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===================== Product Identification ===================== Product ID:FLAW-FINDER AG-4B-FS PENETRANT Preparer's Name:GEORGE KOSEL,CHIEF CHEM CAGE:03530 CAGE:03530 ============= Composition/Information on Ingredients ============= Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA III) CAS:117-81-7 RTECS #:TI0350000 Fraction by Wt: 60.0% OSHA PEL:5 MG/M3/10 STEL ACGIH TLV:5 MG/M3; 9192 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TRIPHENYL PHOSPHATE CAS:115-86-6 RTECS #:TC8400000 Fraction by Wt: 1.0% OSHA PEL:3 MG/M3 ACGIH TLV:3 MG/M3; 9192 Ingred Name:PER MANUFACTURER'S MSDS,ITEM CONTAINS NO OTHER HAZARDOUS INGREDIENTS ACCORDING TO THE PROVISIONS GIVEN IN 29CFR1910.2000 RTECS #:9999999ZZ Fraction by Wt: BALANCE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: CAUSES IRRITATION OF EYES, SKIN, RESPIRATORY TRACT; INGESTION MAY CAUSE NAUSEA, VOMITING,ETC...INGESTION OF SMALL QUANTITIES IS USUALLY NON-FATAL UNLESS ASPIRATION OCCURS. ASPIRATION MAY LEAD T O CHEMICAL PNEUMONITIS. Explanation of Carcinogenicity:DI(2-ETHYLHEXYL)PHTHALATE IS LISTED AS AN ANIMAL CARCINOGEN, IT IS NOT LISTED AS HUMAN CARCINOGEN, PER MFR MSDS INFO. Effects of Overexposure:INHALATION: DUE TO ITS LOW VOLATILITY, EXPOSURE TO THIS MATERIAL UNDER AMBIENT CONDITIONS IS NOT EXPECTED TO PRODUCE ADVERSE HEALTH EFFECTS FOLLOWING NORMAL WORKPLACE EXPOSURE; SKIN: CAN CAUSE SLIGHT IRRITATION; EYES: MAY CAUSE IRRITATION;INGESTION:CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. Medical Cond Aggravated by Exposure:NONE CURRENTLY KNOWN. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR: SEEK MEDICAL HELP.IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOUTH. GIVE OXYGEN IF NEEDED; SKIN AND EYES: FLUSH WITH PLENTY OF WATER FOR ABOUT 15 MINUTES. SEEK MEDICAL HELP IF IRRITATION PERSISTS; INGESTION: DO NOT INDUCE VOMITING. IMMEDIATELY CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:252F/122C Extinguishing Media:REGULAR FOAM,WATER FOG,CARBON DIOXIDE,DRY CHEMICAL. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.COOL EXPOSED CONTAINERS WITH WATER SPRAY.AVOID BREATHING VAPOR OR FUMES. Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST/EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION:REMOVE IGNITION SOURCES:RECOVER FREE LIQUID;USE SUITABLE INERT ABSORBENT SUCH AS SAND,CLAY,ETC.TO ABSORB LIQUID.KEEP MATERIAL OUT OF SEWERS/WATER WAYS.LG SPILLS MAY BE P ICKED UP BY VACUUM PUMPS,SHOVELS & PLACE IN DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE BELOW 120F.DO NOT PUNCTURE OR INCINERATE CONTAINERS.DO NOT STORE OR HANDLE NEAR HEAT,SPARKS OR OXIDANTS.KEEP PLAINLY LABELED Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME,SPARKS OR OTHER SOURCES OF IGNITION;THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.DO NOT ATTEMPT TO CLE AN SINCE RESIDUE IS DIFFICULT TO REMOVE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IF NEEDED. Ventilation:GOOD,GENERAL VENTILATION IS SUFFICIENT. Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR OTHER IMPERVIOUS CLOTHING,IF NEEDED,TO AVOID CONTAMINATING REGULAR CLOTHING.EYE-WASH FAC Work Hygienic Practices:ADHERE TO GENERAL INDUSTRIAL HYGIEN PRACTICE AT THE WORKPLACE. Supplemental Safety and Health NSN IS FOR TYPE I, METHOD C, LEVEL 4 PENETRANTS OF MIL-I-25135,REV E; PER QPL-25135-15, THREE PENETRANTS SUCH AS AG-4B-FS, AG-4C-FW, AND AG-4D-FW QUALIFY FOR THIS NSN. MFRG MAY SHIP ANY ONE OF THESE T O MEET THE REQUIREMENTS.THIS ENTRY DESCRIBES AG-4B-FS;SEE PNIND- B & C FOR AG-4C-FW AND AG-4D-FW PENETRANTS RESPECTIVLY. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:440F IBP Vapor Pres:<.1MMHG@20 Vapor Density:>1.0(AIR=1 Spec Gravity:0.98 Evaporation Rate & Reference:<0.1 (N-BUAC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:YELLOW-GREEN LIQUID;MILD ODOR Percent Volatiles by Volume:>95% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENT. Stability Condition to Avoid:EXTREME HEAT Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON DIOXIDE AND/OR CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE PRODUCT SHOULD BE INCINERATED OR DISPOSED OF IN AN APPROVED DISPOSAL SITE OR FACILITY.CAN BE RECLAIMED AND RECYCLED.ASSURE CONFORMITY WITH ALL APPLICABLE LOCAL,STATE AND FEDERAL DISPOSAL REGULAT IONS.DO NOT INCINERATE EMPTY/PARTIALLY FILLED CANS
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STEARIC ACID CAGE:1B464 CAGE:1B464 CAGE:3D869 ============= Composition/Information on Ingredients ============= Ingred Name:STEARIC ACID CAS:57-11-4 RTECS #:WI2800000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) >5000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE-EYES/SKIN: MAY CAUSE IRRITATION. INHALATION: MAY CAUSE IRRITATION TO THE MUCOUS MEMBRANES, COUGHING & SORE THROAT. INGESION: LARGE DOSES MAY CAUSE NAUSEA,VOMITING & DIARRHEA. Effects of Overexposure:IRRITATION OF THE NOSE AND THROAT, COUGHING OR DIFFICULTY IN BREATHING. INGESTION OF LARGE AMOUNTS MAY RESULT IN INTESTINAL OBSTRUCTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. G ET MEDICAL ATTENTION IMMEDIATELY. INGESTION: GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:385F,196C Autoignition Temp:Autoignition Temp Text:743F Extinguishing Media:CARBON DIOXIDE, REGULAR FOAM, WATER SPRAY OR DRY CHEMICAL. Fire Fighting Procedures:NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUST. KEEP UP WIND. Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL PRECAUTIONS INDICATED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-STORE IN A COOL, DRY, VENTILATED AREA AWAY FROM OXIDIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:GRADES OF STEARIC ACID CONTAINING UNSATURATED FATTY ACIDS MAY UNDERGO SPONTANEOUS HEAT GENERATION BY OXIDATION IN AIR. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A NIOSH APPROVED DUST/MIST RESPIRATOR MAY BE WORN UP TO TEN TIMES THE TLV. CONSULT RESPIRATOR SUPPLIER FOR DETAILS. Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED. Other Protective Equipment:EYE WASH FOUNTAIN AND QUICK-DRENCH FACILITIES IN WORK AREA Work Hygienic Practices:WASH HANDS AFTER USING THIS MATERIAL. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:726F,386C Melt/Freeze Pt:M.P/F.P Text:157F,69C Vapor Pres:1 @ 173C Vapor Density:9.8 Spec Gravity:0.8 Solubility in Water:NEGLIGIBLE Appearance and Odor:HARD, WHITE TO FAINTLY YELLOW, GLOSSY CRYSTALLINE SOLID, TALLOW-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:INCLUDE TOXIC OXIDES OF CARBON ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN CONFORMITY WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 845 CHATEAU GRAY, SPREAD FLOOR OIL/ALKYD (SUPDAT) Cage: IO491 ======================================================= Contractor Summary ======================================================= Cage: 01PD6 Cage: IO491 ======================================================= Ingredients ======================================================= Cas: 1333-86-4 RTECS #: FF5800000 % Wt: 0.1-1.0 OSHA PEL: 3.5 MG/M3 ACGIH TLV: 3.5 MG/M3 ------------------------------ Cas: 136-52-7 % Wt: 0.1-1.0 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 8052-41-3 RTECS #: WJ8925000 % Wt: 30-40 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM ------------------------------ Cas: 64742-95-6 RTECS #: WF3400000 % Wt: 1-5 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 71-43-2 RTECS #: CY1400000 % Wt: 0.1 OSHA PEL: SEE 1910.1028 ACGIH TLV: 10 PPM; A2 EPA Rpt Qty: 10 LBS DOT Rpt Qty: 10 LBS ------------------------------ Cas: 14807-96-6 RTECS #: WW2710000 % Wt: 5-10 OSHA PEL: 0.2 FIBERS/CC ACGIH TLV: 0.2 FIBER/CC, A1 ------------------------------ Cas: 13463-67-7 RTECS #: XR2275000 % Wt: 5-10 OSHA PEL: 15 MG/M3 TDUST ACGIH TLV: 10 MG/M3 TDUST ------------------------------ Cas: 95-63-6 RTECS #: DC3325000 % Wt: 1-5 OSHA PEL: 25 PPM ACGIH TLV: 25 PPM ------------------------------ Cas: 1330-20-7 RTECS #: ZE2100000 % Wt: 1-5 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM/150 STEL EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 66070-62-0 PHTHALIC ANHYDRIDE % Wt: 40-50 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ RTECS #: 9999999VO OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- PG 120, 1987: GROUP 1. NTP 7TH ANNUAL ----------------------------- PG 34460, 1987: OSHA-CANCER HAZ. HUMAN: ----------------------------- MONO ON EVAL OF CARCIN RISK OF ----------------------------- ----------------------------- INCL TOX TO LIVER, KIDNEY, BLOOD, HEART, ----------------------------- THERE IS SUFFICIENT EVID FOR CARCIN OF ----------------------------- DETERM BENZENE IS KNOWN TO BE CARCIN. ----------------------------- RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/ ----------------------------- & INHALING CONTENTS MY BE HARMFUL/FATAL. ----------------------------- (GROUP 2B) BASED ON SUFFICIENT EVID IN ----------------------------- INFORMATION CONT NEHC (FP N). ----------------------------- IMMED 2/LG AMTS OF WATER, ESPECIALLY UNDER ----------------------------- TREATMENT. INGEST: OBTAIN MED TREATMENT IMMED. ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: YES IARC: YES OSHA: YES Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO MUC MEMB IRRIT, FATG, DROW, DIZZ AND/OR LT HEAD, HDCH, UNCOORDINATION, NAUS, VOMIT, COUGH, CNS DEPRESS, ANESTH EFT/NARCOS, ALLERGIC RESPONSE , PNEUMOCONIOSIS, LOSS OF CONSCIOUSNESS, ASPHYX, DEATH. SKIN: IRRIT. PRLNGD/RPTD CONT CAN CAUSE DERM, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: CONTAINS 2-A [53-96-3] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Signs And Symptions Of Overexposure: HLTH HAZ: DEFAT, ALLERGIC RESPONSE. EYE: IRRIT. PRLNGD/RPTD CONT CAN CAUSE CONJ, BLURRED VISION, TEARING, REDNESS, SEV IRRIT. INGEST: MAY CAUSE LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS, FATG , DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORDINATION, NAUS, VOMIT, DIARR, GI DISTURB, CNS DEPRESS, ANESTH EFT/NARCOS, Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS LUNG DISORDERS ASTHMA-LIKE CONDITIONS. First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED HELP FOR ANY BRTHG DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE WATER TING, HDCHS, DIZZ/OTHER DISCOMFORT. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP & WATER. REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. DISPOSE OF CONTAMD LEATHER ITEMS, SUCH AS SHOES ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRONMENTAL REGS. ELIM ALL SOURCES OF IGNIT. VENTILATE AREA. EVAC ALL UNNEC PERS. PLACE COLLECTED MATL IN PROPER CNTNR. COMPLETE PERSONAL PROT EQUIP MUST BE USED DURING CL EANUP. FOR MORE INFORMATION CONT NEHC (FP N). Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. Handling And Storage Precautions: STORE <100F. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. Other Precautions: AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING/ABRADING(SANDING)PAINTED SUR FS. FOR MORE INFO CONT NEHC (FP N). ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 105F,41C Extinguishing Media: DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT/FIRE. VAPS ARE HVR/AIR & MAY TRAVEL LONG DIST TO SOURCE OF IGNIT & FLASH BACK. VAPS CAN FORM EXPLO (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROAL ENVIRONMENTAL CONCS BELOW APPLIC STDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPRVD RESPIRATORS I/A/W OSHA STANDARD 29 CFR 1910.134. Ventilation: PROVIDE DILUTION VENT/LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). IMPERVIOUS CLOTHING, FACE SHIELD, APRON BOOTS. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health: MFR TRADE NAME/PART NO: ENAMEL 840 SERIES. EXPLO HAZ: MIX IN AIR @ ELEVATED TEMPS. CLSD CNTNRS MAY BURST IF EXPOS TO EXTREME HEAT/FIRE. MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING IRRITANT AND/OR TOXIC G ASES. MATLS TO AVOID: PERFORMIC ACID BROMINE PENTAFLUORIDE. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >155F,>68C Spec Gravity: 1.02 (FP N) Evaporation Rate & Reference: NOT KNOWN Solubility in Water: NOT KNOWN Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 54.43 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: SUNLIGHT, ELEVATED TEMPERATURES, CONT W/OXIDIZING AGENTS, CONT W/ALUMINUM OR ZINC, SPARKS, OPEN FLAME. IGNIT SOURCES. Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, ALUMINUM, ZINC, PEROXIDES, NITRIC ACID, MAGNESIUM, SODIUM POTASSIUM. HYDRAZINE (SUPDAT) Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF SULFUR, OXYGEN, ALDEHYDES, TOXIC GASES. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 845 CHATEAU GRAY, SPREAD FLOOR OIL/ALKYD (SUPDAT) Cage: IO491 Assigned IND: Y Company Name: ICI PAINTS Street: 925 EUCLID AVE Zipcode: 44115 Label Required IND: Y Date Of Label Review: 02/03/1998 Status Code: C Label Date: 02/03/1998 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Moderate Reactivity Hazard: None Hazard And Precautions: COMBUSTIBLE. ACUTE: INHAL: IRRITATION OF RESPIRTORY TRACT. PRLNGD INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, FATIGUE, DROWSINESS, DIZZ AND/OR LT HEAD, HEADACHE, UNCOORDINATION, NAUSEA, VOMITIN G, COUGHING, CNS DEPRESSION, ANESTH EFT/NARCOS, PNEUMOCONIOSIS, LOSS OF CONSCIOUSNESS, ASPHYX, DEATH. SKIN: IRRITATION. EYES: IRRITATION, POSSIBLY SEVERE. INGEST: CNS DEPRESSION, NAUSEA, VOMITING, DIA RRHEA. CHRONIC: CANCER HAZARD. CONTAINS COBALT & BENZENE WHICH ARE LISTED AS ANIMAL & HUMAN BLOOD CARCINOGENS & CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). INHAL/SKIN: ALLERGIC R ESPONSE. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PERMALITE BLOCKFILL Preparer's Name:V.B. SAY CAGE:52293 CAGE:52293 ============= Composition/Information on Ingredients ============= Ingred Name:PERLITE; (PERLITE, EXPANDED). (MAY CONTAIN ING 2) CAS:93763-70-3 RTECS #:SD5254000 Fraction by Wt: >98% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <0.1% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:TRANSITORY UPPER RESPIRATORY IRRITANT. INHAL:COUGHING, IRRITATION OF NOSE & THROAT; CONGESTION MAY OCCUR UPON OVEREXPOSURE. EYES:TEMPORARY IRRITATION &/OR INFLAMMATION. CHRONIC:INHALATION OVER L ONG PERIODS OF HIGH AMOUNTS OF ANY NUISANCE DUST MAY OVERLOAD LUNG CLEARANCE MECHANISM & MAKE LUNGS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:MORE VULNERABLE TO RESPIRATORY DISEASE. TARGET ORGAN(S): LUNGS. Medical Cond Aggravated by Exposure:PRE-EXISTING UPPER RESPIRATORY & LUNG DISEASE (SUCH AS BRONCHITIS, EMPHYSEMA, ASTHMA OR OTHERS). ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL:REMOVE FROM DUSTY AREA; DRINK WATER TO CLEAR THROAT; BLOW NOSE TO EVACUATE DUST. EYES:DO NOT RUB EYES. F LUSH W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES TO REMOVE ANY DUST PARTICLES. CONSULT MD IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM CLEAN OR WET SWEEP; AVOID DUSTING; USE A DUST SUPPRESSANT WHEN SWEEPING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:ALWAYS SEGREGATE MATERIALS BY MAJOR HAZARD CLASS. STORE IN DRY PLACE. REPAIR ALL BROKEN BAGS IMMEDIATELY. AVOID CREATING DUST. Other Precautions:FOLLOW THE SAFE HANDLING PRACTICES SHOWN ON THE PRODUCT BAG LABEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EVEN THOUGH PERLITE IS A NUISANCE DUST, WE RECOMMEND THE USE OF NIOSH/MSHA APPROVED RESPIRATORS TO PROTECT AGAINST SILICOSIS PRODUCING DUSTS. INSURE PROPER NIOSH/MSHA APPRVD RESP PROT FOR REPAIR/MAINTOF CONTAM EQUIP. Ventilation:ADEQUATE VENTILATION & APPROPRIATE LOCAL EXHAUST WHERE NEEDED TO KEEP DUST LEVELS BELOW PEL. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:MAINTAIN GOOD HOUSEKEEPING PRACTICE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Spec Gravity:2.35 (H*2O=1) Solubility in Water:SLIGHT Appearance and Odor:DRY, WHITE POWDER; ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/HYDROFLUORIC ACID. Stability Condition to Avoid:NONE IN DESIGNED USE. Hazardous Decomposition Products:REACTS W/HYDROFLUORIC ACID TO FORM TOXIC SILICON TETRAFLUORIDE GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . NOT CONSIDERED AS HAZARDOUS WASTES BY RCRA (40 CFR 261). PLACE WASTE & SPILLAGE IN CLOSED CONTAINERS. DISPOSE OF IN APPROVED LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SPRAYLAT SC-1058T CAGE:87354 CAGE:87354 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0.5-15% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SUPDAT:CUTTING ON SURFACES COATED WITH THIS MATERIAL. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:RESIDUAL VAPORS MAY BE IRRITATING TO EYES. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. DIRECT EYE CONTACT MAY CAUSE IRRITATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND CONSULT MD. SKIN:WASH THOROUGHLY WITH SOAP AND WATER, IF DRENCHED REMOVE AND WASH CLOTHING BEFORE REU SE. INGEST:IF VICTIM IS CONSCIOUS, INDUCE VOMITING AT ONCE BY GIVING 2 GLASSES OF WATER TO DRINK AND PLACE FINGER AT BACK OF THROAT. CALL MD IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE INEFT. WATER AY BE USED TO COOL CLSD CONTRS TO PREV PRESS (SUPDAT) Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:DIKE AND CONTAIN SPILL WITH INERT MATERIAL AND TRANSFER MATERIAL TO CONTAINERS FOR RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWER AND OPEN BODIES OF WATER. FLOORS MAY BE SLIPPERY. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT FREEZE. HANDLE AS A COMBUSTIBLE LIQUID. GROUND ALL CONTAINERS WHEN POURING. Other Precautions:KEEP FROM FREEZING. PRODUCT STABILITY MAY BE AFFECTED. MATERIAL CONTAINS WATER AND IS ELECTRICALLY CONDUCTIVE. DO NOT APPLY BY ELECTROSTATIC SPRAY EQUIPMENT UNLESS EQUIPMENT IS MODIFIED AND INTENDED F OR APPLICATION OF CONDUCTIVE COATINGS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN OUTDOOR AREAS USE NIOSH/MSHA APPROVED MECHANICAL FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLICATION. IN RESTRICTED VENT AREAS USE NIOSH/MSHA APPROVED CHEM-MECH FIL TER DESIGNED TO REMOVE A COMBO (SUPDAT) Ventilation:PROVIDE GENERAL DILUTION/LOC EXHAUST VENT IN VOLUME & PATTERN TO KEEP TLV OF MOST HAZ INGRED BELOW ACCEPTABLE (SUPDAT) Other Protective Equipment:USE APRON WHERE CONTACT IS LIKELY AND CREAM IF SKIN CONTACT IS LIKELY. Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH HANDS AFTER USE. Supplemental Safety and Health FIRE FIGHT PROC:BUILD UP & EXPLOS. IF WATER IS USED FOG NOZZ ARE PREF. HAZ DECOMP PROD:MONOXIDE IN ABSENCE OF OXYGEN. RESP PROT: OF PARTICULATE & VAP. IN CONFINED AREAS USE NIOSH/MSHA APPRVD AIR LINE TYPE RESP/HOODS. VENT:LIM TO KEEP LEL BELOW STATED LIM & TO REMOVE DECOMP PRODS FORMED DURING WELDING/FLAME (ING 2) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Spec Gravity:8.7 Solubility in Water:SOLUBLE Appearance and Odor:LIQUID COATING ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:KEEP FROM FREEZING. Hazardous Decomposition Products:DRY SOLID AT 100C EXPOS FOR SEV HRS MAY RESULT IN RELEASE OF ORGANIC ALDEHYDES AND ALSO ORGANIC ACIDS & CARBON (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL CONTROL REGULATIONS. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILICONE PASTE, VP 1164 CAGE:D2650 CAGE:D2650 ============= Composition/Information on Ingredients ============= Ingred Name:POLYSILOXANE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:FILLERS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYE CONTACT: SLIGHT IRRITATION POSSIBLE. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES:IF THE PRODUCT HAS GOT INTO THE EYES, FLUSH WITH POTABLE WATER FOR A MINIMUM OF 15 MINUTES; IF IT DOES NOT APPEAR ON SHORT TERM, CALL A DOCTER. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOAM, HALONES, CO*2, DRY EXTINGUISHING MEDIA. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NON-OXIDIZING, RESISTANT TO WEAK CAUSTIC LYES, ACIDS AND RADIATIONS, HARDLY FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT AND REMOVE ACCORDING TO REGULATIONS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEPS FOR MANY YEARS. Other Precautions:SILICON PASTES ARE NON-TOXIC AND PHYSIOLOGICALLY INERT; THEY FORM NO CULTURE MEDIUM FOR MICRO-ORGANISMS AND CAN ALSO BE USED IN THE TROPICS UNDER DAMP CONDITIONS. BIOLOGICALLY NON-DEGRADABLE; TOXICITY TO FISH IS NOT DETECTABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:NONE SPECIFIED BY MFR. Work Hygienic Practices:NORMAL CLEANNESS IN HANDLING THE SILICONES PASTES IS SUFFICIENT. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Vapor Density:1.0 Solubility in Water:INSOLUBLE Appearance and Odor:OPAQUE PASTE. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS, FOR EXAMPLE SPECIAL REFUSE DUMP, BURNING OR REGENERATING.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HYSOL 50-100 R (XX0349) CAGE:HO354 CAGE:12405 CAGE:HO354 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-(2-ETHOXYETHOXY)-, ACETATE; (DIETHYLENE GLYCOL MONOETHYL ETHER ACETATE) CAS:112-15-2 RTECS #:KK8925000 Fraction by Wt: 1-15% Ingred Name:BISPHENOL A RESIN; (BPA) CAS:8005-70-0 Fraction by Wt: 1-15% Ingred Name:PHENOL, 4,4'-ISOPROPYLIDENEDI-, POLYMER WITH 1-CHLORO-2,3-EPOXYPROPANE; (BISPHENOL A EPICHLOROHYDRIN POLYMER) CAS:25068-38-6 RTECS #:SL6475000 Fraction by Wt: 15-35% Ingred Name:DIPROPYLENE GLYCOL, MONOMETHYL ETHER. LD50:(ORAL,RAT)5.4 ML/KG. CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: 1-15% OSHA PEL:100 PPM ACGIH TLV:100PPM;150PPM STEL,S Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYL ETHYL ESTER; (PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE). LD50:(ORAL,RAT)8535 MG/KG. CAS:108-65-6 RTECS #:AI8295000 Fraction by Wt: 1-15% OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:MOD TO SEVERE IRRIT,BURNING,TEARING, REDNESS, SLIGHT CORNEAL INJURY POSS. HEATED MATL CAN CAUSE THERMAL BURNS. SKIN:IRRIT, RPTD/PRLNGD CNTCT MAY CAUSE REDNESS, BURNING, DRYING, CRACKING, MILD SENS IT, ALLERGIC RXN, RASH, HIVES. HEATED MATL CAN CAUSE THERMAL BURNS. INHAL:HIGH VAP/MIST CONC MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IRRIT OF NOSE/THROAT, COUGH,SORE THROAT, SNEEZING, KIDNEY/LIVER DMG, ANESTHETIC/NARCOTIC EFT. RPTS ASSOC OVEREXPOS TO SOLV W/PERM BRAIN & CNS DMG. INTENTIONAL MISUSE BY INHAL PROD MAY BE HARM FUL/FATAL. INGEST:MAY CAUSE CRAMPS, DIARRHEA. EXCESSIVE QTY MAY CAUSE CNS DEPRESS, DROWS, DIZZ, LOSS OF COORD, FATIGUE. Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, KIDNEY OR LUNG DISORDERS MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH W/WATER IMMED FOR AT LEAST 15 MIN, HOLDING LIDS OPEN. SEE MD. SKIN:REMOVE CONTAMD CLTHG IMMED & WASH BEFORE REUSE. WIPE EXCESS FROM SKIN & WASH THORO W/SOAP & WATER. IF IRRIT OCCURS, SEE MD. DO NOT PULL CLTHG IF STUCK TO THERMAL BURNS. INGEST:INDUCE VOMIT IF LG AMT INGESTED. IF DROWSY/UNCON, PLACE ON LEFT SIDE W/HEAD DOWN & DO NOT GIVE ANYTHING BY MOUTH. SEE MD IMMED. (SUPP DATA) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:145F,63C Extinguishing Media:CARBON DIOXIDE, FOAM OR DRY CHEMICALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DO NOT STORE OR MIX WITH STRONG OXIDANTS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. COVER SPILL W/ABSORBENT MATERIAL & REMOVE TO WASTE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CNTNRS IN COOL, DRY AREA AWAY FROM HEAT, SPARKS & OPEN FLAMES. USE ONLY WITH ADEQUATE VENTILATION. Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS OR CONTACT WITH SKIN. DISCARD CONTAMINATED LEATHER ARTICLES (SHOES, BELTS, ETC.). ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR PROPERLY FITTED NIOSH/MSHA APPROVED SCBA/INDUSTRIAL TYPE CANISTER MASK IN ENCLOSED AREA W/POOR/NO VENT SYSTEM. IF AIR CONTAM SUSPECTED, CONTAM SHOULD BE VERIFIED BY AIR MONITORING BEFORE SELECTIO N OF RESPIRATOR IS MADE. Ventilation:LOCAL EXHAUST PREFERRED. MECHANICAL ACCEPTABLE. Other Protective Equipment:HYDROCARBON INSOLUBLE APRONS, EYE WASH AND SAFETY SHOWER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC:NOTE TO MD:NO ANTIDOTE. SUPPORTIVE CARE. ================== Physical/Chemical Properties ================== HCC:V4 Boiling Pt:B.P. Text:>320F,>160C Vapor Pres:<0.1 Vapor Density:4.8 Spec Gravity:1.41 Appearance and Odor:WHITE, HIGH VISCOSITY LIQUID. MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:HIGH TEMPERATURE AND OPEN FLAME. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CO AND CO*2. ==================== Disposal Considerations ==================== Waste Disposal Methods:SHOULD BE I/A/W FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:QUICK DRY ENAMEL, F77N20 CONTAINER BROWN CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:MESITYLENE; (1,3,5-TRIMETHYLBENZENE) VP: 10 CAS:108-67-8 RTECS #:OX6825000 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA 313) VP: 2 CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: 2% OSHA PEL:25 PPM ACGIH TLV:25 PPM Ingred Name:VOLATILE ORGANIC COMPOUND: 4.87 LBS/GAL RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HNDLG/STOR PRECS: GONE:KEEP AREA VENTD - DO NOT SMOKE - EXTING ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PREC: (LISTED "AS DUST" IN INGREDS) WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT: NIOSH FOR PROT AGAINST NON-VOLATILE MATERIALS IN INGREDIENT SECTION. RTECS #:9999999ZZ Ingred Name:NAPHTHOL SPIRITS; (VM&P NAPHTHA) VP: 12 CAS:64742-48-9 Fraction by Wt: 11% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA 313) (CERCLA) VP: 22 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 23% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313)VP: 7.1 CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 3% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA)VP: 5.9 CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 20% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT AROMATIC HYDROCARBON) VP: 3.8 CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MIS TS. REDNESS & ITCH OR BURNING SENSATIONINDICATE EYE/EXCESS SKIN EXPOS. CHRONIC: TOLUENE APPEARS ON THE(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . PRLNGD OVEREXP TO SOLVS LISTED IN INGRE D SECTION MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR & REPRO SYS. RPTS HAVE ASSOC (SUPDAT) Medical Cond Aggravated by Exposure:GET MEDICAL ATTENTION. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:35.0F,1.7C Lower Limits:0.7% Upper Limits:6.3% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURFS (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE FLAM. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS. DURING USE & UNTIL ALL VAPS ARE (ING 9) Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. COATING MAY CNTN MATLS CL ASSIFIED AS NUISANCE PARTICULATE(ING 12) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR PROPERLY FITTED, NIOSH APPRVD, ORG VAP/PARTICULATE RESP. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING OR WELDING DRIED FILM, WEA R PARTICULATE RESP APPRVD BY (ING 15) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED BELOW APPLIC LIM. REFER TO OSHA STDS 1910.94,1910.107,1910.108. Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ: REQS SPEC PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE I MMED APPARENT. OBTAIN MED ATTN. EFTS OFOVEREXP: RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS SYS DAMAGE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>222F,>106C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.94 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:68-73 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERM APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE OF I/ A/W FED, STATE & LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PEPTON 76 PLASTICIZER CAGE:70361 CAGE:70361 ============= Composition/Information on Ingredients ============= Ingred Name:ACRYLAMINO DIARYL DISULFIDE Ingred Name:METALLIC FATTY ACID SOAP Ingred Name:INERT CARRIER ===================== Hazards Identification ===================== Effects of Overexposure:NONE EXPECTED ======================= First Aid Measures ======================= First Aid:ORDINARY PERSONAL HYGIENE MEASURES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO*2,DRY CHEMICAL,WATER. Fire Fighting Procedures:DO NOT USE HIGH-PRESSURE WATER STREAM Unusual Fire/Explosion Hazard:AIR-BORNE DUST CREATES AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP AND PLACE IN A WASTE DISPOSAL CONTAINER,FLUSH AREA WITH WATER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH EXPOSURE OF CONCERN. Ventilation:LOCAL Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIGHT-BLUE,FREE FLOWING POWDER;SLIGHT SOAP-LIKE OD ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE IWHT LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:JANTON CHLORO CLEAN CREME CLEANSER CAGE:FO056 CAGE:FO056 CAGE:79833 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS FOR INGREDIENTS Fraction by Wt: 100% ===================== Hazards Identification ===================== Effects of Overexposure:SEVERE EYE IRRITANT. HARMFUL IF SWALLOWED. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FLUSH WITH WATER AND GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INGESTION: GIVE RAW EGG WHITE, MUCILAGE, OR CORNSTARCH. CALL PHYSICIAN IMMEDIATELY. _ ===================== Fire Fighting Measures ===================== Flash Point:NONE Fire Fighting Procedures:PRODUCT IS A WATER MIXTURE. Unusual Fire/Explosion Hazard:WILL NOT BURN OR EXPLODE ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP WITH DAMP CLOTH & RINSE. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE NEEDED Other Precautions:WARNING: KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:PRODUCT HAS PH OF 1.5 APPROX, AND IS NOT CONSIDERED HAZARDOUS. Ventilation:LOCAL EXHAUST NORMAL VENTILATION SATISFACTORY Other Protective Equipment:NONE NEEDED Supplemental Safety and Health MSDS UNDATED. PH: 1.5. PRODUCT IS A MILD CLEANER CONTAINING SILICA SAND, NON-IONIC DETERGENTS, WINTERGREEN FRAGRANCE AND MD OXYGEN-TYPE BLEACH. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Spec Gravity:1.25 Evaporation Rate & Reference:NONE Solubility in Water:EXCELLANT Appearance and Odor:WHITE IN COLOR - MINT FRAGRANCE. Percent Volatiles by Volume:60.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DON'T REUSE EMPTY CONTAINER. RINSE CONTAINER AND PUT IN TRASH COLLECTION.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:SPRAY ON II CAGE:RCHCO CAGE:RCHCO ============= Composition/Information on Ingredients ============= Ingred Name:SILICIC ACID (H2SI03), DISODIUM SALT;(SODIUM METASILICATE) CAS:6834-92-0 RTECS #:VV9275000 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE:REDNESS, IRRITATION. INGEST:MAY IRRITATE MUCOUS MEMBRANES. POSSIBLE VOMITING OR DIARRHEA MAY OCCUR. ACUTE/CHRONIC:NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NOT KNOWN. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF PERSISTENT IRRITATION OCCURS, CALL MD. SKIN:WASH THOROUGHLY WTH SOAP & WATER. INGEST:INDUCE VOMITING BY STICKING FINGER DOWN THROAT. INHAL:REMOVE TO FR ESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:TO BOILING Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE KNOWN. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB WITH SUITABLE ABSORBENT. FOR LARGE SPILLS, ABSORB WITH SUITABLE ABSORBENT, THEN SHOVEL INTO CONTAINERS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES, AND CLOTHING. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED UNDER NORMAL CONDITIONS OF USE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:MAY BE NEEDED IF SPLASHING OR SPRAY DRIFT OCCURS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH:12.5 +/- 0.5. ================== Physical/Chemical Properties ================== HCC:C2 Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.060 +/- 0.005 pH:SUPDAT Evaporation Rate & Reference:AS WATER Solubility in Water:COMPLETE Appearance and Odor:LIQUID, PRACTICALLY ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ANIONIC COMPOUNDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO & OTHER UNIDENTIFIED ORGANIC GASES MAY OCCUR DURING INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, AND LOCAL ORDINANCES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:LITHIUM/MANGANESE DIOXIDE BATTERY CAGE:4M310 CAGE:4M310 ============= Composition/Information on Ingredients ============= Ingred Name:LITHIUM (METAL) CAS:7439-93-2 RTECS #:OJ5540000 Other REC Limits:NONE RECOMMENDED Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Other REC Limits:NONE RECOMMENDED OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3; 9495 Ingred Name:GRAPHITE, NATURAL CAS:7782-42-5 RTECS #:MD9659600 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MPPCF; Z-3 ACGIH TLV:2 MG/M3 RDUST; 9495 Ingred Name:TEFLON Other REC Limits:NONE RECOMMENDED Ingred Name:PROPYLENE CARBONATE CAS:108-32-7 RTECS #:FF9650000 Other REC Limits:NONE RECOMMENDED Ingred Name:DIMETHOXY ETHER Other REC Limits:3 PPM INDUSTRY STD. Ingred Name:LITHIUM TRIFLUOROMETHANE SULFONATE CAS:33454-82-9 Other REC Limits:0.1 MG/M3 (3M) ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:THESE CHEMICALS ARE CONTAINED IN A SEALED CAN. RISK OF EXPOSURE OCCURS ONLY IF BATTERY IS ABUSED. MOST LIKELY RISK IS ACURE EXPOSURE WHEN CELL VENTS. CONTACT W/ELECTROLYTE & EXTRUDED LITHIUM W/SKIN OREYES SHOULD BE AVOIDED. INHALATION OR INGESTION OR LITHIUM TRIFLUOROMETHANE FULFONATE MAY BE HARMFUL. Explanation of Carcinogenicity:MFR GAVE THE ABOVE LISTINGS ON THE MSDS BUT NO OTHER COMMENTS WERE RECORDED ON THE MSDS. Effects of Overexposure:IRRITATION OF SKI OR EYES. LITHIUM CAN CAUSE THERMAL & CHEMICAL BURNS ON CONTACT W/SKIN. DME MAY BE A REPRODUCTIVE HAZARD. Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT GENERALLY AGGRAVATE ANY MEDICAL CONDITION. ======================= First Aid Measures ======================= First Aid:IN CASE OF SKIN CONTACT W/CONTENTS OF BATTERY, FLUSH IMMEDIATELY W/WATER. FOR EYE CONTACT FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MIN. DO NOT INHALE VENTED MATERIAL. IF IRRITATION PERSISTS, GET MEDICA L HELP. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER Fire Fighting Procedures:THE PREFERRED PROCEDURE IS TO RAPIDLY COOL THE BATTERIES & ADJACENT STRUCTURES W/WATER. Unusual Fire/Explosion Hazard:CELLS CAN VENT WHEN SUBJECTED TO EXCESSIVE HEAT. WHEN LARGE NUMBERS OF CELLS ARE INVOLVED IN A FIRE, FIRE FIGHTERS SHOULD USE SELF-CONTAINED BREATHING APPARATUS ================== Accidental Release Measures ================== Spill Release Procedures:THE PREFERRED RESPONSE IS TO LEAVE THE AREA & ALLOW BATTERIES TO COOL & VAPORS TO DISSIPATE. AVOID SKIN & EYE CONTACT OR INHALATION OF VAPORS. REMOVE SPILLED LIQUID W/ABSORBENT & INCINERATE. CLEAN UP CREW SHOULD WEAR FULL FACE RESPIRATOR. Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID MECHANICAL OR ELECTRICAL ABUSE. Other Precautions:BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF DISASSEMBLED, CRUSHED, RECHARGED OR EXPOSED TO FIRE OR HIGH TEMPERATURE. DO NOT SHORT OR INSTALL W/INCORRECT POLARITY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS FOR FIRE; FULL FACE RESPIRATOR W/PARTICULATE/ORGANIC CARTRIDGE FOR SPILL. Ventilation:IN CASE OF VENTING, PROVIDE AS MUCH VENTILATION AS POSSIBLE. Other Protective Equipment:NONE Work Hygienic Practices:MFR:? HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICES. MINIMIZE CONTACT & WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MFR GAVE NO INFORMATION ON MSDS. Stability Condition to Avoid:DO NOT HEAT, DISASSEMBLE OR RECHARGE. Hazardous Decomposition Products:MFR GAVE NO INFORMATION ON MSDS. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W APPROPRIATE REGULATIONS. OPEN CELLS SHOULD BE TREATED AS HAZARDOUS WASTE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STAR SOLV CAGE:IO406 CAGE:IO406 CAGE:0C3Y2 ============= Composition/Information on Ingredients ============= Ingred Name:THERE ARE NO HAZARDOUS COMPONENTS. Fraction by Wt: NA Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. CHRONIC: PROLONGED/REPEATED EXPOSURE CAN CAUSE DRYING, DEFATTING, DERMATITIS OF SKIN. Effects of Overexposure:INGESTION: MAY CAUSE VOMITING, HEADACHE, OTHER MEDICAL PROBLEMS. SKIN: SLIGHT REDNESS. EYES: CAN CAUSE MODERATE TO HIGH IRRITATION. INHALATION: CAN CAUSE NOSE, THROAT, RESPIRATORY TRACT IRRITATION, CO UGHING, HEADACHE. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER >15 MINUTES. IF IRRITATION PERSISTS SEE DR. INGESTION: DO NOT INDUCE VOMITING. GIVE 1 GLASS OF WATER. CALL DR IMMEDIATELY. INHALATION: GET FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:149F,65C Lower Limits:0.7 Upper Limits:6.1 Extinguishing Media:FOAM, CO2, DRY CHEMICAL. Fire Fighting Procedures:SCBA RECOMMENDED. HANDLE AS AN OIL FIRE. CLASS B FIRE PROCEDURES. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT, OPEN FLAME. GUARD AGAINST SPONTANEOUS COMBUSTION OF IMPROPERLY DISCARDED RAGS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: WIPE UP. LARGE SPILLS: ABSORB BY DIRT, SAND, OTHER SUITABLE ABSORBENTS FOR DISPOSAL. DO NOT HOSE SPILLS DOWN DRAINS/SEWERS/WATERWAYS. MAY BE TOXIC TO AQUATIC ORGANISMS. ======================Handling and Storage ====================== Handling and Storage Precautions:USUAL PRECAUTIONS FOR COMBUSTIBLE LIQUIDS. STORE IN SPRINKLED WAREHOUSE. STORE IN TIGHTLY SEALED FULL CONTAINERS. Other Precautions:OPEN CONTAINER CAREFULLY IF PRODUCT APPEARS TO BE UNDER PRESSURE. CAUTION: DO NOT WELD OR CUT EMPTY CONTAINERS. VAPORS MAY IGNITE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT RECOMMENDED BUT IF VAPOR CONCENTRATION BECOMES HIGH USE SELF-CONTAINED AIR MASK, NIOSH APPROVED. Ventilation:USE LOCAL EXHAUST Other Protective Equipment:EMERGENCY EYEWASH & STATIONS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:150F,66C Melt/Freeze Pt:M.P/F.P Text:NA Vapor Pres:2.0 @ 68F Vapor Density:NA Spec Gravity:0.9058 Evaporation Rate & Reference:<1.0 (BUAC=1) Solubility in Water:100% COMPLETE Appearance and Odor:YELLOW COLOR, CITRUS ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS & ACIDIC AGENTS. Stability Condition to Avoid:EXCESSIVE HEAT. Hazardous Decomposition Products:SMOKE MAY BE ACRID & FUME IRRITATING. BURNING GENERATES CO2, CO, SMOKE. Conditions to Avoid Polymerization:POLYMERIZATION CATILISTS SUCH AS ALUMINUM CHLORIDE & ACIDIC CLAYS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE OR DISPOSE IN ACCORDANCE W/LOCAL, STATE, FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PURE LEAD CAGE:9N315 CAGE:9N315 ============= Composition/Information on Ingredients ============= Ingred Name:LEAD (SARA III) CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: >99.9% OSHA PEL:SEE 1910.1025 ACGIH TLV:0.15 MG/M3,DUST EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:OTHER PRECAUT:OR LAUNDERED W/PERSONAL CLTHG. LAUNDER CONTAMD CLTHG BEFORE REUSE. WASH HANDS, FACE, NECK & ARMS (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:THORO BEFORE EATING, DRINKING/SMOKING. THIS PROD IS INTENDED FOR INDUS USE ONLY & SHOULD BE ISOLATED (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:FROM CHILDREN AND THEIR ENVIRONMENT. RTECS #:9999999ZZ Ingred Name:RESP PROT:LOCAL AND STATE REGULATIONS MAY ALSO APPLY. RTECS #:9999999ZZ Ingred Name:VENT:HYGIENISTS, SHALL BE PROVIDED IN AREAS WHERE EXPOS ARE ABOVE PEL/THRESHOLD LIM VALUES SPECIFIED BY OSHA (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:OR OTHER LOCAL, STATE AND FEDERAL REGULATIONS. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP:DISPOS OF I/A/W LOCAL, STATE & FED REGS. HARD HAT, SFTY BOOTS & OTHER SFTY EQUIP SHOULD BE WORN (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:AS APPROP FOR INDUS ENVIRON. PERSON CLTHG & SHOES SHOULD BE PROTECT FROM CONTAMINATION W/THIS PRODUCT. RTECS #:9999999ZZ Ingred Name:HYGIENE PRAC:NON-CONTAMINATED AREAS. RTECS #:9999999ZZ Ingred Name:SUPDAT:REPROD HAZARDS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZARD LSIT INFO AND (ING 12) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 11:SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:OCCUP EXPOS TO LEAD (29CFR 1910.1925). RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IF LEFT UNTREATED:WEAKNESS, VOMIT, LOSS OF APPETITE, UNCOORDINATED BODY MOVEMENTS, CONVULSIONS, STUPOR & POSSIBLY COMA. INHAL:DUST, VAP AND/OR FUME MAY BE IRRITATING TO RESP SYS & CAN RSLT IN BO TH ACUTE & CHRONIC OVEREXP. SKIN:DUST, VAP AND/OR FUME MAY CAUSE IRRIT. SKIN ABSORP:DUST, VAP AND/OR (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:FUME ARE NOT READILY ABSORBED THRU SKIN. EYE:DUST, VAP AND/OR FUME MAY CAUSE IRRIT. INGEST:DUST, VAP AND/OR FUME MAY BE ABSORBED BY DIGESTIVE SYS & CAN RSLT IN BOTH ACUTE & CHRONIC OVEREXP. C HRONIC:IF LEFT UNTREATED:WEAK, INSOM, HYPERTENSION, SLIGHT IRRIT TO SKIN & EYES, METALLIC TASTE IN MOUTH, (SUPDAT) Medical Cond Aggravated by Exposure:CHRONIC FORMS OF KIDNEY, HEMATOPOEITIC AND/OR NEUROLOGIC DISEASES, PREEXISTING SKIN AND/OR RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/COPIOUS QTYS OF COOL WATER FOR AT LEAST 15 MIN. GET IMMED MED ATTN. SKIN:WASH THORO W/SOAP & WATER. INHAL:REMOVE FROM EXPOS. GET MED ATTN IF EXPERIENCING EFTS OF OVEREXP. INGEST:GET IMMED MED ATTN. NOTES TO PHYS:LEAD & ITS INORGAN CMPDS ARE NEUROTOXINS WHICH MAY PRODUCE PERIPHERAL NEUROPATHY. FOR AN OVERVIEW OF EFTS OF LEAD EXPOS, CONSULT OCCUP SFTY & HLTH ADMIN APPENDIX A OF (ING 13) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL/CARBON DIOXIDE SHOULD BE USED ON SURROUNDING FIRE. DO NOT USE WATER ON FIRES WHEN MOLTEN METAL IS PRESENT. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA OPERATED IN POSITIVE-PRESS MODE AND FULL BODY PROT CLOTHING. Unusual Fire/Explosion Hazard:MOLTEN METALS PRODUCE FUME, VAPOR, AND/OR DUST THAT MAY BE TOX AND/OR RESP IRRITANTS. THE PRODUCT, OR ITS DUST, CAN REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:DUST MATL SHOULD BE VACUUMED, OR WET SWEPT WHERE VACUUMING IS NOT FEASIBLE. PARTICULATE MATTER SHOULD BE STORED IN DRY CNTNRS FOR LATER DISP. DO NOT USE COMPRESSED AIR/DRY SWEEPING AS A MEANS OF CLEAN ING. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA WHERE ACCIDENTAL CONT W/ACIDS IS NOT POSS. AVOID SKIN CONT. Other Precautions:ADHERE TO ALL PERS PROT EQUIP PROCEDURES WHEN HANDLING, & VENT REQUIREMENTS WHEN HEAVY METAL EXPOSURES ARE ABOVE PEL OR THRESHOLD LIM VALUES. WORK CLOTHES & EQUIP SHOULD REMAIN IN DESIGNATED LEAD CONT AMD AREAS, & NEVER TAKEN HOME (ING 2) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP APPROP FOR EXPOS OF CONCERN . AS SPECIFIED BY 29CFR1910.1025 SUBPART (F) OF THE FED OCCUP SFTY & HLTH ADMIN STD OCCUP EXPOS TO LEAD. OTHER (ING 5) Ventilation:VENT, AS DESCRIBED IN INDUS VENT, A MANUAL OF REC PRACTICE PRODUCED BY AMERICAN CONFERENCE OF GOVT INDUS (ING 6) Other Protective Equipment:COVERALLS/OTHER FULL BODY CLTHG SHALL BE WORN DURING PROD USE & PROPERLY LAUNDERED AFTER USE, W/WASH WATER (ING 8) Work Hygienic Practices:NORMAL, GOOD PERS HYGIENE PRIOR TO SMOKING, EATING/DRINKING. SMOKING, EATING & DRINKING SHOULD BE CONFINED TO (ING 10) Supplemental Safety and Health EFTS OF OVEREXP:ANEMIA, CONSTIP, HDCH, MUSCLE & JOINT PAINS, NEUROMUSCULAR DYSFUNCTION, POSS PARAL & ENCEPHALOPATHY. LEAD EXPOS CAN POSE RISK TO DEVELOPING FETUSES & MAY ALSO IMPAIR REPROD SYS IN BOTH MEN & WOMEN. DMG TO KIDNEYS, HEMATOPOEITIC AND/OR CNS MAY OCCUR. LEAD APPEARS ON NAVY LISTING OF OCCUP CHEM (ING 11) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:3164F,1740C Melt/Freeze Pt:M.P/F.P Text:621F,327C Spec Gravity:11.3 (H*20=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:SILVER-GREY METAL, TARNISHES; NO APPARENT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND THIS PRODUCT MAY LIBERATE HYDROGEN GAS. Hazardous Decomposition Products:HIGH TEMPERATURES MAY PRODUCE HEAVY METAL FUME, VAPOR AND/OR DUST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF TOX SUBSTANCES AND HAZARDOUS WASTES IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SURE-POXY LMLV CAGE:KAUFM CAGE:KAUFM ============= Composition/Information on Ingredients ============= Ingred Name:EPICHLOROHYDRIN-BIPHENYL A EPOXY RESIN; (BLEND OF LIQUID EPOXY RESIN BASED ON RXN PROD OF EPICHLOROHYDRIN & (ING 2) Fraction by Wt: 5%PPM Other REC Limits:50 PPM (MFR) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 1: BISPHENOL A). BP: 360F,182C. FL PT: 480F,249C. SPEC GRAV: 1.10 RTECS #:9999999ZZ Ingred Name:PROPANE, 1-CHLORO-2,3 EPOXY; (EPICHLOROHYDRIN) CAS:106-89-8 RTECS #:TX4900000 Fraction by Wt: 1.5% PPM Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 5 PPM ACGIH TLV:S, 2 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:BLEND OF COMPLEX ALIPHATIC ETHER AMINES N-AMINO PIPERAZINE PHENOLS. (ING # 5-7). SPEC GRAV: 0.96 Other REC Limits:5 PPM (MFR) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ALIPHATIC ETHER AMINE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:N-AMINO PIPERAZINE OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PHENOLS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE PRIMARY IRRITATION OF SKIN WITH PROLONGED OR REPEATED CONTACT, BUT MAY CAUSE STRONG SENSITIZATION. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE, ADMINISTER ARTF RESP AND OXYGEN IF NECESSARY. CALL A PHYSICIAN. SKIN CONTACT: REMOVE SATURATED CLOTHING AND WASH AFFECTED AREAS WITH SOAP & WATER. EYE CONTACT: PROMPTLY FL USH WITH CLEAN WATER FOR AT LEAST 15 MINUTES. IF IRRITATION CONTINUES, CALL A PHYSICIAN . INGEST: DO NOT INDUCE VOMITING. GIVE LIQUIDS AND CALL A PHYSICIAN IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:SEE INGRED Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . AVOID BREATHING SMOKE. Unusual Fire/Explosion Hazard:DO NOT STORE NEAR STRONG OXIDANTS. ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT IGNITION. STOP LEAKAGE. VENTILATE AREA. ABSORB LIQUID WITH ABSORBENT. KEEP PEOPLE AWAY. KEEP OUT OF PUBLIC SEWERS, STREAMS AND WATERWAYS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT AND SPARKS. Other Precautions:THIS IS AN INDUSTRIAL PRODUCT. USE REASONABLE CARE. KEEP CONTAINERS CLOSED WHEN NOT IN USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR TYPE. Ventilation:LOCAL EXHAUST, AS NEEDED TO COMPLY WITH TLV. Other Protective Equipment:APRON. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:T6 Boiling Pt:B.P. Text:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:SEE ING Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NIL Appearance and Odor:LIGHT COLOR LIQUID. ING 1: ETHER ODOR. ING 2: AMINE ODOR. Percent Volatiles by Volume:3 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:STRONG OXIDIZING AGENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:USE GOVERNMENT REGULATED CHEMICAL DISPOSAL COMPANY. DISPOSE OF I/A/W FEDERDAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ADJUVANT COMPLETE FREUND, 0638-60 CAGE:12717 CAGE:12717 CAGE:TO408 ============= Composition/Information on Ingredients ============= Ingred Name:MYCOBACTERIUM BUTYRICUM = Wt:.05 Ingred Name:NONHAZARDOUS ADDITIONS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PRIMARY IRRITANT EFFECT: ON THE SKIN: NO IRRITANT EFFECT. ON THE EYE: NO IRRITATING EFFECT. SENSITIZATION: NO SENSITIZING EFFECTS KNOWN. SUBACUTE TO CHRONIC TOXICITY: DELAYED HYPERSENSITIVITY RESPONSE AND IMMUNE RESPONSE TO TUBERCULOSIS TEST SERUMS. ADDITIONAL TOXICOLOGICAL INFORMATION: HARMFUL. Effects of Overexposure:SEE HEATLH HAZARDS. ======================= First Aid Measures ======================= First Aid:INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS. IN CASE OF UNCONSCIOUSNESS PLACE PATIENT ON SIDE POSITION FOR TRANSPORTATION. SKIN CONTACT: IMMEDIATELY RINSE WITH WATER. PRIMARY IN JECTION MAY PRODUCE A TYPICAL RESPONSE WHICH MAY INCLUDE AND IS NOT LIMITED TO FEVER, MALAISE, LYMPHADENOPATHY, GRANULOMA DEVELOPMENT, DELAYED HYPERSENSITIVITY RESPONSE, AND IMMUNE RESPONSE. EYE CONTA CT: RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. THEN CONSULT A DOCTOR. REFER TO SKIN CONTACT. INGESTION: CALL A DOCTOR IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:>138.C, 280.4F Autoignition Temp:Autoignition Temp Text:SUPDAT Extinguishing Media:CO*2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER OR ALCOHOL RESISTANT FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DURING HEATING OR IN CASE OF FIRE POISONOUS GASES ARE PRODUCED. PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:PERSON-RELATED SAFETY PRECAUTIONS: WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY. MEASURES FOR ENVIRONMENTAL PROTECTION: WIPE UP WITH DAMP SPONGE OR MOP. MEASURES FOR CLEANING/COLLECTING: A BSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS, UNIVERSAL BINDERS). ======================Handling and Storage ====================== Handling and Storage Precautions:REQUIREMENTS TO BE MET BY STOREROOMS & RECEPTACLES: 15-30C. INFO ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: STORE AWAY FROM OXIDIZING AGENTS. FURTHER INFO ABOUT STORAGE CONDITIONS: STORE IN COOL, D RY CONDITIONS IN WELL SEALED RECEPTACLES. CLASS ACCORDING TO REGULATION ON FLAMMABLE LIQUIDS: VOID. Other Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE. INFO ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES: NO SPECIAL MEASURES REQUIRED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN CASE OF BRIEF EXPOSURE, USE A CHEMICAL FUME HOOD OR A NIOSH APPROVED RESPIRATOR. IN CASE OF INTENSIVE OR LONGER EXPOSURE USE NIOSH APPROVED RESPIRATORY PROTECTIVE DEVICE THAT IS INDEPENDENT OF CIRC ULATING AIR. Ventilation:DOES NOT CNTN ANY RELEVANT QTYS OF MATLS W/CRITICAL VALUES THAT HAVE TO BE MONITORED AT WORKPLACE. LISTS THAT WERE VALID DURING CREATIONS WERE USED AS BASIS. Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED. WASH HANDS BEFORE BREAKS AND AT THE END OF WORK. AVOID CONTACT WITH THE EYES AND SKIN. Supplemental Safety and Health AUTOIGNITION TEMP: PRODUCT IS NOT SELF-IGNITING. ================== Physical/Chemical Properties ================== Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:UNDETERMINED Spec Gravity:NOT DETERMINED Solubility in Water:PARTLY SOLUBLE Appearance and Odor:YELLOW LIQUID; CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO DANGEROUS REACTIONS KNOWN. Stability Condition to Avoid:NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS. Hazardous Decomposition Products:CARBON MONOXIDE (CO) AND CARBON DIOXIDE (CO*2). =================== Toxicological Information=================== Toxicological Information:SEE HEALTH HAZARDS. ===================== Ecological Information ===================== Ecological:THE ECOLOGICAL EFFECTS HAVE NOT BEEN THOROUGHLY INVESTIGATED, BUT CURRENTLY NONE HAVE BEEN IDENTIFIED. WATER HAZARD CLASS 0 (SELF-ASSESSMENT); GENERALLY NOT HAZARDOUS FOR WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS . PRODUCT RECOMMENDATION: MUST NOT BE DISPOSED OF WITH SOLID WASTE. SMALLER QUANTITIES CAN BE DISPOSED OF WITH SOLID WAST E. UNCLEANED PACKAGINGS RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO REGULATIONS FOUND IN 40 C FR 261. =================== MSDS Transport Information =================== Transport Information:MARINE POLLUTANT: NO. ===================== Regulatory Information ===================== Federal Regulatory Information:THE PRODUCT HAS BEEN CLASSIFIED AND MARKED IN ACCORDANCE WITH REGULATIONS ON HAZARDOUS MATERIALS. HAZARD SYMBOLS: XN HARMFUL. HAZARD-DETERMINING COMPONENTS OF LABELING: MYCOBACTERIUM BUTYRICUM. RISK P HRASES: 21/22 HARMFUL IN CONTACT WITH SKIN AND IF SWALLOWED. SAFETY PHRASES: 7 KEEP CONTAINER TIGHTLY CLOSED. 22 DO NOT BREATHE DUST. 24/25 AVOID CONTACT WITH SKIN AND EYES. 36 WEAR SUITABLE PROTECTIV E CLOTHING. WATER HAZARD CLASS 0 (SELF-ASSESSMENT): GENERALLY NOT HAZARDOUS FOR WATER. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:#2 DIESEL FUEL CAGE:3P045 CAGE:3P045 ============= Composition/Information on Ingredients ============= Ingred Name:KEROSENE CAS:8008-20-6 RTECS #:OA5500000 Fraction by Wt: 0-20% % Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:100 PPM 9091 Ingred Name:DISTILLATES,STREIGHT RUN MIDDLE CAS:64741-44-2 RTECS #:LX3296000 Fraction by Wt: 40-70% % Other REC Limits:NONE SPECIFIED Ingred Name:LIGHT HYDROCARBON BLEND CAS:64741-59-9 Fraction by Wt: 20-40% % Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRITATION OF UPPER RESPIRATORY TRACT WITH CENTRAL NERVOUS SYSTEM STIMULATION, SKIN IRRITATION, EYE IRRITATION, IRRITATION OF MUCOUS MEMBRANES OF THROAT, ESOPHAGUS AND STOMACH, GASTROINTESTINAL IRRITA TION, DEPRESSION. EXPERIENCE HAS SHOWN NO MAJOR CUMULATIVE OR LATENT EFFECTS DUE TO CHRONIC EXPOSURE. Explanation of Carcinogenicity:THE MATERIALS IN THIS PRODUCT ARE NOT LISTED AS CARCINOGENIC BY IARC, NTP OR OSHA. Effects of Overexposure:DEPRESSION, DIZZINESS, HEADACHE, INCOORDINATION, ANESTHESIA, COMA, RESPIRATORY ARREST, SKIN DEFATTING, BURNING OF SKIN/EYES, SWELLING OF EYELIDS, NAUSEA, VOMITING. Medical Cond Aggravated by Exposure:CONDITIONS WHICH HAVE THE SAME SYMPTOMS OR EFFECTS AS STATED ABOVE. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS ST OPPED, RESUSCITATE AND ADMINISTER OXYGEN IF AVAILABLE. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. KEEP AIRWAY CLEAR. IN ALL CASES, SEEK MEDICAL ATTENTION ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:140F,60C Lower Limits:1 % Upper Limits:5 % Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE OR WATER SPRAY. Fire Fighting Procedures:PRESSURE-DEMAND, SELF CONTAINED BREATHING APPARATUS SHOULD BE PROVIDED FOR FIRE FIGHTERS IN BUILDINGS OR CONFINED AREAS WHERE PRODUCT IS STORED. Unusual Fire/Explosion Hazard:CLOTHING, RAGS, OR SIMILAR ORGANIC MATERIAL CONTAMINATED WITH THE PRODUCT AND STORED IN A CLOSED SPACE MAY UNDERGO SPONTANEOUS COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:IF MATERIAL IS SPILLED OR RELEASED TO ATMOSPHERE, STEPS SHOULD BE TAKEN TO CONTAIN LIQUIDS AND PREVENT DISCHARGES TO STREAMS OR SEWER SYSTEMS. CONTROL OR STOP THE LOSS OF VOLATILE MATERIALS TO THE AIR . SPILLS OR RELEASES SHOULD BE REPORTED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA OF NON-COMBUSTIBLE CONSTRUCTION AWAY FROM POSSIBLE SOURCES OF IGNITION. Other Precautions:NOTES TO PHYSICIAN: GASTRIC LAVAGE ONLY IF LARGE QUANTITY HAS BEEN INGESTED. GUARD AGAINST ASPIRATION INTO LUNGS WHICH MAY RESULT IN CHEMICAL PNEUMONITIS. IRREGULAR HEARTBEAT MAY OCCUR; USE OF ADRENAL IN IS NOT ADVISABLE. TREAT SYMPTOMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION FOLLOWING MANUFACTURER'S RECOMMENDATION WHERE SPRAY, MIST OR VAPOR IS GENERATED. SUPPLIED AIR RESPIRATORY PROTECTION IS RE QUIRED FOR IDLH AREAS. Ventilation:WORK IN WELL VENTILATED AREAS. SPECIAL VENTILATION IS NOT REQUIRED UNDER NORMAL USE. Other Protective Equipment:STANDARD WORK CLOTHING, ACCESSIBLE EYEWASH AND SHOWER. Work Hygienic Practices:CONTAMINATED CLOTHING AND SHOES SHOULD BE WASHED WITH SOAP AND WATER AND DRIED BEFORE REUSE. Supplemental Safety and Health BLEND VARIES TO MEET SPECIFICATIONS. PHYSICAL DATA MAY VARY SLIGHTLY TO MEET SPECIFICATIONS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:330F,166C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:0.82-0.87 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:TRACE Appearance and Odor:YELLOW (STRAW) LIQUID WITH AROMATIC ODOR; ODOR THRESHOLD APPROX 1 PPM. Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SEPARATE FROM OXIDIZING MATERIALS. Stability Condition to Avoid:AVOID PHYSICAL DAMAGE. AVOID SOURCES OF IGNITION. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE CARBON MONOXIDE, CARBON DIOXIDE AND OTHER HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. WASTE PRODUCT AND CONTAMINATED MATERIAL WILL BE CONSIDERED A HAZARDOUS WASTE IF THE FLASH POINT IS LESS THAN 140F REQ UIRING DISPOSAL AT AN APPROVED HW FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DO-IT BEST LATEX FLOOR & TRIM, W39 A 713 SLATE GRAY Resp. Party Other MSDS Num.:LI/HW1 CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:2-(2-BUTOXYETHOXY) ETHANOL. (VAPOR PRESSURE: 0.1MMHG) CAS:112-34-5 RTECS #:KJ9100000 Minumum % Wt:0. Maxumum % Wt:3. Ingred Name:ETHYLENE GLYCOL. (VAPOR PRESSURE: 0.1 MMHG) CAS:107-21-1 RTECS #:KW2975000 Minumum % Wt:2. Maxumum % Wt:3. OSHA PEL:C50 PPM ACGIH TLV:C50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Minumum % Wt:0. Maxumum % Wt:.1 OSHA PEL:0.05 MG/M3(RESP DUST ACGIH TLV:0.05 MG/M3(RESP DUST Ingred Name:CALCIUM CARBONATE CAS:471-34-1 RTECS #:FF9335000 Minumum % Wt:2. Maxumum % Wt:3. OSHA PEL:15 MG/M3 (RESP DUST) OSHA STEL:5 MG/M3 (RESP DUST) ACGIH TLV:10 MG/M3 (RESP DUST) Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Minumum % Wt:0. Maxumum % Wt:12. OSHA PEL:15 MG/M3 (RESP DUST) OSHA STEL:5 MG/M3 (RESP DUST) ACGIH TLV:10 MG/M3 (RESP DUST) Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:50.9 Maxumum % Wt:61.6 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHAL AND/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW RECS FOR PROPER USE, VENT, & PERSONAL PROT EQUIP. ACUTE: IRRITATION OF EYES, SKIN & UPPER RESPIRATO RY SYSTEM. IN CONFINED AREA VAPORS IN HIGH CONCENTRATION MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. CHRONIC: CRYSTALLINE SILICA (QUARTZ, CRISTOBALITE) IS LISTED BY IARC & NTP. LONG TERM EXPOSURE TO HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING OR ABRADING DRY FILM, MAY CAUSE LUNG DAMAGE (SILICOSIS) AND POSSIBLY CANCER. ETHYLENE GLYCOL IS CONSIDERED ANIMAL TERATOGEN. IT HAS BEEN (EFTS OF OVEREXP) Explanation of Carcinogenicity:CRYSTALLINE SILICA, CRISTOBALITE: IARC MONOGRAPHS, VOL 68, 1997: GROUP 1. NTP 9TH ANNUAL REPORT ON CARCINOGENS. 1998: ANTICIPATED TO BE CARCINOGEN. Effects of Overexposure:HLTH HAZS: SHOWN TO CAUSE BIRTH DEFECTS IN RATS & MICE AT HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE IS NO EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PROLONGED OVEREXPOSURE TO SOLVENT INGREDS IN SECTION II MAY CAUSE ADVERSE EFFECTS TO LIVER & URINARY SYSTEMS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER. HOWEVER, SUCH EXPOSURE LEVELS ARE NOT A TTAINABLE IN THE WORKPLACE. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: FLUS H WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESSURE BUILD -UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. HMIS (NFPA) RATING(HEALTH-FLAMMABILITY-REACTIVITY): 2-0-0. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ======================Handling and Storage ====================== Handling and Storage Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN & EYES. WASH HANDS AFTER USING. THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (LISTED "AS DUST" IN SECTION II) WHICH MAY BE PRESENT ! HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. Other Precautions:IF NO SPECIFIC DUSTS ARE LISTED IN SECTION II, APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE FRACTION. KEEP CNTNR CLSD W HEN NOT IN USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LBLG. DO NOT TAKE INTERNALLY. (SU PDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH FOR PROTECTION AGAINST MATLS IN SECTION II. WHEN SANDING OR ABRADING DRIED FILM. WEAR DUST/MIST RESPIRATOR APPROVED BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM THIS PRODUCT, (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOSURE TO MATLS IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. (SUPDAT) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health WEIGHT PER GALLON: 9.01-9.75 LBS. VOC - TOTAL (LBS/GAL.): 0.45-0.60. VOC - LESS WATER (LBS/GAL): 1.29-1.50. HMIS (NFPA) RATING (HEALTH, FLAMMABILITY, REACTIVITY): 2, 0, 0. OTHER PREC: KEEP OUT OF REACH OF CHILDREN. RESP PROT: UNDERLYING PAINT, OR THE ABRASIVE. VENT: REFER TO OSHA STDS 1910.94, 1919.107, 1910.108. ================== Physical/Chemical Properties ================== Boiling Pt:>100.C, 212.F B.P. Text:212-488F Vapor Pres:SEE INGREDIENTS Vapor Density:HVR/AIR Spec Gravity:1.12-1.55 pH:8.2-9.0 Evaporation Rate & Reference:SLOWER THAN ETHER Percent Volatiles by Volume:57-81 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODS IS NOT HAZ AS DEFINED UNDER RCRA 40 CFR 261. INCINERATE IN APPRVD FACILITY. DO NOT INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIO NS REGARDING POLLUTION. ===================== Regulatory Information ===================== SARA Title III Information:22-(2-BUTOXYETHOXY)-ETHANOL AND ETHYLENE GLYCOL ARE SUBJECT TO REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENT AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR 372.85C. State Regulatory Information:CALIFORNIA PROPOSITION 65: THESE PRODUCTS CONTAIN A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COPPER/COPPER ALLOYS HIGH LEADED BRASS, C34 CAGE:0PAZ9 CAGE:0PAZ9 ============= Composition/Information on Ingredients ============= Ingred Name:ING 13:BODY & MORE SEVERE SYMPT. THESE INCLUDE ANEMIA,PALE SKIN, A BLUE LINE AT THE GUM MARGIN,DECREASED HANDGRIP(ING 15 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 14:STRENGTH,ABDOM PAIN,SEVER CONSTIPATION,NAUS,VOMIT & PARALYSIS OF WRIST JOINT.PRLNGD EXPOS MAY ALSO RESULT(ING 16 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 15:IN KIDNEY DMG.IF NERV SYS IS AFFECTED,USUALLY DUE VERY HIGH EXPOS,THE RESULTING EFFTS INCLUDE SEVERE (ING 17) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 16:HDACHE,CONVULSIONS,COMA,DELIRIUM, & DEATH.ALCOHOL INGES & PHYSICAL EXERTION MAY BRING ON SYMPT.CONTINUED(ING 18 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 17:EXPOS CAN RESULT IN DECREASED FERTILITY AND/OR INCREASED CHANCES OF MISCARRIAGE OR BIRTH DEFECTS. RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 12:MAY LEAD TO SEIZURES,COMA & DEATH. LEAD- LONG TERM EXP:LONG TERM EXPOS CAN RESULT IN A BUILDUP OF LEAD IN (ING 14 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:COPPER CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 63% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2MG/M3 FUME;1 DUST EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 35.25% OSHA PEL:15MG/M3 TDUST/5 FUME ACGIH TLV:10MG/M3 TDUST; 9293 Ingred Name:LEAD CAS:7439-92-1 RTECS #:OF7525000 Fraction by Wt: 1.75% OSHA PEL:0.05 MG/M3 ACGIH TLV:0.15 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:EFTS OF OVEREXP:WHILE INDUSTRIAL DERMATITIS HAS BEEN REPORTED,KERATINIZATION OF HANDS & SOLES OF FEET HAS BEEN (ING 5) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 4:REPORTED.SYSTEMICALLY AS WELL, COPPER DUST & FUME CAUSE IRRIT OF THE UPPER RESP TRACT,METALLIC TASTE IN (ING 6) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 5:MOUTH, & NAUSEA.ZINC(AS OXIDE)-ZINC IS VERY LOW IN TOXICITY BUT INHAL OF FUMES MAY CAUSE "METAL FUME FEVER."(ING 7 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 6:ONSET OF SYMP MAY BE DELAYED 4-12 HRS & INCLUDE IRRIT OFNOSE,THROAT,COUGH,STOMACH PAIN,HDACHE,NAUS,VOMIT,(ING 8) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 7:METALLIC TASTE,CHILLSFEVER,PAINS IN MUSCLES & JOINTS,THIRST,BRONCHITIS OR PNEUM & A BLUISH TINT TO SKIN. (ING 9) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 8:THESE SYMPT GO AWAY IN 24-48 HRS & LEAVE NO EFFT.LEAD- SHORT TERM EXPOS:LEAD IS AN ACCUMULATIVE (ING 10) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 9:POISON.INHAL EFFTS OF EXPOS TO FUMES OR DUST OF INORGANIC LEAD MAY NOT DEVELOP QUICKLY. SYMPT MAY INCLUDE(ING 11) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 10:DECREASED PHYSICAL FITNESS, FATIGUE,SLEEP DISTURBANCE,HDACHE,ACHING BONES & MUSCLES, CONSTIPATION,ABDOM (ING 12) RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED Ingred Name:ING 11:PAINS, & DECREASING APPETITE.EFFTS ARE REVERSIBLE & COMPLETE RECOVERE IS POSS.INHAL OF LARGE AMTS OF LEAD (ING 13 RTECS #:9999999ZZ Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:UNDER NORMAL HANDLING CONDITIONS THE SOLID ALLOY PRESENTS NO SIGNIFICANT HEALTH HAZARDS. PROCESSING OF THE ALLOY BY DUST OR FUME PRODUCING OPERATION (GRINDING, BUFFING, HEATING, WELDING, ETC.) MAY RES ULT IN THE POTENTIAL FOR EXPOSURE TO AIRBORNE METAL PARTICULATES OR FUME. THE EXPOSURE LEVELS ARE (EFTS OF OVEREXPOSURE) Explanation of Carcinogenicity:LEAD:GROUP 2B (IARC) Effects of Overexposure:HLTH HAZ:RELEVANT TO FUMES AND DUSTS. EFTS OF OVEREXPOS:COPPER MELTING, GRINDING, CUTTING OF COPPER MAY PRODUCE FUMES OR DUST EXPOSURE AND BREATHING THESE FUMES OR DUST MAY PRESENT POTENTIALLY SIGNIFI CANT HEALTH HAZ. FUMES OF COPPER MAY CAUSE METAL FUME FEVER WITH FLU-LIKE SYMTPOMS AND SKIN AND HAIRDISCOLORATION(ING 4) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WELL WITH RUNNING WATER FOR AT LEAST 15 MINUTES TO REMOVE PARTICULATE. GET MD. SKIN:VACUUM OFF EXCESS DUST. WASH WELL WITH SOAP & WATER. INHAL:MOVE TO FRESH AIR. GET MD. INGEST:GET MD IF LAR GE QUANTITIES OF MATERIAL HAVE BEEN INGESTED. ===================== Fire Fighting Measures ===================== Extinguishing Media:MIXTURES OF DRY CHEMICAL OR SAND. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . SOLID MASSIVE FORM IS NOT COMBUSTIBLE. Unusual Fire/Explosion Hazard:FIRE & EXPLO HAZ ARE MODERATE WHEN MATERIAL IS IN THE FORM OF DUST AND EXPOSED TO HEAT, FLAMES, CHEMICAL REACTION, OR IN CONTACT WITH POWERFUL OXIDIZERS. ================== Accidental Release Measures ================== Spill Release Procedures:NO SPECIAL PRECS NEC FOR SPILLS OF BULK MATL. IF LGE QTYS OF DUST ARE SPILLED, REMOVE BY VACUUMING OR WET SWEEPING TO PVNT HEAVY CONC OF AIRBORNE DUST. IF LIQS (ACIDS/BASES) CNTNG SOLUBILIZED METAL AR E SPILLED EVACUATE UNPROT PERS FROM AREA.(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATERIAL AWAY FROM INCOMPATIBLE MATERIALS AND KEEP DUST FROM SOURCES OF IGNITION. Other Precautions:SEE ALL OTHER SECTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE ABOVE PEL/TLV, NIOSH/MSHA APPROVED RESPIRATOR FOR FUME OR DUST, DEPENDENT UPON THE SOURCE OF AIRBORNE CONTAMINANT. Ventilation:REQUIRED IF DUST OR FUME CREATED IN HANDLING OR WORKING ON THIS MATERIAL. Other Protective Equipment:AS REQUIRED FOR THE WORK DONE ON OR WITH THE METAL. Work Hygienic Practices:ALWAYS EVALUATE THE JOBS DONE ON THIS PRODUCT IN ACCORDANCE WITH OSHA OR RELEVANT STATE, FEDERAL, OR LOCAL STANDARDS. Supplemental Safety and Health SPILL PROC:ABSORB LIQ BY MEANS OF VERMICULITE, DRY SAND OR SIMILAR MATERIAL. FOLLOW FEDERAL, STATE, AND LOCAL REGULATIONS CONCERNING THE DISPOSAL OF WASTE. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:2260F,1238C Spec Gravity:7.45-9.00 Solubility in Water:INSOLUBLE Appearance and Odor:SILVER OR YELLOW TO RED SOLID WITH NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, BASES, AND OXIDIZERS. Stability Condition to Avoid:MOLTEN METAL MAY REACT VIOLENTLY WITH WATER. Hazardous Decomposition Products:METAL FUME. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. CLEANUP PERSONNEL SHOULD WEAR RESPIRATORS AND PROTECTIVE CLOTHING. VENTILATE AREA OF RELEASE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:VARGLAS SILICONE RESIN 500 Preparer's Name:JAMES SMALL CAGE:79074 CAGE:79074 ============= Composition/Information on Ingredients ============= Ingred Name:GLASS, FIBROUS RTECS #:LK3651000 Other REC Limits:NONE RECOMMENDED OSHA PEL:15 MG/M3 (DUST) ACGIH TLV:10 MG/M3 (DUST);9293 Ingred Name:SILICONE COATING-METHYL & PHENYL Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: ACUTE-MAY RESULT IN IRRITATION OF MOUTH, NOSE & THROAT; CHRONIC-NONE. SKIN: ACUTE-MAY PRODUCE ITCHING, AND TEMPORARY MECHANICAL IRRITATION; CHRONIC-NONE. EYE: ACUTE-MAY PRODUCE TEMPORARY M ECHANICAL IRRITATION; CHRONIC-NONE. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:OBSERVE INDIVIDUAL AND IF SYMPTOMS PERSISTS, CONSULT PHYSICIAN. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF CHRONIC RESPIRATORY OR SKIN CONDITIONS THAT ARE AGGRAVATED BY MECHANICAL IRRITANTS. ======================= First Aid Measures ======================= First Aid:WASH EXPOSED SKIN WITH SOAP & WATER. DO NOT RUB OR SCRATCH IRRITATED AREA. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:IN A SUSTAINED FIRE, USE SELF CONTAINED BREATHING APPARATUS APPROVED BY THE U.S. BUREAU OF MINES. Unusual Fire/Explosion Hazard:NONE.AT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. ================== Accidental Release Measures ================== Spill Release Procedures:FOR DUST & FIBERS GENERATED DURING FABRICATION, VACUUM AND CONTAINERIZE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN THE ABSENCE OF DIRECT SENSITIVE SKIN. Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED. Ventilation:LOCAL AND MECHANICAL(GENERAL) EXHAUST FOR VENTILATION. Other Protective Equipment:NONE. Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE & SAFETY PRACTICES. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:N1 Spec Gravity:1.2 Appearance and Odor:SILICONE RESIN COATED WITH NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:SIZINGS & BINDERS MAY DECOMPOSE IN FIRE PRIMARILY TO CARBON MONOXIDE, CARBON DIOXIDE & OTHER HYDROCARBONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN MUNICIPAL OR INDUSTRIAL LANDFILL. CHECK LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:462-468 MINERAL OIL Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:COPPER COMPOUND Fraction by Wt: 2% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:154A102, SWIMMING POOL PAINT CAGE:ACEHA CAGE:ACEHA ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 20% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 20.3% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE) CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 12% OSHA PEL:15 MG/M3 (MFR) ACGIH TLV:10 MG/M3 (MFR) Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 9.3% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS) CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 1.9% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 32.6% OSHA PEL:500 PPM (MFR) ACGIH TLV:300 PPM (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM MAY OCCUR ON OVEREXPOSURE. MAY ALSO CAUSE NERVOUS SYSTEM DEPRESSION. HEADACHE, DIZZINESS, NAUSEA AND LOSS OF COORDINATION ARE INDICATIONS OF EXCES SIVE EXPOSURE TO VAPORS OR SPRAY MISTS.CHRONIC:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS CAN BE HARMFUL OR FATAL. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:78.0F,25.6C Lower Limits:0.7% Extinguishing Media:FOR DRY SOLIDS, USE WATER, FOAM, CO*2, DRY CHEMICALS. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTO IGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. HEAT MAY CAUSE PRESSURE BUILD-UP IN CLOSED CNTNRS. WATER MAY BE USED TO COOL. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT & OPEN FLAME. USE APPROVED BONDING & GROUNDING PROCEDURES. KEEP OUT OF REACH OF CHILDREN. Other Precautions:TRANSFER ONLY TO APPROVED, PROPERLY MARKED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:PROPERLY FITTED NIOSH APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR. Ventilation:LOCAL EXHAUST:PREFERABLE. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:280F,138C Vapor Density:HVR/AIR Spec Gravity:1.48 (H*2O=1) Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:INSOLUBLE Appearance and Odor:COLORED PIGMENTED LIQUID W/SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE - CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HIGH PERFORMANCE ACRYLIC COATINGS CAGE:08882 CAGE:08882 ============= Composition/Information on Ingredients ============= Ingred Name:TEXANOL, CAS:25265-77-4 RTECS #:UF6000000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:DIETHYLENE GLYCOL MONOMETHYL ETHER CAS:111-77-3 RTECS #:KL6125000 Fraction by Wt: 0-3% Other REC Limits:NONE RECOMMENDED Ingred Name:PROPYLENE GLYCOL CAS:57-55-6 RTECS #:TY2000000 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN OR EYE CONTACT-POSSIBLY PRIMARY IRRITANT. CHRONIC: OVEREXPOSURE TO METHYL CARBITOL HAS BEEN ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY AND TESTIS DAMAGE IN LAB ANIMALS. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION-VAPOR OR MIST MAY CAUSE HEADACHE, NAUSEA AND IRRITATION OF THE NOSE, THROAT AND LUNG. INGESTION-MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:FUMES-REMOVE FROM EXPOSURE. SPRAY-FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. NOTIFY A PHYSICIAN. SPLASH-WASH AFFECTED AREA WITH SOAP AND WATER AND REMOVE CONTAMINATED CLOTH ING AND WASH BEFORE REUSE. INGESTION-DILUTE STOMACH CONTENTS WITH 2 GLASSES OF WATER AND INDUCE VOMITING BY EITHER GIVING IPECAC SYRUP OR BY PLACING 2 FINGERS AT BACK OF THROAT. ===================== Fire Fighting Measures ===================== Flash Point:>200F,>93C Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILD-UP OF STEAM. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILD-UP OF STEAM. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP LIQUID WITH ABSORBENT AND SHOVEL INTO WASTE CONTAINER. WASH SPILL AREA WITH WATER AND FLUSH TO SEWER SERVICED BY WASTEWATER TREATMENT FACILITY Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NON-FLAMMABLE. SEE OSHA 1910.106. KEEP FROM FREEZING. Other Precautions:THESE PRODUCTS ARE NOT KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR (TC23C) TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLICATION. Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME & PATTERN TO KEEP TLV BELOW ACCEPTABLE LIMITS. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:302-385F Vapor Density:>AIR pH:8-9.2 Evaporation Rate & Reference:SLOWER (ETHER=) Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:60-70 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY OPEN FLAME - CARBON MONOXIDE AND CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:92-823092A1 QUICKSILVER 4 CYCLE ENGINE CAGE:5S187 CAGE:5S187 CAGE:88907 ============= Composition/Information on Ingredients ============= Ingred Name:ADDITIVES PACKAGE Fraction by Wt: 10% Ingred Name:OIL PETROLEUM DISTILLATES, SOLVENT-DEWAXED HEAVY PARAFFINIC CAS:64742-65-0 RTECS #:PY8038500 Fraction by Wt: 80% Other REC Limits:5 MG/CUM Ingred Name:VISCOSITY INDEX IMPROVER Fraction by Wt: 10% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: MISTS >TLV MAY CAUSE CHEMICAL PNEUMONITIS. SKIN/EYES: MILD IRRITANT. INGESTION: LOW TOXICITY. RISK OF ASPIRATION INTO LUNGS. INGESTION OF LARGE QUANTITIES MAY CAUSE GASTROINTESTINAL DISCOM FORT. SMALL DOSES MAY PRODUCE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, DIARRHEA, HEADACHE Medical Cond Aggravated by Exposure:NONE EXPECTED ======================= First Aid Measures ======================= First Aid:INHALATION: IMMEDIATELY MOVE TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE CPR. IF BREATHING IS DIFFICULT, GIVE HUMIDIFIED OXYGEN. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:392F Extinguishing Media:CO2, DRY CHEMICAL, FOAM/WATER FOG Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:WATER MAY CAUSE FROTHING. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: REMOVE ALL SOURCES OF HEAT/IGNITION, PROVIDE ADEQUATEVENTILATION. CONTAIN LEAK W/ABSORBENT, INERT, NON-COMBUSTIBLE ,MATERIAL. LARGE: CONTAIN & TRANSFER TO SECURE CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:PRODUCT IS A COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT & FLAMES. STORE <150F. DON'T APPLY TO HIGH HEAT/FLAME TO CONTAINER. Other Precautions:KEEP AWAY FROM STRONG OXIDIZING AGENTS. EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE WHICH COULD INCLUDE FLAMMABLE/EXPLOSIVE VAPORS. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF HIGH VAPOR/MIST CONCENTRATIONS ARE EXPECTED, USE APPROPRIATE NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPOR & MISTS. Ventilation:LOCAL: TO MAINTAIN EXPOSURE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. MECHANICAL: IN CONFINED SPACES. Other Protective Equipment:WEAR BODY-COVERING CLOTHES Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:665F Vapor Density:>1 Spec Gravity:0.88 Solubility in Water:NEGLIGIBLE Appearance and Odor:AMBER, OILY LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS Stability Condition to Avoid:HEAT, FLAME Hazardous Decomposition Products:CO2/CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AMPICILLIN SODIUM INJECTION (125,250,500,1000,2000 MG/VIAL) CAGE:MO552 CAGE:MO552 CAGE:0MN35 ============= Composition/Information on Ingredients ============= Ingred Name:AMPICILLIN SODIUM CAS:69-52-3 RTECS #:XH8400000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >5314 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY & GI TRACTS. ACUTE- THIS PRODUCT IS IN CLOSED VIALS. IF BROKEN OR IN FIRE, MAY CAUSE EYE IRRITATION. INHALATION MAY CAUSE ALLERGIC REACTION. ORAL ADMINSTRATION MA Y CAUSE ALLERGIC REACTIONS INCLUDING SKIN RASHES, RESPIRATORY DISTRESS & MAY BE FATAL. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES IRRITATION, SKIN RASH AND REDNESS, EYE REDNESS, NAUSEA, VOMITING, DIARRHEA, COUGHING, SHORTNESS OF BREATH, RUNNING NOSE, WHEEZING, DIFFICULTY IN BREATHING, STOMACH DISCOMFORT AND GASTRITIS Medical Cond Aggravated by Exposure:INDIVIDUAL WITH KNOWN SENSITIVITY TO PENICILLIN, GASTROINTESTINAL DISORDERS; HEMATOLOGIC DISORDERS; RENAL DISORDERS MAY BE SENSITIVE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. CALL A PHYSICIAN IMMEDIATELY. ORAL:CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE WITHOUT PERSONAL RISK. Unusual Fire/Explosion Hazard:AS WITH ANY FINELY DIVIDED ORGANIC SOLID, DUST MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL PROPORTIONS & IN THE PRESENCE OF AN IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. CAREFULLY SCOOP UP OR SHOVEL SPILLED MATERIAL INTO A SUITABLY LABELLED CONTAINER FOR RECOVERY OR DISPOSAL. AVOID GENERATING DUST. VENTILATE AREA. DECONTAMINATE SPILL AREA AF TER PICK UP IS COMPLETE. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL (59-86), DRY PLACE. KEEP OUT OF REACH OF CHILDREN. PERSONS ALLERGIC TO PENICILLIN SHOULD AVOID CONTACT WITH THIS SUBSTANCE. Other Precautions:AS A GENERAL RULE, WHEN HANDLING PHARMACEUTICAL PRODUCTS, AVOID ALL FORMS OF CONTACT AND INHALATION OF DUST, FUMES, MISTS, AND/OR VAPORS ASSOCIATED WITH THE PRODUCT. GROUND ALL EQUIPMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NORMALLY REQUIRED. IF DUST PRESENT, WEAR NIOSH-APPROVED DUST MASK OR RRESPIRATOR. Ventilation:LOCAL EXHAUST RECOMMENDED FOR DUSTY SITUATION. MECHANICAL ACCETABLE. Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE CLOTHING AND/OR UNIFORM Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH HANDS AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:T6 NRC/State Lic Num:NOT RELEVANT Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:SOLUBLE Appearance and Odor:WHITE TO OFF-WHITE POWDER - PRACTICALLY ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:EXCESSIVE HEAT Hazardous Decomposition Products:TOXIC GASES INCLUDING CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF SULPHUR AND NITROGEN MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVER OR RECYCLE IF POSSIBLE. DISPOSAL SHOULD BE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TX124I I PROTECT CLEANER Preparer's Name:SCOTT FAHY CAGE:21944 CAGE:21994 CAGE:21944 ============= Composition/Information on Ingredients ============= Ingred Name:LAURYL TRIMETHYL AMMONIUM CHLORIDE CAS:112-00-5 Fraction by Wt: <1% Ingred Name:ISOPROPYL ALCOHOL (SARA III) CAS:67-63-0 RTECS #:NT8050000 Fraction by Wt: 29.7% Other REC Limits:400 PPM OSHA PEL:400 PPM/500 STEL ACGIH TLV:400 PPM/500STEL;9192 Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: <2% Other REC Limits:100 PPM OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER CAS:34590-94-8 RTECS #:JM1575000 Fraction by Wt: <2% Other REC Limits:100 PPM OSHA PEL:S,100PPM/150STEL ACGIH TLV:S,100PPM/150STEL9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT IRRITATION, NARCOSIS, NAUSEA, & HEADACHES. EYE: IRRITATION, BURNING SENSATIONS, & DAMAGE. INGESTION: BURNING SENSATIONS OF THE DIGESTIVE TRACT, NAUSEA, VOMITING, BLEEDING, CNS DEPRESSION, & POISONED. SKIN: IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: NOSE/THROAT IRRITATION, NARCOSIS, NAUSEA, & HEADACHES. EYE: IRRITATION, BURNING SENSATIONS, & DAMAGE. INGESTION: BURNING SENSATIONS OF THE DIGESTIVE TRACT, NAUSEA, VOMITING, BLEEDING, CNS DEPRESSION, POISONING, & DEATH. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. INGESTION: GIVE WATER TO DILUTE. INDUCE VOMITING, IF CONSCIOUS & ALERT. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:102F Extinguishing Media:WATER, CO2, DRY CHEMICAL, ALCOHOL TYPE FOAM. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID CLASS 1B. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SMALL SPILLS W/PAPER TOWELS, EVAPORATE FLAMMABLE ALCOHOL IN EXHAUST HOOD & BURN DRY PAPER. CONTAIN LARGE SPILLS. COLLECT LIQUID IF FEASIBLE OR ABSORB W/VERMICULITE OR SAND & PLACE INTO COVERED CONTAINERS USING NON-SPARKING TOOLS FORDISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL VENTILATED AREA & IN CLOSED CONTAINERS AT ROOM TEMPERATURE. REMOVE SOURCES OF IGNITION. Other Precautions:ALUMINUM CONTAINERS SHOULD NOT BE USED FOR ISOPROPYL ALCOHOL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SELF-CONTAINED BREATHING OR AIR-SUPPLIED BREATHING APPARATUS W/FULL FACEPIECE FOR NON-ROUTINE OR IF >TLV. Ventilation:PROVIDE GENERAL/LOCAL EXHAUST VENTILATION EXPLOSION PROOF TO KEEP <TLV. Other Protective Equipment:EYEWASH FOUNTAIN, WASHING FACILITIES, & SAFETY SHOWER. Supplemental Safety and Health ISOPROPANOL IS CONSIDERED POISON W/INGESTION OF 20ML CAUSING SERIOUS ILLNESS. SINGLE LETHAL ORAL DOSE FOR AN ADULT IS 250ML. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:140F Spec Gravity:0.955 Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID Percent Volatiles by Volume:29.7% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM Stability Condition to Avoid:SOURCES OF IGNITION Hazardous Decomposition Products:CO ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. FLAMMABLE LIQUID CLASS 1B. DOT UN1219.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:F76 G 25, KEM AQUA GLOSS ENAMEL NON-LEAD CO CAGE:54636 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:OTHER PREC: (SEE ACGIH TLV LIST, PREFACE & APPENDIX D), WHICH MAY BE PRESENT @ HAZ LEVELS ONLY DURING SANDING (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: OR ABRADING OF DRIED FILM. INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: OR FATAL.USE ONLY W/ADEQ VENT.AVOID BRTHG VAP & SPRAY MIST.AVOID CONT W/SKIN & EYES. PROTECT AGAINST DUST (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: GENERATED BY SANDING OR ABRADING DRIED FILM. DOL STORAGE CATEGORY-2. RTECS #:9999999ZZ Ingred Name:VENT: STANDARDS 1910.94, 1910.107, 1910.108. RTECS #:9999999ZZ Ingred Name:ETHANOL, 2-BUTOXY-; (EGBE) (2-BUTOXYETHANOL). VP: 0.6. CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 10-15% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE). VP: 70. CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 0-5% OSHA PEL:200 PPM;300 PPM STEL ACGIH TLV:200 PPM;300 PPM STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE- RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, THE BLOOD, THE KIDNEYS & THE LIVER, ASSOCD W/THE ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) & ETHYLENE G LYCOL MONOBUTYL ETHER ACETATE (EGBEA). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:ACUTE:OVEREXP CAUSES, EYE, SKIN & RESP IRRIT.MAY CAUSE NERVS SYS DEPRESS ACCOMPANIED BY HDCH, DIZZ, NAUS, CONFUSION & STAGGERING GAIT.EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. CHRONIC:P RLNGD OVEREXP TO INGS MAY CAUSE ADVERSEEFTS TO LIVER, URINARY, BLOOD FORMING & REPRO SYS.RATS EXPOSED TO (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYE: FLUSH WITH LA RGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:120F,49C Lower Limits:1.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .WATER SPRAY MAY BE INEFTIVE.IF WATER IS USED, FOG NOZ ARE PREF.WATER MAY BE USED TO COOL CLSD (SUPP DATA) Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE COMBUST.KEEP AWAY FROM HEAT & OPEN FLAME.CONSULT NFPA CODE.USE APPRVD BONDING & GROUNDING PROCS.KEEP CNTNR CLSD WHEN NOT IN USE. Other Precautions:TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING.DO NOT TAKE INTERNALLY.KEEP OUT OF REACH OF CHILDREN.COATING CONTAINS MATLS CLASSIFIED AS NUISANCE PARTICULATES, FOR EXAMPLE, TITANIUM DIOXI DE, CALCIUM CARBONATE, ETC. (ING 4) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR RESPIRATORY DEVICE APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST INGREDIENTS. Ventilation:LOC EXHST PREF.GEN EXHST ACCEPTABLE IF EXPOS TO INGS IS MAINTAINED < APPLIC EXPOSURE LIMS.REFER TO OSHA (ING 8) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD- UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. HLTH HAZ: TITANIUM DIOXIDE DUST @ 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LVLS ARE NOT A TTAINABLE IN WORKPLACE. REPORTS HAVE ASSOCD RPTD & PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DAM. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>174F,>79C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1-1.3 pH:7-9 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:65-80 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:BY FIRE: CO, CO2. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261.WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE #.INCINERATE IN APPRVD FACILITY.DO NOT INCINERATE CLSD CNTNR.DISPOSE OF I/A/W FED/STATE & LOC REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MIL-L-21260C GRADE 30 Preparer's Name:I. R. SWOAP CAGE:7A348 CAGE:7A348 ============= Composition/Information on Ingredients ============= Ingred Name:PETROLEUM OIL; WT % RANGE:80-95% Fraction by Wt: 87.5% ACGIH TLV:5MG/CUM(MIST) Ingred Name:ADDITIVE PACKAGE CONTAINING NITROGEN,ZINC,CALCIUM,SULFUR & PHOSPHORUS;WT % RANGE:5-10 Fraction by Wt: 07.5% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS > 10000 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE- EYES: MAY CAUSE MINIMAL IRRITATION/TRANSIENT MINOR IRRITATION. SKIN: MAY CAUSE SLIGHT IRRITATION. INHALATION: MINIMALLY IRRITATING IF TLV IS NOT IN EXCESS OF 5MG/M3 OIL MISTS. INGESTION: PRACTI CALLY NON-TOXIC. CHRONIC- NONE KNOWN. Explanation of Carcinogenicity:USED MOTOR OILS HAVE SHOWN TO CAUSE SKIN CANCER IN MICE. Effects of Overexposure:MAY CAUSE MINIMAL EYE IRRITATION OR TRANSIENT MINOR EYE IRRITATION. MAY CAUSE SLIGHT SKIN IRRITATION. INHALATION IS MINIMALLY IRRITATING IF TLV IS NOT IN EXCESS OF 5MG/M3 OIL MISTS. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET MEDICAL HELP IF NEEDED. INHALATION: REMOVE TO FRESH AIR. EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. INGEST ION: NOT CONSIDERED NECESSARY. CALL PHYSICIAN IF SYMPTOMS DEVELOP. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:430F,221C Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER OR FOAM MAY CAUSE FROTHING. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS AND PERSONNEL WITH WATER SPRAY. Unusual Fire/Explosion Hazard:CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES AND KETONES, COMBUSTION PRODUCTS OF NITROGEN AND SULFUR. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN SPILL WITH INERT MATERIAL (SAND,EARTH,FULLERS EARTH ETC.).TRANSFER LIQUID TO DRUMS OR OTHER CONTAINERS FOR RECOVERY OR DISPOSAL.AREA MAY BE SLIPPERY.CARE SHOULD BE TAKEN TO AVOID FALLS. PREVENT MATERIAL FROM GETTING INTO SEWERS & WATERS Neutralizing Agent:NOT APPLICABLE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORAGE-THESE LUBRICANTS BECOME VERY VISCOUS WHEN STORED AT LOW TEMPERATURE. Other Precautions:USE PRODUCT WITH CAUTION AROUND OPEN FLAMES, HEAT, SPARKS, PILOT LIGHTS & STATIC ELECTRICITY. DO NOT BREATHE MISTS/VAPORS. MINIMIZE SKIN CONTACT. DO NOT GET IN EYES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED SPACES IF NEEDED. Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. Other Protective Equipment:EYE WASH STATION Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. DISCARD OIL-SOAKED SHOES. Supplemental Safety and Health "EMPTY" CONTAINERS MAY RETAIN RESIDUE (LIQUID AND/OR VAPOR) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER DRILL, GRIND OR EXPOSE THEM TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNIT ION: THEY MAY EXPLODE AND CAUSE INJURY.DO NOT CLEAN THEM. ================== Physical/Chemical Properties ================== HCC:V6 Spec Gravity:0.892 Appearance and Odor:BRIGHT AND CLEAR LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ALDEHYDES AND KETONES, COMBUSTION PRODUCTS OF NITROGEN AND SULFUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF CONTAMINATED DIKING MATERIAL ACCORDING TO CURRENT FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHOSPHOLIPASE C CAGE:GO448 CAGE:GO448 ============= Composition/Information on Ingredients ============= Ingred Name:PHOSPHOLIPASE C *96-3* CAS:9001-86-9 RTECS #:SZ6116000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE INDIVIDUALS MAY DEVELOP. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS. Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL. USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER. ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR DUST MASK. Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN. Supplemental Safety and Health SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE. ================== Physical/Chemical Properties ================== Solubility in Water:(SEE SUPP) Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH HAVE TYPICAL ENZYME ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= NIIN: 01-383-7086 Product ID: PRINT CARTRIDGES FOR DESKJET PORTABLE, 51633A Cage: JO348 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 28480 Cage: JO348 ======================================================= Item Description Information ======================================================= Item Manager: GSA Item Name: INK,CARTRIDGE Unit of Issue: EA UI Container Qty: 0 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 (ORAL RAT) >2000 MG/KG Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: SKIN: IRRITATION. CONT WITH SKIN MAY CAUSE IRRITATION. EYES: IRRITATION. CONT W/EYES MAY CAUSE IRRIT. DYES IN INK MAKE EXPOSURE EASY TO DETECT. SYMPS OF EXPOSURE ARE DESCRIBED BELOW. INGEST: M AY CAUSE GASTRIC DISTURBANCES. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH WITH LARGE AMOUNTS OF WARM WATER FOR AT LEAST 15 MINUTES. SKIN: WASH AFFECTED AREA W/SOAP & WATER. INGEST: DILUTE WITH WATER. GET MED ATTN. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING(GI VE O*2/ARTF RESP)(FP N). ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: USE ABSORBENT TOWEL TO WIPE UP INK. RINSE AREA WITH DAMP CLOTH TO REMOVE REMAINING TRACES OF INK. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: AVOID CONTACT BETWEEN THE GOLD CARTRIDGE FACE & EYES, SKIN & CLTHG. RAPID REMOVAL OF INK WITH SOAP & WATER FROM SKIN PREVENTS IRRITATION & STAINING. Other Precautions: KEEP OUT OF THE REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: >255F,>124C Extinguishing Media: WATER, DRY CHEMICAL, CARBON DIOXIDE, FOAM. Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT(FP N). Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER. ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATORY APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >230F,>110C Vapor Pres: 15 @ 20C Vapor Density: 3.0 EST Spec Gravity: 1.1 Solubility in Water: COMPLETELY MISCIBLE Appearance and Odor: BLACK LIQUID, PRACTICALLY ODORLESS. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: STABLE UNDER NORMAL STORAGE CONDITIONS. Materials To Avoid: NONE. Hazardous Decomposition Products: NONE. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Trans ID NO: 132317 Product ID: PRINT CARTRIDGES FOR DESKJET PORTABLE, 51633A Review Date: 11/15/1994 Multiple KIT Number: 0 Review IND: Y Unit Of Issue: EA Container QTY: 0 ======================================================= Detail DOT Information ======================================================= DOT PSN Code: ZZZ DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail IMO Information ======================================================= IMO PSN Code: ZZZ IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION ======================================================= Detail IATA Information ======================================================= IATA PSN Code: ZZZ IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= Detail AFI Information ======================================================= AFI PSN Code: ZZZ AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION ======================================================= HAZCOM Label ======================================================= Product ID: PRINT CARTRIDGES FOR DESKJET PORTABLE, 51633A Cage: JO348 Assigned IND: Y Company Name: HEWLETTE-PACKARD CO Street: 11311 CHINDEN BLVD Zipcode: 83714 Label Required IND: Y Date Of Label Review: 08/30/1994 Status Code: C Label Date: 08/30/1994 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: AVOID SKIN & EYE CONTACT. ACUTE: SKIN: IRRITATION. CONT WITH SKIN MAY CAUSE IRRITATION. EYES: IRRITATION. CONT W/EYES MAY CAUSE IRRIT. DYES IN INK MAKE EXPOSURE EASY TO DETECT. INGEST: MAY CAUSE GAST RIC DISTURBANCES. CHRONIC: NONE LISTED BY MFR. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:126 8200 KODALITH LIQUID DEVELOPER,PART B,KAN 365864 CAGE:19139 CAGE:19139 CAGE:82960 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM CARBONATE CAS:584-08-7 RTECS #:TS7750000 Fraction by Wt: 10 - 15% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 5-10% Other REC Limits:NONE RECOMMENDED Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SODIUM BROMIDE CAS:7647-15-6 RTECS #:VZ3150000 Fraction by Wt: <1% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION:LOW HAZARD FOR RECOMMENDED HANDLING. EYE:CAUSES BURNS. SKIN:CAUSES IRRITATION. INGESTION:HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF G/I TRACT IF SWALLOWED. Explanation of Carcinogenicity:IN ADDITION TO THE ABOVE, PRODUCT IS NEGATIVE W/REGARD TO:ACGIH CANCER, CALIFORNIA CANCER & REPRODUCTIVE EFFECTS. Effects of Overexposure:EYE:BURNS. SKIN:IRRITATION. INGESTION:HARMFUL. BURNS OF G/I TRACT. Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION ON MSDS. ======================= First Aid Measures ======================= First Aid:IF ANY SYMPTOMS OCCUR, GET IMMEDIATE MEDICAL ATTENTION. INHALATION:IF SYMPTOMATIC, MOVE TO FRESH AIR. EYE:FLUSH W/PLENTY OF WATER FOR 15 MIN. SKIN:FLUSH W/WATER 15 MIN. REMOVE CONTAMINATED CLOTHING &LAUNDER BEFORE REUSE. INGESTION:DO NOT INDUCE VOMITING. GIVE VICTIM GLASS OF WATER. NOTHING BY MOUTH IF UNCONSCIOUS. CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:FLUSH TO SEWER W/LARGE AMOUNTS OF WATER. Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE;DISPOSE OF PROPERLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NEEDED IN NORMAL SERVICE. Ventilation:USE GENERAL DILUTION VENTILATION WITH 10 AIR CANGES/HOUR. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health KEY1;C2.FOR PART A REFER TO 6750-00-958-6549. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=100.C, 212.F Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.25 pH:13 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID - ODORLESS Percent Volatiles by Volume:66 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE UNDER NORMAL CONDITIONS OF USE Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER W/LARGE AMOUNTS OF WATER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CALCIUM CHLORIDE, ANHYDROUS CAGE:0U103 CAGE:0U103 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 1000 MG/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: UNLIKELY ENTRY ROUTE, MAY CAUSE MILD IRRITATION OF NOSE/THROAT. SKIN: CONTACT WITH SKIN OR EYES MAY CAUSE SEVERE IRRITATION OR BURNS. INGESTION: MAY CAUSE NAUSEA AND VOMITING. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:INHALATION: UNLIKELY ENTRY ROUTE, MAY CAUSE MILD IRRITATION OF NOSE/THROAT. SKIN CONTACT: MAY CAUSE SEVERE IRRITATION AND BURNING. INGESTION: MAY CAUSE NAUSEA AND VOMITING, GASTROINTESTINAL IRRITATION OR ULCERATION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:VAPS ARE UNLIKELY DUE TO PHYSICAL PROPERTIES. INHAL IS AN UNLIKELY ENTRY ROUTE. SKIN CNTCT:REMOVE CLTHG FROM AFFECTED AREA. WASH SKIN CAREFULLY. RINSE CAREFULLY. EYE:FLUSH W/H*2O FOR AT LEAST 15 MIN IMMED LIFTING EYELIDS OCCAS. CONSULT A MD. INGEST:INDUCE VOMIT IMMED. CALL A MD. INGEST MAY CAUSE GI EVENINGS (612) (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:TOXIC GAS PRODUCED - HYDROGEN CHLORIDE. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILLS TO PREVENT CONTAMINATION OF WATER SUPPLY OR SANITARY SEWER SYSTEM. DISPOSE OF ACCORDING TO LOCAL REQUIREMENTS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONSIDERABLE HEAT IS GENERATED WHEN MIXED WITH WATER. LEATHER CLOTHING AND SHOES WILL BE DAMAGED BY CALCIUM CHLORIDE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION EXISTS. IN THE ABSENCE OF ADEQUATE VENTILATION, CARE SHOULD BE EXERCISED TO LIMIT EXPOSURE OF PERSONNEL TO THE VAPORS. NIOSH APPROVED RESPIRATOR APPROPRIATE FO R EXPOSURE OF CONCERN . Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . UNIFORMS ARE RECOMMENDED. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRST AID PROC: (612) 476-1127 (MINNESOTA) OR (510) 791-0775 (CALIFORNIA). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:1935F,1057C Melt/Freeze Pt:M.P/F.P Text:782F,417C Solubility in Water:0.745 Appearance and Odor:SMALL, WHITE HYDROSCOPIC, DELIQUESCENT GRANULES ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS AND OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OR BYPRODUCTS; HYDROGEN CHLORIDE, HYDROCHLORIC ACID, AND CHLORINE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. WASH AWAY WITH LARGE EXCESS OF WATER. KEEP OUT OF WATER SOURCES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:STOVE BRIGHT HIGH TEMP PAINT (BULK) CAGE:FRRES CAGE:FRRES ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 0-5% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:SILICATE, MICA CAS:12001-26-2 RTECS #:VV8760000 Fraction by Wt: 0-5% OSHA PEL:20 MPPCF ACGIH TLV:3 MG/M3 RDUST Ingred Name:BENZENE. VP:100 MM HG @ 26.1 C CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <0.02% OSHA PEL:1PPM;5STEL ACGIH TLV:10 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:CHROMIUM CAS:7440-47-3 RTECS #:GB4200000 Fraction by Wt: 0-10% OSHA PEL:1 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TOLUENE. VP: 25@20C CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 20-60% OSHA PEL:200 PPM;150 STEL ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE. VP: 5.1@20C CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 0-10% OSHA PEL:100 PPM;150 STEL ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ALCOHOL; (BUTANOL). VP: 7@20C CAS:71-36-3 RTECS #:EO1400000 Fraction by Wt: 0-10% OSHA PEL:100 PPM ACGIH TLV:50 PPM,S,C, EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYL ALCOHOL (ETHANOL). VP: 42@60F CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 0-10% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:STODDARD SOLVENT; (MINERAL SPIRIT). VP: 5@20C CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 0-5% OSHA PEL:500 PPM ACGIH TLV:100 PPM Ingred Name:ALUMINUM METAL CAS:7249-90-5 RTECS #:BD0330000 Fraction by Wt: 0-25% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICIC ACID (POLYORTHO); (AMORPHOUS SILICA) CAS:1343-98-2 RTECS #:VV8853000 Fraction by Wt: 0-1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 0-25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CHROMIUM (III) OXIDE (2:3); (CHROMIUM (III) OXIDE (MFR CAS # 68905-79)) CAS:1308-38-9 RTECS #:GB6475000 Fraction by Wt: 0-10% OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 Ingred Name:ANTIMONY CAS:7440-36-0 RTECS #:CC4025000 Fraction by Wt: 0-5% OSHA PEL:0.5 MG/M3 ACGIH TLV:0.5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:COPPER CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: 0-5% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:COBALT CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: 0-2% OSHA PEL:0.1 MG/M3 ACGIH TLV:0.05 MG/M3 DUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE MAY AFFECT BRAIN/NERV SYS, CAUSING DIZZINESS, HEADACHE/NAUSEA. MAY CAUSE EYE, SKIN, NOSE AND THROAT IRRITATION. HARMFUL IF SWALLOWED. OVEREXPOSURE MAY CAUSE EYE DAMAGE. NOTE:TOLUEN E APPEARS ON NAVY LISTING OF OCCUP CHEMREPROD HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS (EFTS OF OVEREXP) Explanation of Carcinogenicity:CHROMIUM: IARC MONO, VOL 49, PG 49, 1990: GRP 1. NTP 6TH ANNUAL REPORT ON CARCIN, 1991: KNOWN TO BE CARCIN. (SUPDAT) Effects of Overexposure:HLTH HAZ: CONCERNING LATEST HAZ LIST INFO & SAFE HANDLING & EXPOS INFO . Medical Cond Aggravated by Exposure:BRONCHITIS, DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR. ADMINISTER OXYGEN/ARTF RESP. EYES: WASH WITH LARGE QTY OF FRESH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH W/SOAP AND WATER. REMOVE CONTAMD CLTHG. INGEST: DRINK 1-2 GLASSES OFWATER TO DILUTE. DO NOT INDUCE VOMIT. CONSULT PHYS OR POIS CTL CTR IMMED. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:<50.0F,10.0C Lower Limits:1% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . HAZ DECOMP PROD MAY FORM FROM INCOMPLETE COMBUSTION. Unusual Fire/Explosion Hazard:FLAMM. CLSD CONTRS CAN BUILD PRESS UNDER HEAT & RUPTURE EXPLOS. VOLATILE VAPS CAN BURN IN OPEN/EXPLODE IF CONFINED. VAP HVR/AIR & CAN TRAVEL LONG DIST (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVAC ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA IF POSSIBLE. AVOID BREATHING VAPORS. DIKE; USE ABSORBANT. USE NON-SPARK TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 120F. STORE ONLY IN RED LABEL APPROVED AREA. KEEP AWAY FROM ALL SOURCES OF IGNITION. Other Precautions:CONTENTS UNDER PRESS. EXPOSURE TO HEAT MAY CAUSE BURSTING. DO NOT PUNCT, INCIN(BURN) OR STORE ABOVE 120F. AVOID PROLONGED EXPOSURE TO SUNLIGHT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENT IS INADEQ TO REDUCE VAPS BELOW TLV LEVELS, USE NIOSH/MSHA APPROVED POSITIVE PRESSURE BREATHING APPARATUS/SOLVENT APPROVED RESPIRATOR. Ventilation:SUFF VENT, IN VOL & PATTERN SHOULD BE PROVIDED TO KEEP AIR CONTAM BELOW TLV. REMOVE HEAVY SOLV FROM LOWER WORK AREAS. Other Protective Equipment:PROTECTIVE APRON SHOULD BE USED WHEN SPLASH PROTECTION NEEDED. Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOM. Supplemental Safety and Health EXPLO HAZ: TO SOURCE OF IGNIT. EXPLAN OF CARCIN: HUMAN/ANIMAL: LUNG CANCER, SKIN ULCERS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>100F,>38C Vapor Pres:SEE INGRED Vapor Density:HVR/AIR Spec Gravity:0.96-1.12 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:79-91 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORSEEABLE. Stability Condition to Avoid:HIGH TEMPERATURES, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:CARBON MONOXIDE, OTHER TOXIC GASES IF INCOMPLETE COMBUSTION CONDITIONS EXIST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF AS HAZARDOUS WASTE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KRC=150-A CAGE:5X384 CAGE:5X384 ============= Composition/Information on Ingredients ============= Ingred Name:AROMATIC SOLVENT Fraction by Wt: 100% ACGIH TLV:300 PPM (MFR) ===================== Hazards Identification ===================== Effects of Overexposure:PROLONGED INHAL OF HIGH VAP CONC POSS RESULTS RANGING FROM DIZZINESS & HEADACHES TO UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF H*2O FOR @ LEAST 15 MIN. SKIN: REMOVE CONTAM CLOTHING,WASH SKIN W/SOAP & H*2O. INHAL: REMOVE FROM EXPOSURE IMMEDIATELY. INGEST: DO NOT INDUCE VOMITING,CALL PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:200F(93.3C), TCC Lower Limits:1.5 Upper Limits:8.0 Extinguishing Media:FOAM,DRY CHEMICAL,CO*2,H*2O SPRAY/FOG. Fire Fighting Procedures:USE AIR-SUPPLIED RESCUE EQUIPMENT FOR ENCLOSED(SEE SUPP DATA Unusual Fire/Explosion Hazard:DO NOT STORE/MIX W/STRONG OXIDANTS.COMBUSTIBLE LIQUID.FIRE & EXPLOSION HAZARD WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:ADD ABSORBANT TO SPILL AREA.KEEP PETROLEUM PRODUCTS OUT OF SEWERS & WATERWAYS. ======================Handling and Storage ====================== Handling and Storage Precautions:MATERIAL STABLE UNDER NORMAL STORAGE & USAGE.KEEP AWAY FROM SPARKS,OPEN FLAME.AVOID PRLNG/RPTD SKIN CONTACT. REMOVE,WASH CONTAM CLOTHING BEFORE REUSE. Other Precautions:USE W/ADEQUATE VENTILATION.NO SMOKING/OPEN LIGHTS. VENTILATION: W/FACE VELOCITY OF 60 FPM. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED HYDROCARBON VAP CANISTER/SUPPLIED-AIR HOSE MASK. Ventilation:MECH EXPLO-PROOF VENT EQUIP & LOCAL EXHAUST (SEE OTHR PRECAU Other Protective Equipment:HYDROCARBON INSOLUBLE APRON IF NEEDED. Supplemental Safety and Health VAP PRESS:40 @ 25C. SPECIAL FIRE FIGHT PROC:AREA.COOL EXP CNTNR W/H*2O. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:260-300F Vapor Density:3.9 Spec Gravity:0.92 Evaporation Rate & Reference:0.2 (BUTYL AC) Solubility in Water:MISCIBLE Appearance and Odor:WATER WHITE LIQ,MILD AROMATIC HYDROCARBON ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDANTS LIKE LIQ CHLORINE & CONCENTRATED OXYGEN. Hazardous Decomposition Products:IF INCOMPLETE COMBUSTION,CO. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IAW FEDERAL,STATE & LOCAL REGULATIONS.DISPOSE OF WASTE BY SUPERVISED INCINERATION/IN CHEMICAL DISPOSAL IN COMPLIANCE W/REGULATIONS.
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:TRICHLOROMETHANE, METHYLENE TRICHLORIDE. CAGE:60777 CAGE:60777 ============= Composition/Information on Ingredients ============= Ingred Name:CHLOROFORM(SARA III) CAS:67-66-3 RTECS #:FS9100000 Fraction by Wt: 100% OSHA PEL:(C) 50 PPM ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Explanation of Carcinogenicity:CHLOROFORM IS SUSPECTED BY NTP AND IARC TO BE CARCINOGENIC. Effects of Overexposure:POISON,HARMFUL IF INHALED.MAY CAUSE IRRITATION.CANCER SUSPECT AGENT. ======================= First Aid Measures ======================= First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O2 IF NEED;EYES/SKIN:FLUSH W LG AMTS H2O FOR 15 MIN;INGEST:RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER SYMPTOMS OF OVEREXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:UNKN Upper Limits:UNKN Unusual Fire/Explosion Hazard:WHEN INVOLVED IN FIRE,CHLOROFORM EMITS HIGHLY TOXIC AND IRRITATING FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION.ABSORB ON SAND,GROUND OR VERMICULITE.CAREFULLY SWEEP UP AND REMOVE,FLUSH SPILL AREA WITH WATER & RECOVE INTO A CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER IN A COOL PLACE,PREFERABLY NOT ABOVE 30C. WASH THOROUGHLY AFTER HANDLING. Other Precautions:AVOID BREATING VAPORS,CONTACT OF EYES,SKIN,AND CLOTHING.ITEM IS SUSPECTED CARCENOGEN(PER ACGIH) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXCED TLV,NIOSH/MSHA APPR SELF-CNTND BRTHG APP (POS PR MODE) Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV. Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health MSDS IS UNDATED ================== Physical/Chemical Properties ================== HCC:T4 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=61.1C, 142.F Vapor Pres:100 Vapor Density:4.12 Spec Gravity:1.49 Solubility in Water:SLIGHTLY Appearance and Odor:COLORLESS LIQUID;HEAVY,ETHEREAL ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES EXCESS WATER;STRONG ALKALIES. Stability Condition to Avoid:OPEN FLAME Hazardous Decomposition Products:PHOSGENE,HCL ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS AND CONTACT PROFESSIONAL DISPOSAL SERVICE
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ALBEMET 150 Resp. Party Other MSDS Num.:M13 Preparer's Name:MARC KOLANZ CAGE:4B151 CAGE:4B151 ============= Composition/Information on Ingredients ============= Ingred Name:BERYLLIUM CAS:7440-41-7 RTECS #:DS1750000 = Wt:50. OSHA PEL:0.002 MG/M3 ACGIH TLV:0.002 MG/M3 Ingred Name:ALUMINIUM CAS:7429-90-5 RTECS #:BD0330000 = Wt:50. Code:F OSHA PEL:15 MG/M3 ACGIH TLV:10 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: PROD IS INSOL & DOES NOT CAUSE ACUTE HLTH EFTS. CHRONIC: INHALING DUST/FUMES CNTNG BERYLLIUM MAY CAUSE SERIOUS, CHRONIC LUNG DISEASE CALLED CHRONIC BERYLLIUM DISEASE (CBD) IN SOME INDIVIDUALS.OVER TIME LUNG DISEASE CAN BE FATAL. SYMPS MAY INCL COUGH, CHEST PAIN, SHORTNESS OF BREATH, WT LOSS, WEAK, & FATG. LONG-TERM EFTS MAY INCL LOSS OF LUNG FUNC, FIBROSIS/SUBSEQUENT SECONDARY EFTS ON HEAR T W/EVENTUAL PERM IMPAIRMENT. CHRONIC BERYLLIUM DISEASE IS A HYPERSENSITIVITY/ALLERGIC RXN IN WHICH TISS OF LUNGS BECOME INFLAMED W/CELLULAR NODULAR RXN. THIS INFLAMM, SOMETIMES (EFTS OF OVEREXP) Explanation of Carcinogenicity:BERYLLIUM: IARC MONOGRAPHS ON EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 58, PAGE 41, 1993: GROUP 1. NTP 8TH ANNUAL RPT ON CARCINS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGE N. Effects of Overexposure:HLTH HAZ: W/ACCOMPANYING FIBROSIS, MAY RESTRICT EXCHANGE OF OXYG BETWEEN LUNGS & BLOODSTREAM. THIS ALLERGIC RESPONSE TO BERYLLIUM IS LIMITED TO SUSCEPTIBLE PERSONS. MED SCIENCE SUGGESTS SUSCEPTIBILITY IS RELATED TO GENETIC FACTORS. EXPOS TO AIRBORNE BERYLLIUM DOES NOT CAUSE CHRONIC RXN IN MOST PEOPLE. Medical Cond Aggravated by Exposure:PERSONS W/IMPAIRED PULM FUNC, AIRWAY DISEASES/ CNDTNS SUCH AS ASTHMA, EMPHYSEMA, CHRONIC BRONCH, ETC MAY INCUR FURTHER IMPAIRMENT IF EXCESS CONCS OF DUST/FUME ARE INHALED. CONT NEHC FOR MORE INFO ======================= First Aid Measures ======================= First Aid:INHAL: BRTHG DFCLTY CAUSED BY INHAL OF DUST/FUME REQS IMMED REMOVAL TO FRESH AIR. THERE ARE NO KNOWN CASES IN WHICH PERSON STOPPED BRTHG AS RSLT OF EXPOS. IF BRTHG HAS STOPPED, PERFORM ARTF RESP & OBT AIN MED HELP. INGEST: SWALLOWING METAL POWDER/DUST CAN BE TREATED BY HAVING PERSON DRINK LG QTYS OF WATER & ATTEMPTING TO INDUCE VOMIT, IF CONSCIOUS. OBTAIN MED HELP. SKIN: SKIN CUTS & ABRASIONS SHOUL D BE TREATED BY STD FIRST AID. SKIN CONTAM W/DUST OR POWDER CAN BE REMOVED BY WASHING W/SOAP & WATER. OBTAIN MED HELP IF IRRIT PERSISTS. ACCIDENTAL (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:ONLY IN POWDER/OTHER FINELY DIVIDED FORM DOES BERYLLIUM & ALUMINUM PRESENT SPEC FIRE PROBLEM. TO EXTING METAL POWDER FIRE, USE CLASS D FIRE EXTING POWDER. DO NOT USE (TOX INFO) Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . DO NOT USE WATER TO EXTING FIRES AROUND OPERATIONS INVOLVING MOLTEN METAL DUE TO POTNTL FOR STEAM EXPLOSIONS. Unusual Fire/Explosion Hazard:INGOTS/SOLIDS MAY CNTN SHRINKAGE CAVITIES WHICH PERMIT ENTRAPMENT OF WATER. TO ELIM MOISTURE PRIOR TO USE IN ANY MELTING OPERATION & TO SAFEGUARD AGAINST POSS STEAM EXPLO HAZS, INGOTS SHOULD BE THORO DRY BEFORE CHARGING INTO FURNANCE. PREHEATING OF INGOTS IS DESIRABLE PRIOR TO MELTING. MOLTEN ALUMINUM IN (OTHER INFO) ================== Accidental Release Measures ================== Spill Release Procedures:IN SOLID FORM MATL POSES NO HLTH/ENVIRONMENTAL RISK. IF IN PWDR/DUST FORM, ESTABLISH RESTRICTED ENTRY ZONE BASED ON SEVERITY OF SPILL. PERS MUST WEAR ADEQ NIOSH APPRVD RESP PROT & PROT CLTHG. CLEANUP SHOULD BE CONDUCTED W/VACUUM SYS UTILIZING HIGH EFFICIENCY PARTICULATE AIR (HEPA) FILTRATION SYS FOLLOWED BY WET CLEANING METH. SPEC PRECS MUST BE TAKEN WHEN (TOX INFO) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DURING REPAIR/MAINT ACTIVITIES POTNTL EXISTS FOR EXPOS TO CONSTITUENTS IN EXCESS OF OCCUP STDS; PROTECTING WORKERS CAN REQ USE OF SPECIFIC WORK PRACTICES/PROCEDURES INVOLVING COMBINED USE OF VENT, WET & VACUUM CLEANING METHS. RESP PROT, DECONTAM, SPEC PROT CLTHG, & WHEN NEC, RESTRICTED WORK ZONES. Other Precautions:I/A/W OSHA REGS WELDING/CUTTING INDOORS, OUTDOORS OR IN CONFINED SPACES INVOLVING BASE/FILLER METALS SHALL BE DONE USING LOCAL EXHST VENT & AIRLINE RESPS UNLESS ATM TESTS UNDER MOST ADVERSE CNDTNS HAV E ESTABLISHED WORKER'S EXPOS IS W/IN ACCEPTABLE CONCS DEFINED BY 29 CFR 1910.1000. FOR MORE INFO CON T NECH . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN POTNTL EXPOS ARE ABOVE OCCUP LIMITS, NIOSH APPRVD RESPS MUST BE USED AS SPECIFIED BY INDUS HYGIENIST/OTHER QUALIFIED PROFESSIONAL.RESP USERS MUST BE MEDICALLY EVAL TO DTERM IF THEY ARE PHYSICALLY CAPABLE OF WEARING RESP. QUANTITATIVE AND/OR QUALITATIVE FIT TESTING & RESP TRAINING MUST BE SATISFACTORILY COMPLETED BY ALL PERS (TRANSPORTATION INFO) Ventilation:USE OF LOC EXHST VENT/OTHER ENGINEERING CTLS IS PREF METH OF CONTROLLING EXPOS TO AIRBORNE DUST & FUME. FOR INFO CONT NECH . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . NO PROT EQUIP REQD WHEN HNDLG SOLID FORMS. FOR MORE INFO CONT NECH . Work Hygienic Practices:VACUUM/WET CLEANING METHS REC FOR DUST REMOVAL. VACUUM CLEANERS W/HIGH EFFICIENCY PARTICULATE AIR FILTERS ARE REC TYPE. Supplemental Safety and Health FIRST AID PROC: IMPLANTATION OF MATL BENEATH SKIN REQS IT BE REMOVED TO PVNT INFECTION/DEVELOPMENT OF CORN-LIKE LESION. EYES: DUST/POWDER SHOULD BE FLUSHED W/LOT OF CLEAN WATER FOR AT LST 15 MINS. OBT IAN MED HELP IF IRRIT PERSISTS. CONT LENSES MUST BE REMOVED TO PROVIDE ADEQ TREATMENT. (OTHER INFO) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=1148.9C, ######F Spec Gravity:0.079 LB/IN3 (DENSITY) Solubility in Water:NONE Appearance and Odor:GRAY SOLID; NO ODOR. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS W/ACIDS & CAUSTIC SOLNS TO PRDCE HYDROGEN GAS; CAN BE EXPLO HAZ. POWDERED ALUMINUM & CHLORINATED HYDROCARBONS MAY REACT WITH EXPLOSIVE FORCE. Hazardous Decomposition Products:NONE UNDER NORMAL CONDITIONS OF USE. =================== Toxicological Information=================== Toxicological Information:FOR QUESTIONS CONCERNING TOXICOLOGY INFORMATION WRITE TO: MEDICAL DIRECTOR, BRUSH WELLMAN INC., 14710 WEST PORTAGE RIVER SOUTH ROAD, ELMORE, OHIO 43416-9502. --EXTINGUISHING MEDIA: WATER TO EXTINGUISHFIRES AROUND OPERATIONS INVOLVING MOLTEN METAL DUE TO POTENTIAL FOR STEAM EXPLOSIONS. --SPILL PROC: CHANGING FILTERS ON HEPA VACUUM CLEANERS USED TO CLEAN UP POTENTIALLY TOXIC MATERIALS. CAUTION SHOU LD BE TAKEN TO MINIMIZE AIRBORNE GENERATION OF POWDER/DUST & AVOID CONTAMINATION OF AIR & WATER. FOR MORE SPECIFIC INFORMATION CONTACT NEHC . ===================== Ecological Information ===================== Ecological:THIS MATERIAL IS INSOLUBLE IN WATER. THIS MATERIAL CAN BE RECYCLED; CONTACT SALES REPRESENTATIVE. ENVIRONMENTAL SURVEY: EXPOSURE TO AIRBORNE MATERIALS SHOULD BE DETERMINED BY HAVING AIR SAMPLES TAKEN IN EMPLOYEE BREATHING ZONE, WORK AREA, & DEPARTMENT. FREQUENCY & TYPE OF AIR SAMPLING SHOULD BE AS SPECIFIED BY INDUSTRIAL HYGIENIST/OTHER QUALIFIED PROFESSIONAL. AIR SAMPLE RESULTS SHOULD BE MADE AVA ILABLE TO EMPLOYEES. ==================== Disposal Considerations ==================== Waste Disposal Methods:SOLID WASTE MANAGEMENT: WHEN SPENT PRODS ARE DECLARED SOLID WASTES (NO LONGER RECYCLABLE), THEY MUST LBLD, MANAGED & DISPOSED OF I/A/W FED, STATE & LOC REQUIREMENTS. MATL IS NOT CLASSIFIED A HAZ WASTEUNDER FED LAW. BYPRODUCT RECYCLING: FOR MORE INFORMATION CONT NEHC . =================== MSDS Transport Information =================== Transport Information:THERE ARE NO U.S. DEPARTMENT OF TRANSPORTATION HAZ MATL REGS WHICH APPLY TO PACKAGING & LBLG OF THIS PROD AS SHIPPED BY BRUSH WELLMAN. FOR MORE INFO CONT NECH . --RESP PROT: PRIOR TO RESP USE. U SERS OF ANY TYPE RESP MUST BE CLEAN SHAVEN ON THOSE AREAS OF FACE WHERE RESP SEAL CONTACTS FACE. EXPOS TO UNKNOWN CONCS OF FUMES/DUST REQS WEARING NIOSH APPRVD PRESS-DEMAND AIRLINE RESP/PRESS-DEMAND S CBA. NIOSH APPRVD PRESS-DEMAND AIRLINE RESPS ARE REC WHEN PERFORMING JOBS W/HIGH POTNTL EXPOS SUCH AS CHANGING FILTERS IN BAGHOUSE AIR CLEANING DEVICE. ===================== Regulatory Information ===================== SARA Title III Information:ON FEB 16, 1988 U.S. EPA ISSUED FINAL RULE THAT IMPLEMENTS REQUIREMENTS OF SARA TITLE III, SECTION 313 (53) FED REGISTER 4525. TITLE III IS PORTION OF SARA CONCERNING EMER PLANNING & COMMUNITY RIGHT-T O-KNOW ISSUES. SECTION 313 COVERS ANNUAL EMISSION REPORTING ON SPECIFIC CHEMS WHICH ARE MANUFACTURED, PROCESSED/USED AT CERTAIN U.S. INDUST FACILITIES. BERYLLIUM IS REPORTABLE UNDER SECTION 313. CHEMABSTRACT SERVICES NUMBERS ARE LISTED IN INGRED SECTION OF MSDS. MAY OBTAIN ADDNL INFO BY CALLING EPA SARA TITLE III HOTLINE @ 1-800-535-0202(OR 202-555-1411). Federal Regulatory Information:AMBIENT AIR EMISSIONS: BERYLLIUM-CNTNG MATLS ARE SUBJECT TO NATL EMISSION STD FOR BERYLLIUM AS PROMULGATED BY EPA (40 CFR 61, SUBPART C)L NATL EMISSION STD FOR BERYLLIUM IS 0.01 MICROGRAMS PER CUBIC M ETER (30 DAY AVERAGE) IN AMBIENT AIR FOR THOSE PRODUCTION FACILITIES WHICH HAVE BEEN QUALIFIED TO BE REGULATED THROUGH AMBIENT AIR MONITORING. OTHER FACILITIES MUST MEET 10 GRAM PER 24-HR TOTAL SITE E MISSION LIMIT. MOST PROCESS AIR EMISSSION SOURCES WILL REQ AIR PERMIT FROM LOC AND/OR STATE AIR POLL UTION CONTROL AGENCY. (STATE REGULATORY INFO) State Regulatory Information:FED REGULATORY: USE OF AIR CLEANING EQUIP MAY BE NECESSARY TO ACHIEVE PERMISSABLE EMISSION. TEMPERED MAKEUP AIR SHOULD BE PROVIDED TO PVNT EXCESS NEG PRESS IN BUILDING. DIRECT RECYCLING OF CLEANED PRO CESS EXHST AIR IS NOT REC. PLANT EXHSTS SHOULD BE LOCATED SO AS NOT TO RE-ENTER PLANT THROUGH MAKEUP AIR/OTHER INLETS. REGULAR MAINTENANCE & INSPECTION OF AIR CLEANING EQUIP & MONITORING OF OPERATING PARAMETERS IS REC TO ENSURE ADEQ EFFICIENCY IS MAINTAINED. WASTEWATER: WASTEWATER REGS CAN VARY CONS IDERABLY. CONT LOC & STATE GOVTS TO DETERM REQS. CONT NECH FOR MORE INFO . ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PERMA-STEEL SHOT CAGE:42736 CAGE:42736 ============= Composition/Information on Ingredients ============= Ingred Name:MANGANESE (SARA III). (PERCENTAGE 0.5-1.3) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: 1.3% Other REC Limits:1 MG/M3; 3 STEL FUME OSHA PEL:5 MG/M3 DUST ACGIH TLV:5 MG/M3 C Ingred Name:CARBON BLACK; (CARBON). (PERCENTAGE 0.8-1.3) CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 1.3% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:SILICON. (PERCENTAGE 0.4-1.2) CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: 1.2% Other REC Limits:15 MG/M3 (MFR) OSHA PEL:10 MG/M3 TDUST ACGIH TLV:10MG/M3 TDUST;5 RESP Ingred Name:SUPP DATA: CLASSED AS A HAZ WASTE AND AS SUCH, MUST BE DISPOSED OF ACCORDING TO APPROP LOCAL, STATE, OR FEDERAL REGS. RTECS #:9999999ZZ Ingred Name:MELTING PT: >1371C, >2403F. RTECS #:9999999ZZ Ingred Name:IRON (III) OXIDE CAS:1309-37-1 RTECS #:NO7400000 Fraction by Wt: > 96% OSHA PEL:5 MG/M3 (FE) ACGIH TLV:5 MG/M3 (FE) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION OF DUST CREATED DURING USE; SHOT, GRIT OR DUST PARTICLES IN EYES. PROLONGED OVEREXPOSURE TO MANGANESE DUST OR FUME CAN CAUSE METAL FEVER. CHRONIC OVEREXPOSURE CAN CAUSE MANGANESE POISONING. OVEREXPOSURE TO DUST CONTAINING THE COMPONENT ELEMENTS OF CAST STEEL ABRASIVE MAY CAUSE SKIN, NOSE, MOUTH & EYE IRRIT. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH RUNNING WATER FOR AT LEAST 15 MIN TO REMOVE PARTICULATE. GET ADDITIONAL ATTENTION BY A QUALIFIED MEDICAL PERSON. SKIN: BRUSH OFF EXCESS DUST. WASH AREA WELL WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION. INGEST: SEEK MEDICAL HELP IF LARGE QUANTITIES OF MATERIAL HAVE BEEN INGESTED. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE DRY CHEMICALS OR SAND TO EXCLUDE AIR. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:SOLID FORM IS NOT COMBUSTIBLE. FIRE/EXPLO HAZ MOD WHEN IN DUST FORM/EXPOSED TO HEAT/FLAME/CHEMICAL REACTION/CONTACT WITH POWERFUL OXIDIZER. ================== Accidental Release Measures ================== Spill Release Procedures:CAST STEEL SHOT OR GRIT SPILLED OR LEAKED ONTO FLOORS CAN CAUSE HAZ WALKING CNDTNS. SPILLS OR LEAKS SHLD BE VACUUMED OR SWEPT FORM WORKING AREAS. WHEN CLEANING UP LRG QTYS OF DUST, NIOSH/MSHA APPRVD R ESP SHLD BE WORN. SPILLED SHOT & GRIT (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE MATL AWAY FROM INCOMPATIBLE MATERIALS, AND KEEP DUST AWAY FROM SOURCES OF IGNITION. KEEP DRY TO REDUCE RUSTING. Other Precautions:OBSERVE MAXIMUM FLOOR LOADING LIMITATIONS. THE COMPANY HAS NO CONTROL OVER THIS PRODUCT OR ITS USE AFTER IT LEAVES OUR FACILITY. THE COMPANY ASSUMES NO LIABILITY FOR LOSS OR DAMAGE FROM THE PROPER ORIMPROPER USE OF THIS PROD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE DUST CREATED BY USE EXCEEDS THE TLV'S INDICATED IN INGRED SECTION, A NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN. Ventilation:GENERAL AND LOCAL EXHAUST VENTILATION SHLD BE PROVIDED TO KEEP THE DUST LEVELS BELOW TLV'S SHOWN IN INGREDIENT SECTION. Other Protective Equipment:SAFETY EYEWASH STATIONS SHOULD BE PROVIDED IN CLOSE PROXIMITY TO WORK AREA. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health APPEAR & ODOR: COLOR W/SLIGHT METALLIC ODOR. BOILING PT: >2850C,>5162F. SPILL PROT: CAN BE RECLAIMED FOR REUSE OR DISPOSED OF AS A NON-HAZ SOLID WASTE. COLLECTED DUST FROM BLAST CLEANING/ SHOT PEENING OPERATIONS ALWAYS CONTAIN CONTAM FROM THE SURFACE OF THE PARTS BEING PROCESSED, & THEREFORE THE DUST MAY BE (ING 5) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:SUPP DATA Melt/Freeze Pt:M.P/F.P Text:ING 6 Spec Gravity:>7.6 @ 60F Appearance and Odor:SHOT IS NEAR SPHERICAL. GRIT IS ANGULAR. BOTH ARE GREY TO BLUE IN (SUPP DATA) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE. SHOT AND GRIT WILL BREAK DOWN INTO PROGRESSIVELY SMALLER PARTICLES DURING NORMAL USE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CATION EXCHANGE RESIN, DOWEX HCR-W2 H+ FORM, 1927 CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SULFONATED COPOLYMER OF STYRENE AND DIVINYLBENZENE; (SULFONATED COPOLYMER) CAS:69011-20-7 Fraction by Wt: 44-51% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 49-56% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN/EYES: IRRITATION. INHALATION/INGESTION: NONE IDENTIFIED. CHRONIC: NONE IDENTIFIED. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGESTION: IF PERSON IS CONSCIOUS, IMMEDIATELY GIVE LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: IF BREATHING IN LARGE AMOUNTS, MOVE TO FRESH AIR. SKIN: IMMEDIATELY WASH WITH SOAP AND PL ENTY OF WATER FOR AT LEAST 15 MINUTES. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL OR ORDINARY FOAM. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CONTRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOS CONTRS COOL. Unusual Fire/Explosion Hazard:CAN BE AN EXPLOSION HAZARD, ESPECIALLY WHEN HEATED. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY SWEEP UP AND REMOVE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE A NIOSH/MSHA APPROVED APPROPRIATE RESPIRATOR OR DUST MASK. Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP FUME OR DUST LEVELS AS LOW AS POSSIBLE. Other Protective Equipment:NONE SPECIFIED BY MFR Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Solubility in Water:NEGLIGIBLE (<0.1%) Appearance and Odor:LIGHT YELLOW TO AMBER BEADS, ODORLESS Percent Volatiles by Volume:52 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT. Hazardous Decomposition Products:OXIDES OF SULFUR, VARIOUS SUBSTITITED BENZENES, CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BRELL-A-PLEX 1475 LIGHT BASE SERIES CAGE:HO230 CAGE:6F145 CAGE:HO230 ============= Composition/Information on Ingredients ============= Ingred Name:WATER BASE ACRYLIC EMULSION Fraction by Wt: 100% ======================= First Aid Measures ======================= First Aid:EYE:FLUSH WITH WATER 15 MINUTES. SKIN:WASH WITH SOAP AND WATER. INHALATION:REMOVE FROM EXPOSURE. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:SUFFICIENT FOR SURROUNDING AREA. Fire Fighting Procedures:SELF-CONTAIN BREATH APP, WATER FOG TO COOL EXPOSED CONTAINER Unusual Fire/Explosion Hazard:EXTREME HEAT MAY CAUSE CANS TO EXPLODE DUE TO PRESSURE BUILD UP. ================== Accidental Release Measures ================== Spill Release Procedures:PICK UP ======================Handling and Storage ====================== Handling and Storage Precautions:NORMAL STORAGE FOR LATEX PAINT. ============= Exposure Controls/Personal Protection ============= Ventilation:GENERAL Supplemental Safety and Health ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:3375-3435 LETTERPRESS Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:COPPER COMPOUND Fraction by Wt: 17% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:R-22 Preparer's Name:DGSC-VBA/HMIS CAGE:02LX8 CAGE:02LX8 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORODIFLUOROMETHANE (SARA 313) (CERCLA) CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9495 Ozone Depleting Chemical:2 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV 1,000 PPM. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:CNS, EYE, SKIN, LUNG. ACUTE- HARMFUL IF INHALED. MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. INTENTIONAL MISUSE IS FATAL. VAPOR REDUCES OXYGEN & IS HEAVIER THAN AIR. EYE/SK IN CONTACT WITH LIQUID CAN CAUSE FROSTBITE. VAPORS CAN CAUSE EYE IRRITATION. INGESTION IS UNLIKELY. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANAESTHETIC EFFECTS SUCH AS DIZZINESS, HEADACHE, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUSNESS, IRREGULAR PULSE, PALPITATIONS, INADEQUATE CIRCULATION, FROST BILTE, IRRITATION, BLURRED VISION, TEARING Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF NEEDED. EYE/SKIN:IMMEDIATELY FLUSH WITH PLENTY OF WATER. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED. ORAL:INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPO SURE. NOTE TO PHYSICIAN:CATECHOLAMINE DRUGS SHOULD BE USED WITH SPECIAL CAUTION ONLY IN SITUATIONS OF EMERGENCY LIFE SUPPORT. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER, CO2, FOAM OR DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. SEE 1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE NO 12. Unusual Fire/Explosion Hazard:THIS PRODUCT CAN BE DECOMPOSED BY HIGH TEMPERATURES (OPEN FLAMES, GLOWING METALS) FORMING HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND TRACES OF CARBONYL HALIDES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF-CONTAINED BREATHING APPARATUS FOR LARGE SPILLS OR RELEASES. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA, AWAY FROM FLAMES & INCOMPATIBLE MATERIALS. DO NOT HEAT ABOVE 125F. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. USE WITH ADEQUATE VENTILATION. NEVER USE IN CONFINED OR CLOSED SPACES WITHOUT PROPER PROTECTIVE E QUIPMENTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IF A LARGE RELEASE OCCURS. Ventilation:NORMAL VENTILATION IS SUFFICIENT. LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED, MECHANICAL VENTILATION IN LOW PLACES Other Protective Equipment:EYEBATH, SAFETY SHOWER, PROTECTIVE CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING. Supplemental Safety and Health THIS MSDS WAS PREPARED BY THE PROFESSIONALS OF DGSC-VBA/HMIS WITHOUT ANY WARRANTY. IT IS THE USER'S RESPONSIBILITY TO GATHER INFORMATION AND USE THE MATERIAL PROPERLY TO PROTECT EMPLOYEES AND ENVIRONM ENT. OTHER TRADE NAME: REFRIGERANT 12. ================== Physical/Chemical Properties ================== HCC:G3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:-41F,-41C Melt/Freeze Pt:M.P/F.P Text:-256F,-160C Decomp Temp:Decomp Text:1170F,632C Vapor Density:3.03 @ 77F Spec Gravity:1.194 (LIQUID) Viscosity:NOT RELEVANT Evaporation Rate & Reference:>1 (CCL4 = 1) Solubility in Water:0.30 BY WT @ 25C/77F Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS - SLIGHT ETHEREAL ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, ZINC, BERYLLIUM, ETC. Stability Condition to Avoid:FLAME, GLOWING METAL SURFACES Hazardous Decomposition Products:MAY FORM HYDROGEN FLUORIDE, HYDROGEN CHLORIDE AND TRACES OF CARBONYL HALIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM BY DISTILLATION. CONSULT LOCAL, STATE AND FEDERAL AUTHORITIES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HOMSA08,06, HOME SAFEGUARD, SMOKE DETECTOR TESTER, HOME SAFE Resp. Party Other MSDS Num.:1103 Preparer's Name:J. STATEN CAGE:7K472 CAGE:7K472 ============= Composition/Information on Ingredients ============= Ingred Name:MIXTURE OF: PROPANE/ISOBUTANE CAS:68476-86-8 = Wt:98. ACGIH TLV:1000 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Health Hazards Acute and Chronic:SKIN/INHALATION: NONE KNOWN. EYE: DIRECT CONTACT OF PRODUCT WITH EYES MAY CAUSE IRRITATION, AND MAY RESULT IN IRREVERSABLE DAMAGE. INGESTION: IF INGESTED MAY CAUSE NAUSEA AND VOMITING. IF IN AEROSOL F ORM INGESTION NOT LIKELY. Explanation of Carcinogenicity:NOT PROVIDED Effects of Overexposure:SKIN/INHALTION: NONE KNOWN. EYE: DIRECT CONTACT OF PRODUCT WITH EYES MAY CAUSE IRRITATION, AND MAY RESULT IN IRREVERSABLE DAMAGE. INGESTION: IF INGESTED MAY CAUSE NAUSEA AND VOMITING. IF IN AEROSOL FO RM INGESTION NOT LIKELY. CHRONIC EFFECTS OF OVEREXPOSURE NOT KNOWN. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:SKIN: WASH EXCESS MATERIAL FROM SKIN WITH SOAP AND WATER. EYES: FLUSH EYES WITH GENEROUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT PHYSICIAN IF IRRITAITON OCCURS OR WORSENS. INGESTION: PRODUCTIS NOT LIKELY TO BE INGESTED. IF THIS OCCURS, TREAT SYMPTOMATICALLY. NEVER GIVE FLUIDS OR INDUCE VOMITING IF THE VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS. INHALATION: MOVE TO FRESH AIR, AID IN BRE ATHING, IF NECESSARY, AND GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:=-94.4C, -138.F Autoignition Temp:=468.3C, 875.F Lower Limits:1.8% Upper Limits:9.5 Extinguishing Media:DRY CHEMICAL, WATER, CARBON DIOXIDE Fire Fighting Procedures:KEEP TEMPERATURE OF CONTAINERS BELOW 120F BY SPRAYING WITH WATER UNTIL FIRE HAS BEEN EXTINGUISHED. Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE AND RELEASE FLAMMABLE GAS IF EXPOSED TO HEAT OF FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:LEAKING CONTAINERS SHOULD BE PLACED OUTDOORS, IN AN OPEN CONTAINER, AWAY FROM SOURCE OF IGNITION. Neutralizing Agent:NOT PROVIDED ======================Handling and Storage ====================== Handling and Storage Precautions:NOT PROVIDED Other Precautions:NOT PROVIDED ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR WHEN VAPORS ARE GENERATED ABOVE THE PERMISSABLE LIMIT. Ventilation:LOCAL EXHAUST TO CONTROL RECOMMENDED PEL NECESSARY TO PREVENT SKIN CONTACT. EYEWASH FOUNTAINS SHOULD BE EASILY ACCESSIBLE. Work Hygienic Practices:AVOID EXCESSIVE INHALTION. READ AND FOLLOW ALL LABEL DIRECTIONS AND CAUTIONS. Supplemental Safety and Health MSDS 1103 ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:=-42.2C, -44.F Vapor Pres:70-80PSIG@70F Vapor Density:1.764 Volatile Org Content %:100 Spec Gravity:~0.537@60F Evaporation Rate & Reference:>1 (BUAC=1) Solubility in Water:0.008% BY WEIGHT @70F Appearance and Odor:FINE MIST AEROSOL SPRAY; ESSENTIALLY ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS OXYGEN OR FLUORINE. Stability Condition to Avoid:DONOT EXPOSE TO HEAT OR FLAME Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION. =================== Toxicological Information=================== Toxicological Information:NO RESULTS AVAILABLE ===================== Ecological Information ===================== Ecological:HAZARDOUS WASTE CODE: D001. CONTAINER MAY BE RECYCLED IN THE FEW BUT GROWING NUMBER OF COMMUNITIES WHERE STEEL AEROSOL CAN RECYCLING IS AVAILABLE. BEFORE OFFERING FOR RECYCLING, EMPTY THE CAN BY USING THE PRODUCT ACCORDING TO THE LABEL. DO NOT PUNCTURE. IF RECYCLING IS NOT AVAILABLE, WRAP THE CONTAINER & DISCARD IN THE TRASH. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY OR INCINERATE IN APPROVED DISPOSAL FACILITY AND IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT: CONSUMER COMMODITY (DOMESTIC), AEROSOLS, FLAMMABLE, N.O.S., UN 1950 (EXPORT). ===================== Regulatory Information ===================== Federal Regulatory Information:NOT PROVIDED State Regulatory Information:NOT PROVIDED
1
eyes_protection_mandatory
======================================================= Product ID: 20-400 WHITE SATIN HOUSE PAINT Cage: 0NWE2 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 0NWE2 ======================================================= Contractor Summary ======================================================= Cage: 0NWE2 ======================================================= Ingredients ======================================================= Cas: 107-21-1 RTECS #: KW2975000 % Wt: 3.36 Other REC Limits: 10 MG/CUM ACGIH TLV: C 127 MG/CUM EPA Rpt Qty: 1 LB DOT Rpt Qty: 1 LB ------------------------------ RTECS #: 9999999WG ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: NO Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INGESTION: LIVER OR KIDNEY DAMAGE. EYE & SKIN IRRITANT. Explanation Of Carcinogenicity: NONE First Aid: EYES: FLUSH W/LARGE QUANTITIES OF WATER FOR 15 MINS. SKIN: WASH THOROUGHLY W/SOAP & WATER. INGESTION: INDUCE VOMITING IMMEDIATELY. SEE PHYSICIAN IMMEDIATELY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DIKE SPILL AREA W/ABSORBENT EARTH OR SAWDUST. COLLECT IN METAL CONTAINER FOR DISPOSAL. Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE, & LOCAL REGULATIONS. Handling And Storage Precautions: STORE IN COOL DRY PLACE. AVOID FREEZING. Other Precautions: AVOID CONTACT W/SKIN & EYES. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point Text: 241F Extinguishing Media: FOAM WATER SPRAY (FOG), DRY CHEMICAL, CO2 Fire Fighting Procedures: RESPIRATORY PROTECTIVE EQUIPMENT SHOULD BE WORN TO AVOID INHALATION OF CONCENTRATED VAPORS. USE WATER ONLY AS A FOG TO KEEP NEARBY CONTAINERS COOL. ======================================================= Control Measures ======================================================= Respiratory Protection: WHEN SPRAYING THIS MATERIAL USE A NIOSH APPROVED MASK. WHEN USING IN POORLY VENTILATED & CONFINED SPACE, USE FRESH AIR SUPPLYING RESPIRATOR OR SCBA. Ventilation: GENERAL MECHANICAL VENTILATION OR LOCAL EXHAUST SHOULD BE SUITABLE TO KEEP VAPOR CONCENTRATIONS BELOW TLV. Other Protective Equipment: APRONS OR PROTECTIVE CLOTHING Work Hygienic Practices: WASH HANDS OR FACE BEFORE EATING OR SMOKING AFTER HANDLING THIS MATERIAL. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: 212-380F Vapor Density: >1 Evaporation Rate & Reference: SLOWER THAN ETHER ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: HEAT, FREEZING Materials To Avoid: WATER-SENSITIVE MATERIALS Hazardous Decomposition Products: CO, CO2 Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 20-400 WHITE SATIN HOUSE PAINT Cage: 0NWE2 Company Name: H-I-S PAINT MFG Street: 1801 W RENO Zipcode: 73106-5000 Label Required IND: Y Date Of Label Review: 09/30/1993 Status Code: C Label Date: 09/30/1993 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Slight Fire Hazard: Slight Reactivity Hazard: None Hazard And Precautions: INGESTION: LIVER OR KIDNEY DAMAGE. EYE & SKIN IRRITANT. TARGET ORGANS: LIVER, KIDNEY, EYES, SKIN. STEM, BRAIN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:QUIXPRAY PROPELLNT RFILL,COMPLETE KIT-(SUP) Preparer's Name:T LIGHT,D HAMRICK CAGE:60088 CAGE:60088 ============= Composition/Information on Ingredients ============= Ingred Name:HALOGENATED HYDROCARBONS Fraction by Wt: 100% Other REC Limits:N/K OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:N/K Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:POSSIBLE CARDIAC ARRHYTHMIAS AT HIGH CONCENTRATIONS.INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING VAPORS AND INHALING CONTENTS CAN BE HARMFUL OR FATAL. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES/SKIN/INGESTION:N/K .INHALATION:LIGHT HEADEDNESS,GIDDINESS,SHORTNESS OF BREATH,POSSIBLE NARCOSIS,POSSIBLE CARDIAC ARRHYTHMIAS AT HIGH CONCENTRATIONS.SOME TOXIC EFFECTS.CAN BE IRRITATING IN HIGHER CONCENTRATIONS. Medical Cond Aggravated by Exposure:N/K ======================= First Aid Measures ======================= First Aid:EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.GET MEDICAL ATTENTION.SKIN:FLUSH WITH PLENTY OF WATER FOLLOWED BY A SOAP AND WATER WASH.INGESTION:GIVE WATER TO DRINK TO DILUTE IN STOMACH;ABOUT 250 ML (1/2 PINT).GET MEDICAL ATTENTION.INHALATION:REMOVE TO FRESH AIR AND CALL PHYSICIAN.DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS.MAKE CERTAIN THIS INFORMATION IS PASSED ON TO THE PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NO RESTRICTIONS Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA & FULL PROTECTIVE APPLICABLE PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:CANS EXPOSED TO HIGH TEMPERATURES MAY EXPLODE FROM PRESSURE.MAY PRODUCE CORROSIVE/TOXIC COMBUSTION PRODUCTS SUCH AS HYDROCHLORIC & HYDROFLUORIC ACIDS,PHOSGENE. ================== Accidental Release Measures ================== Spill Release Procedures:PROVIDE ADEQ VENT.REMOVE/SHUT OFF ALL COMBUSTION SOURCES.WEAR APPROP PROT EQUIP (AT LEAST VINYL LOCATION TO ALLOW COMPLETE EVAPORATI ON UNDER CONTROLLED CONDITIONS INTO THEAIR. Neutralizing Agent:N/K ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT SPRAY INTO OR AROUND OPEN FLAME AND SPARK.EXPOSURE TO HEAT OR SUNLIGHT OR WHERE TEMPERATURE EXCEEDS 120F,49C MAY CAUSE BURSTING. Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT MAY CAUSE THE FORMATION OF HCL AND/OR UV RADIATION AND/OR PHOSGENE . ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ORGANIC VAPOR/SELF-CONTAINED. Ventilation:MECHANICAL (GENERAL) HOOD/EQUIVALENT;OTHER AS REQUIRED. Other Protective Equipment:N/K Work Hygienic Practices:N/K Supplemental Safety and Health PART NO:UNIT.0011160,0011165,0011175,1803720.VAPOR DENSITY:3.9-4.9 (AIR=1).ROUTES OF ENTRY:INHALATION/SKIN/INGESTION .ESTIMATED TLV:1000 PPM (MFR). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<68F,<20C Melt/Freeze Pt:M.P/F.P Text:N/K Decomp Temp:Decomp Text:N/K Vapor Pres:>85 PSIG Vapor Density:SEE SUPP Spec Gravity:1.485 (WATER=1) Solubility in Water:SLIGHT Appearance and Odor:COLORLESS LIQUID;SLIGHT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS. Stability Condition to Avoid:NORMALLY NON-REACTIVE.HIGH TEMPERATURES AND OPEN FLAMES. Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS,POSSIBLY PHOSGENE. Conditions to Avoid Polymerization:WILL NOT OCCUR UNDER NORMAL CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS .FOR AEROSOL CAN:DO NOT PUNCTURE OR INCINERATE.WHEN ALL LIQUID IS EXPELLED,CONTINUE TO DEPRESS BUTTON UNTIL ALL GAS IS EXP ELLED,THEN PLACE IN APPROPRIATE WASTE CONTAINER.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:21868 SELECTIVE SEVEN H11 AGAR CAGE:06531 CAGE:05545 CAGE:06531 CAGE:15481 ============= Composition/Information on Ingredients ============= Ingred Name:PREPARED PLATED MEDIA CLASSIFIED AS GENERAL IN USE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATERSPRAY Fire Fighting Procedures:PRODUCT WILL NOT BURN. IF PRODUCT BECOMES INVOLVED IN A FIRE SITUATION EXTINGUISHING MEDIA FOR SURROUNDING MATERIAL SHOULD BE APPROPRIATE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PAPER TOWELS TO PICK UP GELLED MATERIAL. WASH AREA W/SOAP & WATER AFTER CLEANUP IS COMPLETED. ============= Exposure Controls/Personal Protection ============= Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD BE PRACTICED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Appearance and Odor:GELLED MEDIA OF VARYING COLORS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ASEPTIC TECHNIQUES & ESTABLISHED PRECAUTIONS AGAINST MICROBIOLOGICAL HAZARDS THROUGHOUT ALL PROCEDURES. AFTER USE, PREPARED PLATES, SPECIMEN CONTAINERS & OTHER CONTAMINATED MATERIALS MUST BE S TERLIZED BY AUTOCLAVING. FOLLOW ALL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ACTIVATOR/CLEAR,826-S CAGE:DO229 CAGE:18873 CAGE:DO229 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 6.0% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC ALCOHOL Fraction by Wt: 25.0% Ingred Name:2-ETHOXYETHANOL (EGEE) (SARA III) CAS:110-80-5 RTECS #:KK8050000 Fraction by Wt: 19.7% OSHA PEL:S,200 PPM ACGIH TLV:S, 5 PPM; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ALIPHATIC PETROLEUM DISTILLATE Fraction by Wt: 5.0% Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5.0% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Effects of Overexposure:COUGHNG,CHEST PAIN/BREATHNG DIFFICULTY MAY OCCUR.EARLY SIGNS MAY BE MISTAKEN FOR A COLD. ======================= First Aid Measures ======================= First Aid:SKIN:WASH WITH SOAP AND WATER. EYES: FLUSH WITH WATER. INHALED: REMOVE TO FRESH AIR. REMOVE CONTAMINATED CLOTHING;GET MED ATTN FOR EYES. ===================== Fire Fighting Measures ===================== Flash Point:RANGE 20-73F-CC Lower Limits:1.0 Upper Limits:12.0 Extinguishing Media:CO*2, FOAM, DRY CHEM. Fire Fighting Procedures:USE WATER SPRAY TO COOL CONT, KNOCK-DOWN VAPORS. WEAR SCBA. Unusual Fire/Explosion Hazard:VAPOR & SPRAY MISTS ARE HARMFUL ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & OPEN FLAME;CLOSE CONTAINER AFFTER EACH USE;DO NOT STORE ABOVE 120F Other Precautions:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR SMOKING.OBSERVE LABEL PRECAUTIONS.CONTAINERS SHOULD BE GROUNDED WHEN POURING;ALLERGY-PRONE PERSON MAY BE SENSITV SHOULD NOT BE EXPSD ISOCYNATE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA TC-19C AIRLINE UNIT OR TC-23C VAPOR/PARTCULATE ISGOOD Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:USE APPROPRIATE INDUSTRIAL HYGIENE PRACTICE Supplemental Safety and Health HAZ COMPNTS CONTND:39.3% NON AQUEOUS SOLN,HAZ UNKNOWN,UNIDENTIFIED;VAP DENSITY/VAP PRESSURE NOTED FOR PRINCIPAL SOLVENT;MSDS FM MFR DATED:09/14/81: ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:176-302F Vapor Pres:UNK Vapor Density:UNK Spec Gravity:0.883 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:APPRECIABLE Appearance and Odor:SEMI-VISCOUS LIQUID WITH CHARACTERISTIC ODOR. Percent Volatiles by Volume:64.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES PER MFR,NONE REASONABLY FORESEEABLE;BUT AVOID CORR/OXIDZR Stability Condition to Avoid:HEAT, IGNITION SOURCES;DO NOT MIX ACTVTR W/ENAMEL UNTILREADY Hazardous Decomposition Products:CO,CO*2,SMOKE,OXIDES OF NITROGEN,NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SLICE AWAY AEROSOL, 5049 Preparer's Name:M PERKINS CAGE:JO107 CAGE:47993 CAGE:JO107 ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-; (D-LIMONENE) LD50 (ORAL RAT): 4400 MG/KG CAS:5989-27-5 RTECS #:GW6360000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NONYLPHENOL POLYETHYLENE GLYCOL ETHER; LD50 (ORAL RAT): 1310 MG/KG CAS:127087-87-0 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OCTYLPHENOXY POLYETHOXYETHANOL; LD50 (ORAL RAT): 1800 MG/KG CAS:9036-19-5 RTECS #:MD0907600 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA) CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: <0.1% OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:P-DIOXANE; (DIETHYLENE DIOXIDE) (SARA 313) (CERCLA) CAS:123-91-1 RTECS #:JG8225000 Fraction by Wt: <0.1% OSHA PEL:100 PPM, S ACGIH TLV:25 PPM, S EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ACETALDEHYDE (SARA 313) (CERCLA) CAS:75-07-0 RTECS #:AB1925000 Fraction by Wt: <0.1% OSHA PEL:200 PPM ACGIH TLV:C 25PPM, A3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA) CAS:50-00-0 RTECS #:LP8925000 Fraction by Wt: <0.1% OSHA PEL:SEE 1910.1048 ACGIH TLV:C 0.3 PPM, A2 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:FIRST AID PROC: INGEST: GIVE 3-4 GLASSES OF WATER, BUT DO NOT INDUCE VOMIT. IF VOMIT OCCURS, GIVE FLUIDS AGAIN. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: GET IMMED MED ATTN IF DISCOMFORT OCCURS. NOTES TO MD: INGEST & SUBSEQUENT VOMIT CAN LEAD TO ASPIR OF (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: PRODUCT INTO LUNGS WHICH CAN CAUSE DAMAGE AND MAY BE FATAL. RTECS #:9999999ZZ Ingred Name:SUP DAT: ETHYLENE OXIDE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ LIST. CONSULT APPROP HEALTH PROFESSIONALS (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: CONCERNING LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE INFORMATION . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES SEV IRRIT SEEN AS TEARING, REDNESS, PAIN, EXCESS BLINKING, SWELL OF CONJUNCTIVA & BURNING SENSATION. PRLNG CONT MAY CAUSE BURNS, CORNEAL INJURY/VISUAL IMPAIRMENT. SKIN: MAY CAUSE I RRIT SEEN AS ITCH & REDNESS. RPTD/PRLNGCONT MAY CAUSE DERM & MAY ALLOW ABSORPTION OF POTENTIALLY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: HARMFUL AMTS THRU SKIN. MAY CAUSE SENSIT & ALLERGIC SKIN RXN. INHAL: MAY CAUSE IRRIT W/COUGHING & SNEEZING, NAUS, NASAL DISCHARGE/CHEST PAIN. INHAL OF HICH CONCS OF VAP CAUSES DIZZ, DISORIEN TATION, HDCH, EXCITATION, CNS DEPRESS/ANESTH. MAY CAUSE ALLERGIC RESP RXN. INGEST: CAUSES GI IRRIT W/POSS (SUP DAT) Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY AND SKIN CONDITIONS SUCH AS ASTHMA, EMPHYSEMA, AND DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHAL: MOVE TO FRESH AIR. SEEK MED ATTN IF RESP IRRIT DEVELOPS/IF BRTHG BECOMES DFCLT. EYES: IMMED RINSE W/WATER. REMOVE ANY CONT LENSES, & CONTINUE FLUSHING EYES FOR AT LEAST 15 MIN. HOLD EYELIDS APA RT TO ENSURE RINSING OF ENTIRE SURF OF EYES & LIDS W/WATER. GET IMMED MED ATTN. SKIN: WASH W/SOAP & WATER FOR SEVERAL MIN. REMOVE & CLEAN CONTAM CLTHG & SHOES. SEEK MED ATTN IF IRRIT DEVELOPS.(ING 10) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:116F,47C Lower Limits:0.7% Upper Limits:6.1% Extinguishing Media:FOAM, "ALCOHOL" FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROT EQUIP . DO NOT DIRECT DIRECT STREAM OF WATER INTO BURNING POOLS AS IT MAY CAUSE FROTHING & INCREASE FIRE INTENSITY. Unusual Fire/Explosion Hazard:SPRAY EXPOSED AEROSOL CONTAINERS WITH WATER SPRAY TO AVOID RUPTURING. FLAME EXTENSION IS >30 INCHES, BURNBACK IS 4 INCHES. ================== Accidental Release Measures ================== Spill Release Procedures:DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS UNLIKELY. FOR A SMALL SPILL, ABSORB WITH AN INERT MATERIAL AND TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR DISPOSAL. WEAR A PPROPRIATE PROTECTIVE CLOTHING. Neutralizing Agent:NONE. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE OR STORE NEAR HEAT, HOT SURFACES, SPARKS OR OPEN FLAME. USE ONLY WITH SUFFICIENT VENTILATION. Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE USING THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. A NIOSH APPROVED RESPIRATOR IN POORLY VENTILATED AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV OR OSHA PEL. Ventilation:GEN MECH VENT IS NORN ADEQUATE. LOCAL VENT IS RECOMMENDED TO CONTROL EXPOS FROM OPERATIONS THAT CAN GENERATE MISTS/VAPS. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . GENERAL DUTY WORK CLOTHES AND PROTECTIVE SHOES. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SPEC GRAV: 0.838-0.843 (H*2O=1). EFTS OF OVEREXP: NAUS, VOMIT/DIARR. INGEST & SUBSEQUENT VOMIT CAN LEAD TO ASPIR OF PROD INTO LUNGS WHICH CAN CAUSE DMG & MAY BE FATAL. COMPRESSED LIQ MAY CAUSE FREEZE BURNS. CHRONIC: NO ADDNL CHRONIC EFTS ARE KNOWN. TARGET ORGANS: NONE KNOWN. (ING 13) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:375F,191C Vapor Pres:1.66 Vapor Density:4.8 Spec Gravity:SUP DAT Evaporation Rate & Reference:0.2 (BUTYL ACETATE=1) Solubility in Water:EMULSIFIABLE Appearance and Odor:COLORLESS TRANSPARENT; ORANGE ODOR Percent Volatiles by Volume:85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS & ALKALIS, IODINE, PENTAFLUOROETHYLENE, REDUCING AGENTS, MATLS REACTIVE W/HYDROXYL COMPOUNDS. Stability Condition to Avoid:AVOID HEAT, HOT SURFACES, SPARKS AND OPEN FLAMES. Hazardous Decomposition Products:OXIDES OF CARBON AND ACRID SMOKE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HOUSE PAINT, 110-2A CAGE:09585 CAGE:09585 CAGE:91950 ============= Composition/Information on Ingredients ============= Ingred Name:MINERAL SPIRITS; (MINERAL SPIRITS/66) VP: 2 @ 20C%: 23.2-26.3 CAS:64742-47-8 Fraction by Wt: SEE ING OSHA PEL:100 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:MINERAL SPIRITS VP: <5.0 @ 100F CAS:64742-88-7 Fraction by Wt: 1.0-1.4% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:ZINC OXIDE CAS:1314-13-2 RTECS #:ZH4810000 Fraction by Wt: 11.8% OSHA PEL:10MG/M3 TDUST;5 RESP ACGIH TLV:5MG/M3;10 STEL(FUME) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:RESP IRRIT & CNS EFT-ANESTH. SKIN & EYES:PRIMARY IRRIT. INGEST:IRRIT OF DIGESTIVE TRACT & NERVOUS SYS DEPRESS (DROW, DIZZ, LOSS OF COORDINATION & FATG). ASPIR HAZ:MATL CAN ENTER LUNGS DURI NG SWALLOWING/VOMIT & CAUSE LUNG INFLAMM & DMG. CHRONIC:SKIN:RPT/ PRLNG EXPOS MAY CAUSE DERM. NOTICE: (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:RPTS HAVE ASSOC PERM BRAIN & NERVOUS SYS DMG W/RPT/PRLNG OVEREXP TO SOLV AMONG PERS ENGAGED IN PAINTING TRADE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHAL CONTENTS MAY BE HARMFUL /FATAL. Medical Cond Aggravated by Exposure:NONE EXPECTED WHEN USED IN ACCORDANCE WITH SAFE HANDLING & USE INFORMATION. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM HAZ AREA, MAINTAIN BRTHG, CALL MD. SKIN CONTACT: REMOVE W/SOAP & WATER. EYE CONTACT: FLUSH IMMED W/ LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. CALL MD. INGEST: DRINK 1 OR 2 GLASSE S WATER TO DILUTE. DO NOT INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:125F,52C Lower Limits:1.0% Upper Limits:NOT KNOWN Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . DO NOT USE WATER STREAM ON BURNING LIQUID. COOL EXPOSED CONTAINERS W/WATER. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. TOXIC GASES MAY FORM WHEN PRODUCT BURNS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID BRTHG VAPORS. USE NON-SPARKING TOOLS TO RETURN MATLS TO CONTAINER. ABSORB RESIDUE WITH FULLER'S EARTH. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTIBLE. KEEP AWAY FROM HEAT & FLAME. Other Precautions:USE ONLY W/ADEQUATE VENTILATION. AVOID PROLONGED CONTACT W/SKIN & BREATHING OF VAPOR SPRAY MIST/SANDING DUST. CLOSE CONTAINER AFTER EACH USE. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR SPECIFIED FOR PROTECTION AGAINST PAINT SPRAY MIST, SANDING DUST & ORGANIC VAPORS IN RESTRICTED/CONFINED AREAS. Ventilation:ADEQ TO MAINTAIN WORKING ATMOSPHERE BELOW TLV & LEL. MECH EXHST MAY BE REQD IN CONFINED AREAS. DISCHARGE EXHST (SUPDAT) Other Protective Equipment:CLOTHING ADEQUATE TO PROTECT SKIN. Work Hygienic Practices:REMOVE & WASH CLOTHING BEFORE REUSE. WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM. Supplemental Safety and Health VENT:ONLY IN AREA AWAY FROM IGNITION SOURCES. % VOLATILE (VOL): 41.8 - 44.8 ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>361F,>183C Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN Decomp Temp:Decomp Text:NOT KNOWN Vapor Pres:SEE ING1&2 Vapor Density:HVR/AIR Spec Gravity:1.23-1.33 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:PAINT. WHITE TINTS & COLORS Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE REASONABLY FORESEEABLE. Stability Condition to Avoid:ELEVATED TEMPERATURES & BUILD UP OF VAPORS. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON DIOXIDE AND CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONVENTIONAL PROCEDURES IN COMPLIANCE W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT INCINERATE SEALED CONTAINERS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:812 1857 FLEXICOLOR DEVELOPER REPLENISHER LORR,PART C Kit Part:Y CAGE:19139 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE CAS:25646-77-9 RTECS #:KJ6477000 Fraction by Wt: 40 - 45% Other REC Limits:NONE RECOMMENDED Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA) CAS:7631-90-5 RTECS #:VZ2000000 Fraction by Wt: 1 - 5% Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 50 - 55% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 25-50 MG/KG,ACTIVE ING Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, KIDNEY & GI TRACTS. ACUTE- WARNING! HARMFUL IF SWALLOWED. MAY CAUSE GI TRACT IRRITATION & KIDNEY DAMAGE BASED ON ANIMAL STUDY. MAY CAUSE EYE BURNS. SKIN CONTACT CAUSES IRRITA TION. MAY CAUSE ALLERGIC SKIN REACTION.INHALATION OF SULFUR DIOXIDE CAN CAUSE RESPIRATORY IRRITATION. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION AND BURNS Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL:IF CONSCIOUS, INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. WATER SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. MAY FORM HAZARDOUS DECONPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS OR STREAMS. ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. Neutralizing Agent:WEAK BASE ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL MINIMIZE SKIN REACTION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW TLV, USE NIOSH-APPROVED RESPIRATORY PROTECTION, TYPE ACID. Ventilation:GOOD GENERAL VENTILATION IS SUFFICIENT FOR MOST CONDITIONS (10 ROOM VOLUMES PER HOUR). Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF EXPOSURE. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health KEY1:C2. THIS PRODUCT IS A KIT CONSISTING OF THREE PARTS. PART A HAS PNI B, PART B HAS PNI C, PART C HAS PNI D, SAME NSN. WORKING SOLUTION HAS PNI W. PERCENTAGE OF INGREDIENTS FOR PART C CHANGED. FOR PREVIOUS PERCENTAGES, SEE PNI A, SAME NSN. ================== Physical/Chemical Properties ================== HCC:C2 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:>212F,>100C Decomp Temp:Decomp Text:338F,170C Vapor Pres:18 @ 68F Vapor Density:0.6 Spec Gravity:1.10 pH:2.0 Solubility in Water:COMPLETE Appearance and Odor:LIGHT YELLOW LIQUID - STRONG SULFUR DIOXIDE ODOR Percent Volatiles by Volume:50- 60 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, STRONG OXIDIZING AGENTS Stability Condition to Avoid:HEAT (TEMPERATURES ABOVE 158F/70C) Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BIO-DUR 461 BLACK FAIRING COMPOUND, BD461-17038 Preparer's Name:J. LONGMORE CAGE:THINF CAGE:THINF ============= Composition/Information on Ingredients ============= Ingred Name:EPOXY RESIN; (EPOXY RESIN LIQUID POLYMER) CAS:25085-99-8 Fraction by Wt: 35-50% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE, 1-CHLORO-2,3-EPOXY-; (EPICHLOROHYDRIN) (SARA III), (<75PPM) CAS:106-89-8 RTECS #:TX4900000 Fraction by Wt: <0.1% OSHA PEL:2 PPM, S ACGIH TLV:2 PPM, S EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: SLIGHT IRRIT, POSSIBLE SENSITIZER. EYE: SLIGHT IRRITANT. SKIN & EYE: SLIGHT IRRITATING, POSSIBLE SENSITIZERS. INGEST: CONSIDERED SLIGHTLY TOXIC. INHAL: OVEREXP TO MIST OR VAPOR IS EXTREMELY UNLI KELY HOWEVER INHALATION OF SPRAY MIST MIGHT CAUSE IRRIT OF RESP TRACT. PRLNGD/RPTD EXPOSURE MAY CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: AN ASTHMATIC REACTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN/EYE: IMMED FLUSH EYES WITH FRESH WATER HOLDING LIDS APART FOR AT LEAST 15 MIN, WASHING WITHIN ONE MINUTE IS ESSENTIAL TO ACHIEVE MAXIMUM EFFECTIVENESS. REMOVE FROM SKIN USING SOAP AND WATER. REMO VE CONTAM SHOES & CLTHG. CALL MD. INGEST: DO NOT INDUCE VOMIT! PVNT ASPIR (BRTHG) LIQ INTO LUNGS. GET MED ATTN. INHAL: IMMED MOVE TO FRESH AIR. IF BRTHG IS DIFFICULT GIVE OXYGEN. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:>250F,>121C Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:GENERATION OF TOXIC PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:SCRAPE OR WIPE UP SPILLED MATERIAL. PLACE IN CONTAINER FOR RECOVERY OR DISPOSAL. AVOID CONTACT WITH SKIN AND EYES - WEAR RECOMMENDED PROTECTIVE CLOTHING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHES. STORE IN A COOL, DRY AREA IN CLOSED CONTAINERS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC CHEMICAL CARTRIDGE RESP AS NEEDED, OTHERWISE WEAR NIOSH/MSHA APPROVED SCBA. Ventilation:MECHANICAL LOCAL EXHAUST AT POINT OF CONTAMINANT RELEASE IF CONDITIONS WARRANT. Other Protective Equipment:WEAR LONG SLEEVED SHIRTS, COVERALLS AS FOOTWEAR ETC. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health CNDTNS TO AVOID (STAB): EXPECT A SIGNIFICANT EXOTHERM WITH 25-30 MINUTES AT 70F. ================== Physical/Chemical Properties ================== HCC:T6 Spec Gravity:1.75 Solubility in Water:NEGLIGIBLE Appearance and Odor:BLACK PASTY LIQUID. SLIGHTLY SWEET CHARACTERISTIC EPOXY RESIN. Percent Volatiles by Volume:0.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:MIXING LARGE VOLUMES WITH EPOXY CURING AGENTS SUCH AS BIO-GARD 151-00000. VOLS OF ONE GALLON ARE SAFE HOWEVER(SUPP DATA) Hazardous Decomposition Products:CO, CO2, UNSPECIFIED OTHERS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CS Preparer's Name:THOMAS S. CROCKETT CAGE:ODH21 CAGE:ODH21 ============= Composition/Information on Ingredients ============= Ingred Name:O-CHLOROBENZYLIDENE MALONONITRILE CAS:2698-41-1 RTECS #:OO3675000 Other REC Limits:0.05 PPM OSHA PEL:S, C 0.05 PPM ACGIH TLV:S, C 0.05 PPM; 9192 Ingred Name:POTASSIUM CHLORATE CAS:3811-04-9 RTECS #:FO0350000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN: ALLERGIC REACTION. EYES: TEARING. INHALATION: IRRITATION OF RESPIRATORY TRACT. Explanation of Carcinogenicity:NONE Effects of Overexposure:SKIN: ALLERGIC REACTION. EYES: TEARING. INHALATION; IRRITATION OF RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:ALLERGIC SKIN REACTION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF NEEDED. EYES: FLUSH W/WATER. REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER. INGESTION: CONTACT PHYSICIAN. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, DRY CHEMICAL, WATER. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING, SWEEP MATERIAL ONTO PAPER, PLACE IN FIBER CARTON, INCINERATE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AWAY FROM HEAT, FLAMES & STRONG OXIDIZERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:EAR GAS-TYPE GAS MASK/SELF-CONTAINED BREATHING APPARATUS. Ventilation:LOCAL EXHAUST/MECHANICAL Other Protective Equipment:AS NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:310-315F Melt/Freeze Pt:M.P/F.P Text:95-96C Vapor Pres:0.000034 Spec Gravity:<1 Solubility in Water:SLIGHT Appearance and Odor:WHITE CRYSTALS, PUNGENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Hazardous Decomposition Products:BURNING MAY PRODUCE CO/CO2 ==================== Disposal Considerations ==================== Waste Disposal Methods:SHIP TO LICENSED INCINERATOR.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:IDOPHOR PVP SOLUTION CAGE:0S1P5 CAGE:0S1P5 ============= Composition/Information on Ingredients ============= Ingred Name:IODINE CAS:7553-56-2 RTECS #:NN1575000 Fraction by Wt: 1% Other REC Limits:0.1 PPM OSHA PEL:1 MG/CUM ACGIH TLV:C 1.0 MG/CUM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. INGESTION: HARMFUL. Explanation of Carcinogenicity:NONE ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER. INGESTION: GIVE SUSPENSION OF STARCH OR FLOUR IN WATER & INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER, CO2, POWDER ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP W/TOWELING. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID EXCESSIVE HEAT ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST Work Hygienic Practices:AS REQUIRED Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F Spec Gravity:1.04 Solubility in Water:COMPLETE Appearance and Odor:BROWN LIQUID W/MILD IODINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALI Stability Condition to Avoid:EXCESSIVE HEAT ==================== Disposal Considerations ==================== Waste Disposal Methods:DIPSOSE OF IN GARBAGE. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 70-0703-7722-4, SCOTCHLITE GLASS BUBBLES, (SUP DAT) Cage: 1BY21 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 1BY21 ======================================================= Ingredients ======================================================= Cas: 65997-17-3 % Wt: 97-100 OSHA PEL: 5 MG/M3 RESP DUST ACGIH TLV: 10 MG/M3 (<7MICRONS) ------------------------------ Cas: 112945-52-5 RTECS #: VV7310000 % Wt: <3 OSHA PEL: 6 MG/M3 ACGIH TLV: 10 MG/M3 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYES: MECH IRRIT INCL IRRIT, REDNESS, SCRATCHING OF CORNEA & TEARING. SKIN: MECH IRRIT INCL ITCH & REDNESS. INHAL: IRRIT (UPPER RESP) INCL SORENESS OF NOSE & THROAT, COUGHING & SNEEZING. WHILE THE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF THE INDIVIDUAL INGS IN THIS PROD & ARE REQUIRED TO BE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: INCL ON MSDS BY U.S. OSHA HAZ COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS DURING FORESEEABLE USE OF PROD: LUNG DMG INCL COUGHING, DFCLTY BRTHG, WHEEZING, TIGHTNESS IN CHEST, CONGESTION, & COUGHING UP OF BLOOD. INGEST: IRRIT OF GI TISS INCL PAIN, VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS & IN FECES. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IN HALATION: IF SIGNS/SYMPTOMS OCCUR, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL MD. INGESTION: DRINK TWO GLASSES OF WATER. CALL MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFO REGARDING PHYSICAL & HLTH HAZ, RESP PROT, VENT, & PERS PROT EQUIP. CALL (612) 733-1110 OR (612) 733-6100 FOR 24-HR SPILL ASSIST. VENT AREA. VACUUM, USE WE T SWEEPING CMPD/WATER TO AVOID DUSTING.(SUP DAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP OF WASTE PROD IN SANITARY LANDFILL. SINCE REGS VARY, CONSULT APPLIC REGS/AUTH BEFORE DISP. IN THE EVENT OF AN UNCONTROLLED RELEASE, THE USER SHOULD DETERMINE IF RELEASE QUALIFIES AS REPORTABLE QT Y. DISP OF I/A/W LOC, STATE & FED REGS (FP N). Handling And Storage Precautions: AVOID EYE AND SKIN CONTACT. AVOID INHALATION OF DUST. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. Other Precautions: USE IN WELL-VENTILATED AREA. KEEP CONTAINER DRY. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: NON-COMBUSTIBLE. CHOOSE MATERIAL SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED. ======================================================= Control Measures ======================================================= Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPRVD RESPS BASED ON AIRBORNE CONC OF CONTAMINANTS & I/A/W OSHA REGS: HALF-MASK DUST RESP, HALF-MASK HIGH-EFFICIENCY FILTER RESP, HALF-MASK SUPPLIED AIR RESP, FULL-F ACE DUST RESP, FULL-FACE HIGH- (SUP DAT) Ventilation: USE W/APPROP LOC EXHST VENT. PROVIDE APPROP LOC EXHST VENT AT TRANSFER POINTS. IF EXHST VENT IS NOT ADEQ, USE (SUP DAT) Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). WEAR COVERALLS, APRON. Work Hygienic Practices: WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER. DO NOT INGEST. Supplemental Safety and Health: TRADE NAME/PART #: TYPES B, K, L & S. SPILL PROC: CAUTION! VACUUM CLEANER COULD BE AN IGNIT SOURCE. PLACE IN APPRVD METAL CONTR & SEAL. RESP PROT: EFFICIENCY FILTER RESP, FULL-FACE SUPPLIED AIR RESP. VENT: APPROP NIOSH APPRVD RESP. ======================================================= Physical/Chemical Properties ======================================================= PH: BASIC Solubility in Water: SLIGHT Appearance and Odor: FINE POWDER (LESS THAN 10UM IN DIAMETER), WHITE, ODORLESS ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG ACIDS, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: SILICON TETRAFLUORIDE WHEN DISSOLVED IN HYDROFLUORIC ACID. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 70-0703-7722-4, SCOTCHLITE GLASS BUBBLES, (SUP DAT) Cage: 1BY21 Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV Street: 3M CTR Zipcode: 55144-1000 Label Required IND: Y Date Of Label Review: 11/04/1997 Status Code: C Label Date: 11/04/1997 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: EYES: MECHANICAL IRRITATION INCLUDING IRRITATION, REDNESS, SCRATCHING OF CORNEA AND TEARING. SKIN: MECHANICAL IRRITATION INCLUDING ITCHING AND REDNESS. INHALATION: IRRITATION (UPPER RESPIRATORY ) INCLUDING SORENESS OF NOSE AND THROAT, COUGHING AND SNEEZING. INGESTION: IRRITATION OF GASTROINTESTINAL TISSUE. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
======================================================= Product ID: 103613 LIQUID POR-SAN Cage: 29800 ======================================================= Preparer Co. when other than Responsible Party Co. ======================================================= Cage: 29800 ======================================================= Contractor Summary ======================================================= Cage: 29800 ======================================================= Ingredients ======================================================= Cas: 7732-18-5 RTECS #: ZC0110000 ------------------------------ Cas: 14808-60-7 RTECS #: VV7330000 IARC, NTP) % Wt: 15-35 Other REC Limits: 0.05 MG/CUM NIOSH ACGIH TLV: 0.1 MG/CUM RESP DUST ------------------------------ Cas: 144-62-7 RTECS #: RO2450000 % Wt: 1-10 Other REC Limits: 0.05 PPM OSHA PEL: 1 MG/CUM ACGIH TLV: 1 MG/CUM ======================================================= Health Hazards Data ======================================================= Route Of Entry Inds - Inhalation: NO Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYES: IRRITATION. SKIN: IRRITATION UPON REPEATED/PROLONGED CONTACT. INGESTION: CAUSES SEVERE STOMACH IRRITATION, MAY BE HARMFUL. Explanation Of Carcinogenicity: NONE First Aid: INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING, FLUSH W/PLENTY OF WATER. INGESTION: DRINK SEVERAL GLASSES OF WATER. OBTAIN MEDICAL A TTENTION IN ALL CASES. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: CONTAIN SPILL. DO NOT CONTAMINATE FOOD, FEED, OR WATER. Waste Disposal Methods: IN ACCORDANCE W/ALL LOCAL, STATE & FEDERAL REGULATIONS. THIS PRODUCT IS NOT CONSIDERED RCRA HAZARDOUS. Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. Other Precautions: CONTAINS CRYSTALLINE SILICA. INHALATION OF THE DUST IN EXCESS OF THE TLV OVER MAY YEARS MAY CAUSE DELAYED LUNG INJURY. USE OF IN ACCORDING TO LABEL DIRECTIONS WILL ELIMINATE THIS HAZARD. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: NONE Extinguishing Media: AS FOR SURROUNDING FIRES. ======================================================= Control Measures ======================================================= Work Hygienic Practices: REMOVE CONTAMINATED CLOTHING & WASH BEFORE REUSE. ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: <1 Spec Gravity: 1.08 PH: 9-9.8 Solubility in Water: APPRECIABLE Appearance and Odor: GREEN GRITTY LIQUID W/SASSAFRAS ODOR Percent Volatiles by Volume: 74 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Materials To Avoid: OXIDIZERS,HYDROFLUORIC ACID-COMPONENTS WILL DISSOLVE IN HYDROFLUORIC ACID & PRODUCE A CORROSIVE GAS (SILICON TETRAFLUORE Hazardous Decomposition Products: THERMAL DECOMPOSITION MAY YIELD OXIDES OF CARBON & NITROGEN & FORMIC ACID, Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 103613 LIQUID POR-SAN Cage: 29800 Company Name: HUNTINGTON LABORATORIES INC Street: 970 E TIPTON ST Zipcode: 46750-1611 Label Required IND: Y Date Of Label Review: 12/30/1993 Status Code: C Label Date: 12/30/1993 Origination Code: F Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: CAUTION Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: EYES: IRRITATION. SKIN: IRRITATION UPON REPEATED/PROLONGED CONTACT. INGESTION: CAUSES SEVERE STOMACH IRRITATION, MAY BE HARMFUL. TARGET ORGANS: EYES, SKIN DIGESTIVE TRACT. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TT-E-2784A CAGE:NO367 CAGE:NO367 CAGE:3F338 ============= Composition/Information on Ingredients ============= Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 25%) CAS:111-77-3 RTECS #:KL6125000 Fraction by Wt: 7.20% Other REC Limits:NONE RECOMMENDED Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 0.1%) CAS:770-35-4 Fraction by Wt: 1.30% Other REC Limits:NONE RECOMMENDED Ingred Name:VOC = 1.46 G/L, NON-EXEMPT SOLVENT PER ADJUSTED GALLON. RTECS #:9999999VO Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION. INHAL: IRRITATING TO NOSE/THROAT. INGEST:TOXIC. Effects of Overexposure:INHAL: HEADACHE, NAUSEA, VOMITING, DROWSINESS. Medical Cond Aggravated by Exposure:HEART CONDITIONS, ASTHMA. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES, GET MED AID. SKIN: WASH W/SOAP & WATER. REMOVE CONTAIM CLOTHES. INHAL: GET FRESH AIR. OXGEN IF NEEDED. INGEST: GIVE TWO GLASSES OF WATER. INDUCE VOMIT. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMBLE Extinguishing Media:CO2, FOAM. Fire Fighting Procedures:USE FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:COOL CONTAINERS W/WATER STEAM IN EVENT OF A FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE & CONTAIN. SOAK UP RESIDUE W/ABSORBENT MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. PROTECT FROM FREEZING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:REQUIRED. Ventilation:REQUIRED. Other Protective Equipment:APRON. Work Hygienic Practices:WASH AFTER HANDLING. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,156C Vapor Density:>AIR Evaporation Rate & Reference:VALUE NOT STATED Solubility in Water:100% Percent Volatiles by Volume:58.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE & UNIDENTIFIED ORGANIC COMPOUNDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN RECKA APPROVED FACILITY.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:7366 UNI-WELD Preparer's Name:RAYMOND L. OSWALT CAGE:UNIEL CAGE:UNIEL ============= Composition/Information on Ingredients ============= Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 80-90% Other REC Limits:590 MG/CUM OSHA PEL:200 PPM/300 STEL ACGIH TLV:200 PPM/300STEL 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 10-20% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION, DERMATITIS, & ABSORPTION. INHALATION: MUCOUS MEMBRANE IRRITATION, NOSE, THROAT, HEADACHE, DIZZINESS, NAUSEA, NUMBNESS OF THE EXTREMITIES, NARCOSIS; REPRODUCTIVE, LU NG, LIVER, KIDNEY & NERVOUS SYSTEM TOXIN. INGESTION: ASPIRATION HAZARD & SYSTEMIC EFFECTS AS INHALATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, DERMATITIS & ABSORPTION. INHALATION: MUCOUS MEMBRANE IRRITATION, NOSE, THROAT, HEADACHE, DIZZINESS, NAUSEA, NUMBNESS OF THE EXTREMITIES, NARCOSIS; RESPRODUCTIVE, LU NG, LIVER, KIDNEY & NERVOUS SYSTEM TOXIN. INGESTION: ASPIRATION HAZARD & SYSTEMIC EFFECTS AS INHALATION. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED. KEEP QUIET & WARM. INGESTION: DRINK PLENTY OF WATER. DON'T INDUCE VOMITING. AVOID ASPIRATION OF MATERIAL INTO LUNGS. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. AVOID ALCOHOLIC BEVERAGES. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:0-6F Lower Limits:1.8% Upper Limits:11.8% Extinguishing Media:DRY CHEMICAL, CO2 & WATER OR FOAM EXTINGUISHER. Fire Fighting Procedures:EVACUATE AREA & CALL FIRE DEPRARTMENT IMMEDIATELY. Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. STOP LEAK, W/O RISK. ABSORB W/SAND, EARTH OR OTHER ABSORBING MATERIAL. ======================Handling and Storage ====================== Handling and Storage Precautions:ELIMINATE IGNITION SOURCES. STORE IN COOL DRY PLACE. EMPTY CONTAINERS WILL RETAIN RESIDUE & VAPORS. COMBUSTIBLE LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED CANISTER RESPIRATOR IN ABSENCE OF ADEQUATE VENTILATION. Ventilation:GENERAL MECHANICAL/LOCAL EXHAUST TO KEEP BELOW TLV. OPEN DOORS & WINDOWS. ENCLOSED AREAS USE EXHAUST FAN. Other Protective Equipment:EYE WASH & SHOWER Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health CHEMICALS OF THIS PRODUCT ARE IDENTIFIED AS A SARA SECTION 313 TOXIC CHEMICAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:151F Vapor Pres:145 PSI Vapor Density:2.5 Spec Gravity:0.93-0.95 Evaporation Rate & Reference:(BU AC= 1): 5.5-8 Solubility in Water:NEGLIGIBLE Appearance and Odor:LIQUID W/ETHER LIKE ODOR Percent Volatiles by Volume: 88% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZING MATERIALS, ALKALIES, CHLORINATED INORGANICS SUCH AS POTASSIUM, CALCIUM, ETC. COPPER & COPPER ALLOYS Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES Hazardous Decomposition Products:CO2, CO, HYDROGEN CHLORIDE & SMOKE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. TOXIC & IGNITABLE WASTE. NA 1993.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BOSCODUR 9R Kit Part:Y CAGE:JO971 CAGE:JO971 CAGE:5W425 CAGE:60777 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA 313) (CERCLA) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 44.9% Other REC Limits:NONE RECOMMENDED ACGIH TLV:100 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PETROLEUM NAPHTHA, 1 CAS:64742-89-8 Fraction by Wt: 30.9% Other REC Limits:NONE RECOMMENDED ACGIH TLV:300 PPM Ingred Name:LEAD MONOXIDE (LITHARGE) CAS:1317-36-8 RTECS #:OG1750000 Fraction by Wt: 15.5% Other REC Limits:NONE RECOMMENDED ACGIH TLV:0.05 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:1500-2500 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION, DEFATTING. INHAL: DIZZY, WEAK, DROWSY, LETHARGY, BREATHING DIFFICULTY, HEADACHE, INCOORDINATION, NAUSEA, DIARRHEA, VOMIT. CHRONIC: DERMATITIS, LIVER/KIDNEY DAMAGE. Medical Cond Aggravated by Exposure:SKIN ALLERGY & CARDIOVASCULAR DISEASE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: FLUSH W/WATER FOR 15 MINUTES. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. GET MED AID. ===================== Fire Fighting Measures ===================== Flash Point:32.0F,0.0C Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE SCBA. Unusual Fire/Explosion Hazard:USE SCBA. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITS. ABSORB W/SAND/EARTH/SWEEPING COMPOUNDS. PUT MATERIAL IN STEEL DRUMS. CLEAN AREA THOROUGHLY. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A COOL (60-80F) AREA. KEEP AWAY FROM SUNLIGHT/HEAT SOURCES/SPARK/FLAME. KEEP CONTAINER TIGHTLY CLOSED. Other Precautions:AVOID PROLONGED BREATHING OF VAPORS. ============= Exposure Controls/Personal Protection ============= Ventilation:LOCAL EXHAUST/ MECHANICAL VENTILATION. Other Protective Equipment:SAFETY SHOWER & EYEWASH. Supplemental Safety and Health NK ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212 TO 232F Vapor Pres:57.0 Vapor Density:3.28 Spec Gravity:0.95 Evaporation Rate & Reference:2.7 (BUAC) Appearance and Odor:DARK BROWN LIQUID, W/HYDROCARBON ODOR. Percent Volatiles by Volume:76.5 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ALKALIS, ACIDS, AMIRTES, POTASSIUM & SODIUM. ==================== Disposal Considerations ==================== Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ADHESIVE SPRAY 920 CAGE:57040 CAGE:57040 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROCARBON PROPELLANT CAS:68476-86-8 OSHA PEL:1000 PPM (MFR) ACGIH TLV:1000 PPM (MFR) Ingred Name:HNDLG/STOR PREC:BE EXPOS TO TEMPS >120F & SPRAY SHLD NOT BE DIRECTED TOWARD FACE/EYES, OPEN FLAME/OTHER SOURCE OF IGNIT. RTECS #:9999999ZZ Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: <60% OSHA PEL:500 PPM;1000 PPM C ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <10% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CHLOROCARBON MATLS AHVE PRDCED SENSIT OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS.ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUS TAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS .(EFTS OF OVEREXP) Explanation of Carcinogenicity:METHYLENE CHLORIDE: GROUP 2 (NTP), GROUP 2B (IARC). Effects of Overexposure:HLTH HAZ:INHAL:EXCESSIVE INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAKNESS, FATG, NAUS, HDCH & POSS UNCON. SKIN:PRLNGD/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT & DERM. INGEST:CAN CAUSE SEV GI IRR IT, NAUS, VOMIT & DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMONITIS. EYES: CAN CAUSE SEV IRRIT, (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES LIFTING UPPER & LOWER LIDS. GET MEDICAL ATTENTION. SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. IF BREATHING IS DFCLT, ADMIN ISTER O2. IF BREATHING STOPS GIVE ARTIFICIAL RESPIRATION. GET MED ATTN. INGEST: DO NOT INDUCE VOMITING. GET MEDICAL ATTN. ASPIRATION OF MATL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEM PNEUMONITIS. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:SUPP DATA Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND FULL PROTECTIVE EQUIPMENT (PF N). KEEP CONTAINERS COOL. Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES (ABOVE 120F) CONTAINERS MAY VENT RUPTURE OR BURST. EXTREMELY FLAMMABLE SPRAY. THERMAL DECOMP PRODS MAY INCLUDE HCL & PHOSGENE (FPN ). ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP AREA BY MOPPING OR WITH ABSORBENT MATERIALS AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. CONTACT FEDERAL, STATE OR LOCAL AUTHORITIES FOR APPROVED DISPOSAL PROCEDURES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE @ TEMPS >120F. INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING CONTENTS CAN BE HARMFUL/FATAL. PRESSURIZED CNTNRS MUST NOT (ING 4) Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . PLEASE READ & FOLLOW THE DIRECTIONS ON (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE VAPOR CONCENTRATION IS 100-1000 PPM, A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR. IF CONCENTRATION EXCEEDS 1000 PPM A NIOSH/MSHA APPROVED SCBA. Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:DON'T EAT, DRINK OR SMOKE IN WORK AREA. WASH HANDS BEFORE EATING. Supplemental Safety and Health BP: 105F, 41C (CONC). SPEC GRAV:1.260 @ 75F (H2O=1) OF CONCENTRATE. VP: 43 PSIG IN CAN @ 75F. FL PT:NONE TO 150F CONC. HLTH HAZ:REDNESS, TEARING & BLURRED VISION. OTHER PREC: PROD LABEL: THEY ARE YOUR BEST GUIDE TO USING PROD IN MOST EFTIVE WAY, & THEY ALSO GIVE THE NEC SAFETY PRECAUTIONS TO PROTECT YOUR HLTH. ================== Physical/Chemical Properties ================== HCC:V3 Boiling Pt:B.P. Text:SUPP DATA Vapor Pres:SUPP DATA Spec Gravity:SUPP DATA Solubility in Water:NEGLIGIBLE (CONC) Appearance and Odor:PALE STRAW COLOR LIQUID; MILD SWEETISH ODOR. Percent Volatiles by Volume:80 CAN ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ALKALIES, OXYGEN, NITROGEN PEROXIDE, SODIUM, POTASSIUM AND OTHER OXIDIZERS AND REACTIVE METALS. Stability Condition to Avoid:DO NOT EXPOSE TO TEMPERATURES ABOVE 120F. Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE (SMALL AMOUNTS). ==================== Disposal Considerations ==================== Waste Disposal Methods:WHEN USED PROPERLY AEROSOL PRODS DO NOT GENERATE HAZ WASTE. EMPTY DE-PRESSURIZED CNTNRS CANNOT BE REUSED & SHLD BE WRAPPED & PUT IN A PERMITTED WASTE MANAGEMENT FACILITY. CONSULT FEDERAL, STATE AND LO CAL DISPOSAL AUTHORITIES FOR APPROVED PROCEDURES.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SILAPRENE ADHESIVE, M6127 CAGE:89902 CAGE:4G311 CAGE:89902 ============= Composition/Information on Ingredients ============= Ingred Name:1,3-BUTADIENE, 2-CHLORO-, POLYMERS; (POLYCHLOROPRENE ADHESIVE) CAS:9010-98-4 RTECS #:EI9640000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 28.8% OSHA PEL:100 PPM; 150 STEL ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 35.3% OSHA PEL:200 PPM; 300 STEL ACGIH TLV:200 PPM; 300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ZINC COMPOUND; (ZINC COMPOUNDS) Fraction by Wt: 3.2% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOSURE TO VAPOR CAN CAUSE IRRITATION TO EYES, LUNGS AND MUCOUS MEMBRANES. EXCESS EXPOSURE CAN CAUSE DIZZINESS, HEADACHE, NAUSEA, NARCOSIS AND LIVER AND KIDNEY DAMAGE. CONTACT WITH LIQUID CAN CAUSE E YE AND SKIN IRRITATION AND SKIN DEFATTING. CHRONIC:TOLUENE APPEARS ON THE NAVY LISTING OF OCCUPATIONAL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION . Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN: CLEAN WITH RUBBING ALCOHOL, IF AVAILABLE, FOLLOWED BY SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION, IF NECESSARY. CONTACT MD. INGESTION: CONTACT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:22.0F,-5.6C Lower Limits:1.27% Upper Limits:10% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . USE WATER SPRAY TO COOL ADJACENT SURF & FIRE-EXPOS CNTNRS ONLY. PROTECT AGAINST INHAL OF COMBUST PRODS. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE IGNITION SOURCES. ABSORB ON INERT MATERIAL. USE NON-SPARKING TOOLS. TRANSFER INTO SECURE CONTAINERS FOR PROPER DISPOSAL. USE PERSONAL PROTECTIVE EQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AND USE AWAY FROM ALL SOURCES OF DIRECT HEAT & IGNITION. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:AVOID ALL PERSONAL CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN THE ABSENCE OF ADEQUATE VENTILATION, NIOSH/MSHA APPROVED RESPIRATORY PROTECTION FOR ORGANIC VAPOR SHOULD BE USED AS NECESSARY. Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED TO MINIMIZE ANY VAPOR EXPOSURE. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:173F,78C Vapor Pres:36-71 @20C Vapor Density:1.59-3.1 Spec Gravity:0.902 (H*2O=1) Evaporation Rate & Reference:2.7-4.5 (ETHER =1) Solubility in Water:INSOLUBLE Appearance and Odor:BLACK LIQUID; STRONG KETONE & AROMATIC SOLVENT ODOR. Percent Volatiles by Volume:64.1 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND BASES. Stability Condition to Avoid:STABLE AT AMBIENT TEMPERATURES AND PRESSURES. Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN UNDER BURNING CONDITIONS. ==================== Disposal Considerations ==================== Waste Disposal Methods:AS A HAZARDOUS WASTE IN ACCORDANCE WITH FEDERAL (40CFR 261.21), STATE AND LOCAL REGULATIONS. HAZARDOUS WASTE NO: D001 (IGNITABILITY).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PORTLAND CEMENT TYPE I & II CAGE:0JE83 CAGE:0JE83 ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS. OSHA PEL:5MG/M3 RDUST, 10 TOTAL (MFR). ACGIH TLV:5MG/M3 RDUST, 10 TOTAL (MFR) OSHA PEL:SEE INGREDIENT ACGIH TLV:SEE INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:WET CEMENT CAN DRY SKIN AND CAUSE ALKALI BURNS. CEMENT DUST CAN IRRITATE THE EYES AND UPPER RESPIRATORY SYSTEM. SIGNS & SYMPS OF EXPOS:DRY SKIN &/OR ALKALI TYPE BURNS TO SKIN, TISS LINING OF NOS E; IRRIT OF EYES & UPPER RESP SYS; DERMIN HYPERSENSITIVE INDIVIDUALS. CHRONIC:CEMENT DUST CAN CAUSE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:INFLAMMATION OF THE LINING OF NOSE AND INFLAMMATION OF THE CORNEA. Medical Cond Aggravated by Exposure:HYPERSENSITITIVE INDIVIDUALS MAY DEVELOP AN ALLERGIC DERMATITIS. (CEMENT MAY CONTAIN TRACES OF CHROMIUM). ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IRRIGATE IMMEDIATELY AND REPEATEDLY WITH WATER FOR AT LEAST 15 MINS & GET PROMPT MED A TTN. SKIN:WASH EXPOSED AREAS WITH SOAP AND WATER. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:EMERGENCY PROCEDURES ARE NOT REQUIRED. (USE DRY CLEANUP METHODS THAT DO NOT DISPERSE THE DUST INTO THE AIR. AVOID BREATHING THE DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP DRY UNTIL USED. Other Precautions:DO NOT BREATHE CEMENT DUST; PROTECT SKIN, EYES, NOSE FROM DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED PROTECTIVE (FILTER) MASK IN DUSTY ENVIRONMENTS. Ventilation:LOCAL EXHAUST:IF NECESSARY TO CONTROL AIR BORNE DUST LEVELS. Other Protective Equipment:BARRIER CREAMS, BOOTS, & CLTHG TO PROTECT SKIN FROM PRLNGD CONT W/CEMENT. ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:IMMED AFTER WORKING W/CEMENT/CEMENT-CONTAINING MATLS, WORKERS SHOULD SHOWER W/SOAP & WATER. PREC MUST BE (SUPDAT) Supplemental Safety and Health HYGIENE PRACT:OBSERVED BECAUSE CEMENT CAN BURN WITHOUT WARNING - LITTLE OR NO HEAT IS SENSED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:2700F,1482C Spec Gravity:3.0-3.2(H*2O=1) Solubility in Water:SLIGHT 0.1-1.0% Appearance and Odor:GRAY POWDER. NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO ACIDS. Stability Condition to Avoid:IF SUBJECTED TO ACIDS, KEEP DRY UNTIL USED. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:MATL CAN BE DISPOSED OF AS COMMON WASTE/RETURNED TO CNTNR FOR LATER USE IF IT IS NOT CONTAMINATED. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:BACTERGENT, 1410 Preparer's Name:R. C. JENTE CAGE:0LKT5 CAGE:0LKT5 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, NONYLPHENOXYPOLYETHYLENEOXY-,IODINE COMPLEX; ((NONYLPHENYL) HYDROXYPOLY (OXYETHYLENE)-IODINE COMPLEX) CAS:11096-42-7 RTECS #:KL9625000 Fraction by Wt: <25% Ingred Name:PHOSPHORIC ACID CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: <10% OSHA PEL:1 MG/M3;3 STEL ACGIH TLV:1 MG/M3;3 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:(ACUTE) EYES: CONTACT WITH EYES MAY CAUSE BURNS. SKIN: CONTACT WITH SKIN MAY CAUSE SEVERE IRRITATION. INGEST: IF SWALLOWED, MAY CAUSE INTERNAL DISCOMFORT. (CHRONIC) NONE KNOWN. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH EYES WITH PLENTY OF H*2O FOR AT LST 15 MIN.CALL MD.SKIN:IMMED FLUSH WITH PLENTY OF H*2O FOR AT LEAST 15 MIN.REMOVE AND WASH CONTAMINATED CLTHNG BEFORE REUSE.INGEST:IF SWALLOWED,DRINK PROMPTLY A LARGE QTYOF MILK,EGG WHITES,GELATIN SOLTN OR IF NOT AVAILABLE DRINK LARGE QTYS OF WATER.AVOID ALCOHOL.CALL MD IMMED.INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHNG (GIVE O*2/ARTF RESP) . ===================== Fire Fighting Measures ===================== Extinguishing Media:PRODUCT IS NOT FLAMMABLE OR COMBUSTIBLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT .EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILL AND ABSORB ON ABSORBENT MATERIAL. PLACE IN A D.O.T. APPROVED CONTAINER FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN OR CLOTHING. KEEP CONTAINER CLOSED. Other Precautions:EXERCISE CAUTION WHEN HANDLING AND STORING CHEMICAL SUBSTANCES. READ AND OBSERVE ALL LABELED PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE WITH GOOD GENERAL ROOM VENTILATION. Other Protective Equipment:PROTECTIVE CLOTHING. EMERGENCY EYEWASH, DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH: 2.4-3.5 @ 1% SOLUTION; 1.3-1.9 AS DISTRIBUTED. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:>212F,>100C Spec Gravity:1.06-1.09 pH:SUPDAT Evaporation Rate & Reference:1 (ETHER = 1) Solubility in Water:COMPLETE Appearance and Odor:DARK REDDISH BROWN LIQUID WITH MILD IODINE ODOR. Percent Volatiles by Volume:<5(WT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALIS AND OXIDIZERS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:IODINE ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MONOETHANOLAMINE CAGE:5B970 CAGE:5B970 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOLAMINE CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: >99% OSHA PEL:3 PPM/6 STEL ACGIH TLV:3 PPM/6 STEL; 9192 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:CAUSE BURNS,WITH POSSIBLE PERMANENT VISION IMPAIRMENT; SKIN:IRRITATION; INHALE:DISCOMFORT IN NOSE,THROAT & CHEST. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE STATED. ======================= First Aid Measures ======================= First Aid:EYES:IMMEDIATE & CONTINUOUS IRRIGATION WITH FLOW WATER FOR AT LEAST 15 MINUTES.GET PROMPT MEDICAL ATTENTION; SKIN:FLUSH WITH WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING & SHOES; INHALE: REMOVE TO FRESH AIR; INGEST:GET MEDICALHELP.DO NOT INDUCE VOMITING. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:200F/93C Lower Limits:3 Upper Limits:24 Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE. Fire Fighting Procedures:NONE STATED. Unusual Fire/Explosion Hazard:NONE STATED. ================== Accidental Release Measures ================== Spill Release Procedures:USE APPROPRIATE EQUIPMENT; APPLY ABSORBENT MATERIAL OR SAND.SHOVEL INTO CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED,LIGHT-RESISTANT CONTAINER. USE WITH ADEQUATE VENTILATION.WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR IF TLV IS EXCEEDED. Ventilation:KEEP BELOW TLV. Other Protective Equipment:EYE BATHS & SAFETY SHOWER. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B2 Boiling Pt:=170.6C, 339.F Melt/Freeze Pt:=10.6C, 51.F Vapor Pres:6 Vapor Density:2.11 Spec Gravity:1.018 pH:<7 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID,AMMONICAL ODOR;HYGROSCOPIC. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:HIGH TEMPERATURES. Hazardous Decomposition Products:CO,CO*2,NITROGEN OXIDES. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN AN APPROVED INCINERATE OR BURY AWAY FROM WATER SUPPLIES. FOLLOW ALL FEDERAL,STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:N5222 ORANGE A/D ENAMEL, 12197 Preparer's Name:MIKE LICHATOWICH CAGE:02388 CAGE:02388 ============= Composition/Information on Ingredients ============= Ingred Name:ALKYD RESIN SOLUTION CAS:68459-31-4 Fraction by Wt: 43.0% Other REC Limits:NONE SPECIFIED OSHA PEL:150 PPM ACGIH TLV:150 PPM/STEL 200 PPM Ingred Name:BUTYL ACETATE (VAPOR PRESSURE 10 MM HG @ 20C) CAS:123-86-4 RTECS #:AF7350000 Fraction by Wt: 31.0% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:150 PPM/STEL 200 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:BARIUM SULFATE (SARA 313) CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 9.0% Other REC Limits:NONE SPECIFIED OSHA PEL:5 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ORGANOPHYLIC CLAY CAS:71011-25-1 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED Ingred Name:COBALT COMPOUNDS (AS CO) CAS:7440-48-4 RTECS #:GF8750000 Fraction by Wt: < 1% Other REC Limits:NONE SPECIFIED OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:2.0 MG/M3;DUST 9293 Ingred Name:PROPIETARY INGREDIENTS Fraction by Wt: BALANCE Other REC Limits:NONE SPECIFIED Ingred Name:VOC: 3.07 LB/GAL RTECS #:9999999VO Other REC Limits:NONE SPECIFIED Ingred Name:YELLOW PIGMENT Fraction by Wt: 2.0% Other REC Limits:NONE RECOMMENDED OSHA PEL:N0T EST ACGIH TLV:NOT EST ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: EYES: SEVERE IRRITATION, LACRIMATION, REDNESS, BLURRED VISION. SKIN: REDNESS, IRRITATION. DEFATTING OF SKIN LEADING TO DERMATITIS. INHALE: NASAL & RESP IRRITATION, CNS DEPRESSION. DIZZINESS, DR OWSINESS, WEAKNESS, FATIGUE, CONFUSION.NAUSEA, HEADACHE, VERTIGO, UNCONSCIOUSNESS, ASPHYXIATION. CHRONIC DERMATITIS.* Explanation of Carcinogenicity:NA Effects of Overexposure:*INGESTION: GASTROINTESTINAL IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA. TARGET ORGANS: LIVER, KIDNEYS, EYES, SKIN, RESPIRATORY SYSTEM, NUISANCE DUST, CNS. CHRONIC EFFECTS OVEREXPOSURE: DE RMATITIS, INCOHERENCE, CORNEAL VACUOLIZATION, ANOREXIA. Medical Cond Aggravated by Exposure:NONE KNOWN ======================= First Aid Measures ======================= First Aid:INHAL: GET FRESH AIR. RESTORE BREATHING. GET MED AID IMMED. SKIN: IMMED FLUSH SKIN W/WATER. IF MATERIAL PENETRATES CLOTHING REMOVE & WASH BEFORE REUSE. GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH E YES WITH LOTS WATER > 15 MINS, LIFTING EYELIDS OCCASIONALLY. GET MED AID IMMED. INGEST: DRINK 1-2 GLASSES WATER. DON'T INDUCE VOMITING. SEE DR/POINSON CONTROL CTR IMMEDIATELY. TREAT SYMPTOMATICALLY. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:2.0F,22.2C Lower Limits:0.8 Upper Limits:7.6 Extinguishing Media:DRY CHEMICAL, FOAM, CO2. Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. WATER USED TO COOL CLSD CNTNRS TO PREVENT BUILDUP & POSSIBLE AUTO IGNITION OR EXPLO EXPOS TO HEAT Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. VAPORS > AIR TRAVEL ALONG GRND TO AN IGNITION SOURCE. ISOLATE FM ALL HEAT TYPES. CLSD CNTNRS MAY EXPLODE EXPOSED TO EXTREME HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. DON'T BREATHE VAPORS. AVOID SKIN CONTACT. ABSORB WITH INERT MATERIAL. SHOVEL RECLAIMED INTO DRUMS FOR DISPOSAL. DIKE TO PREVENT FURTHER MOVEMENT & RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. AVOID ROUGH HANDLING. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR AN APPROPRIATE (TYPE TC-23C-75) PROPERLY FITTED HALF-MASK OF FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER APPLICATION UNLESS AIR MONITORING KEEPS VAPOR/MIST BELOW APPLICABLE LEVELS. FOLL OW RESPIRATOR MANUFACTURER'S DIRECTIONS. Ventilation:SUFFICIENT VENT IN VOLUME/PATTERN TO KEEP AIR CONCENTRATION BELOW ACGIH'S TLV LIMIT. Other Protective Equipment:CLOTHING AS NEEDED TO PREVENT SKIN CONTACT Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, USING RESTROOMS. REMOVE/WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health DON'T WEAR CONTACT LENSES WHEN WORKING WITH THIS MATERIAL. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:212 TO 398F Decomp Temp:Decomp Text:NE Vapor Density:> AIR Spec Gravity:1.115 pH:NA Viscosity:70-75 KU Evaporation Rate & Reference:< ETHER Solubility in Water:YES Appearance and Odor:LIQUID, ODOR OF SOLVENTS Percent Volatiles by Volume:41.93 Corrosion Rate:MINIMAL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, NITRATES, ALKALIES, ACIDS. Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING. Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SHER-WOOD WIPING STAIN CONCENTRATE, S64R27 CAGE:54626 CAGE:54626 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:ING 5:CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROC. KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY TO (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF CHILDREN. RTECS #:9999999ZZ Ingred Name:OTHER PREC:ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. COATING MAY CONTAIN MATL (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:CLASS AS NUISANCE PARTICULATES WHICH MAY BE PRESENT @ HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:FILM. APPLIC LIM FOR NUISANCE DUSTS:ACGIH TLV 10MG/M3 (TDUST), OSHA PEL 15MG/M3 (TDUST), 5MG/M3 (RESP FRACTION). RTECS #:9999999ZZ Ingred Name:RESP PROT:GENERATED FROM THIS PROD, UNDERLYING PAINT OR THE ABRASIVE. RTECS #:9999999ZZ Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS) VP: 2 CAS:64742-47-8 RTECS #:OA5504000 Fraction by Wt: 20% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA III)VP: 22 CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 9% OSHA PEL:100 PPM; 50 STEL ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: 2% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:VOLATILE ORGANIC COMPOUNDS: 2.98 LBS/GAL, LESS WATER: 3.00 LBS/GAL RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HNDLG/STOR PREC:PILOT LIGHTS & HEATERS. TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. (ING 6) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOS TO VAP/S PRAY MISTS. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:TOLUENE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:APPEARS ON NAVY LIST OF OCCUP CHEM REPROD HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFORMATION & SAFE HNDLG & EXPOS INFORMATION . PRLNG OVEREXP T O SOLV INGREDS IN PROD MAY CAUSE ADVERSE EFTS TO LIVER, URIN, BLOOD-FORMING, CARDIOVASCULAR & REPROD SYS. RPTS (SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHALATION: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:40.0F,4.4C Lower Limits:0.9% Upper Limits:19% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ PREF. WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPK & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURF (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE FLAMM. KEEP AWAY FROM HEAT, SPK & OPEN FLAME. DURING USE & UNTIL ALL VAPS GONE:KEEP AREA VENT. DO NOT SMOKE. EXTING ALL FLAMES, (ING 5) Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL. THESE PRODS MAY BE MIXED W/OTHER COMPONENTS, INCL REDUCERS, BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LABELS & MSDS ON ALL COMPONENTS. USE (ING 8) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIM BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP APPRVD BY NIO SH/MSHA FOR DUST WHICH MAY BE (ING 11) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IS < APPLIC EXPOS LIM. REFER TO OSHA STDS 1910.94, 107, 108. Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:REQS SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE IMME D APPARENT. OBTAIN MED ATTN. EFTS OF OVEREXP:HAVE ASSOC RPTD/PRLNG OVEREXP TO SOLV W/PERM BRAIN & NERVOUS SYS DMG. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:>172F,>78C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:0.81-1.6 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:40-97 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERM APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE OF I/A/W FED, STATE, & LOCAL REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
======================================================= Product ID: DEVTHANE 378 WHITE TINT BASE, 378B9500 Cage: 1HK86 Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: 1HK86 Box: 7600 Cage: JO708 Cage: 01PD6 ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO LOSS OF APPETITE, MUC MEMB IRRIT, FATIGUE, DROW, DIZZ &/LT HEAD, HDCH, UNCOORDINATION, NAUS, VOMIT, CHEST PAIN, BLURRED VISION, FLU-LIKE SYMPS, COU GHING, DIFFICULTY W/SPEECH, CNS DEPRESS, INTOXICATION, TIGHTNESS OF CHEST, ANESTH EFT/NARCOSIS, (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: DIFFICULTY OF BRTHG, BRONCH, FEVER & CHILLS, TREMORS, LIVER DMG, KIDNEY DMG, PULM EDEMA, PNEUMOCANIOSIS, LOSS OF CONSCIOUSNESS, RESP FAILURE, ASPHY, DEATH, POSS SENSIT TO RESP TRACT. SKIN: I RRIT OF SKIN. PRLNG/RPTD CNTCT CAN CAUSE DERM, DEFAT, BLISTERING, SEV SKIN IRRIT/BURNS. POSS SENSIT TO RESP Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS ASTHMA-LIKE CONDITIONS KIDNEY DISORDERS LIVER DISORDERS. First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG. GET EMER MED ATTN. HAVE TRAINED PERS GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG DIFFICULTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE W ATERING, HDCHS, DIZZ/OTHER DISCOMFORT. SKIN: FLUSH FROM SKIN W/H*2O THEN WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHNG BEFORE RE-USE. IF IRRIT OCCURS, CONSULT A MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM ALL SOURCES OF IGNITION. VENT AREA. VENT AREA W/EXPLOSION-PROOF EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATL. USE NON-SPARKING TOOLS. EVACUATE ALL UNNEC P ERS. PLACE COLLECTED MATL IN PROPER CNTNR Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. Handling And Storage Precautions: STORE BELOW 80F (27C). STORE BELOW 100F (30C). KEEP AWAY FROM HEAT SPKS & OPEN FLAME. KEEP AWAY FROM DIRECT SUNLIGHT, HEAT & ALL SOURCES OF IGNITION. Other Precautions: USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CNTCT W/SKIN & EYES, & BRTHG OF VAPS. KEEP CNTNR TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. FOR MORE SPECIFIC INFORMATIO N CONTACT NEHC (FP N). ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 80.0F,26.7C Extinguishing Media: DRY CHEMICAL OR FOAM WATER FOG CARBON DIOXIDE. Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT/FIRE. VAPS MAY IGNITE EXPOSIVELY AT AMBIENT TEMPS. VAPS ARE HVR/AIR & MAY TRAVEL LONG DISTANCES (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation: PROVIDE SOLUTION VENT/LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. USE EXPLOSION PROOF EQUIP. USE NON-SPARKING EQUIP. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). IMPERVIOUS CLOTHING APRON AND BOOTS. Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE EATING OR SMOKING. Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR" VERSION FOR ADDITIONAL INFO (FP N). EXPLO HAZ: TO A SOURCE OF IGNIT & FLASH BACK. VAPS CAN FORM EXPLOSIVE MIX IN AIR AT ELEVATED TEMPS. CLSD CNTNRS MAY BURST IF EXPOSED TO EXTREME HEAT/FIRE.MAY DECOMPOSE UNDER FIRE CNDTNS EMITTING IRRIT &/TOX GASES. ======================================================= Physical/Chemical Properties ======================================================= B.P. Text: >259F,>126C Spec Gravity: 1.43 (FP N) Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 39.10 ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: ELEVATED TEMPS, MOISTURE, CONT W/OXIDIZING AGENT, CONTACT W/ALUMINUM OR ZINC, SPARKS, OPEN FLAME, IGNITION SOURCES. Materials To Avoid: OXIDIZERS, ACIDS, BASES AMINES, WATER, ALUMINUM, ZINC, METALS, PEROXIDES, NITRIC, ACID, ALCOHOLS, METAL COMPOUNDS Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN, FORMIC ACID, OXIDES OF SULFUR, HYDROGEN CYANIDE, OXYGEN, Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DEVTHANE 378 WHITE TINT BASE, 378B9500 Cage: 1HK86 Company Name: DEVOE COATINGS CO Street: 4000 DUPONT CIRCLE PO Box: 7600 Zipcode: 40207-4802 Label Required IND: Y Date Of Label Review: 11/18/1998 Status Code: C Label Date: 11/18/1998 Origination Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Severe Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: Slight Hazard And Precautions: FLAMM. DECOMP PROD MAY BE HAZ. ACUTE: INHAL: IRRIT LOSS OF APPETITE, FATIGUE, DROW, DIZZ &/LT HEAD, HDCH, UNCOORDINATION, NAUS, VOMIT, CHEST PAIN, BLURRED VISION, FLU-LIKE SYMPS, COUGHING, DIFFICULTY W/SPEECH, CNS DEPRESS, INTOXICATION, TIGHTNESS OF CHEST, ANESTH EFT/NARCOSIS, DIFFICULTY OF BRTHG, BRONCHITIS, FEVER & CHILLS, TREMORS, LIVER, KIDNEY DMG, PULM EDEMA, PNEUMOCONOSIS, LOSS OF CONSCIOUSN ESS, RESP FAILURE, ASPHY, DEATH. POSS SENSIT. SKIN: SEV IRRIT, DERM, DEFAT, BLISTERING, BURNS. POSS SENSIT. EYE: SEVERE IRRIT, CONJ, BLURRED VISION TEARING, INGEST: LUNG DMG & CNS EFTS. KIDNEY & LIVER DMG. CHRONIC: SENSITIZER-ALLERGIC RXN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MAGNESIUM METAL POWDER Resp. Party Other MSDS Num.:MM 20 Preparer's Name:MICHAEL RASZEJA CAGE:63759 Contract Num:MDA414-01-P-1892 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:MAGNESIUM METAL CAS:7439-95-4 RTECS #:OM2100000 = Wt:99.6 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EXPOSURE TO MAGNESIUM METAL OR OXIDE DUST SHOULD BE A LOW HEALTH RISK BY INHALATION AND SHOULD BE TREATED AS A NUISANCE DUST. EXPOSURE TO MAGNESIUM OXIDE FUME AND SUBSEQUENT BURNING CAN RESULT IN META L FUME FEVER. THE TEMPORARY SYMPTOMS CANINCLUDE FEVER, CHILLS, NAUSEA, VOMITING AND MUSCULAR PAIN. ONSET OF SYMPTOMS OCCURS 4-12 HOURS AFTER EXPOSURE. EYES: MAY CAUSE BURNS AND CORNEAL ABRASIONS. SKIN : PARTICLES OF MAGNESIUM EMBEDDED IN THE SKIN MAY PRODUCE LESSIONS THAT RESIST HEALING. INGESTION: NO PROBLEM BECAUSE OF PHYSICAL PROPERTIES. Effects of Overexposure:EXPOSURE TO MAGNESIUM METAL OR OXIDE DUST SHOULD BE A LOW HEALTH RISK BY INHALATION AND SHOULD BE TREATED AS A NUISANCE DUST. EXPOSURE TO MAGNESIUM OXIDE FUME AND SUBSEQUENT BURNING CAN RESULT IN META L FUME FEVER. THE TEMPORARY SYMPTOMS CANINCLUDE FEVER, CHILLS, NAUSEA, VOMITING AND MUSCULAR PAIN. ONSET OF SYMPTOMS OCCURS 4-12 HOURS AFTER EXPOSURE. EYES: MAY CAUSE BURNS AND CORNEAL ABRASIONS. SKIN : PARTICLES OF MAGNESIUM EMBEDDED IN THE SKIN MAY PRODUCE LESSIONS THAT RESIST HEALING. INGESTION: NO PROBLEM BECAUSE OF PHYSICAL PROPERTIES. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: DO NOT FLUSH WITH WATER. REMOVE PARTICALS WITH COTTON TIP APPLICATOR. CORNEAL ABRASIONS ARE A POSSIBILITY. GET IMMEDIATE MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF ILL EFFECTS DEVELOP, GET MEDICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER, NO EFFECT EXPECTED.INGESTION: IF SWALLOWED, IF CONSCIOUS, INDUCE VOMITING AND CALL A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO A N UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:=635.C, 1175.F Autoignition Temp:=510.C, 950.F Extinguishing Media:SMOTHER WITH DRY GRAPHITE, TALC, DRY SAND, G-1 POWDER, PURPLE-K. DO NOT USE WATER. DO NOT USE FOAM, HYDROGENATED EXTINGUISHING AGENTS OR CARBON DIOXIDE. Fire Fighting Procedures:DON'T USE FOAM, CARBON TETRACHLORIDE, OR CARBON DIOXIDE. MANUAL APPLICATION OF WATER SHOULD BE CONDUCTED WITH CARE TO PREVENT CONTACT WITH BURNING/MOLTEN MATERIAL. PROTECT EYES & SKIN AGAINST FLYING P ARTICLES. AVOID DIRECT VIEWING OF MAGNESIUM FIRES. FIREFIGHTERS SHOULD WEAR A NIOSH-APPROVED SCBA & PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:COMBUSTIBLE MEATAL. EASILY IGNITED AND BURNS WITH INTENSE HEAT AND BRILLANT WHITE FLAME. POWDERS FORM EXPLOSIVE MIXTURE WITH AIR WHICH MAY BE IGNITED BY SPARK. IN FINELY DIVIDED FORM, WILL REACT WITH WATER AND ACIDS TO RELEASE HYDROGEN. ================== Accidental Release Measures ================== Spill Release Procedures:RECOVER FOR USE IF NOT CONTAMINATED. DO NOT USE WATER TO CLEAN UP SPILL. USE APPROPRIATE SAFETY EQUIPMENT-CLEAN UP USING NON-SPARKING TOOLS-NO SMOKING OR OPEN FLAMES IN THE AREA. AVOID DUSTING. CLEAN DRY PRODUCT MAY BE RETURNED TO DRY CONTAINER AND SEALED AGAINST MOISTURE OR PLACE IN A SUITABLE CONTAINER FOR DISPOSAL. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE IN A DRY PLACE AWAY FROM OTHER COMBUSTIBLES IN A METAL CABINET. AVOID DIRECT VIEWING OF MAGNESIUM FIRES AS EYE INJURY MAY RESULT. GROUND ALL HANDLING AND TRANSFERRING OPERATI ONS. WET OR CONTAMINATED MATERIAL SHOULD BE PLACED IN VENTED CONTAINERS & DISPOSED OF. Other Precautions:READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. WET, MOIST OR HIGH HUMIDITY STORAGE CONDITIONS WILL LEAD TO CORROSION OF THE PRODUCT. CONSTANT CLEAN-UP AN D GOOD HOUSEKEEPING. FOR LABORATORY USE ONLY. NOT FOR DRY, FOOD OR HOUSEHOLD USE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED IN NORMAL LABORATORY HANDLING. IF DUSTY CONDITIONS PREVAIL, WORK IN VENTILATION HOOD OR WEAR A NIOSH-APPROVED DUST MASK OR RESPIRATOR. Ventilation:LOCAL/MECHANICAL: IF DUSTY. Other Protective Equipment:WEAR APPROPRIATE FIRE-RESISTANT CLOTHING Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:R2 Boiling Pt:=1110.C, 2030.F Melt/Freeze Pt:=651.C, ######F Vapor Pres:1MM@621C Vapor Density:NO DATA Spec Gravity:1.74@20C Evaporation Rate & Reference:N/A (NBUAC=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:SILVERY GRAY METAL POWDER; NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MAGNESIUM WILL REACT WITH WATER AND ACIDS TO RELEASE HYDROGEN; ALSO HAZARDOUS WITH CHLORINE, BROMINE, IODINE, OXIDIZING AGENTS AND ACIDS. Stability Condition to Avoid:DANGEROUS WHEN WET. AVOID EXPOSURE TO MOISTURE, HEAT, SPARKS AND FLAME. Hazardous Decomposition Products:HYDROGEN WILL BE PRODUCED-WHEN EXPOSED FOR LONG TIME TO WATER AND ACIDS. =================== Toxicological Information=================== Toxicological Information:NO DATA PROVIDED BY MANUFACTURER ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY MANUFACTURER ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.THESE DISPOSAL GUIDE LINES ARE INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF IN INCINERATOR OR IN AN APPROVED CHE MICAL LANDFILL OR CONTRACT WITH A LICENSED WASTE DISPOSAL SERVICE. =================== MSDS Transport Information =================== Transport Information:DOT: MAGNESIUM, POWDER, 4.3, UN1418. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EXTRA EDITION, 02098 CAGE:0XZ81 CAGE:0XZ81 CAGE:59327 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE (2:1); (SODIUM CARBONATE) CAS:497-19-8 RTECS #:VZ4050000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TRIPHOSPHORIC ACID, PENTASODIUM SALT; (SODIUM TRIPOLYPHOSPHATE) (SARA III) CAS:7758-29-4 RTECS #:YK4570000 OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM SULFATE (2:1); (SODIUM SULFATE) CAS:7757-82-6 RTECS #:WE1650000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:BENZENESULFONIC ACID, DODECYL-, SODIUM SALT; (SODIUM DODECYLBENZENE SULFONATE) (SARA III) CAS:25155-30-0 RTECS #:DB6825000 OSHA PEL:N/K ACGIH TLV:N/K EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE & CHRONIC:MAY IRRITATE EYES. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:SENSITIVE SKIN. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:FLUSH THOROUGHLY W/FRESH WATER FOR AT LEAST 15 MINUTES, GET MEDICAL ATTENTION. SKIN:FLUSH W/FRESH WATER. WASH W/SOAP & WA TER. REMOVE CONTAMINATED CLOTHES & SHOES. INGEST:GIVE WATER, DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Lower Limits:NONE Upper Limits:NONE Extinguishing Media:CO*2. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP & DISPOSE SMALL AMOUNTS TO SOLID WASTE; COLLECT & RETURN LARGE AMOUNTS TO CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MECHANICAL: PRODUCE NORMAL AIR DILUTION. Other Protective Equipment:NONE Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health WASTE DISP METH:BEFORE SELLING CONTAINER OR DISPOSAL. ALL CHEMICAL COMPONENTS ARE ON TSCA INVENTORY. ================== Physical/Chemical Properties ================== Solubility in Water:5% Appearance and Odor:YELLOW POWDER; ESSENTIALLY ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MINERAL ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CO W/INCOMPLETE COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . PH ADJUSTMENT, CONTAINS PHOSPHATES, DOES NOT CONTAIN PHENOLS, HEAVY METALS/SOLVS. USE UNTIL <1 INCH REMAINS IN CNTNR, EMPTY CNTNR TRIPLE RINSE W/WATER, ADD TO OPERATION. REMOVE/DEFACE LABEL (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CAT-1300 Kit Part:Y Preparer's Name:M SEINO CAGE:FO068 CAGE:FO068 CAGE:S7535 ============= Composition/Information on Ingredients ============= Ingred Name:ORGANOPOLYSILOXANE, TRADE SECRET ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:SKIN/EYES: MAY CAUSE SLIGHT IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:SKIN: REMOVE FLUID W/DRY CLOTH/TOWEL & WASH W/DETERGENT. EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL AREAS. ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:201.2F Extinguishing Media:FOAM, DRY CHEMCIAL/CO2 Fire Fighting Procedures:NOT REQUIRED Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN. SCRAPE UP W/CARDBOARD/RAG & PLACE IN CONTAINER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. VENT CONTAINER PROPERLY TO ELIMINATE INTERNAL PRESSURE. STORE IN A COOL PLACE AWAY FROM IGNITION SOURCES. Other Precautions:DON'T LAY CONTAINER ON IT'S SIDE. AVOID CONTACT W/ACIDIC, BASIC & OXIDIZING MATERIALS. AVOID CONTACT W/EYES & PROLONGED/REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED Ventilation:NOT REQUIRED Other Protective Equipment:EYEWASH EQUIPMENT Work Hygienic Practices:WASH HANDS AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Vapor Pres:NEGLIGIBLE Spec Gravity:1 Evaporation Rate & Reference:(BU AC=1): NEGLIGIBLE Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS, TRANSPARENT FLUID W/NO ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO ACIDIC, BASIC & OXIDIZING MATERIALS Stability Condition to Avoid:HEAT, FLAME & OTHER IGNITION SOURCES Hazardous Decomposition Products:FLAMMABLE HYDROGEN GAS Conditions to Avoid Polymerization:ACIDIC, BASIC & OXIDIZING MATERIALS ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE CAN BE BURNED/DISPOSED OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CPE133260 HTH (R) SUPER SOCK IT CAGE:8X135 CAGE:8X135 CAGE:99530 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORIC ACID, CALCIUM SALT CAS:10137-74-3 RTECS #:FN9800000 Fraction by Wt: 0-5% Ingred Name:CALCIUM CHLORIDE CAS:10043-52-4 RTECS #:EV9800000 Fraction by Wt: 0-5% Ingred Name:CALCIUM HYDROXIDE, LIME, CALCIUM HYDRATE CAS:1305-62-0 RTECS #:EW2800000 Fraction by Wt: 0-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3; 9293 Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1), CALCIUM CARBONATE, DURAMITE CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 0-4% Other REC Limits:10 MG/CUM (DUST) ACGIH TLV:10 MG/CUM Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 0-10% Ingred Name:HYPOCHLOROUS ACID, CALCIUM SALT, CALCIUM HYPOCHLORITE BLEACHING POWDER CAS:7778-54-3 RTECS #:NH3485000 Fraction by Wt: 65-90% EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Fraction by Wt: 0-20% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 850 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE/MOUTH/THROAT/LUNG IRRITATION/RESPIRATORY TRACT BURNS/LUNG EDEMA/SHORTNESS OF BREATH/WHEEZING/CHOKING/CHEST PAIN. EYES: IRRITATION/BURNS. SKIN: IRRITATION/BURNS/REDNESS/SWELLING/SCAB F ORMATION. INGESTION: GASTROINTESTINAL TRACT/STOMACH/INTESTINE IRRITATION/BURNS/NAUSEA/VOMITING/DIARRHEA/ABDOMINAL PAIN. Explanation of Carcinogenicity:NONE Effects of Overexposure:INHALATION: IMPAIRMENT OF LUNG FUNCTION OR PERMANENT LUNG DAMAGE, & HARMFUL. EYES: IMPAIRMENT OF VISION, HARMFUL, & CORNEAL DAMAGE. SKIN: HARMFUL, & TISSUE DESTRUCTION. INGESTION: HARMFUL, BLEEDING, & TISSUE ULCERATION. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. INGESTION: DRINK PLENTY OF WATER. DON'T INDUCE VOMITING. DON'T GIVE ANYTHING BY MOUTH IF UNCONSCIOUS OR HAVING CONVULSIONS. INHALATION: REMOVE TO FRESH AIR. SUPPORT RESPIRATION IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:DON'T USE DRY EXTINGUISHERS CONTAINING AMMONIUM COMPOUNDS. Fire Fighting Procedures:USE WATER TO COOL CONTAINERS EXPOSED TO FIRE. WEAR SCBA AND STANDARD FIRE PROTECTIVE CLOTHING. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL IGNITION SOURCES. STOP SOURCE OF SPILL AS SOON AS POSSIBLE. VAPORS MAY BE SUPPRESSED BY USE OF WATER FOG. CONTAINERIZE PURE MATERIAL IN A CLEAN DRY CONTAINERS, BEING SURE NOT TO TIGHTLY SEA L. CONTAMINATED SPILL MAY BECOME HAZARDOUS WASTE. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY SEALED. STORE IN COOL, DRY, WELL-VENTILATED AREA BELOW 125F. STORE FROM ACIDS, OTHER OXIDIZERS, ORGANIC MATERIALS & CORROSIVE LIQUIDS. Other Precautions:AVOID CONTACT W/EYES, SKIN OR CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR W/FULL FACEPIECE, CHLORINE CARTRIDGES & DUST/MIST FILTER. Ventilation:LOCAL EXHAUST TO MINIMIZE DUST & CHLORINE LEVELS Other Protective Equipment:NEOPRENE OR POLYVINYL BOOTS, APRONS, OR IMPERMEABLE SUIT Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Decomp Temp:Decomp Text:350F pH:10-12 Solubility in Water: 18% Appearance and Odor:WHITE FREE FLOWING POWDER W/CHLORINE-LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ORGANICS, NITROGEN CONTAINING COMPOUNDS, MONO-AMMONIUM PHOSPHATE CONTAINING COMPOUNDS Stability Condition to Avoid:TEMPERATURES >125F, HIGH HUMIDITY Hazardous Decomposition Products:CHLORINE GAS ==================== Disposal Considerations ==================== Waste Disposal Methods:MONITOR ALL EXIT WATER FOR AVAILABLE CHLORINE & PH. AS A HAZARDOUS SOLID WASTE, DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE, & LOCAL REGULATIONS IN PERMITTED HAZARDOUS WASTE TREATMENT, STORAGE & DISPSOA L FACILITY BY TREATMENT.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:KONTROL REGULAR TOOTHPASTE CAGE:MARKA CAGE:MARKA ============= Composition/Information on Ingredients ============= Ingred Name:NON-HAZARDOUS INGREDIENTS Other REC Limits:NONE SPECIFIED ===================== Hazards Identification ===================== Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ======================= First Aid Measures ======================= First Aid:NONE ===================== Fire Fighting Measures ===================== Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:NONE ======================Handling and Storage ====================== Handling and Storage Precautions:NONE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:NONE Other Protective Equipment:NONE Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:YES Appearance and Odor:OFF WHITE PASTE CHARACTERISTIC MINT ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:NONE
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:LIQUID HARDENER, 4351 CAGE:IO677 CAGE:IO677 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:SUPDAT:INHAL THE CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHNG VAP & (ING 5) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 4:SPRAY MIST. AVOID CONTACT W/SKIN & EYES. COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE PARTICULATES, (ING 6) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 5:SUCH AS TITANIUM DIOXIDE/CALCIUM CARBONATE, WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING OR (ING 7) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 6:ABRADING OF THE DRIED FILM IF NO SPECIFIC DUSTS ARE LISTED, THE APPLIC LIMITS FOR NUISANCE DUSTS ARE (ING 8) RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 7:ACGIH TLV 10 MG/M3 (TOTAL DUST), OSHA PEL 15 MG/M3 (TOTAL DUST), 5MG/M3 (RESPIRABLE FRACTION). RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VENT:1910.107, 1910.108. RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:HYDROGEN PEROXIDE, 30% (SARA III) CAS:7722-84-1 RTECS #:MX0900000 Fraction by Wt: <5% OSHA PEL:N/K ACGIH TLV:1 PPM Ingred Name:PHTHALIC ACID, DIMETHYL ESTER; (DIMETHYLPHTHALATE)(SARA III) CAS:131-11-3 RTECS #:TI1575000 Fraction by Wt: 40-50% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:2-BUTANONE, PEROXIDE; (METHYL ETHYL KETONE PEROXIDE) (MEKP) (SARA III) CAS:1338-23-4 RTECS #:EL9450000 Fraction by Wt: 40-50% OSHA PEL:0.7 PPM; C ACGIH TLV:1.50 MG/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:IRRIT OF EYES, SKIN AND RESP SYS. MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXPOS MAY RESULT IN UNCONSCIOUSNESS & POSSIBLY DEATH. HDCH, DIZZ, NAUS, AND LOSS OF COORDINATION ARE INDICATIONS OF EXCESSI VE EXPOS TO VAPORS OR SPRAY MISTS. REDNESS & ITCHING OR BURNING SENSATION MAY INDICATE EYE/EXCESS (EFTS OF OVEREXPOS) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HEALTH HAZARDS:SKIN EXPOSURE. CHRONIC:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND QUIET. SKIN:WASH AFFECTED AREA THORO WITH SOAP AND WATER. REMOVE CONTAM CLOTHING AND LAUNDE R BEFORE RE-USE. EYES:FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:180F,82C Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER SPRAY MAY BE INEFTIVE. IF H*20 IS USED, FOG NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD CNTNRS (SUPDAT) Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATN TO HOT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CONTENTS ARE COMBUST. KEEP AWAY FROM HEAT & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROC. KEEP CNTNR CLOSED WHEN NOT IN USE. Other Precautions:TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LBLG. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. PROD MUST BE MIXED W/OTHER COMPONENTS BEFORE USE. BEFORE OPENING PACKAGES, READ & FOLLOW WARNING LBL ON ALL COMPONENTS. (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH/MSHA FOR PROT AGAINST MATLS IN SECTION II. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST MASK/PARTICULATE RESP. Ventilation:LOC:PREF. GEN:ACCEPTABLE IF EXPOS TO MATLS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94, (ING 9) Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTO-IGNIT/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:SURFACES REQS SPECIAL PREC. DURING EMER CONDS OVEREXPOS TO DECOMP PRODS MAY CAUSE HLTH HAZ. S YMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. OTHER PREC:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & (ING 4) ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:1.15 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NOT KNOWN Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO CONTAM W/POLYM CATALYSTS SUCH AS PEROXIDES & STRONG ACIDS. DO NOT PUT ANY MIXED MATL BACK INTO CAN OF UNMIXED FILLER. Stability Condition to Avoid:STORE IN COOL AREA BELOW 90F AWAY FROM SOURCES OF HEAT. Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THIS PROD IS NOT HAZ AS DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. INCIN IN APPRVD FACILITY. DO NOT INCIN CLOSED CNTNR. DISPOSE OF IN ACCORDANCE WITH FED, S TATE AND LOCAL REGS REGARDING POLLUTION.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:AA200 IRON AA STANDARD Preparer's Name:E. BRULL CAGE:63415 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: 0.1% Other REC Limits:NONE RECOMMENDED Ingred Name:HYDROGEN NITRATE (NITRIC ACID) (SARA 302/313) (CERCLA) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: 6.3% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 PPM ACGIH TLV:2 PPM/4 STEL; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 93.6% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:RAT LC50 (VAPOR) (4-HR): 1063 PPM Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OF VAPOR/MIST MAY CAUSE RESPIRATORY ITTITATION, TISSUE DAMAGE. CONTACT MAY SKIN AND EYE BURNS, SEVERE IRRITATION. CAN BE FATAL IF INHALED OR INGESTED. MAY BE HARMFUL IF INGESTED. CHR ONIC: PROLONGED OR REPEATED EXPOSURE MAY CAUSE RESPIRATORY IRRITATION, SKIN BURNS/ULCERATIONS, EYE IRRITATION. Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. Effects of Overexposure:INHALED-COUGHING, CHOKING, SHORTNESS OF BREATH. INGESTED-SEVERE GI TRACT IRRITATION, BURNS TO MUCOUS MEMBRANES OF MOUTH & THROAT. EYES-PAIN, BURNING/STINGING SENSATION, REDNESS, BLURRED VISION. SKIN-R EDNESS, BURNS, PAIN OR DISCOMFORT. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES-CHECK FOR & REMOVE CONTACT LENSES.SEEK MEDICAL ATTENTION.DO NOT USE EYE OINTMENT.SKIN-REMOVE CONTAMINATED CLOTHES.RINSE WITH LOTS OF WATER.NEUTRALIZE WITH DILUTE SODIUM CARBONATE.GET MEDICAL ATTE NTION.INHALED-REMOVE TO FRESH AIR.SEEK IMMEDIATE MEDICAL ATTENTION.GIVE ARTIFICIAL RESPIRATION OR GIVE OXYGEN AS NEEDED.INGESTED-DO NOT INDUCE VOMITING!IF CONSCIOUS,GIVE WATER. GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:NON-FLAMMABLE. DLA-HMIS: USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:EXTREMELY EXPLOSIVE ON PRESENCE OF REDUCING MATERIALS, OF COMBUSTIBLE MATERIALS, OF ORGANIC MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PERSONAL PROTECTIVE GEAR. ABSORB WITH INERT MATERIAL AND PUT SPILLED MATERIAL IN AN APPROPRIATE WASTE DISPOSAL. IF NEEDED-NEUTRALIZE RESIDUE WITH DILUTE SOLUTION OF SODIUM CARBONATE. Neutralizing Agent:DILUTE SOLUTION OF SODIUM CARBONATE. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A METALLIC OR COATED FIBERBOARD DRUM USING A STRONG POLYETHYLENE INNER PACKAGE. STORE AWAY FROM INCOMPATIBLE MATERIALS. Other Precautions:KEEP LOCKED UP. KEEP CONTAINER DRY. KEEP AWAY FROM SOURCES OF IGNITION. KEEP AWAY FROM COMBUSTIBLE MATERIALS. DO NOT INGEST. DO NOT BREATH GAS, FUMES, VAPOR OR SPRAY. AVOID CONTACT WITH EYES, SKIN & C LOTHES. NEVER ADD WATER TO THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS. Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S). Other Protective Equipment:FULL SUIT. BOOTS. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health HCC IS BASED ON TRANSPORTATION BEING A PKG GRP I FOR TRANSPORTATION. NOTE: NFPA-3,0,0,ACID. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:B.P. Text:210F,99C Vapor Pres:19.27 Vapor Density:0.62 Spec Gravity:1.02 Solubility in Water:INSOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS, METALS, ALKALIS, ACIDS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE TO PROCESS, IF POSSIBLE. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. SARA 313: NITRIC ACID; CERCLA REPORTING: NITRIC ACID; CAL PROP 65: NONE; PA RTK & MASS RTK/EHS/MSL: NITRIC ACID. DSCL(EEC): 9,23,28,35.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:WARM RED COLORSET Preparer's Name:DICK KARBO CAGE:KMADD CAGE:KMADD ============= Composition/Information on Ingredients ============= Ingred Name:BARIUM COMPOUNDS Fraction by Wt: 28% ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN CAUSE IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:IRRITATION ======================= First Aid Measures ======================= First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>200F Extinguishing Media:FOAM, CO2, DRY CHEMICAL ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS APPROVED CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS. Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AS REQUIRED Ventilation:LOCAL EXHAUST Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS USED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:470-610F Evaporation Rate & Reference:SLOWER THAN WATER Solubility in Water:INSOLUBLE Appearance and Odor:OILY ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:FUSER OIL 8836, 93E770 CAGE:0E6G9 CAGE:0E6G9 ============= Composition/Information on Ingredients ============= Ingred Name:POLY (DIMETHYLSILOXANE); (POLYDIMETHYLSILOXANE) CAS:63148-62-9 RTECS #:JJ6484500 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) >35 G/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE MINIMAL IRRITATION OF RESPIRATORY PASSAGES ON CONTINUOUS EXPOSURE TO HIGH CONCENTRATIONS. Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY PRODUCT LITERATURE. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP & WATER. INHAL:REMOVE FROM EXPOSURE. INGEST:DILUTE STOMACH CONTENTS W/SEVERAL GLASSES OF WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:>500F,>260C Extinguishing Media:FOAM, CARBON DIOXIDE, WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:SOAK UP W/ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE REASONABLE CARE & CAUTION. CLEAN UP SPILLS COMPLETELY AS RESIDUE IS SLIPPERY. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . NONE REQUIRED WHEN USED AS INTENDED IN XEROX EQUIPMENT. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:300F,149C Vapor Pres:<5 Spec Gravity:0.98 (H*2O=1) VOC Pounds/Gallon:980 Evaporation Rate & Reference:<1 (ETHER=1) Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR LIQUID; SLIGHT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:SILICONE DIOXIDE, CARBON DIOXIDE & TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:ABSORB LIQUID ON VERMICULITE OR OTHER ABSORBENT MATERIAL. DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS. BIODEGRADATION/NON-BIODEGRADABLE, BIOACCUMULATION/NO EVIDENCE OF ACCUMULATION. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MA3157 CAGE:LO464 CAGE:96341 CAGE:LO464 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT (SARA III) CAS:7440-48-4 RTECS #:GF8750000 OSHA PEL:0.1 MG/M3;AS CO ACGIH TLV:0.05 MG/M3;DUST 9293 ===================== Hazards Identification ===================== Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION. LATENT EFFECTS:SOMATIC/GENETIC DAMAGE. ======================= First Aid Measures ======================= First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT VICTIM(S) MAY BE CON TAMINATED. ===================== Fire Fighting Measures ===================== Flash Point:B/R Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD BRTHG APP. Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE IN HEAT OF FIRE. ================== Accidental Release Measures ================== ======================Handling and Storage ====================== Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION. PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN AREA FOR RADIOACTIVE MATERIALS. Other Precautions:AVOID CONTACT WITH EYES AND SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK. Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS CLOTHING. Supplemental Safety and Health MSDS DATED:SEPT 25,1986 ================== Physical/Chemical Properties ================== HCC:A2 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL Stability Condition to Avoid:NONE NOTED Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION; FISSION PRODUCTS ==================== Disposal Considerations ==================== Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED IN ACCORDANCE WITH DOD REGULATIONS & LOCAL,STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CREOSOTE CAGE:KO910 CAGE:80592 CAGE:KO910 ============= Composition/Information on Ingredients ============= Ingred Name:CREOSOTE (SARA III) CAS:8001-58-9 RTECS #:GF8615000 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:IRRIT TO SKIN & EYES.VAPOR & FUMES EVOLVED ON HEATING IRRIT TO EYES & RESPIRAT TRACT.SKIN MAY BECOME ======================= First Aid Measures ======================= First Aid:REMOVE TO FRESH AIR.IF NOT BREATHING.GIVE ARTIFICIAL RESPIRATION, PREF MOUTH TO MOUTH.IF BREATHING IS DIFFICULT,GIVE OXYG.CALL A PHYS.INCASE OF SKIN OR EYE CONTACT,REMOV FR SKIN W/WATERLESS HAND CLEAN ER;FLUSH EYES IMMED W/PLENTY OF WATER F/AT LEAST ===================== Fire Fighting Measures ===================== Flash Point:>200F TCC >93C Extinguishing Media:CARBON DIOXIDE,WATERFOG,FOAM, DRY CHEMICAL Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCL SELF-CONTAINED BREATH APPARAT Unusual Fire/Explosion Hazard:IN CLOSED CONTAINERS CONTAINING LIQUID,PRESSURE BUILD-UP DUE TO HEAT EXPOSURE.WATER MAY BE US ================== Accidental Release Measures ================== Spill Release Procedures:CLEAN UP & PUT BACK IN CONTAINER OR WASTE RECEPTABLE.COVER W/LAYER OF SAND & SCRAPEUP.USE PROTECTIVE MEASURES OUTLINED IN SECTION VIII.DO NOT ALLOW TO GET INTO STREAM. ======================Handling and Storage ====================== Handling and Storage Precautions:COMBUSTIBLE LIQUID.STORE IN CLOSED,PROPERLY LABELED CONTAINERS IN COOL PLACE.KEEP CONTAIN & FRESHLY TREATED ARTICL AWAY FR HIGH TEMP AREAS,SPARKS,FIRE Other Precautions:DO NOT TAKE INTERNALLY.AVD PROLONGED AND/OR REPEAT BREATH OF MIST,VAP OR SUBTANT SATURATED ATMOS.AVD CONTACT W/SKIN,EYES & CLOTHING.SEE OSHA 1910.106 F/COMPLIAN REQMTS F/COMBUST LIQUIDS.IF STA ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN EXPOS ARE ABOVE TLV/SEC.II & V) & VENTIL IS INADEQUATE,USE APPR Ventilation:LOC EXHAUST-USE ADEQ VENTIL IN VOLUME & PATTERN TO KEEP WORK Other Protective Equipment:OVERALLS OR A NEOPRENE APRON TO PROTECT AGAINST CLOTHING CON Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:7356F 180 Vapor Pres:1 Vapor Density:>1 Spec Gravity:1.050 Evaporation Rate & Reference:SLOW Solubility in Water:SLIGHT Appearance and Odor:BROWN TO BLACK LIQUID W/CREOSOTE OR TARRY ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:OVERHEATING ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN APPRVD INCINERATOR OR USE APPRVD CHEMICALLY DISPOSAL FACILITY.DO NOT INCINERATE CLOSED CONTAINER.DISPOSAL MUST BE CARRIED OUT IN ACCORDANCE W/LOC,STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2%AQUEOUS GLUTARALDEHYDE SOLN(ACTIVATED) 2745,2750,2753,2783 CAGE:DO392 CAGE:DO392 CAGE:64469 ============= Composition/Information on Ingredients ============= Ingred Name:GLUTARALDEHYDE CAS:111-30-8 RTECS #:MA2450000 Fraction by Wt: 2.3% Other REC Limits:NONE RECOMMENDED OSHA PEL:C 0.2 PPM ACGIH TLV:C 0.2 PPM; 9596 Ingred Name:INERT BUFFER SALTS Fraction by Wt: 2.1% Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 95-6% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT): 17500MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:AS LISTED UNDER SIGNS AND SYMPTOMS OF EXPOSURE.CHRONIC:NONE KNOWN FORM CURRENTLY AVAILABLE INFORMATION. Explanation of Carcinogenicity:PER MSDS:NTP/IARC/OSHA:NO. Effects of Overexposure:EYE:CONTACT W/EYES CAUSES DAMAGE.SKIN:CAN CAUSE IRRIT,SENSITIZATION OR ALLERGIC CONTACT DERMATITIS.AVOID SKIN CONTACT.INHAL:VAPORS MAY BE IRRITATING AND CAUSE HEADACHE,CHEST DISCOMFORT,SYMPTOMS OF BRO NCHITITS OR ASTHMA.INGEST:MAY CAUSE NAU,VOMIT,GENERAL SYSTEMIC ILLNESS. Medical Cond Aggravated by Exposure:NONE KNOWN FROM CURRENTLY AVAILABLE INFORMATION ======================= First Aid Measures ======================= First Aid:EYE:FLUSH THOROUGHLY W/WATER.GET MED ATTN.SKIN:FLUSH THOROUGHLY W/WATER.IF IRRIT PERSISTS GET MED ATTN.INHAL:REMOVE TO FRESH AIR.IF SYMPTOMS PERSIST GET MED ATTN.INGEST:DO NOT INDUCE VOMITING.DRINK CO PIOUS AMTS OF MILK.GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:NP Lower Limits:N/DETERMINED Upper Limits:N/DETERMINED Extinguishing Media:H2O EVAPORATED MATL CAN BURN.USE CO2 OR DRY CHEM FOR SMALL FIRE.USE FOAM(ALCOHOL,POLYMER,ORDINARY),H2OFOG FOR LG FIRES. Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE AVAILABLE TO FIREMAN. Unusual Fire/Explosion Hazard:NONE. TOXIC GASES PRODUCED:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:LG SPILLS:USE AMMONIUM CARBONATE TO "NEUTRALIZE"GLUTARALDEHYD ODOR.COLLECT LIQ & DISCARD IT.SMALL SILLS:WIPE W/SPONGE OR MOP DOWN AREA W/EQUAL MIXTURE OF HOUSEHOLD AMMONIA & WATER.FLUSH W/LG QUANTITIE S OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:USE NORMAL STORAGE & HNDLG REQUIREMENTS. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ROUTINE:NONE REQUIRED.EMER:ORGANIC VAPOR CARTRIDGE MASK OR SELF-CONTAINED BREATHING APPARATUS. Ventilation:ROUTINE:SHOULD BE USED IN COVER CNTNR W/TIGHT FIT LID.USE W/STD RM VENTI(AIR CONDITIONING)W/MIN OF 10AIR CHANGES/HR(SUP) AS GLUTARALDEHYDE MAY RAPIDLY PERMEATE THRU MATL.PLAST APRON. Work Hygienic Practices:AVOID CONTAMINATION OF FOOD. EMERG Supplemental Safety and Health CIDEX FORMULA 7"LONG-LIFE ACTIVATED DIALDEHYDE SOLN/ACTIVATOR VIAL. ODOR:SHARP ODOR MASKED W/PEPPERMINT FRAGRANCE. PH=7.5-8.1. VENTI:IN RMS WHERE THERE'RE <10AIR CHANGE/HR USE LOC EXHAU HOOD OR DUCTLE SS FUME HOODS OR PORTABLE VENTI DEVICESWHICH CONTAIN FILT MEDIA WHICH ABSORB GLUTARALDEHYDE FRM AIR.EMERG:NA. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:NA Decomp Temp:Decomp Text:NP Vapor Pres:SAME ASH2O Vapor Density:>1 Spec Gravity:1.003 G/CC pH:SUPPLE Viscosity:NP Evaporation Rate & Reference:0.98, H20=1 Solubility in Water:COMPLETE Appearance and Odor:2 COMPONENTS:COLORLESS FLUID & LIQUID SALTS;TURNS GREEN WHEN ACTIVATED.(SUPPLEM Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:TRIPE RINSE EMPTY CNTNR W/WATER.DISPO IN INCINERATOR OR LANDFILL APPROVED FOR PESTICIDE CNTNRS.DISCARD SOLN W/LG QUANT OF WATER.EPA HAZ WASTE #:NA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:477 FIRE RETARDANT EPOXY, COMPONENT B Kit Part:Y CAGE:JO696 CAGE:JO696 ============= Composition/Information on Ingredients ============= Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 25-30% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SOLVENT NAPHTHA CAS:84742-94-6 Fraction by Wt: 10-15% OSHA PEL:N/K ACGIH TLV:100 PPM (MFR) Ingred Name:PROPYLENE GLYCOL METHYL ETHER CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: 5-7% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL Ingred Name:PIGMENTS; (VARIOUS PIGMENTS (MIXTURE)) Fraction by Wt: 35-45% OSHA PEL:15 PPM (MFR) ACGIH TLV:10 PPM (MFR) Ingred Name:VOLATILE ORGANIC COMPOUNDS: <250 G/L. RTECS #:9999999VO Ingred Name:SUPDAT:BY SPRAYING THEM W/WATER OR FOAM. W/DRAW IMMED FROM AREA IF CNTNRS BEGIN TO VENT/BECOME DISCOLORED DUE TO FIRE. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:OCCURS. PROVIDE OXYGEN/ARTF RESP IF REQD. INGEST:IF VICTIM IS CONSCIOUS & NOT CONVULSING, GIVE 1-2(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:GLASSES OF WATER/MILK. DO NOT INDUCE VOMIT. IF LG AMTS HAVE BEEN INGESTED, GET MED ATTN IMMED. SM AMTS ARE (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:NOT EXPECTED TO PRODUCE ILL EFTS. DO NOT ATTEMPT TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:HIGH VAPOR CONCENTRATIONS MAY CAUSE DROWSINESS OR LIGHT-HEADEDNESS. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING VAPORS MAY BE HARMFUL OR FATAL. THERE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IS CURRENTLY NO EVIDENCE OF ADVERSE EFFECTS RESULTING FROM ROUTINE EXPOSURE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/WATER. REMOVE CONTACT LENSES & FLUSH EYES W/WATER FOR AT LST 15 MINS INCL UNDERNEATH EYELIDS. CONSULT MD AS SOON AS POSS FOR IMMED FOLLOW-UP TREATMENT. SKIN:RINSE AFFECTED AREA W/CO PIOUS AMTS OF SOAP & WATER FOR AT LST 15 MINS. IMMED REMOVE & DISCARD CONTAM CLTHG. CONSULT MD IF IRRIT OCCURS/PERSISTS AFTER WASHING AFFECTED AREA. INHAL:REMOVE TO FRESH AIR IMMED IF IRRIT (ING 7) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:>115F,>46C Lower Limits:0.95% @ 93C Upper Limits:7.59% @ 93C Extinguishing Media:INORGANIC DRY CHEMICAL EXTINGUISHING COMPOUNDS, CARBON DIOXIDE, HIGH-EXPANSION CHEMICAL FOAMS. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . CNTNRS MAY DEVELOP PRESS & BURST IF EXPOS TO HEAT/FLAME. MOVE CNTNRS FROM FIRE AREA IF POSS. COOL CNTNRS(SUPDAT) Unusual Fire/Explosion Hazard:MATERIAL MAY INTURNESCE (FOAM) UPON HEATING & LOSS OF SOLVENT DURING EXPOSURE TO FLAMES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM ALL IGNIT SOURCES. PLACE LEAKING CNTNRS IN WELL VENTED AREA. WEAR PROT CLTHG & NIOSH APPRVD BRTHG APPAR. CONFINE SPILLED MATL & ABSORB W/SAND, SAWDUST, EARTH/OTHER AVAIL SOLIDS. DIKE SPILLS TO PV NT ENTRANCE INTO WATER TABLE/WATER SYS.(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:FLAMMABLE! KEEP AWAY FROM HEAT, SPARKS & OPEN FLAME. DO NOT BREATHE VAPORS. KEEP CONTAINER(S) CLOSED WHEN NOT IN USE. KEEP AWAY FROM CHILDREN. Other Precautions:DO NOT TAKE INTERNALLY. AVOID CONTACT W/SKIN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE OF NIOSH APPRVD RESP FOR USE W/ORGANIC VAPS (TC23C/EQUIVALENT) IS REQD DURING OPEN HNDLG & STD APPLICATION. NIOSH APPRVD FULL-FACE, AIR-SUPPLIED RESPS MAY BE NEC FOR EXTENSIVE SPRAY APPLICATION/FO R PERSONS PARTICULARLY SENSITIVE(SUPDAT) Ventilation:LOC EXHST:USE EXHST FANS TO MAINTAIN EXPOS LEVELS TO RESPECTIVE TLV'S FOR MATLS COMPONENTS. A MINIMUM OF 10 AIR-(SUPDAT) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . AS MAY BE NECESSARY TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health % VOLAT:15-20 (WT). SPILL PROC:SWEEP UP & PLACE MATL IN SUITABLE CNTNR. RESP PROT:TO ODORS & CHEMS BEING USED. VENT:CHANGES PER HR IS REC. PROC:WHICH HAVE BEEN EXPOS TO FLAME(ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>302F,>150C Vapor Pres:<20 @ 25C Vapor Density:5-8 Spec Gravity:1.2-1.3 Solubility in Water:NEGLIGIBLE Appearance and Odor:OPAQUE LIQUID W/CHARACTERISTIC ODOR. Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ISOCYANATES, ALCOHOLS OR ACIDS. DO NOT STORE OR TRANSFER USING COPPER ALLOYS OR ALUMINUM. Stability Condition to Avoid:DO NOT STORE OR USE IN AREAS W/OPEN SOURCES OF IGNITION. Hazardous Decomposition Products:COMBUSTION PRODUCTS CAN INCLUDE CARBON OXIDES, NITROGEN OXIDES & HYDROGEN CHLORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . INCINERATE SOLIDIFIED WASTE OR BURY IN A SUITABLE APPROVED LANDFILL.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:HAEMA-STANDBY CAGE:IO006 CAGE:IO006 CAGE:60851 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL HEXADECYL METHYL AMMONIUM BROMIDE CAS:124-03-8 RTECS #:BQ5425000 Other REC Limits:NONE RECOMMENDED Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Other REC Limits:NONE RECOMMENDED Ingred Name:GLYCOLS, POLYETHYLENE, MONO(P-(1,1,3,3-TETRAMETHYL BUTYL)PHENYL) ETHER (TRITON X) CAS:9002-93-1 RTECS #:MD0907700 Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE TRANSIENT IRRITATION.SKIN:PROLONGED EXPOSURE MAY CAUSE SLIGHT TO SEVERE IRRITATION.INGEST:MAY BE HARMFUL OR FATAL IF SWALLOWED.INHAL:LOW HAZARD FOR RECOMMENDED HANDLING. Explanation of Carcinogenicity:NOT APPLICABLE. Effects of Overexposure:NOT SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:WASH WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE;LIFT LIDS.CALL PHYSICIAN.SKIN:WASH WITH MILD SOAP OR DETERGENT AND WATER.CALL PHYSICIAN IF NEEDED.INGEST:WASH MOUTH OUT WITH WATER(IF CONSCIOUS). CALL PHYSICIAN.INHAL:REMOVE FROM EXPOSURE. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:HMIS SUGGESTS USING A SELF-CONTAINED BREATHING APPARATUS WHENEVER FIGHTING A CHEMICAL FIRE. Unusual Fire/Explosion Hazard:MANUFACTURER STATES THAT THIS PRODUCT IS NOT AN EXPLOSION OR FIRE HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILLS,FLUSH THE AQUEOUS SLOUTION DOWN THE DRAIN WITH EXCESS WATER. Neutralizing Agent:NOT KNOWN.MANUFACTURER HAS NOT GIVEN THE PH OF THE CONCENTRATE OR WORKING SOLN. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. Other Precautions:AVOID DIRECT SUNLIGHT AND EXCESSIVE COLD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. Ventilation:NONE SPECIFIED BY MANUFACTURER. Other Protective Equipment:HMIS SUGGEST HAVING AN EYE WASH STATION AVAILABLE. Work Hygienic Practices:WASH HANDS.USE APPROPRIATE HYGENIC AND SANITARY PRACTICES. Supplemental Safety and Health ALBEIT THE RAW MATERIALS LISTED ARE BELOW THE 1% OSHA THRESHOLD,INDISCRIMINANT MIXING OF THIS REAGENT WITH OTHER CHEMICALS MAY PRODUCE A HAZARDOUS SUBSTANCE. ================== Physical/Chemical Properties ================== HCC:N1 Solubility in Water:COMPLETE Appearance and Odor:LIQUID;CLEAR;SLIGHT ODOR. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES METALS AND ACIDS. Stability Condition to Avoid:AVOID EXCESSIVE HEAT OR COLD. Hazardous Decomposition Products:MANUFACTURER STATES "NONE IDENTIFIED". ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATA AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PHENOLINE 305 FINISH PART A, (0607A1NL) CAGE:06634 CAGE:06634 ============= Composition/Information on Ingredients ============= Ingred Name:CLAY (KAOLIN); (ALUMINUM SILICATE) CAS:1332-58-7 RTECS #:GF1670500 Fraction by Wt: 25% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:PIGMENT; (COLOR PIGMENT) (MIXTURE MAY CONTAIN INGS 3 - 6 IN VARYING AMOUNTS DEPENDING ON COLOR OF PRODUCT) Fraction by Wt: 20% OSHA PEL:3.5 MG/M3 (MFR) ACGIH TLV:3.5 MG/M3 (MFR) Ingred Name:MAGNETITE; (IRON OXIDES) CAS:1309-38-2 RTECS #:OM4800000 OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:OTHER PARTICULATE (NOT OTHERWISE REGULATED) OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:2-PENTANONE, 4-METHYL-; (MIBK) (SARA 313) (CERCLA) CAS:108-10-1 RTECS #:SA9275000 Fraction by Wt: 10% OSHA PEL:100 PPM ACGIH TLV:50 PPM;75 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:GLYCIDYL ETHER Fraction by Wt: 5% OSHA PEL:2 PPM (MFR) ACGIH TLV:2 PPM (MFR) Ingred Name:PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE) (SARA 313) (CERCLA) CAS:84-74-2 RTECS #:TI0875000 Fraction by Wt: 5% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 2500 MG/KG. CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:LIGROINE; (VM&P NAPHTHA) CAS:8032-32-4 RTECS #:OI6180000 Fraction by Wt: 5% OSHA PEL:300 PPM ACGIH TLV:300 PPM Ingred Name:XYLENE (SARA 313) (CERCLA). LD50:(ORAL,RAT) 4300 MG/KG. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 5% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:HYGIENE PRACT:BEFORE REUSE. LEATHER SHOES CAN ABSORB & PASS THROUGH HAZ MATLS. CHECK SHOES CAREFULLY AFTER (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:SOAKING BEFORE REUSE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION:HARMFUL IF INHALED, MAY AFFECT BRAIN OR NERVOUS SYSTEM, CAUSING DIZZINESS, HEADACHE OR NAUSEA. MAY CAUSE NOSE & THROAT IRRITATION. CONTACT:MAY CAUSE EYE/SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. NOTICE:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:SOLVENTS W/PERM BRAIN & NERV SYS DMG. NOTE:TOLUENE APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE H NDLG & EXPOS INFO . Medical Cond Aggravated by Exposure:IF SENSITIZED TO AMINES, EPOXIES OR OTHER CHEMICALS DO NOT USE. SEE MD IF MEDICAL CONDITION EXISTS. ======================= First Aid Measures ======================= First Aid:WHEN EXPOSED ALWAYS GET MEDICAL ATTENTION. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & CLEAN BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. PROVIDE O XYGEN IF BREATHING IS DIFFICULT. USE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOMITING! ALWAYS GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:68.0F,20.0C Lower Limits:0.9% Upper Limits:7.5% Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . EVACUATE HAZ AREA OF UNPROTECTED PERS. COOL SURROUNDING CNTNRS W/WATER IN CASE OF FIRE EXPOSURE. Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & WILL ACCUM. VAPS WILL FORM EXPLO CONCS W/AIR. VAPS TRAVEL LONG DISTS & WILL FLASHBACK. USE MECH VENT WHEN NEC TO KEEP PERCENT VAP BELOW LEL. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING. EVACUATE AREA OF UNPROTECTED PERS. WEAR APPROP PERSONAL PROT CLTHG & EQUIP. FOLLOW SAFE HNDLG & USE GUIDELINES. CONTAIN & SOAK UP RESIDUAL W/ABSORB (CLAY/SAND). TAKE UP(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & STRONG OXIDIZING AGENTS. KEEP CONTAINERS CLOSED. STORE IN COOL, DRY PLACE W/ADEQUATE VENTILATION. Other Precautions:IF POURING OR TRANSFERRING MATERIALS, GROUND ALL CONTAINERS & TOOLS. DO NOT WELD, HEAT, CUT OR DRILL ON FULL OR EMPTY CONTAINERS. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE ONLY W/VENT TO KEEP LEVELS BELOW EXPOS GUIDELINES. USER SHOULD TEST & MONITOR EXPOS LEVELS TO INSURE ALL PERS ARE BELOW GUIDELINES. IF NOT SURE/IF NOT ABLE TO MONITOR USE NIOSH/MSHA APPRVD AIR-PUR IFYING RESPIRATOR. Ventilation:USE EXPLOSION-PROOF VENTILATION WHEN REQUIRED TO KEEP BELOW HEALTH EXPOSURE GUIDELINES & LEL. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . RECOMMEND IMPERVIOUS CLTHG TO AVOID (SUPDAT) Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING, APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG (ING 13) Supplemental Safety and Health HAZ DECOMP PROD:HAZ. WELDING, CUTTING/ABRASIVE GRINDING CAN CREATE SMOKE & FUMES. DO NOT BREATHE. SPILL PROC:ABSORB MATL & SEAL SKIN, CHANGE CLTHG. USE OF A HAND CLEANER IS RECOMMENDED. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>232F,>111C Vapor Density:HVR/AIR Spec Gravity:1.38 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:28 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. Hazardous Decomposition Products:CARBON MONOXIDE, NITROGEN OXIDES & UNIDENTIFIED ORG CMPDS. CONSIDER ALL SMOKE & FUMES FROM BURNING MATL AS VERY (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:SODA ASH CAGE:83339 CAGE:83339 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM CARBONATE CAS:497-19-8 RTECS #:VZ4050000 Fraction by Wt: 58.0% ACGIH TLV:15 MG/CUM ===================== Hazards Identification ===================== Effects of Overexposure:DUST IRRITATES EYES & RESPIRATORY TRACT,SKIN IRRITATION.INGESTION:VOMITING,DIARRHEA,DAMAGE TO STOMAC ======================= First Aid Measures ======================= First Aid:EYES:FLUSH W/WATER.WASH SKIN W/SOAP & H*2O.STOMACH WASH IF SWALLOWED,FOLLOWED BY SALINE CATHARSIS,OR GIVE LARGE AMOUNTS OF WATER OR MILK TO DILUTE & CONSULT A DOCTOR.IF IRRITATION OF EYES PERSIST,CONS UT DOCTOR.INHALED:REMOVE TO FRESH AIR. ===================== Fire Fighting Measures ===================== Flash Point:N.A. Extinguishing Media:N.A. Fire Fighting Procedures:SELF-CONTAINING BREATHING APPARATUS BE WORN. Unusual Fire/Explosion Hazard:NONEXPLOSIVE OR INFLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM OR SWEEP SPILLED POWDER OR WASH WITH LARGE AMOUNTS OF WATER.ADD SODA ASH.MIX & NEUTRALIZE WITH 6M-HCL.AIN INTO APPROVED STORAGE CONTAINERS. ======================Handling and Storage ====================== Handling and Storage Precautions:VACUUM OR SWEEP SPILLED POWDER OR WASH WITH LARGE AMOUNTS OF WATER,AND SODA ASH,MIX & NEUTRALIZE WITH 6M-HCL.DRAIN INTO AN APPROVED STORAGE CONTAINER. Other Precautions:COVERALLS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST MASK,AS CONDITIONS WARRANT. Ventilation:LOCAL EXHAUST FOR DUSTY OPERATIONS. Other Protective Equipment:COVERALLS Supplemental Safety and Health TYPE I OR II OF FED SPEC.O-S-571.REACTIVITY DATA:COMB.OF SODA ASH & LIME DUST IN THE PRESENCE OF MOISTURE OR PERSPIRATION WILL CAUSE THE FORMATION OF IRRITATING CAUSTIC SODA. ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Spec Gravity:2.533 Solubility in Water:49.7GMS/100 Appearance and Odor:WHITE,ODORLESS,ANHYDROUS HYGROSCOPIC POWDER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:AVOID THE SIMULTANEOUS PRESENCE OF SODA ASH & LIME DUST. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:REMOVE SLOWLY INTO A LARGE CNTAINER OF WATER.ADD SODA ASH SLIGHTLY BY STIRRING.AFTER 24 HOURS,DECANT OR SIPHON INTO ANOTHER APPROVED CONTAINER.NEUTRALIZE WITH 6M-HCL & SHIP TO APPROVED DISPOSAL AREA.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:GC FORMULA 1158 CAGE:56733 CAGE:56733 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM METABISULFITE CAS:7681-57-4 RTECS #:UX8225000 Fraction by Wt: 28-30% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 9192 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHAL: PRODUCT DOES NOT EMIT FUMES. EYE: MAY IRRITATE. SKIN: MAY IRRITATE. INGEST: NOT KNOWN TO BE TOXIC, BUT INGESTION MAY CAUSE IRRITATION OR NAUSEA. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NO DATA. ======================= First Aid Measures ======================= First Aid:INHAL:NOT APPLICABLE. REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTIFICIAL RESPIRATION) . EYE:FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS. CONSULT MD IF PAIN, IRRITATIO N OR OTHER PROBLEMS PERSIST. SKIN:WASH W/WATER. CONSULT MD IF PAIN, IRRITATION OR OTHER PROBLEMS PERSIST. INGEST: GIVE WATER OR MILK. INDUCE VOMITING. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:ANY MEDIA MAY BE USED. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NO SPECIAL HAZARDS. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE CLOTHING. SMALL SPILL OF ONE GALLON OR LESS MAY BE FLUSHED TO DRAIN W/LARGE AMOUNTS OF WATER. FOR LARGER SPILLS, CONTAIN W/ABSORBENT MATERIAL. PLACE IN PLASTIC BAG. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. KEEP CONTAINER COVERED & SEALED WHEN NOT IN USE. Other Precautions:DO NOT ADD WATER OR ANY OTHER MATERIAL TO DRUM OF PRODUCT OR OTHERWISE CONTAMINATE IT. READ PRODUCT LABEL FOR FURTHER INSTRUCTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE. Ventilation:NORMAL ROOM VENTILATION. Other Protective Equipment:PLASTIC OR RUBBER APRON. Work Hygienic Practices:WASH THORO AFTER HNDLG. HAVE EYEWASH & SFTY SHOWER IN WORK AREA. REMOVE CONTAMD CLTHG. WASH CONTAMD (SEE SUPP DATA) Supplemental Safety and Health PRACT:CLOTHING BEFORE REUSE. IF LIQUID IS ABSORBED INTO SHOES OR ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:210F,99C Spec Gravity:1.1 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:COMPLETE Appearance and Odor:PALE PINK LIQUID; FAINT SULFUR ODOR. Percent Volatiles by Volume:57 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:SODIUM SULFITE EMITS SO2 FUMES IF HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN WASTE MANAGEMENT FACILITY OR IN COMPLIANCE W/FEDERAL, STATE & LOCAL REGULATIONS. IF SPILL IS NOT CONTAMINATED, YOU MAY BE ABLE TO DISPOSE OF MATERIALS WHERE NORMALLY USED.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:CARBON STEEL HR/CR LEADED CARBON CAGE:4F063 CAGE:4F063 ============= Composition/Information on Ingredients ============= Ingred Name:IRON ION (FE +2) CAS:15438-31-0 RTECS #:NO6925000 Fraction by Wt: 99% OSHA PEL:1 MG/M3 (FE) ACGIH TLV:1 MG/M3 (FE); 8990 Ingred Name:MANGANESE (SARA III) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: <2% OSHA PEL:(C) 5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST 9293 Ingred Name:GRAPHITE, SYNTHETIC CAS:7440-44-0 RTECS #:FF5250100 Fraction by Wt: <2% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST; 9293 Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: <1% OSHA PEL:15MG/M3 DUST/5 FUME ACGIH TLV:10MG/M3 DUST; 9192 Ingred Name:PHOSPHOROUS (YELLOW) (SARA III) CAS:7723-14-0 RTECS #:TH3500000 Fraction by Wt: <1% OSHA PEL:0.1 MG/M3 ACGIH TLV:0.1 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:RESPIRATORY SYSTEM/EYE IRRITATION/THROAT IRRITATION/INFLUENZA-LIKE SYMPTOMS/HEADACHE/CNS DAMAGE. ======================= First Aid Measures ======================= First Aid:IF EXPOSED TO EXCESSIVE LEVELS OF METAL FUMES, REMOVE TO FRESH AIR, SEEK MEDICAL AID IMMEDIATELY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. ===================== Fire Fighting Measures ===================== Unusual Fire/Explosion Hazard:STEEL PRODUCTS IN THE SOLID STATE PRESENT NO FIRE OR EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:ARC OR SPARK GENERATED WHEN WELDING OR BURNING COULD BE A SOURCE OF IGNITION FOR COMSTABLE AND FLAMMABLE MATERIALS. ======================Handling and Storage ====================== Handling and Storage Precautions:IN WELDING PRECAUTIONS SHOULD BE TAKEN FOR AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMPENTS OF THE WELDING ROD. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST & FUME RESPIRATOR FOR PARTICLES WHEN >TLV. Ventilation:LOCAL VENT FOR WELDING/BURNING/SAWING/GRINDING WHEN >TLV Other Protective Equipment:AS REQUIRED Supplemental Safety and Health 11/25/85. ALSO CONTAINS: SULFUR (WS4250000)/SILICON (YW2460000)/VANADIUM (VV0450000)/COLOMBIAN (1000673CO)/BISMUTH (EB26000)/LEAD CARBON LEAD (PB) (OF7525000): <1%. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NONE Vapor Density:NONE Spec Gravity:.7 Solubility in Water:NONE Appearance and Odor:GREY/BLACK, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACT W/STRONG ACID TO PRODUCE HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSER MUST COMPLY WITH FEDERAL, STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:2186, HYDROGEN PEROXIDE 30% CAGE:DO803 CAGE:DO803 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:HYDROGEN PEROXIDE CAS:7722-84-1 RTECS #:MX0899000 Fraction by Wt: 30% OSHA PEL:1 PPM ACGIH TLV:1 PPM Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70% ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT)1518 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: SEVERE IRRITATION OF RESPIRATORY SYSTEM. SKIN: SEVERE IRRITATION OR BURNS. EYE: SEVERE IRRITATION OR BURNS, PROLONGED CONTACT MAY CAUSE SEVERE EYE DAMAGE, BLINDNESS. SKIN ABSORP: NONE ID ENTIFIED. INGEST: IRRITATION OF ESOPHAGUS & BLEEDING STOMACH ULCERS. CHRONIC: NONE IDENTIFIED. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: TARGET ORGANS: EYES, SKIN, MUCOUS MEMBRANES, RESPIRATORY SYSTEM. Medical Cond Aggravated by Exposure:NONE IDENTIFIED. ======================= First Aid Measures ======================= First Aid:INGEST: CALL PHYS. IF SWALLOWED, DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP. IF BREATHING IS DIFFICULT, GIVE O*2. SKIN : IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. WASH CLOTHING BEFORE RE-USE. EYE: IMMED FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CONTR FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTRS COOL. Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIALS, FLAMMABLE MATERIALS, OR POWDERED METALS CAN CAUSE FIRE OR EXPLOSION. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO W/OUT RISK. KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC) AWAY FROM SPILLED MATL. FLUSH AREA W/FLOODING AMTS OF WATER. (USE CAUTIO N). Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE SEPARATELY & AWAY FROM FLAMM & COMBUST MATLS. KEEP CONTR OUT OF SUN & AWAY FROM HEAT. CONTR SHOULD BE COVERED & VENTED. Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION SUCEEDS TLV. @ CONCENTRATIONS ABOVE 1 PPM, A NIOSH/MSHA APPROVED SCBA IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Other Protective Equipment:UNIFORM, PROTECTIVE SUIT, LAB COAT & APRON. EMERGENCY EYEWASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 3.3 (30% SOLUTION). MATLS TO AVOID: MATERIALS; ESP. WOOD, ASBESTOS, SOIL, RUST, STRONG OXIDIZING AGENTS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:222F,106C Melt/Freeze Pt:M.P/F.P Text:-18F,-28C Vapor Pres:23.3@20C Spec Gravity:1.11(H*2O=1) pH:SUPDAT Evaporation Rate & Reference:>1(BUTYL ACETATE=1) Solubility in Water:COMPLETE (100%) Appearance and Odor:CLEAR, COLORLESS LIQUID. PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLE MATLS, STRONG REDUCING AGENTS, MOST COMMON METALS, ORG MATLS, METALLIC SALTS, ALKALIES, POROUS (SUPP DATA) Stability Condition to Avoid:HEAT. Hazardous Decomposition Products:NONE IDENTIFIED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZ WASTE NUMBER: D001, D002 (IGNITABLE, CORROSIVE WASTE).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:COMP B, ZINC RICH PRIMER, W/R, 44GY016CAT Kit Part:Y CAGE:33458 CAGE:33458 CAGE:33461 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, NITRO-; (NITROETHANE). VP:20.9 @ 77F. CAS:79-24-3 RTECS #:KI5600000 Fraction by Wt: 15% OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:22 @ 68F. CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <5% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPDAT:DEVELOP. WARNING:THIS PROD CONTAINS CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS/ (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:OTHER REPRO HARM. NOTE:TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP(ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:VOMITING. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:PRECAUTIONS HAVE BEEN READ & UNDERSTOOD. SMOKE IN SMOKING AREAS ONLY. FLAMMABLE LIQUID. RTECS #:9999999ZZ Ingred Name:VENT:REMOVE ALL IGNITION SOURCES (HEAT, SPARKS, FLAME & HOT SURFACES). RTECS #:9999999ZZ RTECS #:9999999ZZ Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:VAPS ARE IRRIT TO EYES, NOSE & THROAT. INHAL MAY CAUSE HDCHS, DFCLT BRTHG & LOSS OF CONSCIOUSNESS. INHAL:IRRIT OF RESP TRACT & ACUTE NERV SYS DEPRESS CHARACT BY FOLLOWING PROGRESSIVE STEPS:HDCH, DIZZ, STAG GAIT, CONFUSN, UNCON/COMA. SKIN:CONT CAN CAUSE IRRIT. SYMPS MAY BE SWELL, REDNESS & RASH. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EYES:LIQ, AEROSOLS/VAPS ARE IRRIT & MAY CAUSE TEARING, REDNESS & SWELL ACCOMPANIED BY STINGING SENSATION. SKIN ABSORPTION:PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DRYING & DEFAT WHICH CAN CAUSE S KIN TO CRACK. INGEST:CAN RLST IN IRRIT & POSS CORR ACTION IN MOUTH, STOM TISS & DIGEST TRACT. VOMIT MAY CAUSE (SUPDAT) Medical Cond Aggravated by Exposure:ASTHMA & ANY OTHER RESPIRATORY DISORDERS. SKIN ALLERGIES, ECZEMA & DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO AREA FREE FROM RISK OF FURTHER EXPOS. RESTORE BRTHG. ASTHMATIC TYPE SYMPS MAY DEVELOP & MAY BE IMMED/DELAYED BY SEVERAL HRS. OBTAIN MED ATTN. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA S THORO W/SOAP & WATER. WASH CONTAM CLTHG THORO BEFORE REUSE. EYES:FLUSH W/CLEAN LUKEWARM WATER (LOW PRESS) FOR AT LST 15 MINS, OCCAS LIFTING EYELIDS. OBTAIN MED ATTN. INGEST:DO NOT INDUCE (ING 6) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:45.0F,7.2C Lower Limits:1% Upper Limits:7% Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP, AUTO IGNITION OR EXPLOSION. Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT, SPKS, ELEC EQUIP & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES). VENTILATE AREA. CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN BLDGS DESIGNED TO COMPLY W/OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS, FIRE, OPEN FLAMES & SPK SOURCES. STORE IN TIGHTLY CLSD CNTNRS. Other Precautions:STORE IN WELL VENTED AREAS. KEEP CNTNRS TIGHT & UPRIGHT TO PVNT LEAKAGE. PVNT PRLNG BRTHG OF VAPS/SPRAY MISTS. PRLNG OVEREXP MAY CAUSE ALLERGIC RXN. AVOID CONT W/SKIN & EYES. DO NOT TAKE INTERNALLY. D O NOT HANDLE UNTIL MFR'S SFTY (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPRVD RESP THAT IS REC/APPRVD FOR USE IN ORG VAP ENVIRON (AIR PURIFYING/FRESH AIR SUPPLIED) IS NEC. OBSERVE OSHA REGS FOR RESP USE. VENT SHOULD BE PROVIDED TO KEEP EXPOS LEVELS BELOW OSHA PELS. Ventilation:EXHST VENT SUFFICIENT TO KEEP AIRBORNE CONCS OF SOLV VAPS/MISTS BELOW THEIR RESPECTIVE TLV'S MUST BE UTILIZED. (ING 8) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE OF LONG SLEEVE & LONG LEG CLTHG IS REC. Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM. REMOVE & WASH CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health EXPLO HAZ:REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. EFTS OF OVEREXP:ASPIR OF SOLV, RESULTING IN CHEM PNEUM. CHRONIC:PRLNG CONT WILL CAUSE DRYING & CRACKING OF SKIN, DUE TO DEFAT ACTION. SKIN SENSIT, ASTHMA/OTHER ALLERGIC RESPONSES MAY (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>230F,>110C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Spec Gravity:1.12725 Evaporation Rate & Reference:1.38 X N-BUTYL ACETATE Solubility in Water:INSOLUBLE Appearance and Odor:THIN LIQUID TO HEAVY VISCOUS MATERIAL, AMBER LIQUID W/SOLVENT ODOR. Percent Volatiles by Volume:23.4 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS & STRONG LEWIS OR MINERAL ACIDS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS OR OPEN FLAMES. AVOID UNCONTROLLED REACTIONS W/AMINES. Hazardous Decomposition Products:BY HIGH HEAT/TEMP: CARBON MONOXIDE, CARBON DIOXIDE & OXIDES OF NITROGEN. ALDEHYDES & ACIDS MAY BE FORMED DURING COMBUST. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE MUST BE DISPOSED OF I/A/W FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CNTNRS MUST BE HANDLED W/CARE, DUE TO PRODUCT RESIDUE & FLAMM VAP. DO NOT INCIN CLSD CNTNRS. EPA HAZ WAS TE #/CODE: D001, F005 (IGNITABILITY, REACTIVITY).
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:DEIONIZED WATER Preparer's Name:DGSC-SSH-ARQ CAGE:53390 CAGE:61004 CAGE:53390 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 100% Other REC Limits:NONE ===================== Hazards Identification ===================== Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:NONE Effects of Overexposure:NONE Medical Cond Aggravated by Exposure:NONE ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NONE Fire Fighting Procedures:NONE Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB ON ANY MATL. WIPE UP. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT FREEZE Other Precautions:NONE ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE Ventilation:NONE Other Protective Equipment:NONE Work Hygienic Practices:NONE Supplemental Safety and Health MSDS DATED 10-23-85. DOWNLOADED FROM HAWK CREEK LABS, CAGE 61009, SAME NSN. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:212F,100C Vapor Pres:17 Vapor Density:0.62 Spec Gravity:1.00 Evaporation Rate & Reference:1 (WATER=1) Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID. NO ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE
0
eyes_protection_not_mandatory
===================== Product Identification ===================== Product ID:CLEANING COMPOUND, SOLVENT AA-59601A TYPE I CAGE:4W432 Contract Num:SP0450-02-M-M062 CAGE:4W432 ============= Composition/Information on Ingredients ============= Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA CAS:64742-88-7 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:EYE & SKIN CONTACT: PRIMARY IRRITATION TO SKIN, DEFATTING, DERMATITIS, PRIMARY IRRITATION TO EYES, REDNESS, TEARING, BLURRED VISION. LIQUID CAN CAUSE EYE IRRITATION. WASH THOROUGHLY AFTER HANDLING. IN HALATION: ANESTHETIC. IRRITATES RESPIRATORY TRACT. ACUTE OVEREXPOSURE CAN CAUSE SERIOUS NERVOUS SYSTEM DEPRESSION. VAPOR HARMFUL. SWALLOWING: HARMFUL OR FATAL IF SWALLOWED. SWALLOWING CAN CAUSE ABDOMI NAL IRRITATION, NAUSEA, VOMITING & DIARRHEA. Explanation of Carcinogenicity:LEUKEMIA BEEN REPORTED IN HUMANS FROM BENZENE. THIS PRODUCT CONTAINS LESS THAN 1 PPM OF BENZENE. NOT CONSIDERED HAZARDOUS IN SUCH LOW CONCENTRATIONS. ABSORPTION THRU SKIN MAY BE HARMFUL. Effects of Overexposure:EYE & SKIN CONTACT: PRIMARY IRRITATION TO SKIN, DEFATTING, DERMATITIS, PRIMARY IRRITATION TO EYES, REDNESS, TEARING, BLURRED VISION. LIQUID CAN CAUSE EYE IRRITATION. WASH THOROUGHLY AFTER HANDLING. IN HALATION: ANESTHETIC. IRRITATES RESPIRATORY TRACT. ACUTE OVEREXPOSURE CAN CAUSE SERIOUS NERVOUS SYSTEM DEPRESSION. VAPOR HARMFUL. SWALLOWING: HARMFUL OR FATAL IF SWALLOWED. SWALLOWING CAN CAUSE ABDOMI NAL IRRITATION, NAUSEA, VOMITING & DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS WITH SEVERE SKIN, LIVER OR KIDNEY PROBLEMS SHOULD AVOID USE. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: FOR EYES, FLUSH WITH PLENTY OF WATER FOR 15 MINUTES & GET MEDICAL ATTENTION. SKIN CONTACT: IN CASE OF CONTACT WITH SKIN IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH THOROUGHLY WITH SOAP & WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION: AFTER HIGH VAPOR EXPOSURE, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRAT ION. SWALLOWING: IF SWALLOWED, CALL A PHYSICIAN IMMEDIATELY: DO NOT INDUCE VOMITING MAY LEAD TO PNEUMONITIS, WHICH MAY BE FATAL. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=39.4C, 103.F Autoignition Temp:Autoignition Temp Text:530F Lower Limits:1.0 Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE OR FOAM)FOR CLASS II LIQUID FIRES. Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE ON FIRE BUT CAN PROTECT FIRE-FIGHTERS/COOL CLOSED CONTAINERS. USE FOG NOZZLES IF WATER IS USED. DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER BOOTS). USE NIOSH APPROVED POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE FROM OXIDIZERS, HEAT & OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO EXTREME HEAT. APPLYING TO HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. EMPTY CONTAIN ER VERY HAZARDOUS. CONTINUE ALL LABEL PRECAUTIONS. ================== Accidental Release Measures ================== Spill Release Procedures:STOP SPILL AT SOURCE. DIKE AREA & CONTAIN. CLEAN-UP PROCEDURES: CLEAN UP REMAINDER WITH ABSORBENT MATERIALS. MOP UP & DISPOSE OF. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE ABOVE 49 C/120F. STORE LARGE AMOUNTS IN STRUCTURES MADE FOR OSHA CLASS II LIQUIDS. KEEP CONTAINER TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE TO PREVENT LEAKAGE. ISOLATE FROM OXIDIZERS, HEAT , & OPEN FLAME. USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING OF VAPOR OR SPRAY MIST. Other Precautions:AVOID CONTACT WITH SKIN, EYES.WEAR OSHA STANDARD THIS MATERIAL. WASH CLOTHING BEFORE REUSE. AVOID FREE FALL OF LIQUID. GROUND CONTAINER S WHEN TRANSFERRING. DO NOT FLAME, CUT, BRAZE, OR WELD. EMPTY CONTAINER VERY HAZARDOUS. CONTINUE ALL LABEL PRECAUTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE VAPOR, MIST GAS MASK WITHIN USE LIMITS, OR VENTILATE TO KEEP VAPORS OF THIS MATERIAL BELOW 50 PPM. IF OVER TLV, IN ACCORDANCE WITH 29 CFR 1910.134, USE NIOSH APPROVED POSITIVE-PRESSURE SELF-CONTAI NED BREATHING APPARATUS. CONSULT SAFETY EQUIPMENT SUPPLIER. USE EXPLOSION-PROOF EQUIPMENT. Ventilation:LOCAL EXHAUST: NECESSARY. MECHANICAL (GENERAL): ACCEPTABLE. SAFETY EQUIPMENT SUPPLIER. THIS MATERIAL. WASH CLOTHING BEFORE REUSE. PROVIDE READILY ACCESSIBLE EYE WASH STATIONS & SAFETY SHOWERS. Work Hygienic Practices:WASH AT END OF EACH WORKSHIFT, BEFORE EATING, SMOKING OR USING TOILET. PROMPTLY REMOVE CLOTHING THAT BECOMES CONTAMINATED. DESTROY CONTAMINATED LEATHER ARTICLE. LAUNDER OR DISCARD CONTAMINATED CLOTHING. Supplemental Safety and Health RISK STATEMENTS: HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED. COMBUSTIBLE (NORTH AMERICA). FLAMMABLE (ELSEWHERE). SAFETY STATEMENTS: IN CASE OF ACCIDENT, OR IF FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIA TELY. (SHOW THE LABEL WHERE POSSIBLE). AVOID EXPOSURE-OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:310-326-358F Vapor Pres:(MM OF HG)@20C 1.3 Vapor Density:4.7 Spec Gravity:(WATER=1): .771 API: 52. VOC Grams/Liter:6.42 Solubility in Water:NEGLIGIBLE Appearance and Odor:WATER-WHITE LIQUID. ODOR: MILD ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES & PEROXIDES. Stability Condition to Avoid:ISOLATE FROM OXIDIZERS, HEAT, & OPEN FLAME. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE FROM BURNING. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information=================== Toxicological Information:THIS PRODUCT CONTAINS NO EPA HAZARDOUS AIR POLLUTANTS (HAP) IN AMOUNTS>0.1%. ===================== Ecological Information ===================== Ecological:MAMMALIAN INFORMATION: NO MAMMALIAN INFORMATION IS AVAILABLE ON THIS PRODUCT. NO AQUATIC ENVIRONMENTAL INFORMATION IS AVAILABLE ON THIS PRODUCT. MOBILITY: THIS MATERIAL IS A MOBILE LIQUID. DEGRADABILI TY: THIS PRODUCT IS NONBIODEGRADABLE. ACCUMULATION: THIS PRODUCT DOES NOT ACCUMULATE OR BIOMAGNIFY IN THE ENVIRONMENT. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE / DISPOSE OF OBSERVING NATIONAL, REGIONAL, STATE, PROVINCIAL AND LOCAL HEALTH, SAFETY & POLLUTION LAWS. IF QUESTIONS EXIST, CONTACT THE APPROPRIATE AGENCIES. =================== MSDS Transport Information =================== Transport Information:DOT SHIPPING NAME: BULK: PETROLEUM DISTILLATES, N.O.S., COMBUSTIBLE LIQUID, UN1268, PG-III. COMBUSTIBLE LIQUID. NOT DOT REGULATED ON TRUCKS IN CONTAINERS OF <119 GALLONS. DRUM LABEL: NONE (COMBUSTIBLE LIQUID). IATA/ICAO: PETROLEUM DISTILLATES, N.O.S., 3, UN1268, PG-III. IMO/IMDG: PETROLEUM DISTILLATES, N.O.S., 3, UN1268, PG-III. EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128. ===================== Regulatory Information ===================== SARA Title III Information:SARA SECTION 311/312 HAZARDS: ACUTE HEALTH, FIRE. SARA TITLE III INGREDIENTS: MEDIUM ALIPHATIC SOLVENT NAPHTHA, CAS# 64742-88-7, 1005, (REG. SECTION, 311 & 312),RQ (LBS)-NONE. Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE ON THE TSCA LIST. THIS MATERIAL CONTAINS NO KNOWN PRODUCTS RESTRICTED UNDER SARA TITLE III, SECTION 313 IN AMOUNTS GREATER OR EQUAL TO 1%. ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:REFRIGERANT GAS R12 CAGE:Z0209 CAGE:Z0209 ============= Composition/Information on Ingredients ============= Ingred Name:DICHLORODIFLUOROMETHANE (SARA III) CAS:75-71-8 RTECS #:PA8200000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ozone Depleting Chemical:1 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ASPHYXIANT HAZARD. EVAPORATING LIQUID CAN CAUSE TISSUE FREEZING OR COLD BURNS TO SKIN AND/OR EYES. INHALATION CAUSES MILD NARCOTIC EFFECTS. Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA. Effects of Overexposure:RAPID, GASPING RESPIRATION, RAPID FATIGUE AND VOMITING, CYANOSIS, LOSS OF CONSCIOUSNESS, DEATH, TISSUE FREEZING, COL BURNS, DIZZINESS. Medical Cond Aggravated by Exposure:CAN CAUSE CARDIAC IRREGULARITIES. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH TEPID WATER OR WITH A STERILE SALINE SOLUTION. SEEK MEDICAL ATTENTION. SKIN: FLUSH AFFECTED AREAS WITH LUKEWARM WATER. DO NOT USE HOT WATER. SEEK MEDICAL ADVICE. INHALATIO N: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION AND SUPPLEMENTAL OXYGEN IF NECESSARY. FURTHER TREATMENT SHOULD BE SYMPTOMATIC AND SUPPORTIVE. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Lower Limits:NONFLAMMABLE Upper Limits:NONFLAMMABLE Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures:COOL CYLINDERS EXPOSED TO FIRE WITH WATER FROM A PROTECTED LOCATION. DO NOT APPROACH CYLINDERS SUSPECTED TO BE HOT. REMOVE COOL CYLINDERS FROM PATH OF FIRE. Unusual Fire/Explosion Hazard:IN FIRE, PRODUCT MAY DECOMPOSE TO GIVE TOXIC CORROSIVE PRODUCTS. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT INCLUDING BREATHING APPARATUS IN ENCLOSED AREA. PROVIDE GOOD VENTILATION AND ALLOW TO EVAPORATE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:CYLINDERS SHOULD BE STORED UPRIGHT AND FIRMLY SECURED TO PREVENT FALLING OR BEING KNOCKED OVER. FULL AND EMPTY CYLINDERS SHOULD BE SEGREGATED. Other Precautions:USE A FIRST IN-FIRST OUT INVENTORY SYSTEM TO PREVENT CYLINDERS BEING STORED FOR EXCESSIVE PERIODS OF TIME. DO NOT SMOKE WHERE PRODUCT IS BEING HANDLED AS THIS CAN LEAD TO INHALATION OF TOXIC BREAK DOW N PRODUCTS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS,NO RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. Ventilation:NORMAL VENTILATION FOR STANDARD PROCEDURE. PRODUCT IS HEAVIER THAN AIR SO ENSURE FLOOR LEVEL VENTILATION EXISTS. Other Protective Equipment:OVERALLS, SAFETY SHOES, Work Hygienic Practices:AVOID CONTACT WITH GAS OR LIQUID. Supplemental Safety and Health ADVICE TO DOCTOR: TREAT FOR ASPHYXIA OR COLD BURNS. MAY PRODUCE CARDIAC ARRHYTHMIA OR ARREST UNDER CIRCUMSTANCES WHERE AN ABNORMALLY LARGE AMOUNT OF ADRENALIN IS SECRETED ANDOGENOUSLY. ADRENALIN SHOUL D NOT BE ADMINISTERED IN SUSPECTED CASES. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-30F,-34C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:650 KPA Vapor Density:4.2 Spec Gravity:NOT GIVEN Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, SLIGHT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STORE AWAY FROM COMBUSTIBLE MATERIALS OR GASES. Stability Condition to Avoid:PROTECT CYLINDERS FROM PHYSICAL DAMAGE. DO NOT ALLOW THE TEMPERATURE TO EXCEED 45C. Hazardous Decomposition Products:CAN BE DECOMPOSED BY HIGH TEMPERATURES(OPEN FLAMES GLOWING SURFACES,ETC.)FORMING HYDROCHLORIC AND HYDROFLUORIC ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EUTECROD 21 FC-E CAGE:72271 CAGE:72271 ============= Composition/Information on Ingredients ============= Ingred Name:ING 12:PRESENCE OF CONTAM IN ATM (SUCH AS CHLORINATED HYDROCARB VAPS FROM CLEANSING & DEGREASING ACTIVITIES. (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:ONE RECOM WAY TO DETERM COMPOSITION & QTY OF FUMES/GASES WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:SAMPLE INSIDE WELDER'S HELMET IF WORN OR IN WORKER'S BREATHING ZONE (SEE ANSI/AWS F1.1 & AWS F1.3). RTECS #:9999999ZZ Ingred Name:VENT:TRAIN THE WORKER TO KEEP HIS HEAD OUT OF THE FUMES. RTECS #:9999999ZZ Ingred Name:EYE PROT:FILTER LENS. PROVIDE PROT SCREENS & FLASH GOGGS, IF NEC, TO SHIELD OTHERS. AS A RULE, START W/A SHADE (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:THAT IS TOO DARK TO SEE WELD ZONE. THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF THE WELD ZONE. RTECS #:9999999ZZ MAY INCL ARM PROTECTORS, APRONS, HATS, SHOULDER PROT, (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:AS WELL AS DARK SUBSTANTIAL CLTHG. TRAIN WORKER NOT TO TOUCH LIVE ELECTRICAL PARTS & TO INSULATE HIMSELF. RTECS #:9999999ZZ Ingred Name:ING 11:OF WORK AREA, QUALITY & AMT OF VENT, POSITION OF WELDER'S HEAD W/RESPECT TO FUME PLUME, AS WELL AS (ING 13) RTECS #:9999999ZZ Ingred Name:ALUMINUM (SARA III) CAS:7429-90-5 RTECS #:BD0330000 OSHA PEL:15MG/M3 TDUST;5 FUME ACGIH TLV:10MG/M3 DUST; 5 FUME Ingred Name:SILICON. PEL:10 MG/M3 TDUST; 5 RDUST CAS:7440-21-3 RTECS #:VW0400000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:ALUMINUM FLUORIDE CAS:7784-18-1 RTECS #:BD0725000 OSHA PEL:2.5 (F) MG/M3 ACGIH TLV:2.5 (F) MG/M3 Ingred Name:POTASSIUM CHLORIDE CAS:7447-40-7 RTECS #:TS8050000 Ingred Name:SODIUM CHLORIDE CAS:7647-14-5 RTECS #:VZ4725000 Ingred Name:LITHIUM FLUORIDE CAS:7789-24-4 RTECS #:OJ6125000 OSHA PEL:2.5 (F) MG/M3 ACGIH TLV:2.5 (F) MG/M3 Ingred Name:POTASSIUM FLUORIDE CAS:7789-23-3 RTECS #:TT0700000 OSHA PEL:2.5 (F) MG/M3 ACGIH TLV:2.5 (F) MG/M3 Ingred Name:MAGNESIUM CHLORIDE CAS:7786-30-3 RTECS #:OM2800000 Ingred Name:SODIUM FLUOALUMINATE; (CRYOLITE) CAS:15096-52-3 RTECS #:WA9625000 OSHA PEL:2.5 (F) MG/M3 ACGIH TLV:2.5 (F) MG/M3 Ingred Name:LITHIUM CHLORIDE CAS:7447-41-8 RTECS #:OJ5950000 Ingred Name:SUPP DATA:EXPOSED INCL:COATING ON METAL WELDED (SUCH AS PAINT, PLATING OR GALVANIZING), NUMBER OF WELDERS & VOL (ING 12) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:FUMES/GASES CAN BE DANGEROUS TO YOUR HEALTH. ACUTE:OVEREXPOS TO WELDING FUMES MAY RSLT IN DISCOMFORT SUCH AS DIZZ, NAUS OR DRYNESS/IRRIT OF NOSE, THROAT OR EYES. ARC RAY CAN INJURE EYES/BURN SKIN. ELE CTRIC SHOCK CAN KILL. FLUORIDE:FLUORIDECMPDS EVOLVED MAY CAUSE SKIN/EYE BURNS, PULM EDEMA & BRONCH. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:SILICON:POSSIBLE EYE IRRITANT. CHRONIC:MAY AFFECT PULMONARY FUNCTIONS. FLUORIDE:REPEATED EXPOSURE TO FLUORIDES CAN CAUSE SERIOUS BONE EROSION. SILICON:OVEREXPOSURE TO AMORPHOUS SILICA CAN CAU SE PNEUMOCONIOSIS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST-AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. EYES:REMOVE BY IRRIGATING W/COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. C ALL MD . INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . INGEST:CALL MD IMMEDIATELY . ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS . Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WELDING ARC, SPARKS & BRAZING FLAMES CAN IGNITE COMBUSTIBLES & FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING USE OF WELDING & ALLIED PROCEDURES. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:READ/UNDERSTAND MFRS INSTRUCTIONS & THE PRECAUTIONARY LABEL ON PRODUCT. (SEE AMERICAN NATIONAL STANDARD Z49.1 "SAFETY IN WELDING & CUTTING"). Other Precautions:WELDING FUMES/GASES CANNOT BE CLASSIFIED SIMPLY. COMPOSITION/QTY OF BOTH ARE DEPENDENT UPON METAL BEING WELDED, PROCESS, PROCEDURES & ELECTRODE USED. OTHER CNDTNS WHICH ALSO INFLUENCE COMPOSITION/QTY OF FUMES/GASES TO WHICH (SUPP DATA) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW THE RECOMMENDED EXPOSURE LIMIT. Ventilation:USE ENOUGH GEN VENT & LOCAL EXHST AT ARC, OR BOTH, TO KEEP FUMES/GASES FROM WORKER'S BRTHG ZONE & GEN AREA. (ING 16) Other Protective Equipment:WEAR HAND/HEAD/BODY PROT WHICH HELP TO PVNT INJURY FROM RADIA, SPARKS & ELEC SHOCK. SEE ANSI Z49.1. AT A MIN, (ING 19) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PROD:IN INGRED SECTION, PLUS THOSE FROM BASE METAL & COATING. REASONABLY EXPECTED CONSTITUENTS OF FUME WOULD INCL:FLUORIDES, COMPLEX OXIDES OF SILICON & OTHER METALS LISTED IN INGRED SECTIO N. GASEOUS RXN PRDS MAY INCL CO & CO*2.O*3 & NO*X MAY BE FORMED BY RADIA FROM ARC. OTHER PREC:WORKERS MAY BE (ING 11) ================== Physical/Chemical Properties ================== HCC:N1 Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:DECOMP PRODS OF NORM OPERATION INCL THOSE ORIGINATING FROM VOLATILIZATION, RXN OR OXIDATION OF MATLS SHOWN (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FEDERAL, STATE & LOC AL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:1195, ANTIQUE WHITE SATIN ENAMEL CAGE:86483 CAGE:86483 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL SPIRITS) CAS:64742-88-7 Fraction by Wt: 10-14% OSHA PEL:500 PPM (MFR) ACGIH TLV:100 PPM (MFR) Ingred Name:SOLVENT NAPHTHA; (AROMATIC H-C SOLVENTS) CAS:64742-94-5 RTECS #:WF3100000 Fraction by Wt: 2-4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND(EX WATER/EXEMPT SOLV):250 GRAMS/LITER (2.08 LBS/GAL) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:VOLATILE ORGANIC COMPOUND (IN. WATER/EXEMPT SOLVENT):250 GRAMS/LITER (2.08 LBS/GAL) RTECS #:9999999VO OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:ACUTE:SKIN:PROLONGED OR REPEATED CONTACT OF PRODUCT WITH SKIN MAY CAUSE IRRITATION. EYE:DIRECT CONTACT OF PRODUCT WITH EYES CAN CAUSE IRRITATION. INHALATION:VAPOR OR MIST CAN CAUSE HEADACHE, NAUSEA, I RRITATION OF NOSE, THROAT AND EYES. MAYPRODUCE CENTRAL NERVOUS SYSTEM DEPRESSION. INGESTION:POISONOUS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:IF SWALLOWED. MAY RESULT IN VOMITING. ASPIRATION OF VOMITUS INTO LUNGS CAUSES ASPIRATION PHEUMONITUS. CHRONIC:MAY CAUSE DAMAGE TO CENTRAL NERVOUS SYSTEM, RESPIRATORY SYSTEM, EYES AND SKIN. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:WASH AFFECTED AREAS W/WATER WHILE REMOVING CONTAMD CLTHG. GET IMMED MED ATTN. LAUNDER CONTAMD CLTHG BEFORE REUSE. EYES:FLUSH W/GENEROUS AMTS OF WATER FOR @ LEAST 15 MINS. GET IMMED MED ATTN. INGE ST:DO NOT INDUCE VOMIT. CALL PHYS IMMED. NEVER GIVE FLUIDS/INDUCE VOMIT IF VICTIM IS UNCON/HAVING CONVULSIONS. INHAL:MOVE TO FRESH AIR. AID IN BRTHG, IF NEC, AND GET IMMED MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:105F,41C Lower Limits:1.0% Upper Limits:7.0% Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:FLAMMABLE VAPOR CAN FORM EXPLOSIVE MIXTURE WITH AIR. ================== Accidental Release Measures ================== Spill Release Procedures:SPILLS SHOULD BE CONTAINED, SOLIDIFIED, & PLACED IN RCRA LICENSED FACILITY. HNDLG EQUIP TO BE GROUNDED TO PVNT SPK. WEAR ASPIRATORS, EYES & SKIN PROT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:SHOWER AFTER HANDLING THIS PROCDUCT. CLEAN CLOTHING SHOULD BE WORN DAILY. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR WHEN ABOVE PEL LIMIT. Ventilation:LOCAL EXHAUST TO CONTROL RECOMMENDED PEL. Other Protective Equipment:COVERALLS, APRONS, BOOTS. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health WASTE DISP METH:OF IN RCRA LICENSED FACILITY. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGS . ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:280F,138C Vapor Pres:<5 @ 100F Vapor Density:4.8-5.3 Spec Gravity:1.50 Evaporation Rate & Reference:<1 (BUAC =1) Solubility in Water:NEGLIGIBLE Appearance and Odor:OFF-WHITE VISCOUS LIQUID, MILD AROMATIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING, REDUCING AGENTS IN CONJUNCTION WITH HEAT. Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS OR DIRECT SUNLIGHT. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCIN IN RCRA LICENSED FACILITY. DO NOT DISCHARGE INTO WATERWAYS/SEWER SYS. EMPTY CNTNRS W/NO RESIDUE @ ALL MAY BE LANDFILLED @ LICENSED FACILITY/FOR RECONDITION. REC CRUSHING/OTHER MEANS TO PVNT UNAU THORIZED REUSE. OTHER CNTNRS MUST BE DISP (SUPDAT)
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:ASTRO GEM/LEAD FREE GLAZES,FIRED ANTIQUE,UNDERGLAZES,620-475 CAGE:EO367 CAGE:EO367 CAGE:26290 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.1 MG/M3 RDUST;9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL TRACTS. ACUTE- EYE CONTACT MAY CAUSE IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. INHALATION OF DUSTS/MISTS MAY CAUSE LUNG INJURY . HARMFUL IF INGESTED. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:CONTAINS CRYSTALLINE SILICA. Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, TEARING, SHORTNES OF BREATH Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING EYE DISORDERS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. INHALED:MOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. ORAL:CALL A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:NOT RELEVANT Upper Limits:NOT RELEVANT Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS, IF NEEDED. Unusual Fire/Explosion Hazard:NONE ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA. ABSORB ON SAND, VERMICULITE OR SIMILAR MATERIAL. SWEEP UP AND PLACE IN AN APPROPRIATE CONTAINER FOR DISPOSAL. Neutralizing Agent:NOT RELEVANT ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN. Other Precautions:DO NOT GET IN EYES, ON SKIN/ON CLOTHING. AVOID INHALATION OF DUST/MIST. FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. READ AND FOLLOW LABEL DIRECTIONS AND PRECAUTIONS. WASH AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED DUST OR FUME RESPIRATOR. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP MIST OR DUST LEVELS AS LOW AS POSSIBLE, WHILE SPRAYING. Other Protective Equipment:EYEBATH, WASHING FACILITY Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. WASH BEFORE EATING OR DRINKING. Supplemental Safety and Health ASTRO GEM GLAZES, FIRED ANTIQUES, LEAD FREE GLAZES, ONE STROKE COLORS, UNDERGLAZES, CERAMIC GLAZE(S), MISCELLANEOUS, STONEWARE GLASES, LUSTER ASTRO GEMS, SERIES 2000 GLAZES, STROKE AND COAT SERIES ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:1000F,538C Spec Gravity:1.4 - 1.6 Solubility in Water:INSOLUBLE Appearance and Odor:COLOR VARIABLE, AQUEOUS SLURRY - PRACTICALLY ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Stability Condition to Avoid:NONE Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN TRASH. OBSERVE LOCAL, STATE AND FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: DIESEL TECH 10 Cage: GANDG Proprietary Ind: Y ======================================================= Contractor Summary ======================================================= Cage: GANDG ======================================================= Ingredients ======================================================= ----------------------------- ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: EYE CONT:LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MINIMALLY IRRITATING. SKIN CONT:LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN MILDLY IRRITATING. PRLNG & RPTD CONT MAY RESULT I N VARIOUS DISORDERS SUCH AS DERM, FOLLICULITIS/OIL ACNE. INHAL:INHAL OF VAP (GENERATED AT HIGH TEMPS (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: HLTH HAZ:ONLY) OR OIL MIST FROM THIS PROD MAY RSLT IN MILD IRRIT OF UPPER RESP TRACT. INGEST:LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN SLIGHTLY TOX IF SWALLOWED. SIGNS & SYMPS:IRRIT AS NO TED. IARC HAS DETERMINED THERE IS SUFFICIENT EVID FOR CARCIN IN EXPTL ANIMALS OF USED MOTOR OILS. HNDLG PROCS & Medical Cond Aggravated By Exposure: PREEXISTING SKIN & RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. First Aid: SKIN:WASH THORO W/SOAP & WATER. REMOVE SOILED CLTHG. EYES:FLUSH W/CLEAN LOW PRESS WATER FOR AT LST 15 MINS WHILE HOLDING EYELIDS OPEN. IF IRRIT PERSISTS SEEK MED ATTN. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE OXYG IF BRTHG IS DFCLT. GET MED ATTN. INGEST:DO NOT INDUCE VOMIT, SEEK MED ATTN. NOTE TO MD:IN GEN, EMESIS INDUCTION IS UNNEC IN HIGH VISCOSITY, LOW VOLATILITY PRODS, I.E., MOST ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: LUBRICATING OIL MAY BURN, ALTHOUGH NOT READILY IGNITABLE. USE CAUT JUDGMENT WHEN CLEANING UP LG SPILLS. LG SPILLS:WEAR NIOSH APPRVD RESP & PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE TO DO S O. DIKE & CONTAIN. REMOVE W/VACUUM TRUCKS Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N). Handling And Storage Precautions: MINIMIZE SKIN CONTACT. STORE IN A COOL, DRY PLACE W/ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES & HIGH TEMPERATURES. Other Precautions: USE SOAP & WATER TO REMOVE SOIL FROM SKIN. NEVER USE GASOLINE, SOLVENTS OR HARSH ABRASIVE CLEANERS. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: 401F,205C Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, HALON, FOAM OR WATER SPRAY IS RECOMMENDED. Fire Fighting Procedures: USE NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). STOP SPILL/RELS IF IT CAN BE DONE W/OUT RISK. MOVE UNDAMAGED CNTNRS FROM FIRE AREA IF IT CAN BE DONE (SUPP DATA) Unusual Fire/Explosion Hazard: THIS MATL MAY BURN, BUT WILL NOT IGNITE READILY. IF CNTNR IS NOT PROPERLY COOLED, IT MAY EXPLODE IN HEAT OF FIRE. VAPS ARE HVR/AIR & MAY ACCUM IN LOW AREAS. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: IF MIST IS GENERATED, LOCAL EXHAUST IS SUGGESTED. Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). APRONS, ETC OF IMPERVIOUS MATL IS SUGGESTED. Work Hygienic Practices: WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE. Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N). FIRE FIGHT PROC:W/OUT RISK. WATER SPRAY MAY BE USEFUL IN MINIMIZING/DISPERSING VAPS & COOLING EQUIP TO EXPOS HEAT & FLAME. AVOID SPREADING BURNING LIQ W/WATER USED FOR COOLING PURPOSES. HAZ DECOMP PROD:& GASES WILL EVOLVE WHEN THIS ======================================================= Physical/Chemical Properties ======================================================= Vapor Density: >1 Spec Gravity: 0.88 (H*2O=1) Solubility in Water: NEGLIGIBLE Appearance and Odor: BROWN LIQUID; TYPICAL OIL ODOR. Percent Volatiles by Volume: NEGLIG ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: AVOID HEAT & OPEN FLAMES. Materials To Avoid: AVOID OXIDIZING MATERIALS. Hazardous Decomposition Products: THERMAL DECOMP PRODS ARE HIGHLY DEPENDENT ON COMBUST CNDTNS. COMPLEX MIXT OF AIRBORNE SOLID, LIQ, PARTICULATES (SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: DIESEL TECH 10 Cage: GANDG Company Name: HPW, DBA, DURO-FLO XTRA LIFE LUBRICANTS Street: 1851 1ST AVE Zipcode: 47274 Label Required IND: Y Date Of Label Review: 10/30/1996 Status Code: C Label Date: 10/30/1996 Origination Code: G Chronic Hazard IND: Y Skin Protection IND: YES Signal Word: WARNING Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Slight Reactivity Hazard: Slight Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE HAZARDOUS. ACUTE:EYE CONTACT:MINIMALLY IRRITATING. SKIN CONTACT:MILDLY IRRITATING. DERMATITIS, FOLLICULITIS OR OIL ACNE. INHALATION:MILD IRRITATION OF UPPER RESPIRATORY T RACT. INGESTION:SLIGHTLY TOXIC. CHRONIC:POSSIBLE CARCINOGEN. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:EDTA DISODIUM SALT CAGE:62910 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:EDTA DISODIUM DIHYDRATE CAS:6381-92-6 RTECS #:AH4410000 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:INHALATION: IRRITATION, COUGHING OR SNEEZING. INGESTION: LOW TOXICITY. SKIN: IRRITATION. EYES: DUST MAY CAUSE MECHANICAL IRRITATION. Explanation of Carcinogenicity:NONE Effects of Overexposure:INGESTION: LARGE AMOUNTS MAY CAUSE GASTRIC UPSET DUE TO OSMOTIC IMBALANCE THROUGH THE SEQUESTERING OF METAL IONS. SKIN: REDDENING OR INFLAMATION. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: GIVE SEVERAL GLASSES OF WATER TO DRINK TO DILUTE. SKIN: WASH W/SOAP O R MILD DETERGENT & WATER FOR AT LEAST 15 MINS. EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH APPROVED SCBA W/FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. PICK UP & PLACE IN A SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL IN A METHOD THAT DOES NOT GENERATE DUST. ======================Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING. DON'T WEAR CONTACT LENSES WHEN WORKING W/THIS MATERIAL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE EXPOSURE TO DUST IS APPARENT, A DUST/MIST RESPIRATOR MAY BE WORN. EMERGENCIES: A SELF-CONTAINED BREATHING APPARATUS MAY BE NECESSARY. Ventilation:IN GENERAL, USE DILUTION VENTILATION. USE LOCAL EXHAUST IF CONDITIONS CREATE DISCOMFORT TO WORKER. Other Protective Equipment:CLEAN BODY-COVERING CLOTHING, EYE WASH FOUNTAIN & QUICK DRENCH FACILITIES IN WORK AREA. Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Solubility in Water:10G IN 100G WATER Appearance and Odor:WHITE CRYSTALS, ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS Hazardous Decomposition Products:CO, CO2, & NITROGEN OXIDES ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE DISPOSED IN AN APPROVED HAZARDOUS WASTE FACILITY IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
1
eyes_protection_mandatory
======================================================= Product ID: 75-0299-1726-9, SCOTCHLITE GLASS BUBBLES, (SUP DAT) Cage: 1BY21 ======================================================= Contractor Summary ======================================================= Cage: 76381 Cage: 1BY21 ======================================================= Ingredients ======================================================= Cas: 65997-17-3 % Wt: 97-100 OSHA PEL: 5 MG/M3 RESP DUST ACGIH TLV: 10 MG/M3 (<7MICRONS) ------------------------------ Cas: 112945-52-5 RTECS #: VV7310000 % Wt: <3 OSHA PEL: 6 MG/M3 ACGIH TLV: 10 MG/M3 ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: EYES: MECH IRRIT INCL IRRIT, REDNESS, SCRATCHING OF CORNEA & TEARING. SKIN: MECH IRRIT INCL ITCH & REDNESS. INHAL: IRRIT (UPPER RESP) INCL SORENESS OF NOSE & THROAT, COUGHING & SNEEZING. WHILE THE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF THE INDIVIDUAL INGS IN THIS PROD & ARE REQUIRED TO BE (EFTS OF OVEREXP) Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: HLTH HAZ: INCL ON MSDS BY U.S. OSHA HAZ COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS DURING FORESEEABLE USE OF PROD: LUNG DMG INCL COUGHING, DFCLTY BRTHG, WHEEZING, TIGHTNESS IN CHEST, CONGESTION, & COUGHING UP OF BLOOD. INGEST: IRRIT OF GI TISS INCL PAIN, VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS & IN FECES. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IN HALATION: IF SIGNS/SYMPTOMS OCCUR, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL MD. INGESTION: DRINK TWO GLASSES OF WATER. CALL MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFO REGARDING PHYSICAL & HLTH HAZ, RESP PROT, VENT, & PERS PROT EQUIP. CALL (612) 733-1110 OR (612) 733-6100 FOR 24-HR SPILL ASSIST. VENT AREA. VACUUM, USE WE T SWEEPING CMPD/WATER TO AVOID DUSTING.(SUP DAT) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISP OF WASTE PROD IN SANITARY LANDFILL. SINCE REGS VARY, CONSULT APPLIC REGS/AUTH BEFORE DISP. IN THE EVENT OF AN UNCONTROLLED RELEASE, THE USER SHOULD DETERMINE IF RELEASE QUALIFIES AS REPORTABLE QT Y. DISP OF I/A/W LOC, STATE & FED REGS (FP N). Handling And Storage Precautions: AVOID EYE AND SKIN CONTACT. AVOID INHALATION OF DUST. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. Other Precautions: USE IN WELL-VENTILATED AREA. KEEP CONTAINER DRY. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: NON-COMBUSTIBLE. CHOOSE MATERIAL SUITABLE FOR SURROUNDING FIRE. Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED. ======================================================= Control Measures ======================================================= Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPRVD RESPS BASED ON AIRBORNE CONC OF CONTAMINANTS & I/A/W OSHA REGS: HALF-MASK DUST RESP, HALF-MASK HIGH-EFFICIENCY FILTER RESP, HALF-MASK SUPPLIED AIR RESP, FULL-F ACE DUST RESP, FULL-FACE HIGH- (SUP DAT) Ventilation: USE W/APPROP LOC EXHST VENT. PROVIDE APPROP LOC EXHST VENT AT TRANSFER POINTS. IF EXHST VENT IS NOT ADEQ, USE (SUP DAT) Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). WEAR COVERALLS, APRON. Work Hygienic Practices: WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER. DO NOT INGEST. Supplemental Safety and Health: TRADE NAME/PART #: TYPES B, K, L & S. SPILL PROC: CAUTION! VACUUM CLEANER COULD BE AN IGNIT SOURCE. PLACE IN APPRVD METAL CONTR & SEAL. RESP PROT: EFFICIENCY FILTER RESP, FULL-FACE SUPPLIED AIR RESP. VENT: APPROP NIOSH APPRVD RESP. ======================================================= Physical/Chemical Properties ======================================================= PH: BASIC Solubility in Water: SLIGHT Appearance and Odor: FINE POWDER (LESS THAN 10UM IN DIAMETER), WHITE, ODORLESS ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG ACIDS, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: SILICON TETRAFLUORIDE WHEN DISSOLVED IN HYDROFLUORIC ACID. Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: 75-0299-1726-9, SCOTCHLITE GLASS BUBBLES, (SUP DAT) Cage: 1BY21 Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV Street: 3M CTR Zipcode: 55144-1000 Label Required IND: Y Date Of Label Review: 11/05/1997 Status Code: C Label Date: 11/05/1997 Origination Code: G Skin Protection IND: YES Signal Word: CAUTION Respiratory Protection IND: YES Health Hazard: Slight Contact Hazard: Slight Fire Hazard: None Reactivity Hazard: None Hazard And Precautions: ACUTE: EYES: MECHANICAL IRRITATION INCLUDING IRRITATION, REDNESS, SCRATCHING OF CORNEA AND TEARING. SKIN: MECHANICAL IRRITATION INCLUDING ITCHING AND REDNESS. INHALATION: IRRITATION (UPPER RESPIRATORY ) INCLUDING SORENESS OF NOSE AND THROAT, COUGHING AND SNEEZING. INGESTION: IRRITATION OF GASTROINTESTINAL TISSUE. CHRONIC: NONE SPECIFIED BY MANUFACTURER. =======================================================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:TEFLON FLUOROCARBON RESIN FEP, TE9080 Preparer's Name:W.H. MARTIN CAGE:18873 CAGE:18873 ============= Composition/Information on Ingredients ============= Ingred Name:FLUORINATED ETHYLENE PROPYLENE COPOLYMER CAS:25067-11-2 Other REC Limits:10 MG/M3 TDUST (MFR) ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:(ACUTE) INGEST & SKIN: NOT TOXIC. EYE: MECHANICAL IRRIT. INHAL: WHEN THERMALLY DECOMPOSED BY HEATING ABOVE 260C, OR BY SMOKING TOBACCO/CIGS CONTAM W/POLYMER DUST, MAY CAUSE POLYMER FUME FEVER. SYMP AR E FLU-LIKE, W/CHILLS & FEVER, WHICH MAYNOT OCCUR UNTIL SEV HRS AFTER EXPOS & PASS OFF WITHIN 36-48(SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER. Effects of Overexposure:HLTH HAZ: HRS, EVEN IN ABSENCE OF TREATMENT. DUPONT RECOMMENDS TREATING POLYMER DUST AS A NUISANCE PARTICULATE, AND HAS ESTABLISHED AN AEL OF 10 MG/M3 TOTAL DUST, THE SAME AS THE TLV FOR OTHER NUISANC E PARTICULATES. (CHRONIC) NONE KNOWN. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INHAL: IF EXPOSED TO FUMES FROM OVERHEATING OR COMBUSTION, MOVE TO FRESH AIR. CONSULT MD IF SYMPTOMS PERSIST. EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONSULT MD IF SYMPTOMS PERSIST. SKIN: IF MOLTEN POLYMER CONTACTS SKIN, COOL RAPIDLY WITH COLD WATER. DO NOT ATTEMPT TO PEEL POLYMER FROM SKIN. OBTAIN MEDICAL ATTN FOR THERMAL BURN. INGEST: CALL MD IMMED . ===================== Fire Fighting Measures ===================== Flash Point Method:OC Flash Point:DOES NOT FLASH Extinguishing Media:WATER, CO*2, FOAM, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP TO PROT FROM HF FUMES WHICH REACT W/WATER TO FORM HYDROFLUORIC ACID. DOES NOT BURN W/O AN (SEE SUPP DATA) Unusual Fire/Explosion Hazard:TOXIC FLUORINE COMPOUNDS EVOLVED IN FIRE. HYDROGEN FLUORIDE (HF), CARBONYL FLUORIDE, CO & LOW MOLECULAR WEIGHT FLUOROCARBONS. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP TO AVOID SLIPPING HAZARD. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:AVOID CONTAMINATION. KEEP CONTAINERS CLOSED. BEFORE USING, READ TEFLON "SAFETY IN HANDLING AND USE", BULLETIN E-35824-1. Other Precautions:AVOID CONTAMINATION OF CIGARETTES OR TOBACCO WITH POLYMER DUST. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WHEN TEMPERATURE EXCEEDS 260C OR IF VENTILATION IS INADEQUATE TO MAINTAIN HF CONCENTRATION BELOW THE PEL. Ventilation:USE LOCAL EXHAUST TO COMPLETELY REMOVE VAPORS AND FUMES LIBERATED DURING HOT PROCESSING FROM THE WORK AREA. Other Protective Equipment:LONG SLEEVE SHIRT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health REFUSE FROM A FIRE INVOLVING TEFLON. HAZ DECOMP PRODS: PARTICULATE MATTER EVOLVED FROM OVERHEATING MAY CAUSE POLYMER FUME FEVER. ================== Physical/Chemical Properties ================== HCC:N1 Melt/Freeze Pt:M.P/F.P Text:527F,275C Spec Gravity:2.1-2.2 Solubility in Water:INSOLUBLE Appearance and Odor:WHITE TRANSLUCENT PELLETS WITH NO ODOR. ================= Stability and Reactivity Data ================= MOLTEN ALKALI METALS, INTERHALOGEN COMPOUNDS. Stability Condition to Avoid:TEFLON WILL BURN IN A ATMOSPHERE OF 95% OXYGEN WHEN AN IGNITION SOURCE IS PRESENT. Hazardous Decomposition Products:>260C PRODUCE CAN EVOLVE TOXIC GASEOUS MATLS SUCH AS HF & PERFLUOROOLEFINS. THE OSHA PEL FOR HF IS 3 PPM. (SUPP DATA) ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATION IN COMPLIANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. INCINERATION REQUIRES SCRUBBING OF GASEOUS PRODUCTS TO REMOVE HYDROGEN FLUORIDE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MERCURIC OXIDE CELL CAGE:2M734 CAGE:0S4X2 CAGE:NO714 CAGE:2M734 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM HYDROXIDE (CERCLA) CAS:1310-58-3 RTECS #:TT2100000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C 2 MG/M3 ACGIH TLV:C 2 MG/M3; 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MERCURIC OXIDE (SARA 302/313) (CERCLA) CAS:21908-53-2 RTECS #:OW8750000 Other REC Limits:NONE RECOMMENDED OSHA PEL:0.1 MG (HG)/M3; Z-2 ACGIH TLV:S,0.025 MG(HG)/M3;96 Ingred Name:MERCURY (SARA 313) (CERCLA) CAS:7439-97-6 RTECS #:OV4550000 Other REC Limits:NONE RECOMMENDED OSHA PEL:C, 0.1 MG/M3; Z-2 ACGIH TLV:S,0.025 MG/M3; A4;96 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ZINC (SARA 313) (CERCLA) CAS:7440-66-6 RTECS #:ZG8600000 Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MANGANESE DIOXIDE CAS:1313-13-9 RTECS #:OP0350000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG MN/M3 CEILING ACGIH TLV:5 MG MN/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY, GI TRACTS. ACUTE- BATTERY IS HERMETICALLY SEALED. CONTENTS OF AN OPEN BATTERY CAN CAUSE IRRITATION OF RESPIRATORY TRACT, SEVERE EYE IRRITATION & BURNS, SKIN IRRI TATION, BURNS. INGESTION CAN BE HARMFUL.CAUSES BURNS. AT ELEVATED TEMPERATURES, MERCURY INTOXICATION. CHRONIC- UNKNOWN. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:NONE IF BATTERY IS NOT BROKEN OR IN FIRE. OTHERWISE: SEVERE IRRITATION, CHEMICAL BURNS, PAIN Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT GENERALLY AGGRAVATE ANY MEDICAL CONDITION. ======================= First Aid Measures ======================= First Aid:IF INGESTED, DO NOT INDUCE VOMITING NOR GIVE FOOD/DRINK. SEEK MEDICAL ATTENTION IMMEDIATELY. CALL NATIONAL BATTERY INGESTION HOTLINE FOR ADVICE (202-625-3333) COLLECT DAY/NIGHT. IF INHALED, PROVIDE FR ESH AIR & CALL A DOCTOR. IF SKIN IS CONTAMINATED, REMOVE CLOTHING & WASH SKIN WITH SOAP & WATER. IF IRRITATION PERSISTS, SEE DOCTOR. FOR EYE, FLUSH IMMEDIATELY WITH WATER FOR 15 MINUTES. SEE DOCTOR. ===================== Fire Fighting Measures ===================== Flash Point:NOT RELEVANT Lower Limits:NOT GIVEN Upper Limits:NOT GIVEN Extinguishing Media:IN BULK STORAGE AREAS, USE FOAM OR DRY CHEMICAL. WATER SPRAY MAY CAUSE ELECTRCICAL SHORTS. Fire Fighting Procedures:AS WITH ANY FIRE, WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:LIKE ANY SEALED CONTAINER, BATTERY CELLS MAY RUPTURE RESULTING IN RELEASE OF CORROSIVE MATERIAL AND TOXIC MERCURY VAPOR. ================== Accidental Release Measures ================== Spill Release Procedures:IF BROKEN, COLLECT AND TRANSFER TO PROPER Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA. ELEVATED TEMPERATURES CAN RESULT IN SHORTENED BATTERY LIFE. KEEP OUT OF REACH OF SMALL CHILDREN. Other Precautions:DO NOT CARRY BATTERIES LOOSE IN POCKET, PURSE/BAG. DO NOT MIX BATTERY SYSTEMS (MERCURY ALKALINE/ZINC CARBON) IN SAME EQUIPMENT. DO NOT OPEN BATTERY, DISPOSE IN FIRE, RECHARGE, PUT IN BACKWARDS. MAY EX PLODE OR LEAK AND CAUSE PERSONAL INJURY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NECESSARY UNDER NORMAL CONDITIONS. WEAR A NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WHEN CELLS ARE INVOLVED IN A FIRE. Ventilation:SUBSEQUENT TO A FIRE, PROVIDE AS MUCH AS VENTILATION AS POSSIBLE. Other Protective Equipment:NOT NECESSARY UNDER NORMAL CONDITIONS. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health PERCENTAGES OF INGREDIENTS VARY ACCORDING TO TYPE OF CELL USED WITHIN THE BATTERY. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Vapor Pres:NOT GIVEN Vapor Density:NOT GIVEN Spec Gravity:NOT GIVEN Viscosity:NOT RELEVANT Evaporation Rate & Reference:NOT RELEVANT Solubility in Water:NOT RELEVANT Appearance and Odor:BATTERY - ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:EXCESSIVE HEAT, ELECTRICAL SHORTING, CRUSH, PUNCTURE, DISASSEMBLE, RECHARGE Hazardous Decomposition Products:HAZARDOUS MERCURY VAPORS AND CAUSTIC POTASSIUM HYDROXIDE ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN LANDFILL IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:POLYETHYLENE GLYCOL 300, PX1286A CAGE:63612 CAGE:63612 ============= Composition/Information on Ingredients ============= Ingred Name:POLYETHYLENE GLYCOL CAS:25322-68-3 RTECS #:TQ3500000 = Wt:100. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LDRO (ORAL, RAT): 27500 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO Health Hazards Acute and Chronic:MAY CAUSE NAUSEA IF SWALLOWED. Explanation of Carcinogenicity:THE MATERIAL IS NOT LISTED (IARC, NTP, OR OSHA) AS CANCER-CAUSING AGENT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER AND INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:=196.1C, 385.F Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. DO NOT SPRAY FIRE DIRECTLY; MAY CAUSE FROTHING. Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC FUMES. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER CONTROL MEASURES SECTION. ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZS. CONTAIN RELEASE & ELIM ITS SOURCE, IF THIS CAN BE DONE W/OUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP. COMPLY W/FED, STATE, & LOC REGS ON REPORTING RELEASES. REFER TO REGULATORY INFO FOR RQ & OTHER REGULATORY DATA. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY AREA. DO NOT GET IN EYES. RETAINED RESIDUE MAY MAKE EMPTY CONTAINERS HAZARDOUS; USE CAUTION! AVOID PROLONGED OR REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. Supplemental Safety and Health CHEMICAL FAMILY: POLYMER. FORMULA: HO(C*2H*4O)*NH. MOLECULAR WEIGHT: 285 - 315. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:>-15.C, 5.F M.P/F.P Text:-15C TO -8C Spec Gravity:1.1 (H*2O=1) Solubility in Water:SOLUBLE Appearance and Odor:CLEAR LIQUID WITH MILD ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS. Stability Condition to Avoid:EXTREME HEAT; IGNITION SOURCES. Hazardous Decomposition Products:CO*X. =================== Toxicological Information=================== Toxicological Information:TOXICOLOGICAL FINDINGS: NONE. CITED IN REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS). ==================== Disposal Considerations ==================== Waste Disposal Methods:MATERIAL DOES NOT HAVE AN EPA WASTE NUMBER AND IS NOT A LISTED WASTE, HOWEVER CONSULTATION WITH A PERMITTED WASTE DISPOSAL SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME: NON-REGULATED. DOT ID NUMBER: NONE. ===================== Regulatory Information ===================== SARA Title III Information:THE CHEMICAL IS NOT COVERED BY SARA EHS (302), SARA EHS TPQ, CERCLA RQ, SARA 313. Federal Regulatory Information:TSCA: THE CAS NUMBER OF THIS PRODUCT IS LISTED ON THE TSCA INVENTORY. State Regulatory Information: ======================= Other Information =======================
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:PLY-TILE 700 GLOSS & SEMI GLOSS COATING PAR CAGE:85519 CAGE:85519 ============= Composition/Information on Ingredients ============= Ingred Name:EFTS OF OVEREXPO: CHRONIC EXPO HAVE NOT BEEN FULLY INVESTIGATED. RPTD HANDLING/USE MAY PRESENT ADDNL HAZ. (SEE INGRED 8) RTECS #:9999999ZZ Ingred Name:INGRED 7: EXERCISE DUE CARE. RTECS #:9999999ZZ Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 14-42% Other REC Limits:NONE SPECIFIED OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: < 18% Other REC Limits:PEL: .08 MG/M3 (MFG) OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:SILICA, CRYSTALLINE - FUSED CAS:60676-86-0 RTECS #:VV7328000 Fraction by Wt: < 17% Other REC Limits:NONE SPECIFIED OSHA PEL:SEE TABLE Z3 ACGIH TLV:0.1 MG/M3 RDUST;9293 Ingred Name:STODDARD SOLVENT CAS:8052-41-3 RTECS #:WJ8925000 Fraction by Wt: 5-16% Other REC Limits:PEL: 500 PPM (MFG) OSHA PEL:500 PPM ACGIH TLV:100 PPM; 9293 Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER CAS:107-98-2 RTECS #:UB7700000 Fraction by Wt: 1-3% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 Ingred Name:ACETIC ACID (2-METHOXY-1-METHYLETHYL ESTER) (VP 3.8) CAS:108-65-6 RTECS #:AI8925000 Fraction by Wt: 3-8% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM ACGIH TLV:100 PPM ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE INHAL: CAN CAUSE ANESTH RXN. POSS ACUTE NERV SYS DEPRESS/IRRIT OF RESP TRACT CHARAC BY HDCH/DIZZ/STAG GAIT/CONFUSN UNCON/COMA. NOTE: INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS MAY BE HARM FUL/FATAL. REPORTS HAVE ASSOC RPTD & PRLNG OCCUP EXPO TO SOLV W/PERM BRAIN & NERV SYS DMG. (SEE EFTS OF OVEREXPO) Explanation of Carcinogenicity:CRYSTALLINE SILICA (CAS NUMBER 14808-60-7) LISTED IN IARC-2A. Effects of Overexposure:ACUTE SKIN/EYE: MAY CAUSE SLIGHT TRANSIENT EYE IRRIT. MAY CAUSE ALLERGIC SKIN RXN IN SUSCEPTIBLE INDIVIDUALS. RPTD EXPO MAY CAUSE SKIN IRRIT. PRLNG EXPO NO LIKELY TO CAUSE SIGNIFICANT SKIN IRRIT. CHRO NIC INHAL & SKIN/EYE CONTACT: SKIN SENSITIVITY MAY RESULT FROM RPTD EXPO. OTHERWISE THE EFTS OF EXCESSIVE.(SEE INGRED 7) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHNG. (GIVE O*2/ART RESP) . KEEP WARM & QUIET. EYES: FLUSH W/LARGE AMTS OF WATER FOR AT LEAST 15 MIN. REMOVE CONTAMINATED CLOTHING. CONSULT MD. INGEST: CALL MD IMMEDIATELY . SKIN: WASH AFFECTED ARE WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT MD. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:115F,46C Lower Limits:SEE INGRED Extinguishing Media:APPROVED CLASS B FIRE EXTINGUISHER OR EXTING AGENT EX. CO*2,DRY CHEMICAL, FOAM. Fire Fighting Procedures:FULL PROT EQUIP INCLUDING NIOSH/MSHA APPROVED SCBA. H*2O SPRAY MAY BE INEFFECTIVE. IF H*2O IS USED, FOG NOZZ ARE PERFERABLE. H*2O MAY BE (SEE SUPP DATA) Unusual Fire/Explosion Hazard:COMBUSTIBLE. KEEP CNTNRS TIGHTLY CLOSED. ISOLATE FROM HEAT & FLAME. CLOSED CNTNRS MAY EXPLODE WHEN EXPO TO EXTREME HEAT. APPLICATION TO HOT (SEE SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAME AND HOT SURFACES). VENT AREA & AVOID BRTHNG VAPS. CONTAIN & REMOVE WITH INERT ABSORRBENT MATERIAL USING NON-SPARKING TOOLS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN SUN/OR ABOVE 120F. STORE LRG AMTS IN BUILDINGS DESIGNED FOR FLAM/COMBUSTIBLE LIQ. Other Precautions:DO NOT TAKE INTERNALLY OR WELD/FLAME CUT WITHOUT PROPER VENTILATION TO INSURE THE AREA IS FREE OF FAM. VAPS. DO NOT CUT, PUNCTURE OR WELD ON OR NEAR CNTNR. CLOSED STORAGE TANKS ENTRANCE:USE NIOSH/MSHA APPROVED RESP FOR SOLV/CHEM FUMES EXPO. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER RESPIRATOR DESIGNED TO REMOVE A COMBINATION OF PARTICULATE & VAP. Ventilation:ALL APPLICATION AREAS SHOULD BE VENTILATED I/A/W OSHA REGULATION 29 CFR 1910 DURING USE & UNTIL AREA IS FREE OF VAPS. Other Protective Equipment:PROTECTIVE SKIN CREAM. CLEAN UNCONTAMINATED CLOTHING. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: H*2O USED TO COOL CLOSED CNTNRS TO PREVENT PRESS BUILD-UP & POSS AUTO IGNIT/EXPLOSION WHEN EXPO TO EXTREME HEAT. EXPLO HAZ: SURFACES REQUIRES SPECIAL PREC. DURING EMERGENCY COND, OVER EXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. CONSULT MD. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:243F,117C Vapor Pres:SEE INGRED Vapor Density:HEV/AIR Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, ACIDS OR BASES & SELECTED AMINES. CONSIDERABLE HEAT MAY BE RELEASED UPON RXN W/THESE MATRLS. Stability Condition to Avoid:HIGH TEMPERATURES AND FLAME. Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, ALDEHYDES AND ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULAYTIONS .
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:MEDIUM DRY AQUEOUS RECORDER INK, 61100GMA Preparer's Name:GEORGE SARKISIAN CAGE:17405 CAGE:17405 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM, (4-(P-(DIMETHYLAMINO)-ALPHA-(P-(ETHYL(M-SULFOBENZYL) AMINO PHENYL) BENZYLIDE NE)-2,5-CYCLOHEXADIEN-1-YLIDENE)ETHYL(M-SULFOBENZYL)-,HYDROXIDE,INN ER SALT,SODIUM SALT;(C.I. ACID VIOLET 49,DYE) CAS:1694-09-3 RTECS #:BQ1140000 Fraction by Wt: 0.5-1.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER % (WT): 98.5 - 99.5 CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: >98.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NON-HAZARDOUS INGREDIENTS OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): >5 GM/KG Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: SKIN: CAN CAUSE IRRITATION AND SKIN STAINING. EYES: CONTACT MAY CAUSE IRRITATION. INHALATION: INHALATION OF VAPORS MAY RESULT IN RESPIRATORY IRRITATION. INGESTION: MAY RESULT IN GASTRIC DISTURB ANCE. CHRONIC: NONE EXPECTED BASED ON EMPLOYEE HISTORY OF EXPOSURE. Explanation of Carcinogenicity:C. I. ACID VIOLET 49: IARC MONOGRAPHS, SUPP VOL 7, PG 56, 1987: GROUP 2B. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYE: FLUSH WITH WATER FOR AT LEAST 15 MINUTES MINIMUM. IF IRRITATION PERSISTS, GET PROMPT MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH SKIN THOROUGHLY WITH SOAP AND WATER. INHAL: REM OVE PERSON TO FRESH AIR. AID BREATHING IF NECESSARY AND GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DILUTE WITH WATER AND INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NOT FLAMMABLE Extinguishing Media:USE MEDIA PROPER TO PRIMARY CAUSE OF FIRE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:WIPE UP SPILLS WITH TOWELS OR CLOTHS. REMOVE STAINS WITH SOAPY WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ======================Handling and Storage ====================== Handling and Storage Precautions:NO SPECIAL REQUIREMENTS. Other Precautions:NONE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR, IF VAPORS OR MIST ARE GENERATED. Ventilation:MECHANICAL (GENERAL) VENTILATION IS SATISFACTORY. Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health VAPOR DENSITY: DUE TO H*20 ONLY. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>212F,>100C Vapor Pres:DUE TO H*2O ONLY Vapor Density:SUPDAT Spec Gravity:1.038-1.055 (H*20=1) pH:4.0-8.0 Evaporation Rate & Reference:DUE TO H*2O ONLY Solubility in Water:COMPLETE Appearance and Odor:BLACK, RED, BLUE, GREEN, ORANGE, PURPLE; SLIGHT CHARACTERISTIC ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS WITH STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:ACROLEIN. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH EXISTING FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
1
eyes_protection_mandatory
===================== Product Identification ===================== Product ID:RITE-LOK PRIMER N, PN: AC64; MIL-S-22473E GRADE N, FORM R (1 Preparer's Name:JAY TATE CAGE:0ZDS4 CAGE:0ZDS4 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 99% OSHA PEL:1800MG/M3;750PPM TWA ACGIH TLV:1780MG/M3;750 PPMTWA EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ORGANO COPPER COMPOUND CAS:1338-02-9 RTECS #:QK9100000 Fraction by Wt: 1% OSHA PEL:0.1 MG/M3; ACGIH TLV:0.2 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE HEALTH HAZARD ACUTE AND CHRONIC. Health Hazards Acute and Chronic:THRESHOLD LIMIT VALUE: SHORT TERM: 1000 PPM, LONG TERM: 750 PPM. EFFECTS OF OVEREXPOSURE: INGESTION - IF SIGNIFICANT QUANTITY INGESTED, MAY DULL SENSES (ORAL LD50 >5000 MG/KG). INHALATION - MAY CAUSE NAUSEA, HEADACHE, DIZZINESS AND IRRITATION OF RESPIRATORY TRACT. SKIN AND EYES - IRRITATION ON CONTACT. (EST. DERMAL LD50 >500 MG/24TH). SKIN AND EYE IRRITANT, VAPORS HARMFUL. Medical Cond Aggravated by Exposure: ======================= First Aid Measures ======================= First Aid:INGESTION - DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN MEDICAL ATTENTION. INHALATION - REMOVE TO FRESH AIR (OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED). OBTAIN MEDICAL ATTENTION (NOTE TO PHY SICIAN: USE OF EPINEPHRINE IS CONTRA-INDICATED). SKIN - FLUSH WITH WATER AND WASH WITH SOAP. EYES - FLUSH WITH PLENTY OF WATER, CONTACT A PHYSICIAN. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-17.C, 1.3F Autoignition Temp:=465.C, 869.F Lower Limits:2.5 Upper Limits:12.8 Extinguishing Media:CO2, FOAM, DRY CHEMICAL Fire Fighting Procedures:SELF CONTAINED BREATHING GEAR AND PROTECTIVE CLOTHING. VERY HIGHLY FLAMMABLE! Unusual Fire/Explosion Hazard:DIRECT WATER JET WILL SPREAD BURNING MATERIAL. COMBUSTION PRODUCTS ARE VERY TOXIC AND HIGHLY IRRITATING. COOL SEALED DRUMS WITH WATER SPRAY TO LESSEN CHANCE OF RUPTURE. CONTAINER EXPLOSION CAN OCCUR, VAPOR FORMS EXPLOSIVE MIXTURE IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:PERMIT ONLY PROPERLY PROTECTED WORKERS WITH SMALL SPILLS WITH ABSORBENT MATERIAL, OR LET EVAPORATE IN WELL VENTILATED AREA. PUMP LARG E SPILLS INTO SALVAGE TANKS. ======================Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL DRY PLACE. AVOID CONTACT WITH EYES, AVOID VAPOR. Other Precautions:KEEP AWAY FROM ALL HEAT AND FLAMES. KEEP CONTAINER CLOSED WHEN NOT IN USE, KEEP WELL VENTILATED. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ABOVE TLV. NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:LOCAL EXHAUST RECOMMENDED. Other Protective Equipment:PROTECTIVE PLASTIC OR RUBBER APRON. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:=56.1C, 133.F Vapor Pres:181 MMHG @20C Vapor Density:2.0 AIR=1 Spec Gravity:0.79 H20=1 VOC Pounds/Gallon:790 pH:APPROX. 7 Viscosity:2-3 CPS Evaporation Rate & Reference:>7 ETHER=1 Solubility in Water:COMPLETE Appearance and Odor:GREEN LIQUID WITH SWEET, PUNGENT ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS AND PEROXIDES. Hazardous Decomposition Products:NONE ==================== Disposal Considerations ==================== Waste Disposal Methods:LANDFILL OR INCINERATE IN ACCORDANCE WITH EPA AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT: PROPER SHIPPING NAME - ACETONE SOLUTION. IATA: PROPER SHIPPING NAME - ACETONE SOLUTION. IMDG: PROPER SHIPPING NAME: DANGEROUS GOODS SHIPPED IN LIMITED QUANTITY. US POSTAL SERVICE: PROHIBITED.
1
eyes_protection_mandatory