEE ING 1 Vapor Density:SEE ING 1 Spec Gravity:1.029 (H*2O=1) Evaporation Rate & Reference:1.0 (H*2O=1) Solubility in Water:COMPLETE Appearance and Odor:BLUE GREEN LIQUID; CITRUS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND ACIDS. Stability Condition to Avoid:FREEZING. Hazardous Decomposition Products:THERMAL DECOMPOSITION CAN PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE ACCORDING TO FEDERAL, STATE, AND LOCAL LAWS AND 40 CFR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:23831087 H611 HYDROCHLORIC ACID 33-40% CAGE:70829 CAGE:1K925 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN CHLORIDE CAS:7647-01-0 RTECS #:MW4025000 Minumum % Wt:33. Maxumum % Wt:40. OSHA PEL:C7 MG/M3;C5 PPM ACGIH STEL:C7.5 MG/M3;C5 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:60. Maxumum % Wt:67. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RABBIT): 900 MG/KG(SEE SUPP) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CORROSIVE. INHALATION: INFLAMMATION OF THE NOSE, THROAT & UPPER RESPIRATORY TRACT, PULMONARY EDEMA, CIRCULATORY FAILURE & DEATH. INGESTION: BURNS OF THE MOUTH, THROAT, ESOPHAGUS & GASTROINTESTINAL TRA CT. MAY BE FATAL IF SWALLOWED. SKIN: SEVERE BURNS, LIQUID MAY CAUSE DEEP ULCERS & DISCOLORING OF THE SKIN. EYES: IRRITATING, MAY CAUSE DAMAGE. SEVERE BURNS & PERMANENT DAMAGE. LONG TERM EXPOSURE TO VA PORS MAY CAUSE EROSION TO TEETH. Explanation of Carcinogenicity:HYDROGEN CHLORIDE IS IARC CATEGORY 3 Effects of Overexposure:COUGHING, CHOKING, INFLAMMATION, PAIN, BURNS, NAUSEA, VOMITING, DIARRHEA, REDNESS, TEETH EROSION. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS/EYE DISEASE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. INGESTION: DON'T INDUCE VOMITING. GIVE LARGE QUANTITIES OF WATER/MILK. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. SKIN: IMMEDIATELY FLU SH W/PLENTY OF WATER FOR 15 MINS. EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY. NEUTRALIZE W/SODA ASH/SLAKED LIME. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND/OTHER POSITIVE PRESSURE MODE. STAY AWAY FROM ENDS OF TANKS. COOL TANK S W/WATER SPRAY UNTIL WELL AFTER FIRE IS OUT. Unusual Fire/Explosion Hazard:EXTEME HEAT/CONTACT W/METALS CAN RELEASE FLAMMABLE HYDROGEN GAS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. ISOLATE AREA. KEEP UNNECESSARY/UNPROTECTED PERSONNEL FROM ENTERING. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. NEUTRALIZE & ABSORB W/INERT MATERIAL; VERMICULITE , DRY SAND/EARTH & PLACE IN A CHEMICAL WASTE CONTAINER. DON'T USE COMBUSTIBLE MATERIALS, SAWDUST. DON'T FLUSH TO SEWER. Neutralizing Agent:ALKALINE MATERIAL; SODA ASH, LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, VENTILATED STORAGE AREA W/ACID RESISTANT FLOORS & GOOD DRAINAGE. PROTECT FROM PHYSICAL DAMAGE. KEEP OUT OF DIRECT SUNLIGHT & AWAY FROM HEAT, WATER & INCOMPATIBLE MATERIALS. DON'T WASH OUT CONTAINER & USE IT FOR OTHER PURPOSES. USE ONLY W/ADEQUATE VENTILATION. Other Precautions:WHEN DILUTING, THE ACID SHOULD ALWAYS BE ADDED SLOWLY TO WATER & IN SMALL AMOUNTS. NEVER USE HOT WATER & NEVER ADD WATER TO THE ACID. WATER ADDED TO ACID CAN CAUSE UNCONTROLLED BOILING & SPLASHING. WH EN OPENING METAL CONTAINERS, USE NON-SPARKING TOOLS BECAUSE OF THE POSSIBILITY OF HYDROGEN GAS BEING PRESENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL FACEPIECE RESPIRATOR W/AN ACID GAS CARTRIDGE MAY BE WORN UP TO 50 TIMES THE EXPOSURE LIMIT/THE MAXIUMUM USE CONCENTRATION SPECIFIED BY THE APPROPRIATE REGULAT ORY AGENCY/RESPIRATOR SUPPLIER. FOR EMERGENCIES/INSTANCES WHERE THE EXPOSURE LEVELS ARE UNKNOWN, USE A FULL FACEPIECE POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR. Ventilation:LOCAL/GENERAL EXHAUST IS RECOMMENDED TO KEEP AIRBORNE EXPOSURES BELOW THE AIRBORNE. Other Protective Equipment:IMPERVIOUS BOOTS, APRON, COVERALLS, EYE WASH FOUNTAIN, QUICK DRENCH FACILITIES IN THE WORK AREA. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES/VAPORS/LIQUID. OBSERVE ALL WARNINGS & PRECAUTIONS LISTED FOR THE PRODUCT. DON'T GET IN EYES, ON SKIN/ON CLOTH ING. DON'T BREATHE VAPOR/MIST. ================== Physical/Chemical Properties ================== Boiling Pt:=108.9C, 228.F Melt/Freeze Pt:=-74.C, -101.2F Vapor Pres:190 pH:0.1 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS, FUMING LIQUID Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, STRONG BASES, METALS, METAL OXIDES, HYDROXIDES, AMINES, CARBONATES, ALKALINE MATERIALS, CYANIDES, SULFIDES, SULFITES, FORMADEHYDE Stability Condition to Avoid:HEAT, DIRECT SUNLIGHT Hazardous Decomposition Products:HYDROGEN CHLORIDE FUMES, CHLORINE FUMES, HYDROGEN GAS =================== Toxicological Information=================== Toxicological Information:HYDROCHLORIC ACID CONCENTRATED: INVESTIGATED AS A TUMORIGEN, MUTAGEN, REPRODUCTIVE EFFECTOR. ===================== Ecological Information ===================== Ecological:WHEN RELEASED INTO THE SOIL, THIS MATEIAL IS NOT EXPECTED TO BIODEGRADE. WHEN RELEASED INTO THE SOIL, THIS MATERIAL MAY LEACH INTO GROUNDWATER. THIS MATERIAL IS EXPECTED TO BE TOXIC TO AQUATIC LIFE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CAN NOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE & SENT TO A RCRA APPROVED WASTE FACILITY. DISPOSE OF CONTAINER & UNUSED CONTENTS IN ACCORDANCE W/FEDERAL, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:HYDROCHLORIC ACID; UN1789. ===================== Regulatory Information ===================== SARA Title III Information:SARA 311/312: ACUTE=YES, CHRONIC=YES. SARA 302/313: HYDROGEN CHLORIDE Federal Regulatory Information:CDTA & TSCA: HYDROGEN CHLORIDE ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: SLUDGEBUSTER TABLETS Cage: 8W008 Box: 7568 Proprietary Ind: Y ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 8W008 ======================================================= Contractor Summary ======================================================= Cage: 8W008 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: MAY CAUSE EYE & SKIN IRRITATION ON CONTACT. Explanation Of Carcinogenicity: NONE Signs And Symptions Of Overexposure: IRRITATION. First Aid: EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: DRINK 1-2 GLASSES OF WATER/MILK. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: TABLETS SHOULD BE SWEPT UP & PLACED IN AN ACCEPTABLE WASTE CONTAINER FOR DISPOSAL. Waste Disposal Methods: RECOVERED MATERIAL SHOULD BE DISPOSED OF BY INCINERATION/DEPOSITED IN LANDFILL IAW/FEDERAL, STATE & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN COOL DRY AREA. KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL USE ONLY. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER, FOAM, CO2, DRY CHEMICAL. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NEEDED W/NORMAL USE. Ventilation: NONE NEEDED W/NORMAL USE. ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.5 Solubility in Water: COMPLETE Appearance and Odor: YELLOW TABLET W/FLORAL FRAGRANCE. Percent Volatiles by Volume: 0 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: STRONG ACIDS & OXIDIZERS. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: SLUDGEBUSTER TABLETS Cage: 8W008 Company Name: PRECISIONAIRE INC Zipcode: 33734 Label Required IND: Y Date Of Label Review: 12/16/1998 Status Code: C Label Date: 12/16/1998 Origination Code: G Hazard And Precautions: MAY CAUSE EYE & SKIN IRRITATION ON CONTACT. IRRITATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BAR-RUST MULTI-PURPOSE EPOXY NO.: DV235 CNVT CAGE:0Y2E4 CAGE:0Y2E4 ============= Composition/Information on Ingredients ============= Ingred Name:AROMATIC AMINE VP= 4.30 RTECS #:AA1005464 < Wt:65. OSHA PEL:10 PPM (25MG/M3) ACGIH TLV:10 PPM (25MG/M3) Ingred Name:BUTYL ALCOHOL CAS:71-36-3 RTECS #:EO1400000 = Wt:6. OSHA PEL:50 PPM (150MG/M3) ACGIH TLV:50 PPM (150MG/M3) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:VM & P NAPTHA VP = 40 CAS:8032-32-4 RTECS #:OI6180000 = Wt:28. OSHA PEL:300 PPM (1350MG/M3) ACGIH TLV:1370 MG/M3;300 PPM Ingred Name:ETHYLENEDIAMINE VP= 10.70 CAS:107-15-3 RTECS #:KH8575000 < Wt:5. OSHA PEL:25 MG/M3;10 PPM ACGIH TLV:25 MG/M3;10 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:SKIN: IRRITANT. SEVERE BURNS. SENSITIZATION OR ALLERGIC REACTION, SUCH AS RASH OR HIVES. INHALATION: IRRITANT. LUNG INJURY. RESPIRATORY SENSITIZATION AND ALLERGIC REACTION SUCH AS ASTHMA. CENT RAL NERVOUS SYSTEM DAMAGE. EYES: IRRITANT, SEVERE BURNS. INGESTION:HARMFUL IF SWALLOWED. Effects of Overexposure:VAPOR OR SPRAY MIST OR SPATTERED MATERIAL CAN BE HARMFUL. IRRITATING TO EYES, SKIN AND IF INHALED, TO NOSE AND THROAT. EXCESSIVE OR PROLONGED INHALATION CAN CAUSE HEADACH, NAUSEA OR DIZZINESS. REPE ATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS IS ASSOCIATED WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL ABUSE, MISUSE OR OTHER MASSIVE EXPOSUREE TO SOLVENTS MAY CAUSE MULTI PLE ORGAN DAMAGE AND/OR DEATH. Medical Cond Aggravated by Exposure:SKIN, RESPIRATORY, ALLERGIES. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE NORMAL BREATHING. TREAT SYMPTOMATICALLY. SEE PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT PHYSICIAN IF IR RITATION PERSISTS. EYES: FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. INGESTIION: DRINK 1 OR 2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY MOU TH TO AN UNCONSCIOUS PERSON. DON NOT INDUCE VOMITING. CONTACT PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICCALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=37.8C, 100.F 100F Lower Limits:1 Upper Limits:11.20 Extinguishing Media:CO2, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT, SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT AND PRESSURE BUILD UP. ISOLATE FROM ELECTICAL EQUIPMENT, SPARKS, HEAT AND OPEN FLAME. VAPORS MAY SPREAD LONG DISTANCES, CAUSE FLASH FIRE ORIGNITE EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING VAPORS. VENTILATE AREA.USE ABSORBENT, INERT, CLEANUP MATERIALS.(DO NOT USE SAWDUST. ) REMOVE ABSORBENT MATERIAL WITH NON-SPARKING TOOLS. PLACE IN SEPARATE CONTAINER.KEEP OUT OF SEWERS AND WATERWAYS. IF ENTRY IS THREATENED OR OCCURS, NOTIFY LOCAL AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN USE. STORE IN COOL, DRY, WELL-VENTILATIED AREA. AVOID PROLONGED STORAGE TEMPERATURES ABOVE 100' F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA CERTIFIED RESPIRATOR. FOR SPECIFIC CONDITIONS, REFER TO CURRENT NIOSH POCKET GUIDE TO CHEMICAL HAZARDS. USE AIR-LINE RESPIRATORS IN CONFINED OR RESTRICTED VENTILATION AREAS.REFER TO 29 CFR, OSHA PARTS 1910 AND 1915 FOR COATING OPERATIONS. Ventilation:SUFFICIENT VENTILATION, IN VOLUME AND PATTERN, SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT CONCENTRATIONS BELOW TLV LIMITS. SOLVENT(S). Other Protective Equipment:FULL PROTECTIVE CLOTHING, SPARK PROOF EQUIPMENT. Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKIN, OR USING WASHROOM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health REMOVE WELDING OR FLAME CUTTING DECOMPOSITION PRODUCTS. REFER TO 29 CFR, OSHA PARTS 1910 AND 1915 FOR COATING OPERATIONS. ================== Physical/Chemical Properties ================== Boiling Pt:>100.C, 212.F B.P. Text:212-244F Vapor Density:>AIR Spec Gravity:8.0 LBS/GALLON VOC Pounds/Gallon:288 Evaporation Rate & Reference:LOW: 0.50; HI: 2.0 Appearance and Odor:LIQUID/SOLVENT ODOR Percent Volatiles by Volume:49.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS, ALKALIES. Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS. Hazardous Decomposition Products:CO, CO2. =================== Toxicological Information=================== Toxicological Information:VM & P NAPTHA: LC50 3400 PPM (INHALE RAT) ETHYLENEDIAMINE: LD50 0.70G/KG ;LC50 200 PPM ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN SEPARATE, APPROPRIATE, CLOSED CONTAINER IN ACCORDANCE WITH ALL APPLICABLE LOCAL, DSTATE, AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT BEEN TESTED BY TOXICITY CHARACTERISTIC. =================== MSDS Transport Information =================== Transport Information:DOT: PAINT UN# 1263 ===================== Regulatory Information ===================== SARA Title III Information:ALL INGREDIENTS ARE ON TSCA INVENTORY OR ARE EXEMPT. (SARA, CERCLA, HAPS) TOXIC CHEMICAL SUBJECT TO REPORTING REQUIRMENTS OF SARA AND CERCLA (40 CFR 302, 355, 372) OR HAPS (40 CFR 63) 1) BUTYL ALCOH OL2) ETHYLENEDIAMINE State Regulatory Information: ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:INTERGARD HS UNIV EPOXY DARK GRAY, FPR807 CAGE:26351 CAGE:26351 ============= Composition/Information on Ingredients ============= Ingred Name:BENZYL ALCOHOL. VP: 0.1 @ 20C. CAS:100-51-6 RTECS #:DN3150000 Fraction by Wt: 5-10% Ingred Name:AROMATIC PETROLEUM SOLVENT. VP: 10 @ 20C. CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 1-5% OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:2-HEPTANONE; (METHYL N-AMYL KETONE). VP: 2.1 @ 20C. CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 5-10% OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:EPOXY RESIN CAS:25036-25-3 Fraction by Wt: 5-10% Ingred Name:EPOXY RESIN CAS:25068-38-6 RTECS #:KC2100000 Fraction by Wt: 15-20% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, REDNESS, TEARING AND BLURRED VISION. SKIN: IRRITATING. MAY RESULT IN DERMATITIS. MAY CAUSE SENSITIZATION OR OTHER ALLERGIC RESPONSES. INHALATION: MAY CAUSE IRRITATION. INGESTI ON: MAY CAUSE GASTROINTESTINAL IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SKIN AND RESPIRATORY CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY WITH COPIOUS QUANTITIES OF WATER FOR AT LEAST 15 MINUTES.GET MEDICAL ATTENTION IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING, WASH SKIN WITH PLENTY OF SOAP AND WATER. LAUNDER CLOTHES BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NEEDED. GET MEDICAL ATTENTION. INGESTION: CALL PHYSICIAN IMMEDIATELY TO DETERMINE WHETHER OR NOT TO INDUCE VOMIT. ===================== Fire Fighting Measures ===================== Flash Point:107F,42C Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.SMOTHER FLAMES W/ONE OF ABOVE EXTING MEDIA.WATER MAY BE USED TO COOL UNOPENED CNTNRS,BUT MUST NOT BE(SUPDAT) Unusual Fire/Explosion Hazard:NONE KNOWN UNLESS OTHERWISE NOTED.CONTAINS FLAM SOLV.DO NOT USE IN AREAS WHERE SPARK OR OPEN FLAME ARE PRESENT.CLSD CNTNRS MAY EXPLO WHEN EXPOS TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID INHALATION OF VAPORS. VENTILATE AREA. CLEAN UP WITH ABSORBENT MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BUILDINGS DESIGNED & PROT FOR STOR OF LIQS W/NFPA CLASS GIVEN BY OSHA CLASS.AVOID BRTHG DUST CHIPS FROM SANDING/BLASTING SURFS COATED W/PROD. Other Precautions:CHRONIC OVEREXPOSURE TO, AND MISUSE OF, SOLVENTS HAS BEEN LINKED TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR/OPEN AREAS, W/UNRESTRICTED VENT, USE A NIOSH/MSHA APPRVD FILTER RESP TO REMOVE SOLID AIR-BORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLIC. IN RESTRICTED VENT AREAS, USE NIOSH/MSHA APPRVD RE SP I/A/W 29 CFR 1910.134 TO (SUPDAT) Ventilation:PROVIDE SUFF VENT, IN VOL & PATTERN, TO KEEP TLV & LEL OF HAZ INGS BELOW LIMITS SPECIFIED, & TO REMOVE DECOMP (SUPDAT) Other Protective Equipment:WEAR APPROPRIATE IMPERVIOUS PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE, WASH HANDS BEFORE EATING OR SMOKING. Supplemental Safety and Health FIRE FIGHT PROC: USED AS AN EXTINGUISHING MEDIA. TAKE CARE TO PREVENT SPREAD OF BURNING LIQUID WITH WATER. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. RESPIRATORY PROTECTION: REMOVE A COMBINATION ON PARTICULATES AND VAPORS.VENTILATION: PRODUCTS DURING WELDING OR FLAME CUTTING ON SURFS COATED W/PRODUCT. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>300F,>149C Vapor Pres:SEE ING Vapor Density:HVR/AIR Spec Gravity:1.7 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:11 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:STORE AWAY FROM DIRECT HEAT, FLAME OR SPARK. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, VARIOUS HYDROCARBON FRAGMENTS ALDEHYDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE UNOPENED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON BLACK, N-907 STAINLESS CAGE:JO712 CAGE:JO712 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK (NON ACTIVATED, MINERAL ORIGIN) (CONTAINING ING 2) CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 100% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:POLYNUCLEAR AROMATIC HYDROCARBONS (PAH) Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPP DATA:CAN RSLT IN FIRE/EXPLO. CARBON BLACK MIXED W/FATTY OILS/SODIUM CAN UNDERGO SPONT HEATING. MAY REACT (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:VIOLENTLY W/NITRIC ACID. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:STUDY DESIGN & METHODOLOGY, LACK OF APPROP CONTROLS FOR CIGARETTE SMOKING & OTHER CONFOUNDING (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:FACTORS SUCH AS CONCURRENT EXPOS TO CARBON MONOXIDE, COAL OIL & PETRO VAPS. MOREOVER, REVIEW OF THESE (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:STUDIES INDICATES THAT WORK ENVIRON CONCS OF CARBON BLACK WERE CONSIDERABLY GREATER THAN CURRENT OCCUP (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:EXPOS STDS. ANIMAL:IN NON-ADSORBED FORM, SOME POLYNUCLEAR AROMATIC HYDROCARBONS HAVE BEEN FOUND TO BE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CARCINS IN ANIMAL STUDIES. NO CORRELATING CARCIN EFT, HOWEVER, HAS BEEN OBSERVED IN HUMANS DUE TO EXPOS TO(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CARBON BLACK. CHRONIC INFLAMM, LUNG FIBROSIS & LUNG TUMORS HAVE BEEN OBSERVED IN SOME RATS EXPTLY EXPOS, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:FOR LONG PERIODS OF TIME, TO EXCESSIVE CONCS OF CARBON BLACK & SEVERAL OTHER INSOL FINE DUST PARTICLES. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:MANY RESEARCHERS CONDUCTING RAT INHAL STUDIES BELIEVE THAT THESE EFTS MOST LIKELY RSLT FROM MASSIVE ACCUM(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:OF SM DUST PARTICLES IN LUNG WHICH OVERWHELM NATURAL LUNG CLEARANCE MECHANISMS, KNOWN AS "LUNG OVERLOAD" (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:PHENOMENON, RATHER THAN FROM SPECIFIC CHEMICAL EFFECT OF DUST PARTICLES IN LUNG. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:INHAL OF ACUTE CONCS MAY CAUSE TEMPORARY DISCOMFORT TO NOSE & RESP TRACT. INGEST/SKIN:NO CONSEQUENCES. EYE:MAY CAUSE IRRIT AT HIGH DUST LEVELS. TARGET ORGANS:LUNGS & RESP SYS. CHRONIC:HUMA N:EPIDEMIOLOGICAL STUDIES OF WORKERS INCARBON BLACK PRDCG INDUSTRIES OF NORTH AMERICA & WESTERN EUROPE(EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 149, 1996:GROUP 2B. Effects of Overexposure:HLTH HAZ:SHOW NO EVID OF CLINICALLY SIGNIFICANT, ADVERSE HLTH EFTS DUE TO OCCUP EXPOS TO CARBON BLACK. EARLY STUDIES IN FORMER USSR & EASTERN EUROPE RPT RESP DISEASES AMONG WORKERS EXPOS TO CARBON BLA CK, INCL:BRONCH, PNEUMOCONIOSIS, EMPHYSEMA & RHINITIS. THESE STUDIES ARE OF QUESTIONABLE VALIDITY, DUE TO INADEQ (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE FROM EXPOSURE. SKIN:WASH W/SOAP & WATER FOR HYGIENIC PURPOSES. EYES:RINSE W/WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER MIST OR NOZZLE JET TO COOL BELOW IGNITION POINT &/OR EXCLUDE AIR BY PURGING W/CO*2 OR OTHER INERT GAS. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. BE AWARE OF POSS ASPHY HAZ. HAVE AIR SUPPLY AVAIL. SODIUM (NA) IONS IN CARBON BLACK SUPPORT COMBUSTION AT(SUPDAT) Unusual Fire/Explosion Hazard:FLAMMABILITY:IGNITION IN AIR ABOVE 315C. HAZARDOUS GASES/VAPORS PRODUCED IN FIRE ARE CARBON MONOXIDE & CARBON DIOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM UP POWDER, OR SPRAY W/WATER FOG & SWEEP INTO SUITABLE CONTAINER. DO NOT SWEEP DRY TO AVOID TLV. WEAR APPROPRIATE PROTECTIVE EQUIPMENT FOR DUST LEVELS OBTAINED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CHECK FOR ADEQUATE OXYGEN LEVELS & ELEVATED LEVELS OF CO BEFORE ENTERING CLOSED VESSELS OR CONFINED SPACES. Other Precautions:SHELF LIFE: INDEFINITE IF STORED UNDER COVER IN ORIGINAL PACKAGING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED DUST MASK FOR EXTENDED EXPOS; NIOSH APPRVD DUST PROT RESP WHEN CARBON BLACK DUST EXCEEDS LIMIT OF 3.5 MG/M3 TO 17.5 MG/M3; NIOSH APPRVD FULL FACE/POWERED AIR RESP/SUPPLIED AIR/SCBA WHEN LEVELS EXCEED 17 MG/M3. Ventilation:SUFFICIENT VENTILATION, IN VOLUME & PATTERN, TO MAINTAIN EXPOSURE LEVELS BELOW TLV. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING OR FOOTWEAR ARE NOT REQD. Work Hygienic Practices:WASH EXPOSED SKIN DAILY W/MILD SOAP/DETERGENT. WASH EXPOSED CLOTHING DAILY. Supplemental Safety and Health FIRE FIGHT PROC:EXTREME SLOW RATE, FIRES PERSIST ONLY W/DULL RED GLOW UNDER SURF. DUE TO THERMAL INSULATION PROPERTIES OF CARBON, FIRES MAY CONTINUE UNDETECTED FOR EXTENDED PERIODS OF TIME. AVOID APPL YING DIRECT FLAME/SPKS INTO CARBON BLACK. MATLS TO AVOID:W/OXIDIZING AGENT (I.E., CHLORATES, BROMATES & NITRATES)(ING 3) ================== Physical/Chemical Properties ================== Spec Gravity:1.7-1.9 Solubility in Water:INSOLUBLE Appearance and Odor:SOLID, DARK GREY PELLETS OR POWDER; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPAT W/STRONG OXIDIZERS. CARBON BLACK CAN REACT W/OXIDIZING AGENTS. FINELY DIVIDED CARBON INTIMATELY MIXED (SUPDAT) Stability Condition to Avoid:PRODUCT IS STABLE UNDER NORMAL CONDITIONS. CARBON BLACK CAN IGNITE WHEN EXPOSED TO EXCESSIVE HEAT. Hazardous Decomposition Products:HAZARDOUS DECOMPOSITION PRODUCTS ARE CARBON MONOXIDE & CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W ALL FEDERAL, PROVINCIAL STATE & LOCAL REGULATIONS. SPILLED CARBON BLACK IS NOT CLASSIFIED AS HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RUST INHIBITIVE COATING CAGE:72988 CAGE:72988 ============= Composition/Information on Ingredients ============= Ingred Name:RESIN Fraction by Wt: 17% Ingred Name:FISH OIL Fraction by Wt: 11% Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 23% Other REC Limits:10 MG/M3 AS DUST OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:ZINC CHROMATE - AS CR CAS:37300-23-5 RTECS #:GB3300000 Fraction by Wt: 1% Other REC Limits:0.1 MG/M3 AS DUST Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN 1% CRYSTALLINE SILICA CAS:61790-53-2 RTECS #:HL8600000 Fraction by Wt: 6% Other REC Limits:0.08 MG/M3 AS DUST OSHA PEL:20 MPPCF ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 5 MM HG) (TOXICITY: 5 G/KG (ORAL)) CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 25% Other REC Limits:120 PPM Ingred Name:MAGNESIUM SILICATE CAS:14807-96-6 RTECS #:VV7720000 Fraction by Wt: 11% Other REC Limits:2 MG/M3 AS DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Health Hazards Acute and Chronic:INHALATION: DIZZINESS, NAUSEA, UNCONSCIOUSNESS. IRRITATING TO SKIN AND EYES. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NECESSARY. SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER. CONSULT PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:105F,41C Lower Limits:1 Extinguishing Media:FOAM, CO2, DRY CHEMICAL. Unusual Fire/Explosion Hazard:WATER NOT SUITABLE EXTINGUISHING MEDIUM. FIRE FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SMALL SPILLS ON DRY ABSORPTION MEDIA. USE SPARK-PROOF SCOOP FOR LARGER SPILLS. ENSURE ADEQUATE VENTILATION. REMOVE OPEN IGNITION. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT OR OPEN IGNITION SOURCES. Other Precautions:NPCA-HMIS RATING 3,2,0,H. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:VAPOR CARTRIDGE MASK OR AIR-SUPPLIED HOOD. Ventilation:SUFFICIENT TO ENSURE LEL NOT ACHIEVED. Other Protective Equipment:PROTECT SKIN WITH CLOTHING OR BARRIER CREAM. Supplemental Safety and Health PROLONGED EXPOSURE TO DUST FROM SANDING, GRINDING OR BLASTING MAY CAUSE LUNG DISORDERS. USE APPROPRIATE PROTECTION DURING THESE OPERATIONS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:323 TO 390F Vapor Density:>AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:43 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Hazardous Decomposition Products:CARBON DIOXIDE OR CARBON MONOXIDE ON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:AS PER LOCAL AND FEDERAL REGULATIONS FOR HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:414 CAGE:91491 CAGE:91491 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON 14 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health SOURCE OF DATA-MIL HANDBOOK 600-1SEP 76.SAFETY & HEALTH DATA DEVELOPED BY DGSC-STF. ================== Physical/Chemical Properties ================== HCC:A3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH DOD REGULATIONS AND FEDERL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WM-1, NEOPRENE SYNTHETIC RUBBER CAGE:IN612 CAGE:IN612 CAGE:1N612 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLOROPRENE/POLYCHLOROBUTADIENE; (POLYCHLOROPRENE, POLY-2-CHLOROBUTADIENE-1,3) Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:VAPORS OR FUMES MAY BE HARMFUL AND IRRITATING TO UPPER RESPIRATORY TRACT. SKIN:NO IRRITATION. EYES:MECHANICAL IRRITANT TO EYES. INGEST:LOW ORAL TOXICITY. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES, REPEATEDLY HOLDING EYELIDS OPEN TO ENSURE PROPER IRRIGATION. CONSULT MD. SKIN:WASH AFFECTED AREA WITH SOAP AND WATER. LAUNDER CLOTHING BEFORE REUSE. INHA L:REMOVE TO FRESH AIR. KEEP WARM AND QUIET. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. CONSULT MD. INGEST:SEEK MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:500F,260C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . HYDROGEN CHLORIDE IS EVOLVED UNDER FIRE CONDITIONS. Unusual Fire/Explosion Hazard:POTENTIAL ELECTROSTATIC CHARGE BUILD-UP WHEN POURING CHIPS, GROUNDING OF EQUIPMENT IS RECOMMENDED. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLAGE AND TRANSFER TO A CLOSED CONTAINER FOR DISPOSAL. CONTAMINATED SURFACES CAN BE CLEANED WITH SOLVENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALING HEATED VAPORS OR FUMES. STORE IN A COOL PLACE. KEEP CONTAINERS TIGHTLY CLOSED DURING STORAGE AND TRANSPORT. Other Precautions:READ BULLETIN NP-110.1, "TOXICITY AND HANDLING GUIDELINES FOR NEOPRENE" BEFORE USING NEOPRENE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE SHOULD BE USED WHEN VAPORS OR FUMES ARE GENERATED. Ventilation:VENT TO MAINTAIN FUME & VAP LEV W/IN EST SAFE STANDARD. IF LOC EXHAUST IS BEING USED, A CAPTURE VELOCITY OF (SUPDAT) Other Protective Equipment:CHEMICAL RESISTANT CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VENT:150-200 FPM IS RECOMMENDED. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NEGLIGIBLE Appearance and Odor:OFF WHITE CHIPS, MILD CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Stability Condition to Avoid:HEATING TO 392F (200C) OR HIGHER, HYDROGEN CHLORIDE IS EVOLVED AT THESE TEMPERATURES. Hazardous Decomposition Products:CO, HYDROGEN CHLORIDE, CO*2, SULFUR DIOXIDE, ORGANIC ACIDS, ALDEHYDES AND ALCOHOLS. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT A RCRA HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TONER FOR CLASS II AND CLASS III (BLACK),43 Preparer's Name:KRISTINA SAGE CAGE:54726 CAGE:54726 CAGE:29382 CAGE:4M009 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE ACRYLIC RESIN/POLYMER CAS:26655-10-7 Fraction by Wt: 74% Other REC Limits:NONE RECOMMENDED Ingred Name:STYRENE, ACRYLATE COPOLYMER/POLYMER CAS:25213-39-2 Fraction by Wt: 13% Other REC Limits:NONE RECOMMENDED Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 11% Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:DYE CAS:84179-66-8 Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED Ingred Name:DYE (CAS NO. 109125-50-0) Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED Ingred Name:DYE (CAS NO. 109125-51-1) Fraction by Wt: <2% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR CARBON BLACK IS 3.5 MG/M3. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE- MAY CAUSE TEMPORARY EYE DISCOMFORT. PROLONGED/REPEATED SKIN CONTACT MAY CAUSE MILD IRRITATION. INHALATION OF DUST CAUSES GASPING. INGESTION PRACTICALLY NON-TOXIC. CHRONIC- LONG TERM EXPOSURE TO DUST MAY CAUSE "LUNG OVERLOADING". Effects of Overexposure:MAY CAUSE TEMPORARY EYE DISCOMFORT. PROLONGED/REPEATED SKIN CONTACT MAY CAUSE MILD IRRITATION. INHALATION OF DUST CAUSES GASPING. INGESTION PRACTICALLY NON-TOXIC. LONG TERM EXPOSURE TO DUST MAY CAUSE "LUNG OVERLOADING". Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL CARE IF NEEDED. INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. SKIN: WASH WITH SOAP & WATER. INGESTION: DILUTE STOMACH CONTENTS WI TH SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. AVOID INHALATION OF SMOKE. Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. WHEN DISPERSED IN AIR, IT MAY FORM EXPLOSIVE MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP USING AN APPROVED TONER VACUUM CLEANER WITH A 0.5 MICRON FILTER (ATRIX AAA). USE OF A VACUUM CLEANER NOT RATED FOR TONER PARTICULATE COULD BE A POTENTIAL FIRE HAZARD AND/OR RESULT IN INJURY. RESIDUE CAN BE REMOVED WITH SOAP AND WATER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE- STORE IN COOL, DRY PLACE AWAY FROM OXIDIZING MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH EYES AND SKIN. AVOID PROLONGED INHALATION OF EXCESSIVE DUST. WASH THOROUGHLY AFTER HANDLING. DO NOT HANDLE IN AREAS WHERE WIND BLOWS. FLYING POWDER MAY ENTER EYES. AVOID GENERATING DUSTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING OR DRINKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:0.34 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK POWDER, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:FIRE Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND OTHER DECOMPOSITION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. DO NOT INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OS-11773,20227-BSE BWN EPOXY(DISCON W/O RPL Kit Part:Y CAGE:DO758 CAGE:DO758 CAGE:31850 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 35% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-ETHOXYETHANOL (EGEE) (SARA III) CAS:110-80-5 RTECS #:KK8050000 Fraction by Wt: 29% OSHA PEL:S,200 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BUTYL ALCOHOL Fraction by Wt: 19% ACGIH TLV:C,S,50PPM Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 17% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATING TO EYES AND SKIN. TOXIC IF INGESTED. ======================= First Aid Measures ======================= First Aid:REMOVE VICTIM FROM FURTHER EXPOSURE, FLUSH AFFECTED SKIN AREAS WITH WATER. WASH WITH MILD SOAP AND WATER. FLUSH EYES WITH GENTLE STREAM OF WATER FOR 15 MINS, SEE A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:41F,5C TCC ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP AWAY. VENTILATE ENCLOSED SPACES, OPEN ALL WINDOWS/DOORS. AVOID BREATHING VAPOR. ADD ABSORBENT TO SPILL AREA. RECOVER FREE LIQUID. KEEP CHEMICAL PRODUCTS OUT OF STREAM S AND WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE (EQUIVALENT OF OUTDOORS VENTILATION. Other Precautions:AVOID CONTACT WITH EYES AND PROLONGED O REPEATED CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR CANISTER-SUCH AS NIOSH APPRVD TC23C-OR AIR-SUPPLD MASK Ventilation:LOCAL EXHAUST NECESSARY-EXPLOSION PROOF TYPE. Supplemental Safety and Health BP:110-173C. THIS IS PART A OF A TWO PART KIT. THIS KIT IS AVAILABLE IN THREE SIZES: 1 GAL CAN, 5 GAL CAN, AND 55 GAL DRUM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:230-343F Vapor Density:>1.0 Percent Volatiles by Volume:68.0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:ABSORB ON SOLIDS AND INCINERATE. RUN-OFF TO WATERWAY CREATES FIRE HAZARD;NOTIFY FIRE AND HEALTH AGENCIES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:817 5432 3000 FIXER AND REPLENISHER PART A Preparer's Name:HEALTH AND ENVIRONMENTAL CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 40-50% Other REC Limits:NONE SPECIFIED Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: 40-50% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM ACETATE CAS:126-96-5 RTECS #:AJ4375000 Fraction by Wt: 5-10% Other REC Limits:NONE SPECIFIED Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM METABISULFITE CAS:7681-57-4 RTECS #:UX8225000 Fraction by Wt: 1-5% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 55-60% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >2450 MG/KG Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE IRRITATION OF SKIN AND EYES ON CONTACT. LOW OR MINMAL HAZARDS OTHERWISE. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:EYES: REDNESS, DISCOMFORT, ITCHING, TEARING. SKIN: RASH, DISCOMFORT, ITCHING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGESTED: IF CONSCIOUS, DRINK 1-2 GLASSES OF WATER, GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHES. EYES: FLUSH WITH WATER FOR 15 MINUTES. SEE DOCTOR. INH ALED: REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER. DISCHARGE MAY BE SUBJECT TO LOCAL, STATE AND FEDERAL REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED AND AWAY FROM STRONG ALKALIS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. Other Protective Equipment:AS NECESSARY TO PREVENT PROLONGED & REPEATED SKIN CONTACT. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. Supplemental Safety and Health PART A OF 2 PART PACKAGE. KEY 1: N1. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F/>100C Vapor Pres:18 MM HG Vapor Density:0.6 Spec Gravity:1.318 pH:5.0 Evaporation Rate & Reference:N/A (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:SLIGHTLY YELLOW SOLUTION, SLIGHT SULFUR DIOXIDE AND ACETIC ACID ODOR Percent Volatiles by Volume:64% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALI Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY EVOLVE SULFUR DIOXIDE & AMMONIA ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TEFLON-TE-3337 CAGE:DO229 CAGE:18873 CAGE:DO229 ============= Composition/Information on Ingredients ============= Ingred Name:ACID AMMONIUM SALTS,TYPE NOT SPECIFIED Fraction by Wt: <1% Ingred Name:POLYTETRAFLUOROETHYLENE,CAS# 9002-84-0 CAS:116-14-3 RTECS #:KX4025000 Fraction by Wt: 60% Ingred Name:COUPLINGAGENT,TYPE NOT SPECIFIED Fraction by Wt: 10% Ingred Name:2,4,6-TRINITROTOLUENE (TNT) CAS:118-96-7 RTECS #:XU0175000 Fraction by Wt: 5% OSHA PEL:S, 1.5 MG/M3 ACGIH TLV:S, 0.5 MG/M3; 9293 Ingred Name:ANTI-WETTING AGENT,TYPE NOT SPECIFIED Fraction by Wt: 5% ===================== Hazards Identification ===================== Effects of Overexposure:PTFE POLYMER,WHEN THERMALLY DECOMPOSED,MAY CAUSE POLYMER FUME FEVER,AND FLU-LIKE SYMPTOMS. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:NOT BURNABLE W/O EXTERNAL FUEL SOURCE(RATED 94 V-O BY U/L). Unusual Fire/Explosion Hazard:DRY TEFLON WILL BURN IN AN ATMOSPHERE OF 100% OXYGEN WHEN AN IGNITION SOURCE IS PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:DO NOT TOUCH SPILL MATL. SM SPILL:ABSORB W SAND,OTHER NON COMBUSTIBLES ABSORB; FLUSH W/H*2O LG SPILL:DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE.KEEP CONTAINERS CLOSED. MAINTAIN STANDARD HYGIENE FOR CHEM HANDLING Other Precautions:AVOID SKIN CONTACT(PH-10).FREEZNG CONDITIONS/ADDITIVES WHICH REDUCE PH,CAN CAUSE COAGULATION OF THE"TEFLON" DISPERSION.NOT APPRVD FOR FOOD-CONTACT APPLICATIONS.DO NOT CONTAM. TOBACCO UTENSILS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ADEQUATE VENTILATION;IN CONFINED AREAS,USE BUREAU OF MINES RESPIR. Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE VENTILATION Other Protective Equipment:NONE Supplemental Safety and Health NIOSH/ 6:1001685LE,LEVELING AGENT,5%,TLV-N/A.NIOSH 7:1001686LE,LUBRICANT EMULSION,5%,TLV-UNK.NIOSH 8:BO0875000,AMMONIA,CAS#7664-41-7,<1%,TLV-25 PPM;NIOSH9:ZC0110000,WATER,%-UNK,TLV-N/A. ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:1.5 Evaporation Rate & Reference:SAME AS WATER Solubility in Water:INSOLUBLE Appearance and Odor:MILKY SUSPENS/H*2O.PH-10.SLIGHT AMMONIACAL ODOR. Percent Volatiles by Volume:60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PRECIPITATED BY CATIONIC SURFACTANTS. Stability Condition to Avoid:STORE 60-80F TO MINIMIZE SETTLING. Hazardous Decomposition Products:HF & PERFLUOROCARBON OLEFINS EVOLVED ABOVE 250C/482F. ==================== Disposal Considerations ==================== Waste Disposal Methods:SM & LG SPILL:DEPOSIT IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TUNGSTIC ACID Resp. Party Other MSDS Num.:STICA CAGE:TO713 CAGE:TO713 ============= Composition/Information on Ingredients ============= Ingred Name:TUNGSTIC ACID. (SYNONYMS: ORTHOTUNGSTIC ACID, WOLFRAMIC ACID. CHEMICAL FORMULA: H2WO4. MOLECULAR WEIGHT: 249.86) CAS:11105-11-6 RTECS #:YO7840000 ACGIH TLV:5MG(W)/M3 ACGIH STEL:10MG(W)/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:WARNING: MAY BE HARMFUL IF SWALLOWED OR INHALED. CAUSES EYE IRRITATION. CHRONIC INHALATION HAZARD. INHALATION: MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. HIGHER CONCENTRATIONS OR PROLONGED INHALA TION MAY CAUSE PULMONARY FIBROSIS. INGESTION: MAY CAUSE GASTROINTESTINAL DISTURBANCES INCL DIARRHEA. DEATH MAY OCCUR FROM RESPIRATORY ARREST.SKIN CONTACT: MAY CAUSE IRRITATION. EYE CONTACT: MAY CA USE SEVERE IRRITATION, REDNESS, AND PAIN.CHRONIC EXPOSURE: PROLONGED OR REPEATED INHALATION OF TUNGSTEN SALTS MAY CAUSE PULMONARY FIBROSIS. PROLONGED OR REPEATED SKIN EXPOSURE OF TUNGSTEN SALTS MAY CAUSE DERMATITIS & OTHER SKIN DISORDERS. Effects of Overexposure:SEE HEALTH HAZARDS . Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: IF SWALLOWED, GIVE WATER OR MILK TO DRINK. GET MEDICAL ATTENTION IMMEDIATELY. NEVER GIVE ANYTHING BY MO UTH TO AN UNCONSCIOUS PERSON. SKIN EXPOSURE: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION DEVELOPS, GET MEDICAL ATTENTION. EYE EXPOSURE: WA SH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:SPECIAL INFORMATION: IN THE EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE P RESSURE MODE. Unusual Fire/Explosion Hazard:FIRE: NOT CONSIDERED TO BE A FIRE HAZARD. EXPLOSION: NOT CONSIDERED TO BE AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP PERSONNEL MAY REQUIRE RESPIRATORY PROTECTION FROM DUST. SPILLS: SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE: KEEP IN A TIGHTLY SEALED CONTAINER, STORED IN A COOL, DRY,VENTILATED AREA. HANDLING: PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A (NIOSH APPROVED) DUST TO TEN TIMES THE TLV. CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS. LOCAL EXHAUST VENTILATION (OTHER INFO) (SUPP SAFETY & HEALTH) Other Protective Equipment:WEAR CLEAN BODY-COVERING CLOTHING. MAINTAIN EYE WASH FOUNTAIN AND QUICH-DRENCH FACILITIES IN WORK AREA. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=1473.C, 2683.4F Melt/Freeze Pt:M.P/F.P Text:LOSES WATER @ 100C. Vapor Pres:NO INFO FOUND. Vapor Density:NO INFO. Spec Gravity:5.5 Evaporation Rate & Reference:NO INFO FOUND. Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW POWDER, SLIGHT SULFUR-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INCOMPATIBILITY DATA FOUND. Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:TUNGSTEN OXIDE FUMES. =================== Toxicological Information=================== Toxicological Information:NO LD50/LC50 INFORMATION FOUND RELATING TO NORMAL ROUTES OF OCCUPATIONAL EXPOSURE. IRRITATION DATA: EYE RABBIT 500MG/24H SEVERE. AIRBORNE EXPOSURE LIMITS: ACGIH THRESHOLD LIMIT VALUE (TLV): 5 MG(W)/ M3 (TWA). 10 MG(W)/M3 (STEL) FOR INSOLUABLE COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL: WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT HAZARD CLASS: NOT REGULATED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PENSOLV L805TS Resp. Party Other MSDS Num.:4771-506T CAGE:56883 Contract Num:SP0411-00-W-E006 CAGE:56883 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC HYDROCARBONS OR MEDIUM ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) CAS:64742-88-7 = Wt:100. Ingred Name:TERPENE HYDROCARBONS OR HYDROCARBONS, TERPENE PROCESSING BY-PRODUCTS CAS:68956-56-9 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:EYE:SLIGHTLY IRRITATING BUT DOES NOT INJURE EYE TISSUE. SKIN: FREQUENT OR PROLONGD CONTACT MAY IRRITATE OR DRY THE SKIN OR CAUSE DERMATITIS. SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS CONDITION . INHALATION: HIGH VAPOR/AEROSOL CONCENTRATIONS ARE IRRITATING TO THE RESPIRATORY TRACT, MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: ASPIRATION DURING INGESTION MAY CAUSE SEVERE AND DELAYED H EALTH EFFECTS SUCH AS INFLAMMATION OF THE LUNGS AND INFECTION OF THE BRONCHI. INGESTION MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT AND DIARRHEA. SEE TOXICOLOGICAL. FOR CHRONIC EFFECTS. Explanation of Carcinogenicity:NOT PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:EYES: SLIGHT IRRITATION. SKIN: IRRITATION, DRY SKIN, DERMATITIS. INHALATION: RESPIRATORY IRRITATION, HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, OTHER CNS EFFECTS. INGESTION: IRRITA TION OF DIGESTIVE TRACT, DIARRHEA. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS CONDITION. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH EYE WITH LARGE AMOUNTS OF WATER. SEE PHYSICIAN IMMEDIATELY. SKIN: FLUSH SKIN WITH LARGE AMOUNTS OF WATER. USE SOAP IF AVAILABLE. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. IF SK IN IRRITATION DEVELOPS OR PERSISTS, CONSULT PHYSICIAN. INHALATION: REMOVE PERSON TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. CALL A PHYSICIAN IMMEDIATELY. INGESTION: IF SWALLO WED, DO NOT INDUCE VOMITING. USE A STOMACH PUMP. CALL A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=40.6C, 105.F Lower Limits:ABOUT 1% Upper Limits:ABOUT 7.0% Extinguishing Media:EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED CONDITONS OR EXTNGUISH WITH WATER, FOAM, OR DRY CHEMICAL. COOL CONTAINERS WITH WATER SPRAY. Fire Fighting Procedures:EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED CONDITONS OR EXTNGUISH WITH WATER, FOAM, OR DRY CHEMICAL. COOL CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. CAN FORM COMBUSTIBLE MIXTURES AT OR ABOVE THE FLASH POINT. CONTAINERS CAN RUPTURE AND EXPLODE UNDER FIRE CONDITIONS DUE TO PRESSURE AND VAPOR BUILDUP. ================== Accidental Release Measures ================== Spill Release Procedures:LAND SPILL: ELIMINATE SOURCES OF IGNITION. USE ABSORBENT MATERIAL SUCH AS TOWELS OR ABSORBENT POWDERS. PUT ALL MATERIAL INTO PROPER WASTE DISPOSAL CONTAINER WITH LID TIGHTLY COVERED. SOLVENT SOAKED MA TERIAL, MAY SPONTANEOUSLY COMBUST. FOR LARGE SPILL, DIKE SPILL, RECOVER FREE LIQUID, AND USE ABSORBENT MATERIAL TO DRY AREA. PUT ALL MATERIAL INTO WASTE CONTAINERS. *SEE OTHER* Neutralizing Agent:NOT PROVIDED BY RESPONSIBLE PARTY. ======================Handling and Storage ====================== Handling and Storage Precautions:AMBIENT. DO NOT STORE ABOVE 120 DEG. F. Other Precautions:KEEP AWAY FROM HEAT SOURCES, OPEN FLAMES, AND OTHER IGNITION SOURCES. DO NOT STORE NEAR STRONG OXIDANTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AN ORGANIC VAPOR MASK SHOULD BE USED IF THE TLV IS EXCEEDED AND PARTICLE MASK IF THE PRODUCT IS SPRAYED. DO NOT MIST THIS PRODUCET. USE COARSE SPRAY ONLY. Ventilation:NONE NEEDED UNDER NORMAL USE CONDITIONS. FOR ENCLOSED AREAS, OR WHERE LARGE AMOUNTS OF THE PRODUCT ARE BEING USED, THE USE OF FANS OR OTHER MECHANICAL VENTILA CONDITIONS. SHIELD, RUBBER BOOTS, APRONS, GAUNTLETS, OR RAIN GEAR SHOULD BE WORN DEPENDING ON HOW THE PRODUCT IS USED. Work Hygienic Practices:NOT PROVIDED BY RESPONSIBLE PARTY. DLA-HMIS: LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health NOT PROVIDED BY RESPONSIBLE PARTY. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:>157.2C, 315.F B.P. Text:INITIAL 315F Vapor Pres:LESS THAN 5 Vapor Density:ABOUT 4 Spec Gravity:0.80 AT 75F VOC Pounds/Gallon:800 Evaporation Rate & Reference:0.1 N-BUTYL ACETATE=1 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR WATER-WHITE LIQUID; PINE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:THIS PRODUCT IS STABLE. Hazardous Decomposition Products:SMOKE, FUMES, AND OXIDES OF CARBON. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:NOT PROVIDED BY RESPONSIBLE PARTY. FROM ACUTE/CHRONIC: CHRONIC: INGESTION OF LARGE AMOUNTS OF TERPENE HYDROCARBONS HAS CAUSED KIDNEY & LIVER DAMAGE IN MALE RATS BUT NOT IN FEMALE RATS OR MICE OF BOTH SPECIES. ===================== Ecological Information ===================== Ecological:NOT PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:NOT PROVIDED BY RESPONSIBLE PARTY. =================== MSDS Transport Information =================== Transport Information:US DOT PROPER SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CONTAINS PETROLEUM DISTILLATES). HAZARD CLASS: COMBUSTIBLE LIQUID. IDENTIFICATION NUMBER: NA1993. PACKING GROUP: III. LABEL: NOT REQUIRED FOR N ON-BULK. DLA-HMIS: THIS NSN IS FOR AEROSOL CANS; THESE WOULD NOT BE REGULATED BASED ON THIS INFORMATION; BUT ONLY WHEN SHIPPED DOMESTIC OVERLAND. APPEARS WOULD BE REGULATED FOR INTERNATIONAL SHIPMENTS AS A FLAMMABLE AEROSOL OR CONSUMER COMMODITY. ===================== Regulatory Information ===================== SARA Title III Information:SARA 311/312 HAZARD CATAGORIES: ACUTE HEALTH, FIRE. SARA 313 REPORTABLE INGREDIENTS: NONE. Federal Regulatory Information:TSCA: THE INGREDIENTS OF THIS PRODUCT AS LISTED ON THE TSCA INVENTORY. CERCLA: THIS PRODUCT CONTAINS NO REPORTABLE CERCLA MATERIALS. CONTACT LOCAL AUTHORITIES TO DETERMINE IF THERE MAY BE OTHER LOCAL REPORTING REQUIREMENTS. RCRA HAZARD CLASS: D001 IGNITABLE HAZARDOUS WASTE. State Regulatory Information:NEW JERSEY RIGHT-TO-KNOW INFORMATION: THIS PRODUCT CONTAINS ALIPHTACI HYDROCARBONS (CAS# 64742-88-7) AND TERPENE HYDROCARBONS (CAS# 68956-56-9). CALIFORNIA PROPOSITION 65 INFORMATION: THIS PRODUCT DOE S NOT CONTAIN ANY CHEMICALS RECOGNIZED BY THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR BIRTH DEFECTS OR REPRODUCTIVE HARM. SCAQMD INFORMATION: IS THERE A PHOTOCHEMICALLY REACTIVE MATERIAL PRESENT: Y ES. WHAT IS THE % VOLUME OF THE PHOTOCHEMICALLY REACTIVE MATERIAL? ABOUT 15%. WHAT IS THE VOC CONTEN T? 800 G/L. WHAT IS THE VAPOR PRESSURE OF VOC'S? LESS THAN 5 MM HG. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEXTON II AUTOMATIC TRANSMISSION FLUID CAGE:12518 CAGE:12518 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM OIL CAS:64741-89-5 RTECS #:PY8041500 Fraction by Wt: <96% Other REC Limits:NONE RECOMMENDED Ingred Name:MINERAL OIL, SOLVENT REVFINED HEAVY PARAFFINIC, SEVERELY HYDROTREATED (NON-CARCINOGENIC - IARC) CAS:64741-88-4 RTECS #:PY8040501 Fraction by Wt: <95% Other REC Limits:NONE RECOMMENDED Ingred Name:ANTI-OXIDANT, ANTI-WEAR, DISPERSANT Other REC Limits:NONE RECOMMENDED Ingred Name:VISCOSITY IMPROVER Other REC Limits:NONE RECOMMENDED Ingred Name:DYE Other REC Limits:NONE RECOMMENDED Ingred Name:DIALKYLDITHIOPHOSPHORIC ACID, ZINC SALT Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION- MISTS OR FUMES MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. EYES- MILDLY IRRITATING. INGESTION- IRRITATING IF LARGE AMOUNTS ARE INGESTED. SKIN- IRRITATION, ERYTHEMA, EDEMA. CHRONIC: DRYIN G, CRACKING OR FOLLICULITIS. Explanation of Carcinogenicity:MIDDLE DISTILLATES HAVE CAUSED SKIN CANCER IN LABORATORY ANIMALS WHEN REPEATEDLY APPLIED AND LEFT IN PLACE. Effects of Overexposure:MAY CAUSE DEFATTING OF SKIN OR IRRITATION. INHALATION OF VAPORS MAY CAUSE IRRITATION OF THE NOSE AND THROAT, HEADACHE, NOUSEA AND DROWSINESS. INGESTION MAY CAUSE ABDOMINAL DISCOMFORT, NAUSEA, AND DIAR RHEA. Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION. EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:396F,202C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER MAY CAUSE FROTHING. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. AVOID BREATHING VAPOR. USE SELF-CONTAINED BREATHING APPARATUS. STOP FLOW. WIPE OR MOP UP OR ABSORB WITH DIATOMACEOUS EARTH OR OTHER INERT MATERIAL. STORE IN APPROPRIATE CONTAINER FOR D ISPOSAL. AVOID CONTACT WITH SKIN, EYES OR CLOTHING ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURES SHOULD BE MINIMIZED. AVOID WATER CONTAMINATION. Other Precautions:MISUSE OF EMPTY CONTAINERS CAN BE HAZARDOUS. EMPTY CONTAINERS CAN BE HAZARDOUS IF USED TO STORE TOXIC, FLAMMABLE, OR REACTIVE MATERIALS. CUTTING OR WELDING OF EMPTY CONTAINERS MIGHT CAUSE FIRE, EXPLOS ION OR TOXIC FUMES FROM RESIDUES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIRBORNE CONCENTRATIONS SHOULD BE KEPT TO LOWEST LEVELS POSSIBLE. IF VAPOR, MIST OR DUST IS GENERATED, USE RESPIRATOR APPROVED BY NIOSH AS APPROPRIATE. SUPPLIED AIR RESPIRATORY PROTECTION SHOULD BE US ED FOR CLEANING LARGE SPILLS OR TANKS. Ventilation:PROVIDE ADEQUATE VENTILATION TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CHEMICALLY RESISTANT BOOTS AND APRONS RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:621F,327C Vapor Pres:2.7E-4 Vapor Density:>1 Spec Gravity:0.87 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:RED LIQUID, SLIGHT ODOR. Percent Volatiles by Volume:NEG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:NONE Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES, AND COMBUSTION PRODUCTS OR COMPOUNDS OF P, S, & ZN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VP-31A PENETRANT (POST 10/86) NSN CANCELLED CAGE:98733 CAGE:98733 ============= Composition/Information on Ingredients ============= Ingred Name:DISTILLATE (PETROLEUM),HYDROTREATED MIDDLE; ON MSDS MFR SIMPLY NOTED AS "PETROLEUM HYDROCARBON" FOR ABOVE CAS NO. CAS:64742-46-7 RTECS #:JN9379645 OSHA PEL:5 MG/CUM ACGIH TLV:5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:YES Health Hazards Acute and Chronic:PER MANUFACTURER,MAY CAUSE SLIGHT IRRITATION TO SKIN ON CONTACT AND RESPIRATORY TRACT SYSTEM. Explanation of Carcinogenicity:CARCINOGENICITY OF THE PRODUCT FOR OSHA REQUIREMENTS IS SPECIFIED "YES" BY THE MFR BUT DID NOT SPECIFY THE COMPONENT. Effects of Overexposure:EYES:PRESUMED NON-IRRITATING;SKIN:SLIGHT IRRITATION ON LIQUID CONTACT;INHALATION:VAPORS OR OIL MIST MAY CAUSE MILD IRRITATION OF UPPER RESPIRATORT TRACT;INGESTION:MAY RESULT IN VOMITING. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH WATER.GET MEDICAL HELP IF IRRITATION OCCURS OR PERSISTS;SKIN:FLUSH WITH WATER FOR PERSISTING IRRITATION; INHALATION:REMOVE TO FRESH AIR.PROVIDE OXYGEN IF BREATHING IS DIFFICULT GET MED ATTN IF NEEDED; INGESTION:DO NOT INDUCE VOMITING.GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:188F/87C Extinguishing Media:WATER FOG,DRY CHEMICAL,CARBON DIOXIDE OR FOAM;DO NOT USE DIRECT STREAM OF WATER. Fire Fighting Procedures:IN CONFINED AREA,DO NOT ENTER WITHOUT A FULL BUNKER GEAR INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NOT KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM IGNITION SOURCES.WEAR APPROPRIATE PROTECTIVE CLOTHING & RESPIRATOR.DIKE & TRANSFER LIQ TO A SALVAGE TANK.SOAK UP RESIDUE WITH ABSORBENT CLAY,SAND OR OTHR MATL.PLACE RAGS & ABSORBED WASTE MATERL I N COVERED NON-LEAKING CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT/IGNITION SOURCES.STORE IN DRY,COOL,& VENTILATED LOCATION.DO NOT STORE NEAR OXIDIZING MATERIAL. AVOID PHYSICAL DAMAGE TO CANS. Other Precautions:MINIMIZE SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE EXCEEDS TLV,USE NIOSH APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. Ventilation:PER MANUFACTURER,PROVIDE LOCAL EXHAUST, OR MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV. Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS. Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,DRINKING,SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health VP-31A IS REPLACEMENT OF VP-31;THIS NSN WAS OF GROUP II UNDER MIL-I-25135,REV C.EFFECTIVE 88214,NSN HAS BEEN CANCELLED & REPLACED BY 6850-01-267-7988. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:>400F(>204C Spec Gravity:0.86 Solubility in Water:NEGLIGIBLE Appearance and Odor:DEEP REDDISH-PURPLE LIQUID,HYDROCARBON ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIAL. Stability Condition to Avoid:HEAT & IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE & OTHER UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE #D001,IGNITABLE WASTE.PLACE WASTE MATERIAL IN AN APPROPRIATE DISPOSAL FACILITY,OR DISPOSE OF IN COMPLIANCE WITH FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:"SCOTCHLITE" REFLECTIVE LIQUID 7210 SILVER CAGE:76381 CAGE:76381 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS BEADS (SARA III) CAS:65997-17-3 Fraction by Wt: 53-79% Other REC Limits:3M:10 MG/M3(AS DUST) Ingred Name:HYDROTREATED LIGHT PETROLEUM DISTILLATE CAS:64742-47-8 Fraction by Wt: 10-15% Other REC Limits:MFG: 300 PPM TWA Ingred Name:ALKYD RESIN CAS:68515-03-7 Fraction by Wt: 6-10% Other REC Limits:NONE RECOMMENDED Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC CAS:8030-30-6 RTECS #:DE3030000 Fraction by Wt: 5-8% Other REC Limits:MFG: 300 PPM TWA Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA CAS:64475-85-0 RTECS #:PY8240000 Fraction by Wt: 5-8% Other REC Limits:MFG: 100 PPM TWA Ingred Name:LEAD NAPHTHENATE (SARA III) CAS:61790-14-5 RTECS #:QK9150000 Fraction by Wt: 0.04% Other REC Limits:NONE RECOMMENDED Ingred Name:PETROLEUM DISTILLATES CAS:8002-05-9 RTECS #:SE7449000 Fraction by Wt: 0.03% Other REC Limits:NONE RECOMMENDED OSHA PEL:500 PPM TWA;400 PPM ACGIH TLV:400 PPM Ingred Name:VOC: 451.00 GMS/LITER RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION. INHALATION: IRRITATION. PROLONGED/REPEATED OVEREXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION: NOT LIKELY ROUTE OF EXPOSURE. IRRITATION OF GI TISSUE S. CENTRAL NERVOUS SYSTEM DEPRESSION. Effects of Overexposure:EYE:RED,SWELL,PAIN,TEAR,HAZY VISION.SKIN:RED,SWELL,ITCH.INHAL:NOSE/THROAT SORE,SNEEZE.HEADACHE,DIZZY,DROWSY,INCOORDINTN,SLOW REACT TIME,SLURRD SPEECH,GIDDY,UNCONSCIOUS.INGEST:PAIN,VOMIT,ABDOM TENDER,N AUSEA,BLOOD IN VOMIT/FECES.MUSCULR WEAK,INCOORDINTN,SLOW REACT TIME,FATIGUE,BLURRD VISION,TREMOR,SLURRD SPEECH,CONVULSN. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. GET IMMED MEDICAL AID. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRIT PERSISTS, GET MED AID. INHAL: REMOVE PERSON TO FRESH AIR. IF NOT BREATHING,GIVE ARTIF RESPIRATION. IF BREATHING DIFFICULT, GET IMMED MED AID. INGEST: CALL PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITING AT THE INSTRUCTION OF PHYSICIAN. NOTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:85.0F,29.4C Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM Fire Fighting Procedures:FULL PROTECT CLTHES:HELMET,SCBA/PRESSR DEMAND BREATH APPARATUS,BUNKER COAT,PANTS,BANDS,PROTECTV HEAD COVER.WATER INEFFECTIVE,USE TO KEEP FIRE EXPOSD CNTNR COOL. Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL LONG DISTANCES ALONG THE GROUND OR FLOOR TO AN IGNITION SOURCE AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:SEE MSDS FOR PHYSICAL,HEALTH HZD,RESP PROTECTN,VENT,PERSONAL PROTECT EQUIP INFO. CALL 612-733-1110/612-733-6100 FOR SPILL AID. VENT AREA,EXTINGUISH IGNIT SOURCE. CONTAIN. COVER W/INORGANIC ABSORBNT. C OLLECT. CLEAN UP.PLACE IN DOT APPRVD CNTNR & SEAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EYE CONTACT. KEEP CONTAINER CLOSED WHEN NOT IN USE. FLAMMABLE LIQUID & VAPOR. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME, IGNIT SOURCE. Other Precautions:GROUND CONTAINER SECURELY WHEN TRANSFERRING CONTENTS. WEAR LOW STATIC OR PROPERLY GROUNDED SHOES. WASH HANDS AFTER HANDLING AND BEFORE EATING. DO NOT INGEST. AVOID PROLONGED BREATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS & IN ACCORDANCE WITH OSHA REGS: 1/2 MASK ORGANIC VAPOR RESPIRATOR,FULL-FACE ORGANIC VAPOR RESPIRATOR,FULL FACE SUPPLIED AIR RSPRTR,FULL FACE PRESSURE DE MAND SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST VENT AT TRANSFR POINT.USE IN VENTD AREA.MAINTAIN BELOW TLV.IF EXHAUST VENT INADEQUATE USE RESP PROTECTION. Other Protective Equipment:* VINYL ALCOHOL, POLYVINYL ALCOHOL, POLYVINYL CHLORIDE. WEAR LOW STATIC OR PROPERLY GROUNDED SHOES. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:1.66 Viscosity:THIXOTROPIC Solubility in Water:INSOLUBLE Appearance and Odor:LIQUID, SILVER, SOLVENT ODOR Percent Volatiles by Volume:26.60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE, HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF WASTE PRODUCT IN A HAZARDOUS WASTE FACILITY. RECLAIM IF FEASIBLE. US EPA HAZARDOUS WASTE NO: D008 (LEAD), D001 (IGNITABLE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COOLANOL 35R DIELECTRIC HEAT TRANSFER FLUID CAGE:76541 CAGE:76541 ============= Composition/Information on Ingredients ============= Ingred Name:ORGANOSILICATE ESTER (PRODUCT OF REACTING SILICON TETRA CHLORIDE WITH ANHYDROUS ALCOHOL) Ingred Name:2,6-DI-TERT-BUTYL-P-CRESOL CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: 0.5% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3; 9192 Ingred Name:2-ETHYL-1-BUTANOL (PRESENT AS A PRODUCT OF HYDROLYSIS. SEE CASE HISTORY 85098H) CAS:97-95-0 RTECS #:EL3850000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL RAT LD50=>10,000 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS PRACTICALLY NON-TOXIC. DERMAL CONTACT IS SLIGHTLY IRRITATING. 6 HR INHALATION STUDIES HAVE SHOWN NO EFFECTS DUE TO THE LOW VOLITILITY OF THE PRODUCT AND THUS LOW EXPOSURE LEVELS. SEE SUPP D ATA. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:OTHER THAN SLIGHT IRRITATION, NONE WERE REPORTED. Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER 15 MIN. SKIN:REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE RE-USE. WASH PRODUCT FROM SKIN WITH SOAP AND WATER FLUSH. INHALED:REMOVE TO FRESH AIR. INGESTED:GET IMMEDIATE MEDICAL A TTENTION. IF IRRITATION FROM ANY CONTACT IS SEVERE OR PERSISTS,GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:350F,177C Autoignition Temp:Autoignition Temp Text:490F Extinguishing Media:WATER SPRAY,FOAM, DRY CHEMICAL, CARBON DIOXIDE OR ANY CLASS B EXTINGUISHING AGENT. Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS EXPOSED TO PRODUCTS OF COMBUSTION SHOULD WEAR FULL PROTECTIVE CLOTHING INCLUDING SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:PRODUCTS OF DECOMPOSITION MAY INCLUDE HAZARDOUS CARBON MONOXIDE, SILICON DIOXIDE, LOW MOLECULAR WEIGHT HYDROCARBONS AND SILICATE ESTERS. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN AND RECOVER LIQUID IF POSSIBLE. ABSORB ON CLAY,SAWDUST,ETC. IF NOT. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE TIGHTLY CLOSED IN AN AREA FREE FROM IGNITION SOURCES. PROTECT FROM MOISTURE. PRODUCT WILL HYDROLYZE. SEE SUPP DATA. Other Precautions:DO NOT EXPOSE TO MOISTURE AND HIGH TEMP ENVIRONMENTS WHICH MAY DETERIORATE PROD.;WATER AT HIGH TEMP CAUSES HYDROLYSIS;AVOID BREATHG VAP;WASH THOROUGHLY AFTER HANDLING.AVOID FIRE/IGN CONDITION ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NEEDED. USE NIOSH RESPIRATOR OR SUPPLIED AIR RESPIRATOR IF EXPOSED OVER TLV. Ventilation:NORMAL ROOM VENTILATION IS USUALLY SUFFICIENT. USE ADDITIONAL LOCAL EXHAUST AS NEEDED TO MAINTAIN EXPOSURE BELOW TLV. Other Protective Equipment:IF USE INVOLVS SPLASHING,ETC. USE APRONS, BOOTS,ETC. TO PREVENT PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID ANY UNNECESSARY EXPOSURE. Supplemental Safety and Health SEE DGSC-SLM CASE HISTORY 85098H. DESCRIBES EXPOSURE CASE HISTORY WITHIN DOD. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:0.009@149C Vapor Density:17 Spec Gravity:0.889 Viscosity:6.1-6.7CST Solubility in Water:VERY LOW Appearance and Odor:CLEAR OIL LIQUID, MILD, SWEET ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EXPOSURE TO HIGHLY OXIDIZING MATERIALS SHOULD BE AVOIDED. WATER AT HIGH TEMPERATURES WILL CAUSE HYDROLYSIS. Stability Condition to Avoid:RECOMMENDED MAXIMUM USE TEMPERATURE UNDER INERT CONDITIONS IS 350F. Hazardous Decomposition Products:NORMAL PRODUCTS O HYDROCARBON COMBUSTION PLUS SILCON DIOXIDE AND PARTIAL SILICATE ESTERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:370 CERAMIC BLANKET CAGE:3R434 CAGE:3R434 ============= Composition/Information on Ingredients ============= Ingred Name:FIBERS, REFRACTORY CERAMIC RTECS #:LK3628000 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CURRENTLY, THERE ARE NO KNOWN CHRONIC HLTH EFTS IN HUMANS FROM LONG TERM EXPOS TO REFRACTORY CERAMIC FIBERS. ANIMAL STUDIES TO DATE ARE INCONCLUSIVE. HOWEVER, BASED ON LTD TESTING, REFRACTORY CERAMIC FIBERS ARE SUSPECTED CARCIN IN LAB ANIMALS. THERMAL INSULATION MFR'S ASSOC (TIMA) IS SPONSORING ANIMAL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:INHAL STUDIES AS WELL AS EPIDEMIOLOGICAL STUDIES OF WORKERS IN INDUSTRY. UNTIL DEFINITE ANSWERS BECOME AVAIL, STRICT ADHERENCE TO REC SAFE WORK PRACTICES DESCRIBED ELSEWHERE IN THIS MSDS IS A DVISED. THIS PROD CONTAINS MINOR AMTS OF BINDERS WHICH BURN OUT DURING FIRST HEAT UP. THIS PROD AS MFRD IS AN (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:TERMINATE EXPOSURE. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEE K ASSISTANCE FROM MD . SKIN:FLUSHW/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST RESPIRATOR IN COMPLIANCE W/OSHA STANDARD CURRENTLY 29 CFR 1910.134 (NIOSH/MSHA APPROVED AIR PURIFYING, HALF MASK OR FULL FACEPIECE RESPIRATOR W/APPROPRIATE FILTER PAD OR CARTRIDGE(S). Ventilation:LOCAL EXHAUST &/OR MECHANICAL (GENERAL): FOLLOW OSHA STANDARD 29 CFR 1910.134. Other Protective Equipment:LONG SLEEVE, LOOSE FITTING CLOTHING & BARRIER CREAM. Work Hygienic Practices:ROUTINE HOUSEKEEPING. Supplemental Safety and Health EFTS OF OVEREXP:ALUMINOSILICATE WHICH COULD TRANSFORM UPON HEATING TO MULLITE & CRISTOBALITE (FORM OF CRYSTALLINE SILICA). REMOVAL OF THIS PROD AFTER USE MAY RSLT IN GENERATION OF DUST. RPTD INHAL OF RESPIRABLE FREE CRYSTALLINE SILICA DUSTMAY CAUSE DELAYED LUNG INJURY (SILICOSIS). ================== Physical/Chemical Properties ================== Spec Gravity:0.2-1.2(H*2O=1) Solubility in Water:INSOLUBLE Appearance and Odor:FIBER SHAPE; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GODDARDS LONG SHINE SILVER FOAM, 707085 CAGE:6N804 CAGE:6N804 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 1-3% OSHA PEL:400 PPM; 500 STEL ACGIH TLV:400 PPM; 500 STEL Ingred Name:SILICA Fraction by Wt: 25-35% OSHA PEL:2.6MG/M3 RDUST (MFR) ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:DIRECT CONTACT OF PRODUCT WITH EYES CAN CAUSE IRRITATION. PRODUCT MAY CAUSE DISTRESS AND ILLNESS IF TAKEN INTERNALLY. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINU TES. IF IRRITATION PERSISTS, SEEK MEDICAL AID. INGESTION: IF PRODUCT IS SWALLOWED, SEEK MEDICAL AID AT ONCE. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. Unusual Fire/Explosion Hazard:NO SPECIAL HAZARDS KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH OIL-DRI OR SIMILAR INERT MATERIAL. SWEEP OR SCRAPE UP AND CONTAINERIZE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GENERAL ROOM VENTILATION ADEQUATE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F,>93C Spec Gravity:6.4 (H*2O=1) pH:7.4 Solubility in Water:APPRECIABLE Appearance and Odor:BROWN PASTE WITH FRAGRANT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:WHEN EXPOSED TO FIRE, PRODUCES NORMAL PRODUCTS OF COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:NO SPECIAL METHOD. OBSERVE ALL APPLICABLE FEDERAL AND STATE REGULATIONS AND LOCAL ORDINANCES REGARDING DISPOSAL OF NON-HAZARDOUS MATERIALS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:831K087 DSO 420HS BAC 702 WHITE Kit Part:Y CAGE:83574 CAGE:85570 CAGE:83574 ============= Composition/Information on Ingredients ============= Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <5% Other REC Limits:150 PPM OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:NON-HAZARDOUS ADDITIVES, RESINS & PIGMENTS Fraction by Wt: 15% Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN BY IARC-GROUP 3) *94-3* CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 40% OSHA PEL:10 MG/CUM ACGIH TLV:10 MG/CUM (DUST) Ingred Name:BIS (1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL) SEPACATE CAS:41556-26-7 Fraction by Wt: <5% Ingred Name:TOLUENE (IARC - GROUP 3) *94-3* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <1% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VOLATILE ORGANIC COMPOUNDS: 416 G/L RTECS #:9999999VO Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE CAS:110-43-0 RTECS #:MJ5075000 Fraction by Wt: 10% Other REC Limits:50 PPM OSHA PEL:100 PPM ACGIH TLV:50 PPM Ingred Name:1,3-BENZENEDICARBOXYLIC ACID POLYMER (POLYESTER RESIN) CAS:85959-88-2 Fraction by Wt: 20% Ingred Name:METHYL PROPYL KETONE CAS:107-87-9 RTECS #:SA7875000 Fraction by Wt: 5% Other REC Limits:200 PPM OSHA PEL:200 PPM ACGIH TLV:200 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NASAL/RESPIRATORY IRRITATION, CNS DEPRESSION, ASPHYXIATION. SKIN: PROLONGED/REPEATED CONTACT CAUSES IRRITATION, DERMATITIS, SENSITIZATION IN SOME PEOPLE. EYES: IRRITATION. INGESTION: GI IR RITATION. CHRONIC: REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS CAUSES PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, DEFATTING, NAUSEA, VOMITING, DIARRHEA, CONCENTRATION DIFFICULTIES, DIMINISHED ACTUAL DEXTERITY, MEMORY LOSS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG & EYE CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NECESSARY. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. DON'T USE SOLVENTS. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTIO N IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:49F Lower Limits:1 Extinguishing Media:CO2, DRY CHEMICAL, FOAM Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & PROTECTIVE CLOTHING. WATER SPRAY MAY BE INEFFECTIVE BUT MAY BE USED TO COOL FIRE EXPOSED CONTAINERS. FOG NOZZLES PREFERRABLE. Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN INADEQUATELY VENTILATED/CONFINED AREAS, FORM EXPLOSIVE MIXUTRES W/AIR, TRAVEL TO DISTANT IGNITION SOURCES & FLASH BACK. (SEE SUPP) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR PERSONAL PROTECTIVE EQUIPMENT. USE NON-SPARKING TOOLS. SMALL: DIKE & ABSORB W/INERT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM HEAT/ELECTRICAL EQUIPMENT/SPARKS/FLAME. DON'T STORE >120F. Other Precautions:GROUND & BOND WHEN TRANSFERRING THIS MATERIAL. AVOID FREE FALL OF LIQUID. DON'T SMOKE WHERE MATERIAL IS USED/STORED. DON'T APPLY TO HOT SURFACES. DON'T CUT/PUNCTURE/WELD ON/NEAR EMPTY DRUM DUE TO EXPL OSIVE VAPORS IN DRUM. (SEE SUPP) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR IN AREAS WHERE TLVS MAY BE EXCEEDED/SPRAY MIST IS PRESENT. USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATORS IN CONFINED AREAS. Ventilation:GENERAL DILUTION/LOCAL EXHAUST IN VOLUME & PATTERN TO KEEP LEVEL OF CONTAMINANTS BELOW RECOMMENDED/REGULATED LIMITS. Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH, WASHING FACILITIES. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health KEY1:F2. UNUSUAL FIRE CONT'D: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. OTHER PRECAUTIONS CONT'D: DON'T TAKE INTERNALLY/DELIBERATELY CONCENTRATE/INHALE VAPORS. VAPORS ARE >AIR & MAY COLLECT IN LOW/CONFINED AREAS. DON'T ENTER W/O AIR MONITORING, SUPPLIED AIR RESPIRATOR, OBSERVER FOR ASSISTANCE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:213-300F Vapor Density:>1 Spec Gravity:1.45 Evaporation Rate & Reference:SLOWER THAN N-BU AC Appearance and Odor:WHITE LIQUID W/SOLVENT ODOR Percent Volatiles by Volume:41.8 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXTREME HEAT, TEMPS >120F, HEAT, SPARKS, FLAME. Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:ENSURE MATERIAL IS PACKAGED, STORED, TRANSPORTED/OTHERWISE MANAGED IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T CONTAMINATE GROUND/SURFACE WATER & POSE AN ENVIRONMENTAL/HUMAN HEALTH THREAT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PILE DRIVER CAGE:53798 CAGE:53798 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL,2-BUTOXY-;(2-BUTOXYETHANOL) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: <10% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:ETHANOL,2-AMINO-;(ETHANOLAMINE) CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: <2% OSHA PEL:3 PPM/6 STEL ACGIH TLV:3 PPM/6 STEL Ingred Name:ISOPROPYL ALCOHOL;(ISOPROPANOL) (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: <5% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500 STEL Ingred Name:PROPANE,2-METHYL-;(ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: <14% ACGIH TLV:800 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CAN CAUSE EYE & SKIN IRRITATION. CHRONIC: SKIN ABSORPTION OF 2-BUTOXYETHANOL MAY RESULT IN BLOOD ABNORMALITIES. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS TO CNS, HEMATOPOIETIC TISS UES,BLOOD,KIDNEYS & LIVER, ASSOC W/THE ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBEA)(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO 90-118). Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:GIVE SEVERAL GLASSES OF H*20 IMMED. AFTER H*20 HAS BEEN INGESTED,INDUCE VOMIT BY TOUCHING FINGER TO THROAT. DO NOT MAKE UNCON PERS VOMIT. GET MD ATTN IMMED. INHAL:REMOVE TO FRESH AIR. SUPPLY AR TF RESP IF BRTHG HAS STOPPED. GET MD ATTN IMMED. EYES:FLUSH EYES IMMED W/COOL H*20 FOR AT LEAST 15 MINS. SEE MD IMMED. SKIN:FLUSH AREA W/SOAP & H*20 FOR AT LEAST 15 MINS. SEE MD IF IRRIT PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point:SUPP DATA Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SHLD BE USED TO KEEP CNTNR COOL(<120F). FIREFIGHTERS SHLD BE SHIELDED FROM EXPLODING CANS. Unusual Fire/Explosion Hazard:HEAT ABOVE 120F MAY CAUSE CONTAINERS TO BURST. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB EXCESS MATERIAL WITH ABSORBENT OR RAG. RINSE RESIDUE WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE CAN ONLY IN UPSIDE DOWN POSITION. DO NOT STORE NEAR HEAT OR OPEN FLAMES. DO NOT STORE ABOVE 120F. DO NOT PUNCTURE/INCIN CANS. Other Precautions:WARNING: CAUSES EYE IRRITATION. CONTENTS UNDER PRESSURE. DO NOT USE OR STORE NEAR HEAT, SPARKS OR OPEN FLAMES. DO NOT PUNCTURE, INCINERATE, OR STORE ABOVE 120F. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHEN NORMAL VENTILATION AVAILABLE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NORMAL ROOM VENTILATION. DO NOT USE IN CONFINED AREAS WITH NO VENTILATION. Other Protective Equipment:A SOURCE OF CLEAN WATER SHOULD BE NEARBY IN CASE OF ACCIDENTAL EYE CONTACT. Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health FLASH POINT: <20.F, <-6.7C (PROPELLANT). ================== Physical/Chemical Properties ================== Spec Gravity:0.993 (H*20=1) pH:10.9 Solubility in Water:COMPLETE Appearance and Odor:AN AEROSOL SPRAY WITH FRESH CITRUS ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND STRONG ACIDS. Stability Condition to Avoid:HEAT (TEMPERATURES ABOVE 120F). Hazardous Decomposition Products:IN FIRE INVOLVING THIS PRODUCT, GASES MAY BE RELEASED SUCH AS OXIDES OF NITROGEN AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:GIVE TO WASTE DISPOSAL COMPANY EQUIPPED TO HANDLE PRESSURIZED CONTAINERS. DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CCR-6660 ULTRABASE 7 REDUCER CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ACETATE CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 30% Other REC Limits:400 PPM OSHA PEL:1400 MG/CUM ACGIH TLV:1400 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 52% Other REC Limits:150 PPM OSHA PEL:700 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 18% Other REC Limits:375 MG/CUM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WEIGHT PER GALLON IN POUNDS: 7.33 RTECS #:9999999WG Ingred Name:TOTAL VOC LESS WATER & EXEMPT SOLVENTS: 7.32 LBS/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION/RED/ITCHING & BURN. SKIN: ABSORPTION/IRRITATION/RED/ITCHING & BURN. INHALATION: RESPIRATORY IRRITATION/CNS DEPRESSION/UNCONSCIOUSNESS/DEATH/HEADACHE/DIZZINESS/NAUSEA/LOSS OF COORDINATI ON/AFFECTS LIVER/URINARY/BLOOD-FORMING/CARDIOVASCULAR/REPRODUCTIVE SYSTEM/HARMFUL/FATAL/PERMANENT BRAIN & CNS DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYE: IRRITATION/REDN/ITCHING & BURN. SKIN: ABSORPTION/IRRITATION/RED/ITCHING & BURN. INHALATION: RESPIRATORY IRRITATION/CNS DEPRESSION/UNCONSCIOUSNESS/DEATH/HEADACHE/DIZZINESS/NAUSEA/LOSS OF COORDINAT ION/AFFECTS LIVER/URINARY/BLOOD-FORMING/CARDIOVASCULAR/REPRODUCTIVE SYSTEM/HARMFUL/FATAL/PERMANENT BRAIN & CNS DAMAGE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:33F Lower Limits:0.7% Upper Limits:6.7% Extinguishing Media:CO2, DRY CHEMICAL & FOAM Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. USE WATER USED TO COOL CLOSED CONTAINERS. Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. CLOSED CONTAINERS MAY BUILD-UP PRESSURE, EXPLODE OR AUTOIGNITE WHEN EXPOSED TO EXTREME HEAT. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE W/INERT ABSORBENT. ELIMINATE IGNITION SOURCES. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALATION OF VAPOR OR SPRAY MIST & CONTACT W/SKIN & EYES. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE INTERNALLY. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE HARMFUL & FATAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING OR WELDING, WEAR A PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA. Ventilation:LOCAL EXHAUST/GENERAL Work Hygienic Practices:WASH HANDS AFTER USING. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T SMOKE. Supplemental Safety and Health BOILING RANGE: 163-392F. REPORTS HAVE ASSOCIATED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SEE SUPP. Vapor Density:>AIR Spec Gravity:0.87-0.91 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:95-100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAME, PILOT LIGHTS & OTHER IGNITION SOURCES Hazardous Decomposition Products:CO2, CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL BY INCINERATION IN COMPLIANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. DON'T INCINERATE CLOSED CONTAINER. TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. THIS PRODUCT MA Y BE HAZARDOUS AS DEFINED UNDER RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LIQUID CAUSTIC SODA 30% Preparer's Name:R KENNETH LEE,PROD SAFETY CAGE:6T510 CAGE:6T510 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 30% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA:DRINK LGE QTYS OF WATER OR ACIDIC BEVERAGE (TOMATO/ORANGE JUICE, CARBONATED SOFT DRINKS). DO NOT (SEE ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:INDUCE VOMITING. TAKE IMMED TO HOSP OR MD. IF VOMIT OCCURS, GIVE ADDITIONAL WATER. IF UNCON/IN CONVL, (SEE ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:TAKE IMMED TO HOSP. DO NOT ATTEMPT TO INDUCE VOMIT OR GIVE ANYTHING BY MOUTH TO UNCON PERS. NOTE TO MD:TREAT SYMP. RTECS #:9999999ZZ Ingred Name:SPILL PROC:W/DILUTE ACID. PROPERLY NEUTRALIZED LIQ RESIDUES (PH 6-9) MAY BE DISPOSED OF IN WASTE WATER (SEE ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:TREATMENT FACILITIES WHICH ALLOW DISCHARG OF NEUTRAL SALT SOLUTIONS. NEUT MATL CAN BE RECOVERED BY (SEE ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:VACUUM TRUCK FOR DISP. AFTER ALL VISIBLE TRACKS HAVE BEEN REMOVED, FLUSH AREA WAITH LARGE AMOUNT OF WATER. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PREC:EVEN IF IT APPEARS TO BE EMPTY.AVOID CONTACT W/ORGANIC MATLS & CONC ACIDS--MAY CAUSE VIOLENT(SEE ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:REACTION;CAUSTIC SODA REACTS W/MAGNESIUM, ALUMINUM, ZINC (GALVANIZED), TIN, CHRONIUM, BRASS/BRONZE, (SEE ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:GEN HYDROGEN WHICH IS EXPLO. HAZ CO GAS CAN FORM UPON CONTACT W/FOOD & BEVERAGE PROD IN ENCLOSED(SEE ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:VESSELS & CAN CAUSE DEATH. FOLLOW APPROPRIATE TANK ENTRY PROC (SEE ANSI Z177.101977). WHEN DILUTING,(SEE ING 12) RTECS #:9999999ZZ Fraction by Wt: .1-1977% Ingred Name:ING 11:ADD 50% LIQ CAUSTIC SODA SLOWLY TO SURFACE OF COLD WATER TO AVOID VIOLENT ERUPTION. LIQ CAUSTIC SODA (SEE ING 13) RTECS #:9999999ZZ Ingred Name:ING 14:IS SHIPPED HOT (100-180F). AVOID SKIN CONTACT--CAN CAUSE THERMAL BURNS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:EYE:CAUSES SEVERE BURNS; SMALL QUANTITIES CAN RESULT IN PERMANENT DAMAGE AND/OR LOSS OF VISION. SKIN: CORROSIVE ACTION CAUSES BURNS AND FREQUENTLY DEEP ULCERATION W/SUBSEQUENT SCARRING. PRLNGD C ONTACT DESTROYS TISSUE. MIST FROM SOLUTION CAN CAUSE IRRIT DERM. INGEST:CAN CAUSE VERY SERIOUS DMG (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:TO MOUTH, ESOPHAGUS, STOMACH, & OTHER TISS W/WHICH CONTACT IS MADE & MAY BE FATAL. INHAL:CAN CAUSE DMG TO UPPER RESP TRACT & TO LUNG TISS DEPENDING ON EXTENT OF EXPOS. EFTS CAN RANGE FROM MIL D IRRIT OF MUCOUS MEMBRANES, SEVERE PNEUMIT, & DESTRUCTION OF LUNG TISS. CHRONIC:EFTS OF LONG-TERM, LOW LEVEL(SUPP DATA) Medical Cond Aggravated by Exposure:NONE KNOWN BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BRTHG DFCLT, GIVE O2. CALL MD.EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS, HOLDING EYELIDS OPEN. CALL M D. SKIN:IMMEDIATELY FLUSH W/PLENTY OF WATER WHILE REMOVING CONTAM CLTHG & BOOTS. CALL MD. IF SKIN FEELS SLIPPERY, CAUSTIC MAY STILL BE PRESENT IF SUFFICIENT QTYS TO CAUSE RASH/BURN. (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:CONTACT WITH SOME METALS, PARTICULARLY MAGNESIUM, ALUMINIM, AND ZINC (GALVANIZED), CAN GENERATE HYDROGEN RAPIDLY, WHICH IS EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AREA TO CNTN SPILL. ONLY TRAINED PERS EQUIPPED W/NIOSH/MSHA APPRVD, FULL FACEPIECE COMBINATION DUST/MIST & ACID GAS RESPS SHOULD BE PERMITTED IN AREA. RECLAIM SPILLED MATL IF POSS OR DILUTE MATL W/LGE QTY OF WATER, THEN NEUTRALIZE W/(SEE ING 5) Neutralizing Agent:DILUTE ACID. ======================Handling and Storage ====================== THAT MAY BE CONTAM W/CAUSTIC SODA. NEVER ENTER CAUSTIC SODA STOR TANK OR CNTNR (TANK TRUCK/TANK CAR) (SEE ING 10) Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. CAN CAUSE SEVERE INJURY OR BLINDNESS. DO NOT BREATHE MIST. DO NOT SWALLOW. WASH THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK, OR SMOKE IN WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD DUST/MIST FILTER RESP FOR ROUTINE WORK PURPOSES WHEN EXPOS TO MISTS EXCEED PEL. THE RESP USE LIMITATIONS MADE BY NIOSH/MSHA OR MFR MUST BE OBSERVED. RESPIRATORY PROTECTION PROGRA MS MUST MEET REQS OF 29 CFR 1910.134. Ventilation:LOCAL EXHAUST SUFFICIENT TO MINIMIZE EMPLOYEE EXPOSURE TO MIST BELOW PEL. Other Protective Equipment:RUBBER BOOTS W/SAFETY TOES, RUB APRONS, PVC CLTHG, PLASTIC HARD HAT. EMER EYEWASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH:STRONGLY BASIC. HLTH HAZ:EXPOS HAVE NOT BEEN DETERMINED. SAFE HNDLG ON A LONG-TERM BASIS SHOULD EMPHASIZE AVOIDANCE OF ALL EFTS FROM REPETITIVE ACUTE EXPOS. FIRST AID PROC:CONTINUE WASHING UNTIL SL ICK SKIN FEELING IS GONE. THORO CLEAN CONTAM CLTHG & BOOTS BEFORE REUSE OR DISCARD. INGEST:IF CONSCIOUS,(SEE ING 2) ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:288F,142C Vapor Pres:1 Spec Gravity:1.135 @ 60F pH:SUPDAT Solubility in Water:34.7 G WATER @ 100C Appearance and Odor:WATER WHITE TO SLIGHTLY TURBID LIQUID; NO ODOR. Percent Volatiles by Volume:30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ORGANIC MATL & CONC ACIDS, MAGNESIUM, ALUMINUM, ZINC (GALVANIZED), TIN, CHROMIUM, BRASS & BRONZE, & VARIOUS FOOD SUGAR. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:REACTION WITH VARIOUS FOOD SUGARS MAY FORM CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE NEUTRALIZED MATL IN APPRVD HAZARDOUS WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN WHEN USING OR DISPOSING OF CHEM MATLS/THEIR CNTNRS TO PVNT ENVIRON CONTAM. DISPOSE OF IN ACCORDANCE WITH FEDE RAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CMS BUFFER SULUTION PH 7.00, 356-121 CAGE:0B0Y1 CAGE:0B0Y1 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM PHOSPHATE, MONOBASIC CAS:7778-77-0 Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM PHOSPHATE, DIBASIC (SARA III) CAS:7558-79-4 RTECS #:WC4500000 Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PYRAZOLE-3-CARBOXYLIC ACID, 5-HYDROXY-1- (P-SULFOPHENYL)-4-(P-SULFOPHENYL) AZO-, TRISODIUM SALT; (FOOD COLORING) CAS:1934-21-0 RTECS #:UQ6400000 Fraction by Wt: TRACE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZOIC ACID, P-HYDROXY-, METHYL ESTER; (INHIBITOR) CAS:99-76-3 RTECS #:DH2450000 Fraction by Wt: TRACE OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT IS NOT EXPECTED TO PRESENT A HEALTH HAZARD WHEN EMPLOYING GOOD LABORATORY PRACTICES. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT APPLICABLE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . INGEST: INDUCE VOMITING OF CONSCIOUS PATIENT BY GIVING TWO GLASSES OF WATER & PRESSING FINGER DOWN THROAT. CO NTACT MD IMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING & WASH SKIN WITH WATER. IF IRRITATION PERSISTS, CONTACT MD. EYES: FLUSH EYES WITH WATER FOR 15 MINUTES. CONTACT MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN THE SPILL WITH ABSORBENT MATERIAL OR MOP UP WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NORMAL LABORATORY CARE. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL (GENERAL). Other Protective Equipment:NOT APPLICABLE. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:24 Spec Gravity:1.0 (H*2O=1) Appearance and Odor:YELLOW, ODORLESS SOLUTION. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE CARRIED OUT IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EXTERIOR TRIM ENAMEL YELLOW CAGE:6F266 CAGE:6F266 ============= Composition/Information on Ingredients ============= Ingred Name:TEXANOL (ESTER ALCOHOL) CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 4.5% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:VOC: 62 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: PROLONGED INHALATION IN CONFINED AREAS MAY LEAD TO MUCUS MEMBRANE IRRITATION, DIZZINESS, HEADACHE. SKIN: IRRITATION. EYES: IRRITATION. INGESTION: AMOUNTS INGESTED INCIDENTAL TO CONSUMER & INDUSTRIAL HANDLING AREN'T LIKELY TO INJURE, HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJURY. Medical Cond Aggravated by Exposure:NONE, WHEN USED IN ACCORDANCE WITH SAFE HANDLING INSTRUCTIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF RESPIRATORY SYMPTOMS DEVELOP, GET MEDICAL ATTENTION AT ONCE. SKIN: WASH OFF QUICKLY WITH PLENTY OF WATER, THEN SOAP & WATER. REMOVE & WASH CONTAMINATED CLOTHING BEF ORE REUSE. EYES: FLUSH IMMEDIATLEY WITHLARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS, FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, DRY CHEMICAL, WATER FOG OR WATER Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:WILL NOT BURN, CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. VENTILATE AREA. SPILLS MAY BE COLLECTED WITH ABSORBENT MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID TEMPERATURES BELOW 40F. KEEP FROM FREEZING. STORE CONTIANERS WITH LIDS TIGHTLY CLOSED AND APPROPRIATELY LABELED. Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/OSHA FOR PROTECTION AGAINST MATERIALS. Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE. Work Hygienic Practices:KEEP WORK AREA CLEAN & FREE FROM SPILLS/LEAKS. ALWAYS WASH HANDS THOROUGHLY BEFORE EATING, SMOKING, OR DRINKING. Supplemental Safety and Health REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:23.8 Vapor Density:> AIR pH:7-8 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INFINITE Appearance and Odor:THIXOTROPIC LIQUID WITH SLIGHT ODOR; COLOR OF TINT Percent Volatiles by Volume:7.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS AND/OR HYDROFLUORIC ACID Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENTS Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE Conditions to Avoid Polymerization:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENTS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N,N-DIMETHYLFORMAMIDE, 99%, D131 4 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:N,N-DIMETHYLFORMAMIDE LD50: (ORAL, RAT) 2800 MG/KG CAS:68-12-2 RTECS #:LQ2100000 = Wt:100. OSHA PEL:30 MG/M3;10 PPM ACGIH TLV:30 MG/M3;10 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYE: CAUSES SEVERE EYE IRRITATION. VAPORS MAY CAUSE EYE IRRITATION. SKIN: PROLONGED AND/OR REPEATED CONTACT MAY CAUSE IRRITATION AND/OR DERMATITIS. SUBSTANCE IS RAPIDLY ABSORBED THROUGH THE SKIN. IF A BSORBED, CAUSES SYMPTOMS SIMILAR TO INHALATION. STRONG IRRITANT OF THE SKIN. INGESTION: MAY CAUSE IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE EFFECTS SIMILAR TO THOSE FOR INHALATION EXPOSURE. INHALAT ION: MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE KIDNEY DAMAGE. MAY BE HARMFUL IF INHALED. INHALATION MAY PRODUCE NAUSEA, VOMITING, ANOREXIA, COLIC, HIGH BLOOD PRESSURE, HEPATOMEGALY, JAUNDICE A ND (EFFECTS OF OVEREXPOSURE) Explanation of Carcinogenicity:DIMETHYLFORMAMIDE: IARC MONOGRAPHS ON EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 47, PAGE 171, 1989:GROUP 2B. Effects of Overexposure:HEALTH HAZARDS: ALTERED LIVER FUNCTION. CHRONIC: POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY ANIMALS. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY FLUSH SKINW/PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH T O UNCONSCIOUS PERSON. GET MEDICAL AID IMMEDIATELY. INHAL: GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIF FICULT, GIVE OXYGEN. NOTES TO MD: NONE. ===================== Fire Fighting Measures ===================== Flash Point:=58.C, 136.4F Autoignition Temp:=445.C, 833.F Lower Limits:2.2% Upper Limits:15.2% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEM, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL FIRE-EXPOSED CNTNRS. WATER MAY BE INEFTIVE. FOR LARGE FIRES, USE (SUPDAT) Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . CONTACT PROFESSIONAL FIRE-FIGHTERS IMMEDIATELY. COOL CONTAINERS W/FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS OUT. NFPA RATING: HEALTH-1; FLAMMABILITY-2; REACTIVITY-0. Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO SOURCE OF IGNITION & FLASH BACK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL. FLAMMABLE LIQUID. VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW OR CONFINED AREAS. VAPORS MAY FORM AN EXPLOSIVE MIXTURE W/AIR. CONTAINERS MAY EXPLODE WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION. ABSORB SPILL W/INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO CHEMICAL WASTE CONTAINER. DO NOT FLUSH INTO A SEWER. REMOVE ALL SOURCES OF IGNIT. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER SPRAY MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME. KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR. KEEP FROM CONTACT W/OXIDIZING MATLS. STORE IN A COOL, DRY, WELL-VENTD AREA AWAY FROM INCOMPATIBLE S UBSTANCES. WASH THOROUGHLY AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ VENT. Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ &/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT W/HEAT, SPKS & F LAME. AVOID INGEST & INHAL. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHES AND WASH BEFORE REUSE. Supplemental Safety and Health EXTING MEDIA: WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. DO NOT USE STRAIGHT STREAMS OF WATER. OTHER PRECS: SPKS/OPEN FLAMES. EXPOS LIMITS: N,N-DIMETHYLFORMAMIDE - ACGIH: 10 PPM; 30 MG/M3; SKIN-POTNT L FOR CUTANEOUS ABSORPTION. NIOSH: 10 PPM TWA; 30 MG/M3 TWA 500 PPM IDLH. OSHA-FINAL PELS: 10 PPM TWA; 30 MG/M3 TWA. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:153760C Melt/Freeze Pt:=-61.C, -77.8F Decomp Temp:=350.C, 662.F Vapor Pres:3.725 MM HG Vapor Density:2.5(AIR=1) Spec Gravity:0.9450 pH:6.7 Viscosity:0.8 MPAS 20 DEG Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID - CLEAR; AMINE-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS (MINERAL, NON-OXIDIZING, EG HYDROCHLORIC ACID, HYDROFLUORIC ACID, MURIATIC ACID, PHOSOPHORIC ACID), ACIDS (MINERAL, OXIDIZING, EG CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID), METALS (ALKALI & ALKALINE Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES, STRONG OXIDANTS. Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN, CARBON DIOXIDE. =================== Toxicological Information=================== Toxicological Information:CAS # 68-12-2. LD50/LC50: INHALATION, MOUSE: LC50 = 9400 MG/M3/2H; ORAL, MOUSE: LD50 = 3700 MG/KG; SKIN, RABBIT: LD50 = 4720 MG/KG. CARCINOGENICITY: ACGIH: A4 - NOT CLASSIFIABLE AS HUMAN CARCINOGEN. O SHA: POSSIBLE SELECT CARCINOGEN. IARC:GROUP 2B CARCINOGEN. EPIDEMIOLOGY: A SIGNIFICANT EXCESS OF PROSTATE CANCER WAS OBSERVED AMONG WORKERS EXPOSED TO DMF AND ACRYLONITRILE. TERATOGENICITY: EXPERIMENT AL TERATOGEN EFFECTS HAVE BEEN REPORTED. REPRODUCTIVE EFFECTS: EXPERIMENTAL REPRODUCTIVE EFFECTS HAVE BEEN REPORTED. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: HUMAN MUTATION DATA REPORTED. OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:EXOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: SUBSTANCE EXPECTED TO BIODEGRADE RAPIDLY IN ENVIRONMENT & SHOULD BE HIGHLY MOBILE IN SOIL. PHYSICAL/CHEM:NOT AVAIL. OTHER:NOT AVAIL. --FED REG INFO:POLLUTAN TS UNDER CWA. NONE OF CHEMS IN PROD CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN INTERNATIONAL REGS - EUROPEAN LABELING I/A/W EC DIRECTIVES. HAZ SYMBOLS: T. RISK PHRASES: R 20/21 HARMFUL BY INHAL & IN CNTC T W/SKIN. R 36 IRRIT TO EYES. R 61 MAY CAUSE HARM TO UNBORN CHILD. SFTY PHRASES: S 45 IN CASE OF ACCIDENT/IF YOU FEEL UNWELL, SEEK MED ADVICE IMMED (SHOW LABEL WHERE POSS). S 53 AVOID EXPOS - OBTAIN S PEC INSTRUCTIONS (TRANSPORT INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:SHIPPING NAME - US DOT: N,N-DIMETHYLFORMAMIDE, IATA:NO INFO AVAIL, RID/ADR:NO INFO AVAIL, IMO:NO INFO AVAIL, CANADA TDG: N,N-DIMETHYLFORMAMIDE. HAZ CLASS - US DOT:3; CANADA TDG:3. UN NUMBER: US DOT:UN 2265; CANADA TDG:UN2265. PACKING GROUP-US DOT:III; CANADA TDG:III. ADDNL INFO: CANADA TDG: FL PT 58C. --ECOLOGICAL INFO: BEFORE USE. WGK (WATER DANGER/PROT) - CAS #68-12-2:1. CANADA - CAS #68-12-2 LIS TED ON CANADA'S DSL/NDSL LIST. PROD HAS WHMIS CLASSIFICATION OF B3, D2B. NOT LISTED ON CANADA'S INGRED DISCLOSURE LIST. EXPOS LIMS: CAS #68-12-2: OEL-AUSTRALIA:TWA 10PPM (30MG/M3); SKIN OEL-BELGIUM: T WA 10PPM (30MG/M3); (SARA REG INFO) ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ):NONE OF THE CHEMS IN MATL HAVE RQ. SECTION 302 (TPQ):NONE OF CHEMS IN PROD HAVE TPQ. SARA CODES CAS #68-12-2; ACUTE, FLAM. SECTION 313: MATL CONTAINS N,N-DIMETHYLFORMAMIDE (CAS #68-12 -2, 100%), WHICH IS SUBJECT TO REPORTINGREQS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373. --TRANSPORT INFO: SKIN OEL-CZECHOSLOVAKIA:TWA 30MG/M3; STEL 60 MG/M3 OEL-DENMARK:TWA 10PPM (30MG/M3); S KIN OEL-FINLAND:TWA 10PPM (30MG/M3); STEL 20PPM (60MG/M3); SKIN OEL-FRANCE:TWA 10PPM (30MG/M3); SKIN OEL-GERMANY:TWA 20PPM (60MG/M3); SKIN OEL-HUNGARY:TWA 10MG/M3; STEL 20MG/M3; SKIN OEL-JAPAN:TWA 10P PM (30MG/M3); SKIN OEL- (STATE REG INFO) Federal Regulatory Information:CAS #68-12-2 - LISTED ON THE TSCA INVENTORY. HLTH & SAFETY REPORTING LIST: EFTIVE DATE: APRIL 13,1989; SUNSET DATE: 12/19/1995. CHEM TEST RULES:NONE OF CHEMS IN PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED UNDER TSCA SECTION 12B. NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: #68-12-2 IS LISTED AS HAZ AIR POLLUTANT. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. MATL D OES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ S UBSTANCES UNDER CWA. NONE OF CHEMS ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD LISTED AS TOXIC (ECOLOGICAL INFO) State Regulatory Information:CAS #68-12-2 CAN BE FOUND ON FOLLOWING STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CA NO SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN PROD LISTED. --SARA TITLE III: NETHERLANDS:TWA 10PPM (30MG/M3); SKIN OEL-PHILLIPPINES:TWA 10PPM (30MG/M3); SKIN OEL-POLAND:TWA 10MG/M3 OEL-RUSSIA:TWA 10PPM; STEL 10MG/M3; SKIN OEL-SWEDEN:TWA 10PPM (30MG/M3); STEL 15PPM (45MG/M3); SKIN OEL-SWITZERLAND:TWA 10PPM 930 MG/M3); STEL 20PPM; SKIN OEL-TURKEY:TWA 10PPM (30MG/M3); SKIN OEL-UNITED KINGDOM:TWA 10PPM (30MG/M3) ; STEL 20PPM; SKIN OEL BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV. OEL NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:5098, BUFFERED OXIDE ETCH CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ING 7:AN ALTERNATIVE TRTMT IS FOR PHYS TO INJECT STERILE 10% AQUEOUS CALCIUM GLUCONATE SOLN SUBCUTANEOUSLY, (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:BENEATH, AROUND, & IN BURNED AREA. INITIALLY USE NO MORE THAN 0.5 CC PER SQUARE CENTIMETER & DO NOT (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:DISTORT APPEAR OF SKIN. IF PAIN IS NOT COMPLETELY RELEIVED, ADDTNL TRTMT IS INDICATED. SEEK MED ATTN AS (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:SOON AS POSSIBLE FOR ALL BURNS REGARDLESS OF HOW MINOR THEY MAY APPEAR INITIALLY. RTECS #:9999999ZZ Ingred Name:OTHER PREC: INDISCRIMINATE HYDROGEN BLISTERING & SHOULD ROUTINELY BE INSPECTED & REPAIRED. DO NOT GET IN EYES, (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:SKIN, ON CLTHG. USE W/ADEQ VENT. DO NOT BREATHE VAPOR. REACTS VIOLENTLY W/H*2O, LIBERATING EXCESSIVE HEAT. RTECS #:9999999ZZ Ingred Name:AMMONIUM FLUORIDE CAS:12125-01-8 RTECS #:BQ6300000 Fraction by Wt: 2-20% EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:HYDROFLUORIC ACID CAS:7664-39-3 RTECS #:MW7875000 Fraction by Wt: 0-1% OSHA PEL:3 PPM (F) ACGIH TLV:3 PPM, C (F) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SUPP DATA: SHOWER/WASH W/H*2O HOSE, WHICHEVER IS AVAIL. REMOVE ALL CONTAMD CLTHG. KEEP WASHING W/LG AMT OF H*2O (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:FOR 15-20 MIN. MAKE ARRANGEMENTS FOR MED ATTN WHILE YOU CONTINUE FLUSH AFFECTED AREA W/H*2O. (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:IF AVAIL, AFTER THOROUGH WASH, BURNED AREA SHOULD BE IMMERSED IN SOLN OF 0.2% ICED AQUEOUS HYAMINE 1622 (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:OR 0.13% ICED AQUEOUS ZEPHIRAN CHLORIDE. IF IMMERSION IS NOT PRACTICAL, TOWELS SHOULD BE SOAKED W/ONE OF (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:THE ABOVE SOLN & USED AS COMPRESSES FOR BURNED AREA. IDEALLY COMPRESSES SHOULD BE CHANGED EVERY 2 MIN. (ING 8) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:VAP MAY BE IRRITATING TO SKIN, EYES, & MUC MEMB. INHAL OF VAP MAY CAUSE SEV IRRIT/BURNS OF RESP SYS, PULM EDEMA, OR LUNG INFLAMM. LIQ/VAP CAUSE SEV BURNS WHICH MAY NOT BE IMMED PAINFUL OR VISIBLE. SUB STANCE IS READILY ABSORBED THRU SKIN, PENETRATING SKIN TO ATTACK UNDERLYING TISSUES & BONES. INGEST (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MAY CAUSE SEV BURNS TO MOUTH, THROAT, & STOMACH. MAY HAVE ADVERSE EFFECT ON KIDNEY FUNCTION AND MAY BE FATAL. CHRONIC EFFECTS OF EXPOSURE MAY INCLUDE HYPOCALCEMIA, BONE AND JOINT CHANGES. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:CALL PHYS. INGEST:DO NOT INDUCE VOMIT; IF CONSCIOUS, GIVE H2O, MILK/MILK OF MAGNESIA. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O2. EYES: IRRIGATE FOR @ LST 15 MIN W/COPIOUS QTY OF H2O, KEEPING LIDS APART & AWAY FROM EYEBALS DURING IRRIGATION. GET COMPETENT MED ATTN IMMED, PREF AN EYE SPECIALIST. IF PHYS IS NOT IMMED AVAIL, APPLY 1-2 DROPS OF (SUPP DATA) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO W/OUT RISK. VENT AREA. NEUT SPILL W/SODA ASH/LIME. W/CLEAN SHOVEL, CAREFULLY PLACE MATL INTO CLEAN, DRY CONTR & COVER; REMOVE FROM AREA. FLUSH SPILL AREA W/H2O. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE IN CORR-PROOF AREA. ISOLATE FROM INCOMPAT MATL. KEEP CONTR OUT OF SUN & AWAY FROM HEAT. PROTECT FROM FREEZING. Other Precautions:HYDROFLUORIC ACID IS INCOMPAT W/GLASS & ALL SILICON- BEARING MATL & SHOULD NEVER BE TRANSFERRED TO GLASS CONT. MATL SHOULD REMAIN IN ORIGINAL POLYETHYLENE CONTR. UNLINED STEEL TANKS IN HYDROFLUORIC SE RVICE ARE SUBJECT TO (ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP PROT REQD IF AIRBORNE CONC EXCEEDS TLV. @ CONC UP TO 20 PPM, NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/ ACID/ORG CARTRIDGE & DUST/MIST FILTER IS RECOM. ABOVE LEVEL, NIOSH/MSHA APP RVD SCBA IS RECOMMENDED. Ventilation:USE GEN/LOC EXHAUST VENT TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT. EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MATL TO AVOID: OXIDES OF SILICON, ESP. GLASS, CONCRETE, SILICA. FIRST AID PROC: 0.5% PONTOCAINE HYDROCHLORIDE SOLN FOLLOWED BY SEC IRRIGATION FOR 15 MIN. USE NONE OF SOLN DESCRIBED FOR SKIN TRTMT. USE NO OILS/GREASES UNLESS INSTRUCTED TO DO SO BY PHYS. SKIN:REMOVE FROM CONTAMD AREA & IMMED PLACE UNDER SFTY (ING 3) ================== Physical/Chemical Properties ================== HCC:C1 Melt/Freeze Pt:M.P/F.P Text:64.0F,17.8C Spec Gravity:1.10(H2O=1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS SOLUTION Percent Volatiles by Volume:80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIES, ORG MATLS, MOST COMMON METALS, RUB, LEATHER, FLUORINE, STRONG BASES, CARBONATES, SULFIDES, CYANIDES(SUPP DATA) Stability Condition to Avoid:COLD, LIGHT, HEAT. Hazardous Decomposition Products:HYDROGEN FLUORIDE, AMMONIA, NOX. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:V68-540 CAGE:67251 CAGE:67251 ============= Composition/Information on Ingredients ============= Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS FORMS) (SARA III) CAS:1344-28-1 RTECS #:BD1200000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:BARIUM (SARA III) CAS:7440-39-3 RTECS #:CQ8370000 OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 Ingred Name:BORON OXIDE CAS:1303-86-2 RTECS #:ED7900000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3; 9293 Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:MAGNESIUM OXIDE CAS:1309-48-4 RTECS #:OM3850000 OSHA PEL:15 MG/M3 PARTICULATE ACGIH TLV:10 MG/M3;TDUST; 9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Other REC Limits:30 MG/CUM TOTAL DUST OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:TIN CAS:7440-31-5 RTECS #:XP7320000 OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9192 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 OSHA PEL:5 MG/M3/10 STEL ACGIH TLV:5 MG/M3/10 STEL;9192 Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: <5% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: <5% Other REC Limits:0.05 PPM OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <5% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:NICKEL (SARA III) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: <5% Other REC Limits:1 MG/CUM OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3; 9192 Ingred Name:VANADIUM (SARA III) CAS:7440-62-2 RTECS #:YW1355000 Fraction by Wt: <5% OSHA PEL:C,0.5 MG V2O5/M3 RD ACGIH TLV:0.05 MG V205/M3;9293 Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: <5% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION. Explanation of Carcinogenicity:SILICA, CHROMIC OXIDE, & NICKEL OXIDE ARE SUSPECTED A1 CARCINOGENS. Effects of Overexposure:INHALATION: IRRITATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLED MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID INHALATION OF CERAMIC DUST. AVOID LICKING CERAMIC APPLICATION BRUSH. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NUISANCE DUST MASK IS RECOMMENDED WHILE GRINDING FIRED PORCELAIN. Ventilation:MECHANICAL EXHAUST VENTILATION IS RECOMMENDED WHILE GRINDING FIRED PORCELAIN. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>2192F Melt/Freeze Pt:M.P/F.P Text:1760F Solubility in Water:INSOLUBLE Appearance and Odor:WHITE OR LIGHT PASTEL COLORED PORCELAIN POWDER W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED HYDROFLUORIC ACID ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS SOLID WASTE IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SUPER UNLEADED GASOLINE/PREMIUM UNLEADED CAGE:59548 CAGE:59548 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCARBON MIXTURE (AROMATIC & PARAFFINIC) Other REC Limits:NONE RECOMMENDED Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >25 ML/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HIGH VAPOR LEVELS MAY CAUSE EYE IRRITATION. THE LIQUID IS SLIGHTLY IRRITATING TO THE SKIN. PROLONGED OR REPEATED CONTACT CAN RESULT IN DEFATTING AND DRYING WHICH MAY RESULT IN SKIN IRRITATION AND DERM ATITIS. INHALATION OF VAPORS MAY BE IRRITATING TO NOSE & LUNGS. MAY CAUSE CNS DEPRESSION. INGESTION MAY CAUSE VOMITING Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:EYE, SKIN & RESPIRATORY TRACT IRRITATION. CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME CASES, UNCONSCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION OF VOMITUS INTO THE LUNGS MAY CAUSE COUGHING, LABORED BREATHING, CYANOSIS AND IN SEVERE CASES, DEATH. Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ATTENTION. INHALA TION: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-50F,-46C Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. DO NOT ENTER ENCLOSED OR CONFINED SPACE WITHOUT PROPER PROTECTION. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. WEAR APPROPRIATE RESPIRATOR & PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE TO CONTAIN. REMOVE WITH VACUUM OR PUMP TO STORAGE/SALVAGE VESSELS. ABSO RB RESIDUE WITH INERT MATERIAL. WATER FLUSH AREA. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP LIQUID/VAPOR AWAY FROM HEAT, SPARKS & FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. IGNITED VAPORS MAY EXPLODE. Other Precautions:"EMPTY" CONTAINERS CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND CONTAINERS, FIXED & TRANSFER EQUIPMENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. IF EXPOSURE EXCEEDS OCCUPATIONAL EXPOSURE LIMITS, USE A NIOSH/MSHA APPROVED RESPIRATOR. EITHER AN AIR-SUPPLIED OR AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES IS RECOMMENDED. Ventilation:USE EXPLOSION-PROOF LOCAL AND/OR MECHANICAL VENTILATION. AVOID OPEN ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS. Other Protective Equipment:INDUSTRIAL WORK CLOTHING TO MINIMIZE CONTACT. RUBBER APRON AD BOOTS AS REQUIRED. EYE BATH AND SAFETY SHOWER RECOMMENDED. Work Hygienic Practices:WASH THOROUGHLY AFTER USING PRODUCT AND BEFORE EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health STUDIES WITH RODENTS HAVE SHOWN THAT PERTROLEUM DISTILLATES HAVE CAUSED KIDNEY DAMAGE AND KIDNEY OR LIVER TUMORS. HOWEVER, THE KIDNEY EFFECTS WERE NOT SEEN IN SIMILAR STUDIES INVOLVING GUINEA PIGS, DO GS OR MONKEYS. SEVERAL STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN SIGNIFICANT INCREASES OF KIDNEY DAMAGE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:85-437F Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:275-475 Vapor Density:NOT GIVEN Spec Gravity:0.77 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:INSOLUBLE Appearance and Odor:RED LIQUID, GASOLINE ODOR. Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLUE GLOSS ALKYD ENAMEL C-15102 CAGE:72988 CAGE:72988 ============= Composition/Information on Ingredients ============= Ingred Name:RESIN Fraction by Wt: 35% Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 13% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:COMLEX INORGANIC PIGMENT CAS:14038-43-8 Fraction by Wt: 4% Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2) CAS:64742-88-3 Fraction by Wt: 46% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Effects of Overexposure:EYE: IRRITATION SKIN: IRRITATION INHAL: DIZZINESS, NAUSEA, POSSIBLE UNCON SCIOUSNESS ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER CONSULT PHYSICIAN SKIN: WASH WITH SOAP AND WATER INHAL: REMOVE TO FRESH AIR, APPLY ARTIFI CIAL RESPIRATION IF NECESSARY ===================== Fire Fighting Measures ===================== Flash Point:105F/40.56C Lower Limits:0.7 Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:WATER NOT A SUITABLE EXTINGUISHING MEDIUM ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB SMALL SPILLON DRY ABSORPTION MATERIAL. USE SPARK PROOF SCOOP FOR LARGER SPILLS. ENSURE ADEQUATE VENTILATION. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT AND OPEN IGNITION SOURCES. Other Precautions:NPCA/HMIS RATING 3,2,0,H ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CARTRIDGE FUME MASK Ventilation:SUFFICIENT TO ENSURE LEL NOT ACHIEVED Other Protective Equipment:PROTECT SKIN WITH CLOTHING OR BARRIER CREAM Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:323-390F Vapor Density:> AIR Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:62 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Hazardous Decomposition Products:CARBON MONOXIDE/DIOXIDE ON COMBUSTION ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS PER LOCAL AND FEDERAL REGULATIONS FOR HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LYOPHILIZED CATALASE FOR 125 ML,74-6430 CAGE:59896 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:CATALASE (FROM BOVINE LIVER) CAS:9001-05-2 RTECS #:FI4378000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACTS. ACUTE- MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE GASTROINTESTINAL DISCOM FORT. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DISCOMFORT Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN FOR 15 MINUTES. EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXY GEN/CPR IF NEEDED. ORAL:IF CONSCIOUS, DRINK PLENTY OF WATER. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. SWEEP UP CAREFULLY AND PLACE IN A CONTAINER FOR DISPOSAL. AVOID RAISING DUST. CLEAN AREA THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE TIGHTLY CLOSED IN COOL, DRY PLACE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:FOR INDUSTRIAL USE ONLY. READ AND FOLLOW ALL LABEL DIRECTIONS AND PRECAUTIONS. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH EYES AND SKIN. DO NOT INHALE DUSTS. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCETABLE LEVEL, A NIOSH-APPROVED RESPIRATOR FOR DUST MUST BE WORN. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASS URE COMPLIANCE WITH OSHA 29CFR 1910.134. Ventilation:ADEQUATE Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, UNIFORM Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Viscosity:NOT RELEVANT Appearance and Odor:SOLID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PURGEABLES SURROGATE STANDARD MIX 1ML CLP CAGE:54968 CAGE:54968 ============= Composition/Information on Ingredients ============= Ingred Name:BENZENE, 1-BROMO-4-FLUORO- 1 BROMO-4-FLUORBENZENE. (MFR CAS#:460-00-4) CAS:1072-85-1 RTECS #:DA1050000 Fraction by Wt: 0.025% Ingred Name:ETHYLENE DICHLORIDE (SARA III) CAS:107-06-2 RTECS #:KI0525000 Fraction by Wt: 0.025% OSHA PEL:50 PPM/C,100PPM ACGIH TLV:10 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 0.025% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 99.925% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF SWALLOWED. Explanation of Carcinogenicity:1,2-DICHLOROETHANE (A POSSIBLE CAUCINOGEN)IS PRESENT IN LESS THAN THE MINIMUM REPORTING AMOUNT. Effects of Overexposure:HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES, BLINDNESS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MIN. CALL MD. SKIN:FLUSH W/LG VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS, GIVE ARTF RESP. CALL MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS ON. NEVER TRY TO MAKE UNCON PERSON VOMIT. GIVE 2 TBLS OF BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMITING. IMMED CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:50.0F,10.0C Lower Limits:6% Upper Limits:36.5% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . ================== Accidental Release Measures ================== Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA. ELIMINATE ALL IGNITION SOURCES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES. Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED FULL FACE MASK W/ORGANIC VAPOR CANISTER. Ventilation:USE ONLY IN WELL VENTILATED AREA. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F5 Boiling Pt:B.P. Text:149F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:100 Vapor Density:1.10 Spec Gravity:0.790 Evaporation Rate & Reference:>1 (ETHER = 1). Solubility in Water:100% Appearance and Odor:CLEAR, COLORLESS LIQUID. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1502 FLAT WHITE, INDUSTRIAL MAINTENANCE (SUPDAT) CAGE:DO642 CAGE:DO642 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE. VP: 760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 14% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:BUTANE. VP: 760. CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 8% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:ETHYLBENZENE (SARA 313). VP: 7.1. CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP: 5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 13% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP: 180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 35% OSHA PEL:1000 PPM ACGIH TLV:750 PPM; 1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (SARA 313) (CERCLA). VP: 70. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 3% OSHA PEL:200 PPM ACGIH TLV:200 PPM; 300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-METHOXY-2-PROPANOL ACETATE. VP: 1.8. CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 7% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, AMOPRHOUS, PRECIPITATED AND GEL; (AMORPHOUS PRECIPITATED SILICA) CAS:112926-00-8 RTECS #:VV7315000 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 7% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:VOLATILE ORGANIC COMPOUND BY WEIGHT PER BAAQMD RULE 49: 47.4%; VOC TOTAL: 3.18 LBS/GAL. RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:EFTS OF OVEREXP: ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: SYS DMG. WARNING:THESE PRODS CNTN CHEM/S KNOWN TO STATE OF CA TO CAUSE CANCER & BIRTH DEFECTS/OTHER REPRO HARM. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: NOT INCINERATE. DEPRESSURIZE CNTNR. DISPOSE OF I/A/W FED, STATE & LOCAL REGS REGARDING POLLUTION. RTECS #:9999999ZZ Ingred Name:HNDLG/STOR PRECS: VENTD - DO NOT SMOKE - EXTING ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF STOVES, ELEC TOOLS(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:& APPLIANCES & ANY OTHER IGNIT SOURCES. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. CONTENTS(ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMPS >120F. HEAT FROM SUNLIGHT, RADIA, STOVES, HOT (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PRECS: LISTED "AS DUST" IN INGRED SECTION) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING(ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: OF DRIED FILM. IF NO SPECIFIC DUSTS LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT: FROM THIS PRODUCT, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE EXPOS TO VAPS OR SPR AY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: PRLNGD OVEREXP TO SOLV INGREDS LISTED MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYS. METHYL ETHYL KETONE MAY INCR NERVOUS SYS EFTS OF OTHER SOLVS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT (ING 11) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BRTHG. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH EYES W/LARGE AMT S OF WATER FOR AT LEAST 15 MIN. GET MEDATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE CONSCIOUS PATIENT SEVERAL GLASSES OF WATER. SEEK MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:<0F,<-18C Lower Limits:1.0% Upper Limits:13.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT) Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS ARE GONE - KEEP AREA (ING 14) Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES LISTED "AS DUST" IN INGRED SECTION WHICH MAY CONTAIN MATLS CLASS IFIED AS NUISANCE PARTICULATES (ING 18) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR NIOSH APPRVD, PROPERLY FITTED ORG VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIOSH FORDUST WHICH MAY BE GENERATED (ING 21) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.84, 107, 108. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:USE ONLY W/ADEQUATE VENT. AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES. WASH HANDS AFTER USING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: & TOUCH UP SPRAY COLORS. FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS REQS SPEC PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE A HEALTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<0F,<-18C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.81 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING METHYL ETHYL KETONE OR COPPE R MAY REQ TESTING FOR EXTRACTABILITY. DO (ING 13)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON REMOVING COMPOUND MIL-C-19853A II CAGE:82925 CAGE:82925 ============= Composition/Information on Ingredients ============= Ingred Name:METHYLENE CHLORIDE(SARA III) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 50-52% % Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM/C,1000; Z2 ACGIH TLV:50 PPM, A2; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CRESOL, ALL ISOMERS (CRESYLIC ACID) (SARA III) CAS:1319-77-3 RTECS #:GO5950000 Fraction by Wt: 16-19% % Other REC Limits:NONE SPECIFIED OSHA PEL:S, 5 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM CHROMATE (SARA III) CAS:7775-11-3 RTECS #:GB2955000 Fraction by Wt: 4 - 6% % Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 PPM CRO3;CEILING ACGIH TLV:0.05 MG CR/M3; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VOMITING, NAUSEA, DIZZINESS, HEADACHE, LOSS OF COORDINATION AND EQUILIBRIUM. TRANSIENT IRRITATION TO EYES. MAY CAUSE BURNS TO SKIN. CHRONIC: LIVER AND/OR KIDNEY EFFECTS, CENTRAL NERVOUS SYSTEM DEPRESSION, ANESTHETIC OR NARCOTIC EFFECTS. Explanation of Carcinogenicity:PRODUCT CONTAINS NO MATERIALS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:DIZZINESS, NAUSEA, TINGLING, NUMBNESS OF EXTREMITIES, SENSE OF FULLNESS IN HEAD, SENSE OF HEAT, STUPOR, DULLNESS, LETHARGY AND HEADACHE. REDNESS OF SKIN. IRRITATION TO EYES. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION QUICKLY. SKIN: FLUSH WITH WATER. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. RESCITATE IF NECESSARY. GET M EDICAL ATTENTION. INGESTION: GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:202F,94C Lower Limits:6.6 % Upper Limits:15.5 % Extinguishing Media:FOAM,DRY CHEMICAL, CARBON DIOXIDE Fire Fighting Procedures:WATER MAY BE INEFFECTIVE EXCEPT TO KEEP FIRE EXPOSED CONTAINERS COOL. PROPER PROTECTIVE GEAR MUST BE WORN. Unusual Fire/Explosion Hazard:MAY EMIT PHOSGENE GAS AND HALO ACIDS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. VENTILATE AREA. WEAR PROTECTIVE CLOTHING. CONTAIN SPILL IF POSSIBLE. SMALL SPILLS CAN BE ABSORBED IN PERLITE, VERMICULITE, ETC. DO NOT ALLOW TO GET INTO DRAINS, SEWERS, WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN COOL, DRY PLACE. DO NOT RE-USE EMPTY CONTAINERS. Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. AVOID SKIN AND EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CONFINED AREAS, POSITIVE-PRESSURE SUPPLIED AIR RESPIRATORS OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED. Other Protective Equipment:AS NEEDED TO AVOID SKIN/EYE CONTACT. EYE-WASH FOUNTAIN, SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AND FACE AFTER USING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:T3 Boiling Pt:B.P. Text:104F,40C Spec Gravity:1.2 Solubility in Water:NEGLIGIBLE Appearance and Odor:DARK AMBER LIQUID, PUNGENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING SUBSTANCES Stability Condition to Avoid:HIGH ENERGY SOURCES Hazardous Decomposition Products:PHOSGENE, HYDROGEN CHLORIDE AND OTHER HIGHLY TOXIC SUBSTANCES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1824-411 CORROSION REMOVING COMPOUND, MIL-C-10578D, TY II CAGE:07XT7 CAGE:07XT7 ============= Composition/Information on Ingredients ============= Ingred Name:2-ETHOXYETHANOL (SARA 313) (CERCLA) CAS:110-80-5 RTECS #:KK8050000 Fraction by Wt: 19% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S, 5 PPM; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHOSPHORIC ACID (SARA 313) (CERCLA) CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 21% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED CONTACT MAY IRRITATE SKIN.INHALATION: HIGH VAPOR CONCENTRATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: SMALL AMOUNTS MAY BE DRAWN INTO THE LUNGS BY E ITHER SWALLOWING OR VOMITING. Effects of Overexposure:EYES: IRRITATION. SKIN:PROLONGED CONTACT MAY CAUSE BURNS. INHALATION: HIGH CONCENTRATIONS MAY CAUSE HEADACHES, DIZZINESS, AND ANESTHESIA.INGESTION: IF DRAWN INTO LUNGS, MAY CAUSE BURNS AND INFLAMM ATION AND INFECTION TO THE BRONCHI. MAY CAUSE BURNS TO THE DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN CONDITIONS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INHALATION:REMOVE TO FRESH AIR. ADMINISTER OXYGEN AS NEEDED. CALL A PHYSICIAN. INGESTION: GIVE SEVERA L GLASSES OF WATER. DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION.IF IRRITATION DEVELOPS, SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE Extinguishing Media:CARBON DIOXIDE, DRY CHEMICALS, BC/ABC EXTINGUISHERS. Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:LARGE SPILLS: SOAK UP WITH SAND OR SWEEPING COMPOUNDS AND DISPOSE AS A SOLID. SMALL SPILLS: USE AN INDUSTRIAL SEWER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A COOL DRY PLACE. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS. Other Protective Equipment:NONE Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.15 pH:>1.0 Evaporation Rate & Reference:1.2 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:WATER WHITE LIQUID. Percent Volatiles by Volume:90 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI, REDOX AGENTS, ALUMINUM FINES. Hazardous Decomposition Products:OXIDES OF CARBON AND PHOSPHORUS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:23F1067G102 CAGE:03497 CAGE:03497 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMED.SKIN WASH W/SOAP IMMED.INHAL:REMOVE TO FRESH AIR,GIVE ART RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS PER SON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW COLORED-LIQUID,AROMATIC ODOR. ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OLIVE DRAB # 34088 ONE GAL CAN CAGE:3F338 CAGE:3F338 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENE CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 45.70% WT OSHA PEL:100 PPM ACGIH STEL:100PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:DIZZINESS, NAUSEA, VOMITING, LOSS OF COORDINATION AND FATIGUE. Medical Cond Aggravated by Exposure:ASTHMA, HEART CONDITION. ======================= First Aid Measures ======================= First Aid:SKIN CONTACT : FLUSH WITH WATER. IF REDNESS PERSISTS SEEK MEDICAL ATTENTION.INHALATION: IF RESPIRATORY SYSMPTOMS DEVELOP, REMOVE VICTIM FROM SOURCE OF EXPOSURE TO FRESH AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. INGESTION: SEEK EMERGENCY MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=27.2C, 81.F 81F Upper Limits:7 Extinguishing Media:CO2/FOAM Fire Fighting Procedures:THIS MATERIAL MAY BE IGNITED BY HEAT, SPARKS FLAME, OR STATIC ELECTRICITY. KEEP CONTAINERS CLOSED WHEN NOT IN USE. ISOLATE FROM HEAT, SPARKS, PILOT LIGHTS, SMOKING MATERIALS, AND OTHER SOURCES OF IG NITION. Unusual Fire/Explosion Hazard:THE USE OF SCBA IS RECOMMENED FOR FIREFIGHTERS. WATER SPRAY MAY BE USEFUL IN COOLING CONTAINERS EXPOSED TO HEAT AND FLAME.AVOID SPEADING BURNING LIQUID WITH WATER USED FOR COLLING PURPOSES. FIGHT AS VOLATILE LIQUID FIRE. CLOSED CONTIANERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:STAY UPWIND, REMOVE SOURCE OF IGNITION, KEEP OUT OF DRAINS, SEWERS, WATERWAYS. USE ABSORBENT PADS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED ORGANIC SUPPLIED AIR RESPIRATOR. Ventilation:MECHANICAL/ Other Protective Equipment:WEAR IMPERVIOUS CLOTHING. Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:>138.9C, 282.F B.P. Text:282-286F Vapor Density:HEAVIER Volatile Org Content %:4 Evaporation Rate & Reference:SLOWER THAN AIR Solubility in Water:NIL Appearance and Odor:LIQUID Percent Volatiles by Volume:66% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CO2 Stability Condition to Avoid:AVOID HEAT, FLAME, STATIC ELECTRICITY. ===================== Ecological Information ===================== Ecological:KEEP PRODUCT OUT OF DRAINS, SEWERS, WATERWAYS. DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL/STATE/ FED REGULATIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE PRODUCT IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGUALTIONS. ===================== Regulatory Information ===================== State Regulatory Information: ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RCP CAGE:21172 CAGE:21172 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT IS NOT CONSIDERED HAZARDOUS MATERIAL AS DEFINED IN 29CFR1501.2 TO WHICH THIS DATA SHEET PERTAINS. Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THIS SUBSTANCE IS CONSIDERED PRACTICALLY NON-TOXIC TO INTERNAL ORGANS. NO PROLONGED OR SIGNIFICANT SKIN OR EYE IRRITATION IS EXPECTED. Explanation of Carcinogenicity:MFR GAVE THE ABOVE LISTINGS ON THE MSDS BUT NO OTHER COMMENTS ABOUT CARCINOGENICITY WERE RECORDED. Effects of Overexposure:NONE EXPECTED Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER. SKIN:WASH W/SOAP & WATER. INHALATION:NONE. INGESTION:GIVE WATER OR MILK TO DRINK & GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:335F,168C Autoignition Temp:Autoignition Temp Text:365F Lower Limits:NA Upper Limits:NA Extinguishing Media:USE FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SMALL QUANTITIES MAY BE FLUSHED TO SEWER. LARGER SPILLS SHOULD BE SOAKED UP W/ABSORBENT MATERIALS. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:NORMAL. GOOD HOUSKEEPING PRACTICES. DO NOT WELD, HEAT OR DRILL CONTAINER. REPLACE CAP OR BUNG. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. Ventilation:LOCAL EXHAUST IS SUFFICIENT. NONE OTHER RECOMMENDED. Other Protective Equipment:PROTECTIVE COVERALLS & SAFETY SHOES ARE RECOMMENDED. Work Hygienic Practices:NORMAL GOOD WORK & HYGIENIC PRACTICES. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:>212F,>100C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NA Vapor Density:NA Spec Gravity:0.924 Evaporation Rate & Reference:<1 ETHER=1 Solubility in Water:FORMS EMULSION Appearance and Odor:RED LIQUID, MILD DETERGENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAY REACT W/STRONG OXIDIZING AGENTS SUCH AS CHLORATES, PEROXIDES ETC. Stability Condition to Avoid:MFR GAVE NO INFORMATION OF MSDS. Hazardous Decomposition Products:NDA Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE CONTAINERS & DISPOSE OF IN A MANNER CONSISSTANT W/APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TRIDENT R-269 CAGE:0U4X9 CAGE:0U4X9 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCHLORIC ACID (SARA III) CAS:7647-01-0 RTECS #:MW4025000 OSHA PEL:5 PPM, C ACGIH TLV:5 PPM, C EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAUSES SEVERE IRRITATION AND POSSIBLE EYE DAMAGE . SKIN:CAUSES SKIN IRRITATION AND POSSIBLE BURNS. INGEST:SEVERE IRRITATION OF MOUTH AND THROAT. INHAL:SEVERE RESPIRATORY IRRITATION. PRIMARY IRRIT ANT DERMATITIS. PROLONGED CONTACT MAY RESULT IN DESTRUCTION OF TISSUE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT KNOWN ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES . INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) . SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, ALCOHOL FOAM, DRY CHEMICAL Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:PRODUCT WILL FLOAT ON WATER. ================== Accidental Release Measures ================== Spill Release Procedures:NEUTRALIZE SPILLED MATERIAL WITH LIME OR SODA ASH. SQUEEGEE AND COLLECT, OR VACUUM SPILLAGE AND PLACE IN CONTAINER FOR DISPOSAL. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:LIME OR SODA ASH. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PROTECTED LOCATION. KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:CLEAN UP SPILLS IMMEDIATELY. TRIPLE RINSE CONTAINER BEFORE REUSE OR DISPOSAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ACID GAS/ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE. Ventilation:GENERAL MECHANICAL VENT RECOMMENDED FOR ENCLOSED AREAS. Other Protective Equipment:EYE WASH STATION. FULL DRENCH SHOWER. PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:215F,102C Vapor Pres:17 Vapor Density:0.6 Spec Gravity:1.092 (H*2O=1) pH:<1 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID. PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG CAUSTIC, METALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HYDROGEN, HYDROGEN CHLORIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AT APPROVED CHEMICAL WASTE REPROCESSING FACILITY. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGS. SMALL QTYS MAY BE DISPOSED OF TO THE SANITARY SEWER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICA GEL CAGE:16210 CAGE:38056 CAGE:0NAV2 CAGE:16210 ============= Composition/Information on Ingredients ============= Ingred Name:AMORPHOUS SILICA GEL (FORMERLY CAS # 63231-67-4) CAS:112926-00-8 RTECS #:VV7322000 Fraction by Wt: 99.0% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY TRACT. ACUTE- CONSIDERED TO BE A NUISSANCE DUST. HAS LOW POTENTIAL FOR ADVERSE HEALTH EFFECTS. EYES/SKIN:MAY CAUSE MECHANICAL IRRITATION. INHALE:DUSTS MAY CAUSE RE SPIRATORY TRACT IRRITATION. ORAL:LOW TOXICITY. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, COUGH, TEARING, REDNESS Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH AIR. EYES:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:FLUSH WITH PLENTY OF WATER. ORAL:RINSE OUT MOUTH WITH WATER. MATERIAL WIL L PASS THROUGH BODY NORMALLY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. CAREFULLY SWEEP OR VACUUM THE SPILL AREA. COLLECT AND PLACE THE SPILLED MATERIAL IN A WASTE DISPOSAL CONTAINER. AVOID DUSTING. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PLACE, IN TIGHTLY CLOSED CONTAINER, AWAY FROM HYDROFLUORIC ACID. KEEP OUT OF REACH OF CHILDREN. PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR FOR DUSTY CONDITIONS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WIT H EYES AND SKIN. AVOID INHALING DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO CONTROL DUST CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED DUST RESPIRATOR SHOULD BE WORN. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED T O COMPLY WITH OSHA 29CFR 1910.134. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP DUST LEVELS AS LOW AS POSSIBLE. Other Protective Equipment:LONG SLEEVE WORK CLOTHING, EYE WASH FOUNTAIN Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health PERCENTAGE DIFFERENT. PH IN 5% SLURRY: 3.5 - 8.5, PER MSDS. ================== Physical/Chemical Properties ================== HCC:V7 NRC/State Lic Num:NOT RELEVANT Spec Gravity:2.1 Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:INSOLUBLE Appearance and Odor:DRY WHITE GRANULES, POWDER OR BEADS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID Stability Condition to Avoid:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL IN ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REUSING OR RECYCLING IS RECOMMENDED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON DIOXIDE REFRIGERATED LIQUID CAGE:2V584 CAGE:2V584 ============= Composition/Information on Ingredients ============= Ingred Name:ING 5:HAVE MECHANICAL REFRIGERATION COILS WITHIN THE VAPOR SPACE IN ORDER TO MAINTAIN PRESSURE IN VESSEL OR TEMP (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: OF THE LIQUID IN THE VESSEL. STATIONARY CUSTOMER SITE VESSELS SHOULD BE OPERATED IN ACCORDANCE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:W/MFGS & THERMICE'S INSTRUCTIONS. DO NOT ATTEMPT TO REPAIR, ADJUST,OR IN ANY OTHER WAY MODIFY OPERATION (ING 9) RTECS #:9999999ZZ Ingred Name:ING 10:OF VESSELS.IF MALFUNCTION OR OTHER TYPE OF OPERATIONS PROBLEM W/VESSEL,CONTACT CLOSEST THERMICE LOCATION IMMED. RTECS #:9999999ZZ Ingred Name:CDTNS(STAB):THIS WEAKLY ACIDIC MATL WILL REACT W/ALKALINE MATLS TO FORM CARBONATES & BICARBONATES. RTECS #:9999999ZZ Ingred Name:SUPP DATA:SENSITIVE MIXTURES WITH SODIUM, POTASSIUM, OR SODIUM - POTASSIUM ALLOY. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CUSTOMER INTO STATIONARY,INSULATED VESSELS AT THE CUSTOMER'S LOCATION.THESE STATIONARY VESSELS MAY (ING 6) RTECS #:9999999ZZ Ingred Name:CARBON DIOXIDE CAS:124-38-9 RTECS #:FF6400000 Fraction by Wt: 100% OSHA PEL:5000 PPM ACGIH TLV:5000PPM/30000STEL;93 Ingred Name:FIRST AID PROC:SHOULD BE SOUGHT IMMED.SKIN:FLUSH AREAS W/LUKEWARM WATER.DO NOT USE HOT WATER.SEE MD IF CRYOGENIC (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:"BURN" HAS RESULTED IN BLISTERING OF DERMAL SURF/DEEP TISS FREEZING.EYE:FLUSH W/POTABLE WATER FOR AT LEAST (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:15 MIN.CALL MD. INGEST:GET MD IMMED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CNS CONTROL OF RESP IS DEPENDENT ON C02 LEVEL BREATHED IN AIR.BY REDUCING O2 LEVEL IN AIR, CO2 CAN CAUSE SUFFOCATION.SYMP OF OVREXPOS INCLUDE HDCH,DIZZ,SHORT OF BREATH, MUSC WEAKNESS, DROWS & RINGING IN EARS.HIGH CONC PRDCE FAINT ACID TASTE & CAN CAUSE PARALYSIS OF BRTHG CTL CNTR OF CNS SYS:2% (SEE EFTS OF OVREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:BY VOL IN ATM WILL CAUSE 50% INCR IN BRTHG RATE;3%, 100% RATE INCR; >4% PRDCE LABORED BRTHG & IS DANG FOR EVEN FEW MIN OF EXPOS;>12% CAUSES RAPID UNCON; FEW HRS EXPOS AT 25% RESULTS IN DEATH. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXPOS TO C02.RESCUE PERS SHOULD BE EQUIP W/SCBA. INHAL:CONSCIOUS PERS SHOULD BE ASSIST TO UNCONTAM AREA & INHAL FRESH AIR.QUICK REMOVAL FROM CONTAMD AR EA IS MOST IMPORTANT.UNCON PERS SHOULD BE MOVED TO UNCONTAMD AREA,GIVEN MOUTH-TO-MOUTH RESUS/SUPP O2.ASSURE THAT VOM MATL DOES NOT OBSTRUCT AIRWAY BY USE OF POSITIONAL DRAINAGE.MED ASSIST(SEE ING 2) ===================== Fire Fighting Measures ===================== Extinguishing Media:NONFLAMMABLE INERT GAS. MEDIA SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA/FULL PROT EQUIP.USE WATER SPRAY TO COOL FIRE-EXPOS CNTNRS TO PVNT RUPTURE.MATL IS NONCOMBUST.CAN BE USED AS FIRE (SUPP DATA) Unusual Fire/Explosion Hazard:NOT EFTIVE FOR USE ON FIRES INVOLVING CHEM W/OWN O2 SUPPLY(I.E.CELLULOSE NITRATE)/ON FIRES INVOLVING REACTIVE METALS (POTASSIUM, SODIUM, MAGNESIUM, (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF MAJOR SPILL OR RELEASE OF CO2.NOTIFY SAFETY PERSONNEL.PROVIDE VENTILATION.CLEAN-UP PERSONNEL NEED SPECIAL TRAINING & PROT AGAINST CONTACT W/VERY COLD MATL/EXCESSIVE INHAL OF GASEOUS C O2 Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE CYLINDERS IN SUB-SURFACE/CLOSED AREAS.CO2 IS HEAVIER THAN AIR/LEAKING GAS COULD ACCUM & CAUSE SUFFOCATION. Other Precautions:COMPRESSED GAS CYLS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED GASES.SHIPMENT OF COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY OWNER OR W/CONSENT IS VIOLATION OF FED LAW. CO2 ,REFRIGERATED LIQ DELIVERED TO (ING 5) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR LINE W/ MASK OR SCBA SHOULD BE AVAILABLE FOR EMERG USE. Ventilation:LOCAL EXHAUST: TO PREVENT ACCUMULATION ABOVE TWA. Other Protective Equipment:SAFETY SHOES.ADDNL PROT CLOTHING(APRON, FACESHIELD,ETC,WHICH ARE RESIST TO LOW TEMPS)TO PREVENT FREEZE BURNS/ FROSTBITE Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:ALUMINUM,TITANIUM & ZIRCONIUM)OR THEIR HYDRIDES AS MATLS CAN DECOMP CO2.FIRE FIGHT PROC:EXTING AGENT PRIMARILY FOR ITS SMOTHERING EFT(REDUCT OF O2 CONC TO PT WHERE IMMED ATM CANNOT COMBUST). MATLS TO AVOID:OXIDE, OR LITHIUM ACETYLIDE W/AMMONIA CAN IGNITE IN A CO2 ATM. DRY ICE CAN FORM SHOCK (SEE ING 11) ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-109F,-78C Melt/Freeze Pt:M.P/F.P Text:-70F,-57C Vapor Pres:844.7 PSIA Solubility in Water:0.8704 Appearance and Odor:COLORLESS,ODORLESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SODIUM PEROXIDE W/ALUMINUM/MAGNESIUM.REACTIVE METALS, THEIR HYDRIDES, MATLS LIKE DIETHYL MAGNESIUM,MOIST CESIUM (SUP DAT Stability Condition to Avoid:CO2 CAUSES VIOLENT POLYMERIZATION OF ACRYLALDEHYDE/ETHYLENEIMINE.IT DECOMPOSES TO CO & 02 WHEN HEATED >1700C. (ING 10) Hazardous Decomposition Products:CARBON MONOXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:ALLOW GAS TO BLEED OFF AT A MODERATE RATE OR SOLID TO SUBLIME TO A WELL VENTILATED AREA. DISPOSE OF I/A/W/FEDERAL,STATE, AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AQUA FORTIS;AZOTIC ACID;NITRIC ACID 90% CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA III) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 90.0% OSHA PEL:2 PPM/4 STEL ACGIH TLV:2 PPM/4 STEL; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:SKIN AND EYES:CORROSIVE, PAIN,SEVEREBURNS,DAMAG TO EYES;INHAL:PULMONARYEDEMA,DIFFICULY IN BREATHING. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:CO*2DRY CHEMICALFOAM, WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA WITH FULL PERSONAL PROTECTION. Unusual Fire/Explosion Hazard:REACTS EXPLOSIVELY WITH COMBUSTIBLE ORGANIC OR READILY OXIDIZABLE MATERIAL.AS ALCOHOLS,METAL POWDER ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION.NEUTRALIZE WITH ALKALINE MATERIAL,PICK UP WITH ABSORBENT MATERIAL LIKE SAND EARTH AND VERMICULITE,AND RECOVER FOR PROPER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL DRY AND WELL VENTILATED AREA.KEEP CONTAINER TIGHLY CLOSED.PROTECT FROM PHYSICAL DAMAGE,DIRECT SUNLIGHT,MOISTURE. Other Precautions:AVOID SKIN AND EYES CONTACT.DO NOT BREATHE VAPORS.USE FULL PERSONAL PROTECTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED SCBAOR A SUPPLIED AIR,FULL-FACEPIECE RESPIRA Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION Supplemental Safety and Health MSDS DATED 7/30/85 ================== Physical/Chemical Properties ================== HCC:C4 Boiling Pt:=98.C, 208.4F Vapor Density:2.5 Spec Gravity:1.48 Solubility in Water:COMPLETE Appearance and Odor:YELLOW TO BROWNISH-RED FUMING LIQUID.SUFFOCAT.ACRD ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG BASES,METLLIC POWDER,CARBIDES,H*2S,COMBUSTIBLE ORGANI Stability Condition to Avoid:HEAT,HOT SURFACES Hazardous Decomposition Products:TOXIC AND CORROSIVE FUMES.OXIDES OF NITROGEN.WHEN HEATED. Conditions to Avoid Polymerization:HEAT OPEN FLAMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH LOCAL STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:OCTAFLO CONCENTRATE Preparer's Name:J. J. BURGARD CAGE:82925 CAGE:82925 ============= Composition/Information on Ingredients ============= Ingred Name:THIS PRODUCT CONTAINS NO INGREDIENTS CURRENTLY LIST BY OSHA OR ACGIH. Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT Ingred Name:TRADE SECRET COMPONENT, REGISTRY NUMBER: 14866100000-5014P Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: NO ADVERSE EFFECTS ARE EXPECTED. INHALATION: NO ADVERSE EFFECTS ARE EXPECTED WITH NORMAL RECOMMENDED USE. INGESTION: ACCIDENTAL INGESTION MAY CAUSE SLIGHT STOMACH DISTRESS. Effects of Overexposure:EYES: MAY CAUSE A STINGING SENSATION AND REDNESS. Medical Cond Aggravated by Exposure:PRE-EXISING EYE DISEASE MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:EYES: FLOOD WITH WATER FOR AT LEAST 15 MIN. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN: WASH EXPOSED AREAWS WITH MILD SOAP AND WATER. IF IRRITATION OCCURS & PERSISTS, GET MEDICAL ATTENTION. INHALATION: MOVE VICTIM TO FRESH AIR. ASSIST WITH BREATHING SUPPORT MEASURES IF NEEDED. INGESTION: ADMINISTER 4-8 OZ OF WATER TO DILUTE STOMACH CONTENTS. DO NOT INDUCE VOMITING. GET MEDICAL HELP. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:255F,124C Extinguishing Media:THIS PRODUCT WILL NOT BURN. Fire Fighting Procedures:KEEP FIRE-EXPOSED CONTAINERS COOL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PRODUCT IS SLIPPERY WHEN SPILLED. SPREAD GRANULAR COVER ON AREA. CONTAIN SPILL/MINIMIZE DISPERSION. IN CONFINED AREAS WEAR PROPER PROTECTIVE CLOTHING AND EQUIPMENT AS APPROPRIATE. COMPLY WITH SPILL NO TIFICATION REQUIREMENTS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM OXIDIZERS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. PROTECT PRODUCT FROM HIGH MOISTURE PICKUP. Other Precautions:USE THIS PROCUT ONLY AS RECOMMENDED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED WITH NORMAL RECOMMENDED USE. Ventilation:LOCAL EXHAUST VENTILATION AND/OR GENERAL MECHANICAL. Other Protective Equipment:WHEN DEICING/ANTI-ICING AIRCRAFT, USE A FACE SHIELD AND SLICKER SUIT. PROVIDE LOCAL SHOWERS AND EYEWASH STATIONS. Work Hygienic Practices:WASH HANDS AND FACE AFTER USING THIS PRODUCT. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:268F,131C Vapor Pres:<0.1 Spec Gravity:1.04 Evaporation Rate & Reference:<1.0 (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:ORANGE, ODORLESS LIQUID. Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY PRODUCE CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:PRODUCT IS BIODEGRADEABLE. DISPOSE OF WASTE IN COMPLIANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. RECYCLE WHENEVER PRACTICAL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:52104201, 400/800 SERIES TONER CAGE:25405 CAGE:25405 Contract Num:SP0450-00-M-SE83 CAGE:1BM21 ============= Composition/Information on Ingredients ============= Ingred Name:STYRENE-BUTYL ACRYLATE COPOLYMER CAS:25153-46-2 = Wt:90.8 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3(TOTAL DUST) ACGIH TLV:10 MG/M3(TOTAL DUST) Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 = Wt:4.5 Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9293 Ingred Name:CHROMIUM AZO DYE (CHROMIUM III CONTENT IS <1%) CAS:31714-55-3 = Wt:1.6 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 (CR III) ACGIH TLV:0.5 MG/M3 (CR III) Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 = Wt:1.8 Other REC Limits:NONE RECOMMENDED OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICONE POLYMER CAS:63148-62-9 RTECS #:JT6484500 < Wt:2. Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 (T DUST) ACGIH TLV:10 MG/M3(T DUST) Ingred Name:POLYPROPYLENE CAS:9003-07-0 RTECS #:UD1842000 < Wt:3. OSHA PEL:TWA 15 MG/M3 TDUST ACGIH TLV:10 MG/M3 T DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION, CORNEAL HYPOPLASIA, CONJUNCTIVITIS. SKIN: MAY CAUSE IRRITATION, ECZEMA. SUBCUTANEOUS IMPLANTATION MAY CAUSE TUMOR FORMATION. INHALATION: MAY CAUSE IRRITATION , BRONCHITIS,KAOLINOSIS (A TYPE OF PNEUMOCONIOSIS) OF THE LUNGS. LONG-TERM EXPOSURE MAY BE ASSOCIATED WITH CAUSING LUNG CANCER. INGESTION: PERIODIC INGESTION HAS BEEN ASSOCIATED WITH LOW BIRTH WEIGHTS IN LABORATO RY ANIMALS. Explanation of Carcinogenicity:MANUFACTURER STATES LONG TERM INHALATION OF CARBON BLACK AND KAOLIN MAY BE ASSOCIATED WITH CAUSING LUNG CANCER. Effects of Overexposure:EYES: IRRITATION, CORNEAL HYPOPLASIA, CONJUNCTIVIS. SKIN: IRRITATION, ECZEMA, TUMOR FORMATION. INHALATION: IRRITATION, BRONCHITIS, KAOLINOSIS (A TYPE OF PNEUMOCONIOSIS),LUNG CANCER. INGESTION: LOW BIR TH WEIGHTS IN LABORATORY ANIMALS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE QUANTITIES OF COOL WATER FOR 15 MINUTES. KEEPING THE EYELIDS OPEN WIH FINGES. SEEK MEDICAL ATTENTION. SKIN: SMALL AMOUNT OF TONER ON SKIN OR CLOTHING CAN EASILY BE REMOVED WITH SOAP AND COLD WATER. HOT WATER MAKES TONER HARDER TO REMOVE. INHALATION: MOVE TO FRESH AIR. SEEK MEDICAL ATTENTION. INGESTION: DILUTE BY GIVING TWO GLASSES OF WATER AND INDUCE VOMITING BY ADMINISTERIN G SYRUP OF IPECAC (FOLLOW MANUFACTURER'S INSTRUCTIONS). SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH OR ATTEMPT TO INDUCE VOMITING IN A PERSON WHO IS UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:NONE. Unusual Fire/Explosion Hazard:ORGANIC COMPONENTS DECOMPOSE AT 200-455C (392-851F). MATERIAL MAY EXPLOSIVELY COMBUST WHEN FINELY SUSPENDED IN AIR. THERMAL DECOMPOSITION OF ORGANIC COMPONENTS MAY RESULT IN RELEASE OF OXIDES OF CARB ON AND NITROGEN. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. CLEAN SMALL SPILLS WITH A WET CLOTH. FOR LARGE SPILLS REMOVE SOURCES OF IGNITION. WEAR WITH SCOOP BEING CAREFUL NOT TO GENERATE A LOT OF DUST. Neutralizing Agent:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM HIGH HEAT. AVOID MAKING DUST. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY REQUIRED. FOR LARGE SPILLS, USE NIOSH- APPROVED FULL FACE-PIECE RESPIRATOR WITH HEPA CARTRIDGE DURING CLEANUP. Ventilation:OUTSIDE OF NORMAL ROOM VENTILATION, NOT NORMALLY REQUIRED. Other Protective Equipment:NONE. Work Hygienic Practices:AVOID GENERATING AND BREATHING DUST. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:=110.C, 230.F Spec Gravity:1.18 Solubility in Water:INSOLUBLE. Appearance and Odor:BLACK GRANULES. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID EXPOSURESTRONG OXIDIZING AGENTS. Stability Condition to Avoid:DO NOT EXPOSE TO TEMPERATURES ABOVE 392F (200C) Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RESULT IN RELEASE OF OXIDES OF CARBON AND NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:FOLLOW APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT IS NOT REGULATED UNDER SECTION 313 OF SARA, TITLE I I I.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPRAY BUFF Preparer's Name:D. S. CAGE:5T372 CAGE:5T372 ============= Composition/Information on Ingredients ============= Ingred Name:TRADESECRET CAS:9016-45-9 Other REC Limits:NONE RECOMMENDED Ingred Name:VOC = 10/G/L RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Effects of Overexposure:CHRONIC CONTACT OF CONCENTRATE W/EYES CAUSES TRANSEANT IRRIT/REDDENING. MAY CAUSE SKIN IRRIT W/SOME PEOPLE. INGESTION MAY CAUSE NAUSEA/VOMITING/DIARRHEA/MUCOSAL IRRITATION. Medical Cond Aggravated by Exposure:PREEXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER >15 MINUTES. CALL DR. SKIN: WASH W/LARGE AMTS SOAP & WATER. IF IRRITATION PERSISTS CALL DR IMMEDIATELY. INGESTION: DON'T INDUCE VOMITING. DILUTE W/WATER & CALL DR IMMEDIATELY. INHAL ATION: MOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER SPRAY. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SCBA/FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILL AT SOURCE. PREVENT RUN-OFF. MOP/SHOVEL/PUMP/ABSORB W/INERT MATERIAL. PLACE IN SOUND CONTAINERS. RINSE REMAINING RESIDUE W/EXCESS WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T EXPOSE TO EXCESS HEAT OR NEAR FREEZING TEMPS. HANDLE ALL CONTAINERS CAREFULLY. Other Precautions:KEEP AWAY FROM CHILDREN ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED IF GOOD VENTILATION MAINTAINED. Ventilation:LOCAL EXHAUST Other Protective Equipment:WORK CLOTHING COVERING ARMS & LEGS. Work Hygienic Practices:FOLLOW FIRST AID PROCEDURES. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:NOT EST. Vapor Density:NOT EST. Spec Gravity:1.018 pH:9.5 Evaporation Rate & Reference:AS WATER Solubility in Water:EMULSIFIABLE Appearance and Odor:MILKY WHITE EMULSION, PLEASANT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, SALT SOLUTIONS, STRONG OXIDIZERS Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA. ==================== Disposal Considerations ==================== Waste Disposal Methods:ACCORDING TO FEDERAL, STATE, LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:36176F/1 CF FIXER WITH HARDENER, PART A Kit Part:Y CAGE:1HS49 CAGE:1HS49 CAGE:6W820 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (SARA III) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: <6% Other REC Limits:NONE SPECIFIED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 Fraction by Wt: <53% Other REC Limits:NONE SPECIFIED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: TO 100% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRODUCT MAY CAUSE EYE, SKIN & RESPIRATORY OR G/I TRACT IRRITATION. IT IS CONSIDERED A LOW HAZARD FOR NORMAL INDUSTRIAL HANDLING. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO INGREDIENT LISTED AS CARCINOGEN BY IARC,NTP, OR OSHA. Effects of Overexposure:EYE:CAUSES IRRITATION SKIN:CAUSES IRRITATION. INHALED:MAY CAUSE IRRITATION IF DUST OR MIST IS INHALED. INGESTED:MAY BE HARMFUL IF SWALLOWED. HMIS:MAY CAUSE G/I IRRITATION,NAUSEA,VOMITING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING AS NEEDED. INGESTED:GIVE 2 LARGE GLASSES OF MILK OR WATER AND INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL CARE. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH MEDIA APPROPRIATE FOR SOURCE OF FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER AS LIQUID OR ADSORB WITH CLOTH,PAPER,OTHER INERT MATERIAL. Neutralizing Agent:SODIUM BICARBONATE NOTE: AMMONIA IS RELEASED ABOVE PH 7 ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED AREA. KEEP TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY FROM ACIDS AND ALKALIS. Other Precautions:READ LABEL THEN FOLLOW INSTRUCTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR INORGANIC DUST/MIST IF EXPOSURE IS ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONS PERTAINING TO RESPIRATOR USE. Ventilation:NORMAL ROOM VENTILATION SUPPLEMENTED WITH LOCAL EXHAUST ESPECIALLY WHEN MIXING. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. USE APRON AND FACE SHIELD WHEN MIXING LIQUIDS OR IF SPLASHING IS LIKELY. Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID UNNECESSARY CONTACT. Supplemental Safety and Health KEY!: N1. THIS MSDS COVERS THE 1 GALLON BOTTLE OF FIXER PRIOR TO MIXING INTO THE WORKING BATH. REFER ALSO TO P/N IND. B FOR THE MSDS OF THE HARDENER. REFER TO BOTH WHEN WORKING WITH THE MIXED BATH. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:>100.C, 212.F Spec Gravity:1.350 pH:5.3 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE = 1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR PALE YELLOW LIQUID, SOUR ODOR OF AMMONIA & VINEGAR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND ALKALIS Stability Condition to Avoid:YNONE GIVEN BY MANUFACTURER (SUPPLIER). Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, SULFUR OXIDES, AMMONIA ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS. MFR SUGGESTS NEUTRALIZE PH THEN FLUSH TO SEWER IF PERMITTED. NOTE: DISPOSAL OF SPENT FIXER REQUIRES REMOVAL OF SILVER PRIOR TO NEUTRALIZATION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:74-6475, CHROMATOGRAPHY SOLVENT (SEE SUPPL) Kit Part:Y CAGE:59896 Contract Num:MDA414-00-P-4038 CAGE:59896 Contract Num:MDA414-98-A-0118-0082 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM ETHER CAS:8032-32-4 RTECS #:OI6180000 = Wt:90. OSHA PEL:300 PPM ACGIH TLV:300 PPM ACGIH STEL:400 PPM Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 = Wt:10. Other REC Limits:NONE RECOMMENDED OSHA PEL:750 PPM ACGIH TLV:750 PPM ACGIH STEL:1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: LUNGS, CENTRAL NERVOUS SYSTEM AND KIDNEYS. EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANCER BY NTP, IARC OR OSHA. Medical Cond Aggravated by Exposure:NO INFORMATION AVAILABLE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINS, RAISING & LOWERING EYELIDS OCCASIONALLY. GET MEDICAL AID. SKIN: THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15 MINS. REMOVE CONTAMINATED CLOTHING. GET MEDIC AL AID, IF IRRITATION PERSISTS. INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF WATER & INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. IMMEDIATELY CALL A PHYSICIAN OR POISON CONT ROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. KEEP PE RSON WARM, QUIET & GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point:=-40.C, -40.F Lower Limits:1.1 Upper Limits:5.9 Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE (CO2), OR APPROPRIATE FOAM Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE, CONFINED MATERIAL CAN EXPLODE ON HEATING. ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN-UP PERSONNEL SHOULD WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA OF SPILL.ABSORB MATERIAL WITH MATERIAL WITH SUITABLE ABSORBANT AND CONTAINERIZE FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE IN COOL AREA, AWAY FROM IGNITION SOURCES & OXIDIZERS. Other Precautions:DO NOT BREATHE VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:MECHANICAL (GENERAL):RECOMMENDED. LOCAL EXHAUST:YES. ALL TIMES. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN, LAB COAT. Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE RESUE. Supplemental Safety and Health PRODUCT NAME: CHROMATOGRAPHY SOLVENT. PRODUCT CODE(S): 74-6865; 74-6470; 74-6475; 84-0546, 10-1036, 68-8950, 68-8951, 68-8953. SIZE:120 ML. SYNONYMS: PETROLEUM ETHER:ACETONE SOLTION. ITEM IS PART OF A 3 PART KIT. CONTRACTOR'S PART NUMBER/TRADE NAME: PIGMENT & PHOTOTHESIS/PART# 7466475. SEE MSDS SERIAL # CKTVR & CLGMD. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:35-60C Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE Vapor Pres:NOT AVAILABLE Vapor Density:2.5 Spec Gravity:0.6 Evaporation Rate & Reference:O.6 (WATER=1)(P. ETHER) Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; GASOLINE-LIKE ODOR. Percent Volatiles by Volume:90-100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:VAPOR CONTACT SPARKS, FLAME OR HOT SURFACES. Hazardous Decomposition Products:COX. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:PETROLEUM ETHER: INH-RAT LC50: 3400 PPM/4H. N-PENTANE: INV-MUS LD50: 446 MG/KG. ACETONE: ORL-RAT LD50: 5800 MG/KG. IHL-RAT LCLO: 16000 PPM/ 4H. ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBERS: D001, U002. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:FLAMMABLE LIQUID, N.O.S. (CONTAINS PETROLEUM ETHER AND ACETONE), 3, UN1993, II. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312 REPORTING: ACUTE, FIRE. SARA SEC. 313 CHEMICALS NAME LIST: YES (ACETONE). Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. RCRA SEC. 261.33: YES (ACETONE). CERCLA SEC. 103 RQ LBS.: 5000 (ACETONE). ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DI(TETRAHYDROFURFURYL)ADIPATE, O-504 CAGE:84898 CAGE:84898 CAGE:8Y898 ============= Composition/Information on Ingredients ============= Ingred Name:DI(TETRAHYDROFURFURYL)ADIPATE OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! OVERALL TOXIC DATA UNAVAILABLE. CAN BE HARMFUL IF SWALLOWED. CAN BE HARMFUL IF INHALED. CAN BE HARMFUL IF ABSORBED THROUGH SKIN. NO TOXICITY DATA HAS BEEN FOUND.ASSUME THIS CHEMICAL IS TOXIC & USE SPECIAL CARE TO AVOID CONTACT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMED . EYES:FLUSH CONTINUOUSLY W/WATER FOR AT LST 15-20 MINS. SKIN:FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED(SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL POWDER. DO NOT USE WATER. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NO EXPLOSION LIMITS ARE AVAILABLE FOR THIS COMPOUND. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR MATERIAL. SWEEP UP & PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. KEEP TIGHTLY CLOSED & STORE IN A COOL, DRY PLACE. STORE ONLY W/COMPATIBLE CHEMICALS. Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD NOT HANDLE THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LAB USE ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PRODS, FO OD ADDITIVES/AS HOUSEHOLD CHEMICALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE APPROP NIOSH/MSHA APPROVED SAFETY EQUIP. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE LABORATORY. Supplemental Safety and Health FIRST AID PROC:ASSISTANCE HAS ARRIVED. NOTE:AN ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFFECT OF A POISON. IT SHOULD BE ADMINISTERED ONLY BY MD OR TRAINED EMERGENCY PERSONNEL. MEDICAL ADVICE CA N BE OBTAINED FROM A POISON CONTROL CENTER. ================== Physical/Chemical Properties ================== Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE W/STRONG BASES, STRONG ACIDS, STRONG REDUCING AGENTS, STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GELATIN & SEMI-GELATIN DYNAMITES, OIL WELL CAGE:79985 CAGE:79985 ============= Composition/Information on Ingredients ============= Ingred Name:NITROGLYCERIN; (NG) (SARA III) CAS:55-63-0 RTECS #:QX2100000 Fraction by Wt: 3-15% OSHA PEL:0.1 MG/M3, S ACGIH TLV:0.05 PPM, S EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYLENE GLYCOL DINITRATE; (EGDN) CAS:628-96-6 RTECS #:KW5600000 Fraction by Wt: 11-50% OSHA PEL:0.2 MG/M3, S, C ACGIH TLV:0.05 PPM, S Ingred Name:AMMONIUM (I) NITRATE (1:1); (AMMONIUM NITRATE) CAS:6484-52-2 RTECS #:BR9050000 Fraction by Wt: 0-40% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION, INHALATION OR ABSORPTION THROUGH SKIN CONTACT MAY CAUSE HEADACHE, NAUSEA, BLOOD VESSEL DILATION, VOMITING & CONVULSIONS. IN EXTREME CASES, DEATH MAY RESULT. EYES:SLIGHT IRRITANT. SKIN:SLIGH T IRRITANT - ABSORBS THROUGH SKIN. NITRIC ESTERS ARE CORONARY VASODILATORS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:HOLD EYE LID OPEN & FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/MILD SOAP & WATER. INGEST:CONSULT MD IF PERSISTENT HEADACHES OR CHEST PAINS DEVELOP. ===================== Fire Fighting Measures ===================== Extinguishing Media:DO NOT FIGHT FIRE. Fire Fighting Procedures:WITHDRAW PERSONNEL IMMEDIATELY. ALLOW FIRE TO BURN ITSELF OUT. DO NOT FIGHT FIRES. Unusual Fire/Explosion Hazard:MAY EXPLODE WHEN SUBJECTED TO FIRE OR SHOCK. AVOID TOXIC FUMES FROM FIRE. EXPLOSION POINT:337F. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & DISPOSE OF ALL SPILLED MATERIAL IMMEDIATELY USING NON-SPARKING TOOLS. DO NOT PERMIT SMOKING OR OPEN FLAMES NEAR SPILL SITE. TRANSPORTATION EMERGENCIES INVOLVING SPILLS, LEAKS, FIRES/EXPOSUR ES CALL CHEMTREC: 1-800-424-9300. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:MINIMIZE INHALATION & SKIN CONTACT. PREVENT CONTACT W/FOOD & CHEWING OR SMOKING MATERIALS. Other Precautions:COMPLY W/"ALWAYS & NEVER" AS ADOPTED BY THE INSTITUTE OF MAKERS OF EXPLOS. TRANSPORTATION, STOR & USE MUST COMPLY W/OSHA SFTY & HLTH STDS, 29CFR1910.109, APPLIC MSHA REGS, DOT & HAZ MATLS REGS, BATF R EQUIREMENTS & STATE & LOC (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NOT REQUIRED UNDER NORMAL CONDITIONS. Ventilation:VENTILATE MAGAZINES BEFORE ENTERING. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VP:0.038-0.05. SOL IN H*2O:SOL IN WATER, BUT NITRIC ESTERS (NG & EGDN) ARE ONLY SLIGHTLY SOL. APPEAR/ODOR:SLIGHTLY SWEET ODOR. OTHER PREC:TRANSPORTATION, STORAGE & USE REGULATIONS & ORDINANCES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Vapor Pres:SUPP DATA Spec Gravity:1-1.7 (H*2O=1) Solubility in Water:SALTS ARE (SUPDAT) Appearance and Odor:MIXT OF ABSORBANTS, WHITE OXIDIZING SALTS. TAN COLOR W/WHITE GRANULES; (SUPDAT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID ALL CONTAMINATION ESPECIALLY ACIDS, ALKALIES, PEROXIDES & CHLORATES. Stability Condition to Avoid:MAY EXPLODE WHEN SUBJECTED TO FIRE OR SHOCK. Hazardous Decomposition Products:GASEOUS NITROGEN OXIDES & CARBON OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP OF UNDER DIRECT SUPERVISION OF QUALIFIED PERS ACCORDING TO LOC, STATE & FED REGS. CALL MFR FOR RECS & ASSISTANCE. THIS MATL MAY BECOME HAZ WASTE UNDER CERTAIN CNDTNS & MUST BE COLLECTED, LABELED& DISPOSED OF PER STATE & FED HAZ WASTEREGS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLFE2-2Y, PLASMA STANDARDS, 1,000 PPM OF IRON IN 2% NITRIC A Resp. Party Other MSDS Num.:PLFE2/CLCLFE2 Preparer's Name:SUSHA RAMANE CAGE:07977 CAGE:04XT3 CAGE:07977 CAGE:07958 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID; (HNO*3); EINECS 231-714-2 CAS:7697-37-2 RTECS #:QU5775000 Minumum % Wt:2. Maxumum % Wt:5. OSHA PEL:5 MG/M3;2 PPM ACGIH TLV:5.2 MG/M3;2 PPM ACGIH STEL:10 MG/M3;4 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:IRON; (FE) CAS:7439-89-6 RTECS #:NO4565500 Minumum % Wt:.1 Maxumum % Wt:1. Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:94. Maxumum % Wt:97. ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:CORROSIVE. HARMFUL BY INGESTION. IRRITATING TO THE EYES AND SKIN UPON CONTACT. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:GENERAL: REMOVE CONTAMINATED CLOTHING, WASH THOROUGHLY BEFORE REUSE. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING AND FLUSH WITH WATER THOROUGHLY. INHALATION: MOVE TO FRESH AIR. CONSULT DOCTOR IF SYMPTOMS PERSIST. INGESTION: GET IMMEDIATE MEDICAL HELP. IF THE PATIENT IS CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN CAN BE RELEASED IN CASE OF FIRE. NOT EXPLOSIVE. NOT SELF IGNITING. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. DO NOT ALLOW TO ENTER DRAINAGE SYSTEMS OR WATER WAYS. DILUTE SPILL WITH WATER AND NEUTRALIZE WITH SODA ASH, LIMESTONE ETC. WIPE UP AND PUT INTO A SEALED CONT AINER FRO PROPER DISPOSAL. WASH SPILL SITE WITH WATER AFTER MATERIAL PICK UP IS COMPLETE. WEAR CHEMICAL Neutralizing Agent:SODA ASH, LIMESTONE, ETC. ======================Handling and Storage ====================== Handling and Storage Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT WORK PLACE. HAVE AN IMMEDIATE AVAILABILITY OF AN EYE WASH IN CASE OF EMERGENCY. STORE AT ROOM TEMPERATURE. KEEP THE CONTAINER TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF BRIEF EXPOSURE, USE NIOSH APPROVED RESPIRATOR. Ventilation:USE UNDER FUME HOOD. FACESHIELD . Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR PROTECTIVE APRON. Supplemental Safety and Health MFR'S TRADE NAME/PART NO: IN 5% NITRIC ACID. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Spec Gravity:APPROXIMATELY 1 pH:1 TO 2 Solubility in Water:MISCIBLE Appearance and Odor:TRANSPARENT LIQUID WITH AN ACRID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH STRONG ALKALI, VARIOUS METALS AND ORGANIC SUBSTANCES. Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE AND USE. Hazardous Decomposition Products:TOXIC FUMES UNDER CONDITIONS OF FIRE. =================== Toxicological Information=================== Toxicological Information:MAY PRODUCE CAUSTIC EFFECT ON SKIN, MUCOUS MEMBRANES AND EYES. SWALLOWING WILL LEAD TO A STRONG CAUSTIC EFFECT ON MOUTH AND THROAT AND TO THE DANER OF PERFORATION OF ESOPHAGUS AND STOMACH. ACCIDENTAL INGESTION OF MEDICINAL IRON HAVE BEEN KNOWN TO CAUSE INTOXICATIONS. TOXICITY DATA: CONCENTRATED HNO*3 - RTECS #QU5775000 - ORL-HMN LDLO: 430 MG/KG; UNK-MAN LDLO: 110 MG/KG. FE - NO TOXICITY DATA AVAIL ABLE. ===================== Ecological Information ===================== Ecological:DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER BODIES OR SEWAGE SYSTEM. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:AIR - CLASS: 8; UN/ID #3264; PACKING GROUP: III; PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (NITRIC ACID SOLUTION).GROUND - CLASS: 8. UN/ID NUMBER: 3264; PACKING GROUP: III; PRO PER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (NITRIC ACID SOLUTION). ===================== Regulatory Information ===================== SARA Title III Information:SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND OF 40 CFR 372. Federal Regulatory Information:COMPONENTS OF THIS SOLUTION ARE REPORTED IN EPA TSCA INVENTORY LIST. WHMIS CLASSIFICATION (CANADA): CLASS E. EC GUIDELINES: C: CORROSIVE. RISK PHRASES: 34 - CAUSES BURNS. SAFETY PHRASES: 36/37/39 - WE AR SUITABLE PROTECTIVE CLOTHING, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ATTENTION. 45 - IN CASE OF ACCIDENT OR IF Y OU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY. ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: 98-0400-0716-7, 00-51115-03267-7, FIRE (SUPP DATA) Cage: 1BY21 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 1BY21 ======================================================= Ingredients ======================================================= Cas: 471-34-1 RTECS #: FF9335000 % Wt: 18.7-22 OSHA PEL: N/K (FP N) ACGIH TLV: 10 MG/M3 (MFR) ------------------------------ Cas: 9010-98-4 RTECS #: EI9460000 % Wt: <20.4 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 % Wt: <18.5 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM;150 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 78-93-3 RTECS #: EL6475000 % Wt: <18.5 OSHA PEL: 200 PPM ACGIH TLV: 200 PPM;300 STEL EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS ------------------------------ Cas: 1344-09-8 % Wt: <13.6 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 68527-02-6 % Wt: 5-5.8 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1241-94-7 RTECS #: TC6125000 PHOSPHATE) % Wt: 3.3-3.9 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 1305-62-0 RTECS #: EW2800000 % Wt: 2-2.4 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 5 MG/M3 ------------------------------ Cas: 7732-18-5 RTECS #: ZC0110000 % Wt: 1.9-2.2 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ RTECS #: 9999999VO G/L. ----------------------------- COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS ----------------------------- DISORDERS:SIGNS/SYMPS CAN INCL PRLNG WEAK & FATG. ----------------------------- INGEST:NOT LIKELY RTE OF EXPOS TO THIS PROD. ----------------------------- TENDERNESS, NAUS, BLOOD IN VOMITUS & BLOOD IN FECES. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE CONT:MOD IRRIT:SIGNS/SYMPS CAN INCL REDNESS, SWELL, PAIN, TEARING & HAZY VISION. SKIN CONT:MILD IRRIT(AFTER PRLNG/RPTD CONT):SIGNS/SYMPS CAN INCL REDNESS, SWELL & ITCH. MAY BE ABSORBED & PRDCE EFT S SIMILAR TO THOSE CAUSED BY INHAL &/ORINGEST. INHAL:CNS DEPRESS:SIGNS/SYMPS CAN INCL HDCH, DIZZ, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:DROW, INCOORD, SLOWED RXN TIME, SLURRED SPEECH, GIDD & UNCON. IRRIT(UPPER RESP): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGH & SNEEZING. PRLNG/RPTD OVEREXP, ABOVE REC GUIDELINES, MA Y CAUSE:KIDNEY EFTS:SIGNS/ SYMPS CAN INCL REDUCED URINE VOL, BLOOD IN URINE & BACK PAIN. LIVER EFTS:SIGNS/SYMPS (SUPDAT) Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES:IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN:FLUSH W/LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHAL:REMO VE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GET IMMEDIATE MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOMITING, DRINK TWO GLASSES OF WATER. CALL MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFO REGARDING PHYSICAL & HLTH HAZS, RESP PROT, VENT & PPE. IN USA, CALL (612)733-1110/(612)733-6100 FOR 24-HR SPILL ASSISTANCE, VENT AREA. EXTING ALL IGNIT SO URCES. COVER W/ABSORB MATL. COLLECT USING (SUPDAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP MUST BE I/A/W FED, STATE & LOC REGS (FP N). INCIN IN PERMITTED HAZ WASTE INCIN IN PRESENCE OF COMBUST MATL. DISP OF COMPLETELY CURED (OR POLYMERIZED) MATL IN SANIT LANDFILL. SINCE REGS VARY, CONS ULT APPLIC REGS/AUTHS BEFORE DISP. U.S.(SUPDAT) Handling And Storage Precautions: AVOID EYE CONTACT. AVOID PROLONGED OR REPEATED SKIN CONTACT. USE IN A WELL-VENTILATED AREA. AVOID PROLONGED BREATHING OF VAPORS. DO NOT INGEST. Other Precautions: KEEP CONTAINER TIGHTLY CLOSED. FLAMMABLE LIQUID & VAPOR. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & OTHER SOURCES OF IGNITION. PRECAUTIONARY INFORMATION & FLASH POINT REFER TO UNCURED PRODUCT BEFORE AP PLICATION. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: 50.0F,10.0C Lower Limits: 1.81% Upper Limits: 11.5% Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE & EXPLODE. VAPORS MAY TRAVEL LONG DISTANCES ALONG GROUND/FLOOR TO IGNITION SOURCE & FLASH BACK. ======================================================= Control Measures ======================================================= Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS & I/A/W OSHA REGULATIONS: HALF-MASK ORGANIC VAPOR RESPIRATOR. Ventilation: PROVIDE SUFFICIENT VENT TO MAINTAIN EMISSIONS BELOW RELS. IF EXHST VENT IS NOT ADEQ, USE APPROP NIOSH APPRVD RESP PROT. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: MFR'S TRADE NAME/PART NO:BARRIER CP-25 N/S NO-SAG CAULK. SPILL PROC:NON-SPARKING TOOLS. PLACE IN U.S. DOT-APPRVD CNTNR. WASTE DISP METH:EPA HAZ WASTE #:D001(IGNITABLE). EFTS OF OVEREXP:CAN INCL YELLOW SKIN(JAUN) & TENDERNESS OF UPPER ABDOMEN. WHILE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF INDIVIDUAL INGS IN ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 1.26 Solubility in Water: NIL Appearance and Odor: REDDISH BROWN PASTE; SOLVENT ODOR. Percent Volatiles by Volume: 34(WT) ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Hazardous Decomposition Products: CARBON MONOXIDE & CARBON DIOXIDE, HYDROGEN CHLORIDE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 98-0400-0716-7, 00-51115-03267-7, FIRE (SUPP DATA) Cage: 1BY21 Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV Street: 3M CTR Zipcode: 55144-1000 Label Required IND: Y Date Of Label Review: 04/29/1997 Status Code: C Label Date: 04/29/1997 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE. ACUTE:EYE CONT:IRRIT; REDNESS, SWELLING, PAIN, TEARING & HAZY VISION. SKIN CONT:IRRIT; REDNESS, SWELLING & ITCHING. MAY BE ABSORBED & PRDCE EFTS SIMILAR TO THOSE CAUSED BY INHAL &/OR INGEST . INHAL:CNS DEPRESS:HDCH, DIZZ, DROW, INCOORD, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, UNCONSCIOUSNESS. IRRIT; SORE NOSE & THROAT, COUGHING, SNEEZING. BLOOD DISORDERS, PROLONGED WEAKNESS, FAT IGUE. HEART EFTS:ARRHYTHMIA, HEART ATTACK & DEATH. INGEST:IRRIT; PAIN, VOMIT, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMIT & FECES. CHRONIC:KIDNEY EFTS, REDUCED URINE VOLUME, BLOOD IN URINE, BACK PAIN . LIVER:YELLOW SKIN, TENDERNESS OF UPPER ABDOMEN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:THORIUM FLUORIDE CAGE:67027 CAGE:67027 CAGE:3U331 CAGE:11323 CAGE:01295 CAGE:19200 ============= Composition/Information on Ingredients ============= Ingred Name:THORIUM TETRAFLUORIDE CAS:13709-59-6 Fraction by Wt: 100% Other REC Limits:SEE NRC LIMIT FOR TH OSHA PEL:2.5 MG F/M3 ACGIH TLV:2.5 MG F/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-RESPIRATORY IRRITANT. DERMAL IRRITANT. EYE IRRITANT. MAY CAUSE G/I IRRITATION. CHRONIC-ANY EXPOSURE TO THORIUM FLUORIDE BY ANY ROUTE MAY LEAD TO CANCER AT SITE OF RETENTION. WILL CAUSE FLUORIOS IS. Explanation of Carcinogenicity:RADIOACTIVE. IF RETAINED IN BODY, MAY CAUSE CANCER AT SITE OF RETENTION. Effects of Overexposure:EYE:IRRITATION, INFLAMMATION, WATERING. SKIN:IRRITATION, ITCHING, DERMATITIS. INHALATION:RESPIRATORY IRRITATION, COUGHING, SNEEZING, DIFFICULTY BREATHING. MAY ALSO CAUSE (FLUOROSIS) ANOREXIA, ANEMIA, LOSS OF WEIGHT. INGESTION:G/I IRRITATION, NAUSEA, VOMITING, FLUOROSIS. Medical Cond Aggravated by Exposure:PREVIOUS RESPIRATORY OR SKIN DISORDERS. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. AID OR RESTORE BREATHING AS NEEDED. INGESTED:GIVE 2 GLASSES OF WATER & INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NA Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES. Unusual Fire/Explosion Hazard:TOXIC & RADIOACTIVE FUMES MAY GENERATE IF INVOLVED IN A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. ISOLATE SPILL AREA. VENTILATE. VACUUM SPILL USING HIGH EFFICIENCY UNIT (HEPA) & PLACE IN CONTAINER FOR PROPER DISPOSAL. TAKE CARE NO T TO RAISE DUST. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN A COOL, DRY PLACE LABELED AS A RADIOACTIVE STORAGE AREA. WASH HANDS & FACE THOROUGHLY AFTER HANDLING. Other Precautions:SHOWERING AFTER HANDLING IS RECOMMENDED. PERSONAL DOSIMETER SHOULD BE WORN BY PERSONNEL WORKING W/THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED DUST-MIST-FUME RESPIRATOR W/HIGH EFFICIENCY FILTERS APPROVED FOR RADIONUCLIDES. WEAR PERSONAL AIR MONITOR. Ventilation:LOCAL EXHAUST TO MAINTIAN EXPOSURE BELOW NRC LIMIT. SPECIAL VENTILATION:WEAR PERSONAL AIR MONITOR & DOSIMETER. Other Protective Equipment:WEAR DISPOSABLE RADIATION RESISTANT PROTECTIVE CLOTHING TO PREVENT CONTAMINATION OF SKIN & CLOTHES. Work Hygienic Practices:SHOWERING AFTER HANDLING IS RECOMMENDED. PERSONAL DOSIMETER SHOULD BE WORN BY PERSONNEL WORKING W/THIS MATERIAL. Supplemental Safety and Health ADD THAT THIS INFO IS FOR RADIOACITVE INGREDIENT (TH232). NO MSDS IS REQUIRED FOR RECEIVER SUBASSEMBLY FOR THE TH232 SINCE THE QUANTITY IS W/I THE "EXCEPTED QUANTITY" FOR INSTRUMENTS & ARTICLES & NOT CONSIDERED HAZARDOUS BY OSHA. PROPER SHIPPING NAME FOR THIS ITEM IS "RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, UN2910". ================== Physical/Chemical Properties ================== HCC:A2 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:ND Melt/Freeze Pt:M.P/F.P Text:>1652F,>900 Vapor Pres:NA Spec Gravity:6.32 Evaporation Rate & Reference:NA Solubility in Water:VERY SLIGHT Appearance and Odor:WHITE CRYSTALLINE POWDER OR PIECES, NO ODOR. - ALPHA RADIATION EMITTER Percent Volatiles by Volume:NA Corrosion Rate:UNKNOWNN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO ACIDS, INTERAHALOGENS. Stability Condition to Avoid:UNSTABLE - NATURAL RADIOACTIVE DECAY. Hazardous Decomposition Products:FUMES (THERMAL). APLHA, BETA, GAMMA RADIATION. THORIUM DAUGHTERS. Conditions to Avoid Polymerization:WILL NOT OCCUR.HEAT, INCOMPATIBLE MATERIALS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DIPHENYLAMINE CAGE:DO870 CAGE:DO870 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:DIPHENYLAMINE CAS:122-39-4 RTECS #:JJ7800000 Fraction by Wt: 90- 100% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALATION:HEADACHE,COUGHING,DIZZINESS,DIFFICULT BREATHING.EYE/SKIN:IRRITATION.INGESTION:NONE IDENTIFIED.CHRONIC-NONE IDENTIFIED. Effects of Overexposure:SEE HEALTH HAZARDS SECTION. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:CALL A DOCTOR IF NEEDED.EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES,HOLDING LIDS OPEN.SKIN:FLUSH WITH WATER.INHALATION:REMOVE TO FRESH AIR.GIVE CPR/OXYGEN IF NEEDED.INGESTION:IF CONSCIOUS,DRINK SE VERAL GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:307F,153C Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE.COOL CONTAINERS WITH WATER SPRAY. Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP CONTAINER TIGHTLY CLOSED.KEEP PRODUCT OUT OF LIGHT.STORAGE COLOR CODE IS ORANGE (GENERAL STORAGE). Other Precautions:SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. DO NOT STORE NEAR HEAT. MINIMIZE BREATHING DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 1 PPM, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. Ventilation:GENERAL OR LOCAL VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:575F,302C Melt/Freeze Pt:M.P/F.P Text:127F,53C Vapor Pres:0.03 Vapor Density:5.82 Spec Gravity:1.16 Solubility in Water:NEGLIGIBLE Appearance and Odor:WHITE TO GRAY CRYSTALS, FLORAL ODOR Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:LIGHT Hazardous Decomposition Products:OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN CONFORMITY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:4% CITANEST PLAIN SOLUTION CAGE:04473 CAGE:04473 ============= Composition/Information on Ingredients ============= Ingred Name:PRILOCAINE HYDROCHLORIDE CAS:1786-81-8 RTECS #:UG5775000 Fraction by Wt: 4.0% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INGESTION: TOXIC EFFECTS ON CENTRAL NERVOUS SYSTEM/CARDIOVASCULAR SYSTEM. SKIN: ALLERGIC REACTION. INHALATION: MUCOUS MEMBRANE IRRITATION, NUMBNESS, LOSS OF SENSATION, NERVOUSNESS, CONFUSION, DROWSINE SS, VOMITING, TREMORS, CONVULSIONS, RESPIRATORY DEPRESSION/UNCONSCIOUSNESS. EYES: IRRITATION & BLURRED VISION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: SLOWING OF HEART/BLODD PRESSURE DROP, UNCONSCIOUSNESS, NERVOUSNESS, CONFUSION, DROWSINESS, VOMITING, TREMORS, CONVULSION, RESPIRATORY DEPRESSION, MUCOUS MEMBRANE IRRITATION, NUMBNESS & LOS S OF SENSATION. INGESTION: TOXIC EFFECTS ON CNS/CARDIOVASCULAR SYSTEM. SKIN: ALLERGIC REACTION. EYES: BLURRED VISION. Medical Cond Aggravated by Exposure:ALLERGIC REACTION, CONGENITAL OR IDIOPATHIC METHEMOGLOBINEMIA ======================= First Aid Measures ======================= First Aid:EYES: WASH THOROUGHLY W/CLEAN WATER FOR 15 MINUTES. INHALATION: MAINTAIN BREATHING & CONTROL CONVULSION. CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP SPILLS W/NORMAL PROCEDURES USED FOR NON-HAZARDOUS LIQUID. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. AVOID EXTREME TEMPERATURE. HANDLED TO AVOID BREAKAGE. AVOID CONTACT W/EYES & SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED Ventilation:NONE NORMALLY REQUIRED Supplemental Safety and Health PRILOCAIN HYDROCHLORIDE IS A LOCAL ANESTHETIC AGENT, & LIKE ALL LOCAL ANESTHETICS IT CAN DEPRESS EXCITABLE TISSUES. THUS IT MAY CAUSE ADVERSE EFFECTS ON THE NERVOUS SYSTEM. ON RESPIRATION, & ON THE CA RDIOVASCULAR SYSTEM. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text: 100C Melt/Freeze Pt:M.P/F.P Text: 0 Vapor Pres: 17 Vapor Density:0.6 Spec Gravity: 1 Evaporation Rate & Reference:(WATER = 1): 1 Solubility in Water:SOLUBLE Appearance and Odor:CLEAR & ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMPOUNDS OR MATERIALS WHICH REACT VIOLENTLY W/WATER. Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS A NON-HAZARDOUS WASTE.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:SULFURIC ACID, 5374 CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 90-98% OSHA PEL:1 MG/M3;3 MG/M3 STEL ACGIH TLV:1 MG/M3;3 MG/M3 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 2-10% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 2140 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL:SEVERE IRRIT OR BURNS OF RESP SYSTEM, PULM EDEMA, LUNG INFLAM. SKIN:SEVERE BURNS. EYE:SEVERE BURNS. INGEST: NAUSEA, VOMIT, SEVERE BURNS TO MOUTH, THROAT & STOMACH, KIDNEY DYSFUNCTION. (CHRONIC) LUNG DAMAGE. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD. DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LRG AMTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE OXYGEN. SKIN: IMMED FLUSH W/ PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE RE-USE. EYE: IMMED FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Extinguishing Media:USE DRY CHEMICAL OR CO2. DO NOT USE WATER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . DO NOT GET WATER INSIDE CONTAINERS. Unusual Fire/Explosion Hazard:REACTS W/MOST METALS TO PRODUCE HYDROGEN GAS, WHICH CAN FORM AN EXPLO MIXT W/AIR. A VIOLENT EXOTHERMIC RXN OCCURS W/ WATER. SUFF HEAT MAY BE PRODUCED (SUPP DATA ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. DO NOT USE WATER. WITH CLEAN SHOVEL, PLACE MATL IN CLEAN, DRY CNTNR & COVER. MOVE CNTNRS FROM SPILL AREA. Neutralizing Agent:J.T. BAKER NEUTRASORB(R)/TEAM LOW NA+ ACID, SODA ASH OR LIME. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. KEEP CNTNRS OUT OF SUN & AWAY FROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. Other Precautions:DO NOT GET IN EYES, ON SKIN/CLOTHING. DO NOT BREATHE VAPORS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH/MSHA APPROVED SCBA IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT. EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ: TO IGNITE COMBUSTIBLE MATERIALS. MATL TO AVOID: SULFIDES, CYANIDES, STRONG OXIDIZING AGENTS, CARBIDES. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:620F,327C Melt/Freeze Pt:M.P/F.P Text:28.0F,-2.2C Vapor Pres:<0.3 Vapor Density:3.4 Spec Gravity:1.84 pH:1 Evaporation Rate & Reference:<1 (BUTYL ACETATE = 1) Solubility in Water:COMPLETE (100%) Appearance and Odor:CLEAR, COLORLESS TO YELLOW VISCOUS LIQUID WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, MOST COMMON METALS, ORG MATLS, STRONG REDUCING AGENTS, COMBUST MATLS, STRONG BASES, CARBONATES, (SUPP DATA) Stability Condition to Avoid:MOISTURE, HEAT. Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:K5 BLACK INK CAGE:21230 CAGE:21230 ============= Composition/Information on Ingredients ============= Ingred Name:PROPYL ALCOHOL; (N-PROPYL ALCOHOL) VP: 14.5 @ 68F CAS:71-23-8 RTECS #:UH8225000 Fraction by Wt: 25% OSHA PEL:200 PPM; 250 STEL ACGIH TLV:200 PPM; 250 STEL, S Ingred Name:ETHANOL, 2-PROPOXY-; (ETHYLENE GLYCOL MONOPROPYL ETHER) VP: 1.3 @ 77F CAS:2807-30-9 RTECS #:KM2800000 Fraction by Wt: 42% OSHA PEL:25 PPM (MFR) ACGIH TLV:25 PPM, S (MFR) Ingred Name:VOLATILE ORGANIC COMPOUND: 5.71 LB/GAL RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MODERATE IRRITATION OF EYES, NOSE, THROAT & SKIN. HIGH CONCENTRATIONS MAY CAUSE NERVOUS SYSTEM DISTURBANCES. INHALATION: IRRITATION OF NOSE & THROAT, DIZZINESS, HEADACHE & NAUSEA. EYES: MAY CA USE IRRITATION & POSSIBLE CORNEAL DAMAGE. SKIN: CONTACT MAY DRY & IRRITATE SKIN. DERMATITIS MAY RESULT (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: FROM REPEATED CONTACT & LARGE AMOUNTS MAY BE ABSORBED THROUGH SKIN IN TOXIC AMOUNTS. INGESTION: CAN CAUSE NAUSEA, VOMITING & NARCOSIS. CHRONIC: EXCESSIVE EXPOSURE MAY CAUSE KIDNEY, LIVER & P OSSIBLY BLOOD DISTURBANCES (ANEMIA). Medical Cond Aggravated by Exposure:RESPIRATORY IRRITATION, DERMATITIS, ANEMIA AND NAUSEA. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING. TREAT SYMPTOMS. CONSULT MD. EYES: FLUSH IMMEDIATELY W/WATER FOR AT LEAST 15 MIN. SEE MD. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING. CONSULT MD IF IRRITATION PERSISTS. INGEST: DRINK WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:71.0F,21.7C Lower Limits:1.3% Upper Limits:13.5% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT EXPLOS WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE OR COLLAPSE WHEN EXPOSED TO EXTREME HEAT. DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF VAPOR, IGNITION. VENTILATE AREA. AVOID BREATHING VAPORS. REMOVE BY SUITABLE INERT ABSORBING MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. KEEP AWAY FROM SPARKS AND OPEN FLAME. AVOID EXCESSIVE INHALATION OF VAPOR OR MIST. Other Precautions:I/A/W GOOD INDUSTRIAL PRACTICE, HANDLE W/CARE & AVOID UNNEC CNTCT. USE ONLY W/ADEQ VENT. WASH THOROUGHLY AFTER HANDLING. PRACTICE GOOD PERSONAL HYGIENE. FOR INDUSTRIAL USE ONLY. HMIS PERSONAL PROT EQU IP IS DEPENDENT UPON CNDTNS OF USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPRVD RESPIRATOR APPROP FOR EXPOSURE OF CONCERN . WHEN USED W/ADEQ VENTILATION, NONE NORMALLY REQD. HOWEVER, WHEN REQD, ITS USE MUST BE IN COMPLIANCE W/ALL OSHA HLTH & FIT TESTIN G REQS AS GIVEN IN 29CFR 1910.134. Ventilation:SUFFICIENT VOLUME & PATTERN SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT CONCENTRATIONS BELOW CURRENT ACGIH TLV LIMITS. Other Protective Equipment:USE PROTECTIVE CREAM WHERE SKIN CONTACT IS LIKELY. Work Hygienic Practices:WASH HANDS BEFORE EATING, DRINKING OR SMOKING. AVOID SMOKING IN WORK AREA. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:>204F,>96C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.9 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INSOLUBLE Appearance and Odor:THIN COLORED LIQUID; ALCOHOLIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH STRONG ACIDS, ALKALIES OR OXIDIZERS. Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAME. Hazardous Decomposition Products:MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN & OTHER HAZARDOUS DECOMPOSITION PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATION IS PREFERRED, IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REFER TO MSDS CAUTION INFORMATION BEFORE ATTEMPTING CLEANUP.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:C-150 ENGLISH ROSE GROUT CAGE:90300 CAGE:90300 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 40-70% ACGIH TLV:10 MG/CUM (DUST) Ingred Name:PORTLAND CEMENT, CONTAINS: TRICALCIUM SILICATE, DICALCIUM SILICATE, TRICALCIUM ALUMINATE, TETRACALCIUM ALUMINOFERRATE CAS:65997-15-1 RTECS #:VV8770000 Fraction by Wt: 30-45% Other REC Limits:50 MPPCF (MSHA) OSHA PEL:10 MG/CUM (DUST) ACGIH TLV:10 MG/CUM (DUST) Ingred Name:IRON OXIDE, MAGNETITE *94-3* CAS:1317-61-9 Fraction by Wt: 0-10% Ingred Name:IRON HYDROXIDE OXIDE *94-3* CAS:20344-49-4 Fraction by Wt: 0-5% Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0-5% OSHA PEL:10 MG/CUM ACGIH TLV:5 MG/CUM (FE) Ingred Name:CHROMIUM (III) OXIDE (2:3), CR2-O3, CHROMIUM OXIDE CAS:1308-38-9 RTECS #:GB6475000 Fraction by Wt: 0-5% OSHA PEL:1 MG/CUM ACGIH TLV:0.5 MG/CUM Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS (ANIMAL/HUMAN INADEQUATE EVIDENCE, IARC GROUP3)*94-3* CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 0-5% Other REC Limits:3.5 MG/CUM (NIOSH) OSHA PEL:3.5 MG/CUM ACGIH TLV:3.5 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:WET CEMENT CAN DRY THE SKIN & CAUSE ALKALI BURNS. EXPOSURE TO DUST MAY RESULT IN BUILD-UP OF MATERIAL IN EYES, EARS, NOSE & MOUTH WHICH MAY CAUSE IRRITATION. CHRONIC INHALATION OF DUST MAY RESULT IN P ULMONARY & RESPIRATORY DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:WET CEMENT CAN DRY THE SKIN & CAUSE ALKALI BURNS. EXPOSURE TO DUST MAY RESULT IN BUIL-UP OF MATERIAL IN EYES, EARS, NOSE & MOUTH WHICH MAY CAUSE IRRITATION. INHALATION OF DUST MAY RESULT IN PULMONARY & RESPIRATORY DAMAGE. Medical Cond Aggravated by Exposure:ASTHMA & ASTHMA LIKE CONDITIONS ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:USE WATER SPRAY TO COOL EXPOSED SURFACES. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM UP & REUSE EXCESS POWDER. PLACE REMAINING POWDER INTO CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM CAUSTICS & OXIDIZERS. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP CONTAINERS FROM EXCESSIVE HEAT & FREEZING. Other Precautions:KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF 8-HOUR EXPOSURE LIMIT/VALUE IS EXCEEDED USE NIOSH/OSHA APPROVED RESPIRATOR. Ventilation:IF DRY-SANDING, PROVIDE SUFFICIENT MECHANICAL VENTILATION TO MAINTAIN EXPOSURE BELOW PEL & TLV. Work Hygienic Practices:REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health SOLUBILITY IN WATER: FORMS AN ALKALINE DISPERSION IN WATER. ================== Physical/Chemical Properties ================== Spec Gravity:2.3-2.4 Solubility in Water:(SEE SUPP DATA) Appearance and Odor:FREE-FLOWING POWDER, LOW ODOR W/COLOR AS SPECIFIED. Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, STRONG OXIDIZERS & CAUSTICS Stability Condition to Avoid:EXCESSIVE HEAT, FREEZING ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BUFFER SOLUTION PH 10, 41118, SB11610 CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 0.6% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM HYDROXIDE (CERCLA). LD50: (ORAL, RAT) 273 MG/KG. CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 0.2% OSHA PEL:2 MG/M3, C ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:DISODIUM DIHYDROGEN ETHYLENEDIAMINETETRACETATEDIHYDRATE CAS:6381-92-6 RTECS #:AH4410000 Fraction by Wt: 1.0% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:POTASSIUM TETRABORATE; (POTASSIUM BORATE) CAS:12228-88-5 Fraction by Wt: 0.4% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 2 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: MAY CAUSE EYE IRRITATION. SKIN: MAY CAUSE MILD SKIN IRRITATION. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. INGESTION: LOW HAZARD FOR USUAL INDUSTRIAL HANDLING. MAY CAUSE GASTRIC DISTURBANCES AND E LECTROLYTIC IMBALANCE. INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. LOW HAZARD FOR USUAL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: INDUSTRIAL HANDLING. CHRONIC: NO INFORMATION FOUND. TARGET ORGANS: NONE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: GET MEDICAL AID. GENTLY LIFT EYELIDS AND FLUSH CONTINUOUSLY WITH WATER FOR AT LEAST 15 MINUTES. SKIN: GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. FLUSH SKIN WITH PLENTY OF SOAP AND WATER . INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID. INHAL: GET MEDICAL AID IMMEDIATELY. REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED. ABSORB SPILL WITH INERT MATERIAL (EG DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. Other Precautions:USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES. KEEP CONTAINER TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: BREATHING, GIVE ARTIFICIAL RESPIRATION. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ANTIDOTE: NONE REPORTED. ================== Physical/Chemical Properties ================== Evaporation Rate & Reference:1.0 (ETHER =1) Solubility in Water:SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NOT AVAILABLE. Stability Condition to Avoid:NONE REPORTED. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WCP-700 SERIES, FEDERAL TRAFFIC PAINT, (SUPDAT) Preparer's Name:DAN DULAVA CAGE:WC0LL CAGE:WC0LL ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <11.05% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: <19% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: <28% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: TRACE OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: TRACE OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ACETALDEHYDE (SARA 313) (CERCLA) CAS:75-07-0 RTECS #:AB1925000 Fraction by Wt: TRACE OSHA PEL:200 PPM ACGIH TLV:C 25PPM, A3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VINYL CHLORIDE (SARA 313) (CERCLA) CAS:75-01-4 RTECS #:KU9625000 Fraction by Wt: TRACE OSHA PEL:SEE 1910.1017 ACGIH TLV:5 PPM, A1 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:VOLATILE ORGANIC COMPOUNDS LB/GAL:UNDER 250 (GRAM/LITER) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:TRACE COMPONENT & RESIDUAL MONOMER VAP MAY BE IRRIT TO EYES, SKIN, MUC MEMB, RESP TRACT, & MAY PRDCE SYMP OF HDCH, NAUS IN POORLY VENTILATED AREAS. PRLNGD CONT MAY CAUSE TRANSIENT REDDENING OF T HE SKIN. DIRECT EYE CONT MAY CAUSE EYE IRRIT. THIS PROD CONTAINS CRYSTALLINE SILICA WHICH IS (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONO, SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994: (SUPDAT) Effects of Overexposure:HLTH HAZ:CONSIDERED A HAZ BY INHAL. CRYSTALLINE SILICA HAS BEEN CLASSIFIED AS PROBABLY CARCIN FOR HUMANS BY IARC. CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS. THIS PROD CNTNS TRACE AMTS OF F ORMALDEHYDE, VINYL CHLORIDE & ACETALDEHYDE WHICH ARE CONSIDERED CARCIN. TRACE AMTS OF ETHYLENE OXIDE MAY BE (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD ( ). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . NON-FLAMMABLE. AFTER WATER EVAPORATES, REMAINING MATERIAL WILL BURN. Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN BUT MAY SPATTER IF TEMPERATURE EXCEEDS BOILING POINT OF WATER. DRIED SOLIDS CAN BURN GIVING OFF OXIDES OF CARBON. ================== Accidental Release Measures ================== Spill Release Procedures:STAY UPWIND AND AWAY FROM SPILL. IF SPILL IS INDOORS, VENTILATE AREA OF SPILL. IF LARGE SPILL, CALL SPILL RESPONSE TEAM. NOTIFY APPROPRIATE STATE/LOCAL AGENCIES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALWAYS PROTECT YOURSELF AND OTHER WHEN USING THIS PRODUCT. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MAINTAIN PROPER VENT IN WORKING AREA TO KEEP AIR CONTAMINANT CONC BELOW OSHA PEL EXPOSURE LEVEL. Other Protective Equipment:WEAR PROT CLTHG AS REQD TO PVNT SKIN CONTACT. ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMKNG/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE REUSE. Supplemental Safety and Health MFR TRADE NAME/PART NO:YELLOW WATER BORNE. EXPLAN OF CARCIN:ANTIC TO BE CARCIN. EFTS OF OVEREXP:PRESENT WHICH IS CARCIN & REPRO TOXIN. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>210F,>99C Vapor Density:HVR/AIR Spec Gravity:1.54 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:DILUTABLE Appearance and Odor:OPAQUE LIQUID, MILD PAINT ODOR. Percent Volatiles by Volume:48.72 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID MINERALS THAT REACT WITH WATER. Stability Condition to Avoid:AVOID FREEZING. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBOTHANE 134 HS PART A CAGE:06634 CAGE:06634 ============= Composition/Information on Ingredients ============= Ingred Name:COLOR PIGMENT (MIXTURE MAY CONTAINS INGS 2 - 5 IN VARYING AMOUNTS DEPENDING ON COLOR OF PRODUCT) RTECS #:9999999ZZ Fraction by Wt: <30% OSHA PEL:N/K ACGIH TLV:3.5 MG/M3 (MFR) Ingred Name:IRON OXIDES CAS:1309-38-2 RTECS #:OM4800000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:OTHER INGREDIENTS; (OTHER PARTICULATES NOT OTHERWISE REGULATED) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <15% OSHA PEL:N/K ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:ACETIC ACID, BUTYL ESTER; (BUTYL ACETATE) (CERCLA) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <10% OSHA PEL:150 PPM ACGIH TLV:150 PPM;200 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2737 MG/KG. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <10% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:PENETRATES SKIN, CHANGE CLOTHING. USE OF A HAND CLEANER IS RECOMMENDED. RTECS #:9999999ZZ Ingred Name:HYGIENE PRACT:BEFORE REUSE. LEATHER SHOES CAN ABSORB & PASS THRU HAZ MATLS. CHECK SHOES CAREFULLY AFTER SOAKING (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:BEFORE REUSE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 8. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION:HARMFUL IF INHALED, MAY AFFECT BRAIN OR NERVOUS SYSTEM, CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE NOSE & THROAT IRRITATION. CONTACT:MAY CAUSE EYE AND SKIN IRRITATION. NOTICE:CONTAINS SILICA WHICH CAN CAUSE CANCER. RISK OFCANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE. REPORTS HAVE (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC TO BE (SUPDAT) Effects of Overexposure:HLTH HAZ:ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:IF YOU HAVE A CONDITION THAT COULD BE AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS SEE MD PRIOR TO USE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & CLEAN BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. USE ARTIFI CIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOMITING! ALWAYS GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:43.0F,6.1C Lower Limits:1.7% Upper Limits:10.1% Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . EVACUATE HAZARD AREA OF UNPROTECTED PERS. COOL SURROUNDING CNTNRS W/WATER IN CASE OF FIRE EXPOSURE. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. VAPS ARE HVR/AIR & WILL ACCUM. VAPS WILL FORM EXPLO CONCS W/AIR. VAPS TRAVEL LONG DISTS & WILL FLASHBACK. USE MECH VENT WHEN NEC TO (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. EVACUATE AREA OF UNPROT PERS. WEAR APPROP PERSONAL PROT CLTHG & EQUIP. FOLLOW SAFE HNDLG & USE GUIDELINES. CONTAIN & SOAK UP RESI DUAL W/ABSORB (CLAY/SAND). TAKE UP ABSORB (SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & STRONG OXIDIZING AGENTS. KEEP CONTAINERS CLOSED. STORE IN COOL, DRY PLACE W/ADEQUATE VENTILATION. Other Precautions:IF POURING OR TRANSFERRING MATERIALS, GROUND ALL CONTAINERS & TOOLS. DO NOT WELD, HEAT, CUT OR DRILL ON FULL OR EMPTY CONTAINERS. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY W/VENT TO KEEP LEVELS BELOW EXPOS GUIDELINES. USER SHOULD TEST & MONITOR EXPOS LEVELS TO INSURE ALL PERSONNEL ARE BELOW GUIDELINES. IF NOT SURE OR IF NOT ABLE TO MONITOR USE NIOSH APPROVED AI R-PURIFYING RESPIRATOR. Ventilation:USE EXPLOSION-PROOF VENT WHEN REQUIRED TO KEEP BELOW HEALTH EXPOSURE GUIDELINES & LEL. Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . RECOMMEND IMPERVIOUS CLTHG TO AVOID SKIN CONT. IF MATL (ING 11) Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING, APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG (ING 12) Supplemental Safety and Health EXPLO HAZ:KEEP PERCENT VAP BELOW "LEL". HAZ DECOMP PROD:AS VERY HAZ. WELDING, CUTTING/ABRASIVE GRINDING CAN CREATE SMOKE & FUMES. DO NOT BREATHE. EXPLAN OF CARCIN:CARCIN. CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG 24-27, 1995:GRP 2B. SPILL PROC:MATL & SEAL TIGHTLY FOR PROPER DISP. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>175F,>79C Vapor Density:HVR/AIR Spec Gravity:1.39 VOC Pounds/Gallon:375 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:36 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, NITROGEN OXIDES & UNIDENTIFIED ORGANIC COMPOUNDS. CONSIDER ALL SMOKE & FUMES FROM BURNING MATL (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. ======================= Other Information =======================
1
eyes_protection_mandatory
======================================================= Product ID: HIT-HY 20 PART A Kit Part: Y Cage: EO264 Box: 21148 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 11239 Box: 21148 Cage: EO264 Box: 21148 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: NO Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: SIGNS AND SYMPTOMS OF EXPOSURE: EYES: CAN CAUSE IRRITATION. SKIN: PROLONGED AND REPEATED CONTACT CAN CAUSE IRRITATION. AN ALLERGIC SKIN REACTION (E.G., RASH, ITCHING, REDDENING) CAN OCCUR WITH SOME IN DIVIDUALS. INHALATION: POSSIBLE IRRITATION. INGESTION: NONE EXPECTED. (EFFECTS OF OVEREXPOSURE) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HEALTH HAZARDS: EFFECTS OF INGESTION HAVE NOT BEEN DETERMINED. NOT CONSIDERED TO BE A ROUTE OF EXPOSURE. Medical Cond Aggravated By Exposure: EYE, SKIN, AND RESPIRATORY EXPECTED. First Aid: EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL MD. SKIN: WASH W/SOAP & WATER. INHAL: MOVE VICTIM TO FRESH AIR. CALL MD IF SYMPTOMS PERSIST. INGEST: SEEK MEDICAL ATTENTION. DO NOT INDUCE V OMITING UNLESS DIRECTED TO BY MD. NEVERGIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. OTHER: REFERRAL TO MD IS RECOMMENDED IF THERE IS ANY QUESTION ABOUT SERIOUSNESS OF INJURY/EXPOSURE. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: TAKE UP BY MECHANICAL MEANS. AVOID DIRECT CONTACT. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS (FP N). Handling And Storage Precautions: STORE IN A COOL, DRY AREA PREFERABLY BETWEEN 40-80F. DO NOT STORE IN DIRECT SUNLIGHT. KEEP AWAY FROM OPEN FLAMES, HEAT SOURCES AND SPARKS. Other Precautions: AVOID PROLONGED OR REPEATED CONTACT. USE WITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. FOLLOW LABEL/USE INSTRUCTIONS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: >230F,>110C Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE KNOWN. THERMAL DECOMPOSITION PRODUCTS CAN BE PRODUCED UNDER FIRE CONDITIONS. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE GENERALLY REQUIRED. WHERE VENTILATION IS INADEQUATE TO CONTROL VAPORS, USE A NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGES. NEVER ENTER A CONFINED SPACE WITHOUT AN APPROPRIATE NIOSH APP ROVED AIR-SUPPLIED RESPIRATOR. Ventilation: GENERAL (I.E., NATURAL OR MECHANICALLY INDUCED FRESH AIR MOVEMENTS). Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work Hygienic Practices: ALWAYS WASH THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS. Supplemental Safety and Health: USERS OF THE "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFORMATION (FP N). ======================================================= Physical/Chemical Properties ======================================================= Spec Gravity: 0.9-1.2 Solubility in Water: INSOLUBLE Appearance and Odor: GRAY PASTE WITH ESTER-LIKE ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID TEMPERATURE EXTREMES (I.E., BELOW FREEZING AND ABOVE 100F). Materials To Avoid: STRONG ACIDS, PEROXIDES, AND AMINES. Hazardous Decomposition Products: THERMAL DECOMPOSITION CAN YIELD OXIDES OF CARBON AS WELL AS ACRID AND IRRITATING FUMES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= Other Information: VOLATILE ORGANIC COMPOUND: NOT DETERMINED ======================================================= HAZCOM Label ======================================================= Product ID: HIT-HY 20 PART A Cage: EO264 Assigned IND: Y Company Name: HILTI INC Street: 5400 S 122ND EAST AVE PO Box: 21148 Zipcode: 74121 Label Required IND: Y Date Of Label Review: 07/31/1998 Status Code: C Label Date: 07/31/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE: EYES: CAN CAUSE IRRITATION. SKIN: PROLONGED AND REPEATED CONTACT CAN CAUSE IRRITATION. AN ALLERGIC SKIN REACTION (E.G., RASH, ITCHING, REDDENING) CAN OCCUR WITH SOME INDIVIDUALS. INHALATION: PO SSIBLE IRRITATION. INGESTION: NONE EXPECTED. CHRONIC: POSSIBLE SENSITIZATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE, PURUM PELLETS, S318-50 Resp. Party Other MSDS Num.:21300 CAGE:1B464 CAGE:1B464 CAGE:94480 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 = Wt:100. Other REC Limits:10MG/M*3 IDLH NIOSH OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: CAUSES SEVERE EYE BURNS. SKIN: CAUSES SKIN BURNS. MAY CAUSE DEEP, PENETRATING ULCERS OF THE SKIN. INGESTION: HARMFUL IF SWALLOWED. CAUSES GASTROINTESTINAL TRACT BURNS. CAUSES SEVERE PAIN, NAUSEA,VOMITING, DIARRHEA AND SHOCK. INHALATION: IRRITATION MAY LEAD TO CHEMICAL PNEUMONITIS AND PULMONARY EDEMA. CAUSES SEVERE IRRITATION OF UPPER RESPIRATORY TRACT WITH COUGHING, BURNS, BREATHING DIFFICUL TY AND POSSIBLE COMA. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. TARGET ORGANS: NONE. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID IMMED. IMMED FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAS T 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. DISCARD CONTAM CLTHG IN A MANNER WHICH LIMITS FURTHER EXPOS. INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS UNCON & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. N EVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. GET MED AID IMMED. INHAL: REMOVE FROM EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED AID. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAIL Autoignition Temp:Autoignition Temp Text:N/AV Lower Limits:NOT AVAIL Upper Limits:NOT AVAIL Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER WITH CAUTION AND IN FLOODING AMOUNTS. Unusual Fire/Explosion Hazard:CONTACT WITH MOISTURE OR WATER MAY GENERATE SUFFICIENT HEAT TO IGNITE NEARBY COMBUSTIBLE MATERIALS. (ESTIMATED) HEALTH: 3; FLAMMABILITY: 0; REACTIVITY: 1. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM STRONG ACIDS. KEEP AWAY FROM WATER. KEEP AWAY FROM METALS. KEEP AWAY FROM FLAMMABLE LIQUIDS. KEEP AWAY FROM ORGANIC HALOGENS. CORROSIVES AREA. HYGROSCOPIC. Other Precautions:WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATE VENTILATION. DO NOT ALLOW WATER TO GET INTO THE CONTAINER BECAUSE OF VIOLENT REACTION. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT INGEST OR I NHALE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH APPROVED AIR PURIFYING DUST OR MIST RESPIRATOR OR EUROPEAN STANDARD EN 149. Ventilation:USE ADEQ GENERAL OR LOCAL EXHAUST VENT TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. FACESHIELD . Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA ). WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Supplemental Safety and Health MATLS TO AVOID: CINNAMALDEHYDE OR ZINC; & REACTS EXPLOSIVELY W/MIXTURE OF CHLOROFORM & METHANE. CORR TO METALS SUCH AS ALUMINUM, TIN & ZINC AS WELL AS TO ALLOYS SUCH AS STEEL & MAY CAUSE FORMATION OF FLAMMABLE HYDROGEN GAS. ================== Physical/Chemical Properties ================== Boiling Pt:=1390.C, 2534.F B.P. Text:@ 760 MM HG Melt/Freeze Pt:=318.C, 604.4F Decomp Temp:Decomp Text:NOT AVAIL Vapor Pres:100 MM HG Vapor Density:NOT AVAIL Spec Gravity:2.1300 G/CM3 pH:NOT AVAIL Viscosity:NOT AVAILABLE Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:1 G/0.9 ML WATER Appearance and Odor:WHITE SOLID; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES GENERATES LG AMTS OF HEAT WHEN IN CONTACT W/WATER & MAY STEAM & SPLATTER. REACTS W/MINERAL ACIDS TO FORM CORRESPONDING SALTS; REACTS W/WEAK ACIDS, GASES LIKE HYDROGEN SULFIDE, SULFUR DIOXIDE & CARBON DIOXIDE; IGNITED WHEN I Stability Condition to Avoid:INCOMPATIBLE MATERIALS, MOISTURE, CONTACT WITH WATER, ACIDS. Hazardous Decomposition Products:TOXIC FUMES OF SODIUM OXIDE, SODIUM PEROXIDE FUMES. =================== Toxicological Information=================== Toxicological Information:CARCINOGENICITY: SODIUM HYDROXIDE - NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. EPIDEMIOLOGY: NO INFO REPORTED. TERATOGENICITY: NO INFO REPORTED. REPRODUCTIVE EFTS: NO INFO REPORTED. NEUROTOXICITY: NO INFO REPORTED. MUTAGENICITY: MUTATION DATA REPORTED. OTHER STUDIES: NO INFO REPORTED. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: TLM, MOSQUITO FISH, 125 PPM/96HR (FRESH WATER); TLM, BLUEGILL, 88 MG/48HR (TAP WATER). ENVIRONMENTAL FATE: THIS CHEM IS NOT MOBILE IN SOLID FORM, ALTHOUGH IT ABSORBS MOISTURE VERY EASILY. ONCE LIQUID, SODIUM HYDROXIDE LEACHES RAPIDLY INTO THE SOIL, POSSIBLY CONTAMINATING WATER SOURCES. PHYSICAL/CHEMICAL: NO INFO FOUND. OTHER: NO INFO FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN MANNER CONSISTENT W/FEDERAL, STATE & LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LISTED. RC RA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: UN1823. PACKING GROUP: II. IMO - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: 1823. PACKING GROUP: 2. IATA - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZ CLASS: 8. UN NUMBER: 1823. PACKING GROUP: 2. RID/ADR - SHIPPING NAME: SODIUM HYDROXIDE, SOLID. DANGEROUS GOODS CODE: 8(41B). UN NUMBER: 1823. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ) CAS #1310-73-2: FINAL RQ = 1000 LBS (454 KG). SECTION 302 (TPQ) NONE OF CHEMS IN PROD HAVE TPQ. SARA CODES CAS #1310-73-2: ACUTE, REACTIVE. SECTION 313 NO CHEMS ARE REPORTABLE UNDER S ECTION 313. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2 OZONE DEPLETORS. CLEAR WATER ACT: C AS #1310-73-2 IS LISTED AS HAZ SUBSTANCE UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS TOX POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMS IN PROD CONSIDERED HIGHLY HAZ BY OSHA. Federal Regulatory Information:TSCA CAS #1310-73-2 IS LISTED ON THE TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. State Regulatory Information:SODIUM HYDROXIDE CAN BE FOUND ON THE FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHE MICALS IN THIS PRODUCT ARE LISTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2000S-B ISOCYANATE ACTIVATORS,HARDNERS & ADDITIVES Preparer's Name:T R LOUER CAGE:23027 CAGE:90227 CAGE:23027 ============= Composition/Information on Ingredients ============= Ingred Name:ALIPHATIC POLYISOCYANATE, HEXAMETHYLENE DIISOCYANATE POLYMER (HDI POLYMER) *96-3* CAS:28182-81-2 RTECS #:NQ9170000 Other REC Limits:1 MG/CUM Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH AROMATIC NAPHTHA, C8&10 AROMATIC HYDROCARBON *96-3* CAS:64742-95-6 RTECS #:WF3400000 Ingred Name:BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDINYL) SEBACATE CAS:52829-07-9 Ingred Name:BUTYL ACETATE (N-BUTYL ACETATE) *96-3* CAS:123-86-4 RTECS #:AF7350000 Other REC Limits:150 PPM OSHA PEL:710 MG/CUM ACGIH TLV:713 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (IARC CARC- GROUP 3) *96-3* CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 6.96% Other REC Limits:375 MG/CUM OSHA PEL:100 PPM ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TRIXYLENLY PHOSPHATE CAS:25155-23-1 RTECS #:ZE8320000 Ingred Name:2-(2'-HYDROXY-3',5'-DI-TERT-AMYLPHENYL)BENZOTRIAZOLE; BENZOTRIAZOLE UV ABSORBER*96-3* CAS:25973-55-1 Ingred Name:VOLATILE ORGANIC CONTENT: 1.4 LBS/GAL RTECS #:9999999VO ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE & THROAT IRRITATION. ISOCYANATES MAY CAUSE RESPIRATORY SENSITIZATION & MAY DECREASE IN LUNG FUNCTIONS WHICH MAY BE PERMANENT. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PER MANENT BRAIN & NERVOUS SYSTEM DAMAGE. SKIN: IRRITATION, DERMATITIS. EYES: IRRITATION, BURNING. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, BREATHING PROBLEMS, DISCOMFORT, GI DISTRESS ======================= First Aid Measures ======================= First Aid:INGESTION: CALL A PHYSICIAN IMMEDIATELY & HAVE NAMES OF INGREDIENTS AVAILABLE. INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. EYES: WASH W/WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN A LL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:<73F Lower Limits:0.8 Upper Limits:11.5 Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING W/SCBA. WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP. Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS FLAMMABLE VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/EXPLODE. FINE MISTS/SPRAYS MAY BE FLAMMABLE AT TEMP 120F. DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. DON'T BREATHE VAPOR S/MISTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR WHILE MIXING ACTIVATOR W/PAINT/CLEAR ENAMEL, DURING APPLICATION & UNTIL VAPORS & SPRAY MISTS ARE EXHAUSTED. DON'T PERMIT ANYONE W/O PROTECTION IN THE P AINTING AREA. Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS. Other Protective Equipment:COVERALLS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING/SMOKING. Supplemental Safety and Health %VOLATILE BY VOLUME: 6.4-80.9%. SPILLS CONT'D: POUR LIQUID DECONTAMINATE SOLUTION OVER SPILL & ALLOW TO SIT 10 MINS, MINIMUM. DECONTAMINATION SOLUTION: 20% SURFACTANT, 80% WATER, 0-10% AMMONIA, 2-5% D ETERGENT, BALANCE WATER. PRESSURE CAN BE GENERATED. DON'T SEAL CONTAINER. AFTER 48 HRS, IT MAY BE SEALED & DISPOSED OF. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:169-882F Vapor Density:>1 Evaporation Rate & Reference:(ETHER =1): <1 Solubility in Water:MISCIBLE Percent Volatiles by Volume:(SUPP) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, AMINES, METAL SALTS Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, TEMP >120F. Hazardous Decomposition Products:CO, CO2, SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE ABSORBED MATERIAL IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE IN CLOSED CONTAINERS. FLAMMABLE LIQUID, UN1263.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FC-203CF LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM CAGE:28112 CAGE:28112 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 69-71% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER; (2-(2_BUTOXYETHOXY)-ETHANOL) CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 19-21% Other REC Limits:NONE RECOMMENDED Ingred Name:ALKYL SULFATE SALTS (2), NEW JERSEY TRADE SECRET REG NO:04499600-58059, -5806P. Fraction by Wt: 4-6% Other REC Limits:NONE RECOMMENDED Ingred Name:AMPHOTERIC FLUOROALKYLAMIDE DERIVATIVE, NEW JERSEY TRADE SECRET REG NO: 04499600-5804P. Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE) CAS:102-71-6 RTECS #:KL9275000 Fraction by Wt: 0.5-1.5% Other REC Limits:NONE RECOMMENDED ACGIH TLV:5 MG/M3 Ingred Name:PERFLUOROALKYL SULFONATE SALTS (5), NEW JERSEY TRADE SECRET REG NO: 04499600-5804P. Fraction by Wt: 0.5-1.5% Other REC Limits:NONE RECOMMENDED Ingred Name:1H-BENZOTRIAZOLE,METHYL- CAS:29385-43-1 RTECS #:DM1300000 Fraction by Wt: 0-0.1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE/SKIN:MODERATE IRRIT(AFT PROL/REP SKIN CONTACT).PROL/REP EXPO MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS.INHAL:SINGLE OVEREXPO ABOVE RECOMMENDED GUIDELINES MAY CAUSE CNS DEPRESS,IRRIT.PROL/REP OVERE XPO ABOVE RECOMMENDED GUIDELINES MAY CAUSE BLOOD DISORDERS,BONE MARROW DEPRESS,KIDNEY/LIVER EFFECTS,PULM EDEMA. Effects of Overexposure:EYE:RED,SWELL,PAIN,TEAR,HAZY VISION.SKIN:RED,SWELL,ITCH,DRY.INHAL:CNS DEPRESS:HEAD,DIZZ,DROWS,INCOORD,SLOW RX TIME,SLURR SPEECH,GIDDINESS,UNCONSC;IRRIT UPPER RESP:NOSE/THROAT SORENESS,COUGH,SNEEZE;BLO OD/BONE MARROW DEPRESS:PROL WEAK,FTG;KIDNEY:RED URINE VOL,BLOOD IN URINE,BACK PAIN;LIVER:JAUNDICE,TENDER UPPER ABD;(SUP) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:IMMED FLUSH W/LG AMTS OF WATER FOR @LEAST 15MINS.GET MED ATTN IMMED. SKIN:FLUSH W/LG AMTS OF WATER.IRRIT PERSISTS GET MED ATTN. INHAL:SIGNS/SYPMTOMS OCCUR REMOVE PERSON TO FRESH AIR.SIGNS/PSYMPTOM S CONT CALL PHYSICIAN. INGEST:DRINK TWOGLASSES OF WATER.CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NA Lower Limits:NA Upper Limits:NA Extinguishing Media:PRODUCT IS A FIRE-EXTINGUISHING AGENT. Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION OF USAGE CONCENTRATIONS DOES NOT PRESENT A HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:OBSERVE PRECAUT FRM OTHER SECS.VENTILATE AREA.CONTAIN SPILL.COVER W/ABSORBENT MATL.COLLECT MATL.CLEAN UP RESIDUE W/WATER.PLACE IN APPROVED METAL CNTNR.SEAL CNTNR. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT.KEEP CNTNR CLSD WHEN NOT IN USE. Other Precautions:AVOID EYE CONTACT W/VAP/SPRAY/MIST.AVOID SKIN CONTACT.DO NOT EAT/DRINK/SMOKE WHEN USING PRODUCT.WASH EXPO AREAS THOROUGHLY W/SOAP/WATER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AVOID BREATH OF VAP/MIST/SPRAY.SELECT ONE OF FOLLOWING NIOSH APPROVED RES BASED ON AIRBORNE CONCEN OF CONTAMINANTS & IAW OSHA REGS:HALF-MASK ORGANIC VAP RESP W/DUST/MIST PREFILTER. Ventilation:USE W/ADEQUATE DILUTION VENTILATION. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:INGESTION IS NOT LIKELY ROUTE OF EXPO TO THIS PRODUCT. WASH HANDS AFT HNDLG/BEF EATING. Supplemental Safety and Health HEALTH:PULM EDE:COUGH,CONGEST,DIFF BREATH,RESP FAILURE,DEATH. DISPO:TOX CHEM SUBJ TO REPORTING REQMTS SEC 313 TITLE III EPCRA/40CFR372:2-(2-BUTOXYEHTYOXY)-ETHANOL.3M PROD ENVIRO DATA SHEET AVAILABLE.C ONSULT APPLICABLE REG/AUTHORITIES BEF DISPO.IF UNCONTROLLED RELEASE USER DETERMINE IF QUALIFY AS RQ.EPA HAZWASTE#:NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NP Vapor Pres:17 @20C Vapor Density:0.77 Spec Gravity:1.0 VOC Pounds/Gallon:500 pH:8.5 Viscosity:ND Evaporation Rate & Reference:<1.0 (N-BUTYL ACETATE=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, AMBER COLORED LIQUID. Percent Volatiles by Volume:90 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR, HYDROGEN FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE SPENT SOLNS TO WASTEWATER TREAT EYE.REDUCE DISCHARGE RATE IF FOAMING OCCURS.LG QUANT MAY ADVERSELY AFFECT BIO WASTE WATER TREAT SYS.INCINERATE IN INDUSTRIAL/COMMERCIAL FACIL IN PRESENCE OF C OMBUSTIBLE MATL.COMBUST PROD WILL INCLUDE HF.(SUP) ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALUMINUM ALLOY, 1060 CAGE:IO633 CAGE:IO633 CAGE:45845 ============= Composition/Information on Ingredients ============= Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: 95.85% OSHA PEL:N/K ACGIH TLV:10.0 MG/M3 DUST Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 1.1% OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:IRON OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: 0.7% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:N/K Ingred Name:COPPER (SARA III) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: .4% OSHA PEL:N/K ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: .15% OSHA PEL:N/K ACGIH TLV:5 MG/M3 DUST Ingred Name:MAGNESIUM; (MAGNESIUM OXIDE) CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: 1.2% OSHA PEL:N/K ACGIH TLV:10 MG/M3 FUME Ingred Name:CHROMIUM (SARA III) CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: .35% OSHA PEL:N/K ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC (SARA III) CAS:7440-66-6 RTECS #:ZG8600000 Fraction by Wt: .25% OSHA PEL:N/K ACGIH TLV:10 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: .15% OSHA PEL:N/K ACGIH TLV:10 MG/M3 TDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:MAY PRODUCE EYE AND RESPIRATORY IRRITATION. IF EXPOSURE OF ALUMINUM AND ALUMINUM OXIDE IS KEPT BELOW THE TLV THE ALLOYING ELEMENTS SHOULD NOT PRESENT A HEALTH HAZARD. NOTE:OZONE CAN BE GENERATED DURIN G WELDING. (TLV LIMIT 0.1 PPM) Explanation of Carcinogenicity:CHROMIUM:IARC MONOGRAPHS, SUPPLEMENT, VOL.49 PG 49, 1990:GRP I. NTP 6TH ANNUAL REPORT ON CARCIN; KNOWN TO BE CARCIN. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:WASH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ADVICE, IF IRRITATION PERSISTS. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTIFICIAL RESPIRATION) . INGEST:CALL MD IMMEDIATELY ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRES . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . AVOID WATER NEAR MELTING FURNACES. Unusual Fire/Explosion Hazard:WHEN REMELTING ALUMINUM, ENTRAPPED MOISTURE OR THE PRESENCE OF STRONG OXIDIZERS COULD CAUSE AN EXPLOSION. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:HALOGEN ACIDS AND SODIUM HYDROXIDE IN CONTACT WITH ALUMINUM MAY GENERATE EXPLOSIVE MIXTURES OF HYDROGEN. Other Precautions:FINELY DIVIDED ALUMINUM IN PRESENCE OF BROMATES, CHLORATES, IODATES OR AMMONIUM NITRATE WILL FROM EXPLO MIXTURES IN AIR. WHEN REMELTING SCRAP, ENTRAPPED MOIST OR PRESENCE OF STRONG OXIDIZERS SUCH AS A MMONIUM NITRATE COULD CAUSE (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED DISPOSABLE DUSTMASKS IN DUSTY JOBS. Ventilation:LOCAL EXHAUST MAY BE NEEDED WHILE WELDING. Other Protective Equipment:IN NOISY MACHINING OPERATIONS, EAR PROTECTION MAY BE REQUIRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health OTHER PREC:AN EXPLO. THIS APPLIES TO COLLECTIONS OF MOIST IN SOW CAVITIES AS WELL. MOISTURE MUST BE DRIVEN OFF PRIOR TO REMELTING. DO NOT TOUCH CAST ALUMINUM METAL OR HEATED ALUMINUM PRODUCT WITHOUT K NOWING METAL TEMP. ALUMINUM EXPERIENCESNO COLOR CHANGE DURING HEATING. IF METAL IS HOT AND TOUCHED, BURNS CAN RESULT. ================== Physical/Chemical Properties ================== HCC:T6 Solubility in Water:NONE Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:USE ONLY DRY MATERIAL FOR REMELTING OPERATIONS. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PROPIONIC ACID Preparer's Name:GASTON L. PILLORI CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:PROPIONIC ACID (SARA III) CAS:79-09-4 RTECS #:UE5950000 Fraction by Wt: 100% OSHA PEL:10 PPM ACGIH TLV:10 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 3500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALE- MUCOUS MEMBRANE IRRITATION WITH SORE THROAT AND DYSPNEA. SKIN- REDNESS, PAIN AND BLISTERING. EYE- REDNESS, PAIN AND BLURRED VISION. INGEST- SORE THROAT, ABDOMINAL PAIN, VOMITING AND GAS TROINTESTINAL BLEEDING. CHRONIC: CONJUNCTIVITIS OF EYE, DERMATITIS, ULCERATIVE CHANGES OF MOUTH, BROMCHIAL AND GASTROIN. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:IRRITATIONS, SORE THROAT, REDNESS, PAIN, BLISTERING, BLURRED VISION. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE SUBJECT TO FRESH AIR. EYE: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE VOMITING. GET IMMEDIA TE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:126F,52C Autoignition Temp:Autoignition Temp Text:870F Lower Limits:2.9 Upper Limits:12.1 Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. DO NOT GET WQTER INSIDE CONTAINER. COOL FIRE-EXPOSED CONTAINERS WITH WATER FROM SIDE UNTIL WELL AFTER FORE IS OUT. Unusual Fire/Explosion Hazard:USE FLOODING AMOUNTS OF WATER AS FOG. AVOID BREATHING CORROSIVE VAPORS, KEEP UPWIND. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE OR SOAK UP SMALL SPILLS WITH SAND OR INERT ABSORBANT. DO NOT TOUCH SPILLED MATERIAL. DIKE TO RETAIN LARGE SPILLS. NO SMOKING, FLAMES IN HAZARD AREA. ISOLATE AREA AND DENY ENTRY. USE WATER SPRAY T O REDUCE VAPORS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAMAGE. OUTSIDE OR DETACHED STORAGE IS PREFERRED. INSIDE STORAGE SHOULD BE IN A STANDARD FLAMMABLE LIQUIDS ROOM/CABINET. Other Precautions:MAY BE IGNITED BY HEAT, SPARKS OR FLAMES. CONTAINER MAY EXPLODE IN HEAT OF FIRE. VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN SEWERS. RUN-OFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) VENTILATION IS REQUIRED. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA IS NOT VENTED. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED CONTACT. Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health CONTACT LENSES SHOULD BOT BE WORN. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:286F,141C Melt/Freeze Pt:M.P/F.P Text:-6F,-21C Vapor Pres:10 Vapor Density:2.5 Spec Gravity:.9930 pH:<7.0 Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS, OILY LIQUID WITH A PUNGENT, DISAGREEABLE, RANCID ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS: FIRE AND EXPLOSION HAZARD. LEAD AND MOST OTHER METALS: CORROSIVE ACTION. BASES: VIGOROUS OR VIOLENT REACTION. Stability Condition to Avoid:ABNORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:ACRID SMOKE AND IRRITATING FUMES FROM THERMAL DECOMPOSITION. Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KODALITH FIXER & REPLENISHER, 186 5161, PART B Kit Part:Y CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% Other REC Limits:NONE RECOMMENDED Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 14% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALUMINUM SULFATE CAS:10043-01-3 RTECS #:BD1700000 Fraction by Wt: 10-15% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (MALE RAT) IS 3200 MK/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE LOW HAZARD FOR RECOMMENDED HANDLING. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:IRAC HAS DETERMINED THAT OCCUPATIONAL EXPOSURE TO MIST/ VAPORS CONTAINING SULFURIC ACID IS CARCINOGENIC TO HUMANS. Effects of Overexposure:BURNS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN-IMMEDI ATELY FLUSH WITH PLENTY OF WATER FOR 15MIN. REMOVE SOILED CLOTHING/SHOES. GET MEDICAL ATTENTION. INGESTION-DO NOT INDUCE VOMITING. GIVE VICTIM A GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:MAY REQUIRE NEUTRALIZATION IF PH<2 OR >12.5. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:DO NOT BREATHE MIST OR VAPOR. DO NOT GET IN EYES, ON SKIN ON CLOTHING. USE WITH ADEUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:PROTECTIVE CLOTHING APPROPIATE FOR THE RISK OF EXPOSURE. EYE BATH, SAFETY SHOWER, WASHING FACILITIES. Work Hygienic Practices:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ECOLOGICAL INFORMATION: THIS MATERIAL IS STRONGLY ACIDIC AQUEOUS SOLUTION, AND THIS PROPERTY MAY CAUSE ADVERSE ENVIRONMENTAL EFFECTS. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18 MMHG Vapor Density:0.6 Spec Gravity:1.25 pH:<1.0 Solubility in Water:COMPLETE Appearance and Odor:LIQUID, COLORLESS, ODORLESS. Percent Volatiles by Volume:70-75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SULFUR DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:G7057, NICAD BATTERY, SEALED PAGER BATTERY, (SUPDAT) CAGE:56469 CAGE:56469 ============= Composition/Information on Ingredients ============= Ingred Name:NICKEL (SARA 313) (CERCLA) (MIXTURE WITH INGREDIENT 2) CAS:7440-02-0 RTECS #:QR5950000 Fraction by Wt: 20-30% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:NICKEL (II) HYDROXIDE CAS:12054-48-7 RTECS #:QR7040000 Fraction by Wt: 20-30% OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CADMIUM (SARA 313) (CERCLA) (MIXTURE WITH INGREDIENT 4) CAS:7440-43-9 RTECS #:EU9800000 Fraction by Wt: 13-15% OSHA PEL:0.2 MG/M3 DUST ACGIH TLV:0.01 MG/M3 DUST EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CADMIUM HYDROXIDE CAS:21041-95-2 RTECS #:EV1260000 Fraction by Wt: 13-15% OSHA PEL:0.05 MG CD/M3 ACGIH TLV:0.05 MG CD/M3 Ingred Name:POTASSIUM HYDROXIDE (AS DRY HYDROXIDE) (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 2-4% OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPDAT:TO BE CARCINOGENIC. HUMAN:LUNG, PROSTATE, RENAL SYSTEM EFFECTS. CADMIUM HYDROXIDE:IARC MONOGRAPHS ON EVAL (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:OF CARCINOGEN RISK OF CHEMICALS TO MAN, VOL 48, PG 119, 1994:GROUP 1. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:NOTE:UNDER NORMAL USE, THE BATTERY DOES NOT RELEASE TOXIC MATERIALS. INHALATION:DURING A FIRE INVOLVING LARGE QUANTITIES OF BATTERIES, CADMIUM FUMES MAY BE RELEASED. EYES:IF BATTERY RUPTURES, EYES MAY COME IN CONT W/TRACE AMT OF POTASSIUM HYDROXIDE, WILL CAUSE BURN. SKIN:IF BATTERY RUPTURES, SKIN MAY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NICKEL:IARC MONOGRAPHS, VOL 49, PG 257, 1990:GROUP 2B. NTP 7TH ANN REPORT ON CARCINS, ANTICIPATED CARCINOGEN.(SUPP DATA) Effects of Overexposure:HLTH HAZS:COME IN CONTACT WITH TRACE AMOUNT OF POTASSIUM HYDROXIDE, WILL CAUSE BURN. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WAREHOUSE OR DEPOT TYPE STORAGE. Unusual Fire/Explosion Hazard:CADMIUM FUMES MAY BE RELEASED DURING BURNING OF LARGE QUANTITIES OF BATTERIES IN A DEPOT/WAREHOUSE. ================== Accidental Release Measures ================== Spill Release Procedures:ELECTROLYTE, POTASSIUM HYDROXIDE IS CAUSTIC. DO NOT ALLOW SKIN OR EYE CONTACT. FLUSH WITH WATER. THERE IS ONLY A TRACE AMOUNT OF POTASSIUM HYDROXIDE AVAILABLE IN THE BATTERY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT INCINERATE OR MUTILATE; MAY BURST RELEASING TOXIC MATERIAL (CADMIUM FUMES). Other Precautions:DO NOT SHORT CIRCUIT THE BATTERY, IT MAY CAUSE BURNS WHEN IN CONTACT WITH SKIN OR EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Supplemental Safety and Health MFR TRADE/PART #:RECHARGEABLE. EXPLAN OF CARCIN: HUMAN:LUNGS, NASAL CAVITIES. NICKEL HYDROXIDE:NTP 7TH ANNUAL RPT ON CARCINS. 1994:ANTIC TO BE CARCIN. CADMIUM: OSHA REGULATED, 29 CFR 1910.1027; IARC M ONOGRAPHS, SUPP, VOL 7, PG 139, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS. 1994:ANTIC TO (ING 6) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO INFO AVAILABLE. Stability Condition to Avoid:BURNING (FIRE), RUPTURING. Hazardous Decomposition Products:CADMIUM FUMES MAY BE RELEASED DURING A FIRE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: ECO 3NH Cage: 0AVJ9 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 0AVJ9 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:EYE:SEV IRRIT. CONT W/LIQ MAY CAUSE BURNING, REDNESS, SWELL, BURNS & DMG. SKIN:IRRIT. PRLNG/RPTD CONT MAY CAUSE BURNING, REDNESS, DERM, BLISTERING & DMG. INHAL:EXPOS TO MISTS/EXCESS CONCS OF VAP S GENERATED WHEN MATL IS HEATED MAY CAUSE IRRIT OF NOSE, THROAT & RESP TRACT & SIGNS OF CNS DEPRESS; (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:I.E., HDCH, NAUS, DROW & DIZZ. INGEST:ACCIDENTALLY SWALLOWING MAY CAUSE IRRIT & BURNING OF MOUTH, THROAT, ESOPHAGUS & GI TRACT. CHRONIC:REPETITIVE LONG-TERM SKIN APPLICATION OF MATLS/PETRO HY DROCARBON SOLV HAS BEEN SHOWN TO CAUSE SKIN CANCER IN LAB ANIMALS. THERE IS NO EVID THAT THIS CAUSES CANCER IN HUMANS. Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN, LIVER, KIDNEY & RESPIRATORY DISORDERS. First Aid: EYES:IMMED FLUSH W/CLEAN WATER FOR AT LST 30 MINS, WASHING UNDER LIDS. SEEK IMMED MED ASSISTANCE. SKIN:IMMED REMOVE CONTAM CLTHG. FLUSH CONT AREAS W/WATER & THEN THORO CLEANSE BY WASHING W/SOAP & WATE R. IF IRRIT/REDNESS DEVEL & PERSIST, SEEK MED ASSISTANCE. INHAL:MOVE AWAY FROM SOURCE OF EXPOS TO VAPS/MISTS. IF SYMPS OF EXPOS PERSIST, SEEK MED ASSISTANCE. ATTN:IF VICTIM IS NOT BRTHG/IF ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: EVACUATE AREA FOR LG SPILLS. REMOVE ALL IGNIT SOURCES & PROVIDE EXPLO-PROOF VENT. WEAR REC PROT CLTHG & EQUIP. DO NOT ALLOW SPILLS TO ENTER SEWERS, STREAMS/SURF WATERS. DIKE & CNTN SPILLS. USE INERT A BSORB TO REDUCE FUMES & TO PICK UP SPILL. (SUPDAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS. EMPTY CONTAINERS SHOULD BE COMMERCIALLY CLEANED & RECONDITIONED BEFORE REUSE. Handling And Storage Precautions: COMBUST LIQ. STORE IN CLSD CNTNRS IN COOL, DRY, WELL-VENTED AREA AWAY FROM SOURCES OF HEAT & IGNIT & STRONG OXIDIZING AGENTS. AVOID HEATING >120F. Other Precautions: CNTNRS SHOULD BE ELEC BONDED & GROUNDED WHEN TRANSFERRING MATL. USE IN WELL-VENTED AREA & REC PROT EQUIP & CLTHG. USE EXPLO-PROOF TOOLS & EQUIP. AVOID BRTHG VAPS/MISTS & PRLNG/RPTD SKIN CONT. LBL ALL UNATTENDED CNTNRS. MISUSE OF ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: PMCC Flash Point Text: >140F,>60C Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM & WATER SPRAY. Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). USE WATER SPRAY TO COOL FIRE-EXPOS CNTNRS, TO DILUTE & DISPERSE VAPS, PROT PERS & TO FLUSH UNIGNITED (SUPP DATA) Unusual Fire/Explosion Hazard: MOD FIRE & EXPLO HAZ & MAY BE IGNITED BY IGNIT SOURCE ABOVE ITS FLASH POINT. VAPS MAY TRAVEL TO IGNIT SOURCE & FLASH BACK. CNTNRS MAY EXPLODE IN FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: IN SITUATIONS WHERE VAPOR CONCENTRATIONS EXCEED THE RECOMMENDED EXPOSURE LIMITS, A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR SHOULD BE WORN. Ventilation: EXPLOSION-PROOF GENERAL MECHANICAL VENT OR LOCAL EXHAUST IS REC TO MAINTAIN VAPOR CONCS BELOW REC EXPOSURE LIMITS. Other Protective Equipment: ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER(FP N). LONG-SLEEVE CLTHG & CHEM APRON REC TO PVNT SKIN CONT (BUTYL(SUPDAT) Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). FIRE FIGHT PROC:SPILLS FROM FIRE. SPILL LGTH F SHLD (FP N). OTHER PROT EQUIP:RUBBER/POLYETHYLENE ARE REC!) WEAR PROT BOOTS IN SITUATIONS WHERE SPLASHING MAY OCCUR. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >400F,>204C Vapor Pres: 0.3 @ 20C Vapor Density: HVR/AIR Spec Gravity: 0.99-1.01 Evaporation Rate & Reference: SLOWER THAN ETHER Solubility in Water: NEGLIGIBLE Appearance and Odor: A DEEP RED-COLORED LIQUID W/SLIGHTLY PUNGENT ODOR. Percent Volatiles by Volume: 40 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE UNDER NORMAL CONDITIONS OF STORAGE & HANDLING. Materials To Avoid: REACTS W/STRONG OXIDIZING AGENTS & ALKALINE MATERIALS. Hazardous Decomposition Products: CARBON DIOXIDE & CARBON MONOXIDE, OXIDES OF SULFUR & NITROGEN. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: ECO 3NH Cage: 0AVJ9 Company Name: EMULSIONS CONTROL INC Street: 829 HOOVER AVE Zipcode: 91950 Label Required IND: Y Date Of Label Review: 10/15/1997 Status Code: C Label Date: 10/15/1997 Origination Code: G Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE:EYE:SEVERE IRRITATION. CONTACT WITH LIQUID MAY CAUSE BURNING, REDNESS, SWELLING, BURNS AND DAMAGE. SKIN:IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE BURNING, REDNESS, DERMATI TIS, BLISTERING AND DAMAGE. INHALATION:EXPOSURE TO MISTS OR EXCESSIVE CONCENTRATIONS OF VAPORS GENERATED WHEN MATERIAL IS HEATED MAY CAUSE IRRITATION OF NOSE, THROAT AND RESPIRATORY TRACT AND SIGNS OF CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION:IRRITATION AND BURNING OF MOUTH, THROAT, ESOPHAGUS AND GASTROINTESTINAL TRACT. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TROYMAX CALCIUM 6% CAGE:HO199 CAGE:HO199 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS. BP:315-380F, 157.22-193.33C. VP:2.6 MMHG. VAP DENS:4.9,AIR=1. EVAP RATE:>1, ETHYL ETHER=1. (INGRED 2) CAS:64742-88-7 Fraction by Wt: 29% Other REC Limits:100 PPM (MFR) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:INGRED 1: SOL IN H*2O:0.04G/100G. AUTO IGNIT TEMP:450-500F,232-260C. LEL:1% BY VOL. UEL:6% BY VOL. RTECS #:9999999ZZ Fraction by Wt: 29% Ingred Name:SPILL PROC:WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED. RTECS #:9999999ZZ Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXCESSIVE INHALATION MAY LEAD TO ASPHYXIATION.PROLONGED OR REPEATED CONTACT MAY CAUSE DERMATITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES:IRRITATION,REDNESS,TEARING,BLURRED VISION.SKIN:PROLONGED OR REPEATED CONTACT MAY CAUSE MODERATE IRRITATION,DEFATTING.INGESTION:MAY CAUSE GI IRRITATION,NAUSEA,VOMITING,AND DIARRHEA.INHALATION:EXCE SSIVE EXPOSURE CAN CAUSE NASAL & RESP IRRIT,DIZZINESS,WEAKNESS,FATIGUE,NAUSEA,HEADACHE,POSS UNCONSCIOUSNESS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS,CHRONIC RESPIRATORY DISEASE. ======================= First Aid Measures ======================= First Aid:EYES:IMMED WASH W/ LARGE AMTS OF WATER FOR AT LEAST 15 MIN,LIFTING UPPER & LOWER LIDS.GET MEDICAL ATTN IF DISCOMFORT PERSISTS.SKIN:PROMPTLY WASH CONTAM SKIN W/ SOAP OR MILD DETERGENT & WATER.REMOVE SO AKED CLTHG.INGESTION:GET MEDICAL ATTN IMMED.INHALATION:MOVE TO FRESH AIR AT ONCE.IF BREATING DFCLT,ADMINISTER O*2.IF BRTHG STOPPED,PERFORM ARTF RESP;KEEP WARM & AT REST.GET MED ATTN AS SOON AS POSS. ===================== Fire Fighting Measures ===================== Flash Point:SEE SUPP DATA Lower Limits:N/K Upper Limits:N/K Extinguishing Media:USE FOAM,CARBON DIOXIDE,DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . Unusual Fire/Explosion Hazard:MINERAL SPIRITS VAPS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG THE GROUND/BE MOVED BY VENT & IGNITED BY HEAT,PILOT LIGHTS,FLAMES,IGNIT SOURCES AT (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:RESTRICT PERS W/O PROT CLTHG & EQUIP FROM AREA.VENTILATE AREA.REMOVE ALL IGNIT SOURCES (PILOT LIGHTS,OPEN FLAMES,ETC.).STOP SPILL AT SOURCE,DIKE AREA TO PVNT SPREADING.PUMP LIQ TO SALV TANK.TAKE UP RE MAINING LIQ ON SAND,CLAY,EARTH FLOOR (SEE SUPP) Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PROD/RESIDUE CAN IGNITE EXPLOSIVELY. Other Precautions:SOLVENT MAY ATTACK SOME FORMS OF PLASTICS,RUBBER AND COATINGS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VAPOR CONCENTRATION EXCEEDS TLV,USE NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR. Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR CONCENTRATION BELOW TLV . Other Protective Equipment:IMPERVIOUS CLOTHING,AND OTHER APPROPRIATE PROT CLOTHING NECESSARY TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. Work Hygienic Practices:WASH CONTAM SKIN IMMED W/ H*2O & MILD DETERGENT.PUT CONTAM CLTHG IN CLSD CNTNR UNTIL DISCARDED/DECONTAMINATED.(SEE SUPP) Supplemental Safety and Health SPEC GRAV:0.93-0.98,H*2O=1.FL PT:104-140F,40-60C FOR MINERAL SPIRITS.EXPLO HAZ:LOCATION DISTANT FROM MATL HNDLG POINT.HAZ DECOMP PROD:CO,CO*2.HYGIENE PRACT:LAUNDER BEFORE REUSE.SPILL PROC:ABSORB/OTHER ABSORB MATL & SHOVEL INTO METAL CNTNR.PVNT RUN-OFF TO SEWERS (POTENTIALLY EXPLO),STREAMS/OTHER BODIES OF (SEE ING 3) ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:N/K Spec Gravity:SEE SUPP Evaporation Rate & Reference:N/K Solubility in Water:N/K Appearance and Odor:N/K ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT WITH STRONG OXIDIZING OR REDUCING AGENTS.SOLVENT MAY ATTACK SOME FORMS OF PLASTICS,RUBBER AND COATINGS. Stability Condition to Avoid:HEAT Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .DESTROY BY INCINERATION.CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH APPLICABLE REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VARSTAT 55, 645-925 CAGE:IO449 CAGE:IO449 CAGE:5S938 ============= Composition/Information on Ingredients ============= Ingred Name:IMIDAZOLIUM COMPOUNDS;(1H-IMIDAZOLIUM, 1-ETHYL-4,5-DI-HYDRO-3-(2-HYDROXYETHYL)-2-(8-HEPTADECENYL-, ETHYL SULFATE) CAS:68039-12-3 Fraction by Wt: 100% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN:PROLONGED OR REPEATED CONTACT CAN CAUSE SEVERE IRRITAITON. EYE:CAN CAUSE IRRITATION WHICH MAY BE SEVERE. INGEST:CAN CAUSE GI IRRITATION, NAUSEA, VOMITING, DIARRHEA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:THOROUGHLY WASH EXPOSED AREA WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYE:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES LIFTING UPPER & L OWER LIDS OCCASIONALLY. CALL MD. INGEST:IMMEDIATELY DRINK 2 LARGE GLASSES OF WATER. CALL MD. INHAL:MOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>200F,>93C Extinguishing Media:DRY CHEMICAL, WATER FOG, REGULAR FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT, ESPECIALLY IF SPRAYED INTO CNTNRS OF HOT, BURNING LIQ. Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:PERS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN UP HAS BEEN COMPLETED. DIKE AREA OF SPILL TO PVNT SPREADING & PUMP LIQ TO SALVAGE TANK. ABSORB REMAINING LIQ ON VERMICULIT E, FLOOR ABSORB OR OTHER ABSORB MATL & (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health SPILL PROC:SHOVEL INTO CONTAINERS. THIS PRODUCT IS TOXIC TO FISH: PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>425F,>218C Vapor Density:HVR/AIR Spec Gravity:0.88 @ 120F pH:5% Solubility in Water:DISPERSABLE Appearance and Odor:LIQUID @ 25C Percent Volatiles by Volume:<1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:COMBUSTION PRODUCTS MAY INCLUDE SULFUR AND NITROGEN COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCIN IS REC DISP METHOD FOR ALL CHEMICAL WASTES, ALTHOUGH MATERIAL MAY BE LANDFILLED I/A/W ALL APPLIC REGULATIONS. THIS PRODUCT, IF DISPOSED OF, IS NOT CONSIDERED A HAZ WASTE UNDER CURRENT RCRA REGS. DISP MUST BE I/A/W LOC, STATE & LOC REGS .
1
eyes_protection_mandatory
======================================================= Product ID: PRO-POXY 100 LV, COMPONENT A Kit Part: Y Cage: UNITX Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: UNITX ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES/SKIN/INHALATION/INGESTION:WILL PRODUCE IRRITATION, SENSITIZATION. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: REMOVE ANY CONTAM CLTHG. EYES:FLUSH IMMED W/LG AMTS OF WATER FOR @ LST 15 MIN; CONT MD IMMED. SKIN:REMOVE EPOXY IMMED W/DRY CLOTH/PAPER TOWEL. WASH AREA OF CONT THORO W/SOAP & WATER. SOLVS SHOULD NOTBE USED BECAUSE THEY CARRY IRRIT INTO SKIN. INHAL:IF RESP IRRIT OCURS, GO TO FRESH AIR. FLOOD WORK AREA W/FRESH AIR. IF IRRIT CONTINUES, SEEK MED ATTN. INGEST:NOT EXPECTED. CONT MED HELP (SUPP DATA) ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: BIND WITH ABSORBENT MATERIAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: SM SPILL:PER LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: STORE IN A COOL, DRY LOCATION. DO NOT ALLOW THE MATERIAL TO FREEZE, AS PRODUCT MAY BE DAMAGED. STORE AWAY FROM SPARKS AND OPEN FLAME. Other Precautions: NONE. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 200F,93C Extinguishing Media: FOAM, CO*2, WATER FOG. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE, AVOID BREATHING SMOKE. ======================================================= Control Measures ======================================================= Respiratory Protection: RESP PROT IS REQ FOR NORMAL USE OF PROD. NIOSH/MSHA APPRVD RESPS SHOULD BE PROVIDED & WORN. ALL WORKERS REQ TO USE RESP PROT SHOULD BE TRAINED IN THEIR PROPER SELECTION, USE & CARE. WRITTEN RESP PROGR AM IS OUTLINED IN (SUPP DATA) Ventilation: LOCAL EXHAUST AND MECHANICAL-GENERAL ARE RECOMMENDED. SPECIAL VENT IS RECOMMENDED WHEN LOCAL AND MECH VENT IS NOT ADEQ. Other Protective Equipment: EMERGENCY EYE WASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). RECOM; SPLASH BIB WITH PROT CLTHG. Work Hygienic Practices: REMOVE & WASH CONTAM CLTHG. AS WITH ALL COMMERCIAL AND INDUSTRIAL PRODUCTS, ALWAYS WASH HANDS BEFORE EATING/SMOKING. Supplemental Safety and Health: FIRST AID PROC:IMMEDIATELY. UNTRAINED FIRST AID PERSONNEL SHOULD NOT ATTEMPT TO ADMINISTER FIRST AID. CONTAMINATED CLOTHING SHOULD BE WASHED PRIOR TO RE-USE. RESP PROT:29 CFR 1910.134, AND IS REQUIRED BY OSHA. ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: >1 Spec Gravity: 1.135 Solubility in Water: INSOLUBLE Appearance and Odor: YELLOW LIQUID, MILD ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE. Materials To Avoid: STRONG OXIDIZERS, STRONG BASES. Hazardous Decomposition Products: CO, CO*2, NO*2. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: FIRE WHEN CURING. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: PRO-POXY 100 LV, COMPONENT A Cage: UNITX Company Name: UNITEX Street: 3101 GARDNER Zipcode: 64120 Label Required IND: Y Date Of Label Review: 06/16/1995 Status Code: C Label Date: 06/16/1995 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: ACUTE:EYES/SKIN/INHALATION/INGESTION:WILL PRODUCE IRRITATION. CHRONIC: SENSITIZATION. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:P/N GPL-27 BATTERY,ELECTRIC STORAGE,ABSORBED ELECTROLYTE CAGE:63017 CAGE:0FGN2 CAGE:63017 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD OXIDE, (RED LEAD OXIDE); TOTAL PERCENTAGE OF INGREDIENTS 1 AND 2: 60. CAS:1314-41-6 RTECS #:OG5425000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3 Ingred Name:LEAD OXIDE (LITHARGE) (%-SEE INGREDIENT 1) CAS:1317-36-8 RTECS #:OG1750000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 38% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.05MG/M3, A3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 0.006% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE AND CHRONIC- NONHAZARDOUS/NON TOXIC. Explanation of Carcinogenicity:CONTAINS LEAD Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:NONE SPECIFIED BY MANUFACTURER. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NO SPECIAL FIRE FIGHTING PROCEDURES WILL BE APPLIED. IN CASE OF FIRE, HANDLE IN ACCORDANCE WITH STANDARD FIRE FIGHTING PROCEDURES. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:THIS PRODUCT IS A SEALED, VALVE REGULATED, ABSORBED ELECTROLYTE BATTERY. IN THE CASE OF AN ACCIDENT THAT TO HANDLE ANY EXPOSED MATERIA L. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:STORE IN VENTILATED AREA, AT ROOM TEMPERATURE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:KEEP TERMINALS COVERED. AVOID SHORTING BATTERIES. DO NOT CRACK OR OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY FROM CHARGING BATTERIE S. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. Ventilation:ADEQUATE GENERAL VENTILATION. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING. Supplemental Safety and Health THIS IS AN ABSORBED ELECTROLYTE BATTERY. ================== Physical/Chemical Properties ================== HCC:Z4 Appearance and Odor:BATTERY CONTAINING LEAD AND ABSORBED ELECTROLYTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP. SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE FEDERAL, STATE AN D LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HY LUX W/B ACR BLACK ENAMEL, 1201 CAGE:04GC9 CAGE:04GC9 CAGE:0RGC9 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) VP: 0.8 @ 68F CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 8% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL ETHER) VP: 0.0 @ 68F CAS:112-34-5 RTECS #:KJ9100000 Fraction by Wt: 2% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE) (SARA 313) (CERCLA) VP: 0.2 @ 302F CAS:85-68-7 RTECS #:TH9990000 Fraction by Wt: <5% OSHA PEL:5 MG/M3 (MFR) ACGIH TLV:5 MG/M3 (MFR) EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BENZOIC ACID, AMMONIUM SALT; (AMMONIUM BENZOATE) (CERCLA) CAS:1863-63-4 RTECS #:DG3378000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:AMMONIUM HYDROXIDE (CERCLA) VP: 420 @ 60F CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:25 PPM (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1-PROPANOL, 2-AMINO-2-METHYL-; (2-AMINO-2-METHYL-1-PROPANOL) CAS:124-68-5 RTECS #:UA5950000 Fraction by Wt: <0.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOC: 1.93 LB/GL (232 G/L) (COATING); 0.82 LB/GL (98 G/L) (MATERIAL) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: CONCENTRATED VAPS MAY BE HARMFUL. MAY CAUSE HDCH, DIZZ & NAUS. SKIN CONT/EYE CONT/SKIN ABSORPTION: MAY CAUSE IRRIT. INGEST: MAY BE HARMFUL IF SWALLOWED. CHRONIC: ANIMAL STUDIES CLEARLY D EMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/THE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION #90-118) . Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: WASH AFFECTED AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: DONOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>200F,>93C Lower Limits:0.3% Upper Limits:10.6% Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:MATL WILL NOT SUSTAIN COMBUST UNLESS WATER HAS EVAPD. FIRE-EXPOSED CONTRS SHOULD BE COOLED W/WATER TO PVNT PRESS BUILD-UP WHICH COULD RSLT IN CONTR RUPTURE. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION AND PROVIDE VENTILATION. LARGE SPILLS MAY BE SCOOPED UP WITH NON-SPARKING TOOLS. SMALL SPILLS MAY BE PICKED UP WITH ABSORBENT MATERIALS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HIGH TEMPERATURES AND OPEN FLAMES. KEEP CONTAINERS TIGHTLY CLOSED. Other Precautions:DO NOT TAKE INTERNALLY. AVOID PROLONGED CONTACT WITH SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF POOR VENTILATION, USE NIOSH APPROVED ORGANIC VAPOR MASK. Ventilation:ADEQUATE VOLUME AND PATTERN TO KEEP AIR CONTAMINANT CONCENTRATION BELOW CURRENT APPLICABLE OSHA/ACGIH'S TLV LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING THE WASHROOM. SMOKE IN SMOKING AREAS ONLY. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.0 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:SOLUBLE Appearance and Odor:BLACK LIQUID WITH MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXCESSIVE HEAT AND OPAN FLAMES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON DIOXIDE AND/OR CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:PLACE IN TIGHTLY CLOSED CONTAINERS. INCINERATE OR DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WONDER-SPEED EXTERIOR LATEX HOUSE PAINT, WX CAGE:FO133 CAGE:97903 CAGE:FO133 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: 5-30% OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:ETHYLENE GLYCOL. VP:0.08 @ 20C. LEL:3.2%. CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <5% OSHA PEL:50 PPM,C ACGIH TLV:50 PPM,C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:AMMONIUM HYDROXIDE;(AQUA AMMONIA). VP:11.9 @ 68F. CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: <1% OSHA PEL:50 PPM (MFR) ACGIH TLV:25 PPM (MFR) EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ESTER ALCOHOL. VP:1 @ 87C. LEL:0.62%. CAS:25265-77-4 Fraction by Wt: <1% Ingred Name:PALYGORSKITE;(ATTAPULGITE CLAY). CONTAINS CRYSTALLINE SILICA AS AN IMPURITY. CAS:12174-11-7 RTECS #:RT6400000 Fraction by Wt: <1% Ingred Name:DIATOMACEOUS EARTH, FLUX COLLCINED. CONTAINS CRYSTALLINE SILICA AS AN IMPURITY. CAS:68855-54-9 Fraction by Wt: 5-10% OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:IRON (III) OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: <1-5% OSHA PEL:10 MG/M3 (FE) ACGIH TLV:5 MG/M3(FE),B2; 9293 Ingred Name:SUPP DATA:RESPS WHEN FLAME CUTTING, WELDING, BRAZING, & SANDING MATL COATED W/PROD. FOLLOW RESP MFRS DIRECTIONS FOR USE. RTECS #:9999999ZZ Ingred Name:VENT:& HLTH STANDARDS IN MIXING, APPLICATION & CURING AREAS & TO REMOVE SANDING DUSTS OF DRIED COATING & DECOMP (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:PRODS DURING WELDING & FLAME CUTTING ON SURFACES COATED WITH THIS PRODUCT. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:IRRITATION OF UPPER RESPIRATORY TRACT, HEADACHE, NAUSEA, DIZZINESS. SKIN/EYE:PRIMARY IRRITATION. CHRONIC:PROLONGED & REPEATED BREATHING OF SPRAY MIST AND/OR SANDING DUST OVER A PERIOD OF Y EARS MAY CAUSE DUST DISEASE OF THE LUNGS. Explanation of Carcinogenicity:CRYSTALLINE SILICA:GROUP 2A (IARC);ANTICIPATED TO BE A CARCINOGEN (NTP). Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. EYE:FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CALL MD IMMEDIATEALY. SKIN:REMOVE WITH SOAP & WATER. REMOVE SOILED CLOTHING. INGEST:DRINK 1 OR 2 G LASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CALL MD IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:SEE ING Extinguishing Media:CO*2, DRY CHEMICAL, FOAM OR OTHER NFPA APPROVED METHOD FOR TREATING CLASS B FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ ARE PREF. IF EXPOSED TO FIRE/EXTREME HEAT (SUPDAT) Unusual Fire/Explosion Hazard:DUE TO PRESSURE BUILD-UP, CLSD CNTNRS EXPOSED TO EXTREME HEAT MAY EXPLODE. DURING EMERG CNDTNS, OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPT MAY(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:WASH WITH WATER. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF MSDS. CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT. STORE IN CLOSED CONTAINER UNTIL PR OPERLY DISPOSED OF. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 110F & KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY CONTAINERS. Other Precautions:DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELLED CONTAINERS. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALL RESPS MUST BE NIOSH/MSHA APPRVD. OUTDOOR OR OPEN AREAS W/UNRESTRICTED VENT, & DURING SANDING/GRINDING OPERS:USE MECH FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & SANDING DUST. RES TRICTED VENT AREAS:CHEM/MECH (SUPP DATA) Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOLUME & PATTERN TO KEEP AIR CONTAM CONC BELOW CURRENT APPLIC SAFETY (ING 9) Other Protective Equipment:NONE REQUIRED. Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE RESTROOM. Supplemental Safety and Health VAP DENSITY:HVR/AIR.(AMMONIA & WATER ARE LTR/AIR). FIRE FIGHT PROC:WATER SHOULD BE USED TO COOL CLSD CNTNRS & PVNT PRESS BUILD-UP OR POSS AUTO-IGNIT. EXPLO HAZ:NOT BE IMMED APPARENT. GET MD. RESP PROT :FILTERS DESIGNED TO REMOVE COMBINATIONOF PARTICULATES & VAP. CONFINED AREAS:AIR SUPPLY RESPS OR HOODS. USE (ING 8) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:SEE ING Vapor Density:SUPP DATA Spec Gravity:1.28-1.39 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:65-70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY CAUSE HAZARDOUS FUMES WHEN HEATED TO DECOMPOSITION. FUMES MAY CONTAIN CO, CO*2, & NO*X. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:941 ACCELERATOR FOR MC PU CAGE:0ZP91 CAGE:0ZP91 ============= Composition/Information on Ingredients ============= Ingred Name:URETHANE BISOXAZODINE CAS:59719-67-4 Fraction by Wt: 30-60% Other REC Limits:NONE RECOMMENDED Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM (TWA) ACGIH TLV:434MG/M3(TWASTL150PM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 10-30% Other REC Limits:590MG/M3(TWA) OSHA PEL:200 PPMTWA,STEL300PM ACGIH TLV:200 PPM/300STEL)TWA) EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE) CAS:123-42-2 RTECS #:SA9100000 Fraction by Wt: 10-30% Other REC Limits:NONE RECOMMENDED OSHA PEL:50 PPM(TWA) ACGIH TLV:60PPM(TWA)STEL76PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:* Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE/CHRONIC IRRITATION, REDNESS, WTRING, INFLAMATION, ITCHING. SKIN: HARMFUL IF ABSORBED, INFLAMATION, IRRITATION, DESTRUCTION, DERMOTITIS, INGEST: CHEM BURNS IRRITATION, MAY BE FATAL, INJ URY MAY BE SEVERE, INHALE:SEVERE/CHRONIC IRRITATION.MUCUOUSMEMBRANE IRRITANT, MAY BE FATAL. ION, Effects of Overexposure:TOXIC TO MUCUOUS MEMBRANES, UPPER RESP TRACT, LUNGS, BLOOD, KIDNEY, LIVER, POSSIBLE ASTHESMA, PULMONARUOEDEMA, EFFECTS MAY BE DELAYED, POSSIBLE PERMINANT CNS DAMAGE, NAUSEA, HEADACHE, VOMETING. DAN GEROUS IN CASE OF SKIN/EYE CONTACT, (IRRITANT PERMIATOR), VRY SLIGHTLY TO SLIGHTLY DANG AS SKIN SENSITIZER NARCOTIC Medical Cond Aggravated by Exposure:SKIN/ASTHMA TYPE CONDTTIONS, LIVER/KIDNEY DISORDERS, ======================= First Aid Measures ======================= First Aid:EYES: REMOVE CONTACTS, IMMLY FLUSH W/RUNNING WTR >15 MIN HOLDING EYELIDS OPEN. DO NOT USE OINTMENT, GET MED AID. SKIN: WASH W/RUNING WTR/NON-ABRASIVE SOAP 15-30 MIN. HAND CREAM AFTER WASHING. GET MED AID WASH CONTAM CLOTHING.INHALE: REMOVE TO FRESH AIR. GET IMMED MED AID, CPR, GET MED AID. INGEST: DO NOT INDUCE VOMET, IF CONSC, DRINK SEV GLASSES WTR/MLK, GET IMMED MED AID, AVOID ASPIRATION ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:21.2F75.2F,24.0C Autoignition Temp:Autoignition Temp Text:957.2F Lower Limits:1.81.4 Upper Limits:11.57.6 Extinguishing Media:SM FIRE: DRY CHEM, CO2 ALC FOAM, WTR SPRA, LG FIRE: WTR SPRA OR FOG, NEVER DIRECT WTR JET INSIDE CONTAINER Fire Fighting Procedures:COOL CONT W/WTR SPRA/FOG, WEAR SCUBA VPR MAY TRAVL LONG DISTANCES TO SOURCE OF IGNTN AND FLASH BACK. EMITS HIGHLY TOXIC FUMES. CONT MAY EXPLD DUE TO HEAT Unusual Fire/Explosion Hazard:VPR FORMS EXPLOSIVE MIXTURE W/AIT BTWN LEL AND UEL LIQUID WILL FLOAT AND MAY IGNITE ON SURFACE OF WTR ================== Accidental Release Measures ================== Spill Release Procedures:SM: ABSORB W/INERT MATL. PLACE IN CONT. LRG: ELIM ALL IGNITBLESWEAR FULL-PROT EQUIP STOP LEAK PREVENT ENTRY INTO SEWERS/ALL WATRWAYS, CALL FOR ASSISTANCE ON DISPOSAL ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN SEPARATE SAFETY RM. AVOID ALL IGNITS, KEEP CONT TIGHTLY CLOSED IN WELL VENTED DRY PLACE, REFRIG PREF. AVOID INCOMPATIBLES Other Precautions:KEEP OUT OF REACH OF CHILDREN, AVOID ALL CONTACT W/PRODUCT. NO CONTACT LENSES, SHOW LABEL TO MED AID. GROUND AL EQUIP. ISOCYANATES CAN NOT BE SMELLED UNTIL WELL ABV SAFE EXPOSURE LIMIT ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR, (W/ORGANIC VPR CARTRAGES, SCUBA/AIR SUPPLIED RESPIRATOR, IN SPRAY APPLICATION, AIR PURIFYING RESP W/ORGANIC VPR CARTRIDGE/PARTICULATE PREFILTERS Ventilation:EXHAUST VENTILATION, DO AIR MONITORING IF POSSIBLE Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, FULL SUIT, BOOTS, LAB COAT Work Hygienic Practices:KEEP PROD AWAY FROM FOOD, DRINKS, TOBACCO, EATING, DRINKING, SMOKING SHD BE PROHIB AROUND PRODUCT. WASH HANDS, FACE Supplemental Safety and Health XYLENES:(LD50MG/KG) ORAL ACUTE 4300 RAT DERMAL ACUTE 200 RABBIT, VAPR (LC50-PPM) ACUTE 6700 RAT. MEK(LD50-MG/KG) AORAL ACUTE 3400 RAT, DERMAL ACUTE 6480 RAT, VAPR(LC50-PPM) ACUTE 2000 RAT DIACALONE ALCAHOL(LD50-MG/KG) ORAL ACUTE 4000 RAT, DERMAL ACUTE 1360 RABBIT, ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:176F,80C Vapor Pres:15.898.26 Vapor Density:3.464.06 Spec Gravity:.9532.87 Evaporation Rate & Reference:11.6 Solubility in Water:INSOLUABLE Appearance and Odor:CLEAR AROMATIC LIQUID Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HIGHLY REACTIVE W/OXYDIZING AGENTS, SLIGHTLY REACTIVE TO REACTIVE W/REDUCING AGENTS, ORGANIC MTLS, METALS, ALKALI,ACIDS Hazardous Decomposition Products:CARBON OXIDES,AND OTHER POSSIBLY UNIDENTIFIED TOXIC COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:HAZARDOUS WASTE. FILL DRUMS HALFWAY, DO NOT SEAL. KEEP WELL VENTED. PER FED STATE LOCAL REGS, AVOID RESIDUE. DO NOT HEAT/CUT EMPTY CONTS W/ELECT/GAS TORCH
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:25F403 CAGE:JO842 CAGE:24446 CAGE:JO842 ============= Composition/Information on Ingredients ============= Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III) CAS:1336-36-3 RTECS #:TQ1350000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA) ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO MAKE UNCONS CIOUS PERSON VOMIT. ================== Accidental Release Measures ================== Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD Ventilation:LOCAL EXHAUST Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT Supplemental Safety and Health OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES EYES,NOSE THROAT. ================== Physical/Chemical Properties ================== HCC:Z3 Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR ================= Stability and Reactivity Data ================= STRONG OXIDIZERS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:B1012-30B/B1015-30 MICROSCAN PEPTIDASE REAGENT Kit Part:Y CAGE:GO294 CAGE:0WG31 CAGE:GO294 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL MONOMETHYL ETHER (EGME), METHYL CELLOSOLVE, 2-METHOXY ETHANOL, METHYL OXITOL *96-4* CAS:109-86-4 RTECS #:KL5775000 Fraction by Wt: 5% Other REC Limits:16 PPM OSHA PEL:25 PPM ACGIH TLV:16 MG/CUM Ingred Name:ACETIC ACID (GLACIAL), ETHANOIC ACID *96-4* CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 2.4% OSHA PEL:25 MG/CUM ACGIH TLV:25 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM LAURYL SULFATE, SODIUM LAURETH SULFATE *96-4* CAS:151-21-3 RTECS #:WT1050000 Fraction by Wt: 2.4% Ingred Name:DIMETHYL FORMAMIDE (SUSPECTED HUMAN CARCINOGEN BY IARC-GROUP 2B) *96-4* CAS:68-12-2 RTECS #:LQ2100000 Fraction by Wt: 2% Other REC Limits:10 PPM OSHA PEL:30 MG/CUM ACGIH TLV:30 MG/CUM (SKIN) EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:4-DIMETHYLAMINOCINNAMALDEHYDE *96-4* CAS:6203-18-5 Fraction by Wt: 0.014% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 88.2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION. MAY ALSO CAUSE CNS, DIGESTIVE & CARDIOVASCULAR SYSTEM EFFECTS. Explanation of Carcinogenicity:SEE INGREDIENTS Effects of Overexposure:IRRITATION, BURNING, GI DISTURBANCES, NAUSEA, VOMITING, LOSS OF APPETITE, FATIGUE, SLEEP DISORDERS, BRONCHITIS, TUMORS, CANCER. Medical Cond Aggravated by Exposure:SKIN, KIDNEY & LIVER DISORDERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. EYES: WASH W/WATER/NORMAL SALINE FOR 20 MINS. CONTINUE IRRIGATION W/NORMAL SALINE FOR 30-60 MINS. SKIN: WASH W/SOAP & WATER. INGESTION: GIVE WATER/ MILK. IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. TREAT SYMPTOMATICALLY & SUPPORTIVELY. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE MEDIUM SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN PRESSURE-DEMAND/POSITIVE-PRESSURE MODE. DON'T RELEASE RUNOFF FROM FIRE CONTROL METHODS TO SEWERS/WATERWAYS. ================== Accidental Release Measures ================== Spill Release Procedures:TREAT AS A SMALL LABORATORY SPILL. SMALL: EXTINGUISH IGNITION SOURCES. TAKE UP W/ABSORBENT MATERIAL & PLACE INTO CLEAN GLASS CONTAINER FOR LATER DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE AWAY FROM INCOMPATIBLE SUBSTANCES. NEVER EAT, DRINK/SMOKE IN WORK AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR IF NECESSARY. Ventilation:GENERAL/LOCAL EXHAUST TO MAINTAIN AIRBORNE CONCENTRATIONS <PELS. (SEE SUPP) Other Protective Equipment:CHEMICALLY RESISTANT APRON, EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH SHOWERS, WASHING FACILITIES Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS MATERIAL. Supplemental Safety and Health VENTILATION CONT'D: LOCAL EXHAUST IS PREFERRED BECAUSE IT PREVENTS CONTAMINANT DISPERSION INTO WORK AREA BY CONTROLLING IT AT ITS SOURCE. ================== Physical/Chemical Properties ================== Solubility in Water:COMPLETE Appearance and Odor:YELLOWISH LIQUID W/PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CAUSTICS, OXIDIZERS, METALS ACETALDEHYDE, ACETIC ANHYDRIDE. Hazardous Decomposition Products:BY THERMAL OXIDATIVE DECOMPOSITION: TOXIC &/HAZARDOUS GASES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. EMPTY CONTAINER MAY BE RINSED W/WATER & DISPOSED OF AS SOLID NONHAZARDOUS WASTE. FLAMMABLE LIQUID UN2265.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LEAD ACID STORAGE BATTERY Preparer's Name:ALAN L. CSORITAS CAGE:63432 CAGE:0YUR5 CAGE:63432 CAGE:3X778 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA 313) (CERCLA) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 60% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1025 ACGIH TLV:0.05MG/M3, A3; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ANTIMONY (SARA 313) (CERCLA) CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 1-5% Other REC Limits:NONE RECOMMENDED OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG (SB)/M3; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ARSENIC (SARA 313) (CERCLA) CAS:7440-38-2 RTECS #:CG0525000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1018 ACGIH TLV:0.01 MG/M3, A1; 9596 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 10-38% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CALCIUM, METAL CAS:7440-70-2 RTECS #:EV8040000 Fraction by Wt: <0.15% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV FOR SULFURIC ACID IS 1 MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:CONTENTS OF BATTERY ARE CORROSIVE EYES: MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION AND BURNS.INGEST:MAY CAUSE GI TRACT IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION.CHRONIC:DRYING OF THE SKIN, BRONCHITIS,EROSION OF TOOTH ENAMEL. Explanation of Carcinogenicity:SULFURIC ACID MISTS-IARC 2B.LEAD-IARC 2B. Effects of Overexposure:SKIN:DERMATITIS. Medical Cond Aggravated by Exposure:SULFURIC ACID MISTS MAY BRONCHIAL SYSTEM, SKIN AND EYES. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NE EDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,RINSE MOUTH WITH WATER. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:675F Lower Limits:4.1(H2) Upper Limits:74.2(H2) Extinguishing Media:HALON,DRY CHEMICAL. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG.ACID MISTS ARE CORROSIVE. Unusual Fire/Explosion Hazard:HYDROGEN GAS AND SULFURIC ACID MISTS MAY BE PRESENT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.NEUTRALIZE.SOAK UP WITH A NON- COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER CONTAINER FOR DISPOSAL.AVOID SHORTIN G BATTERY TERMINALS. Neutralizing Agent:SODA BICARBONATE,SODA ASH,SAND,LIME SHOULD BE KEPT ON SITE FOR SPILL REMEDIATION ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE. KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS. Other Precautions:AVOID SHORTING BATTERY TERMINALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR A NIOSH/ MSHA APPROVED RESPIRATOR FOR ACID GAS,DEPENDING ON THE AIRBORN CONCENTRATION. Ventilation:USE GENERAL DILUTION VENTILATION(4 AIR CHANGES PER HOUR). Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:275F,135C Melt/Freeze Pt:M.P/F.P Text:>320F,>160C Vapor Density:3.4 Spec Gravity:1.08-1.4 pH:ACID Solubility in Water:ELECTROLYTE-COMPLETE Appearance and Odor:BATTERY WITH POLYPROPYLENE OR HARD RUBBER CASE. ELECTROLYTE IS COLORLESS ACID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:OVERCHARGING,SOURCES OF IGNITION. Hazardous Decomposition Products:EXPLOSIVE HYDROGEN/OXYGEN FORMED BATTERY DURING CHARGING.SULFURIC ACID MISTS,SO2,SO3,STILBENE,ARSINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE WHOLE SCRAP BATTERIES TO LEAD SMELTER. PLACE NEUTRALIZED SPILLS IN CONTAINER WITH SORBENT MATERIALS.DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BLACO-TRON DES CAGE:BARON CAGE:BARON POLYMERS CAGE:99384 ============= Composition/Information on Ingredients ============= Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA III) CAS:76-13-1 RTECS #:KJ4000000 Fraction by Wt: 93.5% OSHA PEL:1000PPM/1250STEL ACGIH TLV:1000PPM/1250STEL9192 Ozone Depleting Chemical:1 Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 2% OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 3.5% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 Ingred Name:NITROMETHANE CAS:75-52-5 RTECS #:PA9800000 Fraction by Wt: 1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 0.4% OSHA PEL:S,200PPM/250STEL ACGIH TLV:S,200PPM/250STEL; 93 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ABOUT 43 G/KG (RAT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:LOW TOXICITY,MILD IRRITANT. IT IS AN ANESTHETIC & INHALATION OF HIGH CONCENTRATIONS CAN PRODUCE ASPHYXIATION. AT LEVELS OF ABOUT 2500 PPM IN AIR THERE BEGINS TO BE INTERFERENCE WITH PSYCHOLOGICAL & PS YCHOMOTOR FUNCTIONS,EXPRESSED AS EXCITEMENT & INCOORDINATION. Effects of Overexposure:LOW CONCENTRATION:HEADACHE,DIZZINESS,NAUSEA; HIGH CONC(>2500 PPM):INTOXICATION,CARDIAC EFFECTS,CENTRAL NERVOUS SYSTEM DEPRESSION; EYE/SKIN:IRRITATION: ING:SIMILAR SYMPTOMS AS FOR INHALATION. Medical Cond Aggravated by Exposure:NONE STATED. ======================= First Aid Measures ======================= First Aid:INH:REMOVE TO FRESH AIR,GIVE MOUTH-TO-MOUTH RESUSCITATION IF BREATHIG HAS STOPPED,GIVE OXYGEN AS NECESSARY.DO NOT GIVE ADRENALIN(EPINEPHRINE); ING:IF CONSCIOUS,INDUCE VOMITING BY GIVING 2-4 GLASSES OF WATER & TOUCH FINGER TO BACK OF THROAT,TAKE TO A HOSPITAL; EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MIN,LIFTING EYELIDS; SKIN:WASH WITH SOAP & WATER,REMOVE CONTAMINATED CLOTHING & SHOES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE PROPER EXTINGUISHING MEDIA FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS FOR POSSIBLE EXPOSURE TO HYDROCHLORIC & HYDROFLUORIC ACIDS & PHOSGENE. Unusual Fire/Explosion Hazard:WILL DECOMPOSE AT TEMPERATURE ABOVE 250F. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA.PROVIDE MAX VENTILATION.UNPROTECTED PERSONNEL SHOULD STAY UPWIND OF SPILL.WEAR PROPER PROTECTIVE CLOTHING.DIKE AREA & CONTAIN SPILL.PREVENT CONTAMINATION OF GROUND & SURFACE WATER.USE SA WDUST OR VERMICULATE,SWEEP INTO CONTAINER & CLOSE. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE IN POORLY VENTILATED AREAS. KEEP CONTAINERS CLOSED WHEN NOT IN USE.AVOID CONTAMINATION OF WATER SUPPLIES. Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. AVOID CONTACT WITH EYES & SKIN.DO NOT TAKE INTERNALLY.DO NOT EAT,DRINK OR SMOKE IN WORK AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK SITUATIONS. USE NIOSH-APPROVED PRESSURE-DEMAND SELF-CONTAINED OR SUPPLIED-AIR RESPIRATOR WHERE THE PLACE IS CONFINED OR ENCLOSED. Ventilation:LOCAL EXHAUST FOR FILLING ZONES & MECHANICAL FOR STORAGE AREAS. Other Protective Equipment:EYE BATH & SAFETY SHOWER. Work Hygienic Practices:USE NORMAL HYGENIC PRACTICES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:112F/44C Melt/Freeze Pt:M.P/F.P Text:<-13F/-35C Decomp Temp:Decomp Text:>250F/121C Vapor Pres:5.6 Vapor Density:5.6 Spec Gravity:1.48 pH:7 Evaporation Rate & Reference:4.2, ETHER=1 Solubility in Water:0.05% (WT) Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL & FAINT SWEETISH ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS & STRONG ALKALIS REACTIVE METAL:POWDERED ALUMINUM,MAGNESIUM,ZINC,MOLTEN BARIUM,LITHIUM SHAVINGS,ETC. Stability Condition to Avoid:AVOID TEMPERATURE ABOVE 250F.AVOID SPARKS,HOT SPARKS,WELDING,FLAMES & CIGARETTES. Hazardous Decomposition Products:HYDROCHLORIC ACID,HYDROFLUORIC ACID,PHOSGENE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DISPOSED OF IN A PERMITTED HAZARDOUS WASTE FACILITY. RECOVERED LIQUID MAY BE REPROCESSED OR INCINERATED OR TREATED IN A WASTE MANAGEMENT FACILITY. FOLLOW FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: DSX-OIL Cage: MSRXN Box: 1372 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: MSRXN Box: 1372 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE:MAY CAUSE SLIGHT SKIN OR EYE IRRITATION UPON PROLONGED CONTACT. CHRONIC:NONE LISTED BY MANUFACTURER. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES:FLUSH THORO WITH WATER FOR @ LEAST 15 MINUTES. SKIN:WASH AFFECTED AREA WITH SOAP AND WATER. INGEST:IF EXCESSIVE, INDUCE V OMITING. GET MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: SM QTYS, FLUSH WITH COOL WATER AND/OR ABSORB WITH ABSORBENT MATERIAL. LARGE QTYS, CONTAIN AND SCOOP INTO CONTAINERS FOR DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER. Other Precautions: NONE SPECIFIED BY MANUFACTURER. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: >400F,>204C Extinguishing Media: WATER FOG, DRY CHEMICAL. Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NONE. ======================================================= Control Measures ======================================================= Respiratory Protection: NONE NEEDED AT NORMAL TEMPERATURES. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: GENERAL ROOM IS ADEQUATE. Other Protective Equipment: ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER (FP N). Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: BP/MP:NOT DISTILLABLE. VAP DENS:8.65 LBS/GAL @ 25C. ======================================================= Physical/Chemical Properties ======================================================= HCC: V6 B.P. Text: SUPDAT M.P/F.P Text: SUPDAT Vapor Pres: VERY LOW Vapor Density: SUPDAT Spec Gravity: 1.0 APPROX PH: 6.7 Evaporation Rate & Reference: NOT KNOWN Solubility in Water: INSOLUBLE Appearance and Odor: WHITE/NO ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DSX-OIL Cage: MSRXN Company Name: MSR INC Street: UNKNOWN PO Box: 1372 Zipcode: 20167-1372 Label Required IND: Y Date Of Label Review: 12/12/1995 Status Code: C Label Date: 12/12/1995 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE:MAY CAUSE SLIGHT SKIN OR EYE IRRITATION UPON PROLONGED CONTACT. CHRONIC:NONE LISTED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:METHYL ALCOHOL 14280, A9474LC CAGE:1B464 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA) LD50 (ORAL RAT): 5628 MG/KG CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: >99% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM/250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE + METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID, & POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: THOSE OF ACUTE INHALATION AND INGESTION. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: EFTS (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM. ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT. MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, INCL EXCITEMENT, FOLLOWEDBY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: COLLAPSE, UNCON, COMA & POSS DEATH DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE RESP TRACT IRRIT, LIVER & KIDNEY DAMAGE, ADVERSE CNS EFTS INCLUDING HDCH, CONVULSIONS, & PO SS DEATH. MAY CAUSE VISUAL IMPAIRMENT &POSS PERM BLINDNESS, & EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING 5) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 7) ===================== Fire Fighting Measures ===================== Flash Point:53.6F,12.0C Lower Limits:6.00% Upper Limits:31.00% Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER MAY BE INEFFECTIVE. Unusual Fire/Explosion Hazard:CONTRS CAN BUILD-UP PRESS IF EXPOSED TO HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DURING FIRE, IRRITATING & HIGHLY TOX GASES (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERS PROT EQUIP AS INDICATED. SCOOP UP W/NON-SPARKING TOOL, THEN PLACE INTO SUITABLE CONTR FOR DISP. USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE SOURCES OF IGNIT. ABSORB SPILL USING ABSORB,NON-COMBUST MATL SUCH AS EARTH, SAND/VERMICULITE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS RETAIN PROD RESIDUE (LIQUID, &/OR VAPOR), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE. Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. KEEP AWAY FROM SOURCES OF IGNITION. STORE IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM IN COMPATIBLE SUBSTANCES. FLAMMABLES-AREA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS. Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ: MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAM LIQ. CAN RELEASE VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASH POINT. MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS POTASSI UM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:96 MMHG Vapor Density:1.1 Spec Gravity:0.791 Evaporation Rate & Reference:5.2 (ETHER=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH SLIGHT ALCOHOL-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT) Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS, IGNITION SOURCES. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA U-SERIES: WASTE NUMBER U154 (IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-C-83286B, 13538 LEAD FREE, 03Y092 Kit Part:Y Preparer's Name:NORM GAUL CAGE:33461 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL 3-ETHOXYPROPIONATE (SARA 313) (VAPOR PRESSURE: .7 MM HG) CAS:763-69-9 RTECS #:UF3325000 Fraction by Wt: 25% Other REC Limits:NONE SPECIFIED Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ACETATE (SARA III) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: <1% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM/200 STEL ACGIH TLV:150 PPM/200STEL;9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ACETATE (SARA III) CAS:141-78-6 RTECS #:AH5425000 Fraction by Wt: 10% Other REC Limits:NONE SPECIFIED OSHA PEL:400 PPM ACGIH TLV:400 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PMGE ACETATE (VAPOR PRESSURE: 3.8 MM HG) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: <0.1% Other REC Limits:RECOMM TLV: 100 PPM Ingred Name:DIBUTYLTIN DILAURATE (VAPOR PRESSURE: .2 MM HG) CAS:77-58-7 RTECS #:WH7000000 Fraction by Wt: <0.1% Other REC Limits:NONE SPECIFIED ACGIH TLV:.1MG/M3;.2MG/M3 STEL Ingred Name:VOC: 484 G/L RTECS #:9999999VO Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: VAPORS IRRITATING TO EYES/NOSE/THROAT. INHALATION: IRRITATION, ACUTE NERVOUS SYSTEM DEPRESSION. CHRONIC: PROLONGED CONTACT WILL CAUSE DEFATTING ACTION, SKIN SENSITIZATION, ASTHMA OR OTHER ALLER GIC RESPONSES MAY DEVELOP. INGESTION: IRRITATION. ASPIRATION CAN CAUSE CHEMICAL PNEUMONITIS. Effects of Overexposure:INHAL: DIFFICULT BREATHING, HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: IRRIT (SWELLING/REDNESS/RASH). EYES: REDNESS, TEARING, SWELLING W/STINGING. SKIN: PROLONGED/RE PEATED--MODERATE IRRIT, DRYING, SKIN CRACKING. INGEST: VOMIT. IRRIT. CORROSIVE TO MOUTH, STOMACH & DIGESTIVE TRACT. Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP (IMMED/DELAYED BY SEVERAL HRS). GET MED AID. SKIN: REMOVE CONTAM CLOTHING. WASH AREA W/SOAP & WATER. WASH CONTAM C LOTHING BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER (LOW PRESSURE)--15 MIN, LIFTING UPPER/LOWER LIDS. GET MED AID. INGESTION: DON'T INDUCE VOMIT. NOTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:24.0F,-4.4C Lower Limits:1.% Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:FULL FIRE FIGHTING EQUIP W/SCBA & FULL PROTECTIVE CLOTHING SHOULD BE WORN. WATER USED TO COOL CLOSED CONTAINERS/PREVENT PRESSURE BUILD-UP/AUTO IGNIT/EXPLOSION. Unusual Fire/Explosion Hazard:KEEP FROM IGNITE SOURCES. CLOSED CNTNR MAY EXPLODE W/HEAT. USE SPECIAL PRECAUTION W/APPLIC TO HOT SRFCS. DURING EMERG COND, OVEREXPOS TO DECOMP PROD/HEALTH HZD. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDG IN COMPLIANCE W/OSHA 1910.106. AVOID HIGH TEMP, IGNITION SOURCES. STORE IN TIGHTLY CLOSED CONTAINERS. STORE IN WELL VENT AREAS. Other Precautions:KEEP CNTNRS TIGHT/UPRIGHT (PREVENT LEAKAGE). NO PROLONGED BREATHING OF VAPORS/SPRAY MISTS. AVOID CONTACT W/SKIN/EYES. DO NOT TAKE INTERNALLY. DO NOT HANDLE UNTIL THE SAFETY PRECAUTIONS HAVE BEEN READ/ UNDERSTOOD. SMOKE ONLY IN SMOKING AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATOR RECOMMENDED/APPROVED FOR USE IN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED) IS NECESSARY. OBSERVE OSHA REGULATIONS--RESPIRATOR USE. VENT SHOULD BE PROVIDED TO KEEP EXPOSURE LEVELS BELOW OSHA PERMISSIBLE LIMITS. Ventilation:EXHAUST VENT SUFFICIENT TO KEEP AIRBORNE CONC (MIST/VAPOR) BELOW TLV'S MUST BE USED. REMOVE ALL IGNITION SOURCE. Other Protective Equipment:FACE SHIELDS. THE USE OF LONG SLEEVE AND LONG LEG CLOTHING IS RECOMMENDED. Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:169 TO 338F Vapor Density:> AIR Spec Gravity:1.18 Viscosity:* Evaporation Rate & Reference:1.81 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:YELLOW LIQUID WITH SOLVENT ODOR. Percent Volatiles by Volume:52.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES. Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED IN ACCORD W/FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE HANDLED W/CARE (PRODUCT RESIDUE/FLAMMABLE VAPOR). DON'T INCINERATE CLOSED CNTNRS. EPA HAZARDOUS WASTE #: D001, F003, F005.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7290 POWER GOLD HAND CLEANER Preparer's Name:DONALD H SINNER CAGE:GO199 CAGE:GO199 CAGE:02905 ============= Composition/Information on Ingredients ============= Ingred Name:CARVENE; CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL), CITRUS TERPENE, D-LIMONENE, P-MENTHADIENE CAS:5989-27-5 RTECS #:GW6360000 Fraction by Wt: 1-5% Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES MINERAL SPIRITS CAS:64742-88-7 Fraction by Wt: 15-40% Other REC Limits:100 PPM OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:WHITE MINERAL OIL CAS:8042-47-5 RTECS #:PY8047000 Fraction by Wt: 10-20% Other REC Limits:STEL 10 MG/CUM OSHA PEL:5 MG/CUM MIST ACGIH TLV:5 MG/CUM MIST Ingred Name:PERLITE CAS:93763-70-3 RTECS #:SD5254000 Fraction by Wt: 3-10% Other REC Limits:30 MPPCF MSHA STD OSHA PEL:15 MG/CUM TOTAL DUST ACGIH TLV:10 MG/CUM TOTAL DUST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. THIS SKIN CARE COSMETIC ISN'T CONSIDERED HAZARDOUS/TOXIC UNDER NORMAL HANDLING & USE CONDITIONS. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, GASTRIC UPSET, CRAMPS, DIARRHEA. ======================= First Aid Measures ======================= First Aid:EYES: DON'T RUB, FLUSH W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS, LOWER HEAD BELOW THE KNEES TO AVOID ASPIRATION. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB & COLLECT FOR DISPOSAL. FLUSH AREA W/WATER TO REDUCE POSSIBLE SLIPPERY FLOOR HAZARD. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT AMBIENT TEMPS. Other Precautions:AVOID EYE CONTACT. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED Other Protective Equipment:NONE REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>200F Vapor Pres:25 Vapor Density:0.6 Spec Gravity:0.9 pH:8-8.8 Evaporation Rate & Reference:(WATER = 1): 1 Solubility in Water:45% EMULSIFIERS Appearance and Odor:OPAQUE EMERALD LIQUID W/CITRUS OIL FRAGRANCE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:STORE AT AMBIENT TEMPS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:SOAP, LAUNDRY BUILT, HIGH TEMPERATURE Preparer's Name:MICHAEL A JACOBS CAGE:0CA58 CAGE:0CA58 ============= Composition/Information on Ingredients ============= Ingred Name:SILICIC ACID, DISODIUM SALT CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: 20-40% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM CARBONATE (NUISANCE DUST PARTICLES) CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 10-30% Other REC Limits:NONE SPECIFIED ACGIH TLV:10 MG/M3 Ingred Name:PENTASODIUM TRIPHOSPHATE CAS:7758-49-4 RTECS #:YK4900000 Fraction by Wt: 5% MIN Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM TALLOWATES CAS:61789-66-0 Fraction by Wt: 30% MIN Other REC Limits:NONE SPECIFIED Ingred Name:POLY (OXY-1,2-ETHANE DIYL), ALPHA-(NONYL PHENYL)-OMEGA-HYDROXY CAS:9016-45-9 RTECS #:WZ4750000 Fraction by Wt: 2% MIN Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:ACUTE: MAY CAUSE SEVERE IRRITATION OF THE EYES, INCLUDING CORNEAL OPACITIES. DUST IS IRRITATING TO THE SKIN, MUCOUS MEMBRANES, AND UPPER RESPIRATORY TRACT. CHRONIC: MAY CAUSE INFLAMATION OF THE MUCOUS MEMBRANES IN THE RESPIRATORY TRACT ANDOF THE SKIN. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEE AN OPTHALMOLOGIST IF IRRITATION PERSISTS. SKIN: WASH WITH PLENTY OF WATER. IF IRRITATION OCCURS AND PERSISTS, OBTAIN MEDICAL ATTE NTION. INGESTION: DRINK A GLASS OF WATER OR MILK. ===================== Fire Fighting Measures ===================== Flash Point:N/K * 12.5 Extinguishing Media:WATER, FOAM, DRY CHEMICALS Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:SPONTANEOUS HEATING, MODERATE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AS MUCH AS POSSIBLE FOR SALVAGE OR DISPOSAL. WASH AWAY RESIDUE WITH WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE CLOSE TO ACIDS. MINIMIZE THE FREE FALL WHEN HANDLING TO MINIMIZE THE DUST GENERATED. RESPIRATOR TO PREVENT IRRITATION WHERE EXCESSIVE DUST IS PRESENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR DUST RESPIRATOR IF NUISANCE DUST TLV OF 10 MG/M3 IS EXCEEDED OR DISCOMFORT IS PRESENT. Ventilation:GENERAL VENTILATION - LOCAL EXHAUST IF NEEDED FOR DUST CONTROL. Other Protective Equipment:FULL COVER CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:NEGLIGIBLE Spec Gravity:0.79 (WATER=1) pH:11.5* Solubility in Water:10% Appearance and Odor:AN OFF WHITE POWDER WITH A SOAP ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH ACIDS RELEASES LARGE VOLUMES OF CARBON DIOXIDE GAS AND HEAT. STRONG OXIDIZING AGENTS. Stability Condition to Avoid:CONTACT WITH ACIDS EXCEPT UNDER CONTROLLED CONDITIONS. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:IF MATERIAL CANNOT BE SALVAGED, THE PREFERRED METHOD OF DISPOSAL IS IN A SECURE CHEMICAL LAND FILL IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. EMPTY CONTAINERS MAY BE INCI NERATED OR DISCARDED AS GENERAL TRASH.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:190 1859, CONC, KODAK GBX DEVELOPER AND REPLENISHER Kit Part:Y Preparer's Name:NOT PROVIDED CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:60. Maxumum % Wt:65. Other REC Limits:NOT PROVIDED Code:F Code:F Ingred Name:POTASSIUM SULFITE CAS:10117-38-1 RTECS #:WT3530000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:HYDROQUINONE CAS:123-31-9 RTECS #:MX3500000 = Wt:6. Other REC Limits:NOT PROVIDED OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:4-(HYDROXYMETHYL)-4-METHYL-1-PHENYL-3-PYRAZOLIDONE (MSDS -PYRAZOLIDINONE NOT FOUND IN CHEM FINDER.) CAS:13047-13-7 < Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: PROLONGED OR REPEATED CONTACT WITH AQUEOUS SOLUTIONS MAY CAUSE IRRITATION. MAY CAUSE SKIN DEPIGMENTATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): HYDROQUINONE, GROUP 3; NOT CLASSIFIABLE. AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): HYDROQUINONE, A3; CONFIRMED ANIMAL CARC INOGEN WITH UNKNOWN RELEVANCE TO HUMANS. NATIONAL TOXICOLOGY PROGRAM (NTP): NONE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. EYES: CAUSES IRRITATION. SKIN: PROLONGED OR REP EATED CONTACT WITH AQUEOUS SOLUTIONS MAY CAUSE IRRITATION. MAY CAUSE SKIN DEPIGMENTATION. MAY CAUSE ALLERGIC SKIN REACTION BASED ON HUMAN EXPERIENCE. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTES TINAL TRACT. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN : IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. IF SKIN IRRITATION OR ALLERGIC SKIN REACTION DEVELOPS, GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. INGESTION: ONLY INDUCE VOMITING AT INSTRUCTION OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media: WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND REACTIVITY SECTION. IF RESPI RATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. APPROPRIATE FOR RISK OF EXPOSURE Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H EATING, ETC. ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:68F: 24 MBAR (18 MM HG) Vapor Density:0.6 Spec Gravity:1.230 pH:10.2 Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:COMPLETE Appearance and Odor:SLIGHT YELLOW, ODORLESS, LIQUID. Percent Volatiles by Volume:65 WT Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF SULFUR. =================== Toxicological Information=================== Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS DIETHYLENE GLYCOL. CAN CAUSE CNS EFFECTS. CAN CAUSE KIDNEY DAMAGE. N F-344 RATS, CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE HAS RESULTED IN THE FORMATION OF BEN IGN KIDNEY TUMORS THOUGHT TO BE SECONDARY TO NEPHROPATHY. HYDROQUINONE-INDUCED NEPHROPATHY FOLLOWING ORAL ADMINISTRATION HAS BEEN NOTED IN THE MALE F-344 RAT, BUT NOT IN OTHER SPECIES OR RAT STRA INS TESTED. ALTHOUGH AN INCREASE IN MONONUCLEAR CELL LEUKEMIA IN F-344 FEMALE RATS HAS BEEN REPORTED FOLLOWING CHRONIC ORAL ADMINISTRATION OF HYDROQUINONE, THIS FINDING WAS NOT REPRODUCED IN A SUBSEQUENT STUDY. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10. DAPHNID EC50 MG/L:< 1. ALGAL IC50 MG/L:10-100. ORGANICS READILY DEGRA DABLE (>70%): YES (14 DAYS).POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 340. BOD5 (APPROXIMATE G/L): 121. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: HYDROQUINONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:A-9 ALUMINUM CUTTING FLUID Preparer's Name:WILLIAM C. KINARD CAGE:14332 CAGE:6A908 CAGE:9J042 CAGE:14332 CAGE:4S446 ============= Composition/Information on Ingredients ============= Ingred Name:WHITE MINERAL OIL CAS:8042-47-5 RTECS #:PY8047000 Fraction by Wt: >85.0% Other REC Limits:5MG/M3 AS OIL MIST Ingred Name:A SEMI-SOLID ANIMAL FAT (TRADE SECRET) Fraction by Wt: <15.0% Other REC Limits:NONE SPECIFIED Ingred Name:A NATURAL FATTY ACID (TRADE SECRET) Fraction by Wt: <5.0% Other REC Limits:NONE SPECIFIED Ingred Name:NEW MOWN HAY PERFUME Fraction by Wt: <1.0% Other REC Limits:NONE SPECIFIED Ingred Name:GREEN DYE,PHARMACY GRADE. Fraction by Wt: TRACE Other REC Limits:NONE SPECIFIED Ingred Name:VOLATILE ORGANIC COMPOUND(PER ASTM 02369-73)= 9.41 GRAMS PER LITER. RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE PULMONARY RESPIRARTION. SKIN AND EYE CONTACT MAY CAUSE SOME IRRITATION. INGESTION MAY CAUSE MILD GI TRACT DISTRESS. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED: COUGHING, SNEEZING, WHEEZING, SHORTNESS OF BREATH. EYES: REDNESS, ITCHING, TEARING. SKIN: REDNESS, DISCOMFORT. INGESTED: NAUSEA. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOV E CONTAMINATED CLOTHING. WASH WITH SOAPAND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:266F,130C Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NO UNUSUSL HAZARDS ================== Accidental Release Measures ================== Spill Release Procedures:TREAT AS OIL SPILL. SOAK UP ON ABSORBENT CLAY OR SAND REMOVE TO CONTAINER; WASH RESIDUE WITH SYNTHETIC DETERGENT & HOT WATER. Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID PRODUCTION OF OIL MIST.AVOID EXCESSIVE HEAT AVOID REPEATED OR PROLONGED SKIN OR EYE CONTACT. Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE. DO NOT PRESSURIZE, CUT, WELD OR EXPOSE TO HEAT, FLAME, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR FOR OIL MIST AS REQUIRED IF ABOVE PEL/TLV. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:B.P. Text:400F,204C Vapor Pres:0.1 MM HG Spec Gravity:0.9 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT GREEN/COLORED OIL WITH SLIGHT FATTY ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. SWELLS NATURAL RUBBER & SOME PLASTICS. SLIGHT ETCHING OF LIGHT METALS WITH PROLONGED EXPOSURE. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND ACROLEIN WHEN COMBUSTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES. DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:98-88 GLOSS BRIGHT GREEN SPRUCE 473 CAGE:59581 CAGE:59581 ============= Composition/Information on Ingredients ============= Ingred Name:ISOBUTANE, 2-METHYLPROPANE CAS:75-28-5 RTECS #:TZ4300000 Other REC Limits:1000 PPM OSHA PEL:1800 MG/CUM ACGIH TLV:1000 PPM Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 12-26% Other REC Limits:100 PPM OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:VM&P NAPHTHA (LIGROINE) CAS:8032-32-4 RTECS #:OI6180000 Other REC Limits:STEL 400 PPM OSHA PEL:300 PPM/400 STEL ACGIH TLV:300 PPM; 9192 Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 1-5% Other REC Limits:100 PPM OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Other REC Limits:50 PPM OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 8-22% Other REC Limits:590 MG/CUM OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Other REC Limits:1800 MG/CUM OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITANT. SKIN: DEFATTING/DERMATITIS/SCALY/REDNESS/DRY/ABSORPTION. INHALATION: RESPIRATORY SYSTEM IRRITATION/HEADACHE/DIZZINESS/NAUSEA/POSSIBLE UNCONSCIOUSNESS/ASPHYXIATION/NOSE/THROAT IRRITATION /NAUSEA/VOMITING/INCOORDINATION/DROWSINESS. INGESTION: STUPER/INTOXICATION/COMA. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: CARDIAC EFFECTS/CNS DEPRESSION/PERIPHERAL POLYNEUROPATHY/COMA/NARCOSIS/HARMFUL/FATAL. INGESTION: HARMFUL/FATAL. EYES: IRRITATION. SKIN: FISSURED DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPS, BEGIN ARTIFICIAL RESPIRATION. EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP & WATER. INGESTION: UNLIKELY FROM AN AEROSOL CAN. OBTAIN MEDICA L ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:-10F Lower Limits:0.70% Upper Limits:9.5% Extinguishing Media:USE CO2, DRY CHEMICAL & FOAM Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:EXPOSURE TO HEAT OR SUN MAY CAUSE BURSTING. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WIPE UP W/INERT MATERIALS & PLACE IN APPROPRIATE CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE >120F. EXPOSURE TO HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE BURSTING. Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING VAPORS & INHALING CONTENTS CAN BE HARMFUL OR FATAL. USE ONLY AS DIRECTED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A SELF-CONTAINED BREATHING APPARATUS REQUIRED FOR CONCENTRATIONS >TLV. Ventilation:ADEQUATE VENTILATION IS SUFFICIENT. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:40 PSIA Vapor Density:>AIR Evaporation Rate & Reference:FASTER THAN ETHER Solubility in Water:INSOLUBLE Appearance and Odor:PAINT W/SOLVENT ODOR Percent Volatiles by Volume: 85% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS & STRONG OXIDIZING AGENTS Stability Condition to Avoid:TEMPS >120F, SPARKS, PILOT LIGHT, OPEN FLAME, SOURCES OF IGNITION, HEAT & SUNLIGHT Hazardous Decomposition Products:CO2 & CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T INCINERATE AEROSOL CAN, DISPOSE OF IN ACCORDANCE W/LOCAL STATE & FEDERAL REGULATIONS. DON'T PLACE AEROSOL CANS IN HOME COMPACTOR. DON'T PUNCTURE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REFINED WAX 141 CAGE:DO735 CAGE:99252 CAGE:DO735 ============= Composition/Information on Ingredients ============= Ingred Name:CLAY TREATED PARAFFIN WAX CAS:8002-74-2 RTECS #:RV0350000 Fraction by Wt: >99% OSHA PEL:2 MG/CUM ACGIH TLV:2 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES/SKIN: THERMAL BURNS & IRRITATION. INHALATION: NAUSEA & IRRITATION OF UPPER RESPIRATORY TRACT. INGESTION: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN: THERMAL BURNS & IRRITATION. INHALATION: NAUSEA & IRRITATION OF UPPER RESPIRATORY TRACT. INGESTION: IRRITATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MIN. SKIN: COOL HOT MELTED WAX IN WATER. DON'T USE SOLVENTS, CAN BE REMOVED W/VEGETABLE/MINERAL OIL. INHALATION: REMOVE TO FRESH AIR, GIVE CPR IF NOT BREATHING. INGESTION: I F CONSCIOUS, INDUCE VOMITING BY GIVING 2 GLASSES OF WATER & STICKING A FINGER DOWN THE THROAT. DON'T GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS/CONVULSING PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:465F Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, & CO2. Fire Fighting Procedures:DON'T USE WATER STREAM TO EXTINGUISH WAX FIRES AS WATER MAY BOIL VIOLENTLY CAUSING AN EXPLOSION OF HOT WAX. Unusual Fire/Explosion Hazard:WAX MAY CATCH FIRE WHEN MELTED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ALLOW LIQUID TO COOL & SOLIDIFY. SWEEP/SHOVEL INTO DOT-APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DON'T USE PRESSURE TO EMPTY CONTAINER. DON'T GET IN EYES/SKIN OR ON CLOTHING. Other Precautions:CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE & VAPORS. ALWAYS OBEY HAZARD WARNINGS & HANDLE EMPTY CONATINERS AS IF THEY WERE FULL. ALWAYS MELT WAX OVER WATER, PREFERABLY A DOUBLE BOILER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED CANNISTER RESPIRATOR IN THE ABSENCE OF ADEQUATE ENVIRONMENTAL CONTROLS. Ventilation:LOCAL & MECHANICAL EXHAUST RECOMMENDED. Other Protective Equipment:LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES, RUBBER BOOTS, RUBBER APRON & EYEWASH/SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text: 145.4F Vapor Pres:20 Spec Gravity:0.92 Solubility in Water:INSOLUBLE Appearance and Odor:TRANSLUCENT SOLID, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS, ALL OTHER CHEMICALS & POTENTIAL SOURCES OF CONTAMINATION. Stability Condition to Avoid:OPEN FLAME & EXPOSED-COIL HOT PLATES. Hazardous Decomposition Products:CO & CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:EMPTY CONTAINERS CAN HAVE RESIDUES, GASES & MISTS THAT ARE SUBJECT TO PROPER WASTE DISPOSAL APPROPRIATE W/FEDERAL, STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAY-SILV ALUMINUM BRONZE BRAZING FLUX CAGE:IO634 CAGE:IO634 CAGE:27911 ============= Composition/Information on Ingredients ============= Ingred Name:ING 11:SHOULDER PROTECTION, AS WELL AS DARK SUBSTANTIAL CLOTHING. RTECS #:9999999ZZ Ingred Name:ZINC CHLORIDE (SARA III) CAS:7646-85-7 RTECS #:ZH1400000 Fraction by Wt: <15% OSHA PEL:1 MG/M3;2 STEL ACGIH TLV:1 MG/M3;2 STEL FUME EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BORIC ACID CAS:10043-35-3 RTECS #:ED4550000 OSHA PEL:10.0 MG/M3 ACGIH TLV:10.0 MG/M3 Ingred Name:SODIUM BORATE, DECAHYDRATE;(SODIUM TETRABORATE, DECAHYDRATE) CAS:1303-96-4 RTECS #:VZ2275000 OSHA PEL:5.0 MG/M3 ACGIH TLV:10.0 MG/M3 Ingred Name:SODIUM FLUORIDE (SARA III) CAS:7681-49-4 RTECS #:WB0350000 OSHA PEL:2.5 PPM, F ACGIH TLV:2.5 MG/M3, F EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHANOL (SARA III) CAS:67-56-1 RTECS #:PC1400000 OSHA PEL:260.0 MG/M3, S ACGIH TLV:262.0 MG/M3, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA: ALSO INFLUENCE THE COMPOSITION AND QUANTITY OF THE FUMES TO WHICH WORKERS MAY BE EXPOSED INCLUDE: (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:COATINGS ON METAL BEING BRAZED (SUCH AS PAINT, PLATING, OR GALVANIZING), AMT OF VENT, & POSITION OF THE (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OPERATOR'S HEAD W/RESPECT TO FUME. WHEN FLUX IS CONSUMED, THE FUME DECOMP PRODS GENERATED MAY BE DIFFERENT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:IN PERCENT & FORM FROM SOLID INGREDS LISTED IN ING SECTION. FUME DECOMP PRODS & NOT INGREDS IN FLUX ARE IMPORTANT. RTECS #:9999999ZZ Ingred Name:VENT:THE EMPLOYEE TO KEEP HIS HEAD OUT OF THE FUMES. SEE ANSI/ASC Z49.1-HEALTH HAZARD SECTION. RTECS #:9999999ZZ SHIELD, & MAY INCL ARM PROTECTORS, APRONS, HATS, (ING 12) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ING SECTION COVERS INGREDIENTS AND EXPOSURE LIMITS ON THE FLUXES. SEE HAZARDOUS DECOMPOSITION SECTION FOR ADDITIONAL INFORMATION. ACTUAL EXPOSURE LIMITS SHOULD BE DETERMINED BY MONITORING THE FUME IN THE OPERATOR'S BREATHING ZONE. INHALATION OF FUME. SKIN OR EYE CONTACT IS ALSO POSSIBLE. FUMES ARE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IRRITATION TO SKIN, EYES, AND THE RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM FUME EXPOSURE. IF BREATHING HAS STOPPED PERFORM ARTIFICIAL RESPIRATION. INGEST:MAY CAUSE BURNS TO DIGESTIVE SYSTEM AND/OR NAUSEA OR DIARRHEA. CALL A PHYSICIAN OR YOUR POISON CONTROL CENTER. SKIN:FLUSH WITH WATER. EYES:IMMEDIATELY FLUSH EYES FOR AT LEAST 15 MINUTES WITH PLENTY OF WATER. GET MEDICAL AID IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRES . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:OPEN FLAME AND SPARKS CAN IGNITE COMBUSTIBLES. SEE ANSI/ASC-Z49.1-1983 HAZARDOUS DECOMPOSITION SECTION. ================== Accidental Release Measures ================== Spill Release Procedures:LARGE SPILLS SHOULD BE NEUTRALIZED WITH A SLAKED LIME-SODA ASH SLURRY. FOLLOW FEDERAL, STATE, AND LOCAL REGULATIONS FOR DISPOSAL. Neutralizing Agent:LIME-SODA ASH SLURRY ======================Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN BRAZING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. Ventilation:USE ENOUGH VENTILATION TO KEEP THE FUMES BELOW TLV'S IN THE WORKERS BREATHING ZONE AND THE GENERAL AREA. TRAIN (ING 10) Other Protective Equipment:WEAR HEAD AND BODY PROTECTION WHICH HELP TO PREVENT INJURY FROM HEAT RADIATION, SPARKS, AND FLAME. SEE ANSI (ING 11) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP:FILLER METALS MAY CONTAIN CADIUM. FUME GENERATED DURING BRAZING W/CADIUM ALLOYS MAY BE TOX. CONSULT MSDS THAT PERTAIN TO THESE PRODS. FLUX FUMES CANNOT BE CLASSIFIED SIMPLY. COMPOSITION & Q UANTITY ARE DEPENDENT UPON METAL BEING BRAZED, PROCESS, PROC, & FILLER METALS BEING USED. OTHER CNDTNS WHICH (ING 6) ================== Physical/Chemical Properties ================== HCC:N1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:FLUXES ARE USED W/BRAZING FILLER METALS. WHEN MELTED, THESE FILLER METALS MAY PRODUCE FUMES WHICH ARE HAZ. (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:04257, SUPREME Preparer's Name:M. ANTOSIAK CAGE:IO244 CAGE:72008 CAGE:IO244 ============= Composition/Information on Ingredients ============= Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SODIUM METASILICATE) CAS:6834-92-0 RTECS #:VV9275000 Fraction by Wt: <40% ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY IRRITATE EYES. CHRONIC: SAME AS ACUTE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SENSITIVE SKIN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. SUPPORT BREATHING (GIVE ARTIFICIAL RESPIRATION/OXYGEN) . EYES: FLUSH THOROUGHLY WITH FRESH WATER FOR AT LEAST 15 MINUTES, GET MEDICAL ATTENTION. SKIN: FLUSH WIT H FRESH WATER, WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. INGESTION: GIVE MILK OR WATER, INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NONE Upper Limits:NONE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH SMALL AMOUNTS TO DRAIN; COLLECT AND RETURN LARGE AMOUNTS TO CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN DRY PLACE. KEEP CONTAINER COVERED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:SUFFICIENT TO KEEP DUST LEVELS AT A MINIMUM . Other Protective Equipment:NONE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.15 Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1) Solubility in Water:20% Appearance and Odor:WHITE POWDER; NO ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED MINERALS ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO WITH INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:PH ADJUSTMENT; CONTAINS PHOSPHATES. USE UNTIL LESS THAN 1 INCH REMAINS IN CONTAINER, EMPTY CONTAINER TRIPLE RINSE WITH WATER, ADD TO OPERATION. REMOVE OR DEFACE LABEL BEFORE SELLING CONTAINER OR DISPO SAL. DISP OF I/A/W FED, ST, & LOC REGS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:194 6730 KODAK RETOUCHING REMOVER CAGE:19139 CAGE:19139 CAGE:5K871 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHYLENE GLYCOL CAS:25322-68-3 RTECS #:TQ3500000 Fraction by Wt: 90-95% Other REC Limits:NONE RECOMMENDED Ingred Name:METAPHOSPHORIC ACID, HEXASODIUM SALT (CERCLA) CAS:10124-56-8 RTECS #:OY3675000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION-EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. EYES-NO SPECIFIC HAZARD KNOWN. SKIN-LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION-EXPECTED TO BE A LOW INGESTION HAZARD. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:EYES-MAY CAUSES TRANSIENT IRRITATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSISTS. EYES-ANY MATERIAL THAT CONTACTS THE EYES SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN-WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION-DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY CAUSE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health KEEP OUT OF REACH OF CHILDREN. ================== Physical/Chemical Properties ================== HCC:N1 Vapor Pres:NEGLIGIBLE Spec Gravity:>1.0 Solubility in Water:APPRECIABLE Appearance and Odor:SOLID (WAXY), WHITE, ODORLESS. Percent Volatiles by Volume:NEGLIE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:STABLE. Hazardous Decomposition Products:CARBON DIOXIDE, CRABON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE OR LOCAL LAWS. INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEGREASER HEAVY CAGE:TRGET CAGE:TRGET ============= Composition/Information on Ingredients ============= Ingred Name:COMPLEX PHOSPHATES Fraction by Wt: < 10% ACGIH TLV:2 MG/M3 (MFR) Ingred Name:POTASSIUM HYDROXIDE (SARA III) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: < 4% OSHA PEL:C, 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: < 6% OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CORROSIVE TO SKIN. MAY CAUSE PERMANENT EYE INJURY IF IN CONTACT WITH EYES. CHRONIC: SKIN CONTACT MAY RESULT IN DERMATITIS AND OR TISSUE DAMAGE. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:IRRITATION OF SKIN AND MUCOUS MEMBRANES, RESPIRATORY PROBLEMS. ======================= First Aid Measures ======================= First Aid:FLUSH SKIN WITH WATER; FLUSH LOWER EYE LIDS FOR AT LEAST 15 MIN AND GET MEDICAL ATTN IMMEDIATELY. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING. (GIVE O*2/ART RESP). INGEST: GET MD IMMED . ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, FOAM OR DRY CHEMCIAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:HYDROGEN GAS WILL BE LIBERATED FROM CONTACT WITH SOME METALS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH SMALL AMOUNTS TO DRAIN, COLLECT AND RETURN LARGE AMOUNTS TO CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP FROM FREEZING, KEEP CONTAINER CLOSED AT ALL TIMES. CORROSIVE MATERIAL. Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ALL CAUTIONS AND LABELS BEFORE USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. Ventilation:MECHANICAL (GENERAL): PRODUCING NORMAL AIR DILUTIONS. Other Protective Equipment:ALKALI RESISTANT. EMERGENCY EYE WASH AND DELUGE SHOWER . Work Hygienic Practices:USE CLEAN, SAFE, SAFETY GEAR. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:220F,104C Vapor Pres:17.5 @ 20F Spec Gravity:1.12 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:100% Appearance and Odor:BLUE-GREEN LIQUID WITH A MILD ODOR. Percent Volatiles by Volume:80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONCENTRATED MINERAL ACIDS, AND METALS SUCH AS ALUMINUM AND TIN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTACT FEDERAL, STATE, COUNTY OR LOCAL ENVIRONMENTAL REGULATOR FOR GUIDANCE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:180-5886 EKTAPRINT 2 DEVELOPER REPLENISHER PART C CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION MAY CAUSE IRRITATION MAY CAUSE RESPRATORY TRACT IRRITATION. CONTACT MAY CAUSE SKIN AND EYE IRRITATION; MAY CAUSE ALLERGIC SKIN REACTION. MAY BE HARMFUL IF INGESTED; MAY CAUSE GI TRAC T IRRITATION. CHRONIC: NONE SPECIFIED BYMANUFACTURER. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED: COUGHING, WHEEZING, SHORTNESS OF BREATH. EYES: REDNESS, TEARING, DISCOMFORT. SKIN: REDNESS, ITCHING, DISCOMFORT. INGESTED: NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. HMIS: PRE-EXISTING SKIN CONDITIONS SUCH AS DERMITITIS. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.EYES:IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.GET MEDICAL ATTENTION.SKI N:REMOVE CLOTHING.FLUSH SKIN WITH PLENTYOF WATER.INGESTION:IF CONSCIOUS,INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. CALL DOCTOR OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:ELEVATED TEMPERATURE CAN CAUSE DECOMPOSITION. FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. Neutralizing Agent:SODIUM BICARBONATE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER CLOSED. Other Precautions:USE A NON-ALKALINE-TYPE CLEANER TO WASH SKIN. SULFUR DIOXIDE GAS, A TOXIC AND IRRITATING GAS MAY BE LIBERATED FROM THIS PRODUCT; USE ONLY IN WELL-VENTILATED AREAS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS FAIL; USE NIOSH/MSHA APPROVED RESPIRATOR WITH ACID CARTRIDGE. IF RESPIRATORS ARE USED A PROGRAM IN ACCORDANCE WITH OSHA STANDARD 29CFR 1910.134 SHOULD B E ESTABLISHED. Ventilation:USE ADEQUATE MECHANICAL VENTILATION. MANUFACTURER SAYS 10 ROOM VOLUMES/HOUR. Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER, WASH FACILITY. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health KEY1=C1. MANUFACTURER DISCONTINUED PRODUCT AS OF 12/93; NSN CANCELLATION STARTED 01/94. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:18MMHG@68F Vapor Density:0.6 Spec Gravity:1.15 (WATER=1) pH:1.1 Evaporation Rate & Reference:N/K (N-BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:AMBER LIQUID WITH SHARP SULFUR DIOXIDE ODOR Percent Volatiles by Volume:60-65 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 230F. HMIS: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE, OXIDES OF NITROGEN AND SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY DISCHARGE OR DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:605302 JELTRATE PLUS REGULAR SET Preparer's Name:KELLY TAYLOR CAGE:11107 CAGE:11107 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN 1% CRYSTALLINE SILICA CAS:61790-53-2 RTECS #:HL8600000 Other REC Limits:10 MG/CUM OSHA PEL:20 MPPCF ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Other REC Limits:0.05 MG/CUM NIOSH OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.05 MG/M3 RDUST9293 Ingred Name:TETRASODIUM PYROPHOSPHATE CAS:7722-88-5 RTECS #:UX7350000 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 Ingred Name:POTASSIUM ALGINATE OSHA PEL:15 MG/CUM ACGIH TLV:10 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: CONGESTION, IRRITATION OF THE THROAT, NASAL PASSAGES & UPPER RESPIRATORY SYSTEM. EYES: TEMPORARILY IRRITATION. Explanation of Carcinogenicity:CRYSTALLINE SILICA IS A SUSPECTED A2 CARCINOGEN BY ACGIH. Effects of Overexposure:RESPIRABLE DUST FROM THIS PRODUCT MAY CONTAIN UP TO 40% FREE CRYSTALLINE SILICA (CRISTOBALITE). INHALATION: AS SUCH IT REPRESENTS A RISK TO THE RESPIRATORY SYSTEM. LONG TERM UNPROTECTED EXPOSURE TO DU ST LEVELS IN EXCESS OF THE TLV OR PEL MAY CAUSE LUNG DISEASE (SILICOSIS). Medical Cond Aggravated by Exposure:UPPER RESPIRATORY & LUNG DISEASE SUCH AS BUT NOT LIMITED TO BRONCHITIS, EMPHYSEMA, & ESTHMA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. DRINK WATER TO CLEAR THROAT & BLOW NOSE. EYES: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINUTES. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:IN COMMON W/MOST ORGANIC MATERIALS, THIS PRODUCT SHOULD BE TREATED AS A COMBUSTIBLE DUST IN THE FINELY DIVIDED & SUSPENDED STATE. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP SPILLED MATERIAL & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:OBSERVE NORMAL WAREHOUSING PROCEDURES. STORE IN A COOL DRY AREA. STORE AWAY FROM FOODSTUFFS & BEVERAGES. AVOID DUSTING WHEN IN USE. Other Precautions:THE AVOIDANCE OF ANY AIR CONTAMINANT IS ALWAYS A RECOMMENDED PRACTICE. ADHERANCE TO WORK PLACE VENTILATION STANDARDS IS AN ASSURANCE OF GENERAL PERSONNEL HEALTH & COMFORT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RECOMMENDED NIOSH APPROVED NUSIANCE DUST MASK. Ventilation:LOCAL EXHAUST REQUIRED W/MECHANICAL VENTILATION RECOMMENDED Other Protective Equipment:RUBBER APRON Work Hygienic Practices:OBSERVE NORMAL CARE WHEN WORKING W/CHEMICALS. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Spec Gravity:0.3 Solubility in Water:PARTIALLY Appearance and Odor:DRY FLUFFY POWDER W/SPEARMINT ODOR; MAY BE COLORED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID Stability Condition to Avoid:HIGH HUMIDITY & WATER CONTAMINATION WILL CAUSE MATERIAL TO GEL. PROLONGED HEAT >140F. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PRECAST POLYACRYLAMIDE ELECTROPHORESIS MINI-GELS, 6415 CAGE:IENU5 CAGE:IENU5 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLAMIDE. LD50 (ORAL, RAT): 295 MG/KG. CAS:79-06-1 RTECS #:AS3325000 < Wt:.2 OSHA PEL:0.3 MG/M3 ACGIH TLV:0.03 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM AZIDE. LD50 (ORAL, RAT): 27 MG/KG. CAS:26628-22-8 RTECS #:VY8050000 = Wt:.02 ACGIH STEL:C0.29 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM. CHRONIC: MAY CAUSE NEUROPATHY SUCH AS INCREASED SWEATING, TINGLING AND WEAKNESS IN THE HANDS AND FEET. UNSTEADY GAIT AND DECREASED REFLEXES MAY A LSO BE OBSERVED. SUSPECTED CANCER AGENT: EITHER ACUTE OR CHRONIC EXPOSURE MAY LEAD TO WEAK OR ABSENT REFLEXES. AN EARLY SIGN OF OVEREXPOSURE IS PEELING OF THE SKIN OF THE FINGERTIPS. Explanation of Carcinogenicity:ACRYLAMIDE: IARC MONOGRAPHS ON THE EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 60, PAGE 389, 1994: GROUP 2A. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998: ANTICIPATED TO BE HUMAN CARCINO GEN. Effects of Overexposure:INHALED: AIRBORNE ACRYLAMIDE IS READILY ABSORBED THROUGH THE LUNG AND OVEREXPOSURE WILL PRODUCE SIGNS OF NEUROPATHY. CONTACT WITH EYES: SODIUM AZIDE: MAY CAUSE IRRITATION. ACRYLAMIDE: MAY CAUSE CONJUN CTIVAL EYE IRRITATION. ABSORBED THROUGHSKIN: ACRYLAMIDE: READILY ABSORBED THROUGH THE SKIN. MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM. INGESTION: NEUROTOXICITY FROM A SINGLE INGESTION CAN RESULT BUT IS MORE LIKELY TO OCCUR AFTER REPEATED INGESTION OF SMALL AMOUNTS OVER A PERIOD OF SEVERAL DAYS OR WEEKS. ======================= First Aid Measures ======================= First Aid:EYE: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING THE UPPER AND LOWER LIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY REMOVE ANY CONTAMI NATED CLOTHING WITHOUT DELAY. DO NOT RE-USE CONTAMINATED CLOTHING WITHOUT RE-LAUNDERING. WASH SKIN WITH SOAP OR MILD DETERGENT AND WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DE VELOPS OR PERSISTS. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. CONSULT MEDICAL PERSONAL. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: GIVE TWO GLASSES OF WATER AND THEN INDUCE VOMI TING. (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT COMBUSTIBLE. USE WHATEVER IS NEEDED TO PUT OUT SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:N/A. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ABSORB LIQUID SPILLS WITH A DRY INERT ABSORBENT MATERIAL. DO NOT PERMIT LIQUID SPILLS TO DRY. CONTAINERIZE ABSORBED MATERIAL FOR DISPOSAL IN APPROVED WASTE FACILITY. ======================Handling and Storage ====================== Handling and Storage Precautions:RECOMMENDED STORAGE CONDITIONS: REFREIGERATED, IN THE DARK. STORAGE TEMPERATURE MAXIMUM: 60 DEG F/-15 DEC C. KEEP CONTAINER TIGHTLY SEALED TO PROTECT QUALITY. STORE AT 4-10 DEG CELSIUS. KEEP AWAY FROM HEAT SOURCES. RESPIRATORY EQUIPMENT MUST BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED WHEN SUFFICIENT VENTILATION IS PROVIDED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:GOOD ENCLOSURE AND LOCAL VENTILATION SHOULD BE PROVIDED. Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER . WEAR LAB COAT OR APRON. ON INSIDE. WASH HANDS AFTER USING & BEFORE EATING. DO NOT EAT, SMOKE OR DRINK IN WORK AREA. Supplemental Safety and Health FIRST AID PROC: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. SOL IN H*2O: UNPOLYMERIZED MATERIAL SOLUBLE IN ANY PROPORTIONS. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:SAME AS H*2O Spec Gravity:1.0 Solubility in Water:SUPDAT Appearance and Odor:CLEAR GEL AND PACKAGING BUFFER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AND REDUCING AGENTS, BRASS, ALUMINUM, COPPER, IRON AND PEROXIDES. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA AND/OR OXIDES OF NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:ACRYLAMIDE (100%): LD50 (DERMAL) RABBIT = 252 MG/KG. SODIUM AZIDE: LD50 (DERMAL) RABBIT= 20 MGKG. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE DONE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS ON SPILL REPORTING, WASTE HANDLING AND WASTE DISPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING NAME: NONE.DOT HAZARD CLASS: NOT REGULATED.DOT REPORTABLE QUANTITY: NONE. UNITED NATIONS INFORMATION: U.N. NUMBER: N/A. U.N. CLASS: N/A. ECOLOGICAL INFO (CONT): VAPORS OR MIS TS. NOTES ON EYE IRRITATION: SEVERELY IRRITATING. IF NOT REMOVED PROMPTLY, WILL INJURE EYE TISSUE, WHICH MAY RESULT IN PERMANENT DAMAGE. OTHER NOTES ON TOXICITY: SENSITIZER. RAW MATERIAL NAME: CUMEN E HYDROPEROXIDE. ORAL LD50, SPECIES TESTED: 800.0 MG/GK RAT; 382.0 MG/KG RAT. NOTES ON ORAL TOXICITY: CORROSIVE TO MOUTH, ESOPHAGUS AND STOMACH. NOTES ON DERMAL TOXICITY: CORROSIVE, CAUSES PERMANENT S KIN DAMAGE. (SARA III) ===================== Regulatory Information ===================== SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1900 AND OF 40 CFR 372: CHEMICAL NA MES: ACRYLAMIDE. CAS NUMBERS: 00079-06-1 PERCENT: <0.2%. APPROX. WT. EXPOSURE LIMITS IN AIR. 0.03 MG/M3 (SKIN). CHEMICAL NAMES: SODIUM AZIDE. CAS NUMBERS: 26628-22-8 PERCENT: 0.02%. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SEPHADEX G-50, FOR GEL FILTRATION, 20-(SUPD CAGE:60928 CAGE:60928 ============= Composition/Information on Ingredients ============= Ingred Name:SEPHADEX G-50, FOR GEL FILTRATION, 20-50 MICRON CAS:9048-71-9 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE EYE AND SKIN IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:IMMEDIATELY WASH WITH COPIOUS AMOUNTS OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. I F NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. INGEST:WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== WASTE DISPOSAL. AVIOD RAISING DUST. VENT AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMP LETE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM MOISTUARE. STORE IN A COOL, DRY PLACE. KEEP TIGHTLY CLOSED. Other Precautions:AVOID INHALATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:MECHANICAL EXHAUST HOOD. Other Protective Equipment:SAFETY SHOWER AND EYE BATH. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MFR'S TRADE NAME/PART NO:50 MICRON, 27112-8. ================== Physical/Chemical Properties ================== Appearance and Odor:WHITE POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:SENSITIVE TO MOISTURE. Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISSOLVE OR MIX MATERIAL WITH A COMBUSIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory